August 10, 2015    Ms. Laura Chern, P.G.  Wisconsin Department of Natural Resources  PO Box 7921  Madison, Wisconsin 53707‐7921    RE:  Groundwater Monitoring Network Documentation    Results of July 2015 Groundwater Sample Analyses    Central Sands Dairy, LLC    WPDES Permit No. WI00063533‐02‐0    Town of Armenia, Juneau County, Wisconsin    Dear Ms. Chern:  Pursuant to our approved groundwater monitoring plan RJN returned to the Central Sands  Dairy (CSD) on July 23, 2015 for groundwater sampling.  Groundwater Flow  Table 1 summarizes groundwater elevations as measured on July 23, 2015 by RJN.  Although  irrigation wells were being utilized in the area on July 23, the water levels were comparable to  those measured in April, indicating that the irrigation wells appear to have little effect on  groundwater levels beyond the field boundaries (note that the irrigation system in the field  adjacent to the CSD‐1 nest was operating at the time of water level measurements).  Vertically, the gradient at the CSD‐1 nest was flat, with water levels in each well at 942.55 feet  (MSL); a slight upward gradient was present at the CSD‐3 nest.   Figure 1 shows the water table as measured on July 23.  The flow is slightly more easterly than  measured at previous times, but still in a generally east‐southeasterly direction.    Groundwater Quality  Groundwater samples were collected from site monitoring wells on July 23, 2015.  Prior to  sampling, water levels were measured in all wells.  Wells were then purged using low flow  methodology.  Wells were pumped using a Geopump peristaltic pump and water quality was  monitored in a flow‐through cell using a Horiba U‐52 meter.  Field measurements of  temperature, pH and conductivity were taken after the removal of each casing volume.  Purge  water was discharged to the facility’s wastewater system.  When the field‐measured  802 West Broadway, Suite 200, Monona, Wisconsin 53713  Phone:  608.576.3001      Ms. Laura Chern  August 10, 2015  Page 2    parameters had stabilized, samples were collected in containers provided by TestAmerica.  The  samples were then placed in an iced cooler.  Field sampling sheets are provided in Attachment  1.  Because of a short (24‐hour) hold time for bacteria samples, those samples were not sent to the  TestAmerica laboratory.  Instead, they were delivered on the morning of July 24, 2015 to the  Wisconsin State Laboratory of Hygiene, in Madison.  Pursuant to the CSD work plan, samples  were analyzed for:            Total dissolved solids  Chloride  Chemical oxygen demand  Ammonium  Total Kjeldahl nitrogen  Total organic carbon  Total coliform bacteria (count)  E. Coli (count)  Nitrogen (nitrite+nitrate)  Potassium  Results of the analyses are summarized in Table 1; the laboratory reports are provided in  Attachment 2.    Coliform was not detected in any of the samples; however, E. Coli was present in CSD‐1D (count  of 11), CSD‐3S (5) and CSD 3D (200).  This is a distinction from the April sampling event, in which  coliform was present in all samples, but E. Coli was not detected in any samples.  Due to a lack  of downward gradient, it is not likely that the presence of E. Coli in the deeper wells are derived  locally, especially in CSD‐3D, which is the most upgradient well location.  Preventive Action Limits (PALs) for ammonium were exceeded in samples from CSD‐1S and  CSD‐1D, as was the case in the April samples; however, the remaining samples yielded  ammonium concentrations significantly below the PAL, if at all.  CSD‐1D results were more  elevated than CSD‐1S.  The ES for nitrite+nitrate was exceeded in samples from CSD‐1D and CSD 4.  The PAL for  nitrite+nitrate was exceeded in samples from CSD‐1S, CSD‐2, and CSD‐3D.  As with previous  rounds of samples, the highest concentrations occurred in the samples (sample and duplicate)  collected from CSD‐4, which is at an upgradient location on the property.  No other ES or PAL  exceedances were detected.  Total organic carbon is present in all samples.  Although there are no data to indicate  background concentrations (because wells CSD‐3 and CSD‐4 are at upgradient locations, and  groundwater has been impacted at those locations), the concentrations appear somewhat  elevated.          Ms. Laura Chern  August 10, 2015  Page 3    As with total organic carbon, we have no data to indicate background concentrations of  chemical oxygen demand.  Again, the highest chemical oxygen demand occurred at well CSD‐4  indirectly indicating the presence of a greater amount of organic compounds at that upgradient  location.  Potassium concentrations remained consistent in the individual wells.  Ammonium concentrations remain stable in the CSD‐1 nest.  As discussed previously, that  location is downgradient from the lagoon; however a recent inspection found the lagoon  construction to be in good working condition.  Additionally, we have seen no variation in  ammonium levels in the CSD‐1 nest, even though the volume of manure contained in the  lagoon varies over the course of the year.  Sincerely,  RJN ENVIRONMENTAL SERVICES, LLC  Robert J. Nauta, P.G.  Hydrogeologist    Cc:        James Wysocki – Central Sands Dairy  David Crass, Esq. – Michael, Best & Friedrich      FIGURE CSD-3 94 3. 5 94 3 943 943.5 944 CSD-1 944 .5 945 945 .5 943 . 944 944.5 945 945 .5 94 6 94 6. 9 46 5 5 94 4 944. 5 945 946 946 .5 94 7 945.5 CSD-4 CSD-2 AERIAL PHOTO: GOOGLE MAPS WATER TABLE MONITORING WELL 946 SCALE IN FEET 0 100 200 300 400 GROUNDWATER ELEVATION (FT, MSL) Surface Water Studies Groundwater Studies Site Investigations 4631 COUNTY ROAD A OREGON, WISCONSIN 53575 (608) 576-3001 CENTRAL SANDS DAIRY, LLC TOWN OF ARMENIA, WISCONSIN WATER TABLE - 23 JULY 2015 DRAWN BY RN PROJ. No. 14-203 DATE 28 JUL 15 FILE WTR TBL 0715 ATTACH ENT 1 RJN Environmental Services, LLC Well number: W778 Groundwater Sample Collection Record Client: Central Sands Dairy Date: 7/23/2015 Project No.: 14-203 Time start: Site Location: Juneau County, WI Finish: 3 30 Wether conditions: Water Level Data: Well: Piez: Total Depth: 28.32 Diameter: 2" Water column: 7- 4 Depth to water: "Li a 0g Well volume: 2/ gal. Purging data: Method: Low flow Acceptance criteria: Minimum purge volume (3 volumes): 3 - (9 gal. Stabilization: pH: 0.1 Temp: 10% Cond: 5% Removed pH hos 25.4 . 25.5 0.2) . i) ?0-7?2 5. 795? 69- 29?? .0, 0~'Zl Sampled by: Nauta Date: 7/23/2015 RJN Environmental Services, LLC Well number: CSD-1D W779 Groundwater Sample Collection Record Client: Central Sands Dairy Date: 7/23/2015 Project No.: 14-203 Time start: up Site Location: Juneau County, WI Finish: 5-.) Wether conditions: Water Level Data: Well: Piez: Total Depth: 49.57 Diameter: 2" Water column: a .59? Depth to water: 2. a. 93 Well volume: gal. Purging data: Method: Low flow Acceptance criteria: Minimum purge volume (3 volumes): 5 gal. Stabilization: pH: 0.1 Temp: 10% Cond: 5% Removed 4 .03 9. .0 . 24-50 (ply-4' .01 6 .0 hos 0 ?52} (as: ?0 as; 0? Sampled by: Nauta Date: 7/23/2015 RJN Environmental Services, LLC Well number: CSD-2 VU928 Groundwater Sample Collection Record Client: Central Sands Dairy Date: 7/23/2015 Project No.: 14-203 Time start: Site Location: Juneau County, WI Finish: 153 Wether conditions: Water Level Data: Well: Piez: Total Depth: 26.22 Diameter: 2" Watercolumn: 2 . if Depth to water: Well volume: L5 gal. Purging data: Method: Low flow Acceptance criteria: Minimum purge volume (3 volumes): 5 gal. Stabilization: pH: 0.1 Temp: 10% Cond: 5% Removed l~5? Zl. ?50 ZZ-LL - 49* 22.44 .2 (pi) 114? 52,2, Sampled by: Nauta Date: 7/23/2015 RJN Environmental Services, LLC Well number: CSD-BS VU925 Groundwater Sample Collection Record Client: Central Sands Dairy Date: 7/23/2015 Project No.: 14-203 Time start: 0 9 2 5 Site Location: Juneau County, WI Finish: [0 5' Wether conditions: Water Level Data: Well: Piez: Total Depth: 25.51 Diameter: 2" Water column: . 3 Depth to water: ?8 Well volume: 1 Ln gal. Purging data: Method: Low flow Acceptance criteria: Minimum purge volume (3 volumes): 4'3 gal. Stabilization: pH: 0.1 Temp: 10% Cond: 5% Removed hos ?at-'2 4-9 0.310 22 . 0.30? 2 93" 060 2.2. 9 - 530 Sampled by: Nauta Date: 7/23/2015 RJN Environmental Services, LLC Well number: CSD-3D VU926 Groundwater Sample Collection Record Client: Central Sands Dairy Date: 7/23/2015 Project No.: 14-203 Time start: Site Location: Juneau County, WI Finish: 09 I Wether conditions: Water Level Data: Well: Piez: Total Depth: 46.80 Diameter: 2" Water column: 3i .1 ?i Depth to water: 5, 543 Well volume: gal. Purging data: Method: Low flow Acceptance criteria: Minimum purge volume (3 volumes): 1 gal. Stabilization: pH: 0.1 Temp: 10% Cond: 5% Removed 0-05 5. 2.0 . 0.05 18-1 5% 0-05 Sampled by: Nauta Date: 7/23/2015 RJN Environmental Services, LLC Well number: CSD-4 VU927 Groundwater Sample Collection Record Client: Central Sands Dairy Date: 7/23/2015 Project No.: 14-203 Time start: 1 2:53 Site Location: Juneau County, WI Finish: Wether conditions: Water Level Data: Well: Piez: Total Depth: 26.03 Diameter: 2" Water column: {2 .93 Depth to water: ID Well volume: . gal. Purging data: Method: Low flow Acceptance criteria: Minimum purge volume (3 volumes): '3 i 3 gal. Stabilization: pH: 0.1 Temp: 10% Cond: 5% Removed hos 25.2: 4. 04+} 1.2, 24-55 43925 035*?? 13- 4?9 045 . Z?S-abaB 45 3-. s' .30 045 Sampled by: Na uta Date: 7/23/2015 ATTACH ENT 2 1 2 3 4 ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Chicago 2417 Bond Street University Park, IL 60484 Tel: (708)534-5200 TestAmerica Job ID: 500-99061-1 Client Project/Site: Central Sands 14-203 For: RJN Environmental Services LLC 4631 County Road A Oregon, Wisconsin 53575 Attn: Robert J Nauta Authorized for release by: 8/7/2015 1:11:44 PM Jim Knapp, Project Manager II (630)758-0262 jim.knapp@testamericainc.com Designee for Sandie Fredrick, Project Manager II (920)261-1660 sandie.fredrick@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. 5 6 7 8 9 10 11 12 13 14 Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Table of Contents Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 3 1 2 3 4 6 7 8 11 12 16 21 4 5 6 7 8 9 10 11 24 25 26 12 13 14 Page 2 of 26 TestAmerica Chicago 8/7/2015 Case Narrative Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 Job ID: 500-99061-1 3 Laboratory: TestAmerica Chicago 4 Narrative 5 Job Narrative 500-99061-1 6 Comments No additional comments. 7 Receipt The samples were received on 7/28/2015 10:00 AM; the samples arrived in good condition, properly preserved and, where required, on ice. The temperatures of the 2 coolers at receipt time were 4.2º C and 4.7º C. Metals No analytical or quality issues were noted, other than those described in the Definitions/Glossary page. 8 9 10 General Chemistry Method(s) 300.0, 9056A: Manual integration was performed on the following IC8 samples in batch 500-298636 due to the software identifying the baseline incorrectly: (CCV 500-298636/13), (CCV 500-298636/25), (ICV 500-298636/1) and (LCS 500-298636/20). No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. 11 12 13 14 Page 3 of 26 TestAmerica Chicago 8/7/2015 Detection Summary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Client Sample ID: CSD-1S Analyte Potassium Result Qualifier 21000 RL 500 MDL Unit 190 ug/L Lab Sample ID: 500-99061-1 3 Dil Fac D Method 1 6020 4 300.0 353.2 1 4500 NH3 G Total/NA 6 1 1 9060A SM 2540C Total/NA Total/NA 1 1 SM 4500 NH3 G Total/NA SM 5220C Total/NA 7 19 24 1.0 2.0 0.38 mg/L 0.90 mg/L 5 20 Nitrogen, Kjeldahl 2.3 0.40 0.29 mg/L Total Organic Carbon - Duplicates Total Dissolved Solids 2.0 300 1.0 10 0.23 mg/L 6.1 mg/L Ammonia Chemical Oxygen Demand 2.6 10 0.20 10 0.043 mg/L 6.1 mg/L Client Sample ID: CSD-1D Lab Sample ID: 500-99061-2 RL 500 MDL Unit 190 ug/L 42 20 2.0 1.0 0.76 mg/L 0.45 mg/L 10 10 Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids 6.5 3.2 480 1.6 1.0 10 1.2 mg/L 0.23 mg/L 6.1 mg/L Ammonia Chemical Oxygen Demand 6.7 9.8 J 0.80 10 0.17 mg/L 6.1 mg/L Chloride Nitrogen, Nitrate Nitrite Result Qualifier 33000 Client Sample ID: CSD-2 Analyte Potassium Chloride Nitrogen, Nitrate Nitrite Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids Chloride Nitrogen, Nitrate Nitrite Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids Chemical Oxygen Demand Result Qualifier 8400 Chloride Prep Type 300.0 353.2 Total Recoverable Total/NA Total/NA 4 1 1 4500 NH3 G 9060A SM 2540C Total/NA Total/NA Total/NA 4 1 SM 4500 NH3 G Total/NA SM 5220C Total/NA RL 500 MDL Unit 190 ug/L 7.0 9.6 0.40 0.50 0.15 mg/L 0.23 mg/L 2 5 300.0 353.2 Total Recoverable Total/NA Total/NA 0.54 2.0 130 0.40 1.0 10 0.29 mg/L 0.23 mg/L 6.1 mg/L 1 1 1 4500 NH3 G 9060A SM 2540C Total/NA Total/NA Total/NA Dil Fac D Method 1 6020 Prep Type Lab Sample ID: 500-99061-4 Result Qualifier 5800 RL 500 MDL Unit 190 ug/L 48 24 2.0 2.0 0.76 mg/L 0.90 mg/L 10 20 0.50 1.6 480 0.40 1.0 10 0.29 mg/L 0.23 mg/L 6.1 mg/L 11 10 6.1 mg/L Client Sample ID: CSD-3D Analyte Potassium Dil Fac D Method 1 6020 Lab Sample ID: 500-99061-3 Client Sample ID: CSD-3S Analyte Potassium Prep Type Total Recoverable Total/NA Total/NA Chloride Nitrogen, Nitrate Nitrite Analyte Potassium 1 Dil Fac D Method 1 6020 Prep Type 300.0 353.2 Total Recoverable Total/NA Total/NA 1 1 1 4500 NH3 G 9060A SM 2540C Total/NA Total/NA Total/NA 1 SM 5220C Total/NA Lab Sample ID: 500-99061-5 Result Qualifier 880 5.1 RL 500 MDL Unit 190 ug/L 0.40 0.15 mg/L Dil Fac D Method 1 6020 2 300.0 Prep Type Total Recoverable Total/NA This Detection Summary does not include radiochemical test results. TestAmerica Chicago Page 4 of 26 8/7/2015 5 8 9 10 11 12 13 14 Detection Summary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Client Sample ID: CSD-3D (Continued) Analyte Nitrogen, Nitrate Nitrite Total Organic Carbon - Duplicates Total Dissolved Solids Ammonia Chemical Oxygen Demand Result Qualifier 2.3 Lab Sample ID: 500-99061-5 3 Dil Fac D Method 2 353.2 4 RL 0.20 MDL Unit 0.090 mg/L 0.65 J 1.0 0.23 mg/L 1 9060A 74 0.076 J 10 0.20 6.1 mg/L 0.043 mg/L 1 1 SM 2540C Total/NA SM 4500 NH3 G Total/NA 8.0 J 10 6.1 mg/L 1 SM 5220C Client Sample ID: CSD-4 Analyte Potassium Result Qualifier 44000 RL 500 MDL Unit 190 ug/L Dil Fac D Method 1 6020 4500 NH3 G Total/NA 0.23 mg/L 6.1 mg/L 1 1 9060A SM 2540C Total/NA Total/NA 6.1 mg/L 1 SM 5220C Total/NA 10 50 Nitrogen, Kjeldahl 1.2 0.40 0.29 mg/L Total Organic Carbon - Duplicates Total Dissolved Solids 4.0 790 1.0 10 13 10 Client Sample ID: CSD-4 DUP Chemical Oxygen Demand Prep Type 1 0.76 mg/L 2.3 mg/L Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids Total/NA 300.0 353.2 2.0 5.0 Chloride Nitrogen, Nitrate Nitrite Total/NA Total Recoverable Total/NA Total/NA 52 77 Analyte Potassium Prep Type Total/NA Lab Sample ID: 500-99061-6 Chloride Nitrogen, Nitrate Nitrite Chemical Oxygen Demand 1 Lab Sample ID: 500-99061-7 Result Qualifier 46000 RL 500 MDL Unit 190 ug/L Dil Fac D Method 1 6020 51 77 2.0 5.0 0.76 mg/L 2.3 mg/L 10 50 1.1 4.0 830 0.40 1.0 10 0.29 mg/L 0.23 mg/L 6.1 mg/L 14 10 6.1 mg/L Prep Type 300.0 353.2 Total Recoverable Total/NA Total/NA 1 1 1 4500 NH3 G 9060A SM 2540C Total/NA Total/NA Total/NA 1 SM 5220C Total/NA This Detection Summary does not include radiochemical test results. TestAmerica Chicago Page 5 of 26 8/7/2015 5 6 7 8 9 10 11 12 13 14 Method Summary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 Method 6020 300.0 353.2 Method Description Metals (ICP/MS) Anions, Ion Chromatography Nitrogen, Nitrate-Nitrite Protocol SW846 MCAWW MCAWW Laboratory TAL CHI TAL CHI TAL CHI 4500 NH3 G 9060A SM 2540C 4500NH3 G - Nitrogen, Total Kjeldahl' Organic Carbon, Total (TOC) Solids, Total Dissolved (TDS) SM SW846 SM TAL CHI TAL CHI TAL CHI SM 4500 NH3 G SM 5220C Ammonia COD SM SM TAL CHI TAL CHI 3 4 5 6 7 8 Protocol References: MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions. SM = "Standard Methods For The Examination Of Water And Wastewater", 9 SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. 10 Laboratory References: TAL CHI = TestAmerica Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200 11 12 13 14 TestAmerica Chicago Page 6 of 26 8/7/2015 Sample Summary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 Lab Sample ID 500-99061-1 500-99061-2 500-99061-3 Client Sample ID CSD-1S CSD-1D CSD-2 Matrix Water Water Water Collected Received 07/23/15 13:30 07/28/15 10:00 07/23/15 12:30 07/28/15 10:00 07/23/15 15:30 07/28/15 10:00 500-99061-4 500-99061-5 500-99061-6 CSD-3S CSD-3D CSD-4 Water Water Water 07/23/15 10:25 07/28/15 10:00 07/23/15 09:15 07/28/15 10:00 07/23/15 14:30 07/28/15 10:00 500-99061-7 CSD-4 DUP Water 07/23/15 14:30 07/28/15 10:00 3 4 5 6 7 8 9 10 11 12 13 14 TestAmerica Chicago Page 7 of 26 8/7/2015 Client Sample Results Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Client Sample ID: CSD-1S Lab Sample ID: 500-99061-1 Date Collected: 07/23/15 13:30 Date Received: 07/28/15 10:00 Matrix: Water Analyte Result Qualifier Potassium 21000 RL 500 MDL Unit 190 ug/L D RL 1.0 2.0 0.40 MDL 0.38 0.90 0.29 D Prepared Analyzed 07/28/15 17:00 07/31/15 00:45 Dil Fac 1 General Chemistry Chloride Nitrogen, Nitrate Nitrite Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids Ammonia Chemical Oxygen Demand Result Qualifier 19 24 2.3 2.0 300 2.6 10 Unit mg/L mg/L mg/L Prepared Analyzed 07/28/15 22:33 08/04/15 22:19 07/30/15 12:25 07/30/15 14:56 Dil Fac 5 20 1 33000 10 6.1 mg/L 07/29/15 10:26 07/29/15 16:08 1 10 Lab Sample ID: 500-99061-2 11 RL 500 MDL Unit 190 ug/L D RL 2.0 1.0 1.6 MDL 0.76 0.45 1.2 D Prepared Analyzed 07/28/15 17:00 07/31/15 01:15 Dil Fac 1 General Chemistry Chloride Nitrogen, Nitrate Nitrite Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids Ammonia Chemical Oxygen Demand Result Qualifier 42 20 6.5 3.2 480 6.7 9.8 J Unit mg/L mg/L mg/L Prepared Analyzed 07/28/15 22:45 08/04/15 21:29 07/30/15 12:25 07/30/15 14:59 Dil Fac 10 10 4 1.0 10 0.80 0.23 mg/L 6.1 mg/L 0.17 mg/L 08/04/15 23:36 07/30/15 06:05 08/03/15 21:05 08/04/15 00:50 1 1 4 10 6.1 mg/L 07/29/15 10:26 07/29/15 16:09 1 Client Sample ID: CSD-2 Lab Sample ID: 500-99061-3 Date Collected: 07/23/15 15:30 Date Received: 07/28/15 10:00 Matrix: Water Method: 6020 - Metals (ICP/MS) - Total Recoverable Analyte Potassium Result Qualifier 8400 RL 500 MDL Unit 190 ug/L D RL 0.40 0.50 0.40 MDL 0.15 0.23 0.29 D Prepared Analyzed 07/28/15 17:00 07/31/15 01:18 Dil Fac 1 General Chemistry Analyte Chloride Nitrogen, Nitrate Nitrite Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids Ammonia Chemical Oxygen Demand Result Qualifier 7.0 9.6 0.54 2.0 130 8 1 1 1 Method: 6020 - Metals (ICP/MS) - Total Recoverable Potassium 7 08/04/15 22:40 07/29/15 06:10 08/03/15 21:05 08/04/15 00:47 Matrix: Water Result Qualifier 6 0.23 mg/L 6.1 mg/L 0.043 mg/L Date Collected: 07/23/15 12:30 Date Received: 07/28/15 10:00 Analyte 5 1.0 10 0.20 Client Sample ID: CSD-1D Analyte 3 4 Method: 6020 - Metals (ICP/MS) - Total Recoverable Analyte 1 Unit mg/L mg/L mg/L Prepared Analyzed 07/28/15 23:22 08/04/15 21:31 07/30/15 12:25 07/30/15 15:02 Dil Fac 2 5 1 <0.043 1.0 10 0.20 0.23 mg/L 6.1 mg/L 0.043 mg/L 08/04/15 23:52 07/30/15 06:07 08/03/15 21:05 08/04/15 00:53 1 1 1 <6.1 10 6.1 mg/L 07/29/15 10:26 07/29/15 16:10 1 TestAmerica Chicago Page 8 of 26 8/7/2015 9 12 13 14 Client Sample Results Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Client Sample ID: CSD-3S Lab Sample ID: 500-99061-4 Date Collected: 07/23/15 10:25 Date Received: 07/28/15 10:00 Matrix: Water Analyte Result Qualifier 5800 RL 500 MDL Unit 190 ug/L D Prepared Analyzed 07/28/15 17:00 07/31/15 01:22 Dil Fac 1 Chloride Nitrogen, Nitrate Nitrite Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids Ammonia Chemical Oxygen Demand Result Qualifier 48 24 0.50 1.6 480 RL 2.0 2.0 0.40 MDL 0.76 0.90 0.29 Unit mg/L mg/L mg/L D Prepared Analyzed 07/28/15 23:34 08/04/15 22:23 07/30/15 12:25 07/30/15 15:05 Dil Fac 10 20 1 <0.043 08/05/15 00:08 07/30/15 06:10 08/03/15 21:05 08/04/15 00:56 1 1 1 11 10 6.1 mg/L 07/29/15 10:26 07/29/15 16:11 1 10 Lab Sample ID: 500-99061-5 11 12 Result Qualifier 880 RL 500 MDL Unit 190 ug/L D Prepared Analyzed 07/28/15 17:00 07/31/15 01:26 Dil Fac 1 General Chemistry Analyte Result Qualifier 5.1 2.3 Nitrogen, Kjeldahl <0.29 Total Organic Carbon - Duplicates Total Dissolved Solids Ammonia Chemical Oxygen Demand 0.65 J 74 0.076 J 8.0 J RL 0.40 0.20 0.40 MDL 0.15 0.090 0.29 1.0 10 0.20 10 Unit mg/L mg/L mg/L Analyzed 07/28/15 23:46 08/04/15 22:23 07/30/15 12:25 07/30/15 15:07 Dil Fac 2 2 1 0.23 mg/L 6.1 mg/L 0.043 mg/L 08/05/15 00:25 07/30/15 06:12 08/03/15 21:05 08/04/15 00:59 1 1 1 6.1 mg/L 07/29/15 10:26 07/29/15 16:11 1 Client Sample ID: CSD-4 D Prepared Lab Sample ID: 500-99061-6 Date Collected: 07/23/15 14:30 Date Received: 07/28/15 10:00 Matrix: Water Method: 6020 - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier Potassium 44000 RL 500 MDL Unit 190 ug/L D RL 2.0 5.0 0.40 MDL 0.76 2.3 0.29 D Prepared Analyzed 07/28/15 17:00 07/31/15 01:29 Dil Fac 1 General Chemistry Analyte Chloride Nitrogen, Nitrate Nitrite Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids Ammonia Chemical Oxygen Demand 9 Matrix: Water Method: 6020 - Metals (ICP/MS) - Total Recoverable Chloride Nitrogen, Nitrate Nitrite 8 0.23 mg/L 6.1 mg/L 0.043 mg/L Client Sample ID: CSD-3D Potassium 7 1.0 10 0.20 Date Collected: 07/23/15 09:15 Date Received: 07/28/15 10:00 Analyte 5 6 General Chemistry Analyte 3 4 Method: 6020 - Metals (ICP/MS) - Total Recoverable Potassium 1 Result Qualifier 52 77 1.2 4.0 790 Unit mg/L mg/L mg/L Prepared Analyzed 08/04/15 20:48 08/04/15 22:24 07/30/15 12:25 07/30/15 15:10 Dil Fac 10 50 1 <0.043 1.0 10 0.20 0.23 mg/L 6.1 mg/L 0.043 mg/L 08/05/15 00:41 07/30/15 06:15 08/03/15 21:05 08/04/15 01:01 1 1 1 13 10 6.1 mg/L 07/29/15 10:26 07/29/15 16:12 1 TestAmerica Chicago Page 9 of 26 8/7/2015 13 14 Client Sample Results Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Client Sample ID: CSD-4 DUP Lab Sample ID: 500-99061-7 Date Collected: 07/23/15 14:30 Date Received: 07/28/15 10:00 Matrix: Water Analyte Result Qualifier Potassium 46000 RL 500 MDL Unit 190 ug/L D Prepared Analyzed 07/28/15 17:00 07/31/15 01:33 Dil Fac 1 Ammonia Chemical Oxygen Demand 5 6 General Chemistry Chloride Nitrogen, Nitrate Nitrite Nitrogen, Kjeldahl Total Organic Carbon - Duplicates Total Dissolved Solids 3 4 Method: 6020 - Metals (ICP/MS) - Total Recoverable Analyte 1 Result Qualifier 51 77 1.1 4.0 830 RL 2.0 5.0 0.40 MDL 0.76 2.3 0.29 Unit mg/L mg/L mg/L D Prepared Analyzed 08/04/15 21:26 08/04/15 22:25 07/30/15 12:25 07/30/15 15:13 Dil Fac 10 50 1 <0.043 1.0 10 0.20 0.23 mg/L 6.1 mg/L 0.043 mg/L 08/05/15 00:57 07/30/15 06:17 08/03/15 21:05 08/04/15 01:04 1 1 1 14 10 6.1 mg/L 07/29/15 10:26 07/29/15 16:13 1 7 8 9 10 11 12 13 14 TestAmerica Chicago Page 10 of 26 8/7/2015 Definitions/Glossary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Qualifiers 3 General Chemistry Qualifier 4 J 1 4 Qualifier Description MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable. Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Glossary Abbreviation ¤ These commonly used abbreviations may or may not be present in this report. Listed under the "D" column to designate that the result is reported on a dry weight basis %R CFL CNF DER Dil Fac Percent Recovery Contains Free Liquid Contains no Free Liquid Duplicate error ratio (normalized absolute difference) Dilution Factor DL, RA, RE, IN DLC MDA EDL MDC MDL Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample Decision level concentration Minimum detectable activity Estimated Detection Limit Minimum detectable concentration Method Detection Limit ML NC ND PQL QC RER Minimum Level (Dioxin) Not Calculated Not detected at the reporting limit (or MDL or EDL if shown) Practical Quantitation Limit Quality Control Relative error ratio RL RPD TEF TEQ Reporting Limit or Requested Limit (Radiochemistry) Relative Percent Difference, a measure of the relative difference between two points Toxicity Equivalent Factor (Dioxin) Toxicity Equivalent Quotient (Dioxin) 6 7 8 9 10 11 12 13 14 TestAmerica Chicago Page 11 of 26 5 8/7/2015 QC Association Summary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 Metals 3 Prep Batch: 297574 Lab Sample ID 500-99061-1 500-99061-1 DU 500-99061-1 MS Client Sample ID CSD-1S CSD-1S CSD-1S Prep Type Total Recoverable Total Recoverable Total Recoverable Matrix Water Water Water Method 3005A 3005A 3005A Prep Batch 500-99061-1 MSD 500-99061-2 500-99061-3 CSD-1S CSD-1D CSD-2 Total Recoverable Total Recoverable Total Recoverable Water Water Water 3005A 3005A 3005A 500-99061-4 500-99061-5 CSD-3S CSD-3D Total Recoverable Total Recoverable Water Water 3005A 3005A 500-99061-6 CSD-4 Total Recoverable Water 3005A 500-99061-7 LCS 500-297574/2-A MB 500-297574/1-A CSD-4 DUP Lab Control Sample Method Blank Total Recoverable Total Recoverable Total Recoverable Water Water Water 3005A 3005A 3005A Lab Sample ID 500-99061-1 500-99061-1 DU 500-99061-1 MS Client Sample ID CSD-1S CSD-1S CSD-1S Prep Type Total Recoverable Total Recoverable Total Recoverable Matrix Water Water Water Method 6020 6020 6020 500-99061-1 MSD 500-99061-2 500-99061-3 CSD-1S CSD-1D CSD-2 Total Recoverable Total Recoverable Total Recoverable Water Water Water 6020 6020 6020 297574 297574 297574 500-99061-4 500-99061-5 CSD-3S CSD-3D Total Recoverable Total Recoverable Water Water 6020 6020 297574 297574 500-99061-6 CSD-4 Total Recoverable Water 6020 297574 500-99061-7 LCS 500-297574/2-A CSD-4 DUP Lab Control Sample Total Recoverable Total Recoverable Water Water 6020 6020 297574 297574 MB 500-297574/1-A Method Blank Total Recoverable Water 6020 297574 Lab Sample ID 500-99061-1 Client Sample ID CSD-1S Prep Type Total/NA Matrix Water Method SM 2540C 500-99061-1 DU LCS 500-297584/2 CSD-1S Lab Control Sample Total/NA Total/NA Water Water SM 2540C SM 2540C MB 500-297584/1 Method Blank Total/NA Water SM 2540C Lab Sample ID 500-99061-1 500-99061-2 500-99061-3 Client Sample ID CSD-1S CSD-1D CSD-2 Prep Type Total/NA Total/NA Total/NA Matrix Water Water Water Method 300.0 300.0 300.0 500-99061-4 500-99061-5 500-99061-5 MS CSD-3S CSD-3D CSD-3D Total/NA Total/NA Total/NA Water Water Water 300.0 300.0 300.0 500-99061-5 MSD LCS 500-297634/4 MB 500-297634/3 CSD-3D Lab Control Sample Method Blank Total/NA Total/NA Total/NA Water Water Water 300.0 300.0 300.0 4 5 6 7 8 9 10 Analysis Batch: 298031 11 Prep Batch 297574 297574 297574 General Chemistry Analysis Batch: 297584 Prep Batch Analysis Batch: 297634 Prep Batch TestAmerica Chicago Page 12 of 26 8/7/2015 12 13 14 QC Association Summary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 General Chemistry (Continued) 3 Prep Batch: 297640 Lab Sample ID 500-99061-1 500-99061-2 500-99061-3 Client Sample ID CSD-1S CSD-1D CSD-2 Prep Type Total/NA Total/NA Total/NA Matrix Water Water Water Method SM 5220 SM 5220 SM 5220 Prep Batch 500-99061-4 500-99061-5 500-99061-6 CSD-3S CSD-3D CSD-4 Total/NA Total/NA Total/NA Water Water Water SM 5220 SM 5220 SM 5220 500-99061-7 LCS 500-297640/2-A CSD-4 DUP Lab Control Sample Total/NA Total/NA Water Water SM 5220 SM 5220 MB 500-297640/1-A Method Blank Total/NA Water SM 5220 Lab Sample ID 500-99061-1 500-99061-2 500-99061-3 Client Sample ID CSD-1S CSD-1D CSD-2 Prep Type Total/NA Total/NA Total/NA Matrix Water Water Water Method SM 5220C SM 5220C SM 5220C Prep Batch 297640 297640 297640 500-99061-4 500-99061-5 500-99061-6 CSD-3S CSD-3D CSD-4 Total/NA Total/NA Total/NA Water Water Water SM 5220C SM 5220C SM 5220C 297640 297640 297640 500-99061-7 LCS 500-297640/2-A MB 500-297640/1-A CSD-4 DUP Lab Control Sample Method Blank Total/NA Total/NA Total/NA Water Water Water SM 5220C SM 5220C SM 5220C 297640 297640 297640 Lab Sample ID 500-99061-1 500-99061-2 Client Sample ID CSD-1S CSD-1D Prep Type Total/NA Total/NA Matrix Water Water Method SM4500Norg_C SM4500Norg_C 500-99061-3 CSD-2 Total/NA Water SM4500Norg_C 500-99061-4 500-99061-5 CSD-3S CSD-3D Total/NA Total/NA Water Water SM4500Norg_C SM4500Norg_C 500-99061-6 CSD-4 Total/NA Water SM4500Norg_C 500-99061-7 CSD-4 DUP Total/NA Water SM4500Norg_C LCS 500-297705/2-A MB 500-297705/1-A Lab Control Sample Method Blank Total/NA Total/NA Water Water SM4500Norg_C SM4500Norg_C Lab Sample ID 500-99061-2 500-99061-3 500-99061-4 Client Sample ID CSD-1D CSD-2 CSD-3S Prep Type Total/NA Total/NA Total/NA Matrix Water Water Water Method SM 2540C SM 2540C SM 2540C 500-99061-5 500-99061-6 500-99061-7 CSD-3D CSD-4 CSD-4 DUP Total/NA Total/NA Total/NA Water Water Water SM 2540C SM 2540C SM 2540C LCS 500-297787/2 MB 500-297787/1 Lab Control Sample Method Blank Total/NA Total/NA Water Water SM 2540C SM 2540C Lab Sample ID 500-99061-1 500-99061-2 500-99061-3 Client Sample ID CSD-1S CSD-1D CSD-2 Prep Type Total/NA Total/NA Total/NA Matrix Water Water Water Method 4500 NH3 G 4500 NH3 G 4500 NH3 G Prep Batch 297705 297705 297705 500-99061-4 CSD-3S Total/NA Water 4500 NH3 G 297705 5 6 7 8 9 Analysis Batch: 297641 Prep Batch: 297705 Prep Batch Analysis Batch: 297787 Prep Batch Analysis Batch: 298053 TestAmerica Chicago Page 13 of 26 4 8/7/2015 10 11 12 13 14 QC Association Summary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 General Chemistry (Continued) 3 Analysis Batch: 298053 (Continued) 4 Lab Sample ID 500-99061-5 Client Sample ID CSD-3D Prep Type Total/NA Matrix Water Method 4500 NH3 G Prep Batch 297705 500-99061-6 CSD-4 Total/NA Water 4500 NH3 G 297705 500-99061-7 CSD-4 DUP Total/NA Water 4500 NH3 G 297705 LCS 500-297705/2-A MB 500-297705/1-A Lab Control Sample Method Blank Total/NA Total/NA Water Water 4500 NH3 G 4500 NH3 G 297705 297705 Lab Sample ID 500-99061-1 500-99061-2 500-99061-3 Client Sample ID CSD-1S CSD-1D CSD-2 Prep Type Total/NA Total/NA Total/NA Matrix Water Water Water Method SM 4500 NH3 B SM 4500 NH3 B SM 4500 NH3 B 500-99061-4 500-99061-5 CSD-3S CSD-3D Total/NA Total/NA Water Water SM 4500 NH3 B SM 4500 NH3 B 10 500-99061-6 CSD-4 Total/NA Water SM 4500 NH3 B 500-99061-7 CSD-4 DUP Total/NA Water SM 4500 NH3 B 11 LCS 500-298347/2-A MB 500-298347/1-A Lab Control Sample Method Blank Total/NA Total/NA Water Water SM 4500 NH3 B SM 4500 NH3 B Prep Batch: 298347 Prep Batch 5 6 7 8 9 12 13 Analysis Batch: 298482 Lab Sample ID 500-99061-1 Client Sample ID CSD-1S Prep Type Total/NA Matrix Water Method SM 4500 NH3 G Prep Batch 298347 500-99061-2 500-99061-3 CSD-1D CSD-2 Total/NA Total/NA Water Water SM 4500 NH3 G SM 4500 NH3 G 298347 298347 500-99061-4 500-99061-5 500-99061-6 CSD-3S CSD-3D CSD-4 Total/NA Total/NA Total/NA Water Water Water SM 4500 NH3 G SM 4500 NH3 G SM 4500 NH3 G 298347 298347 298347 500-99061-7 LCS 500-298347/2-A MB 500-298347/1-A CSD-4 DUP Lab Control Sample Method Blank Total/NA Total/NA Total/NA Water Water Water SM 4500 NH3 G SM 4500 NH3 G SM 4500 NH3 G 298347 298347 298347 Lab Sample ID 500-99061-6 500-99061-7 LCS 500-298636/20 Client Sample ID CSD-4 CSD-4 DUP Lab Control Sample Prep Type Total/NA Total/NA Total/NA Matrix Water Water Water Method 300.0 300.0 300.0 MB 500-298636/19 Method Blank Total/NA Water 300.0 Lab Sample ID 500-99061-1 500-99061-1 MS 500-99061-1 MSD Client Sample ID CSD-1S CSD-1S CSD-1S Prep Type Total/NA Total/NA Total/NA Matrix Water Water Water Method 9060A 9060A 9060A 500-99061-2 500-99061-3 500-99061-4 CSD-1D CSD-2 CSD-3S Total/NA Total/NA Total/NA Water Water Water 9060A 9060A 9060A 500-99061-5 500-99061-6 500-99061-7 CSD-3D CSD-4 CSD-4 DUP Total/NA Total/NA Total/NA Water Water Water 9060A 9060A 9060A LCS 500-298652/5 MB 500-298652/4 Lab Control Sample Method Blank Total/NA Total/NA Water Water 9060A 9060A Analysis Batch: 298636 Prep Batch Analysis Batch: 298652 Prep Batch TestAmerica Chicago Page 14 of 26 8/7/2015 14 QC Association Summary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 General Chemistry (Continued) 3 Analysis Batch: 298906 Lab Sample ID 500-99061-1 500-99061-1 MS 500-99061-1 MSD Client Sample ID CSD-1S CSD-1S CSD-1S Prep Type Total/NA Total/NA Total/NA Matrix Water Water Water Method 353.2 353.2 353.2 500-99061-2 500-99061-3 500-99061-4 CSD-1D CSD-2 CSD-3S Total/NA Total/NA Total/NA Water Water Water 353.2 353.2 353.2 500-99061-5 500-99061-6 CSD-3D CSD-4 Total/NA Total/NA Water Water 353.2 353.2 500-99061-7 CSD-4 DUP Total/NA Water 353.2 LCS 500-298906/13 MB 500-298906/12 Lab Control Sample Method Blank Total/NA Total/NA Water Water 353.2 353.2 Prep Batch 4 5 6 7 8 9 10 11 12 13 14 TestAmerica Chicago Page 15 of 26 8/7/2015 QC Sample Results Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Method: 6020 - Metals (ICP/MS) 3 Lab Sample ID: MB 500-297574/1-A Matrix: Water Analysis Batch: 298031 Client Sample ID: Method Blank Prep Type: Total Recoverable Prep Batch: 297574 MB MB Result Qualifier <190 Analyte Potassium RL 500 MDL Unit 190 ug/L Lab Sample ID: LCS 500-297574/2-A Matrix: Water Analysis Batch: 298031 D LCS LCS Added 10000 Result Qualifier 10400 Unit ug/L D Sample Sample Result Qualifier 21000 Spike Added 10000 MS MS Result Qualifier 30000 Unit ug/L D Limits 80 - 120 %Rec 94 Sample Sample Result Qualifier 21000 Spike Added 10000 MSD MSD Result Qualifier 29600 Unit ug/L D %Rec 91 %Rec. Limits 75 - 125 %Rec. Limits 75 - 125 DU DU Result Qualifier 20300 Unit ug/L D RPD 1 RPD Limit 20 RPD 1 RPD Limit 20 Method: 300.0 - Anions, Ion Chromatography Lab Sample ID: MB 500-297634/3 Matrix: Water Analysis Batch: 297634 Analyte Chloride Client Sample ID: Method Blank Prep Type: Total/NA MB MB Result Qualifier <0.076 RL 0.20 MDL Unit 0.076 mg/L Lab Sample ID: LCS 500-297634/4 Matrix: Water Analysis Batch: 297634 Analyte Chloride D Prepared Analyzed 07/28/15 14:42 Dil Fac 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike Added 3.00 LCS LCS Result Qualifier 2.83 Unit mg/L D %Rec 94 %Rec. Limits 90 - 110 TestAmerica Chicago Page 16 of 26 5 6 7 8 10 11 12 Client Sample ID: CSD-1S Prep Type: Total Recoverable Prep Batch: 297574 Sample Sample Result Qualifier 21000 4 9 Client Sample ID: CSD-1S Prep Type: Total Recoverable Prep Batch: 297574 Lab Sample ID: 500-99061-1 DU Matrix: Water Analysis Batch: 298031 Analyte Potassium %Rec 104 Client Sample ID: CSD-1S Prep Type: Total Recoverable Prep Batch: 297574 Lab Sample ID: 500-99061-1 MSD Matrix: Water Analysis Batch: 298031 Analyte Potassium Dil Fac 1 %Rec. Lab Sample ID: 500-99061-1 MS Matrix: Water Analysis Batch: 298031 Analyte Potassium Prepared Analyzed 07/28/15 17:00 07/31/15 00:30 Client Sample ID: Lab Control Sample Prep Type: Total Recoverable Prep Batch: 297574 Spike Analyte Potassium 1 8/7/2015 13 14 QC Sample Results Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Method: 300.0 - Anions, Ion Chromatography (Continued) 3 Lab Sample ID: 500-99061-5 MS Matrix: Water Analysis Batch: 297634 Analyte Chloride Client Sample ID: CSD-3D Prep Type: Total/NA Sample Sample Result Qualifier 5.1 Spike Added 2.00 MS MS Result Qualifier 6.93 Unit mg/L D Lab Sample ID: 500-99061-5 MSD Matrix: Water Analysis Batch: 297634 Result Qualifier 5.1 Spike MSD MSD 6 Added 2.00 Result Qualifier 7.03 %Rec. Unit mg/L D Lab Sample ID: MB 500-298636/19 Matrix: Water Analysis Batch: 298636 %Rec 96 Limits 80 - 120 RPD RPD 2 Limit 20 Client Sample ID: Method Blank Prep Type: Total/NA MB MB Result Qualifier <0.076 Analyte Chloride %Rec 91 RL 0.20 MDL Unit 0.076 mg/L Lab Sample ID: LCS 500-298636/20 Matrix: Water Analysis Batch: 298636 D Prepared Analyzed 08/04/15 19:44 Dil Fac 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike Added 3.00 Analyte Chloride LCS LCS Result Qualifier 2.89 Unit mg/L D %Rec 96 %Rec. Limits 90 - 110 Method: 353.2 - Nitrogen, Nitrate-Nitrite Lab Sample ID: MB 500-298906/12 Matrix: Water Analysis Batch: 298906 Client Sample ID: Method Blank Prep Type: Total/NA MB MB Analyte Nitrogen, Nitrate Nitrite Result Qualifier <0.045 RL 0.10 MDL Unit 0.045 mg/L Lab Sample ID: LCS 500-298906/13 Matrix: Water Analysis Batch: 298906 Prepared LCS LCS Result Qualifier 0.960 Unit mg/L D Lab Sample ID: 500-99061-1 MS Matrix: Water Analysis Batch: 298906 Analyte Nitrogen, Nitrate Nitrite Sample Sample Result Qualifier 24 Analyzed 08/04/15 20:55 Dil Fac 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike Added 1.00 Analyte Nitrogen, Nitrate Nitrite D %Rec 96 %Rec. Limits 90 - 110 Client Sample ID: CSD-1S Prep Type: Total/NA Spike Added 1.00 MS MS Result Qualifier 27.1 4 Unit mg/L D %Rec 262 %Rec. Limits 90 - 110 TestAmerica Chicago Page 17 of 26 4 5 %Rec. Limits 80 - 120 Client Sample ID: CSD-3D Prep Type: Total/NA Sample Sample Analyte Chloride 1 8/7/2015 7 8 9 10 11 12 13 14 QC Sample Results Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Method: 353.2 - Nitrogen, Nitrate-Nitrite (Continued) 3 Lab Sample ID: 500-99061-1 MSD Matrix: Water Analysis Batch: 298906 Analyte Nitrogen, Nitrate Nitrite Client Sample ID: CSD-1S Prep Type: Total/NA Sample Sample Result Qualifier 24 Spike Added 1.00 MSD MSD Result Qualifier 26.0 4 Unit mg/L D %Rec 157 %Rec. Limits 90 - 110 RPD 4 RPD Limit 20 Lab Sample ID: MB 500-297705/1-A Matrix: Water Analysis Batch: 298053 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 297705 MB MB Result Qualifier <0.29 RL 0.40 MDL Unit 0.29 mg/L Lab Sample ID: LCS 500-297705/2-A Matrix: Water Analysis Batch: 298053 D Prepared Analyzed 07/30/15 12:25 07/30/15 14:22 Dil Fac 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 297705 Spike Added 2.50 Analyte Nitrogen, Kjeldahl LCS LCS Result Qualifier 2.15 Unit mg/L D %Rec 86 %Rec. Limits 80 - 120 Lab Sample ID: MB 500-298652/4 Matrix: Water Analysis Batch: 298652 RL 1.0 MDL Unit 0.23 mg/L Lab Sample ID: LCS 500-298652/5 Matrix: Water Analysis Batch: 298652 D Prepared Spike Added 10.0 Total Organic Carbon Duplicates TOC Result 1 TOC Result 2 10.0 10.0 LCS LCS Result Qualifier 10.3 10.2 10.4 Unit mg/L D mg/L mg/L Lab Sample ID: 500-99061-1 MS Matrix: Water Analysis Batch: 298652 Analyte Total Organic Carbon Duplicates TOC Result 1 TOC Result 2 Analyzed 08/04/15 16:23 Dil Fac 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Analyte %Rec 103 %Rec. Limits 80 - 120 102 104 80 - 120 80 - 120 Client Sample ID: CSD-1S Prep Type: Total/NA Sample Sample Result Qualifier 2.0 2.0 2.0 Spike Added 10.0 10.0 10.0 MS MS Result Qualifier 11.5 11.5 11.5 Unit mg/L mg/L mg/L D %Rec 95 %Rec. Limits 75 - 125 95 95 75 - 125 75 - 125 TestAmerica Chicago Page 18 of 26 6 8 9 10 11 12 14 Client Sample ID: Method Blank Prep Type: Total/NA MB MB Result Qualifier <0.23 5 13 Method: 9060A - Organic Carbon, Total (TOC) Analyte Total Organic Carbon - Duplicates 4 7 Method: 4500 NH3 G - 4500NH3 G - Nitrogen, Total Kjeldahl' Analyte Nitrogen, Kjeldahl 1 8/7/2015 QC Sample Results Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Method: 9060A - Organic Carbon, Total (TOC) (Continued) 3 Lab Sample ID: 500-99061-1 MSD Matrix: Water Analysis Batch: 298652 Analyte Total Organic Carbon Duplicates TOC Result 1 TOC Result 2 Client Sample ID: CSD-1S Prep Type: Total/NA Sample Sample Result Qualifier 2.0 2.0 2.0 Spike Added 10.0 MSD MSD Result Qualifier 11.5 10.0 10.0 11.5 11.5 Unit mg/L D mg/L mg/L %Rec 95 %Rec. Limits 75 - 125 RPD 1 RPD Limit 20 95 95 75 - 125 75 - 125 1 1 20 20 Lab Sample ID: MB 500-297584/1 Matrix: Water Analysis Batch: 297584 Client Sample ID: Method Blank Prep Type: Total/NA MB MB Result Qualifier <6.1 RL 10 MDL Unit 6.1 mg/L Lab Sample ID: LCS 500-297584/2 Matrix: Water Analysis Batch: 297584 D Prepared Spike Added 250 LCS LCS Result Qualifier 280 Unit mg/L D Lab Sample ID: 500-99061-1 DU Matrix: Water Analysis Batch: 297584 Analyte Total Dissolved Solids Analyzed 07/29/15 05:15 Dil Fac 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Analyte Total Dissolved Solids %Rec 112 DU DU Result Qualifier 308 Unit mg/L D Lab Sample ID: MB 500-297787/1 Matrix: Water Analysis Batch: 297787 RPD 4 RPD Limit 5 Client Sample ID: Method Blank Prep Type: Total/NA MB MB Analyte Total Dissolved Solids Result Qualifier <6.1 RL 10 MDL Unit 6.1 mg/L Lab Sample ID: LCS 500-297787/2 Matrix: Water Analysis Batch: 297787 Analyte Total Dissolved Solids D Prepared Analyzed 07/30/15 06:00 Dil Fac 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike Added 250 5 6 7 LCS LCS Result Qualifier 274 Unit mg/L D %Rec 110 %Rec. Limits 80 - 120 TestAmerica Chicago Page 19 of 26 9 10 11 12 13 14 %Rec. Limits 80 - 120 Client Sample ID: CSD-1S Prep Type: Total/NA Sample Sample Result Qualifier 300 4 8 Method: SM 2540C - Solids, Total Dissolved (TDS) Analyte Total Dissolved Solids 1 8/7/2015 QC Sample Results Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Method: SM 4500 NH3 G - Ammonia 3 Lab Sample ID: MB 500-298347/1-A Matrix: Water Analysis Batch: 298482 Analyte Ammonia Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 298347 MB MB Result Qualifier <0.043 RL 0.20 MDL Unit 0.043 mg/L Lab Sample ID: LCS 500-298347/2-A Matrix: Water Analysis Batch: 298482 D Prepared Analyzed 08/03/15 21:05 08/04/15 00:13 Dil Fac 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 298347 Spike Analyte Ammonia LCS LCS Added 2.50 Result Qualifier 2.37 %Rec. Unit mg/L D %Rec 95 Limits 80 - 120 5 6 7 8 10 Lab Sample ID: MB 500-297640/1-A Matrix: Water Analysis Batch: 297641 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 297640 MB MB Result Qualifier <6.1 RL 10 MDL Unit 6.1 mg/L Lab Sample ID: LCS 500-297640/2-A Matrix: Water Analysis Batch: 297641 Analyte Chemical Oxygen Demand 4 9 Method: SM 5220C - COD Analyte Chemical Oxygen Demand 1 D Prepared Analyzed 07/29/15 10:26 07/29/15 16:00 Dil Fac 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 297640 Spike Added 50.0 LCS LCS Result Qualifier 53.6 Unit mg/L D %Rec 107 %Rec. Limits 80 - 120 TestAmerica Chicago Page 20 of 26 8/7/2015 11 12 13 14 Lab Chronicle Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 Client Sample ID: CSD-1S Lab Sample ID: 500-99061-1 Date Collected: 07/23/15 13:30 Date Received: 07/28/15 10:00 Matrix: Water Prep Type Total Recoverable Total Recoverable Batch Type Prep Analysis Batch Method 3005A 6020 Total/NA Analysis 300.0 5 297634 07/28/15 22:33 EAT TAL CHI Total/NA Analysis 353.2 20 298906 08/04/15 22:19 HMW TAL CHI Total/NA Total/NA Prep Analysis SM4500Norg_C 4500 NH3 G 1 297705 07/30/15 12:25 SSF 298053 07/30/15 14:56 SSF TAL CHI TAL CHI Total/NA Analysis 9060A 1 298652 08/04/15 22:40 ELR TAL CHI Total/NA Analysis SM 2540C 1 297584 07/29/15 06:10 CLB TAL CHI Total/NA Total/NA Prep Analysis SM 4500 NH3 B SM 4500 NH3 G 1 298347 08/03/15 21:05 HMW 298482 08/04/15 00:47 HMW TAL CHI TAL CHI Total/NA Total/NA Prep Analysis SM 5220 SM 5220C 1 297640 07/29/15 10:26 LAJ 297641 07/29/15 16:08 LAJ TAL CHI TAL CHI Run Dilution Factor 1 Batch Prepared Number or Analyzed Analyst 297574 07/28/15 17:00 PJH 298031 07/31/15 00:45 PFK Client Sample ID: CSD-1D 4 5 Lab TAL CHI TAL CHI 6 7 8 9 10 11 12 Lab Sample ID: 500-99061-2 Date Collected: 07/23/15 12:30 Date Received: 07/28/15 10:00 3 Matrix: Water 13 14 Batch Batch Prep Type Total Recoverable Type Prep Method 3005A Dilution Total Recoverable Analysis 6020 1 298031 07/31/15 01:15 PFK TAL CHI Total/NA Analysis 300.0 10 297634 07/28/15 22:45 EAT TAL CHI Total/NA Analysis 353.2 10 298906 08/04/15 21:29 HMW TAL CHI Total/NA Total/NA Prep Analysis SM4500Norg_C 4500 NH3 G 4 297705 07/30/15 12:25 SSF 298053 07/30/15 14:59 SSF TAL CHI TAL CHI Total/NA Analysis 9060A 1 298652 08/04/15 23:36 ELR TAL CHI Total/NA Analysis SM 2540C 1 297787 07/30/15 06:05 CLB TAL CHI Total/NA Total/NA Prep Analysis SM 4500 NH3 B SM 4500 NH3 G 4 298347 08/03/15 21:05 HMW 298482 08/04/15 00:50 HMW TAL CHI TAL CHI Total/NA Total/NA Prep Analysis SM 5220 SM 5220C 1 297640 07/29/15 10:26 LAJ 297641 07/29/15 16:09 LAJ TAL CHI TAL CHI Run Factor Batch Prepared Number or Analyzed Analyst 297574 07/28/15 17:00 PJH Client Sample ID: CSD-2 Lab TAL CHI Lab Sample ID: 500-99061-3 Date Collected: 07/23/15 15:30 Date Received: 07/28/15 10:00 Matrix: Water Prep Type Total Recoverable Total Recoverable Batch Type Prep Analysis Batch Method 3005A 6020 Total/NA Analysis 300.0 2 297634 07/28/15 23:22 EAT TAL CHI Total/NA Analysis 353.2 5 298906 08/04/15 21:31 HMW TAL CHI Total/NA Total/NA Prep Analysis SM4500Norg_C 4500 NH3 G 1 297705 07/30/15 12:25 SSF 298053 07/30/15 15:02 SSF TAL CHI TAL CHI Run Dilution Factor 1 Batch Prepared Number or Analyzed Analyst 297574 07/28/15 17:00 PJH 298031 07/31/15 01:18 PFK Lab TAL CHI TAL CHI TestAmerica Chicago Page 21 of 26 8/7/2015 Lab Chronicle Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 Client Sample ID: CSD-2 Lab Sample ID: 500-99061-3 Date Collected: 07/23/15 15:30 Date Received: 07/28/15 10:00 Matrix: Water 3 4 Prep Type Total/NA Batch Type Analysis Batch Method 9060A Total/NA Analysis SM 2540C 1 297787 07/30/15 06:07 CLB TAL CHI Total/NA Total/NA Prep Analysis SM 4500 NH3 B SM 4500 NH3 G 1 298347 08/03/15 21:05 HMW 298482 08/04/15 00:53 HMW TAL CHI TAL CHI 7 Total/NA Prep SM 5220 297640 07/29/15 10:26 LAJ TAL CHI Total/NA Analysis SM 5220C 297641 07/29/15 16:10 LAJ TAL CHI 8 Run Dilution Factor 1 1 Batch Prepared Number or Analyzed Analyst 298652 08/04/15 23:52 ELR Client Sample ID: CSD-3S 5 Lab TAL CHI 6 Lab Sample ID: 500-99061-4 Date Collected: 07/23/15 10:25 Date Received: 07/28/15 10:00 Matrix: Water Prep Type Total Recoverable Total Recoverable Batch Method 3005A 6020 Total/NA Analysis 300.0 10 297634 07/28/15 23:34 EAT TAL CHI Total/NA Analysis 353.2 20 298906 08/04/15 22:23 HMW TAL CHI Total/NA Total/NA Prep Analysis SM4500Norg_C 4500 NH3 G 1 297705 07/30/15 12:25 SSF 298053 07/30/15 15:05 SSF TAL CHI TAL CHI Total/NA Analysis 9060A 1 298652 08/05/15 00:08 ELR TAL CHI Total/NA Analysis SM 2540C 1 297787 07/30/15 06:10 CLB TAL CHI Total/NA Total/NA Prep Analysis SM 4500 NH3 B SM 4500 NH3 G 1 298347 08/03/15 21:05 HMW 298482 08/04/15 00:56 HMW TAL CHI TAL CHI Total/NA Total/NA Prep Analysis SM 5220 SM 5220C 1 297640 07/29/15 10:26 LAJ 297641 07/29/15 16:11 LAJ TAL CHI TAL CHI 1 Batch Prepared Number or Analyzed Analyst 297574 07/28/15 17:00 PJH 298031 07/31/15 01:22 PFK Client Sample ID: CSD-3D Lab TAL CHI TAL CHI 12 13 14 Lab Sample ID: 500-99061-5 Date Collected: 07/23/15 09:15 Date Received: 07/28/15 10:00 Matrix: Water Prep Type Total Recoverable Total Recoverable Batch Type Prep Analysis Batch Method 3005A 6020 Total/NA Analysis 300.0 2 297634 07/28/15 23:46 EAT TAL CHI Total/NA Analysis 353.2 2 298906 08/04/15 22:23 HMW TAL CHI Total/NA Total/NA Prep Analysis SM4500Norg_C 4500 NH3 G 1 297705 07/30/15 12:25 SSF 298053 07/30/15 15:07 SSF TAL CHI TAL CHI Total/NA Analysis 9060A 1 298652 08/05/15 00:25 ELR TAL CHI Total/NA Analysis SM 2540C 1 297787 07/30/15 06:12 CLB TAL CHI Total/NA Total/NA Prep Analysis SM 4500 NH3 B SM 4500 NH3 G 1 298347 08/03/15 21:05 HMW 298482 08/04/15 00:59 HMW TAL CHI TAL CHI Total/NA Prep SM 5220 297640 07/29/15 10:26 LAJ TAL CHI Total/NA Analysis SM 5220C 297641 07/29/15 16:11 LAJ TAL CHI Run Dilution Factor 1 1 Batch Prepared Number or Analyzed Analyst 297574 07/28/15 17:00 PJH 298031 07/31/15 01:26 PFK Lab TAL CHI TAL CHI TestAmerica Chicago Page 22 of 26 10 11 Batch Type Prep Analysis Run Dilution Factor 9 8/7/2015 Lab Chronicle Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 1 2 Client Sample ID: CSD-4 Lab Sample ID: 500-99061-6 Date Collected: 07/23/15 14:30 Date Received: 07/28/15 10:00 Matrix: Water 3 4 Prep Type Total Recoverable Total Recoverable Batch Type Prep Analysis Batch Method 3005A 6020 Total/NA Analysis 300.0 10 298636 08/04/15 20:48 EAT TAL CHI Total/NA Analysis 353.2 50 298906 08/04/15 22:24 HMW TAL CHI Total/NA Total/NA Prep Analysis SM4500Norg_C 4500 NH3 G 1 297705 07/30/15 12:25 SSF 298053 07/30/15 15:10 SSF TAL CHI TAL CHI 8 Total/NA Analysis 9060A 1 298652 08/05/15 00:41 ELR TAL CHI 9 Total/NA Analysis SM 2540C 1 297787 07/30/15 06:15 CLB TAL CHI Total/NA Total/NA Prep Analysis SM 4500 NH3 B SM 4500 NH3 G 1 298347 08/03/15 21:05 HMW 298482 08/04/15 01:01 HMW TAL CHI TAL CHI Total/NA Prep SM 5220 297640 07/29/15 10:26 LAJ TAL CHI Total/NA Analysis SM 5220C 297641 07/29/15 16:12 LAJ TAL CHI Run Dilution Factor 1 1 Batch Prepared Number or Analyzed Analyst 297574 07/28/15 17:00 PJH 298031 07/31/15 01:29 PFK Client Sample ID: CSD-4 DUP 5 Lab TAL CHI TAL CHI 6 7 10 11 12 Lab Sample ID: 500-99061-7 Date Collected: 07/23/15 14:30 Date Received: 07/28/15 10:00 Matrix: Water 13 14 Prep Type Total Recoverable Total Recoverable Batch Type Prep Analysis Batch Method 3005A 6020 Total/NA Analysis 300.0 10 298636 08/04/15 21:26 EAT TAL CHI Total/NA Analysis 353.2 50 298906 08/04/15 22:25 HMW TAL CHI Total/NA Total/NA Prep Analysis SM4500Norg_C 4500 NH3 G 1 297705 07/30/15 12:25 SSF 298053 07/30/15 15:13 SSF TAL CHI TAL CHI Total/NA Analysis 9060A 1 298652 08/05/15 00:57 ELR TAL CHI Total/NA Analysis SM 2540C 1 297787 07/30/15 06:17 CLB TAL CHI Total/NA Total/NA Prep Analysis SM 4500 NH3 B SM 4500 NH3 G 1 298347 08/03/15 21:05 HMW 298482 08/04/15 01:04 HMW TAL CHI TAL CHI Total/NA Prep SM 5220 297640 07/29/15 10:26 LAJ TAL CHI Total/NA Analysis SM 5220C 297641 07/29/15 16:13 LAJ TAL CHI Run Dilution Factor 1 1 Batch Prepared Number or Analyzed Analyst 297574 07/28/15 17:00 PJH 298031 07/31/15 01:33 PFK Lab TAL CHI TAL CHI Laboratory References: TAL CHI = TestAmerica Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200 TestAmerica Chicago Page 23 of 26 8/7/2015 Certification Summary Client: RJN Environmental Services LLC Project/Site: Central Sands 14-203 TestAmerica Job ID: 500-99061-1 2 Laboratory: TestAmerica Chicago 3 The certifications listed below are applicable to this report. Authority Wisconsin Program State Program 1 EPA Region 5 Certification ID 999580010 4 Expiration Date 08-31-15 * 5 6 7 8 9 10 11 12 13 14 * Certification renewal pending - certification considered valid. TestAmerica Chicago Page 24 of 26 8/7/2015 i 0 (optional) (optional) . Tes'fAmerlCO Rename 8110 . Chain of Custody Record Contact: 303557 ?47-17? Contact: $790 a] a I Company: ?dld EN DIVC Company: Lab Job A on ree. nwersn ar . ?9 . aino us um er: Phone: 708.534.5200 Fix: 708.534.5211 Address: ?1 5-3-5 9255 Address: Phone: $56 5-?49 @139 I Phone: Page i of Fax: 1 E-Mail: Temperature?0 ofCOOIer: ?1 Cli Ci'entProjeot# . t- l. . . 27.1101 5? y. . 74w 2 03 ream/awe g: 3 1. 115533313339" Project Name Parameter 2' 000m 30 Cigar/ea? 54:11.13 31 $813: 833i :3 in Project Location/State Lab Projectlt 5. Cool to 4? 5 \j a Sampler Lab PM Aw, ?2 3:320 40 M?qd'r?? RE 9: Other 0 3 Sampling 6 ?g a ME 3 0:3 SampieiD Date Time ?3 Comments 1 (?59 I 57331320 4 7< 177,515 a-aoaezJ (1.5242.; .. Z, 15% ?i 6:525 r- 35? I015 y; 56-ch gauge (55w 12130 1 7 (3523 - 42 292/? 1 +20 11" ii Turnaround Time Required (Business Days) 1 Day Days _5Days_7Days Days Sample Disposal Days 5 7:3 Other Disposal by Lab Requested Due Date Return to Client Archive for Months (A fee may be assessed if samples are retained longer than 1 month) . I Roll is Com any Date Time Received By Company Date Time my and 7/22/31 5} My: we 131001161 Relinquis By Company D'ate Time Received 54/ i Company Date I a Time Relinqulshed By Company Date Time Received By Company Date Time Hand Deliveredl . ?mw - CIienLComments 1. . 77-..-.- . _m LY - 7 7. (7 ta?comm?mg: 7 7 Wastewater SE - Sediment Water SO Soil 1 Soil Leachate SL Sludge WI Wipe MS Miscellaneous DW Drinking Water 0L Oil 0 Other 500-99061 000 A - Air TAL-4124-500 (1209) Page 25 of 26 8/7/2015 1 Login Sample Receipt Checklist Client: RJN Environmental Services LLC 2 Job Number: 500-99061-1 Login Number: 99061 List Number: 1 Creator: Kelsey, Shawn M List Source: TestAmerica Chicago 3 4 5 Question Answer Radioactivity wasn't checked or is