Pilot Study of High Performance Air Filtration for Classrooms Applications Final Report Prepared by: South Coast Air Quality Management District (AQMD) 21865 Copley Dr, Diamond Bar, CA 91765 IQAir North America 10440 Ontiveros Place, Santa Fe Springs, CA 90670 ABSTRACT A pilot study was conducted between April and December 2008 to investigate the effectiveness of three different air purification systems in reducing the exposure of children to air contaminants inside nine classrooms at three Southern California schools (three classrooms per school). Two of them, Del Amo Elementary and Dominguez Elementary, are part of the Los Angeles Unified School District (LAUSD), while the third school, Hudson Elementary, is part of the Long Beach Unified School District (LBUSD). Continuous and integrated measurements were conducted to monitor the indoor and outdoor concentrations of the following species: ultrafine particles (UFP), particulate matter mass (both PM2.5 and PM10), black carbon (BC), and volatile organic compounds (VOCs). An HVAC-based high-performance panel filter (HP-PF), a registerbased air purifier (RS), and a standalone system (SA) were tested alone and in different combinations for their ability to remove the monitored pollutants from the indoor air. Overall, the coupling between a register system and a high-performance panel filter (RS + HP-PF) was the most effective solution for reducing the indoor concentrations of BC, UFP, and PM2.5, with study average removal efficiencies varying from 87 to 96%. When using a HP-PF alone, reductions close to 90% were also obtained. Due to re-suspension of dust and other relatively large particles from common indoor activities such as walking and cleaning, the removal performance of PM10 was lower than that of other particle measurements (68% when using a RS + HP-PF combination). In all cases, air quality conditions were improved substantially with respect to the corresponding baseline (pre-existing) conditions, when removal efficiencies for the different particulate pollutants varied between 20% and 50%. Data obtained from the analysis of canister samples collected at Dominguez elementary showed that the total VOC removal performance of the register system (RS) was 28%. These values were substantially higher for the standalone unit (SA) operated with and without the use of the HVAC system (58 and 86%, respectively). Because gas-absorbing media may be subject to saturation after experiencing high short-term concentrations, the effectiveness, lifetime, costs, benefits, and maintenance of the gas removal systems tested in this pilot study must be further assessed before conclusions and recommendations can be made. i TABLE OF CONTENTS   INTRODUCTION o Background o Objectives and Study Design 1 1 METHODS o Schools and Classrooms Characteristics o Air Purification Solutions  High-performance panel filter (HP-PF)  Register system (RS)  Standalone system (SA) o In-classroom configurations o Indoor and outdoor measurements 3 5 6 8 9 10 12 RESULTS AND DISCUSSION o Removal of PM and other particle species o Impact on the HVAC system airflow o Removal of VOCs 14 23 24  ACKNOWLEDGEMENTS 26  REFERENCES 27  APPENDIX A 28  APPENDIX B 46  ii INTRODUCTION Background Numerous epidemiological and toxicological studies have found positive associations between exposure to atmospheric particulate matter (PM) and adverse health effects (Pope and Dockery, 2006; Environmental Protection Agency Integrated Science Assessments, 2009). Although air quality standards have been established for outdoor ambient environments, a significant portion of human exposures to PM occurs indoors, where people spend around 85-90% of their time. Hence, it is important to understand and reduce the sources of both indoor and outdoor PM. Indoor PM consists of outdoor particles that have infiltrated indoors, particles emitted indoors (primary), and particles formed indoors (secondary) from precursors emitted both indoors and outdoors. Children are regarded as particularly susceptible to potential health hazards related to PM exposure, which include asthma, lung inflammation, allergies and other types of respiratory and cardiovascular problems. School-aged children spend approximately 30% of their day in classrooms. For this reason, minimizing the concentration of PM (as well as that of other air contaminants) inside classrooms is important, especially at schools located in close proximity to roadways and other substantial sources of air pollution. One approach is the installation of panel filters inside the Heating, Ventilating, and Air Conditioning (HVAC) system. Common medium performance filters with a Minimum Performance Reporting Value (MERV) of 7 (those installed in most commercial buildings) remove only a small fraction of the particles with aerodynamic diameters lower than 0.3 µm, although higher removal efficiencies are generally achieved for larger particles. Diesel particulate matter, which is considered an air toxic, generally consists of particles less than 0.3 µm. New evidence also suggests that ultrafine particles, less than 0.1 µm by definition, have harmful health effects beyond those caused by particle mass. Filtration in classrooms presents some unique challenges. The older HVAC systems that exist in older schools were not designed with air filtration in mind. The classroom is a noise sensitive environment, so filtration systems must meet strict decibel limits when in operation. Classrooms often have high ventilation rates with doors and windows that are frequently open to outside air. Finally, classrooms are large, densely occupied spaces with a lot of activity that can lead to indoor generation of particles and other pollutants. Objectives and Study Design The objective of this pilot study was to investigate the effectiveness of three different air purification systems/solutions in reducing the exposure of children to outdoor-infiltrated and indoor-generated air contaminants inside nine classrooms at three Southern California schools. To this end, the South Coast Air Quality Management District (SCAQMD; 21865 Copley Dr, Diamond Bar, CA 91765) worked in close collaboration with IQAir (IQAir North America, 10440 Ontiveros Place, Santa Fe Springs, CA 90670), a company that specializes in air purification solutions, and Thermal Comfort Systems (Thermal Comfort Systems Inc., 8038 Andasol Ave., Northridge, CA 91325), an HVAC contractor. Of particular interest was the removal of various sizes and types of particulate matter, especially the smaller sizes associated with diesel engine 1 exhaust. Solutions for removing gaseous air contaminants that may be air toxics or cause odors were also examined. The types of pollutants for which the performance of the installed systems were tested are described below: - Ultra-fine particles (UFPs; particles with an aerodynamic diameter less than 0.1 µm): UFP are primarily produced from the combustion of fossil fuels (e.g. motor-vehicle emissions). Recent health studies suggest that UFPs are more toxic than fine particles, possibly due to their chemical composition and their ability to penetrate cell walls, enter the blood stream, and translocate to organs throughout the body. UFP are currently unregulated in the United States. - Fine PM (PM2.5; particles with an aerodynamic diameter less than 2.5 µm): Sources of PM2.5 include emissions from motor vehicles, power plants, residential wood burning, forest fires, agricultural burning, and other combustion activities. Fine particles have well established health effects, including multiple adverse respiratory and cardiovascular outcomes. PM2.5 is a U.S. Environmental Protection Agency (U.S. EPA) criteria pollutant for which there exist National Ambient Air Quality Standards (NAAQS). - PM10 (particles with an aerodynamic diameter less than 10 µm): PM10 includes all PM2.5 particles, but also larger particles between 2.5 and 10 µm in diameter. Sources of these coarse particles include crushing or grinding operations, re-suspension of dust from vehicles traveling on roads, and other mechanical processes. PM10 is also a U.S. Environmental Protection Agency (U.S. EPA) criteria pollutant and also has associated National Ambient Air Quality Standards (NAAQS). - Black Carbon (BC; sometimes referred to as soot; related closely to elemental carbon): BC is a component of PM and is formed through the incomplete combustion of fossil fuels and biomass, and is emitted from both natural and anthropogenic sources. Most atmospheric BC is in the fine or ultra-fine particle size ranges. The majority of BC in Southern California comes from diesel particulate matter (DPM) emissions. DPM is considered an air toxic by the State of California, and the SCAQMD has recently estimated that DPM accounts for more than 80% of the total cancer risk from air toxics in the South Coast Air Basin (MATES III Study, 2008). - Volatile Organic Compounds (VOCs): these gases are emitted by a variety of evaporative processes and combustion sources, including paints, cleaning supplies, pesticides, building materials, household products, refineries, and mobile sources. Given some of the indoor sources, concentrations of many VOCs may be much higher indoors than outdoors (Jia et al., 2007; Bruno et al., 2008). Gasoline and diesel fuels are also important sources of VOCs. Exposure to many of these organic contaminants has also been associated with a wide array of toxic health effects. 2 METHODS Schools and Classrooms Characteristics Three elementary schools (all located in Southern Los Angeles County in the Carson-Long Beach area) were selected for this pilot study. Two of them, Del Amo Elementary and Dominguez Elementary, are part of the Los Angeles Unified School District (LAUSD), while the third school, Hudson Elementary, is part of the Long Beach Unified School District (LBUSD). All three schools are in close proximity to at least three large refineries and several heavily trafficked highways and freeways including the I-110, I-405, I-710, and CA-103 (Figure 1). The Los Angeles and Long Beach Port complexes and the Union Pacific Railroad Intermodal Container Transfer Facility (UPRR ICTF) are other major emissions sources in the area. The presence of these important emissions sources has lead to local concerns about the air quality in the surrounding communities. C A B 4 mi Figure 1. Map of the study area as obtained from Google Earth (Google Inc. 1400 Amphitheatre Pkwy, Mountain View, CA 94043). The yellow circles indicate the locations of the three elementary schools participating in this pilot study: Del Amo (A), Hudson (B), and Dominguez (C). The Union Pacific Railroad Intermodal Container Transfer Facility is marked by the black rectangle 3 At each of the three elementary schools, three classrooms with similar structural characteristics and ventilation conditions were selected to provide reproducible test conditions for the various air purification systems deployed. All classrooms (varying between 7533 and 9196 ft3 in size) already included forced-air HVAC systems, although windows and doors were regularly used for additional ventilation. The most relevant characteristics of all nine classrooms are listed in Table 1, along with their respective identification numbers. Table 1. Structural characteristics and ventilation conditions of the nine classrooms selected for this pilot study SCHOOL Classroom ID Total Number of Occupants Room Size (ft) Room Volume (ft3) HVAC System Type HVAC Panel Filter Type Filter Rating HVAC Operation DA-6 18 DEL AMO DA-7 19 DA-8 22 38×24×10 38×24×10 38×24×10 9120 9120 9120 H-11 21 HUDSON H-15 11 H-52 17 DZ-7 28 DOMINGUEZ DZ-9 28 DZ-11 29 30×30×9 30×30×9 31×27×9 38×22×11 38×22×11 38×22×11 7533 9196 8100 DW-M* DW-M* DW-M* DM-ZR** 2" Pleated 2" Pleated 2" Pleated 2" Pleated MERV 7 MERV 7 MERV 7 MERV 7 Manual Manual Manual Automatic 8100 DM-ZR** 2" Pleated MERV 7 Automatic DR*** DR*** 2" Fiberglass 1" Pleated Unclassified MERV 7 Manual Manual 9196 9196 DR*** 1" Pleated MERV 7 Manual DR*** 1" Pleated MERV 7 Manual Number of Supply Vents 1 1 1 1 1 4 3 3 3 Supplied Airflow# (cfm) Air Exchange Rate 1200 7.9 1200 7.9 1250 8.2 840 6.2 903 6.7 1236 9.8 1642 10.7 1681 11.0 1772 11.5 * DW-M = Ducted Wall-Mount ** DM-ZR = Ducted Multi-Zone Rooftop *** DR = Ducted Rooftop # With existing panel filter Prior to beginning this study, none of the selected classrooms featured any specific air purification device other than one or more medium performance panel filters (MERV 7) installed inside the respective HVAC systems. The typical replacement interval for these air filters is approximately three months according to schools schedules. The primary purpose of this panel filter is to remove coarser particles and dust to protect the HVAC system's heating and cooling coils. These filters generally provide little or no removal of smaller particles or gaseous pollutants. 4 Air Purification Solutions Three different air purification solutions were tested for their ability to remove UFP, PM2.5, PM10, BC and, where possible, VOCs from the air stream: a) an HVAC-based high-performance panel filter (HP-PF), b) a register-based air purifier (here referred to as register system or RS), and c) a standalone system (SA). All air purification solutions were provided, installed, and maintained by IQAir, and their primary features are summarized in Table 2. Table 2. Summary of the primary features of the three air purification devices adopted for this pilot study: high-performance panel filter (HP-PF), register system (RS), and standalone system (SA) High-performance Panel Filter (PF) Register Sysyem (RS) Standalone System (SA) √ √ √ 0 √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ 0 √ √ √ √ N/A N/A √ N/A N/A √ High UFP and PM2.5 Filtration Efficiency High Gas Phase Filtration Efficiency Low Pressure Drop / High Air Flow Low Noise Low Maintenance High Classroom Compatibility No HVAC System Retrofit Minimal Impact on Classroom Space Low Power Consumption Tamper-Resistant Design √ = featured 0 = not featured 5 High-performance panel filter (HP-PF) In most classrooms, the existing medium performance panel filters were replaced with one or more HP-PFs as shown to in Figure 2. Figure 2. Schematic of a typical HVAC system. The picture on the right-hand side shows a typical high-performance panel filter (HP-PF) after several months of usage Compared to standard/conventional medium performance MERV filters, the highperformance panel filters used for this pilot study are twice as thick (2” in depth) and have a much larger filter surface area (five to nine times larger). Due to the increased surface area and the special filter material used, they generally have similar air resistance properties as conventional filters and, thus, do not act to reduce the air flow through the HVAC system. Also, due to the increased surface area and specific design, these media have the potential to last longer than conventional filters before replacement is required. Because these filters are manufactured using a proprietary “nano-fiber” technology, their ability to remove UFPs and BC from the air stream is also higher. Table 3 shows a comparison between the characteristics of several conventional MERV filters available for residential and commercial applications and the HP-PF employed in this pilot study. 6 Table 3. Comparison between the main characteristics of several conventional MERV filters and the high-performance panel filters (HP-PF) tested in this study Filter Pressure Media Filter Filter Annual Annual Total Annual Cost ($) Efficiency (%)1 Drop (in w.g.)2 Area (ft2) Life (months) Cost ($) Filter Cost ($) Maintenance Cost ($)3 at 0.3 µm at 1.0 µm CONVENTIONAL PANEL FILTERS Panel Filter Type Low Efficiency 2" Fiberglass Medium Efficiency 1" Pleated Medium Efficiency 2" Pleated High Efficiency 2" Pleated High Efficiency 2" Pleated High Efficiency 2" Mini-Pleat Filter Rating (unrated) 1 10 0.28 4.0 3 3 to 5 12 to 20 50 62 to 70 MERV 7 3 25 0.48 7.5 3 5 to 7 20 to 28 50 70 to 78 MERV 7 5 35 0.30 11.8 3 7 to 10 28 to 40 50 78 to 90 MERV 11 15 58 0.39 17.8 3 13 to 20 52 to 80 50 102 to 130 MERV 13 30 85 0.41 21.1 3 25 to 40 100 to 160 50 150 to 210 MERV 16 90 99 2.00 55.0 3 80 320 50 370 60.0 6 to 12 120 120 to 240 13 to 25 133 to 245 PILOT STUDY HIGH-PERFORMANCE PANEL FILTER High-performance MERV 16 2" Mini-Pleat 93 99 0.38 Data are based on a nominal 24" × 24" filter size Typical minimum efficiency at rated face velocity of 492 fpm 2 Typical pressure drop of a new filter; based on a face velocity of 492 fpm 3 Based on an estimated maintenance time of 15 min per filter change (at $50/hr) 1 7 Register system (RS) This device is installed directly on the HVAC register, where the air supply enters the room. The unit is equipped with a “nano-technology” filter media for the removal of PM and high-capacity gas phase filter cartridges to eliminate certain gaseous pollutants from the air stream (e.g. VOCs) (Figure 3). This particular design allows for a longer contact time between the filtration media and the gaseous pollutants than would be permitted by using an activated carbon panel filter in the HVAC system. Nevertheless, the RS does not reduce the overall HVAC system airflow if installed by a trained specialist. Figure 3. Schematic of the register system (RS) as installed in one of the study classrooms. A high-performance panel filter (HP-PF) may also be installed in the HVAC air handler to provide additional particle filtration 8 Standalone system (SA) A standalone system (SA) is a self-contained air cleaning device that operates independently of a classroom’s HVAC system. This air filtration system is 6 feet tall and has a footprint of about 4 ft2 (Figure 4). The SA is tamper proof, runs on a standard power circuit, and is built with an energy efficient fan, located inside a specially designed box for ultra quiet operation (<45 db(A) at high airflow). Indoor air enters from the lower part of the system (about 6 inches off the ground) and passes, sequentially, through a large “nano-technology” filter media, for the removal of PM, and 12 high-capacity gas phase filter cartridges, for removal of the gaseous pollutants commonly found indoors (VOCs) (Figure 4). Figure 4. Schematic of the standalone system (SA) as installed in one of the classrooms The main characteristics of the SA tested in this pilot study have been summarized in Table 4 and compared to those of other typical “residential” and “commercial” standalone units available on the market. A major design consideration for the SA was low noise. Many school districts have set a 45db(A) noise threshold for new in classroom equipment. At this noise level, available residential and commercial air purification devices offer less than two air changes per hour (ACH) in a typical classroom. This SA unit offers more than five ACH. 9 Table 4. Comparison between the main features of the standalone system used for this pilot study and those of other commercially available standalone air purifiers Residential Commercial Pilot Study Air Purifier Standalone Standalone Particle Filtration Technology Electronic / Media Electronic / Media Media Removal Efficiency at 0.3 µm (%) 40 to 99 60 to 99 > 99 Maximum Airflow (cfm) 150 to 400 400 to 1200 1200 Airflow at 45 dB(A) (cfm) 25 to 100 100 to 200 800 Gas-phase Filtration Media (lb) 0.5 to 18 10 to 80 100 Price ($) 200 to 1,000 1,500 to 12,000 8,500 Price / CFM at 45 db(A) ($) 8 to 10 15 to 60 11 Classroom ACH at 45 db(A)* 0.2 to 0.7 0.7 to 1.3 5.3 *Air Changes per Hour (ACH) based on a 9000 ft 3 room In-classroom configurations Different combinations of the standalone system, HVAC-based high-performance panel filter, and register-based air purifier were used inside the studied classrooms to evaluate the performance of these air filtration devices: 1. High-performance panel filter alone: HP-PF 2. Register-based air purifier alone (RS). It should be noted that in some cases a conventional / medium performance panel filter (PF) was already installed inside the HVAC system prior to the beginning of the study: RS+PF 3. Register-based air purifier in conjunction with a high-performance panel filter: RS + HP-PF 4. Standalone system in classrooms with no HVAC running: SA 5. Standalone system in classrooms with a HVAC running, in which case a conventional / medium performance panel filter (PF) was already installed inside the HVAC system prior to the beginning of the study: SA + PF 6. Standalone system in conjunction with a high-performance panel filter: SA + HPPF A schematic representation of these six configurations is shown below (Figure 5). 10 Registerbased air purifier (RS) Standalone system (SA) HVAC-based highperformance panel filter (HP-PF) Conventional / medium efficiency panel filter (PF) Figure 5. Schematic representation of the six air purification solutions tested in this pilot study 11 Indoor and outdoor measurements Four mobile air quality monitoring stations were used to measure the indoor and outdoor concentrations of the targeted air pollutants. Each of these stations was comprised of a mobile cart supporting the following instruments (Figure 6):       A portable Aethalometer (model AE42, Magee Scientific, 2800 Adeline St., Berkeley CA 94703) to provide continuous measurements of BC concentrations (ng/m3) A water-based condensation particle counter (CPC model 3781, TSI, 500 Cardigan Road, Shoreview, MN 55126) to provide continuous measurements of the particle number concentration (#/cm3), an indicator of UFPs A laser particle counter (IQAir ParticleScan Pro): for determining the number concentration (#/cm3) of particles down to 0.3 μm in diameter. Since the PM2.5 particle mass concentration in urban areas tends to be dominated by particles in the 0.3 – 1.0 μm range, this instrument provides a rough estimate of the PM2.5 mass. A laser-based particle mass monitor (Aerocet 531 Aerosol Particulate Profiler, MetOne; 1600 Washington Blvd., Grants Pass, Oregon 97526): to provide continuous measurements of the mass concentration (µg/m3) of both PM2.5 and PM10 A low volume filter sampler (SKC Leland Legacy Sample Pump with SKC DPS Impactor, 863 Valley View Road Eighty Four, PA 15330): to collect time-integrated filter-based PM10 samples. Samples were collected at 10L/min on 47mm Teflon filters for the duration of a typical school day. These substrates were weighed before and after collection using a microbalance, and the PM10 concentration (µg/m3) was calculated by dividing the difference in PM10 mass by the corresponding sampling volume. These gravimetric measurements were considered as primary indicators of the PM10 mass. 6L EPA TO-15 SUMMA canisters: to collect time-integrated air samples over the course of a typical school day. Samples were then analyzed by gas chromatography-mass spectrometry (GC-MS) to measure the concentrations of 61 specific VOCs (ppbv). 12 Figure 6. One of the four mobile stations used to monitor the indoor and outdoor concentrations of the targeted air pollutants At each school, one air quality monitoring cart was set-up outside to sample outdoor air. The remaining three stations were placed indoors, one in each classroom, near one of the walls and just a few meters away from the students. Measurements were made away from all air conditioning vents to better represent mixed indoor air quality conditions as experienced by students and teachers. All sensors and inlets were approximately three feet above the floor, or about the height of a child’s head when seated. The effectiveness of each of the tested air purification solutions was then evaluated by comparing the indoor concentrations of the targeted air pollutants to the corresponding outdoor levels. Baseline measurements were taken before installing any of the air purification solutions to estimate the pre-existing removal efficiencies of the classrooms before modification. Measurements that were found to be inaccurate or unrepresentative due to meteorological conditions (e.g. rain), improper cart placement, or instrument malfunction were not considered in the data analysis. Before and after school hours, the four measurement stations were collocated in a storage room and the continuous instruments were run “side-by-side” to provide quality assurance of the measurements, to estimate the precision characteristics, and to identify any potential problems. Table 5 shows the specific air purification solutions that were tested inside each of the nine classrooms, along with the dates when all baseline and actual measurements were taken. 13 Table 5. Summary of the air purification solutions tested in each of the nine classrooms. The dates when all baseline and actual measurements were taken are also included School / Class ID 04 / 07-11 / 08 Del Amo / DA-6 Del Amo / DA-7 Del Amo / DA-8 Hudson / H-11 Hudson / H-15 Hudson / H-52 Dominguez / DZ-7 Dominguez / DZ-9 Dominguez / DZ-11 Configurations Used 04 / 14-18 / 08 04 / 21-25 / 08 04 / 28 / 08 to 05 / 02 / 08 Baseline Baseline Baseline SA + PF RS HP-PF SA + PF RS HP-PF SA + HP-PF RS HP-PF 05 / 12-16 / 08 05 / 19-23 / 08 05 / 26-30 / 08 06 / 02-06 / 08 Baseline Baseline Baseline HP-PF HP-PF HP-PF RS + HP-PF RS + HP-PF RS + HP-PF RS + HP-PF RS + HP-PF RS + HP-PF 11 / 18-26 / 08 12 / 01-05 / 08 12 / 08-12 / 08 12 / 15-19 / 08 Baseline Baseline Baseline SA / SA + PF HP-PF HP-PF SA + HP-PF HP-PF RS + HP-PF SA + HP-PF HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter The three schools were tested one at a time from April to December 2008 for a total of over 150 valid measurement days across all schools and classrooms. The period of sampling was during regularly scheduled school hours, with minor adjustments for school schedule changes. RESULTS AND DISCUSSION Removal of PM and other particle species Figure 7a summarizes the study average particle removal efficiencies (here defined as the percentage reduction in the indoor concentration of a particular pollutant relative to its concurrent outdoor concentration) achieved by the six air purification solutions. Indoor and outdoor mass and particle number concentrations were averaged over the duration of a typical school day and across all days, classrooms and schools. The corresponding study average particle removal efficiencies for each elementary school are shown in Figures 7b, 7c, and 7d for Del Amo, Hudson and Dominguez, respectively. Daily and weekly average indoor and outdoor concentrations of BC, UFP, PM2.5 and PM10 at all schools and classrooms are provided in APPENDIX A, along with the corresponding average indoor/outdoor ratios and removal efficiencies. Overall, the combination of a register system and a high-performance panel filter (RS + HP-PF) was the most effective solution for reducing the indoor concentrations of BC, UFP, and PM2.5 (both mass and particle count), with average removal efficiencies varying from 87 to 96% (Figure 7a). Replacing a conventional HVAC-based panel filter (PF) with a HP-PF resulted in a substantial reduction in the indoor levels of all particulate pollutants inside all classrooms, especially when this high-performance panel filter was operated in conjunction with other air filtration devices. When using the HP-PF alone, the study average removal efficiencies were also close to 90% (88, 86, 91, and 88%, for BC, 14 UFP, PM2.5 count, and PM2.5 mass, respectively). These average values are significantly higher than baseline (pre-existing) conditions, when removal efficiencies for the different pollutants were only about 20-50%. Baseline SA + PF SA + HP-PF RS RS + HP-PF PM10 (µg/m3)* PM2.5 (µg/m3) PM2.5 (#/cm3) HP-PF UFP (#/cm3) 100% 90% 80% 70% 60% 50% 40% 30% 20% 10% 0% ALL CLASSROOMS AT ALL SCHOOLS BC (µg/m3) Removal Efficiency a) * From gravimetric / filter measurements The PM10 concentration was higher indoors than outdoors due to indoor sources 15 DEL AMO ELEMENTARY SCHOOL b) 100% Baseline 80% SA + PF ** 70% 60% 50% SA + HP-PF 40% RS 30% 20% HP-PF PM10 (µg/m3)* PM2.5 (µg/m3) PM2.5 (#/cm3) 0% UFP (#/cm3) 10% BC (µg/m3) Removal Efficiency 90% * From gravimetric / filter measurements ** With HVAC The PM10 concentration was higher indoors than outdoors due to indoor sources 16 HUDSON ELEMENTARY SCHOOL Baseline RS + HP-PF * From gravimetric / filter measurements 17 PM10 (µg/m3)* PM2.5 (µg/m3) PM2.5 (#/cm3) HP-PF UFP (#/cm3) 100% 90% 80% 70% 60% 50% 40% 30% 20% 10% 0% BC (µg/m3) Removal Efficiency c) DOMINGUEZ ELEMENTARY SCHOOL d) 90% Baseline 80% SA** 70% SA + PF *** 60% 50% SA + HP-PF 40% 30% RS + HP-PF 20% 10% PM10 (µg/m3)* PM2.5 (µg/m3) PM2.5 (#/cm3) UFP (#/cm3) 0% HP-PF BC (µg/m3) Removal Efficiency 100% * From gravimetric / filter measurements ** Without HVAC *** With HVAC The PM10 concentration was higher indoors than outdoors because of indoor sources Figure 7. Particle removal efficiencies (%) achieved by the six air purification solutions. Bars indicate data averaged a) at all schools and in all classrooms, b) at Del Amo, c) at Hudson, and d) at Dominguez 18 In all cases, air quality conditions were improved substantially with respect to the corresponding baseline measurements. The intra-classroom variability of the measured removal efficiencies was low, as indicated by the low standard deviations given in Table 6a. This reflects the fact that all air purification solutions were highly effective at all schools and in all classrooms, as confirmed by the particle removal performance data for each of the three elementary schools in Tables 6b (Del Amo), 6c (Hudson) and 6d (Dominguez). The stand-alone system (SA) is well suited for indoor environments not equipped with an HVAC. In order to simulate conditions similar to those encountered in older classrooms not equipped with a forced air climate control device, the HVAC in room DZ7 (at Dominguez) was intentionally turned off for part of the study. When the SA unit was running with the HVAC off, removal efficiencies were close to 90% for BC, UFP and PM2.5 (count) (Table 6d). For BC and UFP, these percentages were slightly lower when the HVAC was running since more of the smaller particles (mostly unfiltered by the existing conventional panel filter) were entering the classrooms from outdoors. Overall, our results confirmed that conventional HVAC panel filters are not particularly effective in removing UFP, although they can be effective in removing coarser particles. 19 Table 6. Particle removal efficiencies (%) achieved by the six air purification solutions. Data represent averages a) at all schools and in all classrooms, b) at Del Amo, c) at Hudson, and d) at Dominguez ALL CLASSROOMS AND ALL SCHOOLS a) Study BC (%) UFP (%) 48 22 ± 13 52 ± 17 45 ± 14 37 ± 14 67 ± 6 77 ± 6 79 ± 5 75 11 91 ± 6 93 ± 4 90 ± 3 82 15 74 ± 20 81 ± 10 79 ± 17 35 95 ± 2 96 ± 3 93 ± 5 35 88 ± 5 86 ± 7 91 ± 4 days (#) Baseline SA + PF** SA + HP-PF RS + PF RS + HP-PF HP-PF PM2.5 count (%) Study PM10 gravimetric mass (%) 1 mass monitor (%) 26 -67 ± 156 13 ± ± 5 17 ± 71 59 ± 9 ± 12 49 ± 16 53 ± 33 69 ± 24 31 ± 55 22 ± 46 87 ± 11 68 ± 11 42 ± 28 88 ± 8 54 ± 25 53 ± 31 2 36 15 8 45 ± 16 18 ± 20 27 ± 17 -224 ± 278 26 ± 26 N/A N/A 9 N/A ± N/A PM2.5 mass (%) PM10 UFP (%) ± PM2.5 count (%) PM10 BC (%) days (#) gravimetric mass (%) 1 mass monitor (%) N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± 10 52 ± 7 68 ± 6 60 ± 7 64 ± 5 29 ± 102 51 ± 9 5 90 ± 5 92 ± 3 93 ± 1 91 ± 4 84 ± 11 74 ± 11 15 74 ± 20 81 ± 10 79 ± 17 69 ± 24 31 ± 55 22 ± 46 N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A 87 ± 4 89 ± 5 89 ± 5 58 ± 28 62 ± 13 15 88 ± 4 2 HUDSON ELEMENTARY SCHOOL c) Study BC (%) UFP (%) days (#) Baseline SA* SA + PF** SA + HP-PF RS + PF RS + HP-PF HP-PF PM10 DEL AMO ELEMENTARY SCHOOL b) Baseline SA* SA + PF** SA + HP-PF RS + PF RS + HP-PF HP-PF PM2.5 mass (%) 15 33 ± 9 PM2.5 count (%) PM2.5 mass (%) PM10 PM10 gravimetric mass (%)1 mass monitor (%)2 56 ± 18 46 ± 11 74 ± 5 64 ± 28 54 ± 23 N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A 27 96 ± 2 98 ± 2 94 ± 4 94 ± 5 67 ± 8 51 ± 30 15 92 ± 2 91 ± 4 93 ± 2 93 ± 4 68 ± 19 59 ± 33 DOMINGUEZ ELEMENTARY SCHOOL d) Study BC (%) UFP (%) days (#) PM2.5 count (%) PM2.5 mass (%) PM10 PM10 gravimetric mass (%) 1 mass monitor (%) Baseline SA* 18 24 ± 21 54 ± 16 70 ± 11 11 ± 55 -40 ± 161 -42 ± 60 3 90 ± 4 94 ± 2 92 ± 6 75 ± 10 0 ± 34 31 ± 42 SA + PF** 4 82 ± 5 86 ± 5 97 ± 2 86 ± 4 4 ± 40 66 ± 8 SA + HP-PF RS + PF RS + HP-PF HP-PF 6 91 ± 6 94 ± 4 87 ± 5 72 ± 20 13 ± 20 32 ± 55 N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A N/A ± N/A 8 N/A ± N/A 94 ± 2 94 ± 3 91 ± 6 80 ± 17 69 ± 14 33 ± 25 18 85 ± 8 81 ± 13 91 ± 5 81 ± 16 35 ± 28 39 ± 48 Note: Negative removal efficiencies indicate the presence of an indoor source of PM 10 1 From gravimetric / filter measurements Using a particle mass monitor *The HVAC system was turned off **Operated in conjunction with a standard (MERV 7) panel filter installed in the HVAC system 2 It should be noted that the negative removal efficiencies associated with several baseline PM10 measurements indicate conditions where indoor concentrations were higher than the corresponding outdoor levels. This is likely due to re-suspension of dust and other relatively large particles caused by in-classroom activities such as walking and cleaning. Due to the presence of these indoor sources, the removal performance of PM10 was lower than that of other particle measurements. 20 2 Figure 8 illustrates the effect of indoor activities on in-classroom PM10 levels at Hudson Elementary School (Room H-15) on May 21, 2008. On this day removal efficiencies approached 100% before the school day started and during lunchtime (when students and staff members were outside the classroom) and were substantially lower when classes were in session. EFFECT OF INDOOR ACTIVITIES ON THE REMOVAL EFFICIENCY OF PM10 Class duration +50 -200 Carts moving -150 Recess -100 Lunch -50 Students out of class 0 Recess Removal Efficiency (%) +100 Time Figure 8. Effect of indoor activities on the removal performance of PM10 at Hudson elementary school (Room H-15) on May 21, 2008 Activities occurring immediately outside the school boundaries were observed to influence the indoor concentrations of some pollutants and, thus, their corresponding removal efficiencies. Figure 9 shows the effect of increased motor-vehicle emissions due to the morning drop-off of students (grey areas) on the outdoor concentrations of BC, and the associated spikes in indoor BC levels occurring just before the beginning of the school day, when the classroom doors were left open. Overall, these indoor peaks caused a relatively small decrease in the calculated removal performance when averaged over the course of the entire school day. 21 5/27/08 6:15 0.00 Outdoors H-11 22 H-15 5/30/08 11:15 5/30/08 10:15 5/30/08 08:15 5/30/08 09:15 5/30/08 07:15 5/29/08 11:25 5/29/08 10:25 5/29/08 08:25 5/29/08 09:25 5/29/08 07:25 5/28/08 11:55 5/29/08 6:55 5/29/08 7:25 5/29/08 7:55 5/29/08 8:25 5/29/08 8:55 5/29/08 9:25 5/29/08 9:55 5/29/08 10:25 5/29/08 10:55 5/29/08 11:25 5/29/08 11:55 5/30/08 6:45 5/30/08 7:15 5/30/08 7:45 5/30/08 8:15 5/30/08 8:45 5/30/08 9:15 5/30/08 9:45 5/30/08 10:15 5/30/08 10:45 5/30/08 11:15 5/30/08 11:45 11:25 5/28/08 11:25 5/28/08 5/28/08 10:55 10:25 5/28/08 10:25 5/28/08 5/28/08 9:55 9:25 5/28/08 09:25 5/28/08 5/28/08 8:55 8:25 5/28/08 08:25 5/28/08 5/28/08 7:55 7:25 5/28/08 07:25 5/28/08 5/28/08 6:55 10:45 5/27/08 10:45 5/27/08 5/27/08 11:15 11:45 5/27/08 11:45 5/27/08 5/27/08 10:15 9:45 5/27/08 09:45 5/27/08 5/27/08 9:15 8:45 5/27/08 08:45 5/27/08 5/27/08 8:15 07:45 5/27/08 7:45 5/27/08 5/27/08 7:15 06:45 5/27/08 6:45 5/27/08 BC (µg/m3) EFFECT OF PRE-SCHOOL ACTIVITIES ON BC CONCENTRATIONS 4500 4.5 4000 4.0 3500 3.5 3000 3.0 2500 2.5 2000 2.0 1500 1.5 1000 1.0 500 0.5 H-52 Figure 9. Effect of before school activities on BC concentrations. Grey areas show an increase in both indoor and outdoor levels due to morning drop-off traffic Impact on the HVAC system airflow As discussed earlier, the high-performance panel filters (HP-PF) used for this pilot study are thicker than standard/conventional medium performance MERV filters. However, due to their increased surface area and proprietary “nano-fiber” design, they generally have similar air resistance properties as conventional filters and, thus, do not reduce the airflow through the HVAC system. As shown in Table 7, replacing a conventional panel filter (PF; typically 1” in depth) with a thicker high-performance panel filter (HP-PF; 2” deep) did not alter the measured airflow in any of the studied classrooms. Adding a register system without upgrading to a high-performance panel filter (see the RS-PF configuration data below) reduced the HVAC system airflow by an average of 9%. This small reduction is due to the increased pressure drop resulting from the addition of a gas-phase filtration media. Using a register system while also upgrading to a high-performance panel filter (RS + HP-PF configuration in Table 7) altered the airflow by only 1-3%. At Hudson elementary school, installation of the register system in classrooms H-11 and H-15 required a widening of the connection to the supply duct. This caused an airflow increase between 17 and 24%. Table 7. Effect of a high-performance panel filter (HP-PF) and/or a register system (RS) on the HVAC system airflow DEL AMO ELEMENTARY SCHOOL DA-6 Baseline HP-PF RS + PF Airflow (cfm) 1200 1210 N/A DA-7 Change (%) 1 N/A Airflow (cfm) 1200 N/A 1090 DA-8 Change (%) N/A -9 Airflow (cfm) 1250 1250 N/A Change (%) 0 N/A HUDSON ELEMENTARY SCHOOL H-11 Baseline HP-PF RS + HP-PF Airflow (cfm) 840 844 1039 H-15 Change (%) 0 24 Airflow (cfm) 903 913 1054 H-52 Change (%) 1 17 Airflow (cfm) 1236 1246 1194 Change (%) 1 -3 DOMINGUEZ ELEMENTARY SCHOOL DZ-7 Baseline HP-PF RS + HP-PF Airflow (cfm) 1642 1661 N/A DZ-9 Change (%) 1 N/A Airflow (cfm) 1681 1664 N/A 23 DZ-11 Change (%) -1 N/A Airflow (cfm) 1722 1771 1742 Change (%) 3 1 Removal of VOCs Although canister samples were collected at all schools and classrooms, and all samples were analyzed for VOCs, the data recovery at Del Amo and Hudson was insufficient to guarantee an adequate interpretation of the results. The detection limits of the analysis method used at those schools were not low enough to quantify most of the VOCs of interest. After the analysis methods were modified to correct for this problem, reliable VOC data were obtained for Dominguez elementary. Therefore, only VOC data from Dominguez are discussed in this section. Table 8 summarizes the removal efficiencies for:    Total VOCs: expressed as the sum of 61 individual compounds and 53 unspeciated organic compounds Ethanol: a chemical emitted from both indoor and outdoor evaporative sources Benzene: a species mostly emitted from gasoline-powered vehicles. This compound was used here as an indicator of VOCs of outdoor origin Daily average concentrations of individual VOCs measured at Dominguez elementary school (i.e. DZ-7, DZ-9, and DZ-11) are given in APPENDIX B. Table 8. Average removal efficiencies of total VOCs, ethanol, and benzene at Dominguez elementary school DOMINGUEZ ELEMENTARY SCHOOL Study Days (#) Baseline SA (HVAC off)* SA + PF (HVAC on)** SA + HP-PF RS RS + HP-PF HP-PF 18 3 4 6 N/A 8 18 Total VOCs (%)1 -114 15 19 -6 N/A -3 -64 ± ± ± ± ± ± ± 731 132 198 280 N/A 345 404 Ethanol (%) -1230 -349 -587 -929 N/A -534 -1111 ± ± ± ± ± ± ± 982 276 903 853 N/A 502 1164 Benzene (%) -11 52 58 73 N/A 58 1 ± 22 ± 35 ± 33 ± 11 ± N/A ± 49 ± 38 1 Sum of 61 known VOCs and 53 unspeciated organic compounds *Operated with the HVAC system turned off **Operated with the HVAC system turned on Large standard deviations reflect the wide concentration ranges for the different chemicals. As expected, existing and high-performance panel filters (PF and HP-PF, respectively) had virtually no effect on the VOC levels measured indoors, since these air filtration media did not include gas removal capabilities. The standalone system (SA) demonstrated a 52 to 73% removal performance for benzene. At all three schools, the indoor concentrations of ethanol were consistently the highest among all measured VOCs and higher than outdoor levels. This organic 24 compound is a common solvent used in whiteboard markers, detergents and other cleaning products, and has several potential indoor sources. The negative removal efficiencies shown in Table 8 indicate that the indoor concentrations of some VOCs were often higher than the corresponding outdoor levels. Our findings are in line with those from previous research studies (Jia et al., 2007; Bruno et al., 2008), and confirm that several measured indoor VOCs are mostly of indoor origin. For this reason, a direct comparison of indoor and outdoor total VOC concentrations is not appropriate when significant indoor sources exist. Therefore, classroom DZ-9, whose air conditioning system was equipped with a HP-PF and no gas phase filtration device, was used as the “baseline” (rather than the outdoor monitoring site) to better evaluate the actual effectiveness of the standalone unit (SA) and the register system (RS) installed in classrooms DZ-7 and DZ-11, respectively (Table 9). When compared to the control classroom (DZ-9), the removal efficiencies for total VOCs in classrooms DZ-7 and DZ-11 showed a reduction in gaseous pollutants with respect to baseline conditions. Table 9. Average removal efficiencies of total VOCs with respect to a control classroom (DZ-9) not equipped with any gas phase filtration device. All data refer to measurements taken at Dominguez elementary school DOMINGUEZ ELEMENTARY SCHOOL (removal efficiency with respect to classroom DZ-9) Classroom Study 1 Baseline RS SA (HVAC off)* SA + PF (HVAC on)** Comparison DZ-7 & DZ-11 vs DZ-9 DZ-11 vs DZ-9 DZ-7 vs DZ-9 DZ-7 vs DZ-9 Days (#) 14 10 2 8 Total VOCs (%)2 -31 -3 55 27 ± ± ± ± 367 521 50 198 1 DZ-9 = "control classroom" (HP-PF but no gas-phase filtration) Sum of 61 known VOCs and 53 unspeciated organic compounds 2 *Operated with the HVAC system turned off **Operated with the HVAC system turned on Removal efficiencies corresponding to baseline measurements indicate that the total VOC concentration inside the two test rooms (DZ-7 and DZ-11) were, on average, 31% higher than that in the control classroom (DZ-9), probably because of differences in indoor activities (e.g. cleaning). Assuming this difference persisted throughout the entire duration of the study, the actual VOC removal performance of the register system (RS) was about 28% (-3% + 31%). Similarly, when normalizing for the initial conditions in the control classroom, the removal efficiencies of the standalone (SA) unit operated with and without the use of the HVAC system were about 58% (27% + 31%) and 86% (55% + 31%), respectively. 25 Overall, these solutions demonstrated some ability to reduce VOCs indoors, although not as consistently or effectively as the particle filtration. This may be due to the presence of one or more indoor sources of gaseous pollutants. The removal performance of gas-absorbing media (as opposed to filtration substrates) is dependent on media history and may be subject to saturation after experiencing high short-term concentrations or after longer-term use. Therefore, the lifetime, cost, benefits, and maintenance of the gas removal media must be further assessed before conclusions and recommendations can be made. ACKNOWLEDGEMENTS This pilot study was funded through the use of mitigation fees collected by the South Coast Air Quality Management District (SCAQMD) under Rule 1172 for VOC releases by local refineries. AQMD is the air pollution control agency for all of Orange County and urban portions of Los Angeles, Riverside and San Bernardino counties, the smoggiest region of the United States. IQAir North America, Inc., a leading specialist in air filtration solutions for homes, hospitals and schools, and Thermal Comfort Systems, specialist in HVAC system design, were selected by SCAQMD through a competitive bid process to provide for the design, engineering and installation of the air filtration devices used for this work. 26 REFERENCES Bruno, P., Caselli, M., De Gennaro, G., Iacobellis, S., and Tutino, M. (2008) “Monitoring of volatile organic compounds in non-residential indoor environments”, Indoor Air, 18 (3): 250-256 Environmental Protection Agency Integrated Science Assessments (External Review Draft; 2009). http://cfpub.epa.gov/ncea/cfm/recordisplay.cfm?deid=201805 Jia, C., Batterman, S. and Godwin, C. (2007) “VOCs in industrial, urban and suburban neighborhoods, Part 1: Indoor and outdoor concentrations, variation, and risk drivers”, Atmospheric Environment, 42 (9): 2083-2100 MATES III Study, 2008 (http://www.aqmd.gov/prdas/matesIII/matesIII.html) Pope, C. A., and Dockery, D. W. (2006) "Health effects of fine particulate air pollution: Lines that connect", Journal of the Air & Waste Management Association, 56: 709-742 27 APPENDIX A. Daily and weekly average indoor and outdoor concentrations of black carbon (BC), ultra-fine particles (UFP), fine particulate matter (PM2.5) and coarse PM (PM10) at all schools and classrooms. The corresponding average indoor / outdoor ratios and removal efficiencies are also included. Missing data (mostly due to instrument malfunction) and periods affected by rain have been highlighted in yellow. The air purification solutions adopted in each classroom have been summarized below each Table Del Amo Elementary School - Black Carbon Average Outdoor Concentration (ng/m3) 1,611 948 1,119 1,692 4,451 1,964 1,426 3,688 1,128 1,353 4,392 3,387 2,789 1,462 1,409 2,396 1,180 1,691 3,261 1,987 846 3,789 1,908 1,077 1,055 3,338 2,233 1,272 Date 4/7/2008 4/8/2008 4/9/2008 4/10/2008 4/11/2008 Average (Week 1) Standard Deviation 4/14/2008 4/15/2008 4/16/2008 4/17/2008 4/18/2008 Average (Week 2) Standard Deviation 4/21/2008 4/22/2008 4/23/2008 4/24/2008 4/25/2008 Average (Week 3) Standard Deviation 4/28/2008 4/29/2008 4/30/2008 5/1/2008 5/2/2008 Average (Week 4) Standard Deviation School / Class ID 04 / 07-11 / 08 Del Amo / DA-6 Del Amo / DA-7 Del Amo / DA-8 Average Indoor Concentration (ng/m3) DA-6 DA-7 DA-8 1,392 1,490 1,465 902 1,094 887 1,166 1,147 1,044 1,518 1,495 1,500 3,547 3,665 3,651 1,705 1,778 1,709 1,056 1,071 1,117 1,802 383 410 595 851 93 824 703 333 2,301 1,656 435 1,752 1,061 254 1,455 931 305 718 475 138 537 171 105 1,097 414 265 498 226 125 734 362 193 1,377 455 278 848 326 193 379 122 79 209 349 375 135 269 279 104 108 127 191 156 160 292 1,899 505 186 556 289 73 756 156 Configurations Used 04 / 14-18 / 08 04 / 21-25 / 08 Baseline Baseline Baseline SA + PF RS HP-PF SA + PF RS HP-PF 04 / 28 / 08 to 05 / 02 / 08 SA + HP-PF RS HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 28 DA-6 0.86 0.95 1.04 0.90 0.80 0.91 0.09 0.49 0.53 0.61 0.52 0.52 0.53 0.04 0.38 0.46 0.42 0.43 0.42 0.42 0.03 0.06 0.07 0.10 0.18 0.09 0.10 0.05 Average Indoor/Outdoor Ratio DA-7 DA-8 0.92 0.91 1.15 0.94 1.03 0.93 0.88 0.89 0.82 0.82 0.96 0.90 0.13 0.05 0.10 0.11 0.75 0.08 0.52 0.25 0.38 0.10 0.31 0.07 0.41 0.12 0.24 0.07 0.12 0.07 0.17 0.11 0.19 0.11 0.21 0.11 0.14 0.09 0.17 0.10 0.04 0.02 0.09 0.10 0.14 0.15 0.10 0.12 0.15 0.15 0.57 0.15 0.21 0.13 0.20 0.02 DA-6 14% 5% -4% 10% 20% 9% 9% 51% 47% 39% 48% 48% 47% 4% 62% 54% 58% 57% 58% 58% 3% 94% 93% 90% 82% 91% 90% 5% Average Removal Efficiency DA-7 8% -15% -3% 12% 18% 4% 13% 90% 25% 48% 62% 69% 59% 24% 88% 83% 81% 79% 86% 83% 4% 91% 86% 90% 85% 43% 79% 20% DA-8 9% 6% 7% 11% 18% 10% 5% 89% 92% 75% 90% 93% 88% 7% 93% 89% 89% 89% 91% 90% 2% 90% 85% 88% 85% 85% 87% 2% Del Amo Elementary School - Ultra Fine Particles Date 4/7/2008 4/8/2008 4/9/2008 4/10/2008 4/11/2008 Average (Week 1) Standard Deviation 4/14/2008 4/15/2008 4/16/2008 4/17/2008 4/18/2008 Average (Week 2) Standard Deviation 4/21/2008 4/22/2008 4/23/2008 4/24/2008 4/25/2008 Average (Week 3) Standard Deviation 4/28/2008 4/29/2008 4/30/2008 5/1/2008 5/2/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (particles/cm3) 34,674 39,291 19,124 41,814 42,613 35,503 9,665 53,086 35,591 55,384 35,185 44,812 10,923 57,526 46,241 34,366 38,854 33,004 41,998 10,101 40,429 57,136 30,692 37,507 34,214 39,996 10,249 School / Class ID 04 / 07-11 / 08 Del Amo / DA-6 Del Amo / DA-7 Del Amo / DA-8 Average Indoor Concentration (particles/cm3) DA-6 DA-7 DA-8 25,215 15,555 17,984 14,386 11,354 18,384 12,960 19,800 21,327 19,463 19,833 22,452 19,935 16,635 21,072 16,686 4,054 2,996 3,533 16,017 6,724 7,303 7,878 8,865 10,233 14,757 14,140 8,932 13,945 12,367 5,628 14,434 11,992 4,979 13,406 10,818 7,415 3,184 2,974 2,201 20,259 6,007 5,267 13,552 8,158 7,011 9,741 5,891 3,039 10,831 7,090 5,171 8,965 4,695 2,794 12,670 6,368 4,656 4,585 1,312 1,751 2,179 4,967 5,287 3,963 7,457 7,819 1,909 2,347 3,136 4,076 4,677 3,640 3,845 12,424 4,961 3,194 6,374 4,968 1,058 3,836 1,827 Configurations Used 04 / 14-18 / 08 04 / 21-25 / 08 Baseline Baseline Baseline SA + PF RS HP-PF SA + PF RS HP-PF 04 / 28 / 08 to 05 / 02 / 08 SA + HP-PF RS HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 29 DA-6 0.40 0.59 0.47 0.47 0.48 0.08 0.30 0.41 0.25 0.41 0.34 0.08 0.35 0.29 0.28 0.28 0.27 0.30 0.03 0.05 0.07 0.06 0.11 0.11 0.08 0.03 Average Indoor/Outdoor Ratio DA-7 DA-8 0.73 0.46 0.37 0.96 0.68 0.51 0.47 0.53 0.47 0.64 0.49 0.21 0.13 0.13 0.14 0.40 0.22 0.34 0.27 0.12 0.10 0.18 0.17 0.18 0.14 0.16 0.03 0.12 0.13 0.08 0.12 0.36 0.16 0.11 0.25 0.10 0.14 0.16 0.06 0.09 0.15 0.09 0.13 0.08 0.11 0.03 0.13 0.14 0.10 0.10 0.14 0.12 0.02 Average Removal Efficiency DA-7 DA-8 27% 60% 54% 63% 41% 4% 32% 53% 49% 53% 53% 47% 53% 52% 36% 51% 8% 21% 13% 70% 87% 86% DA-6 59% 75% 59% 66% 8% 65% 71% 72% 72% 73% 70% 3% 95% 93% 94% 89% 89% 92% 3% 60% 78% 66% 73% 12% 90% 82% 83% 82% 86% 84% 3% 88% 87% 92% 88% 64% 84% 11% 75% 90% 86% 84% 6% 91% 85% 91% 87% 92% 89% 3% 87% 86% 90% 90% 86% 88% 2% Del Amo Elementary School - PM2.5 (count) Date Average Outdoor Concentration (particles/ft3) 4/7/2008 4/8/2008 4/9/2008 4/10/2008 4/11/2008 Average (Week 1) Standard Deviation 4/14/2008 4/15/2008 4/16/2008 4/17/2008 4/18/2008 Average (Week 2) Standard Deviation 4/21/2008 4/22/2008 4/23/2008 4/24/2008 4/25/2008 Average (Week 3) Standard Deviation 4/28/2008 4/29/2008 4/30/2008 5/1/2008 5/2/2008 Average (Week 4) Standard Deviation 1,129,234 606,772 878,513 1,657,318 1,067,959 447,095 1,510,925 1,448,473 1,448,590 2,375,182 3,303,699 2,017,374 819,499 1,117,692 1,962,746 1,677,902 1,606,064 1,649,781 1,602,837 305,266 1,284,388 2,011,522 1,367,829 1,554,580 397,917 School / Class ID 04 / 07-11 / 08 Del Amo / DA-6 Del Amo / DA-7 Del Amo / DA-8 Average Indoor Concentration (particles/ft3) DA-6 DA-7 DA-8 1,425,737 860,458 818,779 859,380 589,396 761,753 621,944 654,570 1,007,993 1,686,712 1,092,355 1,098,063 929,208 842,014 293,205 515,070 186,681 608,865 153,470 164,656 675,560 901,449 87,792 823,550 755,949 363,943 935,700 625,960 216,222 1,068,499 835,426 206,160 822,435 654,451 207,755 187,458 298,268 100,893 445,613 132,034 89,866 721,027 258,062 184,328 639,840 235,809 136,928 565,163 258,425 167,180 558,423 189,268 127,409 586,013 214,719 141,142 102,511 54,125 36,669 94,732 159,555 165,842 121,487 205,529 272,593 108,012 120,466 153,098 143,394 155,073 791,947 275,170 108,077 284,178 204,355 13,378 285,555 63,660 Configurations Used 04 / 14-18 / 08 04 / 21-25 / 08 Baseline Baseline Baseline SA + PF RS HP-PF SA + PF RS HP-PF 04 / 28 / 08 to 05 / 02 / 08 SA + HP-PF RS HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 30 DA-6 0.76 Average Indoor/Outdoor Ratio DA-7 DA-8 0.61 0.69 0.11 0.40 0.47 0.57 0.39 0.32 0.43 0.09 0.40 0.37 0.38 0.35 0.34 0.37 0.02 0.07 0.06 0.08 0.73 0.97 0.71 1.02 0.86 0.16 0.10 0.62 0.52 0.26 0.25 0.35 0.21 0.12 0.13 0.14 0.16 0.11 0.13 0.02 0.12 0.10 0.09 0.76 1.26 0.75 0.66 0.86 0.27 0.11 0.06 0.25 0.09 0.06 0.11 0.08 0.08 0.09 0.08 0.10 0.08 0.09 0.01 0.13 0.14 0.11 0.07 0.01 0.10 0.02 0.13 0.01 DA-6 24% Average Removal Efficiency DA-7 DA-8 39% 31% 11% 60% 53% 43% 61% 68% 57% 9% 60% 63% 62% 65% 66% 63% 2% 93% 94% 92% 27% 3% 29% -2% 14% 16% 90% 38% 48% 74% 75% 65% 21% 88% 87% 86% 84% 89% 87% 2% 88% 90% 91% 24% -26% 25% 34% 14% 27% 89% 94% 75% 91% 94% 89% 8% 92% 91% 92% 90% 92% 91% 1% 87% 86% 89% 93% 1% 90% 2% 87% 1% Del Amo Elementary School - PM2.5 (mass) Date 4/7/2008 4/8/2008 4/9/2008 4/10/2008 4/11/2008 Average (Week 1) Standard Deviation 4/14/2008 4/15/2008 4/16/2008 4/17/2008 4/18/2008 Average (Week 2) Standard Deviation 4/21/2008 4/22/2008 4/23/2008 4/24/2008 4/25/2008 Average (Week 3) Standard Deviation 4/28/2008 4/29/2008 4/30/2008 5/1/2008 5/2/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (µg/m3) 8.74 14.25 8.61 7.48 7.24 9.27 2.86 10.14 15.06 12.49 10.60 8.25 11.31 2.58 10.99 11.03 8.59 12.72 7.09 10.08 2.23 5.61 17.88 14.50 12.95 14.08 13.00 4.52 School / Class ID 04 / 07-11 / 08 Del Amo / DA-6 Del Amo / DA-7 Del Amo / DA-8 Average Indoor Concentration (µg/m3) DA-6 DA-7 DA-8 10.50 6.68 6.51 10.54 7.04 5.07 6.43 6.05 6.53 5.73 4.55 3.89 5.94 4.73 6.50 7.06 5.77 2.88 1.98 1.10 3.61 1.93 0.90 4.75 12.40 1.15 5.44 9.75 3.31 5.21 0.62 3.76 3.68 1.05 4.39 6.59 1.41 0.86 4.35 1.08 3.56 2.28 0.81 3.65 1.82 1.31 2.81 2.54 1.18 4.27 2.74 1.70 2.44 1.31 0.52 3.35 2.14 1.10 0.73 0.58 0.45 0.69 1.05 0.34 0.87 1.61 1.79 1.35 1.25 1.87 1.78 1.17 1.62 0.75 5.79 2.10 1.09 2.17 1.55 0.46 2.03 0.69 Configurations Used 04 / 14-18 / 08 04 / 21-25 / 08 Baseline Baseline Baseline SA + PF RS HP-PF SA + PF RS HP-PF 04 / 28 / 08 to 05 / 02 / 08 SA + HP-PF RS HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 31 DA-6 1.20 0.59 0.87 0.54 0.80 0.31 0.36 0.32 0.44 0.46 0.39 0.07 0.32 0.33 0.33 0.34 0.34 0.33 0.01 0.12 0.05 0.09 0.14 0.05 0.09 0.04 Average Indoor/Outdoor Ratio DA-7 DA-8 0.76 74% 0.74 0.49 0.75 0.70 0.77 0.61 0.82 0.65 0.77 0.64 0.03 0.10 0.19 0.09 0.82 0.08 0.78 0.26 0.49 0.06 0.45 0.13 0.55 0.12 0.26 0.08 0.21 0.07 0.17 0.12 0.30 0.14 0.22 0.13 0.19 0.07 0.21 0.11 0.05 0.03 0.19 0.06 0.09 0.10 0.09 0.13 0.09 0.13 0.41 0.15 0.17 0.11 0.14 0.03 DA-6 -20% 41% 13% 46% 20% 31% 64% 68% 56% 54% 61% 7% 68% 67% 67% 66% 66% 67% 1% 88% 95% 91% 86% 95% 91% 4% Average Removal Efficiency DA-7 24% 26% 25% 23% 18% 23% 3% 81% 18% 22% 51% 55% 45% 26% 79% 83% 70% 78% 81% 79% 5% 81% 91% 91% 91% 59% 83% 14% DA-8 26% 51% 30% 39% 35% 36% 10% 91% 92% 74% 94% 87% 88% 8% 93% 88% 86% 87% 93% 89% 3% 94% 90% 87% 88% 85% 89% 3% Del Amo Elementary School - PM10 (from particle mass monitor measurements) Date 4/7/2008 4/8/2008 4/9/2008 4/10/2008 4/11/2008 Average (Week 1) Standard Deviation 4/14/2008 4/15/2008 4/16/2008 4/17/2008 4/18/2008 Average (Week 2) Standard Deviation 4/21/2008 4/22/2008 4/23/2008 4/24/2008 4/25/2008 Average (Week 3) Standard Deviation 4/28/2008 4/29/2008 4/30/2008 5/1/2008 5/2/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (µg/m3) 35.78 45.40 28.99 29.55 41.44 36.23 7.22 37.29 49.49 43.89 43.78 33.84 41.66 6.14 45.13 39.96 33.54 40.68 35.52 38.96 4.56 5.61 49.89 55.49 44.69 52.56 41.65 20.53 School / Class ID 04 / 07-11 / 08 Del Amo / DA-6 Del Amo / DA-7 Del Amo / DA-8 Average Indoor Concentration (µg/m3) DA-6 DA-7 DA-8 35.22 28.42 21.97 55.07 23.04 20.88 24.58 23.40 34.72 22.50 18.44 11.06 25.65 20.46 25.47 31.25 21.46 11.68 13.49 2.04 16.79 31.87 11.31 18.09 81.10 17.11 27.44 75.71 22.75 48.13 11.29 19.71 38.90 16.90 20.51 55.14 15.87 4.77 22.09 4.79 17.94 31.35 14.58 23.99 20.92 18.86 14.53 32.46 18.54 21.02 26.43 21.74 15.42 18.02 10.66 18.58 25.83 16.88 3.94 6.33 4.31 0.69 1.05 0.34 12.13 17.43 13.57 19.75 18.17 23.04 17.16 17.06 21.40 9.90 32.02 19.66 11.93 17.14 15.60 7.40 10.97 9.25 Configurations Used 04 / 14-18 / 08 04 / 21-25 / 08 Baseline Baseline Baseline SA + PF RS HP-PF SA + PF RS HP-PF 04 / 28 / 08 to 05 / 02 / 08 SA + HP-PF RS HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 32 DA-6 0.98 0.72 1.18 0.27 0.79 0.39 0.45 0.37 0.63 0.58 0.51 0.12 0.40 0.60 0.43 0.52 0.43 0.48 0.08 0.12 0.24 0.36 0.38 0.19 0.26 0.11 Average Indoor/Outdoor Ratio DA-7 DA-8 0.79 61% 1.21 0.51 0.85 0.81 0.76 0.62 0.62 0.49 0.85 0.61 0.22 0.13 0.85 0.30 1.64 0.35 1.72 0.52 1.10 0.26 1.15 0.50 1.29 0.38 0.37 0.12 0.69 0.32 0.52 0.47 0.97 0.55 0.65 0.53 0.51 0.30 0.67 0.44 0.19 0.12 0.19 0.06 0.35 0.27 0.33 0.42 0.38 0.48 0.61 0.37 0.37 0.32 0.15 0.16 DA-6 2% 28% -18% 73% 21% 39% 55% 63% 37% 42% 49% 12% 60% 40% 57% 48% 57% 52% 8% 88% 76% 64% 62% 81% 74% 11% Average Removal Efficiency DA-7 21% -21% 15% 24% 38% 15% 22% 15% -64% -72% -10% -15% -29% 37% 31% 48% 3% 35% 49% 33% 19% 81% 65% 67% 62% 39% 63% 15% DA-8 39% 49% 19% 38% 51% 39% 13% 70% 65% 48% 74% 50% 62% 12% 68% 53% 45% 47% 70% 56% 12% 94% 73% 58% 52% 63% 68% 16% Del Amo Elementary School - PM10 (from filter-based measurements) Date 4/7/2008 4/8/2008 4/9/2008 4/10/2008 4/11/2008 Average (Week 1) Standard Deviation 4/14/2008 4/15/2008 4/16/2008 4/17/2008 4/18/2008 Average (Week 2) Standard Deviation 4/21/2008 4/22/2008 4/23/2008 4/24/2008 4/25/2008 Average (Week 3) Standard Deviation 4/28/2008 4/29/2008 4/30/2008 5/1/2008 5/2/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (µg/m3) 11 15 64 30 30 83 61 84 85 73 77 10 100 14 110 61 73 72 38 88 780 67 63 86 217 315 School / Class ID 04 / 07-11 / 08 Del Amo / DA-6 Del Amo / DA-7 Del Amo / DA-8 Average Indoor Concentration (µg/m3) DA-6 DA-7 DA-8 72 44 80 72 22 66 60 11 53 29 65 47 29 43 60 47 44 12 19 29 87 150 11 25 76 52 41 71 42 20 61 32 11 29 53 37 77 38 30 45 17 71 31 11 49 26 14 11 46 21 20 33 43 12 29 21 33 33 22 26 8 13 11 59 30 14 25 36 12 12 22 21 42 28 12 28 28 14 33 29 4 18 5 Configurations Used 04 / 14-18 / 08 04 / 21-25 / 08 Baseline Baseline Baseline SA + PF RS HP-PF SA + PF RS HP-PF 04 / 28 / 08 to 05 / 02 / 08 SA + HP-PF RS HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 33 DA-6 6.55 0.73 3.64 4.11 1.05 0.41 0.49 0.24 0.15 0.47 0.35 0.71 3.50 0.10 0.33 0.16 0.96 1.44 0.13 0.02 0.18 0.33 0.14 0.16 0.11 Average Indoor/Outdoor Ratio DA-7 DA-8 4.00 727% 4.80 1.47 0.45 3.08 2.31 1.81 1.25 0.85 0.72 0.40 1.00 0.54 0.31 1.86 0.42 0.54 0.40 0.70 0.65 0.67 0.03 0.18 0.67 0.33 0.37 0.29 0.67 3.14 3.60 0.13 0.85 0.50 0.38 0.73 0.52 0.28 0.11 1.00 0.19 0.70 0.29 0.46 0.38 0.34 0.05 0.33 0.44 0.33 0.30 0.15 DA-6 -555% 27% -264% 411% -5% 59% 51% 76% 85% 53% 35% 29% -250% 90% 67% 84% 4% 144% 88% 98% 82% 67% 86% 84% 11% Average Removal Efficiency DA-7 DA-8 -300% -627% -380% -47% 55% -208% 231% -81% -25% 15% 28% 60% 0% 54% 69% -86% 58% 46% 60% 30% 65% 33% 97% 82% 33% 67% 63% 29% 33% -214% 360% 87% 15% 50% 62% 27% 48% 28% 89% 0% 81% 30% 71% 54% 38% 66% 95% 67% 56% 67% 70% 15% Hudson Elementary School - Black Carbon Date 5/12/2008 5/13/2008 5/14/2008 5/15/2008 5/16/2008 Average (Week 1) Standard Deviation 5/19/2008 5/20/2008 5/21/2008 5/22/2008 5/23/2008 Average (Week 2) Standard Deviation 5/26/2008 5/27/2008 5/28/2008 5/29/2008 5/30/2008 Average (Week 3) Standard Deviation 6/2/2008 6/3/2008 6/4/2008 6/5/2008 6/6/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (ng/m3) 889 1,765 1,906 3,632 3,756 2,390 1,253 2,007 1,066 1,344 903 731 1,210 499 1,028 778 1,098 1,140 1,011 162 1,128 1,495 1,106 1,320 2,046 1,419 384 School / Class ID 05 / 12-16 / 08 Hudson / H-11 Hudson / H-15 Hudson / H-52 Average Indoor Concentration (ng/m3) H-11 H-15 H-52 557 643 666 983 1,155 1,208 1,031 1,297 1,616 2,026 2,597 2,903 2,163 2,486 2,771 1,352 1,636 1,833 704 863 978 78 97 194 74 71 96 104 75 111 95 67 82 68 71 73 84 76 111 15 12 49 63 59 37 35 48 15 50 55 60 51 54 5 Configurations Used 05 / 19-23 / 08 05 / 26-30 / 08 Baseline Baseline Baseline HP-PF HP-PF HP-PF RS + HP-PF RS + HP-PF RS + HP-PF 72 58 53 41 56 13 45 69 63 58 52 57 9 26 19 23 27 24 4 36 33 18 65 38 38 17 H-11 0.63 0.56 0.54 0.56 0.58 0.57 0.03 0.04 0.07 0.08 0.11 0.09 0.08 0.03 0.06 0.08 0.03 0.03 0.05 0.02 0.03 0.05 0.05 0.03 0.04 0.01 06 / 02-06 / 08 RS + HP-PF RS + HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 34 Average Indoor/Outdoor Ratio H-15 0.72 0.65 0.68 0.72 0.66 0.69 0.03 0.05 0.07 0.06 0.07 0.10 0.07 0.02 H-52 0.75 0.68 0.85 0.80 0.74 0.76 0.06 0.10 0.09 0.08 0.09 0.10 0.09 0.01 H-11 37% 44% 46% 44% 42% 43% 3% 96% 93% 92% 89% 91% 92% 3% 0.07 0.07 0.05 0.04 0.06 0.02 0.04 0.05 0.06 0.04 0.03 0.04 0.01 0.03 0.02 0.02 0.02 0.02 0.00 0.03 0.02 0.02 0.05 0.02 0.03 0.01 94% 92% 97% 97% 95% 2% 97% 95% 95% 97% 96% 1% Average Removal Efficiency H-15 H-52 28% 25% 35% 32% 32% 15% 28% 20% 34% 26% 31% 24% 3% 6% 95% 90% 93% 91% 94% 92% 93% 91% 90% 90% 93% 91% 2% 1% 93% 93% 95% 96% 94% 2% 96% 95% 94% 96% 97% 96% 1% 97% 98% 98% 98% 98% 0% 97% 98% 98% 95% 98% 97% 1% Hudson Elementary School - Ultra Fine Particles Date 5/12/2008 5/13/2008 5/14/2008 5/15/2008 5/16/2008 Average (Week 1) Standard Deviation 5/19/2008 5/20/2008 5/21/2008 5/22/2008 5/23/2008 Average (Week 2) Standard Deviation 5/26/2008 5/27/2008 5/28/2008 5/29/2008 5/30/2008 Average (Week 3) Standard Deviation 6/2/2008 6/3/2008 6/4/2008 6/5/2008 6/6/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (particles/cm3) 14,643 40,865 47,145 44,862 38,322 37,167 13,049 38,368 17,442 80,163 27,886 20,524 36,877 25,505 50,891 36,964 40,035 57,760 46,413 9,639 35,495 32,336 18,941 39,083 43,572 33,885 9,343 School / Class ID 05 / 12-16 / 08 Hudson / H-11 Hudson / H-15 Hudson / H-52 Average Indoor Concentration (particles/cm3) H-11 H-15 H-52 4,083 5,190 8,433 10,619 9,421 19,956 11,563 14,730 19,466 18,397 27,694 29,422 10,435 24,291 29,818 11,019 16,265 21,419 5,083 9,577 8,792 1,835 2,732 5,456 755 2,099 2,033 6,255 4,714 10,681 1,381 1,291 3,353 1,792 1,367 3,214 2,404 2,440 4,947 2,197 1,401 3,434 763 452 367 456 510 174 1,656 53 609 773 814 Configurations Used 05 / 19-23 / 08 05 / 26-30 / 08 Baseline Baseline Baseline HP-PF HP-PF HP-PF RS + HP-PF RS + HP-PF RS + HP-PF 1,295 458 435 566 689 408 430 700 393 570 607 540 127 793 594 572 1,006 741 203 426 432 346 3,727 950 1,176 1,446 06 / 02-06 / 08 RS + HP-PF RS + HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 35 H-11 0.28 0.26 0.25 0.41 0.27 0.29 0.07 0.05 0.04 0.08 0.05 0.09 0.06 0.02 0.01 0.01 0.01 0.01 0.01 0.00 0.09 0.00 0.01 0.03 0.05 Average Indoor/Outdoor Ratio H-15 0.35 0.23 0.31 0.62 0.63 0.43 0.18 0.07 0.12 0.06 0.05 0.07 0.07 0.03 H-52 0.58 0.49 0.41 0.66 0.78 0.58 0.14 0.14 0.12 0.13 0.12 0.16 0.13 0.02 H-11 72% 74% 75% 59% 73% 71% 7% 95% 96% 92% 95% 91% 94% 2% 0.03 0.01 0.01 0.01 0.01 0.01 0.01 0.02 0.02 0.01 0.01 0.02 0.00 0.02 0.02 0.01 0.02 0.02 0.00 0.01 0.01 0.02 0.10 0.02 0.03 0.04 99% 99% 99% 99% 99% 0% 91% 100% 99% 97% 5% Average Removal Efficiency H-15 65% 77% 69% 38% 37% 57% 18% 93% 88% 94% 95% 93% 93% 3% H-52 42% 51% 59% 34% 22% 42% 14% 86% 88% 87% 88% 84% 87% 2% 97% 99% 99% 99% 99% 1% 99% 98% 98% 99% 99% 98% 0% 98% 98% 99% 98% 98% 0% 99% 99% 98% 90% 98% 97% 4% Hudson Elementary School - PM2.5 (count) Date 5/12/2008 5/13/2008 5/14/2008 5/15/2008 5/16/2008 Average (Week 1) Standard Deviation 5/19/2008 5/20/2008 5/21/2008 5/22/2008 5/23/2008 Average (Week 2) Standard Deviation 5/26/2008 5/27/2008 5/28/2008 5/29/2008 5/30/2008 Average (Week 3) Standard Deviation 6/2/2008 6/3/2008 6/4/2008 6/5/2008 6/6/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (particles/ft3) 1,109,627 1,850,803 1,760,128 1,839,611 1,128,564 1,537,747 383,828 660,607 1,477,586 1,613,826 1,530,791 987,855 1,254,133 412,015 440,181 362,533 369,467 529,995 425,544 77,973 1,472,339 2,102,152 1,346,575 1,167,940 998,499 1,417,501 422,678 School / Class ID 05 / 12-16 / 08 Hudson / H-11 Hudson / H-15 Hudson / H-52 Average Indoor Concentration (particles/ft3) H-11 H-15 H-52 576,204 511,734 718,130 757,977 897,986 1,156,730 682,498 838,534 1,199,580 767,375 1,011,002 1,191,460 525,461 723,482 781,768 661,903 796,548 1,009,534 108,096 190,066 238,576 44,930 61,168 59,352 68,443 70,820 131,786 103,883 73,924 125,633 106,300 69,737 94,795 77,470 71,330 70,589 80,205 69,396 96,431 25,650 4,850 32,203 H-11 0.52 0.41 0.39 0.42 0.47 0.44 0.05 0.07 0.05 0.06 0.07 0.08 0.07 0.01 52,467 66,769 33,173 35,119 46,882 15,843 0.12 0.18 0.09 0.07 0.11 0.05 56,800 64,055 77,692 67,890 66,609 8,703 Configurations Used 05 / 19-23 / 08 05 / 26-30 / 08 Baseline Baseline Baseline HP-PF HP-PF HP-PF RS + HP-PF RS + HP-PF RS + HP-PF 51,042 46,541 50,616 28,628 44,207 10,582 38,432 81,009 66,975 56,657 40,091 56,633 18,070 26,303 18,906 17,735 23,916 21,715 4,067 36,347 39,991 19,669 29,352 24,490 29,970 8,331 06 / 02-06 / 08 RS + HP-PF RS + HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 36 0.03 0.05 0.07 0.07 0.05 0.02 Average Indoor/Outdoor Ratio H-15 0.46 0.49 0.48 0.55 0.64 0.52 0.07 0.09 0.05 0.05 0.05 0.07 0.06 0.02 H-52 0.65 0.62 0.68 0.65 0.69 0.66 0.03 0.09 0.09 0.08 0.06 0.07 0.08 0.01 H-11 48% 59% 61% 58% 53% 56% 5% 93% 95% 94% 93% 92% 93% 1% 0.12 0.13 0.14 0.05 0.11 0.04 0.03 0.04 0.05 0.05 0.04 0.04 0.01 0.06 0.05 0.05 0.05 0.05 0.01 0.02 0.02 0.01 0.03 0.02 0.02 0.00 88% 82% 91% 93% 89% 5% 97% 95% 93% 93% 95% 2% Average Removal Efficiency H-15 H-52 54% 35% 51% 38% 52% 32% 45% 35% 36% 31% 48% 34% 7% 3% 91% 91% 95% 91% 95% 92% 95% 94% 93% 93% 94% 92% 2% 1% 88% 87% 86% 95% 89% 4% 97% 96% 95% 95% 96% 96% 1% 94% 95% 95% 95% 95% 1% 98% 98% 99% 97% 98% 98% 0% Hudson Elementary School - PM2.5 (mass) Date 5/12/2008 5/13/2008 5/14/2008 5/15/2008 5/16/2008 Average (Week 1) Standard Deviation 5/19/2008 5/20/2008 5/21/2008 5/22/2008 5/23/2008 Average (Week 2) Standard Deviation 5/26/2008 5/27/2008 5/28/2008 5/29/2008 5/30/2008 Average (Week 3) Standard Deviation 6/2/2008 6/3/2008 6/4/2008 6/5/2008 6/6/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (µg/m3) 8.19 13.38 14.65 20.11 14.66 14.20 4.25 7.86 6.19 14.18 29.03 17.46 14.95 9.11 3.12 2.34 3.36 4.65 3.37 0.96 12.73 15.40 9.62 12.63 16.85 13.45 2.80 School / Class ID 05 / 12-16 / 08 Hudson / H-11 Hudson / H-15 Hudson / H-52 Average Indoor Concentration (µg/m3) H-11 H-15 H-52 2.68 2.55 1.82 3.36 3.62 3.02 2.55 3.74 4.09 3.60 5.52 4.92 3.13 4.81 4.41 3.06 4.05 3.65 0.45 1.15 1.23 0.56 0.84 0.04 1.00 0.82 0.28 1.37 0.79 0.28 2.09 1.00 0.93 1.32 1.20 0.29 1.27 0.93 0.37 0.56 0.17 0.33 H-11 0.33 0.25 0.17 0.18 0.21 0.23 0.06 0.07 0.16 0.10 0.07 0.08 0.10 0.04 0.92 1.48 0.47 0.54 0.86 0.46 0.30 0.63 0.14 0.12 0.30 0.24 1.09 1.43 1.72 1.25 1.38 0.27 Configurations Used 05 / 19-23 / 08 05 / 26-30 / 08 Baseline Baseline Baseline HP-PF HP-PF HP-PF RS + HP-PF RS + HP-PF RS + HP-PF 0.91 0.88 0.84 0.59 0.81 0.15 0.49 1.07 1.10 1.16 0.79 0.92 0.28 0.10 0.07 0.17 1.64 3.05 0.45 0.31 0.00 0.22 0.17 0.23 0.17 06 / 02-06 / 08 RS + HP-PF RS + HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 37 0.07 0.15 0.14 0.07 0.11 0.04 Average Indoor/Outdoor Ratio H-15 0.31 0.27 0.25 0.27 0.33 0.29 0.03 0.11 0.13 0.06 0.03 0.07 0.08 0.04 0.29 0.38 0.25 0.13 0.26 0.10 0.04 0.07 0.11 0.09 0.05 0.07 0.03 H-52 0.22 0.23 0.28 0.24 0.30 0.25 0.03 0.01 0.05 0.02 0.03 0.02 0.02 0.02 H-11 67% 75% 83% 82% 79% 77% 6% 93% 84% 90% 93% 92% 90% 4% 0.03 70% 37% 86% 88% 70% 24% 0.02 0.04 0.03 0.01 0.04 0.02 0.00 0.02 0.01 0.02 0.01 93% 85% 86% 93% 89% 4% Average Removal Efficiency H-15 H-52 69% 78% 73% 77% 75% 72% 73% 76% 67% 70% 71% 75% 3% 3% 89% 99% 87% 95% 94% 98% 97% 97% 93% 98% 92% 98% 4% 2% 71% 62% 75% 87% 74% 10% 96% 93% 89% 91% 95% 93% 3% 97% 98% 96% 97% 1% 96% 98% 100% 98% 99% 98% 1% Hudson Elementary School - PM10 (from particle mass monitor measurements) Date 5/12/2008 5/13/2008 5/14/2008 5/15/2008 5/16/2008 Average (Week 1) Standard Deviation 5/19/2008 5/20/2008 5/21/2008 5/22/2008 5/23/2008 Average (Week 2) Standard Deviation 5/26/2008 5/27/2008 5/28/2008 5/29/2008 5/30/2008 Average (Week 3) Standard Deviation 6/2/2008 6/3/2008 6/4/2008 6/5/2008 6/6/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (µg/m3) 34.99 72.87 57.56 73.56 65.32 60.86 15.86 44.62 29.90 99.04 97.14 62.98 66.74 30.94 21.70 18.66 24.67 28.26 23.32 4.10 47.55 55.46 42.76 48.79 58.51 50.61 6.33 School / Class ID 05 / 12-16 / 08 Hudson / H-11 Hudson / H-15 Hudson / H-52 Average Indoor Concentration (µg/m3) H-11 H-15 H-52 35.13 29.94 9.35 36.97 35.03 14.02 23.93 32.32 13.91 33.55 33.75 11.95 28.13 36.48 18.64 31.54 33.50 13.57 5.38 2.52 3.41 22.67 31.37 3.21 32.03 32.45 7.32 30.71 30.14 5.48 48.80 26.72 6.28 28.55 30.00 3.31 32.55 30.14 5.12 9.77 2.15 1.82 H-11 1.00 0.51 0.42 0.46 0.43 0.56 0.25 0.51 1.07 0.31 0.50 0.45 0.57 0.29 31.71 37.53 20.97 22.01 28.06 7.96 1.46 2.01 0.85 0.78 1.28 0.58 33.55 37.37 40.38 34.10 36.35 3.17 Configurations Used 05 / 19-23 / 08 05 / 26-30 / 08 Baseline Baseline Baseline HP-PF HP-PF HP-PF RS + HP-PF RS + HP-PF RS + HP-PF 35.38 29.44 32.20 18.07 28.77 7.54 23.85 38.16 37.82 34.67 23.89 31.68 7.26 3.04 3.62 6.19 5.26 2.38 10.14 8.32 3.91 7.35 6.60 7.27 2.30 06 / 02-06 / 08 RS + HP-PF RS + HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 38 0.61 0.87 0.83 0.58 0.72 0.15 Average Indoor/Outdoor Ratio H-15 0.86 0.48 0.56 0.46 0.56 0.58 0.16 0.70 1.09 0.30 0.28 0.48 0.57 0.34 1.63 1.58 1.31 0.64 1.29 0.46 0.50 0.69 0.88 0.71 0.41 0.64 0.19 H-52 0.27 0.19 0.24 0.16 0.29 0.23 0.05 0.07 0.24 0.06 0.06 0.05 0.10 0.08 H-11 0% 49% 58% 54% 57% 44% 25% 49% -7% 69% 50% 55% 43% 29% 0.14 -46% -101% 15% 22% -28% 58% 0.15 0.22 0.17 0.04 0.21 0.15 0.09 0.15 0.11 0.14 0.05 39% 13% 17% 42% 28% 15% Average Removal Efficiency H-15 H-52 14% 73% 52% 81% 44% 76% 54% 84% 44% 71% 42% 77% 16% 5% 30% 93% -9% 76% 70% 94% 72% 94% 52% 95% 43% 90% 34% 8% -63% -58% -31% 36% -29% 46% 50% 31% 12% 29% 59% 36% 19% 86% 85% 78% 83% 4% 79% 85% 91% 85% 89% 86% 5% Hudson Elementary School - PM10 (from filter-based measurements) Date 5/12/2008 5/13/2008 5/14/2008 5/15/2008 5/16/2008 Average (Week 1) Standard Deviation 5/19/2008 5/20/2008 5/21/2008 5/22/2008 5/23/2008 Average (Week 2) Standard Deviation 5/26/2008 5/27/2008 5/28/2008 5/29/2008 5/30/2008 Average (Week 3) Standard Deviation 6/2/2008 6/3/2008 6/4/2008 6/5/2008 6/6/2008 Average (Week 4) Standard Deviation Average Outdoor Concentration (µg/m3) 120 110 130 120 10 120 78 60 130 99 97 29 210 120 99 87 129 56 120 110 82 100 120 106 16 School / Class ID 05 / 12-16 / 08 Hudson / H-11 Hudson / H-15 Hudson / H-52 Average Indoor Concentration (µg/m3) H-11 H-15 H-52 68 92 46 20 45 43 24 42 26 26 27 46 35 42 17 13 33 35 24 29 61 11 28 39 29 20 15 27 46 31 11 19 17 31 34 11 20 24 11 90 34 30 27 35 27 30 4 Configurations Used 05 / 19-23 / 08 05 / 26-30 / 08 Baseline Baseline Baseline 53 23 35 19 33 15 41 30 41 36 39 37 5 HP-PF HP-PF HP-PF RS + HP-PF RS + HP-PF RS + HP-PF H-11 0.57 0.42 Average Indoor/Outdoor Ratio H-15 H-52 0.77 0.18 H-11 43% 58% Average Removal Efficiency H-15 H-52 23% 82% 0.00 0.20 100% 80% 0.48 0.40 0.20 0.78 0.47 0.22 0.15 0.36 0.26 67% 29% 71% 63% 82% 70% 80% 73% 8% 0.25 0.19 0.35 0.22 0.25 0.07 0.34 0.27 0.50 0.36 0.33 0.36 0.08 85% 72% 89% 77% 81% 8% 0.33 0.29 0.29 0.37 0.18 0.30 0.20 0.27 0.08 0.15 0.28 0.11 0.23 0.19 0.08 0.27 0.33 0.35 0.23 0.29 0.06 06 / 02-06 / 08 RS + HP-PF RS + HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 39 0.18 73% 67% 65% 78% 71% 6% 82% 52% 40% 80% 22% 53% 78% 85% 64% 26% 75% 81% 65% 78% 75% 7% 66% 73% 50% 64% 68% 64% 8% Dominguez Elementary School - Black Carbon 11/17/2008 11/18/2008 11/19/2008 11/20/2008 11/21/2008 Average (Week 1) Standard Deviation 11/24/2008 11/25/2008 11/26/2008 11/27/2008 11/28/2008 Average (Week 2) Standard Deviation 12/1/2008 12/2/2008 12/3/2008 12/4/2008 12/5/2008 Average (Week 3) Standard Deviation 12/8/2008 12/9/2008 12/10/2008 12/11/2008 12/12/2008 Average (Week 4) Standard Deviation 12/15/2008 12/16/2008 12/17/2008 12/18/2008 12/19/2008 Average (Week 5) Standard Deviation School / Class ID 11 / 18-26 / 08 Dominguez / DZ-7 Dominguez / DZ-9 Dominguez / DZ-11 Average Indoor Concentration (ng/m3) DZ-7 DZ-9 DZ-11 DZ-7 5,137 8,787 9,243 11,210 8,594 2,533 4,474 5,234 2,149 3,951 3,932 6,967 4,250 1,999 2,918 4,005 4,384 5,935 7,292 8,270 6,470 1,688 4,828 4,944 5,096 6,332 6,616 8,928 6,743 1,599 4,903 5,166 0.42 0.45 0.43 0.62 0.48 0.10 0.65 0.77 0.85 0.68 0.79 0.74 0.76 0.08 1.08 0.94 0.99 0.72 0.72 0.80 0.81 0.13 1.10 0.99 58% 55% 57% 38% 52% 10% 35% 23% 15% 32% 21% 26% 24% 8% -8% 6% 1% 28% 28% 20% 19% 13% -10% 1% 4,854 538 8,642 2,434 4,351 3,953 5,734 5,023 2,340 2,112 5,452 2,819 9,169 4,670 4,844 2,769 3,462 768 2,023 268 557 819 766 887 671 290 549 136 515 342 366 169 4,886 82 2,996 217 1,024 354 856 1,089 1,117 269 816 351 892 687 603 279 5,035 186 2,744 187 444 267 346 798 1,092 105 311 249 222 444 266 124 0.71 0.08 0.23 0.11 0.13 0.21 0.13 0.16 0.05 0.14 0.10 0.05 0.06 0.07 0.08 0.04 1.01 0.10 0.35 0.09 0.24 0.09 0.15 0.18 0.11 0.13 0.15 0.12 0.10 0.15 0.13 0.02 1.04 0.08 0.32 0.08 0.10 0.07 0.06 0.12 0.11 0.05 0.06 0.09 0.02 0.10 0.06 0.03 29% 8% 77% 89% 87% 79% 87% 84% 5% 86% 90% 95% 94% 93% 92% 4% -1% 10% 65% 91% 76% 91% 85% 82% 11% 87% 85% 88% 90% 85% 87% 2% -4% 8% 68% 92% 90% 93% 94% 88% 11% 95% 94% 91% 98% 90% 94% 3% 3,274 209 432 187 0.06 0.13 0.06 94% 87% 94% 1,976 4,558 3,269 1,291 397 320 308 95 325 904 554 308 109 234 177 63 0.20 0.07 0.11 0.08 0.16 0.20 0.16 0.03 0.05 0.05 0.05 0.00 80% 93% 89% 8% 84% 80% 84% 3% 95% 95% 95% 0% Average Outdoor Concentration (ng/m3) Date Baseline Baseline Baseline Configurations Used 12 / 01-05 / 08 12 / 08-12 / 08 SA / SA + PF HP-PF HP-PF SA + HP-PF HP-PF RS + HP-PF 12 / 15-19 / 08 SA + HP-PF HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 40 Average Indoor/Outdoor Ratio DZ-9 DZ-11 DZ-7 Average Removal Efficiency DZ-9 DZ-11 Dominguez Elementary School - Ultra Fine Particles Average Outdoor Concentration (particles/cm3) Date 11/17/2008 11/18/2008 11/19/2008 11/20/2008 11/21/2008 Average (Week 1) Standard Deviation 11/24/2008 11/25/2008 11/26/2008 11/27/2008 11/28/2008 Average (Week 2) Standard Deviation 12/1/2008 12/2/2008 12/3/2008 12/4/2008 12/5/2008 Average (Week 3) Standard Deviation 12/8/2008 12/9/2008 12/10/2008 12/11/2008 12/12/2008 Average (Week 4) Standard Deviation 12/15/2008 12/16/2008 12/17/2008 12/18/2008 12/19/2008 Average (Week 5) Standard Deviation School / Class ID 11 / 18-26 / 08 Dominguez / DZ-7 Dominguez / DZ-9 Dominguez / DZ-11 Baseline Baseline Baseline Average Indoor Concentration (particles/cm3) DZ-7 DZ-9 DZ-11 DZ-7 Average Indoor/Outdoor Ratio DZ-9 DZ-11 DZ-7 Average Removal Efficiency DZ-9 DZ-11 25,476 42,651 39,794 38,976 36,724 7,663 34,386 31,838 5,422 9,488 10,924 12,874 9,677 3,158 8,720 10,383 12,344 19,540 24,111 18,814 18,702 4,844 18,565 17,528 12,550 24,676 21,528 22,150 20,226 5,295 24,049 23,812 0.21 0.22 0.27 0.33 0.26 0.05 0.25 0.33 0.48 0.46 0.61 0.48 0.51 0.07 0.54 0.55 0.49 0.58 0.54 0.57 0.55 0.04 0.70 0.75 79% 78% 73% 67% 74% 5% 75% 67% 52% 54% 39% 52% 49% 7% 46% 45% 51% 42% 46% 43% 45% 4% 30% 25% 33,112 1,802 41,439 17,370 16,420 16,970 29,061 24,252 10,957 16,048 34,610 32,657 29,250 23,839 27,281 7,492 9,552 1,176 8,349 1,000 1,805 2,768 2,522 3,289 2,911 1,148 2,241 817 1,146 1,262 1,323 539 18,047 733 9,891 1,962 3,508 2,214 5,130 4,541 3,244 9,995 4,785 5,299 3,203 4,040 5,464 2,653 23,930 168 13,190 1,613 2,413 1,469 2,277 4,192 5,046 440 1,755 2,790 812 2,750 1,709 1,080 0.29 0.05 0.20 0.06 0.11 0.16 0.09 0.12 0.06 0.07 0.06 0.03 0.04 0.05 0.05 0.02 0.55 0.01 0.24 0.11 0.21 0.13 0.18 0.17 0.05 0.62 0.14 0.16 0.11 0.17 0.24 0.22 0.72 0.03 0.32 0.09 0.15 0.09 0.08 0.14 0.10 0.03 0.05 0.09 0.03 0.12 0.06 0.04 71% 5% 80% 94% 89% 84% 91% 88% 6% 93% 94% 97% 96% 95% 95% 2% 45% 1% 76% 89% 79% 87% 82% 83% 5% 38% 86% 84% 89% 83% 76% 22% 28% 3% 68% 91% 85% 91% 92% 86% 10% 97% 95% 91% 97% 88% 94% 4% 26,441 1,066 4,072 1,209 0.04 0.15 0.05 96% 85% 95% 23,513 28,783 26,246 2,641 3,355 1,247 1,889 1,272 2,871 7,747 4,897 2,540 1,283 2,101 1,531 495 0.14 0.04 0.08 0.06 0.12 0.27 0.18 0.08 0.05 0.07 0.06 0.01 86% 96% 92% 6% 88% 73% 82% 8% 95% 93% 94% 1% Configurations Used 12 / 01-05 / 08 12 / 08-12 / 08 SA / SA + PF HP-PF HP-PF SA + HP-PF HP-PF RS + HP-PF 12 / 15-19 / 08 SA + HP-PF HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 41 Dominguez Elementary School - PM2.5 (count) Date Average Outdoor Concentration (particles/ft3) 11/17/2008 11/18/2008 11/19/2008 11/20/2008 11/21/2008 Average (Week 1) Standard Deviation 11/24/2008 11/25/2008 11/26/2008 11/27/2008 11/28/2008 Average (Week 2) Standard Deviation 12/1/2008 12/2/2008 12/3/2008 12/4/2008 12/5/2008 Average (Week 3) Standard Deviation 12/8/2008 12/9/2008 12/10/2008 12/11/2008 12/12/2008 Average (Week 4) Standard Deviation 12/15/2008 12/16/2008 12/17/2008 12/18/2008 12/19/2008 Average (Week 5) Standard Deviation 11 / 18-26 / 08 Dominguez / DZ-7 Dominguez / DZ-9 Dominguez / DZ-11 Baseline Baseline Baseline DZ-7 Average Indoor/Outdoor Ratio DZ-9 DZ-11 DZ-7 Average Removal Efficiency DZ-9 DZ-11 8,866,226 8,237,390 7,625,250 8,242,955 620,507 8,511,436 6,035,358 1,411,242 1,286,754 1,471,170 1,389,722 94,073 1,151,144 949,498 2,600,108 3,015,586 2,634,126 2,749,940 230,684 3,000,744 1,853,996 3,571,960 2,734,509 3,393,425 3,233,298 441,091 3,943,011 2,542,878 0.16 0.16 0.19 0.17 0.02 0.14 0.16 0.29 0.37 0.35 0.33 0.04 0.35 0.31 0.40 0.33 0.45 0.39 0.06 0.46 0.42 84% 84% 81% 87% 9% 86% 84% 71% 63% 65% 75% 17% 65% 69% 60% 67% 55% 71% 20% 54% 58% 7,273,397 1,750,852 7,115,843 6,472,443 10,298,411 10,129,374 5,018,869 7,806,988 2,325,563 1,539,967 2,540,284 425,792 2,040,036 2,259,506 1,761,117 831,458 1,050,321 142,585 375,673 120,635 190,597 294,693 103,392 216,998 116,301 207,455 271,444 74,899 147,307 157,821 171,785 73,119 2,427,370 810,873 1,197,684 344,786 1,628,370 520,489 368,715 812,009 573,363 112,870 165,653 59,053 136,505 151,593 125,135 41,798 3,242,944 990,043 1,210,391 289,496 753,983 458,324 228,546 588,148 403,128 0.33 0.03 0.17 0.05 0.16 0.05 0.07 0.10 0.06 0.07 0.07 0.14 0.07 0.07 0.08 0.03 0.44 0.03 0.17 0.04 0.07 0.05 0.05 0.08 0.05 0.03 0.17 0.03 0.08 0.08 0.07 85% 2% 95% 98% 98% 97% 98% 97% 1% 87% 89% 82% 93% 93% 89% 4% 67% 3% 83% 95% 84% 95% 93% 90% 6% 93% 93% 86% 93% 93% 92% 3% 56% 3% 83% 96% 93% 95% 95% 92% 5% 85,637 73,412 62,538 190,241 102,957 58,950 0.15 0.02 0.05 0.02 0.02 0.03 0.02 0.03 0.01 0.13 0.11 0.18 0.07 0.07 0.11 0.04 518,108 83,088 73,452 54,664 0.16 0.14 0.11 84% 86% 89% 148,282 108,951 113,440 32,828 83,984 203,523 120,320 72,249 1,067 2,678 19,470 30,490 0.16 0.14 0.11 84% 86% 89% 518,108 School / Class ID Average Indoor Concentration (particles/ft3) DZ-7 DZ-9 DZ-11 Configurations Used 12 / 01-05 / 08 12 / 08-12 / 08 SA / SA + PF HP-PF HP-PF SA + HP-PF HP-PF RS + HP-PF 12 / 15-19 / 08 SA + HP-PF HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 42 97% 83% 97% 92% 92% 7% Dominguez Elementary School - PM2.5 (mass) 11/17/2008 11/18/2008 11/19/2008 11/20/2008 11/21/2008 Average (Week 1) Standard Deviation 11/24/2008 11/25/2008 11/26/2008 11/27/2008 11/28/2008 Average (Week 2) Standard Deviation 12/1/2008 12/2/2008 12/3/2008 12/4/2008 12/5/2008 Average (Week 3) Standard Deviation 12/8/2008 12/9/2008 12/10/2008 12/11/2008 12/12/2008 Average (Week 4) Standard Deviation 12/15/2008 12/16/2008 12/17/2008 12/18/2008 12/19/2008 Average (Week 5) Standard Deviation School / Class ID 11 / 18-26 / 08 Dominguez / DZ-7 Dominguez / DZ-9 Dominguez / DZ-11 Average Indoor Concentration (µg/m3) DZ-7 DZ-9 DZ-11 DZ-7 4.11 13.52 30.59 16.15 16.09 10.96 17.12 12.77 4.66 9.93 10.79 11.71 9.27 3.16 11.75 15.62 3.70 6.52 14.26 8.78 8.31 4.48 12.16 11.33 11.47 10.89 12.27 11.07 11.43 0.61 18.94 17.13 1.13 0.73 0.35 0.72 0.74 0.32 0.69 1.22 0.90 0.48 0.47 0.54 0.60 0.20 0.71 0.89 2.79 0.81 0.40 0.69 1.17 1.09 1.11 1.34 -13% 27% 65% 28% 26% 32% 31% -22% 10% 52% 53% 46% 40% 20% 29% 11% -179% 19% 60% 31% -17% 109% -11% -34% 14.95 3.07 17.46 9.45 35.25 27.93 13.35 20.69 10.67 5.77 7.96 1.80 5.82 10.99 6.47 3.37 13.69 2.73 3.27 2.08 3.24 4.50 1.84 2.99 1.07 2.08 2.55 0.84 1.01 0.94 1.49 0.78 11.74 0.58 5.87 0.87 8.29 1.85 1.71 3.72 3.21 1.10 0.87 1.02 0.79 1.35 1.03 0.22 18.04 1.28 3.81 0.87 2.21 1.27 1.22 1.87 1.19 0.79 0.87 1.10 0.88 1.91 1.11 0.46 0.95 0.38 0.19 0.22 0.09 0.16 0.14 0.16 0.05 0.36 0.32 0.47 0.17 0.09 0.28 0.15 0.80 0.13 0.34 0.09 0.24 0.07 0.13 0.17 0.11 0.19 0.11 0.57 0.14 0.12 0.23 0.20 1.22 0.17 0.22 0.09 0.06 0.05 0.09 0.10 0.07 0.14 0.11 0.61 0.15 0.17 0.24 0.21 5% 38% 81% 78% 91% 84% 86% 84% 5% 64% 68% 53% 83% 91% 72% 15% 20% 13% 66% 91% 76% 93% 87% 83% 11% 81% 89% 43% 86% 88% 77% 20% -22% 17% 78% 91% 94% 95% 91% 90% 7% 86% 89% 39% 85% 83% 76% 21% 3.31 0.55 0.41 0.57 0.17 0.12 0.17 83% 88% 83% 1.29 6.18 3.59 2.46 0.73 0.59 0.63 0.09 0.75 1.48 0.88 0.55 0.14 0.68 0.46 0.29 0.57 0.10 0.28 0.25 0.58 0.24 0.31 0.24 0.11 0.11 0.13 0.04 43% 90% 72% 25% 42% 76% 69% 24% 89% 89% 87% 4% Average Outdoor Concentration (µg/m3) Date Baseline Baseline Baseline Configurations Used 12 / 01-05 / 08 12 / 08-12 / 08 SA / SA + PF HP-PF HP-PF SA + HP-PF HP-PF RS + HP-PF 12 / 15-19 / 08 SA + HP-PF HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 43 Average Indoor/Outdoor Ratio DZ-9 DZ-11 DZ-7 Average Removal Efficiency DZ-9 DZ-11 Dominguez Elementary School - PM10 (from particle mass monitor measurements) 11/17/2008 11/18/2008 11/19/2008 11/20/2008 11/21/2008 Average (Week 1) Standard Deviation 11/24/2008 11/25/2008 11/26/2008 11/27/2008 11/28/2008 Average (Week 2) Standard Deviation 12/1/2008 12/2/2008 12/3/2008 12/4/2008 12/5/2008 Average (Week 3) Standard Deviation 12/8/2008 12/9/2008 12/10/2008 12/11/2008 12/12/2008 Average (Week 4) Standard Deviation 12/15/2008 12/16/2008 12/17/2008 12/18/2008 12/19/2008 Average (Week 5) Standard Deviation School / Class ID 11 / 18-26 / 08 Dominguez / DZ-7 Dominguez / DZ-9 Dominguez / DZ-11 Average Indoor Concentration (µg/m3) DZ-7 DZ-9 DZ-11 DZ-7 51.98 52.85 84.85 61.53 62.81 15.32 50.13 48.79 64.34 73.95 62.75 69.08 67.53 5.06 74.55 98.76 34.38 47.85 69.89 58.16 52.57 15.11 76.61 88.63 91.83 79.93 85.40 72.86 82.51 8.06 135.45 128.96 1.24 1.40 0.74 1.12 1.12 0.28 1.49 2.02 0.66 0.91 0.82 0.95 0.83 0.13 1.53 1.82 1.77 1.51 1.01 1.18 1.37 0.34 2.70 2.64 -24% -40% 26% -12% -12% 28% -49% -102% 34% 9% 18% 5% 17% 13% -53% -82% -77% -51% -1% -18% -37% 34% -170% -164% 49.46 0.95 86.09 25.06 57.34 52.74 41.97 52.64 22.45 28.57 39.04 21.52 44.75 46.70 36.12 10.78 86.66 17.12 27.81 26.79 13.40 23.08 14.59 21.13 6.76 21.91 23.09 11.43 11.02 11.24 15.74 6.19 82.62 8.49 54.38 16.38 43.07 13.42 17.31 28.91 18.58 19.27 11.40 16.69 12.31 18.51 15.63 3.59 132.21 4.59 37.73 15.78 18.36 12.93 18.03 20.56 9.84 18.93 17.01 18.02 15.96 24.48 18.88 3.32 1.76 0.38 0.32 1.07 0.23 0.44 0.35 0.48 0.34 0.77 0.59 0.53 0.25 0.24 0.48 0.23 1.67 0.20 0.63 0.65 0.75 0.25 0.41 0.54 0.20 0.67 0.29 0.78 0.28 0.40 0.48 0.23 2.67 0.04 0.44 0.63 0.32 0.25 0.43 0.41 0.15 0.66 0.44 0.84 0.36 0.52 0.56 0.19 -76% 38% 68% -7% 77% 56% 65% 52% 34% 23% 41% 47% 75% 76% 52% 23% -67% 20% 37% 35% 25% 75% 59% 46% 20% 33% 71% 22% 72% 60% 52% 23% -167% 4% 56% 37% 68% 75% 57% 59% 15% 34% 56% 16% 64% 48% 44% 19% 15.49 8.83 8.94 14.83 0.57 0.58 0.96 43% 42% 4% 7.99 27.12 16.87 9.64 14.10 10.76 11.23 2.66 19.02 23.70 17.22 7.54 8.39 14.98 12.73 3.76 1.76 0.40 0.91 0.74 2.38 0.87 1.28 0.97 1.05 0.55 0.85 0.26 -76% 60% 9% 74% -138% 13% -28% 97% -5% 45% 15% 26% Average Outdoor Concentration (µg/m3) Date Baseline Baseline Baseline Configurations Used 12 / 01-05 / 08 12 / 08-12 / 08 SA / SA + PF HP-PF HP-PF SA + HP-PF HP-PF RS + HP-PF 12 / 15-19 / 08 SA + HP-PF HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 44 Average Indoor/Outdoor Ratio DZ-9 DZ-11 DZ-7 Average Removal Efficiency DZ-9 DZ-11 Dominguez Elementary School - PM10 (from filter-based measurements) Average Outdoor Concentration (µg/m3) Date 11/17/2008 11/18/2008 11/19/2008 11/20/2008 11/21/2008 Average (Week 1) Standard Deviation 11/24/2008 11/25/2008 11/26/2008 11/27/2008 11/28/2008 Average (Week 2) Standard Deviation 12/1/2008 12/2/2008 12/3/2008 12/4/2008 12/5/2008 Average (Week 3) Standard Deviation 12/8/2008 12/9/2008 12/10/2008 12/11/2008 12/12/2008 Average (Week 4) Standard Deviation 12/15/2008 12/16/2008 12/17/2008 12/18/2008 12/19/2008 Average (Week 5) Standard Deviation School / Class ID 11 / 18-26 / 08 Dominguez / DZ-7 Dominguez / DZ-9 Dominguez / DZ-11 Baseline Baseline Baseline Average Indoor Concentration (µg/m3) DZ-7 DZ-9 DZ-11 DZ-7 Average Indoor/Outdoor Ratio DZ-9 DZ-11 DZ-7 Average Removal Efficiency DZ-9 DZ-11 720 290 33 200 311 293 180 150 940 100 220 120 345 400 220 220 740 250 150 180 330 277 200 140 310 160 38 25 133 133 180 140 1.31 0.34 6.67 0.60 2.23 2.99 1.22 1.47 1.03 0.86 4.55 0.90 1.83 1.81 1.11 0.93 0.43 0.55 1.15 0.13 0.56 0.43 1.00 0.93 -31% 66% -567% 40% -123% 299% -22% -47% -3% 14% -355% 10% -83% 181% -11% 7% 57% 45% -15% 88% 44% 43% 0% 7% 165 21 180 130 150 140 130 146 21 140 130 91 130 140 126 20 220 0 280 170 110 120 91 154 76 150 100 95 82 78 101 29 170 42 180 110 120 90 87 117 38 120 100 100 77 36 87 32 160 28 82 40 36 36 41 47 20 25 30 34 33 87 42 26 1.34 0.17 1.56 1.31 0.73 0.86 0.70 1.03 0.38 1.07 0.77 1.04 0.63 0.56 0.81 0.23 1.02 0.13 1.00 0.85 0.80 0.64 0.67 0.79 0.14 0.86 0.77 1.10 0.59 0.26 0.71 0.31 0.97 0.05 0.46 0.31 0.24 0.26 0.32 0.32 0.08 0.18 0.23 0.37 0.25 0.62 0.33 0.18 -34% 17% -56% -31% 27% 14% 30% -3% 38% -7% 23% -4% 37% 44% 19% 23% -2% 13% 0% 15% 20% 36% 33% 21% 14% 14% 23% -10% 41% 74% 29% 31% 3% 5% 54% 69% 76% 74% 68% 68% 8% 82% 77% 63% 75% 38% 67% 18% 91 84 70 30 0.92 0.77 0.33 8% 23% 67% 71 93 85 12 79 75 79 5 68 73 70 3 17 23 23 7 1.11 0.81 0.95 0.15 0.96 0.78 0.84 0.10 0.24 0.25 0.27 0.05 -11% 19% 5% 15% 4% 22% 16% 10% 76% 75% 73% 5% Configurations Used 12 / 01-05 / 08 12 / 08-12 / 08 SA / SA + PF HP-PF HP-PF SA + HP-PF HP-PF RS + HP-PF 12 / 15-19 / 08 SA + HP-PF HP-PF RS + HP-PF HP-PF = HVAC-based high-performance panel filter RS = register-based air purifier SA = stand alone system PF = conventional / medium efficiency panel filter 45 APPENDIX B. Daily average concentrations of individual VOCs measured outside Dominguez elementary school and inside three of its classrooms (here referred to as DZ7, DZ-9, and DZ-11) Dominguez Elementary School - Outdoor VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride Methyl-tert-butyl ether(MTBE) trans-1,2-Dichloroethene n-Hexane 1,-Dichloroethane Vinyl acetate 2-Butanone(MEK) cis-1,2-Dichloroethene Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane 1,2-Dichlroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene Bromoform 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl chloride 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.05 0.04 0.03 0.04 0.05 0.07 0.05 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.02 0.04 0.05 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.06 0.06 0.04 0.05 0.10 0.05 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.06 0.10 0.10 0.30 46 11/18/08 11/19/08 11/20/08 7.7 0.7 0.03 0.6 5.7 0.7 4.5 0.7 0.02 0.6 47 36 7.7 0.07 25 0.04 1.2 0.7 11/21/08 11/24/08 11/25/08 0.6 4.7 0.6 0.02 0.6 3.2 0.6 0.02 0.6 0.7 24 15 5.4 0.06 23 0.06 1 0.07 24 0.3 2.1 0.06 16 0.03 0.6 4.9 0.07 20 0.04 1.1 2 0.06 17 0.04 0.6 0.03 14 0.2 1.9 0.06 11 0.01 0.4 1 1 1.2 1.2 0.5 0.4 1.8 3 3 1.9 1.8 0.9 0.5 0.6 0.08 0.2 0.2 0.06 0.2 0.2 0.03 0.3 0.2 0.03 0.2 0.7 0.08 0.9 0.6 0.07 0.7 0.6 0.07 0.7 0.4 0.08 0.3 0.02 0.7 0.07 0.8 0.2 0.07 0.4 0.2 0.06 0.3 1.2 0.1 1.2 0.09 1 0.05 1.4 0.06 0.6 0.03 0.5 0.05 0.2 0.04 0.2 0.2 0.2 0.09 4.8 3.8 5.5 2.2 1.8 0.2 0.2 0.4 0.09 0.01 0.2 0.1 0.08 0.08 0.7 2.3 0.9 1.4 0.8 2.2 0.9 0.7 0.6 1.9 0.8 0.8 0.01 0.8 2.6 1 0.4 0.4 1.2 0.5 0.9 0.3 1 0.4 0.2 0.8 0.2 0.8 0.8 0.2 0.7 0.6 0.9 0.3 0.9 0.4 0.1 0.4 0.3 0.09 0.3 0.09 0.1 0.09 0.07 0.04 5.2 0.3 0.02 0.6 0.01 0.03 0.02 Dominguez Elementary School - Outdoor VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride Methyl-tert-butyl ether(MTBE) trans-1,2-Dichloroethene n-Hexane 1,-Dichloroethane Vinyl acetate 2-Butanone(MEK) cis-1,2-Dichloroethene Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane 1,2-Dichlroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene Bromoform 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl chloride 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.05 0.04 0.03 0.04 0.05 0.07 0.05 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.02 0.04 0.05 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.06 0.06 0.04 0.05 0.10 0.05 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.06 0.10 0.10 0.30 47 11/26/08 12/1/08 12/2/08 1 0.02 0.6 4.6 0.5 0.01 0.5 1.5 0.5 0.02 0.5 0.1 0.05 0.5 0.06 0.07 7 0.2 0.6 0.1 13 0.08 0.3 1.4 0.3 0.3 2.5 5.4 2.3 0.03 21 0.4 4.8 0.07 15 0.03 0.2 0.07 14 0.2 1.6 0.07 0.3 12/3/08 1.4 0.07 18 0.03 0.4 6.4 0.2 1.1 20 0.06 0.08 0.7 0.07 0.2 0.1 0.2 0.07 0.3 0.03 1.2 0.05 0.2 0.08 0.08 0.1 0.9 4.2 0.6 0.9 0.03 0.3 0.02 0.2 0.09 0.4 0.3 0.07 0.04 0.2 0.4 0.2 0.09 0.6 1.9 0.8 0.8 0.08 0.2 0.1 0.06 0.2 0.4 0.2 0.1 0.2 0.05 0.2 0.6 0.1 0.6 0.08 0.02 0.08 0.05 0.06 0.02 0.2 0.04 0.4 0.06 0.04 0.1 0.06 0.1 0.06 0.1 0.04 0.05 0.04 0.04 0.07 0.05 12/4/08 12/5/08 1.4 0.4 0.04 0.7 2.6 0.6 0.05 0.5 0.04 11 0.2 1.7 0.07 17 0.07 0.4 0.04 0.03 0.3 0.03 0.06 4.4 0.03 0.2 0.05 0.03 0.2 0.07 0.2 0.05 0.3 0.09 0.04 0.04 0.2 0.03 1.2 0.03 0.04 0.9 0.07 0.02 0.03 0.04 0.2 0.6 0.3 0.1 0.02 0.06 0.2 0.2 0.04 0.05 0.05 0.04 0.06 0.05 13 0.4 1.5 0.08 19 0.1 0.5 0.5 1.5 0.2 0.08 0.3 0.06 0.4 0.8 0.05 0.09 2.4 0.03 0.1 0.09 0.03 0.3 1 0.4 1 0.04 0.3 0.1 0.3 0.03 0.04 0.03 0.04 0.04 Dominguez Elementary School - Outdoor VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride Methyl-tert-butyl ether(MTBE) trans-1,2-Dichloroethene n-Hexane 1,-Dichloroethane Vinyl acetate 2-Butanone(MEK) cis-1,2-Dichloroethene Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane 1,2-Dichlroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene Bromoform 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl chloride 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.05 0.04 0.03 0.04 0.05 0.07 0.05 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.02 0.04 0.05 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.06 0.06 0.04 0.05 0.10 0.05 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.06 0.10 0.10 0.30 48 12/8/08 12/9/08 12/10/08 12/11/08 12/12/08 12/15/08 1.2 0.5 0.03 0.4 0.6 0.03 0.04 1.6 0.5 0.03 0.4 2.3 0.4 0.02 0.5 2.6 0.4 0.03 0.4 1.1 0.4 3.1 0.3 0.7 0.08 4.3 0.03 0.2 13 0.3 3.3 0.08 23 0.05 0.5 6.3 0.3 1 0.08 9.8 0.04 0.3 9.4 9.1 1.6 0.05 13 0.04 0.5 0.06 11 0.04 0.5 14 0.2 4.6 0.05 8 0.01 0.2 0.8 0.2 0.7 0.8 0.2 0.4 1.3 0.8 1.8 1.5 0.8 0.4 0.07 1.4 0.1 0.2 0.04 0.1 0.08 0.1 0.5 0.07 0.5 0.2 0.07 0.3 0.05 0.4 0.4 0.06 0.4 0.1 0.06 0.2 0.3 0.02 1.5 0.05 0.4 0.02 0.6 0.03 0.7 0.03 0.3 0.02 0.04 0.1 0.05 0.08 0.2 0.7 4.5 1.3 2.2 2.2 0.8 0.03 0.03 0.1 0.1 0.04 0.3 0.08 0.3 0.08 0.1 0.04 0.01 0.1 0.3 0.1 0.05 0.6 2.1 0.8 1.7 0.2 0.6 0.2 0.5 0.4 1.1 0.4 0.2 0.4 1.2 0.4 0.3 0.2 0.5 0.2 0.1 0.6 0.2 0.6 0.2 0.05 0.2 0.3 0.09 0.3 0.04 0.02 0.01 0.04 0.02 0.01 0.05 0.02 0.1 0.03 0.1 0.01 0.02 0.01 0.02 0.06 0.4 0.1 0.4 0.03 0.05 0.03 0.08 0.5 0.2 0.05 0.2 0.02 0.03 Dominguez Elementary School - Outdoor VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride Methyl-tert-butyl ether(MTBE) trans-1,2-Dichloroethene n-Hexane 1,-Dichloroethane Vinyl acetate 2-Butanone(MEK) cis-1,2-Dichloroethene Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane 1,2-Dichlroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene Bromoform 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl chloride 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.05 0.04 0.03 0.04 0.05 0.07 0.05 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.02 0.04 0.05 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.06 0.06 0.04 0.05 0.10 0.05 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.06 0.10 0.10 0.30 49 12/16/08 12/17/08 12/18/08 12/19/08 2.4 0.4 0.4 1.4 0.4 2.6 0.4 0.5 0.5 0.4 0.4 7.6 0.2 1.7 0.06 10 1.7 0.2 4.3 0.2 8.4 0.2 1.4 0.05 1.2 13 0.3 0.08 6.8 0.02 0.1 0.3 0.3 0.03 0.2 0.3 0.9 0.1 1.1 1.3 0.2 0.06 0.5 0.05 0.1 0.05 0.2 0.05 0.4 0.5 0.02 0.1 0.3 0.6 0.02 1.4 0.2 0.8 1.8 0.2 0.3 0.04 0.1 0.06 0.2 0.7 0.3 0.2 0.03 0.09 0.04 0.1 0.4 0.2 0.04 0.3 0.9 0.4 0.7 0.2 0.03 0.01 0.03 0.1 0.04 0.1 0.3 0.08 0.3 0.01 0.02 0.2 0.01 Dominguez Elementary School - Outdoor VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 2,2,3,3-Tetramethyl butane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2,4-Dimethyl hexane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Pentene 3-Methyl hexane 3-Methyl pentane Acetaldehyde Butanal Butane Difluorochloromethane Heptanal Hexamethyl cyclotrisiloxane Isobutane Limonene Methyl cyclohexane Methyl cyclopentane Octamethyl cyclotrisiloxane Pentane Trimethyl silanol Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 11/18/08 11/19/08 11/20/08 11/21/08 N/A 2.1 2.1 2.1 2.5 N/A 1.4 1.2 1 1.5 N/A 7.8 7.9 9.2 N/A 1.2 N/A N/A 3.2 3.3 3.5 3.9 N/A N/A N/A N/A 1.5 1.2 1.1 1.5 N/A N/A 1.7 1.8 2 2.1 N/A N/A 1.6 2.1 N/A N/A N/A N/A 6.8 8.6 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 5.5 11/24/08 11/25/08 4.2 3.6 1.6 1.3 9 1.2 1.8 6.5 3.5 2.9 5.6 2.6 4.4 5.1 4.5 4.6 1.4 1.5 1.8 1.8 3.5 3.7 3.1 4.1 2.6 2.3 Dominguez Elementary School - Outdoor VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 2,2,3,3-Tetramethyl butane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2,4-Dimethyl hexane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Pentene 3-Methyl hexane 3-Methyl pentane Acetaldehyde Butanal Butane Difluorochloromethane Heptanal Hexamethyl cyclotrisiloxane Isobutane Limonene Methyl cyclohexane Methyl cyclopentane Octamethyl cyclotrisiloxane Pentane Trimethyl silanol Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 2.4 N/A N/A 2.6 N/A N/A 1.1 N/A N/A N/A N/A N/A N/A N/A N/A 1 N/A N/A 2.2 N/A N/A N/A N/A N/A N/A 50 11/26/08 12/1/08 12/2/08 12/3/08 12/4/08 12/5/08 1.2 1 2.6 8.8 1.8 2.2 1.8 3.3 3.2 1.6 1.1 2 2 2.1 8.6 4 2.8 2.4 1.3 1.1 1.7 1 2.6 2.4 1.6 2.4 1.2 1.9 2.3 2.4 5.8 1.7 1.1 4.8 Dominguez Elementary School - Outdoor VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 2,2,3,3-Tetramethyl butane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2,4-Dimethyl hexane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Pentene 3-Methyl hexane 3-Methyl pentane Acetaldehyde Butanal Butane Difluorochloromethane Heptanal Hexamethyl cyclotrisiloxane Isobutane Limonene Methyl cyclohexane Methyl cyclopentane Octamethyl cyclotrisiloxane Pentane Trimethyl silanol Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.4 N/A N/A 1.4 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 12/8/08 12/9/08 12/10/08 12/11/08 12/12/08 1.1 1.2 4 3.9 2.5 2.6 1.4 1.5 2.5 2.6 2.1 1.4 1.4 1.5 1.2 1.2 1.7 1.7 1.9 1.2 4.8 1.5 1.1 3.5 1 Dominguez Elementary School - Outdoor VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 2,2,3,3-Tetramethyl butane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2,4-Dimethyl hexane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Pentene 3-Methyl hexane 3-Methyl pentane Acetaldehyde Butanal Butane Difluorochloromethane Heptanal Hexamethyl cyclotrisiloxane Isobutane Limonene Methyl cyclohexane Methyl cyclopentane Octamethyl cyclotrisiloxane Pentane Trimethyl silanol Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 51 12/16/08 12/17/08 12/18/08 12/19/08 1.1 1.3 1.5 1.1 1.1 1.4 12/15/08 Dominguez Elementary School - Room 7 (DZ-7) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone 1,1-Dichloroethene Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 0.5 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.05 0.30 0.04 0.03 0.06 0.08 0.03 0.04 0.04 0.03 0.07 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.04 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.04 0.05 0.10 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 52 11/18/08 11/19/08 11/20/08 11/21/08 11/24/08 11/25/08 9.5 0.7 4.4 0.6 5.9 0.6 0.8 0.9 5.3 0.7 0.02 0.6 140 310 59 2.8 0.5 0.02 0.92 0.02 480 14 0.08 37 35 0.08 44 3.4 0.6 0.01 0.7 0.02 480 0.3 39 0.06 22 31 0.06 35 6.9 0.06 16 32 0.06 33 0.08 1.8 2.2 2.5 1 0.1 1.7 0.08 1 1 2.3 0.7 0.07 0.4 0.07 2.2 1.8 2.5 0.5 0.1 0.6 0.06 0.7 0.8 1.2 0.3 0.06 0.4 0.1 0.5 0.5 2.7 0.3 0.05 0.4 1.5 0.07 2.6 2.1 0.05 0.8 0.07 1.9 1 0.05 0.5 0.06 0.8 1 0.03 0.4 0.06 0.8 0.04 3.3 0.07 1.1 1.6 0.06 0.4 0.4 0.4 4 0.2 0.9 8.3 4.2 2.8 7.2 4.5 3.2 0.3 0.1 0.1 0.08 0.2 0.4 0.2 0.1 0.5 0.1 1.1 3.9 1.4 1.3 0.6 1.8 0.7 0.5 0.5 1.5 0.7 0.4 1.1 3.7 1.4 0.7 0.7 2.3 0.8 0.4 0.5 1.4 0.6 0.6 1.3 0.4 1.4 0.7 0.2 0.8 0.6 0.6 1.2 0.4 1.3 0.7 0.2 0.7 0.5 0.2 0.6 0.5 0.7 0.5 0.7 0.2 0.8 0.02 0.08 0.6 0.9 1.4 0.3 0.06 0.2 0.02 0.5 0.07 0.8 0.02 380 0.6 0.06 Dominguez Elementary School - Room 7 (DZ-7) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone 1,1-Dichloroethene Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 0.5 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.05 0.30 0.04 0.03 0.06 0.08 0.03 0.04 0.04 0.03 0.07 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.04 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.04 0.05 0.10 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 53 11/26/08 12/1/08 12/2/08 12/3/08 12/4/08 12/5/08 1.1 0.5 0.02 0.9 0.02 130 0.2 16 0.06 17 3 0.4 0.5 0.4 0.03 1 3.6 0.04 0.7 1.4 0.05 0.7 49 0.3 7.6 0.04 0.2 0.2 0.5 0.3 0.7 0.04 32 0.8 3.9 6.6 19 6.8 160 0.1 5.9 0.05 10 0.02 0.2 0.4 3.3 0.02 0.2 0.07 0.2 0.08 0.2 0.1 1.4 49 0.7 2.5 0.05 12 0.02 0.07 0.2 0.1 1.4 0.04 0.04 0.08 0.04 0.4 0.1 0.03 0.1 0.04 40 0.2 0.06 0.2 0.06 0.3 0.02 0.3 0.05 0.2 0.1 0.4 0.1 0.1 1.3 0.9 0.1 0.2 0.02 0.03 0.2 0.02 0.2 0.6 0.3 0.2 0.1 0.4 0.2 0.1 0.03 0.06 0.03 0.02 0.3 0.08 0.3 0.2 0.04 0.2 0.04 0.01 0.04 0.8 0.02 0.1 0.08 0.3 0.02 0.03 0.2 0.04 0.03 0.08 0.2 0.08 0.05 0.03 0.1 0.05 0.1 0.03 0.06 0.03 0.04 0.04 0.03 0.2 0.03 0.03 0.06 0.1 0.07 0.04 0.05 0.03 0.05 0.03 0.06 0.03 0.04 0.03 0.1 0.03 9 0.09 0.4 0.2 0.4 0.1 0.03 0.3 0.2 0.04 0.1 0.02 0.7 0.05 0.03 0.1 0.3 0.2 0.1 0.03 0.2 0.07 0.2 0.03 0.05 0.03 0.04 0.03 Dominguez Elementary School - Room 7 (DZ-7) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone 1,1-Dichloroethene Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 0.5 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.05 0.30 0.04 0.03 0.06 0.08 0.03 0.04 0.04 0.03 0.07 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.04 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.04 0.05 0.10 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 54 12/8/08 12/9/08 12/10/08 12/11/08 12/12/08 12/15/08 1 0.03 0.7 1.8 6.3 0.02 0.6 1.7 0.6 0.8 0.5 0.5 0.6 0.5 0.6 26 1.1 3.7 0.03 14 35 0.3 4.6 0.03 9.1 34 0.2 3.6 0.02 9.2 68 0.2 14 27 0.2 3.6 20 10 0.05 0.5 0.1 1.3 0.04 0.3 0.09 0.2 0.04 0.4 0.1 0.6 0.02 0.6 0.2 0.7 0.1 0.02 0.3 0.09 0.5 22 0.3 3.6 0.03 11 0.3 0.07 0.3 0.08 1 0.02 0.06 0.03 0.1 0.03 0.1 0.03 0.1 0.1 0.1 0.3 0.06 0.02 0.1 0.02 0.2 0.02 0.5 0.2 0.1 0.1 0.04 0.08 0.01 0.03 3 0.07 0.3 0.5 0.4 0.7 0.4 0.4 0.1 0.02 0.01 0.05 0.1 0.06 0.02 0.2 0.04 0.02 0.02 0.08 0.07 0.08 0.2 0.1 0.07 0.06 0.2 0.08 0.1 0.1 0.3 0.1 0.08 0.07 0.2 0.08 0.05 0.07 0.2 0.1 0.06 0.05 0.02 0.05 0.01 0.04 0.01 0.02 0.02 0.08 0.03 0.08 0.01 0.05 0.01 0.02 0.02 0.07 0.03 0.07 0.1 0.05 0.2 0.07 0.07 0.1 0.04 0.1 0.02 0.02 0.01 0.07 0.02 0.01 0.03 Dominguez Elementary School - Room 7 (DZ-7) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone 1,1-Dichloroethene Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 0.5 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.05 0.30 0.04 0.03 0.06 0.08 0.03 0.04 0.04 0.03 0.07 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.04 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.04 0.05 0.10 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 55 12/16/08 12/17/08 12/18/08 12/19/08 0.4 1 0.4 0.4 1.5 0.4 0.6 0.5 0.5 0.6 110 0.2 5.4 0.02 7.9 54 0.2 4.6 0.04 6.5 110 0.2 5.6 0.02 11 56 0.2 3.6 0.06 0.4 0.01 0.2 0.1 0.4 0.4 0.03 0.2 0.09 0.8 0.8 0.08 14 0.3 0.1 0.8 0.2 0.2 0.1 0.02 0.3 0.1 0.05 0.05 0.04 0.5 0.6 1.5 0.9 0.04 0.1 0.2 0.02 0.09 0.3 0.4 0.07 0.1 0.3 0.1 0.07 0.05 0.2 0.06 0.02 0.1 0.4 0.2 0.2 0.2 0.06 0.2 0.02 0.05 0.02 0.04 0.1 0.04 0.1 0.06 0.02 0.06 0.2 0.05 0.2 0.04 0.04 0.04 Dominguez Elementary School - Room 7 (DZ-7) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS .alpha.-Pinene 1,3-Pentadiene 1-Butanol 1R-.alpha.-Pinene 2,2,3,3-Tetramethyl butane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2,4-bis(trimethylsiloxane) Benzaldehyde 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl hexane 3-Methyl pentane 4-Ethyl-2,2,6,6-tetramethyl heptane Acetaldehyde Benzaldehyde Butanal Butane Butyl ester acetic acid Decanal Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclopentane Nonanal Ocatanal Octamethyl cyclotrisiloxane Pentane Tridecane Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 16 N/A N/A 2.1 N/A N/A 6.4 N/A N/A N/A N/A 2.5 N/A N/A 3.5 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 7 3.3 12 5 3.8 N/A N/A 3 1.3 1.3 2.3 1.3 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 11/18/08 11/19/08 11/20/08 11/21/08 11/24/08 2.9 1.8 1.5 1.7 4 2.9 2.7 1.9 1.2 28 6.9 6 12 7.3 2.8 2.4 4.9 2.8 3.2 1.3 2.6 4.4 2.5 2 1.2 2.6 1.5 1.5 1.4 1.6 1.3 2.1 2 2.4 2.5 1.9 N/A 11 5.3 5.4 8.4 5.3 N/A 8.8 5.5 1.5 2.6 56 11/25/08 1.8 1.7 1.5 3.1 3.6 1 1.2 1.8 1.2 2.2 2.3 1.8 68 6.1 3.1 5.4 3.1 2.8 Dominguez Elementary School - Room 7 (DZ-7) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS .alpha.-Pinene 1,3-Pentadiene 1-Butanol 1R-.alpha.-Pinene 2,2,3,3-Tetramethyl butane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2,4-bis(trimethylsiloxane) Benzaldehyde 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl hexane 3-Methyl pentane 4-Ethyl-2,2,6,6-tetramethyl heptane Acetaldehyde Benzaldehyde Butanal Butane Butyl ester acetic acid Decanal Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclopentane Nonanal Ocatanal Octamethyl cyclotrisiloxane Pentane Tridecane Reporting Limit (ppbv) Method Detection limit (ppbv) 11/26/08 N/A N/A 1.2 N/A N/A 2.2 N/A N/A 1.8 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1 N/A N/A 1.5 N/A N/A 57 2.6 2 12/1/08 12/2/08 12/3/08 2.8 2.1 2.7 2.7 3.4 1.8 12/4/08 12/5/08 1.3 1.5 1.1 1 1.9 1.1 1.6 1.6 1.3 1.8 1.5 37 1.7 2.6 1.1 1.1 1.9 Dominguez Elementary School - Room 7 (DZ-7) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS .alpha.-Pinene 1,3-Pentadiene 1-Butanol 1R-.alpha.-Pinene 2,2,3,3-Tetramethyl butane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2,4-bis(trimethylsiloxane) Benzaldehyde 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl hexane 3-Methyl pentane 4-Ethyl-2,2,6,6-tetramethyl heptane Acetaldehyde Benzaldehyde Butanal Butane Butyl ester acetic acid Decanal Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclopentane Nonanal Ocatanal Octamethyl cyclotrisiloxane Pentane Tridecane Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 2.4 N/A N/A 2 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 58 12/8/08 12/9/08 12/10/08 1.9 4.1 12/11/08 12/12/08 2.4 1.1 4.3 1 1.8 1.9 1.9 1.9 1.3 1.8 1.3 12/15/08 Dominguez Elementary School - Room 7 (DZ-7) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS .alpha.-Pinene 1,3-Pentadiene 1-Butanol 1R-.alpha.-Pinene 2,2,3,3-Tetramethyl butane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2,4-bis(trimethylsiloxane) Benzaldehyde 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl hexane 3-Methyl pentane 4-Ethyl-2,2,6,6-tetramethyl heptane Acetaldehyde Benzaldehyde Butanal Butane Butyl ester acetic acid Decanal Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclopentane Nonanal Ocatanal Octamethyl cyclotrisiloxane Pentane Tridecane Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 59 12/16/08 12/17/08 12/18/08 12/19/08 1.2 1 Dominguez Elementary School - Room 9 (DZ-9) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) cis-1,2-Dichloroethene Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 2-Hexanone(MBK) Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.03 0.07 0.05 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.04 0.06 0.04 0.05 0.04 0.05 0.04 0.06 0.04 0.05 0.10 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 60 11/18/08 11/19/08 0.6 0.7 0.7 200 580 17 25 0.09 1.2 1.1 1.8 160 0.06 27 0.06 1 1.3 2.2 1.6 0.08 0.5 0.7 0.07 0.2 0.8 0.07 1.2 1.2 0.09 0.5 11/20/08 4.1 0.6 0.02 0.7 11/21/08 11/24/08 11/25/08 0.02 0.7 4.4 0.6 0.02 0.8 2.8 0.5 0.02 0.8 0.05 150 0.3 20 0.06 17 0.04 0.6 1.4 2.5 120 520 92 0.06 27 0.09 1.4 1.2 2.3 270 0.06 31 0.05 0.6 0.7 2.3 0.02 180 0.2 200 0.06 26 0.04 0.4 0.5 2.5 0.8 0.09 0.4 0.02 1.7 0.07 0.9 1.3 0.06 0.4 0.4 0.05 0.3 0.3 0.05 0.2 1.7 0.07 4.7 1.1 0.07 1.3 0.3 0.07 0.1 0.02 0.8 0.07 0.9 1.1 0.05 0.3 0.5 0.06 0.6 0.8 0.03 0.4 0.3 0.06 5.4 5.1 4.3 6.4 3.8 3 0.3 0.1 0.2 0.2 0.1 0.2 0.2 0.4 0.1 0.4 0.09 0.7 2.4 0.9 1.1 0.7 2 0.9 0.6 0.6 1.8 0.7 0.6 0.9 2.9 1.1 0.5 0.5 1.7 0.7 1.1 0.4 1.1 0.5 0.4 0.8 0.2 0.9 0.7 0.2 0.7 0.6 0.6 0.9 0.3 1 0.6 0.2 0.7 0.4 0.1 0.5 0.08 0.09 0.09 0.1 0.1 0.08 0.03 0.6 0.06 0.4 0.03 Dominguez Elementary School - Room 9 (DZ-9) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) cis-1,2-Dichloroethene Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 2-Hexanone(MBK) Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.03 0.07 0.05 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.04 0.06 0.04 0.05 0.04 0.05 0.04 0.06 0.04 0.05 0.10 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 61 11/26/08 12/1/08 12/2/08 12/3/08 12/4/08 12/5/08 0.9 0.5 0.02 0.7 4 0.5 1.1 0.4 0.02 0.6 0.7 0.4 0.04 0.8 0.04 0.05 59 0.3 8.7 0.09 7.8 0.07 0.2 0.2 0.8 0.02 1.1 0.5 0.05 0.6 2.6 0.6 0.05 0.6 61 0.3 4.2 0.08 23 0.09 0.4 0.3 4 84 0.4 39 0.1 16 0.1 0.5 0.5 1 110 0.2 41 0.06 13 0.03 0.2 0.2 0.4 0.7 0.05 210 15 0.06 23 0.04 0.4 1.4 2.2 82 0.2 5.4 0.07 16 0.05 0.1 0.2 2.8 0.4 0.3 0.06 0.4 0.1 0.06 0.7 0.07 0.2 0.02 0.1 1.2 0.04 0.2 1.2 4.9 0.8 0.1 0.06 0.3 0.02 0.2 0.4 0.2 0.1 0.6 1.9 0.8 0.9 0.09 0.2 0.1 0.07 0.1 0.3 0.2 0.08 0.2 0.4 0.2 0.09 0.2 0.05 0.2 0.7 0.2 0.7 0.1 0.03 0.1 0.06 0.02 0.1 0.03 0.2 0.09 0.3 0.03 0.04 0.03 0.04 0.03 0.2 0.06 0.2 0.03 0.04 0.03 0.04 0.03 0.03 0.2 0.08 0.1 0.07 0.6 0.2 0.2 0.1 0.08 0.2 0.03 0.2 0.02 0.6 0.02 0.05 0.2 0.07 0.2 0.4 0.07 0.2 1.2 0.02 0.4 0.07 0.02 0.4 0.07 0.4 0.9 0.05 0.08 0.02 2.6 0.1 0.02 0.03 0.4 1.1 0.4 0.9 0.04 0.4 0.1 0.4 0.03 0.05 0.03 0.03 0.03 Dominguez Elementary School - Room 9 (DZ-9) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) cis-1,2-Dichloroethene Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 2-Hexanone(MBK) Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.03 0.07 0.05 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.04 0.06 0.04 0.05 0.04 0.05 0.04 0.06 0.04 0.05 0.10 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 62 12/8/08 12/9/08 12/10/08 12/11/08 12/12/08 12/15/08 0.5 0.03 0.5 0.6 0.03 0.5 1.4 0.5 0.03 0.4 4.9 0.7 2.6 0.4 1.1 0.4 0.5 0.4 0.5 68 0.3 4.9 0.09 14 0.03 0.3 0.2 1.7 30 0.3 43 0.09 15 0.05 0.6 0.5 0.9 110 68 0.4 6.2 0.06 25 0.03 0.8 0.9 2 21 0.2 36 0.06 17 110 0.2 20 0.05 12 0.6 0.6 2.4 0.2 0.2 1.3 0.1 0.06 0.3 0.06 0.7 0.3 0.07 0.2 0.2 0.08 0.3 0.02 0.08 0.3 0.08 0.5 0.8 0.04 0.1 1.1 0.07 1.6 0.4 0.02 0.3 0.6 0.06 0.8 1.1 0.06 0.1 0.4 0.06 0.6 0.6 0.02 0.1 0.2 0.05 0.6 0.3 0.02 0.2 1 2.2 1.4 4.4 2.3 0.8 0.1 0.03 0.08 0.2 0.04 0.1 0.1 0.4 0.09 0.2 0.03 0.1 0.4 0.2 0.07 0.3 1 0.4 0.4 0.2 0.8 0.2 0.6 0.6 1.9 0.7 0.7 0.3 1.1 0.4 0.3 0.1 0.4 0.2 0.1 0.1 0.04 0.1 0.01 0.02 0.01 0.02 0.3 0.1 0.3 0.01 0.02 0.01 0.02 0.01 0.2 0.06 0.2 0.6 0.2 0.6 0.3 0.1 0.4 0.1 0.05 0.2 0.02 0.04 0.02 0.04 0.02 0.03 0.01 0.04 0.02 53 0.08 15 0.05 0.2 0.6 1.2 0.02 0.01 0.03 Dominguez Elementary School - Room 9 (DZ-9) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) cis-1,2-Dichloroethene Ethyl acetate Chloroform Tetrahydrofuran 1,1,1-Trichloroethane Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 2-Hexanone(MBK) Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.03 0.07 0.05 0.07 0.03 0.07 0.04 0.04 0.04 0.04 0.02 0.04 0.06 0.04 0.05 0.04 0.05 0.04 0.06 0.04 0.05 0.10 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 63 12/16/08 12/17/08 12/18/08 12/19/08 1.7 0.4 2.6 0.4 0.4 0.4 0.4 0.02 0.5 0.4 0.4 76 0.2 2.7 0.05 5.8 0.01 0.1 0.1 0.2 52 0.2 9.6 0.05 9.9 0.02 0.1 0.3 0.9 40 0.2 31 0.05 16 0.03 0.3 0.4 1 0.3 0.05 1.3 0.1 0.2 0.06 3.9 0.1 0.02 0.05 0.1 0.3 0.05 1.4 0.6 0.02 0.06 1.7 0.4 6.5 2 0.06 0.02 0.2 0.8 0.3 0.25 0.05 0.2 0.08 0.03 0.2 0.6 0.3 0.06 0.3 1 0.4 0.8 0.3 0.09 0.2 0.06 0.02 0.07 0.2 0.3 0.2 0.3 0.09 0.3 0.02 0.02 0.02 0.03 54 0.2 2.4 19 0.02 0.4 0.3 2 0.5 0.3 0.05 3.7 0.6 0.3 0.04 0.02 Dominguez Elementary School - Room 9 (DZ-9) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 4-Bromofluorobenzene 1,3-Dimethyl cyclohexane 1,3-Pentadiene 1,4-Pentadiene 1-Butanol 1-Dodecene 1S-.alpha.-Pinene 2,2,3,3-Tetramethyl butane 2,2,4,6,6-Pentamethyl heptane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3,3-Trimethyl pentane 2,3-Dimethyl pentane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl butanal 3-Methyl hexane 3-Methyl pentane Acetaldehyde Benzaldehyde Butanal Butane Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclohexane Methyl cyclopentane Nonanal Ocatanal Octamethyl cyclotrisiloxane Octane Pentane trans-1,4-Dimethyl cyclohexane Reporting Limit (ppbv) Method Detection limit (ppbv) 11/18/08 11/19/08 11/20/08 11/21/08 11/24/08 11/25/08 N/A N/A 9.84 10.13 10.69 11.36 11.97 11.86 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.5 N/A N/A 8.2 7.4 N/A N/A 1.3 1.4 N/A N/A 3.5 3.3 N/A N/A 1.6 N/A N/A N/A N/A 1.5 1.5 1.3 1.5 N/A N/A 1.9 1.8 2.1 2 N/A N/A N/A N/A N/A N/A N/A N/A 5.9 6.1 N/A N/A 26 3.6 N/A N/A 1.1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.4 1.4 1.2 1.9 1.5 2.1 9.4 2.3 5.3 2.1 13 1.2 2.4 1.1 9 8.9 3.6 3.7 3.8 2 1.5 1.5 1.6 8.3 2.4 2.4 1.9 2 3 6.7 4.3 3.1 19 1.7 4 5.1 4.6 1.9 3.5 2.2 N/A 2 2 N/A N/A 2 N/A N/A 10 N/A N/A N/A N/A N/A N/A 64 4.6 5.3 1.1 1.6 3.6 1.6 4 1.9 1.7 4.1 3 16 Dominguez Elementary School - Room 9 (DZ-9) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 4-Bromofluorobenzene 1,3-Dimethyl cyclohexane 1,3-Pentadiene 1,4-Pentadiene 1-Butanol 1-Dodecene 1S-.alpha.-Pinene 2,2,3,3-Tetramethyl butane 2,2,4,6,6-Pentamethyl heptane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3,3-Trimethyl pentane 2,3-Dimethyl pentane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl butanal 3-Methyl hexane 3-Methyl pentane Acetaldehyde Benzaldehyde Butanal Butane Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclohexane Methyl cyclopentane Nonanal Ocatanal Octamethyl cyclotrisiloxane Octane Pentane trans-1,4-Dimethyl cyclohexane Reporting Limit (ppbv) Method Detection limit (ppbv) 11/26/08 12/1/08 12/2/08 12/3/08 12/4/08 12/5/08 N/A N/A 11.53 9.44 9.66 8.08 9.07 8.76 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 3.1 N/A N/A 1.6 N/A N/A N/A N/A N/A N/A 1.9 N/A N/A 1.6 N/A N/A 1.4 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 65 1 1.3 1.1 2 8.5 2.1 1.3 2.6 1.1 1.2 3 1.7 1.8 2.6 7 1.4 2.1 1.1 8.1 3.5 1.9 1 1.6 1.9 2.9 2 2.2 1.1 2.5 1 1.6 5.5 2.1 2 1.6 1.3 1.3 3.4 4.8 Dominguez Elementary School - Room 9 (DZ-9) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 4-Bromofluorobenzene 1,3-Dimethyl cyclohexane 1,3-Pentadiene 1,4-Pentadiene 1-Butanol 1-Dodecene 1S-.alpha.-Pinene 2,2,3,3-Tetramethyl butane 2,2,4,6,6-Pentamethyl heptane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3,3-Trimethyl pentane 2,3-Dimethyl pentane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl butanal 3-Methyl hexane 3-Methyl pentane Acetaldehyde Benzaldehyde Butanal Butane Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclohexane Methyl cyclopentane Nonanal Ocatanal Octamethyl cyclotrisiloxane Octane Pentane trans-1,4-Dimethyl cyclohexane Reporting Limit (ppbv) Method Detection limit (ppbv) 12/8/08 12/9/08 12/10/08 12/11/08 12/12/08 12/15/08 N/A N/A 8.61 8.41 8.22 9.55 9.52 10.21 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.9 1.1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 66 1.9 1 1.6 1.2 2.7 1.4 4.5 1.6 1.2 1.7 3.2 3.2 2.4 1.4 1.8 1.2 1.1 1 2.1 1.2 3.5 2.3 2.3 1.3 1.3 1.8 1.6 1.5 1.1 Dominguez Elementary School - Room 9 (DZ-9) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 4-Bromofluorobenzene 1,3-Dimethyl cyclohexane 1,3-Pentadiene 1,4-Pentadiene 1-Butanol 1-Dodecene 1S-.alpha.-Pinene 2,2,3,3-Tetramethyl butane 2,2,4,6,6-Pentamethyl heptane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3,3-Trimethyl pentane 2,3-Dimethyl pentane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl butanal 3-Methyl hexane 3-Methyl pentane Acetaldehyde Benzaldehyde Butanal Butane Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclohexane Methyl cyclopentane Nonanal Ocatanal Octamethyl cyclotrisiloxane Octane Pentane trans-1,4-Dimethyl cyclohexane Reporting Limit (ppbv) Method Detection limit (ppbv) 12/16/08 12/17/08 12/18/08 12/19/08 N/A N/A 9.66 9.52 9.74 10.01 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.2 N/A N/A 1.4 N/A N/A 1.6 N/A N/A 2.4 N/A N/A 1.1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 67 1.8 5 1.1 1.1 1.5 2.2 1.2 5.1 1.3 1.5 1 1.2 1.1 1.2 2.7 1 Dominguez Elementary School - Room 11 (DZ-11) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) Ethyl acetate Chloroform Tetrahydrofuran Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene Bromoform 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.03 0.07 0.07 0.03 0.07 0.04 0.04 0.04 0.02 0.04 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.04 0.05 0.10 0.05 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 68 11/18/08 11/19/08 11/20/08 11/21/08 11/24/08 11/25/08 5.4 0.7 3.7 0.5 0.01 0.7 6 0.7 0.8 4.5 0.6 0.01 0.8 2.9 0.6 0.01 0.8 0.03 170 270 12 0.06 28 0.05 1.8 1.5 2.4 0.5 0.09 0.5 9.6 0.07 1.1 1.6 0.07 11 0.06 29 0.06 0.6 0.6 2.5 0.2 0.05 0.3 0.5 0.06 0.6 0.8 0.02 0.9 0.8 530 150 70 34 0.08 1.3 1.3 2.4 0.9 0.1 0.7 1 0.07 3.6 1.5 0.07 22 0.07 30 0.07 1 1.1 2.8 0.5 0.08 0.6 0.7 0.07 0.7 1.2 0.07 0.04 180 0.3 15 0.06 20 0.07 0.6 1.9 1.8 0.3 0.06 0.1 2.2 0.07 1.7 1 0.03 42 0.4 0.7 0.5 0.3 0.7 6.8 4.9 3.3 9.6 3.2 2.4 0.3 0.2 0.2 0.1 0.08 0.3 0.4 0.1 0.2 0.09 0.9 3.1 1.1 1.5 0.8 2.3 0.9 0.6 0.5 1.7 0.7 0.4 0.01 1.7 5.7 1.7 0.7 0.5 1.7 0.7 1.3 0.4 1.2 0.6 0.4 1.1 0.3 1.1 0.8 0.2 0.8 0.6 0.6 1.2 0.3 1.2 0.6 0.2 0.6 0.5 0.1 0.5 0.2 0.1 0.09 0.2 0.1 0.08 0.02 0.02 200 0.2 16 0.06 21 0.06 0.4 0.4 1.9 0.2 0.05 0.2 0.3 0.07 0.6 0.05 Dominguez Elementary School - Room 11 (DZ-11) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) Ethyl acetate Chloroform Tetrahydrofuran Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene Bromoform 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.03 0.07 0.07 0.03 0.07 0.04 0.04 0.04 0.02 0.04 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.04 0.05 0.10 0.05 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 69 11/26/08 12/1/08 12/2/08 12/3/08 12/4/08 12/5/08 1.2 0.5 0.01 0.8 4.4 0.4 0.01 0.6 0.5 0.01 0.6 0.5 0.04 0.6 2.7 0.6 0.06 0.6 260 0.2 160 0.06 26 0.03 0.2 0.2 2.1 0.2 0.03 0.06 100 0.2 52 0.06 28 0.06 0.4 1.5 3.9 0.3 0.06 0.4 0.04 0.9 0.05 0.05 210 0.2 13 0.09 17 0.07 0.3 0.3 2 0.3 0.06 63 0.3 4.4 0.09 13 0.04 0.4 0.3 1.2 0.2 41 0.4 5.4 0.1 22 0.1 0.6 0.6 1.6 0.3 0.09 0.06 1.4 0.2 0.02 0.7 0.07 1.3 1.2 0.03 0.2 0.08 0.2 0.07 0.2 0.4 0.06 0.4 0.07 0.5 0.9 0.05 2 0.4 0.1 0.2 0.2 1 4.6 0.8 1 2.7 0.02 0.2 0.03 0.4 0.08 0.2 0.2 0.06 0.2 0.5 0.3 0.1 0.6 2 0.9 0.8 0.1 0.3 0.2 0.1 0.2 0.05 0.2 0.7 0.2 0.8 0.2 0.04 0.2 0.05 0.1 0.03 310 0.2 32 0.06 14 0.2 0.3 1.4 0.07 0.2 0.4 0.04 0.03 0.2 0.02 0.9 0.02 0.2 0.4 0.2 0.1 0.03 0.1 0.07 0.03 0.2 0.4 0.2 0.1 0.1 0.1 0.04 0.4 1.2 0.5 0.9 0.1 0.06 0.1 0.03 0.04 0.03 0.05 0.04 0.03 0.2 0.06 0.2 0.03 0.04 0.03 0.03 0.03 0.04 0.5 0.2 0.5 0.03 0.06 0.04 0.05 0.04 Dominguez Elementary School - Room 11 (DZ-11) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) Ethyl acetate Chloroform Tetrahydrofuran Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene Bromoform 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.03 0.07 0.07 0.03 0.07 0.04 0.04 0.04 0.02 0.04 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.04 0.05 0.10 0.05 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 70 12/8/08 12/9/08 12/10/08 12/11/08 12/12/08 12/15/08 1 0.5 0.03 0.5 0.5 0.02 0.5 0.6 0.6 4.7 0.6 0.7 0.4 0.4 0.6 0.5 0.5 18 0.2 35 0.04 14 0.03 0.2 0.05 0.8 42 0.2 8.4 0.04 15 0.06 0.5 0.1 0.7 6.4 0.2 4.2 60 0.2 7.9 5.9 0.04 0.2 0.07 0.3 19 0.02 0.5 0.2 1.4 23 0.4 3.2 0.06 19 0.02 0.8 0.8 1.3 0.2 99 0.2 13 0.03 15 0.04 0.03 0.08 0.03 0.2 0.07 0.2 0.02 0.5 0.06 0.6 1.1 0.06 0.04 0.09 0.1 0.4 0.5 0.5 3.8 0.1 0.03 0.02 0.2 0.02 0.1 0.07 0.2 0.1 0.06 0.07 0.2 0.1 0.2 0.08 0.2 0.1 0.06 0.6 1.7 0.6 0.7 0.03 0.08 0.03 0.02 0.1 0.05 0.2 0.08 0.03 0.08 0.5 0.1 0.5 0.03 0.01 0.04 0.01 0.01 0.04 0.01 0.02 0.02 0.01 0.01 0.03 0.08 0.04 0.02 0.04 0.02 0.04 0.01 0.01 0.02 0.01 0.03 0.07 0.03 0.08 0.01 0.02 0.02 0.2 0.1 0.2 0.2 0.1 0.3 0.1 0.06 2.9 2.9 0.02 Dominguez Elementary School - Room 11 (DZ-11) VOC data VOC concentration (ppbv) SPECIATED ORGANIC COMPOUNDS Reporting Limit (ppbv) Method Detection limit (ppbv) Propylene Freon 12 (Dichlorodifluoromethane) Freon 114(1,2-Dichlorotetrafluoroethan) Chloromethane Vinyl chloride Bromomethane Ethanol Freon 11(Trichlorofluoromethane) Isopropyl alcohol(2-Propanol) Freon 113(1,1,2-Trichlorotrifluoroethan) Acetone Carbon disulfide Methylene chloride n-Hexane 2-Butanone(MEK) Ethyl acetate Chloroform Tetrahydrofuran Cyclohexane Carbon tetrachloride n-Heptane Benzene Trichloroethene Bromodichloromethane 4-Methyl-2-pentanone(MIBK) cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone(MBK) Tetrachloroethene Chlorobenzene Ethylbenzene Xylene (para & meta) Xylene (Ortho) Styrene Bromoform 1,1,2,2-Tetrachloroethane 4-Ethyltoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Hexachloro-1,3-butadiene 1.0 0.5 0.5 0.5 0.5 0.5 1.5 0.5 1.5 0.5 3.0 1.0 1.5 0.5 1.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.5 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.0 0.5 0.04 0.04 0.03 0.08 0.04 0.05 0.30 0.04 0.03 0.06 0.08 0.04 0.04 0.03 0.07 0.07 0.03 0.07 0.04 0.04 0.04 0.02 0.04 0.04 0.06 0.04 0.05 0.04 0.06 0.05 0.04 0.04 0.05 0.10 0.05 0.05 0.05 0.08 0.06 0.05 0.08 0.06 0.05 0.10 0.10 0.30 71 12/16/08 12/17/08 12/18/08 12/19/08 0.4 0.02 0.5 0.4 1.1 0.4 1.8 0.4 0.6 0.5 0.5 110 0.2 18 150 0.2 20 32 0.1 5.4 14 0.04 0.4 0.1 0.3 17 0.01 0.2 58 0.2 10 0.02 19 0.03 0.2 0.1 0.03 0.6 0.2 15 0.3 0.05 1 0.02 0.05 0.02 0.2 0.02 0.03 0.05 0.09 6.6 3.5 0.2 0.8 0.6 0.07 0.3 0.2 0.08 0.2 0.1 0.4 0.2 0.06 0.02 0.05 0.03 0.07 0.04 0.05 0.2 0.06 0.05 0.2 0.02 0.2 0.01 0.03 0.01 0.05 0.02 0.03 0.01 0.03 0.05 0.02 0.05 0.03 Dominguez Elementary School - Room 11 (DZ-11) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 1,1-Difluoroethane 1-Butanol 1-Dodecene 2,2,3,3-Tetramethyl butane 2,2,4,6,6-Pentamethyl heptane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl butanal 3-Methyl butane 3-Methyl hexane 3-Methyl pentane 3-Methyl-1,2-butadiene Acetaldehyde Benzaldehyde Butanal Butane Butyl ester acetic acid Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclohexane Methyl cyclopentane Naphthalene Nonanal Ocatanal Octamethyl cyclotrisiloxane Pentanal Pentane Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.8 1.3 1.3 N/A N/A 9.2 7.7 8.2 11 N/A N/A 1.5 1.6 1.4 N/A N/A 4.1 3.2 3.6 N/A N/A 2.6 1.8 1.3 N/A N/A N/A N/A N/A N/A 1.9 N/A N/A 2.1 1.8 N/A N/A N/A N/A 1.3 1.7 1.5 1.9 2.1 N/A N/A 1.4 1 1.5 1.8 1.6 N/A N/A N/A N/A 6.4 6.4 7.5 7.9 3.9 3.1 N/A N/A 8.8 N/A N/A 12 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.1 1.3 N/A N/A 5.7 5.3 N/A N/A N/A N/A 72 11/18/08 11/19/08 11/20/08 11/21/08 11/24/08 11/25/08 1.7 2.1 1.2 2.8 2.1 3 1.8 4.7 3.8 4.6 2 1.4 1.7 1.4 1.1 1.7 1.8 1.1 2.2 2.5 1.1 1.4 3.5 4.6 4.9 4.5 4.7 2.9 2.3 1.2 1.8 1.4 2.3 2 1.4 4.1 3.7 4.9 2.5 Dominguez Elementary School - Room 11 (DZ-11) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 1,1-Difluoroethane 1-Butanol 1-Dodecene 2,2,3,3-Tetramethyl butane 2,2,4,6,6-Pentamethyl heptane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl butanal 3-Methyl butane 3-Methyl hexane 3-Methyl pentane 3-Methyl-1,2-butadiene Acetaldehyde Benzaldehyde Butanal Butane Butyl ester acetic acid Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclohexane Methyl cyclopentane Naphthalene Nonanal Ocatanal Octamethyl cyclotrisiloxane Pentanal Pentane Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 2.8 2.7 N/A N/A 1.8 1.6 N/A N/A N/A N/A 2 8.5 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.7 1.7 N/A N/A 1.6 1.8 N/A N/A N/A N/A N/A N/A 73 11/26/08 12/1/08 12/2/08 12/3/08 12/4/08 12/5/08 1 1.6 1.3 2.1 8.7 2.2 2.1 2 3.3 3.9 2 1.2 1.1 1 2.1 1.2 2.1 2.7 1.6 1.1 2.6 2.5 1.8 2.9 2.5 8 1.3 2.6 2.4 3.3 1.2 1.8 5.6 2.3 2.1 6.9 1.5 1.8 Dominguez Elementary School - Room 11 (DZ-11) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 1,1-Difluoroethane 1-Butanol 1-Dodecene 2,2,3,3-Tetramethyl butane 2,2,4,6,6-Pentamethyl heptane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl butanal 3-Methyl butane 3-Methyl hexane 3-Methyl pentane 3-Methyl-1,2-butadiene Acetaldehyde Benzaldehyde Butanal Butane Butyl ester acetic acid Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclohexane Methyl cyclopentane Naphthalene Nonanal Ocatanal Octamethyl cyclotrisiloxane Pentanal Pentane Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.3 N/A N/A 1.7 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 74 12/8/08 12/9/08 12/10/08 12/11/08 12/12/08 12/15/08 2.6 1 1.8 2.7 4.4 1.1 1.7 1.3 3.2 2.1 3.4 2.3 1.3 2.4 1.2 1.7 1.4 1.1 Dominguez Elementary School - Room 11 (DZ-11) VOC data VOC concentration (ppbv) TENTATIVELY IDENTIFIED COMPOUNDS 1,1-Difluoroethane 1-Butanol 1-Dodecene 2,2,3,3-Tetramethyl butane 2,2,4,6,6-Pentamethyl heptane 2,2,4-Trimethyl pentane 2,2-Dimethyl hexane 2,3-Dimethyl pentane 2-Methyl butane 2-Methyl hexane 2-Methyl pentane 2-Methyl-1,3-butadiene 3-Methyl butanal 3-Methyl butane 3-Methyl hexane 3-Methyl pentane 3-Methyl-1,2-butadiene Acetaldehyde Benzaldehyde Butanal Butane Butyl ester acetic acid Difluorochloromethane D-Limonene Heptanal Hexamethyl cyclotrisiloxane Hexanal Isobutane Methyl cyclohexane Methyl cyclopentane Naphthalene Nonanal Ocatanal Octamethyl cyclotrisiloxane Pentanal Pentane Reporting Limit (ppbv) Method Detection limit (ppbv) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.1 N/A N/A 1.6 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 75 12/16/08 1.1 1.4 1.2 12/17/08 12/18/08 12/19/08