EPA 600/R-12/724 December 2012 www.epa.gov/ord Leaching Behavior of “AGREMAX” Collected from a Coal-Fired Power Plant in Puerto Rico ce of Research and Development EPA-600/R-12/724 December 2012 Leaching Behavior of “AGREMAX” Collected from a Coal-Fired Power Plant in Puerto Rico A.C. Garrabrants1, D.S. Kosson1, R. DeLapp1 and Peter Kariher2 1 Vanderbilt University Civil and Environmental Engineering Nashville, TN 37215 2 ARCADIS-US, Inc. Research Triangle Park, NC 27711 Category III / Applied Research Contract No. EP-C-09-027 Work Assignment No. 3-07 Prepared for Susan A. Thorneloe U.S. Environmental Protection Agency Office of Research and Development National Risk Management Research Laboratory Air Pollution Prevention and Control Division Research Triangle Park, NC 27711 Leaching Behavior of “AGREMAX” Collected from a Coal-Fired Power Plant in Puerto Rico Notice The U.S. Environmental Protection Agency through its Office of Research and Development partially funded and managed the research described here under Contract Number EP-C-09-27 coordinated by ARCADIS-US, Inc. Prior to publication, this report will be subjected to the Agency’s peer and administrative review to be approved for publication as an EPA document. i Leaching Behavior of “AGREMAX” Collected from a Coal-Fired Power Plant in Puerto Rico ABSTRACT “AGREMAX” is a partially solidified mixture of coal combustion fly ash and bottom ash. Under the request of the United States Environmental Protection Agency (US EPA) Region 2, the US EPA Office of Research and Development (ORD) has performed two of the leaching tests contained in the Leaching Environmental Assessment Framework (LEAF) on subsamples of AGREMAX sampled from the AES Puerto Rico L.P. coal-fired power plant in Guayama, Puerto Rico. Subsamples of AGREMAX were collected and shipped under chain of custody to ARCADIS-US, Inc. (ARCADIS) serving as the onsite contractor for the EPA ORD Air Pollution Prevention and Control Division. Homogenized samples of the solid material were tested to characterize leaching behavior of AGREMAX during pHdependent leaching using Method 1313 and liquid-to-solid ratio (L/S)-dependent leaching in a percolation column using Method 1314. Method 1313 was conducted at EPA’s Research Triangle Park Laboratories by ARCADIS while Method 1314 was performed at Vanderbilt University (VU). Leaching test eluates were analyzed for nearly 40 target analytes including major, minor and trace constituents. This document presents the results of LEAF-based leaching tests. Eluate concentrations from these leaching methods were compared to the minimum of indicator values derived from US EPA Region 9 regional screening levels (RSLs) for tapwater or US national drinking water regulations (NDWRs) as requested by US EPA Region 2 to put eluate concentrations into perspective. The comparison was based on an indicator ratio defined as the maximum applicable eluate concentration divided by the minimum indicator value. The maximum applicable eluate concentration was considered to be the maximum eluate concentration within an applicable pH range of pH 6.5 to 11.5 for Method 1313 or the maximum eluate concentration over the entire L/S range between 0.2 and 10 mL/g-dry for Method 1314. Indicator ratios greater than 100 were observed for arsenic, boron, chloride and chromium based on results from both leaching tests. For fluoride, lithium and molybdenum, indicator ratios for Method 1314 test results were greater than 100 while indicator ratios for Method 1313 test results were between 10 and 100. Other analytes with indicator ratios between 10 and 100 include selenium, sulfate and thallium in both pH- and L/S-dependent leaching tests. ii Leaching Behavior of “AGREMAX” Collected from a Coal-Fired Power Plant in Puerto Rico ABBREVIATIONS ARCADIS CCR(s) DIC DOC DQI(s) DWEL(s) IC ICP-MS ICP-OES LEAF L/S L/S i LSP MCL(s) MDL ML NDWR(s) ORD QAPP QA/QC RCRA RSL(s) TCLP US EPA VU ARCADIS-US, Inc., Research Triangle Park, NC coal combustion residue(s) dissolved inorganic carbon dissolved organic carbon data quality indicator(s) drinking water equivalent level(s) ion chromatography inductively coupled plasma-mass spectrometry inductively coupled plasma-optical emission spectroscopy Leaching Environmental Assessment Framework cumulative liquid-to-solid ratio [L/kg, dry basis] liquid-to-solid ratio through end of interval or test fraction i [mL/g, dry basis] liquid-solid partitioning maximum concentration level(s) method detection limit minimum level of quantitation national drinking water regulation(s) Office of Research and Development (US EPA) quality assurance project plan quality assurance/quality control Resource Conservation and Recovery Act regional screening level(s), US EPA Region 9 toxicity characteristic leaching procedure, US EPA Method 1311 United States Environmental Protection Agency Vanderbilt University, Nashville, TN iii Leaching Behavior of “AGREMAX” Collected from a Coal-Fired Power Plant in Puerto Rico Table of Contents ABSTRACT ................................................................................................................................................................... II ABBREVIATIONS ......................................................................................................................................................III INTRODUCTION ..........................................................................................................................................................1 CHARACTERIZATION APPROACH ........................................................................................................................1 MATERIAL DESCRIPTION........................................................................................................................................2 CHARACTERIZATION METHODS ..........................................................................................................................2 Method 1313: Liquid-Solid Partitioning as a Function of Eluate pH using a Parallel Batch Extraction Procedure ..........................................................................................................................................................2 Method 1314: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio using an Up-Flow Percolation Column Procedure .......................................................................................................................................3 ELUATE CHEMICAL ANALYSIS ..................................................................................................................................................... 4 Inductively-Coupled Plasma – Optical Emissions Spectrometry ........................................................................4 Inductively-Coupled Plasma – Mass Spectrometry..................................................................................................4 Ion Chromatograph .............................................................................................................................................................4 Total Carbon Analysis .........................................................................................................................................................5 Quality Assurance/Quality Control ...............................................................................................................................5 ENVIRONMENTAL REFERENCE CONCENTRATIONS AND INDICATOR RATIOS ...................................................................... 5 RESULTS AND DISCUSSION .....................................................................................................................................8 TITRATION CURVE AND ELUATE PH .......................................................................................................................................... 8 ELUATE CONCENTRATIONS AS FUNCTIONS OF PH AND L/S.................................................................................................. 8 DATA QUALITY EVALUATION ....................................................................................................................................................10 Analytical QA/QC Results ............................................................................................................................................... 10 Method Blank Analysis Results ..................................................................................................................................... 11 COMPARISON OF LEACHING RESULTS TO ENVIRONMENTAL REFERENCE CONCENTRATIONS ....................................... 11 SUMMARY .................................................................................................................................................................. 13 REFERENCES ............................................................................................................................................................. 14 APPENDIX A. GRAPHICAL LEACHING TEST DATA APPENDIX B. DETAILED QA/QC REPORT iv INTRODUCTION Historically, the results of leaching tests have been the basis for environmental performance assessment of solid materials (e.g., contaminated materials, industrial wastes). For example, the United States Environmental Protection Agency (US EPA) uses the Toxicity Characteristic Leaching Procedure (TCLP; EPA Method 1311) as a regulatory test to classify wastes as “hazardous” or “non-hazardous” (i.e., wastes to be managed under Subtitle C or Subtitle D of RCRA, respectively). TCLP is a single batch extraction procedure using acetic acid that is considered to produce an eluate that estimates the leachate resulting from codisposal of the test material with municipal solid waste. The single extraction of TCLP allows for a simple evaluation process by comparison of eluate concentration results to allowable concentration limits for selected constituents (see 40 CFR 261.24). Although the results of any scenario-simulation test should not be used outside of the intended simulation test conditions, the results of TCLP have been broadly applied beyond their intended use in waste classification (SAB, 2003). More recently, the US EPA has been in the process of developing, validating, and adopting the leaching tests of the Leaching Environmental Assessment Framework (LEAF) for inclusion into its analytical chemistry testing guidance, SW-846, with intended use in situations where TCLP is not required or best-suited (Garrabrants et al., 2010; 2012a; 2012b). The LEAF testing and assessment approach has been developed to provide a comprehensive testing regime through multi-point leach testing over a range of test conditions considered suitable for complex environmental evaluations and material characterizations. The LEAF testing approach, test methods and assessment methodology were developed in parallel with European leach test development efforts. A primary difference between the LEAF methods and TCLP is that the LEAF methods are intended to characterize leaching from a material over a broad range of test conditions that may occur in the environment (e.g., varying values for pH, liquid-to-solid ratio, waste form, etc.) rather than at a single set of test conditions. Testing over a range of conditions provides assessment flexibility in that the results can be used to compare potential release under various environmental conditions or between material treatments. The results of the four leaching tests in LEAF may be used individually or in combinations to characterize the leaching behavior of a material for many plausible field scenarios. The LEAF testing results are intended to provide a source term for subsequent constituent transport and fate evaluation, recognizing that dilution and attenuation of constituents often will occur from the point of release to the point of exposure or compliance evaluation. The LEAF testing methodologies have been applied extensively to coal combustion residues (CCRs) as part of US EPA research on the potential impacts of land disposal or from engineering and commercial applications using fly ash and other secondary materials (Sanchez et al., 2006; 2008; Kosson et al., 2009; Thorneloe, 2010). US EPA Office of Research and Development (ORD) was asked by US EPA Region 2 to determine the leaching properties of a blend of coal combustion fly ash and bottom ash (“AGREMAX”) using the LEAF leach testing approach. This report presents the results of LEAF testing of AGREMAX samples collected from the AES Puerto Rico L.P. coal-fired power plant in Guayama, Puerto Rico. CHARACTERIZATION APPROACH Leaching tests for determining the liquid-solid partitioning (LSP) of AGREMAX as a function of pH using Method 1313 and as a function of liquid-to-solid ratio (L/S) using EPA Method 1314. Batch pH-dependence testing (Method 1313) was conducted by ARCADIS-US, Inc. (ARCADIS) serving as an on-site contractor for the EPA ORD Air Pollution Prevention and Control Division at the National Risk Management and Research Laboratory in the Research Triangle Park, North Carolina. Percolation column testing using Method 1314 was conducted at Vanderbilt University (VU). The remaining LEAF test methods (i.e., EPA Method 1315 and 1 EPA Method 1316) were not conducted because Method 1315 was not considered appropriate based on the granular nature of the AGREMAX while Method 1316 is somewhat redundant in that it yields similar leaching data as provided by Method 1314. All leaching tests were performed between May and July 2012 and were completed within three months of receipt of the field samples from Region 2. Eluate pH and conductivity were measured directly by the performing laboratory (i.e., ARCADIS for Method 1313 or VU for Method 1314) and eluate chemical analysis for analytes of concern was conducted at VU. All chemical analyses were conducted in accordance with an on-going quality assurance project plan (QAPP) for characterization of CCRs approved by US EPA ORD (Kosson et al., 2009). In order to put the results of Method 1313 and Method 1314 into perspective with environmental reference concentrations, this report compares leaching test eluate concentrations to a set of indicator values recommended by US EPA Region 2 (Grossman, personal communications, 19 July 2012; 20 July 2012) for this application. The indicator values were derived from US national drinking water regulations (NDWRs) based on a combination of primary and secondary drinking water standards (US EPA, 2012a) and on US EPA Region 9 regional screening levels (RSLs) for residential tapwater (US EPA, 2012b). A comparison was made between leaching data and the environmental reference concentrations for 29 analytes including Al, As, B, Ba, Be, Cd, Cl, Cr, Co, Cu, F, Fe, Li, Mn, Mo, Ni, NO 2 , NO 3 , Pb, PO 4 , Sb, Se, SO 4 , Sr, Tl, Sn, U, V and Zn. MATERIAL DESCRIPTION AGREMAX is generated by the AES Puerto Rico, LP coal-fired power plant in Guayama, Puerto Rico, and is a combination of 80% coal combustion fly ash and 20% bottom ash by weight. The component materials are mixed together and hydrated. The combined material is transported by conveyor belt to a yard where it is laid out to cure for 7 to 14 days. The cured solidified material is broken into manageable pieces using heavy machinery and transferred to a crushing machine for particle size reduction (Rivera, personal communication, 16 June 2011). Two 5-gallon plastic buckets of cured and crushed AGREMAX were collected from the AES Puerto Rico L.P. coal-fired power plant in Guayama, Puerto Rico and sent under chain of custody by US EPA Region 2 to ARCADIS for homogenization prior to testing. The samples were designated with the material code “AES” and a replicate letter based on the sample location (e.g., “AES-A” was collected as one location while “AES-B” was collected at the other sampling location). The two buckets from each location were homogenized by cone and quartering (ASTM, 2003). After homogenization, samples were returned to the 5-gallon buckets and stored at ARCADIS for archiving and pH-dependent leach testing using Method 1313. Subsamples from each sample location – enough to fill two 500-mL high density polyethylene bottles – were sent to VU for percolation leach testing using Method 1314. CHARACTERIZATION METHODS Method 1313: Liquid-Solid Partitioning as a Function of Eluate pH using a Parallel Batch Extraction Procedure Method 1313 is an equilibrium-based leaching test designed to provide eluate solutions representing the LSP curve of constituents as a function of eluate pH (Garrabrants et al., 2010; 2012a; 2012b). The procedure consists of nine parallel batch extractions at targeted pH values and one extraction at the natural pH of the 2 material. 1 The solid material may require particle size reduction by crushing in order to facilitate the approach to solid-liquid equilibrium within a reasonable extraction timeframe. Dilute acid or base in deionized water is added to each extraction according to a pre-test titration in order to achieve final extract pH values at specified target values ranging between 2 and 13 at an L/S of 10 mL/g-dry. The extraction contact time ranges from 24 to 72 hours based on the grain size of the “as tested” material (i.e., the material after any particle size reduction or air drying required to improve the handling of the “as received” material). The pH and conductivity of the final extract solution are recorded and vacuum- or pressure-assisted filtration is used to separate the liquid and solid phases prior to chemical analysis of the eluate. Eluate concentrations for constituents of interest are plotted as a function of eluate pH allowing for comparison to quality control and assessment limits. Eluate concentrations may also be interpolated to the target pH values to provide a uniform basis for comparison of results as the recorded eluate pH is likely to differ slightly from target values within specified pH tolerances. Method 1314: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio using an Up-Flow Percolation Column Procedure Method 1314 is an up-flow percolation column procedure used to evaluate the release of constituents from solid materials as a function of cumulative L/S (Garrabrants et al., 2010; 2012a; 2012b). 2 In the context of the column test, L/S is defined as the volume of liquid passing through the column relative to the dry equivalent mass of test material in the column bed and is expressed in units of mL/g-dry. As it relates to conditions in the field, L/S can be considered a surrogate measure for time when infiltration rates are considered. Approximately 300-600 grams of “as is” or air-dried solid material (moisture content less than ca. 20% dry basis) is packed under moderate compactive effort into a 5-cm diameter x 30-cm long column. The test material is packed in five “lifts” with each lift hand tamped using a 1-cm diameter rod. Layers of clean silica sand are used at the top and bottom of the column to provide flow regulation on the inlet side and coarse filtration at the outlet. Leaching solution (eluent) is pumped upward through the material and eluate is collected as nine discrete volume fractions of the continuous elution volume. The up-flow percolation mode is intended to minimize air entrapment and flow channeling. The pump flow rate is adjusted to provide a volume of eluent equivalent to 0.75±0.25 L/S per day. For primarily inorganic materials, deionized water is used as the eluent for testing; however, a 1 mM solution of CaCl 2 may be used when testing certain materials (e.g., organic soils, clayey materials) where deflocculation of clay layers or dissolution of organic carbon may be a concern. The collection bottle is placed at a height of 6 to 12 inches above the column to provide sufficient hydraulic head to ensure flow while avoiding siphoning as well as to minimize backpressure which can cause leaks in the system. The nine eluate fractions are collected at specified L/S values of 0.2, 0.5, 1.0, 1.5, 2.0, 4.5, 5.0, 9.5, and 10 mL/g-dry. Analytical sample compositing is allowed depending on the intended use of the test results. The eluate pH, conductivity and (optionally) oxidation-reduction potential are recorded for each fraction prior to filtration through a 0.45-µm membrane and preservation of an analytical sample. After chemical analysis of analytical samples, cumulative release from the column at the specified L/S values is calculated from eluate concentrations and interval liquid-solid ratios (L/S i ). The outputs of Method 1314 include graphs of eluate concentration and cumulative release plotted as a function of L/S, which are intended to illustrate changes in leaching that develop as percolation progresses and L/S increases. The natural pH (also referred to as “own pH”) is the final eluate pH response of a deionized water extraction (i.e., no acid or base added) of a solid material conducted at an L/S 10 mL/g-dry. 1 2 For the purposes of this report, both batch liquid-to-solid ratio and column test cumulative liquid-to-solid ratio will be denoted as L/S whereas the liquid-to-solid ratio for individual test fractions from the column will be denoted as L/Si where the value i represents the endpoint L/S. For example, L/S0.2 refers to first fraction of Method 1314 starting at L/S=0 mL/g-dry and ending at an L/S=0.2 mL/g-dry while L/S10 refers to the last fraction of the test starting at L/S=9.5 mL/g-dry ending at L/S=10 mL/g-dry. 3 Eluate Chemical Analysis All eluate solutions were analyzed at VU to minimize variability in the results associated with individual analytical methods and quality assurance/quality control (QA/QC) assessments. A suite of 40 analytes were measured for the purposes of preparing data for any future potential chemical speciation or other modeling. Inductively-Coupled Plasma – Optical Emissions Spectrometry The concentrations of a suite of analytes were measured by inductively coupled plasma – optical emissions spectrometry (ICP-OES) on a Varian ICP Model 720-ES (Agilent Technologies, Santa Clara, CA) following SW846 Method 6010 (US EPA, 2007b). An ICP-OES analytical range of approximately 0.1 mg/L to 25 mg/L for trace metals was calibrated using five-point standard curves and the analytical range was extended for major components to a maximum of 500 mg/L using seven-point standard curves. During analysis of solutions, blanks and calibration check standards (~0.5 mg/L) were monitored every 10 to 20 samples with the requirement that recoveries be within 20% of the specified value. Analyses were performed on undiluted samples when possible and, when necessary, samples were diluted gravimetrically to within the targeted analytical range using 1% (v/v) Optima grade nitric acid (Fisher Scientific) in deionized water. Yttrium at 10 mg/L was used as an internal standard. One analytical matrix spike was checked for each replicate set of analytical samples of a leaching test (i.e., approximately one spike for every ten analytical samples). For each 5 mL sample aliquot, spikes were prepared by addition of 1 for trace species or 100 L of a 1,000 g/L standard solution for major species. Inductively-Coupled Plasma – Mass Spectrometry Inductively-coupled plasma – mass spectrometry (ICP-MS) was used to determine eluate concentrations for analytes where the detection limit for ICP-OES was above the screening criteria (i.e., As, Be, Sb, Se, Tl) and for analytes not well-quantified by ICP-OES (i.e., Cs, Re, Sn). ICP-MS was conducted following SW-846 Method 6020 (US EPA, 2007c) using a Perkin Elmer model ELAN DRC II (Perkin Elmer, Waltham, MA). A seven point calibration curve was created by dilution of a bulk standard and used to calibrate the analytical range for lowlevel analytes (0.01 to 100 µg/L) and mid-level analytes (1 to 250 µg/L). ICP-MS was conducted initially on 10:1 volumetric dilutions (water-to-sample) of eluate solutions to minimize total dissolved solids loading to the instrument. If the concentrations of the 10:1 dilutions exceeded the calibration range, additional dilutions at 100:1 and 1000:1 were analyzed. If analysis of the diluted sample resulted in concentrations below the ML, the analysis is repeated with full strength analytical sample. 10 mg/L indium solution and a 10 mg/L bismuth solution were added to each 10 mL diluted sample aliquot prior to analysis. Internal standards of indium and bismuth are used to adjust for the concentration response for analytes with mass range below and above 150, respectively. Ion Chromatograph The concentrations of anions (i.e., Br, Cl, F, NO 2 , NO 3 , PO 4 , SO 2 ) analytical samples were determined by ion chromatography (IC) using a Dionex DX600 chromatograph (Dionex Corporation, Sunnyvale, CA) with a conductivity detector following SW-846 Method 9056A (US EPA, 2007d). A five-point standard curve was created by dilution of a seven-anion bulk standard and used to calibrate the analytical range which varied based on the relative concentrations of analytes in the bulk standard. Analytical blanks and calibration check standards at approximately 1 mg/L were measured after every ten analytical samples and compared to acceptable QA/QC criteria (i.e., calibration standard recoveries were required to be 85-115% and concentrations in analytical blanks required to be non-detectable). 4 Total Carbon Analysis Total carbon analysis following SW-846 Method 9060 (US EPA, 2004) for all eluates was performed on a Shimadzu model TOC-V CPH/CPN (Shimadzu Scientific Instruments Inc., Columbia, MD) to determine the concentrations of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC) in analytical samples. Five-point calibration curves for the analytical range between 1 and 100 mg/L were generated for both DIC and non-purgeable DOC analyses. The value for a minimum acceptable standard curve correlation coefficient was set at 0.995. An analytical blank and a calibration check standard at approximately 1 mg/L were measured after every ten analytical solutions and the results compared to acceptable QA/QC criteria (i.e., the recovery of calibration checks were required to be 85-115% and concentrations in analytical blanks were required to be non-detectable). Quality Assurance/Quality Control A series of QA/QC assessments, including method and analytical blanks, spikes, duplicates, and detection limits evaluations, were used to ensure that chemical analysis of eluate solutions were of high quality and that test results were not influenced by external sources of target analytes. Data quality indicators (DQIs), or the applicable criteria established in the project QAPP for ensuring adequate data quality, were reviewed and accepted by US EPA ORD prior to the start of characterization. Chemical Analysis For each analyte, the method of chemical analysis, method detection limit (MDL), and minimum level of quantitation (ML) are presented in Table 1. MDL and ML values were determined by VU following guidance in the Technical Support Document for the Assessment of Detection and Quantitation Approaches (US EPA, 2003). These values were used while assessing the quality control of eluate concentrations as well as in the interpretation and reporting of results. Concentrations measured at values less than the MDL were reported as “non-detected” in tabular formats, but were set to a value of ½ the MDL value for plotting and data analysis. Concentrations measured at less than the ML but greater than the MDL were reported as “estimated values” and were maintained as measured for plotting and data analysis. Method Blank Analysis Each of the LEAF methods includes requirements for the preparation and collection of method blanks which are analytical samples used to assess the potential for interferences in the test results due to contamination from reagent sources or equipment surfaces. Method blanks typically are extractions conducted using the same procedure as the test method, but excluding the solid test material. For Method 1314 where the only reagent is deionized water or 1mM CaCl 2 solution used as an eluant, the method requires that a sample of the eluant is collected as a method blank. For Method 1313 where test reagents include aliquots of acid and base added to deionized water, the three specified method blanks include samples of (i) deionized water, (ii) the extraction fluid at the highest level of acid addition and (iii) the extraction fluid at the highest level of base addition. Using an algorithm developed for validation of the LEAF test methods, the analyte concentration result of a eluate solution (i.e., Method 1313 extraction or Method 1314 eluent fraction) is considered to be influenced by external sources of contaminants if the analyte concentration in the method blank associated with the eluate solution has a valid detectable concentration greater than 20% of the concentration in the eluate solution (Garrabrants et al., 2012a; 2012b). Method blanks with analyte concentrations below the method limit of quantitation are considered not to influence eluate concentrations. Environmental Reference Concentrations and Indicator Ratios In order to place leaching test results into context with environmental reference concentrations, the results of leach testing (i.e., eluate concentrations for Method 1313 and Method 1314) were compared to the set of environmental reference concentrations shown in Table 1. The appropriate sources of environmental 5 reference concentrations designated by US EPA Region 2 were the US EPA Region 9 residential tapwater RSLs and the NDWRs. The NDWRs consist of a combination of primary maximum contaminant levels (MCLs), and treatment technology action levels, which are enforceable regulatory standards, and secondary MCLs and drinking water equivalent levels (DWELs) which are guidance. Based on guidance from US EPA Region 2, From these two sources of reference concentrations, a final set of environmental reference concentrations for comparison with leaching test results was compiled from these two sources by selecting the lower of the two environmental reference concentrations (RSL and NDWR) for each analyte. 3 The selection methodology and final set of environmental reference concentrations were reviewed and approved by US EPA Region 2 prior to use in this project (Grossman, personal communication, 20 July 2012). Indicator ratios were calculated as the maximum eluate concentration from leaching test results (i.e., the maximum concentration within the applicable pH range of 6.5-11.5 or the maximum concentration within the range of L/S-dependent leaching) divided by the selected environmental reference concentration for each analyte. 3 The NDWRs and RSLs were developed for different purposes and so the values for any constituent can differ substantially in some cases. The chromium and arsenic MCL values in particular are several orders of magnitude above the RSLs. As enforceable drinking water standards, MCLs result from rulemaking that considers not only risk, but the feasibility of the regulation on a national basis. The risks corresponding to MCLs may therefore range up to an estimated cancer risk of one per 10,000 and occasionally somewhat higher. MCLs also may not reflect the very latest science, as rulemaking is expensive and time consuming, and so MCLs are not updated as easily or frequently as RSLs. RSLs are non-regulatory guidance values used in assessing Superfund sites, and uniformly represent cancers risks of one per million, or a Hazard Quotient of one for noncarcinogens (G. Helms, personal communication, 1 November 2012). 6 Table 1. Analytical Methods with MDLs and MLs Compared to Environmental Reference Concentrations. The final set of Environmental Reference Concentrations used for comparison to leaching tests results is indicated in bold. d d Analyte Aluminum Antimony Arsenic* Barium Beryllium Boron Bromide Cadmium Calcium Cesium Chloride Chromium* Cobalt Copper Dissolved Inorganic Carbon Dissolved Organic Carbon Fluoride Iron Lead Lithium Magnesium Manganese Molybdenum Nickel Nitrate Nitrite Phosphate Phosphorus Potassium Selenium Silicon Sodium Strontium Sulfate Sulfur Thallium* Tin Titanium Uranium Vanadium Zinc Symbol Al Sb As Ba Be B Br Cd Ca Cs Cl Cr Co Cu DIC DOC F Fe Pb Li Mg Mn Mo Ni NO 3 NO 2 PO 4 P K Se Si Na Sr SO 4 S Tl Sn Ti U V Zn Environmental Reference Concentrations NDWR RSLs (µg/L) (µg/L) 50-200N1 16,000 6 6 10 0.045 2,000 2,900 4 16 7N2 3,100 5 250,000N1 100 1,300N3 4,000 300N1 15N3 6.9 1,600 0.031R1 4.7 620 620 11,000 31 1,600N2 200N2 700N2 10,000 1,000 50 20,000N2 250,000N1 2 30 10N2 320 78 300 25,000 1,600 760,000 78 9,300 0.16 9,300 47 78 4,700 Analytical Method ICP-OES ICP-MS ICP-MS ICP-OES ICP-MS ICP-OES IC ICP-MS ICP-OES ICP-MS IC ICP-MS ICP-OES ICP-OES TOC TOC IC ICP-OES ICP-MS ICP-OES ICP-OES ICP-OES ICP-OES ICP-OES IC IC IC ICP-OES ICP-OES ICP-MS ICP-OES ICP-OES ICP-OES IC ICP-OES ICP-MS ICP-MS ICP-OES ICP-MS ICP-OES ICP-OES MDL (µg/L) 1 0.08 0.64 1 0.64 1 17 0.17 2.6 0.49 6.5 0.5 1.8 3.7 130 170 7 2 0.23 1.9 1.1 2 1.2 1.8 26 18 24 3.7 1.6 0.52 1.1 2.5 1 21 6.8 0.51 0.7 2 0.3 1.5 1 ML (µg/L) 5 0.2 2 5 2 5 50 0.5 10 2 20 2 5 10 500 500 20 10 1 10 5 10 5 5 100 50 100 10 5 2 5 10 5 100 20 2 2 10 1 5 5 Notes: RSLs = Residential Tapwater Regional Screening Levels for US EPA Region 9 (US EPA, 2012b) R1 Chromium RSL based on Cr(VI) NDWRs = National Primary Drinking Water Regulations (US EPA, 2012a) unless noted: N1 National Secondary Drinking Water Regulations - non-enforceable guideline N2 Drinking Water Equivalent Level (DWEL) N3 Treatment Technique Action Level * MDL greater than minimum indicator value. 7 RESULTS AND DISCUSSION In the following section, a brief presentation of pH- and L/S-dependent leaching results for selected analytes is shown to illustrate the general results presentation and compare testing results from Method 1313 and Method 1314. Full presentation of leaching results for all tests and analytes is provided in Appendix A. Titration Curve and Eluate pH Figure 1 shows the titration curve, i.e., eluate pH versus acid addition from Method 1313 (left) and the eluate pH recorded in test fractions of Method 1314 (right). 14 14 AES-M1313-A AES-M1313-B Natural pH AES-M1314-A AES-M1314-B Eluate pH 10 8 12 10 Eluate pH 12 6 8 6 4 4 2 2 0 AES-M1314-A AES-M1314-B 0 -2 0 2 4 6 8 10 12 14 Acid/Base Addition (meq/g) 0.1 1 10 L/S (L/kg) Figure 1. Eluate pH results for Method 1313 (left) and Method 1314 (right) testing of AGREMAX. Each figure shows results for two test replicates (e.g., AES-M1313-A and AES-M1313-B) corresponding to the two material replicates. For the Method 1313 results, the natural pH of AES is 10.9 as indicated by the circled data in the Method 1313 figure for the pH response when no acid or base is added. The range of pH for Method 1314 eluates is 10.9 at low L/S to 10.2 at high L/S. The eluate pH range from the column test is consistent with the natural pH measured from the pH-dependent leaching test. Eluate Concentrations as Functions of pH and L/S The concentrations of arsenic, boron, cadmium and selenium resulting from testing AGREMAX using Method 1313 and Method 1314 are shown in Figure 2. Eluate concentrations are presented for both tests as a function of pH (left panel) and for only Method 1314 as a function of L/S (right panel). Plotting L/Sdependent data as a function of pH allows for comparison of eluate concentrations at low and high L/S values relative to the M1313 LSP curve. The scale of the vertical axes of the two panels has been coordinated so that the progression of L/S-dependent data from low to high L/S can be transferred to the pH-dependent leaching graph using the eluate concentrations values. In the pH-dependent leaching panel (left) gold, dashed vertical lines represent the bounds of an applicable pH range for pH-dependent data. The vertical lines focus the assessment toward the range of potential pH values anticipated. In the case of AGREMAX, the applicable pH range was determined by US EPA Region 2 to be bounded at low pH by the minimum value in the NDWRs (i.e., pH 6.5) and at the upper pH by a pH value ½ unit above the natural pH of the AES sample (i.e., pH 11.5). 8 1 0.1 0.1 NDWR 0.01 TCLP (90% >90% >90% >90% 100% 100% Overall Results Precision 1.9% 2.8% NA 2.0 2% 0.2% Completeness 100% 100% 100% 100% 100% 100% NA = “not available” - RSD as IC analysis is based on a single measurement. 4 TCLP does not require measurement and recording of the final extract pH (i.e., after tumbling). If, however, the final pH had been documented, the TCLP concentration values could be plotted as a function of pH which would provide better perspective on how TCLP data correspond to LEAF testing results. 10 In order to ensure that the analytical techniques accurately account for the target analytes in the analytical solution, matrix spikes (i.e., samples of the analytical solution with addition of a known mass of target analytes) were measured and the recovered spiked mass calculated. The criterion for acceptable spike recovery was that the mass recovered should be between 80 and 120% of the mass added to the sample. Table 3 presents a summary of the spike recovery results for each analytical technique (e.g., ICP-OES, ICP-MS, etc.) and leaching method (i.e., Method 1313 and Method 1314) as a percentage of the mass added to analytical sample. The table shows the mean spike recovery as well as the minimum and maximum spike recovery for all analytes measured by that analytical method. No matrix spikes were conducted for IC in accordance with the QAPP approved by the EPA QA personnel. All spike recoveries for ICP-OES, ICP-MS and carbon analyses were well within the 80 to 120% criteria. Table 3. Analytical Matrix Spike Recovery Summary. Method 1313 Measurement ICP-OES – cations ICP-MS – cations IC – anions Carbon – DIC, DOC Note: Method EPA Method 6010 EPA Method 6020 EPA Method 6056A EPA Method 9060 Mean 99% 99% NA 92% Min 89% 94% NA 91% Method 1314 Max 115% 104% NA 94% Mean 100% 98% NA 93% Min 85% 92% NA 91% Max 113% 102% NA 96% NA = “not available” – Matrix spikes were not conducted for IC analysis. Method Blank Analysis Results Method blank analysis for both Method 1313 and Method 1314 showed that no method blanks had analyte concentrations above the ML values with the exception of those Method 1313 method blanks stemming from addition of acid or base to deionized water (e.g., potassium from KOH addition in the Method 1313 base method blank, or nitrate from HNO 3 addition in the Method 1313 acid method blank). Therefore, method blanks were not considered to influence eluate concentrations for any of the eluate concentrations from either leaching test. Comparison of Leaching Results to Environmental Reference Concentrations In order to facilitate the comparison of eluate concentrations to the selected environmental reference concentrations, the indicator ratio was defined as the maximum eluate concentration (i.e., the maximum concentration within the applicable pH range of 6.5-11.5 or the maximum concentration within the scope of L/S-dependent leaching) divided by the selected environmental reference concentration. The indicator ratio is intended to place leaching test eluate concentrations for various analytes into perspective. However, the indicator ratio does not consider any dilution or attenuation that may occur from the point of release (i.e., leaching source term) to the point of potential exposure or compliance. The resulting indicator ratios for Method 1313 and Method 1314 test results (rounded to whole numbers) are shown in Table 4 for each analyte. The indicator ratios for arsenic, boron, chloride, chromium, fluoride (Method 1314), lithium (Method 1314), and molybdenum (Method 1314) for both leaching tests are greater than 100 as shown in red bold text with a thick red outline. Indicator ratios for aluminum (Method 1314), fluoride (Method 1313), lithium (Method 1313), molybdenum (Method 1313), nitrate (Method 1314), selenium, sulfate and thallium are between 10 and 100 as shown in orange bold text with a thin orange outline. 11 Table 4. Environmental Reference Concentrations, Maximum Leaching Test Eluate Concentrations, and Indicator Ratios for pH-dependent Leaching (Method 1313) and L/S-dependent Leaching (Method 1314). Ratios between 10 and 100 are shown in bold orange while ratios greater than 100 as shown in bold red. Analyte Symbol Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium Cobalt Copper Fluoride Iron Lead Lithium Manganese Molybdenum Nickel Nitrate Nitrite Phosphate Selenium Strontium Sulfate Thallium Tin Uranium Vanadium Zinc Notes: Al Sb As Ba Be B Cd Cl Cr Co Cu F Fe Pb Li Mn Mo Ni NO 3 NO 2 PO 4 Se Sr SO 4 Tl Sn U V Zn Environmental Reference Conc. (mg/L) 0.05 0.006 0.000045 2 0.004 0.007 0.005 1.6 0.000031 0.0047 0.62 0.62 0.3 0.015 0.031 0.32 0.078 0.3 10 1 760 0.05 9.3 250 0.00016 9.3 0.03 0.078 0.01 Maximum M1313* (mg/L) 0.35 0.053 0.051 2.1 0.00032 12 0.0020 780 0.015 0.013 0.0072 40 0.014 0.00012 1.1 0.61 0.99 0.081 41 0.009 0.012 0.51 46 2,700 0.0050 0.00035 0.059 0.43 0.0043 M1313 Indicator Ratio 7 9 1,100 1 1,700 490 470 3 65 36 2 13 4 10 5 11 31 2 6 - Maximum M1314 (mg/L) 0.66 0.019 0.043 0.061 0.00032 2.7 0.0071 12,000 0.28 0.0064 0.018 92 0.001 0.0058 3.9 0.001 13 0.027 560 0.009 0.012 3.6 15 21,000 0.0023 0.0021 0.0015 0.65 0.030 M1314 Indicator Ratio 13 3 950 390 1 7,600 9,000 1 150 120 160 56 73 2 84 14 8 3 * Maximum M1313 concentration between pH 6.5 (lower range of NDWRs) and pH 11.5 (1/2 unit above natural pH) “-“ indicates that the ratio is less than 1 (i.e., the maximum LEAF test result was less than the environmental reference concentration) 12 SUMMARY This document reports on the results of LEAF-based leaching assessment of AGREMAX sampled from the AES Puerto Rico L.P. coal-fired power plant in Guayama, Puerto Rico. AGREMAX is a partially solidified mixture of coal combustion fly ash and bottom ash. Subsamples of AGREMAX were collected and shipped to ARCADIS under chain of custody for testing. Homogenized samples of the solid material were subjected to pHdependent leaching conducted by ARCADIS using Method 1313 and percolation column leaching conducted by VU using Method 1314. Test eluates were analyzed for a range of nearly 40 target analytes including major, minor and trace constituents. The leaching results for a selection of analytes were presented to illustrate how pH-dependence and percolation are related. In order to put eluate concentrations into perspective, the eluate concentrations from these leaching methods were compared to the minimum of indicator values derived from RSLs for tapwater or NDWRs. Based on the above test results, the following observations were made regard the indicator ratios calculated as the maximum applicable eluate concentration from each leaching test 5 divided by the selected environmental reference concentration: pH-dependent Leaching Indicator Ratio greater than 100 for arsenic, boron, chloride and chromium, and Indicator Ratio between 10 and 100 for fluoride, lithium, molybdenum selenium, sulfate, and thallium, L/S-dependent Leaching (maximum concentrations at L/S < 2 L/kg) Indicator Ratio greater than 100 for arsenic, boron, chloride, chromium, fluoride, lithium, and molybdenum, and Indicator Ratio between 10 and 100 for aluminum, nitrate, selenium, sulfate, and thallium. Comparisons of the eluate concentrations to environmental reference concentrations are used to put the leachate concentrations from Method 1313 and Method 1314 into perspective with some regulatory and nonregulatory risk estimate values. The leaching test concentrations provided in this report do not consider dilution and attenuation factors that may be associated with different disposal or use scenarios. However, the LEAF method data can appropriately be used as a source term release estimate for groundwater fate and transport modeling that reflects the range of environmental conditions that AGREMAX is anticipated to encounter in the environment over time. For Method 1313, maximum eluate concentration was determined within the applicable pH range established by US EPA Region 2 to be 6.5 to 11.5. For Method 1314, maximum eluate concentration was the determined to be the maximum concentration in any test fraction between L/S 0.2 and L/S 10 mL/g-dry. 5 13 REFERENCES AES (2009) “TCLP – Agremax Sep 15.09,” AES Puerto Rico, LP, http://www.agremax.com, accessed 9/27/12. AES (2012) “Uses and Applications,” AES Puerto Rico, LP, http://www.agremax.com/#, accessed 9/27/12, (in Spanish, translated to English using the online version of Babylon 9, http://translation.babylon.com/spanish/to-english/). ASTM (2009) D6323-98 “Standard Guide for Laboratory Subsampling of Media Related to Waste Management Activities,” ASTM International, West Conshohocken, PA. CDC (2003) Method 5040, Diesel Particulate Matter (as Elemental Carbon), Centers for Disease Control, NIOSH Manual of Analytical Method (NMAM), 4th edition, 2003. Garrabrants, A.C., D.S. Kosson, H.A. van der Sloot, F. Sanchez and O. Hjelmar (2010) “Background Information for the Leaching Environmental Assessment Framework (LEAF) Test Methods,” EPA-600/R-10/170, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division, December 2010. Garrabrants, A.C., D.S. Kosson, L. Stefanski, R. DeLapp, P.F.A.B. Seignette, H.A. van der Sloot, P. Kariher and M. Baldwin (2012a) “Interlaboratory Validation of the Leaching Environmental Assessment Framework (LEAF) Method 1313 and Method 1316,” EPA-600/R-12/623, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division, September 2012. Garrabrants, A.C., D.S. Kosson, R. DeLapp, P. Kariher, P.F.A.B. Seignette, H.A. van der Sloot, L. Stefanski, and M. Baldwin (2012b) “Interlaboratory Validation of the Leaching Environmental Assessment Framework (LEAF) Method 1314 and Method 1315,” EPA-600/R-12/624, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division, September 2012. Grossman, L. (US EPA Region 2), “Reference Value for LEAF Report,” Email to S. Thorneloe (US EPA ORD), cc-ing N. Kraft and G. Meyer, 19 July 2012. Grossman, L. (US EPA Region 2), “Screening Values for Puerto Rico Leaching Tests,” Email to S. Thorneloe (US EPA ORD), cc-ing N. Kraft, 20 July 2012. Helms, G. (US EPA Office of Solid Waste), “Footnote on Comparison of MCLs and RSLs,” Edit submitted upon draft review to S. Thorneloe (US EPA ORD), 1 November 2012. Kosson, D.S., F. Sanchez, P. Kariher, L.H. Turner, R. DeLapp and P. Seignette (2009) “Characterization of Coal Combustion Residues from Electric Utilities – Leaching and Characterization Data,” EPA-600/R-09/151, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division, December 2009. Rivera, R. (AES Corporation), “AGREMAX Information”, Email to L. Grossman (US EPA Region 2), 16 June 2011. SAB (2003) Consultation Summary in EPA Science Advisory Board, Environmental Engineering Committee Consultation with U.S. Environmental Protection Agency, US EPA Science Advisory Board, Environmental Engineering Committee, Washington, DC (available as Attachment A of Sanchez et al., 2006). Sanchez, F., R. Keeney, D.S. Kosson and R. DeLapp (2006) “Characterization of Mercury-enriched Coal Combustion Residues from Electric Utilities using Enhanced Sorbents for Mercury Control,” EPA-600/R-06/008, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division, February 2006. Sanchez, F., D.S. Kosson, R. Keeney, R. DeLapp, L. Turner and P. Kariher (2008) “Characterization of Coal Combustion Residues from Electric Utilities using Wet Scrubbers for Multi-pollutant Control,” EPA-600/R-08/077, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division, July 2008. Thorneloe, S.A., D.S. Kosson, F. Sanchez, A.C. Garrabrants and G. Helms (2010) “Evaluating the fate of metals in air pollution control residues from coal-fired power plants,” Environmental Science and Technology, 44(19), 7351-7356. US EPA (1996) SW-846 Method 3052 “Microwave Assisted Acid Digestion of Siliceous and Organically Based Matrices,” Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/3052.pdf. US EPA (1998) SW-846 Method 7473 “Mercury in Solids and Solutions by Thermal Decomposition, Amalgamation, and Atomic Absorption Spectrophotometry,” Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/7473.pdf. US EPA (2003) “Technical Support Document for the Assessment of Detection and Quantitation Approaches,” U.S. Environmental Protection Agency, Office of Water, February 2003. 14 US EPA (2004) SW-846 Method 9060 “Total Organic Carbon,” Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/9060a.pdf. US EPA (2007a) SW-846 Method 3051 “Microwave Assisted Acid Digestion of Sediments, Sludges, Soils, and Oils,” Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/3051.pdf. US EPA (2007b) SW-846 Method 6010 “Inductively Coupled Plasma-Atomic Emission Spectroscopy,” Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/6010c.pdf. US EPA (2007c) SW-846 Method 6020 “Inductively Coupled Plasma-Mass Spectroscopy,” Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/6020a.pdf. US EPA (2007d) SW-846 Method 9056 “Determination of Inorganic Anions by Ion Chromatography," Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/9056a.pdf. US EPA (2012a) “2012 Edition of the Drinking Water Standard and Health Advisories”, Office of Water - United States Environmental Protection Agency, EPA 822-S-12-001, Washington DC, April 2012. US EPA (2012b) “Summary Table” Pacific Southwest, Region 9 Regional Screening Levels, updated May 2012, http://www.epa.gov/region9/superfund/prg/ (accessed 22 August 2012). 15 APPENDIX A. GRAPHICAL LEACHING TEST DATA 14 12 12 10 10 Eluate pH Eluate pH 14 8 6 8 6 4 4 2 2 0 0 -2 0 2 4 6 8 10 12 14 Acid/Base Addition (meq/g) AES-M1313-A AES-M1313-B 0.1 1 10 L/S (L/kg) Natural pH AES-M1314-A AES-M1314-B Figure A-1. Eluate pH measured for pH-dependence leaching (Method 1313) and percolation column leaching (Method 1314). 1 10000 1000 1000 100 Aluminum (mg/L) Aluminum (mg/L) 10000 RSL 10 1 0.1 NDWR range 0.01 ML 100 1 0.1 NDWR range 0.01 MDL 0.001 RSL 10 ML MDL 0.001 0.0001 0.0001 0 2 4 6 8 10 12 14 0.1 1 1 1 0.1 0.1 0.01 NDWR RSL 0.001 ML MDL 0.0001 0.00001 0.01 NDWR RSL 0.001 ML MDL 0.0001 0.00001 0 2 4 8 6 10 12 14 1 0.1 pH 1 1 0.1 0.1 NDWR 0.01 TCLP ( ML Al B Ba Ca Co Cu Fe Li Mg Mn Mo Ni P K Si Na Sr S Ti V Zn 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 Symbol Analytical Samples Results > ML Sb As Be Cd Cs Cr Pb Se Tl Sn U 18 18 18 18 18 18 18 18 18 18 18 18 18 4 18 18 18 6 18 10 2 12 18 18 18 18 8 6 8 18 18 12 18 12 12 18 18 18 18 18 2 18 6 RSDs Meeting DQI Goals 18 18 18 18 8 6 8 18 18 12 18 12 12 18 18 18 18 18 2 18 6 Overall Mean RSD (%) Completeness (%) 3.6 1.0 3.2 0.8 2.0 1.9 2.1 2.4 1.3 1.1 1.5 1.9 3.1 2.2 1.0 0.7 1.3 0.8 1.6 1.2 1.2 1.7% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% Mean RSD (%) Completeness (%) ICP-OES Analyte Antimony Arsenic Beryllium Cadmium Cesium Chromium Lead Selenium Thallium Tin Uranium RSDs Meeting DQI Goals 18 18 4 18 18 18 6 18 10 2 12 Overall 1.7 2.7 2.8 2.3 1.6 2.9 1.1 2.4 1.5 3.4 7.8 2.7% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 10 Carbon Analysis Analyte Carbon, Inorganic Carbon, Organic Symbol Analytical Samples Results > ML DIC DOC 18 18 12 18 Symbol Analytical Samples Results > ML Br Cl F NO3 NO2 PO4 SO4 18 18 18 18 18 18 18 0 18 18 18 0 0 18 RSDs Meeting DQI Goals 12 18 Overall Mean RSD (%) 3.8 0.9 2.3% Completeness (%) 100% 100% 100% IC Analyte Bromide Chloride Fluoride Nitrate Nitrite Phosphate Sulfate RSDs Meeting DQI Goals 0 18 18 18 0 0 18 Overall Mean RSD (%) Completeness (%) RSD and Completeness are not available as IC analysis is based on a single measurement of an analytical sample. NA NA 11 Analytical QA/QC Summary – Method 1314 ICP-OES Analyte Aluminum Boron Barium Calcium Cobalt Copper Iron Lithium Magnesium Manganese Molybdenum Nickel Phosphorus Potassium Silicon Sodium Strontium Sulfur Titanium Vanadium Zinc Symbol Analytical Samples Results > ML Al B Ba Ca Co Cu Fe Li Mg Mn Mo Ni P K Si Na Sr S Ti V Zn 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 Symbol Analytical Samples Results > ML Sb As Be Cd Cs Cr Pb Se Tl Sn U 18 18 18 18 18 18 18 18 18 18 18 8 18 0 8 18 13 4 18 2 2 0 18 18 18 18 2 2 0 18 18 0 18 6 6 18 18 18 18 18 0 18 16 RSDs Meeting DQI Goals 18 18 18 18 2 2 0 18 18 0 18 6 6 18 18 18 18 18 0 18 16 Overall Mean RSD (%) 1.7 1.1 1.0 1.0 1.7 6.0 NA 2.0 3.9 NA 1.8 4.9 2.7 1.1 1.1 0.9 1.4 1.0 NA 1.3 4.4 2.2% Completeness (%) 100% 100% 100% 100% 100% 100% NA 100% 100% NA 100% 100% 100% 100% 100% 100% 100% 100% NA 100% 100% 100% ICP-OES Analyte Antimony Arsenic Beryllium Cadmium Cesium Chromium Lead Selenium Thallium Tin Uranium RSDs Meeting DQI Goals 8 18 0 8 18 13 4 18 2 2 0 Overall Mean RSD (%) Completeness (%) 2.1 2.6 NA 2.9 1.8 2.1 4.4 2.1 4.5 2.4 NA 2.8% 100% 100% NA 100% 100% 100% 100% 100% 100% 100% NA 100% 12 Carbon Analysis Analyte Carbon, Inorganic Carbon, Organic Symbol Analytical Samples Results > ML DIC DOC 18 18 18 18 Symbol Analytical Samples Results > ML Br Cl F NO3 NO2 PO4 SO4 18 18 18 18 18 18 18 4 18 18 18 0 0 18 RSDs Meeting DQI Goals 18 18 Overall Mean RSD (%) 2.6 0.9 1.7% Completeness (%) 100% 100% 100% IC Analyte Bromide Chloride Fluoride Nitrate Nitrite Phosphate Sulfate RSDs Meeting DQI Goals 4 18 18 18 0 0 18 Overall Mean RSD (%) Completeness (%) RSD and Completeness are not available as IC analysis is based on a single measurement of an analytical sample. NA NA 13 Matrix Spike Recovery Summary – Method 1313 ICP-OES Analyte Aluminum Aluminum Boron Boron Barium Barium Calcium Calcium Cobalt Cobalt Copper Copper Iron Iron Lithium Lithium Magnesium Magnesium Manganese Manganese Molybdenum Molybdenum Nickel Nickel Phosphorus Phosphorus Potassium Potassium Silicon Silicon Sodium Sodium Strontium Strontium Sulfur Sulfur Titanium Titanium Vanadium Vanadium Zinc Zinc Symbol Al Al B B Ba Ba Ca Ca Co Co Cu Cu Fe Fe Li Li Mg Mg Mn Mn Mo Mo Ni Ni P P K K Si Si Na Na Sr Sr S S Ti Ti V V Zn Zn Sample Conc (µg/L) 348.29 336.59 1,150.93 1,135.35 68.81 69.01 566,606.00 573,389.00 0.90 0.90 1.85 1.85 1.00 1.00 278.99 284.46 9.18 9.98 177.15 214.98 646.46 643.36 0.90 0.90 1.85 1.85 276,032.00 282,925.00 9,420.70 9,392.35 491,942.00 517,956.00 7,809.93 8,742.79 973,267.00 988,445.00 1.00 1.00 158.34 155.34 0.50 0.50 Spike Conc Calculated (g/L) 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 5,000 5,000 1,000 1,000 1,000 1,000 1,000 1,000 Spike Conc Measured (g/L) 1,387.3 1,353.2 2,225.8 2,171.6 1,008.3 997.6 567,514.0 574,264.0 993.9 970.6 1,030.2 1,025.1 1,061.1 1,042.9 1,256.2 1,256.4 1,036.1 1,026.6 1,170.3 1,161.3 1,650.1 1,611.0 1,043.1 1,034.4 1,056.1 1,023.9 276,966.0 283,826.0 10,372.1 10,322.1 492,837.0 518,837.0 8,763.5 9,663.5 978,043.0 993,043.0 1,060.5 1,029.3 1,163.8 1,137.6 1,149.5 1,123.6 Recovery (g/L) 1,039.0 1,016.6 1,074.9 1,036.2 939.4 928.6 908.0 875.0 993.0 969.7 1,028.3 1,023.2 1,060.1 1,041.9 977.2 971.9 1,026.9 1,016.6 993.2 946.3 1,003.7 967.7 1,042.2 1,033.5 1,054.3 1,022.1 934.0 901.0 951.4 929.8 895.0 881.0 953.5 920.7 4,776.0 4,598.0 1,059.5 1,028.3 1,005.4 982.2 1,149.0 1,123.1 Mean Recovery (%) 104% 102% 107% 104% 94% 93% 91% 88% 99% 97% 103% 102% 106% 104% 98% 97% 103% 102% 99% 95% 100% 97% 104% 103% 105% 102% 93% 90% 95% 93% 90% 88% 95% 92% 96% 92% 106% 103% 101% 98% 115% 112% 99% 14 ICP-MS Analyte Antimony Antimony Beryllium Beryllium Cadmium Cadmium Cesium Cesium Chromium Chromium Lead Lead Selenium Selenium Thallium Thallium Tin Tin Uranium Uranium Symbol Sb Sb Be Be Cd Cd Cs Cs Cr Cr Pb Pb Se Se Tl Tl Sn Sn U U Sample Conc (µg/L) 11.30 12.10 0.32 0.32 0.71 0.77 20.10 21.20 12.70 14.60 0.11 0.11 199.00 175.00 0.25 0.25 0.35 0.35 0.15 0.15 Spike Conc Calculated (g/L) 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 Spike Conc Measured (g/L) 517.58 491.05 504.71 484.35 516.38 508.41 499.22 495.03 518.00 512.00 488.03 476.39 705.96 665.41 497.71 474.38 492.10 483.60 502.81 499.38 Recovery (g/L) 506.3 479.0 504.4 484.0 515.7 507.6 479.1 473.8 505.3 497.4 487.9 476.3 507.0 490.4 497.5 474.1 491.8 483.3 502.7 499.2 Mean Recovery (%) 101% 96% 101% 97% 103% 102% 96% 95% 101% 99% 98% 95% 101% 98% 99% 95% 98% 97% 101% 100% 99% TC Analyte Symbol Carbon, inorganic Carbon, inorganic Carbon, organic Carbon, organic DIC DIC DOC DOC Sample Conc (µg/L) 6,413.00 6,405.00 4,873.00 5,357.00 Spike Conc Calculated (g/L) 500 500 500 500 Spike Conc Measured (g/L) 6,877.00 6,865.00 5,341.00 5,814.00 Recovery (g/L) 464.0 460.0 468.0 457.0 Mean Recovery (%) 93% 92% 94% 91% 92% 15 Matrix Spike Recovery Summary – Method 1314 ICP-OES Analyte Aluminum Aluminum Boron Boron Barium Barium Calcium Calcium Cobalt Cobalt Copper Copper Iron Iron Lithium Lithium Magnesium Magnesium Manganese Manganese Molybdenum Molybdenum Nickel Nickel Phosphorus Phosphorus Potassium Potassium Silicon Silicon Sodium Sodium Strontium Strontium Sulfur Sulfur Titanium Titanium Vanadium Vanadium Zinc Zinc Symbol Sample Conc (µg/L) Al Al B B Ba Ba Ca Ca Co Co Cu Cu Fe Fe Li Li Mg Mg Mn Mn Mo Mo Ni Ni P P K K Si Si Na Na Sr Sr S S Ti Ti V V Zn Zn 435.79 520.39 2,142.53 1,964.58 33.56 31.73 427,401.00 416,730.00 2.36 1.92 4.46 4.10 1.00 1.00 2,145.97 2,106.65 1.00 1.00 124.48 117.86 1,447.32 1,590.47 6.82 6.87 37.56 32.54 1,034,420.00 967,993.00 18,312.50 18,063.10 1,028,840.00 967,339.00 8,486.42 8,278.21 2,916,400.00 2,842,140.00 1.00 1.00 458.46 437.57 9.19 8.76 Spike Conc Calculated (g/L) 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,000 5,000 5,000 1,000 1,000 5,000 5,000 1,000 1,000 5,000 5,000 1,000 1,000 1,000 1,000 1,000 1,000 Spike Conc Measured (g/L) 1,461.8 1,546.5 3,066.0 2,848.3 1,115.6 1,075.0 428,358.0 417,658.0 1,058.3 995.4 1,105.1 1,037.9 1,073.0 1,006.3 3,089.3 3,002.7 1,067.6 1,009.3 1,151.8 1,061.1 2,469.7 2,543.7 1,039.5 986.4 1,098.4 1,083.5 1,039,150.0 972,570.0 19,271.8 18,988.6 1,033,350.0 971,630.0 9,592.1 9,333.4 2,920,820.0 2,846,400.0 1,132.3 1,064.7 1,516.3 1,448.4 1,093.8 1,106.7 Recovery (g/L) 1,026.0 1,026.1 923.5 883.7 1,082.1 1,043.2 957.0 928.0 1,055.9 993.5 1,100.6 1,033.8 1,072.0 1,005.3 943.3 896.0 1,066.6 1,008.3 1,027.3 943.2 1,022.4 953.2 1,032.6 979.5 1,060.9 1,051.0 4,730.0 4,577.0 959.3 925.5 4,510.0 4,291.0 1,105.7 1,055.2 4,420.0 4,260.0 1,131.3 1,063.7 1,057.8 1,010.9 1,084.6 1,097.9 Mean Recovery (%) 103% 103% 92% 88% 108% 104% 96% 93% 106% 99% 110% 103% 107% 101% 94% 90% 107% 101% 103% 94% 102% 95% 103% 98% 106% 105% 95% 92% 96% 93% 90% 86% 111% 106% 88% 85% 113% 106% 106% 101% 108% 110% 100% 16 ICP-MS Analyte Antimony Antimony Beryllium Beryllium Cadmium Cadmium Cesium Cesium Chromium Chromium Lead Lead Selenium Selenium Thallium Thallium Tin Tin Uranium Uranium Symbol Sb Sb Be Be Cd Cd Cs Cs Cr Cr Pb Pb Se Se Tl Tl Sn Sn U U Sample Conc (µg/L) 11.90 12.40 0.32 0.32 2.58 2.92 71.30 69.40 36.80 30.90 0.11 0.11 226.00 182.00 0.59 0.56 1.51 1.46 0.15 0.15 Spike Conc Calculated (g/L) 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 Spike Conc Measured (g/L) 512.15 504.71 506.09 499.38 509.32 503.02 543.82 528.78 517.18 504.22 501.07 489.26 694.83 661.07 491.23 485.95 512.85 500.37 496.28 488.44 Recovery (g/L) 500.3 492.3 505.8 499.1 506.7 500.1 472.5 459.4 480.4 473.3 501.0 489.1 468.8 479.1 490.6 485.4 511.3 498.9 496.1 488.3 Mean Recovery (%) 100% 98% 101% 100% 101% 100% 95% 92% 96% 95% 100% 98% 94% 96% 98% 97% 102% 100% 99% 98% 99% TC Analyte Symbol Carbon, inorganic Carbon, inorganic Carbon, organic Carbon, organic DIC DIC DOC DOC Sample Conc (µg/L) 3,465.00 3,848.00 11,840.00 10,678.00 Spike Conc Calculated (g/L) 500 500 500 500 Spike Conc Measured (g/L) 3,944.00 4,308.00 12,310.00 11,132.00 Recovery (g/L) 479.0 460.0 470.0 454.0 Mean Recovery (%) 96% 92% 94% 91% 92% 17 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Al Al Al Al Al Al Al Al Al 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Sample Conc. Qualifier (µg/L) 89.63 108.58 348.29 64.28 25.47 15.65 155.35 234,286.00 1,013,820.00 Al Al Al Al Al Al Al Al Al 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 85.65 113.33 336.59 59.47 28.84 16.25 8.61 232,854.00 1,036,160.00 Al Al Al 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.50 3.08 1.20 Analyte Sample ID Dilution Factor U1/2 E E Instrument Conc. (µg/L) 89.63 108.58 348.29 64.28 25.47 15.65 155.35 234,286.00 1,013,820.00 RSD (%) 1.9 4.5 2.3 4.2 3.0 5.4 7.8 0.7 1.3 85.65 113.33 336.59 59.47 28.84 16.25 8.61 232,854.00 1,036,160.00 0.50 3.08 1.20 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 5.0 2.8 1.8 7.3 3.7 4.3 8.2 0.4 0.4 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 23.3 7.1 2.6 1 1 1 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,387.30 1,353.17 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 104% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 102% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 3.6 % 100.0 % B-18 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 7.62 10.60 11.30 38.80 46.60 50.30 55.10 15.10 77.20 Sb Sb Sb Sb Sb Sb Sb Sb Sb 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Sb Sb Sb Sb Sb Sb Sb Sb Sb 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 6.28 11.50 12.10 38.70 45.80 53.10 63.90 14.30 85.90 Sb Sb Sb 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.04 0.04 0.04 U1/2 U1/2 U1/2 Instrument Conc. (µg/L) 7.62 10.60 11.30 38.80 46.60 50.30 55.10 15.10 77.20 RSD (%) 1.4 2.4 1.3 0.7 0.5 0.3 1.8 2.3 0.1 MDL (µg/L) 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 ML (µg/L) 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 6.28 11.50 12.10 38.70 45.80 53.10 63.90 14.30 85.90 2.0 1.7 7.2 0.3 1.1 1.1 1.8 1.2 2.9 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.04 0.04 0.04 33.8 8.1 11.8 0.08 0.08 0.08 0.2 0.2 0.2 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 500 500 Spike Conc. (µg/L) 517.58 491.05 Spike Recovery (%) 101% 96% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 1.7 % 100.0 % B-19 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 10.60 10.40 22.50 48.50 49.20 42.80 52.70 70.20 397.00 As As As As As As As As As 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 As As As As As As As As As 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 9.87 9.52 18.10 51.20 46.80 42.80 56.50 72.60 403.00 As As As 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.32 0.32 0.32 U1/2 U1/2 U1/2 Spike Sol'n Conc. Volume (µg/L) (µL) Instrument Conc. (µg/L) 10.60 10.40 22.50 48.50 49.20 42.80 52.70 70.20 397.00 RSD (%) 3.9 6.9 0.1 1.4 2.9 2.5 2.5 1.2 2.2 MDL (µg/L) 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 9.87 9.52 18.10 51.20 46.80 42.80 56.50 72.60 403.00 1.8 0.9 1.7 0.2 2.9 1.3 9.4 4.2 2.6 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 2 2 2 2 2 2 2 2 2 0.32 0.32 0.32 4.1 6.1 5.7 0.64 0.64 0.64 2 2 2 Mean RSD Completeness ML (µg/L) 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 511.33 488.22 Spike Recovery (%) 98% 94% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 2.7 % 100.0 % B-20 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 207.54 127.59 1,150.93 4,844.94 8,547.64 11,955.10 13,340.00 8,109.63 9,066.64 B B B B B B B B B 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 B B B B B B B B B 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 229.60 153.88 1,135.35 5,014.33 7,989.17 11,991.60 13,859.90 8,331.32 9,020.34 B B B 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.50 2.37 0.50 U1/2 E U1/2 Instrument Conc. (µg/L) 207.54 127.59 1,150.93 4,844.94 8,547.64 11,955.10 13,340.00 8,109.63 9,066.64 RSD (%) 1.1 2.1 0.9 3.7 1.9 0.6 0.8 0.2 0.4 229.60 153.88 1,135.35 5,014.33 7,989.17 11,991.60 13,859.90 8,331.32 9,020.34 0.50 2.37 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 0.5 1.2 0.6 0.4 0.9 1.2 0.4 0.1 1.3 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 22.1 7.7 0.5 1 1 1 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 2,225.79 2,171.57 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 107% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 104% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.0 % 100.0 % B-21 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 46.76 49.12 68.81 923.74 1,565.71 2,055.63 2,934.40 1,642.70 1,383.87 Ba Ba Ba Ba Ba Ba Ba Ba Ba 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Ba Ba Ba Ba Ba Ba Ba Ba Ba 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 50.75 51.58 69.01 906.91 1,635.56 2,051.60 3,385.76 1,739.18 1,503.13 Ba Ba Ba 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.50 0.50 0.50 U1/2 U1/2 U1/2 Instrument Conc. (µg/L) 46.76 49.12 68.81 923.74 1,565.71 2,055.63 2,934.40 1,642.70 1,383.87 RSD (%) 1.9 4.5 2.3 4.2 2.7 5.4 7.8 0.7 1.3 50.75 51.58 69.01 906.91 1,635.56 2,051.60 3,385.76 1,739.18 1,503.13 0.50 0.50 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 5.0 2.8 1.8 7.3 3.7 4.3 1.2 0.4 0.4 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 13.3 7.1 2.6 1 1 1 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,008.25 997.61 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 94% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 93% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 3.2 % 100.0 % B-22 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 36.40 91.40 Instrument Conc. (µg/L) 0.32 0.32 0.32 0.32 0.32 0.32 0.32 36.40 91.40 RSD (%) 29.3 13.3 9.2 12.7 5.1 15.4 10.8 2.2 2.1 MDL (µg/L) 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) Be Be Be Be Be Be Be Be Be 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Be Be Be Be Be Be Be Be Be 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 0.32 0.32 0.32 0.32 0.32 0.32 0.32 31.20 97.60 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 0.32 0.32 0.32 0.32 0.32 0.32 0.32 31.20 97.60 22.7 1.9 7.1 18.2 10.9 5.2 4.6 2.5 4.2 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 2 2 2 2 2 2 2 2 2 Be Be Be 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.32 0.32 0.32 U1/2 U1/2 U1/2 0.32 0.32 0.32 32.8 25.4 20.0 0.64 0.64 0.64 2 2 2 Mean RSD Completeness 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 504.71 484.35 Spike Recovery (%) 101% 97% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 2.8 % 100.0 % B-23 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.81 0.76 0.71 1.30 1.41 1.57 32.60 62.10 80.00 Cd Cd Cd Cd Cd Cd Cd Cd Cd 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Cd Cd Cd Cd Cd Cd Cd Cd Cd 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 0.87 0.79 0.77 1.56 1.68 2.02 25.70 55.80 78.90 Cd Cd Cd 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.09 0.09 0.09 U1/2 U1/2 U1/2 Instrument Conc. (µg/L) 0.81 0.76 0.71 1.30 1.41 1.57 32.60 62.10 80.00 RSD (%) 2.9 2.1 2.4 1.5 4.0 2.6 1.0 0.4 0.6 MDL (µg/L) 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 ML (µg/L) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.87 0.79 0.77 1.56 1.68 2.02 25.70 55.80 78.90 3.2 2.5 3.2 1.4 6.9 4.1 0.5 0.3 1.5 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.09 0.09 0.09 17.8 2.8 5.5 0.17 0.17 0.17 0.5 0.5 0.5 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 500 500 Spike Conc. (µg/L) 516.38 508.41 Spike Recovery (%) 103% 102% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 2.3 % 100.0 % B-24 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Ca Ca Ca Ca Ca Ca Ca Ca Ca 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 10 10 10 10 10 10 Sample Conc. Qualifier (µg/L) 501,567.00 451,260.00 566,606.00 4,459,290.00 6,156,910.00 7,767,200.00 10,230,500.00 5,544,170.00 5,289,070.00 Ca Ca Ca Ca Ca Ca Ca Ca Ca 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 10 10 10 10 10 10 498,235.00 465,006.00 573,389.00 4,471,920.00 6,126,130.00 8,081,550.00 10,350,300.00 6,060,780.00 5,192,720.00 Ca Ca Ca 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 8.35 8.97 1.30 Analyte Sample ID Dilution Factor E E U1/2 Instrument Conc. (µg/L) 501,567.00 451,260.00 566,606.00 445,929.00 615,691.00 776,720.00 1,023,050.00 554,417.00 528,907.00 RSD (%) 0.9 0.3 0.2 3.2 0.9 0.8 0.7 0.3 0.4 MDL (µg/L) 2.6 2.6 2.6 2.6 2.6 2.6 2.6 2.6 2.6 ML (µg/L) 10 10 10 10 10 10 10 10 10 498,235.00 465,006.00 573,389.00 447,192.00 612,613.00 808,155.00 1,035,030.00 606,078.00 519,272.00 0.8 0.8 0.3 0.8 0.8 1.2 0.7 1.0 0.5 2.6 2.6 2.6 2.6 2.6 2.6 2.6 2.6 2.6 10 10 10 10 10 10 10 10 10 8.35 8.97 1.30 3.6 1.4 4.8 2.6 2.6 2.6 10 10 10 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 Spike Conc. (µg/L) 1,000 567,514.00 1,000 574,264.00 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 91% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 5/3/2012 10:10 5/3/2012 10:12 5/3/2012 10:14 5/3/2012 10:15 5/3/2012 10:17 5/3/2012 10:19 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 88% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 5/3/2012 10:22 5/3/2012 10:24 5/3/2012 10:25 5/3/2012 10:27 5/3/2012 10:28 5/3/2012 10:30 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 0.8 % 100.0 % B-25 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 158.00 109.00 20.10 30.40 37.90 50.10 75.10 140.00 351.00 Cs Cs Cs Cs Cs Cs Cs Cs Cs 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Cs Cs Cs Cs Cs Cs Cs Cs Cs 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 159.00 103.00 21.20 33.30 43.00 53.60 78.90 166.00 352.00 Cs Cs Cs 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.24 0.24 0.24 U1/2 U1/2 U1/2 Spike Sol'n Conc. Volume (µg/L) (µL) Instrument Conc. (µg/L) 158.00 109.00 20.10 30.40 37.90 50.10 75.10 140.00 351.00 RSD (%) 1.0 0.9 0.5 1.1 0.4 2.0 1.0 0.8 1.0 MDL (µg/L) 0.49 0.49 0.49 0.49 0.49 0.49 0.49 0.49 0.49 159.00 103.00 21.20 33.30 43.00 53.60 78.90 166.00 352.00 0.3 1.3 2.4 2.0 3.8 2.2 1.9 1.4 4.0 0.49 0.49 0.49 0.49 0.49 0.49 0.49 0.49 0.49 2 2 2 2 2 2 2 2 2 0.24 0.24 0.24 16.9 8.1 10.9 0.49 0.49 0.49 2 2 2 Mean RSD Completeness ML (µg/L) 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 499.22 495.03 Spike Recovery (%) 96% 95% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 1.6 % 100.0 % B-26 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 12.50 12.40 12.70 8.86 2.60 1.23 E 4.33 48.55 677.00 Cr Cr Cr Cr Cr Cr Cr Cr Cr 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Cr Cr Cr Cr Cr Cr Cr Cr Cr 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 13.10 13.80 14.60 8.23 3.41 2.01 4.45 41.00 708.00 Cr Cr Cr 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.25 0.25 0.25 U1/2 U1/2 U1/2 Spike Sol'n Conc. Volume (µg/L) (µL) Instrument Conc. (µg/L) 12.50 12.40 12.70 8.86 2.60 1.23 4.33 48.55 677.00 RSD (%) 1.0 1.1 1.6 3.8 1.8 9.9 2.6 1.8 0.6 MDL (µg/L) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 13.10 13.80 14.60 8.23 3.41 2.01 4.45 41.00 708.00 1.7 0.6 3.1 1.1 5.2 9.5 1.2 2.7 2.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2 2 2 2 2 2 2 2 2 0.25 0.25 0.25 10.2 1.9 5.5 0.5 0.5 0.5 2 2 2 Mean RSD Completeness ML (µg/L) 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 518.00 512.00 Spike Recovery (%) 101% 99% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 2.9 % 100.0 % B-27 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.90 U1/2 0.90 U1/2 0.90 U1/2 0.90 U1/2 0.90 U1/2 12.50 227.99 173.59 222.99 Instrument Conc. (µg/L) 0.90 0.90 0.90 0.90 0.90 12.50 227.99 173.59 222.99 RSD (%) 10.0 17.4 8.0 5.8 11.7 8.1 0.6 1.0 1.5 MDL (µg/L) 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) Co Co Co Co Co Co Co Co Co 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Co Co Co Co Co Co Co Co Co 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 0.90 0.90 0.90 0.90 0.90 12.29 203.39 169.38 232.89 U1/2 U1/2 U1/2 U1/2 U1/2 0.90 0.90 0.90 0.90 0.90 12.29 203.39 169.38 232.89 9.8 10.3 7.9 2.9 5.0 2.4 0.5 0.7 0.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 5 5 5 5 5 5 5 5 5 Co Co Co 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.90 0.90 0.90 U1/2 U1/2 U1/2 0.90 0.90 0.90 19.5 13.5 20.7 1.8 1.8 1.8 5 5 5 Mean RSD Completeness 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 993.87 970.63 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 99% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 97% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 2.0 % 100.0 % B-28 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 5.53 E 5.14 E 1.85 U1/2 6.36 E 6.81 E 5.58 E 36.21 257.16 655.95 Instrument Conc. (µg/L) 5.53 5.14 1.85 6.36 6.81 5.58 36.21 257.16 655.95 RSD (%) 5.9 5.4 15.7 1.3 9.1 3.9 1.7 0.8 3.9 MDL (µg/L) 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 ML (µg/L) 10 10 10 10 10 10 10 10 10 Cu Cu Cu Cu Cu Cu Cu Cu Cu 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Cu Cu Cu Cu Cu Cu Cu Cu Cu 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 5.39 4.02 1.85 6.64 7.20 6.97 47.85 196.61 693.03 E E U1/2 E E E 5.39 4.02 1.85 6.64 7.20 6.97 47.85 196.61 693.03 3.6 11.8 4.9 2.2 3.6 2.6 3.0 1.5 0.8 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 10 10 10 10 10 10 10 10 10 Cu Cu Cu 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 1.85 1.85 1.85 U1/2 U1/2 U1/2 1.85 1.85 1.85 10.9 13.9 11.8 3.7 3.7 3.7 10 10 10 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,030.17 1,025.07 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 103% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 102% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.9 % 100.0 % B-29 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 13.85 155,132.00 109,152.00 184,366.00 Instrument Conc. (µg/L) 1.00 1.00 1.00 1.00 1.00 13.85 155,132.00 109,152.00 184,366.00 RSD (%) 4.7 8.8 14.5 4.8 4.7 6.9 0.9 1.4 2.4 Fe Fe Fe Fe Fe Fe Fe Fe Fe 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Fe Fe Fe Fe Fe Fe Fe Fe Fe 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 1.00 1.00 1.00 1.00 1.00 14.11 136,155.00 100,962.00 188,253.00 U1/2 U1/2 U1/2 U1/2 U1/2 1.00 1.00 1.00 1.00 1.00 14.11 136,155.00 100,962.00 188,253.00 Fe Fe Fe 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 1.00 2.84 2.69 U1/2 E E 1.00 2.84 2.69 Mean RSD Completeness MDL (µg/L) 2 2 2 2 2 2 2 2 2 ML (µg/L) 10 10 10 10 10 10 10 10 10 3.9 0.7 11.5 14.3 8.0 2.0 0.4 0.5 2.0 2 2 2 2 2 2 2 2 2 10 10 10 10 10 10 10 10 10 4.7 1.7 2.7 2 2 2 10 10 10 Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,061.12 1,042.88 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 106% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 104% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 2.1 % 100.0 % B-30 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 4.19 0.38 E 0.11 U1/2 0.11 U1/2 0.11 U1/2 0.11 U1/2 0.30 E 20.50 139.00 Pb Pb Pb Pb Pb Pb Pb Pb Pb 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Pb Pb Pb Pb Pb Pb Pb Pb Pb 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 3.48 0.39 0.11 0.11 0.11 0.11 0.27 18.50 128.00 Pb Pb Pb 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.11 0.24 0.28 E U1/2 U1/2 U1/2 U1/2 E U1/2 E E Spike Sol'n Conc. Volume (µg/L) (µL) Instrument Conc. (µg/L) 4.19 0.38 0.11 0.11 0.11 0.11 0.30 20.50 139.00 RSD (%) 0.1 6.4 9.0 6.8 2.7 4.8 7.2 0.8 0.3 MDL (µg/L) 0.23 0.23 0.23 0.23 0.23 0.23 0.23 0.23 0.23 3.48 0.39 0.11 0.11 0.11 0.11 0.27 18.50 128.00 3.1 3.0 4.2 2.3 1.1 3.9 3.4 1.2 1.4 0.23 0.23 0.23 0.23 0.23 0.23 0.23 0.23 0.23 1 1 1 1 1 1 1 1 1 0.11 0.24 0.28 11.9 1.2 4.8 0.23 0.23 0.23 1 1 1 Mean RSD Completeness ML (µg/L) 1 1 1 1 1 1 1 1 1 10,000 10,000 500 500 Spike Conc. (µg/L) 488.03 476.39 Spike Recovery (%) 98% 95% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 1.1 % 100.0 % B-31 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 197.51 271.52 278.99 579.09 815.98 1,078.71 1,430.03 970.82 1,131.87 Li Li Li Li Li Li Li Li Li 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Li Li Li Li Li Li Li Li Li 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 220.78 279.68 284.46 596.18 823.63 1,101.83 1,386.82 997.46 1,135.73 Li Li Li 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.95 0.95 0.95 U1/2 U1/2 U1/2 Instrument Conc. (µg/L) 197.51 271.52 278.99 579.09 815.98 1,078.71 1,430.03 970.82 1,131.87 RSD (%) 1.1 1.5 1.5 4.2 5.0 1.8 1.9 4.5 1.1 MDL (µg/L) 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 ML (µg/L) 10 10 10 10 10 10 10 10 10 220.78 279.68 284.46 596.18 823.63 1,101.83 1,386.82 997.46 1,135.73 1.0 0.3 0.9 4.3 2.0 1.7 7.8 2.0 0.6 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 10 10 10 10 10 10 10 10 10 0.95 0.95 0.95 0.7 1.1 2.6 1.9 1.9 1.9 10 10 10 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,256.21 1,256.40 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 98% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 97% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 2.4 % 100.0 % B-32 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 1.00 U1/2 1.00 U1/2 9.18 E 12.79 87.19 541.97 3,603.81 2,369.14 2,986.67 Instrument Conc. (µg/L) 1.00 1.00 9.18 12.79 87.19 541.97 3,603.81 2,369.14 2,986.67 RSD (%) 4.4 7.5 3.4 3.8 1.4 0.4 0.9 0.4 2.2 Mn Mn Mn Mn Mn Mn Mn Mn Mn 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Mn Mn Mn Mn Mn Mn Mn Mn Mn 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 1.00 1.00 9.98 10.23 75.39 606.75 3,443.25 2,386.40 2,845.94 U1/2 U1/2 E 1.00 1.00 9.98 10.23 75.39 606.75 3,443.25 2,386.40 2,845.94 Mn Mn Mn 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 1.00 1.00 1.00 U1/2 U1/2 U1/2 1.00 1.00 1.00 Mean RSD Completeness MDL (µg/L) 2 2 2 2 2 2 2 2 2 ML (µg/L) 10 10 10 10 10 10 10 10 10 13.6 5.7 1.9 0.6 1.5 1.2 0.3 0.3 0.8 2 2 2 2 2 2 2 2 2 10 10 10 10 10 10 10 10 10 1.4 5.7 2.5 2 2 2 10 10 10 Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,036.11 1,026.58 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 103% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 102% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.1 % 100.0 % B-33 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 19.70 36.05 177.15 43,441.60 76,971.90 123,777.00 191,801.00 136,549.00 144,073.00 Mg Mg Mg Mg Mg Mg Mg Mg Mg 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Mg Mg Mg Mg Mg Mg Mg Mg Mg 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 26.58 45.85 214.98 43,304.50 72,402.50 118,932.00 199,580.00 125,856.00 144,817.00 Mg Mg Mg 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 1.21 1.62 0.50 E E U1/2 Instrument Conc. (µg/L) 19.70 36.05 177.15 43,441.60 76,971.90 123,777.00 191,801.00 136,549.00 144,073.00 RSD (%) 2.2 2.0 1.3 2.6 1.7 0.9 0.5 0.2 2.5 26.58 45.85 214.98 43,304.50 72,402.50 118,932.00 199,580.00 125,856.00 144,817.00 1.21 1.62 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 2.0 1.1 1.0 0.8 1.4 1.4 0.9 0.4 1.1 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 1.5 1.2 11.4 1 1 1 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,170.33 1,161.29 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 99% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 95% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.3 % 100.0 % B-34 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 656.92 629.82 646.46 922.98 977.68 763.01 233.88 28.47 18.47 Mo Mo Mo Mo Mo Mo Mo Mo Mo 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Mo Mo Mo Mo Mo Mo Mo Mo Mo 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 660.56 640.48 643.36 949.26 990.84 768.46 440.41 31.01 21.86 Mo Mo Mo 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.60 0.60 0.60 U1/2 U1/2 U1/2 Spike Sol'n Conc. Volume (µg/L) (µL) Instrument Conc. (µg/L) 656.92 629.82 646.46 922.98 977.68 763.01 233.88 28.47 18.47 RSD (%) 1.0 0.9 0.6 3.3 0.7 0.6 1.2 2.7 5.7 MDL (µg/L) 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 660.56 640.48 643.36 949.26 990.84 768.46 440.41 31.01 21.86 0.8 0.8 0.8 0.6 0.8 1.0 0.6 1.2 3.8 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 5 5 5 5 5 5 5 5 5 0.60 0.60 0.60 6.9 12.9 8.9 1.2 1.2 1.2 5 5 5 Mean RSD Completeness ML (µg/L) 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,650.13 1,611.04 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 100% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 97% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.5 % 100.0 % B-35 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.90 U1/2 0.90 U1/2 0.90 U1/2 6.83 12.83 77.21 521.98 392.50 501.68 Instrument Conc. (µg/L) 0.90 0.90 0.90 6.83 12.83 77.21 521.98 392.50 501.68 RSD (%) 24.4 6.8 13.9 3.7 1.3 3.4 1.2 0.7 1.1 MDL (µg/L) 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) Ni Ni Ni Ni Ni Ni Ni Ni Ni 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Ni Ni Ni Ni Ni Ni Ni Ni Ni 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 0.90 0.90 0.90 6.43 11.79 80.83 471.72 386.31 502.91 U1/2 U1/2 U1/2 0.90 0.90 0.90 6.43 11.79 80.83 471.72 386.31 502.91 19.9 15.7 12.2 3.2 1.6 5.7 0.4 0.4 0.5 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 5 5 5 5 5 5 5 5 5 Ni Ni Ni 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.90 0.90 0.90 U1/2 U1/2 U1/2 0.90 0.90 0.90 12.3 4.2 17.6 1.8 1.8 1.8 5 5 5 Mean RSD Completeness 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,043.08 1,034.38 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 104% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 103% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.9 % 100.0 % B-36 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 1.85 U1/2 1.85 U1/2 1.85 U1/2 22.63 23.79 21.64 37.66 81.54 16,108.20 Instrument Conc. (µg/L) 1.85 1.85 1.85 22.63 23.79 21.64 37.66 81.54 16,108.20 RSD (%) 28.4 12.6 37.1 2.9 1.6 3.8 1.4 8.4 1.7 MDL (µg/L) 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 ML (µg/L) 10 10 10 10 10 10 10 10 10 P P P P P P P P P 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 P P P P P P P P P 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 1.85 1.85 1.85 20.97 21.91 23.76 44.52 86.17 16,326.30 U1/2 U1/2 U1/2 1.85 1.85 1.85 20.97 21.91 23.76 44.52 86.17 16,326.30 44.2 15.9 32.2 1.6 2.2 7.3 2.7 2.2 0.8 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 10 10 10 10 10 10 10 10 10 P P P 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 1.85 1.85 1.85 U1/2 U1/2 U1/2 1.85 1.85 1.85 24.1 16.9 4.3 3.7 3.7 3.7 10 10 10 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,056.11 1,023.92 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 105% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 102% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 3.1 % 100.0 % B-37 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) K K K K K K K K K 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 10 10 1 1 1 1 1 1 1 Sample Conc. Qualifier (µg/L) 3,208,260.00 3,015,150.00 276,032.00 344,438.00 381,891.00 414,220.00 542,111.00 366,653.00 510,526.00 K K K K K K K K K 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 10 10 1 1 1 1 1 1 1 3,137,490.00 3,120,010.00 282,925.00 364,779.00 400,921.00 433,405.00 553,012.00 405,850.00 489,806.00 K K K 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.80 5.54 3,153,610.00 Analyte Sample ID Dilution Factor U1/2 Spike Sol'n Conc. Volume (µg/L) (µL) Instrument Conc. (µg/L) 320,826.00 301,515.00 276,032.00 344,438.00 381,891.00 414,220.00 542,111.00 366,653.00 510,526.00 RSD (%) 0.6 1.8 0.7 2.7 1.1 0.4 3.1 4.0 7.8 MDL (µg/L) 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 313,749.00 312,001.00 282,925.00 364,779.00 400,921.00 433,405.00 553,012.00 405,850.00 489,806.00 0.5 1.1 0.8 0.7 3.5 1.4 6.5 1.1 1.4 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 5 5 5 5 5 5 5 5 5 0.80 5.54 3,153,610.00 9.5 3.7 0.9 1.6 1.6 1.6 5 5 5 Mean RSD Completeness 2.2 % 100.0 % ML (µg/L) 5 5 5 5 5 5 5 5 5 10,000 10,000 Spike Conc. (µg/L) 1,000 276,966.00 1,000 283,826.00 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 93% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/3/2012 10:02 5/3/2012 10:04 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 90% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/3/2012 10:05 5/3/2012 10:07 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt B-38 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 233.00 214.00 199.00 459.00 470.00 424.00 510.00 309.00 425.00 Se Se Se Se Se Se Se Se Se 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Se Se Se Se Se Se Se Se Se 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 254.00 214.00 175.00 452.00 484.00 457.00 497.00 247.00 418.00 Se Se Se 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.26 0.26 0.26 U1/2 U1/2 U1/2 Spike Sol'n Conc. Volume (µg/L) (µL) Instrument Conc. (µg/L) 233.00 214.00 199.00 459.00 470.00 424.00 510.00 309.00 425.00 RSD (%) 4.4 4.0 0.7 0.9 1.0 0.4 1.1 0.5 3.3 MDL (µg/L) 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 254.00 214.00 175.00 452.00 484.00 457.00 497.00 247.00 418.00 8.3 3.4 0.1 0.2 1.7 3.3 6.2 1.8 2.6 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 2 2 2 2 2 2 2 2 2 0.26 0.26 0.26 6.7 12.5 9.7 0.52 0.52 0.52 2 2 2 Mean RSD Completeness ML (µg/L) 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 705.96 665.41 Spike Recovery (%) 101% 98% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 2.4 % 100.0 % B-39 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 56.32 1,729.15 9,420.70 6,176.32 7,789.09 10,838.00 18,590.60 30,189.50 970,334.00 Si Si Si Si Si Si Si Si Si 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Si Si Si Si Si Si Si Si Si 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 62.04 1,523.31 9,392.35 6,118.24 7,586.46 10,178.70 16,366.40 32,684.60 1,034,020.00 Si Si Si 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.55 3.81 2.88 U1/2 E E Spike Sol'n Conc. Volume (µg/L) (µL) Instrument Conc. (µg/L) 56.32 1,729.15 9,420.70 6,176.32 7,789.09 10,838.00 18,590.60 30,189.50 970,334.00 RSD (%) 1.6 0.2 0.3 2.5 1.1 0.8 0.8 0.4 1.8 MDL (µg/L) 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 62.04 1,523.31 9,392.35 6,118.24 7,586.46 10,178.70 16,366.40 32,684.60 1,034,020.00 1.6 0.8 0.5 0.9 1.3 1.2 0.6 0.1 1.9 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 5 5 5 5 5 5 5 5 5 0.55 3.81 2.88 13.2 2.7 1.9 1.1 1.1 1.1 5 5 5 Mean RSD Completeness ML (µg/L) 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 10,372.10 10,322.10 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 95% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 93% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.0 % 100.0 % B-40 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 497,776.00 476,431.00 491,942.00 537,786.00 536,333.00 560,222.00 544,462.00 275,377.00 249,908.00 Na Na Na Na Na Na Na Na Na 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Na Na Na Na Na Na Na Na Na 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 493,383.00 487,722.00 517,956.00 555,757.00 571,589.00 563,251.00 568,126.00 298,846.00 250,476.00 Na Na Na 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 1.25 1.25 4.59 U1/2 U1/2 E Instrument Conc. (µg/L) 497,776.00 476,431.00 491,942.00 537,786.00 536,333.00 560,222.00 544,462.00 275,377.00 249,908.00 RSD (%) 0.3 0.6 0.1 2.8 0.8 0.5 0.8 1.0 0.6 MDL (µg/L) 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 ML (µg/L) 10 10 10 10 10 10 10 10 10 493,383.00 487,722.00 517,956.00 555,757.00 571,589.00 563,251.00 568,126.00 298,846.00 250,476.00 0.2 0.5 0.5 0.3 0.8 0.7 1.0 0.2 0.7 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 10 10 10 10 10 10 10 10 10 1.25 1.25 4.59 1.4 1.7 0.6 2.5 2.5 2.5 10 10 10 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 Spike Conc. (µg/L) 1,000 492,837.00 1,000 518,837.00 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 90% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 88% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 0.7 % 100.0 % B-41 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 18,531.70 18,086.10 7,809.93 25,045.10 32,978.80 44,894.60 59,232.80 37,533.80 38,084.90 Sr Sr Sr Sr Sr Sr Sr Sr Sr 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Sr Sr Sr Sr Sr Sr Sr Sr Sr 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 17,381.90 17,610.30 8,742.79 25,746.20 32,010.30 46,374.20 59,448.20 40,575.80 36,969.00 Sr Sr Sr 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.50 0.50 0.50 U1/2 U1/2 U1/2 Instrument Conc. (µg/L) 18,531.70 18,086.10 7,809.93 25,045.10 32,978.80 44,894.60 59,232.80 37,533.80 38,084.90 RSD (%) 0.8 1.0 1.3 3.4 0.9 0.7 1.1 0.6 2.1 17,381.90 17,610.30 8,742.79 25,746.20 32,010.30 46,374.20 59,448.20 40,575.80 36,969.00 0.50 0.50 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 2.0 0.3 1.1 0.5 1.5 1.9 1.2 0.8 1.3 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 8.5 10.5 2.9 1 1 1 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 8,763.46 9,663.46 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 95% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 92% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.3 % 100.0 % B-42 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) S S S S S S S S S 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 10 10 10 1 1 1 1 1 1 Sample Conc. Qualifier (µg/L) 2,513,540.00 1,996,290.00 973,267.00 524,121.00 552,591.00 587,531.00 651,695.00 347,705.00 381,976.00 S S S S S S S S S 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 10 10 10 1 1 1 1 1 1 2,363,900.00 2,022,620.00 988,445.00 526,648.00 558,349.00 591,489.00 672,862.00 356,709.00 360,758.00 S S S 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 3.40 3.40 12.02 Analyte Sample ID Dilution Factor U1/2 U1/2 E Instrument Conc. (µg/L) 251,354.00 199,629.00 97,326.70 524,121.00 552,591.00 587,531.00 651,695.00 347,705.00 381,976.00 RSD (%) 1.0 0.3 0.7 2.5 1.5 0.5 0.8 0.0 1.2 MDL (µg/L) 6.8 6.8 6.8 6.8 6.8 6.8 6.8 6.8 6.8 ML (µg/L) 20 20 20 20 20 20 20 20 20 236,390.00 202,262.00 98,844.50 526,648.00 558,349.00 591,489.00 672,862.00 356,709.00 360,758.00 0.5 1.1 0.6 0.9 0.8 1.2 0.4 0.1 0.6 6.8 6.8 6.8 6.8 6.8 6.8 6.8 6.8 6.8 20 20 20 20 20 20 20 20 20 3.40 3.40 12.02 4.5 7.6 6.0 6.8 6.8 6.8 20 20 20 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 Spike Conc. (µg/L) 5,000 978,043.00 5,000 993,043.00 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 96% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/3/2012 10:02 5/3/2012 10:04 5/3/2012 10:09 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 92% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/3/2012 10:05 5/3/2012 10:07 5/3/2012 10:20 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 0.8 % 100.0 % B-43 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.25 U1/2 0.25 U1/2 0.25 U1/2 1.09 E 2.25 4.57 12.60 21.50 51.00 Instrument Conc. (µg/L) 0.25 0.25 0.25 1.09 2.25 4.57 12.60 21.50 51.00 RSD (%) 15.4 4.6 2.8 2.0 0.9 1.2 0.2 0.8 0.7 MDL (µg/L) 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) Tl Tl Tl Tl Tl Tl Tl Tl Tl 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Tl Tl Tl Tl Tl Tl Tl Tl Tl 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 0.25 0.25 0.25 1.22 2.33 4.95 10.10 19.80 57.50 U1/2 U1/2 U1/2 E 0.25 0.25 0.25 1.22 2.33 4.95 10.10 19.80 57.50 14.2 1.2 4.0 2.9 1.3 2.7 1.7 0.9 4.1 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 2 2 2 2 2 2 2 2 2 Tl Tl Tl 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.25 0.25 0.25 U1/2 U1/2 U1/2 0.25 0.25 0.25 14.3 5.8 8.4 0.51 0.51 0.51 2 2 2 Mean RSD Completeness 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 497.71 474.38 Spike Recovery (%) 99% 95% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 1.5 % 100.0 % B-44 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.35 U1/2 0.35 U1/2 0.35 U1/2 0.35 U1/2 0.35 U1/2 0.35 U1/2 0.35 U1/2 0.35 U1/2 22.80 Instrument Conc. (µg/L) 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 22.80 RSD (%) 8.7 5.8 10.2 18.7 26.9 25.0 4.2 13.2 1.5 MDL (µg/L) 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) Sn Sn Sn Sn Sn Sn Sn Sn Sn 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Sn Sn Sn Sn Sn Sn Sn Sn Sn 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 24.50 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 24.50 6.2 4.4 23.5 15.5 17.0 28.2 18.3 21.0 5.3 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 2 2 2 2 2 2 2 2 2 Sn Sn Sn 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.35 0.35 0.35 U1/2 U1/2 U1/2 0.35 0.35 0.35 14.5 3.0 1.5 0.7 0.7 0.7 2 2 2 Mean RSD Completeness 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 492.10 483.60 Spike Recovery (%) 98% 97% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 3.4 % 100.0 % B-45 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 7.08 E 5,212.00 Instrument Conc. (µg/L) 1.00 1.00 1.00 1.00 1.00 1.00 1.00 7.08 5,212.00 RSD (%) 35.1 56.8 11.7 5.2 3.8 17.1 3.8 2.8 2.5 Ti Ti Ti Ti Ti Ti Ti Ti Ti 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Ti Ti Ti Ti Ti Ti Ti Ti Ti 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 1.00 1.00 1.00 1.00 1.00 1.00 1.00 6.35 8,149.30 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 E 1.00 1.00 1.00 1.00 1.00 1.00 1.00 6.35 8,149.30 Ti Ti Ti 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 1.00 1.00 1.00 U1/2 U1/2 U1/2 1.00 1.00 1.00 Mean RSD Completeness MDL (µg/L) 2 2 2 2 2 2 2 2 2 ML (µg/L) 10 10 10 10 10 10 10 10 10 27.5 22.0 6.8 8.3 18.2 11.8 21.4 2.3 0.8 2 2 2 2 2 2 2 2 2 10 10 10 10 10 10 10 10 10 17.4 29.4 4.1 2 2 2 10 10 10 Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,060.48 1,029.33 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 106% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 103% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.6 % 100.0 % B-46 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.15 U1/2 0.15 U1/2 0.15 U1/2 2.02 42.90 59.40 65.90 34.60 93.80 Instrument Conc. (µg/L) 0.15 0.15 0.15 2.02 42.90 59.40 65.90 34.60 93.80 RSD (%) 6.6 27.5 12.4 2.1 3.9 3.9 4.2 5.4 1.5 MDL (µg/L) 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) U U U U U U U U U 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 U U U U U U U U U 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 0.15 0.15 0.15 1.88 36.30 57.20 71.40 29.90 90.70 U1/2 U1/2 U1/2 0.15 0.15 0.15 1.88 36.30 57.20 71.40 29.90 90.70 26.2 11.2 15.5 3.1 4.4 3.2 4.3 4.4 0.6 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 1 1 1 1 1 1 1 1 1 U U U 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.15 0.15 0.15 U1/2 U1/2 U1/2 0.15 0.15 0.15 27.6 30.3 31.2 0.3 0.3 0.3 1 1 1 Mean RSD Completeness 1 1 1 1 1 1 1 1 1 10,000 10,000 500 500 Spike Conc. (µg/L) 502.81 499.38 Spike Recovery (%) 101% 100% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:56 6/27/2012 19:01 6/27/2012 19:06 6/27/2012 19:11 6/27/2012 19:15 6/27/2012 19:20 6/27/2012 19:25 6/27/2012 19:30 6/27/2012 19:35 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 19:45 6/27/2012 19:50 6/27/2012 19:55 6/27/2012 20:00 6/27/2012 20:05 6/27/2012 20:10 6/27/2012 20:15 6/27/2012 20:20 6/27/2012 20:24 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS 6/27/2012 18:41 6/27/2012 18:46 6/27/2012 18:51 C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1313 AES-PR (orig).xlsx 7.8 % 100.0 % B-47 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 33.31 49.52 158.34 433.04 406.28 410.74 393.41 246.33 4,294.15 V V V V V V V V V 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 V V V V V V V V V 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 28.94 51.09 155.34 428.72 419.63 428.49 413.27 242.37 4,333.87 V V V 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.75 0.75 0.75 U1/2 U1/2 U1/2 Spike Sol'n Conc. Volume (µg/L) (µL) Instrument Conc. (µg/L) 33.31 49.52 158.34 433.04 406.28 410.74 393.41 246.33 4,294.15 RSD (%) 2.1 0.9 0.6 2.7 0.4 0.6 1.3 1.1 2.0 MDL (µg/L) 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 28.94 51.09 155.34 428.72 419.63 428.49 413.27 242.37 4,333.87 0.9 1.4 1.6 0.6 1.5 1.2 0.7 1.0 0.8 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 5 5 5 5 5 5 5 5 5 0.75 0.75 0.75 1.4 12.7 2.3 1.5 1.5 1.5 5 5 5 Mean RSD Completeness ML (µg/L) 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,163.75 1,137.57 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 101% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 98% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.2 % 100.0 % B-48 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.50 U1/2 0.50 U1/2 0.50 U1/2 0.50 U1/2 0.50 U1/2 4.02 E 1,220.78 1,679.85 2,229.84 Instrument Conc. (µg/L) 0.50 0.50 0.50 0.50 0.50 4.02 1,220.78 1,679.85 2,229.84 RSD (%) 11.8 19.9 4.9 5.1 7.1 7.7 1.5 0.4 1.4 Zn Zn Zn Zn Zn Zn Zn Zn Zn 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Zn Zn Zn Zn Zn Zn Zn Zn Zn 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 0.50 0.50 0.50 0.50 0.50 4.26 1,150.88 1,580.09 2,211.50 U1/2 U1/2 U1/2 U1/2 U1/2 E 0.50 0.50 0.50 0.50 0.50 4.26 1,150.88 1,580.09 2,211.50 Zn Zn Zn 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 0.50 0.50 0.50 U1/2 U1/2 U1/2 0.50 0.50 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 17.4 10.6 5.7 13.8 2.2 9.1 1.2 0.7 1.9 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 14.1 1.7 9.9 1 1 1 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,149.47 1,123.60 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 115% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:27 5/2/2012 16:28 4/18/2012 13:54 4/18/2012 13:55 4/18/2012 13:57 4/18/2012 13:59 4/18/2012 14:00 4/18/2012 14:02 4/18/2012 14:04 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES 112% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 5/2/2012 16:30 5/2/2012 16:32 4/18/2012 14:14 4/18/2012 14:15 4/18/2012 14:17 4/18/2012 14:19 4/18/2012 14:20 4/18/2012 14:22 4/18/2012 14:24 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt VU ICP-OES VU ICP-OES VU ICP-OES 4/18/2012 13:41 4/18/2012 13:42 5/2/2012 16:25 C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt C:\ICP-OES Rpt File 1313 AES-PR (orig).txt 1.2 % 100.0 % B-49 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 34,440.00 14,860.00 6,413.00 2,558.00 3,473.00 4,874.00 65.00 U1/2 65.00 U1/2 65.00 U1/2 Instrument Conc. (µg/L) 34,440.00 14,860.00 6,413.00 2,558.00 3,473.00 4,874.00 65.00 65.00 65.00 RSD (%) 1.6 1.6 2.1 0.8 0.7 0.6 8.6 14.1 4.6 MDL (µg/L) 130 130 130 130 130 130 130 130 130 ML (µg/L) 500 500 500 500 500 500 500 500 500 0.4 0.1 2.5 2.9 0.5 1.0 7.6 3.4 15.5 130 130 130 130 130 130 130 130 130 500 500 500 500 500 500 500 500 500 8.1 10.0 0.4 130 130 130 500 500 500 DIC DIC DIC DIC DIC DIC DIC DIC DIC 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 DIC DIC DIC DIC DIC DIC DIC DIC DIC 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 32,330.00 13,310.00 6,405.00 2,723.00 3,716.00 5,136.00 65.00 65.00 65.00 U1/2 U1/2 U1/2 32,330.00 13,310.00 6,405.00 2,723.00 3,716.00 5,136.00 65.00 65.00 65.00 DIC DIC DIC 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 65.00 65.00 270.00 U1/2 U1/2 E 65.00 65.00 270.00 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 100,000 100,000 500 500 Spike Conc. (µg/L) 6,877.00 6,865.00 Spike Recovery (%) 93% 92% Instrument Date/Time Filename VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC 9/4/2012 13:11 9/4/2012 13:21 9/4/2012 13:30 9/4/2012 13:40 9/4/2012 13:49 9/4/2012 13:59 9/4/2012 14:09 9/4/2012 14:16 9/4/2012 14:23 C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC 9/4/2012 15:24 9/4/2012 15:34 9/4/2012 15:43 9/4/2012 15:53 9/4/2012 16:02 9/4/2012 16:12 9/4/2012 16:19 9/4/2012 16:29 9/4/2012 16:36 C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt VU TOC VU TOC VU TOC 9/4/2012 12:44 9/4/2012 12:52 9/4/2012 13:02 C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt 3.8 % 100.0 % B-50 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 41,380.00 16,160.00 4,873.00 5,839.00 5,163.00 6,213.00 3,834.00 5,118.00 11,480.00 DOC DOC DOC DOC DOC DOC DOC DOC DOC 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 DOC DOC DOC DOC DOC DOC DOC DOC DOC 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 50,210.00 17,030.00 5,357.00 5,915.00 5,531.00 6,504.00 4,690.00 5,175.00 12,170.00 DOC DOC DOC 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 85.00 175.00 450.00 U1/2 E E Instrument Conc. (µg/L) 41,380.00 16,160.00 4,873.00 5,839.00 5,163.00 6,213.00 3,834.00 5,118.00 11,480.00 RSD (%) 0.9 1.0 0.3 0.3 0.7 2.0 1.0 0.2 1.7 MDL (µg/L) 170 170 170 170 170 170 170 170 170 ML (µg/L) 500 500 500 500 500 500 500 500 500 50,210.00 17,030.00 5,357.00 5,915.00 5,531.00 6,504.00 4,690.00 5,175.00 12,170.00 0.3 1.1 0.9 0.7 0.9 1.4 0.6 1.4 0.6 170 170 170 170 170 170 170 170 170 500 500 500 500 500 500 500 500 500 85.00 175.00 450.00 2.9 1.9 0.1 170 170 170 500 500 500 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 100,000 100,000 500 500 Spike Conc. (µg/L) 5,341.00 5,814.00 Spike Recovery (%) 94% 91% Instrument Date/Time Filename VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC 9/5/2012 17:17 9/5/2012 17:24 9/5/2012 17:31 9/5/2012 17:40 9/5/2012 17:49 9/5/2012 17:56 9/5/2012 18:06 9/5/2012 18:15 9/5/2012 18:24 C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC 9/5/2012 19:22 9/5/2012 19:30 9/5/2012 19:39 9/5/2012 19:48 9/5/2012 19:57 9/5/2012 20:06 9/5/2012 20:13 9/5/2012 20:23 9/5/2012 20:32 C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt VU TOC VU TOC VU TOC 9/5/2012 16:45 9/5/2012 16:55 9/5/2012 17:09 C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt C:\DIC-DOC 1313 AES-PR (orig).txt 0.9 % 100.0 % B-51 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 Instrument Conc. (µg/L) 8.71 8.71 8.71 8.71 8.71 8.71 8.71 8.71 8.71 RSD (%) MDL (µg/L) 17 17 17 17 17 17 17 17 17 ML (µg/L) 50 50 50 50 50 50 50 50 50 Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 20:35 9/4/2012 20:47 9/4/2012 21:00 9/4/2012 21:12 9/4/2012 21:25 9/4/2012 21:37 9/4/2012 21:49 9/4/2012 22:02 9/4/2012 22:14 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx Br Br Br Br Br Br Br Br Br 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 Br Br Br Br Br Br Br Br Br 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 8.71 8.71 8.71 8.71 8.71 8.71 8.71 8.71 8.71 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 8.71 8.71 8.71 8.71 8.71 8.71 8.71 8.71 8.71 17 17 17 17 17 17 17 17 17 50 50 50 50 50 50 50 50 50 VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 22:27 9/4/2012 22:39 9/4/2012 22:51 9/4/2012 23:04 9/4/2012 23:16 9/4/2012 23:29 9/4/2012 23:41 9/4/2012 23:53 9/5/2012 0:06 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx Br Br Br 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 8.71 8.71 8.71 U1/2 U1/2 U1/2 8.71 8.71 8.71 17 17 17 50 50 50 VU IC VU IC VU IC 9/5/2012 0:43 9/5/2012 1:08 9/5/2012 1:33 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx Mean RSD Completeness NA NA Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. % % B-52 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 650,180.40 639,512.50 643,715.20 648,701.20 752,420.00 672,511.60 710,327.80 896,281.10 850,109.00 Cl Cl Cl Cl Cl Cl Cl Cl Cl 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 20 20 20 20 20 20 20 20 20 Cl Cl Cl Cl Cl Cl Cl Cl Cl 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 20 20 20 20 20 20 20 20 20 649,372.40 650,944.40 655,354.00 654,995.30 777,173.20 665,658.60 700,147.60 914,369.10 898,354.10 Cl Cl Cl 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 3.25 3.25 3.25 U1/2 U1/2 U1/2 Instrument Conc. (µg/L) 32,509.02 31,975.63 32,185.76 32,435.06 37,621.00 33,625.58 35,516.39 44,814.06 42,505.45 MDL (µg/L) 6.5 6.5 6.5 6.5 6.5 6.5 6.5 6.5 6.5 ML (µg/L) 20 20 20 20 20 20 20 20 20 32,468.62 32,547.22 32,767.70 32,749.77 38,858.66 33,282.93 35,007.38 45,718.46 44,917.71 6.5 6.5 6.5 6.5 6.5 6.5 6.5 6.5 6.5 20 20 20 20 20 20 20 20 20 3.25 3.25 3.25 6.5 6.5 6.5 20 20 20 Mean RSD Completeness RSD (%) NA NA Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) --- Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. --- Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 16:27 9/4/2012 16:40 9/4/2012 16:52 9/4/2012 17:04 9/4/2012 18:06 9/4/2012 18:19 9/4/2012 18:31 9/4/2012 18:43 9/4/2012 18:56 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 17:17 9/4/2012 17:29 9/4/2012 17:42 9/4/2012 17:54 9/4/2012 19:08 9/4/2012 19:21 9/4/2012 19:33 9/4/2012 19:45 9/4/2012 19:58 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC 9/5/2012 0:43 9/5/2012 1:08 9/5/2012 1:33 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx % % B-53 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 13,977.00 11,067.90 5,964.00 18,209.90 30,457.10 40,374.20 59,447.70 81,972.90 130,062.50 F F F F F F F F F 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 20 20 20 F F F F F F F F F 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 20 20 20 11,365.00 9,158.50 7,205.20 20,500.60 33,145.20 39,441.20 54,391.30 85,600.70 125,326.80 F F F 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 3.53 351.80 34.80 U1/2 Instrument Conc. (µg/L) 13,977.00 11,067.90 5,964.00 18,209.90 30,457.10 40,374.20 2,972.39 4,098.65 6,503.13 7 7 7 7 7 7 7 7 7 ML (µg/L) 20 20 20 20 20 20 20 20 20 11,365.00 9,158.50 7,205.20 20,500.60 33,145.20 39,441.20 2,719.57 4,280.04 6,266.34 7 7 7 7 7 7 7 7 7 20 20 20 20 20 20 20 20 20 3.53 351.80 34.80 7 7 7 20 20 20 Mean RSD Completeness RSD (%) NA NA MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) --- Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. --- Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 20:35 9/4/2012 20:47 9/4/2012 21:00 9/4/2012 21:12 9/4/2012 21:25 9/4/2012 21:37 9/4/2012 18:31 9/4/2012 18:43 9/4/2012 18:56 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 22:27 9/4/2012 22:39 9/4/2012 22:51 9/4/2012 23:04 9/4/2012 23:16 9/4/2012 23:29 9/4/2012 19:33 9/4/2012 19:45 9/4/2012 19:58 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC 9/5/2012 0:43 9/5/2012 1:08 9/5/2012 1:33 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx % % B-54 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) NO3 NO3 NO3 NO3 NO3 NO3 NO3 NO3 NO3 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 20 20 20 200 200 500 500 500 500 Sample Conc. Qualifier (µg/L) 21,144.10 21,396.00 41,393.80 19,368,127.10 27,682,477.90 38,179,496.00 51,276,792.80 75,456,922.90 152,839,798.90 NO3 NO3 NO3 NO3 NO3 NO3 NO3 NO3 NO3 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 20 20 20 200 200 500 500 500 500 20,876.60 21,797.90 39,728.60 18,882,886.70 24,383,005.70 37,624,090.90 48,757,941.90 68,997,887.60 160,187,868.80 1,043.83 1,089.90 1,986.43 94,414.43 121,915.03 75,248.18 97,515.88 137,995.78 320,375.74 26 26 26 26 26 26 26 26 26 100 100 100 100 100 100 100 100 100 NO3 NO3 NO3 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 500 1 108.00 104,567,473.90 144.20 108.00 209,134.95 144.20 26 26 26 100 100 100 Analyte Sample ID Dilution Factor Instrument Conc. (µg/L) 1,057.21 1,069.80 2,069.69 96,840.64 138,412.39 76,358.99 102,553.59 150,913.85 305,679.60 Mean RSD Completeness RSD (%) NA NA MDL (µg/L) 26 26 26 26 26 26 26 26 26 ML (µg/L) 100 100 100 100 100 100 100 100 100 Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) --- Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. --- Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 16:27 9/4/2012 16:40 9/4/2012 16:52 9/5/2012 13:12 9/5/2012 13:24 9/5/2012 13:36 9/5/2012 13:49 9/5/2012 14:01 9/5/2012 14:13 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 17:17 9/4/2012 17:29 9/4/2012 17:42 9/5/2012 14:26 9/5/2012 14:38 9/5/2012 14:50 9/5/2012 15:02 9/5/2012 15:14 9/5/2012 15:27 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC 9/5/2012 0:43 9/5/2012 15:39 9/5/2012 1:33 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx % % B-55 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 Instrument Conc. (µg/L) 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 RSD (%) MDL (µg/L) 18 18 18 18 18 18 18 18 18 ML (µg/L) 50 50 50 50 50 50 50 50 50 NO2 NO2 NO2 NO2 NO2 NO2 NO2 NO2 NO2 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 NO2 NO2 NO2 NO2 NO2 NO2 NO2 NO2 NO2 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 18 18 18 18 18 18 18 18 18 50 50 50 50 50 50 50 50 50 NO2 NO2 NO2 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 9.16 9.16 9.16 U1/2 U1/2 U1/2 9.16 9.16 9.16 18 18 18 50 50 50 Mean RSD Completeness NA NA Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) --- Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. --- Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 20:35 9/4/2012 20:47 9/4/2012 21:00 9/4/2012 21:12 9/4/2012 21:25 9/4/2012 21:37 9/4/2012 21:49 9/4/2012 22:02 9/4/2012 22:14 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 22:27 9/4/2012 22:39 9/4/2012 22:51 9/4/2012 23:04 9/4/2012 23:16 9/4/2012 23:29 9/4/2012 23:41 9/4/2012 23:53 9/5/2012 0:06 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC 9/5/2012 0:43 9/5/2012 1:08 9/5/2012 1:33 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx % % B-56 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 Instrument Conc. (µg/L) 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 RSD (%) MDL (µg/L) 24 24 24 24 24 24 24 24 24 ML (µg/L) 100 100 100 100 100 100 100 100 100 PO4 PO4 PO4 PO4 PO4 PO4 PO4 PO4 PO4 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 1 1 1 1 1 1 1 1 1 PO4 PO4 PO4 PO4 PO4 PO4 PO4 PO4 PO4 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 1 1 1 1 1 1 1 1 1 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 24 24 24 24 24 24 24 24 24 100 100 100 100 100 100 100 100 100 PO4 PO4 PO4 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 11.83 11.83 11.83 U1/2 U1/2 U1/2 11.83 11.83 11.83 24 24 24 100 100 100 Mean RSD Completeness NA NA Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) --- Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. --- Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 20:35 9/4/2012 20:47 9/4/2012 21:00 9/4/2012 21:12 9/4/2012 21:25 9/4/2012 21:37 9/4/2012 21:49 9/4/2012 22:02 9/4/2012 22:14 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/4/2012 22:27 9/4/2012 22:39 9/4/2012 22:51 9/4/2012 23:04 9/4/2012 23:16 9/4/2012 23:29 9/4/2012 23:41 9/4/2012 23:53 9/5/2012 0:06 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC 9/5/2012 0:43 9/5/2012 1:08 9/5/2012 1:33 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx % % B-57 QA-QC REPORT Client EPA Region 2 Test EPA Method 1313 Material AGREMAX (material code AES) SO4 SO4 SO4 SO4 SO4 SO4 SO4 SO4 SO4 1313-AES-T01-A 1313-AES-T02-A 1313-AES-T03-A 1313-AES-T04-A 1313-AES-T05-A 1313-AES-T06-A 1313-AES-T07-A 1313-AES-T08-A 1313-AES-T09-A 100 100 20 20 20 20 20 20 20 Sample Conc. Qualifier (µg/L) 8,203,931.30 6,525,914.80 2,687,032.70 1,912,312.90 1,959,340.50 2,215,117.70 2,572,540.30 1,080,759.50 1,085,139.90 SO4 SO4 SO4 SO4 SO4 SO4 SO4 SO4 SO4 1313-AES-T01-B 1313-AES-T02-B 1313-AES-T03-B 1313-AES-T04-B 1313-AES-T05-B 1313-AES-T06-B 1313-AES-T07-B 1313-AES-T08-B 1313-AES-T09-B 100 100 20 20 20 20 20 20 20 9,143,854.60 7,052,684.30 2,273,105.60 2,029,118.70 1,954,620.60 1,985,947.10 2,317,698.40 1,030,535.70 1,035,648.40 SO4 SO4 SO4 1313-AES-B01-A 1313-AES-B02-A 1313-AES-B03-A 1 1 1 Analyte Sample ID Dilution Factor 10.39 10.39 10.39 U1/2 U1/2 U1/2 Instrument Conc. (µg/L) 82,039.31 65,259.15 134,351.64 95,615.65 97,967.03 110,755.89 128,627.02 54,037.98 54,257.00 MDL (µg/L) 21 21 21 21 21 21 21 21 21 ML (µg/L) 100 100 100 100 100 100 100 100 100 91,438.55 70,526.84 113,655.28 101,455.94 97,731.03 99,297.36 115,884.92 51,526.79 51,782.42 21 21 21 21 21 21 21 21 21 100 100 100 100 100 100 100 100 100 10.39 10.39 10.39 21 21 21 100 100 100 Mean RSD Completeness RSD (%) NA NA Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) --- Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. --- Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/5/2012 11:58 9/5/2012 12:10 9/4/2012 16:52 9/4/2012 17:04 9/4/2012 18:06 9/4/2012 18:19 9/4/2012 18:31 9/4/2012 18:43 9/4/2012 18:56 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 9/5/2012 12:35 9/5/2012 12:47 9/4/2012 17:42 9/4/2012 17:54 9/4/2012 19:08 9/4/2012 19:21 9/4/2012 19:33 9/4/2012 19:45 9/4/2012 19:58 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC 9/5/2012 0:43 9/5/2012 1:08 9/5/2012 1:33 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx % % B-58 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 655.89 611.07 435.79 378.77 342.29 293.56 266.72 247.79 192.36 Al Al Al Al Al Al Al Al Al 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Al Al Al Al Al Al Al Al Al 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 654.79 592.54 520.39 351.20 334.18 270.03 249.72 230.96 187.98 Al 1314-AES-M01-A 1 0.50 U1/2 Instrument Conc. (µg/L) 655.89 611.07 435.79 378.77 342.29 293.56 266.72 247.79 192.36 RSD (%) 1.3 0.9 1.0 0.9 0.8 2.5 2.7 1.3 2.8 654.79 592.54 520.39 351.20 334.18 270.03 249.72 230.96 187.98 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 1.0 1.8 0.4 2.7 1.0 2.2 1.8 2.1 2.7 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 3.2 1 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,461.82 1,546.48 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 103% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 103% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.7 % 100.0 % B-59 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 17.10 13.10 11.90 8.22 0.18 E 0.04 U1/2 0.04 U1/2 0.04 U1/2 0.04 U1/2 Instrument Conc. (µg/L) 17.10 13.10 11.90 8.22 0.18 0.04 0.04 0.04 0.04 RSD (%) 1.2 3.0 3.2 1.9 6.4 5.5 6.2 2.7 3.1 MDL (µg/L) 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 ML (µg/L) 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 2.6 1.5 1.4 2.2 4.7 7.8 5.9 5.4 4.8 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 9.2 0.08 0.2 Sb Sb Sb Sb Sb Sb Sb Sb Sb 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Sb Sb Sb Sb Sb Sb Sb Sb Sb 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 18.90 13.90 12.40 10.70 0.19 0.04 0.04 0.04 0.04 E U1/2 U1/2 U1/2 U1/2 18.90 13.90 12.40 10.70 0.19 0.04 0.04 0.04 0.04 Sb 1314-AES-M01-A 1 0.04 U1/2 0.04 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 500 500 Spike Conc. (µg/L) 512.15 504.71 Spike Recovery (%) 100% 98% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx 2.1 % 100.0 % B-60 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 41.40 42.60 27.60 11.40 7.66 5.99 4.90 4.89 4.44 As As As As As As As As As 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 As As As As As As As As As 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 39.80 42.90 26.60 10.80 6.61 5.29 4.74 4.52 4.25 As 1314-AES-M01-A 1 0.32 U1/2 Instrument Conc. (µg/L) 41.40 42.60 27.60 11.40 7.66 5.99 4.90 4.89 4.44 RSD (%) 2.2 8.0 0.9 4.3 1.9 2.2 2.6 0.5 0.6 MDL (µg/L) 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 39.80 42.90 26.60 10.80 6.61 5.29 4.74 4.52 4.25 3.7 4.9 3.2 1.0 1.4 1.6 1.8 2.7 3.7 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 2 2 2 2 2 2 2 2 2 0.32 1.9 0.64 2 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 524.18 514.59 Spike Recovery (%) 99% 98% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx 2.6 % 100.0 % B-61 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 2,631.53 2,726.72 2,142.53 1,374.56 1,023.82 706.79 581.20 519.00 457.37 B B B B B B B B B 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 B B B B B B B B B 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 2,571.81 2,682.04 1,964.58 1,295.10 969.71 677.44 574.28 498.44 465.21 B 1314-AES-M01-A 1 0.50 U1/2 Instrument Conc. (µg/L) 2,631.53 2,726.72 2,142.53 1,374.56 1,023.82 706.79 581.20 519.00 457.37 RSD (%) 0.8 1.6 0.7 0.5 0.8 0.6 1.1 1.8 0.4 2,571.81 2,682.04 1,964.58 1,295.10 969.71 677.44 574.28 498.44 465.21 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 0.2 0.3 0.5 1.3 0.5 0.4 2.1 2.1 4.7 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 16.5 1 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 3,066.02 2,848.31 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 92% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 88% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.1 % 100.0 % B-62 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 61.08 45.16 33.56 31.04 32.44 30.22 32.27 30.77 32.09 Ba Ba Ba Ba Ba Ba Ba Ba Ba 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Ba Ba Ba Ba Ba Ba Ba Ba Ba 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 58.35 44.84 31.73 29.72 30.24 29.82 31.48 30.58 31.97 Ba 1314-AES-M01-A 1 0.50 U1/2 Instrument Conc. (µg/L) 61.08 45.16 33.56 31.04 32.44 30.22 32.27 30.77 32.09 RSD (%) 0.8 0.9 0.2 0.9 0.4 0.2 1.2 1.3 0.4 58.35 44.84 31.73 29.72 30.24 29.82 31.48 30.58 31.97 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 0.7 0.8 0.9 1.0 0.5 0.4 1.2 2.2 3.7 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 8.4 1 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,115.62 1,074.96 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 108% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 104% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.0 % 100.0 % B-63 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 0.32 U1/2 Instrument Conc. (µg/L) 0.32 0.32 0.32 0.32 0.32 0.32 0.32 0.32 0.32 RSD (%) 23.0 2.3 11.7 5.9 22.3 33.2 14.7 13.3 4.8 MDL (µg/L) 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) Be Be Be Be Be Be Be Be Be 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Be Be Be Be Be Be Be Be Be 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 0.32 0.32 0.32 0.32 0.32 0.32 0.32 0.32 0.32 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 0.32 0.32 0.32 0.32 0.32 0.32 0.32 0.32 0.32 9.6 12.8 8.0 11.3 3.3 9.7 7.3 7.4 11.5 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 2 2 2 2 2 2 2 2 2 Be 1314-AES-M01-A 1 0.32 U1/2 0.32 31.9 0.64 2 Mean RSD Completeness NA NA 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 506.09 499.38 Spike Recovery (%) 101% 100% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx % % B-64 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 7.14 5.60 2.58 1.20 0.09 U1/2 0.09 U1/2 0.09 U1/2 0.09 U1/2 0.09 U1/2 Instrument Conc. (µg/L) 7.14 5.60 2.58 1.20 0.09 0.09 0.09 0.09 0.09 RSD (%) 3.2 5.0 2.7 2.2 8.6 7.5 10.4 3.7 8.6 MDL (µg/L) 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 ML (µg/L) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.7 2.7 2.7 2.6 0.7 14.1 3.0 8.8 12.3 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 8.7 0.17 0.5 Cd Cd Cd Cd Cd Cd Cd Cd Cd 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Cd Cd Cd Cd Cd Cd Cd Cd Cd 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 6.91 5.67 2.92 1.78 0.09 0.09 0.09 0.09 0.09 U1/2 U1/2 U1/2 U1/2 U1/2 6.91 5.67 2.92 1.78 0.09 0.09 0.09 0.09 0.09 Cd 1314-AES-M01-A 1 0.09 U1/2 0.09 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 500 500 Spike Conc. (µg/L) 509.32 503.02 Spike Recovery (%) 101% 100% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx 2.9 % 100.0 % B-65 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 541,202.00 466,185.00 427,401.00 437,710.00 465,864.00 548,016.00 577,533.00 601,065.00 626,701.00 Ca Ca Ca Ca Ca Ca Ca Ca Ca 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Ca Ca Ca Ca Ca Ca Ca Ca Ca 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 541,972.00 459,229.00 416,730.00 432,754.00 470,218.00 535,580.00 586,744.00 601,204.00 628,427.00 Ca 1314-AES-M01-A 1 3.63 E Instrument Conc. (µg/L) 541,202.00 466,185.00 427,401.00 437,710.00 465,864.00 548,016.00 577,533.00 601,065.00 626,701.00 RSD (%) 1.1 0.9 0.3 0.4 0.8 0.2 0.7 2.4 0.5 MDL (µg/L) 2.6 2.6 2.6 2.6 2.6 2.6 2.6 2.6 2.6 ML (µg/L) 10 10 10 10 10 10 10 10 10 541,972.00 459,229.00 416,730.00 432,754.00 470,218.00 535,580.00 586,744.00 601,204.00 628,427.00 0.6 0.7 0.6 1.2 0.2 0.6 1.8 1.1 3.3 2.6 2.6 2.6 2.6 2.6 2.6 2.6 2.6 2.6 10 10 10 10 10 10 10 10 10 3.63 4.9 2.6 10 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 Spike Conc. (µg/L) 1,000 428,358.00 1,000 417,658.00 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 96% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 93% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.0 % 100.0 % B-66 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 243.00 195.00 71.30 36.60 23.20 12.80 8.86 7.26 6.76 Cs Cs Cs Cs Cs Cs Cs Cs Cs 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Cs Cs Cs Cs Cs Cs Cs Cs Cs 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 249.00 187.00 69.40 31.00 20.00 11.60 8.43 7.23 6.49 Cs 1314-AES-M01-A 1 0.24 U1/2 Instrument Conc. (µg/L) 243.00 195.00 71.30 36.60 23.20 12.80 8.86 7.26 6.76 RSD (%) 1.1 2.4 2.9 1.1 1.1 1.1 1.5 1.1 1.1 MDL (µg/L) 0.49 0.49 0.49 0.49 0.49 0.49 0.49 0.49 0.49 249.00 187.00 69.40 31.00 20.00 11.60 8.43 7.23 6.49 2.1 1.5 1.6 7.0 0.8 2.4 1.3 1.6 0.0 0.49 0.49 0.49 0.49 0.49 0.49 0.49 0.49 0.49 2 2 2 2 2 2 2 2 2 0.24 1.0 0.49 2 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 543.82 528.78 Spike Recovery (%) 95% 92% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx 1.8 % 100.0 % B-67 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 271.00 220.00 36.80 5.26 3.62 2.58 2.12 1.96 E 1.79 E Cr Cr Cr Cr Cr Cr Cr Cr Cr 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Cr Cr Cr Cr Cr Cr Cr Cr Cr 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 281.00 182.00 30.90 4.92 3.67 2.75 1.93 1.77 1.46 Cr 1314-AES-M01-A 1 0.25 E E E U1/2 Instrument Conc. (µg/L) 271.00 220.00 36.80 5.26 3.62 2.58 2.12 1.96 1.79 RSD (%) 4.2 2.5 1.0 2.1 0.4 0.8 5.1 1.8 1.5 MDL (µg/L) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 281.00 182.00 30.90 4.92 3.67 2.75 1.93 1.77 1.46 0.3 2.2 1.0 1.1 4.1 2.8 3.0 1.9 0.6 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2 2 2 2 2 2 2 2 2 0.25 0.9 0.5 2 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 517.18 504.22 Spike Recovery (%) 96% 95% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx 2.1 % 100.0 % B-68 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 5.91 4.46 E 2.36 E 0.90 U1/2 0.90 U1/2 0.90 U1/2 0.90 U1/2 0.90 U1/2 0.90 U1/2 Instrument Conc. (µg/L) 5.91 4.46 2.36 0.90 0.90 0.90 0.90 0.90 0.90 RSD (%) 2.1 1.6 2.2 16.8 23.1 13.1 7.3 10.4 31.6 MDL (µg/L) 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) Co Co Co Co Co Co Co Co Co 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Co Co Co Co Co Co Co Co Co 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 6.45 4.02 1.92 0.90 0.90 0.90 0.90 0.90 0.90 E E U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 6.45 4.02 1.92 0.90 0.90 0.90 0.90 0.90 0.90 1.2 9.2 6.1 14.6 5.7 11.6 15.6 34.7 17.7 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 5 5 5 5 5 5 5 5 5 Co 1314-AES-M01-A 1 0.90 U1/2 0.90 11.4 1.8 5 Mean RSD Completeness 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,058.28 995.45 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 106% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 99% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.7 % 100.0 % B-69 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 16.94 7.43 E 4.46 E 1.85 U1/2 1.85 U1/2 1.85 U1/2 1.85 U1/2 1.85 U1/2 1.85 U1/2 Instrument Conc. (µg/L) 16.94 7.43 4.46 1.85 1.85 1.85 1.85 1.85 1.85 RSD (%) 2.2 1.4 6.8 10.1 8.4 12.2 6.3 15.7 20.8 MDL (µg/L) 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 ML (µg/L) 10 10 10 10 10 10 10 10 10 Cu Cu Cu Cu Cu Cu Cu Cu Cu 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Cu Cu Cu Cu Cu Cu Cu Cu Cu 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 18.21 9.74 4.10 1.85 1.85 1.85 1.85 1.85 1.85 E E U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 18.21 9.74 4.10 1.85 1.85 1.85 1.85 1.85 1.85 9.7 4.8 1.8 24.3 11.1 25.9 3.5 4.1 6.0 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 10 10 10 10 10 10 10 10 10 Cu 1314-AES-M01-A 1 1.85 U1/2 1.85 12.0 3.7 10 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,105.10 1,037.89 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 110% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 103% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 6.0 % 100.0 % B-70 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 Instrument Conc. (µg/L) 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 RSD (%) 6.2 12.3 1.3 4.3 17.3 26.2 9.1 10.2 31.7 Fe Fe Fe Fe Fe Fe Fe Fe Fe 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Fe Fe Fe Fe Fe Fe Fe Fe Fe 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Fe 1314-AES-M01-A 1 1.00 U1/2 1.00 Mean RSD Completeness 2 2 2 2 2 2 2 2 2 ML (µg/L) 10 10 10 10 10 10 10 10 10 17.6 4.0 6.9 34.1 11.7 9.5 16.3 4.4 8.0 2 2 2 2 2 2 2 2 2 10 10 10 10 10 10 10 10 10 3.2 2 10 NA NA MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,072.95 1,006.34 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 107% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 101% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt % % B-71 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 5.57 3.65 0.11 U1/2 0.11 U1/2 0.11 U1/2 0.11 U1/2 0.11 U1/2 0.11 U1/2 0.11 U1/2 Instrument Conc. (µg/L) 5.57 3.65 0.11 0.11 0.11 0.11 0.11 0.11 0.11 RSD (%) 2.3 4.1 2.4 5.5 10.1 4.0 3.8 4.7 2.6 MDL (µg/L) 0.23 0.23 0.23 0.23 0.23 0.23 0.23 0.23 0.23 2.8 8.3 4.8 7.3 10.8 4.6 3.7 3.3 0.7 0.23 0.23 0.23 0.23 0.23 0.23 0.23 0.23 0.23 1 1 1 1 1 1 1 1 1 3.1 0.23 1 Pb Pb Pb Pb Pb Pb Pb Pb Pb 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Pb Pb Pb Pb Pb Pb Pb Pb Pb 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 5.83 3.01 0.11 0.11 0.11 0.11 0.11 0.11 0.11 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 5.83 3.01 0.11 0.11 0.11 0.11 0.11 0.11 0.11 Pb 1314-AES-M01-A 1 0.11 U1/2 0.11 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 10,000 10,000 500 500 Spike Conc. (µg/L) 501.07 489.26 Spike Recovery (%) 100% 98% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx 4.4 % 100.0 % B-72 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 3,734.82 3,440.89 2,145.97 1,342.52 983.89 562.12 361.49 247.84 198.88 Li Li Li Li Li Li Li Li Li 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Li Li Li Li Li Li Li Li Li 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 3,891.39 3,254.29 2,106.65 1,327.52 969.52 560.10 384.91 256.66 193.22 Li 1314-AES-M01-A 1 0.95 U1/2 Instrument Conc. (µg/L) 3,734.82 3,440.89 2,145.97 1,342.52 983.89 562.12 361.49 247.84 198.88 RSD (%) 0.5 1.1 0.6 1.1 0.7 1.1 1.6 5.8 8.7 MDL (µg/L) 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 ML (µg/L) 10 10 10 10 10 10 10 10 10 3,891.39 3,254.29 2,106.65 1,327.52 969.52 560.10 384.91 256.66 193.22 0.1 0.6 0.6 1.0 0.3 0.9 2.8 0.4 7.3 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 10 10 10 10 10 10 10 10 10 0.95 11.9 1.9 10 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 3,089.26 3,002.65 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 94% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 90% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 2.0 % 100.0 % B-73 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 Instrument Conc. (µg/L) 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 RSD (%) 13.6 11.0 6.3 1.5 7.5 24.0 9.5 10.4 19.1 Mn Mn Mn Mn Mn Mn Mn Mn Mn 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Mn Mn Mn Mn Mn Mn Mn Mn Mn 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Mn 1314-AES-M01-A 1 1.00 U1/2 1.00 Mean RSD Completeness 2 2 2 2 2 2 2 2 2 ML (µg/L) 10 10 10 10 10 10 10 10 10 2.7 6.2 8.3 16.4 9.1 9.5 3.9 13.6 3.9 2 2 2 2 2 2 2 2 2 10 10 10 10 10 10 10 10 10 15.9 2 10 NA NA MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,067.59 1,009.31 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 107% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 101% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt % % B-74 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 260.37 173.90 124.48 107.07 83.93 90.58 94.17 106.46 111.83 Mg Mg Mg Mg Mg Mg Mg Mg Mg 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Mg Mg Mg Mg Mg Mg Mg Mg Mg 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 278.80 167.09 117.86 94.85 76.25 85.55 92.57 98.45 112.96 Mg 1314-AES-M01-A 1 0.50 U1/2 Instrument Conc. (µg/L) 260.37 173.90 124.48 107.07 83.93 90.58 94.17 106.46 111.83 RSD (%) 2.1 3.0 0.2 1.5 9.8 1.1 2.9 3.7 8.1 278.80 167.09 117.86 94.85 76.25 85.55 92.57 98.45 112.96 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 1.2 7.5 6.3 1.9 5.4 1.1 4.7 7.7 2.0 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 12.1 1 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,151.75 1,061.06 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 103% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 94% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 3.9 % 100.0 % B-75 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 12,131.20 9,260.90 1,447.32 162.54 101.06 57.78 37.93 27.69 23.02 Mo Mo Mo Mo Mo Mo Mo Mo Mo 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Mo Mo Mo Mo Mo Mo Mo Mo Mo 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 12,757.70 9,373.69 1,590.47 136.02 93.51 58.34 41.91 31.10 28.32 Mo 1314-AES-M01-A 1 0.60 U1/2 Instrument Conc. (µg/L) 12,131.20 9,260.90 1,447.32 162.54 101.06 57.78 37.93 27.69 23.02 RSD (%) 0.5 1.8 0.3 1.3 1.1 0.5 3.8 2.1 2.5 MDL (µg/L) 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 12,757.70 9,373.69 1,590.47 136.02 93.51 58.34 41.91 31.10 28.32 1.7 1.6 0.7 1.5 2.2 0.7 0.1 2.9 7.8 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 5 5 5 5 5 5 5 5 5 0.60 13.5 1.2 5 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 2,469.74 2,543.67 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 102% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 95% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.8 % 100.0 % B-76 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 27.08 20.71 6.82 3.00 E 0.90 U1/2 0.90 U1/2 0.90 U1/2 0.90 U1/2 0.90 U1/2 Instrument Conc. (µg/L) 27.08 20.71 6.82 3.00 0.90 0.90 0.90 0.90 0.90 RSD (%) 1.7 3.6 4.2 5.8 17.3 9.8 13.9 9.3 10.3 MDL (µg/L) 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 4.0 8.9 6.9 6.1 11.7 5.7 14.3 8.2 9.9 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 5 5 5 5 5 5 5 5 5 10.8 1.8 5 Ni Ni Ni Ni Ni Ni Ni Ni Ni 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Ni Ni Ni Ni Ni Ni Ni Ni Ni 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 24.60 18.59 6.87 2.63 0.90 0.90 0.90 0.90 0.90 E U1/2 U1/2 U1/2 U1/2 U1/2 24.60 18.59 6.87 2.63 0.90 0.90 0.90 0.90 0.90 Ni 1314-AES-M01-A 1 0.90 U1/2 0.90 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,039.45 986.36 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 103% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 98% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 4.9 % 100.0 % B-77 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 248.44 113.29 37.56 8.58 E 4.67 E 1.85 U1/2 1.85 U1/2 1.85 U1/2 1.85 U1/2 Instrument Conc. (µg/L) 248.44 113.29 37.56 8.58 4.67 1.85 1.85 1.85 1.85 RSD (%) 2.9 6.0 2.5 3.5 2.3 7.5 12.5 9.9 12.6 MDL (µg/L) 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 ML (µg/L) 10 10 10 10 10 10 10 10 10 1.1 2.4 1.3 3.8 3.0 15.1 12.9 4.0 11.2 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 3.7 10 10 10 10 10 10 10 10 10 24.3 3.7 10 P P P P P P P P P 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 P P P P P P P P P 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 230.17 117.42 32.54 8.91 5.30 1.85 1.85 1.85 1.85 E E U1/2 U1/2 U1/2 U1/2 230.17 117.42 32.54 8.91 5.30 1.85 1.85 1.85 1.85 P 1314-AES-M01-A 1 1.85 U1/2 1.85 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,098.41 1,083.54 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 106% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 105% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 2.7 % 100.0 % B-78 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) K K K K K K K K K 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 10 10 10 1 1 1 1 1 1 Sample Conc. Qualifier (µg/L) 4,611,700.00 4,507,210.00 1,034,420.00 506,138.00 341,598.00 185,608.00 126,691.00 100,566.00 93,394.40 K K K K K K K K K 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 10 10 10 1 1 1 1 1 1 4,625,700.00 4,477,650.00 967,993.00 461,995.00 319,829.00 183,422.00 133,485.00 106,955.00 91,276.50 K 1314-AES-M01-A 1 2.07 Analyte Sample ID Dilution Factor E Instrument Conc. (µg/L) 461,170.00 450,721.00 103,442.00 506,138.00 341,598.00 185,608.00 126,691.00 100,566.00 93,394.40 RSD (%) 0.4 0.9 2.4 0.5 0.6 0.4 1.0 1.7 0.3 MDL (µg/L) 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 462,570.00 447,765.00 96,799.30 461,995.00 319,829.00 183,422.00 133,485.00 106,955.00 91,276.50 0.2 0.7 0.1 2.0 0.4 1.0 1.8 1.9 3.7 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 5 5 5 5 5 5 5 5 5 2.07 7.6 1.6 5 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 5 5 5 5 5 5 5 5 5 10,000 10,000 Spike Conc. (µg/L) 5,000 ######### 5,000 972,570.00 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 95% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 8/1/2012 13:34 8/1/2012 13:36 8/1/2012 13:37 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 92% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 8/1/2012 13:42 8/1/2012 13:44 8/1/2012 13:46 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.1 % 100.0 % B-79 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 3,640.00 2,570.00 226.00 68.70 37.70 19.30 10.50 7.70 7.77 Se Se Se Se Se Se Se Se Se 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Se Se Se Se Se Se Se Se Se 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 3,480.00 2,460.00 182.00 62.30 38.90 16.50 11.90 9.74 9.21 Se 1314-AES-M01-A 1 0.26 U1/2 Instrument Conc. (µg/L) 3,640.00 2,570.00 226.00 68.70 37.70 19.30 10.50 7.70 7.77 RSD (%) 1.7 0.9 1.4 2.5 1.9 1.7 1.1 4.4 2.7 MDL (µg/L) 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 3,480.00 2,460.00 182.00 62.30 38.90 16.50 11.90 9.74 9.21 1.4 1.8 1.5 0.6 5.2 1.2 1.2 2.1 5.0 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 2 2 2 2 2 2 2 2 2 0.26 2.1 0.52 2 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 694.83 661.07 Spike Recovery (%) 94% 96% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx 2.1 % 100.0 % B-80 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 22,047.60 19,551.90 18,312.50 16,217.20 13,979.20 11,617.30 10,535.20 9,863.63 8,682.18 Si Si Si Si Si Si Si Si Si 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Si Si Si Si Si Si Si Si Si 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 21,247.70 20,462.20 18,063.10 16,110.50 12,918.20 10,649.70 9,549.60 9,201.80 8,818.52 Si 1314-AES-M01-A 1 0.55 U1/2 Instrument Conc. (µg/L) 22,047.60 19,551.90 18,312.50 16,217.20 13,979.20 11,617.30 10,535.20 9,863.63 8,682.18 RSD (%) 0.8 1.4 0.5 0.4 1.5 0.8 0.3 2.4 0.9 MDL (µg/L) 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 21,247.70 20,462.20 18,063.10 16,110.50 12,918.20 10,649.70 9,549.60 9,201.80 8,818.52 0.3 1.1 0.6 1.0 0.3 0.6 3.0 0.8 2.6 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 5 5 5 5 5 5 5 5 5 0.55 10.2 1.1 5 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 19,271.80 18,988.60 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 96% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 93% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.1 % 100.0 % B-81 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Na Na Na Na Na Na Na Na Na 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 10 10 10 1 1 1 1 1 1 Sample Conc. Qualifier (µg/L) 1,325,900.00 1,297,570.00 1,028,840.00 693,822.00 495,241.00 257,272.00 134,140.00 66,209.90 30,458.10 Na Na Na Na Na Na Na Na Na 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 10 10 10 1 1 1 1 1 1 1,309,910.00 1,259,620.00 967,339.00 639,973.00 457,791.00 242,555.00 127,738.00 64,231.70 35,922.20 Na 1314-AES-M01-A 1 1.25 Analyte Sample ID Dilution Factor U1/2 Instrument Conc. (µg/L) 132,590.00 129,757.00 102,884.00 693,822.00 495,241.00 257,272.00 134,140.00 66,209.90 30,458.10 RSD (%) 0.0 1.1 0.5 0.3 1.0 1.0 1.1 1.4 0.1 MDL (µg/L) 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 ML (µg/L) 10 10 10 10 10 10 10 10 10 130,991.00 125,962.00 96,733.90 639,973.00 457,791.00 242,555.00 127,738.00 64,231.70 35,922.20 0.2 0.1 0.4 0.6 0.4 0.4 1.9 1.6 3.9 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 10 10 10 10 10 10 10 10 10 1.25 11.1 2.5 10 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 Spike Conc. (µg/L) 5,000 ######### 5,000 971,630.00 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 90% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 8/1/2012 13:34 8/1/2012 13:36 8/1/2012 13:37 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 86% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 8/1/2012 13:42 8/1/2012 13:44 8/1/2012 13:46 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 0.9 % 100.0 % B-82 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 14,930.70 13,578.00 8,486.42 6,903.40 6,900.82 7,773.97 8,165.26 8,478.20 8,791.75 Sr Sr Sr Sr Sr Sr Sr Sr Sr 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Sr Sr Sr Sr Sr Sr Sr Sr Sr 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 15,001.80 12,947.30 8,278.21 6,812.58 6,806.41 7,548.79 8,186.20 8,324.63 8,842.38 Sr 1314-AES-M01-A 1 0.50 U1/2 Instrument Conc. (µg/L) 14,930.70 13,578.00 8,486.42 6,903.40 6,900.82 7,773.97 8,165.26 8,478.20 8,791.75 RSD (%) 2.3 1.4 0.5 0.9 1.7 1.6 0.8 1.2 1.7 15,001.80 12,947.30 8,278.21 6,812.58 6,806.41 7,548.79 8,186.20 8,324.63 8,842.38 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 0.9 1.0 0.4 1.3 0.7 1.5 2.4 2.1 2.1 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 12.4 1 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 9,592.13 9,333.36 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 111% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 106% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.4 % 100.0 % B-83 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) S S S S S S S S S 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 10 10 10 10 10 1 1 1 1 Sample Conc. Qualifier (µg/L) 4,058,400.00 4,139,550.00 2,916,400.00 1,590,030.00 1,064,320.00 672,955.00 545,355.00 504,583.00 498,482.00 S S S S S S S S S 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 10 10 10 10 10 1 1 1 1 4,002,400.00 4,110,210.00 2,842,140.00 1,462,120.00 974,475.00 649,092.00 548,625.00 528,684.00 498,197.00 S 1314-AES-M01-A 1 3.40 Analyte Sample ID Dilution Factor U1/2 Instrument Conc. (µg/L) 405,840.00 413,955.00 291,640.00 159,003.00 106,432.00 672,955.00 545,355.00 504,583.00 498,482.00 RSD (%) 0.8 1.5 0.4 0.3 0.9 0.3 0.9 1.9 0.2 MDL (µg/L) 6.8 6.8 6.8 6.8 6.8 6.8 6.8 6.8 6.8 ML (µg/L) 20 20 20 20 20 20 20 20 20 400,240.00 411,021.00 284,214.00 146,212.00 97,447.50 649,092.00 548,625.00 528,684.00 498,197.00 0.1 0.7 0.6 1.0 0.3 0.9 1.6 2.1 3.7 6.8 6.8 6.8 6.8 6.8 6.8 6.8 6.8 6.8 20 20 20 20 20 20 20 20 20 3.40 10.9 6.8 20 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 Spike Conc. (µg/L) 5,000 ######### 5,000 ######### Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 88% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 8/1/2012 13:34 8/1/2012 13:36 8/1/2012 13:37 8/1/2012 13:39 8/1/2012 13:41 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 85% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 8/1/2012 13:42 8/1/2012 13:44 8/1/2012 13:46 8/1/2012 13:47 8/1/2012 13:49 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.0 % 100.0 % B-84 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 2.01 1.69 E 0.59 E 0.25 U1/2 0.25 U1/2 0.25 U1/2 0.25 U1/2 0.25 U1/2 0.25 U1/2 Instrument Conc. (µg/L) 2.01 1.69 0.59 0.25 0.25 0.25 0.25 0.25 0.25 RSD (%) 7.4 1.5 1.0 3.1 3.3 1.3 7.8 7.7 6.0 MDL (µg/L) 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) Tl Tl Tl Tl Tl Tl Tl Tl Tl 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Tl Tl Tl Tl Tl Tl Tl Tl Tl 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 2.29 1.45 0.56 0.25 0.25 0.25 0.25 0.25 0.25 E E U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 2.29 1.45 0.56 0.25 0.25 0.25 0.25 0.25 0.25 1.7 2.2 2.0 0.9 2.7 1.7 5.8 2.4 4.9 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 2 2 2 2 2 2 2 2 2 Tl 1314-AES-M01-A 1 0.25 U1/2 0.25 2.9 0.51 2 Mean RSD Completeness 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 491.23 485.95 Spike Recovery (%) 98% 97% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx 4.5 % 100.0 % B-85 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 2.11 1.79 E 1.51 E 0.78 E 0.35 U1/2 0.35 U1/2 0.35 U1/2 0.35 U1/2 0.35 U1/2 Instrument Conc. (µg/L) 2.11 1.79 1.51 0.78 0.35 0.35 0.35 0.35 0.35 RSD (%) 2.9 0.9 2.7 0.2 0.8 2.0 4.7 4.4 7.6 MDL (µg/L) 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) Sn Sn Sn Sn Sn Sn Sn Sn Sn 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Sn Sn Sn Sn Sn Sn Sn Sn Sn 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 2.10 1.60 1.46 0.73 0.35 0.35 0.35 0.35 0.35 E E E U1/2 U1/2 U1/2 U1/2 U1/2 2.10 1.60 1.46 0.73 0.35 0.35 0.35 0.35 0.35 2.0 2.3 1.5 2.1 2.1 6.4 4.0 2.3 3.8 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 2 2 2 2 2 2 2 2 2 Sn 1314-AES-M01-A 1 0.35 U1/2 0.35 6.3 0.7 2 Mean RSD Completeness 2 2 2 2 2 2 2 2 2 10,000 10,000 500 500 Spike Conc. (µg/L) 512.85 500.37 Spike Recovery (%) 102% 100% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx 2.4 % 100.0 % B-86 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 1.00 U1/2 Instrument Conc. (µg/L) 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 RSD (%) 11.8 19.9 12.9 8.4 5.1 4.8 17.2 28.1 6.5 Ti Ti Ti Ti Ti Ti Ti Ti Ti 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Ti Ti Ti Ti Ti Ti Ti Ti Ti 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Ti 1314-AES-M01-A 1 1.00 U1/2 1.00 Mean RSD Completeness 2 2 2 2 2 2 2 2 2 ML (µg/L) 10 10 10 10 10 10 10 10 10 12.3 9.4 14.0 11.1 4.4 21.1 2.0 4.7 17.8 2 2 2 2 2 2 2 2 2 10 10 10 10 10 10 10 10 10 26.6 2 10 NA NA MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,132.33 1,064.71 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 113% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 106% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt % % B-87 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 0.15 U1/2 0.15 U1/2 0.15 U1/2 0.15 U1/2 0.15 U1/2 0.15 U1/2 0.15 U1/2 0.15 U1/2 0.15 U1/2 Instrument Conc. (µg/L) 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 RSD (%) 26.6 4.3 4.5 4.5 8.6 22.6 11.2 5.6 24.8 MDL (µg/L) 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) U U U U U U U U U 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 U U U U U U U U U 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 19.8 4.1 2.1 3.4 15.9 24.6 18.6 16.8 36.9 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 1 1 1 1 1 1 1 1 1 U 1314-AES-M01-A 1 0.15 U1/2 0.15 30.8 0.3 1 Mean RSD Completeness NA NA 1 1 1 1 1 1 1 1 1 10,000 10,000 500 500 Spike Conc. (µg/L) 496.28 488.44 Spike Recovery (%) 99% 98% Instrument Date/Time Filename VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 12:25 8/10/2012 12:30 8/10/2012 12:35 8/10/2012 12:40 8/10/2012 12:45 8/10/2012 12:50 8/10/2012 12:55 8/10/2012 13:00 8/10/2012 13:04 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS VU ICP-MS 8/10/2012 13:10 8/10/2012 13:15 8/10/2012 13:20 8/10/2012 13:25 8/10/2012 13:30 8/10/2012 13:34 8/10/2012 13:39 8/10/2012 13:44 8/10/2012 13:49 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx VU ICP-MS 8/10/2012 12:20 C:\ICP-MS Rpt File 1314 AES-PR (orig).xlsx % % B-88 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 570.05 639.39 458.46 255.13 183.27 148.12 134.01 126.83 120.90 V V V V V V V V V 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 V V V V V V V V V 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 581.63 645.99 437.57 251.90 184.19 134.25 124.03 119.61 117.24 V 1314-AES-M01-A 1 0.75 U1/2 Instrument Conc. (µg/L) 570.05 639.39 458.46 255.13 183.27 148.12 134.01 126.83 120.90 RSD (%) 1.1 1.1 0.4 0.7 0.9 0.4 0.5 1.9 1.3 MDL (µg/L) 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 581.63 645.99 437.57 251.90 184.19 134.25 124.03 119.61 117.24 0.8 1.8 0.6 1.4 0.4 1.1 2.7 2.5 3.2 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 5 5 5 5 5 5 5 5 5 0.75 2.6 1.5 5 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 5 5 5 5 5 5 5 5 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,516.28 1,448.44 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 106% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 101% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 1.3 % 100.0 % B-89 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 30.31 12.62 9.19 8.60 7.58 4.81 E 5.37 6.31 6.54 Zn Zn Zn Zn Zn Zn Zn Zn Zn 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Zn Zn Zn Zn Zn Zn Zn Zn Zn 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 28.18 12.53 8.76 8.56 7.61 5.01 4.90 5.67 6.17 Zn 1314-AES-M01-A 1 0.50 E U1/2 Instrument Conc. (µg/L) 30.31 12.62 9.19 8.60 7.58 4.81 5.37 6.31 6.54 RSD (%) 5.2 4.2 3.8 3.4 7.7 1.5 1.4 2.0 4.0 28.18 12.53 8.76 8.56 7.61 5.01 4.90 5.67 6.17 0.50 Mean RSD Completeness MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) ML (µg/L) 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 1.4 5.3 6.4 5.5 6.0 7.8 6.3 4.4 1.4 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 5 5 5 7.7 1 5 10,000 10,000 1,000 1,000 Spike Conc. (µg/L) 1,093.75 1,106.65 Spike Recovery (%) Instrument Date/Time Filename VU ICP-OES VU ICP-OES 108% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 12:57 7/31/2012 12:59 7/31/2012 13:00 7/31/2012 13:02 7/31/2012 13:04 7/31/2012 13:05 7/31/2012 13:07 7/31/2012 13:09 7/31/2012 13:10 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES VU ICP-OES 110% VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES VU ICP-OES 7/31/2012 13:12 7/31/2012 13:14 7/31/2012 13:15 7/31/2012 13:17 7/31/2012 13:18 7/31/2012 13:20 7/31/2012 13:22 7/31/2012 13:23 7/31/2012 13:25 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt VU ICP-OES 7/31/2012 12:56 C:\ICP-OES Rpt File 1314 AES-PR VU (orig).txt 4.4 % 100.0 % B-90 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 10,750.00 8,122.00 3,465.00 2,803.00 2,320.00 1,898.00 1,972.00 2,032.00 1,864.00 DIC DIC DIC DIC DIC DIC DIC DIC DIC 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 DIC DIC DIC DIC DIC DIC DIC DIC DIC 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 11,370.00 8,572.00 3,848.00 2,785.00 2,523.00 2,039.00 2,193.00 1,838.00 1,756.00 DIC 1314-AES-M01-A 1 65.00 U1/2 Instrument Conc. (µg/L) 10,750.00 8,122.00 3,465.00 2,803.00 2,320.00 1,898.00 1,972.00 2,032.00 1,864.00 RSD (%) 2.8 2.8 4.1 1.8 2.7 2.2 1.9 3.5 5.3 MDL (µg/L) 130 130 130 130 130 130 130 130 130 ML (µg/L) 500 500 500 500 500 500 500 500 500 11,370.00 8,572.00 3,848.00 2,785.00 2,523.00 2,039.00 2,193.00 1,838.00 1,756.00 0.4 0.7 3.3 2.1 3.4 2.1 2.2 4.1 1.9 130 130 130 130 130 130 130 130 130 500 500 500 500 500 500 500 500 500 65.00 10.5 130 500 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 100,000 100,000 500 500 Spike Conc. (µg/L) 3,944.00 4,308.00 Spike Recovery (%) 96% 92% Instrument Date/Time Filename VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC 8/27/2012 13:12 8/27/2012 13:22 8/27/2012 13:31 8/27/2012 13:41 8/27/2012 13:50 8/27/2012 14:00 8/27/2012 14:09 8/27/2012 14:19 8/27/2012 14:28 C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC 8/27/2012 14:38 8/27/2012 14:48 8/27/2012 14:57 8/27/2012 15:07 8/27/2012 15:17 8/27/2012 15:26 8/27/2012 15:36 8/27/2012 15:45 8/27/2012 15:55 C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt VU TOC 8/27/2012 13:02 C:\DIC-DOC 1314 AES-PR VU (orig).txt 2.6 % 100.0 % B-91 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 52,220.00 40,990.00 11,840.00 5,473.00 4,734.00 3,771.00 3,210.00 3,067.00 2,835.00 DOC DOC DOC DOC DOC DOC DOC DOC DOC 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 DOC DOC DOC DOC DOC DOC DOC DOC DOC 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 53,080.00 36,900.00 10,678.00 4,603.00 3,781.00 3,543.00 3,345.00 3,038.00 2,712.00 DOC 1314-AES-M01-A 1 85.00 U1/2 Instrument Conc. (µg/L) 52,220.00 40,990.00 11,840.00 5,473.00 4,734.00 3,771.00 3,210.00 3,067.00 2,835.00 RSD (%) 2.0 0.2 0.7 0.5 0.4 2.1 0.5 0.2 0.4 MDL (µg/L) 170 170 170 170 170 170 170 170 170 ML (µg/L) 500 500 500 500 500 500 500 500 500 53,080.00 36,900.00 10,678.00 4,603.00 3,781.00 3,543.00 3,345.00 3,038.00 2,712.00 3.0 1.1 0.2 1.0 0.3 1.6 0.8 0.6 0.2 170 170 170 170 170 170 170 170 170 500 500 500 500 500 500 500 500 500 85.00 13.9 170 500 Mean RSD Completeness Spike Sol'n Conc. Volume (µg/L) (µL) 100,000 100,000 500 500 Spike Conc. (µg/L) 12,310.00 11,132.00 Spike Recovery (%) 94% 91% Instrument Date/Time Filename VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC 8/28/2012 14:49 8/28/2012 14:56 8/28/2012 15:04 8/28/2012 15:13 8/28/2012 15:22 8/28/2012 15:31 8/28/2012 15:40 8/28/2012 15:49 8/28/2012 15:59 C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC VU TOC 8/28/2012 16:08 8/28/2012 16:15 8/28/2012 16:22 8/28/2012 16:31 8/28/2012 16:38 8/28/2012 16:45 8/28/2012 16:55 8/28/2012 17:04 8/28/2012 17:13 C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt C:\DIC-DOC 1314 AES-PR VU (orig).txt VU TOC 8/28/2012 14:40 C:\DIC-DOC 1314 AES-PR VU (orig).txt 0.9 % 100.0 % B-92 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 11,129.90 5,996.50 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 8.71 U1/2 Instrument Conc. (µg/L) 11,129.90 5,996.50 8.71 8.71 8.71 8.71 8.71 8.71 8.71 Br Br Br Br Br Br Br Br Br 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 Br Br Br Br Br Br Br Br Br 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 10,408.60 5,193.10 8.71 8.71 8.71 8.71 8.71 8.71 8.71 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 10,408.60 5,193.10 8.71 8.71 8.71 8.71 8.71 8.71 8.71 Br 1314-AES-M01-A 1 8.71 U1/2 8.71 Mean RSD Completeness RSD (%) NA NA MDL (µg/L) 17 17 17 17 17 17 17 17 17 ML (µg/L) 50 50 50 50 50 50 50 50 50 17 17 17 17 17 17 17 17 17 50 50 50 50 50 50 50 50 50 17 50 Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/28/2012 19:41 8/28/2012 19:54 8/28/2012 20:06 8/28/2012 20:18 8/28/2012 20:31 8/28/2012 20:43 8/28/2012 20:55 8/28/2012 21:08 8/28/2012 21:20 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/28/2012 21:33 8/28/2012 21:45 8/28/2012 21:57 8/28/2012 22:10 8/28/2012 22:22 8/28/2012 22:35 8/28/2012 22:47 8/28/2012 22:59 8/28/2012 23:12 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC 8/28/2012 19:29 C:\IC 1313-1314 AES-PR (orig).xlsx % % B-93 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Cl Cl Cl Cl Cl Cl Cl Cl Cl 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 250 250 25 25 25 1 1 1 1 Sample Conc. Qualifier (µg/L) 12,099,766.50 5,340,889.10 484,118.00 99,096.30 54,003.20 22,899.60 11,184.70 7,108.80 6,551.10 Cl Cl Cl Cl Cl Cl Cl Cl Cl 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 250 250 25 25 25 1 1 1 1 11,873,010.40 4,678,574.90 533,402.60 89,223.70 56,725.70 24,480.70 10,463.60 5,637.50 4,786.10 Cl 1314-AES-M01-A 1 Analyte Sample ID Dilution Factor 3.25 U1/2 Instrument Conc. (µg/L) 48,399.07 21,363.56 19,364.72 3,963.85 2,160.13 22,899.60 11,184.70 7,108.80 6,551.10 MDL (µg/L) 6.5 6.5 6.5 6.5 6.5 6.5 6.5 6.5 6.5 ML (µg/L) 20 20 20 20 20 20 20 20 20 47,492.04 18,714.30 21,336.10 3,568.95 2,269.03 24,480.70 10,463.60 5,637.50 4,786.10 6.5 6.5 6.5 6.5 6.5 6.5 6.5 6.5 6.5 20 20 20 20 20 20 20 20 20 3.25 6.5 20 Mean RSD Completeness RSD (%) NA NA Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/30/2012 11:48 8/30/2012 11:58 8/29/2012 0:14 8/29/2012 0:26 8/29/2012 0:39 8/28/2012 20:43 8/28/2012 20:55 8/28/2012 21:08 8/28/2012 21:20 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/30/2012 13:14 8/30/2012 13:24 8/29/2012 2:05 8/29/2012 2:18 8/29/2012 2:30 8/28/2012 22:35 8/28/2012 22:47 8/28/2012 22:59 8/28/2012 23:12 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC 8/28/2012 19:29 C:\IC 1313-1314 AES-PR (orig).xlsx % % B-94 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 91,674.00 61,792.40 24,099.20 8,332.10 5,484.80 3,292.30 3,157.20 2,522.60 2,393.10 F F F F F F F F F 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 25 25 25 1 1 1 1 1 1 F F F F F F F F F 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 25 25 25 1 1 1 1 1 1 82,413.40 66,198.50 18,552.90 7,376.00 5,169.70 3,211.30 3,012.10 2,758.30 2,624.00 F 1314-AES-M01-A 1 3.53 U1/2 Instrument Conc. (µg/L) 3,666.96 2,471.70 963.97 8,332.10 5,484.80 3,292.30 3,157.20 2,522.60 2,393.10 7 7 7 7 7 7 7 7 7 ML (µg/L) 20 20 20 20 20 20 20 20 20 3,296.54 2,647.94 742.12 7,376.00 5,169.70 3,211.30 3,012.10 2,758.30 2,624.00 7 7 7 7 7 7 7 7 7 20 20 20 20 20 20 20 20 20 3.53 7 20 Mean RSD Completeness RSD (%) NA NA MDL (µg/L) Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/28/2012 23:49 8/29/2012 0:01 8/29/2012 0:14 8/28/2012 20:18 8/28/2012 20:31 8/28/2012 20:43 8/28/2012 20:55 8/28/2012 21:08 8/28/2012 21:20 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/29/2012 1:41 8/29/2012 1:53 8/29/2012 2:05 8/28/2012 22:10 8/28/2012 22:22 8/28/2012 22:35 8/28/2012 22:47 8/28/2012 22:59 8/28/2012 23:12 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC 8/28/2012 19:29 C:\IC 1313-1314 AES-PR (orig).xlsx % % B-95 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 563,453.60 356,426.40 75,579.00 17,943.40 8,176.20 3,647.00 2,199.00 1,441.80 1,236.20 NO3 NO3 NO3 NO3 NO3 NO3 NO3 NO3 NO3 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 25 25 1 1 1 1 1 1 1 NO3 NO3 NO3 NO3 NO3 NO3 NO3 NO3 NO3 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 25 25 1 1 1 1 1 1 1 517,620.70 315,632.60 54,445.10 14,248.30 7,192.40 3,587.90 2,328.00 1,431.30 1,165.10 NO3 1314-AES-M01-A 1 12.92 U1/2 Instrument Conc. (µg/L) 22,538.14 14,257.06 75,579.00 17,943.40 8,176.20 3,647.00 2,199.00 1,441.80 1,236.20 MDL (µg/L) 26 26 26 26 26 26 26 26 26 ML (µg/L) 100 100 100 100 100 100 100 100 100 20,704.83 12,625.30 54,445.10 14,248.30 7,192.40 3,587.90 2,328.00 1,431.30 1,165.10 26 26 26 26 26 26 26 26 26 100 100 100 100 100 100 100 100 100 12.92 26 100 Mean RSD Completeness RSD (%) NA NA Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/28/2012 23:49 8/29/2012 0:01 8/28/2012 20:06 8/28/2012 20:18 8/28/2012 20:31 8/28/2012 20:43 8/28/2012 20:55 8/28/2012 21:08 8/28/2012 21:20 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/29/2012 1:41 8/29/2012 1:53 8/28/2012 21:57 8/28/2012 22:10 8/28/2012 22:22 8/28/2012 22:35 8/28/2012 22:47 8/28/2012 22:59 8/28/2012 23:12 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC 8/28/2012 19:29 C:\IC 1313-1314 AES-PR (orig).xlsx % % B-96 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 9.16 U1/2 Instrument Conc. (µg/L) 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 RSD (%) MDL (µg/L) 18 18 18 18 18 18 18 18 18 ML (µg/L) 50 50 50 50 50 50 50 50 50 NO2 NO2 NO2 NO2 NO2 NO2 NO2 NO2 NO2 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 NO2 NO2 NO2 NO2 NO2 NO2 NO2 NO2 NO2 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 18 18 18 18 18 18 18 18 18 50 50 50 50 50 50 50 50 50 NO2 1314-AES-M01-A 1 9.16 U1/2 9.16 18 50 Mean RSD Completeness NA NA Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/28/2012 19:41 8/28/2012 19:54 8/28/2012 20:06 8/28/2012 20:18 8/28/2012 20:31 8/28/2012 20:43 8/28/2012 20:55 8/28/2012 21:08 8/28/2012 21:20 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/28/2012 21:33 8/28/2012 21:45 8/28/2012 21:57 8/28/2012 22:10 8/28/2012 22:22 8/28/2012 22:35 8/28/2012 22:47 8/28/2012 22:59 8/28/2012 23:12 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC 8/28/2012 19:29 C:\IC 1313-1314 AES-PR (orig).xlsx % % B-97 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) Analyte Sample ID Dilution Factor Sample Conc. Qualifier (µg/L) 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 11.83 U1/2 Instrument Conc. (µg/L) 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 RSD (%) MDL (µg/L) 24 24 24 24 24 24 24 24 24 ML (µg/L) 100 100 100 100 100 100 100 100 100 PO4 PO4 PO4 PO4 PO4 PO4 PO4 PO4 PO4 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 1 1 1 1 1 1 1 1 1 PO4 PO4 PO4 PO4 PO4 PO4 PO4 PO4 PO4 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 1 1 1 1 1 1 1 1 1 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 U1/2 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 11.83 24 24 24 24 24 24 24 24 24 100 100 100 100 100 100 100 100 100 PO4 1314-AES-M01-A 1 11.83 U1/2 11.83 24 100 Mean RSD Completeness NA NA Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/28/2012 19:41 8/28/2012 19:54 8/28/2012 20:06 8/28/2012 20:18 8/28/2012 20:31 8/28/2012 20:43 8/28/2012 20:55 8/28/2012 21:08 8/28/2012 21:20 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/28/2012 21:33 8/28/2012 21:45 8/28/2012 21:57 8/28/2012 22:10 8/28/2012 22:22 8/28/2012 22:35 8/28/2012 22:47 8/28/2012 22:59 8/28/2012 23:12 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC 8/28/2012 19:29 C:\IC 1313-1314 AES-PR (orig).xlsx % % B-98 QA-QC REPORT Client EPA Region 2 Test EPA Method 1314 Material AGREMAX (material code AES) SO4 SO4 SO4 SO4 SO4 SO4 SO4 SO4 SO4 1314-AES-T01-A 1314-AES-T02-A 1314-AES-T03-A 1314-AES-T04-A 1314-AES-T05-A 1314-AES-T06-A 1314-AES-T07-A 1314-AES-T08-A 1314-AES-T09-A 250 250 250 25 25 25 25 25 25 Sample Conc. Qualifier (µg/L) 20,931,741.30 19,326,596.70 12,201,722.70 5,451,370.60 3,625,686.50 2,161,699.00 1,738,522.40 1,598,220.90 1,554,802.60 SO4 SO4 SO4 SO4 SO4 SO4 SO4 SO4 SO4 1314-AES-T01-B 1314-AES-T02-B 1314-AES-T03-B 1314-AES-T04-B 1314-AES-T05-B 1314-AES-T06-B 1314-AES-T07-B 1314-AES-T08-B 1314-AES-T09-B 250 250 250 25 25 25 25 25 25 20,510,698.50 19,761,405.30 11,964,245.90 4,659,422.60 3,330,544.80 2,111,934.20 1,737,952.00 1,621,273.80 1,560,392.00 SO4 1314-AES-M01-A 1 Analyte Sample ID Dilution Factor 10.39 U1/2 Instrument Conc. (µg/L) 83,726.97 77,306.39 48,806.89 218,054.82 145,027.46 86,467.96 69,540.90 63,928.84 62,192.10 MDL (µg/L) 21 21 21 21 21 21 21 21 21 ML (µg/L) 100 100 100 100 100 100 100 100 100 82,042.79 79,045.62 47,856.98 186,376.90 133,221.79 84,477.37 69,518.08 64,850.95 62,415.68 21 21 21 21 21 21 21 21 21 100 100 100 100 100 100 100 100 100 10.39 21 100 Mean RSD Completeness RSD (%) NA NA Spike Sol'n Conc. Volume (µg/L) (µL) Spike Conc. (µg/L) Spike Recovery (%) Note: IC analysis is based on single measurement of an analytical solution. Therefore, RSDs are not available. In addition, matrix spikes are not conducted for IC analyses so that spike recoveries are not available. Instrument Date/Time Filename VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/30/2012 11:48 8/30/2012 11:58 8/30/2012 12:07 8/29/2012 0:26 8/29/2012 0:39 8/29/2012 0:51 8/29/2012 1:03 8/29/2012 1:16 8/29/2012 1:28 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC VU IC 8/30/2012 13:14 8/30/2012 13:24 8/30/2012 13:33 8/29/2012 2:18 8/29/2012 2:30 8/29/2012 2:43 8/29/2012 2:55 8/29/2012 3:07 8/29/2012 3:20 C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx C:\IC 1313-1314 AES-PR (orig).xlsx VU IC 8/28/2012 19:29 C:\IC 1313-1314 AES-PR (orig).xlsx % % B-99