SAFETY DATA SHEET Product Trade Name: Revision Date: BDF™515 11-Jun-2015 Revision Number: 10 1. Identification 1.1. Product Identifier Product Trade Name: Synonyms: Chemical Family: Internal ID Code BDF™515 None Polymer Blend HM006801 1.2 Recommended use and restrictions on use Mud additive Application: No information available Uses Advised Against 1.3 Manufacturer's Name and Contact Details Baroid Fluid Services Manufacturer/Supplier Product Service Line of Halliburton P.O. Box 1675 Houston, TX 77251 Telephone: (281) 871-4000 Emergency Telephone: (281) 575-5000 Prepared By Chemical Stewardship Telephone: 1-580-251-4335 e-mail: fdunexchem@halliburton.com 1.4. Emergency telephone number Emergency Telephone Number (281) 575-5000 2. Hazard(s) Identification 2.1 Classification in accordance with paragraph (d) of §1910.1200 Skin Corrosion / Irritation Serious Eye Damage / Eye Irritation Category 2 - H315 Category 1 - H318 2.2. Label Elements Hazard Pictograms Signal Word Danger _____________________________________________________________________________________________ Page 1 / 9 BDF™515 Revision Date: 11-Jun-2015 _____________________________________________________________________________________________ Hazard Statements H315 - Causes skin irritation H318 - Causes serious eye damage Precautionary Statements Prevention P264 - Wash face, hands and any exposed skin thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P332 + P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician Storage None Disposal None Contains Substances Sodium hydroxide CAS Number 1310-73-2 2.3 Hazards not otherwise classified None known 3. Composition/information on Ingredients Substances Sodium hydroxide CAS Number 1310-73-2 PERCENT (w/w) 1 - 5% GHS Classification - US Skin Corr. 1A (H314) Eye Corr. 1 (H318) STOT SE 3 (H335) Met. Corr. 1 (H290) The exact percentage (concentration) of the composition has been withheld as proprietary. 4. First-Aid Measures 4.1. Description of first aid measures If inhaled, remove from area to fresh air. Get medical attention if respiratory Inhalation irritation develops or if breathing becomes difficult. Immediately flush eyes with large amounts of water for at least 30 minutes. Seek Eyes prompt medical attention. Wash off immediately with soap and plenty of water for at least 15 minutes while Skin removing all contaminated clothing and shoes Get medical attention if irritation persists. Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical Ingestion attention. 4.2 Most important symptoms/effects, acute and delayed Causes severe eye irritation which may damage tissue. Causes skin irritation. 4.3. Indication of any immediate medical attention and special treatment needed _____________________________________________________________________________________________ Page 2 / 9 BDF™515 Revision Date: 11-Jun-2015 _____________________________________________________________________________________________ Treat symptomatically. Notes to Physician 5. Fire-fighting measures 5.1. Extinguishing media Suitable Extinguishing Media All standard fire fighting media Extinguishing media which must not be used for safety reasons None known. 5.2 Specific hazards arising from the substance or mixture Special Exposure Hazards Decomposition in fire may produce toxic gases. Reaction with steel and certain other metals generates flammable hydrogen gas. Do not allow runoff to enter waterways. Organic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices are required to minimize this potential. 5.3 Special protective equipment and precautions for fire-fighters Special Protective Equipment for Fire-Fighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. See Section 8 for additional information 6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas. 6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated with contaminating substances and use appropriate methods for collection, storage and disposal. 7. Handling and storage 7.1. Precautions for Safe Handling Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Avoid dust accumulations. Avoid creating or inhaling dust. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for safe storage, including any incompatibilities Storage Information Keep container closed when not in use. Store in a well ventilated area. Store in a cool, dry location. Keep from heat, sparks, and open flames. Store away from acids. Store away from oxidizers. Store away from direct sunlight. Store at temperatures between 40 and 90 F (5 and 35 C). 8. Exposure Controls/Personal Protection 8.1 Occupational Exposure Limits Substances CAS Number Sodium hydroxide 1310-73-2 OSHA PEL-TWA 2 mg/M3 ACGIH TLV-TWA 2 mg/M3 8.2 Appropriate engineering controls _____________________________________________________________________________________________ Page 3 / 9 BDF™515 Revision Date: 11-Jun-2015 _____________________________________________________________________________________________ Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without good cross ventilation. 8.3 Individual protection measures, such as personal protective equipment Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the selection and proper use of personal protective equipment should be determined by an industrial hygienist or other qualified professional based on the specific application of this product. If engineering controls and work practices cannot keep exposure below Respiratory Protection occupational exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of and instruction on using all personal protective equipment, including respirators, should be performed by an Industrial Hygienist or other qualified professional. Dust/mist respirator. (N95, P2/P3) Impervious rubber gloves. Hand Protection Rubber apron. Skin Protection Chemical goggles; also wear a face shield if splashing hazard exists. Eye Protection Eyewash fountains and safety showers must be easily accessible. Other Precautions 9. Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Physical State: Powder Color: Slight Odor: Odor Threshold: Property Brown No information available Values Remarks/ - Method pH: Freezing Point/Range Melting Point/Range Boiling Point/Range Flash Point Flammability (solid, gas) upper flammability limit lower flammability limit 9.5-10.3 (5%) No data available No data available No data available No data available No data available No data available No data available Evaporation rate Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Explosive Properties Oxidizing Properties No data available No data available No data available 0.3 - 0.9 Soluble in water No data available No data available No data available No data available No data available No information available No information available 9.2. Other information VOC Content (%) No data available 10. Stability and Reactivity 10.1. Reactivity _____________________________________________________________________________________________ Page 4 / 9 BDF™515 Revision Date: 11-Jun-2015 _____________________________________________________________________________________________ Not expected to be reactive. 10.2. Chemical Stability Stable 10.3. Possibility of Hazardous Reactions Will Not Occur 10.4. Conditions to Avoid None anticipated 10.5. Incompatible Materials Strong acids. Strong oxidizers. 10.6. Hazardous Decomposition Products Phenol. Formaldehyde. Sulfur dioxide. Carbon monoxide and carbon dioxide. Oxides of nitrogen. 11. Toxicological Information 11.1 Information on likely routes of exposure Eye or skin contact, inhalation. Principle Route of Exposure 11.2 Symptoms related to the physical, chemical and toxicological characteristics Acute Toxicity May cause respiratory irritation. Inhalation Causes severe eye irritation which may damage tissue. Eye Contact Causes skin irritation. Skin Contact May cause abdominal pain, vomiting, nausea, and diarrhea. Irritation of the mouth, Ingestion throat, and stomach. Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% are chronic health hazards. 11.3 Toxicity data Toxicology data for the components Substances Sodium hydroxide CAS Number 1310-73-2 Substances Sodium hydroxide CAS Number Skin corrosion/irritation 1310-73-2 Causes severe burns Substances Sodium hydroxide CAS Number Eye damage/irritation 1310-73-2 Causes severe eye burns (Rabbit) Substances Sodium hydroxide CAS Number Skin Sensitization 1310-73-2 Did not cause sensitization on laboratory animals (guinea pig) Substances Sodium hydroxide CAS Number Respiratory Sensitization 1310-73-2 No information available Substances Sodium hydroxide CAS Number Mutagenic Effects 1310-73-2 Did not show mutagenic effects in animal experiments In vitro tests did not show mutagenic effects Substances CAS Number Carcinogenic Effects LD50 Oral No data available LD50 Dermal 1350 mg/kg (Rabbit) LC50 Inhalation No data available _____________________________________________________________________________________________ Page 5 / 9 BDF™515 Revision Date: 11-Jun-2015 _____________________________________________________________________________________________ Sodium hydroxide 1310-73-2 No data of sufficient quality are available. Substances Sodium hydroxide CAS Number Reproductive toxicity 1310-73-2 No information available Substances Sodium hydroxide CAS Number STOT - single exposure 1310-73-2 May cause respiratory irritation. Substances Sodium hydroxide CAS Number STOT - repeated exposure 1310-73-2 No significant toxicity observed in animal studies at concentration requiring classification. Not applicable due to corrosivity of the substance. Substances Sodium hydroxide CAS Number Aspiration hazard 1310-73-2 Not applicable 12. Ecological Information 12.1. Toxicity Ecotoxicity Effects Product Ecotoxicity Data No data available Substance Ecotoxicity Data Substances CAS Number Sodium hydroxide 1310-73-2 Toxicity to Algae Toxicity to Fish No information available LC50 (96h) 125 mg/L (Gambusia affinis) LC50 (48h) 189 mg/L (Leuciscus melanotus) LC50 (24h) 145 mg/L (Poecilia reticulate) Toxicity to Toxicity to Invertebrates Microorganisms No information available EC50 (48h) 40.4 mg/L (Ceriodaphnia sp.) 12.2. Persistence and degradability Substances Sodium hydroxide CAS Number 1310-73-2 Persistence and Degradability The methods for determining biodegradability are not applicable to inorganic substances. 12.3. Bioaccumulative potential Substances Sodium hydroxide CAS Number 1310-73-2 Log Pow No information available 12.4. Mobility in soil Substances Sodium hydroxide CAS Number 1310-73-2 Mobility No information available 12.5 Other adverse effects No information available 13. Disposal Considerations 13.1. Waste treatment methods Disposal should be made in accordance with federal, state, and local regulations. Disposal Method _____________________________________________________________________________________________ Page 6 / 9 BDF™515 Revision Date: 11-Jun-2015 _____________________________________________________________________________________________ Contaminated Packaging Follow all applicable national or local regulations. 14. Transport Information US DOT UN Number: UN Proper Shipping Name: Transport Hazard Class(es): Packing Group: Environmental Hazards: Not restricted Not restricted Not applicable Not applicable Not applicable US DOT Bulk DOT (Bulk) Not applicable Canadian TDG UN Number: UN Proper Shipping Name: Transport Hazard Class(es): Packing Group: Environmental Hazards: Not restricted Not restricted Not applicable Not applicable Not applicable IMDG/IMO UN Number: UN Proper Shipping Name: Transport Hazard Class(es): Packing Group: Environmental Hazards: Not restricted Not restricted Not applicable Not applicable Not applicable IATA/ICAO UN Number: UN Proper Shipping Name: Transport Hazard Class(es): Packing Group: Environmental Hazards: Not restricted Not restricted Not applicable Not applicable Not applicable Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable None Special Precautions for User: 15. Regulatory Information US Regulations US TSCA Inventory All components listed on inventory or are exempt. EPA SARA Title III Extremely Hazardous Substances CAS:50-00-0//Chemical Name: Formaldehyde///TPQ: 500 EPA SARA (311,312) Hazard Class Acute Health Hazard _____________________________________________________________________________________________ Page 7 / 9 BDF™515 Revision Date: 11-Jun-2015 _____________________________________________________________________________________________ EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372: Sodium Hydroxide//1310-73-2 Formaldehyde//50-00-0 EPA CERCLA/Superfund Reportable Spill Quantity EPA Reportable Spill Quantity is 27933 Pounds based on Sodium hydroxide (CAS: 1310-73-2). EPA RCRA Hazardous Waste Classification If product becomes a waste, it does NOT meet the criteria of a hazardous waste as defined by the US EPA. California Proposition 65 The California Proposition 65 regulations apply to this product. MA Right-to-Know Law One or more components listed. NJ Right-to-Know Law One or more components listed. PA Right-to-Know Law One or more components listed. Canadian Regulations Canadian DSL Inventory All components listed on inventory or are exempt. 16. Other information Preparation Information Prepared By Chemical Stewardship Telephone: 1-580-251-4335 e-mail: fdunexchem@halliburton.com Revision Date: 11-Jun-2015 Reason for Revision SDS sections updated: 2 Additional information For additional information on the use of this product, contact your local Halliburton representative. For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at 1-580-251-4335. _____________________________________________________________________________________________ Page 8 / 9 BDF™515 Revision Date: 11-Jun-2015 _____________________________________________________________________________________________ Key or legend to abbreviations and acronyms bw–bodywei ght CAS–Chemi calAbst r act sSer vi ce EC50–Ef f ect i veConcent r at i on50% Er C50–Ef f ect i veConcent r at i ongr owt hr at e50% LC50–Let halConcent r at i on50% LD50–Let halDose50% LL50–Let halLoadi ng50% mg/ kg–mi l l i gr am/ ki l ogr am mg/ L–mi l l i gr am/ l i t er NI OSH–Nat i onalI nst i t ut ef orOccupat i onalSaf et yandHeal t h NTP–Nat i onalTox i col ogyPr ogr am OEL–Occupat i onalEx posur eLi mi t PEL–Per mi ssi bl eEx posur eLi mi t ppm –par t spermi l l i on STEL–Shor tTer m Ex posur eLi mi t TWA–Ti meWei ght edAver age UN–Uni t edNat i ons h - hour mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day Key literature references and sources for data www.ChemADVISOR.com/ Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user. End of Safety Data Sheet _____________________________________________________________________________________________ Page 9 / 9