FEASIBILITY STUDY REPORT PATRICK BAYOU SUPERFUND SITE DEER PARK, TEXAS Prepared for Patrick Bayou Joint Defense Group U.S. Environmental Protection Agency Prepared by Anchor QEA, LLC 614 Magnolia Avenue Ocean Springs, Mississippi 39564 March 2017 *100002455* 100002455 FEASIBILITY STUDY REPORT PATRICK BAYOU SUPERFUND SITE DEER PARK, TEXAS Prepared for Patrick Bayou Joint Defense Group U.S. Environmental Protection Agency Prepared by Anchor QEA, LLC 614 Magnolia Avenue Ocean Springs, Mississippi 39564 March 2017 TABLE OF CONTENTS 1 2 INTRODUCTION ................................................................................................................ 1 1.1 Purpose and Organization of the Report..........................................................................2 1.2 Regulatory Background .....................................................................................................2 BACKGROUND INFORMATION ....................................................................................... 5 2.1 Site Location and History ..................................................................................................5 2.2 Aquatic Land Ownership ..................................................................................................6 2.3 Land Use .............................................................................................................................7 2.3.1 Recreational and Navigational Use............................................................................7 2.4 Ecological Conditions ........................................................................................................8 2.5 Physical Description ........................................................................................................10 2.5.1 Bathymetry and Topography ...................................................................................10 2.5.2 Adjacent Facilities, Infrastructure, and Waterway Structures ..............................11 2.5.3 Waterway Hydrodynamics ......................................................................................12 2.5.4 Streambed Characteristics and Sediment Transport ..............................................12 2.5.5 Upstream Stormwater Detention Basin ..................................................................14 2.5.6 Port Terminal Railroad Association Bridge Improvements ...................................15 2.6 Nature and Extent of Contamination .............................................................................15 2.6.1 Contaminant Sources ...............................................................................................15 2.6.2 Distribution of Indicator Chemicals ........................................................................17 2.6.2.1 Surface Sediment ............................................................................................... 18 2.6.2.2 Subsurface Sediment ......................................................................................... 19 2.6.2.3 Porewater ........................................................................................................... 20 2.6.2.4 Surface Water .................................................................................................... 22 2.6.2.5 Tissue .................................................................................................................. 24 2.6.2.6 Mean Probable Effects Level Quotient ............................................................ 25 2.6.3 Chemical Characteristics of Indicator Chemicals ...................................................26 2.6.3.1 Polychlorinated Biphenyls................................................................................ 27 2.6.3.2 Total Polycyclic Aromatic Hydrocarbons ........................................................ 27 2.6.3.3 Bis(2-ethylhexyl) Phthalate .............................................................................. 28 2.6.3.4 Lead and Mercury.............................................................................................. 28 2.6.3.5 Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans .......... 29 Feasibility Study Report Patrick Bayou Superfund Site i March 2017 040284-01.08 Table of Contents 2.7 Contaminant Fate and Transport ....................................................................................29 2.7.1 3 Fate and Transport Modeling ..................................................................................32 BASIS FOR REMEDIAL ACTION ..................................................................................... 34 3.1 Remedial Action Objectives ............................................................................................34 3.2 Benthic Risk Remedial Action Objectives .....................................................................34 3.2.1 Summary of the BERA Risk Characterization ........................................................35 3.2.2 Identification of Preliminary Remediation Goal for Benthic Risk........................36 3.3 Aquatic-dependent Wildlife RAO ..................................................................................36 3.4 PCB Surface Water Remedial Action Objective ............................................................37 3.5 Mercury and PCDD/PCDF TEQ Risk Summary............................................................38 3.6 Applicable or Relevant and Appropriate Requirements and Other Advisories, Criteria, or Guidance To Be Considered ........................................................................39 3.6.1 Water Quality and Water Resources ......................................................................40 3.6.1.1 Section 303 and 304 of the Clean Water Act and Texas Surface Water Quality Standards .............................................................................................. 40 3.6.1.2 Section 401 Water Quality Certification of the Clean Water Act as Administered by Texas ...................................................................................... 41 3.6.1.3 Section 404 and 404(b)(1) of the Clean Water Act and Texas Parks and Wildlife Commission Marl, Sand, and Gravel Permit..................................... 41 3.6.1.4 Texas Pollutant Discharge Elimination System ............................................... 41 3.6.1.5 Rivers and Harbor Act, Texas State Code Obstructions to Navigation, and Port Authority of Houston Marine Construction Permit ............................... 42 4 3.6.2 Protected Species Requirements..............................................................................42 3.6.3 Coastal Zone Management and Texas Coastal Management Plan.........................43 3.6.4 Floodplain .................................................................................................................43 3.6.5 Cultural Resources Management .............................................................................43 3.6.6 Noise Control Act .....................................................................................................46 3.6.7 Hazardous Materials Transportation and Waste Management .............................46 DEVELOPMENT OF REMEDIAL ALTERNATIVES ........................................................ 47 4.1 Delineation of Sediment Management Areas ................................................................47 4.1.1 Sediment Management Area Delineation Approach for PCB Surface Water Remedial Action Objective ......................................................................................47 Feasibility Study Report Patrick Bayou Superfund Site ii March 2017 040284-01.08 Table of Contents 4.1.2 Delineation Approach for Benthic Risk Sediment Management Areas ................48 4.1.2.1 Evaluating Baseline Conditions ........................................................................ 49 4.1.2.2 Evaluating Future Conditions ........................................................................... 50 4.1.2.3 Delineation of Benthic Risk Sediment Management Areas ............................ 52 4.1.3 Delineation of Natural Recovery Areas ..................................................................52 4.1.4 Summary of Sediment Management Area Delineation..........................................52 4.2 Remedial Technologies Screening ..................................................................................53 4.2.1 Institutional Controls ...............................................................................................54 4.2.2 Monitored Natural Recovery ...................................................................................54 4.2.2.1 Monitored Natural Recovery Surface Water Monitoring ............................... 55 4.2.2.2 Porewater Monitoring....................................................................................... 56 4.2.2.2 Surface Sediment Monitoring ........................................................................... 56 4.2.3 Containment .............................................................................................................57 4.2.3.1 Aggregate Caps .................................................................................................. 58 4.2.3.2 Articulated Concrete Block Mat Caps .............................................................. 59 4.2.4 Treatment..................................................................................................................59 4.2.5 Removal ....................................................................................................................62 4.3 4.2.5.1 Removal Best Management Practices............................................................... 63 4.2.5.2 Disposal .............................................................................................................. 64 Assembly of Remedial Alternatives................................................................................64 4.3.1 Alternative 1 – No Further Action ..........................................................................65 4.3.2 Alternative 2 – Monitored Natural Recovery .........................................................65 4.3.3 Alternative 3 – Monitored Natural Recovery, SMA-1 Capping, and SMA-2 through SMA-9 Treatment ......................................................................................68 4.3.4 Alternative 4 – Monitored Natural Recovery and SMA-1 through SMA-9 Capping .....................................................................................................................71 5 DETAILED ANALYSIS OF REMEDIAL ALTERNATIVES ............................................... 74 5.1 Alternative 1 – No Further Action .................................................................................76 5.1.1 5.1.1.1 Overall Protection of Human Health and the Environment .......................... 76 5.1.1.2 Compliance with ARARs .................................................................................. 76 5.1.2 5.2 Threshold Criteria ....................................................................................................76 Balancing Criteria .....................................................................................................77 Alternative 2 – Monitored Natural Recovery ................................................................77 Feasibility Study Report Patrick Bayou Superfund Site iii March 2017 040284-01.08 Table of Contents 5.2.1 5.2.1.1 Overall Protection of Human Health and the Environment .......................... 77 5.2.1.2 Compliance with ARARs .................................................................................. 78 5.2.2 5.3 Threshold Criteria ....................................................................................................77 Balancing Criteria .....................................................................................................78 5.2.2.1 Long-term Effectiveness ................................................................................... 78 5.2.2.2 Reduction of Toxicity, Mobility, or Volume ................................................... 79 5.2.2.3 Short-term Effectiveness ................................................................................... 79 5.2.2.4 Implementability ............................................................................................... 79 5.2.2.5 Cost ..................................................................................................................... 79 Alternative 3 – Monitored Natural Recovery, SMA-1 Capping, and SMA-2 through SMA-9 Treatment .............................................................................................80 5.3.1 5.3.1.1 Overall Protection of Human Health and the Environment .......................... 80 5.3.1.2 Compliance with ARARs .................................................................................. 80 5.3.2 5.4 Balancing Criteria .....................................................................................................81 5.3.2.1 Long-term Effectiveness ................................................................................... 81 5.3.2.2 Reduction of Toxicity, Mobility, or Volume ................................................... 82 5.3.2.3 Short-term Effectiveness ................................................................................... 82 5.3.2.4 Implementability ............................................................................................... 84 5.3.2.5 Cost ..................................................................................................................... 84 Alternative 4 – Monitored Natural Recovery and SMA-1 through SMA-9 Capping ..85 5.4.1 Threshold Criteria ....................................................................................................85 5.4.1.1 Overall Protection of Human Health and the Environment .......................... 85 5.4.1.2 Compliance with ARARs .................................................................................. 85 5.4.2 6 Threshold Criteria ....................................................................................................80 Balancing Criteria .....................................................................................................86 5.4.2.1 Long-term Effectiveness ................................................................................... 86 5.4.2.2 Reduction of Toxicity, Mobility, or Volume ................................................... 86 5.4.2.3 Short-term Effectiveness ................................................................................... 87 5.4.2.4 Implementability ............................................................................................... 88 5.4.2.5 Cost ..................................................................................................................... 89 COMPARATIVE ANALYSIS OF ALTERNATIVES .......................................................... 90 6.1 Threshold Criteria ...........................................................................................................90 6.1.1 Overall Protection of Human Health and the Environment .................................90 Feasibility Study Report Patrick Bayou Superfund Site iv March 2017 040284-01.08 Table of Contents 6.1.2 6.2 Balancing Criteria ............................................................................................................91 6.2.1 Long-term Effectiveness ..........................................................................................91 6.2.2 Reduction of Toxicity, Mobility, or Volume ..........................................................92 6.2.3 Short-term Effectiveness ..........................................................................................92 6.2.4 Implementability ......................................................................................................93 6.2.5 Cost ............................................................................................................................94 6.3 7 Compliance with ARARs .........................................................................................91 Summary of Comparative Evaluation.............................................................................94 REFERENCES .................................................................................................................... 96 List of Tables Table 2-1 Houston Ship Channel Background Dataset Table 2-2 Summary Statistics for Houston Ship Channel Background Dataset Table 2-3 Fate and Transport Chemical Properties of Indicator Chemicals Table 3-1 Sediment Toxicity and Chemistry Lines of Evidence as Presented in the BERA Table 3-2 Potential ARAR Screening for Patrick Bayou Superfund Site, Feasibility Study Report Table 4-1 Mean PEL-Q and Half-life Evaluation Table 4-2 Summary of SMA Delineation Table 4-3 Aggregate Cap Armor Sizing Table 4-4 Summary of Quantities, Durations, and Short-term Impacts Table 5-1 Detailed Evaluation of Remedial Alternatives Table 6-1 Comparative Evaluation of Remedial Alternatives List of Figures Figure 1-1 Patrick Bayou Superfund Site Vicinity Map Figure 2-1 Patrick Bayou Superfund Site Boundaries Figure 2-2 Property Ownership Figure 2-3 Surrounding Land Use Based on H-GAC Data Figure 2-4 Total PCB Results in Surface Sediment Samples Feasibility Study Report Patrick Bayou Superfund Site v March 2017 040284-01.08 Table of Contents Figure 2-5 Total PAH Results in Surface Sediment Samples Figure 2-6 Total BEHP Results in Surface Sediment Samples Figure 2-7 Total Lead Results in Surface Sediment Samples Figure 2-8 2,3,7,8-TCDD TEQ Results in Surface Sediment Samples Figure 2-9 Mercury Results in Surface Sediment Samples Figure 2-10 Surface Sediment Samples Upstream of Site Boundary Figure 2-11 Subsurface Sampling Locations Figure 2-12 Vertical Distribution of Total PCBs in Patrick Bayou Figure 2-13 Vertical Distribution of Total PAH in Patrick Bayou Figure 2-14 Vertical Distribution of Bis(2-Ethylhexyl)phthalate in Patrick Bayou Figure 2-15 Vertical Distribution of Lead in Patrick Bayou Figure 2-16 Vertical Distribution of 2378-TCDD TEQs in Patrick Bayou Figure 2-17 Vertical Distribution of Mercury in Patrick Bayou Figure 2-18 Total PCB Results in Porewater Samples Figure 2-19 Total PAH Results in Porewater Samples Figure 2-20 Bis(2-ethylhexyl)phthalate Results in Porewater Samples Figure 2-21 Mercury Results in Porewater Samples Figure 2-22 Patrick Bayou Surface Water Sample Locations Figure 2-23 Spatial Profile of Water Column Total PCBs Figure 2-24 Spatial Profile of Water Column 2378-TCDD TEQs Figure 2-25 Spatial Profile of Water Column Mercury Figure 2-26 Spatial Profile of Water Column Total PCB in the Houston Ship Channel Figure 2-27 Spatial Profile of Water Column 2378-TCDD TEQs in the Houston Ship Channel Figure 2-28 PCB TEQ (avian) Results in Whole Body Shellfish Tissue Samples Figure 2-29 PCB TEQ (avian) Results of Whole Body Gulf Killifish Tissue Samples Figure 2-30 PCB TEQ (avian) Results in Whole Body Gulf Menhaden Tissue Samples Figure 2-31 PCB TEQ (avian) Results in Whole Body Pinfish, Sand Seatrout, and Striped Mullet Tissue Samples Figure 2-32 Optimized Mean PEL-Q Results in Surface Sediment Samples Figure 2-33 Processes Affecting Chemical Fate and Transport Figure 2-34 Mathematical Modeling Framework Figure 3-1 Areas Exceeding Benthic Risk Preliminary Remediation Goal Feasibility Study Report Patrick Bayou Superfund Site vi March 2017 040284-01.08 Table of Contents Figure 3-2 Historical and Current Aerial Imagery Figure 4-1 Sediment Management Areas Figure 4-2 Adaptive Management Process Figure 4-3 Plan View Alternative 2: Monitored Natural Recovery Figure 4-4 Plan View Alternative 3: Monitored Natural Recovery, AC Treatment and ACBM Figure 4-5 Treatment Processes Figure 4-6 Plan View Alternative 4: Monitored Natural Recovery Zones and ACBM Figure 4-7 ACBM Details List of Appendices Appendix A Chemical Fate and Transport Modeling Study Appendix B Preliminary Capping Assessment Appendix C Remedial Alternative Cost Development Appendix D Supplemental Surface Water Sampling Data Report Appendix E Empirical Evaluation of Natural Recovery Based on Surface Water Data Appendix F Alternatives Analysis for Institutional Controls List of Attachments Attachment 1 Meeting Notes and Response to Comments on Draft Interim Final Feasibility Study Report Feasibility Study Report Patrick Bayou Superfund Site vii March 2017 040284-01.08 LIST OF ACRONYMS AND ABBREVIATIONS µg/L micrograms per liter AC activated carbon ACBM Articulated Concrete Block Mat ACT Antiquities Code of Texas Anchor QEA Anchor QEA, LLC AOC Administrative Order on Consent APE Area of Potential Effect ARAR Applicable or Relevant and Appropriate Requirement AVS acid volatile sulfide BEHP bis(2-ethylhexyl) phthalate BERA Baseline Ecological Risk Assessment BHHRA Baseline Human Health Risk Assessment BMP best management practice BTV background threshold value CDF confined disposal facility CERCLA Comprehensive Environmental Response, Compensation, and Liability Act CFR Code of Federal Regulations cfs cubic feet per second cm centimeter COC chemical of concern COPC chemical of potential concern CWA Clean Water Act ESA Endangered Species Act FR Federal Register FS Feasibility Study Report GLO Texas General Land Office GRA General Response Action HSC Houston Ship Channel HQ hazard quotient IC indicator chemical Feasibility Study Report Patrick Bayou Superfund Site viii March 2017 040284-01.08 List of Acronyms and Abbreviations JDG Joint Defense Group LOE line-of-evidence Lubrizol The Lubrizol Corporation mg/kg milligrams per kilogram MHW mean high water MNR Monitored Natural Recovery MOA Memorandum of Agreement NCP National Contingency Plan ng/L nanograms per liter NAVD 88 North American Vertical Datum of 1988 NPDES National Pollutant Discharge Elimination System NPV net present value NRHP National Register of Historic Places OMM operations, monitoring, and maintenance Oxy Occidental Chemical Corporation PAH polycyclic aromatic hydrocarbon PCB polychlorinated biphenyl PCDD polychlorinated dibenzodioxin PCDF polychlorinated dibenzofuran PEL-Q Probable Effects Level-Quotient PHA Port of Houston Authority PM2.5 fine particulate matter PRG preliminary remediation goal PSCR Preliminary Site Characterization Report RAO Remedial Action Objective RATS Remedial Alternatives Technology Screening RCM Reactive Core Mat RI Remedial Investigation SEM simultaneously extracted metal SH State Highway Shell Shell Oil Company, on behalf of Deer Park Refining Limited Partnership and Shell Chemical, LLP Site Patrick Bayou Superfund Site Feasibility Study Report Patrick Bayou Superfund Site ix March 2017 040284-01.08 List of Acronyms and Abbreviations SMA sediment management area SOW Statement of Work STM sediment transport model TBC To Be Considered TCEQ Texas Commission on Environmental Quality TEF toxic equivalency factor TEQ toxic equivalent TMDL Total Maximum Daily Load TMV toxicity, mobility, or volume TOB top of bank TPDES Texas Pollutant Discharge Elimination System TSWQS Texas Surface Water Quality Standards UPL upper prediction limit USDL U.S. Department of Labor USEPA U.S. Environmental Protection Agency WOE weight-of-evidence WWTP Wastewater Treatment Plant Feasibility Study Report Patrick Bayou Superfund Site x March 2017 040284-01.08 1 INTRODUCTION This Feasibility Study Report (FS) was prepared for the Patrick Bayou Superfund Site (Site) in Deer Park, Texas, (Figure 1-1) on behalf of the Patrick Bayou Joint Defense Group (JDG).1 The work is being conducted under an Administrative Order on Consent (AOC) and Settlement Agreement dated January 31, 2006. This FS builds upon the final Remedial Alternatives Technology Screening report (RATS) submitted on May 31, 2013 (Anchor QEA 2013a), which outlines the general approach of the FS. The RATS also provides additional background information and detailed analysis in support of the FS. This FS develops and evaluates remedial alternatives for the Site based on the Remedial Action Objectives (RAOs) provided in the RATS and the Patrick Bayou Remedial Investigation Report (RI Report; Anchor QEA 2013b) and the results of the Baseline Human Health Risk Assessment Report (BHHRA Report; Anchor QEA 2012) and Baseline Ecological Risk Assessment Report (BERA Report; Anchor QEA 2013c). This FS was prepared by Anchor QEA, LLC, under the direction of the U.S. Environmental Protection Agency (USEPA) and JDG. This FS was revised to address comments received on the Draft Interim Final Feasibility Study Report (Draft Interim Final FS Report; Anchor QEA 2016) from USEPA and Texas Commission on Environmental Quality (TCEQ) and agreements reached between USEPA and the JDG in a meeting conducted on July 20, 2016. See Attachment 1 for related comments, responses, and meeting notes. Each draft remedial alternative is based on the USEPA-approved adaptive management approach (USEPA 2006). Adaptive management involves making, evaluating, and modifying (if appropriate) decisions in a phased manner so that future actions can be optimized to reflect knowledge that is gained over time. For purposes of this FS, adaptive management would allow remedy(s) to be implemented in stages as their effectiveness in achieving RAOs is evaluated. The Patrick Bayou JDG includes the Respondents to the AOC and Settlement Agreement dated January 31, 2006, for the Remedial Investigation/Feasibility Study. The JDG includes The Lubrizol Corporation (Lubrizol), Occidental Chemical Corporation (Oxy), and Shell Oil Company (Shell), on behalf of Deer Park Refining Limited Partnership and Shell Chemical, LLP. 1 Feasibility Study Report Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Introduction 1.1 Purpose and Organization of the Report The purpose of the FS is to describe the development and evaluation of remedial alternatives that will be used in support of the selection of a remedy to address the previously identified RAOs and mitigate potential risks to the environment posed by the Site. This FS was conducted in accordance with USEPA guidance (USEPA 1988). The remainder of Section 1 provides a summary of the regulatory background for the Site. Section 2 provides a summary of Site information as presented in previous documents prepared and submitted in support of the RI/FS process, including a summary of Site setting and history, the nature and extent of contamination, contaminant fate and transport characteristics at the Site, and the results of the BERA Report (Anchor QEA 2013c) and BHHRA Report (Anchor QEA 2012). The other sections of this FS address the following: • Section 3 identifies the RAOs and basis for the remedial action • Section 4 describes the development of each alternative • Section 5 provides a detailed and comparative analysis of each alternative • Section 6 provides the comparative evaluation of alternatives and describes the recommended alternative • Section 7 provides the references • Appendix A describes chemical fate and transport modeling • Appendix B describes cap chemical and erosion modeling • Appendix C provides details on estimated costs for the remedial alternatives • Appendix D describes the 2014 surface water data collection, including results • Appendix E describes analytical modeling of natural recovery of polychlorinated biphenyls (PCBs) in surface water • Appendix F provides an evaluation of institutional controls • Attachment 1 provides a copy of USEPA and TCEQ comments and JDG responses on the Draft Interim Final FS Report submitted to USEPA in October 2016 and meeting notes of a July 20, 2016, meeting between USEPA and the JDG to discuss the FS 1.2 Regulatory Background Patrick Bayou was proposed for addition to the National Priorities List (Federal Register [FR], volume 66, page 32,287) on June 14, 2001, based on ranking developed using the Feasibility Study Report Patrick Bayou Superfund Site 2 March 2017 040284-01.08 Introduction Hazard Ranking System, which USEPA promulgated as Appendix A of the National Contingency Plan (NCP; Code of Federal Regulations [CFR], Title 40 Part 300). The Site listing was finalized on September 5, 2002, (67 FR 56747) under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), also known as Superfund. The RI/FS for the Site is required by the AOC and Settlement Agreement with the USEPA dated January 31, 2006, and was developed in accordance with the Statement of Work (SOW) attached to the AOC. The remedial investigation phase has been completed and the RI Report (Anchor QEA 2013b) was approved by USEPA in February 2014. In addition, the RI Report contained the BHHRA Report (Anchor QEA 2012) and BERA Report (Anchor QEA 2013c), which were reviewed and approved separately by USEPA in April 2013 and June 2013, respectively. Following the RI Report (Anchor QEA 2013b), the RATS Report (Anchor QEA 2013a) was submitted to USEPA and approved in September 2013. This document describes the preliminary screening of potential remedial technologies for the Site and is the first stage in the development of remedial alternatives. The remedial technologies retained for further evaluation were incorporated into the remedial alternatives that are developed and evaluated in the FS presented herein. Following the RATS Report (Anchor QEA 2013a), the Draft FS Report (Anchor QEA 2014) was prepared to satisfy the requirements of Task 7 in the SOW for the submittal of an FS following receipt of USEPA approval of the RI Report (Anchor QEA 2013b). The Draft FS Report (Anchor QEA 2014) was submitted to address the RAOs identified in the RI Report (Anchor QEA 2013b). These RAOs included addressing the Texas Surface Water Quality Standard (TSWQS) for protection of aquatic life for PCBs, direct sediment toxicity, and risk to wildlife receptors from PCBs. Subsequent to the submittal of the Draft FS Report (Anchor QEA 2014), USEPA, in a letter to the JDG dated July 8, 2015, agreed with the TCEQ that the Site meets the definition of a sustainable fishery under Texas Administrative Code Title 30, Chapter 307, and that “the corresponding water quality standards for PCBs, mercury, and dioxin/furans as TCDD equivalents must be considered in the remedial strategy.” During subsequent discussions, USEPA directed the JDG to lower the PCB surface water RAO to the human health TSWQS or background, if higher. A revised Draft Interim FS Report was submitted to USEPA in October 2016 (Anchor QEA 2016). Feasibility Study Report Patrick Bayou Superfund Site 3 March 2017 040284-01.08 Introduction Unacceptable adverse risks due to mercury or dioxins were not indicated in either the BHHRA Report (Anchor QEA 2012) or BERA Report (Anchor QEA 2013c) approved by USEPA. However, USEPA is requiring that additional data collection and analysis be performed during a pre-design investigation phase for mercury and polychlorinated dibenzodioxins and polychlorinated dibenzofurans (PCDDs/PCDFs) toxic equivalents (TEQ)2 due to concentrations in surface water samples from Patrick Bayou that exceed the human health TSWQS for these chemicals. Utilizing the adaptive management framework for the Site, this additional information will provide a basis for establishing Site-specific RAOs; evaluating the potential effect of the preferred alternative selected in the FS on water quality with respect to these chemicals; and, if necessary, identifying additional remedial actions that may be required for the Site. This requirement was addressed in the Draft Interim Final FS Report (Anchor QEA 2016). Polychlorinated dibenzodioxins and polychlorinated dibenzofurans (PCDDs/PCDFs) toxic equivalents (TEQs) were calculated using the toxic equivalency factors provided in the 2014 Texas Surface Water Quality Standards (Texas Administrative Code, Title 30, Chapter 307 effective March 6, 2014). 2 Feasibility Study Report Patrick Bayou Superfund Site 4 March 2017 040284-01.08 2 BACKGROUND INFORMATION This section provides a summary of information gathered during the RI Report (Anchor QEA 2013b) concerning physical, chemical, and biological characteristics of the Site as well as sources, nature and extent of contamination, and fate and transport process. This information is intended to provide the reader with an understanding of the Site and the human actions, natural processes, and physical properties that may influence the nature and extent of chemicals of concern (COCs) at the Site and that may influence evaluation of remedial alternatives presented in Sections 4 through 6 of this FS. A comprehensive description of the physical and biological setting for the Site, as well as a more detailed history of the Site, Site uses, the nature and extent of contaminants, and important fate and transport processes, are provided in the RI Report (Anchor QEA 2013b). 2.1 Site Location and History Patrick Bayou is a tributary of the Houston Ship Channel (HSC) in Harris County, Texas, (Figure 1-1) that discharges at the south shore of the HSC approximately 2.3 miles upstream of the HSC confluence with the San Jacinto River. The Site itself and its physical features are described in detail in the Preliminary Site Characterization Report (PSCR; Anchor 2006) and the RI Report (Anchor QEA 2013b); a brief summary is provided below. The Site originates north of State Highway (SH) 225 at the downstream terminus of a set of box culverts that lie underneath the highway and follows Patrick Bayou north approximately 10,200 feet to the HSC (Figure 2-1).3 The Site itself is bordered by three separate facilities owned by Shell Oil Company, on behalf of Deer Park Refining Limited Partnership and Shell Chemical, LLP (Shell), The Lubrizol Corporation (Lubrizol), and Occidental Chemical Corporation (Oxy; Figure 2-2). The Port of Houston Authority (PHA) is listed as the owner of a parcel of land serving as a railroad corridor leased to and operated by the Port Terminal Railroad Association (PTRA), which crosses Patrick Bayou. Upstream of the Site on the south side of SH 225, Patrick Bayou is largely concrete-lined and serves as a drainage system A station numbering system was developed for the Site for consistency and ease of reference throughout this document and associated figures. In this system, station identifiers are named so the last three numbers in the identifier reflect the station’s distance from the mouth of Patrick Bayou in hundreds of feet. For example, the upstream boundary of the Site is at Station PB-102 (10,200 feet from the HSC). 3 Feasibility Study Report Patrick Bayou Superfund Site 5 March 2017 040284-01.08 Background Information for the City of Deer Park. A City-permitted wastewater discharge enters the Site drainage system in this area approximately 75 feet south of SH 225. The East Fork enters the Site approximately midway between SH 225 and the HSC near Station PB-065 and is the only significant tributary of the Site (Figure 2-1). Rohm and Haas Company and Praxair, Inc., have manufacturing operations upstream and adjacent to the East Fork tributary. In addition to the City-permitted wastewater discharge, an urban developed area is located within the stormwater watershed that drains through Patrick Bayou. This watershed comprises paved surfaces (e.g., roads, parking lots), railroads, commercial/industrial facilities, recreational areas (e.g., athletic fields, golf courses), agricultural/undeveloped areas, and residential areas. Review of readily available information for this area in federal and state databases identified 130 facility registrations and numerous other retail, commercial, and industrial facilities that can potentially discharge chemical and non-chemical stressors to the Site. Patrick Bayou was named for the original 1838 grantee for the land around the bayou, George M. Patrick (Texas Land Grant Office 2013). Deer Park was developed in 1892 by land promoters hoping for Midwestern farmer settlement (Laird 2008), and a railroad station was soon established nearby. The new community grew, and later experienced a great expansion in the 1940s, when Deer Park became the site for various refineries and toluol (toluene) plants (Kleiner 2013), including those that border the Site. Shell’s refinery began operation in 1929 and was the first manufacturer to be based in Deer Park. OxyVinyls, LP, is a subsidiary of Oxy. The OxyVinyls Deer Park facility began operation in 1948. The Lubrizol Deer Park facility has been in operation since 1951. 2.2 Aquatic Land Ownership The aquatic lands within the Site below mean high water (MHW) are owned by the State of Texas and managed by the Texas General Land Office (GLO). In addition to the GLO, the PHA has a significant role and authority regarding the ownership of submerged land in Harris County, granted by the Texas Constitution (PHA 2011). Feasibility Study Report Patrick Bayou Superfund Site 6 March 2017 040284-01.08 Background Information 2.3 Land Use Land use data were obtained from the Houston-Galveston Area Council (Merrick 2008). The Site itself is bounded by industrial facilities and a railroad corridor (Figure 2-3). Upstream of the Site’s watershed, land use is predominantly residential, commercial, and industrial. According to 2010 census data (U.S. Census Bureau 2010), there are no residences within the Patrick Bayou watershed adjacent to the Site (i.e., north of SH 225). Given the long historical record of heavy industrial use, as well as active industrial operations, adjacent land use is not expected to change in the foreseeable future. 2.3.1 Recreational and Navigational Use Access to and use of the Site is generally limited to workers authorized by the respective JDG facilities surrounding the Site. Access to the Site by the public is restricted from the uplands by existing engineering controls (e.g., fencing, pipeline barriers) and security/surveillance controls implemented by the industrial facilities along the Site. However, the PTRA rail corridor limits security at the facilities from restricting unauthorized access at this point. PTRA workers and trespassers could potentially access the Site at this location without the JDG’s knowledge. As a result, unauthorized access by the public (i.e., trespassers) could potentially occur but is considered unlikely (Anchor QEA 2011a). The JDG has entered the Site into the Texas811 notification system and is in the process of installing signs along the Site providing notification that it is a Superfund Site and access is restricted. The Captain of the Port of Houston-Galveston has established navigational security zones for certain areas within the Houston and Galveston area, which include the portion of the HSC that Patrick Bayou enters (USCG 2013). Recreational or unauthorized vessels are excluded from these areas, preventing or discouraging access to the Site through the HSC by recreational or unauthorized vessel traffic. Access to the majority of the Site by water is also blocked by the low bridge and pipe crossings near Station PB-012 (or about 1,200 feet from the HSC). Therefore, the Site affords no casual opportunities for recreational use and is unlikely to do so for the foreseeable future. Feasibility Study Report Patrick Bayou Superfund Site 7 March 2017 040284-01.08 Background Information 2.4 Ecological Conditions This section describes the general types and quality of habitat present as they relate to species use of and access to the Site. This information is largely summarized from the detail provided in the RI Report (Anchor QEA 2013b), the BERA Report (Anchor QEA 2013c), the BERA Work Plan (Anchor QEA 2011b), and the PSCR (Anchor 2006). The Site is bordered by industrial facilities with a developed upland environment. The waterway has been largely channelized and armored, which, when combined with extreme temperature variations, leads to severe limitations in its capacity to provide aquatic ecological functions. However, some areas of the Site are less modified and the waterway is used by several species. The Site provides habitat for bottom-dwelling species (e.g., benthic and epibenthic); foraging and resting opportunities for open-water species (e.g., fish), shorebirds, waterfowl, and other migratory birds; and may also provide foraging or denning opportunities for a variety of small mammalian species that have a higher tolerance for human presence (e.g., raccoons, nutria, rats, and mice). Natural and human-influenced fluctuations in water flows within the Site influence the species mix inhabiting the waterway. Under typical conditions, Patrick Bayou is a lowgradient tidal stream influenced by daily tides of 1.5 feet or less. Moderate and heavy precipitation events can produce significant flows into Patrick Bayou, resulting in rapid changes in salinity, temperature, dissolved oxygen, velocity, and suspended sediment loads in the waterway in the form of stormwater runoff. Conversely, sustained drought can result in significantly higher salinity and temperature regimes and depressed dissolved oxygen levels. Therefore, while tidal ranges are small, flow characteristics at the Site, as discussed below, heavily influence animals inhabiting the water column and sediment surface. A detailed evaluation of the characteristics of these non-contaminant stressors is included in Appendix E-3 of the BERA Report (Anchor QEA 2013c). Environmental conditions and bottom substrate conditions significantly influence benthic species that have close associations with sediment and limited home ranges. Studies of the Site evaluating the condition of the benthic community have shown wide variability in benthic species presence and diversity (Anchor 2006) due to widely fluctuating environmental conditions throughout the Site. Thus, while a benthic community that could Feasibility Study Report Patrick Bayou Superfund Site 8 March 2017 040284-01.08 Background Information potentially provide a base for the food chain may be present, its overall health likely reflects both changes in physical Site conditions and potential impacts to Site sediments. Specifically, with respect to the benthic community, this FS considers remedial alternatives to address potential risks to benthic invertebrates inhabiting the surficial sediments at the Site. In order to evaluate the overall appropriateness and efficacy of alternative remedial measures on this community, it is important to consider the nature of this community in the context of the degree to which non-contaminant characteristics affect the composition and stability of the benthic invertebrate community and the degree to which this community will respond to exposure to contaminants. As discussed in detail in Appendices E-3 and E-4 of the BERA Report (Anchor QEA 2013c), the Site is characterized as a mesohaline system with a salinity gradient between the downstream and upstream limits of the Site as a result of stormwater runoff, upstream flow, and tidal effects. The infaunal macroinvertebrates collected in 2000 and 2001 as part of the Total Maximum Daily Load (TMDL) investigations performed at the Site reflect this gradient, and the benthic index developed as part of the BERA Report (see Appendix E-4; Anchor QEA 2013c) explicitly considered salinity as a determinant of the composition of the benthic community. It is also important to note that, consistent with Gulf of Mexico sites, the benthic community found at the Site tends to be concentrated in the shallowest portion of the sediment column (the upper 1 to 2 centimeters (cm) below the mudline), compared to more northern estuaries (see references in Section 1.1 of Appendix E-3 of the BERA Report; Anchor QEA 2013c). Fish and shellfish are found in Patrick Bayou in various natural or modified aquatic zones and generally include species adapted to shallow water conditions. In addition, fish distribution and abundance is associated with the availability of appropriate prey items, temperature, and salinity regime as required for different species. Shellfish, such as juvenile blue crab4 and shrimp, are generally found at the relatively higher salinity zone near the HSC and are not found in significant numbers in upstream areas of the Site (generally upstream of Adult blue crab, which can tolerate a higher range of salinity, can be found farther upstream (near the concrete-lined channel) than juvenile blue crab under the same conditions. 4 Feasibility Study Report Patrick Bayou Superfund Site 9 March 2017 040284-01.08 Background Information the East Fork Tributary). The steep gradient and larger grain-size materials (gravels and cobbles) in the concrete-lined channel (also referred to as the “gunite-lined” channel in other documents) also significantly limit the potential for benthic habitat in upstream areas. Given the small size of the Site, wider-foraging or migratory fish would not be expected to spend significant time within the Site but may occasionally forage within Patrick Bayou. Wildlife habitat at the Site consists of less modified areas of bank and riparian zones of the downstream portions. Riparian conditions range from maintained turf grass to shrub/scrub with sparse tree cover. Natural banks are generally low and gradually sloping, while banks that have been armored are steep and high. Emergent aquatic vegetation is largely absent from the Site. Given the industrial nature of the upland habitat, lack of riparian cover, and modified nature of the shoreline, habitat to support terrestrial mammals is limited. Thus, species that may be present (or have been observed) would include those with limited ranges and urban-adapted characteristics such as raccoon, muskrat, nutria, mice, and rats. 2.5 Physical Description The following section presents a physical description of the site, including bathymetry and topography, structures, waterway hydrodynamics, and streambed characteristics. 2.5.1 Bathymetry and Topography A bank-to-bank bathymetric survey was conducted in 2005 by Gahagan and Bryant Associates, Inc., for the Site and areas immediately upstream (south of SH 225) and downstream (within the proximal portions of the HSC). The upstream and upper portion of the Site (from the Deer Park Wastewater Treatment Plant [WWTP] outfall to the end of the concrete-lined channel) has a significantly higher hydraulic gradient (about 10 feet of elevation change over 5,000 linear feet) when compared to the middle and lower portions of the Site (less than 1 foot of elevation change over 8,000 linear feet). The channel base elevation between Stations PB-037 and PB-080 (the downstream limit of the concrete-lined channel) generally is not deeper than -3 feet referenced to the North American Vertical Datum of 1988 (NAVD 88). Bank slopes in this area are relatively flat, and transitions between the channel and shoal/deposition areas are poorly defined. Feasibility Study Report Patrick Bayou Superfund Site 10 March 2017 040284-01.08 Background Information Downstream of Station PB-037 to Station PB-028, the bank slopes are steepened slightly, with channel elevations reaching -6 feet NAVD 88. The channel widens downstream of Station PB-028 prior to its intersection with the HSC, and areas of shoaling/deposition and channel flow are more clearly defined. Near the two small islands in the lower portion of the Site (PB-017), the primary channel alignment is offset toward the east bank and transitions to the west bank of the Site. Channel elevations between PB-028 and PB-017 range between -2 and -4 feet NAVD 88. Downstream of PB-017, channel elevations generally reach between -4 and -6 feet NAVD 88. The bottom elevation at the Site boundary ranges between -6 and -8 feet NAVD 88. Stream bank heights in areas with bulkheads and riprap are generally steep with top of bank (TOB) elevations exceeding 9 feet NAVD 88. Areas without bank modifications, which include much of the middle section of the Site, typically have low, sloping banks with bank elevations less than 6 feet NAVD 88. Bank cover in areas without riprap or bulkheads is generally mowed grass with some low shrubs and bare earth. In many areas, industrial facilities and impervious surfaces, such as parking lots and roads, are located adjacent to the banks of the Site. 2.5.2 Adjacent Facilities, Infrastructure, and Waterway Structures Several fixed structures cross the Site as described in the RATS. A bridge crosses Patrick Bayou from the OxyVinyls facility to a ship offloading area along the channel near the confluence with the HSC. A bridge partially crosses the Site at Station PB-057 (approximate) between the Shell and OxyVinyls facilities, and an overhead, pile supported pipe rack is present approximately 300 feet upstream of this location. There are several overhead pipe racks, a vehicle bridge, and the PTRA railroad that cross the Site at Stations PB-079 to PB-080.5 (approximate). Additional overhead pipe racks cross the Site at about Station PB-095. Outfalls are present at several locations along the banks of Patrick Bayou. All of these structures physically limit access to the Site by water vessel from the HSC. The channel has concrete lined slopes between Station PB-081 and the upstream end of the Site (Station PB-102). Feasibility Study Report Patrick Bayou Superfund Site 11 March 2017 040284-01.08 Background Information In addition to the multiple bridge and utility crossings, there are many shoreline structures (e.g., catwalks, sheetpile walls) along the banks of the Site. Overall access to the Site is restricted by the adjacent structures and surrounding facility security systems. The effects of these restrictions are significant and must be considered during remedial design planning. 2.5.3 Waterway Hydrodynamics Water depths in the Site boundary range from shallow inter-tidal zones (less than 1 foot) to 8 feet at the confluence with the HSC. The Site’s open-water system is characteristic of bayous of the coastal Gulf of Mexico, consisting of a tidally influenced secondary stream with sluggish flow during typical conditions. Tides in the HSC are generally weak and exhibit semidiurnal and diurnal components. However, winds and ship traffic within the HSC often disrupt the astronomical tidal cycles and may dominate short-term circulation patterns. Normal tidal ranges (the elevation difference between mean low water and MHW) in the HSC are typically less than 1.5 feet; the mean tidal range of the HSC near Patrick Bayou is 1.2 feet (NOAA 2006). The tidal range at the Site is also affected by flow and wind. During low-flow and wind-driven low tide conditions, the intertidal zone may become dewatered for extended periods (e.g., several days), which is a stressor to the benthic community. Base-flow discharges for the main channel range from about 1 to 100 cubic feet per second (cfs), with an average value of 28 cfs. For the East Fork, base-flow discharge is 2 cfs on average, with a range of about 0.1 to 10 cfs (Anchor QEA 2011c). 2.5.4 Streambed Characteristics and Sediment Transport A detailed evaluation and analysis of the streambed and sediment transport processes within the Site was presented in the RI Report (Anchor QEA 2013b) and the Sediment Transport Modeling Report (STM Report; Anchor QEA 2011c). The nature of the sediment bed affects sediment transport processes, as well as chemical distributions. The sediment bed within the Site is separated into two distinct types: • Cohesive (i.e., muddy bed composed of a mixture of clay, silt, sand, and organic matter) • Non-cohesive (i.e., sandy bed composed of sand and gravel, with small amounts of clay and silt) Feasibility Study Report Patrick Bayou Superfund Site 12 March 2017 040284-01.08 Background Information Sediment samples indicate that the bed is primarily composed of cohesive sediment, with non-cohesive sediment occurring in isolated, localized areas at the Site. For similarly sized materials, cohesive sediments are typically more resistant to erosion than non-cohesive sediments. Erosion rate data of sediment collected at the Site indicate that sediments downstream of approximately PB-040 tend to have significantly less erodibility with increasing depth in the bed due to consolidation; sediments upstream of approximately PB-040 tend to exhibit variable erodibility in the vertical direction. A description of the erosion rate parameters and analysis can be found in Appendix B of the STM Report (Anchor QEA 2011c). The primary sources of sediment to the Site are loading from main inflow, the East Fork Tributary, and direct runoff. The stability of the sediment bed is an important factor for considering natural recovery processes and to evaluate remedial alternatives for sediments that might exceed the identified RAOs (discussed in Section 3.2) for the Site. The results of the sediment transport model (STM) analyses were used to develop the following conceptual model for sediment transport at the Site: • The Site is a net depositional area over annual time scales, with approximately 55 to 60 percent of the sediment load entering the Site from the surrounding watershed being deposited within the Site. • Net sedimentation rates are spatially variable, with values ranging from less than 0.1 cm per year to more than 2 cm per year. • Bed erosion is typically an episodic process that is most pronounced during high-flow events. During the 100-year high-flow event (i.e., event with 1 percent chance of occurring in a given year), net erosion occurs in approximately 65 percent of the total bed area and the majority of the net erosion is less than 6 cm. During the 2-year high-flow event (i.e., event with 50 percent chance of occurring in a given year), net erosion occurs in about 45 percent of the total bed area and erosion depths are less than 2 cm. Generally, erosion at the Site, even during low frequency, high-flow events, only affects surface-layer sediments and is limited to bed depths that represent relatively recent deposition. • Results from natural recovery modeling based on simulation of sediment transport processes indicate that for about 70 percent of the Site, the chemical concentrations in the mixing-zone layer (top 10 cm of sediment; Anchor QEA 2009) will decrease by Feasibility Study Report Patrick Bayou Superfund Site 13 March 2017 040284-01.08 Background Information one-half of their current concentrations in less than 10 years, assuming “clean” sediment input (Anchor QEA 2011c). Note that this estimation assumes an average chemical concentration over the entire 10 cm thickness of sediments and does not discretize concentrations within individual (e.g., shallower) layers. Future evaluations will consider PCB concentrations in discrete depth zones to better evaluate Monitored Natural Recovery (MNR) in critical horizons. 2.5.5 Upstream Stormwater Detention Basin To improve the floodplain storage volume in the Patrick Bayou system, the City of Deer Park and the Harris County Flood Control District jointly purchased approximately 35 acres of undeveloped property located south of SH 225, west of East Boulevard and east of Deer Park Gardens Section Two (upstream of the Site), to construct a stormwater detention basin. The detention basin is intended to alleviate flooding on Patrick Bayou during a significant rain event (i.e., 100-year storm event). The basin creates a backwater condition to direct higher stage flows into the detention basin rather than continue down the channel, but allows the lower stage flows to pass through a 6-foot-by-5-foot box culvert. As the basin fills, the head across the weir gets smaller until it is equal to the channel. In this case, the basin is full after the peak of the hydrograph has passed. As the surface water elevation in Patrick Bayou recedes following the high flow event, water will flow out of the detention basin and back into the channel across the weir. The detention basin is expected to reduce the peak flow rate into Patrick Bayou during the 100-year flood by about 10 percent. In addition, the detention basin would only affect flow into Patrick Bayou during floods with return periods of about 10 years or greater. For floods with return periods of 10 years or more, the reduced inflow rates to Patrick Bayou (i.e., 10 percent decrease for 100-year flood) would produce lower current velocities than present conditions and, thus, less sediment bed erosion. It is anticipated that the detention basin would have a minor effect on sediment loads to Patrick Bayou, which would correspond to relatively minor changes in long-term sedimentation rates in Patrick Bayou. Refinement of the STM is anticipated to account for this change in the pre-design phase of the project, if warranted. Feasibility Study Report Patrick Bayou Superfund Site 14 March 2017 040284-01.08 Background Information Appendix A provides additional discussion regarding the upstream stormwater detention basin and how the basin was evaluated in the chemical fate and transport modeling. 2.5.6 Port Terminal Railroad Association Bridge Improvements In 2015, the PTRA completed a project to replace the existing wooden trestle railroad crossing near Station PB-080 with a series of 14-foot diameter, parallel concrete circular culverts. The JDG understands that these culverts were designed and sized in a manner that will not restrict flow in Patrick Bayou. During development of the FS, the new bridge configuration was reviewed to evaluate whether it could represent a material change to the hydrodynamic model input assumptions, which would indicate that the model should be updated. Based on the relatively small scale change represented by the new bridge configuration within the domain of the hydrodynamic model (i.e., the length of a grid cell is wider than the bridge itself; Appendix A), and because the culverts have been designed and sized so as to not affect flow in the Patrick Bayou, it was determined that modifications to the hydrodynamic model were not necessary. 2.6 2.6.1 Nature and Extent of Contamination Contaminant Sources In the RI Report (Anchor QEA 2013b), extensive effort was expended to evaluate numerous potential sources of contamination to the Site, including point sources, groundwater, spills, bank erosion, atmospheric deposition, and interaction with the HSC. In general, the RI Report (Anchor QEA 2013b) findings are consistent with the conceptual site model of legacy contamination, and no ongoing sources of contamination to sediments were identified. Four outfalls currently discharge just upstream of the Site: City of Deer Park WWTP outfall, Lubrizol outfall 001, and two stormwater-only outfalls (Lubrizol outfalls 002 and 006). Three other outfalls currently discharge directly into the East Fork Tributary: Praxair outfall 001, Rohm and Haas outfall 003 (stormwater), and Lubrizol outfall 007 (stormwater). Within the concrete-lined channel, seven outfalls currently discharge stormwater, treated domestic wastewater, and/or utility wastewater. Downstream of the concrete-lined channel, six outfalls (four Shell and two Oxy) currently discharge stormwater, non-process Feasibility Study Report Patrick Bayou Superfund Site 15 March 2017 040284-01.08 Background Information wastewater, fire water, and/or non-contact cooling water withdrawn from the HSC. Currently, there are no known active point-source discharges that add contaminants to the Site above National Pollutant Discharge Elimination System (NPDES) discharge limits or above typical urban background loading. Thus, current direct discharge to the Site from permitted outfalls is not considered a substantive source of contaminants to the Site. Outfalls are shown on Figure 2-2. Currently, groundwater from each facility has very little measurable interaction with the Site and does not contribute to chemicals of potential concern (COPCs) observed in Site sediments and surface water, as discussed in the RI Report (Anchor QEA 2013b). Historically, contaminated groundwater may have entered the Site via discharge through sediments or bank seeps. While deeper groundwater bearing zones (i.e., below the Beaumont Formation) are not hydraulically connected to the Site, shallow groundwater bearing zones have some connection to the Site. Releases of chemicals to upland soils may have resulted in migration of these chemicals to groundwater, which subsequently migrated to the Site. There is no historical record of spills prior to 1958. Historical spills are potential sources of chemicals at the Site. A review of spill reports maintained by the Texas Parks and Wildlife Department from 1958 to 2005 (Denton 2006) revealed no documented spills at the Site during that time. Numerous spills have occurred in the HSC adjacent to the Site. Spills in the HSC could potentially travel via surface water into the Site. Potentially, soils or fill containing chemicals could erode from unprotected banks of the Site and enter surface water or sediments. However, much of the shoreline has been modified by placement of fill and/or concrete armor over time. The sources and quality of the fill materials is unknown. Currently, much of the Site banks are covered with bank stabilization materials, which inhibit erosion. Unstabilized areas generally have natural cover as well to inhibit erosion; there are few, if any, significant areas of bare soil adjacent to the Site. Thus, there are no known current sources of contaminants loading associated with bank erosion for the Site. Feasibility Study Report Patrick Bayou Superfund Site 16 March 2017 040284-01.08 Background Information Nearly all surface waterbodies are exposed to potential deposition of chemicals in the atmosphere. Chemicals deposited to surface waters of the Site may come from local and regional point and non-point sources. Chemicals deposited to surface water may become dissolved in surface water, adsorbed to particulates in surface water, or may adsorb to sediments. Polycyclic aromatic hydrocarbons (PAHs), PCBs, mercury, and PCDDs/PCDFs are common atmospheric pollutants in urbanized environments and are expected to represent both current and ongoing sources of contamination to the Site, although at very low levels. The HSC is known to be impacted from sources other than the Site by several contaminants, including PAHs, PCBs, PCDDs/PCDFs, pesticides, and mercury. The Site is tidally influenced, and the tidal fluctuation produces an exchange of surface water between Patrick Bayou and HSC within the Site. Chemicals released, historically and currently, into the HSC may migrate into the Site as a result. 2.6.2 Distribution of Indicator Chemicals The RI Report (Anchor QEA 2013b) identified four indicator chemicals (ICs) from the list of COCs that were the basis for the nature and extent evaluation. PCBs were selected as the primary IC based on potential risk to wildlife and benthic invertebrates (i.e., benthos). PAHs, lead, and bis(2-ethylhexyl) phthalate (BEHP) were selected as secondary ICs based on some potential risk to benthos. The ICs selected in the RI Report (Anchor QEA 2013b) were media-specific and were based on the results of the BERA Report (Anchor QEA 2013b, 2013c) and to a lesser extent on non risk-based factors. These four ICs and their rationale for selection for each media are discussed in the RI Report (Anchor QEA 2013b). Following submittal of the Draft FS Report (Anchor QEA 2014) and upon subsequent discussions with the JDG, the USEPA required the evaluation of mercury and PCDD/PCDFs under the human health TSWQS Applicable or Relevant and Appropriate Requirement (ARAR). To address this requirement, mercury and PCDD/PCDF nature and extent are summarized below for sediment and porewater based on their potential as source media for surface water. The PCDD/PCDF results are expressed as 2,3,7,8-tetrachlorodibenzo-p-dioxin Feasibility Study Report Patrick Bayou Superfund Site 17 March 2017 040284-01.08 Background Information (TCDD) TEQs calculated using toxic equivalency factors (TEFs) listed in the Texas Administrative Code, Title 30, Chapter 307 (i.e., TSWQS) effective March 6, 2014. The following sections summarize the nature and extent of ICs, mercury, and PCDD/PCDF TEQ in Site media. 2.6.2.1 Surface Sediment Surface sediment samples from 66 locations within in Site were collected representing the interval from the surface up to a depth of 11 cm below the surface (Anchor QEA 2013b).5 Samples from 14 stations were collected in 2006, 46 stations in 2009, and 6 stations in 2011. All four ICs, mercury, and PCDD/PCDF congeners were included in 2006 and 2009 sediment sample analyses. The 2011 samples were analyzed for PCB Aroclors and PAHs because those are the primary ICs in the upstream area that was the focus of that investigation. Results for surface sediment ICs, mercury, and PCDD/PCDF TEQ are mapped on Figures 2-4 through 2-9 (PCBs, PAHs, BEHP, lead, PCDD/PCDF TEQ, and mercury, respectively). The highest concentrations of total PCB congeners and PCDD/PCDF TEQ were near the downstream end of the Site at Station PB-026; however, total PCB congener concentrations are also elevated at a few station locations between Stations PB-047 and PB-069. Maximum concentrations of BEHP and mercury were further upstream at Stations PB-036 and PB-053A, respectively. Although the maximum lead concentration was observed at PB-081, it demonstrated a generally increasing trend in concentration in the downstream direction. Lastly, the maximum concentration of total PAHs was located near the upstream end of the Site at Station PB-081 and generally decreased in the downstream direction. In addition, several surface sediment samples were collected upstream of the Site boundary and were analyzed for PCBs, PAHs, lead, PCDD/PCDF TEQ, and mercury. Sample locations are shown on Figure 2-10. In general, upstream concentrations of ICs, mercury, and PCDD/PCDF TEQ are less than or within the range of values observed in Site surface sediments. To the extent that upstream concentrations of ICs, mercury, and PCDD/PCDF Several samples have been collected during the RI at shallower intervals (e.g., 0 to 2 cm). Results from these shallow surface intervals are not discussed here. Results for these shallow intervals can be found in Anchor (2007). 5 Feasibility Study Report Patrick Bayou Superfund Site 18 March 2017 040284-01.08 Background Information TEQ are similar to those in certain areas of the Site, this will limit the reduction in concentration that can be achieved in these areas through natural recovery. 2.6.2.2 Subsurface Sediment Subsurface samples, defined as samples collected from depth intervals greater than 11 cm, were collected at 12 locations (Figure 2-11). All samples were analyzed for all sediment ICs, mercury, and PCDD/PCDF TEQs. The distribution of total PCBs,6 total PAHs, BEHP, lead, PCDD/PCDF TEQ, and mercury are shown on Figures 2-12 through Figure 2-17. In general, ICs, mercury, and PCDD/PCDF TEQs show increasing concentration with depth, with subsurface maximum concentrations generally found between 50 and 120 cm below mudline. The stations generally exhibiting the highest subsurface concentrations of total PCBs, total PAHs, and lead were PB-042, PB-048, and PB-057. Maximum PCDD/PCDF TEQ values were reported at Stations PB-022 and PB-042. The stations exhibiting the highest subsurface concentrations of mercury were PB-022, PB-048, and PB-057. With few exceptions, the lowest concentrations of ICs, mercury, and PCDD/PCDF TEQs were observed in sample intervals near the contact with the native regional clay formation (i.e., Beaumont Formation). The vertical profiles of PCBs in Patrick Bayou show changes at the Site in terms of ongoing reduction of surface sediment concentrations. The vertical profiles of PAHs, BEHP, PCDD/PCDF TEQ, and mercury show that the concentrations of these chemicals at the surface (and thus available to potential surface receptors) have also significantly declined over time since the peak of contaminant loading (Figures 2-12 through 2-17; Anchor 2007). Although the peak concentration varies by chemical and location, the vertical profiling and associated radiometric analyses conducted in 2006 indicate that most loading for these chemicals occurred more than 30 years ago (92 cm and deeper; Anchor 2007). These observations indicate the following: • Historical or legacy discharges are responsible for the bulk of the concentrations of chemicals observed at the Site, and 6 Only PCB Aroclors were analyzed in subsurface sediments. Feasibility Study Report Patrick Bayou Superfund Site 19 March 2017 040284-01.08 Background Information • Natural attenuation should continue to lower potential risk to surface receptors at the Site from these chemicals 2.6.2.3 Porewater As part of the remedial investigation, porewater was collected from ten locations within the Site boundary (Anchor QEA 2013b). Figures 2-18, 2-19, and 2-20 present the results for total PCB congeners, total PAHs, and BEHP by location, respectively.7 Lead was not detected in any of the porewater samples. Station PB-036 had the highest concentration of all three detected ICs, while PB-006A had the lowest concentration of all three detected ICs. Porewater concentrations provided site-specific information on chemical partitioning within the sediments (see Appendix A). 2.6.2.3.1 Mercury Speciation in Porewater Mercury in aquatic systems occurs in two general forms, organic and inorganic. Organic mercury is primarily present as methylmercury (CH3Hg+). Methylmercury occurs as an aqueous species and can be adsorbed on to sediment organic carbon through equilibrium partitioning processes. It is the most prevalent and most biochemically active form of organic mercury in sediments. Relative to inorganic forms of mercury, methylmercury is significantly more toxic (Wolfe et al. 1998). Because methylmercury occurs as an aqueous species, actual porewater measurements versus bulk sediment measurements provide more accurate and conservative estimates of the methylation potential, location, and bioavailability. Understanding the partitioning of mercury between inorganic and organic forms on a Site-specific basis provides important information to assess impacts to aquatic systems and water quality compared to measures of total mercury. If the fraction of methylmercury relative to total mercury is low, the probability of mercury entering the aquatic food chain is likely to be lower and bioaccumulation in edible fish tissue less prevalent than would be indicated based on measures of total mercury. PCDD and PCDF congeners were not identified as contaminants of potential concern in porewater and were not included in the target analyte list for the investigation. 7 Feasibility Study Report Patrick Bayou Superfund Site 20 March 2017 040284-01.08 Background Information Vertical profiling of mercury speciation in porewater was performed at ten locations within the Site boundary in 2008 (Anchor QEA 2013b). Sediment was collected in 2-cm intervals from the top 20 cm of sediment. One hundred porewater samples were submitted for total mercury, methylmercury, and alkylatable ionic mercury (weakly complexed mercury) analyses.8 Figure 2-21 presents the vertical profiles of porewater results of the mercury speciation analysis at each station. Total mercury was detected in porewater in all 100 samples. The maximum detected concentrations of total mercury, methylmercury, and mercury sulfide were observed at PB-036. The maximum detected concentration of weakly complexed mercury was observed at PB-053. A distinct vertical gradient of increasing total mercury, weakly complexed mercury, and mercury sulfide in porewater with depth was observed. Concentrations of methylmercury showed little variation with depth at a particular location. The proportion of methylmercury was low relative to total mercury concentrations. Out of 100 samples, 84 samples had methylmercury concentrations less than 5 percent (by weight) of the total mercury in the sample. This analysis indicates that the rate of mercury methylation in Patrick Bayou sediments is low and, as a result, severely limits the bioavailability of mercury to aquatic receptors and exposure to higher trophic-level receptors through bioaccumulation pathways. The conclusions in the BERA Report (Anchor QEA 2013c) and BHHRA Report (Anchor QEA 2012) support this analysis—mercury was not identified as a Site COC due to risk to human health or ecological receptors at the Site.9 Further evaluation of mercury, including the effect of low methylation rates on water quality, will be an important consideration in pre-design investigations. There is evidence, based on the analysis of mercury speciation in porewater for the Site, that measures of total Results for mercury sulfide were calculated based on the difference between total mercury and methylmercury plus weakly complexed mercury. 9 The approved Baseline Human Health Risk Assessment Work Plan (Anchor QEA 2011a) included a spatial analysis of Texas Department of State Health Services fish advisory tissue data. This USEPA-approved analysis concluded that the Site is not an incrementally significant source of mercury to fish in the HSC, and therefore, mercury was eliminated as a chemical of potential concern with respect to the fish consumption pathway. 8 Feasibility Study Report Patrick Bayou Superfund Site 21 March 2017 040284-01.08 Background Information mercury in porewater and potentially surface water (i.e., TSWQS) are conservatively biased measures of potential impacts to human health. 2.6.2.4 Surface Water Surface water was collected during three sampling events (Figure 2-22). Twenty-two samples were collected from eight stations from outside and within the Site boundary in 2009. These surface water samples were analyzed for several target analytes, including PCB congeners, mercury, and PCDDs/PCDFs. In 2011, four samples were collected from within the Site boundary between Stations PB-070 and PB-101. In 2014, a total of 23 samples were collected from 21 stations located both outside and within the Site boundary (Appendix D). In 2011 and 2014, PCBs were the only COC10 included in the surface water sample chemical analysis. Total PCBs were detected in all samples for the 2009, 2011, and 2014 sampling events (Figure 2-23). For the 2009 sampling event, the highest concentration of total PCBs (431 ng/L) was reported at Station PB-059A. For the 2011 sampling event, the highest concentration of total PCB congeners was reported at Station PB-080 (143 ng/L); the farthest upstream station, Station PB-101C, had the lowest total PCB congener concentration (5.65 ng/L). The highest concentration of total PCB congeners reported during the 2014 sampling event was from the sample collected at Station PB-070B (72 ng/L); the farthest upstream station, Station PB-119B, had the lowest total PCB congener concentration (0.566 ng/L). As shown on Figure 2-23, in general, surface water concentrations of PCBs have declined over time. The 22 surface water samples collected in 2009 were analyzed for PCDD/PCDFs. Seven of the 17 PCDD/PCDF congeners were not detected in any of the samples. Only four PCDD/PCDFs were detected in more than 50 percent of the samples. PCDD/PCDF TEQ was calculated for all the surface water samples. Results ranged from 0.00000969 ng/L to 0.00270 ng/L. However, these results may be biased high due to the proportion of 10 Not including conventional analytes such as organic carbon or total suspended solids. Feasibility Study Report Patrick Bayou Superfund Site 22 March 2017 040284-01.08 Background Information non-detects included at one-half the reporting limit, per the summation rules.11 The maximum value was reported at Station PB-031 (Figure 2-24). The lowest PCDD/PCDF TEQ values were reported in the samples located in the upper portion of the Site. The 2009 surface water samples were also analyzed for total and dissolved mercury. Dissolved mercury was detected in only one sample collected at Station PB-006 (0.0051 micrograms per liter [µg/L]). Total mercury was detected in 19 of the 22 samples. Total mercury concentrations ranged from 0.0056 µg/L (HSC-14) to 0.24 µg/L (Station PB-006; Figure 2-25). Surface water samples collected at HSC-14 had the lowest mercury concentrations. As shown on Figure 2-25, there is generally a decreasing trend in total mercury concentrations moving upstream at the Site. 2.6.2.4.1 Background Conditions in the Houston Ship Channel The background concentration for total PCBs and PCDD/PCDF TEQ was derived through an analysis of PCB and PCDD/PCDF congener data in the HSC measured as part of the PCB and Dioxin TMDL studies (Rifai 2006; Rifai and Palacheck 2006, 2007, 2008, 2009, 2010). These data can be used to assess background conditions for Patrick Bayou due to tidal exchange that occurs between Patrick Bayou and the HSC. Consistent with comments received from TCEQ (2016), data from Segments 1006 and 1007 were included in the background dataset (Table 2-1). The dissolved and particulate fractions measured in the TMDL studies were summed to calculate total PCBs and PCDD/PCDF TEQ in surface water at locations in the HSC. For total PCBs, the average concentration in surface water is 3.7 ng/L, with a range of 0.44 to 12.5 ng/L (Figure 2-26; Table 2-2). For PCDD/PCDF TEQ, the average concentration is 0.00051 ng/L, with a range of 0.00009 to 0.0018 ng/L (Figure 2-27; Table 2-2). A background threshold value (BTV) based on an upper limit estimator was established to assist in assessing the attainability of the TSWQS due to water quality conditions in the HSC. Using the 95 percent upper prediction limit (95UPL) as the preferred point estimate for a The detection limits for PCDD/PCDF congeners in surface water were based on data quality objectives set to meet the TSWQS for aquatic life and not human health, which was set as a tissue-based criteria at the time of sampling. 11 Feasibility Study Report Patrick Bayou Superfund Site 23 March 2017 040284-01.08 Background Information BTV (TCEQ 2016), the result for background total PCBs is 8.2 ng/L.12 For PCDD/PCDF TEQ, the BTV based on the 95UPL is 1.2E-3 ng/L.13 These BTVs are higher than the TSWQS human health “fish only” criteria for PCBs and PCDD/PCDF TEQ, which are 0.64 and 7.97E-5 ng/L, respectively. 2.6.2.5 Tissue Hazard quotients (HQ) at or above one (1.0) were calculated in the BERA Report (Anchor QEA 2013c) for piscivorous (HQ = 1.7) and shorebird populations (HQ = 1.0) due to PCBs in potential prey tissue. No tissue COCs were identified in the BHHRA Report (Anchor QEA 2012). Therefore, the nature and extent summary below is limited to whole body tissue data used in the BERA Report (Anchor QEA 2013c) and focuses on PCBs expressed as 2,3,7,8-TCDD TEQs using avian (TEQavian) TEFs. A full discussion of all biota data can be found in the RI Report (Anchor QEA 2013b). A total of 83 whole body tissue samples from locations within the Site were analyzed as part of the BERA investigation (Anchor QEA 2013c). These included 33 shellfish samples and 50 fish samples. Four different shellfish species were collected and analyzed. These included blue crab, brown shrimp, oyster, and white shrimp. Shellfish were analyzed in two different size classes. Five different fish species were collected and analyzed. These included Gulf killifish, Gulf menhaden, pinfish, sand seatrout, and striped mullet. For shellfish, the highest PCB TEQ for avian predators was reported in blue crab samples (782.9 [TEQavian] ng/kg). The average concentration in blue crab samples was 380 PCB TEQavian ng/kg. Spatial representation for shellfish PCB TEQavian results are depicted in scatterplots and maps on Figure 2-28. In general, the highest total PCB TEQavian values for shellfish were observed between 2,000 and 8,000 feet from the HSC (i.e., PB-020 to PB-080). In whole body fish tissue, the concentration of PCB TEQavian values ranged between 77.5 TEQavian ng/kg and 1,173 TEQavian ng/kg. The highest PCB TEQavian value was reported in Calculated using ProUCL Version 5.0 (http://www.epa.gov/osp/hstl/tsc/software.htm). The 95UPL is based on the 95 percent Wilson–Hilferty Approximation Gamma UPL. 13 Calculated using ProUCL Version 5.0 (http://www.epa.gov/osp/hstl/tsc/software.htm). The 95UPL is based on the normal 95UPL. 12 Feasibility Study Report Patrick Bayou Superfund Site 24 March 2017 040284-01.08 Background Information Gulf killifish samples (1,173 [TEQavian] ng/kg). To depict potential spatial relationships of concentrations along the Site PCB TEQavian results were graphed with scatterplots showing results values versus distance from the mouth of the Site at its confluence with the HSC. For Gulf killifish, as shown on Figure 2-29, a general cluster of higher PCB TEQavian values is apparent near stations PB-050 to PB-070 as opposed to either the mouth or the upstream end of the Site. Spatial representation for menhaden PCB TEQavian results is depicted on Figure 2-30. In contrast to Gulf killifish, a general trend of increasing concentration is apparent from the mouth of the Site to station PB-058. Spatial representation for pinfish, sand seatrout, and striped mullet PCB TEQavian results, is depicted on Figure 2-31. The data in these figures show a slight trend of increasing concentrations of PCB result values and TEQs is visible from the mouth of the Site toward the upstream portions of the Site. 2.6.2.6 Mean Probable Effects Level Quotient In the BERA Report (Anchor QEA 2013c), several different quotient or toxic unit models that have been described in the scientific literature to predict potential sediment toxicity based on bulk sediment chemistry were evaluated. The performance of each model was assessed by applying it to Site-specific, co-located bulk sediment chemistry data and bioassay (i.e., toxicity) data for the Site. Of the models assessed, a mean quotient model using the Probable Effects Level (Long et al. 2006) was initially selected based on several performance criteria identified in the BERA Work Plan (Anchor QEA 2011a). This model, referred to as the mean Probable Effects Level-Quotient (PEL-Q), was refined using a series of optimization steps developed in the approved BERA Report (Anchor QEA 2013c). This optimized model included four COPCs (total PCBs, total PAHs, lead, and BEHP) that demonstrated a statistically significant difference in concentration between toxic and nontoxic samples. Of the four COPCs, total PCBs presented the dominant contribution to the calculated mean PEL-Q (Anchor QEA 2013c). This mean PEL-Q metric was then used as one of three lines of evidence (LOEs) within a weight-of-evidence (WOE) framework in the BERA Report (Anchor QEA 2013c) to characterize risk to the benthic community. Surface bulk sediment samples were used to describe the nature and extent of the distribution of these four COPCs using the mean PEL-Q. All surface sediment samples that included all four COPCs were included in the dataset for the RI Report (Anchor QEA Feasibility Study Report Patrick Bayou Superfund Site 25 March 2017 040284-01.08 Background Information 2013b). Surface sediment samples from 66 locations within the Site were collected from 0 to up to 11 cm. Samples from 14 stations were collected in 2006, 46 stations in 2009, and 6 stations in 2011. All four COPCs were included in 2006 and 2009 sediment sample analyses. The 2011 sampling event included only PCBs and PAHs; thus, a mean PEL-Q was not calculated for those locations. As a result, a total of 60 locations were included in the calculation of Mean PEL-Q in the RI Report (Anchor QEA 2013b). Surface sediment mean PEL-Q values are mapped on Figure 2-32. In general, the highest mean PEL-Q values were reported at Stations PB-026, PB-032, and PB-053A. The maximum mean PEL-Q value, 166.5, was reported at Station PB-026. 2.6.3 Chemical Characteristics of Indicator Chemicals The degree to which the ICs, mercury, and PCDD/PCDF congeners move from sediment to water and become bioavailable is affected by their solubility in water, their tendency to adsorb to sediment particles, and the rate at which they degrade in the environment. The parameters used to characterize these properties are the water solubility, partition coefficient, and biodegradation rate of each chemical. PCBs, lead, and PCDD/PCDF congeners (described in Section 2.6.2) do not volatilize to a significant degree, so properties related to volatilization (primarily Henry’s Law constant) are not discussed further. Low molecular weight PAHs (e.g., naphthalene), BEHP, and mercury are more volatile in some environmental settings but under the conditions at the Site, volatilization is not expected to be a significant fate or transport mechanism for these chemicals. Table 2-3 presents a summary of the chemical properties for the ICs, mercury, and PCDD/PCDF congeners. Chemicals with lower water solubility and higher partition coefficients have less potential to enter the aqueous phase and become mobile. Chemicals that are strongly adsorbed to the sediment may be transported with sediment if the sediment is resuspended by high surface water velocities and can also be exchanged between sediment porewater and surface water. The following subsections describe the relevant chemical properties of the ICs, mercury, and PCDD/PCDF congeners. Feasibility Study Report Patrick Bayou Superfund Site 26 March 2017 040284-01.08 Background Information 2.6.3.1 Polychlorinated Biphenyls In general, PCBs are less soluble in water and adsorb more strongly to sediment than the other ICs but are similar in this respect to PCDD/PCDF congeners. Although these properties make PCBs less bioavailable than the other ICs, PCBs tend to bioaccumulate (PCBs that enter an organism tend to be stored rather than broken down or excreted), which can increase the potential effect of PCBs on the food chain. Chemical properties are more difficult to define for groups of chemicals, such as PCBs, than for individual constituents. In general, less chlorinated PCBs are more water-soluble and adsorb less strongly to sediment than the more chlorinated PCBs. This tendency is illustrated by the relatively low solubility and high partition coefficient, in sequence, for the deca-substituted (PCB-209) and tetrasubstituted homologs as compared to the tri-substituted homologs (Table 2-1). The heaviest PCB, PCB-209 (decachlorobiphenyl), is even less water-soluble and partitions more strongly to sediment than the tetra-substituted PCBs. The lighter PCBs also tend to be more biodegradable under aerobic conditions. Anaerobic biodegradation has also been reported in some cases, although anaerobic degradation tends to focus on the heavier PCBs. Reductive dechlorination by aerobic or anaerobic organisms tends to focus on the meta- and parachlorines. Ortho-substituted PCBs are less likely to be biodegraded but these PCBs are also less toxic than the coplanar PCBs (Field et al. 2007). The large majority of sediments at the Site are anaerobic, and degradation of PCBs is typically quite slow under those conditions to the point that degradation of PCBs in sediments is generally not considered an important process on the timescales of interest for the RI/FS. Additional information on Site-specific PCB characteristics is included in the chemical fate modeling documented in Appendix A. 2.6.3.2 Total Polycyclic Aromatic Hydrocarbons As with the group of PCBs, PAHs, as a group, are complex to evaluate and the data presented in Table 2-1 indicate a wide range of chemical properties. Certain PAHs (e.g., acenaphthene and naphthalene) are more likely to be present in the aqueous phase than other PAHs because they have higher solubility in water and lower partition coefficients. However, acenaphthene and naphthalene, in particular, have relatively short half-lives in aerobic conditions, which may prevail in shallow surface water. Other PAHs (e.g., benzo(k) fluoranthene and indeno(1,2,3-cd)pyrene) have significantly less solubility in water and higher partitioning coefficients. These PAHs are less likely to be present in the aqueous Feasibility Study Report Patrick Bayou Superfund Site 27 March 2017 040284-01.08 Background Information phase and have relatively long half-lives under anaerobic conditions that are present in sediment at the Site. Generally, PAHs are more soluble than heavier PCBs (e.g., PCB-209) and less soluble than BEHP. Despite having a greater solubility than heavier PCBs, PAHs are less bioaccumulative because they are metabolized by organisms. Certain PAHs (e.g., anthracene, fluoranthene, and pyrene) demonstrate similar solubility and bioavailability as lighter PCBs (e.g., tri- and tetra- substituted PCBs), while naphthalene and acenaphthene are approximately an order of magnitude more soluble than tri-substituted PCBs. 2.6.3.3 Bis(2-ethylhexyl) Phthalate Data presented in Table 2-1 indicate the solubility and partitioning coefficient of BEHP is similar to tri-substituted PCBs. Biodegradation of BEHP has been reported with a half-life range of 41 to 389 days in anaerobic conditions, which are likely in subsurface sediment at the Site (USEPA 1996). Aqueous BEHP is also relatively biodegradable within the aerobic conditions likely present in the shallow surface water of the Site. The aerobic half-life of BEHP is between 5 and 23 days (USEPA 1996; Table 2-1). 2.6.3.4 Lead and Mercury The solubility of metals, including lead and mercury, is highly dependent on water chemistry, which affects the speciation of the metal. Mercury solubility is controlled by the presence of sulfide radicals and organic matter (Bessinger et al. 2012). Lead is reported as insoluble in water at neutral and higher pH (USEPA 2007). Lead can react with a variety of negative radicals (such as sulfide, sulfate, and carbonate) to form insoluble salts. Analytical tests performed on samples from the Site provide multiple lines of evidence that the chemical states of lead and mercury found at the Site appreciably limit bioavailability: • The acid volatile sulfide (AVS) and simultaneously extracted metal (SEM) analyses test whether the amount of sulfide radicals present in the environment is sufficient to sequester the available divalent metals such as mercury and lead. When the molarity of AVS exceeds the molarity of SEM, the SEM are present in the form of insoluble sulfide salts that are not bioavailable (USEPA 2000). The AVS/SEM analyses Feasibility Study Report Patrick Bayou Superfund Site 28 March 2017 040284-01.08 Background Information summarized by Anchor QEA (2010) demonstrate that sufficient sulfide is present at the Site to sequester all of the available lead and mercury as insoluble sulfide minerals. Moreover, mercury SEM was below detection in all samples. • Methylmercury is the most bioavailable form of mercury found in the environment. The analysis of mercury speciation in porewater discussed in Section 2.6.2.3.1 indicates that rates of mercury methylation in Patrick Bayou sediments is low, and therefore markedly limits the bioavailability of mercury to aquatic receptors and exposure to higher trophic level receptors. • Lead was not detected in porewater (Anchor 2008). 2.6.3.5 Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans As with PCBs and PAHs, PCDDs/PCDFs (as a group) are complex to evaluate due to a wide range of chemical properties that these constituents exhibit (Table 2-3). PCDDs/PCDFs share many of the general physical-chemical properties of PCBs. As with PCBs, PCDDs/PCDFs are hydrophobic organic compounds characterized by low aqueous solubilities, have low vapor pressures, and high octanol-water partition coefficients (Table 2-3), and are not readily degraded in the environment. However, PCDDs/PCDFs are considerably more hydrophobic than PCBs (Table 2-3). 2.7 Contaminant Fate and Transport As discussed in Section 2.6.2 and in greater detail in Section 4 of the RI Report (Anchor QEA 2013b), the primary IC class at the Site is PCBs. Total PAHs, BEHP, and lead are also associated with some risk to benthic receptors. Mercury and PCDD/PCDFs are being considered in this report based on USEPA’s direction to consider the human health TSWQS as an ARAR for the Site. The fate and transport of PCBs, other ICs, mercury, and PCDD/PCDFs is a function of their chemical properties and the physical conditions of the Site. This section discusses key fate and transport processes and the modeling framework used to evaluate the fate and transport of these chemicals at the Site in this FS. There are a number of processes that can affect fate and transport of sorptive chemicals (such as PCBs) within an aquatic system (Figure 2-33). The most significant chemical fate and Feasibility Study Report Patrick Bayou Superfund Site 29 March 2017 040284-01.08 Background Information transport processes affecting concentrations of PCBs (and similar sorptive compounds) within Patrick Bayou include the following: • Sediment-water interactions – Because of the hydrophobic nature of PCBs, they preferentially bind to particulate matter. As discussed above, the extent of hydrophobicity varies by congener, with the lighter, less chlorinated congeners exhibiting less hydrophobicity than the heavier, more chlorinated congeners. The sediment bed, therefore, serves as a net sink, adsorbing PCBs. To the extent that PCBs may have accumulated within the bed over time (e.g., if there were historical releases and subsequent transport), they can act as a source to the water column, and chemicals being transported in the water column can likewise deposit on the bed. The flux of sediment particles (and particle-bound PCBs) between the bed and water column are driven by sediment deposition and erosion processes, especially during episodic events such as floods. Deposition also provides a mechanism for natural recovery if concentrations of PCBs on particles in the water column are lower than those at the bed surface. Thus, within-bed dynamics, such as transfers between surface and deeper layers of the bed, are also important. • Partitioning and dissolved phase flux – The distribution of PCBs between the particulate and dissolved phases within the water column and bed sediments are determined by their partitioning behavior (as quantified by the partitioning coefficient). Because they are hydrophobic (as indicated by relatively high organic carbon/water partition coefficient; Mackay et al. 1992), PCBs will primarily be present in particulate form, which means that their fate is largely determined by sediment transport processes. However, in areas where PCBs have accumulated within the surface layer of the sediment bed, partitioning will result in porewater concentrations that can be much greater than those in the overlying water column. Such a concentration gradient, through the process of surface exchange flux (due to diffusion, bioturbation, and tidal pumping), results in a transfer of dissolved-phase mass to the water column that can affect concentrations in the Site under low flow conditions. • Transport in the water column – PCBs that are present in the water column (in both dissolved and particulate phases) are transported with the currents, which are affected by freshwater flow in addition to more complex circulation patterns associated with tides and ship traffic. Transport in the water column differs depending on the flow Feasibility Study Report Patrick Bayou Superfund Site 30 March 2017 040284-01.08 Background Information regime, since the relative importance of freshwater flow and tidal action, as well as the fate and transport processes that are active, differ by flow conditions. For example, under higher flow conditions, transport associated with sediment deposition and erosion is much greater. • External sources – In addition to fluxes from the sediment bed, which are considered an internal source, PCBs also enter the aquatic environment within the Site via external sources. As discussed in Section 2.6.1, transport of ICs, mercury, and PCDD/PCDFs via groundwater to the Site may have occurred historically but is no longer occurring at the Site. PCBs were detected in surface water samples collected upstream of the Site, as well as in the East Fork, albeit at relatively low concentrations. Furthermore, PCBs were detected in the HSC upstream of the Site and in dry and wet atmospheric deposition samples that were collected adjacent to the Site as part of the TMDL study (Rifai and Palacheck 2006, 2007, 2008, 2009, 2010). These processes therefore represent external sources to the aquatic environment of the Site. Water column data collected during and subsequent to the RI Report (Anchor QEA 2013b) provide a considerable amount of insight regarding PCB fate and transport processes within Patrick Bayou. Figure 2-23 shows spatial profiles of water column PCB data collected during 2009, 2011 (blue and red circles), and 2014 (green circles). These datasets show an increase in water column PCB concentration occurring across the concrete-lined channel (the upstream and downstream ends of the concrete-lined channel are indicated by vertical dashed lines on the figure). In 2009 and 2011, dataset total PCB concentrations increased from approximately 5 ng/L to nearly 100 ng/L across this relatively short reach, followed by a more gradual increase across the remainder of the Site. These data indicate that a significant load of PCBs to the water column begins at this location. Additional water column data were collected in 2014 (green circles on Figure 2-23) at a higher spatial resolution in the concrete-lined channel to develop a better understanding of the nature and extent of PCBs in surface water over this reach. These results confirmed the understanding of the spatial distribution of PCB loading Site-wide, and further demonstrated that a significant load is occurring over a relatively small portion near the downstream end of the concrete-lined channel (from approximately PB-082 to PB-075). Feasibility Study Report Patrick Bayou Superfund Site 31 March 2017 040284-01.08 Background Information Water column concentration increases downstream of the concrete-lined channel are likely a result of dissolved-phase flux of PCBs from PCB-containing sediments to the overlying water column. The subsequent decrease in these data at the downstream end of the Site is likely due to tidal mixing and dilution with water entering Patrick Bayou from the HSC. Figure 2-23 also shows that concentrations measured in 2014 were much lower than concentrations measured in 2009 and 2011, which indicates that natural recovery is active at the Site. Further discussion of these trends with respect to natural recovery is provided in Section 4.3.2 and Appendix E. A comprehensive chemical fate and transport model was developed to support this FS. This model, which was developed and calibrated to reproduce the observed longitudinal gradients in water column PCB concentrations described above, is described in detail in Appendix A. A brief summary of the overall model objectives and framework is provided below. Note that while the model developed to support this FS focused on PCBs, additional data will be collected during remedial design to support fate and transport modeling of surface water quality for mercury and PCDD/PCDF TEQ. 2.7.1 Fate and Transport Modeling The primary goal of the chemical fate and transport modeling study (summarized in Appendix A) is to simulate physical and chemical processes that are controlling the chemical fate and transport of PCBs within Patrick Bayou. Specifically, the primary objective of the modeling was to develop a mathematical framework that can do the following: 1. Build upon the existing hydrodynamic model and STM for the Site that are described in the STM Report (Anchor QEA 2011c) 2. Provide a quantitative linkage between PCBs in sediments and PCBs in surface water (i.e., predict observed mass flux) 3. Be used as a predictive management tool to evaluate the effectiveness of various remedial alternatives, including natural recovery, in meeting the relevant water quality standard, and providing improvements to potential benthic risk issues Feasibility Study Report Patrick Bayou Superfund Site 32 March 2017 040284-01.08 Background Information The mathematical modeling framework that was applied consists of three models that were linked together: hydrodynamic, sediment transport, and chemical fate and transport (Figure 2-34). The hydrodynamic model and STM are documented in the STM Report (Anchor QEA 2011c), while the chemical fate model is documented in Appendix A. These models were developed and calibrated, and together form a quantitative framework that can be used as a management tool to guide risk management decisions for the Site. The calibration and validation of the model framework indicates that it can simulate hydrodynamics, sediment transport, and chemical fate and transport within Patrick Bayou with sufficient accuracy to support its use in making relative comparisons among remedial alternatives in the FS. Because of the uncertainties associated with modeling due to data limitations, model sensitivity analyses were conducted to develop uncertainty bounds around its predictions. These uncertainty bounds were carried through the simulations of remedial alternatives presented in Appendix A. Feasibility Study Report Patrick Bayou Superfund Site 33 March 2017 040284-01.08 3 BASIS FOR REMEDIAL ACTION 3.1 Remedial Action Objectives RAOs for the Site were developed during the RI Report (Anchor QEA 2013b) and refined during preparation of the FS. The RAOs are intended to do the following: • Address potential risk to benthos associated with PCBs, PAHs, lead, and BEHP • Mitigate risk to aquatic-dependent wildlife associated with PCBs • Reduce total PCB concentrations in surface water to the TSWQS for protection of human health or to background levels in the HSC, if higher The surface water RAO was developed to address ARARs as directed by USEPA. Detailed discussion of ARARs, including water quality ARARs, is provided subsequently in this Section. As described in Section 1.2, consistent with the direction provided by USEPA, RAOs for mercury and PCDD/PCDF TEQ in surface water are not included in the FS. Rather, establishment of RAOs for these chemicals will be considered using the adaptive management framework for the Site after additional data collection and analysis (e.g., modeling) has been performed during the design phase. This additional information will provide a basis for establishing additional RAOs; evaluating the potential effect of the alternative selected in this FS on water quality with respect to these chemicals; and, if necessary, identifying additional remedial actions that may be required. 3.2 Benthic Risk Remedial Action Objectives To address potential benthic risk, a benthic RAO was developed for this FS based on the BERA Report (Anchor QEA 2013c). More specifically, the benthic RAO was derived from site-specific, paired sediment chemistry and sediment toxicity data (referenced in section 2.6.2.6.) that were used to characterize risk to the benthic community in the BERA Report (Anchor QEA 2013c). Using the sediment toxicity and sediment chemistry LOEs approved in the BERA Report (Anchor QEA 2013c), a threshold mean PEL-Q was identified that is protective of the narrative intent of the benthic RAO. The development of the benthic RAO is presented in the following subsections. Feasibility Study Report Patrick Bayou Superfund Site 34 March 2017 040284-01.08 Basis for Remedial Action 3.2.1 Summary of the BERA Risk Characterization As stated previously, a WOE approach was developed to assess benthic risk in the BERA Report (Anchor QEA 2013c). This WOE approach included the review and analysis of sitespecific bulk sediment chemistry data, sediment bioassay (toxicity) data, and benthic community data as LOEs. The objective of the WOE approach was to use the apparent correspondence between the values or metrics assigned to the LOEs, and the overall strength of the correspondence, where it existed, to identify areas of the Site where measurable incremental risks to the benthic community due to exposure to site-related COPCs are deemed probable, indeterminate, or low. Twelve different locations within the Site with co-located synoptic bulk sediment chemistry, bioassay, and benthic community data were included in the analysis. Based on the WOE approach, three of these locations were identified as areas where incremental Site-related risks to the benthic community was probable, four areas were identified as indeterminate, and five areas were identified as low (Figure 8-1 of the BERA Report, Anchor QEA 2013c). Although the BERA Report (Anchor QEA 2013c) did not identify any specific risk management recommendations for benthic risk, the RI Report (Anchor QEA 2013b) concluded that remedial alternatives should be evaluated in the FS that lower the overall Site and sub-area risk for areas that are characterized as indeterminate and probable risks to benthos (Anchor QEA 2013b). The RI Report (Anchor QEA 2013b) also recommended that risk management strategies for benthic receptors should be considered within the overall context of other risk management considerations such as surface water quality. To support the remedial alternatives evaluation, the results of the BERA Report (Anchor QEA 2013c) benthic risk assessment were used to identify a mean PEL-Q threshold, the definition of which was discussed in Section 2.6.2.3, that would represent the highest threshold characterized as low risk to the benthic community, based on the sediment toxicity LOE. The benthic community LOE was not incorporated in this analysis given the very low degree of correspondence between this LOE and the sediment toxicity and chemistry LOEs. In the BERA Report (Anchor QEA 2013c), the sediment toxicity LOE was evaluated using the frequency of toxicity associated with a particular location. To characterize toxicity for a Feasibility Study Report Patrick Bayou Superfund Site 35 March 2017 040284-01.08 Basis for Remedial Action specific location, the proportion of toxic samples was determined for each location. The proportion toxic was calculated as follows: Proportion toxic = Toxic results/Total results Next, overall incremental risk to benthos due to sediment toxicity was categorized for each location using the proportion of toxic samples according to the following criteria: • Probable Risk – the proportion of toxic samples was equal to or exceeded 50 percent • Indeterminate Risk – the proportion of toxic samples was between 25 and 50 percent (exclusive) • 3.2.2 Low Risk – the proportion of toxic samples was less than or equal to 25 percent Identification of Preliminary Remediation Goal for Benthic Risk To identify an RAO for benthic risk, the highest mean PEL-Q threshold that resulted in low frequency of adverse effects based on the sediment toxicity LOE was identified using the BERA analysis. The mean PEL-Q and proportion of toxic samples at each sample location evaluated in the BERA Report (Anchor QEA 2013c) are presented in Table 3-1. Based on the dataset presented in the BERA Report (Anchor QEA 2013c), the highest mean PEL-Q associated with low frequency of sediment toxicity is 4.47. Thus, a mean PEL-Q threshold of 4.47 was identified as the benthic RAO for the FS. Figure 2-32 presents mean PEL-Q and toxicity results for surface sediment samples, as described in Section 2.6.4. Figure 3-1 presents Thiessen polygons where the benthic RAO is exceeded based on the 2009 surface sediment dataset. This figure does not consider changes in sediment chemistry/mean PEL-Q that might have occurred due to natural recovery since the baseline sediment dataset was collected in 2009. Additional sampling is planned during the pre-design phase to update surface sediment conditions with respect to the mean PEL-Q (i.e., areas exceeding the RAO will be refined). See Section 4.3 for additional details on the screening and assembly of alternatives to address RAOs, including pre-design sampling. 3.3 Aquatic-dependent Wildlife RAO Potential risks to aquatic-dependent wildlife were identified for two receptors, spotted sandpiper and belted kingfisher, due to exposure to PCBs in their diet and through incidental Feasibility Study Report Patrick Bayou Superfund Site 36 March 2017 040284-01.08 Basis for Remedial Action sediment ingestion. For the spotted sandpiper, the PCB HQ was equal to 1.0, and for the belted kingfisher, the PCB HQ was equal to 1.7. Although these risk levels are at or exceed the threshold HQ of 1.0, these exceedances do not require the derivation of aquatic-dependent wildlife-specific RAOs that are separate from the surface water and benthic RAOs defined in the preceding two sections. This is because the surface water and benthic RAOs directly address PCBs in surface water and sediment, which are the primary exposure pathways that contribute to PCB bioaccumulation in the tissue of food items consumed by these two receptors. Reductions in surface water PCB concentrations and reductions in the bioavailability of sediment-based PCBs will result in a reduction of PCB concentrations in food items consumed by the sandpiper and the kingfisher to levels that are protective of these receptors. Specifically, due to the linkage between site surface water and sediment concentrations of PCBs and the concentration of PCBs in site prey items consumed by the spotted sandpiper and the belted kingfisher, reductions in PCBs concentrations in surface water and sediment on the order of 40 percent should be sufficient to reduce the highest HQ from 1.7 to 1.0 or less. As discussed in Appendix A, surface water concentrations have already dropped by a factor of two to three times from 2009 to 2014, and are expected to decrease further in the future. Sediment concentrations decrease by similar or greater amounts depending on location. These actual and modeled reductions are sufficient to reduce levels in prey items that are protective of these avian receptors. 3.4 PCB Surface Water Remedial Action Objective In the Draft FS Report (Anchor QEA 2014), the TSWQS saltwater chronic criterion for PCBs (30 ng/L) was identified as an ARAR and selected as an RAO. Initially the USEPA directed the JDG to consider the TSWQS human health criterion ‘fish only’ for PCBs (0.64 ng/L) as an ARAR. However, upon further evaluation it became apparent that the TSWQS human health criterion for PCBs is not attainable at the Site due to background conditions within the HSC (see Section 2.6.2). Therefore, USEPA directed the RAO to be the higher of the PCB TSWQS human health criterion or background. Thus, the RAO for total PCBs in surface water for the Site is set at 8.2 ng/L, which is the background value established in the HSC (see Section 2.6.2.4.1). Feasibility Study Report Patrick Bayou Superfund Site 37 March 2017 040284-01.08 Basis for Remedial Action 3.5 Mercury and PCDD/PCDF TEQ Risk Summary In the approved RI Report (Anchor QEA 2013b), mercury and PCDD/PCDF TEQ were not identified as COCs based on the results presented in the BERA Report (Anchor QEA 2013c) and BHHRA Report (Anchor QEA 2012). Unacceptable adverse risk due to these chemicals was not indicated in either the ecological or human health risk assessments approved by USEPA. The proportion of methylated mercury, the most toxic and bioaccumulative form, measured in porewater at the Site is markedly low relative to total mercury. These low concentrations of methylmercury are reflected in relatively low rates of bioaccumulation in fish and shellfish in Patrick Bayou, resulting in no adverse risk to fish or wildlife. Mercury did not demonstrate a significant association with benthic toxicity. For recreationally consumed species, trend analysis indicated that Patrick Bayou was not an incremental source to fish in the HSC at the point of exposure (i.e., San Jacinto monument) and was not selected as a COPC for the human health fish consumption pathway. Overall, based on the USEPA-approved risk assessments, there is no indication that risk management actions are required to address mercury in Patrick Bayou to protect human health or the environment. Similarly, PCDD/PCDF TEQ were not identified as risk drivers in the BERA Report (Anchor QEA 2013c) or BHHRA Report (Anchor QEA 2012). Fish and shellfish data were used to characterize risk to fish and wildlife in the BERA Report (Anchor QEA 2013c). These risks did not exceed unacceptable levels. In the BHHRA Report (Anchor QEA 2012), spatial patterns and congener profile distributions of PCDDs and PCDFs in tissue samples from Patrick Bayou and HSC indicated there was no significant incremental contribution to fish and shellfish caught and consumed by anglers at the point of exposure. Therefore, the exposure pathway from Patrick Bayou to the nearest receptors of concern at the point of exposure was not considered significant. As a result, risk management actions to address risk from PCDD/PCDF TEQ to protect human health or the environment, based on the risk assessments, were not required. The lack of site-specific, risk-based need for risk management to address mercury and PCDD/PCDF TEQ suggests that the chemical-specific ARARs based on the TSWQS are very Feasibility Study Report Patrick Bayou Superfund Site 38 March 2017 040284-01.08 Basis for Remedial Action conservative. This conservatism will be considered when identifying the RAOs for these COCs during the design phase. 3.6 Applicable or Relevant and Appropriate Requirements and Other Advisories, Criteria, or Guidance To Be Considered The development and evaluation of remedial alternatives, as presented in Sections 4 and 5 of this document, includes an assessment of the ability of the remedial alternatives to address ARARs of environmental laws and facility siting standards. In addition to ARARs, other advisories, criteria, and guidance were considered in accordance with the NCP, specifically 40 CFR 300.400(g)(3); these factors are identified as To Be Considered (TBC) guidelines. Table 3-2 provides a broad summary of potential ARARs and TBCs that have been identified for this Site. Many of the ARARs and TBCs in Table 3-2 are relevant to only some of the remedial alternatives, but all of the requirements that may be relevant to the Site and any of the remedial alternatives are identified in the list. After a remedy is selected, a detailed review of ARARs specific to the selected remedial action will be conducted and included in the Design Analysis Report for the selected action. The implementation of on-site remedial actions does not require Federal, State or local permits because of the permit equivalency of the CERCLA remedy-selection process (40 CFR 300.400(e)(i)), but remedial actions will be completed in conformance with substantive technical requirements of those regulations that have been determined to be ARARs. The ARARs in Table 3-2 can be divided into three categories, although some ARARs may belong to more than one of these categories: • Chemical-specific requirements • Location-specific requirements • Performance, design, or other action-specific requirements Chemical-specific ARARs are typically the environmental laws or standards that result in establishment of health- or risk-based numerical values. When more than one of these chemical-specific ARARs are applicable to site-specific conditions, a remedial alternative should generally comply with the most stringent or conservative ARAR. Chemical-specific Feasibility Study Report Patrick Bayou Superfund Site 39 March 2017 040284-01.08 Basis for Remedial Action ARARs presented in Table 3-2 include Clean Water Act (CWA) criteria and State water quality and waste standards, where applicable to a waterbody. Location-specific ARARs include restrictions placed on the implementation of certain types of activities based on the location of a site. Some examples of specific locations where restrictions may be considered include floodplains, wetlands, historic places, certain land use zones, and other sensitive habitats. Location-specific ARARs presented in Table 3-2 include the Rivers and Harbors Act, Coastal Zone Management Act, and Federal Emergency Management Agency/National Flood Insurance Program regulations. The action-specific ARARs are generally technology or activity-based limitations or guidelines for management of pollutants, contaminants, or hazardous wastes. These ARARs are triggered by the type of remedial activity selected to achieve the RAO, and these requirements may indicate how the potential alternative must be achieved. Action-specific ARARs presented in Table 3-2 include water quality certifications (CWA Section 401) and discharges of dredged and fill material (CWA Section 404), Clean Air Act, Endangered Species Act (ESA) and other wildlife protection acts. The following sections discuss ARARs that have the most significance to the evaluation of remedial alternatives for the Site. Action-specific ARARs do not apply to all of the remedial alternatives. For example, requirements for waste management and hazardous materials transportation are most significant for remedial alternatives that involve removal of sediment, and would not apply at all to remedial alternatives that involve no removal of material from the Site. The types of actions that trigger compliance with these requirements are also discussed. 3.6.1 3.6.1.1 Water Quality and Water Resources Section 303 and 304 of the Clean Water Act and Texas Surface Water Quality Standards Section 303 of the CWA requires states to promulgate standards for the protection of water quality based on Federal water quality criteria. Federal water quality criteria are established pursuant to Section 304. The TSWQS, where applicable, are relevant to evaluation of shortFeasibility Study Report Patrick Bayou Superfund Site 40 March 2017 040284-01.08 Basis for Remedial Action term and long-term effectiveness of the remedial alternatives. As discussed in Section 3.1, the RAO was established, in part, to address the TSWQS for PCBs. As discussed in Section 1.2, this ARAR will be considered in establishing surface water RAOs for mercury and PCDD/PCDF TEQ after additional data collection and analysis, if necessary. 3.6.1.2 Section 401 Water Quality Certification of the Clean Water Act as Administered by Texas Section 401 requires that the applicant for Federal permits obtain certification from the appropriate State agency that the action to be permitted will comply with State water quality standards. Although environmental permits are not required for on-site CERCLA response actions, the selected remedy would incorporate elements to comply with State water quality standards if appropriate. 3.6.1.3 Section 404 and 404(b)(1) of the Clean Water Act and Texas Parks and Wildlife Commission Marl, Sand, and Gravel Permit The CWA Section 404 requires that discharges of fill to waters of the United States serve the public interest. In selecting a remedial alternative, including discharge of fill, USEPA would be required to make the determination that the placement of materials into Patrick Bayou serves the public interest as necessary to remediate the Site. The Site includes submerged areas within the Patrick Bayou waterway, as well as areas that are occasionally not submerged. A plan will need to be established that addresses the requirements (to the extent practicable) of Section 404 and 404(b)(1). During design of a remedial action, USEPA may request that any potentially responsible parties prepare a 404(b)(1) report for consideration by the USEPA based on identification of a preferred alternative. In addition, the State of Texas regulates taking sedimentary material (marl, sand, gravel, shell, and mudshell) from public waters under chapter 86, subtitle F of the Texas Parks and Wildlife Code. If the selected remedy includes dredging, permits would not be required from the State, as the activity would be performed as part of an on-site CERCLA action. 3.6.1.4 Texas Pollutant Discharge Elimination System Within the State of Texas, the NPDES, which demonstrates compliance with Section 402 of the CWA, is administered by TCEQ and referred to as Texas Pollutant Discharge Elimination Feasibility Study Report Patrick Bayou Superfund Site 41 March 2017 040284-01.08 Basis for Remedial Action System (TPDES). If the selected remedy includes a discharge to surface water, the discharge would need to comply with the substantive TPDES requirements even though on-site CERCLA actions are exempt from permitting. 3.6.1.5 Rivers and Harbor Act, Texas State Code Obstructions to Navigation, and Port Authority of Houston Marine Construction Permit The Site is within a navigable waterway that is regulated by USACE under Section 10 of the Rivers and Harbors Act, the State of Texas under the Natural Resources Code, and the Port Authority of Houston under their Marine Construction Permitting authority. The construction in navigable waters of structures (potentially including sediment caps), facilities, and bridges or removal and placement of trees that would obstruct navigation are among the activities that may trigger compliance with the regulations. 3.6.2 Protected Species Requirements This section addresses requirements of the ESA, the Fish and Wildlife Coordination Act, the Bald and Golden Eagle Protection Act, and the Migratory Bird Treaty Act. The Site is located within an intensely developed industrial area and is not known to provide habitat suitable for any listed aquatic species; however, the Site is approximately 11 miles upstream of Galveston Bay, which provides rearing, spawning, and adult habitat for numerous marine and estuarine fish and invertebrate species, including blue crab, black drum, flounder, oysters, spotted sea trout, and shrimp, which are among the species identified as National Oceanic and Atmospheric Administration Trust resources.14 The Site also provides suitable resting and foraging habitat for migratory birds. The design and overall goal of the remedial action is to improve habitat conditions through the anticipated reduction of contaminants potentially released to the environment. Certain actions may require timing considerations to avoid potential harm of protected species. Coastal and Estuarine Hazardous Waste Site Reports, Table 1, accessed October 2013. Available from: http://archive.orr.noaa.gov/book_shelf/391_wsr4_patrickbayou.pdf. 14 Feasibility Study Report Patrick Bayou Superfund Site 42 March 2017 040284-01.08 Basis for Remedial Action 3.6.3 Coastal Zone Management and Texas Coastal Management Plan Federal agency activities that have reasonably foreseeable effects on any land or water use or natural resource of the coastal zone (also referred to as coastal uses or resources and coastal effects) must be consistent to the maximum extent practicable with the enforceable policies of a coastal state's federally approved coastal management program (NOAA 2012). The GLO administers the Texas Coastal Management Consistency certification. Under Texas law, a coastal natural resource area is a coastal barrier, coastal historic area, coastal preserve, coastal shore area, coastal wetland, critical dune area, critical erosion area, Gulf beach, hard substrate reef, oyster reef, submerged land, special hazard area, submerged aquatic vegetation, tidal sand or mud flat, water in the open Gulf of Mexico, or water under tidal influence, as these terms are defined in 33.203 of the Texas Natural Resources Code. The remedial alternatives are reviewed for consistency with ARARs, including coastal uses, in Section 5. Consultation with GLO would be performed, if necessary, as part of remedial design. 3.6.4 Floodplain Construction, including remedial response, within a floodplain must not restrict flow such that it would create or exacerbate potential flooding. A hydrologic evaluation would be performed during remedial design to assess existing flow conditions at the Site. Modeling would be used, in part, to evaluate potential impacts of the remedial alternatives on the water levels in Patrick Bayou and steps taken to mitigate such problems. 3.6.5 Cultural Resources Management The National Historic Preservation Act and the Antiquities Code of Texas (ACT) have applicability to remedial action at the Site. This section provides a summary of existing information on recorded historic properties and a summary of potentially applicable requirements. Section 106 of the National Historic Preservation Act and its implementing regulations at 36 CFR 800 require that Federal agencies take into account the effects of their undertakings on historic properties. The Section 106 process requires agencies to: Feasibility Study Report Patrick Bayou Superfund Site 43 March 2017 040284-01.08 Basis for Remedial Action • Determine the Area of Potential Effects (APE), defined as “the geographic area or areas within which an undertaking may directly or indirectly cause alterations in the character or use of historic properties, if any such properties exist” (36 CFR 800.16(d)). • Inventory potential historic properties (prehistoric or historic districts, sites, buildings, structures or objects; including Traditional Cultural Properties) within the APE. • Evaluate the potential historic properties to determine if any are eligible for listing in the National Register of Historic Places (NRHP). • Assess whether the project will have effects on any NRHP-eligible properties in the APE, and whether the effects will be adverse. • Resolve any adverse effects to NRHP-eligible historic properties in a Memorandum of Agreement (MOA) describing mitigation measures. • Consult with interested and affected Indian Tribes, the State Historic Preservation Officer, the public, and other interested parties. The requirements of the ACT (Title 9, Chapter 191 of the Texas Natural Resource Code) and the associated Rules of Practice and Procedure for the ACT (Texas Administrative Code Title 13, Part II, Chapter 26) apply to the project if construction is performed on lands below MHW, which are owned by the State of Texas. The ACT requires that project information be provided to the Texas Historical Commission for review. There are no recorded historic properties in the immediate project area, according to the Texas Archaeological Sites Atlas (checked December 4, 2013). The nearest archaeological sites are at least 1 mile from Patrick Bayou. A number of historical markers, primarily related to the Battle of San Jacinto, are located more than 1 mile east of the project area. Three archaeological surveys have been conducted intersecting the project area. Little information is available on the surveys, but records indicate that no archaeological sites were located in the project vicinity during these surveys. The project area possibly contained archaeological materials at some time in the past. The presence of precontact middens and historic early 20th century sites in the vicinity (in addition to the proximity of the historically significant location of the Battle of San Jacinto) Feasibility Study Report Patrick Bayou Superfund Site 44 March 2017 040284-01.08 Basis for Remedial Action indicates that the area was used in the precontact and historic eras. The Site is unlikely to contain archaeological materials, however, as much of the length of Patrick Bayou has been altered by historic and modern industrial activities. A comparison of 1953 and 2012 aerial photographs illustrates the straightening of Patrick Bayou (Figure 3-2). Despite the extensive industrial activity, some upland areas may contain archaeological resources (possibly under modern fill). These areas, especially those at relatively higher elevations, appear to have changed relatively little. For example, the peninsula created where Patrick Bayou joins the HSC may have been a particularly attractive location for use and settlement in the recent and distant past. Remedial action plans would consider potential effects that staging, access, and other activities may have on potentially historically sensitive areas. If necessary, some areas may be designated off limits for construction activities. To fulfill the requirements of Section 106, the following steps will be implemented during remedial design: • The APE will be determined based on engineering designs for the selected alternative. • Project plans will be analyzed by a qualified archaeologist to determine whether any areas with archaeological potential will be impacted within the APE. • If areas with archaeological potential will be impacted, an archaeological survey will be conducted to identify and evaluate any archaeological historic properties and a report will be prepared documenting the findings of the analysis. Determinations of NRHP-eligibility of any potential historic properties and of potential project effects should be made by USEPA, in consultation with Texas Historical Commission. Determinations and supporting documentation should be provided to consulting parties. • If any adverse effects to NRHP-eligible historic properties are identified, USEPA should work with consulting parties to develop mitigation measures and prepare a MOA. Feasibility Study Report Patrick Bayou Superfund Site 45 March 2017 040284-01.08 Basis for Remedial Action 3.6.6 Noise Control Act Noise abatement may be required if actions are identified as a public nuisance. As the Site is bounded by large industrial facilities and the HSC, noise from construction activity is unlikely to constitute a public nuisance. 3.6.7 Hazardous Materials Transportation and Waste Management Under nearly any remedial action scenario, aside from the No Action alternative, off-site disposal may be required for limited quantities of waste such as used personal protective equipment. Some remedial alternatives may require disposal of more significant quantities of material such as debris. Typically, remedial contractors would be required to package any hazardous materials in appropriate containers and label containers in accordance with Texas Department of Transportation and other applicable requirements. An existing permitted facility (e.g., landfill) would be chosen for any off-site disposal and submitted for approval to USEPA. Feasibility Study Report Patrick Bayou Superfund Site 46 March 2017 040284-01.08 4 DEVELOPMENT OF REMEDIAL ALTERNATIVES This section includes the following discussions: • Preliminary delineation of various sediment management areas (SMAs) at the Site where specific remedial technologies are evaluated. • Remedial technology considerations specific to this Site, as they apply to the assembly of FS alternatives. • Assembly of remedial alternatives, which are carried forward into detailed and comparative evaluations against CERCLA criteria in subsequent sections of the FS. 4.1 Delineation of Sediment Management Areas Preliminary SMAs were delineated that, if addressed, would result in the Site achieving the PCB surface water and benthic RAOs. It was further determined that addressing these SMAs will also address the aquatic-dependent wildlife RAO (see discussion in Section 3.3). This section describes the delineation of SMAs. Note that delineation of sediment SMAs 2 through 9 was completed using 2009 data. Refinement of all SMAs is anticipated using new data in the pre-design phase of this project. The delineation of SMAs herein did not consider a potential new surface water RAO for mercury or PCDD/PCDF TEQ. Additional data will be collected during the design phase to refine the SMA delineation and to assess, using a modeling framework, the effectiveness of the specific technologies identified in the preferred alternative to address mercury and PCDD/PCDF TEQ surface water quality in Patrick Bayou. Based on these results, additional RAOs and the need for further remedial action to address mercury and PCDD/PCDF TEQ in surface water will be determined. 4.1.1 Sediment Management Area Delineation Approach for PCB Surface Water Remedial Action Objective A single SMA (SMA-1) was identified where actions would need to be evaluated for the remedy to achieve the PCB surface water RAO based on background conditions in the HSC. In the Draft FS Report (Anchor QEA 2014) the limits of SMA-1 were delineated using the chemical fate and transport model to estimate the reduction in PCB loading to surface water Feasibility Study Report Patrick Bayou Superfund Site 47 March 2017 040284-01.08 Development of Remedial Alternatives necessary to achieve the TSWQS chronic saltwater aquatic life criteria total PCB value of 30 ng/L throughout a majority of the Site within a few years following completion of construction. The PCB surface water RAO was subsequently lowered to the background concentration in the HSC, 8.2 ng/L, as directed by USEPA (see Section 1.2). A review of the fate and transport modeling results indicated that remedial actions conducted within the limits of the original SMA-1 footprint presented in the Draft FS Report (Anchor QEA 2014) are expected to be sufficient to achieve this lower surface water RAO within several years following construction; therefore, no modification was made to delineation of SMA-1. This evaluation considered surface water quality data collected during three separate events over time (see Section 2.6) and fate and transport modeling as described in Appendix A. Based on the analysis described in Appendix A, it was determined that remediation of sediments between Stations PB-075 and PB-082 would achieve the necessary load reduction in PCBs to the water column. As described in Section 2.6 of this report, additional water column data were collected in 2014 to develop a better understanding of the nature and extent of PCBs in surface water within the concrete-lined channel. Figure 2-23 shows a spatial profile of the 2014 water column data within the concrete-lined channel and throughout Patrick Bayou. This figure shows a relatively small increase in PCB concentration between approximately Stations PB-100 and PB-082 (increasing from approximately 5 to 10 ng/L over this reach), followed by a relatively large increase in PCBs between Stations PB-082 and PB-075 from approximately 10 to 70 ng/L. Based on these data and surface sediment data from this area, SMA-1 was defined as the 700 linear feet of the concrete-lined channel between stations PB-075 and PB-082. Verification and refinement of the extent of SMA-1 is anticipated in the pre-design phase of this project. 4.1.2 Delineation Approach for Benthic Risk Sediment Management Areas To delineate benthic risk SMAs, the benthic RAO was applied to the baseline conditions using the 2009 RI Report (Anchor QEA 2013b) surface sediment dataset. Future conditions under each alternative were projected using the surface sediment half-life of PCBs estimated from simulations with the calibrated chemical fate and transport model (Appendix A). Feasibility Study Report Patrick Bayou Superfund Site 48 March 2017 040284-01.08 Development of Remedial Alternatives Using the 2009 RI Report (Anchor QEA 2013b) surface sediment data, areas that currently meet the benthic RAO were identified. Areas currently exceeding the benthic RAO were further evaluated based on estimated sediment half-lives for PCBs predicted by the model (Appendix A) to evaluate if natural recovery would reduce surface sediment concentrations below the benthic RAO within a reasonable time frame. Areas that were not predicted to recover naturally to meet the benthic RAO within a reasonable time frame were delineated as benthic risk SMAs. Each element of this analysis is described in more detail in the subsections that follow. Table 4-1 summarizes the results of this analysis for two scenarios. Scenario 1 assumes that no remediation has occurred in SMA-1 (as in Alternatives 1 and 2, described subsequently). Scenario 2 assumes that SMA-1 has been remediated (as in Alternatives 3 and 4, described subsequently) and thus natural recovery rates are faster because of this remediation. 4.1.2.1 Evaluating Baseline Conditions In the BERA Report (Anchor QEA 2013c), risk characterization was performed using data collected primarily in 2002 and 2003. However, due to the age of the dataset and the known dynamic nature of the sediment bed and chemistry within the Site, the sediment chemistry data collected in 2002/2003 as part of the sediment toxicity TMDL program are not considered representative of current conditions for the purposed alternatives development in this FS. Data collected in 2009 are more relevant for establishing the preliminary baseline condition to evaluate alternatives relative to benthic risk because the 2009 RI Report (Anchor QEA 2013b) surface sediment dataset is more recent, more comprehensive in terms of spatial coverage, and reflects more current methodology (e.g., high resolution PCB congener analysis) than the BERA Report (Anchor QEA 2013c) benthic risk assessment dataset. Therefore, the surface sediment RI Report (Anchor QEA 2013b) dataset was used to establish the preliminary baseline condition for analysis of the alternatives. To delineate benthic risk SMAs, Thiessen polygons were defined for each of the 60 surface sediment samples used to map baseline conditions for the FS, and the mean PEL-Q was assigned to each polygon based on the sediment chemistry within that polygon. Using this approach, the mean PEL-Qs for the baseline condition were mapped as shown on Figure 3-1. It should be noted that, based Feasibility Study Report Patrick Bayou Superfund Site 49 March 2017 040284-01.08 Development of Remedial Alternatives on the 2002/2003 dataset, areas 4A and 6A (see Figure 8-1 in the BERA Report, Anchor QEA 2013c) had the highest mean PEL-Q values, but the 2009 data indicate that the mean PEL-Q values in these areas have decreased. These decreases are consistent with the characterization of higher net deposition rates in these areas in the STM Report (Anchor QEA 2011c) and thus these decreases should be expected. Conversely, Area 3 in the 2002/2003 dataset was indeterminate from a sediment toxicity perspective, but this area is characterized by relatively low net sedimentation in the STM and thus conditions would not be expected to improve as rapidly as they have in areas 4A and 6A. 4.1.2.2 Evaluating Future Conditions To evaluate natural recovery and future conditions under different alternatives, estimated sediment half-lives for PCBs in surface sediment were developed using the chemical fate and transport modeling (Appendix A). Using the model-predicted half-lives, the number of years that would be needed for benthic risk areas to achieve the benthic RAO as a result of natural recovery processes was evaluated. Development of the PCB half-lives and their application to the baseline condition are described below. 4.1.2.2.1 Surface Sediment Half-life Estimates Mechanisms controlling natural recovery of contaminated sediment (e.g., processes such as deposition and degradation) often follow a first order decline (Chapra 1997; Magar et. al. 2009). Thus, the rate of natural recovery for PCBs was estimated by fitting an exponential rate of decline through surface (0 to 10 cm) sediment PCB concentrations predicted by the chemical fate model for a 24-year simulation period (see Appendix A). Spatially, half-life values were calculated based on spatially averaged, model-predicted concentrations over 1,000-foot-long segments (i.e., every ten sampling stations) across the Site. These predicted half-lives were developed based on model simulation of PCBs using data from 2009 and the upper 10 cm of sediments. Inspection of model results indicates that the surface sediment rates of decline predicted by the model are driven by net sedimentation (consistent with the STM described in Anchor QEA 2011c). Thus, it is expected that that the mean PEL-Q would generally recover at the same rate as PCBs, because of this and the following additional factors: Feasibility Study Report Patrick Bayou Superfund Site 50 March 2017 040284-01.08 Development of Remedial Alternatives • The mean PEL-Q is predominately driven by PCBs for nearly every sample in the surface sediment RI Report (Anchor QEA 2013b) dataset, as well as the benthic risk assessment WOE dataset. For locations with a baseline mean PEL-Q above the benthic RAO (Figure 3-1), PCBs account for a significant proportion of the overall mean PEL-Q. • No ongoing sources of PAHs, BEHP, or lead were identified in the RI Report (Anchor QEA 2013b) that would contribute to the incoming sediment load to the Site beyond background inputs of these COPCs from upstream urban runoff. While using simulated surface sediment PCBs as a representative of mean PEL-Q may introduce some uncertainty in the evaluation of future conditions, this uncertainty is considered relatively minor in the overall assessment and interpretation of future conditions. Note that future baseline evaluations will consider discrete depth zones to better assess MNR. Evaluating discrete depth zones will allow refinement of the bioactive zone and better assessment of MNR in critical horizons. 4.1.2.2.2 Application of Half-lives to Baseline Conditions To evaluate the rates of natural recovery in sediments with respect to the mean PEL-Q and associated risk to benthos, the number of years for each Thiessen polygon to decrease below the benthic RAO threshold of 4.47 was estimated using the following equation: 𝑁𝑁 𝑡𝑡1� ×𝑙𝑙𝑙𝑙 � 𝑁𝑁0 � 2 𝑡𝑡 𝑡𝑡 = 𝑙𝑙𝑙𝑙(2) where: = target mean PEL-Q of 4.47 𝑁𝑁𝑡𝑡 𝑡𝑡 𝑁𝑁0 = years to achieve 𝑁𝑁𝑡𝑡 = year zero (baseline) mean PEL-Q for location (Figure 2-32) 𝑡𝑡1� 2 = half-life estimated from model-predicted surface sediment (0 to 10 cm) PCB concentrations for the 1,000-foot segment containing the location (see Appendix A) Feasibility Study Report Patrick Bayou Superfund Site 51 March 2017 040284-01.08 Development of Remedial Alternatives 4.1.2.3 Delineation of Benthic Risk Sediment Management Areas Using the approach presented in the preceding section (i.e., estimating mean PEL-Q reductions over time using baseline surface [0 to 10 cm] values from 2009 RI Report (Anchor QEA 2013b) data and half-life estimates from the PCB fate model, which are representative of mean PEL-Q changes over time as discussed in Section 4.1.2.2.1), the number of years necessary for natural recovery to achieve the benthic RAO was estimated for each mean PEL-Q polygon. Benthic risk SMAs were then delineated for areas where natural recovery estimates do not reduce the mean PEL-Q below the benthic RAO within 10 years.15 The natural recovery rates used for Alternatives 1 and 2 (described subsequently) do not presume any action has been taken. The natural recovery rates used for Alternatives 3 and 4 assume SMA-1 has been remediated, thus accelerating natural recovery processes. Based on the evaluations described above, Thiessen polygons associated with surface sample locations PB-026, PB-032, PB-034, PB-036, PB-037, PB-041A, PB-047.1, and PB-069069 were identified as benthic risk SMAs for Alternatives 3 and 4 (Table 4-1). 4.1.3 Delineation of Natural Recovery Areas Areas of the Site that currently exceed the benthic RAO (Figure 3-1), but that are projected to be at or below this RAO within 10 years due to natural recovery, will be monitored to assess changes in the mean PEL-Q over time. Thus, the term “Natural Recovery Areas” is defined as representing those areas where baseline data may exceed the benthic RAO, but are not otherwise delineated as surface water RAO SMAs or longer-term potential benthic risk SMAs. 4.1.4 Summary of Sediment Management Area Delineation Table 4-2 summarizes the SMA identification, location, and primary driver for the delineation. Figure 4-1 shows the approximate limits of SMA-1 through SMA-9 and the Natural Recovery Areas. The actual number and limits of these SMAs and Natural Recovery Areas would be refined by pre-design baseline data collection and additional model calibration, which will be used in an adaptive management process to determine whether, Ten years was selected as a reasonable time frame consistent with other Superfund Record of Decisions where natural recovery was a component of the selected remedy (e.g., Nyanza Chemical Waste Dump). 15 Feasibility Study Report Patrick Bayou Superfund Site 52 March 2017 040284-01.08 Development of Remedial Alternatives and to what extent, remediation of SMAs will be necessary to achieve RAOs. For the purpose of this FS, acreages shown in Table 4-2 were developed as follows: • For SMA-1, the area was identified using the chemical fate and transport model by iterating on the size of this area during model calibration until a good match occurred with measured surface water results. • For SMA-2 through SMA-9 and the Natural Recovery Areas, the acreage is based on Thiessen polygons generated using the 2009 surface sediment data. While these acreages provide a starting point for estimating areas, the remedial alternatives development also includes technology-specific considerations, which in some cases increase the footprint over which action would be taken. For example, if capping were to be implemented, the surface area of the cap might be greater than the SMA that it would be covering to accommodate edge details such as bank anchoring. Remedial technology-specific considerations are discussed in additional detail subsequently in this section of the FS. 4.2 Remedial Technologies Screening The RATS (Anchor QEA 2013a) identifies General Response Actions (GRAs) and provides initial screening of remedial technologies. The RATS included consideration of institutional controls, natural recovery, in situ treatment, containment, removal, ex situ treatment, disposal, and beneficial reuse of sediments. Most of these GRAs were retained for further consideration in the FS. However, specific issues related to certain GRAs were identified, and specific screening decisions were made in the RATS that eliminated certain technologies from further consideration for the Site. Based on the screening presented in RATS, the following remedial technologies were not considered applicable to the Site: • Treatment by thermal desorption • Treatment by sediment washing • Disposal in an unconfined open water site • Beneficial reuse of sediments Feasibility Study Report Patrick Bayou Superfund Site 53 March 2017 040284-01.08 Development of Remedial Alternatives In addition, as explained in Section 4.2.5, removal was retained only in limited application to be used if necessary to maintain flood capacity of the channel for an in situ containment remedy. The following supplemental information regarding GRAs is provided in the specific context of the final set of remedial alternatives for the Site in this FS. 4.2.1 Institutional Controls Institutional controls are administrative measures that are implemented to mitigate risks or to protect the integrity of engineered controls. Institutional controls include “Proprietary Controls,” which are restrictions placed on the use of private property, “Governmental Controls,” which include restrictions on the use of public resources, “Enforcement Tools” that may be imposed by an agency to compel certain actions, and “Informational Devices,” which include notices about the presence of contamination or fishing advisories (USEPA 2012). Institutional controls are discussed in detail in the RATS and are evaluated for this FS in Appendix F, and are considered highly implementable and effective for controlling access to the Site and potential on-site exposure. Institutional controls currently in place, not all necessarily associated with the Site, include restricting access to the industrial facilities bordering Patrick Bayou, maintenance agreements, property use restrictions, Homeland Security requirements, monitoring and notification of waterway uses in the HSC, seafood consumption advisories in the HSC and Galveston Bay, and associated public outreach and education (Anchor QEA 2013a). Institutional controls implemented by the members of the JDG at the Site are expected to remain in place for the foreseeable future and as such are integral to any remedial alternative selected for the Site. Additional institutional controls, such as enhanced Texas811 notifications and annual notifications to any entities with easements or property ownership adjacent to the Site, will be considered as part of this GRA. 4.2.2 Monitored Natural Recovery As outlined in USEPA’s Sediment Remediation Guidance (2005), MNR is a remedy for contaminated sediment that typically uses ongoing, naturally occurring processes to contain, destroy, degrade, or reduce the bioavailability or toxicity of chemicals in sediment and Feasibility Study Report Patrick Bayou Superfund Site 54 March 2017 040284-01.08 Development of Remedial Alternatives associated surface water. MNR may rely on a wide range of naturally occurring processes to reduce risk to human and ecological receptors. These processes may include the following: 1) physical; 2) biological; and 3) chemical mechanisms that act together to reduce the risk posed by the chemicals. Depending on the chemicals and the environment, this risk reduction may occur in a number of different ways, including destruction (degradation or transformation) of COCs to less toxic chemicals, reduced mobility of COCs, burial, or dispersion. MNR would entail design and implementation of a sampling and analytical program to monitor the progress of natural recovery. Sampling would be conducted at a representative range of locations and at appropriate time intervals to allow trends in concentrations in surface water and sediments to be assessed. Example sampling and analysis programs could include sampling of surface water, porewater, and sediment. Each component of the MNR remedy is described in more detail in the following sections. Details of the monitoring plans for each component, including data quality objectives and decision rules, would be developed during the remedial design phase. 4.2.2.1 Monitored Natural Recovery Surface Water Monitoring To evaluate the effectiveness of MNR to achieve the PCB surface water RAO of 8.2 ng/L, periodic monitoring of PCBs in surface water would be required. To develop costs for the MNR alternative, it has been assumed that monitoring of surface water PCB concentrations would be required at up to five locations. Locations identified for the MNR evaluation would be determined in consultation with USEPA, and for purposes of this FS assume up to three locations within the Site, one location upstream of the Site, and one location in the HSC. Sampling performed in 2014 as part of the supplemental surface water sampling program in support of the modeling effort (Appendix D) would be used to establish baseline conditions for this media. Monitoring would occur at a frequency and for a duration determined in consultation with USEPA; for purposes of this FS, up to ten monitoring events have been assumed over a 30-year period. Long-term monitoring may require more or less time than Feasibility Study Report Patrick Bayou Superfund Site 55 March 2017 040284-01.08 Development of Remedial Alternatives expected; adaptive Site management would be used to adjust the time frame and the design of the monitoring program as appropriate. 4.2.2.2 Porewater Monitoring The concentration of contaminants in porewater, particularly non-polar organics (e.g., PCBs, PAHs) and divalent metals, has been demonstrated to be a significant predictor of sediment toxicity (USEPA 2005, 2008). Reducing porewater concentrations through treatment will reduce the ability of compounds, such as PCBs, to bioaccumulate into food items for wildlife receptors. Thus, porewater monitoring would be an important component of monitoring remedy effectiveness for treatment technologies that are intended to limit exposure through reductions in porewater concentrations of target COCs. If treatment technologies are part of an alternative, porewater monitoring may be necessary to evaluate the effectiveness of the treatment. For example, to evaluate the reduction in benthic risk due to treatment, porewater sampling would include PCBs, PAHs, lead, and BEHP. Monitoring would occur at a frequency and duration determined in consultation with USEPA; for purposes of this FS, up to ten monitoring events have been assumed over a 30-year period. Long-term monitoring may require more or less time than expected; adaptive site management would be used to adjust the time frame and design of the monitoring program as appropriate. 4.2.2.2 Surface Sediment Monitoring To evaluate the effectiveness of natural recovery to achieve the benthic RAO, monitoring the concentration of primary and secondary ICs in surface sediment would be performed. For FS purposes, it has been assumed that monitoring of PCBs, PAHs, lead, and BEHP would be performed on a composite basis over selected subareas within the Natural Recovery Areas. Within the Natural Recovery Areas, surface sediment samples would be collected at previously sampled surface sediment locations and composited over an appropriate subarea (e.g., a station range based on similar rates of expected recovery). Sampling would be performed prior to remedy implementation and periodically thereafter at time intervals determined in consultation with USEPA. The FS assumes up to ten monitoring events would be implemented across seven Natural Recovery subareas over a 30-year period. Feasibility Study Report Patrick Bayou Superfund Site 56 March 2017 040284-01.08 Development of Remedial Alternatives Long-term monitoring may require more or less time than expected; adaptive site management would be used to adjust the time frame and sampling design for surface sediment monitoring as appropriate. 4.2.3 Containment In situ containment refers to the placement of an engineered subaqueous cap on top of chemically impacted sediment that will remain in place. A cap would be designed to effectively contain and isolate such sediments from the biologically active surface zone. As described in Contaminated Sediment Remediation Guidance for Hazardous Waste Sites (USEPA 2005), in situ caps can quickly reduce exposure to chemicals and typically require less infrastructure than ex situ technologies (e.g., dredging, dewatering, treatment, and disposal). Since capping leaves contaminated sediments in place, long-term monitoring is typically a component of in situ containment to verify that the cap is stable (i.e., not damaged) and continues to effectively isolate chemicals, or sufficiently attenuate chemical mobility through the cap (USEPA 2005). In situ caps isolate chemically impacted sediments from the environment by use of natural (e.g., sand) or constructed (e.g., geosynthetic layers or concrete) products. Depending on the proposed remedial design for a site, a cap can consist of a single sediment layer to isolate chemicals or can be designed as a multi-layered system consisting of a combination of sediment, geosynthetic, and armor layers. Aggregate caps and Articulated Concrete Block Mat (ACBM) caps are two methods of containment that were described in the RATS. Placement of aggregate or ACBM caps in the channel may be combined with treatment and/or removal GRAs, which are discussed subsequently in this FS. To the extent that containment is a component of the remedy, the containment would be designed, monitored, and maintained in accordance with USACE and USEPA capping guidance (USEPA 1998). In situ capping, as discussed in USEPA guidance (USEPA 2005) is a demonstrated technology that has been selected by USEPA for sediment remediation sites across the United States (USEPA 1998; ITRC 2014). Feasibility Study Report Patrick Bayou Superfund Site 57 March 2017 040284-01.08 Development of Remedial Alternatives Compared to removal-focused approaches, in situ capping has a disadvantage, in that caps require monitoring and maintenance to confirm their protectiveness. In addition, caps disrupt the benthic community. Aggregate caps cover the near surface benthos, potentially smothering it. ACBM caps create a concrete surface layer that is inhospitable to the benthic community for a period of time until future sediment deposition on top of the ACBM improves the surface substrate. 4.2.3.1 Aggregate Caps Aggregate caps typically consist of a base layer for chemical isolation (typically sand-sized materials containing an adsorptive amendment as needed), and, as necessary, a filter and/or armor stone surface treatment. The surface armor layer of larger-sized rock prevents the loss of the chemical isolation layer during high flow events. A multi-layered cap consisting of chemical isolation, filter, and armor layers can be on the order of 2 or more feet thick, which can reduce the capacity of the channel to handle flood events. To maintain flood capacity when using an aggregate cap, excavation of the channel bed could be necessary prior to cap construction. As USEPA has described (USEPA 2005), excavation of sediments can result in the generation of dredging residuals and contaminant losses, as further discussed in Section 4.2.5 of this FS. Required armor gradation is a function of the shear stresses that need to be resisted, which vary throughout the channel. Appendix B provides a preliminary evaluation of the size of armor that would be needed for the various SMAs, based on the channel configuration in that area and the worst-case shear stress that might occur during a design-level flood event. Table 4-3 provides a summary of the armor stone size, presented as d50 (the size beyond which at least 50 percent of the cap aggregates are larger) for each SMA, sized to resist a 100-year flow event. The minimum required armor thickness is often taken to be twice the d50 dimension. Based on the relatively thick armor layer requirements, aggregate caps were not carried forward in the FS as the assumed containment technology. However, more refined Site modeling may be performed during remedial design that might conclude that aggregate caps could be an appropriate technology in certain areas, and thus this technology has been retained for remedial design. Feasibility Study Report Patrick Bayou Superfund Site 58 March 2017 040284-01.08 Development of Remedial Alternatives 4.2.3.2 Articulated Concrete Block Mat Caps ACBM systems are used to provide erosion protection to underlying soil from the hydraulic forces of moving water. An ACBM system is comprised of a matrix of individual concrete blocks placed together to form an erosion-resistant revetment with specific hydraulic performance characteristics. The term “articulated” implies the ability of the matrix to conform to minor changes in the subgrade while remaining interconnected with geometric interlock and/or additional system components such as cables. Because of the low profile of the ACBM cap, excavation prior to ACBM placement is not assumed necessary for maintaining channel flood capacity. This advantage, as well as the fact that ACBM can often be placed in areas with limited equipment access, means that ACBM is an ideal choice for channels with limited flood capacity and/or access constraints, both of which are issues for Patrick Bayou. Prior to ACBM installation, the cap footprint would be swept to remove large debris, and the banks of the channel would be prepared for anchoring the ACBM fabric. Preparation of the banks to allow construction access and anchoring would require a corridor approximately 20 to 30 feet wide that would be heavily disturbed during construction. For ACBM installation, the channel would first be lined with geotextile; where a treatment layer is a component of the cap, a Reactive Core Mat (RCM) layer could also be added. A RCM would be designed specifically for the Site, in consultation with suppliers and considering site-specific COC concentrations and other factors. A typical RCM consists of two layers of geofabric with a reactive media sandwiched between the layers. Following placement of the geotextile liner (and RCM if used), ACBM fabric panels would be placed and secured in the channel, filled with concrete, and allowed to cure. The FS assumes that the ACBM will be placed bank to bank in the channel. Because of this, the SMA ACBM areas used in the cost estimates (Appendix C) are larger than the actual SMA delineation areas described in Table 4-2. 4.2.4 Treatment Treatment technologies can be an effective remedial action given the proper chemical properties of the Site-specific COCs and the physical constraints of the Site. The results of Feasibility Study Report Patrick Bayou Superfund Site 59 March 2017 040284-01.08 Development of Remedial Alternatives the treatment technology review presented in the RATS (Anchor QEA 2013a, Appendix A), and the screening of in situ treatment technologies is summarized in this section. In general, in situ sediment treatment technologies include immobilization of the COCs with the addition of sequestering agents (such as activated carbon [AC]), biological or chemical degradation, other forms of immobilization, and other potentially appropriate treatment technologies to reduce the toxicity, mobility, or volume (TMV) of sediment chemicals while leaving sediments in place. As discussed in the RATS (Anchor QEA 2013a), adsorbent amendments may be added to the sediment in situ to effectively reduce the mobility and bioavailability of the Site-specific COCs. Adsorbent materials may also be added to cap fill, as discussed in Section 4.3.3. The primary exposure medium of concern is the shallow sediment, within 10 cm of the sediment-water interface. The consideration of in situ treatment technologies is focused on the top 10 cm of sediment within the Site as this area includes the biologically active zone (see Section 2.5.2). However, as indicated above, the biologically active zone extents will be evaluated in more detail during remedial design. Treatment as a response action could be accomplished with the addition of AC to sequester COCs, reducing surface water concentrations of PCBs and reducing bioavailability of COCs in porewater to address benthic risk and aquatic-dependent wildlife risk. For sediment cleanup projects, treatment with AC could be as direct application to the sediment surface, mixed into the sediments, mixed into a sand cover layer, or incorporated as a component of an isolation cap. Treatment can disturb the benthic community and cause short-term impacts, particularly where amendments are physically mixed or blended into the surface. In these cases, research indicates that within about a year following treatment, the benthic community would be expected to recover such that treated areas would be similar to untreated areas (Alcoa 2010). Treatment can be applied in a very targeted fashion, as needed, which will minimize impacts to benthos to the maximum extent practicable. The appropriate application method would need to be considered during the design phase to manage site-specific sediment properties, including consideration of whether low-density and/or near-neutral buoyancy sediments are present in the proposed treatment footprint. For purposes of this FS, two different treatment options were assumed, depending on which area of the Site is being addressed. Option 1 assumes the use of a RCM, which is two Feasibility Study Report Patrick Bayou Superfund Site 60 March 2017 040284-01.08 Development of Remedial Alternatives geotextile layers with a reactive medium between the geotextile layers. The RCM mat considered for this FS assumes dosage with granular AC at a mass per unit area of 0.4 pounds per square foot, although different dosages could be used if determined appropriate during remedial design. The RCM would be an underlayment to an ACBM isolation cap to provide enhanced protectiveness for the remedy by reducing the mobility and bioavailability of the COCs. For purposes of the FS, Option 2 assumes mixing, or “tilling” bulk AC into the upper 4 to 6 inches of surface sediments to address potential porewater issues associated with benthic risk and bioaccumulation of PCBs into food items consumed by aquatic-dependent wildlife. During remedial design, application methods, such as surface spreading without mixing, will also be considered where appropriate (such as low energy areas of the Site). In this option, a dosage of 5 percent by dry weight AC would be mixed into surface sediments using a tiller or auger system. Based on existing sediment data, the dry unit weight of sediments is on the order of 0.5 tons per cubic yard. Thus, for purposes of FS alternatives evaluation, the Option 2 treatment would entail dosing sediments 20 tons per acre, or 0.9 pounds per square foot AC. The actual dosage used would be determined during remedial design evaluations. To evaluate treatment Option 1, chemical isolation modeling was performed as described in Appendix B to evaluate the long-term performance of a RCM in sequestering PCBs from the sediments. For the RCM product considered, near-surface porewater concentrations were predicted by the model to be reduced by over 99 percent for at least 100 years (Appendix B). This means that the RCM will result in immediate reductions in surface porewater concentrations and will also achieve significant long-term reductions. The actual dosage and reagent for a RCM would be determined during remedial design based on more detailed, SMA-specific modeling. Treatment Option 2 includes mixing AC into surface sediments to reduce potential concentrations of mean PEL-Q chemicals in porewater to address benthic risk and bioaccumulation of PCBs. Treatment of sediments has been studied extensively, and is a well-documented approach to addressing hydrophobic organic COCs, which are the primary benthic risk drivers for this Site. A large body of literature documenting actual performance of treatment projects shows that AC can reduce bioavailability of hydrophobic organic COCs by more than 60 to 90 percent (Janssen and Beckingham 2013). Sediment treatment using a Feasibility Study Report Patrick Bayou Superfund Site 61 March 2017 040284-01.08 Development of Remedial Alternatives blended cover, direct application and/or mixing of AC into sediments has been demonstrated on more than 25 projects over the last decade, including CERCLA projects (Patmont et al. 2014; Janssen and Beckingham 2013; Cornelissen et al. 2012; Cho et al. 2007, 2009; Beckingham and Gosh 2011; Menzie 2012; Norwegian Research Council 2011). Detailed guidance has been prepared for the assessment, design, and monitoring of sediment treatment remedies, including considerations regarding the long-term monitoring of treatment effectiveness in reducing bioavailability (ITRC 2014). If treatment is selected as a remedial technology for the Site, a bench-scale treatability study may be performed to evaluate the appropriate reagent type and dosage to optimize treatment effectiveness. 4.2.5 Removal Removal, if selected as a component of the preferred alternative, would only be used to the extent necessary to offset any loss of channel flood capacity from capping (i.e., if a thick aggregate cap were selected as the remedy). As discussed in the approved RATS (Anchor QEA 2013a), virtually all dredging projects result in some degree of resuspension, release, and residuals despite use of Best Management Practices (BMPs; USEPA 2005; NRC 2007; USACE 2008a; Bridges et al. 2010). Empirical data from numerous sediment remediation projects indicate that residual contamination is a common occurrence that frequently limits the overall protectiveness of removal (Patmont and Palermo 2007; NRC 2007). USEPA guidance on sediment remediation states “there should not be necessarily a presumption that removal of contaminated sediments from a water body will be necessarily more effective or permanent than capping or MNR” (USEPA 2005). Further, as described in the RATS and in Section 2 of this FS, the subsurface profile of Site-specific COC concentrations increase with sediment depth to approximately 4 feet beneath the mudline. Below the soft sediment is a relatively stiff contact with the Beaumont clay formation in the downstream portion of the channel; a hard substrate contact underlies the concrete-lined portion of the channel. Thus, a removal-based remedial alternative would require moving a large volume of relatively clean sediment to reach sediment with higher concentrations of COCs. Even at a removal depth of 5 to 6 feet, the concentration of COCs in dredge residuals would be at least as great as current surface sediment concentrations and would require the placement of a residuals cover or cap. Finally, research indicates that sites like Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site 62 March 2017 040284-01.08 Development of Remedial Alternatives with hard bottom conditions and/or debris have higher potential releases during dredging (USACE 2008a). Construction-related releases associated with dredging increase the short and long-term risk associated with removal by resuspending COCs into the water column; redistribution of impacted sediment downstream and/or offsite would result in a remedy that is less protective than remedial alternatives that are less intrusive. Post-construction monitoring data have shown that dredging-based cleanup remedies can increase fish tissue concentration of contaminants, even several years following completion of dredging (e.g., at the Commencement Bay and Duwamish Waterway Superfund Sites; Patmont et al. 2013). To the extent that dredging-related releases occur, they reduce the overall effectiveness of a dredging remedy and under USEPA sediment remediation guidance (USEPA 2005), which is a consideration during the comparative net risk analysis of the remedial alternatives under consideration. 4.2.5.1 Removal Best Management Practices Operational and engineering controls (rigid and flexible barriers) are often used to the extent practicable to mitigate potential releases. However, because the Site is part of a stormwater drainage system, the implementation of controls in the channel would likely be extremely challenging. Rigid controls would block stormwater flows and could result in flooding upstream, a situation likely very much unacceptable to the City of Deer Park and upstream residents and businesses. If low water levels or high flow velocities occur in the channel, which, as described in the STM Report (Anchor QEA 2011c) are common at the Site, flexible barriers, like turbidity curtains, will likely be ineffective in controlling releases. Turbidity curtains are considered ineffective at current velocities greater than approximately 0.5 meters per second (Francingues and Palermo 2005). In addition to these Site-specific considerations, case studies on engineering controls have shown that they: • May have limited effectiveness • Are subject to leakage Feasibility Study Report Patrick Bayou Superfund Site 63 March 2017 040284-01.08 Development of Remedial Alternatives • Accumulate resuspended sediments at the base of the barrier, which is impossible to completely capture • Have other technical limitations (USACE 2008b; Anchor 2005; Anchor QEA and Arcadis 2010) Further, use of rigid barriers can result in unintended consequences such as concentration of dissolved-phase chemicals inside the barrier, localized scour adjacent to the barrier, and/or the spread of contaminants during structure removal (Ecology 1995; Konechne et al. 2010; Anchor QEA and Arcadis 2010). Flexible barriers, such as turbidity curtains, will suffer from suspended sediment losses because these types of barriers are not truly watertight (USACE 2008a; USACE 2008b; Francingues and Palermo 2005; Anchor 2005; Anchor QEA and Arcadis 2010). 4.2.5.2 Disposal The RATS (Anchor QEA 2013a) retained both upland confined disposal facility (CDF) and landfill disposal as options for the selected alternative. In development of the alternatives presented in this FS, there have been no changes to the disposal considerations presented in the RATS (Anchor QEA 2013a). ACBM capping would require a debris removal phase prior to cap placement; the debris would be shipped offsite for landfill disposal. If excavation were necessary to accommodate a cap, excavated sediment could potentially be disposed of either onsite in a constructed CDF (such as an inoperative stormwater pond), or offsite in a landfill. Disposal decisions would be made during the remedial design. 4.3 Assembly of Remedial Alternatives Remedial alternatives were developed to evaluate candidate methods for achieving the RAOs. Specifically: • The fate and transport model (Appendix A) was used to assess the effectiveness of the remedial alternatives in reducing concentrations of PCBs in surface water to below the RAO of 8.2 ng/L. Reductions in surface water PCB levels also will address the wildlife RAO (see Section 3.3). Feasibility Study Report Patrick Bayou Superfund Site 64 March 2017 040284-01.08 Development of Remedial Alternatives • SMAs were designated to evaluate the effects on surface water quality, benthic risk, and risks to aquatic-dependent wildlife from performing a remedial action in these areas, as described in Section 4.1. The locations of the SMAs are shown on Figure 4-1. The results of the fate and transport and MNR modeling are discussed in Section 5 in the context of the effectiveness of the remedial alternatives in reducing the concentrations of PCBs in surface water and in reducing benthic risk and aquatic-dependent wildlife to acceptable levels within a reasonable time frame, which, for purposes of FS evaluations, is considered to be 10 years. The alternatives are presented below. 4.3.1 Alternative 1 – No Further Action The No Further Action alternative serves as the baseline of comparison for the other remedial alternatives. The NCP requires the development and evaluation of the No Further Action alternative (40 CFR 300.430(e)(6)). 4.3.2 Alternative 2 – Monitored Natural Recovery Alternative 2, MNR, relies on natural processes to reduce benthic risks to acceptable levels, to meet background conditions, and to address the aquatic-dependent wildlife RAO while monitoring recovery over time to verify remedial success. Modeling, presented in Appendix A, projects that the ongoing sedimentation at the Site will reduce PCB concentrations (and thus mean PEL-Q and toxicity) in surface sediment and PCBs in the water column over time. Alternative 2 would be implemented under an Adaptive Management framework and would generally include the following components: • Data collection, and evaluation of natural recovery, including evaluation of the need for and limits of remedial actions Feasibility Study Report Patrick Bayou Superfund Site 65 March 2017 040284-01.08 Development of Remedial Alternatives • The data collection will also be used to develop RAOs for mercury and PCDD/PCDF TEQ in surface water and to assess the effectiveness of Alternative 2 to achieve these RAOs16 • Continued sampling and analysis during the natural recovery period, including evaluation of recovery effectiveness • Maintenance of the existing institutional, security, and physical access controls, which include restrictions to on-site access by fencing, use restrictions, maintenance agreements, and facility security and surveillance • Enhancements to existing Site institutional controls (described in Section 4.2) Figure 4-2 presents a process flow diagram for the adaptive management framework that would be used, including the sequence of sampling, evaluation, and decisions that would be made under all alternatives. The fate and transport model uses an empirically defined PCB source to represent observed PCB loads in the concrete-lined channel; for purposes of predicting natural recovery, it is assumed that this source would not further attenuate (see Appendix A). Based on this conservative assumption, the model simulation of Alternative 2 predicts that more than 19 years of natural recovery would be required before water column PCB concentrations decrease below the surface water RAO of 8.2 ng/L.17 However, water column PCB data collected in 2014 demonstrate that PCB levels are much lower in 2014 when compared to 2009 and 2011 levels (see Section 2.6). It is difficult to account for this reduction in the model parameters, and similar reductions could be observed in the future. This is a key area of uncertainty for the purposes of developing remedial alternatives for the FS, and reducing that uncertainty should be considered as part of the remedial design and adaptive management process for the Site. Additional data collection to establish RAOs for mercury and PCDD/PCDF TEQs is not included in the cost estimate for this alternative due to the uncertainty in the data that will be required. The data requirements will be established during the design phase. 17 Nineteen years is the length of the long-term future model simulation. Predicted water column PCB concentrations are still higher than the PCB surface water RAO of 8.2 ng/L at the end of that simulation period. 16 Feasibility Study Report Patrick Bayou Superfund Site 66 March 2017 040284-01.08 Development of Remedial Alternatives To address the uncertainty in attenuation and the potential impacts of this uncertainty on natural recovery rates, an empirical evaluation of natural recovery was also conducted based on the water column data (Appendix E). This analysis indicates that water column PCB concentrations decreased at a half-life of approximately 3 to 6 years between 2009, 2011, and 2014. If these observed rates of decline continue into the future, it is expected that water column PCB concentrations would decrease below the surface water RAO within 9 to 19 years (depending on location; Appendix E) by natural recovery processes alone. Thus, monitoring would be used to evaluate progress towards such predictions as part of this alternative. To evaluate natural recovery for addressing benthic risk and the aquatic-dependent wildlife RAO, a sediment chemistry based approach was also evaluated for Alternative 2 (see Appendix A). In the BERA Report (Anchor QEA 2013c), toxicity in Site sediments was predicted using the mean PEL-Q model, as described in Section 2.6 of this FS. Sediment half-life estimates based on PCB fate modeling, presented in Appendix A, were used to project reductions in mean PEL-Q values over time. Based on this evaluation, the natural recovery at most stations would achieve the benthic RAO within 10 years or less. However, the benthic RAO is not met within 10 years at 17 discrete locations (PB-001.1, PB-016A, PB018, PB-026, PB-032, PB-034, PB-036, PB-037, PB-041A, PB-043, PB-044A, PB-047.1, PB053A, PB-059.1, PB-063.1, PB-069, and PB-081; see Table 4-1), conservatively assuming no action has been taken in SMA-1 to address the PCB surface water RAO.18 In this alternative, it is expected that MNR monitoring would be conducted for surface water and sediment chemistry (as described in Section 4.2) at various locations throughout the Site to evaluate the following: • Confirm the observed declines in surface water and sediment concentrations continue into the future • Confirm the benthic RAO is being met For Alternatives 3 and 4, consistent with the Adaptive Management approach employed throughout the RI/FS, the evaluation of natural recovery for benthic risk assumes that the first step in the remedial process is remedial action at SMA-1 to address the PCB surface water RAO. In addition to addressing the PCB surface water RAO, remedial action in SMA-1 would also be expected to accelerate natural recovery; thus, fewer locations are identified under Alternatives 3 and 4 where the benthic risk RAO is not met within 10 years. See Table 4-1. 18 Feasibility Study Report Patrick Bayou Superfund Site 67 March 2017 040284-01.08 Development of Remedial Alternatives This alternative also includes maintenance and enhancement of the existing institutional controls and restrictions (e.g., surveillance, fencing) to site access. Figure 4-3 depicts a plan view for Alternative 2. The estimated cost for this alternative is $710,000 (Appendix C). 4.3.3 Alternative 3 – Monitored Natural Recovery, SMA-1 Capping, and SMA-2 through SMA-9 Treatment Alternative 3 would be implemented using an Adaptive Management framework, and it would generally include the following components: • Pre-design surface water and sediment data collection, model recalibration, refinement of SMA extent, and evaluation of natural recovery, including evaluation of the need for and limits of remedial actions in SMA-1 through SMA-9 • The additional data collection will also be used to develop RAOs for mercury and PCDD/PCDF TEQ in surface water and to assess the effectiveness of Alternative 3 to achieve these RAOs19 • Capping of SMA-1 with ACBM and RCM if surface water PCB concentrations do not continue to decline at a rate consistent with that observed between 2009, 2011, and 2014 • Treatment with AC of surface sediments in SMA-2 through SMA-9 if the target mean PEL-Q is not projected to be achieved within 10 years based on model recalibration results • MNR and associated monitoring for those areas where MNR is suitable based on pre-design data collection results • Monitoring and maintenance of capping and treatment remedies, if implemented • Maintenance of the existing institutional, security, and physical access controls, which include restrictions to on-site access by fencing, use restrictions, maintenance agreements, and facility security and surveillance • Enhancements to existing Site institutional controls (described in Section 4.2) Additional data collection to establish RAOs for mercury and PCDD/PCDF TEQs is not included in the cost estimate for this alternative due to the uncertainty in the data that will be required. The data requirements will be established during the design phase. 19 Feasibility Study Report Patrick Bayou Superfund Site 68 March 2017 040284-01.08 Development of Remedial Alternatives Consistent with the adaptive management approach for this Site, pre-design data collection, model recalibration, refinement of SMA extent, and evaluation of ongoing natural recovery would be conducted based on baseline water column, porewater, and sediment chemistry pre-design data collected following the feasibility study. In the event that the pre-design baseline sampling and recovery model re-evaluation does not indicate acceptable natural recovery (i.e., indication of not meeting the PCB surface water or benthic RAO within about 10 years), capping of SMA-1 and/or treatment in SMA-2, -3, -4, -5, -6, -7, -8 and/or SMA-9 would be implemented, as appropriate. For FS purposes, it has been assumed that ACBM would be the technology used for capping; however, aggregate caps may be determined appropriate and selected for certain areas in SMA-1, as determined during remedial design. For treatment, addition of AC into surface sediments has been assumed using augers, tines, or similar technology. The assessment presented in Appendix B assumes that two layers of RCM underlayment could be necessary due to uncertainty in the source loading mechanism of PCBs in SMA-1. The actual thickness, granular AC dosage, and design of the RCM would be determined during remedial design. As shown on Figure 4-4, capping in SMA-1 would involve installing ACBM with an underlayment of AC RCM in the channel. SMA-1 extends for a length of approximately 700 feet along the bayou channel, from Station PB-075 to PB-082. With bank-to-bank widths ranging from approximately 50 to 100 feet, the surface area of capping is 58,200 square feet (1.33 acres) for this alternative. However, the actual footprint and size of SMA-1 would be more thoroughly delineated during remedial design by collecting additional sediment, surface water, and porewater data, as appropriate, and revisiting the modeling if necessary. For the purpose of this FS, treatment of SMA-2 through SMA-9 involves mixing AC into the top 4 to 6 inches of surface sediments. The combined surface area of these SMAs is approximately 6.66 acres.20 With bank-to-bank widths typically on the order of 100 to 150 feet (and in the case of SMA-4, a bank-to-edge distance of 250 feet), only a portion of the While this represents the acreage based on Thiessen polygons, the FS cost development adds a 20 percent contingency to this area to account for engineering design considerations and potential changes to lateral extents as may be determined by pre-design sampling. 20 Feasibility Study Report Patrick Bayou Superfund Site 69 March 2017 040284-01.08 Development of Remedial Alternatives treatment area could be addressed with land-based equipment such as a long-reach excavator. Treatment areas located more than approximately 50 feet from the shoreline would need to be addressed using a shallow-draft, barge-mounted machine equipped with a mixing tool such as an auger or tines. Figure 4-5 depicts conceptual treatment implementation concepts, including mixing of shallow sediments from the bank and from barge-mounted equipment. Figure 4-5 also depicts concepts for surface application of amendments, which will be considered during remedial design as an alternate approach that minimizes sediment disturbance and may be applicable for low-energy areas of the Site. The actual treatment area footprint would be more thoroughly delineated using pre-design sediment and surface water data and updating and refining the MNR modeling as appropriate. Costs for Alternative 3 were developed for the FS based on the following assumptions: • Demolition of the concrete-lined portion of the existing channel is not necessary and contractors would be able to install the ACBM over the existing concrete. • SMA-1 would not require dredging prior to installation of ACBM because of the low profile of the ACBM. • The ACBM will be placed from one TOB to the other TOB in the channel. • The RCM would be placed at the base of the channel but not along the banks. • There are no channel or TOB access or structure restrictions for installation of the cap. • The railroad (PTRA) would allow placement of the cap adjacent to the railroad culvert. • Concrete trucks and/or concrete pumps would have sufficient access to the channel. • Treatment would be performed either from the bank using a long-reach excavator or from a shallow-draft, barge-mounted machine equipped to mix the AC into the top 6 inches of sediment. Based on the production rates provided by ACBM contractors, as well as prior project experience and pilot studies of in situ treatment, the duration of construction for this alternative is estimated to be 5 to 7 months. This alternative is estimated to require approximately 4,600 hours of heavy equipment operations. Feasibility Study Report Patrick Bayou Superfund Site 70 March 2017 040284-01.08 Development of Remedial Alternatives Using construction worker injuries and fatality rates published by the U.S. Department of Labor (USDL; USDL 2011), Alternative 3 is estimated to result in approximately 0.27 lost time injuries and approximately 0.001 fatalities as a result of construction (Table 4-4).21 The cost of this alternative is estimated to be approximately $6.7 million (Appendix C). 4.3.4 Alternative 4 – Monitored Natural Recovery and SMA-1 through SMA-9 Capping Alternative 4 would be implemented using an Adaptive Management framework and would generally include the following components: • Pre-design data collection and natural recovery evaluations as described for Alternative 3 • The additional data collection will also be used to develop RAOs for mercury and PCDD/PCDF TEQ in surface water and to assess the effectiveness of Alternative 4 to achieve these RAOs22 • Capping based on the results of pre-design sampling and MNR evaluations as follows: − SMA-1: capping with ACBM and a RCM underlayment, and MNR − SMA-2 through SMA-9: capping with ACBM but no RCM underlayment, and MNR • MNR and associated monitoring for those areas where MNR is suitable based on pre-design data collection results • Monitoring and maintenance of containment and treatment remedies, if implemented • Maintenance of the existing institutional, security, and physical access controls as described for Alternative 3 • Enhancements to existing Site institutional controls and warning signs as described in Alternative 3 These numbers are not intended to represent actual injuries or fatalities expected (e.g., less than one fatality) but are useful for comparative purposes between alternatives to evaluate the potential impacts of alternatives on worker health and safety. 22 Additional data collection to establish RAOs for mercury and PCDD/PCDF TEQs is not included in the cost estimate for this alternative due to the uncertainty in the data that will be required. The data requirements will be established during the design phase. 21 Feasibility Study Report Patrick Bayou Superfund Site 71 March 2017 040284-01.08 Development of Remedial Alternatives The ACBM cap will effectively eliminate an exposure pathway between benthos and surface sediments because it creates a hard concrete barrier on the sediment surface. Because SMA-2 through SMA-9 were identified as benthic risk areas, the use of ACBM alone (without a RCM underlayment) is considered an appropriate capping technology to achieve RAOs for these SMAs. The use of this technology also will address the aquatic-dependent wildlife RAO because it will reduce the bioavailability and therefore bioaccumulation of PCBs. Anchoring of the ACBM material in SMA-4 could require placing the cap from bank to bank, even though the edge of this SMA is located mid channel. Thus, for example, the cost estimate for capping using ACBM in SMA-4 assumes approximately 3.5 acres of ACBM would be needed to cover this 1.6-acre area. For capping SMA-2 through SMA-9, the Thiessen polygon area of 6.66 acres (Table 4-2) is increased to 13.77 acres when bank-tobank capping, and a 20 percent contingency on areas is included, as reflected in the FS costs (Appendix C). It may be possible to terminate the edge of the ACBM cap beneath the water mid-channel, or it may be more cost-effective to use a granular cap for certain SMAs. If the pre-design sampling and natural recovery evaluation indicate that capping is necessary, the actual details for implementing this cap in all SMAs (including selection of capping technology and cap footprint limits) would be determined during remedial design. Figure 4-6 presents a plan view of Alternative 4. Figure 4-7 depicts typical ACBM details. Based on the production rate from ACBM contractors and prior projects, the duration of construction for this alternative is estimated to be 5 to 7 months (Table 4-4). This alternative is estimated to require approximately 4,500 hours of heavy equipment operations. Using construction worker injuries and fatality rates published by the USDL (2011), Alternative 4 is estimated to result in approximately 0.25 lost time injuries and approximately 0.001 fatalities as a result of construction (Table 4-4). Costs for Alternative 4 were developed for the FS based on the following assumptions: • Demolition of the concrete-lined portion of the existing channel is not necessary and that contractors would be able to install the ACBM over the existing concrete • None of the SMAs would require dredging prior to installation of the ACBM because of the low profile of the ACBM Feasibility Study Report Patrick Bayou Superfund Site 72 March 2017 040284-01.08 Development of Remedial Alternatives • The ACBM will be placed from one TOB to the other TOB in the channel for anchoring requirements • RCM would only be used in SMA-1; The RCM would be placed at the base of the channel but not along the banks • There are no channel or TOB access or structure restrictions for installation of the cap • The railroad (PTRA) would allow placement of the cap adjacent to the railroad culvert • Concrete trucks and/or concrete pumps would have sufficient access to the channel The estimated cost for this alternative is approximately $13 million. Feasibility Study Report Patrick Bayou Superfund Site 73 March 2017 040284-01.08 5 DETAILED ANALYSIS OF REMEDIAL ALTERNATIVES The detailed evaluation of remedial alternatives is based on consideration of the following criteria, as required by the NCP, 40 CFR Section 300.430(e)(9): 1. Overall protection of human health and the environment 2. Compliance with ARARs 3. Long-term effectiveness 4. Reduction of TMV 5. Short-term effectiveness 6. Implementability 7. Cost 8. State acceptance 9. Community acceptance The first two criteria, overall protection and compliance with ARARs, are identified as threshold criteria in 40 CFR Section 300.430(f). Remedial alternatives must address the threshold criteria to be selected as the final remedy, although ARAR waivers are considered in some circumstances. The next five criteria are identified as primary balancing criteria. The comparative analysis in Section 6 considers the anticipated performance of the remedial alternatives relative to these balancing criteria. The final two criteria, identified as modifying criteria, are considered by USEPA in preparing the Record of Decision based on consultation with the State environmental agency and a review of public comments received in response to the FS and the proposed plan. As such, State and community acceptance are not considered directly in this FS and will be evaluated by USEPA separately after public comments are received on the proposed plan. Each threshold and balancing criterion is briefly defined below: • Overall protection is an evaluation of whether the remedial alternative can adequately protect human health and the environment. This may be expressed as an assessment of whether the remedial alternative addresses all of the RAOs, which are identified and described in Section 2. • Compliance with ARARs is an evaluation of whether the remedial alternative addresses or can be implemented in compliance with all of the ARARs, which are identified in Table 3-2. Feasibility Study Report Patrick Bayou Superfund Site 74 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives • Long-term effectiveness is an evaluation of the ability of the remedial alternative to reliably maintain protection of receptors. • Reduction of TMV is an evaluation of the degree to which treatment or recycling of affected media is used to reduce the toxicity, mobility or volume of contaminated media, particularly principal threats. • Short-term effectiveness is an evaluation of both the time required for the remedial alternative to achieve full protection and the degree to which potential risk to human health and the environment is increased during implementation of the remedy, considering measures that may be used to mitigate short-term risks. The short-term effectiveness evaluation also includes an evaluation of the sustainability of the remedial alternative in conformance with the USEPA Region 6 Clean and Green Policy (USEPA 2009). • Implementability is an evaluation of factors that may impede the implementation of the remedy, considering technical and administrative factors. Technical factors include consideration of whether the remedial alternative involves the use of well demonstrated technologies, readily available equipment and materials, and whether any physical conditions of the Site that may impede implementation. Administrative factors include consideration of whether implementation of the remedial alternative might be impeded by the need to obtain approvals from nearby landowners or public agencies. • Cost is an evaluation of construction and long-term operation, maintenance, and monitoring costs. A present-worth cost analysis is used to evaluate the total cost of remedial alternatives. • Assessment of State concerns may not be completed until comments on the RI/FS are received but may be discussed, to the extent possible, in the proposed plan issued for public comment. The State concerns that shall be assessed include the following: 1) The State’s position and key concerns related to the preferred alternative and other alternatives, and 2) State comments on ARARs or the proposed use of waivers. • Community acceptance assessment includes determining which components of the alternatives interested persons in the community support, have reservations about, or oppose. This assessment may not be completed until comments on the proposed plan are received. Feasibility Study Report Patrick Bayou Superfund Site 75 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives Mercury and PCDD/PCDF TEQ surface water quality were not included in the detailed assessment or comparison of alternatives. Although the TSWQS human health criterion has been identified as an ARAR by USEPA, additional data are required to establish RAOs for these chemicals in surface water, assess baseline conditions, and evaluate potential effectiveness of remedial alternatives identified in Section 4 to meet the RAOs. Data collected during the design phase will be used to address these needs and, if necessary, support design modifications to the alternative under an adaptive management framework. The following section describes the individual analyses for each of the alternatives. Table 5-1 summarizes the key discussion points from this section for each of the evaluation criteria. 5.1 Alternative 1 – No Further Action 5.1.1 5.1.1.1 Threshold Criteria Overall Protection of Human Health and the Environment Existing data indicates that ongoing deposition of relatively clean sediment is occurring at the Site independent of any specific actions by the Respondents, which will continue to reduce surface water concentrations of PCBs, and surface sediment concentrations of PCBs, PAHs, lead, and BEHP over time. However, Alternative 1 does not meet the threshold criterion of overall protection of human health and the environment because it does not provide for monitoring to evaluate the progress of natural recovery. Without monitoring, there would be no way to verify that surface water quality objectives are being met over time, or that benthic and aquatic-dependent wildlife risks are decreasing to acceptable levels, and overall protectiveness of the remedy could not be assessed. 5.1.1.2 Compliance with ARARs Compliance with ARARs was not assessed for Alternative 1 because it does not meet the threshold criterion of overall protection of human health and the environment. Feasibility Study Report Patrick Bayou Superfund Site 76 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives 5.1.2 Balancing Criteria Because this alternative does not meet threshold criteria, the balancing criteria were not evaluated in this FS. 5.2 Alternative 2 – Monitored Natural Recovery 5.2.1 Threshold Criteria 5.2.1.1 Overall Protection of Human Health and the Environment Alternative 2 potentially meets the threshold criterion of protection of human health and the environment through MNR over time; however, natural recovery rates would need to be periodically assessed by collecting additional data and evaluating actual natural recovery trends for the Site to ensure the recovery time frame was acceptable. Deposition of relatively clean sediments into Patrick Bayou would provide isolation of impacted sediments from surface water, reducing water column concentrations. Analysis of existing surface water data indicate reductions in PCB concentrations between 2009 and 2014, and reductions in PCB flux may continue into the future so that the PCB surface water RAO could be met. Potential benthic and aquatic-dependent wildlife risks are also expected to be reduced over time, likely to acceptable levels within an acceptable time frame over the majority of the Site. Alternative 2 includes the monitoring necessary to evaluate and assess the rate of MNR, which allows for an adaptive management approach wherein future actions would be considered depending on the effectiveness of MNR in achieving RAOs within a reasonable time frame. The analytic model presented in Appendix E indicates that the PCB surface water RAO of 8.2 ng/L would likely be met throughout the Site within 9 to 19 years, (subject to uncertainty considerations for this particular model) if the rates of decline for PCBs in surface water remain similar to those observed between 2009 and 2014. This uncertainty would be addressed through pre-design sampling, which would be used to assess the validity of the FS modeling. The chemical fate model presented in Appendix A, coupled with the baseline mean PEL-Q and toxicity data, suggests that most of the Site would achieve acceptable benthic and aquatic-dependent wildlife risk through ongoing natural recovery within 10 years; however, Feasibility Study Report Patrick Bayou Superfund Site 77 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives some areas of the Site may have unacceptably long recovery periods. To address uncertainty, benthic risk natural recovery would need to be assessed through additional data collection and natural recovery evaluations. These evaluations would be used to assess whether additional action(s) is/are warranted though an adaptive management process. 5.2.1.2 Compliance with ARARs Alternative 2 would not result in construction impacts or other changes to baseline conditions that would trigger any action-, chemical-, or location-specific ARARs identified in Table 3-2. Because no construction activity is included in this alternative, there are no substantive permit conditions that would need to be met. 5.2.2 5.2.2.1 Balancing Criteria Long-term Effectiveness Analytic MNR Modeling conducted for this FS (Appendix E) indicates that the PCB surface water RAO would be met throughout the Site after 9 to 19 years due to natural recovery processes. The effectiveness would be monitored through periodic sampling of the water column to confirm that the PCB surface water RAO is being met. The ability of natural recovery alone to meet benthic risk RAOs is uncertain. Modeling presented in Appendix A indicates that most of the Site would achieve acceptable benthic risk within 10 years due to natural recovery. However, approximately 16 acres encompassing 17 surface sediment stations (Table 4-1), as described in Section 4.3.2, may have unacceptably long recovery periods. Uncertainty in natural recovery to address benthic risk would need to be assessed by collecting additional data and updating and refining the natural recovery evaluations. MNR has been demonstrated to be a reliable process that is effective in the long term based on monitoring conducted at other sediment cleanup sites (USEPA 2005). Feasibility Study Report Patrick Bayou Superfund Site 78 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives 5.2.2.2 Reduction of Toxicity, Mobility, or Volume Alternative 2 does not take specific active measures to reduce TMV of COCs. The toxicity of surface sediments will naturally decline over time due to deposition of relatively clean sediments within Patrick Bayou. 5.2.2.3 Short-term Effectiveness Alternative 2 ranks uncertain for short-term effectiveness. While analytic MNR modeling (Appendix E) predicts that natural recovery could take on the order of 9 to 19 years to achieve the PCB surface water RAO, natural recovery to address benthic risk could potentially require unacceptably long time frames. Natural recovery modeling is subject to uncertainty that would be addressed through pre-design sampling. Longer time frames to achieve RAOs are balanced by negligible short-term impacts associated with implementing this alternative; benthic, water, and sediment sampling can be performed with very low risk to workers and would have negligible short-term impacts on water and air quality. Noise impacts associated with Alternative 2 are also considered negligible. 5.2.2.4 Implementability Alternative 2 is highly implementable. This alternative requires periodic monitoring through benthic, water, and sediment sample collection, which has already been performed in support of the RI/FS. There are minimal anticipated implementability challenges associated with this alternative, which are limited to the coordination and safety issues associated with sample collection adjacent to active industrial operations bordering Patrick Bayou. 5.2.2.5 Cost Alternative 2 entails periodic sampling of benthos, water, and sediment. The estimated net present value (NPV) cost for Alternative 2 is $710,000 as detailed in Appendix C. Feasibility Study Report Patrick Bayou Superfund Site 79 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives 5.3 Alternative 3 – Monitored Natural Recovery, SMA-1 Capping, and SMA-2 through SMA-9 Treatment 5.3.1 5.3.1.1 Threshold Criteria Overall Protection of Human Health and the Environment Alternative 3 meets the threshold criterion of overall protection of human health and the environment because it is based on the same use of MNR as Alternative 2, and allows for capping of SMA-1 if warranted to achieve the PCB surface water RAO and treatment of SMA-2 thorough SMA-9 to reduce benthic and aquatic-dependent wildlife risks, if/as needed. By capping SMA-1, potential sources of PCBs to the water column in that upstream area are effectively eliminated. Treatment of surface sediments in SMA-2 through SMA-9, if necessary, would reduce bioavailability of secondary ICs and reduce benthic and aquaticdependent wildlife risk to acceptable levels. Modeling presented in Appendix A indicates that capping SMA-1 is expected to achieve the PCB surface water RAO of 8.2 ng/L throughout the Site within 6 years following completion of capping. Treatment of benthic risk areas is expected to reduce bioavailability of ICs relatively quickly. Field scale studies conducted on the Grasse River demonstrated that within 3 years after placement of AC into sediments, PCB bioavailability was reduced by more than 90 percent (Patmont et al. 2014). ITRC guidance recognizes that treatment can provide “near-immediate reduction of the bioavailable fraction of contaminants” with minimal impacts to habitat (ITRC 2014), although the mixing of treatment reagents into surface sediments would be expected to temporarily eliminate the benthic community, requiring up to a year following construction before the benthic community re-establishes itself. 5.3.1.2 Compliance with ARARs Implementation of Alternative 3 would involve the construction of a low-profile cap within a portion of the Site and treatment of benthic risk SMAs. Reduction of PCB concentrations in surface water would address the PCB surface water RAO and also reduce risk to aquaticdependent wildlife. The construction of the cap and addition of AC to sediments would trigger compliance with CWA Section 404(b)(1), Rivers and Harbors Act Section 10, and other ARARs related to surface water quality. Alternative 3 is also expected to meet the substantive requirements of the ARARs in Table 3-2 through implementation of BMPs and Feasibility Study Report Patrick Bayou Superfund Site 80 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives agency documentation and coordination activities. Construction of the cap would require the placement of approximately 1.6 acres of ACBM, a low-profile cap that is expected to have negligible impact on the flood capacity of Patrick Bayou (i.e., the impact of the cap would be immeasurable within the predictive capability of available flood models). If the cap in SMA-1 is required, there would be moderate impacts on habitat quality, as the banks of the area to be capped are already channelized with a concrete-lined surface, and thus the benthic community impacts would be limited to the bottom of the channel. Treatment of approximately 7.9 acres of sediment can be accomplished with a significant but temporary impact to habitat in the treatment footprint; recovery from these impacts would be expected to occur within approximately a year following completion of treatment. 5.3.2 5.3.2.1 Balancing Criteria Long-term Effectiveness Alternative 3 includes capping, if necessary, which is a robust technology that has been demonstrated to be effective in the long term at many sediment cleanup sites and has a well-established design process (USEPA 1998). Modeling conducted for this FS (Appendix A) indicates that the PCB surface water RAO would be met throughout the Site within 6 years after completion of construction for Alternative 3. Treatment of benthic risk areas, if necessary, is expected to reduce bioavailability very quickly (within less than 3 years based on field scale demonstrations) in surface sediments, and it may result in permanent23 sequestration of key risk ICs. As described for Alternative 2, MNR has been demonstrated to be a reliable process that is effective in the long term based on monitoring conducted at other sediment cleanup sites (USEPA 2005). Because treatment can be effective in relatively short time frames, there is little risk for an erosion event to occur before treatment is complete. The STM predicts maximum net erosion of less than 2 cm (less than 1 inch) for a 2-year recurrence interval storm (Anchor QEA 2011c). Because treatment would be conducted within the upper 6 inches (15 cm), treatment media would still be present even Because treatment is a relatively new approach to contaminated sediments, there is some uncertainty about the long-term performance of treatment remedies. There is no case history of monitoring that documents the long-term effectiveness of sediment treatment. Nonetheless, recent literature supports the use of treatment as a sediment remedial technology, and treatment is expected to be effective in the long term for Patrick Bayou. 23 Feasibility Study Report Patrick Bayou Superfund Site 81 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives following an erosion event. Once treatment processes are complete, erosion of the treated media is not a concern. Alternative 3 is highly compatible with adaptive management strategies that would facilitate modifying the monitoring plan and schedule and/or allowing for future actions to be taken if the results of the monitoring indicate additional remedial action is required. For example, if treatment were implemented to address benthic risk, treated areas could potentially be re-addressed in the future, if necessary (for example, by adding additional amendments into sediments or capping with ACBM), if post-treatment monitoring indicated that benthic risk reductions were not being achieved quickly enough. 5.3.2.2 Reduction of Toxicity, Mobility, or Volume Alternative 3 provides for reduction in mobility of PCBs by including a treatment layer within the cap in SMA-1 and treatment of surface sediments in benthic risk areas, if implemented. Appendix B describes the modeling performed assuming the use of a granular AC layer in the form of a RCM underlayment to the ACBM armored cap. Modeling indicates that this treatment is expected to reduce near-surface porewater concentrations of PCBs by 99.8 percent over 100 years. Case studies of AC treatment of sediments demonstrate potential PCB concentration reductions of more than 99 percent and PCB bioavailability reductions of more than 90 percent in treated sediments (Patmont et al. 2014). 5.3.2.3 Short-term Effectiveness Short-term risks to the community, ecological receptors, or workers associated with the implementation of this remedial alternative include the following: • Potential turbidity (manageable) associated with cap construction • Potential turbidity (manageable) during treatment • Moderate benthic impacts in ACBM capping areas, which would require several years of sediment deposition onto the surface of the ACBM before benthic recovery could occur • Significant but temporary benthic impacts in treatment areas due to mixing of near surface sediments, which would require up to a year following treatment before benthic recovery would occur Feasibility Study Report Patrick Bayou Superfund Site 82 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives • Localized impacts to the banks of Patrick Bayou where construction equipment would be staged and where the ACBM cap would be anchored • Potential accidents during construction • Air emissions from construction equipment • Noise impacts from the work • Potential facility impacts during the estimated 5- to 7-month duration of the work Based on the case history of implementing ACBM capping and treatment at other sites, water quality impacts associated with turbidity during debris removal activities, cap construction, and mixing of treatment reagents into surface sediments would be expected to be manageable within Patrick Bayou. Air quality impacts are expected to be moderate for this alternative, associated with equipment operations and truck traffic. An estimated 4,600 hours of heavy equipment operations would be required to complete the project. Equipment and vehicle emissions of hydrocarbons and nitrogen oxides lead to the generation of smog, including ozone, which is a particular concern in Harris County; this County has been classified by USEPA as a “severe” non-attainment area for the 1997 8-hour ozone standard and a “marginal” nonattainment area for the 2008 8-hour ozone standard. Moreover, Harris County has not been classified in the 2012 National Ambient Air Quality Standard (TCEQ 2013) for fine particulate matter (PM2.5). Community impacts associated with truck traffic are expected to be negligible considering that the Site is located in an industrial area. Health and safety impacts were assessed using USDL statistics for accidents and fatalities for the “construction” labor code category, based on the estimated total labor hours required for the alternative. Alternative 3 would result in an estimated 0.027 lost-time injuries and 0.0011 fatalities. While both of these safety statistics are below 1.0, suggesting the likelihood for injury or fatality is very low, they are useful for comparison purposes to the safety-related issues of the other alternatives. Worker safety issues would be addressed during remedial design, and measures would include, at a minimum, development of detailed health and safety plans to help mitigate these risks. Feasibility Study Report Patrick Bayou Superfund Site 83 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives 5.3.2.4 Implementability Capping using ACBM and RCM products has been successfully demonstrated at similar sites. The shallow water and relatively narrow channel should provide for relatively straightforward deployment of the textiles. There are several areas with difficult access, such as pipeline crossings and adjacent to bridge foundations, where hand labor would be required to deploy the fabric prior to pumping concrete into the ACBM formwork. Because the ACBM has a low profile it is not expected to materially impact the flood capacity of Patrick Bayou based on the areas estimated for this alternative. Treatment by mixing AC into sediments has been demonstrated at field scale on several sediment projects. Custom equipment may be required for mixing reagents, and an experienced contractor would be recommended to perform treatment mixing. Access to the center of the channel, while challenging, could be facilitated by using small, shallow-draft barges. Turbidity caused by mixing could present an implementability challenge. This turbidity could be managed using BMPs and engineering controls such as silt curtains. Details on turbidity controls would be developed during remedial design. Additional implementability challenges include the need to coordinate with the railroad during design and construction in SMA-1. In addition, different ACBM anchoring details may be needed at TOB due to the variable Site conditions (presence of utilities, fences, more natural ground, or active production facilities) along the banks of SMA-1. Finally, remedial construction in Patrick Bayou adjacent to active production facilities would be an implementability challenge for scheduling the work, obtaining access to the work areas through active production areas, limited available space on the banks of Patrick Bayou, and providing for remedial contractor safety. None of these challenges is expected to be insurmountable but may impact cost and schedule. 5.3.2.5 Cost Costs for this alternative were estimated as described in detail in Appendix C. Costs include direct construction costs (mobilization/demobilization, Site preparation, installation of environmental controls, survey, debris removal, and capping) and indirect construction costs (permitting, engineering and design, construction oversight, long-term operations, Feasibility Study Report Patrick Bayou Superfund Site 84 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives monitoring, and maintenance [OMM], and USEPA periodic reviews). Future costs, such as OMM and periodic reviews, were estimated on an NPV basis, assuming a discount rate of 7 percent. The estimated cost for Alternative 3 is approximately $6.7 million. 5.4 Alternative 4 – Monitored Natural Recovery and SMA-1 through SMA-9 Capping 5.4.1 5.4.1.1 Threshold Criteria Overall Protection of Human Health and the Environment Alternative 4 meets the threshold criterion of overall protection of human health and the environment because it is based on the same use of MNR as Alternative 2, and allows for capping of SMAs 1 through 9, if warranted, to achieve the PCB surface water RAO and to manage benthic risk in these areas. By capping SMA-1, potential sources of PCBs to the water column would be effectively contained. Capping SMA-2 through SMA-9 would effectively eliminate the exposure pathway between benthos and sediments by creating a hard barrier on the sediment surface. Modeling presented in Appendix A indicates that by capping these areas (specifically SMA-1), the Site would be expected to achieve the PCB surface water RAO of 8.2 ng/L within 6 years following completion of construction. Benthic risk would be reduced within 10 years following completion of construction, and aquatic-dependent wildlife risk would be reduced due to a reduction in the availability of PCBs to bioaccumulate. However, capping would effectively eliminate the benthic community for years within SMA-1 through SMA-9, especially in downstream areas where benthic conditions are more conducive to supporting some benthic organisms. 5.4.1.2 Compliance with ARARs As with Alternative 3, implementation of Alternative 4 would reduce PCB concentrations in surface water, addressing the PCB surface water RAO and would also lower risk to aquaticdependent wildlife. Construction of a low-profile cap would trigger compliance with CWA Section 404(b)(1), Rivers and Harbors Act Section 10, and other ARARs related to surface water quality. Alternative 4 is also expected to generally meet the substantive requirements of the ARARs in Table 3-2 through implementation of BMPs and agency documentation and Feasibility Study Report Patrick Bayou Superfund Site 85 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives coordination activities. Construction of the cap would require the placement of approximately 16.8 acres of low-profile ACBM, which is expected to have negligible impact on the flood capacity of Patrick Bayou (i.e., the impact of the cap would be immeasurable within the predictive capability of available flood models). Unlike Alternative 3, up to 15.3 acres of shallow-water habitat in SMAs 2 through 9 would potentially be capped under Alternative 4. This would result in the immediate elimination of the existing benthic habitat in these SMAs. Although these impacts would be temporary, benthic recovery could require several years before a significant thickness of new sediment were to be deposited onto the surface of the cap to create a suitable habitat substrate. Mitigation for habitat impacts may be required, which would significantly increase the cost of implementing Alternative 4. 5.4.2 5.4.2.1 Balancing Criteria Long-term Effectiveness As with Alternative 3, Alternative 4 also includes capping, which has been demonstrated to be effective in the long-term at many sediment cleanup sites. Modeling conducted for this FS (Appendix A) indicates that the PCB surface water RAO would be met throughout the Site within 6 years after completion of construction, and benthic risk would be reduced within 10 years following completion of construction for Alternative 4. As described for Alternatives 2 and 3, MNR has been demonstrated to be a reliable process in the long term. In addition to capping and natural attenuation processes, the adaptive management approach taken under Alternative 4 would facilitate modifying the monitoring plan and schedule, and/or allow future actions to be taken if the results of the monitoring indicate additional remedial action is required. However, capping with ACBM would allow fewer future options to be considered in capped areas because the hard concrete surface would preclude actions such as in situ treatment once the cap was in place. 5.4.2.2 Reduction of Toxicity, Mobility, or Volume Similar to Alternative 3, Alternative 4 provides for reduction in mobility of PCBs by including a treatment layer within the cap in SMA-1. This alternative assumes the use of a Feasibility Study Report Patrick Bayou Superfund Site 86 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives granular AC layer dosed at the same rate as Alternative 3, in the form of a RCM underlayment to the ACBM armored cap in SMA-1, which is expected to reduce near-surface porewater concentrations of PCBs by 99.8 percent over 100 years (Appendix B). Unlike Alternative 3, there is no treatment component in SMAs 2 through 9 under this alternative. 5.4.2.3 Short-term Effectiveness Short-term risks to the community, ecological receptors, or workers associated with the implementation of this remedial alternative include the following: • Potential turbidity (manageable) associated with cap construction • Significant benthic impacts in ACBM capping areas, which would require several years of sediment deposition onto the surface of the ACBM before benthic recovery could occur. These impacts would occur even beyond the identified SMA footprint because of the need to extend the ACBM to the top of bank for anchoring as described in Section 4. • Widespread impacts to the banks of Patrick Bayou where construction equipment would be staged and where the ACBM cap would be anchored • Potential accidents during construction • Air emissions from construction equipment • Noise impacts from the work • Potential facility impacts during the estimated 5- to 7-month duration of the work Water quality impacts would be expected to be negligible, associated with turbidity during debris removal activities within Patrick Bayou, and cap construction. Air quality impacts are expected to be moderate for this alternative, associated with equipment operations and truck traffic. An estimated 4,500 hours of heavy equipment operations would be required to complete the project. Equipment and vehicle emissions of hydrocarbons and nitrogen oxides lead to the generation of smog, including ozone, which is a particular concern in Harris County which has been classified by USEPA as a “severe” non-attainment area for the 1997 8-hour ozone standard and a “marginal” non-attainment Feasibility Study Report Patrick Bayou Superfund Site 87 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives area for the 2008 8-hour ozone standard. Moreover, Harris County has not yet been classified in the 2012 National Ambient Air Quality Standard (TCEQ 2013) for PM2.5. Community impacts associated with truck traffic are expected to be minimal considering that the Site is located in an industrial area. Health and safety impacts were assessed using USDL statistics for accidents and fatalities for the “construction” labor code category based on the estimated total labor hours required for the alternative. Alternative 4 would result in an estimated 0.25 lost-time injuries and 0.001 fatalities. As with Alternative 3, both of these safety statistics are below 1.0, suggesting the likelihood for injury or fatality is very low. Worker safety issues would be addressed during remedial design, and measures would include, at a minimum, development of detailed health and safety plans to help mitigate these risks. 5.4.2.4 Implementability As discussed under Alternative 3, capping using ACBM and RCM products has been successfully demonstrated at similar sites. Areas with shallow water and/or a relatively narrow channel should provide for relatively straightforward deployment of the textiles. In difficult access areas, such as pipeline crossings and bridge foundations, hand labor can be used to deploy the fabric prior to pumping concrete into the ACBM formwork. Because the ACBM has a low profile, it is not expected to materially impact the flood capacity of Patrick Bayou. However, if it is determined during remedial design that dredging is necessary to maintain flood capacity in Patrick Bayou, the implementability challenges would be significant, including protection of water quality, management of residuals and releases, material handling, and disposal as described in Section 4.2.5. Implementability challenges include the need to coordinate with the PTRA during design and construction in SMA-1. In addition, different anchoring details may be needed at the top of the bank due to variable Site conditions (presence of utilities, fences, more natural ground, or active production facilities) along the channel length. Further, in wider channel areas, the contractor may need to take additional measures to ensure that pumped grout will fully fill the ACBM formwork in the middle of the channel, as grout hoses are typically Feasibility Study Report Patrick Bayou Superfund Site 88 March 2017 040284-01.08 Detailed Analysis of Remedial Alternatives inserted into the formwork at the edge on top of the banks. These wider panels of formwork are also more difficult to deploy accurately because of their size. Finally, remedial construction in Patrick Bayou adjacent to active production facilities would be an implementability challenge for the following reasons: • Scheduling the work to avoid disruptions to production operations • Obtaining access to work areas through active production areas • Finding suitable available work space on the banks of Patrick Bayou • Providing for remedial contractor safety None of these challenges is expected to be insurmountable, but they may impact cost and schedule. 5.4.2.5 Cost Costs for this alternative were estimated as described in detail in Appendix C. Costs include direct construction costs (mobilization/demobilization, Site preparation, installation of environmental controls, survey, debris removal, and capping) and indirect construction costs (permitting, engineering and design, construction oversight, long-term operations, monitoring, and maintenance [OMM], and USEPA periodic reviews). Future costs, such as OMM and periodic reviews, were estimated on an NPV basis, assuming a discount rate of 7 percent. The estimated cost for Alternative 4 is approximately $13.0 million. Feasibility Study Report Patrick Bayou Superfund Site 89 March 2017 040284-01.08 6 COMPARATIVE ANALYSIS OF ALTERNATIVES This section compares the alternatives relative to each of the FS evaluation criteria listed under the NCP. Table 5-1 provides a comparative evaluation summary of the remedial alternatives based on the following criterion: overall protection, compliance with ARARs, long- and short-term effectiveness, reduction in TMV, implementability, and cost. (For a summary of criteria for each alternative and the basis for this comparative evaluation discussion, see Table 5-1.). 6.1 6.1.1 Threshold Criteria Overall Protection of Human Health and the Environment Alternative 1 does not meet the threshold criterion for overall protection of human health and the environment. Thus, it was excluded from further consideration in this comparative evaluation. Preliminary model predictions conducted for this FS indicate that Alternative 2 is uncertain as to whether it can achieve overall protection of human health and the environment. Alternative 2 is estimated (albeit with some uncertainty, as described in Appendix E) to achieve the PCB surface water RAO throughout the Site after 9 to 19 years through natural recovery; however, benthic risk may not be reduced to acceptable levels across the entire Site within a reasonable time frame, as described in Appendix A. Alternatives 3 and 4 provide for protection of human health and the environment through combinations of natural recovery, treatment, and capping. Alternatives 3 and 4 are expected to meet the PCB surface water RAO within about 6 years after construction (Appendix A). Alternative 3 is estimated to reduce aquatic-dependent wildlife and benthic risks to acceptable levels in SMAs within less than 3 years following construction and MNR areas within 10 years. Alternative 4 would remove exposure pathways to benthos and wildlife in SMAs immediately after construction, but it requires a much longer period for habitat recovery than Alternative 3 due to time required for sedimentation and recolonization in areas treated with ACBM. Thus, recovery of benthic habitat would take much longer across significant portions of the Site (15.3 acres) under Alternative 4 than under Alternative 3. Feasibility Study Report Patrick Bayou Superfund Site 90 March 2017 040284-01.08 Comparative Analysis of Alternatives 6.1.2 Compliance with ARARs Alternative 2 is uncertain in regards to natural recovery’s ability to meet the PCB surface water RAO; although recent surface water sampling data indicate reductions in PCB concentrations that, if this trend continues, would achieve the PCB surface water RAO throughout the Site within 9 to 19 years. Because Alternative 2 does not entail active construction in Patrick Bayou, other ARAR compliance is expected to be more straightforward than for Alternatives 3 and 4. Alternatives 3 and 4 are both expected to comply with ARARs. Implementation of Alternative 3 or 4 would require the use of BMPs to protect surface water quality during construction and conform to substantive requirements of ARARs. Alternative 4 has a higher potential ecological impact than Alternative 3 because it potentially requires the use of a larger ACBM cap; as such, implementation of Alternative 4 could trigger a need for mitigation for loss of shallow-water habitat, which would significantly increase the cost and time frame for this alternative. 6.2 6.2.1 Balancing Criteria Long-term Effectiveness Alternative 2 ranks uncertain for long-term effectiveness. Based on modeling conducted for the FS, the PCB surface water RAO may not be fully achieved across the Site until more than 19 years under natural recovery alone. In one location (PB-032, Table 4-1), it is estimated that more than 50 years of natural recovery would be required before benthic risk is reduced to acceptable levels based on empirical model projections (Appendix A). Alternative 3 and Alternative 4 rank the highest for long-term effectiveness. Both are predicted to meet the PCB surface water RAO throughout the Site within about 6 years following remedy construction based on the results of the modeling presented in Appendix A. Residual aquatic-dependent wildlife and benthic risk is projected to be reduced to acceptable levels within less than 3 years under Alternative 3, and this alternative is highly compatible with adaptive management options that allow for future actions to be taken to ensure the long-term effectiveness of the remedy. Under Alternative 4, benthic risk is reduced to acceptable levels in SMAs following completion of construction because the Feasibility Study Report Patrick Bayou Superfund Site 91 March 2017 040284-01.08 Comparative Analysis of Alternatives exposure pathway between benthos and sediment is predicted to be blocked; however, benthic recovery would require a longer time period under Alternative 4 because new sediment input would be needed to improve the habitat substrate on the surface of the ACBM cap. Finally, Alternative 4 provides fewer opportunities to implement adaptive management actions in capped areas because the ACBM cap is a relatively permanent structure. 6.2.2 Reduction of Toxicity, Mobility, or Volume Alternative 2 does not include additional measures to reduce TMV beyond the natural sedimentation processes that are expected to reduce the mobility of impacted surface sediments and continued attenuation of the source of PCBs to the water column. Alternatives 3 and 4 include a treatment layer (granular AC within a RCM) below the armored cap in SMA-1, which will sequester PCBs and is expected to reduce near-surface porewater concentrations by 99.8 percent over 100 years where the RCM is used. Alternative 3 provides additional treatment of contaminants in benthic risk SMAs through the use of in situ treatment, which, based on case studies, could be expected to reduce PCB concentrations in surface sediment porewater by up to 99 percent or more and reduce bioavailability by at least 90 percent. Because of the additional treatment provided under Alternative 3, it ranks higher than Alternative 4 for reduction of TMV. 6.2.3 Short-term Effectiveness Alternative 2 ranks uncertain for short-term effectiveness. Although there are no active construction activities and the work is limited to sample collection for MNR monitoring (and thus short-term environmental impacts, community impacts, and health and safety impacts are negligible), the time frame to meet the PCB surface water RAO is estimated to be about 9 to 19 years, and the time frame for benthic risk to reach acceptable levels could be unacceptable across some parts of the Site. Both estimates are subject to the uncertainty associated with the analytical models used for these predictions. Alternative 3 ranks higher than Alternative 4 for short-term effectiveness, and both rank higher than Alternative 2 for the following reasons: • They achieve the PCB surface water RAO within about 6 years after construction. Feasibility Study Report Patrick Bayou Superfund Site 92 March 2017 040284-01.08 Comparative Analysis of Alternatives • They achieve aquatic-dependent wildlife and benthic risks reduction either within about 3 years (Alternative 3) or within about 10 years (Alternative 4) to allow for sediment deposition to create a suitable habitat substrate in the surface of the ACBM cap. Alternatives 3 and 4 cause disturbance along Patrick Bayou at the top of the bank to facilitate ACBM anchoring; however, under Alternative 4, this disturbance is much more widespread. Based on estimated environmental impacts, as reflected by equipment operation hours and truck trips, the impacts from Alternative 4 are estimated to be essentially the same as Alternative 3. Alternative 3 has a slightly higher potential for water quality impacts than Alternative 4 because it entails mixing of a treatment reagent into surface sediments. However, if surficial application of AC is used for treatment in lieu of mixing, turbidity would be greatly reduced. The risk of health and safety impacts, as reflected by potential lost time injuries or fatalities, is also comparable between Alternative 3 and Alternative 4. Because the potential short-term impacts are relatively lower for Alternative 3 (specifically considering the benthic disturbance following construction), it ranks higher than Alternative 4 for short-term effectiveness. 6.2.4 Implementability Alternative 2 ranks highest for implementability. Benthic, water, and sediment sample collection have been performed at the Site successfully with negligible impact to ongoing operations, using relatively straightforward techniques. Because there is no active construction, there are no implementability concerns such as site access for Alternative 2. Alternative 3 ranks comparably to Alternative 4 for implementability. Placement of an ACBM cap over approximately 1.6 acres in SMA-1 under both alternatives is considered technically feasible for an experienced contractor, albeit with similar implementability challenges associated with working adjacent to active production facilities as described in Section 5. Although the use of ACBM requires less experienced contractor personnel and more traditional construction equipment compared to the specialized equipment that might be needed to implement treatment in SMA-2 through SMA-9, capping could trigger the need Feasibility Study Report Patrick Bayou Superfund Site 93 March 2017 040284-01.08 Comparative Analysis of Alternatives for excavation to maintain flood capacity (see Section 4)—exacerbating implementability and offsetting any advantage of the more traditional construction approach. 6.2.5 Cost Alternative 2 is the lowest cost alternative, with an estimated cost of $710,000 NPV. Alternative 3 is estimated to cost approximately $6.7 million NPV, a factor of more than 8 times greater than Alternative 2. Alternative 4 is estimated to cost approximately $13.0 million NPV, a factor of more than 18 times greater than Alternative 2 and nearly 2 times greater than Alternative 3. While Alternative 2 has the lowest cost, there is some uncertainty around the analytic modeling used to assess Alternative 2 that would not be confirmed until pre-design sampling. For the remedies that include active construction, Alternative 3 is more cost-effective than Alternative 4, as defined under both CERCLA and the NCP, which require that remedies be cost-effective (42 U.S.C. §9621(a); 40 CFR §300.430(f)(1)(ii)(D)). Alternative 3 effectively and permanently reduces risk in a cost-effective manner when compared to Alternative 4. With a similar restoration time frame compared to Alternative 3, Alternative 4 does not provide any material incremental risk reduction and is less compatible with future adaptive management actions than Alternative 3. 6.3 Summary of Comparative Evaluation Table 6-1 presents a comparison matrix providing a qualitative ranking of Alternatives 2, 3, and 4 using a the terms “least favorable,” “middle,” and “most favorable” to indicate each alternative’s rank relative to the others for a particular criterion. An additional ranking, “uncertain,” is included to indicate that RI/FS evaluations are not sufficient to compare the alternative relative to the others until pre-design baseline sampling data are collected. These qualitative rankings are based on the discussion provided in Sections 6.1 and 6.2 and detailed considerations described in Section 5 and presented in Table 5-1. In some cases, alternatives are ranked the same for a particular criterion. Note that Table 6-1 does not consider State or community acceptance, which are considered by USEPA during preparation of the proposed plan for the Site. Feasibility Study Report Patrick Bayou Superfund Site 94 March 2017 040284-01.08 Comparative Analysis of Alternatives As shown in Table 6-1, and based on the data available at the time of the FS, Alternative 3 ranks higher overall compared to Alternative 4 when compared directly. Alternative 3 also provides for higher certainty of outcome than Alternative 2. Feasibility Study Report Patrick Bayou Superfund Site 95 March 2017 040284-01.08 7 REFERENCES Alcoa 2010. Activated Carbon Pilot Study, Grasse River, NY. Summary of 2006 to 2009 Monitoring Results. November 1, 2010. Anchor (Anchor Environmental, L.L.C.), 2005. Public Review Draft Engineering Analysis/Cost Evaluation, Removal Action NW Natural “Gasco” Site. Prepared for submittal to the USEPA, Region 10. May 2005. Anchor, 2006. Preliminary Site Characterization Report. 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Biological Responses to Activated Carbon Amendments in Sediment Remediation. Environmental Science & Technology 2013:47:14. Feasibility Study Report Patrick Bayou Superfund Site 98 March 2017 040284-01.08 References ITRC (Interstate Technology & Regulatory Council), 2014. Contaminated Sediments Remediation Guidance Document. Prepared by The Interstate Technology & Regulatory Council Contaminated Sediments Team. August 2014. Kleiner, D.J., 2013. Deer Park, TX. Handbook of Texas Online. Published by the Texas State Historical Association. Website. Updated: June 12, 2010. Cited: March 10, 2013. Available from: http://www.tshaonline.org/handbook/online/articles/hed02. Konechne, T., C. Patmont, and V. Magar, 2010. Tittabawassee River Cleanup Project Overview. Presented at USEPA/USACE/SMWG Joint Sediment Conference. April 2010. Laird, P.K., 2008. Phase I Cultural Resource Investigations for the Deer Park LPG Terminal Project in Chambers and Harris Counties, Texas. Prepared for Oxy LPG LLC. October 2008. Long, E.R., C.G. Ingersoll, and D.D. MacDonald, 2006. Calculation and Uses of Mean Sediment Quality Guideline Quotients: A Critical Review. Environmental Science & Technology 40:1726-1736. Mackay D., W.Y. Shiu, and K.C. Ma, 1992. Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals. Volume 1. Monoaromatic Hydrocarbons, Chlorobenzenes, and PCBs. Lewis Publishers. Magar, V.S., D.B. Chadwick, T.S. Bridges, P.C. Fuchsman, J.M. Conder, T.J. Dekker, J.A. Steevens, K.E. Gustavson, and M.A. Mills, 2009. Technical Guide: Monitored Natural Recovery at Contaminated Sediment Sites. ESTCP Project ER-0622. May 2009. Menzie, C.A., 2012. Sedimite®A Delivery System for Amending Contaminated Sediment with Activated Carbon and/or other Amendments. Prepared for Lower Duwamish Waterway Workshop. February 2012. Merrick (Merrick & Company), 2008. Houston-Galveston Area Council (H-GAC) LiDAR Data Services, LiDAR Mapping Report. Prepared for H-GAC. October 2008. NOAA (National Oceanic and Atmospheric Administration), 2006. Website. Available from: Feasibility Study Report Patrick Bayou Superfund Site 99 March 2017 040284-01.08 References http://tidesandcurrents.noaa.gov/station_info.shtml?stn=8770777%20Manchester,%20 TX. NOAA, 2012. National Coastal Zone Management Program Fact Sheet. Prepared by NOAA’s Office of Ocean and Coastal Resources Management. Updated: April 2012. Available from: http://coastalmanagement.noaa.gov/resources/docs/czmfactsheet.pdf. Norwegian Research Council, 2011. Sediment Remediation Through Activated Carbon Amendment; Long Term Monitoring of a Field Pilot in Trondheim Harbour. Norwegian Geotechnical Institute Report No. 20081057-1. Gerard Cornelissen Project Leader. Available from: http://sveinerik.me/images/print/pdf/Sediment_RTACA.pdf. NRC (National Research Council), 2007. Sediment Dredging at Superfund Megasites – Assessing the Effectiveness. Washington, DC: National Academy Press. Patmont, C., and M. Palermo, 2007. Case Studies of Environmental Dredging Residuals and Management Implications. Paper D-066, in: Remediation of Contaminated Sediments—2007, Proceedings of the Fourth International Conference on Remediation of Contaminated Sediments. Savannah, Georgia. January 2007. Patmont, C., S. Nadeau, and M. McCulloch, 2013. Learning from the Past to Enhance Remedy Evaluation, Selection, and Implementation. Presented at the Battelle International Conference on Remediation of Contaminated Sediments. February 2013. Patmont, C., U. Ghosh, P. LaRosa, C. Menzie, R. Luthy, M. Greenberg, G. Cornelissen, E. Eek, J. Collins, J. Hull, T. Hjartland, E. Glaza, J. Bleiler, and J. Quadrini, 2015. In Situ Sediment Treatment Using Activated Carbon: A Demonstrated Treatment Technology. Integrated Environmental Assessment and Management 11(2):195-207. PHA (Port of Houston Authority), 2011. Port of Houston Authority Self-Evaluation Report. September 2011. Rifai, H., 2006. Total Maximum Daily Loads for Dioxins in the Houston Ship Channel. Quarterly Report No. 3. Available from: http://www.tceq.state.tx.us/assets/public/waterquality/tmdl/26hscdioxin/26-all-datacompiled-q3-fy06.pdf. Feasibility Study Report Patrick Bayou Superfund Site 100 March 2017 040284-01.08 References Rifai, H., and R. Palacheck, 2006, 2007, 2008, 2009, 2010. Total Maximum Daily Loads for PCBs in the Houston Ship Channel. Quarterly Reports 1, 2, 3, 4, and 5. Available from: http://m.tceq.texas.gov/waterquality/tmdl/78-hsc-pcbs.html. TCEQ (Texas Commission on Environmental Quality), 2013. Houston-Galveston-Brazoria: Current Attainment Status. Available from: http://www.tceq.texas.gov/airquality/sip/hgb/hgb-status. TCEQ, 2016. Letter to Philip Allen, Remedial Project Manager, USEPA Region 6. Regarding: The JDG’s Response to EPA and TCEQ via letter dated September 22, 2015. January 12, 2016. Texas Land Grant Office, 2013. Record of land grant to G.M. Patrick, 1838, abstract number 624, File number 000009. Available from: http://www.glo.texas.gov/ncu/SCANDOCS/archives_webfiles/arcmaps/webfiles/landg rants/PDFs/2/3/2/232641.pdf. USACE (U.S. Army Corps of Engineers), 2008a. The 4 Rs of Environmental Dredging: Resuspension, Release, Residuals, and Risk. ERDC/EL TR-08-4. U.S. Army Corps of Engineers. January 2008. USACE, 2008b. Technical Guidelines for Environmental Dredging of Contaminated Sediments. U.S. Army Corps of Engineers publication ERDC/EL TR-08-29. September 2008. U.S. Census Bureau, 2010. 2010 Census Data Products: United States. Available from: http://www.census.gov/population/www/cen2010/glance/. USCG (U.S. Coast Guard), 2013. Website. Security Zones for Houston, Galveston, and Texas City. Available from: http://www.uscg.mil/vtshouston/docs/SECZONE8_5x14.pdf. USDL (U.S. Department of Labor), 2011. OSHA Recordable Case Rates and Census of Fatal Occupational Injuries. U.S. Department of Labor, Bureau of Labor Statistics. USEPA (U.S. Environmental Protection Agency), 1988. Guidance for Conducting Remedial Investigations and Feasibility Studies under CERCLA. U.S. Environmental Protection Agency, Office of Emergency and Remedial Response, Washington, DC. Feasibility Study Report Patrick Bayou Superfund Site 101 March 2017 040284-01.08 References USEPA, 1996. Soil Screening Guidance: User's Guide. Second Edition, EPA/540/R-96/018. Office of Emergency and Remedial Response, U.S. Environmental Protection Agency, July 1996. USEPA, 1998. Guidance for In-Situ Subaqueous Capping of Contaminated Sediments. Assessment and Remediation of Contaminated Sediments (ARCS) Program. EPA 905B96-004. September 1998. USEPA, 2000. Bioaccumulation Testing And Interpretation For The Purpose Of Sediment Quality Assessment. EPA-823-R-00-001. February 2000. USEPA, 2005. Contaminated Sediment Remediation Guidance for Hazardous Waste Sites. Office of Solid Waste and Emergency Response (OSWER) 9355.0-85. December 2005. USEPA, 2006. Email from USEPA Phil Allen to Project Navigator Bob Piniewski approving the use of the Adaptive Management Approach to Patrick Bayou. June 7, 2006. USEPA, 2007. Monitored Natural Attenuation of Inorganic Contaminants in Ground Water, Volume 2. Assessment for Non-Radionuclides Including Arsenic, Cadmium, Chromium, Copper, Lead, Nickel, Nitrate, Perchlorate, and Selenium. EPA/600/R-07/140. Cincinnati, Ohio: Office of Research and Development. USEPA, 2009. USEPA Region 6 Clean and Green Policy. September 1, 2009. USEPA, 2012. Institutional Controls: A Guide to Planning, Implementing, Maintaining, and Enforcing Institutional Controls at Contaminated Sites, OSWER Directive 9355.0-89. December 2012. Van den Berg, M, L. Birnbaum, M. Denison, M. DeVito, W. Farland, M. Feeley, H. Fiedler, H. Hakansson, A. Hanberg, L. Haws, M. Rose, S. Safe, D. Schrenk, C. Tohyama, A. Tritscher, J. Tuomisto, M. Tysklind, N. Walker, and R. Peterson, 2006. The 2005 World Health Organization Re-evaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-Like Compounds. Toxicological Sciences 93(2):223-241. Wolfe, M.F., S. Schwarzbach, and R.A. Sulaiman, 1998. Effects of Mercury on Wildlife: A Comprehensive Review. Environmental Toxicology and Chemistry 17:146-160. Feasibility Study Report Patrick Bayou Superfund Site 102 March 2017 040284-01.08 Table 2-2 Summary Statistics for Houston Ship Channel Background Dataset Number of Chemical Total PCB PCDD/PCDF TEQs Units ng/L ng/L Number a Minimum Value b Samples Excluded 38 30 2 0 0.4 9.1E-05 Maximum Value Average 12.5 1.8E-03 3.7 5.1E-04 Standard Deviation 2.4 3.9E-04 Best Fit Distribution Gamma Normal 95 Percent Upper Probability Limit 8.2 1.2E-03 Methodc 95% Wilson Hilferty (WH) Approx. Gamma UPL 95% UPL (t) Notes: a - Duplicate and normal sample results are averaged. Shallow and deep sample results are averaged. b - Data from station 15936 at mouth of Patrick Bayou are excluded. c - As determined using ProUCL Version 5.0 (http://www.epa.gov/osp/hstl/tsc/software.htm) ng/L = nanograms per liter PCB = polychlorinated biphenyl PCDD/PCDF - polychlorinated dibenzodioxins / polychlorinated dibenzofurans TEQ - toxic equivalents (based on Texas Surface Water Quality Standard toxic equivlancy factors) UPL (t) = normal upper probability limit Feasibility Study Report Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Table 2-3 Fate and Transport Chemical Properties of Indicator Chemicals Indicator Chemical Polychlorinated Biphenyl Compounds (PCBs) Aroclor 1248 PCB-209 Tri-substituted PCBs Tetra-substituted PCBs Penta Polycyclic Aromatic Hydrocarbons (PAHs) Acenaphthene Anthracene Chemical Abstracts Service Number Water Solubility (milligrams/liter) Value or Range Biodegradation Rate (half life, days) Aerobic Anaerobic Partition Coefficient* (liters/kilogram) Source Value or Range Source Value or Range Not Available Not Available 12672-29-6 2051-24-3 4.30E-02 7.43E-06 - 3.20E-01 6.32E-05 5. 5. 3.16E+04 4.41E+05 - 7.66E+04 Koc 1.63E+06 Koc 13. 13. 25323-68-6 3.91E-01 - 4.00E-01 5. 1.38E+04 - 4.86E+04 Koc 13. 1.32E+05 Koc 1.00E+00 13. LWG 4 26914-33-0 25429-29-2 1.50E-02 - 8.60E-02 5. 2.74E+04 5.6 - 6.8 - 2 Source Value or Range Source Not Available Not Available 6 8.C Not Available - 56 C 8. Not Available 9. 9. 6.D 9. 6.D 4 200 - 28 1,840 408 228 - 2,720 2,120 - 83-32-9 120-12-7 3.57E+00 4.34E-02 7. 9. 3.89E+03 1.58E+04 Koc Koc 7. 7. 1 50 - 7 460 Benzo(a)anthracene Benzo(a)pyrene 56-55-3 50-32-8 9.40E-03 1.62E-03 9. 7. 2.00E+05 5.07E+06 Koc Koc 7. 7. 102 57 - 680 530 Benzo(b)fluoranthene 205-99-2 1.50E-03 9. 1.56E+05 Koc 7. 360 - 610 1,440 - 2,440 9. 9. 6.D 9. 6.D D Benzo(k)fluoranthene 207-08-9 8.00E-04 9. 2.20E+04 Koc 7. 910 - 2,140 6. 3,640 - 8,560 6.D Chrysene 218-01-9 1.60E-03 9. 1.33E+05 Koc 7. 371 - 1,000 6.D 1,484 - 4,000 6.D Dibenz(a,h)anthracene 53-70-3 2.49E-03 9. 3.80E+06 Koc 9. 361 - 940 6.D 440 D 6. 1,760 6.D 128 240 Not Available NOD NOD 6.D Fluoranthene 206-44-0 2.06E-01 9. 4.20E+04 Koc 7. 140 Fluorene lndeno(1 ,2,3-cd)pyrene Naphthalene 86-73-7 193-39-5 91-20-3 1.98E+00 2.20E-05 3.10E+01 9. 9. 9. 1.38E+04 1.60E+06 8.70E+02 Koc Koc Koc 9. 7. 7. 32 60 Not Available 0.2 17 Pyrene Other Organic Indicator Chemicals Bis(2-ethylhexyl)phthalate Inorganic Indicator Chemicals 129-00-0 1.35E-01 9. 1.05E+05 Koc 9. 210 - 1,900 7. 6.D 117-81-7 3.40E-01 9. 8.74E+04 Koc 7. 5 - 23 9. 7439-97-6 5.60E-02A 14. 3.98E+03 kd 11. Not applicable Not applicable 12. 5.01E+03 kd 11. Not applicable Not applicable Mercury Lead 7439-92-1 Polychlorinated dibenzodioxins & Polychlorinated dibenzofurans (PCDDs & PCDFs) PCDDs <0.05 (pH >7) A - Not Available 6.D 560 - 840 - 7,600 7. 6.D 41 - 389 9. Total Tetrachlorodibenzo -p-dioxin (TCDD) 41903-57-5 3.5E-04 13. 7.9E+04 - 2.5E+05 Koc 13. 360 13.F 1,621 13.F Total Pentachlorodibenzo-p -dioxin (PeCDD) 36088-22-9 1.2E-04 13. 3.6E+04 - 4.3E+05 Koc 13. 360 13.F 1,621 13.F F Total Hexachlorodibenzo -p-dioxin (HxCDD) Total Heptachlorodibenzo -p-dioxin (HpCDD) 1,2,3,4,6,7,8,9-0ctachlorodibenzo-p-dioxin (OCDD) PCDFs 34465-46-8 37871-00-4 3268-87-9 4.0E-06 2.4E-06 1.4E-06 4.0E-07 13. 13. 13. 4.1E+05 3.1E+05 4.0E+05 - 7.0E+05 1.2E+06 1.9E+06 Koc Koc Koc 13. 13. 13. 360 360 360 13. 13.F 13.F 1,621 1,621 1,621 13.F 13.F 13.F Total Tetrachlorodibenzofuran (TCDF) 55722-27-5 3.7E-03 3.1E-02 13. 3.5E+04 - 1.5E+05 Koc 13. 360 13.F 1,621 13.F Total Pentachlorodibenzofuran (PeCDF) Total Hexachlorodibenzofuran (HxCDF) Total Heptachlorodibenzofuran (HpCDF) 1,2,3,4,5,6,7,8-0ctachlorodibenzofuran (OCDF) 30402-15-4 55684-94-1 38998-75-3 39001-02-0 1.3E-03 1.1E-04 6.9E-03 1.6E-03 1.4E-06 1.2E-06 13. 13. 13. 13. 5.2E+04 1.8E+05 2.8E+05 6.7E+05 - 2.4E+05 4.0E+05 6.5E+05 1.1E+06 Koc Koc Koc Koc 13. 13. 13. 13. 360 360 360 360 13.F 13.F 13.F 13.F 1,621 1,621 1,621 1,621 13.F 13.F 13.F 13.F Feasibility Study Report Patrick Bayou Superfund Site - 1 March 2017 040284-01.08 Table 2-3 Fate and Transport Chemical Properties of Indicator Chemicals Notes * A. B. C. D. E. F. Partition Coefficients are the ratio of the concentration adsorbed to the solid medium (in milligrams of constituent/kilogram of solid) to the concentration in water (in milligrams of constituent/liter of water). The resulting units for Kd or Koc are liters/kilogram. For organic indicator chemicals, partitioning coefficients are adjusted for organic carbon content (Koc). NOD - No observed degradation Solubility of metals in water is highly dependent on water chemistry, which affects the speciation of the metal. Mercury solubility is controlled by the presence of sulfide radicals and organic matter (Source 2). Lead is reported as insoluble in Half life in sediment for PCBs generally. Degradation rates for individual congeners varies widely. Half life values calculated from data presented in source. Half lives converted from values given in hours. Aerobic degradation half lives measured in vadose-zone soil; anaerobic half lives measured in water. Half lives converted from values given in hours. Degradation half lives measured in water. Half lives converted from values given in hours. Aerobic degradation half lives are for soil; anaerobic half lives are for sediment. Sources 1. Alvarez, P. J. and W. Illman, 2006. Bioremediation and Natural Attenuation: Process Fundamentals and Mathematical Models, Wiley. 2. Bessinger, et al., 2012. Reactive Transport Modeling of Subaqueous Sediment Caps and Implications for the Long-Term Fate of Arsenic, Mercury, and Methylmercury. Aquatic Geochemistry Vol 18. 3. Davis, J., 2004. The long-term fate of polychlorinated Biphenyls in San Francisco Bay (USA). Environmental Toxicology and Chemistry, Vol. 23, No. 10, p. 2306. 4. Duinker, 1986. Role of Small Low Density Particulates on the Partition of Selected PCBs. 5. Mackay, D., W Shiu, K. Ma, 1992. Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals , Lewis. Volume I 6. Mackay, D., W. Shiu, K. Ma, 1992. Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals , Lewis. Volume II 7. SRC, Environmental Fate Data Base (http://www.syrres.com/what-we-do/databaseforms.aspx?id=381) 8. USEPA, 1983. Environmental Transport and Transformation of Polychlorinated Biphenyls, EPA 560/5-83-025. 9. USEPA, 1996. Soil Screening Guidance: User's Guide , Second Edition, EPA/540/R-96/018. Office of Emergency and Remedial Response, U.S. Environmental Protection Agency, July 1996. (solubility and Koc for PAHs, chlorinated hydrocarbons, 10. USEPA, 2000. Bioaccumulation Testing and Interpretation for the Purpose of Sediment Quality Assessment, Appendix: Chemical-Specific Summary Tables , EPA-823-R-00-002. February 2000. 11. USEPA, 2005. Partition Coefficients for Metals in Surface Water, Soil, and Waste . EPA/600/R-05/074. 12. USEPA, 2007. Monitored Natural Attenuation of Inorganic Contaminants in Ground Water, Volume 2. Assessment for Non-Radionuclides Including Arsenic, Cadmium, Chromium, Copper, Lead, Nickel, Nitrate, Perchlorate, and Selenium. 13. USEPA, 2016. Estimation Programs Interface Suite™ for Microsoft® Windows, v 4.11. United States Environmental Protection Agency, Washington, DC, USA. 14. USEPA, CLU-IN http://www.clu-in.org/contaminantfocus/default.focus/sec/mercury/cat/Chemistry_and_Behavior/ Feasibility Study Report Patrick Bayou Superfund Site 2 March 2017 040284-01.08 Table 3-1 Sediment Toxicity and Chemistry Lines of Evidence as Presented in the BERA 2002/2003 Benthic Toxicity Station Proportion Toxic Toxicity Classification 2002/2003 Mean PEL-Q V 2.5 0% Low 1.25 0% Low 1.37 S 0% Low 3.26 E 25% Low 1.98 U 0% Low 0.14 3 31% Indeterminate 7.56 G 25% Low 0.74 4A 54% Probable 56.12 5 25% Low 3.07 T 0% Low 1.53 6A 69% Probable 12.17 Q 25% Low 4.47* Notes: * Highest mean PEL-Q with low toxicity PEL-Q = Probable Effects Level-Quotient Feasibility Study Report Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Table 3-2 Potential ARAR Screening for Patrick Bayou Superfund Site, Feasibility Study Report Potential ARARs1 Citation Summary Comment Federal Clean Water Act (CWA): Criteria and standards for imposing technology-based treatment requirements under §§ 309(b) and 402 of the CWA CWA Sections 303 and 304: Federal Water Quality Criteria CWA Section 307(b): Pretreatment Standards 33 U.S.C. §§ 1319 and 1342 (implementing regulations at 40 CFR Part 125 Subpart A) Both on-site and off-site discharges from Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) sites to surface waters are required to meet the substantive CWA National Pollutant Discharge Elimination System (NPDES) requirements (USEPA 1988). On-site discharges must comply with the substantive technical requirements of the CWA but do not require a permit (USEPA 1988). Off-site discharges would be regulated under the conditions of a NPDES permit (USEPA 1988). Standards of control for direct discharges must meet technology-based requirements. Best conventional pollution control technology (BCT) is applicable to conventional pollutants. Best available technology economically achievable (BAT) applies to toxic and non-conventional pollutants. 33 U.S.C. §§1313 and 1314 (Most recent 304(a) list as updated to issuance of Record of Decision [ROD]) 33 U.S.C. §1317(b) Under §303 (33 U.S.C. §1313), individual states have established water quality standards to protect existing and attainable uses (USEPA 1988). CWA §301(b)(1)(C) requires that pollutants contained in direct discharges be controlled beyond BCT/BAT equivalents (USEPA 1988). CERCLA §121(d)(2)(B)(i) establishes conditions under which water quality criteria, which were developed by U.S. Environmental Protection Agency (USEPA) as guidance for states to establish location-specific water quality standards, are to be considered relevant and appropriate. Two kinds of water quality criteria have been developed under CWA §304 (33 U.S.C. §1314): one for protection of human health, and another for protection of aquatic life. These requirements include establishment of total maximum daily loads (TMDL). CERCLA §121(e) states that no federal, state, or local permit for direct discharges is required for the portion of any removal or remedial action conducted entirely on site (the aerial extent of contamination and all suitable areas in close proximity to the contamination necessary for implementation of the response action; USEPA 1988). For CERCLA sites, BCT/BAT requirements are determined on a case-by-case basis using best professional judgment. This is likely to be a potential requirement only if treated water or excess dredge water is discharged during implementation. The Feasibility Study (FS) considers the ability of remedial alternatives to satisfy established water quality criteria. Best management practices (BMPs) would be established for remedial actions and applied during construction. Water quality would also be monitored during construction, and additional BMPs may be implemented if necessary to protect water quality. Where water quality state standards contain numerical criteria for toxic pollutants, appropriate numerical discharge limitations may be derived for the discharge and considered (USEPA 1988). Where state standards are narrative, either the whole-effluent or chemical-specific approach may generally be used as a standard of care (USEPA 1988). If off-site discharges from a CERCLA response activity were to enter receiving waters directly or indirectly, through treatment at a Publicly Owned Treatment Works (POTWs), they must comply with applicable Federal, State, and Local substantive requirements and formal administrative permitting requirements (USEPA 1988). This requirement may be triggered by disposal methods for waste. Based on the current set of proposed alternatives, none of the alternatives involve discharge to a POTW; therefore, this regulation is not likely to be applicable. 1 ARARs are Applicable or Relevant and Appropriate Requirements of Federal or state environmental laws and state facility siting laws. CERCLA section 121(d) requires that remedial actions generally comply with ARARs. The USEPA has stated a policy of attaining ARARs to the greatest extent practicable on remedial or removal actions (USEPA 1988). USEPA also stated that certain nonpromulgated Federal and state advisories or guidelines would be considered in selecting remedial or removal actions; these guidelines are referred to as TBCs, or “to be considered.” Feasibility Study Report Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Table 3-2 Potential ARAR Screening for Patrick Bayou Superfund Site, Feasibility Study Report Potential ARARs1 Citation 33 U.S.C. §1341 Summary Requires applicants for Federal permits for projects that involve a discharge into navigable waters of the United States to obtain certification from state or regional regulatory agencies that the proposed discharge will comply with CWA Sections 301, 302, 303, 306, and 307. CWA Section 404 and 404(b)(1): Dredge and Fill 33 U.S.C. §1344 (b)(1) (implementing regulations at 33 CFR 320 and 330; 40 CFR 230) Discharges of dredged and fill material into waters of the United States must comply with the CWA §404 (33 U.S.C. 1344) guidelines and demonstrate the public interest is served (USEPA 1988). Safe Drinking Water Act 42 U.S.C. §300f (implementing regulations at 40 CFR Part 141, et seq.) Federal Drinking Water Regulations (Primary and Secondary Drinking Water Standards)2 40 CFR 141 and Part 143 The Safe Drinking Water Act is applicable to public drinking water sources at the point of consumption (“at the tap”). Maximum contaminant levels (MCLs) have been established for certain constituents to protect human health and to preserve the aesthetic quality of public water supplies. USEPA has established two sets of drinking water standards: one for protection of human health (primary) and one to protect aesthetic values of drinking water (secondary) (USEPA 1988). MCLs are applicable to public drinking water sources at the point of consumption. Resource Conservation And Recovery Act (RCRA): Hazardous Waste Management 42 U.S.C. §§6921 et seq. (implementing regulations at 40 CFR Parts 260 – 268) RCRA: General Requirements for Solid Waste Management 42 U.S.C. §§6941 et seq. (implementing regulations at 40 CFR 258) Toxic Substances Control Act (TSCA) 15 USC §2601 et. seq. (implementing regulations at 40 CFR 761) CWA Section 401: Water Quality Certification 2 RCRA is intended to protect human health and the environment from the hazards posed by waste management (both hazardous and nonhazardous). RCRA also contains provisions to encourage waste reduction. RCRA Subtitle C and its implementing regulations contain the Federal requirements for the management of hazardous wastes. Requirements for construction for municipal solid waste landfills that receive RCRA Subtitle D wastes, including industrial solid waste. Requirements for runon/run-off control systems, groundwater monitoring systems, surface water requirements, etc. Potentially applicable to polychlorinated biphenyl (PCB)-contaminated sediment or surface water. Requires remedial action of certain PCB releases depending on the concentration of the source material and the date of the release (or the as-found concentration for releases where the date is undetermined). Disposal and treatment requirements are also specified for environmental media if removed depending on total PCB concentrations. Comment Proposed activities that are on site would not require a Federal permit. Therefore, certification is not legally required for on-site actions. Certification would be required for off-site actions. For on-site or off-site actions, certification should occur as part of the state identification of substantive state ARARs (USEPA 1988). Compliance with water quality criteria is discussed under CWA Sections 303 and 304. Patrick Bayou is a water of the United States (USEPA 2007). Dredge and fill permits are applicable to dredging, in-water disposal, capping, construction of berms or levees, stream channelization, excavation and/or dewatering within waters of the United States (USEPA 1988). Permits are not required, however, for on-site CERCLA actions. Under the 404(b)(1) guidelines, efforts should be made to avoid, minimize, and mitigate adverse effects on the waters of the United States, and, where possible, select a practicable (engineering feasible) alternative with the least adverse effects. The substantive requirements of Section 404 will be considered in the development and evaluation of remedial alternatives to minimize adverse impacts to waters of the United States. Safe Drinking Water Act standards are applicable to public drinking water sources. Patrick Bayou does not supply public drinking water and does not recharge an aquifer used to supply drinking water. Therefore, the Safe Drinking Water Act is not applicable. Safe Drinking Water Act standards are applicable to public drinking water sources. Patrick Bayou does not supply public drinking water and does not recharge an aquifer used to supply drinking water. Therefore, the Safe Drinking Water Act is not applicable. This requirement would apply to certain activities if the affected sediments contain RCRA-listed hazardous waste or exhibit a hazardous waste characteristic. RCRA requirements are applicable only if waste is managed (treated, stored, or disposed of) after effective date of RCRA requirement under consideration, or if CERCLA activity constitutes treatment, storage, or disposal as defined by RCRA. This requirement would be relevant only if a landfill was constructed for the disposal of nonhazardous solid waste. There are no specific Federal requirements for non-hazardous waste management; state regulations provide specific applicable requirements for siting, design, permitting, and operation of landfills. Total PCB concentrations in limited areas of the Site may exceed the regulatory threshold (50 mg/kg, calculated as specified in 40 CFR 761) that would require remedial action and may trigger certain requirements for waste management. TSCA regulations may be insignificant relative to other bases for remedial action. No sediment samples contain total PCB concentrations that would trigger TSCA requirements for disposal by incineration. Underground injection is not anticipated as a part of the potential remedial action. Furthermore, the site is not located in a sole-source aquifer (USEPA 2008). It is also assumed that no wellhead protection area is located near the study area. Feasibility Study Report Patrick Bayou Superfund Site 2 March 2017 040284-01.08 Table 3-2 Potential ARAR Screening for Patrick Bayou Superfund Site, Feasibility Study Report Potential ARARs1 Clean Air Act (CAA) Citation 42 U.S.C. §§7401 et seq. Summary Would apply if dredging and/or excavation activities generate air emissions sufficient to require a permit: greater than 10 tons of any pollutant per year under the CAA operational permit (USEPA 2009). Controls the alteration of navigable waters (i.e., waters subject to ebb and flow of the tide shoreward to the mean high water mark). Activities controlled include construction of structures such as piers, berms, and installation of pilings as well as excavation and fill. Section 10 may be applicable for any action that may obstruct or alter a navigable waterway. Comment None of the remedial alternatives would trigger an operational permit. This requirement is not relevant as there are no Federally listed threatened or endangered (T&E) species or critical habitat present at the site. U.S. Fish and Wildlife Service (USFWS) and National Marine Fisheries Service (NMFS) maps, aerial imagery, and photographs of the site were reviewed to determine that there is no critical habitat is present at the site. Some protected species may be present downstream in the Houston Ship Channel vicinity. Pursuant to CERCLA 121(e) and USEPA policy, USEPA will consult with the USFWS and NMFS and no permits are required. Applicable to any action that controls or modifies a body of water. Rivers And Harbors Act of 1899: Obstruction of Navigable Waters (generally, wharves; piers, etc.); excavation and filling-in 33 U.S.C. §401 Endangered Species Act 16 U.S.C.§§ 1531 et seq. Federal agencies must ensure that actions they authorize, fund, or carry out are not likely to adversely modify or destroy critical habitat of endangered or threatened species. Actions authorized, funded, or carried out by federal agencies may not jeopardize the continued existence of endangered or threatened species as well as adversely modify or destroy their critical habitats. Fish and Wildlife Coordination Act 16 U.S.C. §§661 et seq.; 16 U.S.C. §742a; 16 U.S.C. § 2901 Bald and Golden Eagle Protection Act 16 U.S.C. §668a-d Migratory Bird Treaty Act 16 U.S.C.§§703-712 (implementing regulations at 50 CFR §10.12) Requires adequate provision for protection of fish and wildlife resources. This title has been expanded to include requests for consultation with USFWS for water resources development projects (Mueller 1980 ). Any modifications to rivers and channels require consultation with the USFWS, Department of Interior, and state wildlife resources agency.3 Project-related losses (including discharge of pollutants to waterbodies) may require mitigation or compensation. Makes it unlawful to take, import, export, possess, buy, sell, purchase, or barter any bald or golden eagle, nest, or egg. “Take” is defined as pursuing, hunting, shooting, poisoning, wounding, killing, capturing, trapping and collecting, molesting, or disturbing. Makes it unlawful to take, import, export, possess, buy, sell, purchase, or barter any migratory bird. “Take” is defined as pursuing, hunting, shooting, poisoning, wounding, killing, capturing, and trapping and collecting. Coastal Zone Management Act 16 USC §§1451 et seq. (implementing regulations at 15 CFR 930) Federal activities must be consistent with, to the maximum extent practicable, State coastal zone management programs (CZMPs). Federal agencies must supply the State with a consistency determination (USEPA 1989). 3 No permit is required for on-site activities. Construction activities will comply with substantive requirements. This requirement is potentially relevant to CERCLA activities. No readily available information suggests bald or golden eagles frequent the project area; however, a qualified biologist will perform a site visit prior to implementation of the remedial action to confirm that bald and golden eagles do not frequent the project area and would not be affected by construction activities. This requirement is relevant to CERCLA activities. No readily available information suggests migratory birds frequent the project area, and aerial photography of the site suggests no suitable nesting or stopover habitat is present; however, a qualified biologist will perform a site visit prior to implementation of the remedial action to confirm that migratory birds would not be affected by construction activities. Patrick Bayou lies within the Coastal Zone Boundary according to the Texas Coastal Management Plan (TCMP) prepared by the General Land Office (GLO). The FS considers whether the remedial alternatives would affect (adversely or not) the coastal zone, and the lead agency is required to determine whether the activity will be consistent with the State’s CZMP (USEPA 1989). More information regarding the state requirements is provided under Texas Coastal Coordination Council (TCCC) Policies for Development in Critical Areas. Texas Parks and Wildlife Department. Feasibility Study Report Patrick Bayou Superfund Site 3 March 2017 040284-01.08 Table 3-2 Potential ARAR Screening for Patrick Bayou Superfund Site, Feasibility Study Report Potential ARARs1 Citation 42 U.S.C. 4001 et seq. (implementing regulations at 44 CFR Chapter 1) Summary Prohibits alterations to river or floodplains that may increase potential for flooding. Comment This requirement is relevant because the project area is within a designated flood zone. An assessment of the potential impacts of remedial alternatives on the floodplain found that the remedial alternatives will not significantly impact flood storage capacity. Additional evaluation of hydraulic capacity will be performed as part of the remedial design. National Flood Insurance Program (NFIP) Regulations 42 U.S.C. subchapter III, §§4101 et seq. Title 40: Protection of the Environment - Statement of Procedures on Floodplain Management and Wetlands Protection 40 CFR Part 6 App. A; Executive Orders (EO) 11988 and 11990 Provides federal flood insurance to local authorities and requires that the local authorities not allow fill in the river that would cause an increase in water levels associated with floods. Requires federal agencies to conduct their activities to avoid, if possible, adverse impacts associated with the destruction or modification of wetlands and occupation or modification of floodplains. The EOs 11988 and 11990 require federal projects to avoid adverse effects and minimize potential harm to wetlands and within flood plains. An assessment of the potential impacts of remedial alternatives on the floodplain found that the remedial alternatives will not likely significantly impact flood storage capacity. Additional evaluation of hydraulic capacity will be performed as part of the remedial design. An assessment of the potential impacts of remedial alternatives on the floodplain found that the remedial alternatives will not likely significantly impact flood storage capacity. Additional evaluation of hydraulic capacity will be performed as part of the remedial design. FEMA (Federal Emergency Management Agency), Department of Homeland Security (Operating Regulations) Implementation of the remedial alternatives would not involve adverse impacts to wetlands. Minimal disturbance during construction would be temporary. The EO 11990 requires federal agencies to avoid to the extent possible the longand short-term adverse impacts associated with the destruction or modification of wetlands and to avoid direct or indirect support of new construction in wetlands wherever there is a practicable alternative (USEPA 1994). National Historic Preservation Act 16 U.S.C. §§ 470 et seq. (implementing regulations at 36 CFR 800) Noise Control Act 42 U.S.C. §§ 4901 et seq. (implementing regulations at 40 CFR Subchapter G §201 et seq.) 49 U.S.C. §§1801 et seq. (implementing regulations at 49 CFR Subchapter C) Hazardous Materials Transportation Act The agency also adopted a requirement that the substantive requirements of the Protection of Wetlands Executive Order must be met (USEPA 1994). Unavoidable impacts to wetlands must be mitigated (USEPA 1994).4 Section 106 of this statute requires Federal agencies to consider effects of their undertakings on historic properties. Historic properties may include any district, site, building, structure, or object included in or eligible for the National Register of Historic Places (NRHP), including artifacts, records, and material remains related to such a property. Noise Control Act remains in effect but unfunded (USEPA 2010). Establishes standards for packaging, documenting, and transporting hazardous materials. Because of the extensive disturbance to the site and minimal upland disturbance that will likely occur for the project, it is unlikely that NRHP-eligible historic properties will be affected by remedial activities. Noise is regulated at the state level. See Texas Penal Code under state ARARs. This requirement applies to the transportation of hazardous materials off site for treatment or disposal. The remedial alternatives involve transportation of minimal quantities of potentially hazardous materials off site in the form of debris that would be cleared prior to remedy implementation. 4 Each agency is expected to minimize the destruction, loss, or degradation of wetlands and to preserve and enhance the natural and beneficial values of wetlands when implementing actions such as CERCLA sites (President of the United States 1977). If §404 of the Clean Water Act is considered an ARAR, then the 404(b)(1) guidelines established in a Memorandum of Understanding (MOU) between USEPA and Department of Army should be followed (USEPA 1994). When habitat is severely degraded, a mitigation ratio of 1:1 may be acceptable (USEPA 1994). However, any mitigation would be at the discretion of the agency, and the USEPA may elect to orient mitigation towards “minimizing further adverse environmental impacts rather than attempting to recreate the wetlands original value on site or off site” (USEPA 1988). Feasibility Study Report Patrick Bayou Superfund Site 4 March 2017 040284-01.08 Table 3-2 Potential ARAR Screening for Patrick Bayou Superfund Site, Feasibility Study Report Potential ARARs Citation Summary Comment State 30 Texas Administrative Code (TAC) Part 1: Industrial Solid Waste and Municipal Hazardous Waste General Terms 30 TAC §§335.1 – 335.15 General Terms: Substantive requirements for the transportation of industrial solid and hazardous wastes; requirements for the location, design, construction, operation, and closure of solid waste management facilities. Guidelines to promote the proper collection, handling, storage, processing, and disposal of industrial solid waste or municipal hazardous waste in a manner consistent with the purposes of Texas Health and Safety Code, Chapter 361. Solid nonhazardous waste provisions are applicable if material is transported to an upland disposal facility. 30 TAC Part 1: Texas Risk Reduction Program (TRRP) Institutional Controls (ICs) 30 TAC Chapter 350.111 Whenever required by this chapter, the person or landowner shall file a copy of the appropriate deed notice, voluntary cleanup program certificate of completion or restrictive covenant in the real property records of the county in which the property is located to notify future owners of any limitations on the use of the property. The chapter includes descriptions of the information required to be recorded. 30 TAC Part 1: Industrial Solid Waste and Municipal Hazardous Waste: Generators 30 TAC Chapter 335, Subchapter C Standards for hazardous waste generators either disposing of waste on site or shipping off site with the exception of conditionally exempt small quantity generators. The definition of hazardous involves state and federal standards. In general, any substantive portion of a state IC law or regulation that meets the requirements of CERCLA §121(d) and is consistent with the NCP (e.g., 40 C.F.R. §300.400(g)(4)) may be considered as a potential ARAR. Substantive standards typically establish a level or standard of control, and may include a narrative requirement; in the context of ICs, a substantive requirement could be one that, for example, is designed to protect human health and the environment by requiring land use or activity use restrictions on property with residual contamination where that residual contamination makes the property unsuitable for specific land uses. A portion of a state IC law or regulation that requires mechanisms or procedures (e.g., state-approved recordation) to implement the IC may be considered part of the substantive ARAR requirement if it provides for enforceability of the IC (USEPA 2012). The sediment at the site is not listed hazardous waste, does not contain listed hazardous waste, and does not meet any of the characteristics of hazardous waste. Therefore, the rules for hazardous waste are neither applicable nor relevant and appropriate. Texas Surface Water Quality Standards (TSWQS) 30 TAC §307.4-7, 10 These state regulations provide: • General narrative criteria • Anti-degradation Policy • Numerical criteria for pollutants • Numerical and narrative criteria for water-quality related uses (e.g., human use) • Site-specific criteria for Patrick Bayou The TSWQS are considered an ARAR for PCBs. Currently, the TSWQS saltwater chronic criterion for total PCBs is 30 ng/L and the TSWQS human health criterion ‘fish only’ for total PCBs is 0.64 ng/L. USEPA has directed that the RAO for total PCBs in surface water be set to the TSWQS, or to background, if higher. Texas Water Quality: Pollutant Discharge Elimination System (TPDES) 30 TAC §279.10 These state regulations require stormwater discharge permits for either industrial discharge or construction-related discharge. The State of Texas was authorized by USEPA to administer the NPDES program in Texas on September 14, 1998 (Texas Commission on Environmental Quality 2009). The remedial alternatives include no off-site remedial actions that would trigger the need for a discharge permit. Texas Water Quality: Water Quality Certification 30 TAC §279.10 The development and evaluation of remedial alternatives considers potential water quality impacts relevant to the Water Quality Certification in Texas. Texas Risk Reduction Program (TRRP) 30 TAC §350 These state regulations establish procedures and criteria for applying for, processing, and reviewing state certifications under CWA, §401. It is the purpose of this chapter, consistent with the Texas Water Code and the federal CWA, to maintain the chemical, physical, and biological integrity of the state's waters. Activated upon release of Chemicals of Concern (COC). The Risk Reduction Program uses a tiered approach incorporating risk assessment techniques to help focus investigations, to determine appropriate protective concentration levels for human health, and, when necessary, for ecological receptors. Includes protective concentration levels. Feasibility Study Report Patrick Bayou Superfund Site 5 The development of the Preliminary Remediation Goal is consistent with state requirements, including the TRRP. March 2017 040284-01.08 Table 3-2 Potential ARAR Screening for Patrick Bayou Superfund Site, Feasibility Study Report Potential ARARs Natural Resources Code, Antiquities Code of Texas Citation Texas Parks and Wildlife Commission Regulations 191.092-171 Summary Requires that the Texas Historical Commission staff review any action that has the potential to disturb historic and archeological sites on public land. Actions that need review include any construction program that takes place on land owned or controlled by a state agency or a state political subdivision such as a city or a county. Without local control, this requirement does not apply. Regulations implementing the Antiquities Code of Texas. Describes criteria for evaluating archaeological sites and permit requirements for archaeological excavation. Comment Disturbance of any archaeological or historic resources is unlikely due to the highly modified nature of the site and focus of action within the sediments as opposed to upland areas. The magnitude and specific boundaries of ground disturbance were considered in the development of the remedial alternatives, and implementation of the remedy should not disturb archaeological or historic resources. Additional review will be performed after specific implementation plans are developed. This requirement is only applicable if an archaeological site is found. The Baseline Ecological Risk Assessment considered the list of rare, threatened, and endangered species that may be found in Harris County and concluded that none of the listed species would use the site other than potentially incidentally. Implementation of any of the remedial alternatives should not impact these species. If the selected remedy includes construction of a cap, coordination with the Coastal Zone Permit Coordinator would need to be performed prior to implementing the remedy. Practice and Procedure, Administrative Code of Texas 13 TAC Part 2, Chapter 26 State of Texas Threatened and Endangered Species Regulations 31 TAC 65.171 - 65.176 No person may take, possess, propagate, transport, export, sell or offer for sale, or ship any species of fish or wildlife listed as threatened or endangered. TCCC Policies for Development in Critical Areas 31 TAC §501.23 Texas Coastal Management Plan Consistency 31 TAC, §506.12 Dredging in critical areas is prohibited if activities have adverse effects or degradation on shellfish and/or jeopardize the continued existence of endangered species or results in an adverse effect on a coastal natural resource area (CNRA)5; prohibit the location of facilities in coastal natural resource areas unless adverse effects are prevented and/or there is no practicable alternative. Actions should not be conducted during spawning or nesting seasons or during seasonal migration periods. Specifies compensatory mitigation. Specifies Federal actions within the CMP boundary that may adversely affect CNRAs; specifically selection of remedial actions. Texas State Code – Obstructions to Navigation Natural Resources Code § 51.302 Prohibition and Penalty Noise Regulations Texas Penal Code Chapter 42, Section 42.01 5 Prohibits construction or maintenance of any structure or facility on land owned by the State without an easement, lease, permit, or other instrument from the State. The Texas Penal Code regulates any noise that exceeds 85 decibels after the noise is identified as a public nuisance. Patrick Bayou lies within the Coastal Zone Boundary (GLO TCMP). If the selected remedy includes construction of a cap, coordination with the Coastal Zone Permit Coordinator would need to be performed prior to implementing the remedy. If the selected remedy includes construction of a cap, coordination with the Texas General Land Office would need to be performed prior to implementing the remedy. Noise abatement may be required if actions are identified as a public nuisance. Due to the isolation of the site, its location adjacent to a freeway with high volumes of traffic during normal working hours, and the industrial nature of the nearest properties, noise from construction activity associated with a potential remedial action is unlikely to constitute a public nuisance. Noise associated with truck traffic to and from the site should be considered. A CNRA is a coastal wetland, oyster reef, hard substrate reef, submerged aquatic vegetation, tidal sand, or mud flat. Feasibility Study Report Patrick Bayou Superfund Site 6 March 2017 040284-01.08 Table 3-2 Potential ARAR Screening for Patrick Bayou Superfund Site, Feasibility Study Report Potential ARARs Citation Summary Comment Local Harris County Floodplain Management Permit6 Regulations of Harris County, Texas, for Flood Plain Management All development occurring within the floodplain of unincorporated Harris County requires a permit from Harris County; provide land use controls necessary to qualify unincorporated areas of Harris County for flood insurance under requirements of the National Flood Insurance Act of 1968, as amended, to protect human life and health (Harris County 2007). Floodplain management is addressed under the Federal requirements for floodplains. 6 Harris County authorization is based upon Texas Local Government Code Section 240.901, as amended; Texas Transportation Code Sections 251.001 - 251.059 and Sections 254.001 - 254.019, as amended; the Harris County Road Law, as amended; and the Flood Control and Insurance Act, Subchapter I of Chapter 16 of the Texas Water Code, as amended. Feasibility Study Report Patrick Bayou Superfund Site 7 March 2017 040284-01.08 Table 3-2 Potential ARAR Screening for Patrick Bayou Superfund Site, Feasibility Study Report References: CFR (Code of Federal Regulations), 1985. "40 CFR Appendix A to Part 6 - Statement of Procedures on Floodplain Management and Wetlands Protection." vLex United States. June 25, 1985 as amended. http://cfr.vlex.com/vid/appendix-6-statement-floodplain-wetlands19781438. Harris County Flood Control District, 2007. FEMA Floodplains Effective June 18, 2007. Houston, TX: Harris County, TX, 2007. Harris County Public Infrastructure Department, Architecture and Engineering Division (Harris County), 2007. Regulations of Harris County, Texas for Floodplain Management. As Adopted June 5, 2007. Effective June 2007. Amended November 2011. http://hcpid.org/permits/fp_regs.html. (Accessed April 13, 2012). Mueller, D.H., and A.J. Smalley, 1980. Water Resources Development Act Under the Fish and Wildlife Coordination Act. Arlington, VA: U.S. Fish and Wildlife Service, 1980. TAC (Texas Administrative Code). http://www.sos.state.tx.us/tac/. (Accessed April 2012). TCEQ (Texas Commission on Environmental Quality), 2009. "What is the Texas Pollutant Discharge Elimination System?" Texas Commission on Environmental Quality. September 24, 2009. Available from: http://www.tceq.state.tx.us/permitting/water_quality/wastewater/pretreatment/tpdes_definition.html. (Accessed April 2012). TCEQ. http://www.tceq.state.tx.us/. (Accessed April 2012). Texas General Land Office Texas Coastal Management Program Coastal Zone Boundary Map http://www.glo.texas.gov/what-we-do/caring-for-the-coast/_documents/landing-page-folder/CoastalBoundaryMap.pdf . (Accessed April 13, 2012). TPWD (Texas Parks and Wildlife Department), 2010. Wildlife Division, Diversity and Habitat Assessment Programs. County Lists of Texas' Special Species. [Harris County, updated 3/5/2010. (Accessed June 23, 2010). Texas Natural Resources Code Title 31. Natural Resources and Conservation, Part 16. Coastal Coordination Council, Chapter 501 Rule 503.1. Coastal Management Program Boundary. (Accessed April 13, 2012). Department of Commerce Combined Coastal Management Program and Final Environmental Impact Statement for the State of Texas. Prepared by: Office of Ocean and Coastal Resource Management National Oceanic and Atmospheric Administration U.S. Department of Commerce And The State of Texas, August 1996. http://www.glo.state.tx.us/coastal/cmp/feis/CMP_FEIS_1996.pdf. University of Houston. "On Shaky Ground: Geological Faults Threaten Houston." ScienceDaily 29 April 2008. . University of Texas. Karst and pseudokarst regions of Texas. http://www.utexas.edu/tmm/sponsored_sites/tss/images/tk1.gif. (Accessed April 13, 2012). USEPA (U.S. Environmental Protection Agency), 1988. CERCLA Compliance with Other Laws Manual: Interim Final. 1988. USEPA, 1994. Considering Wetlands at CERCLA Sites. 1994. USEPA, 2007. Clean Water Act Jurisdiction. Following the U.S. Supreme Court’s Decision in Rapanos v. United States & Carabell v. United States. USEPA, 2008. "Sole Source Aquifers." Region 6 Water Programs. March 18, 2008. http://www.epa.gov/region6/water/swp/ssa/maps.htm. (Accessed April 13, 2012). USEPA, 2009. "Air Pollution Operating Permit Program Update: Key Features and Benefits." Operating Permits. July 10, 2009. http://www.epa.gov/air/oaqps/permits/permitupdate/brochure.html. USEPA, 2010. Does the EPA Regulate Noise? http://publicaccess.custhelp.com/cgi-bin/publicaccess.cfg/php/enduser/std_adp.php?p_faqid=1765.. USEPA, 2012. Institutional Controls: A guides to planning, implementing, maintaining, and enforcing Institutional Controls at contaminated sites. EPA-540-R-09-001. Office of Enforcement and Compliance Assurance. OSWER. USFWS (U.S. Fish and Wildlife Service), 2012. USFWS Wetland Mapper for National Inventory Map Information. Accessed online at http://www.fws.gov/wetlands/data/Mapper.html on April 13, 2012. Feasibility Study Report Patrick Bayou Superfund Site 8 March 2017 040284-01.08 Table 4-1 Mean PEL-Q and Half-life Evaluation Scenario 1 No Action Taken in SMA-1 (Alternatives 1 and 2) Half-life – Time Needed to Natural Reach Mean Recovery Only PEL-Q Threshold (years) (years) Scenario 2 Capping in SMA-1 (Alternatives 3 and 4) Half-life – Time Needed to Remediation of Reach Mean SMA-1 PEL-Q Threshold (years) (years) Location 2009 Mean PEL-Q PB-001.1 14.7 6 10.3 3 5.2 PB-016A 15.2 6 10.6 3 5.3 PB-018 16.3 6 11.2 3 5.6 PB-026 166.5 5 26.1 5 26.1 PB-032 80.7 13 54.3 12 50.1 PB-034 8.7 13 12.4 12 11.5 PB-036 15.9 13 23.8 12 22.0 PB-037 13.9 13 21.3 12 19.7 PB-041A 14.2 9 15.0 7 11.7 PB-043 10.6 9 11.2 7 8.7 PB-044A 10.4 9 11.0 7 8.6 PB-047.1 26.7 9 23.2 7 18.1 PB-053A 129.7 5 24.3 2 9.7 PB-059.1 62.5 5 19.0 2 7.6 PB-063.1 43.4 5 16.4 3 9.8 PB-069 58.8 5 18.6 3 11.2 PB-081 49.1 3 10.4 3 6.9 Note: PEL-Q = Probable Effects Level-Quotient Feasibility Study Report Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Table 4-2 Summary of SMA Delineation ID1 Location Acreage2 Reason for Delineation SMA-1 PB-075 to PB-082 0.63 Surface Water RAO SMA-2 PB-032 0.73 Future3 exceeds Benthic RAO SMA-3 PB-026 0.79 Future3 exceeds Benthic RAO SMA-4 PB-047.1 1.31 Future3 exceeds Benthic RAO SMA-5 PB-036 0.70 Future3 exceeds Benthic RAO SMA-6 PB-037 0.74 SMA-7 PB-041A 0.81 Future3 exceeds Benthic RAO Future3 exceeds Benthic RAO SMA-8 PB-034 0.76 Future3 exceeds Benthic RAO SMA-9 PB-069 0.71 Future3 exceeds Benthic RAO Natural Recovery Areas See Figure 4-1 26.6 Baseline4 exceeds Benthic RAO Notes: 1 - SMA-2 through SMA-9 were delineated using MNR rates that assume potential downstream loading of PCBs from SMA-1 is resolved. 2 - Acreage is based on Thiessen polygon areas. For FS cost purposes, a 20 percent contingency has been added, and additional area has been added to account for bank-to-bank capping where ACBM is used. Thus, the areas presented in the Appendix C costs do not match the areas presented in this table. 3 - Predicted to exceed benthic Remedial Action Objective (RAO) after 10 years of natural recovery 4 - Currently exceeds benthic RAO but predicted to fall below mean Probable Effects Level-Quotient threshold of 4.47 within 10 years Feasibility Study Report Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Table 4-3 Aggregate Cap Armor Sizing Cap Armor Stone d50 (inches)1 Minimum Armor Layer Thickness (feet)2,3 6.5 2 37 8 3 9 1.5 4 0.5 0.25 5 6 1.0 6 6 1.0 7 2.5 5 6 1.0 SMA 1 1.5 8 9 Notes: 1 - d50 is based on the 100-year storm event. 2 - Minimum armor layer thickness shown for SMA-1, -2, -3, -5 and -6 is based on 2*d50 dimension. 3 - Minimum armor layer thickness for SMA-4 is shown as the thinnest layer considered reasonably constructible, which is greater than the thickness determined based on the 2*d50 dimension. SMA = sediment management area Feasibility Study Report Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Table 4-4 Summary of Quantities, Durations, and Short-term Impacts Alternative 2 Monitored Natural Recovery (MNR) Alternative 3 MNR, SMA-1 Capping & SMA-2 through SMA-9 Treatment Alternative 4 MNR & SMA-1 to 9 Capping N/A N/A N/A N/A N/A 5 10 5 175 575 5 10 5 250 700 N/A N/A N/A N/A 343,000 86 3,200 9,700 0 0 0 0 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 70,200 0 23 1,200 3,300 6 4,600 13,600 0.27 0.0011 70,200 597,000 71 4,250 12,000 5 4,500 12,700 0.25 0.0010 1.0 1.0 1.0 0.9 Site Preparation Mobilization/Demobilization duration (days) Environmental controls & survey duration (days) Debris removal duration (days) Site Preparation Equipment Hours Site Preparation Labor Hours In Situ Treatment In Situ Treatment area (sf) In Situ Treatment duration (days) In Situ Treatment Equipment Hours In Situ Treatment Labor Hours ACBM Capping ACBM placement area - constrained channel (sf) ACBM placement area - open channel (sf) ACBM placement duration (days) ACBM Equipment Hours ACBM Labor Hours TOTAL DURATION (months) TOTAL EQUIPMENT HOURS TOTAL LABOR HOURS TOTAL NON-FATAL INJURIES TOTAL FATAL INJURIES NORMALIZED IMPACTS Equipment Hours Health and Safety Feasibility Study Report Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Table 4-4 Summary of Quantities, Durations, and Short-term Impacts Notes: 1 - Durations assume a 22-day month, rounded up 2 - Production rates assumed as follows: a. ACBM placement - constrained channel- 3,000 sf/day b. ACBM placement - open channel - 12,500 sf/day c. In situ treatment - 4,000 sf/day 3 - Incident rates based on data from U.S. Department of Labor (USDL), Bureau of Labor Statistics (USDL 2011). 4 - Non-fatal injury estimate based on a rate of 3.9 per 200,000 work hours (NAICS code 23 - construction). 5 - Fatal injury estimate based on a rate of 15.7 per 200,000,000 work hours (construction laborer). sf/day = square feet per day USDL, 2011. U.S. Department of Labor, Bureau of Labor Statistics, OSHA Recordable Case Rates and Census of Fatal Occupational Injuries, 2011 Feasibility Study Report Patrick Bayou Superfund Site 2 March 2017 040284-01.08 Table 5-1 Detailed Evaluation of Remedial Alternatives Alternative 1 No Further Action Alternative 2 MNR Alternative 3 MNR, SMA-1 Capping, and SMA-2 through SMA-9 Treatment Alternative 4 MNR and SMA-1 through SMA-9 Capping Overall Protection Does not meet Uncertain Meets Meets Compliance with ARARs Does not Meet Meets Meets Meets Threshold Criteria Balancing Criteria • Not evaluated because threshold criteria not met • • PCB surface water RAO met throughout the site after 9 to 21 years based on analytical evaluation of PCB half lives Benthic risk potentially not addressed within reasonable time frame in some areas of the Site • • • Long-term Effectiveness • • Not evaluated because threshold criteria not met • No additional reduction in TMV beyond that achieved by natural recovery processes • Reduction of TMV Feasibility Study Report Patrick Bayou Superfund Site • 1 PCB surface water RAO met throughout the Site within 7 years after completing construction based on modeling results Benthic risk addressed in reasonable time frame in SMA-1 by capping, assuming sediment deposition on cap surface would provide a suitable benthic substrate over time. Benthic risk addressed within less than 3 years through treatment of surface sediments with activated carbon in SMA-2 through SMA-9 Adaptive management approach would facilitate modifying monitoring schedule and/or allow for future actions to be taken if necessary Reactive Core Mat (RCM) underlayment beneath the ACBM cap in SMA-1 expected to reduce near-surface porewater concentrations of PCBs by 99% for at least 100 years Bioavailability reduction of more than 90% expected for benthic risk ICs by treatment of surface sediments with activated carbon • • • • • PCB surface water RAO met throughout the Site within 7 years after completing construction based on modeling results Benthic risk addressed in reasonable time frame in SMA-1 through SMA-9 by capping, assuming sediment deposition on cap surface would provide a suitable benthic substrate over time. Adaptive management approach would facilitate modifying monitoring schedule and/or allow for future actions to be taken if necessary Adaptive management options are more limited in areas where ACBM caps have been constructed because the hard substrate of ACBM would prevent access to the sediments that are capped. RCM underlayment beneath the ACBM cap in SMA-1 expected to reduce near-surface porewater concentrations of PCBs by 99% for at least 100 years March 2017 040284-01.08 Table 5-1 Detailed Evaluation of Remedial Alternatives • Alternative 1 No Further Action Not evaluated because threshold criteria not met • • • Alternative 2 MNR Achieve surface water protection after an estimated 9 to 21 years based on natural recovery modeling Uncertain time frame for reducing potential benthic risk Negligible short term impacts related to water quality, air quality, noise, traffic, and worker health and safety Short-term Effectiveness Feasibility Study Report Patrick Bayou Superfund Site 2 Alternative 3 MNR, SMA-1 Capping, and SMA-2 through SMA-9 Treatment • Achieve surface water protection within 7 years following completion of implementation • Reduce benthic risk to acceptable levels within 3 years following completion of implementation in SMA-2 through SMA-9 • Manageable water quality impacts from turbidity during sediment treatment • Localized disturbance to the top of bank along the bayou where construction equipment would be staged and ACBM would be anchored • Potential production facility impacts during 5 to 7 month duration of the project • 0.27 estimated construction worker injuries • 0.0011 estimated construction worker fatalities • Air emissions from 4,600 hours of equipment operations Alternative 4 MNR and SMA-1 through SMA-9 Capping Same as Alternative 3 with the following modifications: • Reduce benthic risk to acceptable levels within 10 years, following deposition of new sediment onto cap surface that will create a habitatcompatible substrate • Manageable water quality impacts from turbidity during capping • Widespread disturbance to the top of bank along the bayou where construction equipment would be staged and ACBM would be anchored • Minimal sediment quality impacts associated with implementation • No tissue impacts associated with implementation • Potential production facility impacts during 5 to 7 month duration of the project • 0.25 estimated construction worker injuries • 0.001 estimated construction worker fatalities • Air emissions from 4,500 hours of equipment operations March 2017 040284-01.08 Table 5-1 Detailed Evaluation of Remedial Alternatives Alternative 1 No Further Action • Not evaluated because threshold criteria not met • Alternative 2 MNR Minimal implementability issues associated with sample collection adjacent to active industrial operations Implementability N/A Total Cost Modifying $710,000 Alternative 3 MNR, SMA-1 Capping, and SMA-2 through SMA-9 Treatment • Capping with ACBM has been demonstrated as implementable at sites with similar constraints • Hand labor can be used to construct the cap in difficult areas • Low profile of ACBM minimizes the need to dredge the channel to maintain flood capacity • Specialized equipment and a highly trained contractor work force may be required to mix AC into surface sediments • Treatment by mixing AC into sediments could cause turbidity issues that need to be managed with engineering controls such as silt curtains or similar barriers • Coordination with the railroad will be necessary for capping adjacent to the bridge in the railroad right-of-way • Utilities and facility infrastructure on the banks may require several different types of anchoring details • Construction within active production facilities can present implementability challenges for contractor safety, access and scheduling $6,730,000 Alternative 4 MNR and SMA-1 through SMA-9 Capping Same as Alternative 3 but: • ACBM is not as technically challenging to construct compared to treatment, and would not require specialized equipment • Placement of ACBM cap less likely to create turbidity issues than mixing AC into surface sediments • In wider channel areas, the contractor may have more difficulty deploying the ACBM textiles due to the size of the panels, and/or may need to take additional measures to ensure the grout fully fills the ACBM textile in the middle of the channel • If dredging is determined to be necessary to maintain flood capacity in the channel, the implementability of this alternative is much more difficult. • ACBM capping implementability issues are magnified because a much larger area of the Site would be capped $13,020,000 Criteria1 State Acceptance N/A T.B.D. T.B.D. T.B.D. Community Acceptance N/A T.B.D. T.B.D. T.B.D. Notes: 1 - Modifying criteria will be evaluated by U.S. Environmental Protection Agency after receipt of comments on the Proposed Plan for the Site. AC = activated carbon ACBM = Articulated Concrete Block Mat ARARs = Applicable or Relevant and Appropriate Requirements IC = indicator chemical MNR = Monitored Natural Recovery N/A = Not Applicable PCB = polychlorinated biphenyl RAO = Remedial Action Objective T.B.D. = To Be Determined TMV = toxicity, mobility, or volume Feasibility Study Report Patrick Bayou Superfund Site 3 March 2017 040284-01.08 Table 6-1 Comparative Evaluation of Remedial Alternatives Alternative 2 Criterion MNR Alternative 3 MNR, SMA-1 Capping and SMA-2 through SMA-9 Treatment Alternative 4 MNR and SMA-1 through SMA-9 Capping Overall Protection Uncertain Similar to Alternative 4 Similar to Alternative 3 Compliance with ARARs Uncertain Most Favorable Middle Long-term Effectiveness Uncertain Similar to Alternative 4 Similar to Alternative 3 Reduction in TMV Least Favorable Most Favorable Middle Short-term Effectiveness Uncertain Most Favorable Middle Implementability Most Favorable Similar to Alternative 4 Similar to Alternative 3 Cost Most Favorable Middle Least Favorable Notes: ARARs = Applicable or Relevant and Appropriate Requirements MNR = Monitored Natural Recovery TMV = Toxicity, Mobility, or Volume Feasibility Study Report Patrick Bayou Superfund Site 1 March 2017 040284-01.08 HGES Lake Houston TEXAS San Jacinto River Houston Ship Channel Q:\Jobs\040284-Patrick_Bayou\Maps\2013_09_FS\Vicinity Map 8x11L FS.mxd ckiblinger 9/27/2013 3:35:57 PM MEXICO GULF OF MEXICO _ ^ HOUSTON Patrick Bayou Superfund Site Trinity Bay DEER PARK Upper Galveston Bay East Bay Lower Galveston Bay West Bay GULF OF MEXICO GALVESTON Miles 0 10 [ Figure 1-1 Patrick Bayou Superfund Site Vicinity Map Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 ON T US O H IP H S EL N AN H C 5 £ ¤ 90 10 15 £ ¤ § ¦ ¨ 290 10 Site Location ^ § ¦ ¨ Houston 610 20 Deer Park Trinity Bay Galveston Bay § ¦ ¨ 25 45 30 35 40 45 50 55 60 65 5 10 70 15 Eas t Fo rk 75 20 25 Q:\Jobs\040284-Patrick_Bayou\Maps\2013_09_FS\Patrick Bayou Superfund Site Boundaries 11x17P FS.mxd ckiblinger 9/27/2013 3:26:24 PM 30 80 35 40 85 90 45 50 95 55 100 105 Station Lines Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: Copyright:© 2013 Esri. Source: Esri, DigitalGlobe, GeoEye, i-cubed, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS User Community. [ 0 Feet 750 1,500 Figure 2-1 Patrick Bayou Superfund Site Boundaries Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 £ ¤ 90 £ ¤ 290 § ¦ ¨ 10 Houston Site Location Deer Park § ¦ ¨ 610 ^ OXY VINYLS Trinity Bay 5 10 15 § ¦ ¨ 45 Galveston Bay ROHM & HAAS 20 25 30 OxyChem 003 35 OXY VINYLS @ ! OxyChem 002 Shell 40 R-004 ! @ @ ! 45 ! Shell @ R-009 50 @ OxyChem ! 001 SHELL ROHM & HAAS 55 @ Shell ! 60 R-003 65 5 10 70 OXY VINYLS 15 75 Shell R-002 @ ! 80 Shell C101/001 PORT OF HOUSTON AUTHORITY 20 SHELL Praxair 001 Shell R-001 ! @ @ LUBRIZOL ! 25 Rohm Hass 003 !30 @ @ PORT OF HOUSTON AUTHORITY ! @ ! 85 Lubrizol 007 PRAXAIR 90 Shell C003 @ ! SHELL 45 50 Shell C002 @ ! LUBRIZOL 55 Lubrizol @ 002 ! 105 110 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_09\Property_Ownership_Outfalls.mxd ckiblinger 2/3/2016 3:24:15 PM 40 ROHM & HAAS Lubrizol 006 ! @ @ Lubrizol ! 001 Deer 115 Park WWTP @ ! CITY OF DEER PARK POTW 120 125 130 135 140 145 @ Outfall ! Station Lines Approximate Property Boundaries [ Site Boundary as Defined in AOC NOTES: 1. Property Information from Harris County Appraisal District (HCAD). 2. Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. 3. Aerial Imagery Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS User Community. Copyright:© 2014 Esri. 0 Feet 1,000 2,000 Figure 2-2 Property Ownership Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ £ ¤ 59 90 5 10 15 £ ¤ § ¦ ¨ 290 10 Site Location 20 ^ § ¦ ¨ 610 Trinity Bay Deer Park 25 Houston 30 Galveston Bay § ¦ ¨ 35 45 40 45 50 55 60 65 5 10 70 15 75 20 25 30 80 35 40 85 90 45 50 95 55 100 105 110 115 120 125 130 135 140 145 Q:\Jobs\040284-Patrick_Bayou\Maps\2013_09_FS\Surrounding_Land_Use_Based_On_H-GAC_Data 11x17P FS.mxd ckiblinger 9/27/2013 3:46:07 PM 150 155 160 H-GAC Current Land Use Parks/Open Spaces Approximate Drainage Basin Commercial Vacant Developable (includes Farming) Site Boundary as Defined in AOC Industrial Undevelopable Residential Water Government/Medical/Education Unknown Multiple Undetermined Other Station Lines Intermittent Streams NOTES: 1. Land use data obtained from Houston-Galveston Area Council (HGAC). 2013. Land Use Streaming Map Service. ArcGIS link: http://arcgis02.h-gac.com/arcgis/services. Accessed 9/27/2013. 2. Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. 3. Aerial imagery: Copyright:© 2013 Esri. Source: Esri, DigitalGlobe, GeoEye, i-cubed, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS User Community. [ 0 Feet 750 1,500 Figure 2-3 Surrounding Land Use Based on H-GAC Data Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 PB011_A PB011_A PB001.1 PB001.1 PB009_A PB009_A PB004 PB004 10 PB013.2 PB013.2 PB013.1 PB013.1 ON T US O H IP SH E L PB015 PB015 N N PB016 PB016 A CH PB001.2 PB001.2 PB001.3 PB001.3 £ ¤ 90 PB002 PB002 £ ¤ § ¦ ¨ 290 PB016_A PB016_A 10 PB005 PB005 PB009 PB009 Site Location ^ PB003 PB003 PB018 PB018 PB018_A PB018_A PB022 PB022 § ¦ ¨ Houston PB007.1 PB007.1 PB007.2 PB007.2 PB019 PB019 PB022_A PB022_A 610 Deer Park PB023_A PB023_A Trinity Bay Galveston Bay PB024_A PB024_A PB026 PB026 25 § ¦ ¨ 45 PB028 PB028 30 PB030 PB030 PB032 PB032 PB034 PB034 35 PB036 PB036 PB037 PB037 40 PB041_A PB041_A PB042 PB042 PB043 PB043 45 PB044_A PB044_A PB047.1 PB047.1 PB047.2 PB047.2 PB048 PB048 50 PB048_A PB048_A PB049 PB049 PB053_A PB053_A PB056 PB056 55 PB057_A PB057_A PB057 PB057 PB059.1 PB059.1 PB059.2 PB059.2 60 PB063.2 PB063.2 PB063.1 PB063.1 PB063 PB063 PB064 PB064 EF-001 EF-001 5 PB069 PB069 70 PB073 PB073 PB066 PB066 10 15 Eas t Fo rk 75 PB077 PB077 PB074 PB074 20 25 30 PB081 PB081 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 7/7/2014 12:59:42 PM 80 35 40 85 90 45 PB093 PB093 95 50 PB097 PB097 100 55 PB101_A PB101_A 105 Total PCBs (mg/kg) " ) 0 - 2.31 " ) 2.32 - 3.37 " ) 3.38 - 4.77 " ) 4.78 - 10.15 " ) 10.16 - 124 " 2006 Sediment Sample Station Lines ! 2009 Sediment Sample Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 750 1,500 Figure 2-4 Total PCB Results in Surface Sediment Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas ON T US O H IP SH PB013.1 PB013.1 PB015 E L PB015 N PB016 PB016 AN H C £ ¤ PB009 PB009 PB007.1 PB007.1 PB004 PB004 PB001.1 PB001.1 PB001.2 PB001.2 5 PB011_A PB011_A 59 PB001.3 PB001.3 £ ¤ 90 10 15 PB002 PB002 PB016_A PB016_A £ ¤ PB005 PB005 PB018 PB018 PB013.2 PB013.2 PB018_A PB018_A PB022 PB022 10 Site Location PB003 PB003 PB007.2 PB007.2 PB009_A PB009_A PB019 PB019 20 § ¦ ¨ 290 ^ § ¦ ¨ Houston 610 Deer Park PB022_A PB022_A PB023_A PB023_A Trinity Bay Galveston Bay PB024_A PB024_A PB026 PB026 25 § ¦ ¨ 45 PB028 PB028 PB030 PB030 30 PB032 PB032 PB034 PB034 35 PB036 PB036 PB037 PB037 40 PB041_A PB041_A PB042 PB042 PB043 PB043 PB044_A PB044_A 45 PB047.1 PB047.1 PB047.2 PB047.2 PB048 PB048 PB048_A PB048_A 50 PB049 PB049 PB053_A PB053_A PB056 PB056 PB057_A PB057_A PB057 PB057 PB059.2 PB059.2 PB059.1 PB059.1 PB063.2 PB063.2 PB063 PB063 PB063.1 PB063.1 65 PB064 PB064 PB068 PB068 PB069 PB069 PB070_A PB070_A EF-001 EF-001 PB066 PB066 70 PB069.1 PB069.1 PB076.1 PB076.1 PB073 PB073 75 PB077 PB077 PB074 PB074 EF-008 EF-008 15 Eas t Fo rk 20 25 30 PB081 PB081 PB081.1 PB081.1 80 35 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/27/2014 12:14:35 PM PB082 PB082 40 85 90 45 PB093 PB093 50 PB097 PB097 95 55 PB101_A PB101_A 100 105 " 2006 Sediment Sample Station Lines " ) 0.0164 - 7.63 ! 2009 Sediment Sample Site Boundary as Defined in AOC " ) 7.64 - 12.9 # 2011 Sediment Sample " ) 13.0 - 18.2 " ) 18.3 - 41.2 " ) 41.3 - 1,310 Total PAH (mg/kg) PB119.2 PB119.2 SE-002 SE-002 NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 750 1,500 Figure 2-5 Total PAH Results in Surface Sediment Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas PB001.1 PB001.1 PB007.1 PB007.1 ON T US O H IP SH PB013.1 PB013.1 PB011_A PB011_A PB015 E L PB015 N PB016 A N PB016 H C PB016_A £ ¤ 59 PB001.2 PB001.2 PB009 PB009 PB001.3 PB001.3 15 £ ¤ 90 PB002 PB002 PB016_A £ ¤ PB018 PB018 PB009_A PB009_A PB013.2 PB013.2 PB018_A PB018_A PB022 PB022 § ¦ ¨ 290 PB004 PB004 10 Site Location PB005 PB005 PB003 PB003 PB019 PB019 ^ § ¦ ¨ Houston 610 PB007.2 PB007.2 Deer Park Trinity Bay Galveston Bay PB023_A PB023_A PB022_A PB022_A § ¦ ¨ PB026 PB026 PB024_A PB024_A 45 PB028 PB028 30 PB030 PB030 PB032 PB032 PB034 PB034 35 PB036 PB036 PB037 PB037 40 PB041_A PB041_A PB043 PB043 PB042 PB042 45 PB044_A PB044_A PB047.2 PB047.2 PB047.1 PB047.1 PB048 PB048 50 PB048_A PB048_A PB049 PB049 PB053_A PB053_A PB056 PB056 55 PB057 PB057 PB059.1 PB059.1 PB057_A PB057_A PB059.2 PB059.2 60 PB063.2 PB063.2 PB063.1 PB063.1 PB063 PB063 65 PB064 PB064 EF-001 EF-001 PB069 PB069 PB066 PB066 70 PB073 PB073 75 PB077 PB077 PB074 PB074 15 Eas t Fo rk 20 25 30 PB081 PB081 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/27/2014 12:15:52 PM 80 35 40 85 90 45 PB093 PB093 50 PB097 PB097 95 55 PB101_A PB101_A 100 105 BEHP (µg/kg) ! 132 - 812 ( ! ( 813 - 1,140 ! ( 1,150 - 1,530 ! ( 1,540 - 2,120 ! ( 2,130 - 12,000 " 2006 Sediment Sample Station Lines ! 2009 Sediment Sample Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 750 1,500 Figure 2-6 Total BEHP Results in Surface Sediment Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas PB016 PB016 ON T US O H IP SH £ ¤ PB011_A PB011_A PB009 PB009 PB007.1 PB007.1 PB015 PB015 PB013.1 PB013.1 EL N A N PB016_A PB016_A H C 59 PB001.1 PB001.1 PB001.2 PB001.2 5 PB001.3 PB001.3 10 15 £ ¤ 90 PB002 PB002 £ ¤ PB004 PB004 PB018 PB018 § ¦ ¨ 290 10 PB005 PB005 PB013.2 PB013.2 PB018_A PB018_A PB022 PB022 20 ^ § ¦ ¨ Houston 610 PB007.2 PB007.2 PB019 PB019 PB022_A PB022_A Site Location PB003 PB003 PB009_A PB009_A Deer Park Trinity Bay Galveston Bay PB023_A PB023_A PB024_A PB024_A 25 § ¦ ¨ 45 PB026 PB026 PB028 PB028 PB030 PB030 PB032 PB032 PB034 PB034 35 PB036 PB036 PB037 PB037 PB042 PB042 PB041_A PB041_A PB043 PB043 PB044_A PB044_A PB047.1 PB047.1 PB047.2 PB047.2 PB048 PB048 PB049 PB049 50 PB048_A PB048_A PB049 PB049 PB053_A PB053_A PB057 PB057 55 PB056 PB056 PB059.1 PB059.1 PB057_A PB057_A PB059.2 PB059.2 60 PB063.1 PB063.1 PB063.2 PB063.2 PB063 PB063 PB064 PB064 EF-001 EF-001 PB069 PB069 PB066 PB066 70 PB073 PB073 15 Eas t Fo rk 75 PB077 PB077 PB074 PB074 20 25 30 PB081 PB081 80 35 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 7/7/2014 1:03:56 PM 40 85 90 45 PB093 PB093 50 PB097 PB097 95 55 100 PB101_A PB101_A 105 Lead (mg/kg) " 0 - 23.9 ) " ) 24.0 - 33.1 " ) 33.2 - 43.2 " ) 43.3 - 98.7 " ) 98.8 - 335 " 2006 Sediment Sample Station Lines ! 2009 Sediment Sample Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 750 1,500 Figure 2-7 Total Lead Results in Surface Sediment Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 PB001.1 PB001.1 PB004 PB004 ON T US O H IP SH EL N AN H C PB013.1 PB013.1 5 PB009 PB009 PB011_A PB011_A PB015 PB015 15 PB016 PB016 PB001.2 PB001.2 PB007.1 PB007.1 PB002 PB002 £ ¤ 90 PB001.3 PB001.3 £ ¤ § ¦ ¨ 290 PB013.2 PB013.2 PB018 PB018 20 10 PB005 PB005 PB016_A PB016_A Site Location PB007.2 PB007.2 PB009_A PB009_A PB003 PB003 § ¦ ¨ 610 PB019 PB019 PB018_A PB018_A Deer Park ^ Trinity Bay Houston PB023_A PB023_A PB022 PB022 PB022_A PB022_A PB024_A PB024_A 25 Galveston Bay § ¦ ¨ 45 PB026 PB026 PB028 PB028 PB030 PB030 30 PB032 PB032 PB034 PB034 35 PB036 PB036 PB037 PB037 40 PB041_A PB041_A PB042 PB042 PB043 PB043 PB044_A PB044_A 45 PB047.2 PB047.2 PB047.1 PB047.1 PB048 PB048 50 PB048_A PB048_A PB049 PB049 PB053_A PB053_A PB057 PB057 PB056 PB056 55 PB057_A PB057_A PB059.1 PB059.1 PB059.2 PB059.2 60 PB063.1 PB063.1 PB063.2 PB063.2 65 PB066 PB066 PB063 PB063 PB064 PB064 PB069 PB069 PB073 PB073 10 EF-001 EF-001 70 15 Eas t Fo rk PB074 PB074 PB077 PB077 20 25 30 80 35 PB081 PB081 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 9/7/2016 1:20:02 PM 40 85 90 45 PB093 PB093 50 PB097 PB097 55 100 PB101_A PB101_A 105 2,3,7,8-TCDD TEQs (ng/kg) " 0 - 21.51 ) " ) 21.51 - 53.33 " ) 53.33 - 109.38 " ) 109.38 - 141.83 " ) 141.83 - 2223.63 " 2006 Sediment Sample Station Lines ! 2009 Sediment Sample Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 750 1,500 Figure 2-8 2,3,7,8-TCDD TEQ Results in Surface Sediment Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 PB001.1 PB001.1 PB004 PB004 PB013.1 N O ON T T SS U U O H HO PP HII SSH PB013.1 LL E E PB015 PB015 N N N N 15 PB016 A A PB016 ( ! ! H H ( C C ) (" ! PB016_A PB016_A ( ! ( ! ) ! ( (" ! PB009_A PB009_A PB018 PB018 PB013.2 PB013.2 PB001.3 PB001.3 £ ¤ 90 PB002 PB002 £ ¤ ¦ ¨ § 290 PB005 PB005 PB003 PB003 10 Site Location PB007.2 PB007.2 ¦ ¨ § 610 PB019 PB019 ( ( ! ! 20 ! ( ( ! ( ! ( ! 5 ! ( " ) ( ! ( ! " ) PB018_A PB018_A PB001.2 PB001.2 PB007.1 PB007.1 PB009 PB009 PB011_A PB011_A Houston " )! ( PB022 PB022 Deer Park ^ Trinity Bay PB023_A PB023_A ( ! PB022_A PB022_A ( ! ! ( 45 PB030 PB030 " ) PB032 PB032 ( ! 900 PB034 PB034 ( ! 35 ¦ ¨ § PB028 PB028 ( ! 30 Galveston Bay PB026 PB026 800 " ) PB036 PB036 700 Mercury (mg/kg) PB024_A PB024_A ( ! PB037 PB037 40 PB041_A PB041_A ( ! " ) PB042 PB042 ( ! 45 PB047.1 PB047.1 ( ! 4000 6000 8000 10000 Distance from Mouth of Patrick Bayou (ft) PB047.2 PB047.2 PB057_A PB057_A ( ! PB057 PB057 PB059.2 PB059.2 ( ( ! ! PB059.1 PB059.1 PB063.2 PB063.2 PB063.1 PB063.1 ! (( ! 65 ( ! " ) PB063 PB063 ( ! " ) PB064 PB064 EF-001 EF-001 PB066 PB066 10 PB069 PB069 " ) 15 Eas t Fo rk 75 " ) 2000 PB053_A PB053_A " ) ( ! 0 PB048_A PB048_A PB049 PB049 PB056 PB056 PB077 PB077 100 PB044_A PB044_A ( ! ( ! ( ! 300 ( ! PB048 PB048 50 70 400 0 ( ! ( ! " ) PB073 PB073 500 200 PB043 PB043 ( ! 600 PB074 PB074 20 25 30 80 PB081 PB081 35 ( ! 40 85 Q:\Jobs\040284-Patrick_Bayou\Maps\2016_08_FS\AQ_PB_Multiple_Maps.mxd nkochie 8/25/2016 3:30:57 PM 90 45 PB093 PB093 ( ! 50 PB097 PB097 ( ! 55 100 ( ! PB101_A PB101_A 105 Mercury (mg/kg) " ) 0 - 0.77 " ) 0.77 - 2.35 " ) 2.35 - 3.84 " ) 3.84 - 6.98 " ) 6.98 - 843 " 2006 Sediment Sample Station Lines ! 2009 Sediment Sample Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 750 1,500 Figure 2-9 Mercury Results in Surface Sediment Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 £ ¤ 90 £ ¤ § ¦ ¨ 290 EF-008 EF-008 10 ! ( Site Location § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston Eas t Fo rk § ¦ ¨ Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:48:29 PM 45 PB119.1 PB119.1 PB119.5 PB119.5 ! PB119.2 PB119.2 ( ! (! (! ( ! ( PB119.4 PB119.4 PB119.3 PB119.3 Galveston Bay V U 225 SE-002 SE-002 ! ( PB-123 PB-123 ! ( ! ( 2006 Sediment Sample ! ( 2011 Sediment Sample Station Lines Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 475 950 Figure 2-10 Surface Sediment Samples Upstream of Site Boundary Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 ON T US O H IP SH EL N AN H C £ ¤ 90 PB009 PB009 PB003 PB003 ! ( PB016 PB016 ! ( ! ( £ ¤ § ¦ ¨ 290 10 PB018 PB018 Site Location ! ( § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston PB022 PB022 ! ( § ¦ ¨ 45 Galveston Bay PB036 PB036 ! ( PB042 PB042 ! ( PB048 PB048 ! ( PB057 PB057 ! ( PB063 PB063 EF-001 EF-001 ! ( ! ( PB073 PB073 ! ( Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:29:19 PM Eas t Fo rk ! ( Subsurface Sampling Locations Station Lines Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 750 1,500 Figure 2-11 Subsurface Sampling Locations Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Depth (cm) PB-003 PB-009 PB-022 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 100 200 300 400 500 250 0 100 PB-030 Depth (cm) PB-018 0 250 0 200 300 400 500 250 0 100 PB-036 200 300 400 500 250 0 100 PB-042 200 300 400 500 250 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 200 300 400 500 250 0 PB-063 100 200 300 400 500 250 0 PB-073 100 200 300 400 500 250 0 PB-077 100 200 300 400 500 250 0 PB-084 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 100 200 300 400 500 Concentration (mg/kg) Aroclor 250 0 100 200 300 400 500 Concentration (mg/kg) 250 0 congener NOTES: Cores were collected in October 2006; values are plotted at mid-depth, with non-detects shown as open symbols at half the method detection limit. Horizontal dotted line indicates approximate core depth. 100 200 300 400 500 Concentration (mg/kg) 250 0 300 400 500 100 200 300 400 500 Concentration (mg/kg) 100 200 300 400 500 EF-001 0 250 0 200 PB-057 0 100 100 PB-048 0 250 0 Depth (cm) PB-016 0 250 0 100 200 300 400 500 Concentration (mg/kg) Figure 2-12 Vertical Distribution of Total PCBs in Patrick Bayou Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas EC - \\austin2\Austin\D_drive\Projects\Patrick_Bayou_JDG\Patrick_Bayou\Analysis\sediment\profiles\PB_Oct06coreprofiles.pro Thu Sep 01 10:34:34 2016 Depth (cm) PB-003 PB-009 PB-022 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 500 1000 1500 2000 250 0 500 PB-030 Depth (cm) PB-018 0 250 0 1000 1500 2000 250 0 500 PB-036 1000 1500 2000 250 0 500 PB-042 1000 1500 2000 250 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 1000 1500 2000 250 0 PB-063 500 1000 1500 2000 250 0 PB-073 500 1000 1500 2000 250 0 PB-077 500 1000 1500 2000 250 0 PB-084 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 500 1000 1500 2000 Concentration (mg/kg) 250 0 500 1000 1500 2000 Concentration (mg/kg) 250 0 NOTES: Cores were collected in October 2006; values are plotted at mid-depth. Horizontal dotted line indicates approximate core depth. 500 1000 1500 2000 Concentration (mg/kg) 250 0 1500 2000 500 1000 1500 2000 Concentration (mg/kg) 500 1000 1500 2000 EF-001 0 250 0 1000 PB-057 0 500 500 PB-048 0 250 0 Depth (cm) PB-016 0 250 0 500 1000 1500 2000 Concentration (mg/kg) Figure 2-13 Vertical Distribution of Total PAH in Patrick Bayou Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas EC - \\austin2\Austin\D_drive\Projects\Patrick_Bayou_JDG\Patrick_Bayou\Analysis\sediment\profiles\PB_Oct06coreprofiles.pro Thu Sep 01 10:34:34 2016 Depth (cm) PB-003 PB-009 PB-022 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 10 20 30 40 50 250 0 10 PB-030 Depth (cm) PB-018 0 250 0 20 30 40 50 250 0 10 PB-036 20 30 40 50 250 0 10 PB-042 20 30 40 50 250 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 20 30 40 50 250 0 PB-063 10 20 30 40 50 250 0 PB-073 10 20 30 40 50 250 0 PB-077 10 20 30 40 50 250 0 PB-084 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 10 20 30 40 Concentration (mg/kg) 50 250 0 10 20 30 40 Concentration (mg/kg) 50 250 0 NOTES: Cores were collected in October 2006; values are plotted at mid-depth, with non-detects shown as open symbols at half the method detection limit. Horizontal dotted line indicates approximate core depth. 10 20 30 40 Concentration (mg/kg) 50 250 0 30 40 50 10 20 30 40 Concentration (mg/kg) 10 20 30 40 50 EF-001 0 250 0 20 PB-057 0 10 10 PB-048 0 250 0 Depth (cm) PB-016 0 50 250 0 10 20 30 40 Concentration (mg/kg) 50 Figure 2-14 Vertical Distribution of Bis(2-Ethylhexyl)phthalate in Patrick Bayou Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas EC - \\austin2\Austin\D_drive\Projects\Patrick_Bayou_JDG\Patrick_Bayou\Analysis\sediment\profiles\PB_Oct06coreprofiles.pro Thu Sep 01 10:34:35 2016 Depth (cm) PB-003 PB-009 PB-022 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 200 400 600 800 1000 250 0 200 PB-030 Depth (cm) PB-018 0 250 0 400 600 800 1000 250 0 200 PB-036 400 600 800 1000 250 0 200 PB-042 400 600 800 1000 250 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 400 600 800 1000 250 0 PB-063 200 400 600 800 1000 250 0 PB-073 200 400 600 800 1000 250 0 PB-077 200 400 600 800 1000 250 0 PB-084 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 200 400 600 800 1000 Concentration (mg/kg) 250 0 200 400 600 800 1000 Concentration (mg/kg) 250 0 NOTES: Cores were collected in October 2006; values are plotted at mid-depth. Horizontal dotted line indicates approximate core depth. 200 400 600 800 1000 Concentration (mg/kg) 250 0 600 800 1000 200 400 600 800 1000 Concentration (mg/kg) 200 400 600 800 1000 EF-001 0 250 0 400 PB-057 0 200 200 PB-048 0 250 0 Depth (cm) PB-016 0 250 0 200 400 600 800 1000 Concentration (mg/kg) Figure 2-15 Vertical Distribution of Lead in Patrick Bayou Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas EC - \\austin2\Austin\D_drive\Projects\Patrick_Bayou_JDG\Patrick_Bayou\Analysis\sediment\profiles\PB_Oct06coreprofiles.pro Thu Sep 01 10:34:36 2016 Depth (cm) PB-003 PB-009 PB-022 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 200 400 600 800 10001200 250 0 PB-030 Depth (cm) PB-018 0 250 0 200 400 600 800 10001200 250 0 PB-036 200 400 600 800 10001200 250 0 PB-042 200 400 600 800 10001200 250 0 PB-048 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 200 400 600 800 10001200 250 0 PB-063 200 400 600 800 10001200 250 0 PB-073 200 400 600 800 10001200 250 0 PB-077 200 400 600 800 10001200 250 0 PB-084 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 200 400 600 800 10001200 Concentration (ng/kg) 250 0 200 400 600 800 10001200 Concentration (ng/kg) 250 0 NOTES: Cores were collected in October 2006; values are plotted at mid-depth, with non-detects shown as open symbols at half the method detection limit. Horizontal dotted line indicates approximate core depth. 200 400 600 800 10001200 Concentration (ng/kg) 250 0 200 400 600 800 10001200 Concentration (ng/kg) 200 400 600 800 10001200 EF-001 0 250 0 200 400 600 800 10001200 PB-057 0 250 0 Depth (cm) PB-016 0 250 0 200 400 600 800 10001200 Concentration (ng/kg) Figure 2-16 Vertical Distribution of 2378-TCDD TEQs in Patrick Bayou Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas EC - \\austin2\Austin\D_drive\Projects\Patrick_Bayou_JDG\Patrick_Bayou\Analysis\sediment\profiles\PB_Oct06coreprofiles.pro Wed Sep 07 10:41:40 2016 Depth (cm) PB-003 PB-009 PB-022 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 200 400 600 800 250 0 200 PB-030 Depth (cm) PB-018 0 250 0 400 600 800 250 0 200 PB-036 400 600 800 250 0 200 PB-042 400 600 800 250 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 400 600 800 250 0 PB-063 200 400 600 800 250 0 PB-073 200 400 600 800 250 0 PB-077 200 400 600 800 250 0 PB-084 0 0 0 0 50 50 50 50 50 100 100 100 100 100 150 150 150 150 150 200 200 200 200 200 200 400 600 800 Concentration (mg/kg) 250 0 200 400 600 800 Concentration (mg/kg) 250 0 NOTES: Cores were collected in October 2006; values are plotted at mid-depth. Horizontal dotted line indicates approximate core depth. 200 400 600 800 Concentration (mg/kg) 250 0 600 800 200 400 600 800 Concentration (mg/kg) 200 400 600 800 EF-001 0 250 0 400 PB-057 0 200 200 PB-048 0 250 0 Depth (cm) PB-016 0 250 0 200 400 600 800 Concentration (mg/kg) Figure 2-17 Vertical Distribution of Mercury in Patrick Bayou Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas EC - \\austin2\Austin\D_drive\Projects\Patrick_Bayou_JDG\Patrick_Bayou\Analysis\sediment\profiles\PB_Oct06coreprofiles.pro Thu Sep 01 10:34:37 2016 £ ¤ 59 ON T US O H IP SH EL N AN H C £ ¤ PB-006A PB-006A PB-006B PB-006B 90 £ ¤ § ¦ ¨ 290 10 Site Location § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston PB-023 PB-023 PB-024 PB-024 § ¦ ¨ 45 Galveston Bay PB-036 PB-036 PB-044 PB-044 PB-046 PB-046 PB-052 PB-052 PB-053 PB-053 PB-059 PB-059 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:28:55 PM Eas t Fo rk Total PCB (U = 1/2, µg/L) " 1.56 - 2.21 J " J 2.22 - 5.89 " J 5.90 - 14.5 " J 14.6 - 18.6 " J 18.7 - 7,110 Station Lines Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 750 1,500 Figure 2-18 Total PCB Results in Porewater Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 ON T US O H IP SH EL N AN H C £ ¤ PB-006A PB-006A PB-006B PB-006B 90 £ ¤ § ¦ ¨ 290 10 Site Location § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston PB-023 PB-023 PB-024 PB-024 § ¦ ¨ 45 Galveston Bay PB-036 PB-036 PB-044 PB-044 PB-046 PB-046 PB-052 PB-052 PB-053 PB-053 PB-059 PB-059 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:28:27 PM Eas t Fo rk Total PAH (U = 1/2, µg/L) " J 1.87 - 3.30 " J 3.31 - 4.60 " J 4.61 - 8.70 " J 8.71 - 45.1 " J 45.2 - 18,300 Station Lines Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 750 1,500 Figure 2-19 Total PAH Results in Porewater Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 ON T US O H IP SH EL N AN H C £ ¤ 90 £ ¤ § ¦ ¨ 290 10 Site Location § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston § ¦ ¨ 45 Galveston Bay Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:29:47 PM Eas t Fo rk Bis(2-ethylhexyl)phthalate (µg/L) ! ( ! ( ! ( ! ( ! ( 1-3 Station Lines Site Boundary as Defined in AOC 4-6 [ 7 - 49 50 - 84 85 - 180 NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. 0 Feet 750 1,500 Figure 2-20 Bis(2-ethylhexyl)phthalate Results in Porewater Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas C:\Users\sballard\Documents\Projects\Patrick Bayou\2013\Feasibility Study\August 2016 Revisions\New Figures\Section 2 figure\Figure 2-21.docx Figure 2-21 Mercury Results in Porewater Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 HSC-14.1 HSC-14.1 # I PB006.2 PB006.2 # I HSC14 HSC14 £ ¤ 90 # I ON T US O H IP H S EL N AN H C # I PB006 PB006 £ ¤ § ¦ ¨ 290 10 Site Location § ¦ ¨ 610 # I Deer Park ^ Trinity Bay Houston PB020 PB020 § ¦ ¨ 45 PB031 PB031 # I # I Galveston Bay PB031.1 PB031.1 # I PB047.3 PB047.3 PB056_C PB056_C # I PB059 PB059 # I # I PB079 PB079 # I # I EF006.1 EF006.1 PB076 PB076 Eas t Fo rk I # I# # I PB080 PB080 # I PB082 PB082 PB083 PB083 # I PB085 PB085 # I PB087 PB087 # I PB089 PB089 # I PB091 PB091 # I PB093_A PB093_A # I PB097_A PB095 PB097_A PB095 # I PB099 PB099 # I # I PB-101.1 PB-101.1 PB101 PB101 # I PB081_A PB081_A # I V U 225 PB-119_B PB-119_B # I # I Surface Water Sampling Locations # I 2009 # I Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:32:51 PM # I PB070_B PB070_B EF006 EF006 # I PB066 PB066 2011 # I 2014 Station Lines Site Boundary as Defined in AOC NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. [ 0 Feet 875 1,750 Figure 2-22 Patrick Bayou Surface Water Sample Locations Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Water Column Total PCB (ng/L) Houston Ship Channel East Fork End Concrete-lined Channel 100.0 Start Concrete-lined Channel 1000.0 10.0 1.0 2009 Data 2011 Data 2014 Data Upstream Data 0.1 100 80 60 40 Station ID 20 0 -20 Figure 2-23 Spatial Profile of Water Column Total PCBs Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Open circles represent samples having potential incomplete lateral mixing. The human health Texas Surface Water Quality Standard is 0.64 ng/L.The aquatic life Texas Surface Water Quality Standard is 30 ng/L. DR - \\helios\aq\D_Drive\Projects\Patrick_Bayou_Joint_Defense_Group\Patrick_Bayou(040284-01)\MODEL\EFDC\Post_process\Water_Column\plot\plot_all\PB_WC_data_spatial_depth_avg_longterm_2014_TFigure.pro Mon Aug 29 15:41:54 2016 Houston Ship Channel East Fork End Concrete-lined Channel Water Column 2378-TCDD TEQs (ng/L) 10-2 Start Concrete-lined Channel 10-1 10-3 10-4 10-5 2009 2378-TCDD TEQs Upstream 2378-TCDD TEQs 10-6 100 80 60 40 Station ID 20 0 -20 Figure 2-24 Spatial Profile of Water Column 2378-TCDD TEQs Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Open circles represent non-detect. The human health Texas Surface Water Quality Standard is 7.97E-8 ug/L. ZL - \\helios\aq\D_Drive\Projects\Patrick_Bayou_Joint_Defense_Group\Patrick_Bayou(040284-01)\MODEL\EFDC\Post_process\Water_Column\plot\plot_all\pb_wc_data_spatial_depth_avg_longterm_hg_teq.pro Thu Oct 13 14:25:16 2016 Water Column Mercury (ug/L) Houston Ship Channel East Fork End Concrete-lined Channel Start Concrete-lined Channel 1.000 0.100 0.010 2009 Total Mercury 2009 Dissolved Mercury Upstream Total Mercury Upstream Dissolved Mercury 0.001 100 80 60 40 Station ID 20 0 -20 Figure 2-25 Spatial Profile of Water Column Mercury Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Open circles represent non-detect. The human health Texas Surface Water Quality Standard is 0.0250 ug/L. The aquatic life Texas Surface Water Quality standard is 1.1 ug/L. ZL - \\helios\aq\D_Drive\Projects\Patrick_Bayou_Joint_Defense_Group\Patrick_Bayou(040284-01)\MODEL\EFDC\Post_process\Water_Column\plot\plot_all\pb_wc_data_spatial_depth_avg_longterm_hg_teq.pro Thu Oct 13 14:33:18 2016 en t1 00 6 Se gm en t1 00 7 Se gm 100 Upper Houston Ship Channel Background Threshold Value (8.2 ng/L) ^ ^ 10 Total PCB (ng/L) Lower Houston Ship Channel 1 HH TSWQS (0.64 ng/L) Non-detect congeners set to zero. 0.1 I I I 20 I I I I I I I 15 I I I I 10 Upper HSC River Mile TCEQ TMDL Study Data I I I I I I 5 I I I I I 0 Patrick Bayou Confluence of San Jacinto River and Houston Ship Channel I I I I 5 Lower HSC River Mile I I I 0 Morgans Point Figure 2-26 Spatial Profile of Water Column Total PCB in the Houston Ship Channel Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Nondetects set to 0 and are plotted with open symbols. Samples from Galveston Bay assigned river mile -0.5. Studies included: TMDLTCEQ, TMDLTCEQ_PCB MJR/ZL - \\helios\D_Drive\Projects\Patrick_Bayou_Joint_Defense_Group\Patrick_Bayou(040284-01)\ANALYSIS\HSC_TMDL\pb_plot_spatial_chem_wat_1panel_forRI.pro Wed Aug 31 10:19:30 2016 en t1 00 6 Se gm en t1 00 7 Se gm 0.01 Upper Houston Ship Channel Lower Houston Ship Channel Background Threshold Value (0.0012 ng/L) ^^ DF TEQ (ng/L) 0.001 0.0001 HH TSWQS (7.97E-5 ng/L) 1e-005 1e-006 I I I 20 I I I I I I I 15 I I I I 10 Upper HSC River Mile TCEQ TMDL Study Data I I I I I I 5 I I I I I 0 Patrick Bayou Confluence of San Jacinto River and Houston Ship Channel I I I I 5 Lower HSC River Mile I I I 0 Morgans Point Figure 2-27 Spatial Profile of Water Column 2378-TCDD TEQs in the Houston Ship Channel Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Nondetects set to 0 and are plotted with open symbols. Samples from Galveston Bay assigned river mile -0.5. Studies included: TCEQ_2009, TMDLTCEQ DF TEQ: Dioxin/Furan Toxic Equivalents. TEQs were calculated using TEFs from TSWQ2014. MJR/ZL - \\helios\D_Drive\Projects\Patrick_Bayou_Joint_Defense_Group\Patrick_Bayou(040284-01)\ANALYSIS\HSC_TMDL\pb_plot_spatial_chem_wat_1panel_TEQ_forRI.pro Wed Sep 07 12:06:37 2016 £ ¤ 59 ON T US O H IP SH EL N AN H C £ ¤ 90 £ ¤ § ¦ ¨ 290 10 Site Location § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston § ¦ ¨ 45 Galveston Bay Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:30:33 PM Eas t Fo rk Total PCB Congener TEQ 1998 $ + Blue Crab Class A Station Lines (Avian) (ng/kg) Site Boundary as Defined in AOC 98 - 281 # * k j 282 - 341 " ) Shrimp Class B 342 - 434 F G 435 - 545 546 - 783 Blue Crab Class B Shrimp Class A [ Oyster NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. 0 Feet 750 1,500 Figure 2-28 PCB TEQ (avian) Results in Whole Body Shellfish Tissue Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 ON T US O H IP SH EL N AN H C £ ¤ 90 £ ¤ § ¦ ¨ 290 10 Site Location § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston § ¦ ¨ 45 Galveston Bay Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:31:07 PM Eas t Fo rk Total PCB Congener TEQ 1998 (Avian) (ng/kg) X Gulf killifish Station Lines Site Boundary as Defined in AOC 78.0 - 242 [ 243 - 445 446 - 714 715 - 837 838 - 1,170 NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. 0 Feet 750 1,500 Figure 2-29 PCB TEQ (avian) Results in Whole Body Gulf Killifish Tissue Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 ON T US O H IP SH EL N AN H C £ ¤ 90 £ ¤ § ¦ ¨ 290 10 Site Location § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston § ¦ ¨ 45 Galveston Bay Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:31:38 PM Eas t Fo rk Total PCB Congener TEQ 1998 (Avian) (ng/kg) G Gulf menhaden Station Lines Site Boundary as Defined in AOC 78.0 - 242 [ 243 - 445 446 - 714 715 - 837 838 - 1,170 NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. 0 Feet 750 1,500 Figure 2-30 PCB TEQ (avian) Results in Whole Body Gulf Menhaden Tissue Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas £ ¤ 59 ON T US O H IP SH EL N AN H C £ ¤ 90 £ ¤ § ¦ ¨ 290 10 Site Location § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston § ¦ ¨ 45 Galveston Bay Total PCB Congener TEQ 1998 ! Pinfish Station Lines (Avian) (ng/kg) # Q:\Jobs\040284-Patrick_Bayou\Maps\2014_06_FS_Figures_Revamp\PB FS Multiple Maps.mxd ckiblinger 8/29/2016 6:32:12 PM Eas t Fo rk Site Boundary as Defined in AOC 78.0 - 242 Sand seatrout " Striped mullet [ 243 - 445 446 - 714 715 - 837 838 - 1,170 NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2011. 0 Feet 750 1,500 Figure 2-31 PCB TEQ (avian) Results in Whole Body Pinfish, Sand Seatrout, and Striped Mullet Tissue Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas PB009 PB007.1 £ ¤ 59 PB001.1 PB011_A PB001.2 PB013.1 ON T US O H IP SH EL N AN H PB016 C 5 PB015 PB001.3 £ ¤ 90 10 15 PB002 £ ¤ § ¦ ¨ 290 PB004 10 PB016_A PB013.2 PB018_A PB019 PB022 Site Location PB005 PB003 PB007.2 PB018 § ¦ ¨ 610 Deer Park ^ Trinity Bay Houston PB009_A PB023_A PB022_A PB024_A PB026 Galveston Bay § ¦ ¨ 45 PB028 PB030 PB032 PB034 35 PB036 PB037 40 PB041_A PB042 PB043 PB044_A 45 PB047.1 PB048 PB047.2 50 PB048_A PB049 PB053_A 55 PB056 PB057_A PB057 60 PB059.2 PB059.1 PB063.2 PB063.1 65 PB063 5 PB069 EF-001 70 10 PB066 PB073 75 PB064 15 Eas t Fo rk PB074 PB077 20 25 30 80 PB081 35 40 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_08_PELQ\PB_PELQ_Thiessens.mxd ckiblinger 8/29/2016 6:39:18 PM 85 90 45 PB093 50 95 PB097 55 PB101_A NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2014. 105 Optimized Mean PEL-Q ! ( ! ( ! ( ! ( ! ( ! ( " ) ! ( 0.229 - 3.30 Station Lines Site Boundary as Defined in AOC 3.31 - 7.60 [ 7.61 - 11.7 11.8 - 26.7 26.8 - 80.7 80.8 - 166 2006 Sediment Sample 0 Feet 750 1,500 2009 Sediment Sample Figure 2-32 Optimized Mean PEL-Q Results in Surface Sediment Samples Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Figure 2-33 Processes Affecting Chemical Fate and Transport Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Figure 2-34 Mathematical Modeling Framework Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas PB009 PB007.1 ON T US O H IP SH ! . . ! ! . ! . 5 PB015 ! . 15 ! . ! .. ! .. ! ! . ! .! ! .! . ! . ! . ! . PB016_A PB018_A 20 PB013.2 £ ¤ 90 PB002 £ ¤ § ¦ ¨ 290 PB004 10 Site Location § ¦ ¨ 610 PB007.2 PB019 ! .! . ! . PB022 PB001.3 PB005 PB003 ! . . ! . ! PB018 59 PB001.2 PB013.1 EL N AN H PB016 C £ ¤ PB001.1 PB011_A Deer Park ^ Trinity Bay Houston PB009_A PB023_A PB022_A ! . ! . PB024_A PB026 Galveston Bay § ¦ ¨ 45 ! . ! . ! . PB030 PB028 PB032 PB034 . 35 ! ! . PB036 ! . 40 PB042 PB037 ! . ! . PB041_A ! . PB043 45 PB044_A ! ! . . ! . ! . ! . PB047.1 PB048 ! . 50 PB047.2 PB048_A PB049 ! . PB053_A 55 PB056 PB057 ! . ! . ! . PB057_A . ! .! 60 PB059.2 PB059.1 65 ! . ! ! . . ! . PB069 70 PB063.2 . !! . PB063.1 5 PB077 ! . 10 PB066 PB073 15 Eas t Fo rk 75 ! . PB064 EF-001 ! . ! . PB063 PB074 20 25 30 80 PB081 ! . 35 40 Q:\Jobs\040284-Patrick_Bayou\Maps\2014_08_PELQ\PB_PELQ_Thiessens.mxd ckiblinger 1/18/2016 3:04:36 PM 85 90 45 PB093 ! . 50 95 PB097 ! . 100 NOTES: Stations are placed in 500-foot intervals. Station numbers indicate length along channel in hundreds of feet. Aerial imagery: ESRI 2014. ! . 55 PB101_A 105 ! . Station Locations Mean PELQ Station Lines Site Boundary as Defined in AOC 0.229 - 4.47 [ 4.48 - 166 0 Feet 750 1,500 Figure 3-1 Areas Exceeding Benthic Risk Preliminary Remediation Goal Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas C:\Users\sballard\Documents\Projects\Patrick Bayou\2013\Feasibility Study\August 2016 Revisions\New Figures\Section 3 figures\Fig 3-2 Historical and Current Aerials.docx 1952 Aerial Imagery 2014 Aerial Imagery Figure 3-2 Historical and Current Aerial Imagery Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas l ne ton C 5 us Ho ip Sh n ha 0 0 5 0 10 20 SMA-3 10 -5 10 30 0 0 SMA-2 SMA-8 0 SMA-5 SMA-6 40 0 0 SMA-7 SMA-4 Aug 31, 2016 9:00am tgriga 0 0 60 5 LEGEND: 70 Sediment Management Area 0 SMA-9 Ea st Natural Recovery Area Fo rk 5 Existing Contours (2005, 1 ft Intervals) Site Boundary as Defined in AOC Station 80 0 0 70 0 K:\Projects\0284-Patrick Bayou Joint Defense Group\Patrick Bayou 2013\0284-RP-013.dwg Figure 4-1 50 SMA-1 SOURCE: Aerial imagery by ESRI, 2/5/11. Bathymetry by GBA dated May/June 2005. HORIZONTAL DATUM: Texas State Plane Central, NAD83, U.S. Feet. VERTICAL DATUM: NAVD88. 85 0 700 Scale in Feet Figure 4-1 Sediment Management Areas Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Figure 4-2 Adaptive Management Process Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas M:\Projects\Patrick_Bayou_Joint_Defense_Group\040284-01.08_RI_FS\Deliverables\FS Report\Agency Draft Final March 2017\Figures\Figure 4-2 March 2017.dotx l ne C 5 ton ip Sh n ha s ou H 0 0 5 0 10 20 SMA-3 10 -5 10 30 0 0 SMA-2 SMA-8 0 SMA-5 SMA-6 40 0 0 SMA-7 SMA-4 Aug 31, 2016 9:07am tgriga 0 0 60 5 70 0 SMA-9 Ea st LEGEND: Fo rk Monitored Natural Recovery 5 Existing Contours (2005, 1 ft Intervals) Site Boundary as Defined in AOC 70 0 0 80 0 K:\Projects\0284-Patrick Bayou Joint Defense Group\Patrick Bayou 2013\0284-RP-015-Alt2-3-4.dwg Figure 4-3 50 SMA-1 Station SOURCE: Aerial imagery by Microsoft Bing Maps, copyright 2010. Bathymetry by GBA dated May/June 2005. HORIZONTAL DATUM: Texas State Plane Central, NAD83, U.S. Feet. VERTICAL DATUM: NAVD88. 85 0 500 Scale in Feet Figure 4-3 Plan View Alternative 2: Monitored Natural Recovery Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas l ne C 5 ton ip Sh n ha s ou H 0 0 5 0 10 20 SMA-3 10 -5 10 30 0 0 SMA-2 SMA-8 0 SMA-5 SMA-6 40 0 0 SMA-7 SMA-4 Aug 31, 2016 9:07am tgriga 0 60 0 LEGEND: 5 ACBM with RCM Treatment AC Treatment 70 0 SMA-9 Monitored Natural Recovery Ea st 5 Fo rk Site Boundary as Defined in AOC 0 0 70 80 SMA-1 Existing Contours (2005, 1 ft Intervals) Station SOURCE: Aerial imagery by Microsoft Bing Maps, copyright 2010. Bathymetry by GBA dated May/June 2005. HORIZONTAL DATUM: Texas State Plane Central, NAD83, U.S. Feet. VERTICAL DATUM: NAVD88. 0 K:\Projects\0284-Patrick Bayou Joint Defense Group\Patrick Bayou 2013\0284-RP-015-Alt2-3-4.dwg Figure 4-4 50 85 0 500 Scale in Feet Figure 4-4 Plan View Alternative 3: Monitored Natural Recovery, AC Treatment and ACBM Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas PLACEMENT IN CHANNEL Mixing Apparatus (auger, tiller, tine sled) Amendment Mixed with Sediments PLACEMENT IN CHANNEL Amendment Reagent PLACEMENT FROM SHORELINE Biologically Active Zone Bulk Placement - Surface Application Sep 02, 2016 11:27am hhayward K:\Projects\0284-Patrick Bayou Joint Defense Group\Draft Feasibility Study\0284-RP-001 (Treatment Processes).dwg 4-5 PLACEMENT FROM SHORELINE Figure 4-5 Treatment Processes Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas l ne C 5 ton ip Sh n ha s ou H 0 0 5 0 10 20 SMA-3 10 -5 10 30 0 0 SMA-2 SMA-8 0 SMA-5 SMA-6 40 0 0 SMA-7 SMA-4 Aug 31, 2016 9:07am tgriga 0 60 0 LEGEND: 5 ACBM with RCM Treatment ACBM 70 0 SMA-9 Monitored Natural Recovery Ea st 5 Fo rk Site Boundary as Defined in AOC 0 0 70 80 SMA-1 Existing Contours (2005, 1 ft Intervals) Station SOURCE: Aerial imagery by Microsoft Bing Maps, copyright 2010. Bathymetry by GBA dated May/June 2005. HORIZONTAL DATUM: Texas State Plane Central, NAD83, U.S. Feet. VERTICAL DATUM: NAVD88. 0 K:\Projects\0284-Patrick Bayou Joint Defense Group\Patrick Bayou 2013\0284-RP-015-Alt2-3-4.dwg Figure 4-6 50 85 0 500 Scale in Feet Figure 4-6 Plan View Alternative 4: Monitored Natural Recovery Zones and ACBM Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas K:\Projects\0284-Patrick Bayou Joint Defense Group\Patrick Bayou 2013\0284-RP-008.dwg Figure 4-7 Sep 23, 2014 11:46am tgriga SOURCE: Details provided by Synthetex on 5/22/2014. Figure 4-7 ACBM Details Patrick Bayou Feasibility Study Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas APPENDIX A CHEMICAL FATE AND TRANSPORT MODELING STUDY PATRICK BAYOU SUPERFUND SITE Prepared for Patrick Bayou Joint Defense Group U.S. Environmental Protection Agency Prepared by Anchor QEA, LLC 614 Magnolia Avenue Ocean Springs, Mississippi 39564 March 2017 TABLE OF CONTENTS 1 2 3 INTRODUCTION ................................................................................................................ 1 1.1 Site and Project Background .............................................................................................1 1.2 Overview of Prior Hydrodynamic and Sediment Transport Modeling .........................1 1.3 General Description of Modeling Framework .................................................................2 1.4 Study Objectives ................................................................................................................3 1.5 Overview of Technical Approach .....................................................................................3 1.6 Appendix Organization .....................................................................................................4 HYDRODYNAMIC AND SEDIMENT TRANSPORT MODEL ........................................... 6 2.1 Modifications to Numerical Grid ......................................................................................6 2.2 Development and Application of 19-year Simulation (1993 to 2011) ............................7 2.3 Potential Effects of Deer Park Detention Basin ...............................................................8 CHEMICAL FATE AND TRANSPORT MODEL DEVELOPMENT AND CALIBRATION .................................................................................................................. 11 3.1 Model Development ........................................................................................................11 3.1.1 State Variables ..........................................................................................................11 3.1.2 Model Grid ................................................................................................................11 3.1.3 Boundary Conditions and External Sources ...........................................................12 3.1.4 Initial Conditions......................................................................................................14 3.1.4.1 Water Column ................................................................................................... 14 3.1.4.2 Sediment Bed ..................................................................................................... 14 3.1.5 Partition Coefficients ...............................................................................................16 3.1.6 Parameterization for Water Column Processes ......................................................18 3.1.6.1 Water Temperature ........................................................................................... 18 3.1.6.2 Volatilization Parameters.................................................................................. 19 3.1.6.3 Water Column Organic Carbon ....................................................................... 20 3.1.7 3.2 Parameterization for Sediment Processes ...............................................................21 3.1.7.1 Sediment Bed Physical Properties .................................................................... 22 3.1.7.2 Sediment Organic Carbon ................................................................................. 22 3.1.7.3 Sediment Bed Mass Transport Parameters ....................................................... 24 Model Calibration ............................................................................................................26 3.2.1 Calibration Approach ...............................................................................................26 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site i March 2017 040284-01.08 Table of Contents 4 5 6 3.2.2 Calibration Results ...................................................................................................28 3.2.3 Revised Calibration to 2014 Water Column Data ..................................................29 LONG-TERM FUTURE SIMULATIONS ........................................................................... 31 4.1 Approach and Setup ........................................................................................................31 4.2 Results ..............................................................................................................................32 MODEL UNCERTAINTY EVALUATION......................................................................... 35 5.1 Approach and Setup ........................................................................................................35 5.2 Results ..............................................................................................................................36 REFERENCES .................................................................................................................... 38 List of Tables Table 3-1 Mean PCB Concentrations at Locations Near Model Boundaries .................13 Table 3-2 Surface Sediment Scale Factors Used to Estimate Deep Sediment Concentrations .................................................................................................16 Table 3-3 Summary of Chemical-specific Parameters Used in Volatilization Equations ..........................................................................................................20 Table 4-1 Summary of Model-predicted Sediment Half-lives........................................34 List of Figures Figure 1-1 Mathmatical Modeling Framework Figure 1-2 Processes Affecting Chemical Fate and Transport Figure 2-1 Numerical Grid Including Concrete-lined Channel Figure 3-1 Average Sediment PCB Homolog Distribution in Patrick Bayou Figure 3-2 Locations of Model Boundaries and Water Column Sampling Locations used to Define Boundary Conditions Figure 3-3a Sediment Initial Conditions Methodology (PCB1-9) Figure 3-3b Sediment Initial Conditions Methodology (PCB10) Figure 3-4 Identification of Subsurface PCB Concentration Factors Applied to Surface Data for Model Initial Conditions Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site ii March 2017 040284-01.08 Table of Contents Figure 3-5 Annual Temperature Function Based on NOAA Data and Patrick Bayou Site Data Figure 3-6 Spatial Distribution of Water Column Dissolved Organic Carbon Concentrations Figure 3-7 Relationship between Percent of Class 1 Sediment and Fraction Organic Carbon Figure 3-8 Total Organic Carbon Methodology Figure 3-9 Spatial Profile of 2009/2011 Water Column Total PCB Data Figure 3-10a Spatial Profile of Model-predicted Water Column PCB1-9 Concentration and Data Figure 3-10b Spatial Profile of Model-predicted Water Column PCB10 Concentration and Data Figure 3-10c Spatial Profile of Model-predicted Water Column Total PCB Concentration and Data Figure 3-11 Spatial Profile of 2009/2011 and 2014 Water Column Total PCB Data Figure 3-12 Spatial Profile of Model-predicted Water Column Total PCBs Following Re-calibration to 2014 Water Column Data Figure 4-1 Model Grid Cells Remediated for SMA-1 Scenario Figure 4-2a-x Spatial Profile of Model-predicted Water Column Total PCB Concentration for MNR and Remediation of SMA-1 Figure 4-3 Model-predicted Site-wide Average Sediment (Top 10 cm) Total PCB Concentration Figure 4-4 Model-predicted Sediment (Top 10 cm) Total PCB Concentration, Averaged Every 10 Stations Figure 5-1a-x Uncertainty in Model-predicted Water Column Total PCB Concentration (MNR) Figure 5-2a-x Uncertainty in Model-predicted Water Column Total PCB Concentration (Remediate SMA-1) Figure 5-3 Uncertainty in Model-predicted Site-wide Average Sediment (Top 10 cm) Total PCB Concentration (MNR) Figure 5-4 Uncertainty in Model-predicted Site-wide Average Sediment (Top 10 cm) Total PCB Concentration (Remediate SMA-1) Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site iii March 2017 040284-01.08 Table of Contents List of Attachments Attachment 1 Chemical Fate and Transport Model Theory and Formulation Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site iv March 2017 040284-01.08 LIST OF ACRONYMS AND ABBREVIATIONS µm micrometers BEHP bis-2 ethyl-hexyl phthalate BERA Baseline Ecological Risk Assessment Cd freely dissolved porewater concentration (mg/L) cfs cubic feet per second cm centimeter cm/d centimeters per day cm2/s square centimeters per second cm /mol cubic centimeters per mole Cs PCB concentration associated with the sediment phase (mg/kg 3 dry sediment) CSM conceptual site model DOC dissolved organic carbon foc TOC fraction in sediment FS Feasibility Study g/mol grams per mole HLC Henry’s Law Constant HSC Houston Ship Channel IDW inverse distance weighting J/mol Joules per mole Kdoc chemical-specific dissolved organic carbon equilibrium partition coefficient kf Koc Kow octanol-water partition coefficient L/kg liters per kilogram mg/kg milligrams per kilogram mg/L milligrams per liter MNR monitored natural recovery ND non-detect ng/L nanograms per liter surface porewater exchange coefficient chemical-specific organic carbon equilibrium partition coefficient Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site v March 2017 040284-01.08 List of Acronyms and Abbreviations NOAA National Oceanic and Atmospheric Administration PAH polycyclic aromatic hydrocarbon PCB10 decachlorobiphenyl PCB1-9 mono- through nona-chlorobiphenyls PCB polychlorinated biphenyl PEL-Q Probable Effects Level-Quotient RAO Remedial Action Objectives RI Remedial Investigation Site Patrick Bayou Superfund Site SMA Sediment Management Area TMDL Total Maximum Daily Load TOC total organic carbon Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site vi March 2017 040284-01.08 1 INTRODUCTION 1.1 Site and Project Background Patrick Bayou is a tributary of the Houston Ship Channel (HSC) in Harris County, Texas, that discharges at the south shore of the HSC approximately 2.3 miles upstream of the HSC confluence with the San Jacinto River. The Patrick Bayou Superfund Site (Site) and the surrounding area have been used for industrial and commercial operations for nearly a century. During this time, chemicals associated with those practices were released from various sources via several migration pathways (e.g., direct discharge, spills, HSC interaction, upstream sources) to the Site sediments. Numerous sampling and investigative efforts were conducted to characterize the nature and extent of contaminants at the Site, understand sources of contaminants, develop conceptual site models (CSMs), and evaluate potential human health and ecological risks at the Site. These efforts are documented in the Patrick Bayou Remedial Investigation Report (RI; Anchor QEA 2013a). An evaluation of remedial alternatives to address contaminants within the sediments at the Site is being conducted in the Feasibility Study (FS). The primary indicator chemicals for surface and subsurface sediments in Patrick Bayou are polychlorinated biphenyls (PCBs; Anchor QEA 2013). To support the evaluations conducted in the RI and FS, modeling of hydrodynamics, sediment transport, and PCB fate and transport was performed. These modeling efforts are the subject of this appendix to the FS. 1.2 Overview of Prior Hydrodynamic and Sediment Transport Modeling A mathematical modeling framework was developed for Patrick Bayou that consisted of watershed, hydrodynamic, and sediment transport models that were linked together (Anchor QEA 2011). The watershed model was used to predict freshwater inflows to Patrick Bayou due to precipitation in the surrounding watershed. The hydrodynamic model was used to simulate temporal and spatial changes in water depth, current velocity, and bed shear stress. The sediment transport model was used to simulate temporal and spatial changes in suspended sediment concentrations in the water column, bed elevation changes (i.e., bed scour depth, net sedimentation rate), and changes in sediment bed composition (i.e., Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Introduction relative amounts of clay, silt, and sand from different sources). The models were developed and calibrated using Site-specific data. In particular, the sediment transport model was calibrated to suspended sediment concentration data collected during several high-flow events that occurred in October 2006 by adjusting the settling speed of cohesive sediment. In addition, net sedimentation rate data from Patrick Bayou were also used to calibrate the model over multi-year periods by adjusting the incoming sediment load during low-flow conditions. Successful calibration of the model produced a reliable tool to develop a CSM for sediment transport within the Site. Further use of the model included simulating sediment transport during high-flow events, including an event with a return period of 100 years. This simulation was used to estimate the location(s) and depth of bed scour in Patrick Bayou after a high-flow event. Additional details of the watershed, hydrodynamic, and sediment transport models can be found in the Patrick Bayou Sediment Transport Modeling Report (Anchor QEA 2011). The hydrodynamic and sediment transport models provide the basis for the Site-specific chemical fate and transport model described in this appendix. 1.3 General Description of Modeling Framework The chemical fate and transport model described in this appendix is an additional modeling component that uses information from the existing hydrodynamic and sediment transport models developed for this Site, which were documented in Anchor QEA (2011). The chemical fate and transport model is linked with the hydrodynamic and sediment transport models, as illustrated in Figure 1-1. The processes simulated by the chemical fate and transport model are depicted in Figure 1-2. The chemical fate and transport model simulates temporal and spatial changes in concentrations in the water column and sediment bed. In the water column, the model incorporates partitioning between the particulate and dissolved phases (as well as to dissolved organic carbon [DOC] in certain cases), chemical fluxes across the air-water interface due to volatilization and atmospheric deposition, and exchange fluxes at the sediment-water interface due to erosion, deposition, and dissolved-phase exchange processes. The model also simulates chemical dynamics within the sediment bed, which is discretized Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 2 March 2017 040284-01.08 Introduction into multiple layers to allow for simulation of vertical gradients in contaminant concentrations. The processes simulated in the bed include mixing (i.e., bioturbation) within the surficial sediments, vertical transport/exchange via diffusion within the porewater phase, and partitioning. The processes described above are combined together in mass balance computations for both the water column and the sediment bed. A detailed description of underlying theory and formulations of the model code (named AQFATE) is provided in Attachment 1. 1.4 Study Objectives The main goal of the modeling described in this appendix is to simulate physical and chemical processes that are controlling chemical fate and transport of PCBs within Patrick Bayou. Specifically, the primary objective of the modeling is to develop a mathematical framework that can: 1) build upon the existing hydrodynamic and sediment transport models for the Site; 2) provide a quantitative linkage between PCBs in sediments and PCBs in surface water (i.e., predict observed mass flux); and 3) be used as a predictive management tool to evaluate the effectiveness of remedial alternatives being evaluated in the FS, including natural recovery. 1.5 Overview of Technical Approach Development of a mechanistic model of chemical fate and transport is a common approach for contaminated sediment sites because it provides a means of simulating physical and chemical processes that are controlling chemical fate and transport, and it allows for estimation of future conditions under natural recovery and active remediation scenarios. The U.S. Environmental Protection Agency’s contaminated sediment guidance discusses development of chemical fate and transport models as a tool to support remedial decision making (USEPA 2005). As stated above, the primary indicator chemicals for surface and subsurface sediments in Patrick Bayou are PCBs. Other chemicals of concern at the Site related to potential risk to benthos in Site sediments include polycyclic aromatic hydrocarbons (PAHs), Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 3 March 2017 040284-01.08 Introduction bis 2 ethyl-hexyl phthalate (BEHP), and lead.1 The chemical fate and transport model focuses on simulation of PCBs; this is considered sufficient for purposes of the FS because PCBs are a key contributor to sediment Probable Effects Level-Quotient (PEL-Q) and are a driver for surface water quality issues. Further, it is likely that the other sorptive chemicals that contribute to PEL-Q at the Site will behave similar to PCBs with respect to natural attenuation due to deposition of clean sediments. The Patrick Bayou chemical fate and transport model incorporated data from the Site to develop the following inputs: 1) surface water concentrations at the model’s boundary locations; 2) concentrations of PCBs within the sediment bed; 3) sediment bed properties such as bulk density, porosity, and organic carbon content; 4) concentrations of dissolved and particulate organic carbon within the water column; and 5) Site-specific estimates of partition coefficients for PCBs based on Site porewater sampling. The chemical fate and transport model was calibrated to multiple rounds of Site-specific data on spatial patterns of water column PCB concentrations. In addition, sensitivity analyses were conducted to evaluate the impacts of parameter uncertainty on model results. The calibrated model was then used to make future predictions of water column and sediment concentrations in Patrick Bayou. 1.6 Appendix Organization This appendix is organized as follows: • Section 2 provides information on certain updates that were made to the hydrodynamic and sediment transport models that were previously developed for During the development of the Baseline Ecological Risk Assessment (BERA; Anchor QEA 2013b), several different quotient or toxic unit models that have been described in the open literature to predict potential sediment toxicity based on bulk sediment chemistry were evaluated. The performance of each model was assessed by applying it to Site-specific, co-located bulk sediment chemistry data and bioassay (i.e., toxicity) data for the Site. Of the models assessed, a mean quotient model using the Probable Effects Level was initially selected based on several performance criteria identified in the BERA Work Plan. This model, referred to as the mean Probable Effects Level-Quotient (PEL-Q), was refined using a series of optimization steps in the BERA (Anchor QEA 2013b). This optimized model included four contaminants of potential concern (total PCBs, total PAHs, lead, and BEHP) that demonstrated a statistically significant difference in concentration between toxic and nontoxic samples. This mean PEL-Q metric was then used as a line of evidence, in conjunction with other lines of evidence within a weight of evidence framework in the BERA (Anchor QEA 2013b), to characterize risk to the benthic community. Thus, this metric is relevant to describing the nature and extent of surface sediment conditions with respect to the four indicator chemicals included in the RI (Anchor QEA 2013a) and discussed herein. 1 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 4 March 2017 040284-01.08 Introduction Patrick Bayou (Anchor QEA 2011). This section also includes an evaluation of the effects of the Deer Park Detention Basin on hydrodynamics and sediment transport within the Site. • Section 3 provides information on the development and calibration of the chemical fate and transport model. • Section 4 describes long-term future simulations of natural recovery and active remediation that were conducted with the model to support the FS evaluations. • Section 5 describes an evaluation of model uncertainty that was conducted for the long-term future simulations. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 5 March 2017 040284-01.08 2 HYDRODYNAMIC AND SEDIMENT TRANSPORT MODEL As described in Section 1.2, a hydrodynamic and sediment transport model was previously developed and calibrated for Patrick Bayou (Anchor QEA 2011). To support the chemical fate and transport model for the Site, the hydrodynamic and sediment transport models were modified as follows: 1. The water column data collected in 2009 indicated the need to simulate changes in PCB concentrations within the upstream portion of the Site (located between stations PB101 and PB075, hereafter referred to as the concrete-lined channel2; Figure 2-1); therefore, the extent of the hydrodynamic and sediment transport model domain was extended upstream of PB075 to include this channel. Additional details on this revision to the numerical grid are provided in Section 2.1. 2. The original model simulation period for the hydrodynamic and sediment transport models was a 14-year period from 1993 through 2006 (Anchor QEA 2011). Because the primary dataset for calibration of the chemical fate and transport model is water column data collected during the RI in 2009 and 2011 (described in Section 3.2.1), the simulation period was extended to 19 years (i.e., 1993 through 2011). Additional details regarding the long-term simulation are provided in Section 2.2. 3. The 19-year hydrodynamic model simulation was also modified to include a high-flow event with an approximate 100-year return frequency to permit an evaluation of the impacts of such an event on chemical fate and transport model predictions. 2.1 Modifications to Numerical Grid The concrete-lined channel located upstream of PB075 is approximately 2,800 feet long and extends from the culverts at SH 225 to the upstream portion of Patrick Bayou. The geometry of the concrete-lined channel was represented in the model as a straight, one-dimensional numerical grid that was added to the original three-dimensional numerical grid within Patrick Bayou (Figure 2-1). The numerical grid for the concrete-lined channel includes 55 grid elements with an average length and width of 50 and 30 feet, respectively. Bathymetry Note that this area is a combination of a concrete-lined channel (upstream of approximately PB080) and an un-armored channel (between approximately PB075 and the railroad bridge located near PB080); however, for simplicity, this entire reach is referred to as the concrete-lined channel. 2 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 6 March 2017 040284-01.08 Hydrodynamic and Sediment Transport Model in this channel was specified as -4 feet mean sea level based on bathymetry data collected during June 2005. For the sediment transport model, the grid cells in the concrete-lined channel were set to hard bottom (i.e., no deposition or erosion), which is consistent with observations on the physical characteristics of the channel. 2.2 Development and Application of 19-year Simulation (1993 to 2011) Boundary condition inputs to the watershed, hydrodynamic, and sediment transport models for the 19-year simulation were developed by extending the original 14-year simulation period (1993 through 2006) by 5 years (i.e., to include 2007 through 2011). For the watershed model, precipitation data were obtained from the Harris County Office of Emergency Management (HC-OEM) and applied using the same methods described in Anchor QEA (2011). Results of the watershed model were used to specify freshwater inputs to the hydrodynamic model. For the hydrodynamic model, flow rates for the three OxyChem outfalls during the 19-year simulation period were specified using the average values of data collected during the 5-year period from 2007 to 2011 (i.e., 0.1, 22, and 5.5 cubic feet per second [cfs], for Outfalls 001, 002, and 003, respectively).3 Tidal boundary conditions in the HSC were specified using data from the National Oceanic and Atmospheric Administration (NOAA) tidal gauge station at Morgan’s Point. The magnitude and composition of incoming sediment loads were specified using the procedure discussed in Anchor QEA (2011). The effects of a 100-year flood were incorporated into the 19-year simulation as follows. First, a random number generator was used to select one year during the period from 1993 to 2000 (selected year was 1996). The largest high-flow event during 1996 occurred in September corresponding to an event with a return period of 2 years (i.e., peak flow rate of 2,700 cfs). The September 1996 event was transformed from a 2-year event to a 100-year event (peak flow rate of 10,000 cfs) by increasing the original peak freshwater inflows by 370%. These values are different from values used historically in the hydrodynamic model and are representative of more recent operational changes that have reduced flows in these outfalls. 3 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 7 March 2017 040284-01.08 Hydrodynamic and Sediment Transport Model The “base-case” 19-year sediment transport simulation used the parameter values for the calibration simulation described in Anchor QEA (2011). Two additional 19-year simulations were conducted to evaluate the sensitivity of model results to variations in the following model inputs: 1) incoming sediment load; 2) clay/silt settling speed; and 3) effective bed roughness (see Section 3.3.2 of Anchor QEA [2011] for a description of the original sensitivity analysis). The input combinations for these “lower bound” and “upper bound” simulations corresponded to results of the original sensitivity analysis that produced minimum and maximum net sedimentation rates within Patrick Bayou, respectively (see Section 3.3.2 of Anchor QEA [2011]). The performance and reliability of the revised hydrodynamic and sediment transport models were evaluated and compared to the original model results presented in Section 2 of Anchor QEA (2011). Because the only change to these models was an extension of the simulation period by 5 years, this evaluation showed that the performance (accuracy) of the revised model (with respect to predicted net sedimentation rates) is similar to and consistent with the original model, as expected. 2.3 Potential Effects of Deer Park Detention Basin In addition to the modifications and simulation discussed in the previous sections, potential effects of the proposed Deer Park detention basin on hydrodynamic and sediment transport model results were evaluated. The proposed detention basin is a 35-acre facility consisting of a pond and weir emplacements that are to be constructed in the City of Deer Park, with the objective of mitigating out-of-bank flooding of residential areas during high-flow events. Information on the proposed design of the detention basin was found in four documents: • Preliminary Engineering Report (PBS&J 2006) • Patrick Bayou Flood Mitigation Project Environmental Assessment (Essayon Engineering & Development, Inc. 2010) • Impact Analysis for Patrick Bayou Detention Facility (Pate Engineers 2012) • Patrick Bayou Detention Basin City of Deer Park Construction Notes (IDS Engineering Group 2012) Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 8 March 2017 040284-01.08 Hydrodynamic and Sediment Transport Model Historical flooding has occurred in the residential area south of SH 225 during high-flow events when the capacity of the highway culverts is exceeded. The Harris County Flood Control District evaluated the effectiveness of various flood control measures to solve the flooding problem, with the detention basin being selected as the optimum approach to achieve the flood control objectives (PBS&J 2006). The detention basin would affect hydrodynamics in Patrick Bayou because it would distribute the flood inflows over a longer time period and also reduce the peak inflow rate. In addition, the detention basin would tend to reduce sediment loads to Patrick Bayou during extreme high-flow events. The proposed detention basin has a storage volume of 258 acre-feet of water (PBS&J 2006). Flood flow would be diverted into the pond along the drainage channel by an in-line weir and a side weir. The combination of the weirs would function to hold back and divert the flow to the detention basin. The reports listed above primarily discuss the results of one-dimensional hydrodynamic (HEC-RAS) modeling of the 100-year flood and the design of the weir system. However, the HEC-RAS modeling only simulates steady-state conditions, and the reports do not provide detailed information on the dynamic effects of the detention basin. Thus, insufficient information was available to incorporate the effects of the proposed detention basin during high-flow events into the hydrodynamic and sediment transport models. The available information presented in the above reports indicates that the proposed detention basin would reduce the peak flow rate into Patrick Bayou during the 100-year flood by about 10%. In addition, the detention basin would only affect flow into Patrick Bayou during floods with return periods of about 10 years or greater. For floods with return periods of 10 years or more, the reduced inflow rates to Patrick Bayou (i.e., 10% decrease for 100-year flood) would produce lower current velocities than present conditions and, thus, less sediment bed erosion. It is anticipated that the proposed detention basin would have a minor effect on sediment loads to Patrick Bayou, which would correspond to relatively minor changes in long-term sedimentation rates in the bayou. A diagnostic simulation was conducted with the model to evaluate the potential effects of the proposed detention basin on Patrick Bayou sediment transport during a 100-year flood. For this diagnostic simulation, the peak inflow to the hydrodynamic and sediment transport Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 9 March 2017 040284-01.08 Hydrodynamic and Sediment Transport Model models during the 100-year flood simulation was reduced by 10% (i.e., from 10,000 to 9,000 cfs). Model predictions of the effects of a 100-year flood for current conditions (i.e., peak flow rate of 10,000 cfs) are presented in Section 3.2 of Anchor QEA (2011). The results of the diagnostic simulation (i.e., peak flow rate of 9,000 cfs) showed that the proposed detention basin would reduce net erosion depths by about 5 to 10% during the 100-year flood. This result is consistent with the reduced peak flow rate that would be produced by the proposed detention basin (i.e., reduced peak flow rate would cause lower current velocities and, thus, less erosion). Therefore, the proposed detention basin would have a relatively minor effect on hydrodynamics and sediment transport processes within Patrick Bayou during high-flow events and over multi-year periods. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 10 March 2017 040284-01.08 3 CHEMICAL FATE AND TRANSPORT MODEL DEVELOPMENT AND CALIBRATION 3.1 Model Development Application of the chemical fate and transport model framework (described in Section 1.3 and Attachment 1) to the Site was accomplished by using a combination of data collected from the Site during the RI (Anchor QEA 2013a), information on PCBs documented in the scientific literature, experience from modeling other systems, and professional judgment to specify the parameters of the governing model equations. A limited number of parameters were adjusted so that the model was able to reproduce the trends in PCB concentrations within the Site over relevant spatial and temporal scales. The subsections that follow describe the development of the model and how its various input parameters were specified. 3.1.1 State Variables The chemical fate and transport model was developed to simulate PCBs as two separate homolog groupings: the sum of mono- through nona-chlorobiphenyls (PCB1-9) and decachlorobiphenyl (PCB10). This approach was selected primarily because of the observed difference in spatial distribution of these two homolog groupings in the water column and sediments of Patrick Bayou. Figure 3-1 shows average PCB homolog weight percents in sediments downstream (top panel) and upstream (bottom panel) of approximately Station PB040. As shown in this figure, the weight percent of PCB10 (relative to PCB1-9) is higher in sediments downstream of PB040 compared to sediments upstream of that location. These two homolog groupings exhibit differing spatial patterns and have different physicochemical properties (e.g., partitioning); therefore, the approach of simulating these two homolog groupings separately increases the robustness of the model. In the end, the model predictions were summed to calculate total PCBs. 3.1.2 Model Grid The chemical fate and transport model uses the same curvilinear three-dimensional grid developed for the hydrodynamic and sediment transport models described in Anchor QEA (2011). The model grid contains about 930 grid cells in the horizontal plane and is also segmented into ten layers vertically in the water column, resulting in a total of about 9,300 grid cells. Spatially, the model domain extends a total distance of approximately Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 11 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration 2 miles, from the upstream end of the concrete-lined channel down through Patrick Bayou to its confluence with the HSC.4 The sediment bed is simulated in the chemical fate and transport model using multiple layers; such discretization of the bed is necessary to properly simulate changes in surface sediment concentrations over time and to capture vertical concentration gradients within the sediment. One of the primary uses of the model is to predict concentrations in the surficial sediment zone, which has been taken to be approximately the upper 4 inches of sediment in this application (defined based on Mixing Zone Layer Study; Anchor QEA 2009). The bed model for the Site was segmented into twelve 1-inch layers, for a total bed thickness of 1 foot. Although the total simulated bed thickness does not necessarily correspond to the total thickness of sediments across the Site, it provides ample resolution to allow for simulation of the surface sediment layer (i.e., top 4 inches), as well as potential interactions of that layer with deeper sediments. 3.1.3 Boundary Conditions and External Sources As described in Anchor QEA (2011), the hydrodynamic model is defined by several boundary conditions: 1) an upstream inflow boundary at Station PB101; 2) inflow from the East Fork; and 3) two downstream water surface elevation boundaries (i.e., free surface that reflects tidal fluctuations) within the HSC, with one boundary located upstream of Patrick Bayou and the other located downstream. Locations of these boundaries are shown in Figure 3-2. The chemical fate and transport model requires that contaminant concentrations be specified at each of these boundaries throughout the model calibration period. The available surface water data at these boundary locations were limited, but exhibited limited variability in PCB concentrations; as such, boundary condition concentrations were based on average values calculated from the data. The following samples were used to calculate average water As described in Anchor QEA (2011), the model domain also includes a 4-mile portion of the HSC that extends from the NOAA gauging station at Battleship Texas State Park (downstream boundary) to a location about 2 miles upstream of Patrick Bayou confluence. Inclusion of the HSC in the model domain increases the predictive capability and reliability of the hydrodynamic model; however, the chemical fate and transport model calculations are only relevant within Patrick Bayou, not the HSC. 4 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 12 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration column concentrations at each of the various boundary locations (sample locations are shown in Figure 3-2): • Upstream Inflow Boundary: This boundary condition was characterized by one water column sample collected at Station PB101 during the RI in 2011. • East Fork Inflow Boundary: This boundary condition was characterized by two water column samples collected at Station EF006 during the RI in 2009. • HSC Downstream Boundaries: The HSC boundary conditions were characterized by water column sampling data collected as part of the Patrick Bayou Total Maximum Daily Load (TMDL) Study conducted by the Texas Commission on Environmental Quality (TCEQ). The upstream and downstream boundary concentrations in the HSC were characterized by PCB concentrations at TMDL sampling stations 15979 and 11264, respectively. Table 3-1 contains a summary of the average water column concentrations at the sampling locations described above. Table 3-1 Mean PCB Concentrations at Locations Near Model Boundaries Location Station PCB1-9 (ng/L) PCB10 (ng/L) Number of Samples PB Upstream PB101 5.3 0.0094 (ND) 1 August 2011 East Fork EF006 2.2 0.076 2 November 2009 HSC (Upstream) 15979 3.8 0.72 4 August 2002 to May 2009 HSC (Downstream) 11264 3.3 0.50 4 August 2002 to May 2009 Collection Date Range Notes: ND – non-detect ng/L – nanograms per liter These average concentrations were specified in the model to be constant over time, in all ten vertical water column layers at the respective boundaries. The hydrodynamic model also specifies inflows for three industrial outfalls and three direct runoff locations in the main channel of Patrick Bayou (Anchor QEA 2011); PCB concentrations for all six of these inflows were set to zero given that current direct discharge to the Site from permitted outfalls is not Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 13 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration considered a significant source of contaminants to the Site (see Section 5.2 of the RI, Anchor QEA 2013a). 3.1.4 Initial Conditions The chemical fate and transport model was initially calibrated to surface water data collected in 2009 and 2011 (described in detail in Section 3.2); thus, initial concentrations in the model needed to be specified consistent with PCB levels observed in the system in 2009. The following subsections describe how initial water column and sediment concentrations were specified in the chemical fate and transport model. 3.1.4.1 Water Column The chemical fate and transport model requires specification of an initial water column concentration within each horizontal and vertical grid cell at the beginning of a model simulation. In general, surface water model predictions are insensitive to water column initial conditions because the water containing these initial concentrations is “washed out” of the system relatively quickly by incoming flows and tides. As a result, initial water column concentrations in the model were set to zero, and the model rapidly “spun up” to concentrations that reflect inputs from boundaries and fluxes from sediments. 3.1.4.2 Sediment Bed The chemical fate and transport model requires specification of an initial sediment concentration within each grid cell and for each vertical layer within the simulated bed at the beginning of a model simulation. Surface sediment data from the RI collected in 2009 were used to define the initial sediment concentrations within Patrick Bayou. These data provided good spatial coverage within Patrick Bayou, although spatial coverage in the concrete-lined channel was somewhat limited in this dataset. The 2009 RI sediment dataset generally characterized PCBs within the top 4 inches of sediment; data to characterize PCB concentrations at depth were limited to 12 deeper, high-resolution cores collected throughout Patrick Bayou in 2006. The methods used to assign initial sediment concentrations in the model based on these data are described in the following subsections. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 14 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration 3.1.4.2.1 Surface Sediments The methodology used to develop surface sediment initial conditions was to interpolate the 2009 PCB data using inverse distance weighting (IDW), consistent with the methods used in the RI.5 The interpolation was performed at a 1-foot horizontal resolution and then projected onto the fate model grid by spatially averaging the interpolated values within each model grid cell. The process described above was repeated for each of the two homolog groupings simulated by the model (i.e., PCB1-9 and PCB10). Figures 3-3a and 3-3b present the following: 1) the original raw 2009 surface sediment data; 2) the IDW interpolated surface generated based on the data; and 3) the final surface sediment initial conditions specified for the model grid for PCB1-9 and PCB10, respectively.6 Because the 2009 sediment data represent the top 4 inches of sediment, the initial concentrations described above were specified for each of the top four 1-inch layers of the sediment bed in the model. 3.1.4.2.2 Subsurface Sediment As described above, fewer data are available to characterize the subsurface sediments (i.e., 12 high-resolution sediment cores collected in 2006). Data from these cores were reviewed to develop scale factors that were applied to the interpolated surface sediment concentrations to estimate subsurface concentrations for use in the model. Vertical profiles of PCB concentrations observed in the 2006 cores generally showed increasing concentrations with depth in many areas of the Site; thus, scale factors were developed that varied over both space (i.e., longitudinal distance along Patrick Bayou) and depth to represent the observed patterns. Subsurface scale factors were developed by calculating the ratio of subsurface to surface sediment PCB concentrations in each interval within each high-resolution core; these ratios are plotted as a function of depth in Figure 3-4. The dotted line in this figure To increase normality in the surface sediment data used to develop the fate model initial conditions, the concentrations were log transformed prior to the IDW analysis. This log transformation approach follows the data treatment used for total PCBs in the BERA (Anchor QEA 2013b). After the interpolation, the results were back-transformed prior to averaging the values onto the fate model grid. 6 Note that the model grid includes both the main channel of Patrick Bayou and a portion of the floodplain (as shown in Figure 2-1). As such, sediment PCB inputs were developed for the entire model grid (i.e., the IDW interpolation shown in the middle panels of Figures 3-3a and 3-3b extend out into the floodplain). However, the model results focus on the main channel. 5 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 15 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration represents the average scale factor within each depth interval; Table 3-2 provides a summary of these average scale factors that were then applied to the surface sediment initial conditions to estimate subsurface concentrations in the model. Table 3-2 Surface Sediment Scale Factors Used to Estimate Deep Sediment Concentrations Sediment PCB Concentration Scale Factor (Relative to Surface) Model Layers Depth (inches) HSC to PB030 PB030 to PB073 Upstream of PB073 1–4 0–4 1 1 1 5–8 4–8 2 5 1 9 – 12 8 – 12 4 15 1 3.1.5 Partition Coefficients Due to the hydrophobic nature of PCBs, partitioning between particulate and dissolved phases is a key process affecting PCB fate and transport in a surface water/sediment system. Partitioning of organic contaminants between the aqueous and sorbed (i.e., sediment) phases is described in the fate and transport model using chemical-specific organic carbon equilibrium partition coefficients (𝐾𝐾𝑜𝑜𝑜𝑜 ; see Section 2.3 of Attachment 1). In addition, DOC can account for an important fraction of sorption for highly hydrophobic contaminants (such as PCBs), so a 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 (e.g., see Equation 8 in Attachment 1) was also specified for the model. Selection of values for 𝐾𝐾𝑜𝑜𝑜𝑜 and 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 for use in the model was based on a review of literature sources and a detailed assessment of the sediment porewater data collected during the RI, as described in the remainder of this section. Paired measurements of PCB concentrations in sediment and porewater from ten samples collected in Patrick Bayou during the RI were first used to estimate Site-specific 𝐾𝐾𝑜𝑜𝑜𝑜 values using the traditional two-phase partitioning model shown by the equation below: 𝐾𝐾𝑂𝑂𝑂𝑂 = Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 𝐶𝐶𝑠𝑠 𝐶𝐶𝑑𝑑 𝑓𝑓𝑜𝑜𝑜𝑜 16 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration where: 𝐶𝐶𝑠𝑠 = = freely dissolved porewater concentration (mg/L) 𝑓𝑓𝑜𝑜𝑜𝑜 = total organic carbon (TOC) fraction in sediment 𝐶𝐶𝑑𝑑 PCB concentration associated with the sediment phase (milligrams per kilogram [mg/kg] dry sediment) Initial calculations produced 𝐾𝐾𝑜𝑜𝑜𝑜 values that were lower than anticipated based on literature. Additional review of the data and sampling procedures indicated that the porewater concentrations likely contained some amount of particulate matter in the samples because no filtration was performed after extraction of porewater from the sediments (Anchor Environmental, L.L.C. 2007). For example, measurements of TOC and DOC in the porewater samples differed by significant amounts, with TOC being twice as high as DOC on average, confirming the presence of particulate matter in the samples. Therefore, the calculation of Site-specific 𝐾𝐾𝑜𝑜𝑜𝑜 values was revised to include a correction to account for the presence of particulate matter in the samples. The correction involved subtracting out the particulate-phase contribution to the porewater PCB concentration (i.e., to convert it to the freely dissolved concentration) using measured TOC and DOC in the samples and literature-based estimates of 𝐾𝐾𝑜𝑜𝑜𝑜 and 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 (which were subsequently found to be similar to the final calculated values). Following correction of the porewater data, the calculated Site-specific 𝐾𝐾𝑜𝑜𝑜𝑜 values for the ten samples ranged as follows: • • PCB1-9 log 𝐾𝐾𝑜𝑜𝑜𝑜 range: 4.6 to 5.6 liters per kilogram (L/kg) PCB10 log 𝐾𝐾𝑜𝑜𝑜𝑜 range: 6.1 to 7.2 L/kg As expected, calculated log 𝐾𝐾𝑜𝑜𝑜𝑜 values for PCB10 were higher than the values for PCB1-9 because PCB10 is more hydrophobic. As a means of checking these ranges, 𝐾𝐾𝑜𝑜𝑜𝑜 values for PCB homologs were also developed using several widely used literature models (DiToro 1985; Baker et al. 1996; Swackhamer and Armstrong 1987) that calculate 𝐾𝐾𝑜𝑜𝑜𝑜 based on the chemical’s octanol-water partition coefficient (𝐾𝐾𝑜𝑜𝑜𝑜 ), which is also well documented in the literature for PCBs (e.g., Hawker and Connell 1988). These literature models yielded a range of partition coefficients for each of the modeled homolog groupings that generally matched the values calculated from the Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 17 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration Site-specific porewater data listed above (e.g., log 𝐾𝐾𝑜𝑜𝑜𝑜 of 5 to 6 for PCB1-9 and 7 to 8 for PCB10). The calculated Site-specific 𝐾𝐾𝑜𝑜𝑜𝑜 ranges listed above, as well as the literature-based ranges, were used to guide selection of final 𝐾𝐾𝑜𝑜𝑜𝑜 values during model calibration. The final log 𝐾𝐾𝑜𝑜𝑜𝑜 values specified in the model were 5.3 and 7.5 for PCB1-9 and PCB10, respectively. In addition, sorption to dissolved organic matter can be important for contaminants with log 𝐾𝐾𝑜𝑜𝑜𝑜 values greater than approximately 6 to 7 (e.g., Chiou et al. 1986). Therefore, based on the partition coefficient (𝐾𝐾𝑜𝑜𝑜𝑜 ) values summarized above, a three-phase partitioning formulation was used in the model by specifying a value for 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 . Predictive relationships developed by Burkhard (2000) for sediment porewater and surface waters were used to specify 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 in the fate and transport model (𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 = 0.1 𝐾𝐾𝑜𝑜𝑜𝑜 in sediment porewater and 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 = 0.01 𝐾𝐾𝑜𝑜𝑜𝑜 in surface water). 3.1.6 Parameterization for Water Column Processes A number of parameters representing physical- and chemical-specific characteristics and fate and transport properties within the water column needed to be specified in the model (i.e., the various parameters included in the equations presented in Attachment 1). These parameters and coefficients were developed from a combination of Site data (when available), literature, and experience with other systems. A brief description of each of the water column input parameters is included in the subsections below. 3.1.6.1 Water Temperature The rates of most kinetic reactions in natural waters increase with temperature (e.g., Chapra 1997). Water temperature is used within the chemical fate and transport model to account for such temperature effects. For example, as discussed in Section 2.6.1.3 of Attachment 1, several of the terms used in calculating the volatilization mass transfer coefficient are a function of water temperature. Water temperature data from three RI sampling locations located in Patrick Bayou (PB020, PB045, and PB075) and one NOAA station located relatively close to the Site at Battleship Texas State Park (Station No. 8770743) were obtained to develop an annual temperature function for the fate and transport model based on measurements from a representative Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 18 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration 4-year period (2004 to 2008). A monthly average temperature function was specified in the model based on these data, because year-to-year variations in this cycle are not significant on the timescales of importance. Figure 3-5 shows the water temperature data and the monthly average function that was fit through these data and input to the fate and transport model. 3.1.6.2 Volatilization Parameters Based on the equations presented in Section 2.6.1.3 of Attachment 1, the model computes volatilization flux for each computational grid element dynamically over the course of a simulation. The following parameters are provided as input to the model to support these calculations: • Henry’s Law Constant (HLC): The model uses the input value of HLC divided by the product of the absolute water temperature and universal gas constant to dynamically calculate the unitless HLC. HLC values used in the model for PCB1-9 and PCB10 were assigned based on published literature (Table 3-3). • Concentration of contaminant in ambient air: This input was set equal to zero for both PCB1-9 and PCB10 because atmospheric concentrations (vapor phase) of PCBs are typically several orders of magnitude lower than those in water, due to the fact that PCBs have very low fugacity in air. • Wind speed (at an elevation of 10 meters): A constant value of 3.6 meters per second was used, consistent with average wind speed in Houston, Texas, as recorded by NOAA.7 • The molecular weight and molar volume of each contaminant: These inputs are used by the model to dynamically calculate the Schmidt Number of the contaminant in air and water as a function of temperature. Values were assigned based on published chemical properties literature (Table 3-3). 7 http://www.ncdc.noaa.gov/oa/climate/online/ccd/avgwind.html Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 19 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration Table 3-3 Summary of Chemical-specific Parameters Used in Volatilization Equations Modeling Compound Molecular Weighta (g/mol) Molar Volumeb (cm3/mol) Henry’s Law Constantc (J/mol) PCB1-9 299 270 20 PCB10 499 394 5 Notes: a Molecular weights were calculated for each homolog grouping using the periodic table and chemical formulas. Molecular weight for PCB1-9 was calculated from these homolog-specific values and the relative weight percent of each homolog grouping in water and sediment sample results. b Molar volume values are presented in Mackay et al. 1992 (referenced as LeBas method; Shiu and Mackay [1986]). Molar volume for PCB1-9 was calculated from individual homolog values and the relative weight percent of each homolog grouping in water and sediment sample results. c HLC values were selected after review of several literature sources (USEPA 2012; Brunner et al. 1990; Bamford et al. 2000; and Fang et al. 2006), and are generally equivalent to the mid-point of the ranges reported in these references. cm3/mol – cubic centimeters per mole g/mol – grams per mole J/mol – Joules per mole The remaining parameters used in the volatilization equations presented in Attachment 1 are computed internally by the model or are provided as model inputs as in the case of temperature. Although the volatilization gas and liquid phase mass transfer coefficients are computed internally within the model, the model overrides the computed values if they are lower than a user-defined value. Minimum gas- and liquid-phase mass transfer coefficients of 100 and 0.0864 meters per day, respectively, were assigned based on Mackay and Yeun (1983). Finally, the temperature correction for the overall volatilization mass transfer coefficient was based on a typical θ value in the Arrhenius Equation of 1.025 (Chapra 1997). 3.1.6.3 Water Column Organic Carbon The chemical fate and transport model requires specification of organic carbon concentrations for water column particulate matter (𝑓𝑓𝑜𝑜𝑜𝑜 ), as well as the dissolved phase (i.e., DOC), to allow calculation of three-phase equilibrium partitioning according to the equations presented in Section 2.3 of Attachment 1. There are no direct measurements of the organic carbon content of water column particulate matter (i.e., reported on a mass fraction basis as 𝑓𝑓𝑜𝑜𝑜𝑜 ) for the Site. Calculation of 𝑓𝑓𝑜𝑜𝑜𝑜 was considered using measured TOC, DOC, and total suspended solids concentrations in the surface water, but it could not be Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 20 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration reliably calculated because differences between measured DOC and TOC were less than the precision of the two measurements. Therefore, a spatially and temporally constant 𝑓𝑓𝑜𝑜𝑜𝑜 value of 10% was specified for the Patrick Bayou fate and transport model based on data from other sites.8 As discussed in Anchor QEA (2011), the sediment transport model simulates four sediment size classes (Class 1 represents clay/silt-sized particles and Class 2 through Class 4 represent particle sizes corresponding to sands and gravel). The information directly passed to the chemical fate and transport model by the sediment transport model (sediment size classes and erosion and deposition fluxes) is done so separately for each simulated size class; therefore, water column 𝑓𝑓𝑜𝑜𝑜𝑜 values are required for each simulated size class. As discussed in Section 3.1.7.2.1, evaluation of sediment TOC and grain size relationships suggests that Class 1 sediment has an organic carbon content that averages seven times higher than that of the coarser sediment size classes. That same relationship was maintained for the organic carbon content of water column suspended sediments specified in the model. The total 𝑓𝑓𝑜𝑜𝑜𝑜 developed from the average of 10% (described above) translates to an 𝑓𝑓𝑜𝑜𝑜𝑜 on water column size Class 1 particles of 11%, and 1.6% on water column size Class 2 through Class 4—these values were specified as model inputs. Water column DOC collected during the RI showed spatial variation across the Site (Figure 3-6); DOC was generally highest in Patrick Bayou immediately downstream of the concrete-lined channel, and decreased with distance downstream toward the HSC. Therefore, water column DOC was specified as spatially variable (temporally constant) in the fate and transport model; the green dashed line in Figure 3-6 represents the values specified in the model. 3.1.7 Parameterization for Sediment Processes A number of parameters representing physical and chemical-specific characteristics and fate and transport properties within the sediment bed needed to be specified in the model (i.e., the various parameters included in the equations presented in Attachment 1). These For example, data from the nearby San Jacinto River indicated an average water column 𝑓𝑓𝑜𝑜𝑜𝑜 of approximately 9% (Anchor QEA 2012). 8 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 21 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration parameters and coefficients were developed from a combination of Site data (when available), literature, and experience with other systems. A brief description of each of the sediment bed input parameters is included in the following subsections. 3.1.7.1 Sediment Bed Physical Properties The chemical fate and transport model uses two parameters to characterize the physical properties of the sediment bed: bulk density (on a dry weight basis) and porosity. Fate model input values for these two parameters were specified consistent with values used in the sediment transport model; spatially and temporally constant values of 0.77 and 0.7 grams per cubic centimeter were specified for bulk density and porosity, respectively. 3.1.7.2 3.1.7.2.1 Sediment Organic Carbon Fraction Organic Carbon The fate and transport model requires specification of the organic carbon content of sediments to allow calculation of contaminant partitioning in the bed. As described in Anchor QEA (2011), the sediment transport model simulates sediment in the following four particle size classes: • Class 1: less than 62 micrometers (µm) (silt/clay) • Class 2: 62 to 250 µm (fine sand) • Class 3: 250 to 1,000 µm (medium/coarse sand) • Class 4: greater than 1,000 µm (coarse sand and gravel) It is necessary to specify an organic carbon fraction for each of these size classes in the fate and transport model. Analysis of Site-specific data indicates that organic carbon varies by sediment size class, which is expected (e.g., fine sediments generally have a higher organic carbon content than coarse sediments). Figure 3-7 shows 𝑓𝑓𝑜𝑜𝑜𝑜 in RI surface sediment samples compared to the percent of Class 1 sediments (i.e., fraction silt and clay) based on grain size data from the corresponding samples. This figure demonstrates there is a positive relationship between these two parameters, in which samples with a higher fraction of clay and silt have higher organic carbon. Evaluations exploring similar relationships between 𝑓𝑓𝑜𝑜𝑜𝑜 and the percent by weight for the other size classes indicated that the sediment size Class 1 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 22 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration content (i.e., silt/clay) exhibited the strongest relationships with 𝑓𝑓𝑜𝑜𝑜𝑜 and that differences in 𝑓𝑓𝑜𝑜𝑜𝑜 among the three coarser sediment size classes (i.e., Class 2 through Class 4) were small. To represent the observed variation in 𝑓𝑓𝑜𝑜𝑜𝑜 with grain size demonstrated by the Site data, a two-class mixing formulation was used to fit the relationship illustrated by the data. This formulation assumed that the 𝑓𝑓𝑜𝑜𝑜𝑜 of the coarse sediment fractions (i.e., Class 2 through Class 4) can be expressed as a ratio of the 𝑓𝑓𝑜𝑜𝑜𝑜 of sediment size Class 1. Based on this approach, a log-linear least squares regression was performed to develop a best fit to the data, as shown by the line in Figure 3-7. This best fit line corresponds to a ratio of 𝑓𝑓𝑜𝑜𝑜𝑜 in sediment size Class 1 to 𝑓𝑓𝑜𝑜𝑜𝑜 in sediment size Class 2 through Class 4 of seven. That is, this formulation indicates that the 𝑓𝑓𝑜𝑜𝑜𝑜 of sediment size Class 1 is approximately seven times higher than that of the coarser fractions. This difference is evident by the 𝑓𝑓𝑜𝑜𝑜𝑜 values at the two extreme ends of the data shown in Figure 3-7: the average 𝑓𝑓𝑜𝑜𝑜𝑜 of samples with almost 100% silt/clay (Class 1) is approximately 4%, whereas the 𝑓𝑓𝑜𝑜𝑜𝑜 of samples with almost no silt/clay (Class 1) averages approximately 0.6%. The sediment 𝑓𝑓𝑜𝑜𝑜𝑜 was then specified in the model so that, at any point in space, it matched both the TOC from the nearby surface sediment sample, as well as the observed sevenfold difference in 𝑓𝑓𝑜𝑜𝑜𝑜 among sediment size classes discussed above. First, an IDW interpolation was performed for the surface sediment TOC data (using the same dataset and interpolation approach used to develop the sediment initial conditions as described in Section 3.1.4.2). Second, the IDW raster surface was averaged over the model grid giving each model grid cell a TOC value (using the same approach described in Section 3.1.4.2 to develop the sediment initial conditions). Figure 3-8 shows the following: 1) the original raw surface sediment TOC data; 2) the IDW raster surface generated based on the TOC data; and 3) the final TOC concentrations mapped onto the model grid. Third, for each model grid cell, organic carbon was apportioned among the four sediment size classes based on the size class distribution predicted by the sediment transport model at that location. For example, consider one sample location with a TOC of 5%. If the sediments at that location are 70% sediment size Class 1 and 30% Class 2 through Class 4, the resulting Class 1 𝑓𝑓𝑜𝑜𝑜𝑜 would be 6.7% and that of Class 2 through Class 4 would be 0.96% based on the ratio of 7 between Class 1 and Class 2 through Class 4. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 23 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration 3.1.7.2.2 Porewater Dissolved Organic Carbon Porewater DOC values in samples collected from Patrick Bayou ranged from 12 to 57 mg/L, with an average of approximately 30 mg/L. These data did not exhibit any strong spatial pattern; therefore, a constant value of 30 mg/L was specified in the fate and transport model. 3.1.7.3 Sediment Bed Mass Transport Parameters In addition to chemical fluxes associated with deposition and resuspension (predicted by the sediment transport model), the fate and transport model simulates the following three processes by which contaminants are transported vertically within the sediment bed and/or exchanged with the overlying water column (see Sections 2.4.2 and 2.5 of Attachment 1): 1) diffusion of dissolved-phase and DOC-bound contaminants within sediment porewater; 2) exchange of dissolved-phase and DOC-bound contaminants at the sediment/water interface; and 3) mixing (bioturbation) of particulate-phase (as well as dissolved-phase and DOCbound) contaminants within the upper layers of the bed. The following subsections discuss how each of these mass transport processes was parameterized in the model. 3.1.7.3.1 Porewater Diffusion Diffusive transport of contaminants within sediment porewater is computed in the model using a molecular diffusion coefficient, which is adjusted by a tortuosity factor to account for porous media effects (see Section 2.4.2 of Attachment 1). Molecular diffusion coefficient values for the two simulated PCB homolog groupings were specified based on literature (USEPA 2005): • PCB1-9: 2.0E-06 square centimeters per second (cm2/s) • PCB10: 1.6E-06 cm2/s These molecular diffusion coefficients were subsequently multiplied by a tortuosity factor of 0.25, based on the formulations of Boudreau (1996), which relates tortuosity to the porosity of the sediment. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 24 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration 3.1.7.3.2 Surface Porewater Exchange As described in Section 2.5 of Attachment 1, the fate and transport model employs a surface porewater exchange coefficient (𝑘𝑘𝑓𝑓 ) to represent the combined effects of a number of processes occurring at the sediment surface that result in a dissolved-phase mass transfer at the sediment-water interface (e.g., diffusion, bioturbation-driven porewater release, gas ebullition, tidal pumping). Because these processes act in unison and are difficult or impossible to measure independently in the field, and the magnitude of each can vary from site to site, 𝑘𝑘𝑓𝑓 is a site-specific empirical parameter. As discussed in Section 2.5 of Attachment 1, Thibodeaux et al. (2001) developed a two-layer theoretical model of the exchange process in which the overall mass transfer rate is controlled by mass transfer in two discrete layers: a water-side layer and a sediment-side layer. The Thibodeaux et al. (2001) two-layer formulation predicts that much of the variation in 𝑘𝑘𝑓𝑓 observed among different contaminants at a given site can be explained by their partition coefficients (because the mass transport is limited by sorption and mixing in the sediment side for contaminants that bind strongly to particulates; e.g., Thibodeaux and Bierman 2003). 𝑘𝑘𝑓𝑓 was treated as a calibration parameter for the fate and transport model; however, the relationship between 𝑘𝑘𝑓𝑓 and 𝐾𝐾𝑜𝑜𝑜𝑜 predicted by the Thibodeaux et al. (2001) two-layer formulation indicated that the 𝑘𝑘𝑓𝑓 for PCB10 should be approximately 1.5 times higher than that for PCB1-9. Based on this approach, the final calibrated 𝑘𝑘𝑓𝑓 values were 12 centimeters per day (cm/d) for PCB1-9 and 18 cm/d for PCB10, which are in the range of values published in the literature (e.g., Erickson et al. 2005) and used for modeling PCBs at other sites (e.g., USEPA 2000; Anchor QEA 2012). 3.1.7.3.3 Mixing (Bioturbation) As described in Section 2.4.2 of Attachment 1, the fate and transport model represents mixing by bioturbation as a vertical dispersion process. Within the fate and transport model, each discrete sediment bed layer (1 inch thick in this application) is completely mixed; mixing between adjacent sediment bed layers occurs according to a mixing rate that is input to the model. The depth and rate of mixing are difficult to measure at a given site; general ranges have been reported in the literature, and they are known to vary from site to site depending on a number of factors. For this model, mixing was specified to occur over the Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 25 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration top 4 inches of sediment (which corresponds to the upper four layers of the bed model) based on results of the Patrick Bayou Sediment Mixing-Zone Layer Study (Anchor QEA 2009). The mixing rate between these layers of the model was specified to be 1E-6 cm2/s. This specified mixing rate is uncertain, although it is well within the range of values observed or estimated from other sites (e.g., Thoms et al. 1995; Clarke et al. 2001; Reible 2012). 3.2 3.2.1 Model Calibration Calibration Approach Model calibration is the process whereby model inputs or parameters that are relatively uncertain, and to which the model is relatively sensitive, are adjusted to improve the “fit” of the model predictions to the available Site data over the specified calibration period. These adjustments are made based on a combination of values from published literature, observed ranges in Site data, and experience from other systems. The calibration period for the Patrick Bayou chemical fate and transport model was a 1-year period that utilized hydrologic conditions from 2009. The calibration process focused on reproducing observed longitudinal gradients in whole-water PCB1-9 and PCB10 (and total PCB) concentrations in water column samples collected in 2009 and 2011.9 Two adjustments to input parameters were made to calibrate the fate and transport model. First, surface porewater exchange coefficients (see Section 3.1.7.3.2) were adjusted by less than a factor of 2; the final values were well within the ranges reported in the literature and used for modeling of other systems. Second, partition coefficients for PCB1-9 and PCB10 were adjusted within the range of values estimated based on the Site-specific data and literature (see Section 3.1.5). Figure 3-9 shows a spatial profile of the 2009/2011 water column total PCB data that were used for model calibration. These data show a prominent increase in water column concentration based on the data collected near the upstream and downstream ends of the concrete-lined channel (the upstream and downstream ends of the concrete-lined channel are indicated by vertical dashed lines in the figure); total PCB concentrations increase from Note that the model calibration was later refined based on additional water column data collected in 2014 (see Section 3.2.3). 9 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 26 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration approximately 5 nanograms per liter (ng/L) to nearly 100 ng/L between these locations. Water column concentrations downstream of the concrete-lined channel within Patrick Bayou increase further to approximately 200 ng/L in the general area of Station PB030 and then decline to approximately 80 to 100 ng/L near the confluence with the HSC (concentrations within the HSC are low, in the range of 2 to 4 ng/L). Initial attempts at calibrating the model were unable to match the large observed increase in water column concentration across the concrete-lined channel. Because the only known PCB source in that reach is sediments, the model calibration was first attempted by increasing the surface porewater exchange coefficient (𝑘𝑘𝑓𝑓 ) to result in a greater transfer of PCBs from the sediment porewater into the overlying water column. This approach resulted in a continued under-prediction of water column PCBs in the concrete-lined channel (although to a lesser degree), but a large over-prediction of observed water column PCBs downstream in Patrick Bayou. Based on this modeling exercise, it was concluded that there is likely an uncharacterized source of PCBs to the water column within this reach, and the only way to calibrate the fate and transport model to the observed water column spatial profile was to include an additional PCB mass flux term within the concrete-lined channel. Possible explanations of the nature of this source include: • Disproportionately high sediment/porewater PCB concentrations that may not have been fully characterized during the RI. Oily sediments and sheens were observed in this area during the RI (particularly in the vicinity of PB080). Because this channel is concrete-lined on its sides, with a “natural” bottom containing large amounts of debris, it has proven difficult to collect sediment samples in this area, which may explain why sediments in this reach may not have been fully characterized. • Advective flow of groundwater through the PCB-contaminated sediments within this reach. This reach is an incised channel (i.e., sloped, concrete sides with a natural bottom), which could represent an area of preferential flow of groundwater up through sediments. Under this mechanism, uncontaminated groundwater flow could drive PCBs contained in sediment deposits to continually desorb into the porewater as it flows into the overlying water column. • A combination of the two hypotheses described above Preliminary simulations indicated this source could be represented a number of different ways in the model. Given that the specific nature of this source is unknown, it was Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 27 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration represented in the model as a distributed loading (specified mass per unit time) across this reach.10 Further, it was assumed that this source did not change over time during the 1-year simulation that was used for calibration to the 2009 and 2011 RI data. Additional water column data were collected in 2014 to develop a better understanding of the nature and extent of PCBs in surface water of the concrete-lined channel. The model calibration results described in Section 3.2.2 describe the initial calibration of the model to the 2009/2011 water column data that was completed prior to collection of the 2014 water column data. Section 3.2.3 describes a revised calibration of the model to the 2014 water column data, in which the distributed loading in the concrete-lined channel was updated. 3.2.2 Calibration Results The results from the model calibration are presented in a series of graphics comparing model predictions with observed PCB concentrations. Longitudinal profiles of water column PCB concentrations are presented for PCB1-9, PCB10, and total PCB in Figures 3-10a through 3-10c, respectively. In these figures, the data are presented as discrete data points at the sampling station in which they were collected. Blue symbols represent water column samples collected in 2009, and samples collected in 2011 are shown in red. There are multiple sample points at each 2009 location because water column samples were collected during two tidal conditions (one at approximately slack low tide and the second at approximately mid-tide [ebb tide]) and two different depths (mid-depth and near bottom). All samples collected during 2011 were collected at mid-depth during ebb tide. For comparison to these data on a longitudinal profile, model results were averaged temporally (over the 1-year calibration period), vertically (over all ten model water column layers), and laterally (i.e., across the channel) for each longitudinal grid element, as shown by the solid lines. The ranges associated with the model averages are also indicated in these figures as dashed lines. In general, the calibration results shown in Figures 3-10a to 3-10c indicate that the model captures the observed longitudinal gradients in PCB concentrations across Patrick Bayou. Specifically, the model generally reproduces the observed increase in PCB1-9 (and total PCBs) The longitudinal distribution of this distributed PCB loading in the concrete-lined channel was developed based on the observed 2014 water column PCB spatial profile over this reach described in Section 3.2.3. 10 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 28 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration across the concrete-lined channel, followed by the approximate 1.5X increase in observed water column concentration from the downstream end of the concrete-lined channel to the downstream end of Patrick Bayou (Figures 3-10a and 3-10c). The model also captures the observed significant decline in concentration near the confluence and moving out into the HSC. For PCB10, the model captures the observed increase in water column concentrations downstream of PB040 (Figure 3-10b), which differs from the pattern for PCB1-9 and is a result of spatial variations in PCB composition. The ability of the model to simulate these differing patterns with no changes to input parameters beyond chemical-specific properties and sediment concentrations provides added confidence that the model is reliably calculating flux from sediments and porewater to the water column. 3.2.3 Revised Calibration to 2014 Water Column Data As described in Section 3.2.1, additional water column data were collected in 2014 to develop a better understanding of the surface water PCB concentrations at the Site, including characterization of PCBs at a finer spatial resolution in the concrete-lined channel. Figure 3-11 shows a spatial profile of the water column total PCB data collected in 2014 (green symbols) along with the 2009/2011 water column total PCB data shown in Figures 3-9 and 3-10. Figure 3-11 illustrates the following: • The 2014 data collected within the concrete-lined channel provide better spatial resolution of the PCB source within this reach. Specifically, these data show a relatively small PCB concentration increase between stations PB100 and PB080 from approximately 5 to 10 ng/L, followed by a larger increase from approximately 10 to 70 ng/L between stations PB080 and PB070. • The 2014 water column PCB results are systematically lower than those collected previously. Several factors were evaluated to attempt to explain the observed differences between the 2009/2011 and 2014 datasets, including differences in sampling locations, tidal conditions, flows, and antecedent precipitation. Based on this evaluation, it was determined that there were no significant differences in any of these factors that could explain the change in water column PCB concentration over Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 29 March 2017 040284-01.08 Chemical Fate and Transport Model Development and Calibration this 5-year period.11 As such, it was concluded that the observed reduction in water column concentrations between 2009 and 2014 was a result of natural attenuation processes, including some reduction in the magnitude of the upstream source loading within the concrete-lined channel, as well as reductions in surface sediment concentrations in downstream portions of Patrick Bayou associated with sedimentation. The model calibration, therefore, was adjusted by modifying the distributed PCB loading within the concrete-lined channel to match the observed 2014 water column data collected within this reach. In addition, the fate and transport model (previously calibrated to water column data collected in 2009, and parameterized using initial sediment concentrations measured in 2009) was run for a period of 5 years to account for reductions in surface sediment concentrations that may have occurred between 2009 and 2014 as a result of ongoing sedimentation.12 As shown in Figure 3-12, this revised calibration simulation showed good agreement with the water column data collected in 2014 (with the exception of the three points collected between PB020 and PB050 described in footnote 11). Tidal conditions at the time of sampling were relatively consistent between the sampling conducted during 2009/2011 and 2014 (i.e., samples were generally collected during low tide). Flows estimated based on velocity measurements collected during the 2014 sampling were low (generally less than or equal to 15 cfs); flow/velocity measurements were not taken during the 2009/2011 sampling; however, field personnel present during all three water column sampling events indicated flow conditions in 2009/2011 were similar to those in 2014. Antecedent precipitation in the week prior to sample collection was also relatively consistent between all three sampling events; there was no rain in the week prior to sampling in 2009 and 2011, and only approximately 0.5 inches of rain in the week prior to the 2014 sampling event. Lastly, sampling locations were generally consistent during the three sampling events. However, one possible exception is the three locations sampled in 2014 between stations PB020 and PB050 (shown as open symbols in Figure 3-11). The 2014 results for these three locations were considerably lower than the remaining 2014 sampling locations relative to 2009/2011. The one location sampled in this area during 2009 (near PB030) was collected from the center of the channel. By contrast, the three locations sampled in this area in 2014 were collected near shore and may have been influenced by dilution from non-contact flow through water from the HSC being discharged from nearby OxyChem Outfalls 002 and 003, or may have been affected by incomplete lateral mixing of the water column. 12 This 5-year simulation used hydrologic conditions from 2007 through 2011 because the hydrodynamic model simulation period covers the period of 1993 through 2011 (see Section 2.2). 11 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 30 March 2017 040284-01.08 4 LONG-TERM FUTURE SIMULATIONS This section presents the results of model projection simulations that were conducted to estimate the effectiveness of remedial alternatives being evaluated in the FS, including natural recovery. Specifically, the model projection simulations were used to support and evaluate the ability of the remedial alternatives and natural recovery to achieve the remedial action objectives (RAOs) for the Site. 4.1 Approach and Setup For the long-term future simulations conducted to support the FS, the fate and transport model used the long-term, 19-year hydrodynamic and sediment transport simulations described in Section 2 (which included the effects of a 100-year flood that occurs in the fourth year of the 19-year simulation period), combined with the 5-year period simulated from 2009 to 2014 as part of the revised calibration to the 2014 water column data (described in Section 3.2.3). As such, the total simulation period for the model projections was 24 years (using 2009 sediment concentrations as a starting point). These simulations were developed to predict future PCB concentrations to support relative comparisons of remedial options being evaluated as part of the FS; the historical hydrodynamic information used to project future conditions was only used as a means of estimating future flow and tide conditions at the Site (this makes the reasonable assumption that flows in the future will be statistically similar to those observed in the past). The calibrated fate and transport model was used to simulate the following two general scenarios in support of the FS: 1. Monitored natural recovery (MNR). For this simulation, the calibrated model simulation that began in 2009 and ended at 2014 was continued for an additional 19 years, with no changes to model inputs. This simulation allowed for evaluation of the effects of ongoing sediment deposition, as well as the effects of a large flow event, on future surface sediment PCB concentrations to be evaluated. For this simulation, it was conservatively assumed that no further reductions in the distributed PCB source within the concrete-lined channel (i.e., beyond those observed between 2009 and 2014 based on the surface water data) would occur. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 31 March 2017 040284-01.08 Long-term Future Simulations 2. Remediation of Sediment Management Area (SMA)-1. Remediation of this area is being considered in the FS alternatives because it encompasses the region over which the distributed PCB load within the concrete-lined channel is observed. Simulation of active remediation in SMA-1 consisted of: 1) setting the distributed PCB load within the SMA footprint to zero (to simulate remediation of this source) after Year 5 (which corresponds to 2014); and 2) setting sediment concentrations in the model within the SMA-1 footprint to zero (Figure 4-1 shows the model grid cells corresponding to the SMA-1 footprint). It was assumed that remediation was completed instantaneously at the beginning of Year 6 of the simulation. 4.2 Results This subsection presents the results from the fate and transport model long-term (24-year) simulations of the two scenarios described above. For comparison purposes, the water column and surface sediment total PCB concentrations predicted for these two scenarios are presented together on overlay plots. Longitudinal profiles of annual average water column total PCB concentrations for each year of the 24-year simulation are shown in Figures 4-2a through 4-2x. Under MNR, water column concentrations at the upstream end of the Site do not change appreciably over time due to the distributed loading within the concrete-lined channel (i.e., SMA-1). As described in Section 3.2.1, the exact nature (and rate of attenuation) of this source is unknown; therefore, it was conservatively assumed for the purpose of this simulation that this source would not change over time.13 However, water column concentrations in Patrick Bayou, downstream of the concrete-lined channel, are predicted to decrease over time for the MNR simulation due to decreasing surface sediment PCB concentrations resulting from ongoing sedimentation. For example, water column concentrations in Patrick Bayou near the confluence with the HSC (i.e., PB006) decrease from approximately 40 ng/L in Year 6 to approximately 35 ng/L by Year 15, at which point they reach equilibrium (i.e., there is no additional decrease in water column concentration after approximately Year 15). For the Note that an empirical evaluation of time to achieve the PCB surface water RAO is provided in Appendix E, which is based on insights gained from the modeling and estimated rates of decline based on 2009/2011 and 2014 water column data. 13 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 32 March 2017 040284-01.08 Long-term Future Simulations simulation of remediation of SMA-1, water column concentrations at the upstream end of the Site decrease considerably (to levels consistent with those specified at the upstream boundary [approximately 5 ng/L]) in Year 6 in response to the simulated remediation. Water column concentrations under this scenario are predicted to increase with distance downstream due to ongoing sediment contributions, but are also predicted to decrease over time as surface sediment PCB concentrations are predicted to decrease as a result of ongoing sedimentation (consistent with the MNR simulation). As described in Section 3.4 of the FS, one of the RAOs for the Site is to reduce PCB concentrations in surface water of Patrick Bayou to the background threshold value for PCBs in the HSC upstream of Patrick Bayou. The model results demonstrate that MNR alone is insufficient to achieve the PCB surface water RAO of 8.2 ng/L throughout Patrick Bayou by the end of the model simulation period (based on the assumption that the PCB source in the concrete channel would be unchanged from that estimated based on the 2014 data). PCB concentrations in water column are predicted to remain above the RAO throughout this simulation because of the distributed loading within the concrete-lined channel (see discussion above). By contrast, the simulation of remediation of SMA-1 (combined with MNR in the remainder of Patrick Bayou) results in model-predicted water column PCB concentrations that achieve the RAO throughout the Site within 6 years following remediation (note that the remediation is assumed to occur at the beginning of model Year 6, shown in Figure 4-2f). Time-series of model-predicted surface sediment (top 4 inches) PCB concentrations for the two scenarios evaluated are presented in Figures 4-3 and 4-4. Specifically, Figure 4-3 presents the Site-wide average sediment concentrations, and Figure 4-4 shows spatial averages calculated every ten stations (i.e., 1,000 feet). Note that the first 5 years of the 24-year time series represents the 5 years simulated from 2009 to 2014 (described in Section 3.2.3). As shown in Figure 4-3, Site-wide average sediment concentrations under MNR decrease from approximately 8 to 9 mg/kg in Year 1 (corresponding to 2009) to approximately 0.6 mg/kg in Year 24. Site-wide average sediment concentrations are predicted to decline even further (to approximately 0.3 mg/kg) when simulating remediation of SMA-1. These predicted declines are largely driven by ongoing sedimentation in Patrick Bayou. Figure 4-4, which presents average sediment concentrations in 1,000-foot Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 33 March 2017 040284-01.08 Long-term Future Simulations intervals, illustrates that predicted rates of decline in surface sediment PCB concentrations are spatially variable. For example, sediment concentrations in several areas of the Site decrease relatively quickly, particularly in response to the upstream remediation (e.g., PB060 to PB050, PB020 to PB010), whereas some areas decrease more slowly (e.g., PB040 to PB030). To quantify the model-predicted rates of decline in surface sediment PCB concentrations, first order (exponential) decay curves were fit through the 24-year model results for each of the various spatial scales shown in Figures 4-3 and 4-4. A summary of estimated half-lives for both scenarios (MNR and remediation of SMA-1) is provided in Table 4-1. The model-predicted rate of decline of total PCBs in surface sediments averaged over the entire Site corresponds to a half-life of 7 years under MNR alone, and decreases to 5 years when coupled with remediation of SMA-1. Half-lives over these 1,000-foot intervals range from 3 years (PB080-PB070) to 13 years (PB040-PB030) under MNR, and range from 2 years (PB080-PB070 and PB060-PB050) to 12 years (PB040-PB030) when coupled with remediation of SMA-1. These half-life values calculated based on model-predicted surface sediment PCB concentrations averaged every 1,000 feet were used to support the evaluation of benthic risk described in Section 4.1.2 of the FS. Table 4-1 Summary of Model-predicted Sediment Half-lives Half-life (years) Remediate SMA-1 Area MNR Site-wide 7 5 PB080 - PB070 3 2 PB070 - PB060 5 3 PB060 - PB050 5 2 PB050 - PB040 9 7 PB040 - PB030 13 12 PB030 - PB020 5 5 PB020 - PB010 6 3 PB010 - HSC 6 3 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 34 March 2017 040284-01.08 5 MODEL UNCERTAINTY EVALUATION Any model has some amount of uncertainty associated with its predictions. As such, it is often desirable to attempt to quantify the model uncertainty so that this can be factored into the model predictions of future conditions and any decisions that may be made based on the results. The following section describes the approach used to quantify the chemical fate and transport model uncertainty for Patrick Bayou, and the results of the analysis. 5.1 Approach and Setup The effect of input uncertainty on the chemical fate model predictions was evaluated through a sensitivity analysis. To develop uncertainty bounds on the model predictions of the long-term future simulations, two bounding sediment transport simulations described in Section 3.3.2 of Anchor QEA (2011)14 were propagated through the fate and transport model uncertainty simulations. Specifically, these two sediment transport simulations were combined with three bounding chemical fate and transport input parameters to which the model is most sensitive: 1) the surface porewater exchange coefficient (𝑘𝑘𝑓𝑓 ); 2) the partition coefficient (𝐾𝐾𝑜𝑜𝑜𝑜 ); and 3) depth of mixing (i.e., bioturbation). The lower and upper bound limits of these parameters were specified by modifying the 𝑘𝑘𝑓𝑓 term by ± a factor of 2, modifying log 𝐾𝐾𝑜𝑜𝑜𝑜 by ±10%, and increasing the bioturbation depth from 10 cm (used in the model calibration) to 15 cm. The goal of these simulations was to produce upper bound and lower bound results to quantify the uncertainty range associated with the model’s future predictions. Therefore, alternate values for each parameter were selected such that each produced a model response that varied in the same direction relative to the base calibration.15 Because one of the key uses of the model is to quantify rates of natural recovery within the Site, the alternate parameters were all selected so that they would result in both a faster (upper bound) and slower (lower bound) rate of recovery. For example, for the lower bound uncertainty simulation, the surface porewater exchange coefficient was decreased (which decreases the flux of contaminant mass exiting the surface sediment layer) and the partition The sediment transport model uncertainty analysis examined the effects of three inputs on model uncertainty: 1) external sediment load; 2) settling speed of the Class 1 (fine silt/clay) sediment; and 3) effective bed roughness (D90). Lower and upper bound limits of these three inputs were specified as ± a factor of 2 with respect to the base-case simulation. 15 The mixing depth was only varied for the lower bound (i.e., slower rate of recovery) uncertainty simulation. 14 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 35 March 2017 040284-01.08 Model Uncertainty Evaluation coefficient was increased (which results in an increase in concentration on depositing particulate matter) and the depth of sediment mixing was increased to 15 cm to elicit a slower rate of recovery in the system. 5.2 Results Figures 5-1 and 5-2 show longitudinal profiles of water column total PCB concentrations (base-case and upper and lower bound simulations) for each year of the MNR and SMA-1 remediation scenario simulations, respectively. These figures show that predicted water column concentrations for the uncertainty simulations under MNR (and pre-remediation of SMA-1) quickly converge to levels that are consistent with the base case. This is because water column concentrations are largely controlled by the loading entering the water column from upstream, and not the loading to the water column from the internal sediments (which is what would be affected by the model parameters that were adjusted for the uncertainty analysis). This can be seen in Figures 5-3 and 5-4, which show time-series of Site-wide average model-predicted surface sediment concentrations (base-case and upper and lower bound simulations) for the MNR and SMA-1 remediation scenario simulations, respectively. The changes made to model parameters for the uncertainty analysis result in relatively large differences in sediment concentrations between the base-case and upper and lower bound scenarios (while still decreasing) throughout the duration of the model simulation. As described in Section 4.2, model-predicted rate of decline of total PCBs in surface sediments averaged over the entire Site (base-case) corresponds to a half-life of 7 years under MNR alone, and decreases to 5 years when coupled with remediation of SMA-1. Consideration of model uncertainty only increases the half-life by less than 1 to nearly 2 years under both scenarios (Figures 5-3 and 5-4). As described in Section 4.2, the base-case model results for the MNR simulation indicate that MNR alone is insufficient to achieve the PCB surface water RAO of 8.2 ng/L throughout Patrick Bayou by the end of the model simulation period. Consideration of uncertainty in the model’s most sensitive parameters does not change this conclusion (Figure 5-1). However, model uncertainty does increase the time in which the RAO is predicted to be met following remediation of SMA-1 (Figure 5-2); specifically, consideration of model Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 36 March 2017 040284-01.08 Model Uncertainty Evaluation uncertainty increases the time to achieve the RAO throughout Patrick Bayou from 6 years following remediation to approximately 16 years. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 37 March 2017 040284-01.08 6 REFERENCES Anchor Environmental, L.L.C, 2007. Draft Supplemental Work Plan, Additional Hydrodynamic Data Collection, Geotechnical Data Collection, Sediment Accretion Evaluations, Porewater Sampling, and Estimation of Distribution Coefficients. Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas. Prepared for U.S. Environmental Protection Agency and the Patrick Bayou Joint Defense Group. May 2007. Anchor QEA (Anchor QEA, LLC), 2009. Patrick Bayou Sediment Mixing-Zone Layer Study. Memorandum from Kirk Ziegler, David Keith, and David Glaser to Phillip Allen, USEPA Region 6. June 15, 2009. Anchor QEA, 2011. Sediment Transport Modeling Report. Patrick Bayou Superfund Site, Deer Park, Texas. Prepared for U.S. Environmental Protection Agency and the Patrick Bayou Joint Defense Group. September 2011. Anchor QEA, 2012. Portland Harbor RI/FS, Draft Feasibility Study. Prepared for the Lower Willamette Group. March 30, 2012. Anchor QEA, 2013a. Patrick Bayou Remedial Investigation Report. Patrick Bayou Superfund Site, Deer Park, Texas. Prepared for U.S. Environmental Protection Agency and the Patrick Bayou Joint Defense Group. September 2013. Anchor QEA, 2013b. Baseline Ecological Risk Assessment Report. Patrick Bayou Superfund Site, Deer Park, Texas. Prepared for U.S. Environmental Protection Agency and the Patrick Bayou Joint Defense Group. March 2013. Baker, J.R., J.R. Mihelcic, D.C. Luehrs, and J.P. Hickey, 1996. Evaluation of estimation methods for organic carbon normalized sorption coefficients. Water Environ. Res. 69:136-145. Bamford, H.A., D.L. Poster, and J.E. Baker, 2000. Henry’s Law Constants of Polychlorinated Biphenyl Congeners and Their Variation with Temperature. J. Chem. Eng. Data 45:1069-1074. Boudreau, B.P., 1996. The diffusive tortuosity of fine-grained unlithified sediments. Geochimica et Cosmochimica Acta 60:3139–3142. doi: 10.1016/0016-7037(96)00158-5. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 38 March 2017 040284-01.08 References Brunner, S., W. Hornung, H. Santi, E. Wolff, and O. Piringer, 1990. Henry’s Law Constants for Polychlorinated Biphenyls: Experimental Determination and Structure-Property Relationships. Environ. Sci. Technol. 24:1751-1754. Burkhard, L.P., 2000. Estimating dissolved organic carbon partition coefficients for nonionic organic chemicals. Environ. Sci. Technol. 34:4663-4668. Chapra, S.C., 1997. Surface Water-Quality Modeling. New York: McGraw-Hill. Chiou, C.T., R.L. Malcolm, T.I. Brinton, and D.E. Kile, 1986. Water solubility enhancement of some organic pollutants and pesticides by dissolved humic and fulvic acids. Environ. Sci. Technol. 20:502-508 Clarke, D.G., M.R. Palermo, and T.C. Sturgis, 2001. Subaqueous cap design: Selection of bioturbation profiles, depths, and rates. DOER Technical Notes Collection (ERDC TN-DOER-C21). U.S. Army Engineer Research and Development Center, Vicksburg, Mississippi. Di Toro, D.M., 1985. A particle interaction model of reversible organic chemical sorption. Chemosphere 14(10):1503-1538. Erickson, M.J., C.L. Turner, and L.J. Thibodeaux, 2005. Field Observation and Modeling of Dissolved Fraction Sediment-Water Exchange Coefficients for PCBs in the Hudson River. Environ. Sci. Technol. 39:549-556. Essayon Engineering & Development, Inc., 2010. Patrick’s Bayou Flood Mitigation Project Environmental Assessment for the City of Deer Park, Harris County, TX. January 6, 2010. Fang, F., S. Chu, and C-S Hong, 2006. Air-Water Henry’s Law Constants for PCB Congeners: Experimental Determination and Modeling of Structure-Property Relationship. Anal. Chem. 78:5412-5418. Hawker, D.W., and D.W. Connell, 1988. Octanol-water partition coefficients of polychlorinated biphenyl congeners. Environ. Sci. Technol. 22:382-387. IDS Engineering Group, 2012. Patrick’s Bayou Detention Basin HCFCD Project ID# G50401-00-E001 Construction Notes for City of Deer Park, Texas. June 26, 2012. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 39 March 2017 040284-01.08 References Mackay, D., and A.T.K. Yuen, 1983. Mass transfer coefficient correlations for volatilization of organic solutes from water. Environ. Sci. Technol. 17(4):211-217. Mackay, D., W.Y. Shiu, and K.C. Ma, 1992. Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals. Volume 1. Lewis Publishers. Pate Engineers, 2012. Impact Analysis for Patrick’s Bayou Detention Facility City of Deer Park. March 23, 2012. PBS&J, 2006. Final Preliminary Engineering Report for Drainage Study of G104-00-00, G104-08-00, and G105-00-00 HCFCD ID #Z100-00-00-PG007 Harris County, Texas. PBS&J Project No. 461134.00. Document No. 06H088. Prepared for Harris County Flood Control District. October 2006. Reible, D., 2012. Modeling of 2 Layer Sediment Cap. Version - 2 Layer Analytical Model v.1.18 and Active Cap Layer Model v 4.1. Available from: http://www.caee.utexas.edu/reiblegroup/downloads/2%20layer%20analytical%20mod el%20description.doc. Shiu, W.Y., and D. Mackay, 1986. A critical review of aqueous solubilities, vapor pressures, Henry’s law constants and octanol-water partition coefficients of the polychlorinated biphenyls. J. Phys. Chem. Data 15:911-929. Swackhamer, D.L., and D.E. Armstrong, 1987. Distribution and characterization of PCBs in lake Michigan water. J. Great Lakes Res. 13:24–36. Thibodeaux, L.J., and V.J. Bierman, 2003. The bioturbation-driven chemical release process. Environ. Sci. Technol. 37(13):252A-258A. Thibodeaux, L.J., K.T. Valsaraj, and D.D. Reible, 2001. Bioturbation-Driven Transport of Hydrophobic Organic Contaminants from Bed Sediment. Environmental Engineering Science 18(4):215-223. Thoms, S.R., G. Matisoff, P.L. McCall, and X. Wang, 1995. Models for Alteration of Sediments by Benthic Organisms. Project 92-NPS-2, Water Environment Research Foundation. Alexandria, Virginia. USEPA (U.S. Environmental Protection Agency), 2000. Hudson River PCBs Reassessment RI/FS Phase 2 Report. Review Copy: Further Site Characterization and Analysis – Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 40 March 2017 040284-01.08 References Volume 2D – Revised Baseline Modeling Report. Developed for USEPA Region 2 by TAMS Consultants et al. January 2000. USEPA, 2005. Contaminated Sediment Remediation Guidance for Hazardous Waste Sites. United States Environmental Protection Agency, Office of Solid Waste and Emergency Response. EPA-540-R-05-012, OSWER 9355.0-85. December 2005. USEPA, 2012. Estimation Programs Interface Suite™ for Microsoft® Windows, v 4.11. U.S. Environmental Protection Agency, Washington, DC, USA, HENRYWIN™ model. Available from: http://www.epa.gov/opptintr/exposure/pubs/episuite.htm Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 41 March 2017 040284-01.08 1 INTRODUCTION This attachment to Appendix A, Chemical Fate and Transport Modeling Study, provides background on the chemical fate and transport model. Section 1 includes a discussion of the model background, the overall framework, and its linkage to other models as well as the processes simulated by the model. The governing equations used to represent those processes are presented in Section 2 of this attachment, and cited references are provided in Section 3. 1.1 Model Background and History Anchor QEA, LLC’s chemical fate and transport model (referred to as AQFATE) simulates the fate and transport of chemical constituents in surface water and sediment bed systems. AQFATE includes a flexible framework for modeling different chemical and physical processes and is designed to accommodate multiple chemical constituents that are affected by a basic suite of physical and chemical processes represented in the model. The AQFATE model code is built into the Environmental Fluid Dynamics Code (EFDC) hydrodynamic model framework that includes sediment transport based on the SEDZLJ algorithm. The AQFATE model framework has a long development and application history1 and has been successfully applied at a wide range of contaminated sediment sites across the United States. Recent examples include the following: • Hudson River, New York (e.g., Connolly et al. 2000; QEA 2005; Anchor QEA 2010) • Grasse River, New York (e.g., Alcoa 2012) • Housatonic River, Connecticut (ARCADIS, Anchor QEA, and AECOM 2010) • Neal’s Landfill Site (Conard’s Branch and Richland Creek), Indiana (QEA 2007; USEPA 2007) • Portland Harbor/Lower Willamette River, Oregon (Anchor QEA 2012a) • San Jacinto River, Texas (Anchor QEA 2012b) AQFATE was developed by personnel at Quantitative Environmental Analysis, LLC (QEA; now Anchor QEA, LLC) in 1998 using the Water Quality Analysis Simulation for Toxics (WASTOX) model as a starting point. WASTOX was developed on behalf of U.S. Environmental Protection Agency (USEPA) in the 1980s (Connolly and Winfield 1984; Connolly and Thomann 1985); it also formed the basis for the widely used, USEPAsupported Water Quality Analysis Simulation Program (WASP) model (Wool et al. 2008). Since its development, the AQFATE code has been continually improved and updated by Anchor QEA (formerly QEA) personnel. In a USEPA evaluation of tools for modeling contaminated sediment sites, an earlier version of AQFATE received a favorable review (Imhoff et al. 2003). 1 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 1 March 2017 040284-01.08 Attachment 1 1.2 Model Framework and Linkages In order to predict chemical concentrations in the water column and sediments of a surface water system, AQFATE must be linked to hydrodynamic and sediment transport models. These models all perform dynamic simulations in which time-varying calculations are performed over generally long timescales. A brief description of these linkages is provided in the following: • The hydrodynamic model predicts current velocities, water depths, dispersion coefficients (which represent turbulent mixing in the water column), and bottom shear stress over time. This information is passed to the sediment transport model as well as the chemical fate and transport model (with the exception of bottom shear stress). • The sediment transport model uses the information from the hydrodynamic model to predict suspended sediment concentrations in the water column and fluxes of solids between the water column and bed resulting from deposition (settling) of particulate matter and erosion of bottom sediment over time. This information is passed to the chemical fate and transport model. • The chemical fate and transport model (i.e., AQFATE) uses the information from the hydrodynamic and sediment transport models to predict concentrations of chemicals in the water column and the sediment bed, for both particulate and dissolved phases, over time. Additional details on the model framework and linkages between the models are provided in Section 1 (and Figure 1-1) of Appendix A. 1.3 Model Processes The chemical fate and transport model is based on the first principle of mass balance. The model framework consists of a set of general equations that describe the basic physical, chemical, and biological processes affecting chemical fate and transport within an aquatic system (i.e., both the water column and the sediment bed). Application of this general framework to a given site is accomplished by using site-specific data, literature, experience from modeling other systems, and professional judgment to specify values for the parameters Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 2 March 2017 040284-01.08 Attachment 1 of the governing equations such that the model reproduces the trends in chemical concentrations within the system over relevant spatial and temporal scales. The processes simulated by AQFATE are depicted on Figure 1-2 in Appendix A. Chemicals can enter the water column as loads from inflows or tidal exchange at the boundaries of the simulated area (i.e., boundary conditions), as well as from external loads that are represented as point sources (e.g., outfalls) or sources distributed over a larger area, such as atmospheric deposition over the water surface.2 Processes simulated within the water column in the model include transport via advection and dispersion, partitioning between the particulate and dissolved phases, as well as to dissolved organic carbon (DOC) in certain cases, and degradation/transformation reactions (for certain chemicals/conditions). Chemicals in the water column can also be lost to the atmosphere via volatilization and exchanged with the underlying sediment bed via the processes of deposition and resuspension of sediments and associated particulate-phase chemicals, and by dissolved-phase exchange processes, which include diffusion, porewater exchange flux, and advective flow. The model also simulates the sediment bed, which communicates with the water column through the exchange processes listed above. Within the bed itself, the chemical fate and transport processes simulated include mixing (i.e., bioturbation) within the surficial sediments, vertical transport/exchange via diffusion, dispersion, and advection within the porewater phase, as well as partitioning and biodegradation/transformation (when applicable). In cases where the model is simulating a depositional environment, there is a net transfer of chemicals from the surficial layers to the deeper layers of the simulated bed (i.e., net sedimentation). The processes described above and shown on Figure 1-2 (Appendix A) are combined together in mass balance computations for both the water column and the sediment bed, which because of the exchange processes between the two must be performed simultaneously. In simple terms, the mass balance is used to compute changes in chemical concentration of the water column and sediment bed over time by summing the various terms that represent losses or gains of chemical mass to each. These mass balance calculations are performed over AQFATE has the ability to simulate inputs from external loads such as point sources and/or groundwater discharge, however there are no loads specified for these types of sources in the Patrick Bayou model. This attachment provides a general description of the capabilities of AQFATE; Appendix A describes the specific inputs and processes simulated in its application to Patrick Bayou. 2 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 3 March 2017 040284-01.08 Attachment 1 all computational elements in AQFATE, which are defined by the numerical grid that is used to represent the simulated waterbody. Mechanistic representations of the chemical fate and transport processes are embodied in the model’s governing equations, which are presented in the next section. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 4 March 2017 040284-01.08 2 CHEMICAL FATE AND TRANSPORT MODEL GOVERNING EQUATIONS The governing equations for the processes represented in AQFATE are summarized in this section. First, the equations for mass balance in the water column and sediment bed are presented, followed by the equations that are used to describe partitioning and the exchange, transport, external source loadings, and transformation processes included in the general mass balance equations. Additional discussion and details of model theory can be found in Connolly and Winfield (1984), Chapra (1997), Connolly et al. (2000), and Anchor QEA (2010). 2.1 Water Column Mass Balance The three-dimensional equation describing the conservation of mass for a chemical in the water column can be described by the following (Connolly and Winfield 1984): 𝜕𝜕𝑐𝑐𝑡𝑡 𝜕𝜕𝜕𝜕 𝜕𝜕 = 𝜕𝜕𝜕𝜕 �𝐸𝐸𝑥𝑥 𝜕𝜕𝜕𝜕𝑦𝑦 𝑐𝑐𝑡𝑡 where: 𝑐𝑐𝑡𝑡 t x, y, z = 𝜕𝜕𝜕𝜕𝑡𝑡 𝜕𝜕𝜕𝜕 𝜕𝜕𝜕𝜕 − 𝜕𝜕 � + 𝜕𝜕𝜕𝜕 �𝐸𝐸𝑦𝑦 𝜕𝜕𝜕𝜕𝑧𝑧 𝑐𝑐𝑡𝑡 𝜕𝜕𝜕𝜕 𝜕𝜕𝜕𝜕𝑡𝑡 𝜕𝜕𝜕𝜕 𝜕𝜕 � + 𝜕𝜕𝜕𝜕 �𝐸𝐸𝑧𝑧 𝜕𝜕𝜕𝜕𝑡𝑡 𝜕𝜕𝜕𝜕 �− ± 𝑆𝑆𝑤𝑤𝑤𝑤/𝑏𝑏𝑏𝑏𝑏𝑏 + 𝑆𝑆𝑒𝑒𝑒𝑒𝑒𝑒 ± 𝑆𝑆𝑤𝑤𝑤𝑤 𝜕𝜕𝜕𝜕𝑥𝑥 𝑐𝑐𝑡𝑡 𝜕𝜕𝜕𝜕 − Equation 1 total water column concentration of chemical (M/L3), (particulate phase, freely dissolved phase, and DOC-bound phase) = time (T) = coordinate directions (i.e., longitudinal, lateral, and vertical distance [L]) Ex, Ey, Es = longitudinal, lateral, and vertical dispersion coefficients, respectively (L2/T) ux, uy, uz = longitudinal, lateral, and vertical current velocity, respectively (L/T) Swc/bed = net mass exchange at the sediment/water interface (applies to the bottommost vertical grid cell in the water column) Sext Swc = source term resulting from external loads (M/[L3T]) = source and sink terms resulting from kinetic reactions (M/[L3T]) Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 5 March 2017 040284-01.08 Attachment 1 The first six terms in this equation represent transport processes, which are discussed in Section 2.4.1. The seventh term represents the exchange flux that embodies the linkage between the water column and sediment bed mass balances, and is described in Section 2.5. The final two terms in this equation represent external source loads, and kinetic reactions and are discussed in Section 2.6.1. 2.2 Sediment Bed Mass Balance The equation describing the conservation of mass within the sediment bed simulated in AQFATE it is given by the following equation: 𝜕𝜕𝜕𝜕𝑡𝑡 𝜕𝜕𝜕𝜕 where: ct = 𝜕𝜕 = 𝜕𝜕𝜕𝜕 �𝐸𝐸𝑧𝑧 𝜕𝜕𝜕𝜕𝑡𝑡 𝜕𝜕𝜕𝜕 𝜕𝜕 � + 𝜕𝜕𝜕𝜕 �𝐷𝐷𝑧𝑧 𝜕𝜕(𝑐𝑐𝑑𝑑 +𝑐𝑐𝑑𝑑𝑑𝑑𝑑𝑑 ) 𝜕𝜕𝜕𝜕 �− 𝑆𝑆𝑤𝑤𝑤𝑤/𝑏𝑏𝑏𝑏𝑏𝑏 + 𝑆𝑆𝑔𝑔𝑔𝑔 ± 𝑆𝑆𝑏𝑏𝑏𝑏𝑏𝑏 𝜕𝜕𝑢𝑢𝑧𝑧,𝑏𝑏𝑏𝑏𝑏𝑏 (𝑐𝑐𝑑𝑑 +𝑐𝑐𝑑𝑑𝑑𝑑𝑑𝑑 ) 𝜕𝜕𝜕𝜕 ± Equation 2 total sediment concentration of chemical (M/L3), (particulate phase, freely dissolved phase, and DOC-bound phase) z = coordinate direction (i.e., vertical distance within sediment bed [L]) Ez = vertical dispersion (mixing) coefficient (L2/T) Dz = effective vertical porewater diffusion coefficient (L2/T) cd = freely dissolved phase concentration of chemical (M/L3) cdoc = DOC-sorbed phase concentration of chemical (M/L3) uz,bed = vertical advective velocity in porewater (L/T) Swc/bed = net mass exchange at the sediment/water interface (applies to the uppermost layer of the simulated sediment bed) Sgw = external source term associated with loads from groundwater (M/[L3T]; applies to the bottommost layer of the simulated sediment) Sbed = source/sink terms resulting from kinetic reactions in the bed (M/[L3T]) Equation 2 is solved only in the vertical dimension, and is similar to that used to describe chemical fate and transport in a groundwater system (e.g., Domenico and Schwartz 1990) except that additional terms are included to represent bioturbation and exchange with the water column (e.g., Boudreau 1997). Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 6 March 2017 040284-01.08 Attachment 1 The first three terms in the above equation represent transport processes within the sediment bed, which are discussed in Section 2.4.2. The fourth term represents the exchanges between the water column and sediment bed, which is described in Section 2.5. The final two terms in the above equation represent external loading (via deep groundwater, if applicable to a particular site) and kinetic reactions within the bed and are discussed in Section 2.6.2. 2.3 Partitioning AQFATE uses partitioning relationships to calculate the concentrations of chemicals in three separate phases (particulate phase, freely dissolved phase, and DOC-bound phase3) that together comprise the total concentration referenced in the above mass balance equations (water column or sediment bed), as shown in Equation 3: 𝑐𝑐𝑡𝑡 = 𝑐𝑐𝑝𝑝 + 𝑐𝑐𝑑𝑑 + 𝑐𝑐𝑑𝑑𝑑𝑑𝑑𝑑 where: 𝑐𝑐𝑝𝑝 Equation 3 = concentration of chemical adsorbed to particulate matter, expressed on a volumetric basis (M/L3) Some terms in the model express the particulate-phase concentration on a mass of chemical per mass of dry solids basis rather than on a volumetric basis; this is accomplished by the following equation: 𝑟𝑟 = where: 𝑟𝑟 𝑐𝑐𝑝𝑝 𝑚𝑚𝑠𝑠 Equation 4 = concentration of chemical adsorbed to particulate matter, expressed on a mass per unit mass basis (M/M) It should be noted that in certain cases (e.g., for some metals and less hydrophobic organics), the dissolved organic carbon-bound phase may not be represented in the model. 3 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 7 March 2017 040284-01.08 Attachment 1 𝑚𝑚𝑠𝑠 = concentration of solids (M/L3), which is equal to the suspended solids concentration in the water column and the dry bulk density in the sediment bed As discussed in the Sediment Transport Modeling Report (Anchor QEA 2011), the sediment transport model simulates solids in multiple classes to represent differences in the transport characteristics of fine (i.e., silts and clays) versus coarse (i.e., sands and gravels) sediments, as well as differences in organic carbon content. Therefore, the model’s partitioning formulations compute chemical concentrations separately for each of these classes of solids based on the above equations (i.e., using the individual concentrations of solids for each solids class computed by the sediment transport model). It is often useful to express the individual phase concentrations in terms of their respective fractions of the total, as follows: 𝑐𝑐𝑝𝑝 = 𝑓𝑓𝑝𝑝 𝑐𝑐𝑡𝑡 ; 𝑐𝑐𝑑𝑑 = 𝑓𝑓𝑑𝑑 𝑐𝑐𝑡𝑡 ; 𝑐𝑐𝑑𝑑𝑑𝑑𝑑𝑑 = 𝑓𝑓𝑑𝑑𝑑𝑑𝑑𝑑 𝑐𝑐𝑡𝑡 where: 𝑓𝑓𝑝𝑝 , 𝑓𝑓𝑑𝑑 , 𝑓𝑓𝑑𝑑𝑑𝑑𝑑𝑑 = Equation 5 fraction in the particulate, freely dissolved, and DOC-bound phases, respectively The chemical fate and transport model uses the principles of linear equilibrium sorption to represent the relationships between the various phases. For the particulate phase, equilibrium sorption is represented by (e.g., Karickhoff 1984; Chapra 1997): 𝑟𝑟 = 𝐾𝐾𝑑𝑑 𝑐𝑐𝑑𝑑 where: Kd = Equation 6 the distribution or partition coefficient of the chemical (L3/M) Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 8 March 2017 040284-01.08 Attachment 1 For hydrophobic organic chemicals, sorption is usually controlled by the organic carbon content of the solids and the chemical’s organic carbon partition coefficient (e.g., Karickhoff 1984; Chapra 1997): 𝐾𝐾𝑑𝑑 = 𝑓𝑓𝑜𝑜𝑜𝑜 𝐾𝐾𝑜𝑜𝑜𝑜 where: 𝑓𝑓𝑜𝑜𝑜𝑜 𝐾𝐾𝑜𝑜𝑜𝑜 Equation 7 = the fraction of organic carbon of the suspended solids or sediment = organic carbon partition coefficient of the chemical (L3/M) Similar to particulate organic carbon, partitioning to DOC is described by the chemical’s partition coefficient between the DOC-bound and freely dissolved phases: where: 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 𝑚𝑚𝑑𝑑𝑑𝑑𝑑𝑑 𝑐𝑐𝑑𝑑𝑑𝑑𝑑𝑑 / 𝑚𝑚𝑑𝑑𝑑𝑑𝑑𝑑 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 = 𝑐𝑐𝑑𝑑 Equation 8 = DOC partition coefficient (L3/M) = concentration of DOC in the water column or porewater (M/L3) Using the above equations, the equations representing the fractions in the particulate, dissolved, and DOC-bound phases are as follows: 𝐾𝐾𝑑𝑑 𝑚𝑚𝑠𝑠 𝑓𝑓𝑝𝑝 = 𝜙𝜙 + 𝐾𝐾 𝑑𝑑 𝑚𝑚𝑠𝑠 + 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 𝑚𝑚𝑑𝑑𝑜𝑜𝑜𝑜 𝜙𝜙 𝑓𝑓𝑑𝑑 = 𝜙𝜙 + 𝐾𝐾 𝑑𝑑 𝑚𝑚𝑠𝑠 + 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 𝑚𝑚𝑑𝑑𝑑𝑑𝑑𝑑 𝑓𝑓𝑑𝑑𝑑𝑑𝑑𝑑 = 𝜙𝜙 + 𝐾𝐾 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 𝑚𝑚𝑑𝑑𝑑𝑑𝑑𝑑 𝑑𝑑 where: 𝜙𝜙 𝑚𝑚𝑠𝑠 + 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 𝑚𝑚𝑑𝑑𝑑𝑑𝑑𝑑 Equation 9 Equation 10 Equation 11 = volume fraction of water (= 1 for water column and = porosity within the sediment bed) Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 9 March 2017 040284-01.08 Attachment 1 When the sediment transport model simulates multiple classes of solids, as is the case for Patrick Bayou, the Kd and ms terms in Equations 9 through 11 are repeated for each class of solids because these terms can vary by class (due to differing solids concentration and/or differing partition coefficient due to differences in organic carbon content as per Equation 7). For example, the fraction of chemical in the particulate phase of a given solids class is represented by the following: 𝑓𝑓𝑝𝑝,𝑖𝑖 = 𝜙𝜙 + ∑𝑛𝑛 𝐾𝐾𝑑𝑑,𝑖𝑖 𝑚𝑚𝑠𝑠,𝑖𝑖 𝑖𝑖=1 𝐾𝐾𝑑𝑑,𝑖𝑖 𝑚𝑚𝑠𝑠,𝑖𝑖 + 𝐾𝐾𝑑𝑑𝑑𝑑𝑑𝑑 𝑚𝑚𝑑𝑑𝑑𝑑𝑑𝑑 Equation 12 where: i = index referring to an individual class of solids simulated by the sediment transport model n = total number of solids classes simulated by the sediment transport model The chemical mass calculated for each individual solids class is also summed in the model to allow for aggregation into the total particulate-phase concentration. 2.4 Mass Transport Processes The terms in the general mass balance equations that describe the movement or transport of chemicals within the water column and within the sediment bed (i.e., Equations 1 and 2, respectively) are discussed in the following two subsections. 2.4.1 Water Column The first three terms in the water column mass balance (Equation 1) represent transport by longitudinal, lateral, and vertical dispersion in the water column, respectively, which results from turbulent mixing processes. The next three terms in Equation 1 represent transport by advection, or movement of the chemicals with flow of water. In the model, the dispersion coefficients and current velocities that describe these processes are predicted by the hydrodynamic model. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 10 March 2017 040284-01.08 Attachment 1 2.4.2 Sediment Bed The first term in the sediment bed mass balance equation (Equation 2) represents mixing by bioturbation, which is based on the typical approach of representing it as a vertical dispersion process (e.g., Boudreau 1997; Lampert and Reible 2009). This mixing is applied to all phases of chemicals in the model, although for sorptive compounds, the particulate-phase dispersive flux accounts for the vast majority of the mass transport associated with this process. Bioturbation is usually specified in the model to occur over the upper layers of the simulated sediment bed, which are the layers that correspond to the “active layer” or the depth of biological mixing at a site. This process can also be used to represent other nonbiological mixing processes that occur at some sites, as long as they can be represented as a dispersion process. The second term in Equation 2 represents diffusive transport of chemical in the sediment porewater, which acts on the freely dissolved and DOC-bound phases. The effective diffusion coefficient includes the combined effects of molecular diffusion, which is adjusted for the tortuosity effects of a porous medium (e.g., Shen and Chen 2007), and dispersion, which accounts for small-scale velocity variations associated with flow in a porous medium (e.g., Domenico and Schwartz 1990): 𝐷𝐷𝑧𝑧 = 𝐷𝐷𝑚𝑚 𝜏𝜏 + 𝛼𝛼 where: 𝑢𝑢𝑧𝑧,𝑏𝑏𝑏𝑏𝑏𝑏 𝜙𝜙 Equation 13 Dm τ = molecular diffusion coefficient of the chemical in water (L2/T) = tortuosity factor (unitless) α = dispersivity (L), which is taken to be a scale-dependent coefficient (e.g., Gelhar et al. 1992) The third transport term in the bed mass balance (Equation 2) represents the advection of porewater (i.e., driven by groundwater flow) within the sediments, which acts upon the mobile phase of chemical (i.e., the freely dissolved plus DOC-bound). This process is characterized by an advective volumetric flux (i.e., Darcy velocity), which is a model input for the chemical fate and transport model. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 11 March 2017 040284-01.08 Attachment 1 2.5 Sediment/Water Column Exchange Processes The sediment and water column mass balance equations (i.e., Equations 1 and 2, respectively) are linked by the net mass exchange at the sediment/water interface. This net exchange is calculated in the model by summing the chemical fluxes calculated for the following individual exchange processes: sediment deposition, sediment resuspension, porewater exchange, and porewater advection. For the water column mass balance, the net mass exchange is calculated as follows: 𝑆𝑆𝑤𝑤𝑤𝑤/𝑏𝑏𝑏𝑏𝑏𝑏 = 𝐴𝐴𝑠𝑠 𝑉𝑉 �𝑅𝑅 𝑟𝑟𝑏𝑏𝑏𝑏𝑏𝑏 − 𝐷𝐷 𝑟𝑟𝑤𝑤𝑤𝑤 + 𝑘𝑘𝑓𝑓 [(𝑐𝑐𝑑𝑑 + 𝑐𝑐𝑑𝑑𝑑𝑑𝑑𝑑 )𝑏𝑏𝑏𝑏𝑏𝑏 − (𝑐𝑐𝑑𝑑 + 𝑐𝑐𝑑𝑑𝑑𝑑𝑑𝑑 )𝑤𝑤𝑤𝑤 ]� where: As +𝑢𝑢𝑧𝑧,𝑏𝑏𝑏𝑏𝑏𝑏 (𝑐𝑐𝑑𝑑 + 𝑐𝑐𝑑𝑑𝑑𝑑𝑑𝑑 )𝑏𝑏𝑏𝑏𝑏𝑏 Equation 14 = surface area of sediment/water interface (L2), which is the area of a computational grid cell in the model’s calculation V = volume (L3) of the bottom layer of the water column (when used in Equation 1) or surface layer of the sediment bed (when used in Equation 2) R D wc, bed = resuspension (erosion) flux of sediment (M/[L2T]) = deposition (settling) flux of sediment (M/[L2T]) = subscripts referring to chemical concentrations in the bottom layer of the water column and surface layer of the sediment bed, respectively kf = porewater exchange coefficient (L/T) For the sediment bed mass balance, the net exchange is based on the same calculation, except the sign of the calculated value is reversed (i.e., a net negative flux for the water column mass balance, which would be a chemical loss term, is a net positive flux, or a chemical gain, for the sediment bed mass balance) and the volume term differs between the two compartments as noted above. The first two terms in Equation 14 represent the transfer of chemical between the water column and sediment bed associated with sediment resuspension and deposition, respectively. Both of these chemical fluxes are calculated based on the flux of solids that is Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 12 March 2017 040284-01.08 Attachment 1 calculated by the sediment transport model multiplied by the particulate-phase chemical concentration expressed on a per unit mass of solids basis. The chemical flux from resuspension, which results in a transfer of mass from the bed to the water column, is calculated as the flux of solids times the concentration of chemical on the surface layer bed solids. Likewise, the chemical flux from deposition, which results in a transfer of mass from the water column to the bed, is calculated as the flux of solids times the concentration of chemical on water column solids. As discussed previously, the sediment transport model simulates solids as multiple classes, which results in separate deposition and erosion fluxes for each class. Therefore, the first two terms in Equation 14 are calculated for each simulated solids class (i.e., the solids flux of the given solids class times the particulate-phase chemical concentration of that solids class), and these fluxes are aggregated in computing the total mass transfer at the sediment-water interface. The third term in Equation 14 represents exchange of dissolved-phase chemical between the surface sediment porewater and the overlying water column. This exchange is represented as a diffusion process, with a mass transfer coefficient multiplied by the concentration difference between the surface layer porewater and the water column (for both freely dissolved and DOC-bound phases). This term is used in the model to represent the net effect of multiple processes acting in unison, all of which result in a dissolved-phase mass transfer at the sediment-water interface; these processes include diffusion, bioturbation, gas ebullition, and micro-scale propagation of turbulence4. Indeed, data from several contaminated sediment sites indicate that observed porewater mass transfer coefficients are typically much greater than those which would be expected from diffusion alone (e.g., Thibodeaux and Bierman 2003). As such, the porewater mass transfer coefficient is typically taken to be a site-specific parameter (e.g., USEPA 2000, 2006; Anchor QEA 2010; Alcoa 2012). Research has shown that within a given site, the mass transfer coefficient can vary as a function of the chemical’s partition coefficient, with the mass transfer coefficient increasing with increasing Kd or Koc. Based on such information, the porewater exchange process has been conceptualized to be driven by mass transport processes within a benthic boundary layer that consists of two components: a sediment side, which is influenced by In addition, exchange fluxes associated with tidal pumping, if applicable, can also be represented by this process (e.g., La Licata et al. 2011). 4 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 13 March 2017 040284-01.08 Attachment 1 sorption and particle mixing, and a water side, which is influenced by propagation of turbulence (e.g., Thibodeaux et al. 2001). The last term in Equation 14 represents dissolved-phase advective flux, which is associated with vertical flow of porewater. This flux can result in mass transport from the sediment to the water column, or vice versa, depending on the direction of flow (i.e., upwelling or downwelling). 2.6 Source/Sink Terms The last terms in the sediment and water column mass balance equations (i.e., Equations 1 and 2, respectively) represent changes in chemical mass resulting from external source/sink and reaction terms. The terms represented in each of these portions of the model are described in the following two subsections. 2.6.1 Water Column 2.6.1.1 External Loadings Sources of chemicals to the water column can include processes such as point sources (i.e., discharges from outfalls), surface runoff, atmospheric deposition, and groundwater flowing into the surface water through the banks of the waterbody. Such processes are incorporated directly into the model’s water column mass balance (i.e., Equation 1) through specification of the associated chemical mass loading as follows: 𝑆𝑆𝑒𝑒𝑥𝑥𝑥𝑥 = where: W = 𝑊𝑊 𝑉𝑉 Equation 15 external chemical mass loading entering a computational grid cell (M/T) In cases where the volumetric flow of water associated with the external load is explicitly represented in the hydrodynamic model, the mass loading is represented in AQFATE by specifying a chemical concentration associated with the flow rate. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 14 March 2017 040284-01.08 Attachment 1 2.6.1.2 Kinetic Reactions AQFATE includes a generalized kinetics algorithm, capable of simulating any order chemical reaction, for the purposes of simulating loss (or gain) of chemical by transformation or degradation processes. The most common approach is to use the kinetics framework to represent degradation processes (for applicable chemicals) as a first order decay process: Equation 16 𝑆𝑆𝑤𝑤𝑤𝑤,𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑 = −𝑘𝑘𝑐𝑐𝑡𝑡 where: 𝑆𝑆𝑤𝑤𝑤𝑤,𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑 = degradation sink term in water column (M/[L3T]) k = first order reaction coefficient (T-1) However, as noted above, other order reactions can be represented in the model. 2.6.1.3 Volatilization The other water column kinetic reaction typically simulated by the model for organic chemicals is volatilization, through which dissolved-phase chemicals are exchanged with the atmosphere. The flux at the air-water interface is calculated by the following: 𝑘𝑘 𝑆𝑆𝑣𝑣 = 𝐿𝐿 �𝑐𝑐𝑑𝑑 − ℎ 𝑤𝑤𝑤𝑤 where: 𝑐𝑐𝑎𝑎𝑎𝑎𝑎𝑎 𝐻𝐻 � Equation 17 𝑆𝑆𝑣𝑣 = volatilization mass transfer at the air-water interface (M/[L3T]) 𝐻𝐻 = dimensionless Henry’s Law Constant (HLC) of the chemical (unitless) 𝑘𝑘𝐿𝐿 𝑐𝑐𝑎𝑎𝑎𝑎𝑎𝑎 = volatilization mass transfer coefficient (L/T) = concentration of the chemical in air (M/L3) The above equation simulates the chemical flux at the air-water interface based on a mass transfer coefficient, the total water depth (hwc, which is predicted by the hydrodynamic model), and the concentration gradient between the dissolved phase in the upper layer of the water column and the air phase. The volatilization flux also depends on the dimensionless Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 15 March 2017 040284-01.08 Attachment 1 HLC, which is a fundamental property of the chemical that represents its equilibrium activities in the air and water phases. HLCs are typically reported in units of partial pressure per unit aqueous concentration; therefore, the model calculates the dimensionless form by dividing the input value by the product of the universal gas constant and the water temperature (thus converting pressure into concentration using the ideal gas law), as follows: 𝐻𝐻𝐻𝐻𝐻𝐻 𝐻𝐻 = 𝑅𝑅 𝑇𝑇 where: HLC R Tabs 𝑎𝑎𝑎𝑎𝑎𝑎 Equation 18 = Henry’s Law Constant (E/mol) = Universal Gas Constant (L/T) = Absolute water temperature Apart from the HLC, the key parameter in describing volatilization is the mass transfer coefficient. The model calculates the volatilization mass transfer coefficient based on the classic two-film theory of Lewis and Whitman (1924), which conceptualizes the mass transfer at the air-water interface to be controlled by two thin layers—a liquid film and a gas film. The overall volatilization mass transfer coefficient is calculated based on mass transfer coefficients in each of these films (O’Connor 1983, 1984): 𝑘𝑘𝐿𝐿 = 𝑘𝑘𝑔𝑔 𝑘𝑘𝑙𝑙 𝑘𝑘 𝑘𝑘𝑔𝑔 + 𝑙𝑙 Equation 19 𝐻𝐻 where: kg kl = gas film mass transfer coefficient (L/T) = liquid film mass transfer coefficient (L/T) The gas film mass transfer coefficient is calculated by AQFATE using the following empirical relationship from Mackay and Yeun (1983): 𝑘𝑘𝑔𝑔 = Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 0.0462 𝑈𝑈 ∗ 𝑆𝑆𝑆𝑆𝑎𝑎 16 Equation 20 March 2017 040284-01.08 Attachment 1 where: U* = the friction velocity of the moving air (L/T; meters per second [m/s]), given by: where: U10 Sca 𝑈𝑈 ∗ = 𝑈𝑈10 (6.1 + 0.63𝑈𝑈10 )0.5 ∗ 10−2 Equation 21 = the wind speed measured 10 meters above the water surface (L/T; m/s) = Schmidt Number of the chemical in air, which represents the ratio of its kinematic viscosity in air (which is calculated by the model as a function of temperature) to its diffusivity The model uses two formulations to calculate the liquid film mass transfer coefficient, and then applies the larger of the two. The first formulation, which accounts for flowing conditions, relates the mass transfer coefficient to the current velocity of the surface water (O’Connor and Dobbins 1958), as follows: 𝐷𝐷 𝑘𝑘𝑙𝑙 = � ℎ𝑚𝑚 𝑈𝑈 Equation 22 𝑤𝑤𝑤𝑤 where: U = total current velocity of the water (L/T) calculated by the hydrodynamic model The second formulation applied by the chemical fate and transport model to calculate the liquid film mass transfer coefficient, which is more applicable for quiescent flow conditions, relates the mass transfer to the shearing action of winds at the water surface based on the empirical formulation of Mackay and Yeun (1983): 𝑘𝑘𝑙𝑙 = 0.0144 (U∗ )0.22 Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site �Scw 17 ; U ∗ < 0.3 Equation 23 March 2017 040284-01.08 Attachment 1 𝑘𝑘𝑙𝑙 = 0.0341 U∗ U ∗ > 0.3 ; �Scw Equation 24 where: Scw = Schmidt Number of the chemical in water, which represents the ratio of its kinematic viscosity in water (which is calculated by the model as a function of water temperature) to its diffusivity Finally, the overall volatilization mass transfer coefficient calculated using Equations 19 through 24 is corrected for temperature effects in the model using the standard Arrhenius Equation (e.g., Chapra 1997): 𝑇𝑇−𝑇𝑇𝑟𝑟𝑟𝑟𝑟𝑟 𝑘𝑘𝐿𝐿,𝑇𝑇 = 𝑘𝑘𝐿𝐿,𝑇𝑇𝑟𝑟𝑟𝑟𝑟𝑟 𝜃𝜃𝑣𝑣 where: T Tref θv 2.6.2 Equation 25 = water temperature = reference temperature (usually taken to be 20 degrees Celsius) = volatilization temperature correction factor (unitless) Sediment Bed Similar to the water column, the model is capable of simulating external loadings and reactions in the sediment bed. 2.6.2.1 External Loadings As noted in Equation 2, the model can simulate chemical loads entering the bottom of the sediment bed, which may be used to represent the case of chemical flowing into the sediments from deep groundwater. (Such loadings were not included in the model’s application to Patrick Bayou.) The loading term in the model is calculated based on the product of Darcy velocity and concentration of the groundwater, as follows: 𝑆𝑆𝑔𝑔𝑔𝑔 = Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 𝑢𝑢𝑧𝑧,𝑏𝑏𝑏𝑏𝑏𝑏 𝑐𝑐𝑔𝑔𝑔𝑔 𝑉𝑉 18 Equation 26 March 2017 040284-01.08 Attachment 1 where: cgw = concentration of chemical in groundwater flowing up into the simulated sediment bed (M/L3) 2.6.2.2 Kinetic Reactions Kinetic reactions within the sediment bed are simulated in the model similar to those in the water column, as discussed in Section 2.6.1.2. The most commonly represented process is degradation (for applicable chemicals), which is simulated in the sediment bed in the same manner as for the water column, as described above (Section 2.6.1.2 and Equation 16). When used to simulate biodegradation, the first order rate coefficients are typically varied in the modeled sediment vertically to represent differences in this process between aerobic and anaerobic zones of the bed. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 19 March 2017 040284-01.08 3 REFERENCES Alcoa, Inc., 2012. Analysis of Alternatives Report, Grasse River Study Area, Massena, New York. June 2012. Anchor QEA (Anchor QEA, LLC), 2010. The Upper Hudson River PCB Modeling System. Prepared for General Electric Company. June 2010. Anchor QEA, 2011. Sediment Transport Modeling Report, Patrick Bayou. Prepared for Patrick Bayou Joint Defense Group and U.S. Environmental Protection Agency, Region 6. September 2011. Anchor QEA, 2012a. Portland Harbor RI/FS Draft Feasibility Study. Prepared for the Lower Willamette Group. March 2012. Anchor QEA, 2012b. Chemical Fate and Transport Modeling Study, San Jacinto River Waste Pits Superfund Site. Prepared for McGinnes Industrial Maintenance Corporation, International Paper Company, and U.S. Environmental Protection Agency, Region 6. October 2012. ARCADIS, Anchor QEA, and AECOM, 2010. CT 1D Analysis: Appendix J of the Housatonic River – Rest of River Revised Corrective Measures Study Report. Prepared for General Electric Company. October 2010. Boudreau, B., 1997. Diagenetic Models and Their Implementation: Modeling Transport Reactions in Aquatic Sediments. Springer-Verlag, New York. Chapra, S.C., 1997. Surface Water-Quality Modeling. New York: McGraw-Hill. Connolly, J.P. and R.P. Winfield, 1984. WASTOX, A Framework for Modeling Toxic Chemicals in Aquatic Systems. U.S. Environmental Protection Agency, Gulf Breeze, FL, EPA 600/3 84 077. Connolly, J.P., H.A. Zahakos, J. Benaman, C.K. Ziegler, J. Rhea, and K. Russell, 2000. A model of PCB fate in the Upper Hudson River. Environ. Sci. Technol. 34(19):40764087. Connolly, J.P. and R.V. Thomann, 1985. WASTOX, A Framework for Modeling Toxic Chemicals in Aquatic Systems, Part II: Food Chain. U.S. Environmental Protection Agency, Gulf Breeze, FL, EPA 600/3 85 017. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 20 March 2017 040284-01.08 Attachment 1 Domenico, P.A. and F.W. Schwartz, 1990. Physical and Chemical Hydrogeology. John Wiley & Sons, New York. Gelhar, L.W., C. Welty, and K.R. Rehfeldt, 1992. A Critical Review of Data on Field-Scale Dispersion in Aquifers. Water Resources Research 28(7):1955-1974. Imhoff, J.C., A. Stoddard, and E.M. Buchak, 2003. Evaluation of Contaminated Sediment Fate and Transport Models. Final Report. U.S. EPA, National Exposure Research Laboratory, Athens, GA. Karickhoff, S.W., 1984. Organic pollutant sorption in aquatic system. J. Hydr. Eng. 110:707-735. La Licata, I., C.D. Langevin, A. M. Dausman, and L. Alberti. 2011. Effect of tidal fluctuations on transient dispersion of simulated contaminant concentrations in coastal aquifers. Hydrogeology Journal 19: 1313–1322. Lampert, D.J. and D. Reible, 2009. An Analytical Modeling Approach for Evaluation of Capping of Contaminated Sediments. Soil and Sediment Contamination: An International Journal 18(4):470-488. Lewis, W.K. and W.G. Whitman, 1924. Principles of Gas Absorption. Ind. Eng. Chem. 16(12):1215-1220. Mackay, D. and Yeun, A.T.K., 1983. Mass Transfer Coefficient Correlations for Volatilization of Organic Solutes from Water. Environ. Sci. Technol. 17(4):211-217. O’Connor, D.J., 1983. The effect of wind on the gas-liquid transfer coefficients. J. Environ. Eng. Div. ASCE 109:731-752. O’Connor, D.J., 1984. The significance of gas exchange in water quality assessment and planning. In: Gas Transfer at Water Surfaces, Eds. W. Brutsaert, and G.H. Jirka, D. Reidel Publishing Company, pp. 559-576. O’Connor, D.J. and W.E. Dobbins, 1958. Mechanisms of reaeration in natural streams. Trans. Am. Soc. Civ. Eng. 123:641-684. QEA (Quantitative Environmental Analysis, L.L.C.), 2005. Dredge Resuspension Modeling: Attachment E to the Phase 1 Intermediate Design Report Hudson River PCBs Superfund Site. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 21 March 2017 040284-01.08 Attachment 1 QEA, 2007. Development, Calibration, and Application of a Mathematical Model of Surface Water PCB Fate, Transport, and Bioaccumulation at the Neal’s Landfill Site, Bloomington, IN. Prepared for CBS Corporation, March 2007. Shen, L. and Z. Chen, 2007. Critical review of the impact of tortuosity on diffusion. Chemical Engineering Science 62:3748-3755. Thibodeaux, L.J. and V.J. Bierman, 2003. The bioturbation-driven chemical release process. Environ. Sci. Technol. 37(13):252A-258A. Thibodeaux, L.J., K.T. Valsaraj, and D.D. Reible, 2001. Bioturbation-Driven Transport of Hydrophobic Organic Contaminants from Bed Sediment. Environmental Engineering Science 18(4):215-223. USEPA (U.S. Environmental Protection Agency), 2000. Hudson River PCBs Reassessment RI/FS Phase 2 Report – Review Copy: Further Site Characterization and Analysis – Volume 2D – Revised Baseline Modeling Report. Developed for USEPA Region 2 by TAMS Consultants et al., January 2000. USEPA, 2006. Final Model Documentation Report: Modeling Study of PCB Contamination in the Housatonic River. Prepared by Weston Solutions, Inc., West Chester, PA. Prepared for the U.S. Army Corps of Engineers, New England District, and the U.S. Environmental Protection Agency, New England Region, November 2006. USEPA, 2007. Record of Decision Amendment for Neal’s Landfill Site Operable Units 2 and 3. Neal’s Landfill Site, Bloomington, Indiana. Superfund Site ID IND980614556, USEPA Region 5. September 2007. Wool, T.A., R.B. Ambrose, J.L. Martin, and E.A. Comer, 2008. Water Quality Analysis Simulation Program (WASP), Version 6.0 Draft User’s Manual, as supplied with electronic model files obtained from http://epa.gov/athens/wwqtsc/html/wasp.html. Chemical Fate and Transport Modeling Study Patrick Bayou Superfund Site 22 March 2017 040284-01.08 APPENDIX B PRELIMINARY CAPPING ASSESSMENT PATRICK BAYOU SUPERFUND SITE Prepared for Patrick Bayou Joint Defense Group U.S. Environmental Protection Agency Prepared by Anchor QEA, LLC 614 Magnolia Avenue Ocean Springs, Mississippi 39564 March 2017 TABLE OF CONTENTS 1 INTRODUCTION ................................................................................................................ 1 2 CHEMICAL ISOLATION ANALYSIS ................................................................................. 3 2.1 Approach ..........................................................................................................................3 2.2 Model Inputs ....................................................................................................................4 2.2.1 Underlying Porewater Concentrations .....................................................................4 2.2.2 Groundwater Velocity ...............................................................................................5 2.2.3 RCM Sorption .............................................................................................................6 2.3 3 4 Model Results .................................................................................................................10 EROSION PROTECTION ANALYSIS ............................................................................... 11 3.1 Hydrodynamic Modeling...............................................................................................12 3.2 Stable Particle Size Calculation .....................................................................................12 3.3 Armor Layer Thickness..................................................................................................14 3.4 Bridge Replacement .......................................................................................................15 REFERENCES .................................................................................................................... 17 List of Tables Table B-1 Initial Porewater Concentration with Depth....................................................... 5 Table B-2 Input Parameter Values for the Chemical Isolation Cap Model ......................... 8 Table B-3 Sediment Cap Armor Stone D50 SMA (inches) ................................................... 14 Table B-4 Sediment Cap Minimum Armor Layer Thickness by SMA (inches) ................ 14 List of Figures Figure B-1 Model Domain and Cap Configuration Figure B-2 Spatial Distribution of Maximum Depth-Averaged Velocities During the 2-Year Flow Event Figure B-3 Spatial Distribution of Maximum Depth-Averaged Velocities During the 10Year Flow Event Preliminary Capping Assessment Patrick Bayou Superfund Site B-i March 2017 040284-01.08 Table of Contents Figure B-4 Spatial Distribution of Maximum Depth-Averaged Velocities During the 100Year Flow Event Figure B-5 Computed Armor Stone D50 for the 2-Year Flow Event Figure B-6 Computed Armor Stone D50 for the 10-Year Flow Event Figure B-7 Computed Armor Stone D50 for the 100-Year Flow Event Preliminary Capping Assessment Patrick Bayou Superfund Site B-ii March 2017 040284-01.08 LIST OF ACRONYMS AND ABBREVIATIONS µg/L micrograms per liter ACBM articulated concrete block mat cfs cubic feet per second cm centimeters cm/yr centimeters per year COC chemical of concern EFDC Environmental Fluid Dynamics Code FS Feasibility Study GAC Granular Activated Carbon n.d. no date PCB polychlorinated biphenyl RATS Patrick Bayou Remedial Alternatives Technology Screening RCM reactive core mat RI Remedial Investigation SMA Sediment Management Area USACE U.S. Army Corps of Engineers USEPA U.S. Environmental Protection Agency Preliminary Capping Assessment Patrick Bayou Superfund Site B-iii March 2017 040284-01.08 1 INTRODUCTION This appendix describes preliminary analyses to assess the feasibility of in situ containment (i.e., capping) to chemically and physically isolate and stabilize potentially contaminated sediment located within Patrick Bayou. These analyses were performed in accordance with U.S. Environmental Protection Agency’s (USEPA’s) Guidance for In-Situ Subaqueous Capping of Contaminated Sediments (Palermo et al. 1998), based on consideration of the following five components: • Chemical isolation of contaminants • Bioturbation • Consolidation • Erosion • Operational considerations (e.g., placement inaccuracies, geotechnical filtering) Oftentimes, caps are constructed of multiple layers that provide the above functions, although not every component adds to the total cap thickness. For example, as noted in Palermo et al. (2002), the erosion and bioturbation components may be a combined thickness, not requiring independent analysis if it is assumed that the erosion protection layer can resist erosion as well as accommodate bioturbation. In addition, the chemical isolation component, which is evaluated through contaminant transport modeling, explicitly accounts for bioturbation and may also include consolidation processes. As described in the Remedial Alternatives Technology Screening report (RATS) (Anchor QEA 2013a), aggregate caps and articulated concrete block mat (ACBM) caps are two applicable methods of containment. Aggregate caps typically consist of a base layer for chemical isolation (typically sand-sized materials, amended with organic or sorptive material as needed), and, as necessary, a filter and/or armor stone surface layer. The surface armor layer consisting of larger-sized rock prevents erosion of the chemical isolation layer during high flow events. A multi-layered cap consisting of chemical isolation, filter, and armor layers can be on the order of 2 or more feet thick, which can reduce the capacity of the channel to convey flood flows during storm events. To maintain flood flow conveyance capacity when using an aggregate cap, excavation of the channel bed may be necessary prior to cap construction. Where such thick caps are necessary, the required excavation to Preliminary Capping Assessment Patrick Bayou Superfund Site B-1 March 2017 040284-01.08 Introduction accommodate the cap may be such that the entire depth of contaminated sediment would be removed merely to accommodate the cap, thus precluding the need for post-excavation capping. Because of the low profile of the ACBM cap (on the order of 4 to 8 inches thick), excavation prior to ACBM placement is not assumed necessary for maintaining channel flood flow conveyance capacity. This advantage, as well as the fact that ACBM can often be placed in areas with limited equipment access, means that ACBM is an ideal choice for channels with limited flood flow conveyance capacity and/or access constraints, both of which are issues for Patrick Bayou. Furthermore, ACBM can provide erosion control for relatively thin chemical isolation layers, such as reactive core mats (RCMs), thereby providing the multiple functions of a cap while maintaining a low profile. This appendix focuses on the chemical isolation and erosion protection components of the cap and preliminarily addresses the other thickness components. Additional cap design analysis would be performed as part of the remedial design if capping is selected as part of the remedy for Patrick Bayou through the Feasibility Study (FS). Preliminary Capping Assessment Patrick Bayou Superfund Site B-2 March 2017 040284-01.08 2 CHEMICAL ISOLATION ANALYSIS Preliminary modeling analyses were conducted to assess the feasibility of in situ containment (i.e., capping) to chemically isolate potentially contaminated sediment located within the portions of Patrick Bayou identified for evaluation as part of this FS. These analyses were performed in accordance with the U.S. Environmental Protection Agency’s (USEPA’s) Guidance for In-Situ Subaqueous Capping of Contaminated Sediments (Palermo et al. 1998) and other technical guidance documents referenced where appropriate. The primary goal of this modeling was to simulate the transport of polychlorinated biphenyls (PCBs) within the chemical isolation component of a sediment cap and to use the model to evaluate the longterm effectiveness of the cap in reducing porewater PCB concentrations within the biologically active zone, thereby reducing potential exposure to benthic organisms and flux to the surface water. 2.1 Approach The one-dimensional model of chemical transport within sediment caps developed by Dr. Danny Reible was used for this evaluation (Reible 2012; Lampert and Reible 2009; Go et al. 2009). This model simulates the time-variable fate and transport of chemicals (dissolved and sorbed phases) under the processes of advection, diffusion/dispersion, biodegradation, bioturbation/bioirrigation, and exchange with the overlying surface water. This model has been used to support the evaluation and design of sediment caps at numerous sites around the United States. Details on the model structure and underlying theory and equations are provided in Lampert and Reible (2009), Go et al. (2009), and the USEPA/USACE capping guidance (Palermo et al. 1998). A schematic of the cap profile represented in the model is shown on Figure B-1. As discussed in Section 4 of the main FS, the conceptual cap design being evaluated in this FS consists of a RCM overlain by ACBM. The RCM provides chemical isolation through adsorption, while the ACBM provides physical stability/armor protection (see Section 3). The RCM is relatively thin (CETCO 2012), and was simulated in the model as 1-cm thick adsorptive layer. The ACBM product is offered in various thicknesses typically ranging from 4 to 8 inches; for purposes of the FS, an ACBM thickness of 4 inches has been assumed. While this material is 4 inches at its thickest point, thinner areas are present between blocks. Preliminary Capping Assessment Patrick Bayou Superfund Site B-3 March 2017 040284-01.08 Chemical Isolation Analysis These thinner areas are expected to fill in with material depositing over time. Therefore, this portion of the cap was represented in the model as a 10 cm granular layer, where bioturbation occurs (termed the bioturbation zone). This approach is conservative, because the ACBM will largely prevent any bioturbation from occurring; only the depressions of the ACBM, where material deposits, would be subject to bioturbation. The model was used to evaluate the ability of a cap to reduce surface porewater PCB concentrations over a long timeframe, which was taken to be 100 years for this evaluation. The chemical isolation layer modeling was conducted to evaluate cap effectiveness for the Sediment Management Areas (SMAs) within the Bayou being evaluated in this FS (see Section 4 and Figure 4-1 of main FS). 2.2 Model Inputs The model uses several input parameters that describe site-specific conditions, chemicalspecific properties, cap material properties, and chemical mass transport rates. These input parameters were based on site-specific data, information from literature, and experience with cap design at other sites. Many of these input parameters are also used in the chemical fate and transport model that was developed and calibrated for the site (see Appendix A); in these cases, the values used in the cap evaluation modeling are the same as those used in the chemical fate and transport model. 2.2.1 Underlying Porewater Concentrations As part of the remedial investigation (RI), porewater samples were collected from the Site at 10 locations; these data provided information to assess partitioning within the sediments, but were not intended to provide detailed spatial coverage across the Site, nor were they without limitations (e.g., it is likely that the centrifugation method used to extract porewater did not fully separate the particulate and dissolved phases; see Appendix A). Therefore, porewater concentrations used in this cap modeling evaluation were specified based on values calculated by the chemical fate and transport model described in Appendix A.1 As a conservative approach, the average value calculated by the fate and transport model from the Porewater concentrations calculated by the fate and transport model are based on detailed site-wide mapping of sediment total organic carbon and PCB data and site-specific partition coefficients developed from the porewater data, after correcting for particulate matter (see Appendix A for details). 1 Preliminary Capping Assessment Patrick Bayou Superfund Site B-4 March 2017 040284-01.08 Chemical Isolation Analysis area having the highest predicted porewater concentrations within the Site (near sediment management area [SMA] 4 [SMA-4]), were used for this analysis.2 Porewater concentrations in the chemical fate and transport model represent the upper 30 cm of sediment (see Appendix A), whereas the cap modeling effort simulates 1 meter of sediment based on interpretation of vertical profiles of PCB concentrations within sediment cores collected from Patrick Bayou that indicate an increase in concentrations to a depth of approximately 1 meter (Figure 4-6 of RI report; Anchor QEA 2013b). Thus, porewater concentrations predicted by the chemical fate and transport model, were used to estimate concentrations down to a 1 meter thickness. The model also conservatively assumes an infinite source of contaminated porewater at the bottom of the simulated 1 meter sediment column. Table B-1 presents the porewater PCB concentrations used in the cap model for various depth intervals of sediment beneath the simulated cap. Table B-1 Initial Porewater Concentration with Depth 2.2.2 Depth (cm) Total PCB (µg/L) 0-10 12.0 10-30 62.5 30-100 188 Groundwater Velocity The groundwater (Darcy) velocity used in the cap model evaluation was estimated based on hydraulic conductivity and hydraulic gradient measurements from the Deer Park Lubrizol facility. Darcy velocities calculated from these data were generally within the range of 10 cm/yr to 100 cm/yr. However, upward groundwater flow through sediments is dictated by vertical hydraulic conductivity and hydraulic gradients; recognizing that the upland measurements represent horizontal hydraulic gradients (based on differences in head between wells) and horizontal hydraulic conductivity (based on slug tests and pumping tests), the calculated Darcy velocity range noted above is likely higher than the actual The chemical fate model indicates that the PCB flux associated with SMA-1 is the greatest within the Site (see Appendix A); however, because the exact nature of the source of PCBs in SMA-1 is currently not well understood from a mechanistic standpoint, the chemical-isolation modeling was not applied to this area. 2 Preliminary Capping Assessment Patrick Bayou Superfund Site B-5 March 2017 040284-01.08 Chemical Isolation Analysis vertical velocities within the sediment. Horizontal hydraulic conductivity is at least a factor of 5 to 10 higher than vertical hydraulic conductivity (Spitz and Moreno 1996); therefore, the vertical Darcy velocity within the sediments could be 10 times less than the range calculated. To address uncertainties in groundwater velocity based on these upland data, a range of values was simulated in the capping model, including 0 centimeters per year (cm/yr; i.e., no seepage), 1 cm/yr, 10 cm/yr and 100 cm/yr. 2.2.3 RCM Sorption The reactive core mat simulated in this analysis is based on the properties of a CETCO® Reactive Core MatTM with a Granular Activated Carbon (GAC) Core. This RCM includes GAC at a dose of 0.4 lb/ft2. To represent this RCM in the model, the porosity and particle density values were specified to result in a mass per unit area of active material within the 1-cm thick simulated layer of 0.4 lb/ft2, as shown in Equations B-1 and B-2. (B-1) 𝐷𝐷𝐺𝐺𝐺𝐺𝐺𝐺 = 𝜌𝜌𝑏𝑏 ∙ 𝑡𝑡 (B-2) 𝜌𝜌𝑏𝑏 = 𝜌𝜌 ∙ (1 − 𝜙𝜙) where: DGAC = GAC Dose (M/L2) ρb = dry bulk density (M/L3) t = thickness (L) ρ = particle density (M/L3) φ = porosity Setting porosity of the RCM to a typical value of 0.4, thickness to a representative value of 1 cm, and GAC dose to 0.4 lb/ft2, the resulting particle density used in the model for the RCM was calculated as 0.33 g/cm3. Research has shown that adsorption of PCBs onto GAC is non-linear, and typically can be described by a Freundlich isotherm (McDonough et. al. 2008). Therefore, the sorption properties of the GAC RCM were specified based on Freundlich isotherm coefficients (Kf and Preliminary Capping Assessment Patrick Bayou Superfund Site B-6 March 2017 040284-01.08 Chemical Isolation Analysis 1/n) for a Tri-PCB homolog (McDonough et. al. 2008), which is representative of the PCB composition at the site. Input Parameter Summary A listing of input parameter values used for this preliminary modeling evaluation, and the source(s) from which they were derived is provided in Table B-2. Preliminary Capping Assessment Patrick Bayou Superfund Site B-7 March 2017 040284-01.08 Chemical Isolation Analysis Table B-2 Input Parameter Values for the Chemical Isolation Cap Model Model Input Parameter Value Data Source Chemical-specific Properties Organic carbon partition coefficient, log KOC (log L/kg) 5.3 Log Kf (ng/kg) (L/ng)1/n 8.0 1/n 0.7 Water diffusivity (cm2/s) 2E-06 Chemical biodegradation rate (yr-1) 0 Underlying porewater concentration (µg/L) See Table B1 Based on values used in the fate and transport model for PCB1-9 homolog groups (Appendix A). Value is applied in the model to simulate 1-m of underlying sediment and bioturbation zone. Freundlich isotherm coefficient for adsorption of PCBs onto GAC. Value represents Tri-PCB homolog (McDonough et al. 2008) Freundlich isotherm coefficient for adsorption of PCBs onto GAC. Value representing Tri-PCB homolog (McDonough et al. 2008) Based on values used in the fate and transport model for PCB1-9 homolog groups (Appendix A) No degradation, consistent with fate and transport model inputs (Appendix A). Porewater concentrations predicted at the beginning of the fate model simulation. Because sediment represented in the fate model is 30 cm thick, the porewater concentrations were estimated to deeper depths based on data from RI sediment cores that indicate concentrations generally increase with depth down to a depth of approximately 1 m. Cap Properties RCM thickness (cm) 1 Particle density of RCM layer (g/cm3) 0.33 Porosity of RCM layer 0.4 Bioturbation zone thickness (cm) 10 Particle density of Bioturbation zone (g/cm3) 2.6 Porosity of bioturbation zone 0.7 Preliminary Capping Assessment Patrick Bayou Superfund Site Nominal thickness used in model to represent relatively thin layer of RCM. Calculated to achieve 0.4 lb/sf GAC for a 1-cm RCM assuming a porosity of 0.4. See Equations B-1 and B-2. Typical value for cap material; value is specified together with thickness and particle density of RCM to produce 0.4 lb/sf of GAC. 10-cm layer representing material that fills in the depressions of ACBM. Typical value for sediment (e.g., Domenico and Schwartz 1990). Consistent with porosity of sediment assuming materials depositing in depressions of ACBM are consistent with surface sediment. B-8 March 2017 040284-01.08 Chemical Isolation Analysis Model Input Parameter Fraction organic carbon (foc) of bioturbation zone (%) Value 1.5 Data Source Consistent with foc of existing surface sediment assuming material depositing in depressions of ACBM is similar. Sediment Properties Sediment thickness (cm) 100 Sediment porosity 0.7 Sediment particle density (g/cm3) 2.6 Sediment fOC (%) 1.5 Thickness of sediment underlying the cap simulated in the model is consistent with the depth of contaminated sediment based on the RI sediment cores, which indicate concentrations generally increase with depth down to a depth of approximately 1 m. Consistent with fate and transport model (see Appendix A). Typical value for sediment (e.g., Domenico and Schwartz 1990). Consistent with fate and transport model (see Appendix A). Mass Transport Properties Boundary layer mass transfer coefficient (cm/hr) 0.5 Consistent with fate and transport model (Appendix A). Groundwater seepage Darcy velocity (cm/yr) Range Depositional velocity (cm/yr) 0 Groundwater velocities ranging from 0 cm/yr to 100 cm/yr were selected based on data analyzed from Lubrizol facility and expectation that vertical velocities within sediments are lower than those based on upland horizontal gradients and slug/pumping test measurements. Conservatively assumed no net sedimentation. Dispersion length (cm) 1 Based on recommendation from Reible (2012). Bioturbation layer thickness (cm) 10 Consistent with fate and transport model (Appendix A). Particle and Porewater Biodiffusion coefficients (cm2/yr) 31.5 Consistent with fate and transport model (Appendix A). Notes: µg/L – micrograms per liter cm – centimeter cm/hr – centimeters per hour cm/yr – centimeters per year cm2/s – square centimeters per second cm2/yr – square centimeters per year fOC – organic carbon content g/cm3 – grams per cubic centimeter L/kg – liters per kilogram yr-1 – per year Preliminary Capping Assessment Patrick Bayou Superfund Site B-9 March 2017 040284-01.08 Chemical Isolation Analysis 2.3 Model Results Results of the modeling indicate that a single 0.4 lb/sf RCM with a GAC core would prevent any significant flux of PCBs for an extended timeframe. Model-predicted porewater concentrations within the bioturbation zone above the cap are essentially zero for the duration of the 100-year simulation—a reduction in porewater concentration of over 99.9 percent, even at the highest groundwater velocity simulated (100 cm/yr). Although a single layer RCM was considered in the modeling, for FS purposes a double layer of RCM has been assumed in SMA-1 where the PCB source is not well characterized (see Appendix A). The actual thickness, dosage, and number of layers of RCM that might be needed to effectively address porewater PCBs would be more fully evaluated during remedial design. Although deposition was conservatively ignored in this analysis, Patrick Bayou is known to be a depositional environment based on the sediment transport modeling (Anchor QEA 2011). Deposition of cleaner sediments on top of the cap would produce even lower predicted porewater concentrations at the surface, resulting in a cap that is more effective at reducing concentrations at the surface than the modeling presented herein has estimated. Preliminary Capping Assessment Patrick Bayou Superfund Site B-10 March 2017 040284-01.08 3 EROSION PROTECTION ANALYSIS As described in the Section 4 of the main FS, engineered capping (or capping) is a remedial technology for containing contaminants in sediments and preventing or reducing the potential exposure to and mobility of those contaminants from the sediment. It involves the placement of a subaqueous covering or cap of suitable material over contaminated sediment. The engineered sediment caps will consist of separate layers to provide specific functions: • Chemical isolation from chemicals of concern (COCs) in the underlying sediment (i.e., “chemical isolation layer”), as described in Section 2 of this Appendix • Protection from physical forces causing erosion (i.e., “armor layer”) As described in the USEPA and the USACE Guidance for In-Situ Subaqueous Capping of Contaminated Sediments (Palermo et al. 1998): “The cap component for stabilization/erosion protection has a dual function. On the one hand, this component of the cap is intended to stabilize the contaminated sediments being capped, and prevent them from being resuspended and transported offsite. The other function of this component is to make the cap itself resistant to erosion. These functions may be accomplished by a single component, or may require two separate components in an in-situ cap.” In addition, USEPA’s Contaminated Sediment Remediation Guidance for Hazardous Waste Sites (USEPA 2005) states that: “[t]he design of the erosion protection features of an in-situ cap (i.e., armor layers) should be based on the magnitude and probability of occurrence of relatively extreme erosive forces estimated at the capping site. Generally, insitu caps should be designed to withstand forces with a probability of 0.01 per year, for example, the 100-year storm.” This section describes the evaluation of the erosive forces for the sediment cap in Patrick Bayou (Bayou), which define the extent and type of armor layer necessary to protect the cap. Preliminary Capping Assessment Patrick Bayou Superfund Site B-11 March 2017 040284-01.08 Erosion Protection Analysis 3.1 Hydrodynamic Modeling The primary objective of the armor layer is to prevent erosion of the chemical isolation layer due to high flows in the Bayou. Hydrodynamic flows, particularly during high-flow events, can result in elevated water velocities and corresponding elevated bed shear stresses, which have the potential to erode sediments. To evaluate the current velocities and stable particle size to resist these velocities, the hydrodynamic model that was developed to evaluate the remedial alternatives was used (described in Anchor QEA 2011). The hydrodynamic model used in this study is the Environmental Fluid Dynamics Code (EFDC), which is approved and supported by the USEPA. EFDC is a general purpose hydrodynamic model capable of simulating flow in rivers, lakes, reservoirs, estuaries, and coastal oceans. The model framework, boundary conditions, development, and calibration are described in detail in Anchor QEA (2011), the simulations conducted for the FS, which considered a range of high flow events up to the 100-year return-interval flow events, are described in Appendix A. Several events were simulated to capture the maximum velocities that may act upon the sediment cap in each potential SMA. For the FS evaluation, the 2-, 10- and 100-year return interval flow events were simulated. This represents flow rates of 3,000, 6,000, and 10,000 cubic feet per second (cfs), respectively (Anchor QEA 2011). Figures B-2 through B-4 present the maximum depth-averaged velocities for each event. 3.2 Stable Particle Size Calculation The stable particle size (expressed as D50) in each SMA to resist the flow velocity and related bed shear stress was estimated using the Maynord method, from USEPA Guidance for In-Situ Subaqueous Capping of Contaminated Sediment – Appendix A: Armor Layer Design (Maynord 1998). The method presented in Maynord (1998) and shown in Equation B-3 is based on the USACE’s Hydraulic Design of Flood Control Channels (USACE 1994). This method uses depth-averaged velocity and flow depth to determine the stable median armor stone size (D50).  γ w D50 = S f C s C v CT C G d   γ s − γ w Preliminary Capping Assessment Patrick Bayou Superfund Site B-12    1/ 2   K 1 gd  V 2.5 (B-3) March 2017 040284-01.08 Erosion Protection Analysis where: D50 = Median particle size in feet Sf = Safety factor = 1.5 from page A-6 of Maynord 1998 Cs = Stability coefficient for incipient failure = 0.3 for angular rock (from page A-6 of Maynord 1998) CV = Velocity distribution coefficient = 1.0 (from page A-6 of Maynord 1998) CT = Blanket thickness coefficient = 1.0 for flood flows and thickness = D100 (from page A-6 of Maynord 1998) CG = Gradation coefficient = (D85/D15)1/3 D85/D15 = Gradation uniformity coefficient = 3.5 (from page A-6 of Maynord 1998) d = Water depth in feet (from the hydrodynamic model) γs = Specific (unit) weight of stone = 165 pounds per cubic foot γw = Specific (unit) weight of water = 64.0 pounds per cubic foot (saltwater) V = Maximum depth-averaged velocity in feet per second (from the hydrodynamic model) K1 = Side slope correction factor = based on maximum slope within the model grid cell using from Plate B-39 from USACE 1994 g = Acceleration due to gravity = 32.2 feet per second squared The results are also shown on Figures B-5 through B-7. The computed armor stone D50 for each SMA is summarized in Table B-3. Preliminary Capping Assessment Patrick Bayou Superfund Site B-13 March 2017 040284-01.08 Erosion Protection Analysis Table B-3 Sediment Cap Armor Stone D50 SMA (inches) SMA 1 2 3 4 5 6 7 8 9 3.3 2-Year Flow Event 5.1 2.4 2.2 0.5 3.1 2.7 1.2 3.1 0.6 10-Year Flow Event 14.4 4.9 5.2 0.5 5.8 3.8 1.9 6.8 1.7 100-Year Flow Event 36.8 8.0 9.0 0.5 6.0 5.1 2.2 6.1 5.6 Armor Layer Thickness Maynord (1998) recommends that the thickness of the armor layer be 1.5 times the maximum particle diameter (1.5D100) or twice the median particle diameter (2D50), whichever is greater. Although this recommendation would result in minimum design thicknesses of only a few inches in some SMAs, the minimum armor protection layer thickness was assumed to be 3 inches in this FS evaluation due to construction tolerances. Table B-4 below summarizes the minimum armor layer thickness for each SMA. Table B-4 Sediment Cap Minimum Armor Layer Thickness by SMA (inches) SMA 1 2 3 4 5 6 7 8 9 Preliminary Capping Assessment Patrick Bayou Superfund Site Armor Layer D50 36.8 8.0 9.0 0.5 6.0 5.1 2.2 6.8 5.6 B-14 Minimum Thickness 74 16 18 3 12 10 4.5 14 12 March 2017 040284-01.08 Erosion Protection Analysis For larger armor stone sizes, a filter layer would be required to prevent the chemical isolation layer material (e.g., sand and carbon) from passing through the void spaces in the overlying larger material (e.g., erosion protection armor stone). As described in the Introduction, in lieu of an aggregate armored cap, an ACBM could be used for the armor layer of the cap to minimize the armor layer thickness. Depth-averaged velocities over the capping areas ranged between 3 and 14 feet per second. A 4-inch thick ACBM has been shown to be very resistant to high flow velocity (15 to 17 feet per second) and shear stress (18 to 26 pounds per square foot) (Ayres Associates n.d). This indicates that ACBM could be used to resist these erosive forces. ACBM provides the advantage of being protective of erosive forces, but requiring significantly less armor layer thickness than traditional loose-placed riprap or armor stone. 3.4 Bridge Replacement Currently, the Railroad Bridge located in SMA-1 is being replaced. Flow in Patrick Bayou will be conveyed under the bridge through a series of culverts. The U.S. Department of Transportation Federal Highway Administration (USDOT FHWA) describes the use of riprap aprons as a common form of erosion protection used at culvert outlets in their Hydraulic Engineering Circular No. 14 (HEC 14; USDOT FHWA 2006). Riprap aprons are constructed at a zero grade for a distance that is often related to the outlet pipe diameter. They do not dissipate significant energy except through increased roughness for a short distance. However, they do serve to spread the flow helping to transition to the natural drainage. The key design elements of a riprap apron are the riprap size as well as the length, width, and depth of the apron (USDOT FHWA 2006). Equation 10.4 from USDOT FHWA (2006) was used to evaluate the stable armor stone size and associated riprap apron dimensions. Equation 10.4 (USDOT FHWA 2006) computes the median stable armor stone size (i.e., D50) based on the flow rate through the culvert, the diameter of the culvert, and the water depth at the outlet of the culvert (i.e., tailwater depth). The flow rate and water depth used in analysis were equivalent to the 100-year return interval conditions and were based on outputs of the hydraulic model developed for the area. The proposed bridge crossing calls for a configuration of five elliptical-shaped culverts with a span of approximately 11.2 feet and a rise of approximately 14.9 feet. Equation 10.4 (USDOT FHWA 2006) is intended to evaluate Preliminary Capping Assessment Patrick Bayou Superfund Site B-15 March 2017 040284-01.08 Erosion Protection Analysis circular culverts but was considered an appropriate method to determine a preliminary estimate of a suitable riprap apron. The D50 calculated using Equation 10.4 (USDOT FHWA 2006) equaled approximately 1 foot. Table 10.1 in USDOT FHWA (2006) provides examples of riprap classes and apron dimensions. A D50 of 1 foot would fall into a Class 4 riprap, which has a D50 of 14 inches. The associated riprap apron length for Class 4 riprap is 6 times the culvert rise, which resulted in an apron length of approximately 90 feet. The riprap apron depth (i.e., thickness) for Class 4 riprap is 2.2 times the D50, which resulted in an apron depth of approximately 26 inches. In summary, the culverts will change the flow characteristics of Patrick Bayou locally in the vicinity of the bridge. The evaluation of the proposed scour protection using FHWA design guidance indicates that the proposed cap armor protection for SMA-1 (either the aggregate materials or ACBM) will be capable of withstanding any increases in scour potential due to the installation of the culverts. Preliminary Capping Assessment Patrick Bayou Superfund Site B-16 March 2017 040284-01.08 4 REFERENCES Anchor QEA (Anchor QEA, LLC), 2011. Sediment Transport Modeling Report: Patrick Bayou. September 2011. Anchor QEA, 2013a. Remedial Alternatives and Technology Screening Report. Patrick Bayou Superfund Site, Deer Park, Texas. Prepared for U.S. Environmental Protection Agency and the Patrick Bayou Joint Defense Group. May 2013. Anchor QEA, 2013b. Patrick Bayou Remedial Investigation Report. Patrick Bayou Superfund Site, Deer Park, Texas. Prepared for U.S. Environmental Protection Agency and the Patrick Bayou Joint Defense Group. September 2013. Ayres Associates, n.d. Hydrotex, Hydraulic stability of Hydrotex Fabric Formed Concrete Mattresses in Steep-Slope, High-Velocity flow. CETCO, 2012. Remediation Technologies Technical Data Sheet: Reactive Core Mat™. February 2012. Available from: http://remediation.cetco.com/DesktopModules/Bring2mind/DMX/Download.aspx?Ent ryId=745&Command=Core_Download&language=en-US&PortalId=9&TabId=1359 Domenico, P.A., and F.W. Schwartz, 1990. Physical and Chemical Hydrogeology. John Wiley & Sons, New York. Go, J., D.J. Lampert, J.A. Stegemann, and D.D. Reible, 2009. Predicting contaminant fate and transport in sediment caps: Mathematical modeling approaches. Applied Geochemistry 24(2009):1347-1353. Lampert, D.J., and D. Reible, 2009. An Analytical Modeling Approach for Evaluation of Capping of Contaminated Sediments. Soil and Sediment Contamination: An International Journal 18(4):470-488. Maynord, S., 1998. Appendix A: Armor Layer Design for the Guidance for In-Situ Subaqueous Capping of Contaminated Sediment. EPA 905-B96-004, Great Lakes National Program Office, Chicago, Illinois. McDonough, K.M., L.F. Julian, and G.V. Lowry, 2008. Adsorption of polychlorinated biphenyls to activated carbon: Equilibrium isotherms and a preliminary assessment of the effect of dissolved organic matter and biofilm loadings. Water Research 42(2008):575-584. Preliminary Capping Assessment Patrick Bayou Superfund Site B-17 March 2017 040284-01.08 References Palermo, M., S. Maynord, J. Miller, and D. Reible, 1998. Guidance for In-Situ Subaqueous Capping of Contaminated Sediments. EPA 905-B96-004, Great Lakes National Program Office, Chicago, Illinois. Palermo, M.R., T.A. Thompson, and F. Swed, 2002. In Situ Capping as a Remedy Component for the Lower Fox River, Responsiveness Summary, Lower Fox River and Green Bay, Wisconsin Site Record of Decision, Operable Units 1 and 2. White Paper No. 6b. Wisconsin Department of Natural Resources, Madison, Wisconsin and USEPA Region 5, Chicago, Illinois. December 2002. Reible, D., 2012. Model of 2 Layer Sediment Cap, Description And Parameters. Version - 2 Layer Analytical Model v.1.18 and Active Cap Layer Model v 4.1. Accessed online at: http://www.caee.utexas.edu/reiblegroup/downloads/2 layer analytical model description.doc. Spitz, K., and J. Moreno, 1996. A Practical Guide to Groundwater and Solute Transport Modeling. New York, New York: John Wiley & Sons, Inc. USACE (U.S. Army Corps of Engineers), 1994. Hydraulic Design of Flood Control Channels. Engineering Manual EM 1110-2-1601. U.S. Army Corps of Engineers. Washington, DC. USDOT FHWA (U.S. Department of Transportation Federal Highway Administration), 2006. Hydraulic Design of Energy Dissipators for Culverts and Channels - Hydraulic Engineering Circular No. 14, Third Edition. Prepared by the U.S. Department of Transportation Federal Highway Administration National Highway Institute. Publication No. FHWA-NHI-06-086. July 2006. USEPA (U.S. Environmental Protection Agency), 2005. Contaminated Sediment Remediation Guidance for Hazardous Waste Sites. EPA-540-R-05-012, Office of Solid Waste and Emergency Response. Preliminary Capping Assessment Patrick Bayou Superfund Site B-18 March 2017 040284-01.08 HGES Overlying Water  Column ABM* Deposition Bioturbation* Advection Diffusion Tidal Mixing Sorption RCM (Activated Carbon) Model  Domain Impacted  Sediment/ Porewater (Infinite Source) *The layer of ABM in the model represents the thinner portions of the ABM that fill in with depositing material, where bioturbation can occur.  Figure B‐1 Model Domain and Cap Configuration Patrick Bayou Feasibility Study Report –Appendix B Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas on t s u Ho Sh ip ne n a Ch l S MA3 S MA2 S MA5 S MA8 S MA6 S MA7 S MA4 E s0t FE or S e rvic e Laye r Cre d it s :Copyrig ht : ©a 2 14 s rk i, De Lorm e ,HERE,Tom Tom I nflow S ource :Es ri,Dig it alGlobe ,Ge oEye ,icube d , US DA,US GS ,AEX,Ge t m apping ,Ae rog rid , \ \ hous t on2\ Com put e r_Bac kups \ Dale e l\ E_DRI VE\ DEMpat \ Dat a\ 140819_Re m e d iat ion_Zone s \ pb_fig ure s _fs _160217. m xd d nang ju 2/ 17/ 2016 1: 12: 49PM Main I nflow S MA9 S MA1 LEGEND S hore line S e d im e ntManag e m e ntAre as Current Velocity (ft/s) 0-0. 1 0. 1-1 1-2 2-4 4-6 6-8 Hous t on 8-10 10-12 >12 [ 0 500 1, 000 Fe e t Figure B-2 S pat ialDis t ribut ion of Maxim um De pt hAv e rag e d Ve locit ie s During t he 2Ye ar Flow Eve nt Pat rick Bayou Fe as ibilit yS t ud yRe port– Appe nd ixB Pat rick Bayou S upe rfund S it e Re m e d ialI nve s t ig at ion,De e r Park,T e xas on t s u Ho Sh ip ne n a Ch l S MA3 S MA2 S MA5 S MA8 S MA6 S MA7 S MA4 E s0t FE or S e rvic e Laye r Cre d it s :Copyrig ht : ©a 2 14 s rk i, De Lorm e ,HERE,Tom Tom I nflow S ource :Es ri,Dig it alGlobe ,Ge oEye ,icube d , US DA,US GS ,AEX,Ge t m apping ,Ae rog rid , \ \ hous t on2\ Com put e r_Bac kups \ Dale e l\ E_DRI VE\ DEMpat \ Dat a\ 140819_Re m e d iat ion_Zone s \ pb_fig ure s _fs _160217. m xd d nang ju 2/ 17/ 2016 1: 14: 06PM Main I nflow S MA9 S MA1 LEGEND S hore line S e d im e ntManag e m e ntAre as Current Velocity (ft/s) 0-0. 1 0. 1-1 1-2 2-4 4-6 6-8 Hous t on 8-10 10-12 >12 [ 0 500 1, 000 Fe e t Figure B-3 S pat ialDis t ribut ion of Maxim um De pt hAv e rag e d Ve locit ie s During t he 10Ye ar Flow Eve nt Pat rick Bayou Fe as ibilit yS t ud yRe port– Appe nd ixB Pat rick Bayou S upe rfund S it e Re m e d ialI nve s t ig at ion,De e r Park,T e xas on t s u Ho Sh ip ne n a Ch l S MA3 S MA2 S MA5 S MA8 S MA6 S MA7 S MA4 E s0t FE or S e rvic e Laye r Cre d it s :Copyrig ht : ©a 2 14 s rk i, De Lorm e ,HERE,Tom Tom I nflow S ource :Es ri,Dig it alGlobe ,Ge oEye ,icube d , US DA,US GS ,AEX,Ge t m apping ,Ae rog rid , \ \ hous t on2\ Com put e r_Bac kups \ Dale e l\ E_DRI VE\ DEMpat \ Dat a\ 140819_Re m e d iat ion_Zone s \ pb_fig ure s _fs _160217. m xd d nang ju 2/ 17/ 2016 1: 14: 55PM Main I nflow S MA9 S MA1 LEGEND S hore line S e d im e ntManag e m e ntAre as Current Velocity (ft/s) 0-0. 1 0. 1-1 1-2 2-4 4-6 6-8 Hous t on 8-10 10-12 >12 [ 0 500 1, 000 Fe e t Figure B-4 S pat ialDis t ribut ion of Maxim um De pt hAv e rag e d Ve locit ie s During t he 100Ye ar Flow Eve nt Pat rick Bayou Fe as ibilit yS t ud yRe port– Appe nd ixB Pat rick Bayou S upe rfund S it e Re m e d ialI nve s t ig at ion,De e r Park,T e xas on t s u Ho Sh ip ne n a Ch l S MA3 S MA2 S MA5 S MA8 S MA6 S MA7 S MA4 \ \ hous t on2\ Com put e r_Bac kups \ Dale e l\ E_DRI VE\ DEMpat \ Dat a\ 140819_Re m e d iat ion_Zone s \ pb_fig ure s _fs _160217. m xd d nang ju 2/ 17/ 2016 1: 15: 46PM Main I nflow E s0t FE or S e rvic e Laye r Cre d it s :Copyrig ht : ©a 2 14 s rk i, De Lorm e ,HERE,Tom Tom I nflow S ource :Es ri,Dig it alGlobe ,Ge oEye ,icube d , US DA,US GS ,AEX,Ge t m apping ,Ae rog rid , S MA9 S MA1 LEGEND S hore line S e d im e ntManag e m e ntAre as D50 (in) 0-0. 5 0. 5-1 1-2 2-4 4-6 6-8 Hous t on 8-10 10-12 >12 [ 0 500 1, 000 Fe e t Figure B-5 he Com put e d Arm or S t one D50for t 2Ye ar Flow Eve nt Pat rick Bayou Fe as ibilit yS t ud yRe port– Appe nd ixB Pat rick Bayou S upe rfund S it e Re m e d ialI nve s t ig at ion,De e r Park,T e xas on t s u Ho Sh ip ne n a Ch l S MA3 S MA2 S MA5 S MA8 S MA6 S MA7 S MA4 \ \ hous t on2\ Com put e r_Bac kups \ Dale e l\ E_DRI VE\ DEMpat \ Dat a\ 140819_Re m e d iat ion_Zone s \ pb_fig ure s _fs _160217. m xd d nang ju 2/ 17/ 2016 1: 16: 15PM Main I nflow E s0t FE or S e rvic e Laye r Cre d it s :Copyrig ht : ©a 2 14 s rk i, De Lorm e ,HERE,Tom Tom I nflow S ource :Es ri,Dig it alGlobe ,Ge oEye ,icube d , US DA,US GS ,AEX,Ge t m apping ,Ae rog rid , S MA9 S MA1 LEGEND S hore line S e d im e ntManag e m e ntAre as D50 (in) 0-0. 5 0. 5-1 1-2 2-4 4-6 6-8 Hous t on 8-10 10-12 >12 [ 0 500 1, 000 Fe e t Figure B-6 he Com put e d Arm or S t one D50for t 10Ye ar Flow Eve nt Pat rick Bayou Fe as ibilit yS t ud yRe port– Appe nd ixB Pat rick Bayou S upe rfund S it e Re m e d ialI nve s t ig at ion,De e r Park,T e xas on t s u Ho Sh ip ne n a Ch l S MA3 S MA2 S MA5 S MA8 S MA6 S MA7 S MA4 \ \ hous t on2\ Com put e r_Bac kups \ Dale e l\ E_DRI VE\ DEMpat \ Dat a\ 140819_Re m e d iat ion_Zone s \ pb_fig ure s _fs _160217. m xd d nang ju 2/ 17/ 2016 1: 16: 48PM Main I nflow E s0t FE or S e rvic e Laye r Cre d it s :Copyrig ht : ©a 2 14 s rk i, De Lorm e ,HERE,Tom Tom I nflow S ource :Es ri,Dig it alGlobe ,Ge oEye ,icube d , US DA,US GS ,AEX,Ge t m apping ,Ae rog rid , S MA9 S MA1 LEGEND S hore line S e d im e ntManag e m e ntAre as D50 (in) 0-0. 5 0. 5-1 1-2 2-4 4-6 6-8 Hous t on 8-10 10-12 >12 [ 0 500 1, 000 Fe e t Figure B-7 he Com put e d Arm or S t one D50for t 100Ye ar Flow Eve nt Pat rick Bayou Fe as ibilit yS t ud yRe port– Appe nd ixB Pat rick Bayou S upe rfund S it e Re m e d ialI nve s t ig at ion,De e r Park,T e xas APPENDIX C REMEDIAL ALTERNATIVE COST DEVELOPMENT PATRICK BAYOU SUPERFUND SITE Prepared for Patrick Bayou Joint Defense Group U.S. Environmental Protection Agency Prepared by Anchor QEA, LLC 614 Magnolia Avenue Ocean Springs, Mississippi 39564 March 2017 REMEDIAL ALTERNATIVE COST DEVELOPMENT This appendix summarizes the approaches used to develop remedial alternative quantities and cost estimates for the Patrick Bayou Superfund Site (Site) as a part of the Feasibility Study (FS). A Guide to Developing and Documenting Cost Estimates During the Feasibility Study (USEPA 2000) was followed to develop these cost estimates and was supplemented with contractor estimates and professional judgment where appropriate in estimating daily costs and production rates. Professional judgment drew on the recently completed construction projects in the region. The remainder of this appendix discusses the following: • • Method for developing unit costs for the construction elements, including: − Defining each construction task − Discussion of the cost approach for each construction task Method for developing quantities for each construction element UNIT COST DEVELOPMENT The cost estimate consists of direct and indirect cost elements: • • Direct Construction Tasks − Mobilization/Demobilization − Environmental Protection and Erosion Control − Construction Surveys, Site Preparation, and Utility Clearance − Debris Removal − Treatment – Mixing Activated Carbon (AC) into surface sediments − Treatment – Reactive Core Mat (RCM) with AC − Capping - Articulated Concrete Block Mat (ACBM) Indirect Construction Tasks − Permitting − Engineering Design − Construction Administration/Observation − Long-Term Natural Recovery Monitoring (net present value) Remedial Alternative Cost Development Patrick Bayou Superfund Site C-1 March 2017 040284-01.08 − Long-Term Armored Cap Monitoring (net present value) − Cap Maintenance (net present value) − U.S. Environmental Protection Agency (USEPA) 5-Year Review (net present value) Table 1 provides a summary of unit cost assumptions for the cost sub-elements of each cost element bulleted above. Where appropriate, the source of the assumption is presented. USEPA (2000) states that contingencies for detailed analysis of alternatives can be as high as 50 percent. For this FS, a contingency of 30 percent of the total direct construction costs was assumed. REMEDIAL ELEMENT QUANTITY ASSUMPTIONS The total cost of a remedial alternative will be a function of the unit costs for each remedial element (Table 1) and the quantity of each remedial element. Table 2 summarizes the assumptions used to develop the quantities of the remedial alternative elements. REFERENCES USEPA (U.S. Environmental Protection Agency), 2000. A Guide to Developing and Documenting Cost Estimates During the Feasibility Study. USEPA 540-R-00-002 OSWER 9355.0-75. July 2000. Remedial Alternative Cost Development Patrick Bayou Superfund Site C-2 March 2017 040284-01.08 Table C-1 Unit Cost Assumptions Unit Cost Unit Source and/or Comment 15% of Direct Construction Costs % Engineering judgment. Because Alternative 3 has a smaller project footprint, a higher rate is assumed. Environmental Protection and Erosion Control $50,000 Lump Sum Engineering judgment and similar work with larger scope. Construction Surveys, Site Preparation & Utility Clearance $50,000 Lump Sum Engineering judgment. Debris Removal $16,400 Acre Mix Activated Carbon (AC) into Sediments $4.20 Square Foot Engineering judgment and similar project costs. Reactive Core Mat (RCM) with AC $7.00 Square Foot Previous Contractor Quotes on similar project. Articulated Concrete Block Mat (ACBM) $9.10 Square Foot Contractor Site Visit Quote. $200,000 Lump Sum Engineering judgment and similar project costs. $360,000 to $410,000 Lump Sum Engineering judgment. $370,000 to $520,000 Lump Sum Engineering judgment. Element Mobilization and Demobilization Mobilization/ Demobilization and Setup Treatment and Capping Permitting Indirect Construction Costs Engineering Design Construction Administration/Observation Remedial Alternative Cost Development Patrick Bayou Superfund Site C-3 Previous Texas project experience; assumes 5 Tons of Debris collected per acre. Includes removal and disposal costs. March 2017 040284-01.08 Element Long-Term Natural Recovery Monitoring Long-Term Armored Cap Monitoring Unit Cost Net Present Value Net Present Value Unit Source and/or Comment Lump Sum Assumed $79,000 for Alternatives 2 and 4 and $106,000 for Alternative 3; 10 natural recovery monitoring events in Years 1, 2, 3, 4, 5, 10, 15, 20, 25 and 30. Assumed discount rate of 7% to determine net present value. Lump Sum Assumed $32,000 (Alt 3) and $56,000 (Alt 4) cap monitoring events in Year 1, 2, 5, 10, 15, and 30. Assumed discount rate of 7% to determine net present value. Cap Maintenance Net Present Value Lump Sum Assumes cap maintenance in years 1 and 2. Maintenance costs are assumed to be 10% of the capping cost for Alternative 3, and 5% of the capping cost for Alternative 4. Assumed discount rate of 7% to determine net present value. USEPA 5-Year Review Net Present Value Lump Sum Assumed $50,000 for USEPA costs every 5 years for 30 years. Assumed discount rate of 7% to determine net present value. Indirect Construction Costs Remedial Alternative Cost Development Patrick Bayou Superfund Site C-4 March 2017 040284-01.08 Table C-2 Quantity Assumptions Element Assumption Source and/or Comment Assumes small debris can be capped by ACBM material but large and sharp objects must be removed for successful capping Debris Removal The debris coverage is 20% of the capping or treatment area Mix with AC AC will be mixed into SMA-2 through SMA-9 remediation areas Area determined from GIS; 20% contingency added to GIS area RCM with AC RCM/AC will be installed in SMA-1 area as defined in the FS text Area determined from CAD; 20% contingency added to CAD area ACBM ACBM will be installed from channel bank to bank Area determined from CAD; 20% contingency added to CAD area Notes: AC – Activated Carbon ACBM – Articulated Concrete Block Mat CAD – Computer-Aided Design GIS – Geographic Information Systems RCM – Reactive Core Mat Remedial Alternative Cost Development Patrick Bayou Superfund Site C-5 March 2017 040284-01.08 APPENDIX D SUPPLEMENTAL SURFACE WATER SAMPLING DATA REPORT PATRICK BAYOU SUPERFUND SITE Prepared for Patrick Bayou Joint Defense Group U.S. Environmental Protection Agency Prepared by Anchor QEA, LLC 614 Magnolia Avenue Ocean Springs, Mississippi 39564 August 2014 SUPPLEMENTAL SURFACE WATER SAMPLING DATA REPORT PATRICK BAYOU SUPERFUND SITE REMEDIAL INVESTIGATION DEER PARK, TEXAS Prepared for Patrick Bayou Joint Defense Group Prepared by Anchor QEA, LLC 614 Magnolia Avenue Ocean Springs, Mississippi 39564 August 2014 TABLE OF CONTENTS 1 2 3 4 5 INTRODUCTION AND PURPOSE ..................................................................................... 1 1.1 Site Description ................................................................................................................1 1.2 Sampling Objectives .........................................................................................................1 SURFACE WATER COLLECTION SUMMARY ................................................................. 3 2.1 Sample Identification Scheme .........................................................................................3 2.2 Sampling Locations ..........................................................................................................4 2.3 Sample Collection Methods and Schedule ......................................................................4 2.4 Field Measurements .........................................................................................................6 2.5 Field Deviations from the SAP ........................................................................................6 LABORATORY METHODS................................................................................................. 8 3.1 Methods for Chemical Analysis ......................................................................................8 3.2 Laboratory Deviations from SAP ....................................................................................8 ANALYTICAL DATA VALIDATION AND DATA MANAGEMENT ................................ 9 4.1 Overall Data Quality ........................................................................................................9 4.2 Sample Transport and Holding Times...........................................................................10 4.3 Equipment Blank Results ...............................................................................................10 4.4 Field Duplicate Results ..................................................................................................10 4.5 Method Duplicate Results..............................................................................................10 4.6 Laboratory Quality Control ...........................................................................................11 RESULTS ............................................................................................................................ 12 5.1 Water Quality .................................................................................................................12 5.2 Velocity and Discharge ..................................................................................................12 5.3 Conventional Parameters...............................................................................................13 5.4 PCB Congeners ...............................................................................................................13 6 SUMMARY ........................................................................................................................ 15 7 REFERENCES .................................................................................................................... 16 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site i August 2014 040284-01.08 Table of Contents List of Tables Table 1 Surface Water Sample Locations and Analyses Table 2 Rainfall Events and Sample Collection Dates Table 3 Water Quality Measurements Table 4 Discharge Measurements Table 5 Summary of Analytical Results List of Figures Figure 1 Patrick Bayou Superfund Site Vicinity Map Figure 2 Surface Water Sampling Locations Figure 3 Spatial Distribution of Total PCB Concentration in Surface Water List of Appendices Appendix A Field Logbook Appendix B Data Sheets Appendix C Laboratory Reports Appendix D Data Validation Reports Appendix E Detailed Analytical Results Appendix F Discharge Calculations Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site ii August 2014 040284-01.08 LIST OF ACRONYMS AND ABBREVIATIONS °C degrees Celsius mS/cm millisiemen per centimeter AOC Administrative Order on Consent D field duplicate of the normal sample DOC dissolved organic carbon EB equipment blank EF East Fork ft/s foot per second ft3/s cubic foot per second FS Feasibility Study HSC Houston Ship Channel JDG Patrick Bayou Joint Defense Group LDC Laboratory Data Consultants, LLC MD method duplicate mg/L milligram per liter MID mid-depth of the water column mV millivolt N normal sample ng/L nanogram per liter ORP Oxidation Reduction Potential PB Patrick Bayou PCB polychlorinated biphenyl PSCR Preliminary Site Characterization Report PVC polyvinyl chloride QA quality assurance Report Supplemental Surface Water Sampling Data Report RI Remedial Investigation SAP Supplemental Surface Water Sampling and Analysis Plan SD standard deviation SDG sample delivery group SGS SGS North America Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site iii August 2014 040284-01.08 List of Acronyms and Abbreviations Site Patrick Bayou Superfund Site SM standard method SW surface water grab TOC total organic carbon TSS total suspended solids QA quality assurance USEPA U.S. Environmental Protection Agency Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site iv August 2014 040284-01.08 1 INTRODUCTION AND PURPOSE This Supplemental Surface Water Sampling Data Report (Report) describes the methods and results for the evaluation of polychlorinated biphenyls (PCBs) in surface water at the Patrick Bayou Superfund Site (Site) in Deer Park, Texas. This Report was prepared for the Patrick Bayou Joint Defense Group (JDG) in response to an Administrative Order on Consent (AOC) and Settlement Agreement with the U.S. Environmental Protection Agency (USEPA) dated January 31, 2006. The AOC concerns the performance of a Remedial Investigation/Feasibility Study (RI/FS) at the Site. The data collection activities described in this Report were conducted to support refinement of the Site chemical fate and transport model being developed for the FS. 1.1 Site Description Patrick Bayou is a tributary of the Houston Ship Channel (HSC) in Harris County, Texas (Figure 1). The Site originates south of State Highway 225 in the city of Deer Park, Texas, and flows approximately 2.5 miles in a northerly direction, discharging into the south side of the HSC approximately 2.3 miles upstream of its confluence with the San Jacinto River. The Site and its salient features are described in more detail in the Preliminary Site Characterization Report (PSCR; Anchor 2006) and the Remedial Investigation Report (RI Report; Anchor QEA 2013). 1.2 Sampling Objectives As part of the FS, a mathematical model for the Site is being developed to simulate the physical and chemical processes that are controlling the fate and transport of PCBs in Patrick Bayou and to develop a predictive tool that can be used to evaluate and support the selection of remedial alternatives. Based on the results of the modeling to date, it is hypothesized that sediments are the primary source of PCBs observed in surface water due to flux from surface sediment porewater. Consistent with the Adaptive Management Strategy in use at the Site, additional sampling was performed to address uncertainty in the model due to data gaps identified in the surface water dataset and to assess current conditions at previous sampling locations. Objectives included the following: 1. Sample surface water at target points in the upstream portion of the Site to determine the nature and extent of PCBs in surface water. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 1 August 2014 040284-01.08 Introduction and Purpose 2. Sample surface water in the midstream and downstream portions of the Site and outside of the Site boundary to provide a complete and synoptic characterization of PCBs in surface water at the time of sampling. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 2 August 2014 040284-01.08 2 SURFACE WATER COLLECTION SUMMARY Samples were collected and identified in accordance with the methods set forth in the USEPA-approved Supplemental Surface Water Sampling and Analysis Plan (SAP; Anchor QEA 2014). The field logbook documenting sample collection is provided in Appendix A. 2.1 Sample Identification Scheme As described in the SAP, sample identification for surface water samples followed the previously identified scheme for the Site (Anchor QEA 2009). Sample identification for surface water samples followed the format PB###-#XXXXX-YYMMDD-X: • PB###-#XXXXX-YYMMDD-X: Each location was identified by “PB” to depict the project location (Patrick Bayou) and the station identifier associated with the channel station in hundreds of feet (e.g., PB100 1). Samples collected in the East Fork were designated with “EF” and locations in the Houston Ship Channel as “HSC.” • PB###-#XXXXX-YYMMDD-X: Individual samples at each location were identified by the same alphanumeric identifier used to identify the stations (PB###), followed by a one-digit numeric substation identifier (#), a two-digit matrix identifier (i.e., SW = surface water grab), and a three-digit identifier to show the relative position in the water column (i.e., MID = mid depth of the water column) for that sample. • PB###-#XXXXX-YYMMDD-X: The collection date of each sample was included in the sample name to distinguish among previously collected samples from the same station. The following alphanumeric identifiers indicated the sample type: − N – normal sample − D – field duplicate of the normal sample − MD – method duplicate Because sampling has occurred over the course of several years and many stations have been revisited, “.#” has been appended to station identifiers with multiple sampling events. For example, Station HSC-14 was originally sampled in 2009 and was re-sampled during this event. Therefore, to distinguish between sampling events, “HSC14.1” was used as the station identifier for the 2014 sample. Additionally, “_X” has been appended to station identifiers that have the same lateral distance from the mouth of Patrick Bayou as previous stations but that were collected at a different location (e.g., “PB-070_B”). 1 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 3 August 2014 040284-01.08 Surface Water Collection Summary The equipment blank was labeled as “EB#.” The “#” is a sequential identifier. All relevant information for the blank (date and time of collection, station, associated surface water sample, and sample collector’s name) was recorded in the field notes. 2.2 Sampling Locations A total of 21 locations were included in this surface water sampling program. This number is based on reoccupying six surface water stations sampled in 2009 and 2011, 12 additional stations spaced at approximately 200-foot intervals beginning at the upstream Site boundary (PB-102) and extending downstream to PB-079 (i.e., the gunite channel), and three more stations located within the main channel of the Site (Figure 2 and Table 1). In accordance with the SAP, all locations were sampled during a slack, low-tide condition to assess baseline conditions and avoid potential dilution due to inflowing tidal water. In addition, in accordance with the SAP, other samples were taken as needed based on field observations during the sampling event. Two additional samples were taken near high tide at two locations to compare any potential differences during varying tidal conditions (PB070_B and PB-081_A). These comparisons are discussed in Section 5.4. 2.3 Sample Collection Methods and Schedule After an approximate 1-month delay in sampling due to weather, samples were collected between March 11 and March 19, 2014. Samples were collected using a peristaltic pump and dedicated tubing. Water was collected from the mid-depth of the water column, as determined in the field, at each station. Sampling occurred at approximately slack low tide (the time surrounding the nadir of the low tide), generally progressing from downstream to upstream to ensure collection of representative samples. Whenever safely possible, samples were collected from the shoreline as required by the SAP. Samples were collected from the shoreline at four locations: PB-020, PB-031.1, PB-047.3, and PB-056_C. Additionally, a shoreline sample was collected at Station PB-099 (as well as a sample collected from a boat) for a method duplicate. To collect samples from the shoreline, a polyvinyl chloride (PVC) tripod was used and tubing was affixed to one leg at the desired sample depth. The tripod was then carefully deployed from the shoreline to extend the Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 4 August 2014 040284-01.08 Surface Water Collection Summary tubing inlet away from bank. In general, samples collected using this method were taken within 5 to 7 feet of the shoreline and in relatively shallow water (i.e., 1 to 2.5 feet deep) compared to samples taken by boat from adjacent sampling locations. For samples collected from a boat, the station was approached from downstream and care was taken to avoid disturbing sediments while approaching. Samples were taken as close to the apparent thalweg of the channel as possible. Once on station, the water depth was measured using a lead line and then a 10-minute delay was observed prior to sampling to allow any disturbed sediment to settle. Samples were then collected from the upstream side of the boat. Sample collection dates occurred in accordance with the SAP, which specified that sampling was not to occur within 48 hours after a heavy rainfall event 2 and sampling would not be performed during measureable rainfall events. Sampling began on March 11, 2014. The next day, March 12, high winds and extreme low tides began affecting sample representativeness 3; therefore, samples taken on that day were discarded, and sampling was halted until weather conditions were appropriate. On the following days, March 13 and 14, the wind ceased, and samples were again collected. On March 15, intermittent light drizzle was observed at the Site during sampling, but periodic checks of nearby real-time rain gauges 4 did not indicate measurable amounts of rainfall. However, by the afternoon, measureable amounts of rainfall were recorded for that day and continuous light rainfall was observed at the Site. Therefore, sampling was suspended and samples collected that day were discarded, consistent with the SAP, which states sampling will not occur during or between measurable rainfall events. On March 16 and 17, fieldwork did not occur due to continued rainy conditions. Sampling began again on March 18 and was completed on March 19. Table 2 shows these rain events and shows the dates on which sample collection occurred. Unfiltered water samples were collected at each station and submitted to SGS North America for analysis of PCB congeners, total organic carbon (TOC), and total suspended solids (TSS). Samples from four stations (PB-101.1, PB-081_A, PB-056_C, and PB-006.2), were also subsequently vacuum filtered by the laboratory through a 0.45 µm glass fiber filter for Defined as greater than 1 inch per 24-hour period for the purposes of this work. Significant increases in water turbidity due to low tides and wind driven wave action were observed. 4 Harris County Flood Warning Service gages 1420, 240, and 270. 2 3 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 5 August 2014 040284-01.08 Surface Water Collection Summary analyses of PCB congeners and dissolved organic carbon (DOC) to evaluate total versus dissolved concentrations of PCBs in the water column. 2.4 Field Measurements Immediately after a surface water sample was collected, field parameters were measured at each sample location (at approximately the same sample depth from which the surface water sample was collected) using a water column-deployed multi-parameter water quality instrument. Measurements of pH, temperature, oxidation reduction potential (ORP or Eh), conductivity, and dissolved oxygen were recorded on water quality sampling forms (Appendix B). In addition, at stations between PB-102 and PB-079 (i.e., gunite channel), velocity measurements were taken at every third station to permit calculation of stream discharge at the time of sampling (Stations PB-081_A, PB-087, PB-095, PB-097_A, and PB-099). Velocity measurements were collected consistent with the SAP, as discussed in Section 2.5. 2.5 Field Deviations from the SAP There were three minor deviations from the SAP. 1. The SAP states that ORP would be recorded at each sampling station; however, due to unforeseen instrument issues, ORP was not able to be collected at certain stations, as shown in Table 3. However, this equipment malfunction does not impact the intended use of the data, which is to assess PCB concentrations in surface water. 2. The SAP prescribes that “method” duplicates would be collected at two locations, wherein the sample would be taken from the shoreline and resampled from a boat and the PCB analytical results subsequently compared to check for method bias. However, based on weather and channel conditions, it was only possible to collect one method duplicate (Station PB-099). This does not impact the intended use of the data because the observed discrepancy between shoreline and boat sampling results at station PB-099 was not significant. 3. The SAP states that “the highly variable channel geometry in downstream areas makes accurate velocity measurements and discharge calculations difficult.” This statement proved true in the field, as velocity measurements were collected in Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 6 August 2014 040284-01.08 Surface Water Collection Summary accordance with the procedures outlined in the SAP; however, there are concerns regarding the validity of these data due to observed flow reversals that occurred during velocity data collection. These reversals are hypothesized to be a result of large ships passing the outlet of Patrick Bayou and the wedge of water thus pushed upstream in the waterway. Often, the field crew could not see these vessels from their upstream vantage point within the gunite channel and could not determine the timing or influence of these events directly. Therefore, velocity and discharge data collected during this sampling program might have been influenced by these conditions. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 7 August 2014 040284-01.08 3 LABORATORY METHODS This section briefly describes the analytical methods used to generate the chemistry data for the surface water samples in this Report. A detailed description of the analytical methods can be found in the SAP (Anchor QEA 2014). This section also summarizes any deviations by the laboratory from the SAP. 3.1 Methods for Chemical Analysis Table 1 lists the surface water samples that were analyzed for each of the chemical methods listed below. Analyses were performed by SGS North America (SGS) in Wilmington, North Carolina. SGS is NELAP-accredited by the Texas Commission on Environmental Quality (certificate number: T104704260-14-6). Twelve reports were received from the laboratory and were validated. Laboratory reports are provided in Appendix C. Twenty-three surface water samples, two field duplicates, one method duplicate and one equipment blank were sent to the laboratory for total PCB congeners, total organic carbon (TOC) and total suspended solids (TSS) analyses. Four samples and one field duplicate were also analyzed for dissolved PCB congeners and DOC. The equipment blank was analyzed for total and dissolved PCB congeners. 3.2 Laboratory Deviations from SAP The laboratory used the required analytical methods and all reporting limits were met with the following exceptions: • TSS: Standard method (SM) 2540D was used instead of SM 2540C. These two methods are comparable and are expected to produce similar results so data quality is not expected to be impacted. Additionally, the reporting limit for one field duplicate sample (PB083-1SWMID-140318-D) was reported as not detected at 25 milligrams per liter (mg/L), which is a higher reporting limit than what is listed in the SAP (5 mg/L). The parent sample associated with this field duplicate had an estimated TSS concentration of 5 mg/L. • DOC: One sample and its associated field duplicate were filtered and preserved 5 days after receipt at the lab. Samples for DOC should be filtered and preserved within 48 hours of sample collection. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 8 August 2014 040284-01.08 4 ANALYTICAL DATA VALIDATION AND DATA MANAGEMENT Third party data validation was performed on each data set of chemical analyses. Data validation verified the accuracy and precision of chemical determinations performed during this investigation. This section presents the results of the data validation conducted by Laboratory Data Consultants (LDC). The following sections summarize the overall data quality and do not necessarily address each individual sample result affected by data qualification. Detailed information regarding sample result qualifications is available in the data validation reports (Appendix D). 4.1 Overall Data Quality A review of the validation report indicates that the overall data quality of the chemistry data generated was considered acceptable. Total and dissolved PCB congeners were reported under six sample delivery groups (SDGs): A6492, A6504, A6506, A6517, A6521, and A6528. TOC, DOC, and TSS were reported under SDGs 31400373, 31400389, 31400395, 31400411, 31400420, and 31400427. Detailed data quality objectives and quality assurance (QA) procedures are provided in the SAP (Anchor QEA 2014). Laboratory data packages were validated by LDC under USEPA National Functional Guidelines (USEPA 1986, 2010, 2011) and using the data quality objectives described in the SAP. The validation reports are in Appendix D. Any data qualifiers applied to the data during the final validation procedures have been incorporated into the final database for this project. Data qualifiers assigned as a result of the data validation and their definitions are shown on the analytical results table (Appendix E). All data were considered useable as reported or as qualified, and no data were rejected. The data may have been qualified as estimated for a particular analysis based on method or technical criterion as stated in the functional guidelines (USEPA 1986, 2010, 2011). Data qualified with a “J” indicates that the associated numerical value is the approximate concentration of the analyte. Data qualified with a “UJ” indicates the approximate reporting limit below which the analyte was not detected. In some cases, reporting limits were raised to account for method blank contamination or matrix interference. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 9 August 2014 040284-01.08 Analytical Data Validation and Data Management 4.2 Sample Transport and Holding Times All samples were received at the laboratories in good condition and within the recommended temperature range. All analyses were performed within holding times, with the exception of one sample and its associated field duplicate for DOC (samples PB006.2-1SWMID-140311-N and PB006.2-1SWMID-140311-D), as discussed in Section 3.2. Therefore, the detected results for DOC for these two samples were qualified as estimated. 4.3 Equipment Blank Results One equipment blank was collected and analyzed for total and dissolved PCBs. Several PCB congeners were detected in the field blank. Most detections were insignificant compared to sample concentrations, with the exceptions of PCB-051 and PCB-068. Detections of these congeners in the samples may be due to equipment blank contamination, and associated sample results may be biased high for these congeners. However, PCB-051 and PCB-068 did not contribute more than 4 percent to the total PCB concentration for any samples, indicating that any high bias due to their presence in the equipment blank is not significant. No qualifiers were applied to associated sample results due to equipment blank detections. 4.4 Field Duplicate Results Two field duplicates were collected with the surface water samples. Duplicates were analyzed for the same parameters as the parent samples. No results were qualified based on field duplicate results. Field duplicate results are discussed in detail in the data validation reports (Appendix D). 4.5 Method Duplicate Results One method duplicate was collected with the surface water samples. The method duplicate was analyzed for the same parameters as the parent sample. When a target analyte was detected in both the parent sample and the method duplicate, the relative percent difference was below 50 percent, with the exception of PCB-003, which had a relative percent difference of 54 percent. Both results for PCB-003 were below the reporting limit. No results were qualified based on the method duplicate results. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 10 August 2014 040284-01.08 Analytical Data Validation and Data Management 4.6 Laboratory Quality Control The validation report indicates the majority of the data results did not require qualification. Some data were qualified as estimated based on data quality objective or method exceedances. No data were rejected. Some PCB congener results were qualified as non-detects due to detections in the associated method blanks. Some PCB congener results were qualified as estimated because the laboratory flagged them as Estimated Maximum Potential Concentration due to ion abundance ratios that did meet method criteria. Two DOC results were qualified due to a hold time exceedance. All data are usable as reported or as qualified. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 11 August 2014 040284-01.08 5 RESULTS This section reports sampling results, including water quality measurements, discharge measurements, and analytical results. 5.1 Water Quality Water quality parameters were measured at Patrick Bayou stations as well as one station in the East Fork and one in the HSC, as shown in Table 3. In Patrick Bayou, water parameter results were as follows: • Water depth ranged from 1 foot at Station PB-020 to 5.2 feet at Station PB-079. • pH ranged from 8.2 at Station PB-056_C to 7.4 at Station PB-119_B (mean = 7.7, standard deviation [SD] = 0.2). • Temperature ranged from 17.2 degrees Celsius (°C) at Station PB-006.2 to 22.7 °C at Station PB-091 (mean = 20.4 °C, SD = 1.7 °C ). • ORP ranged from 200.1 millivolts (mV) at Station PB-083 to 26.1 mV at Station PB-087 (mean = 120.5 mV, SD = 55 mV). • Conductivity was within the range expected for standard base flow conditions and ranged from 0.738 millisiemens per centimeter (mS/cm) at Station PB-119_B to 50.1 mS/cm at Station PB-006.2 (mean = 10.7 mS/cm, SD = 9.6 mS/cm). • Dissolved oxygen ranged from 5.9 milligrams per liter (mg/L) at Station PB-081_A to 13.9 mg/L at Station PB-056_C (mean = 9.5 mg/L, SD = 1.9 mg/L). Dissolved oxygen was recorded as percent at three stations: HSC-14.1, PB-070_B, and PB-079. The results for these stations ranged from 83.1 percent (Station HSC-14.1) to 110.3 percent (Station PB-070_B). 5.2 Velocity and Discharge Velocity measurements at sampling stations varied by station and ranged from 0 feet per second (ft/s) to 0.69 ft/s. The resulting calculated discharge values ranged from 3.9 cubic feet per second (ft3/s) to 51 ft3/s, and all but one discharge value was less than 15 ft3/s (Table 4). The most rapid velocities and discharge occurred at Station PB-087 on March 14, 2014. Appendix F provides velocity measurements and the resulting calculations for discharge for each of the sampled stations. As noted in Section 2.5, there is uncertainty in the velocity Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 12 August 2014 040284-01.08 Results measurements and discharge calculations due to flow reversal possibly caused by ship traffic in the HSC. 5.3 Conventional Parameters TSS and TOC were measured at all stations and DOC was measured at a subset of stations. TSS ranged from 5.00 mg/L at Stations PB-083 and PB-087 to 34.0 mg/L at Station PB-056_C (mean 13.4 mg/L). TOC ranged from 5.47 mg/L at Station PB-006.2 to 16.2 mg/L at Station PB-081_A (mean 10.3 mg/L). For DOC, the stations with the lowest and highest concentrations remained the same as TOC. A DOC concentration of 26.3 mg/L was observed at Station PB-081_A and a concentration of 9.40 mg/L was observed at Station PB-006.2 (mean 14.9 mg/L). A summary of these results can be found in Table 5, and detailed results can be found in Appendix E. 5.4 PCB Congeners PCB congeners were detected in all unfiltered samples. Total PCB concentrations in unfiltered samples ranged from 0.566 nanograms per liter (ng/L) at Station PB-119_B to 72.1 ng/L at Station PB-070_B (mean 19.9 ng/L). Dissolved PCB congeners were also measured and detected at all four of the stations sampled in Patrick Bayou. The total dissolved PCB concentrations in filtered samples were always lower than the total concentrations and ranged from 1.27 ng/L at Station PB-101.1 to 16.3 ng/L at Station PB056_C (mean 9.85 ng/L). Although the reasons for differences between unfiltered and filtered results are not clear, higher TSS is associated with greater differences between unfiltered and filtered samples and may be a factor contributing to the observed differences. Figure 3 presents the PCB concentration data as a function of distance along the Site. A summary of these results can be found in Table 5, and detailed results can be found in Appendix E. To determine the effects of sampling from the boat versus the shoreline, a method duplicate sample was taken at Station PB-099. The method duplicate was sampled first from the shoreline, and a total PCB concentration of 3.93 ng/L was detected. The station was then resampled from the boat and had a total PCB concentration of 3.69 ng/L. There was only a 6.15 percent difference in results between the two sampling methods, which suggests that Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 13 August 2014 040284-01.08 Results the method of collection (i.e., boat vs. shoreline) at a specific location did not influence the sample results. As noted in Section 2.2, two samples were collected during high tide to assess the potential for tidal influence on PCB concentrations and distribution. At Station PB-070_B, the relative percent difference (RPD) in total PCB concentration between the high tide sample (72.1 ng/L) and low tide sample (67.7 ng/L) is 6.3 percent. The RPD in total PCB concentration between the high tide sample at Station PB-081_A (14.1 ng/L) and the low tide sample (23.2 ng/L) is 48.9 percent. For comparison, the RPD in total PCB concentrations between the normal and field duplicate samples collected at PB006.2 is 53.7 percent. These results suggest that the concentration of PCBs may not have been significantly affected by tidal stage during this investigation. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 14 August 2014 040284-01.08 6 SUMMARY In summary, surface water samples were successfully collected and analyzed to assist in characterization of PCBs at the Site and continued development of the Site fate and transport model. The samples were collected to meet the objectives outlined in Section 1.2 and was performed consistent with the SAP with minor deviations, which did not affect the overall usability or representativeness of the data. The results from this investigation will be used to support refinement of the Site chemical fate and transport model being developed for the FS. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 15 August 2014 040284-01.08 7 REFERENCES Anchor (Anchor Environmental, LLC), 2006. Preliminary Site Characterization Report. Patrick Bayou Superfund Site. Deer Park, Texas. Prepared for USEPA and Patrick Bayou Joint Defense Group. Anchor QEA (Anchor QEA, LLC), 2009. Draft Patrick Bayou Sediment Transport Modeling Report. Prepared for U.S. Environmental Protection Agency and the Patrick Bayou Joint Defense Group. Prepared by Anchor QEA, LLC. April 2009. Anchor QEA, 2013. Remedial Investigation Report. Prepared for U.S. Environmental Protection Agency and the Patrick Bayou Joint Defense Group. Prepared by Anchor QEA, LLC. September 2013. Anchor QEA, 2014. Supplemental Surface Water Sampling and Analysis Plan, Patrick Bayou Superfund Site, Remedial Investigation, Deer Park, Texas. Prepared for Patrick Bayou Joint Defense Group. January 2014. USEPA (U.S. Environmental Protection Agency), 1986. Test methods for Evaluating Solid Waste: Physical/Chemical Methods. U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response. EPA 530/SW-846. USEPA, 2010. USEPA Contract Laboratory National Functional Guidelines for Inorganic Superfund Data Review. U.S. Environmental Protection Agency, Office of Emergency and Remedial Response. US EPA 540-R-10-011. January. USEPA, 2011. USEPA Contract Laboratory Program National Functional Guidelines for Chlorinated Dibenzo-p-Dioxins and Chlorinated Dibenzofurans Data Review. U.S. Environmental Protection Agency, Office of Emergency and Remedial Response. USEPA 540-R-11-016. September. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 16 August 2014 040284-01.08 Northing 13831060.06 13837021.25 13836299.79 13836299.79 13835636.41 13834597.35 13832857.26 13832189.45 13830874.06 13830874.06 13830192.24 13829960.4 13829960.4 13829765.67 13829765.67 13829591.43 13829475.11 13829302.2 13829124.52 13828915.14 13828738.31 13828556.69 13828426.23 13828443.85 13828263.24 13826349.57 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Total Suspended Solids Easting 3201916.502 3201174.507 3202147.786 3202147.786 3201304.601 3201398.814 3201688.048 3201506.287 3201105.667 3201105.667 3200739.589 3200753.748 3200753.748 3200739.892 3200739.892 3200716.688 3200888.515 3200952.521 3200940.118 3200967.7 3201056.962 3201111.781 3201138.74 3201139.939 3201247.135 3201529.198 Dissolved Organic Carbon Sample ID EF006.1-1SWMID-140313-N HSC-14.1-1SWMID-140311-N PB006.2-1SWMID-140311-N PB006.2-1SWMID-140311-D PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-2SWMID-140314-N PB070_B-1SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-N PB083-1SWMID-140318-D PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-MD PB099-1SWMID-140319-N PB-101.1-1SWMID-140319-N PB-119_B-1SWMID-140313-N Total Organic Carbon Station ID EF-006.1 HSC-14.1 PB-006.2 PB-006.2 b PB-020 PB-031.1b PB-047.3b b PB-056_C PB-070_B PB-070_B PB-079 PB-081_A PB-081_A PB-083 PB-083 PB-085 PB-087 PB-089 PB-091 PB-093_A PB-095 PB-097_A PB-099 PB-099 PB-101.1 PB-119_B PCB Congener (Dissolved) Station Coordinatesa PCB Congener (Total) Table 1 Surface Water Sample Locations and Analyses X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Notes: a - Station Coordinates are State Plane coordinates based on North American Datum (NAD) 83 for Texas, South Central (feet). b - Sample collected from shoreline PCB = polychlorinated biphenyl Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Page 1 of 5 August 2014 040284-01.08 Table 2 Rainfall Events and Sample Collection Dates Date 3/11/2014 3/12/2014 3/13/2014 3/14/2014 3/15/2014 3/16/2014 3/17/2014 3/18/2014 3/19/2014 Rainfall (inches)a 0.04 0.00 0.00 0.00 0.00 0.64 0.24 0.00 0.00 Sample Collection Occurred X X X X X Note: a - Data from Harris County Flood Control District rain gauge 1420 (N100 Carpenters Bayou @ I-10). Available from: http://www.harriscountyfws.org/GageDetail/Index/1420?R=1 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Page 2 of 5 August 2014 040284-01.08 Table 3 Water Quality Measurements Station ID EF-006.1 HSC-14.1 PB-006.2 PB-020d PB-031.1d PB-047.3d PB-056_Cd PB-070_B PB-070_B PB-079 PB-081_A PB-081_A PB-083 PB-083 PB-085 PB-087 PB-089 PB-091 PB-093_A PB-095 PB-097_A PB-099 PB-101.1 PB-119_B Sample ID EF006.1-1SWMID-140313-N HSC-14.1-1SWMID-140311-N PB006.2-1SWMID-140311-N PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-2SWMID-140314-N PB070_B-1SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-N PB083-1SWMID-140318-D PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB-101.1-1SWMID-140319-N PB-119_B-1SWMID-140313-N Water Depth Sample Depth (ft)a (ft) 2 1 44.6 22 2.8 1.4 1 0.8 2 1 2 1 2.5 1.8 3.4 1.7 2.9 1.5 5.2 2.6 4 2 4.1 2 4.5 2.2 4.5 2.2 3.7 1.8 4.4 2.2 2 1 3.5 1.7 2.1 1 1.7 0.9 4 2 1.3 0.9 3.5 1.7 1.5 1 pH 7.93 7.5 7.59 8.03 7.71 7.74 8.2 7.6 7.54 7.45 7.49 7.43 7.73 7.73 7.58 7.85 7.63 7.91 7.89 7.86 7.67 7.74 7.77 7.39 Temperature (˚C) 20.4 15 17.23 19.22 18.55 19.79 20.37 17.28 19.93 20.8 21.42 20.51 19.95 19.95 21.88 21.09 21.87 22.71 22.67 22.01 21.06 22.35 22.2 20.29 ORP (mV)b not measured 160 151.8 not measured not measured 169 143.3 167.3 152 135.1 112.4 111.5 200.1 200.1 62.2 26.1 86.7 123 164.9 139.6 37.9 30 45.5 not measured Conductivity (mS/cm) 0.939 17.04 50.1 15.86 16.24 17.77 13.19 13.19 10.56 9.887 9.218 8.664 8.39 8.39 7.982 7.88 6.419 6.465 7.234 6.009 4.385 8.23 7.037 0.738 Dissolved Oxygen (mg/L) 10.35 83.1 (%)c 9.14 11.58 9.71 11.72 13.91 6.96 110.3 (%)c 101.3 (%)c 9.12 5.88 9.68 9.68 10.44 11.4 11.15 9.75 9.36 8.8 9.96 7.38 6.79 7 Notes: ft - foot ˚C - degrees Celsius mV - millivolt µS/cm - millisiemen per centimeter mg/L - milligram per liter a - At most stations, depth was measured using lead line and measuring tape from a boat. At stations PB031.1, PB047.3, PB056_C, PB099, and PB-101.1, depth was estimated using plastic pole due to inaccessibility for boats. b - ORP was not measured at some stations due to instrument issue. c - Dissolved oxygen recorded as percent, not mg/L. d - Samples were collected from shoreline Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Page 3 of 5 August 2014 040284-01.08 Table 4 Discharge Measurements Station ID PB081_A PB087 PB087 PB095 PB097_A PB097_A PB099 Date 3/14/2014 3/14/2014 3/18/2014 3/18/2014 3/15/2014 3/19/2014 3/19/2014 Time 16:00 15:40 16:15 18:00 17:56 16:00 18:18 Discharge (ft3/s)a 14 51 8.4 10 14 11 3.9 Notes: a - It is possible that discharge data collected during this sampling program may have been influenced by wedges of water pushed upstream in the waterway from large ships passing the outlet of Patrick Bayou. ft3/s - cubic foot per second Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Page 4 of 5 August 2014 040284-01.08 Table 5 Summary of Analytical Results Number of Number of Number of NonMinimum Maximum Average a Detects Detects Detected Result Detected Result Detected Result Results Conventional Parameters (mg/L) Total suspended solids Dissolved organic carbon Total organic carbon PCB Congeners (ng/L) Total PCB Congenerb (U = 1/2) PCB Congeners, Dissolved (ng/L) Total PCB Congenerb (U = 1/2) 23 4 23 23 4 23 0 0 0 5.00 9.40 5.47 34.0 26.3 16.2 13.4 14.9 10.3 23 23 0 0.566 72.1 19.9 4 4 0 1.27 16.3 9.85 Notes: mg/L - milligrams per liter ng/L - nanograms per liter PCB - polychlorinated biphenyls a - Field duplicates are excluded from statistics b - Total PCB congeners is the sum of all PCB congeners calculated as the sum of all detected results and half of the estimated detection limit of undetected results (U=1/2) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Page 5 of 5 August 2014 040284-01.08 HGJB Lake Houston TEXAS MEXICO HOUSTON Patrick Bayou _ ^ Trinity Bay DEER PARK G:\Jobs\040284-Patrick_Bayou\Maps\2014_04\Vicinity Map.mxd sballard 4/30/2014 10:07:36 AM GULF OF MEXICO Upper Galveston Bay East Bay Lower Galveston Bay West Bay GULF OF MEXICO GALVESTON 0 Miles 10 [ Figure 1 Patrick Bayou Superfund Site Vicinity Map Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas 45 40 35 30 25 10 PB006.2 ( ! ( ! 50 55 65 PB070_B 70 PB087 PB081_A 20 75 PB079 90 PB091 PB085 PB083 85 80 PB099 120 110 100 95 PB097_A PB093_A V U 225 Surface Water Sample Site Boundary as Defined in AOC NOTES: Station numbers from Patrick Bayou PSCR indicate length along channel in hundreds of feet. Stations PB020, PB031.1, PB047.3 and PB056_C were collected from the shoreline. Aerial imagery: Microsoft Bing Maps, copyright 2010 0 Feet 500 1,000 [ ( ! PB089 ! ( ( ! ( ! 25 PB095 ! ( ( ! ( ! ( ! 45 ! ( ( ! ( ! 40 ( ! 35 PB-101.1 105 ( ! ( ! 115 60 ( ! ( ! G:\Jobs\040284-Patrick_Bayou\Maps\2014_04\2014_SW_samples.mxd sballard 7/28/2014 9:33:57 AM 30 15 PB-119_B PB056_C PB031.1 PB020 HSC-14.1 5 PB047.3 ( ! 10 ( ! EF006.1 ( ! 5 ( ! HANNEL N SHI P C H O U S TO 15 Eas t Fo rk 20 Figure 2 Surface Water Sampling Locations Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Total PCB Concentration (ng/L) 50 Houston Ship Channel East Fork End Concrete-lined Channel Start Concrete-lined Channel 75 25 0 100 80 60 Total Concentration Dissolved Concentration 40 Station ID Normal Sample Method Duplicate Sample 20 0 -20 Low-Tide High-Tide Figure 3 Spatial Distribution of Total PCB Concentration in Surface Water Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas HS - \\HOUL-HSAMAHA\D_Drive\Patrick_Bayou\Documents\2014_Supplemental_Water_Sampling_Data_Report\Figures\PB_WC_data_spatial_2014_20140619.pro Thu Jun 19 16:25:36 2014 ALL-WEATHER FIELD No. 351 [abut/?34100 00102 6% 08 3/14/51 73? ff - _le?xm1 f?p/QL _Z/jdl (Err/c/ Lam. 1 K14 . Zr; . [c.4572 cg!? "uni; ?nk/32742.? 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I 2524522 5:292:51? 5A2- 92/2222 2252/ 042: Afr/05?] pr NM 7?72 mmsb/?L?Wtb STREAM FLOW (DISCHARGE) MEASUREMENT FORM Stream 2 int/? Date Station Description @5704" . gcud Time Begin 6 Time Ended "0 1 Meter Type 0 6/ Observers 1771 Stream Width1 23 Section Width Z1 3 Observations Section Observational Velocity A Fiow(Q) Midpoint ,oepar? Depth2 At Point Average (mi) pm)W-m-cm (ft/s) (ft/S) (ms/S) (0 . 05 i as? 4525??f?owrwsa(/110/ 7- cf 57 i (.7, i094 (9 7a a . I a, (9.. i MW 1'51 52? Ls? Total Discharge . 3 1Make minimum 7of 10 measurements when the total width is 5.0 ft, 20 measurements preferred. eas re at 60% of depth from surface where 2.5 ft. deep. Measure at 20% and 80% of depth i? waters 2.5 ft. deep15?5?? Stream hUi5/?Ao/z? (Lice-ts; f/ow cr/L/ri-p Pr if.) f? '5 AM (6450/? vat?J? STREAM FLOW (DISCHARGE) MEASUREMENT FORM Station Description 956 Time Begin 0Z9 Time Ended 9' Meter Type Sway/44" Date e/t/ Stream Width?Z?L 5" Section Width 2 Observers L776 . [4/5 Observations Section Section Observational Velocity Flow (Q) Midpoint Depth Depth2 At Point Average A ft-m-cm (ft/s) (ft/s) (ma/s) (ft364.7: 2H ?1 Li" L?I'fJirblf ?ow/A ?(Mi <33 i. C) 7.25 '2 t} . no ago-m4; Qua) 3 0% . [5 in @5339? Frai- mum: to .1 2? 0. 12125 3 :2 - 7' . 3 ilr (am 79,, . .4 i . 4) 62.56 ?7.75 3 . (/abumglrSka/4w fo Heep/5M1? Total Discharge 1Make a minimum of 10 measurements when the total width is 5.0 ft, 20 measurements preferred. 2Measure at 60% of depth from surface where 2.5 ft. deep. Measure at 20% and 80% of depth in waters 2.5 ft. deep. Stream STREAM FLOW (DISCHARGE) MEASUREMENT FORM (2 7471'. Station Description 7' Time Begin 6 Observers ,3 Time Ended Meter Type 51%, Date Stream Section Width 3: 35- f4, 34? Observations 35 51/ 32; (5?12; Section Section Observational Velocity Flow (Q) Midpoint Depth Depthz At Point Average ng A ?'m'cm (ft/S) (ft/S) (ms/3) . 9 3, a? ?533,615Mid? .5 . 5 ?221 Marx (I) {34% ??jm 9 5 3.3-3 . . 3 ?572, (5,515.23/35 5, 7- 5 .. C) 6?Total Discharge . 1Make a minimum of 10 measurements when the total width is 5.0 it, 20 measurements preferred. 2Measure at 60% of depth from surface where 2.5 ft. deep. Measure at 20% and 80% of depth in waters 2.5 ft. deep. 5513 6 704/626 #7 STREAM FLOW (DISCHARGE) MEASUREMENT FORM - I Stream 2 7?2? 15/6 ?f-sof/JL/ Date 3 ?Ll 1 Station Description P137) 952C, Time Begin fags/?g) Time Ended /5 7 0 Meter Type glad fr/t?? Observers (TIC, HS Stream Width1z?' 25" Section Width 2? Observations Section Section Observational Flow (Q) Midpoint Depth Depthz At Point Average A ft-m-cm (W5) (W3) (W5) (W3) (ma/s) (ft3(2.054(301.0 5230* C5) - 2 25", 5215120.0 6-3? 1?153.Total Discharge 1Make a minimum of 10 measurements when the total width is 5.0 ft, 20 measurements preferred. 2Measure at 60?41 of depth from surface where 2.5 ft. deep. Measure at 20% and 80% of depth in waters 2.5 ft. deep. l? [1/6/65 451/7557}. 77 y- ?5 (y 05/335 ?1?15?6?6? I It?" 16 ?/aki 01L H) Md and 75/0?) obgvVaLWa 6 ?fe dip/4x alu?. AM (ons?m'n?fs Stream STREAM FLOW (DISCHARGE) MEASUREMENT FORM [Bridal Hyena/m2 (?malt 911M Date 3 Station Description ?151; /5/omn9?rtm Salk? in {um-d? (?aws/JP) Time Begin /g?00 Time Ended Meter Type awn! Observers 31? 5 Stream Width1 3 7 Section Width 0 70+ Observations 32 9?76 97. {1 95?2?3 . 22? Section Sec ion Ob erva ional Velocity Flow (Q) Midpoint Depth SDepth2 At Point Average mac) A 3 ft?m-cm (ft/S) (ft/Q?6735% 3.5? . . - 22 Li.) at; (cf/i Z.<40 18? 07? 00?; ire-r 0.95 2 <9 . 3 37y,3.8 C) :52A/of? Vlake a minimum of 10 measurements when the total width is 5.0 ft, 20 measurements preferred. Measure at 60% of depth from surface where 2.5 ft. deep. Measure at 20% and 80% of depth in waters 2.5 ft. deep. A/ov?c?a r) cal Total Discharge W'f? CL urgi'b/z c/CJ/i 16mm 1?0 Ci P?'l?th?v{ t?n H56 505,4 3% /l 7/ STREAM FLOW (DISCHARGE) MEASUREMENT FORM 3/ /5 r" . . . ?pk; I Datew??l/ Stream Station Description #753674 7. Time Begin Time Ended Meter Type 5000 Observers 55 1 3L Stream Width122?: Section Width 5/ Observations Section Section Observational VEIOCHV Area Flow (Q) Midpoint MDepth ?Eepthz At Point Average (m2) (C(m ?(cm J?'m'cm (@119 (ft/s) (?13/5515;; Cr) :7 .7 . spa. .. #1 if] 0 g2. 25ISL-J ti?? o, a 2.. 5 I [7?0 i - :11 {2,1 .. jiy??-522gb Total Discharge . Vlake a minimum of 10 measurements when the total width is 5.0 ft. 20 measurements preferred. Measure at 60% of depth from surface where 2. 5 ft deep Measure at 20% and 80% of depth in waters 2. 5 it deep it\fcfl/?f?i/ . I .2. Fr. t. (C- Fij? I ~39; I T- 2 6 52/717616? mz 72%st [or as 362? #2 ?331,625 (5 c/ an? 5:5 STREAM FLOW (DISCHARGE) MEASUREMENT FORM 34/5 Station Description 9505 9? Time Begin /5 0/0? Time Ended Meter Type Observers 3 572,571.} 3&5; Stream Width1 33- }:32 Section Width 3. Observations Section Section Observational Velocity Flow (Q) . - Area WXD Midpoint ?Depth Depth2 At - A 2 (ft/:iang/es) (m (ma/s) (fts2.0 (2225" . {335" Tl. x51424. 02,5? 3 0 '2 ?75? 2 9. 2,2511 3 3 2. 0 5 7 30' 73"? . Total Discharge Vlake a minimum of 10 measurements when the total width is 5.0 ft., 20 measurements preferred. Measure at 60% of depth from surface where 2.5 ft. deep. Measure at 20% and 80% of depth in waters 2.5 ft. deep. Water Quality Sample Form ISIEEHOR Project Name: Patrick Bayou Project Number: 040284-01 Station ID: [17/35) Sample ID: P13 gag/g; - H) {1/03/53 samp'ing 315.513 HS Weather: (3le . 6 /0 7'5" /z a/s Subcontractor(s): ?44 Date: 3 Time: ?3 7 Tide: Aim) Ac/i Station Coordinates: 7 C: 1 Sampling Method: :7 74?. Jana, 3 ?(3)0qu ZQSZ7Q- (5?0 Parameter Units Result Water Depth Sample Depth 0 pH Sgt} 9 Temperature 22.. cm /6 LA 7 Conductivity 7 2 3 0/ Dissolved Oxygen ?5/5 a 3& Dissolved Sample Collected: YES Velocity MeasurementsTaken: YES Comments: /0mmdi[5A Aa/g/ /nr 15f Urinal/DMD Minx/i1,? ?it/f {Amp/15$ g/chf bna? Water Quality Sample Form Project Name: Patrick Bayou Station y?g?e ,0 Sampling Crew: Subcontractor(s); Date: Time: Station Coordinates: ANCHOR QEA Project Number: 040284-01 5'3um 9136?? 376 374 HS: 135 Weather: (1/?ch . 5 cur/r Lee/(5" . 3 A9 Tide: Aux/x ma 6 32393/0. ?3 Sampling Method: I. . 0 2025300? 31 Parameter Units Result Water Depth Sample Depth 6} pH 50 37: 66 Temperature 27-. ORP l/ 5. 6 Conductivity M5444 ?5j Dissolved Oxygen M5 {if 230 Dissolved Sample Collected: YES. 6) Velocity MeasurementsTaken: 9 NO Comments. /0 min/lit? I?f Mint.) lift In/ 791/ {4144?} Water Quality Sample Form QEEHOR Project Name: Patrick Bayou Project Number: 040284-01 Station ID: #139053 SamplelD: p305? #7513152 Pgdg? /903/5 Sampling Crew: g5 Weather: 2.552: 3: (Q: Subcontractor(s): [9615/ Date: 3/4; Time: 2523 Tide: Station Coordinates: 3273397625. Sampling Method: CH Parameter Units Result Water Depth 9- 5/ Sample Depth pH 50? 7 {-73 Temperature CZ: ORP W, 254:2. Conductivity ?3920 Dissolved Oxygen ?5/4 7 Dissolved Sample Collected: YES NO Velocity Measurements Taken: YES NO Comment? (7/1441: 440/ 14/7; {Mil/ll :54? In x" 491)}; 1?7) jM/T?f/j [Gina-U bar" TL f?/A?L?Ilr?r/ 4214/ Water Quality Sample Form Project Name: Station ID: Sample ID: Sampling Crew: Subcontractor(s): Date: Time: Station Coordinates: Patrick Bayou P336) 43 7? ANCHOR Project Number: 040284-01 {-3575} 5 7L - mum ID ?ag/g; 4U 315; H5 13 65 31/, 5"3 Weather: (1 lam? .- y/?oml?) k4 w? 519/; - Tide; '32 ,3 ?7 53 2f) Sampling Method: 2. 291$? 26 z} 21 Parameter Units Result Water Depth 4/ Sample Depth 193-. pH 5 c/ 7. as" Temperature Conductivity :2 960 Dissolved Oxygen Dissolved Sample Collected: YES Velocity Measurements Taken: N0 Comments: Dis-ri?es 45?} i?xnc ?rm {am a? Water Quality Sample Form Project Name: Station ID: [730/ Sample ID /3809/ Sam Iin Crew: Weather: 5 . ?45, Of?f'n #:1116 /0 ?495 Subcontractor(s): 6 go}: Date: . . 705 Me: mus Station Coordinates: 51/7 Sampling MEthOdi gel/?SE ?Cc. 245/26; 9. 9?5 Parameter Units Result Water Depth 3 5' Sample Depth yak "77' pH 7 . Temperature 2,2 ORP 23 0 Conductivity ?Sam 6, y?g? Dissolved Oxygen Adj/? cl 7; Dissolved Sample Collected: YES Velocity Measurements Taken: YES 75/9/?7 Comments. A6: [gm mg I?Q/Jm??mr Patrick Bayou ANCHOR Project Number: 040284-01 0/ I'm far. 2/ mm Sam fr ?rtm Ark; Water Quality Sample Form Sigifl-IOR Project Name: Patrick Bayou Project Number: 040284-01 Station lD: ?g 9:17 Sample ID: [1/53/52 SamplingCrew: J74: HS gg? Weather: 56 {Jay/1 Subcontractor(s): 3945/ 20 Date: a; .- I 1? .. Time: Zg/qgi I 4/ Tide: fry?) . Station Coordinates: 32:25?; 37 Sampling Method: . H. "295724. a: Parameter Units Water Depth f' Sample Depth PH Temperature -- ORP Conductivity Dissolved Oxygen Dissolved Sample Collected: YES A/M?fwnf Wits Velocity Measurements Taken: YES Comments: mmu 74:? a iz/z/ 114/ in 515/ n/a; 5?.wa .7 .M .142' Inn/Jr? yo! far #10 I (Kr/van rad Ana! Water Quality Sample Form ANCHOR QEA Project Name: Patrick Bayou Project Number: 040284-01 Station ID: p30 9 Sample ID: /J/j?09??/5a/M 0) ?7 Sampling Crew: Hji [55 Weather: 7% me/ Subcontractor(s): 5?45] Date: Time: Tide: ?YZzi/[ahs //auJ Station Coordinates: 545323. ,15" Sampling Method: {Cw 145,44. 1U Parameter Units Result Water Depth 5 Sample Depth 0.. 7 pH 5 7 7 Temperature 6'6 52 35? ORP ~70 C) Conductivity Z30 Dissolved Oxygen 7' 35 Dissolved Sample Collected: YES @9 Velocity MeasurementsTaken: YES Comments: var/(cal 5,0,W49l'ff . I yJCW/ri" l' LJ y/lc? v1.4 arr. I Water Quality Sample Form ANCHOR Project Name: Patrick Bayou Project Number: 040284-01 Station ID: [38 Sample ID: PEMH awn/no M03 ?9 4? Sampling Crewr HS: J71, 5; Weather Dani/.4 f/aw/c/ Subcontractorls): {36.57 1451 ,1 (/i/wJHy/l Date: A Time: 1 7195/ Tide: kw - Station Coordinates: 3297/63. Sampling Method: no; [#15 (Lot f5 24F3f2502 Parameter Units Result Water Depth Sample Depth pH 57/ Temperature 5? ORP Conductivity Dissolved Oxygen (L Dissolved Sample Collecte' NO Velocity Measurements Taken: YES Comments Mind/c? [fa/?/mh?u?f lay/val?! 2/14 nu-L- nzurr/ Jena/w Watot Qua?ity Sample Form Project Name: Patrick Eavou Project Number; 040284-01 Station iD: Samnieln: woww liswwowogs/MM Sampiing Crew: $33; 13$ Weather: Subcontractor(s): lg 53;; Date: Ma??fv: 19 3 mtg?? {.441ng ?if; imer We: /?ow Station Coordinates: 4/ 3 2&5 323 Sampling MEth0d3 ?er g@ 23", Parameter Units Resuit Water {Depth Samoie {Depth E?emperature if: 1? (D Conductiv?ty m?g/?m {96/ DEssolved Oxygen ?33 1? ?145% Dissolved Sampte Cof?ectedr YES {39 Veiocity Measurements Taken: YES K1323 Comments: mgmf} at? ?sjsr??/ 7" mm toy/? Xw?/g 53/in fj?wf?i g?a?gmdg Water Quality Sample Form Project Name: Station ID Sample ID Sampling Crew: Subcontractorls): Date: Time: 3 3296063.?1?? Station Coordinates Patrick Bayou Pgooe. 105006.; - ISwm ID - ANCHOR Project Number: 040284?01 @5ch - IIWM ID - Mos/l? 53'. 35 Weatheri 26: f4 . 501523, 3615/ Mr? [30.3 Tide: [5 37: Sampling Mammw Parameter Units Result Water Depth Z. ?3 Sample Depth LL pH 50 7. Temperature 5 ORP 5?7- 5 Conductivity 5AM .50. IO Dissolved Oxygen /03 I Dissolved Sample Collected: NO Velocity Measurements Taken: YES Comments: air/mo mrc/ pry/f Z'f- Linn/C lapj?ft? fumiga?g Lat: angina/VJ Water Quality Sample Form ISIEEHOR Project Name: Patrick Bayou Project Number: 040284-01 Station ID: Sample Mam dawn/0 - - IV SamplingCrew: ?774 A/l?l/ Weather. alga, {frag-5 AZ winql Subcontractor(s): 3g5/ {3'60 7. Date: gym/,4 Time: /Zp'7. . Tide: {32' If g; Station Coordinates: e/o/na Sampling Method: aazfi? Parameter Units Result Water Depth 6) Sample Depth .5 pH X..- no?? Temperature ORP Conductivity Dissolved Oxygen Dissolved Sample Collected: YES Velocity Measurements Taken: YES Comments: [Dy/Mp ,p/JG/f/ Mm 75) 1 {11??nraxi a. JIY fir 74) Wrn?/ a/wl7 /0w Wa7lf~ ANCHOR QEA Water Quality Sample Form Project Name: Patrick Bayou Project Number: 040284?01 Station ID: P3230- I Sample ID: a?cio'l - [jwm ?2 SamplingCrew: TK 35 ?1?5 Weather: Sylranq ?5 Date: Tide: AW Time: [250 Station Coordinates: [it/J Sampling Method: away/41.42 Parameter Units Result I Water Depth (f 6 a . ampe ep 2 3 Manet! H, 2014 [LtTemperature IE. 7 ORP - Conductivity 50M 4/6 Dissolved Oxygen 9 7-C, Dissolved Sample Collected: YES Velocity MeasurementsTaken: YES Comments: 14/47/115 ?un?e'lc/ ales ?f?fo/ . L. (Elm Elma -M - 1.0 5/51] ?Ar/0716 "?5uop/? J'szwcAc/a/w 7/29 examve a/ArW h/bla/ub 0946/ /0w Water Quality Sample Form ANCHOR Project Name: Patrick Bayou Project Number: 040284-01 Station ID: P30 ;0 Sample ID: ?ag 20 - 156cm 10? Sampling Crew: 53? Hi NH Weather: c/mr'; 0?th Subcontractor(s): 355/ nae: aim/,4 Tide: Time: /236 /ow Station Coordinates: gag/qoq, 9/ Sampling Method: ?zz; ?5 2 5" UTM Mews Elg- Parameter nits Result Water Depth Sample Depth 4? pH i) Temperature ORP Conductivity Dissolved Oxygen Dissolved Sample Collected: YES 613 Velocity MeasurementsTaken: YES Comments: lag/5gg/ gr 7?0 54mio/z'nj? 5 fr/I'mmf' 47) jl?? ram .5 Mining ,7 Sauna/(J [no/15A 'ne WaterQuality Sample Form ANCHOR QEA Project Name: Patrick Bayou Project Number: 040284-01 Station ID: x0807? 3 Sample 3? ?/5wm up M0313 Sampling Crew: NH. 3,5: H5 Weather: 6255 Subcontractor(s): 555/ CZ Date= 3/13/14 Time: {0/25 Tide: Station Coordinates: .V 3144?5?5'5?5'6 Sampling Method: 2 . 5 d5. 2 lasts: '41 shuns/M: Parameter Result Water Depth . 0 A Sample Depth pH Temperature ORP . . - Conductiwty . 7 Dissolved Oxygen . Dissolved Sample Collected: YES Velocity Measurements Taken: YES Comments: /0 mm. nrrar k) A n! Sara/unenl? dug Agar ZMMIJJ: ?nals; pugs; am?? @wa/.L - Sago/5 za/fr'clf" (bar/Alla: ?so :55: fig?! a: I it ?Mm; Inm?'m Water Quality Sample Form ANCHOR QEA :33 Project Name: Patrick Bayou Project Number: 04028401 Station ID: (98056,- Sample ID: 2305.6 - l5a/M l0 ?1?4035 Sampling Crew: Weather: 6&2: SE if Subcontractor(s): 35$ 66"" 706/: Date= s/c. Time: fs?vis/ Tide: /aw /rr_sm0\ Station 5'03 {49? Sampling Method: - Z?s'tmz . 45' sum/me Parameter Units Result Water Depth ?f Sample Depth Temperature 20.3} ORP 1/ 3 Conductivity /3 . Dissolved Oxygen 7/ Dissolved Sample Collected@ NO Velocity Measurements Taken: YES Water Quality Sample Form ISIEEHOR Project Name: Patrick Bayou Project Number: 040284-01 Station ID: pgo?? Sample ID: [std/MID lql??3 Sampling Crew: 31;! ig?yj: N/f Weather: (by: 6N6 wine, Subcontractor(s): 565/- Go? ?0 Date: Time: {"2254 T'de- teal/M5: [Key 244%: Fri?) Station Coordinates: ;3 [(1301 .1 Sampling Method. Watt/'1: :77 #512983 may: 2/5" Parameter Units Result Water Depth 2. 0 Sample Depth a pH Temperature ORP Conductivity Dissolved Oxygen l- Dissolved Sample Collected: YES Velocity Measurements Taken: YES Comments: qu?/CO/ gem Ska /0mmu/g ha/g/ af?x {o/aczn? /5r1?/ma\ 7?ubf?a Ming-J: forror fawn/r ft ?((71400 ANCHOR QEA Water Qua?ity Sample Form Praject Name: Patrick Bayou Project Number; 04028401 Station ID: MEKMQ .3 f, effigy SampEing Crew: i Weather: {gf??gwwl H. Date: ?g [g as?) Twafgmx?xe Station?Coordinates: g1; Sampling Method: ?gm??eag?ig?gi i? 6* Parameter Units Water Gepth Sampie De ?ch 9% Temgerature ORP Cenductiviiy Dissoived Dissoived Samp?e Coffected: YES Vemc?ty Measurements Taken: YES .W gem wgi?? 593$ ?g Comments: {keg} emit 13': ANCHOR Water Quaiiw Sample Form Project Name: Patrick Bayou Project Number: 040284~01 Stationli}: Samplem: mg as Samp?ng Crew: 6g; Subcontracto?s): Date: ?3 Time: :5 Tide: Station Coordinates: Sampting Method: I ??322, Parameter Result Water Depth I. 5" Sam?le De th pH Temperature ORP Cenductivity Dissoived Dissaived Sampie Coiiected: YES Veiocity Measurements Taken: YES Comments: ga?zgwag? a 5% {Agg? Mg! ?akdm a? xiu?aig 33;.ng gg?gm Water Quality Sample Form ANCHOR Project Name: Patrick Bayou Project Number: 040284-01 StationlD: p?oza E- ?903/?l- IV Sample ID B?am_ (f SamplingCrew: Weather: 6/1? 0L: ?1 Subcontractor(s): 5/5/ Date= . Time: 07/0 Tide: Af Station Coordinates: QC :2 Sampling MEthOd: ?ow 604 7? 295-399. 7/ Parameter Units Result Water Depth 3 Sample Depth 4* pH 5 7 (p 0 Temperature 7 28 ORP 7- 3 Conductivity 9 Dissolved Oxygen ?5 /4 6 26 Dissolved Sample Collected: YES Velocity MeasurementsTaken: YES 69 Comments 75 /pum?/?j a [Dinar 6v) (fa-449 ?A/n I Water Quality Sample Form Project Name: Station ID Sample ID Sampling Crew: Subcontractor(s): Date Time: $13q16?1 1% NOYTNV3 Sampling Method: Station Coordinates Patrick Bayou ANCHOR QEA 2225 Project Number: 040284-01 =l?Bo'l?1 HS, SB Weather: [4-00 Tide: 26! 92.21319: 928?!in Parameter Units Result Water Depth 5 Sample Depth 2, pH 50 7. 4 5" Temperature 0C 30' 80 ORP )35 . Conductivity m's?m 4' 3? 7 Dissolved Oxygen 0A. I 3 Dissolved Sample Collected: YES Velocity Measurements Taken: Comments: YES Water Quality Sample Form Project Name: Station ID Sampling Crew Project Number: 040284-01 Subcontractorls): Date: Time: Station Coordinates: Patrick Bayou P9201 .- 8 Sample ID: PlbO'l l4oal+~N H9: Q9 Weather: elm/l 4 l?5l ?5 Tide: Sampling Method: Parameter Units Result Water Depth Ja? 2.01 Sample Depth \5 pH 5 a 7. 9+ Temperature 4'9 3 ORP [57. 0 Conductivity 0. CG Dissolved Oxygen 3 Dissolved Sample Collected: YES Velocity Measurements Taken: YES Comments: ANCHOR Water Quality Sample Form Project Name: Station ID: 14 Patrick Bayou ANCHOR QEA Project Number: 040284~01 Sample e/JwM/p - ?/0374 Sampling Crew Subcontractor(s): Date Time: 553774. 53 /5 Station Coordinates: 125965106 5 Weather: c/M . far/7%; wuc/ Tide: . Sampling Method: - - baaf? Parameter Units Result Water Depth Al? 0 Sample Depth [01Temperature (Z, I. ORP Conductivity A 7. 1/6 Dissolved Oxygen ?7 I Z. Dissolved Sample Collected: NO Velocity Measurements Taken: NO Comments: It. lo/g/ Mfr) {Ill/F 69:46 n: ?0 9" -or . g/rr run on Water Quality Sample Form Project Name: Patrick Bayou Station ID: Sample ID: Sampling Crew: Subcontractor(s): Date: Time: Station Coordinates: P696747 7. ANCHOR QEA ?1?21 Project Number: 040284-01 Dissolved Sample Collected: YES P609 72.14 50?7" 35 Weather: 24;: Eda?! {Si??ll 5wr?ac/ 3515/ . . /75 7 Tide: . 225 9251f Sampling Method: - 9.7" eff/V. 6 5? Parameter Units Result Water Depth Ff- 4/ 0 Sample Depth Temperature Conductivity (f 555- Dissolved Oxygen A. 7. ?g NO Velocity Measurements Taken: YES Comments: I?m/s?c! [?nal A arr/Ir xam 6mi- Water Quality Sample Form Project Name: Station ID: Sample ID: Sampling Crew: Subcontractor(s): Date: Time: Patrick Bayou ANCHOR Project Number: 040284?01 p/mgf? eras/cz-M J76 56? 35 555/, 72g 57:? ?ks Station Coordinates: g294'5?7?9? ?5 96 Weather: C?m? 0155? fwma/ v65? Tide: I - . Sampling Method: - ram Aoaf Parameter U?nits Result Water Depth Sample Depth #71- 5 pH 5 7L. 5'3 Temperature .66 ORP 6 Z. Conductivity 9? 96Z Dissolved Oxygen 9V Dissolved Sample Collected: YES Velocity Measurements Ta ken: YES Comments. 10/4/49 {Mozar 7 ?044?? XMAES Water Quality Sample Form ANCHOR QEA Project Name: Patrick Bayou Project Number: 040284-01 Station ID: {9505 Sample Pga? - ID - #70 3 Sampling Crew: J76. 513' 55 Weather. 640434; Swma/ Subcontractorls): ?gs/ v?55"?5?3' Date= 3 . Time: Way/q #25 We 4w rsma Station Coordinates: ll/ 32 399'55?37. Sampling Method: 2,055,; [12215ch 1 [90471. 5' 7.957 :15. z/ Parameter Units Regal Water Depth Z. 0 Sample Depth pH $0 ?71.63 Temperature 5 7' ORP (141/, 96.? Conductivity SAM Go 9/ Dissolved Oxygen f/L /5r Dissolved Sample Collected: YES Velocity MeasurementsTaken: YES Comments: /Umm [y?/ar 10/ A) [Dum?fnr 10 gm/a; (Cup? 7? Water Quality Sample Form ANCHOR QEA 8% Project Name: Patrick Bayou Project Number: 040284-01 Station ID: Pg?g?? Sample [9505/4 1st 20 - Sampling Crew:55 ,jK Weather: Subcontractor(s): 565/ .p 6 golf Time: 11,51. [cf/h: Station Coordinates: 5 32 @2951?. Sampling Method: ?95423. .517 Parameter Units Result Water Depth Sample Depth 2 0 pH 5 l/ 7-1/3 Temperature 20. 5'7 ORP l/ 5" Conductivity Ms/am 5. 664 Dissolved Oxygen 5-55 Dissolved Sample Collected: YES Velocity Measurements Taken: YES Comments: lay/l? AA fanJ Am saw/z mm A m' . bit, a" Water Quality Sample Form Project Name: Station lD Sample ID: Sampling Crevy: Subcontractor(s): Date: Time: Station Coordinates Patrick Bayou ANCHOR Project Number: 040284-01 Rama/?2 - - - may .55, 55 Weather: c/agc/a/ I 365/? I 3/xr/H . /530 Tide: /ooc/ ?ns-m1 32224372.- 95 Sampling Method: fie/?55; U7: 6' 15?. r/ Parameter Units Result Water Depth ?at. 2 0 Sample Depth [11. 0 pH 5 t/ 7 7(9 Temperature ?7 5 ORP l/ 25 Z). Conductivity ?1 5/0? /7.3 Dissolved Oxygen 5 Dissolved Sample Collected: YES Velocity Measurements Taken: YES Comments: gem-2:11? 5rd Av/a/ P257425 Water Quality Sample Form Project Name: Patrick Bayou ANCHOR Project Number: 040284-01 Weather: [ljb'f? Station ID: P5045, Sample ID: 193.9%2? A) Sampling Crew: 5,37, [25? 31C Subcontractorlsli 655/: Date: Tide: 15 Station Coordinatesg? 329?? gm; 6?5} 5" 3Z Sampling MethodParameter Units Result Water Depth A 7? Sample Depth pH 5 a 67 Temperature 0C 7 ORP 7. Conductivity $53 Dissolved Oxygen Dissolved Sample Collected: YES Velocity Measurements Taken: a 5 Comments: .5er ol-KCaJo/ro? {m %4 . [an Water Quality Sample Form ANCHOR Project Name: Patrick Bayou Project Number: 040284-01 Station ID: [9509? Sample ID: {9,575} 95:" Sampling Crew: \j?l?l 554 85 Weather: 71;? fret Subcontractor(s): 136;:5/ . ff?) Datega-z?ew?e?t 3/15/19! w: 541-}. mild? Time: j?3? Tide: Station Coordinates: 96:. Sampling Method: g/z M, I Z'cgg?in??si Parameter Units Result Water Depth 5 Sample Depth {if} ?7 Temperature ORP Mei-,1" Conductivity -. Z. .- ,3 ?3y Dissolved Oxygen ?En-{s 57 3' Dissolved Sample Collected: YES (E16: Velocity Measurements Taken: YES r/hlo I Comments: savvy/g ngla/zo/l/f [yr/c/?/vlcs 4?1 Water Quality Sample Form ANCHOR Project Name: Patrick Bayou Project Number: 040284-01 . Station ID: ?23 samp'e @3295 wag/fm/ Sampling Crew: :06 . 53 3-5 Weather: ff}: Subcontractor(s): 3575/; sin/I1 Date= sW'E/zf/lq Time: 6?22? I I Tide: [diux' Station Coordinates: 3251?:?fh30 Sampling Method: 6 345755 (2:63 Parameter Units Result Water Depth pr 37 Sample Depth fie-[r [ii 9? PH 5 u" "31-1 .- Temperature "Li Cv a: ORP C) Conductivity 9" 3 (I: Dissolved Oxygen 1" DissolvedSampleCollected: YES 68 VelocityMeasurementsTakenm YES NO CommentSi 5M4 a??sza?o/ra/I) (re, Aa/z/Ad/rs ANCHOR QEA WW Water Quality Sampae Form Project Name: Patrick anou Project Number: 040284-01 Station ID: SampEelD: gJ-Mgw 7 Sampiing Crew: Subcontractor(s): Date: ??g?gg Weather: mg; i a" 5 "v 3'55?: 1?23Time: Egg? Tide: fa; z?twriygfiww- Station Coordinates: 3f 5323in #3 Sampiing Method: ?wfgf? {gig ?ii? ?git E: x? var/s 1/?4 Parameter Units 335?? Water Semi?: 79+ Sampie Depth if 50? :53; 3:3 Temgerature 0C, ORP t/ 55:? Cmn?umv?ty Mg?m a; ?g Dissoived Oxygen Mia/L 5 1* Dissoived Sampie (In?ected: YES Vefocity Measurements Taken: YES if NO 3? Comments: rm ?wg/ ?gmgw? it?" REVISED REPORT Laboratory Report of Analysis To: Delaney Peterson ANCHOR ENVIRONMENTAL 720 Olive Way Suite 1900 Seattle, WA 98101 US Report Number: 31400373 Client Project: Patrick Bayou Dear Delaney Peterson, Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Amy J. Boehm at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you again on any additional analytical needs. Sincerely, SGS North America Inc. __________________________________________________________________ Jeannie Milholland Date QA Director jeannie.milholland@sgs.com Print Date: 04/08/2014 N.C. Certification # 481 1/62 REVISED REPORT Laboratory Qualifiers Report Definitions DL Method, Instrument, or Estimated Detection Limit per Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions * Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) V Recovery is below quality control limit. The data has been validated based on a favorable signal-to-noise A Amount detected is less than the Lower Method Calibration Limit J Estimated Concentration. O The recovery of this analyte in the OPR is above the Method QC Limits and the reported concentration in E Amount detected is greater than the Upper Calibration Limit S The amount of analyte present has saturated the detector. This situation results in an Q Indicates the presence of a quantitative interference. This situation may result in an I Indicates the presence of a qualitative interference that could cause a false positive or an DPE Indicates the presence of a peak in the polychlorinated diphenylether channel that could TIC Tentatively Identified Compound and detection limit the sample may be biased high underestimation of the affected analyte(s) underestimation of the affected analyte(s) overestimation of the affected analyte(s) cause a false positive or an overestimation of the affected analyte(s) EMPC Estimated Maximum possible Concentration due to ion ratio failure ND Not Detected K Result is estimated due to ion ratio failure in High Resolution PCB Analysis P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code definition is provided below: M1 Mis-identified peak Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Print Date: 04/08/2014 N.C. Certification # 481 2/62 REVISED REPORT Sample Summary Client Sample ID Lab Sample ID Collected Received Matrix PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N HSC14.1-1SWMID-140311-N 31400373001 31400373002 31400373003 03/11/2014 13:03 03/11/2014 13:03 03/11/2014 12:11 03/12/2014 09:45 03/12/2014 09:45 03/12/2014 09:45 Water Water Water Print Date: 04/08/2014 N.C. Certification # 481 3/62 REVISED REPORT Case Narrative 9060A ­ Samples for analysis for DOC were not filtered and preserved immediately upon receipt per SGS SOP. The samples were filtered and preserved 5 days after receipt, as soon as the error was noted. The late filtering and preservation may lead to a high bias on reported data. The DOC results are greater than the TOC results; this may be due to the late filtering. 2540­D ­ Revised report to J flag TSS results down to the MDL in order to meet the reporting limit requirements of the SAP for this project. Print Date: 04/08/2014 N.C. Certification # 481 4/62 REVISED REPORT Detectable Results Summary Client Sample ID: PB006.2-1SWMID-140311-D Lab Sample ID: 31400373001-C Parameter Dissolved Organic Carbon SW-846 9060A Total Organic Carbon Client Sample ID: PB006.2-1SWMID-140311-N Lab Sample ID: 31400373002-D Parameter Dissolved Organic Carbon SW-846 9060A Total Organic Carbon Client Sample ID: HSC14.1-1SWMID-140311-N Lab Sample ID: 31400373003-A Parameter Total Organic Carbon SW-846 9060A Print Date: 04/08/2014 Result 9.80 6.75 Result 9.40 5.47 Result 5.52 Units mg/L mg/L Units mg/L mg/L Units mg/L N.C. Certification # 481 5/62 6/62 CHAIN OF CUSTODY CONVENTIONAL 81 SHALE PROJECT INFO: PROJECT: 35?qu PO. #2 QUOTE SITEREF: ?L/ozg TURN AHOUNDTIME: 5+ L: (see reverse) Level I Level II XLeveI IV SPECIAL DELIVERAB LES: JXEDD: State of Origin: ETI Other: SEND DOCUMENTATION 1 RESULTS TO: chor LL C. CONTACT: 5} 2 (3 PHONE: 200- 03 3 -. EMAIL: ?ea ?ckarie?-?9m INVOICE T0: IF SAME) COMPANY: CONTACT: 30$ ADDRESS: PHONE: ll INSTRUCTIONS ET 5400 373 77a) SaPiwA 573DESCRIPTION DATE EMAIL: babp?pw/ era/17a Inga/0r. (om 00 TYPE TIME M8 M80 DUP Ian) OTY CONT. 07 ?Kl/#77797 wean/a 077.37 5H- 29 $75779770/ "?W?izx 82d 5 70.1 96666.2 -15r7rm 70- 0 #7er 730 1303 I I ?530577" a 1303 6 61/5 GI 1967776.; 157m 10 n. .717!? 3/71/17 72/} W5 2456/9/- .- [543mm 10 903/], u?n-r- COLL TIME: M50 7/ RECEIVED BY: #2fo . RECEIVED BY LA 7577777 RATO RY 0001 DATE fc?oc SEAL K: TAET 177W lr-I 7 RELINOUISHED BY (2): DATE: TIME: RECEIVED BY: SAMPLE RECEIPT 3?4 ?772? TRACKING #2 Page I of I 565 NORTH AMERICA INC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington. NC 28405 910 35019031910 7941613 R?nmhar AF fha CC: nrnun IQCQ CAI REVISED REPORT Edd 4 REVISED REPORT SGS North America Inc. Sample Receipt Checklist (SRC) Client: Anchor Environmental Work Order No.: 31400373 1. iShipped Notes: Hand Delivered COC Present on Receipt No 000 Additional Transmittal Forms Custody Tape on Container _No Custody Tape Samples Intact :Samples Broken Leaking 5. iChilled on Receipt Actual Temp.(s) in 3.4, 2.2 Thermometer Login-1D _Ambient on Receipt Walk-in on Ice; Coming down to temp. ZTemperature Blank Present .03 Sufficient Sample Submitted Insufficient Sample Submitted 7. Chlorine absent Additional Preservatives veri?ed (see notes) Received Within Holding Time _Not Received Within Holding Time No Discrepancies Noted Discrepancies Noted NCDENR notified of Discrepancies* 10. _No Headspace present in VOC vials Headspace present in VOC vials >6mm . I I I Comments. 5-w- a e, allull?l? Inspected and Logged in by: RCH Date: Wed-3/12/14 00:00 7/62 must be notified when collection, holding time or preservation requirements are not met. REVISED REPORT SM 2540-D Sample Data Print Date: 04/08/2014 N.C. Certification 481 55111] Business US - EMDE-Wilmirmnn. ME IN 3103-5111303 1+1 310350155? wan-.595 cum 8/62 LII 1hr SEE SIM REVISED REPORT Results of PB006.2-1SWMID-140311-D Client Sample ID: PB006.2-1SWMID-140311-D Client Project ID: Patrick Bayou Lab Sample ID: 31400373001-E Lab Project ID: 31400373 Collection Date: 03/11/2014 13:03 Received Date: 03/12/2014 09:45 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Total Suspended Solids 11 J 3.6 25.0 mg/L 1 Date Analyzed 03/14/2014 17:48 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:48 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 9/62 REVISED REPORT Results of PB006.2-1SWMID-140311-N Client Sample ID: PB006.2-1SWMID-140311-N Client Project ID: Patrick Bayou Lab Sample ID: 31400373002-F Lab Project ID: 31400373 Collection Date: 03/11/2014 13:03 Received Date: 03/12/2014 09:45 Matrix: Water Results by SM 2540-D Parameter Result Total Suspended Solids 17 Qual J DL 3.6 LOQ/CL Units DF Date Analyzed 25.0 mg/L 1 03/14/2014 17:49 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:49 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 10/62 REVISED REPORT Results of HSC14.1-1SWMID-140311-N Client Sample ID: HSC14.1-1SWMID-140311-N Client Project ID: Patrick Bayou Lab Sample ID: 31400373003-B Lab Project ID: 31400373 Collection Date: 03/11/2014 12:11 Received Date: 03/12/2014 09:45 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Total Suspended Solids 14 J 3.6 25.0 mg/L 1 Date Analyzed 03/14/2014 17:49 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:49 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 11/62 5500 Business Drive Wilmington, NC 28405 REVISED REPORT Total Suspended Solids SM 2540 Batch: 3014 Balance: BAL10 In Oven Date: 3/14/2014 Analyst: VS Oven: Oven #6 In Oven Time: 14:36 StandardlD: TSA15 In Oven Temp: 105 Out Oven Date: 3/14/2014 Out Oven Temp: 105 Out Oven Time: 15:58 Vol Filte Analyzed Filter Final Result Type Lab ID mL Lot Date Time 9 MB 132298 100 INV2 03/14/2014 14:17 0.1171 0.1169 -2 L03 132299 25 INV2 03/14/2014 14:17 0.1174 0.1286 448 SAMPLE 31400373001 100 03/14/2014 14:1 7 0.1195 0.1206 11 DUP 132300 100 INV2 03/14/2014 14:17 0.1179 0.1190 11 SAMPLE 31400373002 100 INV2 03/14/2014 14:17 0.1228 0.1245 17 SAMPLE 31400373003 100 INV2 03/14/2014 14:17 0.1224 0.1238 14 SAMPLE 31400386001 100 03/14/2014 14:17 0.1177 0.1177 0 SAMPLE 31400389001 100 INV2 03/14/2014 14:17 0.1194 0.1214 20 SAMPLE 31400389002 100 INV2 03/14/2014 14:17 0.1242 0.1258 16 SAMPLE 31400389003 100 INV2 03/14/2014 14:17 0.1183 0.1201 18 SAMPLE 31400389004 100 INV2 03/14/2014 14:18 0.1190 0.1224 34 SAMPLE 31400389005 100 INV2 03/14/2014 14:18 0.1192 0.1203 11 SAMPLE 31400389006 100 INV2 03/14/2014 14:18 0.1171 0.1178 7 KL 3 - 9 Analyst ngnature Date Analyst signature indicates that the data pn?nted is a true representation of volumes and weights encountered in the analytical process. Weights are obtained through overnight drying at 105C. The calculation of T83 is: (F2 - F1) 1,000,000 V1 Where: Final (9) F1 Filter (9) V1 Vol (mL) mg/L TSS 12/62 Printed: 3/14/2014 5:37:49 PM 1 of 1 Pages REVISED REPORT SM 2540-D QC, Blanks Data Print Date: 04/08/2014 N.C. Certification # 481 13/62 REVISED REPORT Batch Summary Analytical Method: SM 2540-D Prep Method: Prep Batch: Prep Date: SM 2540-D INO3014 03/14/2014 17:44 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41318 [INO/3014] 132298 03/14/2014 17:44 INO3014 BAL10 VS LCS for HBN 41318 [INO/3014] 132299 03/14/2014 17:47 INO3014 BAL10 VS PB006.2-1SWMID-140311-D 31400373001 03/14/2014 17:48 INO3014 BAL10 VS PB006.2-1SWMID-1...(132120DUP) 132300 03/14/2014 17:49 INO3014 BAL10 VS PB006.2-1SWMID-140311-N 31400373002 03/14/2014 17:49 INO3014 BAL10 VS HSC14.1-1SWMID-140311-N 31400373003 03/14/2014 17:49 INO3014 BAL10 VS Print Date: 04/08/2014 N.C. Certification # 481 14/62 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41318 [INO/3014] Blank Lab ID: 132298 Prep Batch: INO3014 Matrix: Water Analysis Date/Time: 03/14/2014 17:44 Results by SM 2540-D Client Sample ID Lab Sample ID LCS for HBN 41318 [INO/3014] PB006.2-1SWMID-140311-D Date Analyzed Analyst 132299 03/14/2014 17:47 VS 31400373001 03/14/2014 17:48 VS PB006.2-1SWMID-1...(132120DUP) 132300 03/14/2014 17:49 VS PB006.2-1SWMID-140311-N 31400373002 03/14/2014 17:49 VS HSC14.1-1SWMID-140311-N 31400373003 03/14/2014 17:49 VS Print Date: 04/08/2014 Filename N.C. Certification # 481 15/62 REVISED REPORT Method Blank Blank ID: MB for HBN 41318 [INO/3014] Blank Lab ID: 132298 Matrix: Water QC for Samples: 31400373001, 31400373002, 31400373003 Results by SM 2540-D Parameter Result Total Suspended Solids ND Qual DL LOQ/CL Units DF 3.60 25.0 mg/L 1 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 3/14/2014 5:44:34PM Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 16/62 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41318 [INO/3014] Blank Spike Lab ID: 132299 Date Analyzed: 03/14/2014 17:47 Matrix: Water QC for Samples: 31400373001, 31400373002, 31400373003 Results by SM 2540-D Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Suspended Solids 500 448 90 80.0-120 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:47 Spike Init Wt./Vol.: 1 mL Extract Vol: 1 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/08/2014 N.C. Certification # 481 17/62 REVISED REPORT Duplicate Sample Summary Original Sample ID: 31400373001-E Duplicate Sample ID: 132300 QC for Samples: Analysis Date: 03/14/2014 17:48 Analysis Date: 03/14/2014 17:49 Matrix: Water 31400373001, 31400373002, 31400373003 Results by SM 2540-D PARAMETER Original (mg/L) Qual Duplicate (mg/L) Qual RPD (%) RPD CL Total Suspended Solids 11 J 11 J 0 20.00 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Print Date: 04/25/2014 N.C. Certification # 481 18/62 REVISED REPORT SW-846 9060A Sample Data Print Date: 04/08/2014 N.C. Certification # 481 19/62 REVISED REPORT Results of PB006.2-1SWMID-140311-D Client Sample ID: PB006.2-1SWMID-140311-D Client Project ID: Patrick Bayou Lab Sample ID: 31400373001-C Lab Project ID: 31400373 Collection Date: 03/11/2014 13:03 Received Date: 03/12/2014 09:45 Matrix: Water Results by SW-846 9060A Parameter Dissolved Organic Carbon Total Organic Carbon Result Qual LOQ/CL 1.00 1.00 9.80 6.75 Units mg/L mg/L DF 1 1 Date Analyzed 03/18/2014 23:33 03/18/2014 13:30 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 13:30 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 23:33 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/08/2014 N.C. Certification # 481 20/62 REVISED REPORT PSW 3/19f2014 2:37:35 PM Sample Sample Name: . 0373_1 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result NPOC 1.000 IL 1. Det Anal.: NPOC Area . Date 1 . :41 75.84 . 30414W.2014 57.ca 4 11:36:40 74. . 14W 1 57.ca 1:39: 75. .8 14W 51 57.cal 1411:42- Mean Area 75.55 Signa [mV] 40 Mean Conc. 9.795mglL 30 44Time[min] 35/43 21/62 REVISED REPORT P??w 3/19/2014 2:37:35 PM Sample Sample Name: 0373?1 Sample ID: Origin: 9060A_TOC1_Walers.mel Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal: NPOC No. Area In]. Vol. Aut. Ex. Dil. 51. . 14 52. 6.74 .2014 5 . 6.6 4W.201 7 .2014 Mean Area 52.04 Signal[mV] 20 Mean Conc. 6.747mg/L 14 (AW 7 3419?? -2 16 18 20 INO3016.137 TimeImin] 7/43 22/62 REVISED REPORT Results of PB006.2-1SWMID-140311-N Client Sample ID: PB006.2-1SWMID-140311-N Client Project ID: Patrick Bayou Lab Sample ID: 31400373002-D Lab Project ID: 31400373 Collection Date: 03/11/2014 13:03 Received Date: 03/12/2014 09:45 Matrix: Water Results by SW-846 9060A Parameter Dissolved Organic Carbon Total Organic Carbon Result Qual LOQ/CL 1.00 1.00 9.40 5.47 Units mg/L mg/L DF 1 1 Date Analyzed 03/18/2014 22:32 03/18/2014 14:30 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 14:30 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 22:32 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/08/2014 N.C. Certification # 481 23/62 REVISED REPORT ?sw 3/19/2014 2:37:35 PM INOSO16.132 Sample Sample Name: 0373?2 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dll. Result Unknown NPOC 1.000 1. Del Anal.: NPOC Datel 9.3 1 51 . PM 9. 14W. 13 51 57 35:57.ca .3821.cal 10:41:07 Mean Area 72.52 Signal[mV] Mean Conc. 9.402mglL 61Time[min] 32/43 24/62 REVISED REPORT PSW Sample Sample Name: Sample ID: Origin: Status Chk. Result 3/19/2014 2:37:35 PM 0373_2 9060A_TOC1_Waters.met Completed Type Anal. Dil. Resuli Unknown NPOC 1.000 1. Det Ana .: NPOC Area '39 1.31 14 Mean Area Mean Conc. nj. Vol. 1 1 1 1 42.22 5.474mg/L law .1 Aut. Dil. 4W.20 4 14w.201 4w.2014 14w.2014 Signal[mVINO301 6.132 Timelmin] 10/43 25/62 REVISED REPORT Results of HSC14.1-1SWMID-140311-N Client Sample ID: HSC14.1-1SWMID-140311-N Client Project ID: Patrick Bayou Lab Sample ID: 31400373003-A Lab Project ID: 31400373 Collection Date: 03/11/2014 12:11 Received Date: 03/12/2014 09:45 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 5.52 Units mg/L DF 1 Date Analyzed 03/18/2014 14:52 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 14:52 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/08/2014 N.C. Certification # 481 26/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 0373_3 Sample ID: Origin: 906 0A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. 1 Result Unknown NPOC 1.0001 1, Del Anal: NPOC No. Area lnj. Vol. Aut. Cal. Curve Date Time Dil. . .20 PM 5.44 14W.20 :30 PM .261 14W 4 . 1 :39 PM 5 30414W. 3:01:47 PM .46 30414W. :05:06 PM Mean Area 42.59 Signal[mV] 20 Mean Conc. 5.522mg/L 45Time[min] 11/43 27/62 REVISED REPORT SW-846 9060A QC, Blanks Data Print Date: 04/08/2014 N.C. Certification # 481 28/62 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3016 03/18/2014 00:53 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41460 [INO/3016] 132565 03/18/2014 00:53 INO3016 TOC1 PSW LCS for HBN 41460 [INO/3016] 132566 03/18/2014 13:11 INO3016 TOC1 PSW PB006.2-1SWMID-140311-D 31400373001 03/18/2014 13:30 INO3016 TOC1 PSW PB006.2-1SWMID-14...(132120MS) 132567 03/18/2014 13:49 INO3016 TOC1 PSW PB006.2-1SWMID-1...(132120MSD) 132568 03/18/2014 14:09 INO3016 TOC1 PSW PB006.2-1SWMID-140311-N 31400373002 03/18/2014 14:30 INO3016 TOC1 PSW HSC14.1-1SWMID-140311-N 31400373003 03/18/2014 14:52 INO3016 TOC1 PSW PB097A-1SWMID-14...(132401DUP) 132569 03/18/2014 21:28 INO3016 TOC1 PSW Print Date: 04/08/2014 N.C. Certification # 481 29/62 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41460 [INO/3016] Blank Lab ID: 132565 Prep Batch: INO3016 Matrix: Water Analysis Date/Time: 03/18/2014 00:53 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41460 (INO/3016) 132764 INO3016.csv 03/18/2014 00:17 PSW LCS for HBN 41460 [INO/3016] 132566 INO3016.csv 03/18/2014 13:11 PSW PB006.2-1SWMID-140311-D 31400373001 INO3016.csv 03/18/2014 13:30 PSW PB006.2-1SWMID-14...(132120MS) 132567 INO3016.csv 03/18/2014 13:49 PSW PB006.2-1SWMID-1...(132120MSD) 132568 INO3016.csv 03/18/2014 14:09 PSW PB006.2-1SWMID-140311-N 31400373002 INO3016.csv 03/18/2014 14:30 PSW HSC14.1-1SWMID-140311-N 31400373003 INO3016.csv 03/18/2014 14:52 PSW CBV for HBN 41460 (INO/3016) 132768 INO3016.csv 03/18/2014 16:25 PSW PB097A-1SWMID-14...(132401DUP) 132569 INO3016.csv 03/18/2014 21:28 PSW Print Date: 04/08/2014 N.C. Certification # 481 30/62 REVISED REPORT Method Blank Blank ID: MB for HBN 41460 [INO/3016] Blank Lab ID: 132565 Matrix: Water QC for Samples: 31400373001, 31400373002, 31400373003 Results by SW-846 9060A Parameter Result Total Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 3/18/2014 12:53:41AM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/08/2014 N.C. Certification # 481 31/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 132565 MB Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk? Result A Type Anal. Dil. Result lUnknown NPOC 1.000 1. Del Anal.: NPOC No. Area . . Date Time Mean Area 1.710 Signal[mV] 10 Mean Conc. 0.2217mg/L mm 3?qvTimeImin] 5/43 32/62 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41460 [INO/3016] Blank Spike Lab ID: 132566 Date Analyzed: 03/18/2014 13:11 Matrix: Water QC for Samples: 31400373001, 31400373002, 31400373003 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Organic Carbon 50.0 48.6 97 90.0-110 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 13:11 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/08/2014 N.C. Certification # 481 33/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sampie Name: 132566 LCS Sample Origin: 9060A_TOC1_Waters.met Status Comp1eted Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Ana .: NPOC No. Area Conc. lnj. Vol. Aut. Ex. Cal. Curve Date/Time Oil. 1 371.4 48.15mq/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/20141:11:11 PM 2 375.9 48.74mg/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/2014 1:14:03 PM 3 371.8 48.21mg/L 100uL 1 030414W.2014 03 04 13 51 57.cal 3/18/20141216251 PM 379.5 49.20mg/L 100uL 1 030414W.2014 O3 04 13 51 57.ca 3/18/2014 1:19:42 PM Mean Area 374.7 Signal[mV] 200 Mean Conc. 48.57mg/L 5 140 341Time[min] 6/43 34/62 REVISED REPORT Matrix Spike Summary Original Sample ID: 31400373001 (PB006.2-1SWMID-140311-D) MS Sample ID: 132567 MSD Sample ID: 132568 QC for Samples: Analysis Date: 03/18/2014 13:30 Analysis Date: 03/18/2014 13:49 Analysis Date: 03/18/2014 14:09 Matrix: Water 31400373001, 31400373002, 31400373003 Results by SW-846 9060A Matrix Spike (mg/L) Parameter Total Organic Carbon Sample 6.75 Spike 50.0 Result 53.6 Spike Duplicate (mg/L) Rec (%) 94 Spike 50.0 Result 53.1 Rec (%) CL RPD (%) 93 75.0-125 0.94 RPD CL 25.00 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 13:30 MS Init Wt./Vol.: 40 mL Extract Vol.: 40 mL MSD Init Wt./Vol.: 40 mL Extract Vol.: 40 mL Print Date: 04/08/2014 N.C. Certification # 481 35/62 REVISED REPORT ESW 3/19/2014 2:37:35 PM lNO3016.t32 Sample Sample Name: 132567 MS SamplelD; Origin: 9060A_TOC1_Waters.met Status Completed Chk.P.esu l Type Anal. Dil. Result IUnknown POC 1.000 I 1. Del Ana .: NPOC No. Area .Curve 408. 3 04 3 7 418. 54..cal 407.5 52. 03 04 1 57. 417.2 54. 04 13 Mean Area 413.1 Signa1[mV] Mean Conc. 53.55mg/L Time[min] 8743 36/62 REVISED REPORT PSW 3/19l2014 2:37:35 PM Sample Sample Name: 132568 MSD SamplelD: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1.Det No. Area .Curve DatelTime .14.9 14W.2014 03 3 57.cal 14 . . 407.5 52. .2014 1 57.cal 14 411.1 53. .2014 1 57.cal 181201 MeanArea 409.6 Signal[mVMean Conc. 53.11mgTime[min] 9l43 37/62 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3017 03/18/2014 21:49 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB-F1 for HBN 41461 [INO/3017] 132570 03/18/2014 21:49 INO3017 TOC1 PSW LCS for HBN 41461 [INO/3017] 132571 03/18/2014 22:12 INO3017 TOC1 PSW PB006.2-1SWMID-140311-N 31400373002 03/18/2014 22:32 INO3017 TOC1 PSW PB006.2-1SWMID-14...(132121MS) 132572 03/18/2014 22:52 INO3017 TOC1 PSW PB006.2-1SWMID-1...(132121MSD) 132573 03/18/2014 23:12 INO3017 TOC1 PSW PB006.2-1SWMID-140311-D 31400373001 03/18/2014 23:33 INO3017 TOC1 PSW Print Date: 04/08/2014 N.C. Certification # 481 38/62 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB-F1 for HBN 41461 [INO/3017] Blank Lab ID: 132570 Prep Batch: INO3017 Matrix: Water Analysis Date/Time: 03/18/2014 21:49 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41461 (INO/3017) 132778 INO3017.csv 03/18/2014 20:45 PSW LCS for HBN 41461 [INO/3017] 132571 INO3017.csv 03/18/2014 22:12 PSW PB006.2-1SWMID-140311-N 31400373002 INO3017.csv 03/18/2014 22:32 PSW PB006.2-1SWMID-14...(132121MS) 132572 INO3017.csv 03/18/2014 22:52 PSW PB006.2-1SWMID-1...(132121MSD) 132573 INO3017.csv 03/18/2014 23:12 PSW PB006.2-1SWMID-140311-D 31400373001 INO3017.csv 03/18/2014 23:33 PSW CBV for HBN 41461 (INO/3017) 132779 INO3017.csv 03/19/2014 00:53 PSW Print Date: 04/08/2014 N.C. Certification # 481 39/62 REVISED REPORT Method Blank Blank ID: MB-F1 for HBN 41461 [INO/3017] Blank Lab ID: 132570 Matrix: Water QC for Samples: 31400373001, 31400373002 Results by SW-846 9060A Parameter Result Dissolved Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 3/18/2014 9:49:14PM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/08/2014 N.C. Certification # 481 40/62 REVISED REPORT RSW 3119/2014 2:37:35 PM 1N03016.l32 Sample Sample Name: 132570 MB-F1 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result lUnknown NPOC 1.000 1. Det Anal: NPOC No. Area lnj. Vol. Aut. Cal. Curve Dil2.834 . 4W 03 04 1 57 2.839 . 4W. 03 04 1 57.cal 3.525 . 4 03 04 1 7.ca 2. . 14W 4 03 Mean Area 3.010 ?10 Mean Conc. 0.3902mglL 6 34?1Time[min] 30l43 41/62 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41461 [INO/3017] Blank Spike Lab ID: 132571 Date Analyzed: 03/18/2014 22:12 Matrix: Water QC for Samples: 31400373001, 31400373002 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Dissolved Organic Carbon 50.0 49.1 98 90.0-110 Batch Information Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 22:12 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/08/2014 N.C. Certification # 481 42/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 132571 LCS Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Ana .: NPOC Area Date Time .cal PM 3843 9. . 3 51 57.cal 114:52 PM 375.9 .7 . 13 51 57.cal 10:17:42 PM 332. . 1 13 51 57 10:20:30 PM Mean Area 379.0 Signal[mV] 200 . . Mean Conc, 49.14mgTimeImin] 31/43 43/62 REVISED REPORT Matrix Spike Summary Original Sample ID: 31400373002 (PB006.2-1SWMID-140311-N) MS Sample ID: 132572 MSD Sample ID: 132573 QC for Samples: Analysis Date: 03/18/2014 22:32 Analysis Date: 03/18/2014 22:52 Analysis Date: 03/18/2014 23:12 Matrix: Water 31400373001, 31400373002 Results by SW-846 9060A Matrix Spike (mg/L) Parameter Dissolved Organic Carbon Sample 9.40 Spike 50.0 Result 56.3 Spike Duplicate (mg/L) Rec (%) 94 Spike 50.0 Result 56.2 Rec (%) CL RPD (%) 94 75.0-125 0.18 RPD CL 25.00 Batch Information Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 22:32 MS Init Wt./Vol.: 40 mL Extract Vol.: 40 mL MSD Init Wt./Vol.: 40 mL Extract Vol.: 40 mL Print Date: 04/08/2014 N.C. Certification # 481 44/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM 1N03016.t32 Sample Sample Name: 132572 MS Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result IUnknown NPOC 1.000 1. Det Anal: NPOC No. Area lnj.Vo . AutI Cal. Curve Dil. . 1 .20 4 cal 57. 14W.2014 13 5 .cal 55. 1 14W 3 04 57.cal 56. 1 14W 03 O4 1 57.cal Mean Area 434.2 200 . . Mean Conc. 56.30mglL an'54Time[min] 33/43 45/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 132573 MSD Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Del Anal.: NPOC No. [Time W20 .cal 41 .9 14W 51 57.cal 1411: 32.4 30414 51 57.ca 8/2014 437.4 1 812014 Mean Area 433.1 Signa [mV] 200 Mean Conc. 56.16mg/L 140 544Time[min] 34/43 46/62 REVISED REPORT SW-846 9060A Prep, Standard, Run Logs Print Date: 04/08/2014 N.C. Certification # 481 47/62 Method: Matrix: Initial Cal. Curve: 9060 Water ICAL-030414W SGS Environmental Services TOC Runlog Sheet Batch: Primary Lot#: D-437 Secondary Lot#: D-455 30/7 SAMPLE ID DILUTION DATE TIME OPER QC pH Comments ICV 3/18/201411155 PSW CBV 3/18/201412:17 PSW NEG 3/18/201412235 PSW [132565 MB 3/18/201412:53 PSW 132566 LCS PSW o373_1 3/18/201413130 PSW 132567 MS 3/18/2014 13:49 PSW 132568 3/18/201414209 PSW 45/b2 0373_2 3/18/201414130 PSW 0373_3 3/18/201414252 PSW 0389_1 0389_2 3/18/201415118 PSW 3/18/201415241 PSW 30% 3/18/201416103 PSW 3/18/201416225 PSW 0389_3 3/18/201416246 PSW 3/18/201417207 PSW 0389_4 I 0389_5 3/18/201417:29 PSW 0389_6 3/18/201417251 PSW o395_1 3/18/201418214 PSW o395_2 3/18/201418236 PSW o395_3 3/18/201418158 PSW K, Analyst: REVISED REPORT Method: Matrix: Initial Cal. Curve: 9060 Water ICAL-030414W 868 Environmental Services TOC Runlog Sheet Batch: IN03016 Primary Lot#: Secondary Lot#: 0455 SAMPLE ID DILUTION DATE TIME OPER QC pH Comments 0395_4 3/18/2014 19:20 PSW 0395_5 3/18/2014 19:42 PSW 0395_5 3/18/2014 20:03 PSW ICV 3/18/2014 20:24 PSW 3/18/2014 20:45 PSW 3/18/2014 21:08 PSW @2559 DUP 3/18/2014 21:28 PSW 132570 3/18/2014 21:49 PSW 49 62 132571 LCS 3/18/2014 22:12 PSW 0373_2 3/18/2014 22:32 PSW REVISE I) RE 132572 MS 3/18/2014 22:52 PSW @031?? 132573 MSD 3/18/2014 23:12 PSW o373__1 3/18/2014 23:33 PSW 0389_4 3/18/2014 23:53 PSW 0395_4 3/19/2014 0:14 PSW ICV 3/19/2014 0:33 PSW CBV 3/19/2014 0:53 PSW 0395_7 Sling/e 3/19/20141215 PSW 132574 DUP 3/19/20141135 PSW ICV 3/19/20141256 PSW CBV - 1'05 3/19/2014 2:16 PSW Analyst: REVISED REPORT SW-846 9060A Initial Calibration Data Print Date: 04/08/2014 N.C. Certification # 481 50/62 REVISED REPORT PSW 3/4/2014 4:35:34 PM 030414W.t32 Cal. Curve Sample Name: Untitled Sample ID: Untitled Cal. Curve: Status Completed Type Anal. 'DStandard NPOC Conc: 100.0mg/L No. Area nj.Vol. Aut. Rem. Ex. Date/Time Dil. 1 778.3 100uL 1 3/4/2014 2:00:59 PM 2 774.6 100uL 1 3/4/2014 2:06:27 PM 3 776.1 100uL 1 3/4/2014 2:11:52 PM 4 769.8 100uL 1 3/4/2014 2:17:17 PM Acid Add. 1.500% SignalImV] 400 . . Sp. Time 90.005ec 300 1 MeanArea 774.7 1/ fle 200 75 1 3,54Time[min] Conc: 50.00mg/L No. Area In]. Vol. . . Date Time :27. 2: :3 4/2014 2:43:10 PM Acid Add. 1.500% Signal[mV] 200 Sp. Time 90.00513} Mean Area 381.1 140 3:64Time[min] Conc: 10.00mg/L No. Area . . . DateAcid Add. 1.500% Signal[mV] 20 Sp. Time 90.005ec Mean Area 75.Time[min] 'Conc: 1.000mg/L Area 1 .2 14 3:22:03 PM 10.27 14 3:26:47 PM 10.29 14 3:31: PM 2/3 51/62 REVISED REPORT PSW 31'4/2014 4:35:34 PM 030414W.132 ACidAdd. 1.500% 10 Sp. Time 90.0058C Mean Area 10.26 6 HM #3541 Time[min] Conc: 0.5000mg/L No. Area DatelTime iti??ti 43. 6118 until 6.095 1 4/20143: .1PM 5.719 1 4 - pm 5.93? 1 4 . PM AcidAdd. 1.500% 10 Sp. Time 90.005ec MeanArea 6.108 6 ml 3,547 Time[min] Conc: 0.000mg/L No. Area In]. Vol. Aut. Rem. Ex. DatelTime 1.725 . 1. 4: . :1614 PM 1.572 1 PM AcidAdd. 1.500% Signa [mV] 10 Sp. Time 90.0059c MeanArea 1.646 Time[min] 7-713 Area 852.17 Intercept 0.000 r?2 0.999906 . 0999953 500 Zero Shl100110 Conc[mg/L] 3/3 52/62 REVISED REPORT SW-846 9060A Continuing Calibration Data Print Date: 04/08/2014 N.C. Certification # 481 53/62 REVISED REPORT PSW 3119/2014 2:37:35 PM Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dll. Result Unknown NPOC 1.000 1. Det Ana .: NPOC No. Area In]. Vol. Aut, Dil. 7.7 1 .cal :47 .5 MW 1 57.ca 1:58:40 .2 14 57.ca 01:35 PM 384.5 14 51 57.ca 12:04:22 PM .2 14W 1 57.ca 2:07:09 PM Mean Area 379.6 Signal[mV] 200 Mean Conc. 49.22mg/L TD 340' 4?4 -20 18 20 Time[min] 2/43 54/62 REVISED REPORT PSW 3719/2014 2:37:35 PM Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Ana .: NPOC Area Cal. Curve Date I Time 9.0 . 04 3 . :17 377.2 .91 . 03 04 :06:12 PM 373.1 48.37 4W 1 03 04 108159 375. 48.67 03 04 :11:44 PM Mean Area 373.7 Sig na [mV] Mean Conc. 48.45mglL Time[min] 14/43 55/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Samp1e Name: ICV SampIe ID: Origin: 9060A_TOC1_Waters.met Status Comp1eted Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal.: NPOC No. Cal. Curve Date 13 5 381.6 14W.2014 03 04 8:27:32 PM 3760 14W.2014 0 1 4 8:30:23 PM 379.7 14W.2014 03 14 8:33:10 PM Mean Area 376.7 Signall?mV] 200 Mean Conc. 48.84mg/L WI 140 br?q.?Time[min] 25/43 56/62 REVISED REPORT PSW 3l19/2014 2:37:35 PM Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.mel Status Completed Chk. Result Type Anal. Dll. Result lUnknown NPOC 1.000 1. Del Anal; NPOC Area Date I Time 49. . 12:3612:39: AM .2 1 Mean Area 377.4 Signal[mV] Mean Conc, 48.93mglL Time[min] 38l43 57/62 REVISED REPORT Analytical Blank Summary Form 3 Analytical Batch: INO3016 Units: mg/L Instrument: TOC1 Analyst: PSW Results by SW-846 9060A 132764 03/18/14 00:17 Dissolved Organ Total Organic Ca 132768 03/18/14 16:25 132778 03/18/14 20:45 1.00U 1.00U 132779 03/19/14 00:53 1.00U 1.00U Print Date: 04/08/2014 N.C. Certification # 481 58/62 REVISED REPORT PSW 311912014 2:37:35 PM Sample Sample Name: CBV SamplelD: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result NPOC 1.000 1. Del Anal.: NPOC No. Area Vol. Aut. .Curve Dil57.ca 03 O4 51 .cal 03 04 Mean Area 2.008 Signal[mV] 10 Mean Conc. 0.2604mg/L 4K 6 3aTime[min] 3/43 59/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Walers.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal; NPOC 7N0. Area Conc. lnj. Vol. Aut. Ex. Cal.Curve Date/Time Dil. 1 5.089 0.6598mg/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/2014 4:25:05 PM 2 1.923 0.2493mg/L 100uL 1 030414W2014 03 04 13 51 57.cal 3/18/2014 4:27:08 PM 3 1.512 0.1960mg/L 100uL 1 030414W.2014 03 04 13 51 57.cal 3/18/2014 4:29:12 PM 4 1.512 '1 0.1960mg/L 100uL 1 030414W.2014 03 04 13 51 57.cal /18/2014 4:31:15 PM 5 2.904 I 0.3765mg/L 100uL 1 30414W.2014 03 04 13 51 57.cal /18/20144:34:07 PM Mean Area 1.963 Signal[mV] 10 Mean Conc. 0.2545mgTimeImin] 15/43 60/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM IN03016.132 Sample Sample Name: CBV SamplelD: Origin: 9050A_TOC1_Waters.me1 Status Completed Chk. Result Type Anal. Dil. Result ll?Jnknown POC 1.000 1. Del No. Area . . Date/Time . .2014 3 51 .cal 18/2014 8: :4 2.94 .2014 .2014 13 51 .cal 1 148: :1 PM 3.21 . 13 51 57.ca 14 :57: PM Mean Area 3.141 Signa [mv1 10 Mean Conc. 0.4072mg/L 01W 6 A baTimeImin] 27/43 61/62 REVISED REPORT PSW 3/19/2014 2:37:35 PM N03016.t32 Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal; NPOC No. Date Time 1 . 4 :4 .938 . 4W.20 . 12. AM .330 . 4W.20 . 12: 2 AM .443 . 4W.20 46 . 14W. Mean Area 3.114 SignaumV] 10 Mean Conc. 0.4038mglL NJ - 6 34'1Time[min] 39/43 62/62 REVISED REPORT Laboratory Report of Analysis To: Delaney Peterson ANCHOR ENVIRONMENTAL 720 Olive Way Suite 1900 Seattle, WA 98101 US Report Number: 31400389 Client Project: Patrick Bayou Superfund Site Dear Delaney Peterson, Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Amy J. Boehm at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you again on any additional analytical needs. Sincerely, SGS North America Inc. __________________________________________________________________ Jeannie Milholland Date QA Director jeannie.milholland@sgs.com Print Date: 04/10/2014 N.C. Certification # 481 1/63 REVISED REPORT Laboratory Qualifiers Report Definitions DL Method, Instrument, or Estimated Detection Limit per Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions * Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) V Recovery is below quality control limit. The data has been validated based on a favorable signal-to-noise A Amount detected is less than the Lower Method Calibration Limit J Estimated Concentration. O The recovery of this analyte in the OPR is above the Method QC Limits and the reported concentration in E Amount detected is greater than the Upper Calibration Limit S The amount of analyte present has saturated the detector. This situation results in an Q Indicates the presence of a quantitative interference. This situation may result in an I Indicates the presence of a qualitative interference that could cause a false positive or an DPE Indicates the presence of a peak in the polychlorinated diphenylether channel that could TIC Tentatively Identified Compound and detection limit the sample may be biased high underestimation of the affected analyte(s) underestimation of the affected analyte(s) overestimation of the affected analyte(s) cause a false positive or an overestimation of the affected analyte(s) EMPC Estimated Maximum possible Concentration due to ion ratio failure ND Not Detected K Result is estimated due to ion ratio failure in High Resolution PCB Analysis P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code definition is provided below: M1 Mis-identified peak Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Print Date: 04/10/2014 N.C. Certification # 481 2/63 REVISED REPORT Sample Summary Client Sample ID Lab Sample ID Collected PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N EF006.1-1SWMID-140313-N PB119_B-1SWMID-140313-N 31400389001 31400389002 31400389003 31400389004 31400389005 31400389006 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/13/2014 Print Date: 04/10/2014 Received 12:36 13:25 14:28 15:45 15:00 16:10 03/14/2014 03/14/2014 03/14/2014 03/14/2014 03/14/2014 03/14/2014 Matrix 09:40 09:40 09:40 09:40 09:40 09:40 Water Water Water Water Water Water N.C. Certification # 481 3/63 REVISED REPORT Case Narrative 9060A ­ Sample for analysis for DOC was filtered and preserved immediately upon receipt per SGS SOP. The DOC results are greater than the TOC results. SGS confirmed via blank analyses that the filtering process in the laboratory did not cause an elevated DOC result. The higher DOC result may be due to the sampling process or the elapsed time from sampling to receipt and processing at the lab. 2540­D ­ Revised report to J flag TSS results down to the MDL in order to meet the reporting limit requirements of the SAP for this project. Print Date: 04/08/2014 N.C. Certification # 481 4/63 REVISED REPORT Detectable Results Summary Client Sample ID: PB020-1SWMID-140313-N Lab Sample ID: 31400389001-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB031.1-1SWMID-140313-N Lab Sample ID: 31400389002-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB047.3-1SWMID-140313-N Lab Sample ID: 31400389003-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB056_C-1SWMID-140313-N Lab Sample ID: 31400389004-E Parameter Total Suspended Solids SM 2540-D Dissolved Organic Carbon SW-846 9060A Total Organic Carbon 7.12 6.79 5.69 Result 34.0 12.9 9.34 Client Sample ID: EF006.1-1SWMID-140313-N Lab Sample ID: 31400389005-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB119_B-1SWMID-140313-N Lab Sample ID: 31400389006-A Parameter Total Organic Carbon SW-846 9060A Result Print Date: 04/10/2014 6.44 8.12 Units mg/L Units mg/L Units mg/L Units mg/L mg/L mg/L Units mg/L Units mg/L N.C. Certification # 481 5/63 CHAIN OF CUSTODY CONVENTIONAL 81 SHALE PROJECT INFO: SEND DOCUMENTATION I RESULTS TO: SPECIAL INSTRUCTIONS I COMMENTS: PROJECT: ??17 5617eg 1/ 5 1/ 6 aging/@514, 66 PO. Dc/qnaf pa-frf-iogh 3&2) 3 QUOTE or?: w? SITE REF: 0 ?/02 54/- Q6 PHONE: 99/6? PBESEBVATIVE - TURNAROUNDTIME: 51m" EMAIL: 20? it)? 30 3 . . 6/ 1/50/16REPORT LEVEL: LI Li I IIV P9 (see reverse} eve eve eve INVOICE TO: ?5 CHECK IF SAM E) SPECIAL DELIVERABLES: State of Origin: COMPANY: DNTACT: ANALYSIS METHOD 9:00: mower: ADDRESS: 5?6 ?hl?Kdd/S?i' PHONE: 7/6, (435?. M34, EMAIL: bo?pgpro/?aTYPE com. 8 31 SAMPLE IDIDESCRIPTION DATE TIME M5 M80 DUP (as) MATRIX P5020 75wm/0?/?/03/3 ?u ails/M my, 6+ ws P3031. I - [542/1420 - Mom-M ale/M If. 2.5? 6* ws P570403 454??: 1049mm? ms [Isl/"I I 5 015? vt/ 3/13/14 I 00 157/543 451de 44/03/31) 3/,3/14 mo 5670/ 3/131?; #300 at 3/5/11 1:00 7U Wit: d: +d'9211 7:22.! U-7d? "m .0 ?y 7 pug- I: 94:79.16; ME 95.; EM 6/(1): DATE: TIME: RECEIVED BY: @gg/ . 3/:5 Egg/5x RELINOUISHED BY (2): DATE: TIME: RECEIVED BY: Page of 353 NORTH AMERICA INC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 910 350 1903 I 910 794 1613 REVISED REPORT REVISED REPORT SGS North America Inc. Sample Receipt Checklist (SRC) Client: Anchor Environmental Work Order No.: 31400389 1. Shipped Notes: Hand Delivered 2. ACOC Presenton Receipt No COC Transmittal Forms 3. iCustody Tape on Container No Custody Tape 4. iSamples Intact _Samples Broken Leaking 5. iChilled on Receipt Actual Temp.(s) in 2.8, 2.1, 2.1 Thermometer Login-1D Ambient on Receipt Walk?In on Ice; Coming down to temp. Temperature Blank Present Sufficient Sample Submitted Insufficient Sample Submitted 7. Chlorine absent 1 Additional Preservatives veri?ed (see notes) I 8. Received Within Holding Time :Not Received Within Holding Time 9. AND Discrepancies Noted I _Discrepancies Noted notified of Discrepancies" 10. _No Headspace present in VOC vials _Headspace present in VOC vials >6mm Comments: Inspected and Logged in by: RCH Date: Fri-3/14/14 00:00 7/63 must be notified when collection, holding time or preservation requirements are not met. Ml_11.7 REVISED REPORT SM 2540-D Sample Data Print Date: 04/10/2014 N.C. Certification 481 55111] Business US - EMDE-Wilmirmnn. ME IN 3103-51] 1903 1+1 310350155? wan-.595 cum 8/63 LII 1hr SEE SIM REVISED REPORT Results of PB020-1SWMID-140313-N Client Sample ID: PB020-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389001-C Lab Project ID: 31400389 Collection Date: 03/13/2014 12:36 Received Date: 03/14/2014 09:40 Matrix: Water Results by SM 2540-D Parameter Result Total Suspended Solids 20.0 Qual J DL 3.60 LOQ/CL 25.0 Units DF mg/L 1 Date Analyzed 03/14/2014 17:50 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:50 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 9/63 REVISED REPORT Results of PB031.1-1SWMID-140313-N Client Sample ID: PB031.1-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389002-C Lab Project ID: 31400389 Collection Date: 03/13/2014 13:25 Received Date: 03/14/2014 09:40 Matrix: Water Results by SM 2540-D Parameter Result Total Suspended Solids 16.0 Qual J DL LOQ/CL 3.60 25.0 Units DF mg/L Date Analyzed 1 03/14/2014 17:51 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:51 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 10/63 REVISED REPORT Results of PB047.3-1SWMID-140313-N Client Sample ID: PB047.3-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389003-C Lab Project ID: 31400389 Collection Date: 03/13/2014 14:28 Received Date: 03/14/2014 09:40 Matrix: Water Results by SM 2540-D Parameter Result Total Suspended Solids 18.0 Qual J DL 3.60 LOQ/CL 25.0 Units DF mg/L 1 Date Analyzed 03/14/2014 17:51 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:51 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 11/63 REVISED REPORT Results of PB056_C-1SWMID-140313-N Client Sample ID: PB056_C-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389004-E Lab Project ID: 31400389 Collection Date: 03/13/2014 15:45 Received Date: 03/14/2014 09:40 Matrix: Water Results by SM 2540-D Parameter Result Total Suspended Solids 34.0 Qual DL LOQ/CL Units DF Date Analyzed 3.60 25.0 mg/L 1 03/14/2014 17:52 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:52 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 12/63 REVISED REPORT Results of EF006.1-1SWMID-140313-N Client Sample ID: EF006.1-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389005-C Lab Project ID: 31400389 Collection Date: 03/13/2014 15:00 Received Date: 03/14/2014 09:40 Matrix: Water Results by SM 2540-D Parameter Result Qual Total Suspended Solids 11.0 J DL 3.60 LOQ/CL 25.0 Units DF mg/L 1 Date Analyzed 03/14/2014 17:52 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:52 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 13/63 REVISED REPORT Results of PB119_B-1SWMID-140313-N Client Sample ID: PB119_B-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389006-C Lab Project ID: 31400389 Collection Date: 03/13/2014 16:10 Received Date: 03/14/2014 09:40 Matrix: Water Results by SM 2540-D Parameter Result Qual Total Suspended Solids 7.0 J DL 3.60 LOQ/CL 25.0 Units DF mg/L 1 Date Analyzed 03/14/2014 17:53 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:53 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 14/63 5500 Business Drive Wilmington, NC 28405 REVISED REPORT Total Suspended Solids SM 2540 Batch: 3014 Balance: BAL10 In Oven Date: 3/14/2014 Analyst: VS Oven: Oven #6 In Oven Time: 14:36 StandardlD: TSA15 In Oven Temp: 105 Out Oven Date: 3/14/2014 Out Oven Temp: 105 Out Oven Time: 15:58 Vol Filte Analyzed Filter Final Result Type Lab ID mL Lot Date Time 9 MB 132298 100 INV2 03/14/2014 14:17 0.1171 0.1169 -2 L03 132299 25 INV2 03/14/2014 14:17 0.1174 0.1286 448 SAMPLE 31400373001 100 03/14/2014 14:1 7 0.1195 0.1206 11 DUP 132300 100 INV2 03/14/2014 14:17 0.1179 0.1190 11 SAMPLE 31400373002 100 INV2 03/14/2014 14:17 0.1228 0.1245 17 SAMPLE 31400373003 100 INV2 03/14/2014 14:17 0.1224 0.1238 14 SAMPLE 31400386001 100 03/14/2014 14:17 0.1177 0.1177 0 SAMPLE 31400389001 100 INV2 03/14/2014 14:17 0.1194 0.1214 20 SAMPLE 31400389002 100 INV2 03/14/2014 14:17 0.1242 0.1258 16 SAMPLE 31400389003 100 INV2 03/14/2014 14:17 0.1183 0.1201 18 SAMPLE 31400389004 100 INV2 03/14/2014 14:18 0.1190 0.1224 34 SAMPLE 31400389005 100 INV2 03/14/2014 14:18 0.1192 0.1203 11 SAMPLE 31400389006 100 INV2 03/14/2014 14:18 0.1171 0.1178 7 KL 3 - 9 Analyst ngnature Date Analyst signature indicates that the data pn?nted is a true representation of volumes and weights encountered in the analytical process. Weights are obtained through overnight drying at 105C. The calculation of T83 is: (F2 - F1) 1,000,000 V1 Where: Final (9) F1 Filter (9) V1 Vol (mL) mg/L TSS 15/63 Printed: 3/14/2014 5:37:49 PM 1 of 1 Pages REVISED REPORT SM 2540-D QC, Blanks Data Print Date: 04/10/2014 N.C. Certification # 481 16/63 REVISED REPORT Batch Summary Analytical Method: SM 2540-D Prep Method: Prep Batch: Prep Date: SM 2540-D INO3014 03/14/2014 17:44 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41318 [INO/3014] 132298 03/14/2014 17:44 INO3014 BAL10 VS LCS for HBN 41318 [INO/3014] 132299 03/14/2014 17:47 INO3014 BAL10 VS PB006.2-1SWMID-1...(132120DUP) 132300 03/14/2014 17:49 INO3014 BAL10 VS PB020-1SWMID-140313-N 31400389001 03/14/2014 17:50 INO3014 BAL10 VS PB031.1-1SWMID-140313-N 31400389002 03/14/2014 17:51 INO3014 BAL10 VS PB047.3-1SWMID-140313-N 31400389003 03/14/2014 17:51 INO3014 BAL10 VS PB056_C-1SWMID-140313-N 31400389004 03/14/2014 17:52 INO3014 BAL10 VS EF006.1-1SWMID-140313-N 31400389005 03/14/2014 17:52 INO3014 BAL10 VS PB119_B-1SWMID-140313-N 31400389006 03/14/2014 17:53 INO3014 BAL10 VS Print Date: 04/10/2014 N.C. Certification # 481 17/63 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41318 [INO/3014] Blank Lab ID: 132298 Prep Batch: INO3014 Matrix: Water Analysis Date/Time: 03/14/2014 17:44 Results by SM 2540-D Client Sample ID Lab Sample ID LCS for HBN 41318 [INO/3014] Date Analyzed Analyst 132299 03/14/2014 17:47 VS PB006.2-1SWMID-1...(132120DUP) 132300 03/14/2014 17:49 VS PB020-1SWMID-140313-N 31400389001 03/14/2014 17:50 VS PB031.1-1SWMID-140313-N 31400389002 03/14/2014 17:51 VS PB047.3-1SWMID-140313-N 31400389003 03/14/2014 17:51 VS PB056_C-1SWMID-140313-N 31400389004 03/14/2014 17:52 VS EF006.1-1SWMID-140313-N 31400389005 03/14/2014 17:52 VS PB119_B-1SWMID-140313-N 31400389006 03/14/2014 17:53 VS Print Date: 04/10/2014 Filename N.C. Certification # 481 18/63 REVISED REPORT Method Blank Blank ID: MB for HBN 41318 [INO/3014] Blank Lab ID: 132298 Matrix: Water QC for Samples: 31400389001, 31400389002, 31400389003, 31400389004, 31400389005, 31400389006 Results by SM 2540-D Parameter Result Total Suspended Solids ND Qual DL LOQ/CL Units DF 3.60 25.0 mg/L 1 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 3/14/2014 5:44:34PM Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 19/63 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41318 [INO/3014] Blank Spike Lab ID: 132299 Date Analyzed: 03/14/2014 17:47 Matrix: Water QC for Samples: 31400389001, 31400389002, 31400389003, 31400389004, 31400389005, 31400389006 Results by SM 2540-D Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Suspended Solids 500 448 90 80.0-120 Batch Information Analytical Batch: INO3014 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3014 Prep Method: SM 2540-D Prep Date/Time: 03/14/2014 17:47 Spike Init Wt./Vol.: 1 mL Extract Vol: 1 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/10/2014 N.C. Certification # 481 20/63 REVISED REPORT SW-846 9060A Sample Data Print Date: 04/10/2014 N.C. Certification # 481 21/63 REVISED REPORT Results of PB020-1SWMID-140313-N Client Sample ID: PB020-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389001-A Lab Project ID: 31400389 Collection Date: 03/13/2014 12:36 Received Date: 03/14/2014 09:40 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 7.12 Units mg/L DF 1 Date Analyzed 03/18/2014 15:18 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 15:18 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/10/2014 N.C. Certification # 481 22/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 0389_1 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 i 1. Det Anal: NPOC N0. . Date I Time . . .2014 .cal 3:1 . .48 . 14W.2014 51 57.cal 143:2 PM 4 14W 14 5157.ca 143:24: PM 54.70 . 14W 51 57.Ca 0143' 1PM .85 14W 51 57.Cal Mean Area 54.94 Signa [mV] 20 Mean Conc. 7.123mgTime[min] 12/43 23/63 REVISED REPORT Results of PB031.1-1SWMID-140313-N Client Sample ID: PB031.1-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389002-A Lab Project ID: 31400389 Collection Date: 03/13/2014 13:25 Received Date: 03/14/2014 09:40 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 6.79 Units mg/L DF 1 Date Analyzed 03/18/2014 15:41 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 15:41 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/10/2014 N.C. Certification # 481 24/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM N03016.t32 Sample Sample Name: 0389_2 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Result g?J Unknown NPOC 1.000 1. Det Anal: NPOC No. Area . . 14 . 25 .2014 51 57.ca 51.70 .2014 3 51 57 52.54 .81 W.2014 Mean Area 52.33 Signa][mV] 20 Mean Conc. 6.785mg/L @001 ?Time[min] 13/43 25/63 REVISED REPORT Results of PB047.3-1SWMID-140313-N Client Sample ID: PB047.3-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389003-A Lab Project ID: 31400389 Collection Date: 03/13/2014 14:28 Received Date: 03/14/2014 09:40 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 5.69 Units mg/L DF 1 Date Analyzed 03/18/2014 16:46 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 16:46 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/10/2014 N.C. Certification # 481 26/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM 1N03016.t32 Sample SampIe Name: 0389_3 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Resuh 1Unknown NPOC 1.000 1. Det Anal.: NPOC Area Cal. . 14 03 7.ca .10 . 4 14 03 57.ca .22 . .2014 3 57. .81 . 1 W.2014 51 57.ca Mean Area 43.90 Signa [mV] 20 Mean Conc. 5.691mglL Time[min] 16/43 27/63 REVISED REPORT Results of PB056_C-1SWMID-140313-N Client Sample ID: PB056_C-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389004-C Lab Project ID: 31400389 Collection Date: 03/13/2014 15:45 Received Date: 03/14/2014 09:40 Matrix: Water Results by SW-846 9060A Parameter Dissolved Organic Carbon Total Organic Carbon Result Qual LOQ/CL 1.00 1.00 12.9 9.34 Units mg/L mg/L DF 1 1 Date Analyzed 03/18/2014 23:53 03/18/2014 17:07 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 17:07 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 23:53 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/10/2014 N.C. Certification # 481 28/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM 1N03016.t32 Sample Sample Name: 0389_4 SamplelD: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result [Unknown NPOC 1.000 1. Det Anal.: NPOC No. Area Conc. Inj. Vol. Aut. Ex. Cal. Curve Date/Time Dil. 1 99.27 12.87mg/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/2014 11:53:55 PM 2 100.0 12.97mg/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/2014 11:56:45 PM 3 99.05 12.84mg/L 1OOUL 1 030414W.2014 03 04 13 51 57.ca 3/18/201411:59:48 PM 4 100.4 13.02mg/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/19/2014 12:02:37 AM Mean Area 99.68 Signal[mV] 40 Mean Conc. 30 344.Time[min] 36/43 29/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM N03016.t32 Sample Sample Name: 0389_4 SamplelD: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal, Dil. Result Unknown NPOC 1.000 1. Det Anal.: NPOC No. Area Conc. nj.Vol. Aut. Ex. Date/Time Dil. 1 72.27 9.370rng/L 100uL 1 030414W.2014 03 04 13 51 57.cal 3/18/2014 5:07:29 PM 2 72.39 9.386mg/L 100uL 1 030414W.2014 03 O4 13 51 57.ca 3/18/2014 5:10:41 PM 3 71.40 9.257mg/L 100uL 1 D30414W.2014 03 04 13 51 57.cal 3/18/2014 5:13:42 PM 4 72.08 9.345mg/ 100uL 1 30414W.2014 03 04 13 51 57.ca l18/20145:16:35 PM Mean Area 72.04 Signa [mV] 40 Mean Conc. 9.340mgTime[min] 17/43 30/63 REVISED REPORT Results of EF006.1-1SWMID-140313-N Client Sample ID: EF006.1-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389005-A Lab Project ID: 31400389 Collection Date: 03/13/2014 15:00 Received Date: 03/14/2014 09:40 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 6.44 Units mg/L DF 1 Date Analyzed 03/18/2014 17:29 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 17:29 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/10/2014 N.C. Certification # 481 31/63 REVISED REPORT PSW 3/19l2014 2:37:35 PM Sample Sample Name: 0389_5 SamplelD: Origin: 9060A_TOC1_Waters.mel Status Completed Chk. Result Type Anal. Dil. Result NPOC 1.000 1.Det No. Area 4W.2014 14W .cal PM .06 . 14W 0 04 57.031 14 PM MeanArea 49.70 Signa [mVMean Conc. 6.443mgTime[min] 18/43 32/63 REVISED REPORT Results of PB119_B-1SWMID-140313-N Client Sample ID: PB119_B-1SWMID-140313-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400389006-A Lab Project ID: 31400389 Collection Date: 03/13/2014 16:10 Received Date: 03/14/2014 09:40 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 8.12 Units mg/L DF 1 Date Analyzed 03/18/2014 17:51 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 17:51 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/10/2014 N.C. Certification # 481 33/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM N03016.l32 Sample Sample Name: 0389_6 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 Det Anal; NPOC No. Area . . 14 62.82 8.1 W.2014 61.69 .998 4W.2014 62.97 8.1 1 W.2014 Mean Area 62.60 Signal[mV] 20 Mean Conc. 8.115mg/L 1 4 t?oTime[min] 1.9/43 34/63 REVISED REPORT SW-846 9060A QC, Blanks Data Print Date: 04/10/2014 N.C. Certification # 481 35/63 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3016 03/18/2014 00:53 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41460 [INO/3016] 132565 03/18/2014 00:53 INO3016 TOC1 PSW LCS for HBN 41460 [INO/3016] 132566 03/18/2014 13:11 INO3016 TOC1 PSW PB006.2-1SWMID-14...(132120MS) 132567 03/18/2014 13:49 INO3016 TOC1 PSW PB006.2-1SWMID-1...(132120MSD) 132568 03/18/2014 14:09 INO3016 TOC1 PSW PB020-1SWMID-140313-N 31400389001 03/18/2014 15:18 INO3016 TOC1 PSW PB031.1-1SWMID-140313-N 31400389002 03/18/2014 15:41 INO3016 TOC1 PSW PB047.3-1SWMID-140313-N 31400389003 03/18/2014 16:46 INO3016 TOC1 PSW PB056_C-1SWMID-140313-N 31400389004 03/18/2014 17:07 INO3016 TOC1 PSW EF006.1-1SWMID-140313-N 31400389005 03/18/2014 17:29 INO3016 TOC1 PSW PB119_B-1SWMID-140313-N 31400389006 03/18/2014 17:51 INO3016 TOC1 PSW PB097A-1SWMID-14...(132401DUP) 132569 03/18/2014 21:28 INO3016 TOC1 PSW Print Date: 04/10/2014 N.C. Certification # 481 36/63 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41460 [INO/3016] Blank Lab ID: 132565 Prep Batch: INO3016 Matrix: Water Analysis Date/Time: 03/18/2014 00:53 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41460 (INO/3016) 132764 INO3016.csv 03/18/2014 00:17 PSW LCS for HBN 41460 [INO/3016] 132566 INO3016.csv 03/18/2014 13:11 PSW PB006.2-1SWMID-14...(132120MS) 132567 INO3016.csv 03/18/2014 13:49 PSW PB006.2-1SWMID-1...(132120MSD) 132568 INO3016.csv 03/18/2014 14:09 PSW PB020-1SWMID-140313-N 31400389001 INO3016.csv 03/18/2014 15:18 PSW PB031.1-1SWMID-140313-N 31400389002 INO3016.csv 03/18/2014 15:41 PSW CBV for HBN 41460 (INO/3016) 132768 INO3016.csv 03/18/2014 16:25 PSW PB047.3-1SWMID-140313-N 31400389003 INO3016.csv 03/18/2014 16:46 PSW PB056_C-1SWMID-140313-N 31400389004 INO3016.csv 03/18/2014 17:07 PSW EF006.1-1SWMID-140313-N 31400389005 INO3016.csv 03/18/2014 17:29 PSW PB119_B-1SWMID-140313-N 31400389006 INO3016.csv 03/18/2014 17:51 PSW CBV for HBN 41460 (INO/3016) 132770 INO3016.csv 03/18/2014 20:45 PSW PB097A-1SWMID-14...(132401DUP) 132569 INO3016.csv 03/18/2014 21:28 PSW Print Date: 04/10/2014 N.C. Certification # 481 37/63 REVISED REPORT Method Blank Blank ID: MB for HBN 41460 [INO/3016] Blank Lab ID: 132565 Matrix: Water QC for Samples: 31400389001, 31400389002, 31400389003, 31400389004, 31400389005, 31400389006 Results by SW-846 9060A Parameter Result Total Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 3/18/2014 12:53:41AM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/10/2014 N.C. Certification # 481 38/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 132565 MB Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk? Result A Type Anal. Dil. Result lUnknown NPOC 1.000 1. Del Anal.: NPOC No. Area . . Date Time Mean Area 1.710 Signal[mV] 10 Mean Conc. 0.2217mg/L mm 3?qvTimeImin] 5/43 39/63 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41460 [INO/3016] Blank Spike Lab ID: 132566 Date Analyzed: 03/18/2014 13:11 Matrix: Water QC for Samples: 31400389001, 31400389002, 31400389003, 31400389004, 31400389005, 31400389006 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Organic Carbon 50.0 48.6 97 90.0-110 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 13:11 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/10/2014 N.C. Certification # 481 40/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sampie Name: 132566 LCS Sample Origin: 9060A_TOC1_Waters.met Status Comp1eted Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Ana .: NPOC No. Area Conc. lnj. Vol. Aut. Ex. Cal. Curve Date/Time Oil. 1 371.4 48.15mq/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/20141:11:11 PM 2 375.9 48.74mg/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/2014 1:14:03 PM 3 371.8 48.21mg/L 100uL 1 030414W.2014 03 04 13 51 57.cal 3/18/20141216251 PM 379.5 49.20mg/L 100uL 1 030414W.2014 O3 04 13 51 57.ca 3/18/2014 1:19:42 PM Mean Area 374.7 Signal[mV] 200 Mean Conc. 48.57mg/L 5 140 341Time[min] 6/43 41/63 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3017 03/18/2014 21:49 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB-F1 for HBN 41461 [INO/3017] 132570 03/18/2014 21:49 INO3017 TOC1 PSW LCS for HBN 41461 [INO/3017] 132571 03/18/2014 22:12 INO3017 TOC1 PSW PB006.2-1SWMID-14...(132121MS) 132572 03/18/2014 22:52 INO3017 TOC1 PSW PB006.2-1SWMID-1...(132121MSD) 132573 03/18/2014 23:12 INO3017 TOC1 PSW PB056_C-1SWMID-140313-N 31400389004 03/18/2014 23:53 INO3017 TOC1 PSW Print Date: 04/10/2014 N.C. Certification # 481 42/63 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB-F1 for HBN 41461 [INO/3017] Blank Lab ID: 132570 Prep Batch: INO3017 Matrix: Water Analysis Date/Time: 03/18/2014 21:49 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41461 (INO/3017) 132778 INO3017.csv 03/18/2014 20:45 PSW LCS for HBN 41461 [INO/3017] 132571 INO3017.csv 03/18/2014 22:12 PSW PB006.2-1SWMID-14...(132121MS) 132572 INO3017.csv 03/18/2014 22:52 PSW PB006.2-1SWMID-1...(132121MSD) 132573 INO3017.csv 03/18/2014 23:12 PSW PB056_C-1SWMID-140313-N 31400389004 INO3017.csv 03/18/2014 23:53 PSW CBV for HBN 41461 (INO/3017) 132779 INO3017.csv 03/19/2014 00:53 PSW Print Date: 04/10/2014 N.C. Certification # 481 43/63 REVISED REPORT Method Blank Blank ID: MB-F1 for HBN 41461 [INO/3017] Blank Lab ID: 132570 Matrix: Water QC for Samples: 31400389004 Results by SW-846 9060A Parameter Result Dissolved Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 3/18/2014 9:49:14PM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/10/2014 N.C. Certification # 481 44/63 REVISED REPORT RSW 3119/2014 2:37:35 PM 1N03016.l32 Sample Sample Name: 132570 MB-F1 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result lUnknown NPOC 1.000 1. Det Anal: NPOC No. Area lnj. Vol. Aut. Cal. Curve Dil2.834 . 4W 03 04 1 57 2.839 . 4W. 03 04 1 57.cal 3.525 . 4 03 04 1 7.ca 2. . 14W 4 03 Mean Area 3.010 ?10 Mean Conc. 0.3902mglL 6 34?1Time[min] 30l43 45/63 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41461 [INO/3017] Blank Spike Lab ID: 132571 Date Analyzed: 03/18/2014 22:12 Matrix: Water QC for Samples: 31400389004 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Dissolved Organic Carbon 50.0 49.1 98 90.0-110 Batch Information Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 22:12 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/10/2014 N.C. Certification # 481 46/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 132571 LCS Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Ana .: NPOC Area Date Time .cal PM 3843 9. . 3 51 57.cal 114:52 PM 375.9 .7 . 13 51 57.cal 10:17:42 PM 332. . 1 13 51 57 10:20:30 PM Mean Area 379.0 Signal[mV] 200 . . Mean Conc, 49.14mgTimeImin] 31/43 47/63 REVISED REPORT SW-846 9060A Prep, Standard, Run Logs Print Date: 04/10/2014 N.C. Certification # 481 48/63 Method: Matrix: Initial Cal. Curve: 9060 Water ICAL-030414W SGS Environmental Services TOC Runlog Sheet Batch: Primary Lot#: D-437 Secondary Lot#: D-455 30/7 SAMPLE ID DILUTION DATE TIME OPER QC pH Comments ICV 3/18/201411155 PSW CBV 3/18/201412:17 PSW NEG 3/18/201412235 PSW [132565 MB 3/18/201412:53 PSW 132566 LCS PSW o373_1 3/18/201413130 PSW 132567 MS 3/18/2014 13:49 PSW 132568 3/18/201414209 PSW 4::1/b3 0373_2 3/18/201414130 PSW 0373_3 3/18/201414252 PSW 0389_1 0389_2 3/18/201415118 PSW 3/18/201415241 PSW 30% 3/18/201416103 PSW 3/18/201416225 PSW 0389_3 3/18/201416246 PSW 3/18/201417207 PSW 0389_4 I 0389_5 3/18/201417:29 PSW 0389_6 3/18/201417251 PSW o395_1 3/18/201418214 PSW o395_2 3/18/201418236 PSW o395_3 3/18/201418158 PSW K, Analyst: REVISED REPORT Method: Matrix: Initial Cal. Curve: 9060 Water ICAL-030414W 868 Environmental Services TOC Runlog Sheet Batch: IN03016 Primary Lot#: Secondary Lot#: 0455 SAMPLE ID DILUTION DATE TIME OPER QC pH Comments 0395_4 3/18/2014 19:20 PSW 0395_5 3/18/2014 19:42 PSW 0395_5 3/18/2014 20:03 PSW ICV 3/18/2014 20:24 PSW 3/18/2014 20:45 PSW 3/18/2014 21:08 PSW @2559 DUP 3/18/2014 21:28 PSW 132570 3/18/2014 21:49 PSW 50 63 132571 LCS 3/18/2014 22:12 PSW 0373_2 3/18/2014 22:32 PSW REVISE I) RE 132572 MS 3/18/2014 22:52 PSW @031?? 132573 MSD 3/18/2014 23:12 PSW o373__1 3/18/2014 23:33 PSW 0389_4 3/18/2014 23:53 PSW 0395_4 3/19/2014 0:14 PSW ICV 3/19/2014 0:33 PSW CBV 3/19/2014 0:53 PSW 0395_7 Sling/e 3/19/20141215 PSW 132574 DUP 3/19/20141135 PSW ICV 3/19/20141256 PSW CBV - 1'05 3/19/2014 2:16 PSW Analyst: REVISED REPORT SW-846 9060A Initial Calibration Data Print Date: 04/10/2014 N.C. Certification # 481 51/63 REVISED REPORT PSW 3/4/2014 4:35:34 PM 030414W.t32 Cal. Curve Sample Name: Untitled Sample ID: Untitled Cal. Curve: Status Completed Type Anal. 'DStandard NPOC Conc: 100.0mg/L No. Area nj.Vol. Aut. Rem. Ex. Date/Time Dil. 1 778.3 100uL 1 3/4/2014 2:00:59 PM 2 774.6 100uL 1 3/4/2014 2:06:27 PM 3 776.1 100uL 1 3/4/2014 2:11:52 PM 4 769.8 100uL 1 3/4/2014 2:17:17 PM Acid Add. 1.500% SignalImV] 400 . . Sp. Time 90.005ec 300 1 MeanArea 774.7 1/ fle 200 75 1 3,54Time[min] Conc: 50.00mg/L No. Area In]. Vol. . . Date Time :27. 2: :3 4/2014 2:43:10 PM Acid Add. 1.500% Signal[mV] 200 Sp. Time 90.00513} Mean Area 381.1 140 3:64Time[min] Conc: 10.00mg/L No. Area . . . DateAcid Add. 1.500% Signal[mV] 20 Sp. Time 90.005ec Mean Area 75.Time[min] 'Conc: 1.000mg/L Area 1 .2 14 3:22:03 PM 10.27 14 3:26:47 PM 10.29 14 3:31: PM 2/3 52/63 REVISED REPORT PSW 31'4/2014 4:35:34 PM 030414W.132 ACidAdd. 1.500% 10 Sp. Time 90.0058C Mean Area 10.26 6 HM #3541 Time[min] Conc: 0.5000mg/L No. Area DatelTime iti??ti 43. 6118 until 6.095 1 4/20143: .1PM 5.719 1 4 - pm 5.93? 1 4 . PM AcidAdd. 1.500% 10 Sp. Time 90.005ec MeanArea 6.108 6 ml 3,547 Time[min] Conc: 0.000mg/L No. Area In]. Vol. Aut. Rem. Ex. DatelTime 1.725 . 1. 4: . :1614 PM 1.572 1 PM AcidAdd. 1.500% Signa [mV] 10 Sp. Time 90.0059c MeanArea 1.646 Time[min] 7-713 Area 852.17 Intercept 0.000 r?2 0.999906 . 0999953 500 Zero Shl100110 Conc[mg/L] 3/3 53/63 REVISED REPORT SW-846 9060A Continuing Calibration Data Print Date: 04/10/2014 N.C. Certification # 481 54/63 REVISED REPORT PSW 3119/2014 2:37:35 PM Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dll. Result Unknown NPOC 1.000 1. Det Ana .: NPOC No. Area In]. Vol. Aut, Dil. 7 1 .cal :47 7 5 . 14W 1 57.ca 1:58:40 2 . 14 57.cal 01:35 PM 384.5 2 14 51 57.ca 12:04:22 PM 14W 1 57.ca 2:07:09 PM Mean Area 379.6 Signal[mV] 200 Mean Conc. 49.22mg/L and 140 3.1Time[min] 2/43 55/63 REVISED REPORT PSW 3719/2014 2:37:35 PM Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Ana .: NPOC Area Cal. Curve Date I Time 9.0 . 04 3 . :17 377.2 .91 . 03 04 :06:12 PM 373.1 48.37 4W 1 03 04 108159 375. 48.67 03 04 :11:44 PM Mean Area 373.7 Sig na [mV] Mean Conc. 48.45mglL Time[min] 14/43 56/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Samp1e Name: ICV SampIe ID: Origin: 9060A_TOC1_Waters.met Status Comp1eted Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal.: NPOC No. Cal. Curve Date 13 5 381.6 14W.2014 03 04 8:27:32 PM 3760 14W.2014 0 1 4 8:30:23 PM 379.7 14W.2014 03 14 8:33:10 PM Mean Area 376.7 Signall?mV] 200 Mean Conc. 48.84mg/L WI 140 br?q.?Time[min] 25/43 57/63 REVISED REPORT PSW 3l19/2014 2:37:35 PM Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.mel Status Completed Chk. Result Type Anal. Dll. Result lUnknown NPOC 1.000 1. Del Anal; NPOC Area Date I Time 49. . 12:3612:39: AM .2 1 Mean Area 377.4 Signal[mV] Mean Conc, 48.93mglL Time[min] 38l43 58/63 REVISED REPORT Analytical Blank Summary Form 3 Analytical Batch: INO3016 Units: mg/L Instrument: TOC1 Analyst: PSW Results by SW-846 9060A 132764 03/18/14 00:17 Dissolved Organ Total Organic Ca 132768 03/18/14 16:25 132770 03/18/14 20:45 132778 03/18/14 20:45 1.00U 1.00U 1.00U 132779 03/19/14 00:53 1.00U 1.00U Print Date: 04/10/2014 N.C. Certification # 481 59/63 REVISED REPORT PSW 311912014 2:37:35 PM Sample Sample Name: CBV SamplelD: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result NPOC 1.000 1. Del Anal.: NPOC No. Area Vol. Aut. .Curve Dil57.ca 03 O4 51 .cal 03 04 Mean Area 2.008 Signal[mV] 10 Mean Conc. 0.2604mg/L 4K 6 3aTime[min] 3/43 60/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Walers.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal; NPOC 7N0. Area Conc. lnj. Vol. Aut. Ex. Cal.Curve Date/Time Dil. 1 5.089 0.6598mg/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/2014 4:25:05 PM 2 1.923 0.2493mg/L 100uL 1 030414W2014 03 04 13 51 57.cal 3/18/2014 4:27:08 PM 3 1.512 0.1960mg/L 100uL 1 030414W.2014 03 04 13 51 57.cal 3/18/2014 4:29:12 PM 4 1.512 '1 0.1960mg/L 100uL 1 030414W.2014 03 04 13 51 57.cal /18/2014 4:31:15 PM 5 2.904 I 0.3765mg/L 100uL 1 30414W.2014 03 04 13 51 57.cal /18/20144:34:07 PM Mean Area 1.963 Signal[mV] 10 Mean Conc. 0.2545mgTimeImin] 15/43 61/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM IN03016.132 Sample Sample Name: CBV SamplelD: Origin: 9050A_TOC1_Waters.me1 Status Completed Chk. Result Type Anal. Dil. Result ll?Jnknown POC 1.000 1. Del No. Area . . Date/Time . .2014 3 51 .cal 18/2014 8: :4 2.94 .2014 .2014 13 51 .cal 1 148: :1 PM 3.21 . 13 51 57.ca 14 :57: PM Mean Area 3.141 Signa [mv1 10 Mean Conc. 0.4072mg/L 01W 6 A baTimeImin] 27/43 62/63 REVISED REPORT PSW 3/19/2014 2:37:35 PM N03016.t32 Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal; NPOC No. Date Time 1 . 4 :4 .938 . 4W.20 . 12. AM .330 . 4W.20 . 12: 2 AM .443 . 4W.20 46 . 14W. Mean Area 3.114 SignaumV] 10 Mean Conc. 0.4038mglL NJ - 6 34'1Time[min] 39/43 63/63 REVISED REPORT Laboratory Report of Analysis To: Delaney Peterson ANCHOR ENVIRONMENTAL 720 Olive Way Suite 1900 Seattle, WA 98101 US Report Number: 31400395 Client Project: Patrick Bayou Superfund Site Dear Delaney Peterson, Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Amy J. Boehm at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you again on any additional analytical needs. Sincerely, SGS North America Inc. __________________________________________________________________ Jeannie Milholland Date QA Director jeannie.milholland@sgs.com Print Date: 04/11/2014 N.C. Certification # 481 1/65 REVISED REPORT Laboratory Qualifiers Report Definitions DL Method, Instrument, or Estimated Detection Limit per Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions * Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) V Recovery is below quality control limit. The data has been validated based on a favorable signal-to-noise A Amount detected is less than the Lower Method Calibration Limit J Estimated Concentration. O The recovery of this analyte in the OPR is above the Method QC Limits and the reported concentration in E Amount detected is greater than the Upper Calibration Limit S The amount of analyte present has saturated the detector. This situation results in an Q Indicates the presence of a quantitative interference. This situation may result in an I Indicates the presence of a qualitative interference that could cause a false positive or an DPE Indicates the presence of a peak in the polychlorinated diphenylether channel that could TIC Tentatively Identified Compound and detection limit the sample may be biased high underestimation of the affected analyte(s) underestimation of the affected analyte(s) overestimation of the affected analyte(s) cause a false positive or an overestimation of the affected analyte(s) EMPC Estimated Maximum possible Concentration due to ion ratio failure ND Not Detected K Result is estimated due to ion ratio failure in High Resolution PCB Analysis P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code definition is provided below: M1 Mis-identified peak Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Print Date: 04/11/2014 N.C. Certification # 481 2/65 REVISED REPORT Sample Summary Client Sample ID Lab Sample ID Collected PB070_B-2SWMID-140314-N PB070_B-1SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB089-1SWMID-140314-N PB085-1SWMID-140314-N PB097A-1SWMID-140314-N 31400395001 31400395002 31400395003 31400395004 31400395005 31400395006 31400395007 03/14/2014 03/14/2014 03/14/2014 03/14/2014 03/14/2014 03/14/2014 03/14/2014 Print Date: 04/11/2014 Received 09:10 13:15 14:00 13:45 17:25 16:54 17:54 03/15/2014 03/15/2014 03/15/2014 03/15/2014 03/15/2014 03/15/2014 03/15/2014 Matrix 10:30 10:30 10:30 10:30 10:30 10:30 10:30 Water Water Water Water Water Water Water N.C. Certification # 481 3/65 REVISED REPORT Case Narrative 9060A ­ Samples for analysis of DOC were filtered and preserved immediately upon receipt per SGS SOP. On March 19, 2014 per client request the DOC analyses for sample PB097_A was placed on hold. The DOC result for sample PB081_A­1SWMID­140314­N s are greater than the TOC results. The higher DOC result may be due to the sampling process, the particular push filters that were used or the elapsed time from sampling to receipt and processing at the lab. 2540­D ­ Revised report to J flag TSS results down to the MDL in order to meet the reporting limit requirements of the SAP for this project. Print Date: 04/08/2014 N.C. Certification # 481 4/65 REVISED REPORT Detectable Results Summary Client Sample ID: PB070_B-2SWMID-140314-N Lab Sample ID: 31400395001-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB070_B-1SWMID-140314-N Lab Sample ID: 31400395002-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB079-1SWMID-140314-N Lab Sample ID: 31400395003-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB081_A-1SWMID-140314-N Lab Sample ID: 31400395004-C Parameter Dissolved Organic Carbon SW-846 9060A Result Total Organic Carbon 9.99 9.44 13.7 26.3 16.2 Client Sample ID: PB089-1SWMID-140314-N Lab Sample ID: 31400395005-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB085-1SWMID-140314-N Lab Sample ID: 31400395006-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB097A-1SWMID-140314-N Lab Sample ID: 31400395007-A Parameter Total Organic Carbon SW-846 9060A Result Print Date: 04/11/2014 14.9 15.4 10.3 Units mg/L Units mg/L Units mg/L Units mg/L mg/L Units mg/L Units mg/L Units mg/L N.C. Certification # 481 5/65 REVISED REPORT 2191, vs; 016 I met 09: 0L6 sovaz 3N ?um?uwum enua ssewsna 0095 saamuas 1V1N3WNOHIAN3 ?nmvaluawv 40 959d "if salon I .X 9?25}! uamwn . f7] 3A8 aamaoau iawu BLVD ?ma aaHsmoNnau Naxoaagjj - 2 95.9 mm r: Siva - we: =awu m: (IEIHSI 33/0 3110:) II I :9 A515 ?7?77 (7556057 11 1 5 .4 I759 hI/hlli 9 gm .7 ?zci MA MA ?ll/hull 'Ila/C? If: [9 WV) .9 H/?hys 1 mlhI/E i 5 9m .9 00H W-h/SObl? I 9 gm -9 915/ rv-h/sOhI-orwm -I shadow 4 I 9 9m .9 9159 N?htfoh! - Ga? sxuvwau ?g AllWar M100.) '11vwa :03 - . . #5277 [9/5 ?85 7/90?? =ssaucrav .JB 1 5 ?7 7/Vd 3A - qOLj - N, GONE 6] 1-3 i 03 samvuamaa 03 t; :3 3 Allemaenlamm (awe/~61 685) 3131\31 a .g a s? egg?2:92 702 M?msmm anuvnuasaud .7075 Q75 715? $5207 m' 00211.: ssauaav ammo 96 SM) (1: ??75-?77?74 pd lavmoo 0a (7/30 fad? (ml? 9? 1'9 UNHS 7L 5 a 0-1le ?8 I NIVHD .D?sm REVISED REPORT SGS North America Inc. Sample Receipt Checklist (SRC) Client: Anchor Environmental Work Order No.: 31400395 1. LShipped Notes: Hand Delivered 2. COC Present on Receipt No coc :Additional Transmittal Forms 3. Custody Tape on Container No Custody Tape 4. Samples Intact Samples Broken Leaking 5. Chilled on Receipt Actual Temp.(s) in 1.4 Thermometer lD#: Login-1D :Ambient on Receipt Walk-in on Ice; Coming down to temp. :Temperature Blank Present 6. Sufficient Sample Submitted Insufficient Sample Submitted 7. Chlorine absent Additional Preservatives veri?ed (see notes) 8. Received Within Holding Time :Not Received Within Holding Time 9. Discrepancies Noted Discrepancies Noted notified of Discrepancies* 10. No Headspace present in VOC vials :Headspace present in VOC vials >6mm Comments: Inspected and Logged in by: RCH Date: Mon-3H 7/14 00:00 7/65 must be notified when collection, holding time or preservation requirements are not met. ?l .7 REVISED REPORT SM 2540-D Sample Data Print Date: 04/11/2014 N.C. Certification 481 55111] Business US - EMDE-Wilmirmnn. ME IN 3103-51] 1903 1+1 310350155? wan-.595 cum 8/65 LII 1hr SEE SIM REVISED REPORT Results of PB070_B-2SWMID-140314-N Client Sample ID: PB070_B-2SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395001-C Lab Project ID: 31400395 Collection Date: 03/14/2014 09:10 Received Date: 03/15/2014 10:30 Matrix: Water Results by SM 2540-D Parameter Result Total Suspended Solids 18.0 Qual J DL 3.60 LOQ/CL 25.0 Units mg/L DF 1 Date Analyzed 03/21/2014 14:59 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 14:59 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 9/65 REVISED REPORT Results of PB070_B-1SWMID-140314-N Client Sample ID: PB070_B-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395002-C Lab Project ID: 31400395 Collection Date: 03/14/2014 13:15 Received Date: 03/15/2014 10:30 Matrix: Water Results by SM 2540-D Parameter Result Total Suspended Solids 19.0 Qual J DL LOQ/CL 3.60 25.0 Units DF mg/L Date Analyzed 1 03/21/2014 15:00 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 15:00 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 10/65 REVISED REPORT Results of PB079-1SWMID-140314-N Client Sample ID: PB079-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395003-C Lab Project ID: 31400395 Collection Date: 03/14/2014 14:00 Received Date: 03/15/2014 10:30 Matrix: Water Results by SM 2540-D Parameter Result Qual Total Suspended Solids 18.0 J DL 3.60 LOQ/CL 25.0 Units mg/L DF 1 Date Analyzed 03/21/2014 15:00 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 15:00 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 11/65 REVISED REPORT Results of PB081_A-1SWMID-140314-N Client Sample ID: PB081_A-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395004-E Lab Project ID: 31400395 Collection Date: 03/14/2014 13:45 Received Date: 03/15/2014 10:30 Matrix: Water Results by SM 2540-D Parameter Result Qual Total Suspended Solids 8.0 J DL 3.60 LOQ/CL 25.0 Units DF mg/L 1 Date Analyzed 03/21/2014 15:00 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 15:00 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 12/65 REVISED REPORT Results of PB089-1SWMID-140314-N Client Sample ID: PB089-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395005-C Lab Project ID: 31400395 Collection Date: 03/14/2014 17:25 Received Date: 03/15/2014 10:30 Matrix: Water Results by SM 2540-D Parameter Result Total Suspended Solids 12.0 Qual J DL 3.60 LOQ/CL 25.0 Units mg/L DF 1 Date Analyzed 03/21/2014 15:00 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 15:00 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 13/65 REVISED REPORT Results of PB085-1SWMID-140314-N Client Sample ID: PB085-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395006-C Lab Project ID: 31400395 Collection Date: 03/14/2014 16:54 Received Date: 03/15/2014 10:30 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 8.0 J 3.60 25.0 mg/L 1 03/21/2014 15:00 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 15:00 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 14/65 REVISED REPORT Results of PB097A-1SWMID-140314-N Client Sample ID: PB097A-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395007-D Lab Project ID: 31400395 Collection Date: 03/14/2014 17:54 Received Date: 03/15/2014 10:30 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 19.0 J 3.60 25.0 mg/L 1 03/21/2014 15:00 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 15:00 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 15/65 REVISED REPORT 55??Busineswrive Total Suspended Solids Wilmington, NC 28405 SM 2540 Batch: INC 3026 Balance: BAL10 In Oven Date: 312112014 Analyst: DTF Oven: Oven #6 ln Oven Time: 15:00 StandardlD: TSA15 In Oven Temp: 105 Out Oven Date: 312412014 Out Oven Temp: 105 Out Oven Time: 9:00 Vol Filte Analyzed Filter Final Result Type Lab ID mL Lot Date Time 9 SAMPLE 132950 100 inv26 0312112014 14:59 0.1221 0.1220 -1 SAMPLE 132951 25 inv26 0312112014 14:59 0.1231 0.1343 448 SAMPLE 31400395001 100 inv26 0312112014 14:59 0.1183 0.1201 18 SAMPLE 132952 100 inv26 0312112014 14:59 0.1240 0.1261 21 SAMPLE 31400395002 100 inv26 0312112014 15:00 0.1241 0.1260 19 SAMPLE 31400395003 100 inv26 0312112014 15:00 0.1189 0.1207 18 SAMPLE 31400395004 100 inv26 0312112014 15:00 0.1225 0.1233 8 SAMPLE 31400395005 100 inv26 0312112014 15:00 0.1238 0.1250 12 SAMPLE 31400395006 100 inv26 0312112014 15:00 0.1205 0.1213 8 SAMPLE 31400395007 100 inv26 0312112014 15:00 0.1224 0.1243 19 SAMPLE 31400411001 100 inv26 0312112014 15:00 0.1197 0.1208 11 3/21/15" Analyst Signature Date ?ewewcd ?y Analyst signature indicates that the data printed is a true representation 4 of volumes and weights encountered in the analytical process. Weights are obtained through overnight drying at 1050. 344141, (F2 - F1) 1.000.000 The calculation of T88 is: TSS V1 Where: F2 Final (9) F1 Filter(g) Printed: 312412014 9:28:47 AM V1 Vol (mL) 1 of1 Pages 16/65 REVISED REPORT SM 2540-D QC, Blanks Data Print Date: 04/11/2014 N.C. Certification # 481 17/65 REVISED REPORT Batch Summary Analytical Method: SM 2540-D Prep Method: Prep Batch: Prep Date: SM 2540-D INO3026 03/21/2014 14:59 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41520 [INO/3026] 132950 03/21/2014 14:59 INO3026 BAL10 DTF LCS for HBN 41520 [INO/3026] 132951 03/21/2014 14:59 INO3026 BAL10 DTF PB070_B-2SWMID-140314-N 31400395001 03/21/2014 14:59 INO3026 BAL10 DTF PB070_B-2SWMID-1...(132394DUP) 132952 03/21/2014 14:59 INO3026 BAL10 DTF PB070_B-1SWMID-140314-N 31400395002 03/21/2014 15:00 INO3026 BAL10 DTF PB079-1SWMID-140314-N 31400395003 03/21/2014 15:00 INO3026 BAL10 DTF PB081_A-1SWMID-140314-N 31400395004 03/21/2014 15:00 INO3026 BAL10 DTF PB089-1SWMID-140314-N 31400395005 03/21/2014 15:00 INO3026 BAL10 DTF PB085-1SWMID-140314-N 31400395006 03/21/2014 15:00 INO3026 BAL10 DTF PB097A-1SWMID-140314-N 31400395007 03/21/2014 15:00 INO3026 BAL10 DTF Print Date: 04/11/2014 N.C. Certification # 481 18/65 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41520 [INO/3026] Blank Lab ID: 132950 Prep Batch: INO3026 Matrix: Water Analysis Date/Time: 03/21/2014 14:59 Results by SM 2540-D Client Sample ID Lab Sample ID LCS for HBN 41520 [INO/3026] PB070_B-2SWMID-140314-N Date Analyzed Analyst 132951 03/21/2014 14:59 DTF 31400395001 03/21/2014 14:59 DTF PB070_B-2SWMID-1...(132394DUP) 132952 03/21/2014 14:59 DTF PB070_B-1SWMID-140314-N 31400395002 03/21/2014 15:00 DTF PB079-1SWMID-140314-N 31400395003 03/21/2014 15:00 DTF PB081_A-1SWMID-140314-N 31400395004 03/21/2014 15:00 DTF PB089-1SWMID-140314-N 31400395005 03/21/2014 15:00 DTF PB085-1SWMID-140314-N 31400395006 03/21/2014 15:00 DTF PB097A-1SWMID-140314-N 31400395007 03/21/2014 15:00 DTF Print Date: 04/11/2014 Filename N.C. Certification # 481 19/65 REVISED REPORT Method Blank Blank ID: MB for HBN 41520 [INO/3026] Blank Lab ID: 132950 Matrix: Water QC for Samples: 31400395001, 31400395002, 31400395003, 31400395004, 31400395005, 31400395006, 31400395007 Results by SM 2540-D Parameter Result Total Suspended Solids ND Qual DL LOQ/CL Units DF 3.60 25.0 mg/L 1 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 3/21/2014 2:59:46PM Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 20/65 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41520 [INO/3026] Blank Spike Lab ID: 132951 Date Analyzed: 03/21/2014 14:59 Matrix: Water QC for Samples: 31400395001, 31400395002, 31400395003, 31400395004, 31400395005, 31400395006, 31400395007 Results by SM 2540-D Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Suspended Solids 500 448 90 80.0-120 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 14:59 Spike Init Wt./Vol.: 1 mL Extract Vol: 1 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 21/65 REVISED REPORT Duplicate Sample Summary Original Sample ID: 31400395001-C Duplicate Sample ID: 132952 QC for Samples: Analysis Date: 03/21/2014 14:59 Analysis Date: 03/21/2014 14:59 Matrix: Water 31400395001, 31400395002, 31400395003, 31400395004, 31400395005, 31400395006, 31400395007 Results by SM 2540-D PARAMETER Original (mg/L) Qual Total Suspended Solids 18.0 J Duplicate (mg/L) 21.0 Qual RPD (%) RPD CL J 15.4 20.00 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Print Date: 04/25/2014 N.C. Certification # 481 22/65 REVISED REPORT SW-846 9060A Sample Data Print Date: 04/11/2014 N.C. Certification # 481 23/65 REVISED REPORT Results of PB070_B-2SWMID-140314-N Client Sample ID: PB070_B-2SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395001-A Lab Project ID: 31400395 Collection Date: 03/14/2014 09:10 Received Date: 03/15/2014 10:30 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 9.99 Units mg/L DF 1 Date Analyzed 03/18/2014 18:14 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 18:14 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 24/65 REVISED REPORT PSW 31190014 2:37:35 PM Sample Sample Name: 0395_1 Sample lD: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Li NPOC 1.000 1. Del Anal.: NPOC Area . . Curve 78 10 .cal 7 . 9. O4 1 1 .cal 76. 9.87 03 04 5 57.cal 77.5 10. O4 1 Mean Area 77.08 Signal[mV] Mean Conc. 9.994mg/L 41Time[min] 20/43 25/65 REVISED REPORT Results of PB070_B-1SWMID-140314-N Client Sample ID: PB070_B-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395002-A Lab Project ID: 31400395 Collection Date: 03/14/2014 13:15 Received Date: 03/15/2014 10:30 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 9.44 Units mg/L DF 1 Date Analyzed 03/18/2014 18:36 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 18:36 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 26/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM 1N03016.t32 Sample Sample Name: 0395_2 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1,000 1: Det Anal: NPOC No. Area . Time . 6:40: 7 . 9. 14 . 6:43:14 7 .05 9.471 14W . 6:46:09 PM Mean Area 72.83 SignaumV] Mean Conc. 9.443mg/L (W 34Time[min] 21/43 27/65 REVISED REPORT Results of PB079-1SWMID-140314-N Client Sample ID: PB079-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395003-A Lab Project ID: 31400395 Collection Date: 03/14/2014 14:00 Received Date: 03/15/2014 10:30 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 13.7 Units mg/L DF 1 Date Analyzed 03/18/2014 18:58 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 18:58 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 28/65 REVISED REPORT PSW 3119/2014 2:37:35 PM lNO3016.t32 Sample Sample Name: 0395_3 SamplelD: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Re5ult Type Anal. Dil. Result @nknown NPOC 1.000 1. Del Anal.: NPOC No. Area Cal. Date! 1 .2 . 1 03 .cal :57. 47. 1:57.ca 1 :04:57. Mean Area 105.9 Signal[mV] 40 Mean Conc. 13.73mgTime[min] 22/43 29/65 REVISED REPORT Results of PB081_A-1SWMID-140314-N Client Sample ID: PB081_A-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395004-C Lab Project ID: 31400395 Collection Date: 03/14/2014 13:45 Received Date: 03/15/2014 10:30 Matrix: Water Results by SW-846 9060A Parameter Dissolved Organic Carbon Total Organic Carbon Result Qual LOQ/CL 1.00 1.00 26.3 16.2 Units mg/L mg/L DF 1 1 Date Analyzed 03/19/2014 0:14 03/18/2014 19:20 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 19:20 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 03/19/2014 00:14 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 30/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM N03016.t32 Sample Sample Name: 03914 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dll. Result Unknown NPOC 1.000 1. Det Ana .: NPOC N0. Area 03 W.2014 03 .2014 100u 4W.2014 Mean Area 202.5 Signal[mV] 80 Mean Conc. 26.25mg/L6kw 60 40 squl Time[min] 37/43 31/65 REVISED REPORT PSW 3l19l2014 2:37:35 PM 1N03016.t32 Sample Sample Name: 0395_4 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result I Type Anal. Dil. Result I 1 Unknown NPOC 1.000 I 1. Det Anal.: NPOC Area 57. . 1 57.ca 5. 4 1 57.631 6.4 1 5 57.ca Mean Area 125.1 Signa [mV] Mean Conc. 16.22mglL Time[min] 23/43 32/65 REVISED REPORT Results of PB089-1SWMID-140314-N Client Sample ID: PB089-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395005-A Lab Project ID: 31400395 Collection Date: 03/14/2014 17:25 Received Date: 03/15/2014 10:30 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 14.9 Units mg/L DF 1 Date Analyzed 03/18/2014 19:42 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 19:42 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 33/65 REVISED REPORT PSW 3/19l2014 2:37:35 PM N03016.t32 Sample Sample Name: 0395_5 Sample ID: Origin: Status Completed Chk. Result 1 Type Anal. Dil. Resull I annown NPOC 1.000 1. Det Anal: NPOC No. ea 3 16-.3 15: 14.1 14. 15. 14 Mean Area 115.1 Signal[mV] Mean Conc. 14.92mgTime[min] 24/43 34/65 REVISED REPORT Results of PB085-1SWMID-140314-N Client Sample ID: PB085-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395006-A Lab Project ID: 31400395 Collection Date: 03/14/2014 16:54 Received Date: 03/15/2014 10:30 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 15.4 Units mg/L DF 1 Date Analyzed 03/18/2014 20:03 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 20:03 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 35/65 REVISED REPORT PSW 3119/2014 2:37:35 PM Sample Sample Name: 0395_6 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dll. Re3ult Unknown POC 1000' 1. Det Ana .: NPOC No. Area . Cal. Curve 5.4 3041 . 03 Mean Area 118.5 Signal[mV] Mean Conc. 15.36mgTime[min] 25l43 36/65 REVISED REPORT Results of PB097A-1SWMID-140314-N Client Sample ID: PB097A-1SWMID-140314-N Client Project ID: Patrick Bayou Superfund Site Lab Sample ID: 31400395007-A Lab Project ID: 31400395 Collection Date: 03/14/2014 17:54 Received Date: 03/15/2014 10:30 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 10.3 Units mg/L DF 1 Date Analyzed 03/18/2014 21:08 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 21:08 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 37/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 0395_7 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dll. Result Unknown POC 1.000 1. Det Anal: NPOC NO. .2 14 57. 10. .2014 51 57.cal 10 .2014 51 57. 10. .2014 51 57.ca Mean Area 79.67 Signa ImV1 40 Mean Conc. 10.33mglL Time[min] 28/43 38/65 REVISED REPORT SW-846 9060A QC, Blanks Data Print Date: 04/11/2014 N.C. Certification # 481 39/65 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3016 03/18/2014 00:53 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41460 [INO/3016] 132565 03/18/2014 00:53 INO3016 TOC1 PSW LCS for HBN 41460 [INO/3016] 132566 03/18/2014 13:11 INO3016 TOC1 PSW PB006.2-1SWMID-14...(132120MS) 132567 03/18/2014 13:49 INO3016 TOC1 PSW PB006.2-1SWMID-1...(132120MSD) 132568 03/18/2014 14:09 INO3016 TOC1 PSW PB070_B-2SWMID-140314-N 31400395001 03/18/2014 18:14 INO3016 TOC1 PSW PB070_B-1SWMID-140314-N 31400395002 03/18/2014 18:36 INO3016 TOC1 PSW PB079-1SWMID-140314-N 31400395003 03/18/2014 18:58 INO3016 TOC1 PSW PB081_A-1SWMID-140314-N 31400395004 03/18/2014 19:20 INO3016 TOC1 PSW PB089-1SWMID-140314-N 31400395005 03/18/2014 19:42 INO3016 TOC1 PSW PB085-1SWMID-140314-N 31400395006 03/18/2014 20:03 INO3016 TOC1 PSW PB097A-1SWMID-140314-N 31400395007 03/18/2014 21:08 INO3016 TOC1 PSW PB097A-1SWMID-14...(132401DUP) 132569 03/18/2014 21:28 INO3016 TOC1 PSW Print Date: 04/11/2014 N.C. Certification # 481 40/65 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41460 [INO/3016] Blank Lab ID: 132565 Prep Batch: INO3016 Matrix: Water Analysis Date/Time: 03/18/2014 00:53 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst LCS for HBN 41460 [INO/3016] 132566 INO3016.csv 03/18/2014 13:11 PSW PB006.2-1SWMID-14...(132120MS) 132567 INO3016.csv 03/18/2014 13:49 PSW PB006.2-1SWMID-1...(132120MSD) 132568 INO3016.csv 03/18/2014 14:09 PSW CBV for HBN 41460 (INO/3016) 132768 INO3016.csv 03/18/2014 16:25 PSW PB070_B-2SWMID-140314-N 31400395001 INO3016.csv 03/18/2014 18:14 PSW PB070_B-1SWMID-140314-N 31400395002 INO3016.csv 03/18/2014 18:36 PSW PB079-1SWMID-140314-N 31400395003 INO3016.csv 03/18/2014 18:58 PSW PB081_A-1SWMID-140314-N 31400395004 INO3016.csv 03/18/2014 19:20 PSW PB089-1SWMID-140314-N 31400395005 INO3016.csv 03/18/2014 19:42 PSW PB085-1SWMID-140314-N 31400395006 INO3016.csv 03/18/2014 20:03 PSW CBV for HBN 41460 (INO/3016) 132770 INO3016.csv 03/18/2014 20:45 PSW PB097A-1SWMID-140314-N 31400395007 INO3016.csv 03/18/2014 21:08 PSW PB097A-1SWMID-14...(132401DUP) 132569 INO3016.csv 03/18/2014 21:28 PSW CBV for HBN 41460 (INO/3016) 132772 INO3016.csv 03/19/2014 00:53 PSW Print Date: 04/11/2014 N.C. Certification # 481 41/65 REVISED REPORT Method Blank Blank ID: MB for HBN 41460 [INO/3016] Blank Lab ID: 132565 Matrix: Water QC for Samples: 31400395001, 31400395002, 31400395003, 31400395004, 31400395005, 31400395006, 31400395007 Results by SW-846 9060A Parameter Result Total Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 3/18/2014 12:53:41AM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 42/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 132565 MB Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk? Result A Type Anal. Dil. Result lUnknown NPOC 1.000 1. Del Anal.: NPOC No. Area . . Date Time Mean Area 1.710 Signal[mV] 10 Mean Conc. 0.2217mg/L mm 3?qvTimeImin] 5/43 43/65 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41460 [INO/3016] Blank Spike Lab ID: 132566 Date Analyzed: 03/18/2014 13:11 Matrix: Water QC for Samples: 31400395001, 31400395002, 31400395003, 31400395004, 31400395005, 31400395006, 31400395007 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Organic Carbon 50.0 48.6 97 90.0-110 Batch Information Analytical Batch: INO3016 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3016 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 13:11 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 44/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sampie Name: 132566 LCS Sample Origin: 9060A_TOC1_Waters.met Status Comp1eted Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Ana .: NPOC No. Area Conc. lnj. Vol. Aut. Ex. Cal. Curve Date/Time Oil. 1 371.4 48.15mq/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/20141:11:11 PM 2 375.9 48.74mg/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/2014 1:14:03 PM 3 371.8 48.21mg/L 100uL 1 030414W.2014 03 04 13 51 57.cal 3/18/20141216251 PM 379.5 49.20mg/L 100uL 1 030414W.2014 O3 04 13 51 57.ca 3/18/2014 1:19:42 PM Mean Area 374.7 Signal[mV] 200 Mean Conc. 48.57mg/L 5 140 341Time[min] 6/43 45/65 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3017 03/18/2014 21:49 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB-F1 for HBN 41461 [INO/3017] 132570 03/18/2014 21:49 INO3017 TOC1 PSW LCS for HBN 41461 [INO/3017] 132571 03/18/2014 22:12 INO3017 TOC1 PSW PB006.2-1SWMID-14...(132121MS) 132572 03/18/2014 22:52 INO3017 TOC1 PSW PB006.2-1SWMID-1...(132121MSD) 132573 03/18/2014 23:12 INO3017 TOC1 PSW PB081_A-1SWMID-140314-N 31400395004 03/19/2014 00:14 INO3017 TOC1 PSW Print Date: 04/11/2014 N.C. Certification # 481 46/65 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB-F1 for HBN 41461 [INO/3017] Blank Lab ID: 132570 Prep Batch: INO3017 Matrix: Water Analysis Date/Time: 03/18/2014 21:49 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41461 (INO/3017) 132778 INO3017.csv 03/18/2014 20:45 PSW LCS for HBN 41461 [INO/3017] 132571 INO3017.csv 03/18/2014 22:12 PSW PB006.2-1SWMID-14...(132121MS) 132572 INO3017.csv 03/18/2014 22:52 PSW PB006.2-1SWMID-1...(132121MSD) 132573 INO3017.csv 03/18/2014 23:12 PSW PB081_A-1SWMID-140314-N 31400395004 INO3017.csv 03/19/2014 00:14 PSW CBV for HBN 41461 (INO/3017) 132779 INO3017.csv 03/19/2014 00:53 PSW Print Date: 04/11/2014 N.C. Certification # 481 47/65 REVISED REPORT Method Blank Blank ID: MB-F1 for HBN 41461 [INO/3017] Blank Lab ID: 132570 Matrix: Water QC for Samples: 31400395004 Results by SW-846 9060A Parameter Result Dissolved Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 3/18/2014 9:49:14PM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 48/65 REVISED REPORT RSW 3119/2014 2:37:35 PM 1N03016.l32 Sample Sample Name: 132570 MB-F1 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result lUnknown NPOC 1.000 1. Det Anal: NPOC No. Area lnj. Vol. Aut. Cal. Curve Dil2.834 . 4W 03 04 1 57 2.839 . 4W. 03 04 1 57.cal 3.525 . 4 03 04 1 7.ca 2. . 14W 4 03 Mean Area 3.010 ?10 Mean Conc. 0.3902mglL 6 34?1Time[min] 30l43 49/65 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41461 [INO/3017] Blank Spike Lab ID: 132571 Date Analyzed: 03/18/2014 22:12 Matrix: Water QC for Samples: 31400395004 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Dissolved Organic Carbon 50.0 49.1 98 90.0-110 Batch Information Analytical Batch: INO3017 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3017 Prep Method: SW-846 9060A Prep Date/Time: 03/18/2014 22:12 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 50/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: 132571 LCS Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Ana .: NPOC Area Date Time .cal PM 3843 9. . 3 51 57.cal 114:52 PM 375.9 .7 . 13 51 57.cal 10:17:42 PM 332. . 1 13 51 57 10:20:30 PM Mean Area 379.0 Signal[mV] 200 . . Mean Conc, 49.14mgTimeImin] 31/43 51/65 REVISED REPORT SW-846 9060A Prep, Standard, Run Logs Print Date: 04/11/2014 N.C. Certification # 481 52/65 Method: Matrix: Initial Cal. Curve: 9060 Water ICAL-030414W SGS Environmental Services TOC Runlog Sheet Batch: Primary Lot#: D-437 Secondary Lot#: D-455 30/7 SAMPLE ID DILUTION DATE TIME OPER QC pH Comments ICV 3/18/201411155 PSW CBV 3/18/201412:17 PSW NEG 3/18/201412235 PSW [132565 MB 3/18/201412:53 PSW 132566 LCS PSW o373_1 3/18/201413130 PSW 132567 MS 3/18/2014 13:49 PSW 132568 3/18/201414209 PSW bd/bb 0373_2 3/18/201414130 PSW 0373_3 3/18/201414252 PSW 0389_1 0389_2 3/18/201415118 PSW 3/18/201415241 PSW 30% 3/18/201416103 PSW 3/18/201416225 PSW 0389_3 3/18/201416246 PSW 3/18/201417207 PSW 0389_4 I 0389_5 3/18/201417:29 PSW 0389_6 3/18/201417251 PSW o395_1 3/18/201418214 PSW o395_2 3/18/201418236 PSW o395_3 3/18/201418158 PSW K, Analyst: REVISED REPORT Method: Matrix: Initial Cal. Curve: 9060 Water ICAL-030414W 868 Environmental Services TOC Runlog Sheet Batch: IN03016 Primary Lot#: Secondary Lot#: 0455 SAMPLE ID DILUTION DATE TIME OPER QC pH Comments 0395_4 3/18/2014 19:20 PSW 0395_5 3/18/2014 19:42 PSW 0395_5 3/18/2014 20:03 PSW ICV 3/18/2014 20:24 PSW 3/18/2014 20:45 PSW 3/18/2014 21:08 PSW @2559 DUP 3/18/2014 21:28 PSW 132570 3/18/2014 21:49 PSW 54 65 132571 LCS 3/18/2014 22:12 PSW 0373_2 3/18/2014 22:32 PSW REVISE I) RE 132572 MS 3/18/2014 22:52 PSW @031?? 132573 MSD 3/18/2014 23:12 PSW o373__1 3/18/2014 23:33 PSW 0389_4 3/18/2014 23:53 PSW 0395_4 3/19/2014 0:14 PSW ICV 3/19/2014 0:33 PSW CBV 3/19/2014 0:53 PSW 0395_7 Sling/e 3/19/20141215 PSW 132574 DUP 3/19/20141135 PSW ICV 3/19/20141256 PSW CBV - 1'05 3/19/2014 2:16 PSW Analyst: REVISED REPORT SW-846 9060A Initial Calibration Data Print Date: 04/11/2014 N.C. Certification # 481 55/65 REVISED REPORT PSW 3/4/2014 4:35:34 PM 030414W.t32 Cal. Curve Sample Name: Untitled Sample ID: Untitled Cal. Curve: Status Completed Type Anal. 'DStandard NPOC Conc: 100.0mg/L No. Area nj.Vol. Aut. Rem. Ex. Date/Time Dil. 1 778.3 100uL 1 3/4/2014 2:00:59 PM 2 774.6 100uL 1 3/4/2014 2:06:27 PM 3 776.1 100uL 1 3/4/2014 2:11:52 PM 4 769.8 100uL 1 3/4/2014 2:17:17 PM Acid Add. 1.500% SignalImV] 400 . . Sp. Time 90.005ec 300 1 MeanArea 774.7 1/ fle 200 75 1 3,54Time[min] Conc: 50.00mg/L No. Area In]. Vol. . . Date Time :27. 2: :3 4/2014 2:43:10 PM Acid Add. 1.500% Signal[mV] 200 Sp. Time 90.00513} Mean Area 381.1 140 3:64Time[min] Conc: 10.00mg/L No. Area . . . DateAcid Add. 1.500% Signal[mV] 20 Sp. Time 90.005ec Mean Area 75.Time[min] 'Conc: 1.000mg/L Area 1 .2 14 3:22:03 PM 10.27 14 3:26:47 PM 10.29 14 3:31: PM 2/3 56/65 REVISED REPORT PSW 31'4/2014 4:35:34 PM 030414W.132 ACidAdd. 1.500% 10 Sp. Time 90.0058C Mean Area 10.26 6 HM #3541 Time[min] Conc: 0.5000mg/L No. Area DatelTime iti??ti 43. 6118 until 6.095 1 4/20143: .1PM 5.719 1 4 - pm 5.93? 1 4 . PM AcidAdd. 1.500% 10 Sp. Time 90.005ec MeanArea 6.108 6 ml 3,547 Time[min] Conc: 0.000mg/L No. Area In]. Vol. Aut. Rem. Ex. DatelTime 1.725 . 1. 4: . :1614 PM 1.572 1 PM AcidAdd. 1.500% Signa [mV] 10 Sp. Time 90.0059c MeanArea 1.646 Time[min] 7-713 Area 852.17 Intercept 0.000 r?2 0.999906 . 0999953 500 Zero Shl100110 Conc[mg/L] 3/3 57/65 REVISED REPORT SW-846 9060A Continuing Calibration Data Print Date: 04/11/2014 N.C. Certification # 481 58/65 REVISED REPORT PSW 3719/2014 2:37:35 PM Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Ana .: NPOC Area Cal. Curve Date I Time 9.0 . 04 3 . :17 377.2 .91 . 03 04 :06:12 PM 373.1 48.37 4W 1 03 04 108159 375. 48.67 03 04 :11:44 PM Mean Area 373.7 Sig na [mV] Mean Conc. 48.45mglL Time[min] 14/43 59/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Samp1e Name: ICV SampIe ID: Origin: 9060A_TOC1_Waters.met Status Comp1eted Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal.: NPOC No. Cal. Curve Date 13 5 381.6 14W.2014 03 04 8:27:32 PM 3760 14W.2014 0 1 4 8:30:23 PM 379.7 14W.2014 03 14 8:33:10 PM Mean Area 376.7 Signall?mV] 200 Mean Conc. 48.84mg/L WI 140 br?q.?Time[min] 25/43 60/65 REVISED REPORT PSW 3l19/2014 2:37:35 PM Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.mel Status Completed Chk. Result Type Anal. Dll. Result lUnknown NPOC 1.000 1. Del Anal; NPOC Area Date I Time 49. . 12:3612:39: AM .2 1 Mean Area 377.4 Signal[mV] Mean Conc, 48.93mglL Time[min] 38l43 61/65 REVISED REPORT Analytical Blank Summary Form 3 Analytical Batch: INO3016 Units: mg/L Instrument: TOC1 Analyst: PSW Results by SW-846 9060A 132768 03/18/14 16:25 Dissolved Organ Total Organic Ca 132770 03/18/14 20:45 132772 03/19/14 00:53 132778 03/18/14 20:45 1.00U 1.00U 1.00U 132779 03/19/14 00:53 1.00U 1.00U Print Date: 04/11/2014 N.C. Certification # 481 62/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Walers.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal; NPOC 7N0. Area Conc. lnj. Vol. Aut. Ex. Cal.Curve Date/Time Dil. 1 5.089 0.6598mg/L 100uL 1 030414W.2014 03 04 13 51 57.ca 3/18/2014 4:25:05 PM 2 1.923 0.2493mg/L 100uL 1 030414W2014 03 04 13 51 57.cal 3/18/2014 4:27:08 PM 3 1.512 0.1960mg/L 100uL 1 030414W.2014 03 04 13 51 57.cal 3/18/2014 4:29:12 PM 4 1.512 '1 0.1960mg/L 100uL 1 030414W.2014 03 04 13 51 57.cal /18/2014 4:31:15 PM 5 2.904 I 0.3765mg/L 100uL 1 30414W.2014 03 04 13 51 57.cal /18/20144:34:07 PM Mean Area 1.963 Signal[mV] 10 Mean Conc. 0.2545mgTimeImin] 15/43 63/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM IN03016.132 Sample Sample Name: CBV SamplelD: Origin: 9050A_TOC1_Waters.me1 Status Completed Chk. Result Type Anal. Dil. Result ll?Jnknown POC 1.000 1. Del No. Area . . Date/Time . .2014 3 51 .cal 18/2014 8: :4 2.94 .2014 .2014 13 51 .cal 1 148: :1 PM 3.21 . 13 51 57.ca 14 :57: PM Mean Area 3.141 Signa [mv1 10 Mean Conc. 0.4072mg/L 01W 6 A baTimeImin] 27/43 64/65 REVISED REPORT PSW 3/19/2014 2:37:35 PM N03016.t32 Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal; NPOC No. Date Time 1 . 4 :4 .938 . 4W.20 . 12. AM .330 . 4W.20 . 12: 2 AM .443 . 4W.20 46 . 14W. Mean Area 3.114 SignaumV] 10 Mean Conc. 0.4038mglL NJ - 6 34'1Time[min] 39/43 65/65 REVISED REPORT Laboratory Report of Analysis To: Delaney Peterson ANCHOR ENVIRONMENTAL 720 Olive Way Suite 1900 Seattle, WA 98101 US Report Number: 31400411 Client Project: Patrick Bayou Dear Delaney Peterson, Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Amy J. Boehm at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you again on any additional analytical needs. Sincerely, SGS North America Inc. __________________________________________________________________ Jeannie Milholland Date Quality Director jeannie.milholland@sgs.com Print Date: 04/11/2014 N.C. Certification # 481 1/40 REVISED REPORT Laboratory Qualifiers Report Definitions DL Method, Instrument, or Estimated Detection Limit per Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions * Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) V Recovery is below quality control limit. The data has been validated based on a favorable signal-to-noise A Amount detected is less than the Lower Method Calibration Limit J Estimated Concentration. O The recovery of this analyte in the OPR is above the Method QC Limits and the reported concentration in E Amount detected is greater than the Upper Calibration Limit S The amount of analyte present has saturated the detector. This situation results in an Q Indicates the presence of a quantitative interference. This situation may result in an I Indicates the presence of a qualitative interference that could cause a false positive or an DPE Indicates the presence of a peak in the polychlorinated diphenylether channel that could TIC Tentatively Identified Compound and detection limit the sample may be biased high underestimation of the affected analyte(s) underestimation of the affected analyte(s) overestimation of the affected analyte(s) cause a false positive or an overestimation of the affected analyte(s) EMPC Estimated Maximum possible Concentration due to ion ratio failure ND Not Detected K Result is estimated due to ion ratio failure in High Resolution PCB Analysis P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code definition is provided below: M1 Mis-identified peak Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Print Date: 04/11/2014 N.C. Certification # 481 2/40 REVISED REPORT Sample Summary Client Sample ID Lab Sample ID Collected Received Matrix PB081_A-2SWMID-140315-N 31400411001 03/15/2014 10:15 03/18/2014 15:30 Water Print Date: 04/11/2014 N.C. Certification # 481 3/40 REVISED REPORT Case Narrative Samples were received in good condition. There were no discrepancies to report. 2540­D ­ Revised report to J flag TSS results down to the MDL in order to meet the reporting limit requirements of the SAP for this project. Print Date: 04/08/2014 N.C. Certification # 481 4/40 REVISED REPORT Detectable Results Summary Client Sample ID: PB081_A-2SWMID-140315-N Lab Sample ID: 31400411001-A Parameter Total Organic Carbon SW-846 9060A Print Date: 04/11/2014 Result 13.8 Units mg/L N.C. Certification # 481 5/40 6/40 PROJECT INFO: PROJECT: 0610 ~0 I 8 '90. QUOTE SITE REF: Ell-u OU TURN AROUNDTIME: REPORT LEVEL: (see reverse) I Level! I Level II We IV SPECIAL DELIVERABLES: ?37.21! State of Origin: gran: Other: CHAIN OF CUSTODY CONVENTIONAL SHALE SPECIAL INSTRUCTIONS COMMENTS: 3(4004-0 PRESERVATIVE SEND DOCUMENTATION I TO: COMPANY: anInct' (DEA (LC. CONTACT: :pg Iang ADDRESS: W20 OCI 5mm; I I00 -. j?a?l?-Ig? Edi-I 206*?1035 - 35%. A Ganchonlea . cam INVOICE T0: IF SAME) COMPANY: PNL ADDRESS: I 0qu 1212?" . 509M ?30 PHONE. I-n? -??02'Li EMAIL: b05953 pr?jec?I'h?lv . cm EMAIL: SAMPLE ID DESCRIPTION DATE 1 93031,,qi-ijmm~ 0?103) I ?54m Z234 I IRWSHED BY (1): DAT . 44?? 4 5/8, ?17 TIME: Ha) RELINOUISHED BY IZI: DATE: TIME: Page of SGS NUIITII AMERICA INC. R: Larson 2 20:70 a R?n y?z/ra 1 53.1.\ REVISED REPORT fie/Ex RECEIPTTEMPC . .. . ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 910 350 1903 I 910 794 1613 Member of the 568 Group [863 SAI REVISED REPORT SGS North America Inc. Sample Receipt Checklist (SRC) Client: Anchor Environmental Work Order No.: 31400411 1. Shipped Notes: Hand Delivered 2. COC Present on Receipt _No coc Additional Transmittal Forms 3. Tape on Container No Custody Tape 4. _X_Samples lntact _Samples Broken [Leaking 5. LChilled on Receipt Actual Temp.(s) in 1.9 Thermometer Login-1D Ambient on Receipt ?Walk-in on Ice; Coming down to temp. :Temperature Blank Present 6. Sufficient Sample Submitted Insufficient Sample Submitted 7. _Chlorine absent HNO3 2 Additional Preservatives veri?ed (see notes) Received Within Holding Time Not Received Within Holding Time No Discrepancies Noted 9? Discrepancies Noted notified of Discrepancies* 10. _No Headspace present in VOC vials Headspace present in VOC vials >6mm Comments: inspected and Logged in by: RCH Date: Tue?3/1 8/ 14 00:00 7/40 must be notified when collection, holding time or preservation requirements are not met. Ml_11.7 REVISED REPORT SM 2540-D Sample Data Print Date: 04/11/2014 N.C. Certification 481 55111] Business US - EMDE-Wilmirmnn. ME IN 3103-51] 1903 1+1 310350155? wan-.595 cum 8/40 LII 1hr SEE SIM REVISED REPORT Results of PB081_A-2SWMID-140315-N Client Sample ID: PB081_A-2SWMID-140315-N Client Project ID: Patrick Bayou Lab Sample ID: 31400411001-C Lab Project ID: 31400411 Collection Date: 03/15/2014 10:15 Received Date: 03/18/2014 15:30 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 11.0 J 3.60 25.0 mg/L 1 03/21/2014 15:00 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 15:00 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 9/40 REVISED REPORT 55??Busineswrive Total Suspended Solids Wilmington, NC 28405 SM 2540 Batch: INC 3026 Balance: BAL10 In Oven Date: 312112014 Analyst: DTF Oven: Oven #6 ln Oven Time: 15:00 StandardlD: TSA15 In Oven Temp: 105 Out Oven Date: 312412014 Out Oven Temp: 105 Out Oven Time: 9:00 Vol Filte Analyzed Filter Final Result Type Lab ID mL Lot Date Time 9 SAMPLE 132950 100 inv26 0312112014 14:59 0.1221 0.1220 -1 SAMPLE 132951 25 inv26 0312112014 14:59 0.1231 0.1343 448 SAMPLE 31400395001 100 inv26 0312112014 14:59 0.1183 0.1201 18 SAMPLE 132952 100 inv26 0312112014 14:59 0.1240 0.1261 21 SAMPLE 31400395002 100 inv26 0312112014 15:00 0.1241 0.1260 19 SAMPLE 31400395003 100 inv26 0312112014 15:00 0.1189 0.1207 18 SAMPLE 31400395004 100 inv26 0312112014 15:00 0.1225 0.1233 8 SAMPLE 31400395005 100 inv26 0312112014 15:00 0.1238 0.1250 12 SAMPLE 31400395006 100 inv26 0312112014 15:00 0.1205 0.1213 8 SAMPLE 31400395007 100 inv26 0312112014 15:00 0.1224 0.1243 19 SAMPLE 31400411001 100 inv26 0312112014 15:00 0.1197 0.1208 11 3/21/15" Analyst Signature Date ?ewewcd ?y Analyst signature indicates that the data printed is a true representation 4 of volumes and weights encountered in the analytical process. Weights are obtained through overnight drying at 1050. 344141, (F2 - F1) 1.000.000 The calculation of T88 is: TSS V1 Where: F2 Final (9) F1 Filter(g) Printed: 312412014 9:28:47 AM V1 Vol (mL) 1 of1 Pages 10/40 REVISED REPORT SM 2540-D QC, Blanks Data Print Date: 04/11/2014 N.C. Certification # 481 11/40 REVISED REPORT Batch Summary Analytical Method: SM 2540-D Prep Method: Prep Batch: Prep Date: SM 2540-D INO3026 03/21/2014 14:59 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41520 [INO/3026] 132950 03/21/2014 14:59 INO3026 BAL10 DTF LCS for HBN 41520 [INO/3026] 132951 03/21/2014 14:59 INO3026 BAL10 DTF PB070_B-2SWMID-1...(132394DUP) 132952 03/21/2014 14:59 INO3026 BAL10 DTF PB081_A-2SWMID-140315-N 31400411001 03/21/2014 15:00 INO3026 BAL10 DTF Print Date: 04/11/2014 N.C. Certification # 481 12/40 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41520 [INO/3026] Blank Lab ID: 132950 Prep Batch: INO3026 Matrix: Water Analysis Date/Time: 03/21/2014 14:59 Results by SM 2540-D Client Sample ID Lab Sample ID LCS for HBN 41520 [INO/3026] Date Analyzed Analyst 132951 03/21/2014 14:59 DTF PB070_B-2SWMID-1...(132394DUP) 132952 03/21/2014 14:59 DTF PB081_A-2SWMID-140315-N 31400411001 03/21/2014 15:00 DTF Print Date: 04/11/2014 Filename N.C. Certification # 481 13/40 REVISED REPORT Method Blank Blank ID: MB for HBN 41520 [INO/3026] Blank Lab ID: 132950 Matrix: Water QC for Samples: 31400411001 Results by SM 2540-D Parameter Result Total Suspended Solids ND Qual DL LOQ/CL Units DF 3.60 25.0 mg/L 1 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 3/21/2014 2:59:46PM Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 14/40 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41520 [INO/3026] Blank Spike Lab ID: 132951 Date Analyzed: 03/21/2014 14:59 Matrix: Water QC for Samples: 31400411001 Results by SM 2540-D Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Suspended Solids 500 448 90 80.0-120 Batch Information Analytical Batch: INO3026 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: DTF Prep Batch: INO3026 Prep Method: SM 2540-D Prep Date/Time: 03/21/2014 14:59 Spike Init Wt./Vol.: 1 mL Extract Vol: 1 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 15/40 REVISED REPORT SW-846 9060A Sample Data Print Date: 04/11/2014 N.C. Certification # 481 16/40 REVISED REPORT Results of PB081_A-2SWMID-140315-N Client Sample ID: PB081_A-2SWMID-140315-N Client Project ID: Patrick Bayou Lab Sample ID: 31400411001-A Lab Project ID: 31400411 Collection Date: 03/15/2014 10:15 Received Date: 03/18/2014 15:30 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 13.8 Units mg/L DF 1 Date Analyzed 03/21/2014 14:19 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 03/21/2014 14:19 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 17/40 REVISED REPORT PSW 3/24/2014 9:14:52 AM N03022.t32 Sampte Sample Name: 0411_1 Sample 10: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Result Unknown NPOC 1.000 1. Det Anal.: NPOC Area Mean Area 106.2 Signal[mV] Mean Conc. 13.77mgTime[min] 7/27 1 8/40 REVISED REPORT SW-846 9060A QC, Blanks Data Print Date: 04/11/2014 N.C. Certification # 481 19/40 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3022 03/21/2014 13:38 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41500 [INO/3022] 132788 03/21/2014 13:38 INO3022 TOC1 PSW LCS for HBN 41500 [INO/3022] 132789 03/21/2014 13:57 INO3022 TOC1 PSW PB081_A-2SWMID-140315-N 31400411001 03/21/2014 14:19 INO3022 TOC1 PSW PB081_A-2SWMID-14...(132630MS) 132790 03/21/2014 14:41 INO3022 TOC1 PSW PB081_A-2SWMID-1...(132630MSD) 132791 03/21/2014 15:01 INO3022 TOC1 PSW Print Date: 04/11/2014 N.C. Certification # 481 20/40 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41500 [INO/3022] Blank Lab ID: 132788 Prep Batch: INO3022 Matrix: Water Analysis Date/Time: 03/21/2014 13:38 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41500 (INO/3022) 132985 INO3022.csv 03/21/2014 00:59 PSW LCS for HBN 41500 [INO/3022] 132789 INO3022.csv 03/21/2014 13:57 PSW PB081_A-2SWMID-140315-N 31400411001 INO3022.csv 03/21/2014 14:19 PSW PB081_A-2SWMID-14...(132630MS) 132790 INO3022.csv 03/21/2014 14:41 PSW PB081_A-2SWMID-1...(132630MSD) 132791 INO3022.csv 03/21/2014 15:01 PSW CBV for HBN 41500 (INO/3022) 132988 INO3022.csv 03/21/2014 16:58 PSW Print Date: 04/11/2014 N.C. Certification # 481 21/40 REVISED REPORT Method Blank Blank ID: MB for HBN 41500 [INO/3022] Blank Lab ID: 132788 Matrix: Water QC for Samples: 31400411001 Results by SW-846 9060A Parameter Result Total Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 3/21/2014 1:38:20PM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 22/40 REVISED REPORT PSW 3/24/2014 9:14:52 AM N03022.t32 Sample Sampie Name: 132788 MB Sample fD: Origin: Status Comp/eted Chk. Resuit Type Anal DII Result Unknown NPOC 1.00 1. De! Anal.: NPOC NoMean Area 1.814 SignaumV] 10 Mean Conc. 0.2351mgTime[min] 5/27 23/40 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41500 [INO/3022] Blank Spike Lab ID: 132789 Date Analyzed: 03/21/2014 13:57 Matrix: Water QC for Samples: 31400411001 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Organic Carbon 50.0 49.4 99 90.0-110 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 03/21/2014 13:57 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 24/40 REVISED REPORT PSW 1 3/24l2014 9:14:52 AM N03022.t32 Sample Sample Name: 132789 LCS Sample ID: Origin: 9060A_TOCl_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.00 1. Det Anal: NPOC Area 49: Mean Area 380.9 Signa [mV] Mean Conc. 49.39mgTime[min] 6/27 25/40 REVISED REPORT Matrix Spike Summary Original Sample ID: 31400411001 (PB081_A-2SWMID-140315-N) MS Sample ID: 132790 MSD Sample ID: 132791 QC for Samples: Analysis Date: 03/21/2014 14:19 Analysis Date: 03/21/2014 14:41 Analysis Date: 03/21/2014 15:01 Matrix: Water 31400411001 Results by SW-846 9060A Matrix Spike (mg/L) Parameter Total Organic Carbon Sample 13.8 Spike 50.0 Result 61.1 Spike Duplicate (mg/L) Rec (%) 95 Spike 50.0 Result 61.2 Rec (%) CL RPD (%) 95 75.0-125 0.16 RPD CL 25.00 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 03/21/2014 14:19 MS Init Wt./Vol.: 40 mL Extract Vol.: 40 mL MSD Init Wt./Vol.: 40 mL Extract Vol.: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 26/40 REVISED REPORT PSW 3/24/2014 9:14:52 AM 1N03022.t32 Sample Sample Name: 132790 MS Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Del Anal: NPOC Area . . . Date l2014 . . . . 112014 4 . . . 142:50:1 Mean Area 471.2 Signa [mV] Mean Gone. 61 .09mg/L 0W btTime[min] 8/27 27/40 REVISED REPORT PSW Sample Sample Name: Sample ID: Origin: Status Chk. Result 3/2472014 9:14:52 AM 132791 MSD 9060A_TOC1_Waters.met Completed Type Anal. Dil. Result Unknown NPOC 1.000 Det Anal.: NPOC No. Mean Area Mean Cone. 472.0 61 .20mg/L 14 Signal[mV] 9/27 28/40 N03022.t32 Time[min] REVISED REPORT SW-846 9060A Prep, Standard, Run Logs Print Date: 04/11/2014 N.C. Certification # 481 29/40 Method: Matrix: Initial Cal. Curve: 9060 Water SGS Environmental Services TOC Runlog Sheet Batch: Primary Lot#: D-526 Secondary Lot#: D-455 SAMPLE ID DATE TIME OPER QC pH Comments Icv,/ 3/21/201412139 PSW CBV 3/21/201412:59 PSW NEG 3/21/201413218 PSW 132788 MB 3/21/201413:38 PSW 132789 LCS 3/21/201413157 PSW o411_1 3/21/201414119 PSW 132790 MS 3/21/201414:41 PSW 132791 MSD qn/Am 3/21/201415:01 PSW o420_1 3/21/201415121 PSW o42o__2 3/21/2014 15:40 PSW 042o_3 042o?4 PSW 3/21/201416219 PSW 1/ 3/21/201416238 PSW CBV 3/21/201416:58 PSW 3/21/201417219 PSW {0420_5 [942035 3/21/201417241 PSW 0427_1 PSW 0427_2 PSW m? 0427_3 PSW ?132800 PSW 132801 LCS PSW Analyst: REVISED REPORT Method: Matrix: Initial Cal. Curve: 9060 Water SGS Environmental Services TOC Runlog Sheet Batch: Primary Lot#: 0?526 Secondary Lot#: D-455 SAMPLE ID DILUTION DATE TIME OPER QC pH Comments 0427_3 PSW 132799 DUP PSW- ICV PSW CBV PSW Q1/i?) Analyst: REVISED REPORT REVISED REPORT SW-846 9060A Initial Calibration Data Print Date: 04/11/2014 N.C. Certification # 481 32/40 REVISED REPORT PSW 3/4/2014 4:35:34 PM 030414W.t32 Cal. Curve Sample Name: Untitled Sample ID: Untitled Cal. Curve: Status Completed Type Anal. 'DStandard NPOC Conc: 100.0mg/L No. Area nj.Vol. Aut. Rem. Ex. Date/Time Dil. 1 778.3 100uL 1 3/4/2014 2:00:59 PM 2 774.6 100uL 1 3/4/2014 2:06:27 PM 3 776.1 100uL 1 3/4/2014 2:11:52 PM 4 769.8 100uL 1 3/4/2014 2:17:17 PM Acid Add. 1.500% SignalImV] 400 . . Sp. Time 90.005ec 300 1 MeanArea 774.7 1/ fle 200 75 1 3,54Time[min] Conc: 50.00mg/L No. Area In]. Vol. . . Date Time :27. 2: :3 4/2014 2:43:10 PM Acid Add. 1.500% Signal[mV] 200 Sp. Time 90.00513} Mean Area 381.1 140 3:64Time[min] Conc: 10.00mg/L No. Area . . . DateAcid Add. 1.500% Signal[mV] 20 Sp. Time 90.005ec Mean Area 75.Time[min] 'Conc: 1.000mg/L Area 1 .2 14 3:22:03 PM 10.27 14 3:26:47 PM 10.29 14 3:31: PM 2/3 33/40 REVISED REPORT PSW 31'4/2014 4:35:34 PM 030414W.132 ACidAdd. 1.500% 10 Sp. Time 90.0058C Mean Area 10.26 6 HM #3541 Time[min] Conc: 0.5000mg/L No. Area DatelTime iti??ti 43. 6118 until 6.095 1 4/20143: .1PM 5.719 1 4 - pm 5.93? 1 4 . PM AcidAdd. 1.500% 10 Sp. Time 90.005ec MeanArea 6.108 6 ml 3,547 Time[min] Conc: 0.000mg/L No. Area In]. Vol. Aut. Rem. Ex. DatelTime 1.725 . 1. 4: . :1614 PM 1.572 1 PM AcidAdd. 1.500% Signa [mV] 10 Sp. Time 90.0059c MeanArea 1.646 Time[min] 7-713 Area 852.17 Intercept 0.000 r?2 0.999906 . 0999953 500 Zero Shl100110 Conc[mg/L] 3/3 34/40 REVISED REPORT SW-846 9060A Continuing Calibration Data Print Date: 04/11/2014 N.C. Certification # 481 35/40 REVISED REPORT PSW Sample Sample Name: Sample ID: Origin: Status Chk. Result 3/24/2014 9:14:52 AM 9060A_TOC1_Waters.met Completed Type Anal. Dil. Result Mnknown NPOC 1.0001 1. Det Anal: NPOC No. Area Mean Area Mean Conc. 374.0 48.48mg/L 4 Sig nal[mV] 200 140 14 16 18 1N03022.t32 Timefmin] 2/27 36/40 REVISED REPORT PSW 3l24/2014 9:14:52 AM lN03022.t32 Sample Sample Name: ICV Sample lD: Origin: Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal: NPOC N0. Area lnj.Vol. Aut. Ex. . Date Dil. :38:58 PM 3 Mean Area 371.0 Signal[mV] Mean Conc. 48.09mglL 011?? 3391?.? Time[min] 14/27 37/40 REVISED REPORT Analytical Blank Summary Form 3 Analytical Batch: INO3022 Units: mg/L Instrument: TOC1 Analyst: PSW Results by SW-846 9060A 132985 03/21/14 00:59 Total Organic Ca 1.00U 132988 03/21/14 16:58 1.00U Print Date: 04/11/2014 N.C. Certification # 481 38/40 REVISED REPORT PSW 3/24/2014 9:14:52 AM [N03022.t32 Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1mWaters.met Status Completed Chk. Result Type Anal. 'Dil. Result Unknown NPOC 1.000 1. Del Anal: NPOC Mean Area 2.445 Signal[mV] 10 Mean Conc. 0.3170mg/L 65M 6 3rw"?Time[min] 3/27 39/40 REVISED REPORT PSW 3/24/2014 9:14:52 AM Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.00 1. Det Anal.: NPOC Area 0.501 0 3347 0. Mean Area 2.833 Signal[mV] 10 Mean Conc. 0.3673mgTimeImin] 15/27 40/40 REVISED REPORT Laboratory Report of Analysis To: Delaney Peterson ANCHOR ENVIRONMENTAL 720 Olive Way Suite 1900 Seattle, WA 98101 US Report Number: 31400420 Client Project: Patrick Bayou Dear Delaney Peterson, Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Amy J. Boehm at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you again on any additional analytical needs. Sincerely, SGS North America Inc. __________________________________________________________________ Jeannie Milholland Date Quality Director jeannie.milholland@sgs.com Print Date: 04/11/2014 N.C. Certification # 481 1/71 REVISED REPORT Laboratory Qualifiers Report Definitions DL Method, Instrument, or Estimated Detection Limit per Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions * Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) V Recovery is below quality control limit. The data has been validated based on a favorable signal-to-noise A Amount detected is less than the Lower Method Calibration Limit J Estimated Concentration. O The recovery of this analyte in the OPR is above the Method QC Limits and the reported concentration in E Amount detected is greater than the Upper Calibration Limit S The amount of analyte present has saturated the detector. This situation results in an Q Indicates the presence of a quantitative interference. This situation may result in an I Indicates the presence of a qualitative interference that could cause a false positive or an DPE Indicates the presence of a peak in the polychlorinated diphenylether channel that could TIC Tentatively Identified Compound and detection limit the sample may be biased high underestimation of the affected analyte(s) underestimation of the affected analyte(s) overestimation of the affected analyte(s) cause a false positive or an overestimation of the affected analyte(s) EMPC Estimated Maximum possible Concentration due to ion ratio failure ND Not Detected K Result is estimated due to ion ratio failure in High Resolution PCB Analysis P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code definition is provided below: M1 Mis-identified peak Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Print Date: 04/11/2014 N.C. Certification # 481 2/71 REVISED REPORT Sample Summary Client Sample ID Lab Sample ID Collected PB083-1SWMID-140318-N PB083-1SWMID-140318-D PB087-1SWMID-140318-N PB091-1SWMID-140318-N PB093-1SWMID-140318-N PB095-1SWMID-140318-N 31400420001 31400420002 31400420003 31400420004 31400420005 31400420006 03/18/2014 03/18/2014 03/18/2014 03/18/2014 03/18/2014 03/18/2014 Print Date: 04/11/2014 Received 15:23 15:23 15:53 17:08 17:37 18:47 03/19/2014 03/19/2014 03/19/2014 03/19/2014 03/19/2014 03/19/2014 Matrix 10:15 10:15 10:15 10:15 10:15 10:15 Water Water Water Water Water Water N.C. Certification # 481 3/71 REVISED REPORT Case Narrative Samples were received in good condition. There were no discrepancies to report. 2540­D ­ Revised report to J flag TSS results down to the MDL in order to meet the reporting limit requirements of the SAP for this project. Print Date: 04/08/2014 N.C. Certification # 481 4/71 REVISED REPORT Detectable Results Summary Client Sample ID: PB083-1SWMID-140318-N Lab Sample ID: 31400420001-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB083-1SWMID-140318-D Lab Sample ID: 31400420002-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB087-1SWMID-140318-N Lab Sample ID: 31400420003-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB091-1SWMID-140318-N Lab Sample ID: 31400420004-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB093-1SWMID-140318-N Lab Sample ID: 31400420005-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB095-1SWMID-140318-N Lab Sample ID: 31400420006-A Parameter Total Organic Carbon SW-846 9060A Result Print Date: 04/11/2014 10.3 10.2 11.1 11.6 11.4 10.7 Units mg/L Units mg/L Units mg/L Units mg/L Units mg/L Units mg/L N.C. Certification # 481 5/71 6/71 CHAINOF CUSTODY CONVENTIONAL SHALE PROJECT INFO: SEND RESULTS TO: SPECIAL INSTRUCTIONS I PROJECT: J?P?+oggn CONTACT: QUOTE . ADDRESS: Oliur, but" SITE REF: EL . Staff/? (4/24 ?75/ PHESERVATIVE . 20:2: -'29 63-480 TURN AROUNDTIME: pa?: EMAIL: prwm??cmohww'? Jam RI REPORT LEVEL: (see reverse) CI Level Level II WW INVOICE T0: CHECK IF SAME) ANALYSIS 8. METHOD SPECIA ELIVERABLES: State of Origin: COMPANY: CONTACT: gob DD: In Other: Mich-CF I ADDRESS: - a PHONE: EMAIL: ~bob a?y??m ac CONT. MS nun (ac) MATRIX rm SAMPLE ID DESCRIPTION DATE TIME I REMARKS 13%. ?44255 601DATE: RECEIVED BY: Eur/K RECEIVED BY: RELINOUISHED BY (2): Page of SOS NORTH AMERICA IND. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 910 350 1903 910 794 1613 I R?nmkav a; Hun IQCQ CAI REVISED REPORT REVISED REPORT 868 North America Inc. Sample Receipt Checklist (SRC) Client: Anchor Environmental Work Order No.: 31400420 1. _X_Shipped Notes: Hand Delivered 2. Present on Receipt No COC _Additional Transmittal Forms 3. _Custody Tape on Container No Custody Tape 4. Samples Intact :Samples Broken Leaking 5. _X_Chilled on Receipt Actual Temp.(s) in 2.4, 2.2 Thermometer Login-1D _Ambient on Receipt _Walk?in on ice; Coming down to temp. _Temperature Blank Present 6. Sufficient Sample Submitted insufficient Sample Submitted 7. Chlorine absent Additional Preservatives veri?ed (see notes) 8. Received Within Holding Time _Not Received Within Holding Time 9. iNo Discrepancies Noted _Discrepancies Noted notified of Discrepancies* 10. _No Headspace present in VOC vials Headspace present in VOC vials >6mm Comments: inspected and Logged in by: RCH Date: Wed-3/19l14 00:00 7/71 must be notified when collection, holding time or preservation requirements are not met. Ml_11.7 REVISED REPORT SM 2540-D Sample Data Print Date: 04/11/2014 N.C. Certification 481 55111] Business US - EMDE-Wilmirmnn. ME IN 3103-51] 1903 1+1 310350155? wan-.595 cum 8/71 LII 1hr SEE SIM REVISED REPORT Results of PB083-1SWMID-140318-N Client Sample ID: PB083-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420001-C Lab Project ID: 31400420 Collection Date: 03/18/2014 15:23 Received Date: 03/19/2014 10:15 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 5.0 J 3.60 25.0 mg/L 1 03/24/2014 9:40 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:40 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 9/71 REVISED REPORT Results of PB083-1SWMID-140318-D Client Sample ID: PB083-1SWMID-140318-D Client Project ID: Patrick Bayou Lab Sample ID: 31400420002-C Lab Project ID: 31400420 Collection Date: 03/18/2014 15:23 Received Date: 03/19/2014 10:15 Matrix: Water Results by SM 2540-D Parameter Result Total Suspended Solids ND Qual DL LOQ/CL Units DF Date Analyzed 3.60 25.0 mg/L 1 03/24/2014 9:40 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:40 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 10/71 REVISED REPORT Results of PB087-1SWMID-140318-N Client Sample ID: PB087-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420003-C Lab Project ID: 31400420 Collection Date: 03/18/2014 15:53 Received Date: 03/19/2014 10:15 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 5.0 J 3.60 25.0 mg/L 1 03/24/2014 9:40 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:40 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 11/71 REVISED REPORT Results of PB091-1SWMID-140318-N Client Sample ID: PB091-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420004-C Lab Project ID: 31400420 Collection Date: 03/18/2014 17:08 Received Date: 03/19/2014 10:15 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 12.0 J 3.60 25.0 mg/L 1 03/24/2014 9:40 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:40 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 12/71 REVISED REPORT Results of PB093-1SWMID-140318-N Client Sample ID: PB093-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420005-C Lab Project ID: 31400420 Collection Date: 03/18/2014 17:37 Received Date: 03/19/2014 10:15 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 6.0 J 3.60 25.0 mg/L 1 03/24/2014 9:40 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:40 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 13/71 REVISED REPORT Results of PB095-1SWMID-140318-N Client Sample ID: PB095-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420006-C Lab Project ID: 31400420 Collection Date: 03/18/2014 18:47 Received Date: 03/19/2014 10:15 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 14.0 J 3.60 25.0 mg/L 1 03/24/2014 9:40 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:40 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 14/71 REVISED REPORT 5500 Business Drive Total Suspended Solids a Wilmington, NC 28405 ?um man-m? ,?htj . SM 2540 Batch: INC 3027 Balance: BAL10 In Oven Date: 3/24/2014 Analyst: VS Oven: Oven #6 In Oven Time: 11:50 StandardlD: TSA15 In Oven Temp: 105 Out Oven Date: 3/24/2014 Out Oven Temp: 105 Out Oven Time: 15:00 Vol Filte Analyzed Filter Final Result Type Lab ID mL Lot Date Time 9 9 mg/L MB 132953 100 INV2 03/24/2014 9:39 0.1202 0.1199 -3 LCS 132954 25 INV2 03/24/2014 9:39 0.1214 0.1318 416 SAMPLE 31400422001 10 INV2 03/24/2014 9:40 0.1203 0.1226 230 DUP 132955 10 03/24/2014 9:40 0.1194 0.1213 190 SAMPLE 31400422002 10 03/24/2014 9:40 0.1185 0.1258 730 SAMPLE 31400401002 100 03/24/2014 9:40 0.1171 0.1241 70 . SAMPLE 31400420001 100 03/24/2014 9:40 0.1223 0.1228 5 SAMPLE 31400420002 100 INV2 03/24/2014 9:40 0.1182 0.1185 3 SAMPLE 31400420003 100 INV2 03/24/2014 9:40 0.1178 0.1183 5 SAMPLE 31400420004 100 INV2 03/24/2014 9:40 0.1184 0.1196 12 SAMPLE 31400420005 100 INV2 03/24/2014 9:40 0.1189 0.1195 6 SAMPLE 31400420006 100 INV2 03/24/2014 9:40 0.1190 0.1204 14 SAMPLE 31400427001 100 INV2 03/24/2014 9:40 0.1167 0.1176 SAMPLE 31400427002 100 INV2 03/24/2014 9:40 0.1192 0.1198 SAMPLE 31400427003 100 INV2 03/24/2014 9:40 0.1243 0.1250 3 '2?7-4 gay/ewe! Analyst Signature Date gr! WA Analyst signature indicates that the data printed is a true representation of volumes and weights encountered in the analytical process. Weights 3..)4141/ are obtained through overnight drying at 1050. (F2 - F1) 1,000,000 The calculation of T63 is: mg/L TSS V1 Where: Final (9) F1 Filter (9) Printed: 3/24/2014 3:00:40 PM V1 Vol (mL) 1 of1 Pages 15/71 REVISED REPORT SM 2540-D QC, Blanks Data Print Date: 04/11/2014 N.C. Certification # 481 16/71 REVISED REPORT Batch Summary Analytical Method: SM 2540-D Prep Method: Prep Batch: Prep Date: SM 2540-D INO3027 03/24/2014 09:39 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41522 [INO/3027] 132953 03/24/2014 09:39 INO3027 BAL10 VS LCS for HBN 41522 [INO/3027] 132954 03/24/2014 09:39 INO3027 BAL10 VS V13501(132775DUP) 132955 03/24/2014 09:40 INO3027 BAL10 VS PB083-1SWMID-140318-N 31400420001 03/24/2014 09:40 INO3027 BAL10 VS PB083-1SWMID-140318-D 31400420002 03/24/2014 09:40 INO3027 BAL10 VS PB087-1SWMID-140318-N 31400420003 03/24/2014 09:40 INO3027 BAL10 VS PB091-1SWMID-140318-N 31400420004 03/24/2014 09:40 INO3027 BAL10 VS PB093-1SWMID-140318-N 31400420005 03/24/2014 09:40 INO3027 BAL10 VS PB095-1SWMID-140318-N 31400420006 03/24/2014 09:40 INO3027 BAL10 VS Print Date: 04/11/2014 N.C. Certification # 481 17/71 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41522 [INO/3027] Blank Lab ID: 132953 Prep Batch: INO3027 Matrix: Water Analysis Date/Time: 03/24/2014 09:39 Results by SM 2540-D Client Sample ID Lab Sample ID LCS for HBN 41522 [INO/3027] Date Analyzed Analyst 132954 03/24/2014 09:39 VS V13501(132775DUP) 132955 03/24/2014 09:40 VS PB083-1SWMID-140318-N 31400420001 03/24/2014 09:40 VS PB083-1SWMID-140318-D 31400420002 03/24/2014 09:40 VS PB087-1SWMID-140318-N 31400420003 03/24/2014 09:40 VS PB091-1SWMID-140318-N 31400420004 03/24/2014 09:40 VS PB093-1SWMID-140318-N 31400420005 03/24/2014 09:40 VS PB095-1SWMID-140318-N 31400420006 03/24/2014 09:40 VS Print Date: 04/11/2014 Filename N.C. Certification # 481 18/71 REVISED REPORT Method Blank Blank ID: MB for HBN 41522 [INO/3027] Blank Lab ID: 132953 Matrix: Water QC for Samples: 31400420001, 31400420002, 31400420003, 31400420004, 31400420005, 31400420006 Results by SM 2540-D Parameter Result Total Suspended Solids ND Qual DL LOQ/CL Units DF 3.60 25.0 mg/L 1 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 3/24/2014 9:39:56AM Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 19/71 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41522 [INO/3027] Blank Spike Lab ID: 132954 Date Analyzed: 03/24/2014 09:39 Matrix: Water QC for Samples: 31400420001, 31400420002, 31400420003, 31400420004, 31400420005, 31400420006 Results by SM 2540-D Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Suspended Solids 500 416 83 80.0-120 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:39 Spike Init Wt./Vol.: 1 mL Extract Vol: 1 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 20/71 REVISED REPORT SW-846 9060A Sample Data Print Date: 04/11/2014 N.C. Certification # 481 21/71 REVISED REPORT Results of PB083-1SWMID-140318-N Client Sample ID: PB083-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420001-A Lab Project ID: 31400420 Collection Date: 03/18/2014 15:23 Received Date: 03/19/2014 10:15 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 10.3 Units mg/L DF 1 Date Analyzed 03/21/2014 15:21 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 03/21/2014 15:21 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 22/71 REVISED REPORT PSW 3/24/2014 9:14:52 AM Sample Sample Name: 0420?1 Sample ID: Origin: 9060A_TOC1mWaters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal.: NPOC Area . . Date I Time .ca 80.65 . 3 51 57.ca Mean Area 79.25 Signa [mV] 40 Mean Conc. 10.27mg/L 30 Span-4Time[min] 10l27 23/71 REVISED REPORT Results of PB083-1SWMID-140318-D Client Sample ID: PB083-1SWMID-140318-D Client Project ID: Patrick Bayou Lab Sample ID: 31400420002-A Lab Project ID: 31400420 Collection Date: 03/18/2014 15:23 Received Date: 03/19/2014 10:15 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 10.2 Units mg/L DF 1 Date Analyzed 03/21/2014 15:40 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 03/21/2014 15:40 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 24/71 REVISED REPORT PSW 3/24/2014 9:14:52 AM lN03022.t32 Sample Sample Name: 0420_2 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal; NPOC N0. 10: 30414 10. 14W 10. 14W.201 Mean Area 78.89 Signa [mV] 40 Mean Conc. 10.23mg/L 30 AW 20 3?Time[min] 11/27 25/71 REVISED REPORT Results of PB087-1SWMID-140318-N Client Sample ID: PB087-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420003-A Lab Project ID: 31400420 Collection Date: 03/18/2014 15:53 Received Date: 03/19/2014 10:15 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 11.1 Units mg/L DF 1 Date Analyzed 03/21/2014 15:59 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 03/21/2014 15:59 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 26/71 REVISED REPORT PSW 3/24/2014 9:14:52 AM Sample Sample Name: Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dll. Result Unknown NPOC 1.00 1. Det Anal: NPOC Area 86.34 Mean Area 85.28 Signal[mV] Mean Conc. 11.06mgTime[min] 12/27 27/71 REVISED REPORT Results of PB091-1SWMID-140318-N Client Sample ID: PB091-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420004-A Lab Project ID: 31400420 Collection Date: 03/18/2014 17:08 Received Date: 03/19/2014 10:15 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 11.6 Units mg/L DF 1 Date Analyzed 03/21/2014 16:19 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 03/21/2014 16:19 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 28/71 REVISED REPORT PSW 3/24l2014 9:14:52 AM Sample Sample Name: 0420*4 SamplelD: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. De! Anal: NPOC Area Cal. Curve 7. 14w.2014 3 90. . W201 03 04 1 89.12 . W.2014 03 04 1 90.60 . 14W.2014 1 Mean Area 89.50 Signa [mV] 40 Mean Conc. 11.60mglL Time[min] 13127 29/71 REVISED REPORT Results of PB093-1SWMID-140318-N Client Sample ID: PB093-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420005-A Lab Project ID: 31400420 Collection Date: 03/18/2014 17:37 Received Date: 03/19/2014 10:15 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 11.4 Units mg/L DF 1 Date Analyzed 03/26/2014 18:27 Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 03/26/2014 18:27 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 30/71 REVISED REPORT PSW 3/27/2014 8:07:06 AM 1N03034.z32 Sample 1 Sample Name: 420__5 Sample ID: Origin: Status Completed Chk. Resuit Type Anal. Qil. Result Unknown NPOC 1.00 1. Det Anal.: NPOC Area 4W 714 71 Mean Area 103.3 Signal[mV] 40 . 11.TimeImin] 16l35 31/71 REVISED REPORT Results of PB095-1SWMID-140318-N Client Sample ID: PB095-1SWMID-140318-N Client Project ID: Patrick Bayou Lab Sample ID: 31400420006-A Lab Project ID: 31400420 Collection Date: 03/18/2014 18:47 Received Date: 03/19/2014 10:15 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 10.7 Units mg/L DF 1 Date Analyzed 03/26/2014 17:03 Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 03/26/2014 17:03 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 32/71 REVISED REPORT PSW 5 3/27/2014 8:07:06 AM N03034.t32 Sample Sample Name: 1 420_6 Sample ID: Origin: 1 9060A_Toc1_Waters.met Status Completed Chk. Result Type Anal. Result Unknown NPOC 1.000 1. Det 1 Anal.: NPOC Area :8 . 1 1 4 Mean Area 96.81 1 Signa 1mV1 40 Mean Conc. 10.71mgTime[min] 12/35 33/71 REVISED REPORT SW-846 9060A QC, Blanks Data Print Date: 04/11/2014 N.C. Certification # 481 34/71 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3022 03/21/2014 13:38 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41500 [INO/3022] 132788 03/21/2014 13:38 INO3022 TOC1 PSW LCS for HBN 41500 [INO/3022] 132789 03/21/2014 13:57 INO3022 TOC1 PSW PB081_A-2SWMID-14...(132630MS) 132790 03/21/2014 14:41 INO3022 TOC1 PSW PB081_A-2SWMID-1...(132630MSD) 132791 03/21/2014 15:01 INO3022 TOC1 PSW PB083-1SWMID-140318-N 31400420001 03/21/2014 15:21 INO3022 TOC1 PSW PB083-1SWMID-140318-D 31400420002 03/21/2014 15:40 INO3022 TOC1 PSW PB087-1SWMID-140318-N 31400420003 03/21/2014 15:59 INO3022 TOC1 PSW PB091-1SWMID-140318-N 31400420004 03/21/2014 16:19 INO3022 TOC1 PSW Print Date: 04/11/2014 N.C. Certification # 481 35/71 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41500 [INO/3022] Blank Lab ID: 132788 Prep Batch: INO3022 Matrix: Water Analysis Date/Time: 03/21/2014 13:38 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41500 (INO/3022) 132985 INO3022.csv 03/21/2014 00:59 PSW LCS for HBN 41500 [INO/3022] 132789 INO3022.csv 03/21/2014 13:57 PSW PB081_A-2SWMID-14...(132630MS) 132790 INO3022.csv 03/21/2014 14:41 PSW PB081_A-2SWMID-1...(132630MSD) 132791 INO3022.csv 03/21/2014 15:01 PSW PB083-1SWMID-140318-N 31400420001 INO3022.csv 03/21/2014 15:21 PSW PB083-1SWMID-140318-D 31400420002 INO3022.csv 03/21/2014 15:40 PSW PB087-1SWMID-140318-N 31400420003 INO3022.csv 03/21/2014 15:59 PSW PB091-1SWMID-140318-N 31400420004 INO3022.csv 03/21/2014 16:19 PSW CBV for HBN 41500 (INO/3022) 132988 INO3022.csv 03/21/2014 16:58 PSW Print Date: 04/11/2014 N.C. Certification # 481 36/71 REVISED REPORT Method Blank Blank ID: MB for HBN 41500 [INO/3022] Blank Lab ID: 132788 Matrix: Water QC for Samples: 31400420001, 31400420002, 31400420003, 31400420004 Results by SW-846 9060A Parameter Result Total Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 3/21/2014 1:38:20PM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 37/71 REVISED REPORT PSW 3/24/2014 9:14:52 AM N03022.t32 Sample Sampie Name: 132788 MB Sample fD: Origin: Status Comp/eted Chk. Resuit Type Anal DII Result Unknown NPOC 1.00 1. De! Anal.: NPOC NoMean Area 1.814 SignaumV] 10 Mean Conc. 0.2351mgTime[min] 5/27 38/71 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41500 [INO/3022] Blank Spike Lab ID: 132789 Date Analyzed: 03/21/2014 13:57 Matrix: Water QC for Samples: 31400420001, 31400420002, 31400420003, 31400420004 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Organic Carbon 50.0 49.4 99 90.0-110 Batch Information Analytical Batch: INO3022 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3022 Prep Method: SW-846 9060A Prep Date/Time: 03/21/2014 13:57 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 39/71 REVISED REPORT PSW 1 3/24l2014 9:14:52 AM N03022.t32 Sample Sample Name: 132789 LCS Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.00 1. Det Anal: NPOC Area 49: Mean Area 380.9 Signa [mV] Mean Conc. 49.39mgTime[min] 6/27 40/71 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3034 03/26/2014 14:38 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41852 [INO/3034] 133117 03/26/2014 14:38 INO3034 TOC1 PSW LCS for HBN 41852 [INO/3034] 133118 03/26/2014 14:57 INO3034 TOC1 PSW PB099-1SWMID-1403...(132796MS) 133119 03/26/2014 15:36 INO3034 TOC1 PSW PB099-1SWMID-140...(132796MSD) 133120 03/26/2014 15:59 INO3034 TOC1 PSW PB095-1SWMID-140318-N 31400420006 03/26/2014 17:03 INO3034 TOC1 PSW PB095-1SWMID-140...(132717DUP) 132792 03/26/2014 17:25 INO3034 TOC1 PSW PB093-1SWMID-140318-N 31400420005 03/26/2014 18:27 INO3034 TOC1 PSW Print Date: 04/11/2014 N.C. Certification # 481 41/71 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41852 [INO/3034] Blank Lab ID: 133117 Prep Batch: INO3034 Matrix: Water Analysis Date/Time: 03/26/2014 14:38 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41852 (INO/3034) 133306 INO3034.csv 03/26/2014 13:11 PSW LCS for HBN 41852 [INO/3034] 133118 INO3034.csv 03/26/2014 14:57 PSW PB099-1SWMID-1403...(132796MS) 133119 INO3034.csv 03/26/2014 15:36 PSW PB099-1SWMID-140...(132796MSD) 133120 INO3034.csv 03/26/2014 15:59 PSW PB095-1SWMID-140318-N 31400420006 INO3034.csv 03/26/2014 17:03 PSW PB095-1SWMID-140...(132717DUP) 132792 INO3034.csv 03/26/2014 17:25 PSW CBV for HBN 41852 (INO/3034) 133309 INO3034.csv 03/26/2014 18:06 PSW PB093-1SWMID-140318-N 31400420005 INO3034.csv 03/26/2014 18:27 PSW CBV for HBN 41852 (INO/3034) 133311 INO3034.csv 03/26/2014 22:24 PSW Print Date: 04/11/2014 N.C. Certification # 481 42/71 REVISED REPORT Method Blank Blank ID: MB for HBN 41852 [INO/3034] Blank Lab ID: 133117 Matrix: Water QC for Samples: 31400420005, 31400420006 Results by SW-846 9060A Parameter Result Total Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 3/26/2014 2:38:03PM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 43/71 REVISED REPORT PSW 3/27/2014 8:07:06 AM lNO3034.t32 Sample Sample Name: 133117 MB Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. EEil. Result Unknown NPOC 1.000 i 1. Det Anal: NPOC i No. . . . Date I Time . 14 .828 714W .807 . 7 4W.201 1.903 71 Mean Area 1.877 Signal[mV] 10 Mean Conc. 0.2077mgTime[min] 5/35 44/71 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41852 [INO/3034] Blank Spike Lab ID: 133118 Date Analyzed: 03/26/2014 14:57 Matrix: Water QC for Samples: 31400420005, 31400420006 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Organic Carbon 50.0 47.7 95 90.0-110 Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 03/26/2014 14:57 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 45/71 i REVISED REPORT PSW 3/27/2014 8:07:06 AM 1N03034.t32 Sample Sample Name: i 133113 LCS Sample ID: Origin: Status 5 Completed Chk. Result Type Anal. 15:111. Result Unknown NPOC 1.000 1. Det . Anal: NPOC No. Area . . 14 3:00343 PM 429.2 47. 7 . 1 3:03:32 PM 436.8 48.31 . - mean?rea 3316/3 Signal[mV] 200 ean onc. . mg 43'" 140 17Tlmelmln] 6/35 46/71 REVISED REPORT Duplicate Sample Summary Original Sample ID: 31400420006-A Duplicate Sample ID: 132792 QC for Samples: Analysis Date: 03/26/2014 17:03 Analysis Date: 03/26/2014 17:25 Matrix: Water 31400420005, 31400420006 Results by SW-846 9060A PARAMETER Total Organic Carbon Original (mg/L) 10.7 Qual Duplicate (mg/L) 10.7 Qual RPD (%) 0.0 RPD CL Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Print Date: 04/11/2014 N.C. Certification # 481 47/71 i REVISED REPORT PSW 3/27/2014 8:07:06 AM Sample I 3179?- Sample Name: 138592 DUP Sample ID: Origin: Status Completed Chk. Result 5 Type Anal. Result Unknown NPOC 1.000 1. Del Anal: NPOC No. Area Date . 5 . 4 . . 7.39 10. . 14 5:28:22 PM 94.42 10, . 4 5:30:56 PM 97.17 1 . Mean Area 96.93 Signa [mV] 40 Mean Conc. 10.72mglL Time[min] 13/35 48/71 REVISED REPORT SW-846 9060A Prep, Standard, Run Logs Print Date: 04/11/2014 N.C. Certification # 481 49/71 Method: Matrix: Initial Cal. Curve: 9060 Water SGS Environmental Services TOC Runlog Sheet Batch: Primary Lot#: D-526 Secondary Lot#: D-455 SAMPLE ID DATE TIME OPER QC pH Comments Icv,/ 3/21/201412139 PSW CBV 3/21/201412:59 PSW NEG 3/21/201413218 PSW 132788 MB 3/21/201413:38 PSW 132789 LCS 3/21/201413157 PSW o411_1 3/21/201414119 PSW 132790 MS 3/21/201414:41 PSW 132791 MSD l710/7 3/21/201415:01 PSW o420_1 3/21/201415121 PSW o42o__2 3/21/2014 15:40 PSW 042o_3 042o?4 PSW 3/21/201416219 PSW 1/ 3/21/201416238 PSW CBV 3/21/201416:58 PSW 3/21/201417219 PSW {0420_5 [942035 3/21/201417241 PSW 0427_1 PSW 0427_2 PSW m? 0427_3 PSW ?132800 PSW 132801 LCS PSW Analyst: REVISED REPORT Method: Matrix: Initial Cal. Curve: 9060 Water SGS Environmental Services TOC Runlog Sheet Batch: Primary Lot#: 0?526 Secondary Lot#: D-455 SAMPLE ID DILUTION DATE TIME OPER QC pH Comments 0427_3 PSW 132799 DUP PSW- ICV PSW CBV PSW Analyst: REVISED REPORT Method: Matrix: Initial Cal. Curve: 9060 Water 868 Environmental Services TOC Runlog Sheet Batch Primary Lot# Secondary Lot# INO3034 IMO 3025 SAMPLE ID DILUTION DATE TIME OPER pH Comments f'lcvw 3/26/2014 12:50 PSW I CBV 3/26/2014 13:11 PSW NEG 3/26/2014 14:19 PSW 133117 MB 3/26/2014 14:38 PSW 133118 Los/ 3/26/2014 14:57 PSW 427_1 3/26/2014 15:17 PSW 133119 MS 3/26/2014 15:36 PSW 52/?1 133120 MSD c/ 3/26/2014 15:59 PSW 427_2 3/26/2014 16:19 PSW 427_3 3/26/2014 16:40 PSW 132792 DUP 3/26/2014 17:03 PSW 3/26/2014 17:25 PSW Mm ICV 3/26/2014 17:45 PSW CBV 3/26/2014 18:06 PSW 420_5 3/26/2014 18:27 PSW 434_25 3/26/2014 18:46 PSW 434_26 3/26/2014 19:07 PSW 434_27 3/26/2014 19:28 PSW 1 434_28 3/26/2014 19:50 PSW 434_29 3/26/2014 20:13 PSW 53430 3/26/2014 20:36 PSW Analyst: REVISED REPORT SGS Environmental Services TOC Runlog Sheet Method: 9060 Matrix: Water Batch: INO3034 Primary Lot#: Initial Cal. Curve: Secondary D-455 SAMPLE iD DILUTION DATE TIME OPER QC pH Comments 434-31 3/26/2014 20:57 PSW 434_32 3/2'072014 21 :20? PSW 3/26/2014 21 :42 PSW 3/26/2014 22:03 PSW :5 Am: 3/26/2014 22:24 PSW 434-34 3/26/2014 22:45 PSW 434.35 3/26/2014 23:08 PSW 132800 MB-F1 3/26/2014 23:29 PSW 132801 L05 1/ 3/26/2014 23:51 PSW 427-3 3/27/2014 0:11 PSW REVISED REPORT .L 132799 DUP 3/27/2014 0:31 PSW 3/27/2014 0:51 PSW CBV 1/ 3/27/2014 1:12 PSW Analyst: REVISED REPORT SW-846 9060A Initial Calibration Data Print Date: 04/11/2014 N.C. Certification # 481 54/71 REVISED REPORT PSW 3/4/2014 4:35:34 PM 030414W.t32 Cal. Curve Sample Name: Untitled Sample ID: Untitled Cal. Curve: Status Completed Type Anal. 'DStandard NPOC Conc: 100.0mg/L No. Area nj.Vol. Aut. Rem. Ex. Date/Time Dil. 1 778.3 100uL 1 3/4/2014 2:00:59 PM 2 774.6 100uL 1 3/4/2014 2:06:27 PM 3 776.1 100uL 1 3/4/2014 2:11:52 PM 4 769.8 100uL 1 3/4/2014 2:17:17 PM Acid Add. 1.500% SignalImV] 400 . . Sp. Time 90.005ec 300 1 MeanArea 774.7 1/ fle 200 75 1 3,54Time[min] Conc: 50.00mg/L No. Area In]. Vol. . . Date Time :27. 2: :3 4/2014 2:43:10 PM Acid Add. 1.500% Signal[mV] 200 Sp. Time 90.00513} Mean Area 381.1 140 3:64Time[min] Conc: 10.00mg/L No. Area . . . DateAcid Add. 1.500% Signal[mV] 20 Sp. Time 90.005ec Mean Area 75.Time[min] 'Conc: 1.000mg/L Area 1 .2 14 3:22:03 PM 10.27 14 3:26:47 PM 10.29 14 3:31: PM 2/3 55/71 REVISED REPORT PSW 31'4/2014 4:35:34 PM 030414W.132 ACidAdd. 1.500% 10 Sp. Time 90.0058C Mean Area 10.26 6 HM #3541 Time[min] Conc: 0.5000mg/L No. Area DatelTime iti??ti 43. 6118 until 6.095 1 4/20143: .1PM 5.719 1 4 - pm 5.93? 1 4 . PM AcidAdd. 1.500% 10 Sp. Time 90.005ec MeanArea 6.108 6 ml 3,547 Time[min] Conc: 0.000mg/L No. Area In]. Vol. Aut. Rem. Ex. DatelTime 1.725 . 1. 4: . :1614 PM 1.572 1 PM AcidAdd. 1.500% Signa [mV] 10 Sp. Time 90.0059c MeanArea 1.646 Time[min] 7-713 Area 852.17 Intercept 0.000 r?2 0.999906 . 0999953 500 Zero Shl100110 Conc[mg/L] 3/3 56/71 REVISED REPORT PSW Cal. Curve Sample Name: Sample ID: Cal. Curve: Status 3 p? Type Anal. Standard NPOC Conc: 100.0mglL Area 895. 906.7 .5 918.5 Acid Add. Sp. Time Mean Area Conc: 50.00mg/L Area .4 .6 Acid Add. Sp. Time Mean Area Conc: 10.00mg/L No. Area .46 Acid Add. Sp. Time Mean Area Cone: 1.000mg/L No. Area 1 :25 0.90 1.500% 90.005ec 907.2 i**li*l 1.500% 90.00360 447.1 1.500% 90.005ec 87.97 3f18/2014 7:49:56 AM Untitled Untitled Completed Signal[mV] 400 300 200 100 -40 1?20 4 3. 7/2014 3. 4 Signal[mVSignal[mV} 40 30 20 1O -4 Date Time 7 1 I 20 Time[min] Time[min] Time[min] 2/3 57/71 REVISED REPORT 58/71 PSW 3/18l2014 7:49:56 AM Acid Add. 1.500% Signai[mV] 1o Sp. Time 90.005ec 1 Mean Area 11.Timeimin] Conc: 0.5000mg/L No. Area Date Time 1 100u 17 100u 7/20 100u 7/2014 4: Acid Add. 1.500% SignaI[mV1 1O Sp. Time 90.005ec Mean Area 6.449 Time[min] Conc: 0.000mg/L Area 1.803 1: Acid Add. 1.500% Sig na [mV] 1O Sp. Time 90.005ec 1 Mean Area 1.719 Time[min] Slope: 9.041 Area 997.893 intercept 0.000 r"2 0.999926 800 0.999963 1 Zero Shift Yes 110 Conc[mg/L] 3/3 REVISED REPORT PSW instr. Information System Detector Catalyst Cell Length TOC WaterNew Combustion Regular Sensitivity long 3/18/2014 7:49:56 AM ?1/3 59/71 REVISED REPORT SW-846 9060A Continuing Calibration Data Print Date: 04/11/2014 N.C. Certification # 481 60/71 REVISED REPORT PSW Sample Sample Name: Sample ID: Origin: Status Chk. Result 3/24/2014 9:14:52 AM 9060A_TOC1_Waters.met Completed Type Anal. Dil. Result Mnknown NPOC 1.0001 1. Det Anal: NPOC No. Area Mean Area Mean Conc. 374.0 48.48mg/L 4 Sig nal[mV] 200 140 14 16 18 1N03022.t32 Timefmin] 2/27 61/71 REVISED REPORT PSW 3l24/2014 9:14:52 AM lN03022.t32 Sample Sample Name: ICV Sample lD: Origin: Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal: NPOC N0. Area lnj.Vol. Aut. Ex. . Date Dil. :38:58 PM 3 Mean Area 371.0 Signal[mV] Mean Conc. 48.09mglL 011?? 3391?.? Time[min] 14/27 62/71 i i REVISED REPORT PSW 3/27/2014 8:07:06 AM Sample Sample Name: Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. jDiI. Result Unknown NPOC 1.000 1. Det . Ana1.: NPOC No. Area In}. Vol} Aut. Ex. Date I Time Dil. Mean Area 435.4 Signal[mV] Mean Conc. 48.15mg/L I 34Time[min] 2/35 63/71 REVISED REPORT PSW 3/27/2014 8:07:06 AM N03034.t32 Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Result Unknown NPOC 1.000 1. Det Anal.: NPOC Date W201 14 W.2014 03 1 . 14 5:48:41 W.2014 14 03 Mean Area 430.1 Signa [mV] 200 Mean Conc. 47.57mgTime[min] 14/35 64/71 REVISED REPORT PSW 3/27/2014 8:07:06 AM N03034.t32 Sample Sample Name: ICV Sample ID: Origin: 9060AHTOC1HWatersmet Status Completed Chk. Result Type Anal. Dil? Result Unknown NPOC 1.000 1. Det Anal; NPOC N0. Area . Cal. Curve Date Time Mean Area 433.3 SignalImV] 200 Mean Conc. 47.92mg/L 140 05?? 71Time[min] 25/35 65/71 REVISED REPORT Analytical Blank Summary Form 3 Analytical Batch: INO3022 Units: mg/L Instrument: TOC1 Analyst: PSW Results by SW-846 9060A 132985 03/21/14 00:59 Total Organic Ca 1.00U 132988 03/21/14 16:58 1.00U 133306 03/26/14 13:11 1.00U Print Date: 04/11/2014 133309 03/26/14 18:06 1.00U 133311 03/26/14 22:24 1.00U N.C. Certification # 481 66/71 REVISED REPORT PSW 3/24/2014 9:14:52 AM [N03022.t32 Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1mWaters.met Status Completed Chk. Result Type Anal. 'Dil. Result Unknown NPOC 1.000 1. Del Anal: NPOC Mean Area 2.445 Signal[mV] 10 Mean Conc. 0.3170mg/L 65M 6 3rw"?Time[min] 3/27 67/71 REVISED REPORT PSW 3/24/2014 9:14:52 AM Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.00 1. Det Anal.: NPOC Area 0.501 0 3347 0. Mean Area 2.833 Signal[mV] 10 Mean Conc. 0.3673mgTimeImin] 15/27 68/71 REVISED REPORT PSW i 3/27/2014 8:07:06 AM INO3034.I32 Sample Sample Name: ?5 CBV Sample ID: 5 Origin: 2 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Pil. Result Unknown NPOC 1.00 1. De! I Anal; NPOC No. Area 4W 1 14 W201 Mean Area 2.241 Signa [mV] 10 Mean Conc. 0.2479mgTime[min] 3/35 69/71 REVISED REPORT PSW 3/27/2014 8:07:06 AM 1N03034.132 Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Diil. Result Unknown NPOC 1.000 1. Det Anal; NPOC No. Mean Area 2.044 Signal[mV] 10 Mean Conc. 0.2260mg/L 06?! 1.Time[min] 15/35 70/71 REVISED REPORT PSW Sample Sample Name: Sample ID: Origin: Status Chk. Result 312712014 8:07:06 AM 1N03034.t32 CBV 9060A_TOC1_Waters.met Completed Type Anal. Dili. Result Unknown NPOC 1.000 1. Det Ana .: NPOC Area :6 .3 7 77 1 Time :19 14 26:46 PM :55 4 10:30:59 PM Mean Area 1.697 1 Signal[mV] '10 Mean Conc. 0.1876mg1L 6 1'Time[min] 27135 71/71 REVISED REPORT Laboratory Report of Analysis To: Delaney Peterson ANCHOR ENVIRONMENTAL 720 Olive Way Suite 1900 Seattle, WA 98101 US Report Number: 31400427 Client Project: Patrick Bayou Dear Delaney Peterson, Enclosed are the results of the analytical services performed under the referenced project for the received samples and associated QC as applicable. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or services performed during this project, please call Amy J. Boehm at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you again on any additional analytical needs. Sincerely, SGS North America Inc. __________________________________________________________________ Jeannie Milholland Date Quality Director jeannie.milholland@sgs.com Print Date: 04/11/2014 N.C. Certification # 481 1/60 REVISED REPORT Laboratory Qualifiers Report Definitions DL Method, Instrument, or Estimated Detection Limit per Analytical Method CL Control Limits for the recovery result of a parameter LOQ Reporting Limit DF Dilution Factor RPD Relative Percent Difference LCS(D) Laboratory Control Spike (Duplicate) MS(D) Matrix Spike (Duplicate) MB Method Blank Qualifier Definitions * Recovery or RPD outside of control limits B Analyte was detected in the Lab Method Blank at a level above the LOQ U Undetected (Reported as ND or < DL) V Recovery is below quality control limit. The data has been validated based on a favorable signal-to-noise A Amount detected is less than the Lower Method Calibration Limit J Estimated Concentration. O The recovery of this analyte in the OPR is above the Method QC Limits and the reported concentration in E Amount detected is greater than the Upper Calibration Limit S The amount of analyte present has saturated the detector. This situation results in an Q Indicates the presence of a quantitative interference. This situation may result in an I Indicates the presence of a qualitative interference that could cause a false positive or an DPE Indicates the presence of a peak in the polychlorinated diphenylether channel that could TIC Tentatively Identified Compound and detection limit the sample may be biased high underestimation of the affected analyte(s) underestimation of the affected analyte(s) overestimation of the affected analyte(s) cause a false positive or an overestimation of the affected analyte(s) EMPC Estimated Maximum possible Concentration due to ion ratio failure ND Not Detected K Result is estimated due to ion ratio failure in High Resolution PCB Analysis P RPD > 40% between results of dual columns D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration range Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code definition is provided below: M1 Mis-identified peak Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content. Print Date: 04/11/2014 N.C. Certification # 481 2/60 REVISED REPORT Sample Summary Client Sample ID Lab Sample ID Collected Received Matrix PB099-1SWMID-140319-N PB099-1SWMID-140319-MD PB101.1-1SWMID-140319-N 31400427001 31400427002 31400427003 03/19/2014 17:13 03/19/2014 16:45 03/19/2014 17:45 03/20/2014 09:40 03/20/2014 09:40 03/20/2014 09:40 Water Water Water Print Date: 04/11/2014 N.C. Certification # 481 3/60 REVISED REPORT Case Narrative 9060A ­ Sample for analysis for DOC was filtered and preserved immediately upon receipt per SGS SOP. 2540­D ­ Revised report to J flag TSS results down to the MDL in order to meet the reporting limit requirements of the SAP for this project. Print Date: 04/08/2014 N.C. Certification # 481 4/60 REVISED REPORT Detectable Results Summary Client Sample ID: PB099-1SWMID-140319-N Lab Sample ID: 31400427001-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB099-1SWMID-140319-MD Lab Sample ID: 31400427002-A Parameter Total Organic Carbon SW-846 9060A Result Client Sample ID: PB101.1-1SWMID-140319-N Lab Sample ID: 31400427003-C Parameter Dissolved Organic Carbon SW-846 9060A Result Total Organic Carbon Print Date: 04/11/2014 12.1 11.9 10.9 10.9 Units mg/L Units mg/L Units mg/L mg/L N.C. Certification # 481 5/60 I - - Les-3mm PROJECT INFO: PROJECT: 0 LIOZ $314 0g P.0. OUOTE SITE REE: {Ad/Cg ?rm/J0 TURN AROUND TIME: REPORT LEVEL: (see reverse) E'fjifl LeveI I Level II ve IV LIVERABLES: Ef] State Of Origin: 51 Other: SPECIAL SEND DOCUMENTATION I RESULTS COMPANY CONTACT: 361M Rad?5" 72.0 IILC ADDRESS: CHAIN OF CUSTODY CONVENTIONAL SHALE SPECIAL INSTRUCTIONS I COMMENTS: 54:. I900 315100552; Jc?c- Mi WA 75/0/ PHONE: PRES ERVATIVE EMAIL: (?pdfasz-n INVOICE T0: IEIJCHECK IF SAME) 1711;); ,f r/ 4t d?ajell 'v I I COMPANY: CONTA it) ADDRESS: PHONE: Pi DIEWSILI EMAIL: 66+th I) . com SAMPLE ID OC MSD TYPE (C. G) CO NT. OTY DATE TIME MS DUP MATRIX .0- gale didi?l 1 I ME ?quE 6? 2 AIM 6' 541.5 10556177" - - #7031 61 agar/ml) Mag/?7 we? 6' 14142314 ~10 3/14/19 6' Luis . A A COLLECT DAT 4 14.1: 3 [7?70 RECEIVED BY. ?17/ ?x TIME: DAT TIME 594 d9. 40 COC SEAL INTACT BROKEN ABSENT RELINOUISHED BY (2): DATE: TIME: RECEIVED BY: BECEEPTTEMP cc 4 a CARRIER: I TRACKING Page of 363 NORTH AMERICA WC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405- r-nn :1 910 1903 910 791 1613 com ihnn rut REVISED REPORT REVISED REPORT 868 North America Inc. Sample Receipt Checklist (SRC) Client: Anchor Environmental Work Order No.: 31400427 1. LShipped Notes: Hand Delivered 2. COC Present on Receipt ?No coc :Additional Transmittal Forms 3. _Custody Tape on Container LNG Custody Tape 4. Samples Intact :Samples Broken Leaking 5. iChilled on Receipt Actual Temp.(s) in 4 Thermometer Login-1D _Ambient on Receipt _Walk-in on Ice; Coming down to temp. A Temperature Blank Present 6. iSuf?cient Sample Submitted Insufficient Sample Submitted 7. _Chlorine absent 2 LHCL 2 Additional Preservatives veri?ed (see notes) 8. Received Within Holding Time :Not Received Within Holding Time 9. LNG Discrepancies Noted Discrepancies Noted notified of Discrepancies? 10. No Headspace present in VOC vials Headspace present in VOC vials >6mm Comments: Inspected and Logged in by: RCH Date: Thu-3/20/14 00:00 7/60 must be notified when collection, holding time or preservation requirements are not met. Ml_11.7 REVISED REPORT SM 2540-D Sample Data Print Date: 04/11/2014 N.C. Certification 481 55111] Business US - EMDE-Wilmirmnn. ME IN 3103-51] 1903 1+1 310350155? wan-.595 cum 8/60 LII 1hr SEE SIM REVISED REPORT Results of PB099-1SWMID-140319-N Client Sample ID: PB099-1SWMID-140319-N Client Project ID: Patrick Bayou Lab Sample ID: 31400427001-C Lab Project ID: 31400427 Collection Date: 03/19/2014 17:13 Received Date: 03/20/2014 09:40 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 9.0 J 3.60 25.0 mg/L 1 03/24/2014 9:40 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:40 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 9/60 REVISED REPORT Results of PB099-1SWMID-140319-MD Client Sample ID: PB099-1SWMID-140319-MD Client Project ID: Patrick Bayou Lab Sample ID: 31400427002-C Lab Project ID: 31400427 Collection Date: 03/19/2014 16:45 Received Date: 03/20/2014 09:40 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 6.0 J 3.60 25.0 mg/L 1 03/24/2014 9:40 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:40 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 10/60 REVISED REPORT Results of PB101.1-1SWMID-140319-N Client Sample ID: PB101.1-1SWMID-140319-N Client Project ID: Patrick Bayou Lab Sample ID: 31400427003-E Lab Project ID: 31400427 Collection Date: 03/19/2014 17:45 Received Date: 03/20/2014 09:40 Matrix: Water Results by SM 2540-D Parameter Result Qual DL LOQ/CL Units DF Date Analyzed Total Suspended Solids 7.0 J 3.60 25.0 mg/L 1 03/24/2014 9:40 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:40 Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 11/60 REVISED REPORT 5500 Business Drive Total Suspended Solids a Wilmington, NC 28405 ?um man-m? ,?htj . SM 2540 Batch: INC 3027 Balance: BAL10 In Oven Date: 3/24/2014 Analyst: VS Oven: Oven #6 In Oven Time: 11:50 StandardlD: TSA15 In Oven Temp: 105 Out Oven Date: 3/24/2014 Out Oven Temp: 105 Out Oven Time: 15:00 Vol Filte Analyzed Filter Final Result Type Lab ID mL Lot Date Time 9 9 mg/L MB 132953 100 INV2 03/24/2014 9:39 0.1202 0.1199 -3 LCS 132954 25 INV2 03/24/2014 9:39 0.1214 0.1318 416 SAMPLE 31400422001 10 INV2 03/24/2014 9:40 0.1203 0.1226 230 DUP 132955 10 03/24/2014 9:40 0.1194 0.1213 190 SAMPLE 31400422002 10 03/24/2014 9:40 0.1185 0.1258 730 SAMPLE 31400401002 100 03/24/2014 9:40 0.1171 0.1241 70 . SAMPLE 31400420001 100 03/24/2014 9:40 0.1223 0.1228 5 SAMPLE 31400420002 100 INV2 03/24/2014 9:40 0.1182 0.1185 3 SAMPLE 31400420003 100 INV2 03/24/2014 9:40 0.1178 0.1183 5 SAMPLE 31400420004 100 INV2 03/24/2014 9:40 0.1184 0.1196 12 SAMPLE 31400420005 100 INV2 03/24/2014 9:40 0.1189 0.1195 6 SAMPLE 31400420006 100 INV2 03/24/2014 9:40 0.1190 0.1204 14 SAMPLE 31400427001 100 INV2 03/24/2014 9:40 0.1167 0.1176 SAMPLE 31400427002 100 INV2 03/24/2014 9:40 0.1192 0.1198 SAMPLE 31400427003 100 INV2 03/24/2014 9:40 0.1243 0.1250 3 '2?7-4 gay/ewe! Analyst Signature Date gr! WA Analyst signature indicates that the data printed is a true representation of volumes and weights encountered in the analytical process. Weights 3..)4141/ are obtained through overnight drying at 1050. (F2 - F1) 1,000,000 The calculation of T63 is: mg/L TSS V1 Where: Final (9) F1 Filter (9) Printed: 3/24/2014 3:00:40 PM V1 Vol (mL) 1 of1 Pages 12/60 REVISED REPORT SM 2540-D QC, Blanks Data Print Date: 04/11/2014 N.C. Certification # 481 13/60 REVISED REPORT Batch Summary Analytical Method: SM 2540-D Prep Method: Prep Batch: Prep Date: SM 2540-D INO3027 03/24/2014 09:39 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41522 [INO/3027] 132953 03/24/2014 09:39 INO3027 BAL10 VS LCS for HBN 41522 [INO/3027] 132954 03/24/2014 09:39 INO3027 BAL10 VS V13501(132775DUP) 132955 03/24/2014 09:40 INO3027 BAL10 VS PB099-1SWMID-140319-N 31400427001 03/24/2014 09:40 INO3027 BAL10 VS PB099-1SWMID-140319-MD 31400427002 03/24/2014 09:40 INO3027 BAL10 VS PB101.1-1SWMID-140319-N 31400427003 03/24/2014 09:40 INO3027 BAL10 VS Print Date: 04/11/2014 N.C. Certification # 481 14/60 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41522 [INO/3027] Blank Lab ID: 132953 Prep Batch: INO3027 Matrix: Water Analysis Date/Time: 03/24/2014 09:39 Results by SM 2540-D Client Sample ID Lab Sample ID LCS for HBN 41522 [INO/3027] Date Analyzed Analyst 132954 03/24/2014 09:39 VS V13501(132775DUP) 132955 03/24/2014 09:40 VS PB099-1SWMID-140319-N 31400427001 03/24/2014 09:40 VS PB099-1SWMID-140319-MD 31400427002 03/24/2014 09:40 VS PB101.1-1SWMID-140319-N 31400427003 03/24/2014 09:40 VS Print Date: 04/11/2014 Filename N.C. Certification # 481 15/60 REVISED REPORT Method Blank Blank ID: MB for HBN 41522 [INO/3027] Blank Lab ID: 132953 Matrix: Water QC for Samples: 31400427001, 31400427002, 31400427003 Results by SM 2540-D Parameter Result Total Suspended Solids ND Qual DL LOQ/CL Units DF 3.60 25.0 mg/L 1 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 3/24/2014 9:39:56AM Prep Initial Wt./Vol.: 1 mL Prep Extract Vol: 1 mL Print Date: 04/25/2014 N.C. Certification # 481 16/60 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41522 [INO/3027] Blank Spike Lab ID: 132954 Date Analyzed: 03/24/2014 09:39 Matrix: Water QC for Samples: 31400427001, 31400427002, 31400427003 Results by SM 2540-D Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Suspended Solids 500 416 83 80.0-120 Batch Information Analytical Batch: INO3027 Analytical Method: SM 2540-D Instrument: BAL10 Analyst: VS Prep Batch: INO3027 Prep Method: SM 2540-D Prep Date/Time: 03/24/2014 09:39 Spike Init Wt./Vol.: 1 mL Extract Vol: 1 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 17/60 REVISED REPORT SW-846 9060A Sample Data Print Date: 04/11/2014 N.C. Certification # 481 18/60 REVISED REPORT Results of PB099-1SWMID-140319-N Client Sample ID: PB099-1SWMID-140319-N Client Project ID: Patrick Bayou Lab Sample ID: 31400427001-A Lab Project ID: 31400427 Collection Date: 03/19/2014 17:13 Received Date: 03/20/2014 09:40 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 12.1 Units mg/L DF 1 Date Analyzed 03/26/2014 15:17 Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 03/26/2014 15:17 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 19/60 REVISED REPORT PSW 3/27/2014 8:07:06 AM Sample Sample Name: 427_1 Sample ID: I Origin: Status Completed Chk. Result Type Anal. Result 4 {Unknown NPOC 1.000 1. Det Anal.: NPOC N0. Area Inj. Vol. Aut: Dil. Mean Area 109.3 Signal[mV] Mean Conc. 12.09mg/L 337Time[min] 7/35 20/60 REVISED REPORT Results of PB099-1SWMID-140319-MD Client Sample ID: PB099-1SWMID-140319-MD Client Project ID: Patrick Bayou Lab Sample ID: 31400427002-A Lab Project ID: 31400427 Collection Date: 03/19/2014 16:45 Received Date: 03/20/2014 09:40 Matrix: Water Results by SW-846 9060A Parameter Total Organic Carbon Result Qual LOQ/CL 1.00 11.9 Units mg/L DF 1 Date Analyzed 03/26/2014 16:19 Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 03/26/2014 16:19 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 21/60 I 1 REVISED REPORT PSW 3/27/2014 8:07:06 AM 1N03034.t32 Samp1e 1 Sample Name: 5 427_2 Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Result Unknown NPOC 1.000 1. Det Anal.: NPOC Curve 1 . 7 14 28 41.081 14 4' 17 14 28 41.ca 14 . 14 4:28:02 PM Mean Area 107.2 Signa [mV] 40 Mean Conc. 11.86mg/L 30 W1 31,Time[min] i 10/35 22/60 REVISED REPORT Results of PB101.1-1SWMID-140319-N Client Sample ID: PB101.1-1SWMID-140319-N Client Project ID: Patrick Bayou Lab Sample ID: 31400427003-C Lab Project ID: 31400427 Collection Date: 03/19/2014 17:45 Received Date: 03/20/2014 09:40 Matrix: Water Results by SW-846 9060A Parameter Dissolved Organic Carbon Total Organic Carbon Result Qual LOQ/CL 1.00 1.00 10.9 10.9 Units mg/L mg/L DF 1 1 Date Analyzed 03/27/2014 0:11 03/26/2014 16:40 Batch Information Analytical Batch: INO3023 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3023 Prep Method: SW-846 9060A Prep Date/Time: 03/27/2014 00:11 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 03/26/2014 16:40 Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 23/60 REVISED REPORT PSW Sampie Sample Name: Sample ID: Origin: Status Chk. Result 427_3 3/27l2014 8:07:06 AM 9060A_TOC1_Waters.met Completed Type Anal. Resuit Unknown NPOC 1.000 IL 1. Det Ana .: NPOC No. Area Mean Area Mean Conc. 98.65 10.91mg/L Signal[mVTime[min] 32/35 24/60 PSW Sample Sample Name: Sample ID: Origin: Status Chk. Result REVISED REPORT 3/27/2014 8:07:05 AM 427_3 9060A__TOC1_Water5.met Completed Type Anal. Result Unknown NPOC 1. Del Anal: NPOC No. GoneMean Area 98.81 Mean Conc. 10.93mglL i i ?l 71 4W. Signal[mV] 40 30 20 1O -4 11/35 25/60 INO3034.132 Time[min] REVISED REPORT SW-846 9060A QC, Blanks Data Print Date: 04/11/2014 N.C. Certification # 481 26/60 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3023 03/26/2014 23:29 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB-F1 for HBN 41502 [INO/3023] 132800 03/26/2014 23:29 INO3023 TOC1 PSW LCS for HBN 41502 [INO/3023] 132801 03/26/2014 23:51 INO3023 TOC1 PSW PB101.1-1SWMID-140319-N 31400427003 03/27/2014 00:11 INO3023 TOC1 PSW PB101.1-1SWMID-1...(132798DUP) 132799 03/27/2014 00:31 INO3023 TOC1 PSW Print Date: 04/11/2014 N.C. Certification # 481 27/60 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB-F1 for HBN 41502 [INO/3023] Blank Lab ID: 132800 Prep Batch: INO3023 Matrix: Water Analysis Date/Time: 03/26/2014 23:29 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41502 (INO/3023) 133315 INO3023.csv 03/26/2014 22:24 PSW LCS for HBN 41502 [INO/3023] 132801 INO3023.csv 03/26/2014 23:51 PSW PB101.1-1SWMID-140319-N 31400427003 INO3023.csv 03/27/2014 00:11 PSW PB101.1-1SWMID-1...(132798DUP) 132799 INO3023.csv 03/27/2014 00:31 PSW CBV for HBN 41502 (INO/3023) 133318 INO3023.csv 03/27/2014 01:12 PSW Print Date: 04/11/2014 N.C. Certification # 481 28/60 REVISED REPORT Method Blank Blank ID: MB-F1 for HBN 41502 [INO/3023] Blank Lab ID: 132800 Matrix: Water QC for Samples: 31400427003 Results by SW-846 9060A Parameter Result Dissolved Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3023 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3023 Prep Method: SW-846 9060A Prep Date/Time: 3/26/2014 11:29:46PM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 29/60 i REVISED REPORT PSW 3/27/2014 8:07:06 AM 1N03034.t32 Sample Sample Name: 132800 MB-F1 Sample ID: Origin: 2 Status Completed Chk. Result Type Anal. DEE. Result Unknown NPOC 1.000 [013000.21 13mg/L 1. Det Anal.: NPOC Area Curve Time 2. 14 28 4 :29246 :32:SignalImV] 10 3 Mean Area 1.910 Mean Conc. 0.2113mglL 3,Time[mln] 30/35 30/60 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41502 [INO/3023] Blank Spike Lab ID: 132801 Date Analyzed: 03/26/2014 23:51 Matrix: Water QC for Samples: 31400427003 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Dissolved Organic Carbon 50.0 47.5 95 90.0-110 Batch Information Analytical Batch: INO3023 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3023 Prep Method: SW-846 9060A Prep Date/Time: 03/26/2014 23:51 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 31/60 REVISED REPORT PSW 3/27/2014 8:07:06 AM Sample 5 Sample Name: 132801 LCS Sample ID: Origin: 9060A_TOC1_Water5.met Status 3 Completed Chk. Result Type Anal. Dili Result Unknown NPOC i 1.000 1. De! I Anal.: NPOC No. Date I Time Mean Area 4297 i Signal[mV] Mean Conc. 47.52mg/L 03TimeImin] 31/35 32/60 REVISED REPORT Duplicate Sample Summary Original Sample ID: 31400427003-C Duplicate Sample ID: 132799 QC for Samples: Analysis Date: 03/27/2014 00:11 Analysis Date: 03/27/2014 00:31 Matrix: Water 31400427003 Results by SW-846 9060A PARAMETER Dissolved Organic Carbon Original (mg/L) 10.9 Qual Duplicate (mg/L) 11.4 Qual RPD (%) 4.5 RPD CL Batch Information Analytical Batch: INO3023 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Print Date: 04/11/2014 N.C. Certification # 481 33/60 1 1 5 REVISED REPORT PSW 3/27/2014 8:07:06 AM lN03034.t32 Sample Sample Name: 132799 DUP Sample ID: 2 Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. 00% Result Unknown NPOC 1.000 1. Det Anal.: NPOC No. Area . . . urve 17 14 28 41. 103.9 . 7 14 28 41. 101. . 7 14 28 41.Ca . . 4 031714 28 41. Mean Area 103.3 Signal[mV] 40 Mean Conc. 11.42mgTime[min] 33/35 34/60 REVISED REPORT Batch Summary Analytical Method: SW-846 9060A Prep Method: Prep Batch: Prep Date: SW-846 9060A INO3034 03/26/2014 14:38 Client Sample ID Lab Sample ID Analysis Date Analytical Batch Instrument Analyst MB for HBN 41852 [INO/3034] 133117 03/26/2014 14:38 INO3034 TOC1 PSW LCS for HBN 41852 [INO/3034] 133118 03/26/2014 14:57 INO3034 TOC1 PSW PB099-1SWMID-140319-N 31400427001 03/26/2014 15:17 INO3034 TOC1 PSW PB099-1SWMID-1403...(132796MS) 133119 03/26/2014 15:36 INO3034 TOC1 PSW PB099-1SWMID-140...(132796MSD) 133120 03/26/2014 15:59 INO3034 TOC1 PSW PB099-1SWMID-140319-MD 31400427002 03/26/2014 16:19 INO3034 TOC1 PSW PB101.1-1SWMID-140319-N 31400427003 03/26/2014 16:40 INO3034 TOC1 PSW PB095-1SWMID-140...(132717DUP) 132792 03/26/2014 17:25 INO3034 TOC1 PSW Print Date: 04/11/2014 N.C. Certification # 481 35/60 REVISED REPORT Method Blank Summary Form 4 Blank ID: MB for HBN 41852 [INO/3034] Blank Lab ID: 133117 Prep Batch: INO3034 Matrix: Water Analysis Date/Time: 03/26/2014 14:38 Results by SW-846 9060A Client Sample ID Lab Sample ID Filename Date Analyzed Analyst CBV for HBN 41852 (INO/3034) 133306 INO3034.csv 03/26/2014 13:11 PSW LCS for HBN 41852 [INO/3034] 133118 INO3034.csv 03/26/2014 14:57 PSW PB099-1SWMID-140319-N 31400427001 INO3034.csv 03/26/2014 15:17 PSW PB099-1SWMID-1403...(132796MS) 133119 INO3034.csv 03/26/2014 15:36 PSW PB099-1SWMID-140...(132796MSD) 133120 INO3034.csv 03/26/2014 15:59 PSW PB099-1SWMID-140319-MD 31400427002 INO3034.csv 03/26/2014 16:19 PSW PB101.1-1SWMID-140319-N 31400427003 INO3034.csv 03/26/2014 16:40 PSW PB095-1SWMID-140...(132717DUP) 132792 INO3034.csv 03/26/2014 17:25 PSW CBV for HBN 41852 (INO/3034) 133309 INO3034.csv 03/26/2014 18:06 PSW Print Date: 04/11/2014 N.C. Certification # 481 36/60 REVISED REPORT Method Blank Blank ID: MB for HBN 41852 [INO/3034] Blank Lab ID: 133117 Matrix: Water QC for Samples: 31400427001, 31400427002, 31400427003 Results by SW-846 9060A Parameter Result Total Organic Carbon ND Qual LOQ/CL Units DF 1.00 mg/L 1 Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 3/26/2014 2:38:03PM Prep Initial Wt./Vol.: 40 mL Prep Extract Vol: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 37/60 REVISED REPORT PSW 3/27/2014 8:07:06 AM lNO3034.t32 Sample Sample Name: 133117 MB Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. EEil. Result Unknown NPOC 1.000 i 1. Det Anal: NPOC i No. . . . Date I Time . 14 .828 714W .807 . 7 4W.201 1.903 71 Mean Area 1.877 Signal[mV] 10 Mean Conc. 0.2077mgTime[min] 5/35 38/60 REVISED REPORT Blank Spike Summary Blank Spike ID: LCS for HBN 41852 [INO/3034] Blank Spike Lab ID: 133118 Date Analyzed: 03/26/2014 14:57 Matrix: Water QC for Samples: 31400427001, 31400427002, 31400427003 Results by SW-846 9060A Blank Spike (mg/L) Parameter Spike Result Rec (%) CL Total Organic Carbon 50.0 47.7 95 90.0-110 Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 03/26/2014 14:57 Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL Dupe Init Wt./Vol.: Extract Vol: Print Date: 04/11/2014 N.C. Certification # 481 39/60 i REVISED REPORT PSW 3/27/2014 8:07:06 AM 1N03034.t32 Sample Sample Name: i 133113 LCS Sample ID: Origin: Status 5 Completed Chk. Result Type Anal. 15:111. Result Unknown NPOC 1.000 1. Det . Anal: NPOC No. Area . . 14 3:00343 PM 429.2 47. 7 . 1 3:03:32 PM 436.8 48.31 . - mean?rea 3316/3 Signal[mV] 200 ean onc. . mg 43'" 140 17Tlmelmln] 6/35 40/60 REVISED REPORT Matrix Spike Summary Original Sample ID: 31400427001 (PB099-1SWMID-140319-N) MS Sample ID: 133119 MSD Sample ID: 133120 QC for Samples: Analysis Date: 03/26/2014 15:17 Analysis Date: 03/26/2014 15:36 Analysis Date: 03/26/2014 15:59 Matrix: Water 31400427001, 31400427002, 31400427003 Results by SW-846 9060A Matrix Spike (mg/L) Parameter Total Organic Carbon Sample 12.1 Spike 50.0 Result 60.5 Spike Duplicate (mg/L) Rec (%) 97 Spike 50.0 Result 60.2 Rec (%) CL RPD (%) 96 75.0-125 0.50 RPD CL 25.00 Batch Information Analytical Batch: INO3034 Analytical Method: SW-846 9060A Instrument: TOC1 Analyst: PSW Prep Batch: INO3034 Prep Method: SW-846 9060A Prep Date/Time: 03/26/2014 15:17 MS Init Wt./Vol.: 40 mL Extract Vol.: 40 mL MSD Init Wt./Vol.: 40 mL Extract Vol.: 40 mL Print Date: 04/11/2014 N.C. Certification # 481 41/60 I a REVISED REPORT 5 PSW 3/27/2014 8:07:06 AM N03034.t32 Sample Sample Name: 133119 MS Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result . Type Anal. ?il. Result Unknown NPOC 1.000 1. Del Anal: NPOC ea Conc. .91 59.77 61.1 60.2 Mean Area 547.2 Mean Conc. 60.52mg/L 3,73%? Cal.2014 03 1 1 Signal[mV] 200 140 70 Date I Time :47:Time[min] 8/35 42/60 i REVISED REPORT PSW 3/27/2014 8:07:06 AM lN03034.t32 Sample . Sample Name: 133120 MSD Sample ID: Origin: Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.00 1. Det Ana .: NPOC Mean Area 543.9 Signa [mV] 200 Mean Conc. 60.15mg/L gayTime[min] 9/35 43/60 REVISED REPORT SW-846 9060A Prep, Standard, Run Logs Print Date: 04/11/2014 N.C. Certification # 481 44/60 Method: Matrix: Initial Cal. Curve: 9060 Water 868 Environmental Services TOC Runlog Sheet Batch Primary Lot# Secondary Lot# INO3034 IMO 3025 SAMPLE ID DILUTION DATE TIME OPER pH Comments f'lcvw 3/26/2014 12:50 PSW 3/26/2014 13:11 PSW NEG 3/26/2014 14:19 PSW 133117 MB 3/26/2014 14:38 PSW 133118 Los/ 3/26/2014 14:57 PSW 427_1 3/26/2014 15:17 PSW 133119 MS 3/26/2014 15:36 PSW 45/ 133120 MSD c/ 3/26/2014 15:59 PSW 427_2 3/26/2014 16:19 PSW 427_3 3/26/2014 16:40 PSW 132792 DUP 3/26/2014 17:03 PSW 3/26/2014 17:25 PSW Mm ICV 3/26/2014 17:45 PSW CBV 3126/2014 18:06 PSW 420_5 3/26/2014 18:27 PSW 434_25 3/26/2014 18:46 PSW 434_26 3/26/2014 19:07 PSW 434_27 3/26/2014 19:28 PSW 1 434_28 3/26/2014 19:50 PSW 434_29 3/26/2014 20:13 PSW 53430 3/26/2014 20:36 PSW Analyst: REVISED REPORT SGS Environmental Services TOC Runlog Sheet Method: 9060 Batch: INO3034 Matrix: Water Primary Lot#: Initial Cal. Curve: Secondary Lol#: D-455 SAMPLE ID DILUTION DATE TIME OPER QC pH Comments 434-31 3/26/2014 20:57 PSW 434_32 3/2'072014 21 :20? PSW 3/26/2014 21 :42 PSW 3/26/2014 22:03 PSW 0 A902 3/26/2014 22:24 PSW 434-34 3/26/2014 22:45 PSW 434.35 3/26/2014 23:08 PSW 132800 MB-F1 3/26/2014 23:29 PSW 132801 L05 1/ 3/26/2014 23:51 PSW 91/2940! 427-3 3/27/2014 0:11 PSW REVISED REPORT .L 132799 DUP 3/27/2014 0:31 PSW 3/27/2014 0:51 PSW CBV 1/ 3/27/2014 1:12 PSW Analyst: REVISED REPORT SW-846 9060A Initial Calibration Data Print Date: 04/11/2014 N.C. Certification # 481 47/60 REVISED REPORT PSW Cal. Curve Sample Name: Sample ID: Cal. Curve: Status 3 p? Type Anal. Standard NPOC Conc: 100.0mglL Area 895. 906.7 .5 918.5 Acid Add. Sp. Time Mean Area Conc: 50.00mg/L Area .4 .6 Acid Add. Sp. Time Mean Area Conc: 10.00mg/L No. Area .46 Acid Add. Sp. Time Mean Area Cone: 1.000mg/L No. Area 1 :25 0.90 1.500% 90.005ec 907.2 i**li*l 1.500% 90.00360 447.1 1.500% 90.005ec 87.97 3f18/2014 7:49:56 AM Untitled Untitled Completed Signal[mV] 400 300 200 100 -40 1?20 4 3. 7/2014 3. 4 Signal[mVSignal[mV} 40 30 20 1O -4 Date Time 7 1 I 20 Time[min] Time[min] Time[min] 2/3 48/60 REVISED REPORT 49/60 PSW 3/18l2014 7:49:56 AM Acid Add. 1.500% Signai[mV] 1o Sp. Time 90.005ec 1 Mean Area 11.Timeimin] Conc: 0.5000mg/L No. Area Date Time 1 100u 17 100u 7/20 100u 7/2014 4: Acid Add. 1.500% SignaI[mV1 1O Sp. Time 90.005ec Mean Area 6.449 Time[min] Conc: 0.000mg/L Area 1.803 1: Acid Add. 1.500% Sig na [mV] 1O Sp. Time 90.005ec 1 Mean Area 1.719 Time[min] Slope: 9.041 Area 997.893 intercept 0.000 r"2 0.999926 800 0.999963 1 Zero Shift Yes 110 Conc[mg/L] 3/3 REVISED REPORT PSW instr. Information System Detector Catalyst Cell Length TOC WaterNew Combustion Regular Sensitivity long 3/18/2014 7:49:56 AM ?1/3 50/60 REVISED REPORT SW-846 9060A Continuing Calibration Data Print Date: 04/11/2014 N.C. Certification # 481 51/60 i i REVISED REPORT PSW 3/27/2014 8:07:06 AM Sample Sample Name: Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. jDiI. Result Unknown NPOC 1.000 1. Det . Ana1.: NPOC No. Area In}. Vol} Aut. Ex. Date I Time Dil. Mean Area 435.4 Signal[mV] Mean Conc. 48.15mg/L I 34Time[min] 2/35 52/60 REVISED REPORT PSW 3/27/2014 8:07:06 AM N03034.t32 Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Result Unknown NPOC 1.000 1. Det Anal.: NPOC Date W201 14 W.2014 03 1 . 14 5:48:41 W.2014 14 03 Mean Area 430.1 Signa [mV] 200 Mean Conc. 47.57mgTime[min] 14/35 53/60 REVISED REPORT PSW 3/27/2014 8:07:06 AM N03034.t32 Sample Sample Name: ICV Sample ID: Origin: 9060AHTOC1HWatersmet Status Completed Chk. Result Type Anal. Dil? Result Unknown NPOC 1.000 1. Det Anal; NPOC N0. Area . Cal. Curve Date Time Mean Area 433.3 SignalImV] 200 Mean Conc. 47.92mg/L 140 05?? 71Time[min] 25/35 54/60 REVISED REPORT PSW 3/27/2014 8:07:06 AM lN03034.132 Sample Sample Name: ICV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Dil. Result Unknown NPOC 1.000 1. Det Anal: NPOC Area 47187 47 Mean Area 430.2 Signa [mV] 200 Mean Conc. 47.58mg/L 5 140 .4 y??Time[min] 34/ 35 55/60 REVISED REPORT Analytical Blank Summary Form 3 Analytical Batch: INO3034 Units: mg/L Instrument: TOC1 Analyst: PSW Results by SW-846 9060A 133306 03/26/14 13:11 Dissolved Organ Total Organic Ca 133309 03/26/14 18:06 133315 03/26/14 22:24 1.00U 1.00U 133318 03/27/14 01:12 1.00U 1.00U Print Date: 04/11/2014 N.C. Certification # 481 56/60 REVISED REPORT PSW i 3/27/2014 8:07:06 AM INO3034.I32 Sample Sample Name: ?5 CBV Sample ID: 5 Origin: 2 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Pil. Result Unknown NPOC 1.00 1. De! I Anal; NPOC No. Area 4W 1 14 W201 Mean Area 2.241 Signa [mV] 10 Mean Conc. 0.2479mgTime[min] 3/35 57/60 REVISED REPORT PSW 3/27/2014 8:07:06 AM lN03034.132 Sample Sample Name: CBV Sample ID: Origin: 9060A_TOC1_Waters.met Status Completed Chk. Result Type Anal. Diil. Result Unknown NPOC 1.000 1. Det Anal; NPOC No. Mean Area 2.044 Signal[mV] 10 Mean Conc. 0.2260mg/L 06?! 1.Time[min] 15/35 58/60 REVISED REPORT PSW Sample Sample Name: Sample ID: Origin: Status Chk. Result 312712014 8:07:06 AM 1N03034.t32 CBV 9060A_TOC1_Waters.met Completed Type Anal. Dili. Result Unknown NPOC 1.000 1. Det Ana .: NPOC Area :6 .3 7 77 1 Time :19 14 26:46 PM :55 4 10:30:59 PM Mean Area 1.697 1 Signal[mV] '10 Mean Conc. 0.1876mg1L 6 1'Time[min] 27135 59/60 REVISED REPORT PSW 3/27/2034 8:07:06 AM N03034.t32 Sample Sample Name: CBV Sample ID: Origln: 9060A_TOC1_Waters.met Status Completed Chk. Result ype 1. Del Ana .: NPOC No. Area .49 Mean Area 1.955 Signal[mV] Mean Conc. 0.2163mgfL 6% 31Time[min] 35/35 60/60 1 of 515 2 APRIL 2014 DELANEY PETERSON ANCHOR QEA 7200 Olive Way, Ste 300 Seattle WA 98101 t. 206-287-9130 e. DPeterson@anchorqea.com SUBJECT: CERTIFICATE OF RESULTS Dear Delaney; Attached to this narrative are the analytical results for sample(s) submitted for the determination of polychlorinated biphenyl congeners. The insert below summarizes information about the project. If applicable, QC annotations below highlight specific analytical observations and assessments made during the sample handling and data interpretation phases. Results reported relate only to the items tested. PROJECT INFORMATION SUMMARY (When applicable, see QC Annotations for details) Client Project Patrick Bayou Superfund Ste SGS Project # A6492 Analytical Protocol(s) Method 1668A No. Samples Submitted 5 Additional QC Sample(s) 0 No. Laboratory Method Blanks 1 No. OPRs / Batch CS3 1 Date Received 12-Mar-2014 Condition Received good Temperature upon Receipt (C) 2.2 - 3.4 Extraction within Holding Time yes Analysis within Holding Time yes SGS Environmental Services 5500 Business Drive Wilmington, NC 28405 +1 910 350 1903 +1 866 846 8290 www.sgs.com Member of the SGS Group (SGS SA) 2 of 515 + - , - " ! ? " ( " ! < - ! " = - ( ; < ! $ ! " ' < ! " $ ! " # $ " % " & $ & " " ! ' ( ) & ! ! * ! " ( ( ! ( ) = ! ! " ( ( - ; ! & > ; / 0 = " - . ) 1 $ ' 2 ' - ! - - 4 ! = $ ! 5 ( ! ( ' / ! ' 3 ( ! ! ( % ( $ " < " 0 ! & / " ( ! @ ' " " ! ! $ " ) ' ! $ < 6 7 8 9 ) # ( $ ! " " ! ! " " ! : " ! ! & - $ > @ ! ! < A 4 ( B = A < @ > ! " ' = ! ! ! ! $ " $ $ " < ) ) ( " " ! < ! ? $ " @ ) ! $ - > Digitally signed by Amy Boehm Date: 2014.04.02 17:34:31 -04'00' - ( ) C ! " D " ! ! * ( E = " 3 of 515 APPENDIX A: GENERAL DATA QUALIFIERS / DATA ATTRIBUTES B The analyte was found in the method blank, at a concentration that was at least 10% of the concentration in the sample. C Two or more congeners co-elute. In EDDs, C denotes the lowest IUPAC congener in a co-elution group and additional co-eluters for the group are shown with the number of the lowest IUPAC co-eluter. E The reported concentration exceeds the calibration range (upper point of the calibration curve) and is an estimated value. EMPC Represents an Estimated Maximum Possible Concentration. EMPCs arise in cases where the signal/noise ratio is not sufficient for peak identification (the determined ion-abundance ratio is outside the allowed theoretical range), or where there is a co-eluting interference. H/h If the standard recovery is below the method or SOP specified value “H” is assigned. If the obtained value is less than half the specified value “h” is assigned.1 J Indicates that an analyte has a concentration below the reporting limit (lowest point of the calibration curve) and is an estimated value. ND Indicates a non-detect. NR Indicates a value that is not reportable. PR Due to interference, the associated congener is poorly resolved. QI Indicates the presence of a quantitative interference. SI Denotes “Single Ion Mode” and is utilized for PCBs where the secondary ion trace has a significantly elevated noise level due to background PFK. Responses for such peaks are calculated using an EMPC approach based solely on the primary ion area(s) and may be considered estimates.1 U The analyte was not detected. The estimated detection limit (EDL) may be reported for this analyte. V The labeled standard recovery was found to be outside of the method control limits. Page 3 of 5 4 of 515 APPENDIX B: DRBC/TMDL SPECIFIC DATA QUALIFIERS / DATA ATTRIBUTES J The reported result is an estimate. The value is less than the minimum calibration level but greater than the estimated detection limit (EDL). U The analyte was not detected in the sample at the estimated detection limit (EDL). E The reported concentration is an estimate. The value exceeds the upper calibration range (upper point of the calibration curve). D Dilution Data. Result was obtained from the analysis of a dilution. B Analyte found in the sample and associated method blank. C Co-eluting congener Cxx Co-elutes with the indicated congener, data is reported under the lowest IUPAC congener. ‘Xx’ denotes the IUPAC number with the lowest numerical designated congener. NR Analyte is not reportable because of problems in sample preparation or analysis. V Labeled standard recovery is not within method control limits. X Results from re-injection/repeat/second-column analysis. EMPC Estimated maximum possible concentration. Indicates that a peak is identified but did not meet the method specified ion-abundance ratio. APPENDIX C: LAB IDENTIFIERS AR Indicates use of the archived portion of the sample extract. CU Indicates a sample that required additional clean-up prior to MS injection/processing. D Indicates a dilution of the sample extract. The number that follows the “D” indicates the dilution factor. DE Indicates a dilution performed with the addition of ES (extraction standard) solution. DUP Designation for a duplicate sample. MS Designation for a matrix spike. MSD Designation for a matrix spike duplicate. RJ Indicates a reinjection of the sample extract. S Indicates a sample split. The number that follows the “S” indicates the split factor. Page 4 of 5 5 of 515 SGS CERTIFICATIONS California 07255CA Connecticut PH-0258 Florida (primary NELAP) E87634 ISO17025 2726.01 Kansas E-10330 Louisiana 04115 Maryland (DW only) 299 New Jersey NC100 New York 11685 North Carolina DENR 481 North Carolina DHHS (DW only) 37776 North Dakota R-197 Oregon NC200002 Pennsylvania 68-03675 South Carolina 99029 Texas T104704260-13-5 Utah NC009192013-3 Virginia (DW only) 00235 Virginia 460214 Washington State C913 West Virginia 293 Page 5 of 5 6 of 515 A6492 Project ID: Patrick Bayou Sample Summary Analyte PB006.2-1 PB006.2-1 PB006.2-1 PB006.2-1 Method Blank SWMID-140311- SWMID-140311- SWMID-140311- SWMID-140311A6492 N (Dissolved) D (Total) D (Dissolved) N (Total) HSC14.11SWMID140311-N (Total) Conc. pg/L Conc. pg/L Conc. pg/L Conc. pg/L Conc. pg/L Conc. pg/L PCB-77 PCB-81 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-156/157 PCB-167 PCB-169 PCB-189 (2.89) (2.89) (2.31) (2.08) (2.2) (2.24) (2.79) (4.73) (3.35) (3.77) (3.12) 102 (4.33) 308 16.7 600 14.2 (2.52) 37.8 [11.1] (3.1) (2.86) 30 (4.6) 77.4 (3.95) 145 (4.09) (3.32) 6.59 (3.55) (4.87) (3.59) 196 (10.2) 591 26.3 1170 24.6 (6.96) [78.6] 28 (10.1) (7.82) 35.1 (3.33) 78.1 (3) 157 4.17 (2.62) [7.6] (2.54) (3.16) (3.28) 3.38 (2.77) 15.9 (2.74) 42.7 (2.98) (2.32) 5.72 (2.95) (3.57) (2.49) Total Mono-CBs Total Di-CBs Total Tri-CBs Total Tetra-CBs Total Penta-CBs Total Hexa-CBs Total Hepta-CBs Total Octa-CBs Total Nona-CBs PCB-209 (1.7) 6.09 (3.51) (2.85) (2.28) (3.46) (3.41) (3.98) (6.36) (7.08) 44.7 622 5850 12700 5300 1610 524 156 148 1680 39.4 512 4190 6340 1660 294 61.3 9.37 7.57 189 56.6 908 9650 20800 9860 3010 941 149 289 3660 33.2 603 4670 6560 1630 357 75.2 7.46 7.1 196 6.04 190 590 637 388 204 34.6 [5.05] (5.6) 44.1 0 0 0.0395 0.0399 0.00988 0.00988 0.0748 0.0771 0.0107 0.0109 0.00227 0.00227 ND = DL/2; EMPC = 0 ND = DL/2; EMPC = EMPC 0.197 0.197 0.213 0.213 0.25 0.25 0.577 0.579 0.19 0.19 0.172 0.172 ND = DL; EMPC = 0 ND = DL; EMPC = EMPC 0.394 0.394 0.386 0.386 0.49 0.49 1.08 1.08 0.369 0.369 0.343 0.343 553-005-XNW 712-582-BWJ 148-327-GVW 911-445-NVG 444-564-YLD 058-314-YQZ TEQs (WHO 2005 M/H) ND = 0; EMPC = 0 ND = 0; EMPC = EMPC Checkcode () = DL [] = EMPC Method 1668A 7 of 515 A6492 Project ID: Patrick Bayou PCB Recoveries Standard ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 Checkcode () = DL [] = EMPC Method 1668A PB006.2-1 PB006.2-1 PB006.2-1 PB006.2-1 Method Blank SWMID-140311- SWMID-140311- SWMID-140311- SWMID-140311A6492 D (Total) D (Dissolved) N (Total) N (Dissolved) HSC14.11SWMID140311-N (Total) 72.4 76.3 84.2 78.4 86.9 80.4 88.2 82.9 81.8 89.1 92.6 93.8 94.9 91.5 86 87 82.5 85.8 86.9 81.9 90.5 87.3 89.2 90.3 89.8 87.3 84.2 92.7 77.8 70.1 75.8 82.4 86.8 86.6 85 90.9 86.5 85.2 96 94.8 96.9 99.9 98.2 87.5 96.5 90.8 93.6 95 84.6 92.7 93.1 95.8 97.7 94.4 91.2 90.3 99.8 82.2 68.7 77.9 83.7 86.5 93.4 89.9 97.1 92.6 94.2 94.5 101 101 108 102 91.4 97.4 89.9 94.3 98 86.6 97.5 94.1 95.4 102 97.4 93.9 93.9 102 85.8 42.7 49.9 51.8 63.1 55.9 78.9 63.6 86.8 83.9 67.9 89.1 90.5 92.9 91.4 82.8 89.4 77.2 82.9 85 71.2 74 79.1 83.8 69.7 89.5 58.6 51.5 76.1 45.7 55.6 62.2 65 72 70 82.9 72.4 91.7 88.8 69.3 94.6 98 101 98 90.2 96.1 76.4 95.3 97.6 88.7 94.4 91.8 91.3 97.2 96 91.3 93.2 97.6 86.7 45.9 52.1 53.2 63 57.2 73.8 60.1 81.9 78.4 61.8 85.7 87.3 88.2 83.8 82.6 83.7 65 84.2 86.2 80.3 82.2 78.2 77.6 86.8 83.8 82.2 80.1 87.6 74.6 553-005-XNW 712-582-BWJ 148-327-GVW 911-445-NVG 444-564-YLD 058-314-YQZ 8 of 515 PCB Homologues Project ID: Patrick Bayou A6492 25000 20000 pg/L 15000 10000 5000 0 Total Mono-PCBs Total Di-PCBs Total Tri-PCBs Total Tetra-PCBs Total Penta-PCBs Total Hexa-PCBs Total Hepta-PCBs Total Octa-PCBs Total Nona-PCBs PCB-209 9 of 515 PCB TEQ Project ID: Patrick Bayou A6492 1.2 1 pg/L 0.8 0.6 0.4 0.2 0 ND = 0; EMPC = 0 ND = 0; EMPC = EMPC ND = DL/2; EMPC = 0 ND = DL/2; EMPC = EMPC ND = DL; EMPC = 0 ND = DL; EMPC = EMPC 10 of 515 PCB Totals Project ID: Patrick Bayou A6492 50000 45000 40000 35000 pg/L 30000 25000 20000 15000 10000 5000 0 Sample 11 of 515 PCB WHO Project ID: Patrick Bayou A6492 1200 1000 pg/L 800 600 400 200 0 PCB-77 PCB-81 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-156/157 PCB-167 PCB-169 PCB-189 % Rec. 70 50 40 30 20 10 0 43-72 80 46-87 85-98 74-98 52-94 59-94 76-102 84-97 70-102 78-96 88-108 87-101 84-102 83-95 78-94 Mean Recoveries of Extraction Standards (N=6) Project ID: Patrick Bayou A6492 86-101 84-97 83-91 71-89 65-91 62-96 82-93 100 78-94 74-90 90 60-97 56-93 63-87 52-84 50-78 12 of 515 60 Std. Dev. Mean 13 of 515 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB006.2-1 SWMID-140311-D (Total) ANCHOR QEA Patrick Bayou 11-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 102 ND 308 16.7 600 14.2 ND 37.8 EMPC ND ND Aqueous 0.97 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11883 Qualifier 4.33 2.52 C 11.1 3.1 2.86 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.0395 0.213 0 386 0.386 0.0399 0.213 0 386 0.386 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 44.7 622 5,850 12,700 5,300 1,610 524 156 148 1,680 48.1 Total PCB (Mono-Deca) 28,700 Checkcode: 712-582-BWJ SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6492 A6492_11883_PCB_001-RJ 12,700 5,310 1,690 535 176 28,800 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 12-Mar-2014 14-Mar-2014 24-Mar-2014 Recovery % 70.1 75.8 82.4 86.8 86.6 85 90.9 86.5 85.2 96 94.8 96.9 99.9 98.2 87.5 96.5 90 8 90.8 93.6 95 84.6 92.7 93.1 95.8 97.7 94.4 91.2 90.3 99.8 82.2 99.3 109 114 Report Created: 02-Apr-2014 13:06 Analyst: JJ 14 of 515 Sample ID: PB006.2-1 SWMID-140311-D (Total) Client Data Sample Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: Date Collected: 11-Mar-2014 pH Conc. Qualifiers PCB-1 35 PCB-2 [3.48] J EMPC PCB-3 9.63 J Conc. 1,180 Qualifiers Conc. PCB-54 [5.6] J EMPC PCB-72 (3.94) PCB-50/53 300 C PCB-68 (3.64) [4.63] 96.2 PCB-58 (3.95) Conc. J C Tetra 17:38:59 Conc. PCB-51 Di 4.41 Time Analyzed: Tetra 65.3 429 10.9 712-582-BWJ Checkcode: Qualifiers PCB-27 6.04 PCB-7 24-Mar-2014 PCB-57 PCB-16 PCB-9 Date Analyzed: 303 PCB-24 J 14-Mar-2014 11883 QC Batch No.: 12-Mar-2014 PCB-45 48.1 245 Date Extracted: 417 44.7 9.49 Date Received: A6492_11883_PCB_001-RJ PCB-17 Conc. PCB-10 A6492 Sample ID: 134 PCB-30/18 EMPC PCB-4 Project No.: 0.97 L pg/L Tri PCB-19 Qualifiers Aqueous 7 Units Mono Method 1668A Laboratory Data PCB-32 353 PCB-34 5.42 PCB-23 (3.77) PCB-26/29 170 J PCB-46 113 PCB-67 27.2 PCB-52 2,160 PCB-63 39.3 PCB-61/70/74/76 2,210 PCB-66 1,300 PCB-55 [10.8] PCB-56 582 PCB-73 (2.76) J PCB-43 55.7 PCB-69/49 1,080 C PCB-48 C 312 PCB-25 67.8 PCB-44/47/65 1,740 C PCB-60 242 PCB-31 1,120 PCB-59/62/75 124 C PCB-80 (3.57) PCB-6 37.7 PCB-28/20 1,070 C PCB-42 427 PCB-79 (3.58) PCB-5 (3.75) PCB-21/33 376 C PCB-41 82.9 PCB-78 (4.37) PCB-8 163 PCB-22 281 PCB-71/40 743 PCB-81 (4.33) PCB 14 PCB-14 (3 24) (3.24) PCB 36 PCB-36 (3 6) (3.6) PCB 64 PCB-64 681 PCB 77 PCB-77 102 PCB-11 29.8 B PCB-39 (3.61) PCB-13/12 14.5 JC PCB-38 (3.99) PCB-15 108 PCB-35 (4.25) PCB-37 173 C Conc. 622 Conc. 5,850 Conc. 12,700 EMPC 622 EMPC 5,850 EMPC 12,700 Qualifiers J EMPC C EMPC Totals Conc. Mono-Tri 6,520 6,520 Tel: +1 910 794-1613 Tetra-Hexa 19,600 19,700 www.us.sgs.com Hepta-Deca 2,510 2,540 Mono-Deca 28,700 28,800 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 EMPC 15 of 515 Sample ID: Penta PCB-104 PB006.2-1 SWMID-140311-D (Total) Conc. Qualifiers (2.53) Conc. Qualifiers PCB-108/119/86/97/125/87 565 C PCB-155 PCB-152 (3.02) PCB-146 60.2 C PCB-150 (3.02) PCB-161 (3.22) PCB-117 Conc. 16.4 PCB-103 [8.84] PCB-94 (5.1) PCB-110 940 PCB-136 55.8 PCB-95 643 PCB-115 (3.5) PCB-145 (3.15) PCB-148 (4.06) JC PCB-116/85 183 PCB-100/93 16.1 PCB-82 124 PCB-102 43.1 PCB-111 (3.45) PCB-151/135 PCB-98 (5) PCB-120 (3.47) PCB-88 (4.92) PCB-91 160 PCB-107/124 25.3 PCB-109 47.1 C [6.98] J EMPC PCB-164 27.9 PCB-144 [14.3] EMPC 292 C EMPC 14.2 PCB-134 [22.2] (3.9) PCB-143 (4.44) PCB-121 (3.47) PCB-118 600 PCB-139/140 PCB-83 JC J PCB-122 9.52 PCB-131 6.77 16.7 PCB-142 (4.63) 36 PCB-105 308 PCB-132 125 PCB-99 433 PCB-127 (3.92) PCB-133 6.63 PCB-112 (3.63) PCB-126 (2.52) Hepta Conc. Qualifiers J 398 (3.44) PCB-158 39.2 56 PCB-159 (2.63) [11.1] EMPC 37.8 C PCB-169 (3.1) Conc. 1,610 EMPC 1,690 Hepta Conc. Nona Conc. PCB-179 34.1 PCB-184 (2.14) PCB-176 8.95 PCB-186 PCB-178 Octa Conc. Qualifiers [19.6] EMPC PCB-208 46.8 PCB-201 9.06 J PCB-207 39.5 PCB-204 (2.58) PCB-206 62.1 PCB-197 (2.3) PCB-200 (2.61) PCB-202 PCB-177 37.8 PCB-181 (4.58) PCB-171/173 18.8 JC (2.05) PCB-172 [10.8] EMPC 20.1 PCB-192 (4) PCB-180/193 138 PCB-198/199 C 48 PCB-175 (4.59) PCB-196 22.9 PCB-187 84.5 PCB-191 (3.91) PCB-203 30.2 PCB-182 (4.25) PCB-170 64.7 PCB-195 14.1 PCB-183 40.5 PCB-190 13.4 PCB-194 32 PCB-185 (4.42) PCB-189 (2.86) PCB-205 (5.09) Conc. 524 Conc. 156 EMPC 535 EMPC 176 209 Congener PCB Summary Page 2 of 2 C C PCB-156/157 5,300 Qualifiers C (2.62) 5,310 63.5 EMPC PCB-162 EMPC PCB-174 C PCB-167 Conc. (1.94) J PCB-163/138/129 PCB-160 PCB-128/166 9.07 PCB-114 PCB-188 56.9 PCB-154 PCB-123 J 298 PCB-141 30.7 PCB-106 C PCB-153/168 [16.8] PCB-147/149 Qualifiers (3.48) PCB-130 263 118 Conc. PCB-137 20.7 715 PCB-165 C PCB-84 PCB-92 Hexa 113 PCB-89 PCB-113/90/101 Qualifiers (2.79) PCB-96 J EMPC (3.86) Hexa Method 1668A Penta Conc. 148 EMPC 148 Deca Conc. PCB-209 1,680 Qualifiers Qualifiers 16 of 515 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB006.2-1 SWMID-140311-D (Dissolved) ANCHOR QEA Patrick Bayou 11-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 30 ND 77.4 ND 145 ND ND 6.59 ND ND ND Aqueous 0.96 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 0.00988 0.25 0 49 0.49 3.95 4.09 3.32 JC 3.55 4.87 3.59 0.00988 0.25 0 49 0.49 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 39.4 512 4,190 6,340 1,660 294 61.3 9.37 7.57 189 6,370 1,660 343 68.3 Total PCB (Mono-Deca) 13,300 13,400 Checkcode: 148-327-GVW SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11883 Qualifier 4.6 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6492 A6492_11883_PCB_002-RJ 542 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 12-Mar-2014 14-Mar-2014 24-Mar-2014 Recovery % 68.7 77.9 83.7 86.5 93.4 89.9 97.1 92.6 94.2 94.5 101 101 108 102 91.4 97.4 89 9 89.9 94.3 98 86.6 97.5 94.1 95.4 102 97.4 93.9 93.9 102 85.8 101 112 114 Report Created: 02-Apr-2014 13:06 Analyst: JJ 17 of 515 Sample ID: PB006.2-1 SWMID-140311-D (Dissolved) Client Data Sample Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: Date Collected: 11-Mar-2014 pH Conc. PCB-1 32.8 PCB-2 (2.91) PCB-3 6.62 Qualifiers J Aqueous Project No.: A6492 Date Received: 0.96 L Sample ID: A6492_11883_PCB_002-RJ Date Extracted: 14-Mar-2014 11883 Date Analyzed: 24-Mar-2014 148-327-GVW Time Analyzed: 7 Units Mono pg/L Tri Method 1668A Laboratory Data Conc. PCB-19 117 PCB-30/18 919 PCB-17 QC Batch No.: Checkcode: Qualifiers Tetra Conc. PCB-54 C Qualifiers (4.17) 18:38:02 Conc. PCB-72 (4.18) PCB-68 (3.87) PCB-50/53 194 309 PCB-45 181 PCB-57 (4.3) PCB-27 50.3 PCB-51 58.9 PCB-58 (4.2) Conc. 39.4 PCB-24 5.38 PCB-46 68 PCB-67 9.26 EMPC 39.4 PCB-16 327 PCB-52 1,220 PCB-63 13.9 PCB-61/70/74/76 948 Di Conc. PCB-66 522 PCB-55 (4.47) Qualifiers J C Tetra 12-Mar-2014 PCB-32 256 PCB-73 (3.75) PCB-34 (4.33) PCB-43 [31] EMPC PCB-23 (4.35) C PCB-4 241 PCB-10 8.13 J PCB-26/29 118 PCB-9 6.91 J PCB-25 44.4 C PCB-69/49 569 PCB-48 173 PCB-44/47/65 940 PCB-7 (3.62) PCB-31 773 PCB-59/62/75 67.8 PCB-6 28 PCB-28/20 719 C PCB-42 219 PCB-5 (3.89) PCB-21/33 254 C PCB-41 71 PCB-8 144 PCB-22 190 PCB-71/40 381 PCB 14 PCB-14 (3 35) (3.35) PCB 36 PCB-36 (4 16) (4.16) PCB 64 PCB-64 351 PCB-11 [30] B EMPC PCB-39 (4.17) (4.06) C PCB-13/12 PCB-15 83.6 PCB-38 (4.61) PCB-35 9.95 PCB-37 93.7 PCB-56 231 C PCB-60 96.2 C PCB-80 (3.79) PCB-79 (3.81) PCB-78 (4.65) PCB-81 (4.6) PCB 77 PCB-77 30 C Qualifiers J C J Conc. 512 Conc. 4,190 Conc. 6,340 EMPC 542 EMPC 4,190 EMPC 6,370 Totals Conc. EMPC Mono-Tri 4,740 4,770 Tel: +1 910 794-1613 Tetra-Hexa 8,290 8,380 www.us.sgs.com Hepta-Deca 268 275 Mono-Deca 13,300 13,400 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 18 of 515 Sample ID: Penta PCB-104 PB006.2-1 SWMID-140311-D (Dissolved) Conc. Qualifiers (3.83) Conc. Qualifiers PCB-108/119/86/97/125/87 184 C PCB-155 C PCB-152 (3.12) PCB-146 15.7 (3.13) PCB-161 (3.13) (5.63) PCB-110 283 PCB-136 [13.5] PCB-95 252 PCB-115 (3.86) PCB-145 (3.26) PCB-82 45.9 PCB-148 (3.94) PCB-111 (3.81) PCB-151/135 [27.3] C 16.2 PCB-98 (5.51) PCB-120 (3.82) PCB-88 (5.42) PCB-107/124 [7.54] PCB-91 53 PCB-109 14.8 J EMPC C Conc. PCB-150 PCB-94 (5.28) Hexa PCB-165 7.61 54.4 Qualifiers (2.89) (4.86) PCB-116/85 (4.25) Method 1668A Conc. PCB-96 PCB-102 PCB-117 Hexa PCB-103 PCB-100/93 J Penta EMPC EMPC C PCB-153/168 64.4 PCB-141 15.6 PCB-130 (4.73) PCB-137 (4.15) (3.04) PCB-154 (3.55) PCB-164 PCB-144 (3.95) PCB-163/138/129 PCB-147/149 70 C PCB-160 Qualifiers (3.38) 83.2 C C (3.34) PCB-84 102 PCB-123 (4.09) PCB-134 (4.65) PCB-158 9.32 J PCB-89 (5.81) PCB-106 (4.3) PCB-143 (4.31) PCB-128/166 [8.22] J EMPC C PCB-159 (3.66) PCB-121 (3.82) PCB-118 145 PCB-139/140 (3.89) PCB-92 38 PCB-122 (4.5) PCB-131 (4.51) PCB-162 (3.64) PCB-113/90/101 236 PCB-114 (3.95) PCB-142 (4.49) PCB-167 (3.55) PCB-83 17.6 PCB-105 77.4 PCB-132 28.8 PCB-99 129 PCB-127 (4.25) PCB-133 (4.25) PCB-112 (4) PCB-126 (3.32) Hepta PCB-188 Conc. C Qualifiers (3.02) PCB-179 [7.06] PCB-184 (3.34) PCB-156/157 PCB-169 6.59 1,660 Conc. 294 EMPC 1,660 EMPC 343 Hepta Conc. Qualifiers Nona Conc. 9.75 J Octa PCB-202 Conc. Qualifiers (4.03) PCB-208 7.57 PCB-177 (5.5) PCB-201 (3.72) PCB-207 (5.62) PCB-181 (4.88) PCB-204 (3.98) PCB-206 (8.65) PCB-176 (2.97) PCB-171/173 (5.47) PCB-197 (3.55) PCB-186 (3.19) PCB-172 (5.49) PCB-200 (4.02) PCB-178 (4.33) PCB-192 (4.26) PCB-198/199 PCB-180/193 24.3 C C 9.37 PCB-175 (4.88) PCB-196 (5.46) PCB-187 15.9 PCB-191 (4.16) PCB-203 (5.33) PCB-182 (4.52) PCB-170 11.3 PCB-195 (7.77) PCB-183 (4.46) PCB-190 (4.34) PCB-194 (7.59) PCB-185 (4.71) PCB-189 (3.59) PCB-205 (6.5) Conc. 61.3 Conc. 9.37 EMPC 68.3 EMPC 9.37 209 Congener PCB Summary Page 2 of 2 JC Conc. 7.57 EMPC 7.57 Deca Conc. PCB-209 JC (4.87) Conc. PCB-174 J EMPC C 189 Qualifiers J Qualifiers 19 of 515 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB006.2-1 SWMID-140311-N (Total) ANCHOR QEA Patrick Bayou 11-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 196 ND 591 26.3 1,170 24.6 ND EMPC 28 ND ND Aqueous 0.95 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11883 Qualifier 10.2 6.96 78.6 10.1 7.82 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.0748 0.577 1 08 1.08 0.0771 0.579 1 08 1.08 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 56.6 908 9,650 20,800 9,860 3,010 941 149 289 3,660 73.2 Total PCB (Mono-Deca) 49,300 Checkcode: 911-445-NVG SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6492 A6492_11883_PCB_003-RJ 20,800 9,910 3,140 1,090 272 49,800 C Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 12-Mar-2014 14-Mar-2014 24-Mar-2014 Recovery % 42.7 49.9 51.8 63.1 55.9 78.9 63.6 86.8 83.9 67.9 89.1 90.5 92.9 91.4 82.8 89.4 77 2 77.2 82.9 85 71.2 74 79.1 83.8 69.7 89.5 58.6 51.5 76.1 45.7 99.9 103 107 Report Created: 02-Apr-2014 13:08 Analyst: JJ 20 of 515 Sample ID: PB006.2-1 SWMID-140311-N (Total) Client Data Sample Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: Date Collected: 11-Mar-2014 pH Conc. Qualifiers Project No.: A6492 Date Received: 0.95 L Sample ID: A6492_11883_PCB_003-RJ Date Extracted: 14-Mar-2014 11883 Date Analyzed: 24-Mar-2014 911-445-NVG Time Analyzed: pg/L Tri PCB-1 56.6 PCB-19 PCB-2 (6.6) PCB-30/18 PCB-3 [16.7] EMPC Aqueous 7 Units Mono Method 1668A Laboratory Data Conc. Checkcode: Qualifiers 219 2,080 QC Batch No.: Tetra PCB-54 C PCB-50/53 Conc. Qualifiers [10.6] EMPC 426 C Tetra 12-Mar-2014 19:37:08 Conc. Qualifiers PCB-72 [23.9] EMPC PCB-68 32.3 PCB-17 741 PCB-45 418 PCB-57 (9.53) PCB-27 123 PCB-51 140 PCB-58 (9.32) Conc. 56.6 PCB-24 20.6 PCB-46 164 PCB-67 48.5 EMPC 73.2 PCB-16 753 PCB-52 3,310 PCB-63 70.5 PCB-61/70/74/76 4,000 Di Conc. PCB-66 2,340 PCB-55 (9.92) PCB-56 1000 Qualifiers PCB-32 642 PCB-73 (7.92) PCB-34 (9.67) PCB-43 86.5 PCB-23 (9.72) PCB-69/49 1,690 PCB-4 368 PCB-10 (10.6) PCB-26/29 248 PCB-9 (14.5) PCB-25 96.8 PCB-44/47/65 2,660 C PCB-60 428 PCB-7 (13.1) PCB-31 1,700 PCB-59/62/75 181 C PCB-80 (8.41) PCB-6 52.4 PCB-28/20 1,660 C PCB-42 674 PCB-79 (8.45) PCB-5 (14) PCB-21/33 595 C PCB-41 160 PCB-78 (10.3) PCB-8 244 PCB-22 436 PCB-81 (10.2) PCB 14 PCB-14 (12 1) (12.1) PCB 77 PCB-77 196 PCB-11 45.9 B PCB-13/12 22.8 C PCB-15 175 PCB 36 PCB-36 (9 29) (9.29) PCB-39 (9.3) PCB-38 (10.3) PCB-35 27.3 PCB-37 308 C PCB-48 C 486 PCB-71/40 1,180 PCB 64 PCB-64 1 090 1,090 C Conc. 908 Conc. 9,650 Conc. 20,800 EMPC 908 EMPC 9,650 EMPC 20,800 C Totals Conc. EMPC Mono-Tri 10,600 10,600 Tel: +1 910 794-1613 Tetra-Hexa 33,700 33,900 www.us.sgs.com Hepta-Deca 5,040 5,310 Mono-Deca 49,300 49,800 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 21 of 515 Sample ID: Penta PCB-104 PB006.2-1 SWMID-140311-N (Total) Conc. Qualifiers (7.98) Penta Conc. Qualifiers PCB-108/119/86/97/125/87 1,050 C 41.1 303 Method 1668A Conc. PCB-152 (7.36) PCB-146 105 PCB-150 (7.38) PCB-161 (7.12) 41.1 PCB-94 (12.5) PCB-110 1,690 PCB-136 114 PCB-95 1,150 PCB-115 38.9 PCB-145 (7.69) PCB-100/93 (11.7) PCB-148 (8.96) PCB-82 224 PCB-102 79.5 PCB-111 (8.45) PCB-151/135 PCB-98 (12.2) PCB-120 (8.49) PCB-154 (8.07) PCB-88 (12) PCB-107/124 PCB-91 307 PCB-109 PCB-84 499 PCB-89 [31.6] PCB-121 (8.49) PCB-92 EMPC 228 C 221 C PCB-144 30.1 89.4 PCB-147/149 594 C EMPC PCB-123 24.6 PCB-134 [30.9] PCB-106 (9.55) PCB-143 (9.82) PCB-118 1,170 PCB-139/140 (8.85) 558 102 PCB-130 53.8 PCB-137 [19.6] PCB-164 49.2 C (7.61) PCB-158 64.7 PCB-128/166 121 PCB-159 (8) (7.97) [14.3] PCB-131 (10.3) PCB-162 26.3 PCB-142 (10.2) PCB-167 63.2 PCB-105 591 PCB-132 229 PCB-99 824 PCB-127 (10) PCB-133 (9.67) PCB-112 (8.89) PCB-126 (6.96) PCB-83 Hepta PCB-188 Conc. C Qualifiers Conc. 3,010 EMPC 3,140 Hepta Conc. Nona Conc. 65.3 (7.66) 12.4 PCB-178 [24] PCB-175 (12.3) EMPC Qualifiers Octa Conc. 132 PCB-202 PCB-177 91.6 PCB-201 [13.9] PCB-181 (12.3) PCB-204 (9.45) 51.1 C PCB-197 (8.43) [23.9] EMPC PCB-200 (9.55) PCB-192 (10.7) PCB-198/199 [61.6] EMPC C PCB-196 [24.9] EMPC PCB-180/193 279 C 173 PCB-191 (10.5) PCB-203 37.8 PCB-170 137 PCB-195 [22.9] [76.1] EMPC EMPC PCB-171/173 (11.4) (11.8) PCB-208 PCB-172 PCB-182 PCB-185 Qualifiers 39.7 PCB-187 PCB-183 (10.1) 9,860 PCB-184 (7.32) PCB-169 9,910 PCB-179 PCB-176 [78.6] EMPC PCB-174 PCB-190 [24.6] PCB-189 (7.82) EMPC PCB-194 71.6 PCB-205 (15.5) Conc. 941 Conc. 149 EMPC 1,090 EMPC 272 209 Congener PCB Summary Page 2 of 2 EMPC EMPC C C EMPC C Qualifiers 84.1 PCB-207 61 PCB-206 144 Conc. 289 EMPC 289 Deca Conc. PCB-209 C 28 PCB-156/157 Conc. (6.93) PCB-186 739 PCB-160 PCB-122 1,370 EMPC PCB-153/168 PCB-163/138/129 Qualifiers (7.69) PCB-141 PCB-114 PCB-113/90/101 Conc. PCB-165 (10.8) 40 Hexa (6.82) PCB-96 C Qualifiers PCB-155 PCB-103 C PCB-117 PCB-116/85 Hexa 3,660 Qualifiers 22 of 515 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB006.2-1 SWMID-140311-N (Dissolved) ANCHOR QEA Patrick Bayou 11-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 35.1 ND 78.1 ND 157 4.17 ND EMPC ND ND ND Aqueous 0.96 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11883 Qualifier 3.33 3 J 2.62 7.6 2.54 3.16 3.28 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.0107 0.19 0.369 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 33.2 603 4,670 6,560 1,630 357 75.2 7.46 7.1 196 Total PCB (Mono-Deca) 14,100 Checkcode: 444-564-YLD SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6492 A6492_11883_PCB_004-RJ 0.0109 0.19 0.369 6,570 1,650 390 88.3 15.3 14,200 JC Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 12-Mar-2014 14-Mar-2014 24-Mar-2014 Recovery % 55.6 62.2 65 72 70 82.9 72.4 91.7 88.8 69.3 94.6 98 101 98 90.2 96.1 76.4 95.3 97.6 88.7 94.4 91.8 91.3 97.2 96 91.3 93.2 97.6 86.7 95.3 104 105 Report Created: 02-Apr-2014 13:08 Analyst: JJ 23 of 515 Sample ID: PB006.2-1 SWMID-140311-N (Dissolved) Client Data Sample Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: Date Collected: 11-Mar-2014 pH Conc. Project No.: A6492 Date Received: 12-Mar-2014 0.96 L Sample ID: A6492_11883_PCB_004-RJ Date Extracted: 14-Mar-2014 11883 Date Analyzed: 24-Mar-2014 444-564-YLD Time Analyzed: pg/L Qualifiers Tri PCB-19 Conc. PCB-1 33.2 PCB-2 (2.79) PCB-30/18 PCB-3 (2.76) PCB-17 PCB-27 64.7 Conc. 33.2 PCB-24 7.52 EMPC 33.2 PCB-16 Di Conc. Qualifiers Aqueous 7 Units Mono 139 C 362 PCB-72 C PCB-68 13.9 PCB-45 194 PCB-57 (3.11) [9.35] PCB-52 1,230 PCB-63 15 PCB-61/70/74/76 PCB-32 312 PCB-73 (2.64) PCB-34 (4.21) PCB-43 32.6 PCB-23 (4.23) PCB-69/49 567 PCB-48 171 PCB-44/47/65 944 C PCB-59/62/75 69.8 C PCB-42 223 PCB-25 44.4 PCB-7 (4.32) PCB-31 803 PCB-6 34.2 PCB-28/20 738 C PCB-5 (4.64) PCB-21/33 260 C PCB-8 152 PCB-22 203 C PCB-36 (4.05) PCB-39 (4.05) PCB-38 (4.48) PCB-35 9.66 PCB-37 98.7 PCB-41 81 PCB-71/40 379 PCB-64 354 C C Qualifiers (3.03) 398 J JC J EMPC 195 (3.04) 9.72 7.52 [4.53] PCB-50/53 PCB-58 PCB-9 90.4 20:36:12 Conc. PCB-67 121 PCB-13/12 Tetra 50.8 PCB-26/29 PCB-15 Qualifiers 68.1 J B Conc. PCB-51 265 (4) Tetra PCB-46 J 9.72 34.8 Checkcode: PCB-54 1,110 PCB-10 PCB-11 QC Batch No.: Qualifiers PCB-4 PCB-14 Method 1668A Laboratory Data J EMPC 1,010 PCB-66 559 PCB-55 (3.24) PCB-56 266 PCB-60 104 PCB-80 (2.75) PCB-79 (2.76) PCB-78 (3.37) PCB-81 (3.33) PCB-77 35.1 C J Conc. 603 Conc. 4,670 Conc. 6,560 EMPC 603 EMPC 4,670 EMPC 6,570 Totals Conc. EMPC Mono-Tri 5,310 5,310 Tel: +1 910 794-1613 Tetra-Hexa 8,550 8,610 www.us.sgs.com Hepta-Deca 286 307 Mono-Deca 14,100 14,200 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 24 of 515 Sample ID: Penta PCB-104 PB006.2-1 SWMID-140311-N (Dissolved) Conc. Qualifiers (3.2) Conc. Qualifiers PCB-108/119/86/97/125/87 177 C PCB-155 (2.15) PCB-165 [5] J EMPC PCB-152 (2.32) PCB-146 17.5 47.2 C PCB-150 (2.32) PCB-161 (2.15) PCB-117 Hexa Method 1668A Penta Conc. PCB-96 11 PCB-103 (3.73) PCB-94 (4.32) PCB-110 292 PCB-136 19.2 PCB-95 246 PCB-115 (2.96) PCB-145 (2.42) PCB-116/85 PCB-100/93 (4.05) C PCB-82 35 PCB-102 [9.99] J EMPC PCB-111 (2.92) PCB-98 (4.23) PCB-120 (2.93) PCB-88 (4.16) PCB-107/124 7.08 PCB-91 48.6 PCB-109 12.5 JC PCB-148 (2.7) PCB-151/135 [25.9] PCB-154 PCB-144 PCB-147/149 Hexa 70.6 17.1 PCB-130 11.2 PCB-137 (2.84) (2.43) PCB-164 (2.08) (2.71) PCB-163/138/129 74.2 EMPC C C (2.29) 11.2 101 PCB-123 4.17 PCB-134 (3.19) PCB-158 PCB-106 (3.3) PCB-143 (2.96) PCB-128/166 PCB-121 (2.93) PCB-118 157 PCB-139/140 (2.66) PCB-92 38.9 PCB-122 (3.42) PCB-131 PCB-113/90/101 234 PCB-114 (3) PCB-142 PCB-83 14.9 PCB-105 78.1 PCB-132 31.8 PCB-99 128 PCB-127 (3.39) PCB-133 (2.91) PCB-112 (3.07) PCB-126 (2.62) Hepta Conc. Qualifiers (2.62) (3.09) PCB-162 (2.61) (3.08) PCB-167 (2.54) Conc. 357 EMPC 390 Hepta Conc. Nona Conc. Qualifiers 12.1 Conc. PCB-208 7.1 PCB-201 (2.91) PCB-207 (4.72) PCB-204 (3.12) PCB-206 (7.2) PCB-197 (2.78) PCB-177 [7.94] PCB-181 (4.24) PCB-176 (2.11) PCB-171/173 (4.76) PCB-186 (2.26) PCB-172 (4.77) PCB-200 (3.15) PCB-178 (3.07) PCB-192 (3.7) PCB-198/199 [7.87] PCB-175 (4.24) PCB-180/193 PCB-196 (4.28) PCB-187 16.5 PCB-191 (3.61) PCB-203 (4.18) PCB-182 (3.92) PCB-170 11.8 PCB-195 (5.05) PCB-190 (3.46) PCB-194 7.46 PCB-189 (3.28) PCB-205 (4.22) C C Qualifiers (3.16) 10.6 24.2 J EMPC Octa PCB-202 (2.36) J EMPC [7.6] Conc. 75.2 Conc. 7.46 EMPC 88.3 EMPC 15.3 209 Congener PCB Summary Page 2 of 2 J EMPC C Conc. 7.1 EMPC 7.1 Deca Conc. PCB-209 J C C JC J EMPC C (3.16) 1,650 PCB-179 [5.13] PCB-169 1,630 PCB-184 (4.09) PCB-156/157 EMPC PCB-174 PCB-185 13.2 PCB-159 Conc. (2.14) PCB-183 C 90.6 PCB-160 (4.46) Qualifiers (2.32) PCB-141 PCB-84 PCB-188 Conc. PCB-153/168 PCB-89 C J Qualifiers 196 Qualifiers J Qualifiers 25 of 515 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A HSC14.1-1SWMID-140311-N (Total) ANCHOR QEA Patrick Bayou 11-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 3.38 ND 15.9 ND 42.7 ND ND 5.72 ND ND ND Aqueous 0.96 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB J 2.74 2.98 2.32 JC 2.95 3.57 2.49 0.00227 0.172 0 343 0.343 0.00227 0.172 0 343 0.343 6.04 190 590 637 388 204 34.6 ND 44.1 645 392 224 66.1 5.05 5.6 Total PCB (Mono-Deca) 2,090 Checkcode: 058-314-YQZ SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11883 Qualifier 2.77 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6492 A6492_11883_PCB_005-RJ 2,160 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 12-Mar-2014 14-Mar-2014 24-Mar-2014 Recovery % 45.9 52.1 53.2 63 57.2 73.8 60.1 81.9 78.4 61.8 85.7 87.3 88.2 83.8 82.6 83.7 65 84.2 86.2 80.3 82.2 78.2 77.6 86.8 83.8 82.2 80.1 87.6 74.6 89.1 99.1 95.5 Report Created: 02-Apr-2014 13:09 Analyst: JJ 26 of 515 Sample ID: HSC14.1-1SWMID-140311-N (Total) Client Data Sample Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: Date Collected: 11-Mar-2014 pH Aqueous Project No.: A6492 Date Received: 0.96 L Sample ID: A6492_11883_PCB_005-RJ Date Extracted: 14-Mar-2014 11883 Date Analyzed: 24-Mar-2014 058-314-YQZ Time Analyzed: 7 Units Mono pg/L Tri Method 1668A Laboratory Data Conc. Qualifiers Conc. PCB-1 6.04 J PCB-19 47.5 PCB-2 (2.07) PCB-30/18 110 PCB-3 (2.04) PCB-17 QC Batch No.: Checkcode: Qualifiers Qualifiers PCB-54 [3.15] J EMPC PCB-72 PCB-50/53 19.5 JC PCB-68 20.7 55.9 PCB-45 12.7 PCB-57 (2.58) PCB-58 (2.53) PCB-27 12.1 PCB-51 21.7 Conc. 6.04 PCB-24 (3.33) PCB-46 6.24 EMPC 6.04 PCB-16 54.2 PCB-52 113 Di Conc. Qualifiers J Tetra 21:35:17 Conc. C Tetra 12-Mar-2014 Conc. (2.52) PCB-67 (2.44) PCB-63 (2.31) PCB-32 48.6 PCB-73 (2.41) PCB-61/70/74/76 PCB-34 (2.94) PCB-43 (4.14) PCB-66 51 PCB-23 (2.95) PCB-55 (2.69) PCB-4 98.6 PCB-10 (4.73) PCB-26/29 15.9 PCB-9 (4.4) PCB-25 PCB-7 (3.96) PCB-31 PCB-69/49 JC 60 PCB-48 12.7 12.5 PCB-44/47/65 104 76.7 PCB-59/62/75 6.96 C 87.1 PCB-56 24.1 C PCB-60 [4.9] JC PCB-80 (2.28) (2.29) PCB-6 (4.23) PCB-28/20 96.2 C PCB-42 23.5 PCB-79 PCB-5 (4.25) PCB-21/33 17.6 JC PCB-41 (4.06) PCB-78 (2.8) PCB-8 20.5 PCB-22 27.1 PCB-81 (2.77) PCB 14 PCB-14 (3 66) (3.66) PCB 77 PCB-77 3 38 3.38 PCB-11 23.3 B (4.45) C PCB-13/12 PCB-15 47.2 PCB 36 PCB-36 (2 82) (2.82) PCB-39 (2.83) PCB-38 (3.13) PCB-35 (3.33) PCB-37 15.8 PCB-71/40 38.5 PCB 64 PCB-64 31 5 31.5 C Qualifiers Conc. 190 Conc. 590 Conc. 637 EMPC 190 EMPC 590 EMPC 645 C J EMPC J Totals Conc. Mono-Tri 786 786 Tel: +1 910 794-1613 Tetra-Hexa 1,230 1,260 www.us.sgs.com Hepta-Deca 78.8 115 Mono-Deca 2,090 2,160 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 EMPC 27 of 515 Sample ID: Penta HSC14.1-1SWMID-140311-N (Total) Conc. Qualifiers Hexa Method 1668A Penta Conc. Qualifiers Conc. Qualifiers Hexa JC PCB-155 Conc. PCB-152 (2.29) PCB-146 8.22 JC PCB-150 (2.29) PCB-161 (2.09) Qualifiers PCB-104 (2.72) PCB-108/119/86/97/125/87 38.9 PCB-96 (3.09) PCB-117 (3.1) PCB-103 (3.55) PCB-116/85 10.5 PCB-94 (4.1) PCB-110 71.9 PCB-136 10.4 PCB-153/168 42.4 PCB-95 55.5 PCB-115 (2.82) PCB-145 (2.39) PCB-141 8.49 J PCB-82 9.41 PCB-148 (2.63) PCB-130 3.49 J PCB-100/93 (3.85) C J (2.12) J C PCB-102 (3.47) PCB-111 (2.78) PCB-151/135 PCB-137 (2.76) (4.02) PCB-120 (2.79) PCB-154 (2.36) PCB-164 [3.17] J EMPC PCB-88 (3.95) PCB-107/124 (3.03) C PCB-144 (2.63) PCB-163/138/129 51.5 C PCB-91 13 PCB-109 [4.03] J EMPC PCB-84 20.8 PCB-123 (2.98) PCB-134 PCB-89 (4.24) PCB-106 (3.13) PCB-143 PCB-121 (2.79) PCB-118 42.7 PCB-139/140 (2.59) PCB-92 14.1 PCB-113/90/101 62.7 PCB-83 (4.9) PCB-99 32.6 PCB-112 (2.92) Hepta PCB-188 Conc. C Qualifiers (1.91) PCB-179 [4.26] PCB-184 (2.11) PCB-160 (2.23) (3.1) PCB-158 [3.03] J EMPC (2.88) PCB-128/166 9.46 JC PCB-131 (3.01) PCB-162 (3.03) PCB-142 (2.99) PCB-167 (2.95) PCB-105 15.9 PCB-132 [14] PCB-127 (2.98) PCB-133 (2.83) PCB-126 (2.32) PCB-156/157 PCB-169 5.72 388 Conc. 204 392 EMPC 224 Hepta Conc. Qualifiers Nona Conc. [10.6] EMPC PCB-177 [4.95] J EMPC PCB-181 (3.85) Conc. (2.53) PCB-207 (4.21) (2.71) PCB-206 (6.84) PCB-197 (2.42) PCB-200 (2.74) PCB-178 (2.74) PCB-192 (3.36) PCB-198/199 [5.05] 13.8 PCB-191 PCB-180/193 (3.28) 20.8 PCB-182 (3.57) PCB-170 [7.4] C J EMPC PCB-196 (3.72) PCB-203 (3.63) PCB-195 (5.38) PCB-190 (3.08) PCB-194 (5.25) PCB-189 (2.49) PCB-205 (4.49) Conc. 34.6 Conc. 0 EMPC 66.1 EMPC 5.05 209 Congener PCB Summary Page 2 of 2 J EMPC C Conc. 0 EMPC 0 Deca Conc. PCB-209 Qualifiers (4.37) PCB-201 (4.32) (3.85) PCB-208 PCB-204 (4.33) PCB-175 Qualifiers (2.74) PCB-171/173 PCB-187 C Octa PCB-202 JC (3.57) EMPC PCB-172 J EMPC EMPC Conc. (1.88) [4.27] (3.04) (3.13) (2.02) (3.72) PCB-159 (2.74) PCB-176 PCB-185 C PCB-122 PCB-186 PCB-183 C PCB-114 PCB-174 J EMPC 45.7 JC (2.25) PCB-98 PCB-147/149 18.5 PCB-165 44.1 Qualifiers 28 of 515 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A Method Blank A6492 ANCHOR QEA Patrick Bayou n/a PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L ND ND ND ND ND ND ND ND ND ND ND Aqueous 1.00 L n/a DL pg/L 2.89 2.89 2.31 2.08 2.2 2.24 2.79 4.73 3.35 3.77 3.12 Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 0 0.197 0 394 0.394 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB ND 6.09 ND ND ND ND ND ND ND ND Total PCB (Mono-Deca) 6.09 Checkcode: 553-005-XNW 0 0.197 0 394 0.394 1.7 3.51 2.85 2.28 3.46 3.41 3.98 6.36 7.08 6.09 SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11883 Qualifier C TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6492 MB1_11883_PCB_TLX-RJ Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 n/a 14-Mar-2014 24-Mar-2014 Recovery % 72.4 76.3 84.2 78.4 86.9 80.4 88.2 82.9 81.8 89.1 92.6 93.8 94.9 91.5 86 87 82 5 82.5 85.8 86.9 81.9 90.5 87.3 89.2 90.3 89.8 87.3 84.2 92.7 77.8 89.9 102 106 Report Created: 02-Apr-2014 13:03 Analyst: JJ 29 of 515 Sample ID: Method Blank A6492 Client Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: n/a Date Collected: Mono Method 1668A Sample Data Conc. Laboratory Data Aqueous Project No.: A6492 Date Received: n/a 1.00 L Sample ID: MB1_11883_PCB_TLX-RJ Date Extracted: 14-Mar-2014 11883 Date Analyzed: 24-Mar-2014 553-005-XNW Time Analyzed: pH n/a QC Batch No.: Units pg/L Checkcode: Qualifiers Tri Conc. PCB-1 (1.55) PCB-19 (3.9) PCB-2 (1.88) PCB-30/18 (3.05) PCB-3 (1.86) PCB-17 PCB-27 Qualifiers Tetra Conc. Qualifiers Tetra 16:41:39 Conc. PCB-54 (2.49) PCB-50/53 (2.91) (3.57) PCB-45 (3.34) PCB-57 (2.7) (2.64) PCB-51 (2.92) PCB-58 (2.64) C C PCB-72 (2.63) PCB-68 (2.43) Conc. 0 PCB-24 (2.69) PCB-46 (3.54) PCB-67 (2.55) EMPC 0 PCB-16 (5.02) PCB-52 (3.09) PCB-63 (2.41) PCB-32 (2.46) PCB-73 (2.22) PCB-61/70/74/76 (2.63) PCB-34 (2.87) PCB-43 (3.81) PCB-66 (2.73) PCB-55 (2.81) PCB-56 (2.85) Di Conc. Qualifiers PCB-4 (3.76) PCB-23 (2.88) PCB-10 (2.32) PCB-26/29 (2.82) PCB-69/49 (2.52) PCB-48 (3.05) PCB-9 (4.11) PCB-25 (2.86) PCB-44/47/65 (2.84) C PCB-60 PCB-7 (3.7) (2.79) PCB-31 (2.72) PCB-59/62/75 (2.21) C PCB-80 (2.39) PCB-6 PCB-5 (3.95) PCB-28/20 (2.92) C PCB-42 (3.39) PCB-79 (2.4) (3.97) PCB-21/33 (2.81) C PCB-41 (3.73) PCB-78 (2.92) C PCB-8 (3.92) PCB-22 (3.03) PCB-71/40 (2.97) PCB 14 PCB-14 (3 42) (3.42) PCB 36 PCB-36 (2 76) (2.76) PCB 64 PCB-64 (2 09) (2.09) (2.76) PCB-11 6.09 J PCB-39 PCB-13/12 (4.15) C PCB-38 (3.06) PCB-15 (4.03) PCB-35 (3.25) PCB-37 (3.12) C C PCB-81 (2.89) PCB 77 PCB-77 (2 89) (2.89) Conc. 6.09 Conc. 0 Conc. 0 EMPC 6.09 EMPC 0 EMPC 0 Qualifiers C Totals Conc. EMPC Mono-Tri 6.09 6.09 Tel: +1 910 794-1613 Tetra-Hexa 0 0 www.us.sgs.com Hepta-Deca 0 0 Mono-Deca 6.09 6.09 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 30 of 515 Sample ID: Penta PCB-104 Method Blank A6492 Conc. Qualifiers (2.07) Method 1668A Penta Conc. Qualifiers PCB-108/119/86/97/125/87 (2.54) C PCB-155 PCB-152 (2.15) PCB-146 (2.86) C PCB-150 (2.15) PCB-161 (2.31) PCB-96 (2.35) PCB-117 (2.33) PCB-103 (2.67) PCB-116/85 (2.51) Hexa Conc. Qualifiers (1.99) Hexa PCB-165 Conc. PCB-94 (3.09) PCB-110 (2.38) PCB-136 (2.31) PCB-153/168 (2.43) PCB-95 (2.87) PCB-115 (2.12) PCB-145 (2.24) PCB-141 (3.05) PCB-100/93 (2.89) PCB-82 (3.53) PCB-148 (2.9) PCB-102 (2.61) PCB-111 (2.09) PCB-151/135 (2.99) PCB-98 (3.02) PCB-120 (2.1) PCB-88 (2.97) PCB-107/124 (2.28) PCB-91 (2.72) PCB-109 (2.2) C C C PCB-130 (3.49) PCB-137 (3.06) PCB-154 (2.62) PCB-164 (2.24) PCB-144 (2.91) PCB-163/138/129 (2.87) PCB-147/149 (2.9) PCB-160 (2.47) C PCB-84 (3.38) PCB-123 (2.24) PCB-134 (3.43) PCB-158 (2.25) PCB-89 (3.19) PCB-106 (2.36) PCB-143 (3.18) PCB-128/166 (4.05) PCB-121 (2.1) PCB-118 (2.2) PCB-139/140 (2.87) PCB-159 (3.46) PCB-92 (3.05) PCB-122 (2.37) PCB-131 (3.33) PCB-162 (3.45) PCB-113/90/101 (2.59) PCB-114 (2.08) PCB-142 (3.31) PCB-167 (3.35) PCB-83 (3.68) PCB-105 (2.31) PCB-132 (3.26) PCB-156/157 (4.73) PCB-99 (2.58) PCB-127 (2.26) PCB-133 (3.13) PCB-169 (3.77) PCB-112 (2.19) PCB-126 (2.79) Hepta PCB-188 Conc. (2.03) C Qualifiers C Conc. 0 Conc. 0 EMPC 0 EMPC 0 Hepta Conc. Nona Conc. Qualifiers Octa Conc. Qualifiers PCB-174 (4.53) PCB-202 (3.23) PCB-208 (4.72) PCB-179 (2.16) PCB-177 (4.52) PCB-201 (2.98) PCB-207 (4.55) PCB-184 (2.25) PCB-181 (4) PCB-204 (3.19) PCB-206 (8.01) PCB-176 (2) PCB-197 (2.85) PCB-186 (2.15) PCB-172 (4.5) PCB-200 (3.23) PCB-178 (2.92) PCB-192 (3.49) PCB-198/199 (4.5) PCB-175 (4) PCB-180/193 (3.72) PCB-196 (4.38) PCB-187 (3.79) PCB-191 (3.41) PCB-203 (4.28) PCB-182 (3.71) PCB-170 (4.53) PCB-195 (5.65) PCB-171/173 (4.49) C C PCB-183 (3.66) PCB-190 (3.39) PCB-194 (5.52) PCB-185 (3.86) PCB-189 (3.12) PCB-205 (4.72) Conc. 0 Conc. 0 EMPC 0 EMPC 0 209 Congener PCB Summary Page 2 of 2 C Conc. 0 EMPC 0 Deca Conc. PCB-209 Qualifiers (2.49) (7.08) C C C C Qualifiers Qualifiers 31 of 515 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM4_PCB_10292013_05FEB2014 Instrument ID: MM4 GC Column ID: VER Data Filename: 140324S05 Analysis Date: Lab ID: OPR1_11883_PCB-RJ NATIVE ANALYTES PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-104 22'466'-PeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-155 22'44'66'-HxCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-188 22'34'566'-HpCB PCB-189 233'44'55'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-206 22'33'44'55'6-NoCB PCB-208 22'33'455'66'-NoCB PCB-209 DeCB Processed: 02 Apr 2014 13:02 24-MAR-2014 14:44:33 SPIKE CONC. RECOVERY RANGE (%) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 99.7 99.7 103 99.3 99.2 101 99.3 102 107 99.7 102 102 99.9 103 100 101 101 104 101 104 104 107 106 103 106 103 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 Contract-required recovery limits for OPR as specified in Table 6, Method 1668A. Analyst: JJ FORM 8A OK - 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 32 of 515 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM4_PCB_10292013_05FEB2014 Instrument ID: MM4 GC Column ID: VER Data Filename: 140324S05 Analysis Date: Lab ID: OPR1_11883_PCB-RJ LABELED STANDARDS ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 FORM 8B 24-MAR-2014 14:44:33 SPIKE CONC. RECOVERY RANGE (%) 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 98.8 94 104 87 102 86.9 102 91 87.1 97.4 93.8 95.4 98 95.7 86.2 91.5 86.7 90 87 83.5 92.5 90.1 93.1 94.4 88.7 88.9 87.6 95.8 78.6 15 15 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 - 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 100 100 100 92.1 102 105 40 40 40 - 125 125 125 Y Y Y OK CLEANUP STANDARDS CS PCB-28 CS PCB-111 CS PCB-178 Processed: 02 Apr 2014 13:02 Analyst: JJ 33 of 515 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: Amy Boehm 12-Mar-14 at 09:40 A6492 21 days 2-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com AP Smp ID Sample Condition & Notes Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Quantity Size Delaney Peterson ANCHOR QEA Patrick Bayou N/A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Sampling Date Sampling Time Received Temp Container # PB006.2-1 SWMID-140311-D (Total) A6492_001 WS 2 1L Amber 11-Mar-14 13:03 3.4, 2.2 1, 2 PB006.2-1 SWMID-140311-D (Dissolved) A6492_002 WS 2 1L Amber 11-Mar-14 13:03 3.4, 2.2 1, 2 PB006.2-1 SWMID-140311-N (Total) A6492_003 WS 2 1L Amber 11-Mar-14 13:03 3.4, 2.2 1, 2 PB006.2-1 SWMID-140311-N (Dissolvedl) A6492_004 WS 2 1L Amber 11-Mar-14 13:03 3.4, 2.2 1, 2 HSC14.1-1SWMID-140311-N (Total) A6492_005 WS 2 1L Amber 11-Mar-14 12:11 3.4, 2.2 1, 2 Preservation Type: Notes/Comments: Ice - Good Condition+Ice - Sample Seals: Samples received intact Dissolved samples need to be lab filtered before extraction. See Amy for questions Received by: Christina Newkirk Logged in by: Christina Newkirk Shipping # 867316309120, 867316309130 867316309120, 867316309130 867316309120, 867316309130 867316309120, 867316309130 867316309120, 867316309130 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. QC'ed by: AK 12 Mar 14 SGS Analytical Perspectives 34 Of 515 051/ CHAIN OF CUSTODY CONVENTIONAL SHALE kw? PROJECT INFO: SEND DOCUMENTATION RESULTS TO: SEECIAL INSTRUCTIONS I COMMENTS: JV PROJECT. . 6 aligazu?o 0 COMPANYCONTACT: ?3-76.14? 7:;er QUOTE . we?) HOD SITE REF: PHONE. 206- -5I 03 3 46 TURN 5 +anaIar .. EMAIL: Ape-P160 0 ea ?ckofie?laii . . REPORTLEVEL. (see reverse} Level I Level II XLeveI IV INVOICE T0. (BCHECK IF SAME) ?k SPECIAL DELIVERABLES: State of Origin: COMPANY: PAIL CONTACT 30$ ANALYSIS METHOD Vin EOO- ?Other: ADDRESS. . - \n PHONE: ?7547/. 7/2 ?k EMAIL. bob flora] v? gE 11!: TIIPE OONT. i: i SAMPLE ID I DESCRIPTION DATE TIME MS MSD DUP (C, G) MATRIX OTY 9? REMARKS A 6- If If RECEIVED BY: RECEIVED BY: TIME: 3 M50 TIME: BY I1I: DATE RELINQUISHED BY (2): Page I of I 863 NORTH AMERICAINC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 910 350 1903 910 794 1613 I . Member of the 868 Group (863 SA) 35 of 515 Project Initiation Form Project Number: A6492 Initiation Date: Client Name: ANCHOR QEA 1668A Analysis Method: Sample Matrix: TAT: Project Manager: 12-Mar-14 Aqueous 21 days Amy Special Instructions 1668A w/ OPR Dissolved samples need to be filtered before extraction Reporting Instructions 1668A w/ OPR Anchor Equis EDD PM Initials: akornega Date: 12-Mar-2014 36 of 515 Prep Sheet TRt".~- --. ~ .~~J:_r-Jj'th I A6492 Project # IBalch # llXX3 Extracllnit/Dale: Watcr 1668A \ , \-\\L. -; \ \ l{ \ It.1 hSIT!i l"io'Dale. -1'11 LI 114 Transfer Init/Date: u1 A.. J j t-.., "OJ bl:: Ct-J"i ,1 111.., AI' Samplc Client Sample II) Volul11e (mI.) ID 1'1l006.2-1 SWMID-140311-D(Total) PB006.2-1SWMID-140JII-D(Dissolved) I'B006.2-1 SWMID-140311-N (Total) PB006.2-1SWMtD-140JII-N (DIssolved!) HSCI4.1-ISWMID-140311-N MBI OI'RU Method 11883 (Total) Blank SDS # q - lO - \\ \'l. - ~S~ C\ 7.. \ \> \OCO 1 \OM 0_1 1883_0PROOI 1883 ~10 QS1 qs~ Talex # "6 --- RV # ('I'd) Initials Clean-up Observations crP vtr'$ L1 1 3 n - 2\ Z t.t .3 vrB L-\..o~~ \l(\\OvJ'\ ~~ ~ L\\DW1' S'~ ~ Q,\ \" h"-l S\... T (, \ -. . Il'v\.l~ l V4.-\\OWl<:'~ - ~<-\~I)"'-l sl cL:,v._ •.L~ To..~)( \\~O t1~~ 115 - ~-r \o-.,~'>c ~, \-\'l-O o ~ ".z ....•.. '1-.e)\ L{ 0)\ "Z. -z..o \ l{ . 1:;1"7 /70/4 Dissolved samples need 10 be liltered bcilHe extraction SUllIJly J[)s Cycle Time Sllccial Instructions: 1668A w/ OI'R Start: \\:\0 t). ••••••. Toluene CI12CL2 Stop --\-'2.:l{o ~ Gt~I'\ Start: Sand Florisil Hexane ISilica Stop: I - Acid Silica - Base Silica - !)}lo~lo .- HydroMatrix 'I'ctradecanc \-1lto-l~1 K Silicate CB\'-\W\Ll ""-- - , CnZ5L~<.J 37 of 515 1668A Project # A6492 Batch # Aqueous 11883 Inter-Department Communication Sheet )UVJ 00 Special Instructions 1668A wi OPR Dissolved samples need to be filtered before extraction 38 of 515 TSS % TSS Determination I~ liii't!~.'",.~.' .........._..__ . A~ ••• l.Yll(;Al Pt:'I'Sol>t;("Trvl',r. Tarc Balancc Add boat & 0.45 11mfiltcr and weigh. Rccord "Boat WI." Placc filter in glass lilling funnel Fillcr 10 mL ofallUCOUSsamplc through filtcr into a wastcjar Rinsc filtcr with 20 mL of 01 water Dry in ovcn ovcrnight @ 107 C Return dish to toploader and record "Dry WI." Proccdurcs: Project: A6492 Batch: 11883 AI' S"mllic II> WorkSheet llo"tWT. b'L Chemist: Prep Daic: Dry WT. 'y" TSS InitID"tc 0 o. \ Mu- 1\6492 - 11883 00\ \.\~ \:1" 1\6492 - \1883_002 \-1' \ .\1, 1\6492 - 1\883 003 \-\Cb \,,,\ l () ~i- 1\6492 -1\883 004 \-~"\ \.1, 0 ~ \\,~ \~11 0 ;\6492 -1\883 005 (7\\ G\'- la,-\;-- ...., 0 ~1~1 ~ ~II * -, "1 1 ~\\,\\\,\ 0 Commcnts 39 of 515 Spike Sheet PCB 1668A Batch # A6492 Project # 11883 SPIKE PROFILE Soiked Amoullt Spike Comoounds Anah'te Spiker InitialslDate: Client Sample AI' Sample ID Observer Initials A6492 - I 1883- 00 I I'B006.2-1 SWMID-140311-D(Total) A6492 - I 1883 -002 1'1l006.2-1 SWMID-140JII-D A6492 - 11883 - 004 1'1l006.2-1 SWMID-1403l1-N IISCI4.1-ISWMID-140311-N MBI OPRI Method 11883 Blank (Total) Observer Initials M 1/nJ17 I'cn cs Amount: 7D.,t Observer Initials Solit Factor M- 3/17/1'1 I'cn ,IS Amount: ID~ Observer Inltiuls ~\~ \ (Dissolved!) ~ \~~ \\\\L.- (Total) ~~ 0_1 I883_01'ROOI 11883 3/1t /11 PCB 209 Ax Amount: "2,0,,(,. Solution Cone, \\\t-. (Dissolved) I'B006.2-1 SWMID-140311-N PCBs Soiked Volume M J 111/ / '1 M PCB ES Amount:"ld> •.\.. ID \Vater :{.... >\\'1 \\\{ Standard I'cn ES Std. Type \CI"1."\ Spike \[) \~ -4(,-\ SIL# 100 Conccntration Jlg I/,lL Units \'1.\''1. \\"\ Exp. Date Spike amount 1-OY)~ (~L) 20' Information ••cn 209 Ax \O""2.."\vn.'1 \;-1 ~-t 50 \pg 1~IL \.o\'2A 11'1 20 ••cn CS/SS ••cn.ls q LOI~">\..'") \01.£\ t.D\''\ A. \~-q lD-"t\,'1~.4 '1l1.. 100 pg/f,lL \1--\q-l~ 20 200 pg If,lL IOI1Ji \ 11.\ 10 Filial Volume Filial Solvent 40 of 515 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: Amy Boehm 12-Mar-14 at 09:40 A6492 21 days 2-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com AP Smp ID Sample Condition & Notes Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Quantity Size Delaney Peterson ANCHOR QEA Patrick Bayou N/A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Sampling Date Sampling Time Received Temp Container # PB006.2-1 SWMID-140311-D (Total) A6492_001 WS 2 1L Amber 11-Mar-14 13:03 3.4, 2.2 1, 2 PB006.2-1 SWMID-140311-D (Dissolved) A6492_002 WS 2 1L Amber 11-Mar-14 13:03 3.4, 2.2 1, 2 PB006.2-1 SWMID-140311-N (Total) A6492_003 WS 2 1L Amber 11-Mar-14 13:03 3.4, 2.2 1, 2 PB006.2-1 SWMID-140311-N (Dissolvedl) A6492_004 WS 2 1L Amber 11-Mar-14 13:03 3.4, 2.2 1, 2 HSC14.1-1SWMID-140311-N (Total) A6492_005 WS 2 1L Amber 11-Mar-14 12:11 3.4, 2.2 1, 2 Preservation Type: Notes/Comments: Ice - Good Condition+Ice - Sample Seals: Samples received intact Dissolved samples need to be lab filtered before extraction. See Amy for questions Received by: Christina Newkirk Logged in by: Christina Newkirk Shipping # 867316309120, 867316309130 867316309120, 867316309130 867316309120, 867316309130 867316309120, 867316309130 867316309120, 867316309130 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. QC'ed by: AK 12 Mar 14 SGS Analytical Perspectives 41 of 515 I CONVENTIONAL CHAIN OF CUSTODY PROJECT: 'PA-I (' •.de- p~'1 ~H) A (\G~orQeA COMPANY: I QUOTE #: 0'-/ tJ Zgij-0 TURN AROUNDifIME: S tAJ"\J REPORT.LEVEL: (see reverse) 1-1 o State II ~ Level IV (""I INVOICE TO: of Origin: (OCHECK IF SAME) PH!.. COMPANY: CONTACT: EMAIL: DATE ..• / I SAMPLE ID / DESCRIPTION ~ 7-1StrlMIf)-/4b3il- •••••••• _~,.. ~'" - ...• ••• ..- "':1) 1"1 ~.2.- /50tv'l/1J '~w. ~~~HEDBV'" ...I~ Jt:.-t 1':._ BY (2): 'J '. n - - boh pe (.Jrtli ~c-I/1aVi.sC. "," MS TIME I~D~ '7 11/)3 MSD DUP ~1,I/J4 - - l'-/IJ3J/-/\/ 5//1//'1 - - ---D7/t 3. If It{ DATE: 1~56 TIME: (;- IV} TIME: 6- /~/')3 , TYPE (C. G) G- - --v -1l.(o.V/-1'I ~ I"V1 CONT. MATRIX wS nTY q wS q }J I~~ ~ ~ ~ V V VVV 5 VV 940 ,0/.'.. RECEIVED BY: ,.' ''c' ;, S~Mf?lJRECEIPTTSMP: 5500 Business Drive Wilmington, °C red f'f.. .df: ENVIRONMENTAL SERVICES ./ ---- - ',~ ~cI£';( . - RECEIVED BY: ( -- V CARRIER: SGS NORTHAMERICA INC. REMARKS - - - - --- ~ pagelOf~ ~ \r* ~ ~ ~ (, V' V- I/' - V V '-"J (c: '\.C. wS ,\I) ~\i~ ~ \) .~ ~ ~~ ~ ~~~ ~~~ ~' .. \. •..... .~ ) .~ ~ '\? ANALYSIS & METHOD 1 . 11? -e:;cq .. crf2' I I wll'lIm" RELINQUISHED ~ 15tVfYlIO rlSC/'f./- .-...J.' 1..- ~ ..f nc ""',o? J ~ J~~JJ ADDRESS: PHONE: ..•....• BeJb / " lA..JA <7&/0 •PRESERVATIVE W~ ISh:. Itt00 I d pekC50 eO. ,..e""o,.t:t, ec. EMAIL: o Level iIX I COMMENTS: INSTRUCTIONS n ZOe._tll) 3 .'3 &I" PHONE: DOther: j ; / 0 = " - . ) 1 $ ' 2 ' - ! - - 4 5 ( ! ( ' / ! ' 3 ! ! = $ ( ! ! ( % $ ( " < " 0 ! & / " ( ! @ ' " " & ! $ " ) ' ! $ < 6 7 8 9 ) # ( $ ! " " ! ! " " ! : " ! ! ! - $ > @ ! ! < A 4 ( B = A < @ > ! " ' = ! ! ! ! $ " $ $ " < ) ) ( " " ! < ! ? $ " @ ) ! $ - > Digitally signed by Amy Boehm Date: 2014.04.01 15:15:03 -04'00' ( - ) C ! " D ! " ! * ( E = " 3 of 711 APPENDIX A: GENERAL DATA QUALIFIERS / DATA ATTRIBUTES B The analyte was found in the method blank, at a concentration that was at least 10% of the concentration in the sample. C Two or more congeners co-elute. In EDDs, C denotes the lowest IUPAC congener in a co-elution group and additional co-eluters for the group are shown with the number of the lowest IUPAC co-eluter. E The reported concentration exceeds the calibration range (upper point of the calibration curve) and is an estimated value. EMPC Represents an Estimated Maximum Possible Concentration. EMPCs arise in cases where the signal/noise ratio is not sufficient for peak identification (the determined ion-abundance ratio is outside the allowed theoretical range), or where there is a co-eluting interference. H/h If the standard recovery is below the method or SOP specified value “H” is assigned. If the obtained value is less than half the specified value “h” is assigned.1 J Indicates that an analyte has a concentration below the reporting limit (lowest point of the calibration curve) and is an estimated value. ND Indicates a non-detect. NR Indicates a value that is not reportable. PR Due to interference, the associated congener is poorly resolved. QI Indicates the presence of a quantitative interference. SI Denotes “Single Ion Mode” and is utilized for PCBs where the secondary ion trace has a significantly elevated noise level due to background PFK. Responses for such peaks are calculated using an EMPC approach based solely on the primary ion area(s) and may be considered estimates.1 U The analyte was not detected. The estimated detection limit (EDL) may be reported for this analyte. V The labeled standard recovery was found to be outside of the method control limits. Page 3 of 5 4 of 711 APPENDIX B: DRBC/TMDL SPECIFIC DATA QUALIFIERS / DATA ATTRIBUTES J The reported result is an estimate. The value is less than the minimum calibration level but greater than the estimated detection limit (EDL). U The analyte was not detected in the sample at the estimated detection limit (EDL). E The reported concentration is an estimate. The value exceeds the upper calibration range (upper point of the calibration curve). D Dilution Data. Result was obtained from the analysis of a dilution. B Analyte found in the sample and associated method blank. C Co-eluting congener Cxx Co-elutes with the indicated congener, data is reported under the lowest IUPAC congener. ‘Xx’ denotes the IUPAC number with the lowest numerical designated congener. NR Analyte is not reportable because of problems in sample preparation or analysis. V Labeled standard recovery is not within method control limits. X Results from re-injection/repeat/second-column analysis. EMPC Estimated maximum possible concentration. Indicates that a peak is identified but did not meet the method specified ion-abundance ratio. APPENDIX C: LAB IDENTIFIERS AR Indicates use of the archived portion of the sample extract. CU Indicates a sample that required additional clean-up prior to MS injection/processing. D Indicates a dilution of the sample extract. The number that follows the “D” indicates the dilution factor. DE Indicates a dilution performed with the addition of ES (extraction standard) solution. DUP Designation for a duplicate sample. MS Designation for a matrix spike. MSD Designation for a matrix spike duplicate. RJ Indicates a reinjection of the sample extract. S Indicates a sample split. The number that follows the “S” indicates the split factor. Page 4 of 5 5 of 711 SGS CERTIFICATIONS California 07255CA Connecticut PH-0258 Florida (primary NELAP) E87634 ISO17025 2726.01 Kansas E-10330 Louisiana 04115 Maryland (DW only) 299 New Jersey NC100 New York 11685 North Carolina DENR 481 North Carolina DHHS (DW only) 37776 North Dakota R-197 Oregon NC200002 Pennsylvania 68-03675 South Carolina 99029 Texas T104704260-13-5 Utah NC009192013-3 Virginia (DW only) 00235 Virginia 460214 Washington State C913 West Virginia 293 Page 5 of 5 6 of 711 Sample ID: Method 1668A PB020-1SWMID-140313-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 13-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 123 PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB 370 PCB-114 2344'5-PeCB 21.1 PCB-118 23'44'5-PeCB 702 PCB-123 23'44'5'-PeCB 18.8 PCB-126 33'44'5-PeCB 5.08 PCB-156/157 233'44'5/233'44'5'-HxCB 51.1 PCB-167 23'44'55'-HxCB 16.5 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB 3.61 Aqueous 0.97 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11892 Qualifier 1.71 J C 1.02 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.556 0.571 0 587 0.587 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 47.5 545 5,610 14,700 6,500 2,100 671 179 163 1,370 Total PCB (Mono-Deca) 31,900 Checkcode: 320-870-RRF SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6504 0.556 0.571 0 587 0.587 555 14,700 6,510 2,100 31,900 Date Received: A6504_11892_PCB_001 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 14-Mar-2014 18-Mar-2014 26-Mar-2014 Recovery % 58.8 72.1 83.8 95 90 84.2 99 84.5 82.6 115 93.2 90.7 93.4 92.5 87.6 92.4 94 4 94.4 76.4 78.1 68.4 92.5 94.7 110 94.8 99.3 86.6 91.1 106 83 84.8 94.2 111 Report Created: 31-Mar-2014 18:57 Analyst: CM 7 of 711 Sample ID: PB020-1SWMID-140313-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 13-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers Aqueous Project No.: A6504 Date Received: 0.97 L Sample ID: A6504_11892_PCB_001 Date Extracted: 18-Mar-2014 11892 Date Analyzed: 26-Mar-2014 320-870-RRF Time Analyzed: 7 Units Mono pg/L Tri PCB-19 Method 1668A Laboratory Data Conc. QC Batch No.: Checkcode: Qualifiers 109 Tetra Conc. Qualifiers Tetra 14-Mar-2014 22:02:20 Conc. PCB-1 34.3 PCB-2 2.96 J PCB-30/18 PCB-3 10.2 J PCB-17 381 PCB-45 323 PCB-57 6.11 PCB-27 57.7 PCB-51 103 PCB-58 (1.57) 1,060 C PCB-54 6.02 J PCB-72 14 PCB-50/53 333 C PCB-68 28.8 Conc. 47.5 PCB-24 (1.34) PCB-46 126 PCB-67 34 EMPC 47.5 PCB-16 368 PCB-52 2,350 PCB-63 50 Di Conc. PCB-4 191 PCB-10 8.35 PCB-9 11 PCB-7 4.37 Qualifiers J J PCB-32 317 PCB-34 5.75 PCB-23 (1.66) PCB-73 [3.21] J PCB-43 65.1 PCB-69/49 1,200 C PCB-48 J EMPC C 367 PCB-61/70/74/76 2,650 PCB-66 1,540 PCB-55 13.8 PCB-56 703 PCB-26/29 172 PCB-25 70.7 PCB-44/47/65 1,950 C PCB-60 302 PCB-31 1,110 PCB-59/62/75 143 C PCB-80 (1.38) PCB-6 36.9 PCB-28/20 1,060 C PCB-42 486 PCB-79 14 PCB-5 (1.18) PCB-21/33 382 C PCB-41 132 PCB-78 (1.72) PCB-81 (1.71) PCB 77 PCB-77 123 PCB-8 160 PCB-22 295 PCB-71/40 849 PCB 14 PCB-14 (0 983) (0.983) PCB 36 PCB-36 (1 6) (1.6) PCB 64 PCB-64 773 PCB-11 30.7 B PCB-39 (1.55) PCB-13/12 [10.4] J EMPC C PCB-38 (1.71) PCB-15 102 PCB-35 19 PCB-37 205 C Conc. 545 Conc. 5,610 Conc. 14,700 EMPC 555 EMPC 5,610 EMPC 14,700 Qualifiers J C Totals Conc. Mono-Tri 6,210 6,220 Tel: +1 910 794-1613 Tetra-Hexa 23,300 23,300 www.us.sgs.com Hepta-Deca 2,380 2,380 Mono-Deca 31,900 31,900 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 EMPC 8 of 711 Sample ID: Penta PCB-104 PB020-1SWMID-140313-N (TOTAL) Conc. Qualifiers (0.455) Conc. Qualifiers PCB-108/119/86/97/125/87 716 C PCB-155 PCB-152 (0.473) PCB-146 72.2 C PCB-150 (0.459) PCB-161 (0.54) PCB-96 20.2 PCB-117 PCB-103 11.5 PCB-116/85 PCB-94 [10] PCB-95 770 PCB-100/93 17.3 PCB-102 61.6 PCB-98 PCB-88 PCB-91 205 J EMPC (1.33) 240 Hexa Method 1668A Penta Conc. (0.408) PCB-165 Conc. 1,090 PCB-136 63.9 (1.29) PCB-145 (0.496) PCB-82 167 PCB-148 [1.2] J EMPC PCB-130 35.1 PCB-111 (1.21) PCB-151/135 141 C PCB-137 22.5 (1.7) PCB-120 (1.19) J PCB-164 33.9 (1.72) PCB-107/124 31.3 PCB-109 59.5 JC C PCB-154 8.48 PCB-144 20.7 PCB-147/149 368 330 PCB-123 18.8 PCB-134 31.3 29.7 PCB-106 (1.34) PCB-143 (0.703) PCB-121 (1.19) PCB-118 702 PCB-139/140 PCB-92 157 PCB-122 15.4 PCB-113/90/101 880 PCB-114 21.1 C PCB-158 492 47 PCB-128/166 78.2 C J PCB-131 7.86 J PCB-162 2.15 J PCB-142 (0.833) PCB-167 16.5 PCB-105 370 PCB-132 159 PCB-127 (1.37) PCB-133 8.16 PCB-112 (1.25) PCB-126 [5.08] PCB-156/157 J PCB-169 51.1 J 6,500 Conc. 2,100 EMPC 6,510 EMPC 2,100 Hepta Conc. Nona Conc. (0.543) PCB-174 PCB-179 38.4 PCB-184 (0.661) PCB-176 11.5 PCB-186 (0.638) PCB-172 15.1 PCB-178 20.9 PCB-192 (0.986) Qualifiers Octa Conc. 80.6 PCB-202 PCB-177 52.3 PCB-201 8.49 PCB-181 (1.17) PCB-204 (0.855) PCB-197 6.82 28.6 C 49.1 PCB-206 60.5 J Conc. 163 C EMPC 163 Deca Conc. PCB-180/193 157 C PCB-196 19.7 4.26 J PCB-203 23.6 PCB-182 (1.06) PCB-170 79.5 PCB-195 15 PCB-183 46.3 PCB-185 9.57 PCB-194 36.7 PCB-205 3.03 Conc. 671 Conc. 179 EMPC 671 EMPC 179 209 Congener PCB Summary Page 2 of 2 Qualifiers J 4.77 PCB-191 J PCB-207 44.1 4.5 13.9 53.4 PCB-200 105 3.61 J PCB-208 PCB-198/199 PCB-175 PCB-190 Qualifiers 16.7 PCB-187 PCB-189 C (1.02) Conc. PCB-171/173 C (0.607) 4.27 524 J PCB-160 PCB-159 54.3 J C C JC PCB-83 Qualifiers 351 75.4 10 PCB-99 Conc. PCB-153/168 PCB-141 PCB-163/138/129 Qualifiers (0.582) PCB-110 PCB-84 Hepta Hexa PCB-115 PCB-89 PCB-188 Qualifiers PCB-209 J 1,370 Qualifiers 9 of 711 Sample ID: Method 1668A PB031.1-1SWMID-140313-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 13-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 83.4 PCB-81 344'5-TeCB 3.64 PCB-105 233'44'-PeCB 268 PCB-114 2344'5-PeCB 15.5 PCB-118 23'44'5-PeCB 500 PCB-123 23'44'5'-PeCB 12.3 PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB 35.1 PCB-167 23'44'55'-HxCB 10.9 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB EMPC Aqueous 0.98 L 6 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11892 Qualifier J 1.04 C 1.08 2.05 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.0347 0.103 0 171 0.171 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 31.9 467 4,690 11,100 4,740 1,400 455 90.5 64.6 580 Total PCB (Mono-Deca) 23,600 Checkcode: 645-564-GVL SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6504 0.0348 0.103 0 171 0.171 475 11,100 1,420 459 105 23,600 Date Received: A6504_11892_PCB_002 Date Extracted: J Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 14-Mar-2014 18-Mar-2014 26-Mar-2014 Recovery % 58.4 71.2 82 100 93.1 88.3 99 89.4 88.4 117 97.7 95.8 98.7 97.4 96.7 94.3 96 2 96.2 78.4 80.4 74.6 95.3 97.7 113 98.8 104 91 96.1 109 89 92.1 103 118 Report Created: 31-Mar-2014 18:57 Analyst: CM 10 of 711 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 13-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. PCB-1 25.1 PCB-2 (1.29) PCB-3 6.72 Qualifiers J Aqueous Project No.: A6504 Date Received: 0.98 L Sample ID: A6504_11892_PCB_002 Date Extracted: 18-Mar-2014 11892 Date Analyzed: 26-Mar-2014 645-564-GVL Time Analyzed: 6 Units Mono pg/L Tri Method 1668A Laboratory Data Conc. PCB-19 103 PCB-30/18 918 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. PCB-72 9.5 C PCB-68 32.2 PCB-17 316 PCB-45 261 PCB-57 4.99 J PCB-27 51 PCB-51 85.3 PCB-58 3.02 J PCB-67 25.9 PCB-46 98.3 EMPC 31.9 PCB-16 324 PCB-52 1,790 PCB-32 274 PCB-73 [2.15] PCB-34 4.47 J PCB-43 54.2 PCB-23 (1.63) PCB-69/49 887 C PCB-48 295 169 PCB-10 7.09 J PCB-9 [7.97] PCB-7 3.84 J J 266 (1.19) PCB-4 Qualifiers 5.71 PCB-24 Qualifiers 22:57:34 Conc. PCB-50/53 31.9 Conc. Tetra PCB-54 Conc. Di Qualifiers 14-Mar-2014 J EMPC C PCB-63 38.9 PCB-61/70/74/76 1,940 PCB-66 1,120 PCB-55 (1.79) PCB-56 519 PCB-26/29 140 J EMPC PCB-25 59.8 PCB-44/47/65 1,470 C PCB-60 240 J PCB-31 903 PCB-59/62/75 107 C PCB-80 (1.49) PCB-6 29 PCB-28/20 879 C PCB-42 367 PCB-79 8.84 PCB-5 (1.55) PCB-21/33 296 C PCB-41 113 PCB-78 (1.85) PCB-8 130 PCB-22 245 PCB 14 PCB-14 (1 29) (1.29) PCB 36 PCB-36 (1 57) (1.57) PCB-11 23.5 B PCB-39 (1.51) PCB-13/12 10.6 JC PCB-38 (1.67) PCB-15 94.6 PCB-35 12.9 PCB-37 162 PCB-71/40 658 PCB 64 PCB-64 589 C PCB-81 3.64 PCB 77 PCB-77 83 4 83.4 Conc. 467 Conc. 4,690 Conc. 11,100 EMPC 475 EMPC 4,690 EMPC 11,100 C J J Totals Conc. Mono-Tri 5,190 5,200 Tel: +1 910 794-1613 Tetra-Hexa 17,200 17,200 www.us.sgs.com Hepta-Deca 1,190 1,210 Mono-Deca 23,600 23,600 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 EMPC 11 of 711 Sample ID: Penta PB031.1-1SWMID-140313-N (TOTAL) Conc. Qualifiers PCB-104 (0.591) PCB-96 15.7 PCB-103 7.16 J PCB-94 8.32 J PCB-95 570 JC Hexa Method 1668A Penta Conc. Qualifiers Conc. PCB-108/119/86/97/125/87 523 C PCB-155 (0.437) PCB-117 13.8 PCB-152 (0.507) PCB-146 46.7 PCB-116/85 167 C PCB-150 (0.492) PCB-161 (0.607) PCB-110 792 PCB-136 42.9 PCB-115 (1.2) PCB-145 (0.531) PCB-148 (0.769) PCB-100/93 12.1 PCB-82 125 PCB-102 46.9 PCB-111 (1.12) PCB-98 (1.58) PCB-120 (1.1) PCB-88 (1.59) PCB-107/124 PCB-91 148 PCB-109 96.8 C J EMPC PCB-154 [4.67] 13.3 43.3 PCB-147/149 247 C C PCB-84 244 PCB-123 12.3 PCB-134 21.4 23.8 PCB-106 (1.24) PCB-143 (0.79) PCB-121 (1.1) PCB-118 500 PCB-139/140 [6.05] J EMPC C J PCB-92 114 642 PCB-122 11.4 PCB-131 5.15 PCB-114 15.5 PCB-142 (0.937) PCB-83 44.2 PCB-105 268 PCB-132 111 PCB-99 367 PCB-127 (1.3) PCB-133 5.21 PCB-112 (1.16) PCB-126 (1.04) Hepta PCB-188 Conc. C Qualifiers (0.455) 24.4 12.5 PCB-164 24.1 PCB-160 335 31.1 52.7 C PCB-159 [2.91] J EMPC PCB-162 (0.968) PCB-167 10.9 PCB-169 35.1 1,400 1,420 Hepta Conc. Nona Conc. Octa Conc. Qualifiers 9.14 J PCB-208 20.5 J PCB-207 19.2 PCB-206 24.9 26.2 PCB-177 37.5 PCB-201 4.8 (0.554) PCB-181 (1.02) PCB-204 (0.732) PCB-176 6.5 PCB-171/173 20 JC PCB-197 (0.697) J PCB-200 (0.7) PCB-198/199 28.9 PCB-186 (0.534) PCB-172 10 PCB-178 12.9 PCB-192 (0.857) PCB-175 3.36 109 C PCB-196 13 PCB-187 73.1 PCB-180/193 PCB-191 [1.74] J EMPC PCB-203 [14.6] PCB-182 (0.921) PCB-170 54 PCB-195 10.2 PCB-183 32.1 PCB-185 5.26 PCB-190 11.6 PCB-189 [2.05] J EMPC PCB-194 24.5 PCB-205 (1.32) Conc. 455 Conc. 90.5 EMPC 459 EMPC 105 209 Congener PCB Summary Page 2 of 2 C EMPC Conc. 64.6 EMPC 64.6 Deca Conc. PCB-209 C (1.08) Conc. PCB-202 C PCB-158 EMPC Qualifiers C PCB-128/166 4,740 53.9 Qualifiers (0.682) 4,740 PCB-179 J PCB-130 PCB-137 EMPC PCB-184 J 54.4 Conc. PCB-174 J 234 PCB-141 PCB-156/157 J Conc. (0.654) PCB-153/168 PCB-163/138/129 PCB-89 PCB-113/90/101 Hexa PCB-165 PCB-151/135 PCB-144 23 Qualifiers 580 Qualifiers Qualifiers 12 of 711 Sample ID: Method 1668A PB047.3-1SWMID-140313-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 13-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 43.7 PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB 134 PCB-114 2344'5-PeCB 7.32 PCB-118 23'44'5-PeCB 256 PCB-123 23'44'5'-PeCB 7.24 PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB 18.9 PCB-167 23'44'55'-HxCB 6.35 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB 1.75 Aqueous 0.97 L 6 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11892 Qualifier 1.88 J J 1.03 JC J 1.03 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.0173 0.0842 0 151 0.151 0.0173 0.0842 0 151 0.151 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 25.9 231 2,020 5,520 2,540 796 276 41.3 28.6 223 29.7 266 Total PCB (Mono-Deca) 11,700 Checkcode: 786-548-GYQ SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6504 5,520 2,550 817 63.9 11,800 Date Received: A6504_11892_PCB_003 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 14-Mar-2014 18-Mar-2014 26-Mar-2014 Recovery % 57.4 68.1 78.9 95.8 89.8 84.5 94.4 85.1 85.4 109 89.8 90.5 91.4 90.8 91.8 92.3 91 8 91.8 76.6 78.6 72.9 91.4 93.1 109 93.2 98.8 84.4 89.2 104 79.3 86.3 95 108 Report Created: 31-Mar-2014 18:58 Analyst: CM 13 of 711 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 13-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers PCB-1 17.8 PCB-2 [3.83] J EMPC PCB-3 8.08 J Aqueous Project No.: A6504 Date Received: 0.97 L Sample ID: A6504_11892_PCB_003 Date Extracted: 18-Mar-2014 11892 Date Analyzed: 26-Mar-2014 786-548-GYQ Time Analyzed: 6 Units Mono pg/L Tri Method 1668A Laboratory Data Conc. PCB-19 57.3 PCB-30/18 370 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. Qualifiers Tetra 14-Mar-2014 23:52:48 Conc. Qualifiers J PCB-54 3.89 J PCB-72 4.88 PCB-50/53 141 C PCB-68 13.2 PCB-17 140 PCB-45 117 PCB-57 2.26 PCB-27 24.5 PCB-51 47.8 PCB-58 (1.73) Conc. 25.9 PCB-24 (1.5) PCB-46 51.9 PCB-67 11.9 EMPC 29.7 PCB-16 131 PCB-52 912 PCB-63 18.5 Di Conc. Qualifiers PCB-4 100 PCB-10 5.33 J PCB-9 [4.31] J EMPC PCB-7 (1.49) PCB-6 [12.3] PCB-5 (1.62) EMPC PCB-32 123 PCB-34 2.22 PCB-23 (1.63) PCB-26/29 63 PCB-73 2.66 J PCB-43 27 PCB-69/49 456 C PCB-48 139 J C PCB-61/70/74/76 953 PCB-66 541 PCB-55 5.1 PCB-56 252 PCB-25 27.4 PCB-44/47/65 770 C PCB-60 106 PCB-31 390 PCB-59/62/75 51.6 C PCB-80 (1.53) PCB-28/20 397 C PCB-42 184 PCB-79 [4.02] PCB-21/33 109 C PCB-41 44.1 PCB-78 (1.9) PCB-81 (1.88) PCB 77 PCB-77 43 7 43.7 PCB-8 58.6 PCB-22 103 PCB 14 PCB-14 (1 35) (1.35) PCB 36 PCB-36 (1 57) (1.57) PCB-11 [18.8] B EMPC PCB-39 4.11 PCB-13/12 7.53 JC PCB-38 (1.68) PCB-15 58.9 PCB-35 7.35 PCB-37 71.5 PCB-71/40 330 PCB 64 PCB-64 289 C J C J J EMPC J J Conc. 231 Conc. 2,020 Conc. 5,520 EMPC 266 EMPC 2,020 EMPC 5,520 Totals Conc. EMPC Mono-Tri 2,280 2,320 Tel: +1 910 794-1613 Tetra-Hexa 8,850 8,890 www.us.sgs.com Hepta-Deca 569 592 Mono-Deca 11,700 11,800 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 14 of 711 Sample ID: Penta PCB-104 PB047.3-1SWMID-140313-N (TOTAL) Conc. Qualifiers (0.593) PCB-96 9.67 J PCB-103 [4.47] J EMPC PCB-94 5.62 J PCB-95 324 PCB-100/93 (1.73) C Conc. Qualifiers PCB-108/119/86/97/125/87 280 C PCB-155 (0.488) PCB-165 PCB-152 (0.565) PCB-146 28.8 C PCB-150 (0.549) PCB-161 (0.624) PCB-117 PCB-116/85 (1.39) 98.2 Hexa Method 1668A Penta Conc. PCB-110 419 PCB-136 25.4 PCB-115 (1.35) PCB-145 (0.592) PCB-148 (0.79) Qualifiers Hexa Conc. Qualifiers (0.673) PCB-153/168 140 PCB-141 29.7 C PCB-82 64 PCB-130 [11.7] EMPC PCB-102 23.6 PCB-111 (1.26) PCB-151/135 57.5 C PCB-137 6.78 J PCB-98 (1.77) PCB-120 (1.24) PCB-154 3.18 J PCB-164 12.9 PCB-88 (1.79) PCB-107/124 12.7 PCB-144 8.03 J PCB-163/138/129 PCB-91 84.3 PCB-109 22.8 PCB-147/149 146 C PCB-160 PCB-84 139 PCB-123 7.24 PCB-134 [10] J EMPC PCB-89 12.4 PCB-106 (1.4) PCB-143 (0.812) PCB-121 (1.24) PCB-118 256 PCB-139/140 PCB-92 66.7 PCB-113/90/101 352 PCB-83 JC J 4.1 JC J PCB-122 [4.91] J EMPC PCB-131 3.21 PCB-114 7.32 J PCB-142 (0.963) 19.7 PCB-105 134 PCB-132 63.4 PCB-99 200 PCB-127 (1.4) PCB-133 3.38 PCB-112 (1.31) PCB-126 (1.03) Hepta PCB-188 Conc. C Qualifiers 8.13 PCB-175 (1.47) J J 18.9 JC PCB-169 (1.03) Hepta Conc. Nona Conc. Conc. Qualifiers 4.58 J PCB-208 8.41 Qualifiers J PCB-201 2.84 J PCB-207 7.92 J PCB-204 (0.917) PCB-206 12.3 31 PCB-202 PCB-177 22.8 PCB-181 (1.49) PCB-171/173 12 JC PCB-197 (0.874) PCB-172 6.34 J PCB-200 (0.877) PCB-192 (1.25) PCB-198/199 19.8 JC PCB-180/193 67.7 C PCB-196 7.84 J J PCB-203 [8.63] J EMPC PCB-195 6.21 J EMPC PCB-187 45.1 PCB-191 1.27 PCB-182 (1.34) PCB-170 30.1 PCB-183 19.9 PCB-185 2.92 J 6.35 PCB-156/157 796 16.5 PCB-178 (0.93) 817 Octa C PCB-162 Conc. Qualifiers C PCB-167 EMPC (0.713) J (0.926) 2,540 PCB-184 4.53 PCB-159 2,550 PCB-179 (0.688) 16.8 30.6 Conc. PCB-174 PCB-186 PCB-158 PCB-128/166 EMPC (0.585) PCB-176 J 191 (0.701) PCB-190 6.33 J PCB-194 [14] PCB-189 1.75 J PCB-205 (1.35) Conc. 276 Conc. 41.3 EMPC 276 EMPC 63.9 209 Congener PCB Summary Page 2 of 2 Conc. 28.6 EMPC 28.6 Deca Conc. PCB-209 223 Qualifiers 15 of 711 Sample ID: Method 1668A PB056_C-1SWMID-140313-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 13-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 298 PCB-81 344'5-TeCB 15.4 PCB-105 233'44'-PeCB 977 PCB-114 2344'5-PeCB 56 PCB-118 23'44'5-PeCB 1,660 PCB-123 23'44'5'-PeCB 48.8 PCB-126 33'44'5-PeCB 10.7 PCB-156/157 233'44'5/233'44'5'-HxCB 108 PCB-167 23'44'55'-HxCB 31 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB EMPC Aqueous 0.97 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 1.11 5.03 1.19 1.21 1 23 1.23 1.19 1.21 1 23 1.23 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 33.7 747 10,400 32,500 14,900 3,730 1,070 253 85.4 545 41.4 Total PCB (Mono-Deca) 64,300 Checkcode: 848-343-NKY SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11892 Qualifier C TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6504 32,500 3,780 1,080 64,400 Date Received: A6504_11892_PCB_004 Date Extracted: J Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 14-Mar-2014 18-Mar-2014 27-Mar-2014 Recovery % 56.8 69.5 83.2 98.3 93.1 87.8 100 89 87.8 111 93.2 93.1 95.4 94.1 92.1 94 93 3 93.3 77.8 79 73.1 95.8 97.8 110 98.6 99.7 89.5 93.3 108 83.6 87.3 92.8 111 Report Created: 31-Mar-2014 18:58 Analyst: CM 16 of 711 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 13-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. PCB-1 33.7 PCB-2 (1.36) PCB-3 [7.73] Qualifiers Project No.: A6504 Date Received: 0.97 L Sample ID: A6504_11892_PCB_004 Date Extracted: 18-Mar-2014 11892 Date Analyzed: 27-Mar-2014 848-343-NKY Time Analyzed: pg/L Tri PCB-19 Conc. PCB-17 1,790 QC Batch No.: Checkcode: Qualifiers 155 PCB-30/18 J EMPC Aqueous 7 Units Mono Method 1668A Laboratory Data C 625 Tetra Conc. Qualifiers Tetra 14-Mar-2014 00:47:55 Conc. PCB-54 9.82 J PCB-72 PCB-50/53 690 C PCB-68 30.5 PCB-45 661 PCB-57 13.7 22.6 PCB-27 98.7 PCB-51 167 PCB-58 [4.67] Conc. 33.7 PCB-24 11.4 PCB-46 251 PCB-67 81.2 EMPC 41.4 PCB-16 623 PCB-52 4,870 PCB-63 PCB-32 559 PCB-73 (0.761) PCB-34 8.85 J PCB-43 170 PCB-23 (1.37) C PCB-48 Di Conc. PCB-4 218 PCB-10 8.21 PCB-9 14.5 PCB-7 5.88 Qualifiers J J PCB-69/49 2,500 C 846 6,230 PCB-66 3,610 PCB-55 (2.14) PCB-56 1,710 327 PCB-25 133 PCB-44/47/65 4,100 C PCB-60 809 PCB-31 2,170 PCB-59/62/75 298 C PCB-80 (1.78) PCB-6 54.3 PCB-28/20 2,130 C PCB-42 1,050 PCB-79 31.8 PCB-5 (1.71) PCB-21/33 702 C PCB-41 353 PCB-78 (2.22) PCB-81 15.4 PCB 77 PCB-77 298 233 PCB-22 594 PCB 14 PCB-14 (1 42) (1.42) PCB 36 PCB-36 (1 32) (1.32) PCB-11 30.9 B PCB-39 26 PCB-13/12 22.4 C PCB-15 160 PCB-38 6.85 PCB-35 39 PCB-37 447 PCB-71/40 1,840 PCB 64 PCB-64 1 690 1,690 C J EMPC 125 PCB-61/70/74/76 PCB-26/29 PCB-8 Qualifiers C J Conc. 747 Conc. 10,400 Conc. 32,500 EMPC 747 EMPC 10,400 EMPC 32,500 Totals Conc. EMPC Mono-Tri 11,200 11,200 Tel: +1 910 794-1613 Tetra-Hexa 51,100 51,200 www.us.sgs.com Hepta-Deca 1,960 1,970 Mono-Deca 64,300 64,400 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 17 of 711 Sample ID: Penta PB056_C-1SWMID-140313-N (TOTAL) Conc. Qualifiers Penta Conc. Qualifiers PCB-108/119/86/97/125/87 1,700 C PCB-104 (0.408) PCB-96 48.8 PCB-117 68.5 PCB-103 19.7 PCB-116/85 566 C Hexa PCB-155 Method 1668A Conc. PCB-152 (0.47) PCB-146 115 PCB-150 (0.456) PCB-161 (0.491) 24.1 PCB-110 2,430 PCB-136 107 1,600 PCB-115 (1.68) PCB-145 (0.492) PCB-100/93 38.7 PCB-82 417 PCB-148 (0.621) PCB-102 138 PCB-111 (1.56) PCB-151/135 240 PCB-98 (2.2) PCB-120 (1.54) PCB-154 10.8 PCB-88 (2.22) PCB-144 39.9 PCB-91 467 PCB-147/149 608 PCB-107/124 81.2 135 C PCB-84 731 PCB-123 48.8 PCB-134 56.1 PCB-89 73.3 PCB-106 (1.74) PCB-143 (0.638) PCB-121 (1.54) PCB-118 1,660 PCB-139/140 18.9 PCB-92 357 PCB-122 40.1 PCB-131 PCB-113/90/101 PCB-153/168 593 PCB-141 154 PCB-130 68.7 PCB-137 [44.2] PCB-164 60.7 PCB-163/138/129 C 926 PCB-160 (0.551) PCB-158 93.6 159 J 16.4 PCB-162 3.54 J 56 PCB-142 (0.757) PCB-167 31 977 PCB-132 306 PCB-156/157 108 PCB-99 1,160 PCB-127 (1.73) PCB-133 12.5 PCB-169 PCB-112 (1.63) PCB-126 Qualifiers C [10.7] 14,900 Conc. 3,730 EMPC 14,900 EMPC 3,780 Hepta Conc. Nona Conc. Qualifiers 129 Octa PCB-202 Conc. PCB-179 58.6 PCB-177 82.9 PCB-201 9.6 (0.597) PCB-181 [1.85] J EMPC PCB-204 (0.825) PCB-176 17.3 PCB-171/173 48.5 C PCB-197 4.31 PCB-186 (0.576) PCB-172 25.5 PCB-178 29.5 PCB-192 (1.04) J PCB-208 25.9 PCB-207 21.1 PCB-206 38.3 PCB-200 7.64 J Conc. 85.4 68.9 C EMPC 85.4 Deca Conc. PCB-175 6.36 PCB-180/193 263 C PCB-196 30.2 161 PCB-191 6.36 J PCB-203 35.6 PCB-182 (1.12) PCB-170 133 PCB-195 22.2 PCB-183 75.4 PCB-190 25.7 PCB-194 54.9 PCB-185 12.8 PCB-189 [5.03] PCB-205 3.01 Conc. 1,070 Conc. 253 EMPC 1,080 EMPC 253 209 Congener PCB Summary Page 2 of 2 Qualifiers J PCB-198/199 PCB-187 J EMPC Qualifiers 16.7 PCB-184 J C (1.11) Conc. PCB-174 C 6.72 PCB-105 (0.49) EMPC PCB-159 JC PCB-114 Conc. C PCB-128/166 146 Hepta C C Qualifiers (0.529) PCB-83 PCB-188 1,950 Conc. PCB-165 PCB-95 PCB-109 Hexa (0.405) PCB-94 C Qualifiers PCB-209 J 545 Qualifiers 18 of 711 Sample ID: Method 1668A PB056_C-1SWMID-140313-N (DISSOLVED) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 13-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 46.6 PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB 110 PCB-114 2344'5-PeCB 6.7 PCB-118 23'44'5-PeCB 199 PCB-123 23'44'5'-PeCB 5.35 PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB 9.76 PCB-167 23'44'55'-HxCB 3.06 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 0.96 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11892 Qualifier 1.67 J J 0.899 JC J 0.701 0.874 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.0147 0.0704 0 126 0.126 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 31.4 463 4,650 8,380 2,140 357 65.2 7.41 11.9 65 Total PCB (Mono-Deca) 16,200 Checkcode: 681-037-MXQ SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6504 0.0147 0.0704 0 126 0.126 4,660 2,170 368 88.5 17.2 16,300 Date Received: A6504_11892_PCB_005 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 14-Mar-2014 18-Mar-2014 27-Mar-2014 Recovery % 54 66.2 72.8 95.2 86.6 84.6 94.2 86.7 84.8 110 91.3 91.4 94.2 92.4 93.2 92.3 94 8 94.8 78.2 79.5 74 91.7 94.4 111 93.5 104 86.8 91.8 105 84.7 84.5 94.1 111 Report Created: 31-Mar-2014 18:58 Analyst: CM 19 of 711 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 13-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. PCB-1 26.4 PCB-2 (1.21) PCB-3 4.96 Qualifiers J Conc. PCB-19 96.7 PCB-30/18 995 681-037-MXQ Time Analyzed: Checkcode: Qualifiers C Tetra Conc. 01:43:07 Conc. Qualifiers J PCB-54 3.83 J PCB-72 4.59 PCB-50/53 238 C PCB-68 16.7 PCB-57 3.32 PCB-58 (1.53) Conc. PCB-32 275 PCB-34 3.65 PCB-23 (1.61) PCB-26/29 136 PCB-25 53.3 J EMPC PCB-46 83.3 PCB-67 18.5 PCB-52 1,490 PCB-63 27.1 PCB-61/70/74/76 1,330 PCB-73 (0.899) J PCB-43 47 PCB-69/49 697 C PCB-48 242 C PCB-44/47/65 1,170 C C PCB-7 (1.83) PCB-31 894 PCB-59/62/75 84.3 PCB-6 33.7 PCB-28/20 818 C PCB-42 285 PCB-5 (1.99) PCB-21/33 277 C PCB-41 93.2 PCB-8 136 PCB-22 239 PCB-71/40 510 PCB 14 PCB-14 (1 66) (1.66) PCB 36 PCB-36 (1 55) (1.55) PCB 64 PCB-64 461 PCB-11 24.3 B PCB-39 (1.49) PCB-13/12 11.6 JC PCB-38 (1.65) PCB-35 12.3 PCB-37 137 80 Tetra 227 Di PCB-15 Qualifiers 58.4 340 (2.1) 27-Mar-2014 PCB-45 [5.73] PCB-9 Date Analyzed: PCB-51 PCB-16 J 18-Mar-2014 11892 QC Batch No.: 14-Mar-2014 321 PCB-24 170 Date Extracted: 55.5 31.4 7.43 Date Received: A6504_11892_PCB_005 PCB-17 31.4 PCB-10 A6504 Sample ID: PCB-27 Conc. PCB-4 Project No.: 0.96 L pg/L Tri EMPC Qualifiers Aqueous 7 Units Mono Method 1668A Laboratory Data C PCB-66 729 PCB-55 (1.63) PCB-56 350 PCB-60 168 PCB-80 (1.36) PCB-79 (1.42) PCB-78 (1.69) PCB-81 (1.67) PCB 77 PCB-77 46 6 46.6 Conc. 463 Conc. 4,650 Conc. 8,380 EMPC 463 EMPC 4,660 EMPC 8,380 J C Totals Conc. Mono-Tri 5,150 5,150 Tel: +1 910 794-1613 Tetra-Hexa 10,900 10,900 www.us.sgs.com Hepta-Deca 150 183 Mono-Deca 16,200 16,300 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 EMPC 20 of 711 Sample ID: Penta PCB-104 PB056_C-1SWMID-140313-N (DISSOLVED) Conc. Qualifiers (0.576) J Hexa Conc. Conc. Qualifiers PCB-108/119/86/97/125/87 247 C PCB-155 (0.443) PCB-165 PCB-117 6.51 J PCB-152 (0.513) PCB-146 11.9 PCB-116/85 75.6 C PCB-150 (0.499) PCB-161 (0.584) PCB-96 8.95 PCB-103 (1.33) PCB-94 (1.58) PCB-110 357 PCB-136 [11.3] PCB-95 292 PCB-115 (1.13) PCB-145 (0.538) PCB-148 (0.74) J EMPC C Method 1668A Penta PCB-100/93 [5.66] PCB-82 56.2 PCB-102 23.8 PCB-111 (1.05) PCB-98 (1.48) PCB-120 (1.03) PCB-88 (1.49) PCB-107/124 PCB-151/135 9.47 26.5 Qualifiers EMPC Hexa Conc. Qualifiers (0.63) PCB-153/168 59.7 PCB-141 14.6 C PCB-130 6.86 J C PCB-137 4.29 J PCB-164 6.38 J PCB-163/138/129 87.4 C PCB-154 (0.662) JC PCB-144 3.96 J PCB-147/149 63.4 C PCB-160 J PCB-134 5.83 J PCB-158 9.56 J PCB-143 (0.76) PCB-128/166 13.5 JC PCB-91 70.7 PCB-109 16.7 PCB-84 125 PCB-123 5.35 PCB-89 13 PCB-106 (1.17) PCB-121 (1.04) PCB-118 199 PCB-139/140 (0.748) PCB-159 (0.672) PCB-92 55.1 PCB-122 5.32 J PCB-131 (0.881) PCB-162 (0.675) PCB-113/90/101 295 C PCB-114 6.7 J PCB-142 (0.901) PCB-167 3.06 J [20.2] EMPC PCB-105 110 PCB-132 30.2 PCB-156/157 9.76 JC PCB-133 (0.801) PCB-83 PCB-99 164 PCB-127 (1.23) PCB-112 (1.09) PCB-126 (0.899) Hepta PCB-188 Conc. Qualifiers (0.553) PCB-179 5.81 PCB-184 (0.673) PCB-176 1.66 PCB-186 (0.65) PCB-178 2.9 PCB-175 (1.08) PCB-187 [13] PCB-182 (0.985) PCB-183 6.5 PCB-185 (1.12) J J J (0.701) Conc. 2,140 Conc. 357 2,170 EMPC 368 Hepta Conc. Qualifiers Nona Conc. [10.4] EMPC PCB-177 7.6 J PCB-181 (1.09) PCB-171/173 4.92 JC Octa PCB-202 Conc. Qualifiers 1.74 J (0.838) PCB-207 3.01 J PCB-206 6 J (0.859) PCB-200 (0.862) PCB-192 (0.917) PCB-198/199 [6.1] J EMPC C PCB-196 2.78 J J PCB-191 (0.872) PCB-203 2.89 PCB-170 11.4 PCB-195 (1.52) PCB-190 2.06 PCB-189 (0.874) J Qualifiers J (0.901) PCB-197 C 2.93 PCB-201 (1.19) 22.3 PCB-208 PCB-204 PCB-172 PCB-180/193 EMPC PCB-169 EMPC PCB-174 J C (0.656) PCB-194 [3.71] PCB-205 (1.08) Conc. 65.2 Conc. 7.41 EMPC 88.5 EMPC 17.2 209 Congener PCB Summary Page 2 of 2 Conc. 11.9 EMPC 11.9 Deca Conc. PCB-209 J EMPC 65 Qualifiers 21 of 711 Sample ID: Method 1668A EF006.1-1SWMID-140313-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 13-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 11.4 PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB 43.9 PCB-114 2344'5-PeCB EMPC PCB-118 23'44'5-PeCB 76.9 PCB-123 23'44'5'-PeCB ND PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB 10.8 PCB-167 23'44'55'-HxCB 3.58 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 0.93 L 6 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 2.2 J 0.779 1.07 JC J 0.971 1.03 0.00519 0.0733 0 141 0.141 0.00526 0.0734 0 142 0.142 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB ND 43.7 276 997 634 334 120 10.7 4.15 41.4 Total PCB (Mono-Deca) 2,460 Checkcode: 889-569-FHN SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11892 Qualifier 1.25 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6504 1.46 1,000 638 337 123 26.6 6.67 2,490 Date Received: A6504_11892_PCB_006 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 14-Mar-2014 18-Mar-2014 27-Mar-2014 Recovery % 42.1 51 55.1 80.3 65.9 79.4 78 83.6 82.3 99.9 91.7 89.8 93.3 89.5 91 87.6 86 5 86.5 71.5 75.7 65.7 89.2 92 102 86.3 96.7 73.9 75.5 97.8 67.1 84.7 96.4 112 Report Created: 31-Mar-2014 18:58 Analyst: CM 22 of 711 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 13-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers Aqueous Project No.: A6504 Date Received: 0.93 L Sample ID: A6504_11892_PCB_006 Date Extracted: 18-Mar-2014 11892 Date Analyzed: 27-Mar-2014 889-569-FHN Time Analyzed: 6 Units Mono pg/L Tri Method 1668A Laboratory Data Conc. QC Batch No.: Checkcode: Qualifiers Tetra Conc. PCB-1 (1.45) PCB-19 8.17 J PCB-54 PCB-2 (1.32) PCB-30/18 53.2 C PCB-50/53 18.2 PCB-3 (1.47) PCB-17 18.3 PCB-45 13.9 (0.732) Tetra PCB-72 JC 02:38:21 Conc. 23.4 PCB-57 (1.16) PCB-58 (1.15) PCB-67 (1.08) PCB-63 (1.03) PCB-27 4.75 PCB-51 21.7 0 PCB-24 (1.85) PCB-46 5.86 EMPC 0 PCB-16 17 PCB-52 182 PCB-32 19.3 PCB-73 (0.63) PCB-61/70/74/76 148 PCB-43 (0.97) PCB-66 118 PCB-55 (1.22) Conc. Qualifiers PCB-34 (1.44) J PCB-23 (1.42) PCB-4 8.69 PCB-10 (1.89) PCB-26/29 9.45 JC PCB-9 (1.61) PCB-25 6.08 J PCB-7 (1.41) PCB-31 46.7 PCB-6 (1.53) PCB-28/20 67.7 C PCB-5 (1.53) PCB-21/33 11.2 JC PCB-8 5.1 PCB 14 PCB-14 (1 28) (1.28) PCB-11 23.1 B (1.47) C PCB-38 (1.46) 6.74 J PCB-35 (1.51) PCB-37 (1.64) PCB-13/12 PCB-15 J PCB-22 13.9 PCB 36 PCB-36 (1 37) (1.37) PCB-39 (1.32) J PCB-69/49 82.4 PCB-48 14.1 C PCB-44/47/65 140 PCB-59/62/75 11.1 PCB-42 26.3 PCB-41 [5.49] J EMPC PCB-71/40 51.8 C PCB 64 PCB-64 58 3 58.3 Qualifiers (1.1) PCB-68 Conc. Di J Qualifiers 14-Mar-2014 PCB-56 42.5 C PCB-60 27.8 JC PCB-80 (1.01) PCB-79 (1.06) PCB-78 (1.26) PCB-81 (1.25) PCB 77 PCB-77 11 4 11.4 Conc. 43.7 Conc. 276 Conc. 997 EMPC 43.7 EMPC 276 EMPC 1,000 C Totals Conc. Mono-Tri 319 319 Tel: +1 910 794-1613 Tetra-Hexa 1,960 1,980 www.us.sgs.com Hepta-Deca 176 197 Mono-Deca 2,460 2,490 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 EMPC 23 of 711 Sample ID: Penta PCB-104 EF006.1-1SWMID-140313-N (TOTAL) Conc. Qualifiers (0.472) Conc. Qualifiers PCB-108/119/86/97/125/87 67.4 C PCB-155 PCB-152 (0.451) PCB-146 12.1 C PCB-150 (0.438) PCB-161 (0.494) Conc. (0.58) PCB-117 PCB-103 (0.991) PCB-116/85 PCB-94 (1.18) PCB-110 115 PCB-136 6.76 PCB-95 66 PCB-115 (0.842) PCB-145 (0.472) PCB-148 (0.625) 27 Qualifiers (0.389) PCB-96 PCB-100/93 (0.868) Hexa Method 1668A Penta PCB-165 J (1.08) C PCB-82 12.6 PCB-102 4.27 J PCB-111 (0.785) PCB-151/135 PCB-98 (1.11) PCB-120 (0.773) PCB-154 (0.559) PCB-88 (1.12) PCB-107/124 PCB-144 [2.27] J EMPC 3.37 JC J 19.5 Hexa JC Conc. Qualifiers (0.532) PCB-153/168 59.6 PCB-141 12.2 C PCB-130 6.79 J PCB-137 4.35 J PCB-164 6.1 J PCB-163/138/129 90.5 C PCB-91 16.7 PCB-109 7.32 PCB-147/149 48.9 C PCB-160 PCB-84 26.5 PCB-123 (0.779) PCB-134 5.42 J PCB-158 8.68 J PCB-89 [1.86] PCB-106 (0.872) PCB-143 (0.642) PCB-128/166 15.1 JC PCB-139/140 (0.632) PCB-159 (0.805) PCB-131 (0.744) PCB-162 (0.809) PCB-142 (0.761) PCB-167 3.58 J PCB-156/157 10.8 JC J EMPC PCB-121 (0.775) PCB-118 76.9 PCB-92 18.1 PCB-122 (0.927) PCB-113/90/101 89.2 C PCB-114 [2.2] PCB-83 6.69 J PCB-105 43.9 PCB-132 24 PCB-133 (0.677) J EMPC PCB-99 52.5 PCB-127 (0.871) PCB-112 (0.816) PCB-126 (1.07) Hepta PCB-188 Conc. Qualifiers (0.541) PCB-179 5.55 PCB-184 (0.659) PCB-176 1.32 PCB-186 (0.636) PCB-178 3.97 PCB-175 (0.897) J J 634 Conc. 334 638 EMPC 337 Hepta Conc. Nona Conc. Qualifiers 13.8 PCB-177 8.34 PCB-181 (0.908) J Conc. Qualifiers PCB-202 Octa 2.55 J PCB-201 (0.748) PCB-204 (0.805) PCB-171/173 5.48 JC PCB-197 (0.767) PCB-172 3.46 J PCB-200 (0.77) PCB-192 (0.763) PCB-198/199 [8.64] J EMPC C PCB-196 3.99 J J PCB-180/193 33 C 18.3 PCB-191 (0.726) PCB-203 4.18 PCB-182 (0.82) PCB-170 18 PCB-195 (1.86) 8.74 PCB-185 (0.933) J (0.971) Conc. PCB-187 PCB-183 PCB-169 EMPC PCB-174 J C (0.554) PCB-190 [2.93] PCB-189 (1.03) J EMPC PCB-194 [7.22] PCB-205 (1.31) Conc. 120 Conc. 10.7 EMPC 123 EMPC 26.6 209 Congener PCB Summary Page 2 of 2 4.15 Qualifiers J PCB-207 [2.52] J EMPC PCB-206 (3.69) PCB-208 Conc. 4.15 EMPC 6.67 Deca Conc. PCB-209 J EMPC 41.4 Qualifiers 24 of 711 Sample ID: Method 1668A PB119_B-1SWMID-140313-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 13-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 3.49 PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB EMPC PCB-114 2344'5-PeCB ND PCB-118 23'44'5-PeCB 13.2 PCB-123 23'44'5'-PeCB ND PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB 1.69 PCB-167 23'44'55'-HxCB ND PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 0.94 L 6 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L A6504 11892 Qualifier J 1.44 4.26 J 0.788 B 0.814 1.6 JC 0.547 0.711 0.781 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.000796 0.0916 0 182 0.182 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB ND 30.4 85.4 187 83.3 75.4 32.4 8.39 ND 2.49 Total PCB (Mono-Deca) 504 Checkcode: 251-126-RZF 0.000924 0.0917 0 183 0.183 1.67 189 108 77.1 34.6 9.64 2.68 J 537 SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA Date Received: A6504_11892_PCB_007 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 14-Mar-2014 18-Mar-2014 27-Mar-2014 Recovery % 44.9 55.8 62.4 88.1 74.9 82.7 83.5 87.2 84.7 101 90.8 89.8 92.2 90.6 91.4 90.2 87 5 87.5 75 75.6 69.4 90.9 94.3 107 94.6 100 84 89.6 105 82.1 85.9 95.1 112 Report Created: 31-Mar-2014 18:59 Analyst: CM 25 of 711 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 13-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers Aqueous Project No.: A6504 Date Received: 0.94 L Sample ID: A6504_11892_PCB_007 Date Extracted: 18-Mar-2014 11892 Date Analyzed: 27-Mar-2014 251-126-RZF Time Analyzed: 6 Units Mono pg/L Tri Method 1668A Laboratory Data Conc. QC Batch No.: Checkcode: Qualifiers (2.54) Tetra PCB-1 (1.7) PCB-19 PCB-2 (1.49) PCB-30/18 13.5 PCB-3 (1.65) PCB-17 11.3 PCB-45 Conc. PCB-54 JC Qualifiers (0.678) PCB-50/53 [2.13] Tetra PCB-72 J EMPC C 14-Mar-2014 03:33:35 Conc. Qualifiers (1.27) PCB-68 30.1 (0.975) PCB-57 (1.34) PCB-27 (1.62) PCB-51 26.3 PCB-58 (1.32) Conc. 0 PCB-24 (1.7) PCB-46 (1.09) PCB-67 (1.25) EMPC 0 PCB-16 6.94 J PCB-52 23.5 PCB-63 (1.19) PCB-32 4.63 J PCB-73 (0.681) PCB-61/70/74/76 23.4 JBC (1.05) PCB-66 8.86 J JBC PCB-55 (1.4) Di Conc. Qualifiers PCB-34 (1.54) PCB-43 PCB-4 7.04 J PCB-23 (1.52) PCB-69/49 9.2 B PCB-10 (1.57) PCB-26/29 2.75 JC PCB-48 3.09 J PCB-56 4.52 J PCB-9 (1.62) PCB-25 4.58 J PCB-44/47/65 33.6 C PCB-60 2.97 J PCB-7 (1.42) PCB-31 12.2 B PCB-59/62/75 (0.645) C PCB-80 (1.17) J PCB-6 (1.54) PCB-28/20 14.9 JBC PCB-42 3.73 PCB-5 (1.54) PCB-21/33 3.24 JC PCB-41 (1.07) PCB-8 (1.47) PCB-22 3.33 J PCB 14 PCB-14 (1 28) (1.28) PCB 36 PCB-36 (1 46) (1.46) PCB-11 15 B PCB-39 (1.41) (1.48) C PCB-38 (1.55) 8.3 J PCB-35 (1.62) PCB-37 7.91 PCB-13/12 PCB-15 PCB-79 (1.23) PCB-78 (1.45) PCB-71/40 7.71 JC PCB-81 (1.44) PCB 64 PCB-64 61 6.1 J PCB 77 PCB-77 3 49 3.49 J J Conc. 30.4 Conc. 85.4 Conc. 187 EMPC 30.4 EMPC 85.4 EMPC 189 Totals Conc. EMPC Mono-Tri 116 116 Tel: +1 910 794-1613 Tetra-Hexa 345 374 www.us.sgs.com Hepta-Deca 43.3 46.7 Mono-Deca 504 537 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 26 of 711 Sample ID: Penta PB119_B-1SWMID-140313-N (TOTAL) Conc. PCB-104 (0.604) Qualifiers Conc. Qualifiers PCB-108/119/86/97/125/87 [12.8] J EMPC C PCB-155 PCB-152 (0.573) PCB-146 3.02 [2.64] J EMPC C PCB-150 (0.556) PCB-161 (0.651) B Conc. Qualifiers 1.4 J Hexa PCB-165 Conc. Qualifiers (0.701) PCB-96 (0.742) PCB-117 PCB-103 (1.03) PCB-116/85 PCB-94 (1.23) PCB-110 20.4 PCB-136 2.61 PCB-153/168 16.3 JBC PCB-95 16 B PCB-115 (0.879) PCB-145 (0.6) PCB-141 3.27 J (1.13) C PCB-82 (1.42) PCB-148 (0.824) PCB-130 (1.02) PCB-100/93 (0.906) Hexa Method 1668A Penta PCB-102 (1.12) PCB-111 (0.82) PCB-151/135 PCB-137 (0.806) PCB-98 (1.15) PCB-120 (0.807) PCB-154 (0.737) PCB-164 (0.675) PCB-88 (1.17) PCB-107/124 (0.897) PCB-144 (0.839) PCB-163/138/129 PCB-91 2.95 J PCB-109 (0.807) J EMPC C PCB-147/149 7.43 J 14.7 JC JBC 16.9 PCB-160 (0.731) J JBC PCB-84 [5.43] PCB-123 (0.814) PCB-134 (1.14) PCB-158 [1.71] J EMPC PCB-89 (1.26) PCB-106 (0.91) PCB-143 (0.846) PCB-128/166 2.84 JC PCB-121 (0.809) PCB-118 13.2 PCB-139/140 (0.834) B C PCB-159 (0.592) PCB-92 3.34 J PCB-122 (0.939) PCB-131 (0.981) PCB-162 (0.594) PCB-113/90/101 19.3 JBC PCB-114 (0.788) PCB-142 (1) PCB-167 (0.547) PCB-105 [4.26] J PCB-127 (0.89) PCB-126 (1.6) PCB-83 (1.49) PCB-99 8.09 PCB-112 (0.852) Hepta PCB-188 Conc. Qualifiers (0.581) J EMPC PCB-132 5.17 PCB-133 (0.892) 83.3 Conc. 75.4 108 EMPC 77.1 Hepta Conc. Qualifiers Nona Conc. 3.59 J J EMPC PCB-174 Octa PCB-202 Conc. Qualifiers [1.25] J EMPC 2.93 J PCB-177 [2.15] 2.99 J PCB-181 (0.846) PCB-176 (0.639) PCB-171/173 (0.967) PCB-197 (0.73) PCB-186 (0.682) PCB-172 (0.924) PCB-200 (0.733) PCB-178 (0.977) PCB-192 (0.711) PCB-198/199 PCB-175 (0.836) PCB-180/193 6.65 (0.764) PCB-183 2.69 PCB-185 (0.869) J J 1.69 9.83 C PCB-208 PCB-201 (0.712) PCB-207 (1.96) (0.766) PCB-206 (3.37) JC PCB-196 PCB-203 2.2 J PCB-195 (1.52) Conc. 0 EMPC 0 Deca Conc. Qualifiers 2.49 J (1.04) PCB-191 (0.677) PCB-170 3.74 PCB-190 (0.71) PCB-194 1.98 PCB-189 (0.781) PCB-205 (1.08) Conc. 32.4 Conc. 8.39 EMPC 34.6 EMPC 9.64 209 Congener PCB Summary Page 2 of 2 JC Qualifiers (1.99) PCB-204 4.21 JC (0.711) EMPC PCB-184 PCB-182 PCB-156/157 PCB-169 Conc. PCB-179 PCB-187 J J PCB-209 J 27 of 711 Sample ID: Method 1668A EB1-01 (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 13-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB ND PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB ND PCB-114 2344'5-PeCB ND PCB-118 23'44'5-PeCB 2.66 PCB-123 23'44'5'-PeCB ND PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB ND PCB-167 23'44'55'-HxCB ND PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 0.97 L 5 DL pg/L 1.6 1.75 1.22 1.04 Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB Total PCB (Mono-Deca) Checkcode: 842-903-YGS 0.0000799 0.107 0 214 0.214 ND 16.1 16.5 151 16.1 2.84 ND ND ND 202 C 0.0000799 0.107 0 214 0.214 3.05 21 155 11.1 4.69 1.53 4.13 1.69 224 SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11892 Qualifier JB 1.11 1.73 1.63 1.06 1.34 1.5 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6504 Date Received: A6504_11892_PCB_008 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 14-Mar-2014 18-Mar-2014 27-Mar-2014 Recovery % 47.8 61.2 69.7 94 84.7 83.6 90.2 88.7 85.5 108 92.8 92.7 95.4 92.2 94.2 95.4 94 9 94.9 78.9 82.3 75.1 99.4 98.8 113 102 104 93.1 96 112 91.4 86.3 95.4 113 Report Created: 31-Mar-2014 18:59 Analyst: CM 28 of 711 Sample ID: EB1-01 (TOTAL) Client Data ANCHOR QEA Name: Project ID: Method 1668A Sample Data Patrick Bayou Superfund Site 13-Mar-2014 Date Collected: Laboratory Data Matrix: Weight/Volume: pH Conc. Qualifiers Project No.: A6504 Date Received: 0.97 L Sample ID: A6504_11892_PCB_008 Date Extracted: 18-Mar-2014 11892 Date Analyzed: 27-Mar-2014 842-903-YGS Time Analyzed: 5 Units Mono Aqueous pg/L Tri Conc. QC Batch No.: Checkcode: Qualifiers Tetra Conc. PCB-1 (3.34) PCB-19 (4.32) PCB-54 (1.38) PCB-2 (2.49) PCB-30/18 (3.22) C PCB-50/53 (1.7) PCB-3 (2.76) PCB-17 8.35 J PCB-45 Qualifiers Tetra PCB-72 C 14-Mar-2014 04:28:49 Conc. (1.54) PCB-68 37.1 (1.87) PCB-57 (1.62) PCB-27 (2.76) PCB-51 81.8 PCB-58 (1.6) Conc. 0 PCB-24 (2.89) PCB-46 (2.1) PCB-67 (1.51) EMPC 0 PCB-16 (5.05) PCB-52 [4.45] PCB-63 (1.44) PCB-32 (2.58) PCB-73 (1.31) PCB-61/70/74/76 (1.61) PCB-34 (2.55) PCB-43 (2.02) PCB-66 (1.67) Di Conc. Qualifiers PCB-4 (4.8) PCB-23 (2.51) PCB-10 (3.08) PCB-26/29 (2.47) PCB-9 (3.45) PCB-25 (2.46) PCB-7 (3) PCB-31 3.3 PCB-69/49 C JB 2.85 PCB-48 J B EMPC JBC (1.73) PCB-55 (1.7) PCB-56 (1.69) PCB-44/47/65 29.3 JBC PCB-60 (1.68) PCB-59/62/75 (1.24) C PCB-80 (1.42) PCB-6 (3.26) PCB-28/20 4.85 JBC PCB-42 (1.89) PCB-79 (1.49) PCB-5 (3.27) PCB-21/33 [4.52] J EMPC C PCB-41 (2.06) PCB-78 (1.76) PCB-81 (1.75) PCB 77 PCB-77 (1 6) (1.6) PCB-8 3.13 PCB 14 PCB-14 (2 72) (2.72) J PCB-11 13 B PCB-13/12 (3.15) C PCB-15 (3.24) PCB-22 (2.65) PCB-71/40 (1.7) PCB 36 PCB-36 (2 42) (2.42) PCB 64 PCB-64 (1 17) (1.17) PCB-39 (2.34) PCB-38 (2.58) PCB-35 (2.68) PCB-37 (2.91) C Qualifiers Conc. 16.1 Conc. 16.5 Conc. 151 EMPC 16.1 EMPC 21 EMPC 155 C Totals Conc. EMPC Mono-Tri 32.6 37.1 Tel: +1 910 794-1613 Tetra-Hexa 167 183 www.us.sgs.com Hepta-Deca 2.84 4.69 Mono-Deca 202 224 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 29 of 711 Sample ID: Penta EB1-01 (TOTAL) Conc. Qualifiers Method 1668A Penta Conc. Qualifiers Hexa Conc. PCB-108/119/86/97/125/87 (1.38) C PCB-155 PCB-152 (0.901) PCB-146 (1.22) PCB-150 (0.875) PCB-161 (0.991) PCB-104 (0.864) PCB-96 (1.06) PCB-117 (1.24) PCB-103 (1.41) PCB-116/85 (1.39) C PCB-94 (1.68) PCB-110 4.57 JB PCB-95 4.66 JB PCB-115 (1.2) PCB-100/93 (1.54) C PCB-82 (1.94) PCB-148 (1.25) PCB-102 (1.53) PCB-111 (1.12) PCB-151/135 (1.33) PCB-98 (1.57) PCB-120 (1.1) PCB-88 (1.59) PCB-107/124 (1.22) PCB-91 (1.57) PCB-109 (1.1) C Qualifiers (0.777) Hexa PCB-165 Conc. PCB-136 (0.956) PCB-153/168 [2.32] PCB-145 (0.944) PCB-141 (1.4) C PCB-130 (1.55) PCB-137 (1.23) (1.03) PCB-154 (1.12) PCB-164 PCB-144 (1.28) PCB-163/138/129 [4.18] PCB-147/149 [4.57] PCB-160 (1.11) (0.946) J B EMPC C PCB-84 (1.87) PCB-123 (1.11) PCB-134 (1.73) PCB-158 PCB-89 (1.72) PCB-106 (1.24) PCB-143 (1.29) PCB-128/166 (1.4) PCB-121 (1.1) PCB-118 2.66 PCB-139/140 (1.27) PCB-159 (1.15) PCB-92 (1.59) PCB-122 (1.23) PCB-131 (1.49) PCB-162 (1.16) PCB-114 (1.04) PCB-142 (1.53) PCB-167 (1.06) PCB-113/90/101 4.16 JBC JB C PCB-83 (2.04) PCB-105 (1.22) PCB-132 (1.45) PCB-156/157 (1.63) PCB-99 (1.37) PCB-127 (1.27) PCB-133 (1.36) PCB-169 (1.34) PCB-112 (1.16) PCB-126 (1.73) Hepta PCB-188 Conc. Qualifiers (0.936) Conc. 16.1 Conc. 0 EMPC 16.1 EMPC 11.1 Hepta Conc. Nona Conc. PCB-174 Qualifiers (1.51) Octa Conc. Qualifiers PCB-202 (1.28) PCB-208 (3.07) PCB-179 (1.09) PCB-177 (1.59) PCB-201 (1.21) PCB-207 (3.03) PCB-184 (1.14) PCB-181 (1.41) PCB-204 (1.3) PCB-206 (5.2) PCB-176 (1.03) PCB-171/173 (1.61) PCB-197 (1.24) C PCB-186 (1.1) PCB-172 (1.54) PCB-200 (1.24) PCB-178 (1.58) PCB-192 (1.19) PCB-198/199 (1.87) PCB-175 (1.39) PCB-196 (1.77) PCB-187 [1.86] PCB-182 (1.27) PCB-180/193 J EMPC 2.84 JC PCB-191 (1.13) PCB-203 (1.73) PCB-170 (1.63) PCB-195 (2.51) PCB-183 (1.24) PCB-190 (1.18) PCB-194 (2.31) PCB-185 (1.45) PCB-189 (1.5) PCB-205 (1.77) Conc. 2.84 Conc. 0 EMPC 4.69 EMPC 0 209 Congener PCB Summary Page 2 of 2 C Conc. 0 EMPC 0 Deca Conc. PCB-209 Qualifiers (1.07) (1.69) J B EMPC C J B EMPC C C C Qualifiers Qualifiers 30 of 711 Sample ID: Method 1668A EB1-01 (DISSOLVED) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 13-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB ND PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB ND PCB-114 2344'5-PeCB ND PCB-118 23'44'5-PeCB EMPC PCB-123 23'44'5'-PeCB ND PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB ND PCB-167 23'44'55'-HxCB ND PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 0.90 L 5 DL pg/L 1.37 1.37 0.915 0.82 Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 1.73 0.844 1.05 1.32 0.815 1.02 1.08 0 0.0682 0 136 0.136 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB ND 11.6 16.8 117 6.83 4.86 ND ND ND ND Total PCB (Mono-Deca) 157 Checkcode: 477-807-FJT 0.0000518 0.0682 0 136 0.136 1.64 23.1 121 12 1.15 1.37 3.24 1.31 173 SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11892 Qualifier JB C TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6504 A6504_11892_PCB_009-RJ2 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 14-Mar-2014 18-Mar-2014 28-Mar-2014 Recovery % 46.1 57.8 65.4 88.7 76.1 87 90.1 93.1 92.8 108 95.5 94.7 97.1 94 96 92.6 94 7 94.7 77.4 80 72.8 92.1 91.4 107 99.5 99.4 89.8 93.6 107 88.3 88.1 99.2 111 Report Created: 31-Mar-2014 19:02 Analyst: CM 31 of 711 Sample ID: EB1-01 (DISSOLVED) Client Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 13-Mar-2014 Date Collected: Laboratory Data Matrix: Weight/Volume: pH Conc. Qualifiers Aqueous Project No.: A6504 Date Received: 0.90 L Sample ID: A6504_11892_PCB_009-RJ2 Date Extracted: 18-Mar-2014 11892 Date Analyzed: 28-Mar-2014 477-807-FJT Time Analyzed: 5 Units Mono Method 1668A Sample Data pg/L Tri Conc. QC Batch No.: Checkcode: Qualifiers Tetra Conc. PCB-1 (1.67) PCB-19 (3.28) PCB-54 (0.84) PCB-2 (1.38) PCB-30/18 (2.42) C PCB-50/53 (1.31) PCB-3 (1.61) PCB-17 5.99 J PCB-45 Qualifiers Tetra PCB-72 C 14-Mar-2014 14:24:30 Conc. (1.13) PCB-68 33.1 (1.55) PCB-57 (1.2) (1.15) PCB-27 (2.08) PCB-51 52.5 PCB-58 Conc. 0 PCB-24 (2.18) PCB-46 (1.63) PCB-67 (1.13) EMPC 0 PCB-16 (3.62) PCB-52 [4.05] PCB-63 (1.07) Di Conc. Qualifiers J B EMPC Qualifiers PCB-32 (1.95) PCB-73 (1.03) PCB-61/70/74/76 4.48 JBC PCB-34 (1.46) PCB-43 (1.6) PCB-66 2.47 J PCB-23 (1.44) PCB-69/49 2.45 JBC PCB-55 (1.26) (1.41) C PCB-48 PCB-56 (1.28) 2.98 J PCB-44/47/65 22.2 JBC PCB-60 (1.27) C PCB-80 (1.07) PCB-4 (3.07) PCB-10 (1.98) PCB-26/29 PCB-9 (2.2) PCB-25 PCB-7 (1.87) PCB-31 3.09 JB PCB-59/62/75 (0.989) PCB-6 (1.99) PCB-28/20 4.76 JBC PCB-42 (1.49) PCB-79 (1.12) PCB-5 (1.96) PCB-21/33 [4.35] J EMPC C PCB-41 (1.66) PCB-78 (1.34) J EMPC PCB-81 (1.37) PCB 77 PCB-77 (1 37) (1.37) PCB-8 (1.91) PCB-22 [1.95] PCB 14 PCB-14 (1 68) (1.68) PCB 36 PCB-36 (1 45) (1.45) PCB-11 11.6 B PCB-39 (1.39) PCB-13/12 (1.99) C PCB-38 (1.55) PCB-15 (2.07) PCB-35 (1.65) PCB-37 (1.8) (1.35) PCB-71/40 (1.33) PCB 64 PCB-64 (0 936) (0.936) C Conc. 11.6 Conc. 16.8 Conc. 117 EMPC 11.6 EMPC 23.1 EMPC 121 Totals Conc. EMPC Mono-Tri 28.4 34.7 Tel: +1 910 794-1613 Tetra-Hexa 129 138 www.us.sgs.com Hepta-Deca 0 0 Mono-Deca 157 173 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 32 of 711 Sample ID: Penta PCB-104 EB1-01 (DISSOLVED) Conc. Qualifiers (0.709) Method 1668A Penta Conc. Qualifiers Hexa PCB-108/119/86/97/125/87 (0.997) C PCB-155 (0.936) Conc. Qualifiers Hexa Conc. (0.588) PCB-165 (0.788) PCB-96 (0.861) PCB-117 PCB-152 (0.69) PCB-146 (0.906) PCB-103 (0.997) PCB-116/85 (1.1) C PCB-150 (0.689) PCB-161 (0.726) PCB-94 (1.18) PCB-110 3.51 JB PCB-136 (0.75) PCB-153/168 PCB-95 [3.45] J B EMPC PCB-115 (0.837) PCB-145 (0.722) PCB-141 PCB-100/93 (1.11) C PCB-82 (1.4) PCB-148 (0.914) PCB-102 (0.942) PCB-111 (0.818) PCB-151/135 (0.946) PCB-98 (1.3) PCB-120 (0.808) PCB-88 (1.21) PCB-107/124 (0.915) PCB-91 (1.03) PCB-109 (0.809) PCB-147/149 C PCB-154 (0.8) PCB-144 (0.931) 2.57 C JBC 2.29 PCB-130 (1.15) PCB-137 (0.925) PCB-164 (0.773) PCB-163/138/129 (0.947) PCB-160 (0.815) (0.701) PCB-84 (1.32) PCB-123 (0.844) PCB-134 (1.31) PCB-158 (1.26) PCB-106 (0.925) PCB-143 (0.915) PCB-128/166 (1.07) PCB-121 (0.782) PCB-118 [1.73] PCB-139/140 (0.913) PCB-159 (0.879) PCB-92 (1.16) PCB-113/90/101 3.32 JBC C PCB-122 (0.955) PCB-131 (1.09) PCB-162 (0.887) PCB-114 (0.82) PCB-142 (1.11) PCB-167 (0.815) PCB-83 (1.35) PCB-105 (0.915) PCB-132 (1.07) PCB-156/157 (1.32) PCB-99 (1.07) PCB-127 (0.893) PCB-133 (0.995) PCB-169 (1.02) PCB-112 (0.82) PCB-126 (1.05) Hepta Conc. PCB-188 (0.837) Qualifiers Conc. 6.83 Conc. 4.86 EMPC 12 EMPC 4.86 Hepta Conc. Nona Conc. PCB-174 Qualifiers (1.4) Octa Conc. Qualifiers PCB-202 (1.18) PCB-208 (2.53) PCB-179 (0.992) PCB-177 (1.42) PCB-201 (1.13) PCB-207 (2.48) PCB-184 (1.03) PCB-181 (1.26) PCB-204 (1.2) PCB-206 (3.94) PCB-176 (0.937) PCB-171/173 (1.45) PCB-197 (1.1) PCB-186 (1.02) PCB-172 (1.4) PCB-200 (1.19) PCB-178 (1.43) PCB-192 (1.07) PCB-198/199 (1.78) PCB-196 (1.67) C PCB-175 (1.26) PCB-180/193 (1.11) PCB-187 (1.17) PCB-191 (1.03) C PCB-203 (1.6) PCB-182 (1.15) PCB-170 (1.43) PCB-195 (2.03) PCB-183 (1.1) PCB-190 (1.03) PCB-194 (1.98) PCB-185 (1.33) PCB-189 (1.08) PCB-205 (1.57) Conc. 0 Conc. 0 EMPC 0 EMPC 0 209 Congener PCB Summary Page 2 of 2 C Conc. 0 EMPC 0 Deca Conc. PCB-209 JBC (1.04) PCB-89 J B EMPC Qualifiers (1.31) C C C Qualifiers Qualifiers 33 of 711 Sample ID: Method 1668A Method Blank A6504 Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: n/a pH Conc. pg/L PCB-77 33'44'-TeCB ND PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB ND PCB-114 2344'5-PeCB ND PCB-118 23'44'5-PeCB 2.52 PCB-123 23'44'5'-PeCB ND PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB ND PCB-167 23'44'55'-HxCB ND PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 1.00 L n/a DL pg/L 1.65 1.74 1.8 1.71 Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 0.0000756 0.0976 0 195 0.195 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 4.85 6.65 5.66 ND ND ND ND Total PCB (Mono-Deca) 26.1 Checkcode: 967-196-GFH ND 8.96 C 0.0000756 0.0976 0 195 0.195 2.15 4.77 12.3 13.2 8.22 1.6 1.52 3.42 1.61 47.5 SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11892 Qualifier J 1.62 1.55 1.71 1.12 1.29 1.55 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6504 Date Received: MB1_11892_PCB_TLX Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 n/a 18-Mar-2014 26-Mar-2014 Recovery % 60.5 70.7 78.2 93.2 90.2 81.2 92.5 86 84.4 107 90.5 89.6 92.4 90.3 90 87.9 88 6 88.6 73.6 74.1 70.2 90.1 92.7 104 93.8 94.4 88.7 94.8 106 88.5 84 94.7 108 Report Created: 31-Mar-2014 18:54 Analyst: CM 34 of 711 Sample ID: Method Blank A6504 Client Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site n/a Date Collected: Mono Method 1668A Sample Data Conc. Laboratory Data Matrix: Weight/Volume: Aqueous Project No.: A6504 Date Received: n/a 1.00 L Sample ID: MB1_11892_PCB_TLX Date Extracted: 18-Mar-2014 11892 Date Analyzed: 26-Mar-2014 967-196-GFH Time Analyzed: pH n/a QC Batch No.: Units pg/L Checkcode: Qualifiers Tri Conc. Qualifiers Tetra Conc. PCB-1 (2.18) PCB-19 (3.89) PCB-2 (1.91) PCB-30/18 (2.9) PCB-3 (2.12) PCB-17 (3.39) PCB-45 PCB-27 (2.49) PCB-51 (2.12) C PCB-54 (1.23) PCB-50/53 (1.72) Qualifiers Tetra PCB-72 (1.54) PCB-68 (1.47) (1.9) PCB-57 (1.62) (1.78) PCB-58 (1.6) PCB-67 (1.51) PCB-63 (1.43) C Conc. 0 PCB-24 (2.61) PCB-46 EMPC 0 PCB-16 (4.56) PCB-52 [4.39] PCB-32 (2.32) PCB-73 (1.33) PCB-61/70/74/76 PCB-34 (2.48) PCB-43 (2.04) PCB-66 Di Conc. Qualifiers PCB-4 (3.26) PCB-23 (2.45) PCB-10 (2.1) PCB-26/29 (2.41) PCB-69/49 PCB-9 (3.02) PCB-25 (2.4) PCB-7 (2.64) PCB-31 [2.28] EMPC PCB-6 (2.86) PCB-28/20 [2.49] PCB-5 (2.87) PCB-21/33 (2.41) C 2 PCB-48 J EMPC C PCB-60 (1.67) C PCB-80 (1.41) J EMPC C PCB-42 (1.91) PCB-79 (1.48) C PCB-41 (2.08) PCB-78 (1.75) PCB-22 (2.58) PCB-71/40 (1.72) (2 36) (2.36) PCB 64 PCB-64 (1 19) (1.19) (2.28) J PCB-39 PCB-38 (2.51) PCB-15 (2.84) PCB-35 (2.61) PCB-37 (2.83) (1.69) (1.68) [3.07] PCB 36 PCB-36 C PCB-55 PCB-56 (1.25) (2.73) 8.96 2.85 PCB-59/62/75 (2 39) (2.39) (2.76) JC C Qualifiers JC (1.66) PCB-44/47/65 PCB-8 PCB-13/12 J EMPC (1.75) PCB 14 PCB-14 PCB-11 21:07:05 Conc. PCB-81 (1.74) PCB 77 PCB-77 (1 65) (1.65) Conc. 8.96 Conc. 0 Conc. 4.85 EMPC 8.96 EMPC 4.77 EMPC 12.3 Totals Conc. EMPC Mono-Tri 8.96 13.7 Tel: +1 910 794-1613 Tetra-Hexa 17.2 33.8 www.us.sgs.com Hepta-Deca 0 0 Mono-Deca 26.1 47.5 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 35 of 711 Sample ID: Penta PCB-104 Method Blank A6504 Conc. Qualifiers (1.3) Method 1668A Penta Conc. Qualifiers PCB-108/119/86/97/125/87 (2.01) C PCB-155 PCB-152 (1.01) PCB-146 (1.31) PCB-150 (0.978) PCB-161 (1.07) PCB-96 (1.6) PCB-117 (1.81) PCB-103 (2.06) PCB-116/85 (2.03) C PCB-110 [2.77] J EMPC PCB-115 (1.75) Hexa Conc. (0.869) PCB-94 (2.45) PCB-95 [3.83] J EMPC PCB-100/93 (2.24) C PCB-82 (2.83) PCB-148 (1.35) PCB-102 (2.23) PCB-111 (1.63) PCB-151/135 (1.43) PCB-98 (2.3) PCB-120 (1.61) PCB-88 (2.32) PCB-107/124 (1.79) PCB-91 (2.29) PCB-109 (1.61) C Qualifiers Hexa PCB-165 Conc. PCB-136 (1.07) PCB-153/168 2.84 PCB-145 (1.06) PCB-141 (1.5) C PCB-130 (1.67) PCB-137 (1.32) (1.11) PCB-154 (1.21) PCB-164 PCB-144 (1.37) PCB-163/138/129 2.82 PCB-147/149 [2.56] PCB-160 (1.2) J EMPC C PCB-84 (2.73) PCB-123 (1.62) PCB-134 (1.86) PCB-158 (1.02) PCB-89 (2.52) PCB-106 (1.81) PCB-143 (1.39) PCB-128/166 (1.47) PCB-121 (1.61) PCB-118 2.52 PCB-139/140 (1.36) PCB-159 (1.21) PCB-92 (2.33) PCB-113/90/101 4.13 JC J C PCB-122 (2.03) PCB-131 (1.61) PCB-162 (1.22) PCB-114 (1.71) PCB-142 (1.64) PCB-167 (1.12) PCB-83 (2.97) PCB-105 (1.8) PCB-132 (1.56) PCB-156/157 (1.71) PCB-99 (2) PCB-127 (1.88) PCB-133 (1.46) PCB-169 (1.29) PCB-112 (1.7) PCB-126 (1.55) Hepta Conc. Qualifiers Conc. 6.65 Conc. 5.66 EMPC 13.2 EMPC 8.22 Hepta Conc. Nona Conc. Qualifiers Octa Conc. Qualifiers PCB-188 (1.04) PCB-174 (1.97) PCB-202 (1.48) PCB-208 (2.72) PCB-179 (1.22) PCB-177 (2.07) PCB-201 (1.4) PCB-207 (2.69) PCB-184 (1.27) PCB-181 (1.84) PCB-204 (1.5) PCB-206 (4.12) PCB-176 (1.15) PCB-171/173 (2.1) PCB-197 (1.43) PCB-186 (1.23) PCB-172 (2) PCB-178 (1.76) PCB-192 (1.54) C C PCB-200 (1.44) PCB-198/199 (2.16) PCB-196 (2.05) PCB-175 (1.81) PCB-180/193 (1.61) PCB-187 (1.7) PCB-191 (1.47) PCB-203 (2) PCB-182 (1.66) PCB-170 (2.24) PCB-195 (2.19) PCB-183 (1.61) PCB-190 (1.62) PCB-194 (2.02) PCB-185 (1.89) PCB-189 (1.55) PCB-205 (1.55) Conc. 0 Conc. 0 EMPC 0 EMPC 0 209 Congener PCB Summary Page 2 of 2 C Conc. 0 EMPC 0 Deca Conc. PCB-209 Qualifiers (1.15) (1.61) JC JC C C Qualifiers Qualifiers 36 of 711 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140326X06 Analysis Date: Lab ID: OPR1_11892_PCB-RJ NATIVE ANALYTES PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-104 22'466'-PeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-155 22'44'66'-HxCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-188 22'34'566'-HpCB PCB-189 233'44'55'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-206 22'33'44'55'6-NoCB PCB-208 22'33'455'66'-NoCB PCB-209 DeCB Processed: 31 Mar 2014 18:50 26-MAR-2014 19:16:37 SPIKE CONC. RECOVERY RANGE (%) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 110 108 95.1 104 96.5 109 95.5 100 104 94.7 95 97 95.7 97.1 108 92.8 95.7 95.9 98.3 95.1 106 96.6 98.3 99.5 98.7 97.1 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 Contract-required recovery limits for OPR as specified in Table 6, Method 1668A. Analyst: CM FORM 8A OK - 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 37 of 711 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140326X06 Analysis Date: Lab ID: OPR1_11892_PCB-RJ LABELED STANDARDS ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 FORM 8B 26-MAR-2014 19:16:37 SPIKE CONC. RECOVERY RANGE (%) 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 73.9 77.8 89.5 89.3 88.6 80.4 91.3 85.1 83 101 87 84.8 88.1 86.2 86.8 85.3 84.5 71.6 72.3 67.8 85 87.2 97.7 89.8 91.5 83.1 87.8 98 81.2 15 15 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 - 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 100 100 100 84.8 94.3 109 40 40 40 - 125 125 125 Y Y Y OK CLEANUP STANDARDS CS PCB-28 CS PCB-111 CS PCB-178 Processed: 31 Mar 2014 18:50 Analyst: CM 38 of 711 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: Amy Boehm 14-Mar-14 at 09:40 A6504 21 days 4-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com AP Smp ID Sample Condition & Notes Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Quantity Size Sampling Date Sampling Time Delaney Peterson ANCHOR QEA Patrick Bayou Superfund Site N/A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Received Temp Container # PB020-1SWMID-140313-N (TOTAL) A6504_001 WS 2 1L Amber 13-Mar-14 12:36 2.8, 2.1, 2.1 1, 2, 3 PB031.1-1SWMID-140313-N (TOTAL) A6504_002 WS 2 1L Amber 13-Mar-14 13:25 2.8, 2.1, 2.1 1, 2, 3 PB047.3-1SWMID-140313-N (TOTAL) A6504_003 WS 2 1L Amber 13-Mar-14 14:28 2.8, 2.1, 2.1 1, 2, 3 PB056_C-1SWMID-140313-N (TOTAL) A6504_004 WS 2 1L Amber 13-Mar-14 15:45 2.8, 2.1, 2.1 1, 2, 3 PB056_C-1SWMID-140313-N (DISSOLVED) A6504_005 WS 2 1L Amber 13-Mar-14 15:45 2.8, 2.1, 2.1 1, 2, 3 EF006.1-1SWMID-140313-N (TOTAL) A6504_006 WS 2 1L Amber 13-Mar-14 15:00 2.8, 2.1, 2.1 1, 2, 3 PB119_B-1SWMID-140313-N (TOTAL) A6504_007 WS 2 1L Amber 13-Mar-14 16:10 2.8, 2.1, 2.1 1, 2, 3 EB1-01 (TOTAL) A6504_008 WS 2 1L Amber 13-Mar-14 15:00 2.8, 2.1, 2.1 1, 2, 3 EB1-01 (DISSOLVED) A6504_009 WS 2 1L Amber 13-Mar-14 15:00 2.8, 2.1, 2.1 1, 2, 3 FB1-01 A6504_010 WS-ARCHIVE 1 1L Amber 13-Mar-14 15:00 2.8, 2.1, 2.1 1, 2, 3 Preservation Type: Notes/Comments: Ice - Good Condition+Ice - Sample Seals: 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. Samples received intact Received by: Christina Newkirk Shipping # 870464717440, 798214382421, 798214382432 Logged in by: Christina Newkirk QC'ed by: AK 17 Mar 14 SGS Analytical Perspectives SEND DOCUMENTATION I RESULTS TO: PROJECT INFO- g/Z 5417,?, 5116 COMPANY. 4? PROJECT: 0 CONTACT: pus/4n We? grit/6?02 ADDRESS: WW: 3m . 0 Gum" cw/ozgo/wl. 06 PHONE. 95? SITE REF EM IL 256; 523?"? 130 A . TURN AROUND TIME 11v #124, wane? ?Jo/$541? . com REPORT LEVEL: (see reverse) LeveI LeveI ?3 INVOICE TO: CHECK IF SAME) - State of Orlgm' COMPANY: ONTACT: DELIVERABLES- . "1 Other: ADDRESS: Rn (?Ask D: PHONE: -q3g?, 093?, EMAIL: be '66;ncaw DATE: TIME. RECEIVED BY: 3/14 10f [Ea/?x RECEIVED BY: 4" 62 RELINOUISHED BY (2): TIME: DATE: CHAIN or- cusmnv CONVENTIONAL SHALE SOS NORTH AMERICAINC. I ENVIRONMENTAL SERVICES 5500 Business Drive WiImington, NC 28405 39 Of 711 SPECIAL INSTRUCTIONS I COMMENTS: PRESERVATIVE (ism/d- apon arm; ANALYSIS 81 METHOD on micIP'I? #va ?Ff 2:11:42: ,4 . 8 in 910 350 1903 910 794 1613 Member of the SGS Group ISGS SA) 40 of 711 Project Initiation Form Project Number: A6504 Initiation Date: Client Name: ANCHOR QEA 1668A Analysis Method: Sample Matrix: TAT: Project Manager: 17-Mar-14 Aqueous 21 days Amy Special Instructions 1668A w/ OPR Dissolved samples need to be filtered before extraction Reporting Instructions 1668A Anchor Equis EDD PM Initials: akornega Date: 17-Mar-2014 I Balch II 1\6504 II AI' Sample Client Sample II) ID Volumc (mi.) IIX92 Talex II Extract II X92 001 PB020-1 SWMID-140J IJ-N (TOTAL) ,\'1\ 1 .•.... 1\6504 II X92 002 PBOJ 1.1-ISWMJD-140J U-N (TOTAL) ~19 \.t - PB047.J-ISWMID-140J 9~\ 5 C\~~ q~\ ~ - { - - II X92_003 1\6504 IIX92 1\6504 004 IIX92_005 U-N (TOTAL) I'l1056_C'-ISWMID-14OJ I3-N (TOTAL) PIl056_C-ISWMllJ-140.11.1-N (lJISSOI.\'EIlI 1\6504 II X92 006 EF006.1-ISWMJD-140J U-N (TOTAL) ~ ~'1- ~ 1\6504 II X92_007 I'll I 19_lJ-ISWMID-140313-N (TOTAL) <\ 1\6504- II X92_008 EB 1-0 I (TOTAL) '\ q\ '\\0<; \.~ EB 1-0 I (DISSOLVED) ~C{l \\ Method \\i~~ \tttl \ A6504 MBI OPRI IIX92 IIX92 11892 009 Blank 0 - I I 892_0PROOI I'l - - II __ Watcr I , tJW..')\l1Ii RV SDS II 1\6504 1\6504 IniUDatc: R k:. E IV ED:-'--_---'--......1668A \ Projcct 41 of 711 ~- R : T A ,-~~t: Prep Sheet Initials Transfer Init/Datc: (Td) Obscrvations Clean-up o.J ~ w aJ \ 0-J L Q.J l\ 3 (~ ~ - I l113 - 2- ~ -- \ Q-J - L r~ y 113 5\\(~ I\~ Cvclc Timc Special Instructions: 1668A wi OPR Dissolvcd samples nccd to bc filtered bdiJre extraction Start: \O~?.s c-.v-. SUIIII!V J1)s Tolucnc CII1CL1 Stop: 1~'~I1A. I.' '\ Sand Florisil Start: Ilcxanc Silica Stop: ~ -- -- Q](ef6lo - Acid Silica Basc Silica IlydroMatrix Telradccanc tJJl~~ ttr*7, K Silicate 031Lt ?Ollf -- c)"Lc l) 'LO)'-I - 42 of 711 1668A Project # A6504 Batch # Aqueous 11892 Inter-Department Communication Sheet 00 Special Instructions 1668A wi OPR Dissolved samples need to be filtered before extraction 0.1 43 of 711 TSS % TSS Determination WorkSheet ..MiiIOi A",,,,.,, •• ~ Tarc Balancc Add hoat & 0.45 ~1111 filtcr and wcigh, Rccord "!loat WI." Placc fillcr in glass lilling runnel Filtcr 10 mL or aqucous samplc through fillcr into a waslc jar Rinsc liller with 20 mi. or DI watcr Dry in ovcn ovcrnight @ 107 C Return dish to toploader and reeord "Dry WI." Proccdurcs: ProjcCl: A6504 Batch: 11892 AI' Sall1lJlc ID A6504 _I 1892 J)O I A6504_11892_002 A6504 - I 1892 - 003 lloatWT. \:y\ \J""L Chcmist: ~\V6\\'-t Prcp Datc: Dry WT. 'v.. TSS Init/l)atc 0\\ ~\- '7 b 0 0 111\ b ~ \ .l~ I.l~ 0 M \:t ~ Vl~ 0 Nt- ~ () 0 -'1 0 I 0 ~ 0 0 A6504_11892_004 \ ,11 A6504 _I 1892_005 \ ,10\ /,lj 0 M 1r\A- A6504_11892Jl06 \,\"1 l,rJl 0 4 A6504_11892_007 \ :1'b I.I~ 0 I.ll A6504 -I 1892 -008 \,~\ In, () A6504 - I 1892 -009 \,\.~ \.I~ (;J f\A- ~ s ~ IlJr 7 ,,,,It... '/' 0/ 5 0 n COll1l11cnts 44 of 711 Spike Sheet PCB I ill •••• ~ ,~~- •• "no<" "'.•••'.n'v'. A6504 I'rojl:l:( 1/ BaldI Spike •. Inilials/l)ale: 1\1' Sampk Clknt ID Sampk ID Snikcd Amount IV\-:J 11~)11 PCB ES I'lC vL I\mount: Observer Initials 1\6504 - I 1892 - 00 I I'B020-1 SWM ID-140313-N (TOTAL) IV~I{ 1\6504_1 1892_002 I'B031.1-1 SWMID-140313-N (TOTAL) \\\t- I'B047.3-ISWMID-140313-N (rUrAL) \'\'l 1\6504 - 11892 003 PB056_C-ISWMID-140313-N (TOTAL) 1\6504_11892_o05 1'1l056_C-1 SWMID-140J 1\6504 - I 1892 - 006 EF006.1-ISWMID-140313-N (TOTAL) 'W'I- 1\6504_11892_o07 PBI19_B-ISWMID-140313-N (TOTAL) ~\L 1\6504_11892_008 EBI-OI (TOTI\L) ~\( 1\6504 - I 1892 - 009 EBI.OI (DISSOLVED) ~~ MBI - 11892 Mdhod Blank \\'l OI'RI - 11892 o - I 1892 - OI'ROO I M 1Jrg/H PCB AX 209 Observer Initials "- - - \'J\~ - - - \O'1-<\Ul\)~ \1.-%- \ SIL# 100 Conl:cntration pg IltL Units Exp. Datc Spikl: amount \'}.. \1\ \\'\ (~I.) 20 LI/ u. pcncs l'tnAs I\mount: \V.uJ... Observer Initials Q-J 0° oJ o.J (y r~ u-J OJ C~ D-J Q-i ~ ~\( Q-> 00 1\\ ~ \ \~ 'J\ \0-hJ 3 )-zO/1 Y \"\-1'i-\ Observer Initials ()0 (j-J \()1-~ 1,A)\") I\mount: ~ o-J Information AX 2119 Final Soh'cnt I I\mount:~O Observer Initials Q--J Final Volumc 3fuJl,~ ('~ Standard Spikc ID ,u- J "1/''1 00 - ES Slllit Fal"to •. Solntion Conc. ('0 \t\'t-. I'cn 1.{)"L. I\mount: - >\V\,\,~ Std. Typc PCBs Snikcd Volumc \V\'L. 1\6504_11892_004 IJ-N (DISSOLVED) I Wale •. 11892 # SPIKE PROFILE Spike Compounds Analvtc I I 1668A pcn CSISS \[)7Q 1.(1'-. {h, \ '"A-C\,( 0 •..• 2- I'Cn./S A 10 1-:'-l-'7??-L/ 200 50 100 ,pghlL pg htl. pg /~L \ 1.-\tA.-,Ll 'D-L.q-l~ \O\vt\t'i \ 20~ 20 10 45 of 711 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: Amy Boehm 14-Mar-14 at 09:40 A6504 21 days 4-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com AP Smp ID Sample Condition & Notes Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Quantity Size Sampling Date Sampling Time Delaney Peterson ANCHOR QEA Patrick Bayou Superfund Site N/A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Received Temp Container # PB020-1SWMID-140313-N (TOTAL) A6504_001 WS 2 1L Amber 13-Mar-14 12:36 2.8, 2.1, 2.1 1, 2, 3 PB031.1-1SWMID-140313-N (TOTAL) A6504_002 WS 2 1L Amber 13-Mar-14 13:25 2.8, 2.1, 2.1 1, 2, 3 PB047.3-1SWMID-140313-N (TOTAL) A6504_003 WS 2 1L Amber 13-Mar-14 14:28 2.8, 2.1, 2.1 1, 2, 3 PB056_C-1SWMID-140313-N (TOTAL) A6504_004 WS 2 1L Amber 13-Mar-14 15:45 2.8, 2.1, 2.1 1, 2, 3 PB056_C-1SWMID-140313-N (DISSOLVED) A6504_005 WS 2 1L Amber 13-Mar-14 15:45 2.8, 2.1, 2.1 1, 2, 3 EF006.1-1SWMID-140313-N (TOTAL) A6504_006 WS 2 1L Amber 13-Mar-14 15:00 2.8, 2.1, 2.1 1, 2, 3 PB119_B-1SWMID-140313-N (TOTAL) A6504_007 WS 2 1L Amber 13-Mar-14 16:10 2.8, 2.1, 2.1 1, 2, 3 EB1-01 (TOTAL) A6504_008 WS 2 1L Amber 13-Mar-14 15:00 2.8, 2.1, 2.1 1, 2, 3 EB1-01 (DISSOLVED) A6504_009 WS 2 1L Amber 13-Mar-14 15:00 2.8, 2.1, 2.1 1, 2, 3 FB1-01 A6504_010 WS-ARCHIVE 1 1L Amber 13-Mar-14 15:00 2.8, 2.1, 2.1 1, 2, 3 Preservation Type: Notes/Comments: Ice - Good Condition+Ice - Sample Seals: 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 870464717440, 798214382421, 798214382432 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. Samples received intact Received by: Christina Newkirk Shipping # 870464717440, 798214382421, 798214382432 Logged in by: Christina Newkirk QC'ed by: AK 17 Mar 14 SGS Analytical Perspectives 46 of 711 I CONVENTIONAL CHAIN OF CUSTODY PROJECT INFO: f.ritlt lJe).ruv PROJECT:k P.o. JI! ~ .)vf'~rlv/l' SEND DOCUMENTATION 5:/t:: ff'-ll of. ~fj 0(,/02 J)e/e:,f1 ~1 Pe./-v.!(,II1 QI,..,.~.C,VC;'1' 5/k Zez> s~~Ilk tvA 9 vic) PHONE: 5~~4C/t.../&/ TURN AROUND TIME: 0 Levell SPECIAL DELIVERABLES: o State of Origin: 0 Level II ~vel COMPANY: P;VL EMAIL: C ..•...•. to/",,?~e ...c::.,'fV'\ .:'h CfICf - '135-- •..•..• "-A., -15tt/fflIO-I"lo3/3-'u '],1,-:) l-I 11,1,(. C;,.. PA/)3/./-/5ttJ.fI1111 - /4ojr:z.-N '),//"3../ tI 12,.1<' 6- ,Pldbl/},3 -/~WII/JID-/'//J'{N-N 1'/1/5,"(:'_/ . Nh./M In-/t:i/.'~I~-N ~"J1.,"I Ic.n~ c- '? I,:••, /'1 I~l.t~ ......., "'_/3 -1:!JbJIII1 In -1t..in"'2I''Z'' "•.) £BflJl ~q"'OI MSD DUP (C, G) I cOO CON~ MATRIX aTY 1"",/<' C; W5 S - "- .. .:;; RELINQUISHED BY (1): $C; /~ BY (2): c, ;7.'~j,~/1-0~ TIME: DATE: TIME: ~ ~ \~ ,l I II I ~ ~ , SGS NORTHAMERICA INC.~. i1'~ wS 5 I..d(;, II Cr W5 ws q 5 '", " \ ..:::t:~ .~ l:':c/&'1' \.tll~ ~~ 'll'EM~KS "- \ \ \ \ \ '" \ \ t~ 'N ilYiA f ~, ~ ------- J~1'''~'Y" RECEIVED BY: t) Tirv1E:~l~lW : ,. ,If ''''TE~ lfl 'iti' N RECEIVED BY: ENVIRONMENTAL SERVICES 5500 Business ~ b ~ ~ ~ (r fAA 5 \\ \ \ 1 e::t ~ ~ ':-') ,@~~MPLE RECEIPT' Ii Page_of_ ~,It c } (;- (;j:,. .;'; C~ED~~~UISHED 1 ~ ~ () ~ .~ It f , I, i \ I I , \ ,I II t I II \ II It t C•... &- ",JI",h", I'SOD ~J, ~11c.{ 1(,10 ~J r'2.,J fLo( 1&;00 "1 ~tl TYPE DATE J. 8tdMJ/J-/"ldiJ-'1,-1V MS < .: ~ ~.~ ~ ~ ~/I/~.v6k,' bobpe pr(> /f"~l1Ct vt ••.0.10 r. t::.CI"'l"\J TIME :t: ~ ANALYSIS & METHOD SAMPLE ID I DESCRIPTION F#:/1, r:' C 0Ci3'1 ac \ ~ ~ "J AONTACT: ADDRESS: PHONE: "r e. dt.. pel PRESERVATIVE 1.30 VS()1'l e1l'1 INVOICE TO: (0 CHECK IF SAME) IV o Other: ~D: Z c'C. -Zt) ~-.e'j EMAIL: REPORT LEVEL: (see reverse) wi SPECIAL INSTRUCTIONS I COMMENTS: ADDRESS.~20 QUOTE #. SITE REF: I RESULTS TO: .A r'\~J,I.I~&eA,'--'-Co COMPANY: CONTACT: #: & SHALE Drive Wilmington, ' NC 28405 • ~ :J. I "Illi; 910350 d J. 1., i[\; ... 19031910794 Member 1613 www.sgs.com of the SGS Group (SGS SAl 47 of 711 SGS Analytical Perspectives — Run Log Project: A6504_11892_PCB Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Wt/Vol Client/Sample ID Analyst(s) Checkcode Acq Date Datafile Vial# Lab ID Acq Time 5 140326X05 Tray1:03 CS3_140326_PCB_XC 1.00 SIL 13-73-3 LKB, CEM 507-144 26-Mar-2014 18:21:41 6 140326X06 Tray1:32 OPR1_11892_PCB-RJ 1.00 0_11892_OPR001 LKB, CEM 678-882 26-Mar-2014 19:16:37 7 140326X07 Tray1:02 SBS_140326_PCB_XB 1.00 SIL 13-42-1 LKB, CEM 654-631 26-Mar-2014 20:11:52 8 140326X08 Tray1:33 MB1_11892_PCB_TLX 1.00 Method Blank LKB, CEM 967-196 26-Mar-2014 21:07:05 9 140326X09 Tray1:34 A6504_11892_PCB_001 0.97 PB020-1SWMID-140313-N (TOTAL) LKB, CEM 320-870 26-Mar-2014 22:02:20 10 140326X10 Tray1:35 A6504_11892_PCB_002 0.98 PB031.1-1SWMID-140313-N (TOTAL) LKB, CEM 645-564 26-Mar-2014 22:57:34 11 140326X11 Tray1:36 A6504_11892_PCB_003 0.97 PB047.3-1SWMID-140313-N (TOTAL) LKB, CEM 786-548 26-Mar-2014 23:52:48 12 140326X12 Tray1:37 A6504_11892_PCB_004 0.97 PB056_C-1SWMID-140313-N (TOTAL) LKB, CEM 848-343 27-Mar-2014 00:47:55 13 140326X13 Tray1:38 A6504_11892_PCB_005 0.96 PB056_C-1SWMID-140313-N (DISSOLVED) LKB, CEM 681-037 27-Mar-2014 01:43:07 14 140326X14 Tray1:39 A6504_11892_PCB_006 0.93 EF006.1-1SWMID-140313-N (TOTAL) LKB, CEM 889-569 27-Mar-2014 02:38:21 15 140326X15 Tray1:40 A6504_11892_PCB_007 0.94 PB119_B-1SWMID-140313-N (TOTAL) LKB, CEM 251-126 27-Mar-2014 03:33:35 16 140326X16 Tray1:41 A6504_11892_PCB_008 0.97 EB1-01 (TOTAL) LKB, CEM 842-903 27-Mar-2014 04:28:49 17 140326X17 Tray1:42 A6504_11892_PCB_009 0.90 EB1-01 (DISSOLVED) LKB, CEM 490-847 27-Mar-2014 05:24:04 1 140328X01 Tray1:03 CS3_140328_PCB_XA 1.00 SIL 13-73-3 LKB, CEM 523-232 28-Mar-2014 10:43:57 3 140328X03 Tray1:02 SBS_140328_PCB_XA 1.00 SIL 13-42-1 LKB, CEM 851-325 28-Mar-2014 12:34:10 5 140328X05 Tray1:42 A6504_11892_PCB_009-RJ2 0.90 EB1-01 (DISSOLVED) LKB, CEM 477-807 28-Mar-2014 14:24:30 Project file: not saved AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 Printed: 31-Mar-2014 19:24 48 of 711 Lab ID: MB1_11892_PCB_TLX ACQ: 26-Mar-2014 21:07:05 LKB Wt/Vol: 1.00 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Client ID: Method Blank A6504 UTP: 31-Mar-2014 13:54 CEM J-level: 10 pg/L Datafile: 140326X08 RPT: 31-Mar-2014 18:54 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB NotFnd NotFnd NotFnd NotFnd 34.79 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.88 14.17 14.42 20.13 17.51 26.46 20.42 32.78 32.31 25.39 35.77 35.23 34.76 34.48 38.38 36.34 30.34 40.92 39.94 43.64 43.15 42.09 35.22 45.76 39.75 47.93 49.39 45.38 50.83 QC J C Pred RRT Actual RRT 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0009 - 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7243 0.8639 0.8793 1.2276 1.0673 1.0789 0.8326 1.3369 1.3174 0.8323 1.1723 1.1546 1.1393 1.1301 1.2578 0.9716 0.8112 1.0941 1.0678 1.1666 0.9080 0.8855 0.7410 0.9629 0.8365 1.0084 1.0392 0.9548 1.0695 Diff Secs +0.6 -0.1 0 -0.1 +0.4 0 +0.2 -0.2 +0.6 +0.4 -0.2 +0.4 +0.4 +0.2 +0.2 +0.2 0 -0.2 +0.2 +0.2 0 0 0 -0.2 0 0 0 0 0 +0.3 Page 1 of 5 Split: 1 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.99E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.49E+07 3.71E+07 1.98E+07 4.69E+07 2.21E+07 3.64E+07 2.15E+07 3.21E+07 3.12E+07 2.14E+07 2.71E+07 2.72E+07 2.66E+07 2.67E+07 2.30E+07 1.97E+07 2.81E+07 4.70E+07 2.47E+07 2.18E+07 1.45E+07 1.79E+07 1.95E+07 2.11E+07 1.83E+07 1.57E+07 1.12E+07 1.76E+07 1.39E+07 Checkcode: 967-196-GFH Ra 0.71 3.25 3.35 1.57 1.58 1.06 1.09 0.75 0.79 0.78 1.57 1.57 1.65 1.58 1.59 1.52 1.22 1.26 1.27 1.29 1.24 1.09 1.07 1.04 1.02 0.89 0.86 0.78 0.79 1.18 Method 1668A RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ND ND ND ND 2.52 ND ND ND ND ND ND ND 3.07E+03 3.07E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.02E+03 1.55E+03 1.55E+03 1.55E+03 1.65E+03 1.10E+03 1.65 1.74 1.8 1.71 1.77 1.62 1.55 1.71 1.12 1.29 1.55 1.61 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 60.5 % 70.7 % 78.2 % 93.2 % 90.2 % 81.2 % 92.5 % 86 % 84.4 % 107 % 90.5 % 89.6 % 92.4 % 90.3 % 90 % 87.9 % 88.6 % 73.6 % 74.1 % 70.2 % 90.1 % 92.7 % 104 % 93.8 % 94.4 % 88.7 % 94.8 % 106 % 88.5 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Printed: 3/31/2014 7:04 PM 49 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 4.19E+07 2.88E+07 1.25E+07 1.09 1.56 1.09 1.11 1.03 0.62 103 % 105 % 104 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 4.19E+07 2.88E+07 1.25E+07 1.09 1.56 1.09 1.85 1.22 0.58 84 % 94.7 % 108 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.40 24.52 30.51 37.41 47.53 4.84E+07 2.70E+07 2.49E+07 2.00E+07 1.42E+07 1.59 0.79 1.63 1.29 0.92 5.56E+03 5.56E+03 5.56E+03 5.57E+03 5.57E+03 7.75E+03 7.75E+03 7.75E+03 7.75E+03 7.75E+03 7.75E+03 7.75E+03 7.75E+03 7.75E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 2.18 1.91 2.12 3.26 2.1 3.02 2.64 2.86 2.87 2.73 2.39 2.72 2.76 2.84 3.89 2.9 3.39 2.49 2.61 4.56 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 19.57 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd J C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 0.9720 - -0.1 Page 2 of 5 NON-EMPC 0 8.96 0 4.85 6.65 5.66 0 0 0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.23E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 0 8.96 4.77 12.3 13.2 8.22 0 0 0 1.47 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 2.15 3.05 3.36 1.62 1.62 1.25 1.6 1.52 3.42 ND ND ND ND ND ND ND ND ND ND ND 8.96 ND ND ND ND ND ND ND ND Printed: 3/31/2014 7:04 PM 50 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB NotFnd NotFnd NotFnd NotFnd NotFnd 22.66 22.92 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 24.54 NotFnd NotFnd 24.97 NotFnd 25.45 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 28.77 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC C EMPC J EMPC C C C J EMPC J C J EMPC C C C J C Pred RRT Actual RRT 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.8563 0.8664 1.0008 1.0184 1.0377 0.8904 - Diff Secs +0.1 -0.7 -0.1 +0.4 -1.1 +0.5 Page 3 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.51E+04 5.60E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.10E+04 0.00E+00 0.00E+00 3.39E+04 0.00E+00 4.54E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.42E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.47 1.30 0.91 0.89 1.10 0.71 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 ND ND ND ND ND 2.28 2.49 ND ND ND ND ND ND ND ND ND ND ND ND 4.39 ND ND 2 ND 3.07 ND ND ND ND ND ND ND ND ND ND ND 2.85 ND ND ND ND ND ND ND ND ND ND ND 5.89E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 2.07E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 2.45E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 3.07E+03 2.08E+03 2.08E+03 2.64E+03 2.64E+03 2.32 2.48 2.45 2.41 2.4 2.3 2.47 2.41 2.58 2.36 2.28 2.51 2.61 2.83 1.23 1.72 1.9 1.78 2.12 1.75 1.33 2.04 1.43 1.75 1.64 1.25 1.91 2.08 1.72 1.19 1.54 1.47 1.62 1.6 1.51 1.43 1.6 1.66 1.69 1.68 1.67 1.41 1.48 1.75 1.3 1.6 2.06 2.45 Printed: 3/31/2014 7:04 PM 51 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 28.00 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.53 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 32.23 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 33.80 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 36.37 SGS Evironmental Services QC J EMPC C J C C C J EMPC C C J EMPC C C J C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9176 1.0008 1.0563 1.1141 0.9723 0 +1.6 0 -0.2 -1.1 Page 4 of 5 Response Ra RRF Conc. / Recv. 4.43E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.36E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.05E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.77E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.86E+04 0.76 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 3.83 ND ND ND ND ND ND ND ND ND 4.13 ND ND ND ND ND ND 2.77 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.56 ND ND ND ND ND ND ND ND ND ND 2.84 0.56 0.78 1.74 1.07 Noise / Recv. Low DL / Recv. High 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 2.64E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 2.26 2.24 2.23 2.3 2.32 2.29 2.73 2.52 1.61 2.33 2.02 2.97 2 1.7 2.01 1.81 2.03 1.79 1.75 2.83 1.63 1.61 1.79 1.61 1.81 2.03 1.88 0.869 1.01 0.978 1.07 1.06 1.35 1.43 1.21 1.37 1.38 1.86 1.39 1.36 1.61 1.64 1.56 1.46 1.15 1.31 1.07 1.1 Printed: 3/31/2014 7:04 PM 52 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB NotFnd NotFnd NotFnd NotFnd 37.43 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J C C C C C Pred RRT Actual RRT 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 1.0006 - Diff Secs -1.1 Page 5 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.12E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.34 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 ND ND ND ND 2.82 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.55E+03 1.55E+03 1.55E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.66E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.23E+03 1.23E+03 1.23E+03 2.51E+03 2.51E+03 2.51E+03 1.5 1.67 1.32 1.11 1.35 1.2 1.02 1.47 1.21 1.22 1.04 1.22 1.27 1.15 1.23 1.76 1.81 1.7 1.66 1.61 1.89 1.97 2.07 1.84 2.1 2 1.54 1.61 1.47 2.24 1.62 1.48 1.4 1.5 1.43 1.44 2.16 2.05 2 2.19 2.02 1.55 2.72 2.69 4.12 Printed: 3/31/2014 7:04 PM 53 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.68e7 2.84e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.59e7 7.97e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.29e7 6.45e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 1.99e7 9.96e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.20e7 6.01e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.79e6 1.39e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.68e6 1.34e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 967-196 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:16 Page 1 of 21 54 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 1.72e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 2.52e3 8.62e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.18e5 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 3.04e3 5.91e4 0% 11.0 12.0 13.0 ES-1 2.67e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 2.86e7 14.17 0.00e0 16.0 RT Abs. Int. 1.02e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.79e3 5.12e6 0% 11.0 12.0 13.0 ES-1 8.20e6 11.88 Rel. Int. 100% 14.0 15.0 ES-3 8.54e6 14.17 0.00e0 16.0 RT Abs. Int. 3.22e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.23e4 1.61e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.68e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.84e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2785, 2261 scc: 967-196 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:41 Printed: 31-Mar-2014 19:16 Page 2 of 21 55 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 6.94e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 3.39e3 3.47e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.76e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 1.29e4 1.38e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.21e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.23e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 6.85e3 2.12e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 7.68e6 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.71e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 2.71e3 1.36e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.68e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.84e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3582, 8531 scc: 967-196 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:41 (CEM) Printed: 31-Mar-2014 19:16 Page 3 of 21 56 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 PCB-11 1.33e5 19.57 Rel. Int. 100% Abs. Int. 3.85e4 DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.72e3 1.93e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-11 9.05e4 19.57 Rel. Int. 100% Abs. Int. 4.38e4 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.67e4 2.19e4 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 2.97e7 16.40 20.0 21.0 0.00e0 RT Abs. Int. 9.90e6 ES-15 2.87e7 20.13 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.54e4 4.95e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 1.87e7 16.40 20.0 21.0 0.00e0 RT Abs. Int. 6.18e6 ES-15 1.81e7 20.13 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 4.80e3 3.09e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.59e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.97e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2262, 9767 scc: 967-196 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:53 (CEM) Printed: 31-Mar-2014 19:16 Page 4 of 21 57 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 1.02e4 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: B 4σ 3.47e3 5.09e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.65e3 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: B 4σ 2.41e3 3.82e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.55e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 3.84e4 ES-19 1.14e7 17.51 3.78e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.07e7 17.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.31e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 3.19e4 1.66e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.59e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.97e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3314, 5998 scc: 967-196 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:53 (CEM) Printed: 31-Mar-2014 19:16 Page 5 of 21 58 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 PCB-31 3.96e4 22.66 TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 3.52e3 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Abs. Int. 1.22e4 28/20 3.57e4 22.92 6.11e3 0% 22.0 Rel. Int. 100% 23.0 PCB-31 2.70e4 22.65 TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 1.87e3 24.0 25.0 0.00e0 RT 26.0 Abs. Int. 1.06e4 28/20 2.74e4 22.93 5.29e3 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 2.18e7 22.90 Rel. Int. 100% ES-37 1.90e7 26.46 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.91e4 Abs. Int. 5.93e6 2.96e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 2.01e7 22.90 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 1.74e7 26.46 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.51e4 Abs. Int. 5.41e6 2.70e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.45e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3938, 3908 scc: 967-196 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:42 (CEM) Printed: 31-Mar-2014 19:16 Page 6 of 21 59 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 3.38e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 1.21e3 1.69e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.86e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 8.61e2 1.93e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 9.23e6 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 6.36e3 1.33e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.23e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.47e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 5.26e3 1.74e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.59e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.97e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5285, 7826 scc: 967-196 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:41 (CEM) Printed: 31-Mar-2014 19:16 Page 7 of 21 60 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Rel. Int. 100% PCB-52 3.11e4 24.54 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.08e3 69/49 1.60e4 24.97 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Abs. Int. 9.16e3 44/47… 2.80e4 25.45 4.58e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-52 3.43e4 24.55 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.37e3 Abs. Int. 1.30e4 69/49 1.79e4 24.99 44/47… 2.55e4 25.45 6.48e3 0% 22.0 23.0 24.0 25.0 26.0 JS-52 1.20e7 24.52 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 3.20e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.43e4 1.60e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 1.50e7 24.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.91e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.16e4 1.96e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.45e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4761, 7310 scc: 967-196 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:43 (CEM) Printed: 31-Mar-2014 19:16 Page 8 of 21 61 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 61/70... 2.26e4 28.77 Rel. Int. 100% Abs. Int. 5.89e3 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.17e3 2.94e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 61/70... 3.16e4 28.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.77e3 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 1.90e3 3.39e3 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.36e7 32.31 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.45e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 3.56e6 ES-77 1.42e7 32.78 1.78e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.75e7 32.31 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.02e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 4.55e6 ES-77 1.80e7 32.79 2.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 9.96e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5812, 7203 scc: 967-196 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:43 (CEM) Printed: 31-Mar-2014 19:16 Page 9 of 21 62 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 3.04e3 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PB 4σ 1.15e3 1.52e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.40e3 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PB 4σ 9.33e2 1.70e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.31e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.18e3 1.70e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 8.30e6 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.23e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.75e3 1.11e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.45e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0582, 2413 scc: 967-196 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:44 (CEM) Printed: 31-Mar-2014 19:16 Page 10 of 21 63 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 9.90e2 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 113/90… 1.92e4 30.53 PCB-95 2.08e4 28.00 PCB-110 1.96e4 32.23 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Abs. Int. 8.06e3 PCB-118 1.65e4 34.79 4.03e3 0% 28.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.65e3 30.0 32.0 113/90… 3.44e4 30.53 PCB-95 2.73e4 27.99 34.0 36.0 38.0 Abs. Int. 1.00e4 PCB-118 2.34e4 34.78 PCB-110 2.50e4 32.23 0.00e0 RT 5.01e3 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.75e7 32.80 JS-101 1.54e7 30.51 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.04e3 ES-118 ES-114 ES-123 1.63e7 1.69e7 1.63e7 34.76 35.23 34.48 36.0 38.0 0.00e0 RT Abs. Int. 4.53e6 ES-105 1.66e7 35.77 2.26e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.12e7 32.80 JS-101 9.47e6 30.51 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.14e3 ES-118 ES-114 1.02e7 ES-123 1.03e7 1.03e7 34.76 35.23 34.48 36.0 38.0 0.00e0 RT Abs. Int. 2.74e6 ES-105 1.05e7 35.77 1.37e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 9.96e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0853, 7163 scc: 967-196 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:45 (CEM) Printed: 31-Mar-2014 19:16 Page 11 of 21 64 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 6.59e3 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 9.04e2 3.30e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 1.52e4 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.11e3 7.58e3 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.54e6 ES-126 1.39e7 38.38 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 3.56e3 1.77e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.28e6 ES-126 9.13e6 38.38 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 2.31e3 1.14e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.01e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3306, 3290 scc: 967-196 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:41 Printed: 31-Mar-2014 19:16 Page 12 of 21 65 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 147/149 2.14e4 33.80 Rel. Int. 100% Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 153/168 2.00e4 36.37 163/138… 1.78e4 37.43 Abs. Int. 7.20e3 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 7.85e2 3.60e3 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 153/168 1.87e4 36.37 147/149 1.23e4 33.80 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 7.40e2 36.0 38.0 0.00e0 RT Abs. Int. 6.77e3 163/138… 1.34e4 37.42 3.39e3 0% 28.0 30.0 32.0 34.0 ES-155 1.57e7 30.34 Rel. Int. 100% 36.0 ES-153 1.08e7 36.34 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.52e3 38.0 0.00e0 RT Abs. Int. 3.88e6 JS-138 1.12e7 37.41 1.94e6 0% 28.0 30.0 32.0 34.0 ES-155 1.24e7 30.34 Rel. Int. 100% 36.0 ES-153 8.87e6 36.34 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 2.00e3 38.0 0.00e0 RT Abs. Int. 3.06e6 JS-138 8.73e6 37.41 1.53e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 9.96e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1336, 4642 scc: 967-196 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:45 (CEM) Printed: 31-Mar-2014 19:16 Page 13 of 21 66 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 4.74e3 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PB 4σ 7.74e2 2.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e3 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PB 4σ 7.73e2 1.71e3 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.39e7 39.94 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 4.44e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 2.62e7 40.92 0.00e0 RT Abs. Int. 4.60e6 ES-169 1.21e7 43.64 2.30e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.08e7 39.94 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 4.31e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 2.07e7 40.92 0.00e0 RT Abs. Int. 3.65e6 ES-169 9.72e6 43.64 1.83e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.01e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7845, 7570 scc: 967-196 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:52 Printed: 31-Mar-2014 19:17 Page 14 of 21 67 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 3.85e3 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PB 4σ 6.66e2 1.92e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.04e3 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PB 4σ 6.26e2 2.02e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 9.93e6 35.22 Rel. Int. 100% Abs. Int. 2.49e6 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.50e3 CS/SS-178 6.53e6 37.78 1.24e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 9.54e6 35.22 Rel. Int. 100% CS/SS-178 5.99e6 37.78 1.19e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 2.37e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.33e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 9.96e6 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4575, 7082 scc: 967-196 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:41 Printed: 31-Mar-2014 19:17 Page 15 of 21 68 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 4.67e3 HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PB 4σ 9.77e2 2.34e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.64e3 HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PB 4σ 6.80e2 2.32e3 0% 39.0 40.0 41.0 42.0 ES-180 9.24e6 42.09 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.00e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.16e6 ES-170 7.54e6 43.15 1.08e6 0% 39.0 40.0 41.0 42.0 ES-180 8.63e6 42.09 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 1.73e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.11e6 ES-170 6.93e6 43.15 1.05e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.01e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2366, 4379 scc: 967-196 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:41 Printed: 31-Mar-2014 19:17 Page 16 of 21 69 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 2.37e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 8.63e2 1.18e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 2.90e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 7.83e2 1.45e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.06e7 45.76 0.00e0 RT Abs. Int. 2.50e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 2.85e3 1.25e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.05e7 45.76 0.00e0 RT Abs. Int. 2.59e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.33e3 1.30e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.39e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5282, 7711 scc: 967-196 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:41 Printed: 31-Mar-2014 19:17 Page 17 of 21 70 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 4.07e3 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PB 4σ 5.78e2 2.03e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.68e3 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PB 4σ 7.52e2 1.84e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 8.59e6 39.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 2.23e3 1.00e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 9.67e6 39.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.30e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.09e3 1.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.01e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3188, 4635 scc: 967-196 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:41 Printed: 31-Mar-2014 19:17 Page 18 of 21 71 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 1.77e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PB 4σ 6.62e2 8.84e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.00e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PB 4σ 5.72e2 1.00e3 0% 46.0 47.0 48.0 JS-194 6.80e6 47.53 Rel. Int. 100% 49.0 50.0 ES-205 7.24e6 47.93 0.00e0 RT Abs. Int. 1.74e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 1.75e3 8.68e5 0% 46.0 47.0 48.0 JS-194 7.40e6 47.53 Rel. Int. 100% 49.0 50.0 ES-205 8.42e6 47.93 0.00e0 RT Abs. Int. 2.04e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.24e3 1.02e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.39e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6462, 9227 scc: 967-196 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:41 Printed: 31-Mar-2014 19:17 Page 19 of 21 72 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 2.49e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 7.23e2 1.25e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 4.60e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 1.79e3 2.30e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 7.78e6 45.38 50.0 0.00e0 RT Abs. Int. 1.82e6 ES-206 4.91e6 49.39 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 8.01e2 9.09e5 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 9.83e6 45.38 50.0 Abs. Int. 2.41e6 ES-206 6.27e6 49.39 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.46e3 0.00e0 RT 1.21e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.39e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4254, 9205 scc: 967-196 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:41 Printed: 31-Mar-2014 19:17 Page 20 of 21 73 of 711 SGS-AP ID: MB1_11892_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 33 Acq: 26-Mar-2014 21:07:05 User: LKB Datafile: 140326X08 Rel. Int. 100% Abs. Int. 2.12e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: PB 4σ 6.01e2 1.06e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.35e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: PB 4σ 4.94e2 1.18e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 7.55e6 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.65e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 9.51e2 8.27e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 6.39e6 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.38e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 7.66e2 6.91e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.68e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.34e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\MB1_11892_PCB_TLX.utp_res, saved 31-Mar-2014 13:54 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9356, 5396 scc: 967-196 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:41 (CEM) Printed: 31-Mar-2014 19:17 Page 21 of 21 74 of 711 Lab ID: A6504_11892_PCB_001 ACQ: 26-Mar-2014 22:02:20 LKB Wt/Vol: 0.97 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Client ID: PB020-1SWMID-140313-N (TOTAL) UTP: 31-Mar-2014 15:12 CEM J-level: 10.3 pg/L Datafile: 140326X09 RPT: 31-Mar-2014 18:57 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.81 NotFnd 35.79 35.25 34.79 34.51 38.40 40.94 39.97 NotFnd 45.78 50.85 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.88 14.17 14.43 20.14 17.51 26.46 20.42 32.79 32.31 25.40 35.77 35.23 34.77 34.49 38.38 36.35 30.35 40.93 39.95 43.65 43.16 42.09 35.22 45.77 39.76 47.93 49.40 45.39 50.83 QC J C J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0006 1.0006 1.0006 1.0007 1.0004 1.0002 1.0005 1.0003 1.0004 0 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7244 0.8639 0.8793 1.2275 1.0674 1.0789 0.8327 1.3368 1.3174 0.8323 1.1723 1.1545 1.1393 1.1301 1.2578 0.9716 0.8112 1.0941 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 Split: 1 Checkcode: 320-870-RRF Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.79 -0.3 0 4.03E+06 0.00E+00 1.03E+07 6.29E+05 2.03E+07 5.60E+05 1.13E+05 1.20E+06 4.36E+05 0.00E+00 7.37E+04 1.78E+07 1.06 1.15 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 123 ND 370 21.1 702 18.8 5.08 51.1 16.5 ND 3.61 1,370 5.19E+03 5.19E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 2.53E+03 2.06E+03 2.06E+03 2.06E+03 2.10E+03 1.23E+03 1.64 1.71 1.31 1.19 1.21 1.2 1.15 1.21 0.785 1.02 1.08 1.11 0 0 -0.1 +0.2 +0.1 +0.2 -0.1 +0.4 +0.4 -0.2 +0.4 +0.2 +0.2 +0.2 +0.2 0 -0.2 +0.2 0 0 0 0 0 0 0 0 0 0 0 6.53E+07 7.29E+07 4.08E+07 9.20E+07 4.24E+07 7.04E+07 4.29E+07 5.88E+07 5.68E+07 4.25E+07 5.17E+07 5.10E+07 5.00E+07 5.06E+07 4.16E+07 3.72E+07 5.39E+07 8.78E+07 4.69E+07 3.83E+07 2.73E+07 3.35E+07 3.72E+07 3.92E+07 3.46E+07 2.81E+07 1.97E+07 3.25E+07 2.40E+07 3.31 3.32 1.62 1.57 1.07 1.10 0.76 0.79 0.79 1.60 1.59 1.62 1.60 1.58 1.53 1.31 1.28 1.26 1.29 1.27 1.08 1.09 1.07 1.03 0.92 0.89 0.80 0.81 1.19 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 58.8 % 72.1 % 83.8 % 95 % 90 % 84.2 % 99 % 84.5 % 82.6 % 115 % 93.2 % 90.7 % 93.4 % 92.5 % 87.6 % 92.4 % 94.4 % 76.4 % 78.1 % 68.4 % 92.5 % 94.7 % 110 % 94.8 % 99.3 % 86.6 % 91.1 % 106 % 83 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% -0.2 0 0 0 -0.2 -0.7 -0.2 Page 1 of 5 0.62 0.63 0.61 0.65 0.58 1.24 1.15 Printed: 3/31/2014 7:04 PM 75 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.91 32.81 37.79 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 7.87E+07 5.31E+07 2.32E+07 1.09 1.56 1.10 1.11 1.03 0.62 101 % 102 % 100 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.91 32.81 37.79 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 7.87E+07 5.31E+07 2.32E+07 1.09 1.56 1.10 1.85 1.22 0.58 84.8 % 94.2 % 111 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.41 24.53 30.52 37.41 47.53 9.31E+07 5.03E+07 4.62E+07 3.59E+07 2.61E+07 1.56 0.81 1.57 1.29 0.90 6.20E+03 6.20E+03 6.20E+03 1.10E+04 1.10E+04 5.56E+03 5.56E+03 5.56E+03 5.56E+03 5.56E+03 5.56E+03 5.56E+03 5.56E+03 5.56E+03 5.55E+03 5.55E+03 5.55E+03 5.55E+03 5.55E+03 5.55E+03 1.25 1.12 1.24 3.2 2.06 1.24 1.09 1.18 1.18 1.12 0.983 1.12 1.14 1.17 2.01 1.5 1.75 1.29 1.34 2.35 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.90 14.01 14.19 14.44 14.62 16.42 16.59 16.82 NotFnd 17.24 NotFnd 19.58 19.85 20.15 17.53 19.30 19.69 19.88 NotFnd 20.11 J J J J B J EMPC C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 1.0011 0.9881 1.0009 1.0011 1.0137 1.0010 1.0111 1.0249 1.0507 0.9721 0.9855 1.0007 1.0011 1.1019 1.1244 1.1354 1.1486 0 +0.1 -0.1 0 +0.2 0 0 0 +0.2 0 -1.3 -0.1 +0.1 +0.5 0 0 +0.1 Page 2 of 5 NON-EMPC 47.5 545 5,610 14,700 6,500 2,100 671 179 163 1.04E+06 1.17E+05 3.65E+05 4.66E+06 3.17E+05 4.70E+05 2.15E+05 1.67E+06 0.00E+00 7.59E+06 0.00E+00 1.46E+06 4.90E+05 4.66E+06 2.58E+06 3.37E+07 1.03E+07 2.13E+06 0.00E+00 7.44E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 47.5 555 5,610 14,700 6,510 2,100 671 179 163 3.34 2.82 3.29 1.64 SI 1.55 SI 1.61 1.60 1.71 1.89 1.62 1.03 1.05 1.07 1.10 1.08 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 1.25 2.19 1.97 1.23 1.09 0.857 1.02 1.05 2.39 34.3 2.96 10.2 191 8.35 11 4.37 36.9 ND 160 ND 30.7 10.4 102 109 1,060 381 57.7 ND 368 Printed: 3/31/2014 7:04 PM 76 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.59 21.74 NotFnd 22.15 22.38 22.65 22.93 23.14 23.50 NotFnd NotFnd NotFnd 26.12 26.49 20.44 22.40 23.02 23.09 23.30 24.55 24.68 24.77 24.99 25.25 25.45 25.74 25.91 26.24 26.34 26.54 27.25 27.51 27.88 NotFnd 28.25 28.47 28.77 29.04 29.19 29.62 29.82 NotFnd 31.48 NotFnd NotFnd 25.74 27.43 27.62 SGS Evironmental Services QC J C C C J C J EMPC C C C C J C J EMPC Pred RRT Actual RRT Diff Secs 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1760 0.8215 0.8371 0.8456 0.8560 0.8664 0.8745 0.8878 0.9870 1.0009 1.0009 0.9134 0.9385 0.9415 0.9499 1.0009 1.0060 1.0100 1.0189 1.0296 1.0374 1.0493 1.0564 1.0699 1.0739 1.0820 0.8434 0.8513 0.8629 0.8741 0.8810 0.8903 0.8987 0.9033 0.9167 0.9228 0.9741 1.0134 0.8987 0.9050 +0.1 -0.4 -1.5 -0.1 -0.3 -0.7 +1.0 -0.1 -0.2 +0.3 -0.1 -1.5 0 +0.1 0 0 -0.3 0 +1.2 0 -1.5 -0.6 +0.2 -0.2 +0.2 +0.2 -0.2 -0.2 -0.2 0 -0.2 +0.3 -0.2 0 -0.2 0 +0.8 0 -0.3 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 1.26E+07 2.42E+05 0.00E+00 7.46E+06 3.08E+06 5.02E+07 4.48E+07 1.65E+07 1.19E+07 0.00E+00 0.00E+00 0.00E+00 7.58E+05 7.57E+06 1.70E+05 8.32E+06 7.31E+06 2.50E+06 2.55E+06 5.77E+07 1.04E+05 1.37E+06 3.59E+07 9.02E+06 5.10E+07 4.90E+06 1.09E+07 2.72E+06 2.12E+07 2.80E+07 4.89E+05 1.05E+06 2.03E+05 0.00E+00 1.21E+06 1.87E+06 8.89E+07 4.98E+07 4.37E+05 2.24E+07 9.72E+06 0.00E+00 5.06E+05 0.00E+00 0.00E+00 4.86E+05 2.69E+05 1.97E+05 1.05 1.01 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 317 5.75 ND 172 70.7 1,110 1,060 382 295 ND ND ND 19 205 6.02 333 323 103 126 2,350 3.21 65.1 1,200 367 1,950 143 486 132 849 773 14 28.8 6.11 ND 34 50 2,650 1,540 13.8 703 302 ND 14 ND ND 20.2 11.5 10 1.01 0.99 1.00 1.01 1.00 0.98 1.01 1.03 0.80 0.79 0.79 0.81 0.79 0.79 0.90 0.76 0.79 0.78 0.79 0.77 0.79 0.75 0.79 0.77 0.83 0.77 0.88 0.80 0.79 0.80 0.80 0.81 0.80 0.79 0.81 0.62 0.62 0.72 Noise / Recv. Low DL / Recv. High 5.55E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 2.12E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 2.58E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 1.41E+03 1.41E+03 3.65E+03 3.65E+03 1.2 1.69 1.66 1.64 1.63 1.56 1.68 1.64 1.75 1.6 1.55 1.71 1.77 1.92 0.677 1.05 1.16 1.08 1.29 1.06 0.808 1.24 0.872 1.07 1 0.765 1.16 1.27 1.05 0.724 1.51 1.44 1.58 1.57 1.48 1.41 1.57 1.63 1.66 1.65 1.64 1.38 1.45 1.72 0.455 0.559 1.52 1.81 Printed: 3/31/2014 7:04 PM 77 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 28.00 28.21 28.32 NotFnd NotFnd 28.76 28.95 29.37 NotFnd 30.03 30.54 30.94 31.04 NotFnd 31.52 NotFnd 32.09 32.24 NotFnd 32.52 NotFnd NotFnd 34.20 34.41 NotFnd 35.08 NotFnd NotFnd NotFnd NotFnd 30.98 NotFnd 32.53 33.04 33.25 33.51 33.81 33.99 NotFnd 34.33 34.51 NotFnd 34.89 35.29 NotFnd 35.85 NotFnd 36.37 SGS Evironmental Services QC J C C C C C J EMPC C J C J C J J C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9175 0.9245 0.9282 0.9424 0.9487 0.9624 0.9840 1.0007 1.0139 1.0173 1.0329 1.0517 1.0564 1.0656 0.9916 0.9977 1.0091 1.0208 1.0720 1.0886 1.0956 1.1043 1.1141 1.1202 1.1312 1.1372 1.1496 1.1629 0.9581 0.9722 -0.2 -0.2 0 -0.2 0 0 -0.2 +1.5 -0.6 0 +1.7 -1.5 +0.2 0 +0.2 +0.2 0 +0.2 +1.0 0 +0.2 +0.2 -0.2 +0.6 -0.2 +0.4 +0.2 +0.2 -0.2 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.65E+07 3.72E+05 1.33E+06 0.00E+00 0.00E+00 4.32E+06 5.83E+06 5.69E+05 0.00E+00 3.27E+06 2.11E+07 8.81E+05 1.27E+07 0.00E+00 1.72E+07 0.00E+00 5.73E+06 2.94E+07 0.00E+00 2.85E+06 0.00E+00 0.00E+00 8.46E+05 1.79E+06 0.00E+00 3.86E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.71E+06 0.00E+00 2.43E+04 2.69E+06 1.92E+05 4.12E+05 7.32E+06 4.60E+05 0.00E+00 2.01E+05 1.34E+05 0.00E+00 2.80E+06 1.53E+05 0.00E+00 1.51E+06 0.00E+00 8.77E+06 0.62 0.62 0.59 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 770 17.3 61.6 ND ND 205 330 29.7 ND 157 880 54.3 524 ND 716 ND 240 1,090 ND 167 ND ND 31.3 59.5 ND 15.4 ND ND ND ND 63.9 ND 1.2 141 8.48 20.7 368 31.3 ND 10 7.86 ND 159 8.16 ND 72.2 ND 351 0.61 0.61 0.60 0.61 0.62 0.59 0.62 0.62 0.60 0.61 0.61 0.61 0.63 0.60 1.30 1.47 1.27 1.21 1.26 1.25 1.25 1.29 1.31 1.23 1.24 1.32 1.24 Noise / Recv. Low DL / Recv. High 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 3.65E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.67 1.66 1.65 1.7 1.72 1.69 2.02 1.86 1.19 1.72 1.49 2.2 1.48 1.25 1.49 1.33 1.5 1.32 1.29 2.09 1.21 1.19 1.32 1.19 1.34 1.42 1.37 0.408 0.473 0.459 0.502 0.496 0.684 0.725 0.612 0.697 0.698 0.945 0.703 0.692 0.814 0.833 0.791 0.741 0.582 0.664 0.54 0.555 Printed: 3/31/2014 7:04 PM 78 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.54 36.88 37.08 37.16 37.44 NotFnd 37.77 38.52 39.30 39.56 NotFnd 35.53 NotFnd 36.28 NotFnd 37.81 38.35 38.58 NotFnd 39.10 39.19 39.30 39.68 NotFnd 40.21 41.55 NotFnd 42.11 42.40 43.18 43.63 39.78 40.57 NotFnd 41.33 41.43 43.76 44.32 44.49 45.61 47.55 47.96 45.41 46.20 49.41 SGS Evironmental Services QC C C J J J J C C J J J J C J Pred RRT Actual RRT Diff Secs 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 0.9859 0.9911 0.9934 1.0007 1.0096 0.9643 0.9837 0.9903 1.0086 1.0300 1.0734 1.0888 1.0953 1.1101 1.1126 1.1157 1.1264 1.1416 0.9079 0.9200 0.9265 0.9434 0.9533 1.0005 1.0204 1.0395 1.0419 1.1007 1.1147 1.1190 0.9516 0.9921 1.0005 1.0005 1.0178 1.0004 -0.2 0 -0.2 0 -0.9 0 +0.7 -1.4 0 0 0 +0.2 0 0 0 +0.2 +0.2 +0.2 +0.5 0 +1.8 -0.3 0 0 0 +0.2 0 +0.2 +1.3 0 +0.3 0 0 +0.3 0 0 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 1.37E+06 5.77E+05 4.68E+05 8.39E+05 9.99E+06 0.00E+00 1.26E+06 1.57E+06 1.04E+05 5.23E+04 0.00E+00 7.53E+05 0.00E+00 2.39E+05 0.00E+00 2.85E+05 8.01E+04 1.99E+06 0.00E+00 9.26E+05 1.64E+05 1.32E+06 8.17E+05 0.00E+00 4.40E+05 2.44E+05 0.00E+00 3.15E+06 9.36E+04 1.17E+06 2.84E+05 2.95E+05 1.59E+05 0.00E+00 1.25E+05 8.70E+04 5.34E+05 2.53E+05 3.09E+05 1.53E+05 4.08E+05 4.39E+04 9.45E+05 8.79E+05 6.45E+05 1.24 1.29 1.15 1.43 1.28 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 75.4 35.1 22.5 33.9 492 ND 47 78.2 4.27 2.15 ND 38.4 ND 11.5 ND 20.9 4.5 105 ND 46.3 9.57 80.6 52.3 ND 28.6 15.1 ND 157 4.26 79.5 13.9 16.7 8.49 ND 6.82 4.77 44.1 19.7 23.6 15 36.7 3.03 53.4 49.1 60.5 1.25 1.20 1.17 1.22 1.04 1.02 1.01 0.97 1.09 1.03 1.16 1.06 1.07 1.07 1.07 1.07 1.05 1.08 1.04 1.01 0.89 0.93 0.92 0.85 0.95 0.99 0.96 0.95 0.80 0.79 0.78 0.76 Noise / Recv. Low DL / Recv. High 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 2.06E+03 2.06E+03 2.06E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 2.11E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.77E+03 1.77E+03 1.77E+03 3.01E+03 3.01E+03 3.01E+03 0.763 0.845 0.669 0.561 0.683 0.607 0.516 1.03 0.849 0.853 0.543 0.635 0.661 0.598 0.638 0.914 1.16 1.09 1.06 1.03 1.21 1.26 1.32 1.17 1.34 1.28 0.986 1.03 0.938 1.53 1.11 0.843 0.795 0.855 0.814 0.818 1.23 1.16 1.14 1.79 1.65 1.26 1.78 1.76 2.99 Printed: 3/31/2014 7:04 PM 79 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.87e7 2.94e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.52e7 7.59e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.22e7 6.08e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.09e7 1.05e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.27e7 6.33e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.86e6 1.43e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.77e6 1.38e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 320-870 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:17 Page 1 of 21 80 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-1 7.97e5 11.90 Rel. Int. 100% Abs. Int. 3.26e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.63e3 PCB-3 2.80e5 14.19 PCB-2 8.63e4 14.01 1.63e5 0% 11.0 Rel. Int. 100% 12.0 13.0 14.0 15.0 Abs. Int. 1.43e5 PCB-1 2.39e5 11.90 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.58e3 7.13e4 PCB-3 8.49e4 14.19 PCB-2 3.06e4 14.00 0% 11.0 12.0 13.0 ES-1 5.01e7 11.88 Rel. Int. 100% 0.00e0 16.0 RT 14.0 15.0 ES-3 5.60e7 14.17 0.00e0 16.0 RT Abs. Int. 2.06e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.31e3 1.03e7 0% 11.0 12.0 13.0 ES-1 1.52e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 1.69e7 14.17 0.00e0 16.0 RT Abs. Int. 6.33e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.63e4 3.16e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.87e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.94e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3986, 6830 scc: 320-870 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:11 (CEM) Printed: 31-Mar-2014 19:17 Page 2 of 21 81 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 Rel. Int. 100% Abs. Int. 9.82e5 PCB-4 2.90e6 14.44 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.70e3 4.91e5 PCB-10 1.93e5 SI 14.62 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 1.77e6 14.44 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.04e5 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.01e4 3.02e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.52e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.88e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.73e3 4.44e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.56e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.44e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.43e3 2.72e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.87e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.94e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7377, 2687 scc: 320-870 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:12 (CEM) Printed: 31-Mar-2014 19:17 Page 3 of 21 82 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 PCB-8 4.68e6 17.24 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 3.39e3 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-9 2.86e5 16.42 Abs. Int. 1.41e6 PCB-6 1.03e6 16.82 PCB-11 9.21e5 19.58 PCB-15 2.88e6 20.15 7.06e5 13/12 3.63e5 19.85 0% 17.0 19.0 20.0 21.0 PCB-8 2.92e6 17.24 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.87e4 18.0 PCB-9 1.85e5 16.42 Abs. Int. 8.49e5 PCB-15 1.78e6 20.15 PCB-6 6.39e5 16.81 4.25e5 PCB-11 5.39e5 19.58 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 5.68e7 16.41 (5.62e7 + 3.58e7) * 2000 pg * 100 = 94.9% (5.68e7 + 3.64e7) * 2000 pg * 1.04 CEM 31-Mar-2014 19:12 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.50e4 20.0 21.0 0.00e0 RT Abs. Int. 1.75e7 ES-15 5.62e7 20.14 Recv(ES-15) = 8.74e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 3.64e7 16.41 20.0 21.0 0.00e0 RT Abs. Int. 1.11e7 ES-15 3.58e7 20.14 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 7.44e3 5.53e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.59e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7837, 8415 scc: 320-870 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 14:19 (CEM) Printed: 31-Mar-2014 19:17 Page 4 of 21 83 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Rel. Int. 100% Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 Abs. Int. 4.90e6 30/18 1.73e7 19.30 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.45e3 PCB-17 5.33e6 19.69 PCB-19 1.31e6 17.53 PCB-27 1.12e6 19.88 PCB-16 3.86e6 20.11 PCB-32 6.42e6 20.59 2.45e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 4.73e6 30/18 1.64e7 19.30 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.11e3 PCB-17 4.99e6 19.69 PCB-19 1.27e6 17.53 PCB-27 1.01e6 19.88 PCB-16 3.57e6 20.11 PCB-32 6.14e6 20.59 2.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.19e7 17.51 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.00e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 5.08e4 3.50e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.05e7 17.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.05e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 3.29e4 3.02e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.59e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6189, 7214 scc: 320-870 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 14:12 (CEM) Printed: 31-Mar-2014 19:17 Page 5 of 21 84 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 PCB-31 2.51e7 28/20 22.65 2.25e7 22.93 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 4.38e3 26/29 3.74e6 22.15 0% Abs. Int. 6.71e6 21/33 8.25e6 23.14 PCB-25 1.53e6 22.38 22.0 PCB-22 5.90e6 23.50 23.0 PCB-37 3.83e6 26.49 24.0 25.0 26/29 3.71e6 22.15 PCB-25 1.55e6 22.38 Abs. Int. 6.61e6 21/33 8.27e6 23.14 PCB-22 6.02e6 23.50 PCB-37 3.74e6 26.49 23.0 24.0 25.0 26.0 CS/SS-28 4.11e7 22.91 Rel. Int. 100% 3.30e6 0.00e0 RT 0% 22.0 3.36e6 0.00e0 RT 26.0 PCB-31 2.51e7 28/20 22.65 2.23e7 22.93 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.83e3 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 ES-37 3.69e7 26.46 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.47e4 Abs. Int. 1.12e7 5.60e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 3.77e7 22.91 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.35e7 26.46 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.18e4 Abs. Int. 1.04e7 5.20e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.08e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4134, 9638 scc: 320-870 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:11 (CEM) Printed: 31-Mar-2014 19:17 Page 6 of 21 85 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-54 7.55e4 20.44 Rel. Int. 100% Abs. Int. 2.50e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.19e3 1.25e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 9.40e4 20.44 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.54e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 9.23e2 1.27e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.86e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.15e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 7.05e3 2.58e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.43e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.67e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 3.40e3 3.33e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.59e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5028, 3215 scc: 320-870 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 14:12 (CEM) Printed: 31-Mar-2014 19:17 Page 7 of 21 86 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-52 2.54e7 24.55 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.03e3 69/49 1.58e7 24.99 50/53 3.68e6 22.40 PCB-45 3.23e6 23.02 44/47… 2.24e7 25.45 PCB-48 3.96e6 25.25 PCB-51 1.12e6 23.09 Abs. Int. 6.70e6 PCB-42 4.83e6 25.91 59/62… 2.13e6 25.74 23.0 24.0 25.0 PCB-64 1.22e7 26.54 PCB-41 1.17e6 26.24 0% 22.0 71/40 9.37e6 26.34 0.00e0 RT 26.0 PCB-52 3.23e7 24.55 Rel. Int. 100% 69/49 2.01e7 24.99 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.54e3 50/53 4.64e6 22.40 PCB-45 4.09e6 23.02 Abs. Int. 8.43e6 44/47… 2.85e7 25.45 PCB-48 5.06e6 25.25 PCB-51 1.38e6 23.09 PCB-42 6.12e6 25.91 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.25e7 24.53 Rel. Int. 100% 3.35e6 71/40 1.18e7 26.34 PCB-64 1.58e7 26.54 4.21e6 0.00e0 RT Abs. Int. 5.93e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.42e4 2.97e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.78e7 24.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.44e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 9.69e3 3.72e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.08e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7835, 3851 scc: 320-870 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:11 (CEM) Printed: 31-Mar-2014 19:17 Page 8 of 21 87 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 Abs. Int. 7.35e6 61/70... 3.96e7 PCB-66 28.77 2.21e7 29.04 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 2.10e3 PCB-56 9.99e6 29.62 PCB-60 4.30e6 29.82 3.67e6 PCB-77 1.78e6 32.81 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 9.13e6 61/70... 4.94e7 PCB-66 28.77 2.76e7 29.04 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 3.08e3 PCB-56 1.24e7 29.62 PCB-60 5.42e6 29.82 4.56e6 PCB-77 2.25e6 32.81 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.51e7 32.31 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.38e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 6.26e6 ES-77 2.59e7 32.79 3.13e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.17e7 32.31 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.04e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 8.10e6 ES-77 3.28e7 32.79 4.05e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.09e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.05e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2503, 1669 scc: 320-870 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 14:18 (CEM) Printed: 31-Mar-2014 19:17 Page 9 of 21 88 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-96 1.86e5 25.74 Rel. Int. 100% Abs. Int. 4.74e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 6.25e2 2.37e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 3.01e5 25.74 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 7.87e2 4.24e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.62e7 25.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.87e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.99e3 3.43e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.63e7 25.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.27e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.38e3 2.13e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.08e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0251, 0696 scc: 320-870 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 14:00 Printed: 31-Mar-2014 19:17 Page 10 of 21 89 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.35e3 113/90… 8.06e6 30.54 PCB-95 6.27e6 28.00 PCB-91 1.64e6 28.76 PCB-84 2.20e6 28.95 PCB-92 1.24e6 30.03 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-110 1.12e7 32.24 Abs. Int. 2.71e6 PCB-118 7.71e6 34.79 PCB-99 4.86e6108/119... 31.04 6.58e6 116/85 31.52 2.16e6 32.09 PCB-82 1.07e6 32.52 PCB-109 6.87e5 34.41 PCB-105 3.96e6 35.79 1.35e6 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 2.30e3 32.0 113/90… 1.30e7 30.54 PCB-95 1.02e7 28.00 PCB-91 2.68e6 28.76 PCB-84 3.63e6 28.95 PCB-92 2.03e6 30.03 34.0 36.0 38.0 PCB-110 1.82e7 32.24 PCB-99 7.81e6108/119... 31.04 1.06e7 116/85 31.52 3.57e6 32.09 Abs. Int. 4.46e6 PCB-118 1.25e7 34.79 PCB-82 1.77e6 32.52 PCB-109 1.10e6 34.41 PCB-105 6.36e6 35.79 2.23e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 3.24e7 32.81 JS-101 2.82e7 30.52 0.00e0 RT PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.13e3 ES-123 3.10e7 34.49 36.0 ES-118 ES-114 3.08e7 3.15e7 34.77 35.23 38.0 0.00e0 RT Abs. Int. 8.26e6 ES-105 3.17e7 35.77 4.13e6 0% 28.0 30.0 32.0 CS/SS-111 2.07e7 32.81 JS-101 1.80e7 30.52 Rel. Int. 100% 34.0 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.39e3 ES-118 ES-114 ES-123 1.92e7 1.94e7 1.96e7 34.77 35.23 34.49 36.0 38.0 0.00e0 RT Abs. Int. 5.19e6 ES-105 2.00e7 35.77 2.59e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.09e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.05e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2816, 6499 scc: 320-870 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:04 (CEM) Printed: 31-Mar-2014 19:17 Page 11 of 21 90 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 Rel. Int. 100% PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 1.34e3 Abs. Int. 8.10e4 4.05e4 PCB-126 4.17e4 38.40 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 1.19e3 Abs. Int. 1.71e5 8.54e4 PCB-126 7.18e4 38.40 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.22e6 ES-126 2.51e7 38.38 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 5.05e3 3.11e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.06e6 ES-126 1.64e7 38.38 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 4.57e3 2.03e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.33e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9035, 0196 scc: 320-870 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:04 (CEM) Printed: 31-Mar-2014 19:17 Page 12 of 21 91 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Rel. Int. 100% Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 153/168 4.86e6 36.37 147/149 4.07e6 33.81 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 7.49e2 PCB-136 9.68e5 30.98 PCB-132 1.54e6 34.89 151/135 1.51e6 33.04 163/138… 5.62e6 37.44 Abs. Int. 1.27e6 PCB-141 PCB-164 PCB-158 7.59e5 7.01e5 4.94e5 36.54 37.77 37.16 PCB-146 8.59e5 35.85 0% 28.0 30.0 32.0 34.0 36.0 38.0 153/168 3.92e6 36.37 Rel. Int. 100% 163/138… 4.37e6 37.44 PCB-136 7.47e5 30.98 151/135 1.19e6 33.03 0% 28.0 30.0 PCB-132 1.26e6 34.89 PCB-144 1.82e5 33.51 32.0 34.0 PCB-146 6.52e5 35.84 PCB-141 6.13e5 PCB-137 36.54 2.17e5 37.08 PCB-158 5.63e5 37.77 36.0 38.0 ES-155 3.03e7 30.35 Rel. Int. 100% ES-153 2.11e7 36.35 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.70e3 0.00e0 RT Abs. Int. 9.96e5 147/149 3.25e6 33.81 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 6.47e2 6.37e5 4.98e5 0.00e0 RT Abs. Int. 7.86e6 JS-138 2.02e7 37.41 3.93e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.36e7 30.35 Rel. Int. 100% ES-153 1.61e7 36.35 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.40e3 0.00e0 RT Abs. Int. 5.96e6 JS-138 1.57e7 37.41 2.98e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.09e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.05e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6353, 1828 scc: 320-870 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:06 (CEM) Printed: 31-Mar-2014 19:17 Page 13 of 21 92 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 128/166 8.60e5 38.52 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 1.18e3 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 Abs. Int. 1.98e5 156/157 6.61e5 40.94 PCB-159 PCB-162 5.63e4 2.87e4 39.30 39.56 PCB-167 2.34e5 39.97 9.88e4 0% 39.0 Rel. Int. 100% 40.0 128/166 7.14e5 38.52 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.58e5 156/157 5.35e5 40.94 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 8.87e2 PCB-159 4.82e4 39.30 PCB-167 2.03e5 39.97 7.90e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.64e7 39.95 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 6.34e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.90e7 40.93 0.00e0 RT Abs. Int. 8.89e6 ES-169 2.14e7 43.65 4.44e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.05e7 39.95 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 5.80e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.89e7 40.93 0.00e0 RT Abs. Int. 6.93e6 ES-169 1.68e7 43.64 3.47e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.33e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6504, 2755 scc: 320-870 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:12 (CEM) Printed: 31-Mar-2014 19:17 Page 14 of 21 93 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-179 3.85e5 35.53 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 6.36e2 Abs. Int. 9.25e4 PCB-176 1.21e5 36.28 PCB-178 1.43e5 37.81 4.62e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 3.69e5 35.53 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 5.80e2 Abs. Int. 9.45e4 PCB-178 1.42e5 37.81 PCB-176 1.19e5 36.28 4.72e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.93e7 35.22 Rel. Int. 100% CS/SS-178 1.21e7 37.79 2.35e6 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.80e7 35.22 Rel. Int. 100% CS/SS-178 1.11e7 37.79 2.21e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 4.42e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.11e3 31.0 0.00e0 RT Abs. Int. 4.70e6 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.47e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.09e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.05e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8952, 9596 scc: 320-870 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:07 (CEM) Printed: 31-Mar-2014 19:17 Page 15 of 21 94 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 180/193 1.63e6 42.11 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 8.30e2 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-187 1.04e6 38.58 PCB-174 6.81e5 PCB-183 39.30 4.69e5 39.10 PCB-185 8.80e4 39.19 PCB-177 4.21e5 39.68 171/173 2.27e5 40.21 Abs. Int. 3.59e5 PCB-170 6.10e5 43.18 PCB-172 1.26e5 41.55 1.79e5 PCB-190 1.45e5 43.63 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 1.52e6 42.11 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 1.28e3 43.0 PCB-187 9.54e5 38.58 PCB-174 6.41e5 PCB-183 39.30 4.57e5 39.10 PCB-185 7.59e4 39.19 PCB-177 3.95e5 39.67 171/173 2.12e5 40.22 Abs. Int. 3.46e5 PCB-170 5.64e5 43.18 PCB-172 1.18e5 41.55 1.73e5 PCB-190 1.39e5 43.63 0% 39.0 40.0 41.0 42.0 ES-180 1.75e7 42.09 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 3.31e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.47e6 ES-170 1.42e7 43.16 2.23e6 0% 39.0 40.0 41.0 42.0 ES-180 1.60e7 42.09 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 2.04e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.92e6 ES-170 1.31e7 43.16 1.96e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.33e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7989, 3600 scc: 320-870 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:09 (CEM) Printed: 31-Mar-2014 19:17 Page 16 of 21 95 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-189 3.79e4 45.78 Abs. Int. 1.20e4 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 9.34e2 5.98e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 3.58e4 45.79 Abs. Int. 9.51e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 1.17e3 4.75e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.99e7 45.77 0.00e0 RT Abs. Int. 4.73e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 3.72e3 2.36e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.93e7 45.77 0.00e0 RT Abs. Int. 4.48e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.65e3 2.24e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.43e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7305, 8518 scc: 320-870 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:10 (CEM) Printed: 31-Mar-2014 19:17 Page 17 of 21 96 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 198/199 2.45e5 43.76 Rel. Int. 100% PCB-202 1.48e5 39.78 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 5.56e2 PCB-201 7.50e4 40.57 Abs. Int. 6.17e4 PCB-196 1.23e5 44.32 PCB-197 6.03e4 PCB-200 4.16e4 41.33 41.43 PCB-203 1.54e5 44.49 3.08e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 2.90e5 43.76 Rel. Int. 100% PCB-202 1.47e5 39.78 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 8.71e2 PCB-201 8.43e4 40.57 Abs. Int. 6.31e4 PCB-196 1.30e5 44.32 PCB-197 6.45e4 PCB-200 4.53e4 41.33 41.43 PCB-203 1.55e5 44.49 3.15e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.66e7 39.76 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 3.97e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.32e3 1.98e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.80e7 39.76 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.33e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.34e3 2.16e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.33e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6692, 2455 scc: 320-870 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:10 (CEM) Printed: 31-Mar-2014 19:17 Page 18 of 21 97 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 PCB-194 1.99e5 47.55 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 7.28e2 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-195 7.49e4 45.61 Abs. Int. 5.24e4 2.62e4 PCB-205 1.95e4 47.96 0% 46.0 47.0 49.0 50.0 PCB-194 2.09e5 47.55 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 1.04e3 48.0 PCB-195 7.84e4 45.61 0.00e0 RT Abs. Int. 5.25e4 2.63e4 PCB-205 2.44e4 47.96 0% 46.0 47.0 48.0 JS-194 1.23e7 47.53 Rel. Int. 100% 49.0 50.0 ES-205 1.32e7 47.93 0.00e0 RT Abs. Int. 3.20e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 1.90e3 1.60e6 0% 46.0 47.0 48.0 JS-194 1.38e7 47.53 Rel. Int. 100% 49.0 50.0 ES-205 1.49e7 47.93 0.00e0 RT Abs. Int. 3.57e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.51e3 1.78e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.43e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8106, 8537 scc: 320-870 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 14:00 Printed: 31-Mar-2014 19:17 Page 19 of 21 98 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-207 3.85e5 46.20 PCB-208 4.16e5 45.41 Abs. Int. 1.03e5 PCB-206 2.78e5 49.41 NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.25e3 5.17e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-207 4.95e5 46.19 PCB-208 5.29e5 45.41 Abs. Int. 1.34e5 PCB-206 3.67e5 49.41 NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 1.76e3 6.69e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.46e6 ES-208 1.45e7 45.39 ES-206 8.79e6 49.40 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.22e3 1.73e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 4.33e6 ES-208 1.80e7 45.39 ES-206 1.09e7 49.40 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.85e3 2.17e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.43e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0632, 9456 scc: 320-870 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 14:00 Printed: 31-Mar-2014 19:17 Page 20 of 21 99 of 711 SGS-AP ID: A6504_11892_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB020-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 34 Acq: 26-Mar-2014 22:02:20 User: LKB Datafile: 140326X09 PCB-209 9.55e6 50.85 Rel. Int. 100% Abs. Int. 2.04e6 (9.55e6 + 8.29e6) *2000 pg = 1,370 pg/L (1.31e7 + 1.10e7) * 1.11 * 0.971 L CEM 31-Mar-2014 19:09 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 6.16e2 Conc(PCB-209) = 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 8.29e6 50.85 Rel. Int. 100% 1.02e6 0.00e0 52.0 RT Abs. Int. 1.79e6 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.11e2 8.93e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.31e7 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.79e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.11e3 1.40e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.10e7 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.45e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 5.88e2 1.23e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.77e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.38e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_001.utp_res, saved 31-Mar-2014 19:12 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4600, 7469 scc: 320-870 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:59 (CEM) Printed: 31-Mar-2014 19:17 Page 21 of 21 100 of 711 Lab ID: A6504_11892_PCB_002 ACQ: 26-Mar-2014 22:57:34 LKB Wt/Vol: 0.98 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Client ID: PB031.1-1SWMID-140313-N (TOTAL) UTP: 31-Mar-2014 15:25 CEM J-level: 10.2 pg/L Datafile: 140326X10 RPT: 31-Mar-2014 18:58 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.80 32.33 35.79 35.25 34.78 34.51 NotFnd 40.93 39.96 NotFnd 45.78 50.84 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.88 14.17 14.42 20.14 17.51 26.46 20.42 32.79 32.31 25.39 35.77 35.23 34.76 34.48 38.38 36.34 30.34 40.92 39.94 43.64 43.15 42.09 35.22 45.76 39.75 47.92 49.39 45.38 50.82 QC J C J EMPC Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0005 1.0007 1.0006 1.0006 1.0006 1.0007 1.0002 1.0005 1.0005 1.0004 -0.2 +0.4 -0.2 0 0 0 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7243 0.8639 0.8793 1.2275 1.0674 1.0789 0.8326 1.3369 1.3174 0.8323 1.1723 1.1545 1.1393 1.1301 1.2578 0.9716 0.8112 1.0941 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 Split: 1 Checkcode: 645-564-GVL Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.80 0.71 0.61 0.62 0.61 0.61 +0.3 0 2.66E+06 1.10E+05 7.08E+06 4.41E+05 1.38E+07 3.48E+05 0.00E+00 7.82E+05 2.75E+05 0.00E+00 4.01E+04 7.43E+06 0.71 1.18 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 83.4 3.64 268 15.5 500 12.3 ND 35.1 10.9 ND 2.05 580 5.49E+03 5.49E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 2.22E+03 2.19E+03 2.19E+03 2.19E+03 1.65E+03 1.42E+03 1.72 1.84 1.24 1.13 1.17 1.11 1.04 1.32 0.891 1.08 0.9 1.26 -0.1 0 -0.1 +0.2 +0.1 +0.2 -0.2 +0.6 +0.4 -0.2 +0.4 +0.2 +0.2 +0.2 +0.2 0 -0.2 +0.2 0 0 0 0 0 0 0 0 0 0 0 5.79E+07 6.43E+07 3.56E+07 8.65E+07 3.91E+07 6.71E+07 3.90E+07 5.65E+07 5.52E+07 3.88E+07 4.85E+07 4.82E+07 4.72E+07 4.77E+07 4.11E+07 3.50E+07 5.06E+07 8.30E+07 4.44E+07 3.84E+07 2.56E+07 3.15E+07 3.50E+07 3.72E+07 3.32E+07 2.69E+07 1.90E+07 3.05E+07 2.35E+07 3.26 3.28 1.64 1.58 1.06 1.10 0.76 0.81 0.80 1.59 1.60 1.65 1.64 1.59 1.52 1.28 1.29 1.26 1.25 1.26 1.09 1.09 1.10 1.04 0.89 0.90 0.80 0.79 1.19 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 58.4 % 71.2 % 82 % 100 % 93.1 % 88.3 % 99 % 89.4 % 88.4 % 117 % 97.7 % 95.8 % 98.7 % 97.4 % 96.7 % 94.3 % 96.2 % 78.4 % 80.4 % 74.6 % 95.3 % 97.7 % 113 % 98.8 % 104 % 91 % 96.1 % 109 % 89 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% -0.7 -0.2 Page 1 of 5 1.22 1.30 Printed: 3/31/2014 7:04 PM 101 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 7.77E+07 5.20E+07 2.26E+07 1.10 1.60 1.07 1.11 1.03 0.62 104 % 106 % 104 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 7.77E+07 5.20E+07 2.26E+07 1.10 1.60 1.07 1.85 1.22 0.58 92.1 % 103 % 118 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.40 24.52 30.51 37.41 47.53 8.31E+07 4.57E+07 4.13E+07 3.31E+07 2.38E+07 1.57 0.81 1.59 1.31 0.90 6.31E+03 6.31E+03 6.31E+03 7.58E+03 7.58E+03 7.23E+03 7.23E+03 7.23E+03 7.23E+03 7.23E+03 7.23E+03 7.23E+03 7.23E+03 7.23E+03 4.70E+03 4.70E+03 4.70E+03 4.70E+03 4.70E+03 4.70E+03 1.45 1.29 1.42 2.56 1.64 1.63 1.42 1.54 1.55 1.47 1.29 1.47 1.49 1.53 1.78 1.33 1.55 1.14 1.19 2.09 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.89 NotFnd 14.19 14.44 14.62 16.42 16.59 16.81 NotFnd 17.23 NotFnd 19.57 19.85 20.15 17.53 19.29 19.69 19.88 NotFnd 20.11 J J J EMPC J B J C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 1.0011 1.0011 1.0011 1.0135 1.0010 1.0111 1.0249 1.0507 0.9721 0.9856 1.0007 1.0010 1.1020 1.1245 1.1355 1.1486 0 +0.1 0 0 0 0 0 +0.2 0 -1.2 -0.1 0 +0.6 +0.1 +0.1 +0.1 Page 2 of 5 NON-EMPC 31.9 467 4,690 11,100 4,740 1,400 455 90.5 64.6 6.79E+05 0.00E+00 2.13E+05 3.63E+06 2.37E+05 3.24E+05 1.79E+05 1.25E+06 0.00E+00 5.84E+06 0.00E+00 1.06E+06 4.71E+05 4.09E+06 2.27E+06 2.71E+07 7.97E+06 1.75E+06 0.00E+00 6.08E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 31.9 475 4,690 11,100 4,740 1,420 459 105 64.6 3.01 2.89 1.58 1.51 1.30 SI 1.42 1.63 1.49 SI 1.70 1.07 1.04 1.07 1.04 1.08 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 1.44 2.04 1.83 1.29 1.05 0.933 0.869 1.02 2.53 25.1 ND 6.72 169 7.09 7.97 3.84 29 ND 130 ND 23.5 10.6 94.6 103 918 316 51 ND 324 Printed: 3/31/2014 7:04 PM 102 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.59 21.74 NotFnd 22.15 22.37 22.65 22.92 23.14 23.49 NotFnd NotFnd NotFnd 26.12 26.48 20.44 22.40 23.02 23.09 23.29 24.55 24.67 24.77 24.99 25.25 25.44 25.73 25.91 26.24 26.34 26.53 27.25 27.51 27.88 28.09 28.24 28.47 28.76 29.04 NotFnd 29.62 29.81 NotFnd 31.47 NotFnd NotFnd 25.73 27.42 27.61 SGS Evironmental Services QC J C C C J C J EMPC C C C C J J J C J J J Pred RRT Actual RRT Diff Secs 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1761 0.8216 0.8372 0.8456 0.8560 0.8664 0.8745 0.8878 0.9871 1.0009 1.0011 0.9134 0.9385 0.9416 0.9498 1.0009 1.0059 1.0101 1.0189 1.0296 1.0374 1.0493 1.0564 1.0700 1.0739 1.0820 0.8434 0.8514 0.8629 0.8693 0.8741 0.8811 0.8903 0.8987 0.9168 0.9228 0.9741 1.0134 0.8988 0.9051 +0.2 -0.3 -1.3 -0.1 -0.3 -0.7 +1.0 -0.1 0 +0.3 +0.1 -1.5 0 +0.3 -0.1 0 -0.4 +0.1 +1.2 0 -1.5 -0.6 +0.2 0 +0.2 +0.2 -0.2 0 -0.2 +0.2 0 0 +0.3 -0.2 0 0 +0.8 0 -0.2 0 Page 3 of 5 Response Ra RRF Conc. / Recv. 1.01E+07 1.80E+05 0.00E+00 5.82E+06 2.50E+06 3.94E+07 3.56E+07 1.23E+07 9.51E+06 0.00E+00 0.00E+00 0.00E+00 4.95E+05 5.75E+06 1.47E+05 6.53E+06 5.79E+06 2.02E+06 1.95E+06 4.31E+07 6.84E+04 1.12E+06 2.61E+07 7.10E+06 3.77E+07 3.58E+06 8.09E+06 2.29E+06 1.61E+07 2.09E+07 3.26E+05 1.15E+06 1.63E+05 9.97E+04 9.06E+05 1.43E+06 6.40E+07 3.54E+07 0.00E+00 1.62E+07 7.56E+06 0.00E+00 3.14E+05 0.00E+00 0.00E+00 3.49E+05 1.59E+05 1.55E+05 1.04 1.02 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 274 4.47 ND 140 59.8 903 879 296 245 ND ND ND 12.9 162 5.71 266 261 85.3 98.3 1,790 2.15 54.2 887 295 1,470 107 367 113 658 589 9.5 32.2 4.99 3.02 25.9 38.9 1,940 1,120 ND 519 240 ND 8.84 ND ND 15.7 7.16 8.32 1.01 0.99 1.01 1.00 0.99 1.00 1.09 1.00 0.82 0.77 0.77 0.77 0.79 0.78 1.28 0.76 0.79 0.81 0.78 0.79 0.79 0.75 0.78 0.79 0.74 0.74 0.71 0.76 0.84 0.80 0.79 0.80 0.81 0.80 0.75 0.65 0.62 0.55 Noise / Recv. Low DL / Recv. High 4.70E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 6.97E+03 2.33E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 2.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 5.49E+03 1.68E+03 1.68E+03 3.20E+03 3.20E+03 1.06 1.65 1.63 1.6 1.59 1.53 1.65 1.6 1.72 1.57 1.51 1.67 1.74 1.88 0.827 1.03 1.14 1.07 1.27 1.05 0.794 1.22 0.858 1.05 0.985 0.752 1.14 1.25 1.03 0.712 1.62 1.55 1.71 1.69 1.59 1.52 1.69 1.76 1.79 1.78 1.76 1.49 1.56 1.85 0.591 0.726 1.41 1.68 Printed: 3/31/2014 7:04 PM 103 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.99 28.20 28.32 NotFnd NotFnd 28.75 28.95 29.36 NotFnd 30.02 30.53 30.94 31.04 NotFnd 31.51 32.01 32.09 32.23 NotFnd 32.51 NotFnd NotFnd 34.19 34.40 NotFnd 35.08 NotFnd NotFnd NotFnd NotFnd 30.97 NotFnd NotFnd 33.03 33.24 33.51 33.81 33.99 NotFnd 34.32 34.50 NotFnd 34.88 35.29 NotFnd 35.84 NotFnd 36.36 SGS Evironmental Services QC J C C C C C C J EMPC C J EMPC C J J C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9175 0.9243 0.9282 0.9424 0.9487 0.9624 0.9841 1.0007 1.0140 1.0174 1.0329 1.0491 1.0519 1.0564 1.0656 0.9916 0.9977 1.0091 1.0207 1.0886 1.0956 1.1043 1.1141 1.1201 1.1312 1.1372 1.1496 1.1630 0.9581 0.9722 -0.2 -0.5 0 -0.2 0 0 0 +1.5 -0.4 +0.2 +1.7 -0.8 -1.2 +0.2 0 +0.2 +0.2 0 0 0 +0.2 +0.2 -0.2 +0.4 -0.2 +0.4 +0.2 +0.4 -0.2 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.16E+07 2.47E+05 9.65E+05 0.00E+00 0.00E+00 2.97E+06 4.09E+06 4.34E+05 0.00E+00 2.24E+06 1.46E+07 6.82E+05 8.44E+06 0.00E+00 1.19E+07 3.52E+05 3.78E+06 2.03E+07 0.00E+00 2.04E+06 0.00E+00 0.00E+00 5.90E+05 1.24E+06 0.00E+00 2.71E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.09E+06 0.00E+00 0.00E+00 1.76E+06 1.00E+05 2.51E+05 4.66E+06 2.98E+05 0.00E+00 1.15E+05 8.32E+04 0.00E+00 1.84E+06 9.25E+04 0.00E+00 9.26E+05 0.00E+00 5.55E+06 0.63 0.59 0.62 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 570 12.1 46.9 ND ND 148 244 23.8 ND 114 642 44.2 367 ND 523 13.8 167 792 ND 125 ND ND 23 43.3 ND 11.4 ND ND ND ND 42.9 ND ND 96.8 4.67 13.3 247 21.4 ND 6.05 5.15 ND 111 5.21 ND 46.7 ND 234 0.61 0.61 0.66 0.63 0.62 0.62 0.61 0.61 0.57 0.63 0.62 0.60 0.57 0.61 0.66 1.21 1.23 1.00 1.28 1.28 1.29 1.48 1.22 1.27 1.14 1.20 1.31 Noise / Recv. Low DL / Recv. High 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 3.20E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.55 1.54 1.53 1.58 1.59 1.57 1.87 1.73 1.1 1.59 1.38 2.04 1.37 1.16 1.38 1.24 1.39 1.23 1.2 1.94 1.12 1.1 1.22 1.1 1.24 1.35 1.3 0.437 0.507 0.492 0.538 0.531 0.769 0.815 0.688 0.783 0.784 1.06 0.79 0.778 0.915 0.937 0.889 0.833 0.654 0.746 0.607 0.624 Printed: 3/31/2014 7:04 PM 104 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.53 36.88 37.07 37.15 37.43 NotFnd 37.77 38.51 39.29 NotFnd NotFnd 35.52 NotFnd 36.28 NotFnd 37.80 38.35 38.58 NotFnd 39.10 39.18 39.29 39.67 NotFnd 40.21 41.55 NotFnd 42.10 42.40 43.17 43.62 39.77 40.56 NotFnd NotFnd NotFnd 43.76 44.31 44.48 45.60 47.55 NotFnd 45.40 46.19 49.41 SGS Evironmental Services QC C C J EMPC J J J J C J C J EMPC J J C EMPC Pred RRT Actual RRT Diff Secs 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 0.9859 0.9910 0.9933 1.0007 1.0096 0.9643 0.9838 1.0086 1.0300 1.0733 1.0889 1.0953 1.1102 1.1126 1.1157 1.1264 1.1416 0.9080 0.9200 0.9265 0.9434 0.9532 1.0005 1.0204 1.1007 1.1146 1.1189 0.9515 0.9921 1.0004 1.0178 1.0005 -0.2 0 -0.4 -0.2 -0.9 0 +0.7 -1.2 0 0 0 +0.2 0 +0.2 +0.2 +0.2 +0.2 +0.5 +0.2 +1.8 -0.3 0 -0.3 0 +0.2 +1.3 -0.3 0 -0.3 0 -0.3 0 +0.3 Page 5 of 5 Response Ra RRF Conc. / Recv. 9.38E+05 3.80E+05 2.45E+05 5.66E+05 6.44E+06 0.00E+00 7.94E+05 1.01E+06 6.78E+04 0.00E+00 0.00E+00 4.87E+05 0.00E+00 1.28E+05 0.00E+00 1.67E+05 5.67E+04 1.32E+06 0.00E+00 6.09E+05 8.53E+04 8.39E+05 5.55E+05 0.00E+00 2.91E+05 1.53E+05 0.00E+00 2.06E+06 3.63E+04 7.56E+05 2.24E+05 1.57E+05 8.72E+04 0.00E+00 0.00E+00 0.00E+00 3.39E+05 1.61E+05 1.85E+05 1.01E+05 2.63E+05 0.00E+00 3.44E+05 3.26E+05 2.57E+05 1.27 1.27 1.18 1.40 1.25 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 54.4 24.4 12.5 24.1 335 ND 31.1 52.7 2.91 ND ND 26.2 ND 6.5 ND 12.9 3.36 73.1 ND 32.1 5.26 53.9 37.5 ND 20 10 ND 109 1.74 54 11.6 9.14 4.8 ND ND ND 28.9 13 14.6 10.2 24.5 ND 20.5 19.2 24.9 1.23 1.19 1.46 1.16 0.97 0.97 1.16 1.05 1.02 0.99 1.07 1.10 1.00 1.16 1.04 1.47 1.10 1.00 0.93 0.84 0.86 0.95 0.74 0.92 0.90 0.82 0.77 0.80 Noise / Recv. Low DL / Recv. High 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 2.19E+03 2.19E+03 2.19E+03 9.79E+02 9.79E+02 9.79E+02 9.79E+02 9.79E+02 9.79E+02 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.62E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.75E+03 1.75E+03 1.75E+03 3.04E+03 3.04E+03 3.04E+03 0.858 0.95 0.752 0.63 0.768 0.682 0.58 1.17 0.964 0.968 0.455 0.532 0.554 0.501 0.534 0.765 1.01 0.944 0.921 0.897 1.05 1.09 1.15 1.02 1.17 1.11 0.857 0.894 0.815 1.29 0.934 0.721 0.68 0.732 0.697 0.7 1.05 0.995 0.974 1.87 1.72 1.32 1.93 1.9 3.14 Printed: 3/31/2014 7:04 PM 105 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.28e7 2.64e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.48e7 7.40e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.30e7 6.48e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.20e7 1.10e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.32e7 6.60e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.85e6 1.43e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.51e6 1.26e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 645-564 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:17 Page 1 of 21 106 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 PCB-1 5.10e5 11.89 Rel. Int. 100% Abs. Int. 2.05e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.40e3 PCB-3 1.58e5 14.19 1.03e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.24e5 PCB-1 1.69e5 11.89 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 2.91e3 6.19e4 PCB-3 5.49e4 14.18 0% 11.0 12.0 13.0 ES-1 4.43e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 4.93e7 14.17 0.00e0 16.0 RT Abs. Int. 1.79e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 4.10e3 8.93e6 0% 11.0 12.0 13.0 ES-1 1.36e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 1.50e7 14.17 0.00e0 16.0 RT Abs. Int. 5.54e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.27e4 2.77e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.28e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.64e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6979, 5463 scc: 645-564 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:13 (CEM) Printed: 31-Mar-2014 19:17 Page 2 of 21 107 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 Rel. Int. 100% Abs. Int. 8.08e5 PCB-4 2.22e6 14.44 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 4.62e3 4.04e5 PCB-10 1.43e5 14.62 0% 11.0 12.0 13.0 14.0 Rel. Int. 100% 15.0 Abs. Int. 4.98e5 PCB-4 1.41e6 14.44 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.17e4 0.00e0 16.0 RT 2.49e5 PCB-10 9.43e4 14.63 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.21e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.63e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 6.80e3 3.82e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.35e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.59e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 2.52e3 2.30e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.28e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.64e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9113, 9426 scc: 645-564 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:13 (CEM) Printed: 31-Mar-2014 19:17 Page 3 of 21 108 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 PCB-8 3.62e6 17.23 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.40e3 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 Abs. Int. 1.12e6 PCB-15 2.57e6 20.15 PCB-9 1.97e5 16.42 PCB-6 7.30e5 16.81 PCB-11 6.33e5 19.57 5.62e5 13/12 2.87e5 SI 19.85 0% 17.0 19.0 20.0 21.0 PCB-8 2.22e6 17.23 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.85e4 18.0 Abs. Int. 6.43e5 PCB-15 1.51e6 20.15 PCB-9 1.52e5 16.42 PCB-6 5.15e5 16.81 3.21e5 PCB-11 4.25e5 19.57 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 5.07e7 16.40 20.0 21.0 ES-15 5.30e7 20.14 0.00e0 RT Abs. Int. 1.59e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.90e4 7.96e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 3.24e7 16.40 20.0 21.0 ES-15 3.35e7 20.14 0.00e0 RT Abs. Int. 1.02e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.06e3 5.10e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.48e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.40e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1025, 6231 scc: 645-564 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:15 (CEM) Printed: 31-Mar-2014 19:17 Page 4 of 21 109 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Rel. Int. 100% Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 Abs. Int. 3.96e6 30/18 1.38e7 19.29 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.07e3 PCB-17 4.12e6 19.69 PCB-19 1.17e6 17.53 PCB-27 8.91e5 19.88 PCB-16 3.15e6 20.11 PCB-32 5.16e6 20.59 1.98e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 3.77e6 30/18 1.33e7 19.29 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.63e3 PCB-17 3.84e6 19.69 PCB-19 1.10e6 17.52 PCB-27 8.60e5 19.88 PCB-16 2.93e6 20.11 PCB-32 4.95e6 20.59 1.88e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.02e7 17.51 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 6.16e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.09e4 3.08e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.90e7 17.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.84e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.58e4 2.92e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.48e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.40e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7267, 3995 scc: 645-564 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 15:13 Printed: 31-Mar-2014 19:17 Page 5 of 21 110 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 PCB-31 1.98e7 28/20 22.65 1.78e7 22.92 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 3.75e3 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 26/29 2.92e6 22.15 Abs. Int. 5.38e6 21/33 6.10e6 23.14 PCB-25 1.24e6 22.37 2.69e6 PCB-22 4.76e6 23.49 PCB-37 2.88e6 26.48 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 1.96e7 28/20 22.65 1.78e7 22.92 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 3.22e3 24.0 26/29 2.90e6 22.15 PCB-25 1.26e6 22.37 Abs. Int. 5.25e6 21/33 6.18e6 23.14 2.62e6 PCB-22 4.75e6 23.49 PCB-37 2.87e6 26.48 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 4.07e7 22.90 Rel. Int. 100% ES-37 3.51e7 26.46 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.51e4 Abs. Int. 1.09e7 5.43e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 3.70e7 22.90 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.20e7 26.46 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 3.60e4 Abs. Int. 9.95e6 4.97e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.30e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.48e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4194, 7893 scc: 645-564 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:15 (CEM) Printed: 31-Mar-2014 19:17 Page 6 of 21 111 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 PCB-54 6.65e4 20.44 Rel. Int. 100% Abs. Int. 1.84e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 9.67e2 9.19e3 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 8.07e4 20.44 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.03e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.36e3 1.52e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.69e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.61e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 5.99e3 2.31e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.21e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.95e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 5.40e3 2.97e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.48e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.40e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8566, 6959 scc: 645-564 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:25 (CEM) Printed: 31-Mar-2014 19:17 Page 7 of 21 112 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 PCB-52 1.89e7 24.55 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.28e3 69/49 1.15e7 24.99 50/53 2.83e6 22.40 PCB-45 2.53e6 23.02 44/47… 1.66e7 25.44 PCB-48 3.17e6 25.25 PCB-51 8.81e5 23.09 Abs. Int. 5.12e6 PCB-42 3.57e6 25.91 59/62… 1.58e6 25.73 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 2.42e7 24.55 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.21e3 69/49 1.46e7 24.99 50/53 3.70e6 22.40 PCB-45 3.26e6 23.02 Abs. Int. 6.52e6 44/47… 2.12e7 25.44 PCB-42 4.52e6 25.91 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.05e7 24.52 Rel. Int. 100% 2.56e6 0.00e0 RT 26.0 PCB-48 3.93e6 25.25 PCB-51 1.14e6 23.09 PCB-64 9.19e6 26.53 PCB-41 9.80e5 26.24 0% 22.0 71/40 7.08e6 26.34 71/40 9.04e6 26.34 PCB-64 1.17e7 26.53 3.26e6 0.00e0 RT Abs. Int. 5.32e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.12e4 2.66e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.52e7 24.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.43e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.12e4 3.22e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.30e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.48e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6869, 3305 scc: 645-564 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:25 (CEM) Printed: 31-Mar-2014 19:17 Page 8 of 21 113 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 Abs. Int. 4.99e6 61/70... PCB-66 2.83e7 1.57e7 28.76 29.04 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 3.20e3 PCB-56 7.24e6 29.62 PCB-60 3.35e6 29.81 2.50e6 PCB-77 1.18e6 32.80 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 6.40e6 61/70... 3.57e7 PCB-66 28.76 1.97e7 29.04 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.29e3 PCB-56 8.99e6 29.62 PCB-60 4.21e6 29.81 3.20e6 PCB-77 1.48e6 32.80 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.45e7 32.31 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.61e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 6.35e6 ES-77 2.53e7 32.79 3.17e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.08e7 32.31 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.20e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.63e6 ES-77 3.13e7 32.79 3.82e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.20e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.10e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1788, 0342 scc: 645-564 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:19 (CEM) Printed: 31-Mar-2014 19:17 Page 9 of 21 114 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 PCB-96 1.38e5 25.73 Rel. Int. 100% Abs. Int. 3.79e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 8.61e2 1.90e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 2.11e5 25.73 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.70e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 8.15e2 2.85e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.38e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.20e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.34e3 3.10e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.50e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.91e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.43e3 1.95e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.30e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.48e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4422, 5307 scc: 645-564 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:19 (CEM) Printed: 31-Mar-2014 19:17 Page 10 of 21 115 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.48e3 PCB-95 4.46e6 27.99 0% 113/90… 5.62e6 30.53 PCB-91 1.13e6 28.75 PCB-84 1.56e6 PCB-102 28.95 3.71e5 28.32 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.72e3 PCB-91 1.84e6 28.75 PCB-84 2.54e6 28.94 Abs. Int. 1.86e6 PCB-118 5.24e6 34.78 PCB-82 7.60e5 32.51 32.0 113/90… 8.99e6 30.53 PCB-95 7.11e6 27.99 PCB-110 7.77e6 32.23 PCB-99 3.20e6108/119... 31.04 4.51e6 116/85 31.51 1.46e6 32.09 PCB-92 8.65e5 30.02 PCB-105 2.69e6 35.79 PCB-109 4.71e5 34.40 34.0 36.0 9.30e5 38.0 PCB-110 1.26e7 32.23 PCB-99 5.25e6108/119... 31.04 7.42e6 116/85 31.51 2.32e6 32.10 PCB-92 1.38e6 30.02 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 Abs. Int. 3.07e6 PCB-118 8.53e6 34.78 PCB-82 1.28e6 32.51 PCB-109 7.66e5 34.40 PCB-105 4.39e6 35.79 1.53e6 0% 28.0 30.0 Rel. Int. 100% 32.0 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.22e3 34.0 CS/SS-111 3.20e7 32.80 JS-101 2.54e7 30.51 0.00e0 RT ES-118 ES-114 ES-123 2.94e7 3.00e7 2.93e7 34.76 35.23 34.48 36.0 38.0 0.00e0 RT Abs. Int. 8.25e6 ES-105 2.98e7 35.77 4.12e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 2.00e7 32.80 JS-101 1.59e7 30.51 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 1.65e3 34.0 ES-118 ES-114 ES-123 1.79e7 1.82e7 1.84e7 34.76 35.23 34.48 36.0 38.0 0.00e0 RT Abs. Int. 5.04e6 ES-105 1.87e7 35.77 2.52e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.20e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.10e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1760, 5448 scc: 645-564 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:20 (CEM) Printed: 31-Mar-2014 19:17 Page 11 of 21 116 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 Rel. Int. 100% Abs. Int. 7.08e4 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 8.37e2 3.54e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 1.55e5 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.38e3 7.77e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.92e6 ES-126 2.48e7 38.38 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 4.35e3 2.96e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.98e6 ES-126 1.63e7 38.38 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 4.85e3 1.99e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.32e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.60e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9051, 5481 scc: 645-564 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 15:13 Printed: 31-Mar-2014 19:17 Page 12 of 21 117 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Rel. Int. 100% Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 153/168 3.14e6 36.36 147/149 2.61e6 33.81 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 7.12e2 PCB-136 5.96e5 30.97 PCB-132 1.03e6 34.88 151/135 9.69e5 33.03 163/138… 3.58e6 37.43 Abs. Int. 8.44e5 PCB-141 PCB-164 PCB-158 5.25e5 4.38e5 3.30e5 36.53 37.77 37.15 PCB-146 5.05e5 35.84 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% 36.0 153/168 2.41e6 36.36 147/149 2.04e6 33.80 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 6.94e2 PCB-136 4.93e5 30.97 38.0 PCB-132 8.12e5 34.88 151/135 7.87e5 33.03 163/138… 2.86e6 37.43 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.85e7 30.34 Rel. Int. 100% ES-153 1.97e7 36.34 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.20e3 0.00e0 RT Abs. Int. 6.64e5 PCB-141 PCB-158 4.13e5 PCB-164 3.55e5 2.36e5 36.53 37.77 37.15 PCB-146 4.20e5 35.84 4.22e5 3.32e5 0.00e0 RT Abs. Int. 7.33e6 JS-138 1.87e7 37.41 3.66e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.21e7 30.34 Rel. Int. 100% ES-153 1.53e7 36.34 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.63e3 0.00e0 RT Abs. Int. 5.72e6 JS-138 1.44e7 37.41 2.86e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.20e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.10e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1206, 8203 scc: 645-564 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:23 (CEM) Printed: 31-Mar-2014 19:17 Page 13 of 21 118 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 128/166 5.52e5 38.51 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 Abs. Int. 1.20e5 156/157 4.30e5 40.93 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 1.01e3 PCB-159 4.41e4 39.29 PCB-167 1.56e5 39.96 5.99e4 0% 39.0 Rel. Int. 100% 40.0 128/166 4.62e5 38.51 41.0 42.0 43.0 44.0 45.0 Abs. Int. 9.96e4 156/157 3.52e5 40.93 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 1.17e3 PCB-159 3.01e4 39.29 PCB-167 1.19e5 39.96 4.98e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.46e7 39.94 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 5.99e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.63e7 40.92 0.00e0 RT Abs. Int. 8.58e6 ES-169 2.14e7 43.64 4.29e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.97e7 39.94 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 6.30e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.67e7 40.92 0.00e0 RT Abs. Int. 6.58e6 ES-169 1.70e7 43.64 3.29e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.32e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.60e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4702, 3708 scc: 645-564 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:23 (CEM) Printed: 31-Mar-2014 19:17 Page 14 of 21 119 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 PCB-179 2.62e5 35.52 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 5.33e2 Abs. Int. 6.79e4 PCB-178 8.23e4 37.80 PCB-176 6.32e4 36.28 3.39e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 2.25e5 35.52 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 4.46e2 Abs. Int. 5.64e4 PCB-178 8.47e4 37.80 PCB-176 6.51e4 36.28 2.82e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.84e7 35.22 Rel. Int. 100% CS/SS-178 1.17e7 37.78 2.27e6 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.66e7 35.22 Rel. Int. 100% CS/SS-178 1.09e7 37.78 2.10e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 4.20e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.42e3 31.0 0.00e0 RT Abs. Int. 4.55e6 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.38e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.20e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.10e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5618, 5193 scc: 645-564 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:23 (CEM) Printed: 31-Mar-2014 19:17 Page 15 of 21 120 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 180/193 1.05e6 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 7.24e2 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 PCB-187 6.74e5 38.58 PCB-174 4.33e5 PCB-177 PCB-183 39.29 2.91e5 3.08e5 39.67 39.10 PCB-185 4.25e4 39.18 171/173 1.46e5 40.21 Abs. Int. 2.65e5 PCB-170 3.96e5 43.17 PCB-172 8.21e4 41.55 1.32e5 PCB-190 1.12e5 43.62 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 1.01e6 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 8.92e2 43.0 PCB-187 6.43e5 38.58 PCB-174 PCB-183 4.06e5 PCB-177 3.01e5 39.29 2.64e5 39.10 39.67 171/173 1.46e5 40.20 Abs. Int. 2.21e5 PCB-170 3.61e5 43.17 PCB-172 7.09e4 41.55 1.10e5 PCB-190 1.12e5 43.62 0% 39.0 40.0 41.0 42.0 ES-180 1.64e7 42.09 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 3.60e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.90e6 ES-170 1.34e7 43.15 1.95e6 0% 39.0 40.0 41.0 42.0 ES-180 1.51e7 42.09 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 1.24e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.71e6 ES-170 1.23e7 43.15 1.86e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.32e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.60e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0932, 7724 scc: 645-564 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:24 (CEM) Printed: 31-Mar-2014 19:17 Page 16 of 21 121 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 PCB-189 2.04e4 45.78 Abs. Int. 6.16e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 8.19e2 3.08e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.86e4 45.78 Abs. Int. 6.93e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 8.32e2 3.47e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.90e7 45.76 0.00e0 RT Abs. Int. 4.45e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 2.87e3 2.23e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.82e7 45.76 0.00e0 RT Abs. Int. 4.29e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 3.70e3 2.14e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.85e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.43e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1886, 0810 scc: 645-564 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:24 (CEM) Printed: 31-Mar-2014 19:17 Page 17 of 21 122 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 198/199 1.57e5 43.76 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 5.37e2 PCB-202 7.54e4 39.77 Abs. Int. 3.98e4 PCB-196 7.85e4 44.31 PCB-201 3.97e4 40.56 PCB-203 8.69e4 44.48 1.99e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 1.82e5 43.76 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.46e2 PCB-202 8.12e4 39.77 Abs. Int. 4.04e4 PCB-196 8.25e4 44.32 PCB-201 4.75e4 40.56 PCB-203 1.17e5 44.48 2.02e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.56e7 39.75 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 3.75e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.48e3 1.87e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.76e7 39.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.29e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.53e3 2.14e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.32e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.60e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6245, 9911 scc: 645-564 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:24 (CEM) Printed: 31-Mar-2014 19:18 Page 18 of 21 123 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 PCB-194 1.24e5 47.55 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 7.35e2 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 Abs. Int. 2.90e4 PCB-195 4.84e4 45.60 1.45e4 0% 46.0 47.0 49.0 50.0 PCB-194 1.38e5 47.54 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 1.01e3 48.0 0.00e0 RT Abs. Int. 3.66e4 PCB-195 5.28e4 45.60 1.83e4 0% 46.0 47.0 48.0 JS-194 1.13e7 47.53 Rel. Int. 100% 49.0 50.0 ES-205 1.28e7 47.92 0.00e0 RT Abs. Int. 3.03e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.65e3 1.51e6 0% 46.0 47.0 48.0 JS-194 1.25e7 47.53 Rel. Int. 100% 49.0 50.0 ES-205 1.41e7 47.92 0.00e0 RT Abs. Int. 3.29e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.75e3 1.64e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.85e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.43e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7274, 1405 scc: 645-564 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:24 (CEM) Printed: 31-Mar-2014 19:18 Page 19 of 21 124 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 PCB-207 1.41e5 46.19 PCB-208 1.55e5 45.40 Abs. Int. 3.92e4 PCB-206 1.15e5 49.41 NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 7.89e2 1.96e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 PCB-207 1.85e5 46.18 PCB-208 1.89e5 45.40 50.0 Abs. Int. 4.70e4 PCB-206 1.42e5 49.41 NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.25e3 2.35e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.17e6 ES-208 1.35e7 45.38 ES-206 8.42e6 49.39 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.35e3 1.59e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 1.70e7 45.38 50.0 Abs. Int. 3.98e6 ES-206 1.05e7 49.39 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.89e3 0.00e0 RT 1.99e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.85e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.43e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8915, 8378 scc: 645-564 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:25 (CEM) Printed: 31-Mar-2014 19:18 Page 20 of 21 125 of 711 SGS-AP ID: A6504_11892_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB031.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 35 Acq: 26-Mar-2014 22:57:34 User: LKB Datafile: 140326X10 PCB-209 4.02e6 50.84 Rel. Int. 100% Abs. Int. 8.45e5 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 4.79e2 4.22e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 3.41e6 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.40e5 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 9.44e2 3.70e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.28e7 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.82e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 7.83e2 1.41e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.07e7 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.34e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 8.34e2 1.17e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.51e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.26e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_002.utp_res, saved 31-Mar-2014 15:25 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7399, 7818 scc: 645-564 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 15:13 Printed: 31-Mar-2014 19:18 Page 21 of 21 126 of 711 Lab ID: A6504_11892_PCB_003 ACQ: 26-Mar-2014 23:52:48 LKB Wt/Vol: 0.97 L Client ID: PB047.3-1SWMID-140313-N (TOTAL) UTP: 31-Mar-2014 16:04 CEM J-level: 10.3 pg/L Datafile: 140326X11 RPT: 31-Mar-2014 18:58 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.80 NotFnd 35.79 35.24 34.78 34.50 NotFnd 40.93 39.96 NotFnd 45.78 50.84 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.88 14.17 14.42 20.13 17.51 26.46 20.42 32.78 32.31 25.39 35.76 35.22 34.76 34.48 38.37 36.34 30.34 40.92 39.94 43.64 43.15 42.08 35.22 45.76 39.75 47.92 49.39 45.38 50.82 QC J J J C J J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0006 1.0005 1.0006 1.0007 1.0002 1.0007 1.0005 1.0004 0 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7243 0.8639 0.8793 1.2276 1.0674 1.0789 0.8326 1.3369 1.3175 0.8322 1.1723 1.1545 1.1393 1.1301 1.2578 0.9716 0.8112 1.0940 1.0678 1.1666 0.9080 0.8855 0.7410 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Split: 1 Checkcode: 786-548-GYQ Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.81 +0.3 0 1.13E+06 0.00E+00 2.83E+06 1.71E+05 5.70E+06 1.67E+05 0.00E+00 3.49E+05 1.33E+05 0.00E+00 2.76E+04 2.18E+06 0.95 1.17 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 43.7 ND 134 7.32 256 7.24 ND 18.9 6.35 ND 1.75 223 4.87E+03 4.87E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 1.84E+03 1.69E+03 1.69E+03 1.69E+03 1.67E+03 1.25E+03 2.05 1.88 1.34 1.23 1.28 1.25 1.03 1.3 0.856 1.03 1.13 1.54 -0.1 0 -0.1 +0.4 +0.1 +0.2 -0.2 +0.6 +0.6 -0.3 +0.4 +0.2 +0.2 +0.2 +0.2 0 -0.2 0 +0.2 0 0 0 -0.2 0 0 0 0 0 0 4.91E+07 5.31E+07 2.96E+07 7.15E+07 3.26E+07 5.52E+07 3.20E+07 4.63E+07 4.59E+07 3.19E+07 3.92E+07 4.01E+07 3.85E+07 3.91E+07 3.43E+07 2.92E+07 4.12E+07 6.92E+07 3.70E+07 3.20E+07 2.12E+07 2.59E+07 2.88E+07 3.03E+07 2.70E+07 2.16E+07 1.52E+07 2.50E+07 1.80E+07 3.34 3.34 1.58 1.58 1.07 1.09 0.77 0.80 0.82 1.63 1.56 1.61 1.56 1.61 1.56 1.25 1.28 1.26 1.23 1.26 1.08 1.12 1.08 1.04 0.92 0.87 0.79 0.78 1.20 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% -0.2 -0.2 0 0 -0.7 +0.2 Page 1 of 5 0.61 0.63 0.63 0.61 1.13 1.07 57.4 68.1 78.9 95.8 89.8 84.5 94.4 85.1 85.4 109 89.8 90.5 91.4 90.8 91.8 92.3 91.8 76.6 78.6 72.9 91.4 93.1 109 93.2 98.8 84.4 89.2 104 79.3 % % % % % % % % % % % % % % % % % % % % % % % % % % % % % Printed: 3/31/2014 7:04 PM 127 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 6.27E+07 4.22E+07 1.78E+07 1.10 1.61 1.04 1.11 1.03 0.62 102 % 105 % 99.9 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 6.27E+07 4.22E+07 1.78E+07 1.10 1.61 1.04 1.85 1.22 0.58 86.3 % 95 % 108 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.40 24.52 30.51 37.40 47.52 7.18E+07 3.93E+07 3.63E+07 2.82E+07 2.05E+07 1.55 0.80 1.60 1.29 0.92 6.10E+03 6.10E+03 6.10E+03 6.11E+03 6.11E+03 6.51E+03 6.51E+03 6.51E+03 6.51E+03 6.51E+03 6.51E+03 6.51E+03 6.51E+03 6.51E+03 4.85E+03 4.85E+03 4.85E+03 4.85E+03 4.85E+03 4.85E+03 1.74 1.52 1.68 2.53 1.63 1.71 1.49 1.62 1.62 1.54 1.35 1.54 1.56 1.61 2.24 1.67 1.95 1.43 1.5 2.62 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.89 14.00 14.18 14.44 14.62 16.42 NotFnd 16.81 NotFnd 17.23 NotFnd 19.57 19.84 20.15 17.52 19.29 19.68 19.88 NotFnd 20.11 J EMPC J J J EMPC EMPC B EMPC J C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 1.0011 0.9881 1.0010 1.0011 1.0138 1.0011 1.0250 1.0507 0.9721 0.9855 1.0007 1.0010 1.1019 1.1245 1.1354 1.1487 0 +0.1 0 0 +0.3 +0.1 +0.1 +0.2 0 -1.3 -0.1 0 +0.5 +0.1 0 +0.2 Page 2 of 5 NON-EMPC 25.9 231 2,020 5,520 2,540 796 276 41.3 28.6 4.05E+05 1.10E+05 2.10E+05 1.77E+06 1.47E+05 1.44E+05 0.00E+00 4.32E+05 0.00E+00 2.16E+06 0.00E+00 6.95E+05 2.74E+05 2.09E+06 1.04E+06 9.02E+06 2.93E+06 6.97E+05 0.00E+00 2.04E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 29.7 266 2,020 5,520 2,550 817 276 63.9 28.6 3.24 2.45 3.28 1.64 SI 0.97 1.21 1.51 1.86 SI 1.56 1.09 1.03 1.06 1.11 1.06 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 1.71 2.07 2.06 1.51 1.12 0.918 1.2 1.13 2.82 17.8 3.83 8.08 100 5.33 4.31 ND 12.3 ND 58.6 ND 18.8 7.53 58.9 57.3 370 140 24.5 ND 131 Printed: 3/31/2014 7:04 PM 128 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.59 21.74 NotFnd 22.15 22.37 22.65 22.92 23.14 23.49 NotFnd 25.24 NotFnd 26.11 26.48 20.43 22.40 23.01 23.08 23.29 24.54 24.68 24.77 24.98 25.25 25.44 25.73 25.90 26.23 26.33 26.53 27.25 27.50 27.87 NotFnd 28.24 28.46 28.76 29.03 29.18 29.62 29.81 NotFnd 31.46 NotFnd NotFnd 25.73 27.42 27.61 SGS Evironmental Services QC J C C C J J J C J C C C C J J C J J EMPC J J EMPC J Pred RRT Actual RRT Diff Secs 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1760 0.8216 0.8371 0.8456 0.8560 0.8664 0.8745 0.8879 0.9540 0.9870 1.0009 1.0009 0.9134 0.9384 0.9413 0.9498 1.0009 1.0064 1.0101 1.0189 1.0296 1.0374 1.0493 1.0564 1.0698 1.0739 1.0820 0.8433 0.8514 0.8628 0.8741 0.8811 0.8902 0.8987 0.9032 0.9167 0.9228 0.9739 1.0133 0.8989 0.9051 +0.1 -0.3 -1.5 -0.1 -0.3 -0.7 +1.0 0 +2.7 -0.2 +0.3 -0.1 -1.5 -0.1 -0.1 -0.1 0 +0.3 +0.1 +1.2 0 -1.5 -0.6 +0.2 -0.3 +0.2 +0.2 -0.3 0 -0.3 0 0 +0.2 -0.2 -0.2 -0.2 0 +0.4 -0.2 0 0 Page 3 of 5 Response Ra RRF Conc. / Recv. 3.75E+06 7.31E+04 0.00E+00 2.14E+06 9.37E+05 1.39E+07 1.31E+07 3.70E+06 3.27E+06 0.00E+00 1.48E+05 0.00E+00 2.30E+05 2.07E+06 8.16E+04 2.85E+06 2.14E+06 9.33E+05 8.48E+05 1.81E+07 6.98E+04 4.60E+05 1.11E+07 2.77E+06 1.63E+07 1.43E+06 3.35E+06 7.34E+05 6.66E+06 8.45E+06 1.38E+05 3.90E+05 6.09E+04 0.00E+00 3.42E+05 5.61E+05 2.59E+07 1.41E+07 1.31E+05 6.49E+06 2.76E+06 0.00E+00 1.18E+05 0.00E+00 0.00E+00 1.74E+05 8.10E+04 8.55E+04 1.07 0.92 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 123 2.22 ND 63 27.4 390 397 109 103 ND 4.11 ND 7.35 71.5 3.89 141 117 47.8 51.9 912 2.66 27 456 139 770 51.6 184 44.1 330 289 4.88 13.2 2.26 ND 11.9 18.5 953 541 5.1 252 106 ND 4.02 ND ND 9.67 4.47 5.62 0.98 0.95 1.01 1.01 1.03 0.99 0.99 0.95 1.02 0.76 0.78 0.77 0.80 0.81 0.78 0.84 0.80 0.80 0.79 0.78 0.77 0.78 0.77 0.79 0.79 0.80 0.73 0.81 0.82 0.81 0.80 0.78 0.87 0.80 0.83 0.93 0.62 0.79 0.66 Noise / Recv. Low DL / Recv. High 4.85E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 2.34E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 2.81E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 4.87E+03 1.40E+03 1.40E+03 2.78E+03 2.78E+03 1.34 1.66 1.63 1.61 1.6 1.53 1.65 1.61 1.72 1.57 1.52 1.68 1.74 1.89 0.935 1.34 1.48 1.39 1.66 1.36 1.03 1.59 1.12 1.37 1.28 0.979 1.49 1.63 1.34 0.927 1.66 1.59 1.75 1.73 1.63 1.55 1.73 1.8 1.83 1.82 1.81 1.53 1.6 1.9 0.593 0.728 1.59 1.89 Printed: 3/31/2014 7:04 PM 129 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.99 NotFnd 28.32 NotFnd NotFnd 28.75 28.94 29.36 NotFnd 30.02 30.53 30.93 31.04 NotFnd 31.51 NotFnd 32.09 32.23 NotFnd 32.51 NotFnd NotFnd 34.19 34.39 NotFnd 35.07 NotFnd NotFnd NotFnd NotFnd 30.97 NotFnd NotFnd 33.03 33.24 33.51 33.80 33.98 NotFnd 34.32 34.49 NotFnd 34.88 35.28 NotFnd 35.84 NotFnd 36.36 SGS Evironmental Services QC C C C C J C J EMPC C J J C J EMPC J C J J C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9175 0.9281 0.9424 0.9487 0.9624 0.9840 1.0007 1.0138 1.0174 1.0329 1.0518 1.0564 1.0657 0.9916 0.9976 1.0089 1.0207 1.0885 1.0956 1.1043 1.1141 1.1201 1.1313 1.1368 1.1496 1.1627 0.9581 0.9722 -0.2 -0.2 -0.2 0 0 -0.2 +1.5 -0.7 +0.2 +1.7 -1.3 +0.2 +0.2 +0.2 0 -0.4 0 -0.2 +0.2 +0.2 -0.2 +0.4 0 -0.4 +0.2 -0.2 -0.2 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 5.35E+06 0.00E+00 3.94E+05 0.00E+00 0.00E+00 1.37E+06 1.90E+06 1.84E+05 0.00E+00 1.07E+06 6.50E+06 2.47E+05 3.75E+06 0.00E+00 5.19E+06 0.00E+00 1.81E+06 8.75E+06 0.00E+00 8.45E+05 0.00E+00 0.00E+00 2.65E+05 5.30E+05 0.00E+00 9.65E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.21E+05 0.00E+00 0.00E+00 8.63E+05 5.67E+04 1.25E+05 2.28E+06 1.16E+05 0.00E+00 6.46E+04 4.29E+04 0.00E+00 8.72E+05 4.97E+04 0.00E+00 4.72E+05 0.00E+00 2.74E+06 0.63 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 324 ND 23.6 ND ND 84.3 139 12.4 ND 66.7 352 19.7 200 ND 280 ND 98.2 419 ND 64 ND ND 12.7 22.8 ND 4.91 ND ND ND ND 25.4 ND ND 57.5 3.18 8.03 146 10 ND 4.1 3.21 ND 63.4 3.38 ND 28.8 ND 140 0.65 0.62 0.65 0.63 0.60 0.62 0.60 0.62 0.60 0.64 0.59 0.61 0.71 0.60 0.77 1.35 1.33 1.16 1.25 1.35 1.51 1.35 1.29 1.26 1.19 1.40 1.26 Noise / Recv. Low DL / Recv. High 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 2.78E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.74 1.73 1.72 1.77 1.79 1.76 2.1 1.94 1.24 1.79 1.55 2.29 1.54 1.31 1.55 1.39 1.56 1.38 1.35 2.18 1.26 1.24 1.37 1.24 1.4 1.47 1.4 0.488 0.565 0.549 0.6 0.592 0.79 0.838 0.707 0.805 0.807 1.09 0.812 0.8 0.941 0.963 0.914 0.856 0.673 0.767 0.624 0.642 Printed: 3/31/2014 7:04 PM 130 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.53 36.88 37.07 37.15 37.43 NotFnd 37.76 38.51 NotFnd NotFnd NotFnd 35.52 NotFnd 36.27 NotFnd 37.80 NotFnd 38.57 NotFnd 39.10 39.18 39.29 39.67 NotFnd 40.21 41.54 NotFnd 42.10 42.39 43.17 43.62 39.78 40.56 NotFnd NotFnd NotFnd 43.75 44.31 44.48 45.60 47.54 NotFnd 45.40 46.18 49.41 SGS Evironmental Services QC EMPC J C C J J J J C J C J J J J J C J J EMPC J EMPC J J Pred RRT Actual RRT Diff Secs 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 0.9859 0.9910 0.9933 1.0007 1.0095 0.9643 1.0086 1.0300 1.0734 1.0953 1.1102 1.1127 1.1157 1.1264 1.1417 0.9079 0.9200 0.9264 0.9434 0.9532 1.0006 1.0203 1.1006 1.1148 1.1190 0.9515 0.9921 1.0004 1.0178 1.0005 -0.2 0 -0.4 -0.2 -0.9 -0.2 +0.7 0 0 +0.2 0 +0.2 +0.5 +0.2 +0.2 +0.7 0 +1.8 -0.5 0 -0.3 +0.2 0 +1.0 +0.3 +0.3 -0.3 0 -0.3 0 +0.3 Page 5 of 5 Response Ra RRF Conc. / Recv. 4.24E+05 1.51E+05 1.10E+05 2.51E+05 3.04E+06 0.00E+00 3.55E+05 4.86E+05 0.00E+00 0.00E+00 0.00E+00 2.51E+05 0.00E+00 7.30E+04 0.00E+00 8.56E+04 0.00E+00 6.62E+05 0.00E+00 3.07E+05 3.87E+04 3.93E+05 2.75E+05 0.00E+00 1.42E+05 7.89E+04 0.00E+00 1.05E+06 2.16E+04 3.46E+05 1.01E+05 6.34E+04 4.16E+04 0.00E+00 0.00E+00 0.00E+00 1.88E+05 7.85E+04 8.83E+04 4.88E+04 1.19E+05 0.00E+00 1.14E+05 1.09E+05 1.01E+05 1.21 1.46 1.20 1.22 1.24 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 29.7 11.7 6.78 12.9 191 ND 16.8 30.6 ND ND ND 16.5 ND 4.53 ND 8.13 ND 45.1 ND 19.9 2.92 31 22.8 ND 12 6.34 ND 67.7 1.27 30.1 6.33 4.58 2.84 ND ND ND 19.8 7.84 8.63 6.21 14 ND 8.41 7.92 12.3 1.12 1.18 1.04 1.05 0.89 1.05 1.06 1.03 0.96 1.10 0.99 1.04 1.06 1.03 1.00 0.95 0.83 0.83 0.94 0.86 1.07 0.99 1.07 0.85 0.75 0.90 Noise / Recv. Low DL / Recv. High 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.23E+03 1.69E+03 1.69E+03 1.69E+03 1.04E+03 1.04E+03 1.04E+03 1.04E+03 1.04E+03 1.04E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.43E+03 1.43E+03 1.43E+03 2.73E+03 2.73E+03 2.73E+03 0.882 0.977 0.773 0.648 0.79 0.701 0.596 1.12 0.926 0.93 0.585 0.684 0.713 0.645 0.688 0.985 1.47 1.38 1.34 1.31 1.53 1.59 1.68 1.49 1.7 1.62 1.25 1.3 1.19 1.81 1.31 0.904 0.853 0.917 0.874 0.877 1.32 1.25 1.22 1.91 1.77 1.35 2.08 2.05 3.57 Printed: 3/31/2014 7:04 PM 131 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.28e7 2.64e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.50e7 7.51e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.35e7 6.73e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.23e7 1.11e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.35e7 6.73e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.73e6 1.36e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.42e6 1.21e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 786-548 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:18 Page 1 of 21 132 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-1 3.09e5 11.89 Rel. Int. 100% Abs. Int. 1.23e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.74e3 PCB-3 1.61e5 14.18 PCB-2 8.36e4 14.00 6.16e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.24e5 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.36e3 PCB-1 9.54e4 11.89 6.19e4 PCB-3 4.91e4 14.18 PCB-2 3.40e4 13.99 0% 11.0 12.0 13.0 ES-1 3.78e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 4.08e7 14.17 0.00e0 16.0 RT Abs. Int. 1.46e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.90e3 7.30e6 0% 11.0 12.0 13.0 ES-1 1.13e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 1.22e7 14.17 0.00e0 16.0 RT Abs. Int. 4.52e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.87e4 2.26e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.28e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.64e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4816, 0882 scc: 786-548 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:39 (CEM) Printed: 31-Mar-2014 19:18 Page 2 of 21 133 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 Rel. Int. 100% Abs. Int. 3.86e5 PCB-4 1.10e6 14.44 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 3.72e3 1.93e5 PCB-10 8.94e4 SI 14.62 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 6.71e5 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.42e5 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.34e4 1.21e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.81e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.18e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 6.75e3 3.09e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.15e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.12e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.38e3 2.06e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.28e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.64e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0118, 5051 scc: 786-548 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:26 (CEM) Printed: 31-Mar-2014 19:18 Page 3 of 21 134 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 PCB-8 1.30e6 17.23 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 3.97e3 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-9 8.75e4 16.42 Abs. Int. 3.80e5 PCB-15 1.27e6 20.15 PCB-11 5.04e5 19.57 PCB-6 2.63e5 16.81 1.90e5 13/12 1.67e5 SI 19.84 0% 17.0 19.0 20.0 PCB-8 8.61e5 17.23 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.62e4 18.0 PCB-9 8.99e4 16.42 21.0 Abs. Int. 2.64e5 PCB-15 8.15e5 20.15 PCB-11 2.71e5 19.57 PCB-6 2.18e5 16.81 1.32e5 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 4.37e7 16.40 20.0 21.0 ES-15 4.38e7 20.13 0.00e0 RT Abs. Int. 1.39e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.85e4 6.97e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 2.81e7 16.40 20.0 21.0 ES-15 2.77e7 20.13 0.00e0 RT Abs. Int. 8.93e6 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.47e3 4.46e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.50e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.51e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0795, 3498 scc: 786-548 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:46 (CEM) Printed: 31-Mar-2014 19:18 Page 4 of 21 135 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Rel. Int. 100% Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 Abs. Int. 1.36e6 30/18 4.57e6 19.29 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.28e3 PCB-17 1.51e6 19.68 PCB-19 5.42e5 17.52 PCB-27 3.67e5 19.88 PCB-16 1.05e6 20.11 PCB-32 1.94e6 20.59 6.81e5 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 1.35e6 30/18 4.45e6 19.29 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.57e3 PCB-17 1.42e6 19.68 PCB-19 4.98e5 17.52 PCB-27 3.30e5 19.88 PCB-16 9.91e5 20.11 PCB-32 1.81e6 20.59 6.74e5 0% 17.0 Rel. Int. 100% 18.0 19.0 0.00e0 RT 20.0 21.0 0.00e0 RT Abs. Int. 6.10e6 ES-19 1.68e7 17.51 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 5.04e4 3.05e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.58e7 17.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.86e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 3.22e4 2.43e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.50e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.51e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1185, 7855 scc: 786-548 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:40 (CEM) Printed: 31-Mar-2014 19:18 Page 5 of 21 136 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 PCB-31 7.00e6 28/20 22.65 6.58e6 22.92 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 3.05e3 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 26/29 1.06e6 22.15 Abs. Int. 1.96e6 21/33 1.87e6 23.14 PCB-25 4.57e5 22.37 9.82e5 PCB-22 1.62e6 23.49 PCB-37 1.04e6 26.48 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 6.91e6 28/20 22.65 6.54e6 22.92 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.69e3 24.0 26/29 1.08e6 22.15 PCB-25 4.80e5 22.37 Abs. Int. 1.92e6 21/33 1.82e6 23.13 9.59e5 PCB-22 1.64e6 23.49 PCB-37 1.02e6 26.48 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 3.28e7 22.90 Rel. Int. 100% ES-37 2.87e7 26.46 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.47e4 Abs. Int. 8.82e6 4.41e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 2.99e7 22.90 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 2.65e7 26.46 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 3.08e4 Abs. Int. 8.22e6 4.11e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.73e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6861, 7759 scc: 786-548 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 15:26 Printed: 31-Mar-2014 19:18 Page 6 of 21 137 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-54 3.53e4 20.43 Rel. Int. 100% Abs. Int. 1.06e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.13e3 5.31e3 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 4.63e4 20.44 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.21e3 7.06e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.39e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.15e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 6.88e3 2.07e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.81e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.28e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 4.95e3 2.64e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.50e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.51e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2531, 5132 scc: 786-548 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:40 (CEM) Printed: 31-Mar-2014 19:18 Page 7 of 21 138 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Rel. Int. 100% PCB-52 7.97e6 24.54 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.35e3 50/53 1.25e6 22.40 PCB-51 4.13e5 23.08 PCB-45 9.36e5 23.01 69/49 4.92e6 24.98 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 44/47… 7.13e6 25.44 PCB-48 1.22e6 25.25 PCB-46 3.79e5 23.29 Abs. Int. 2.17e6 71/40 2.93e6 26.33 59/62… 6.21e5 25.73 PCB-64 3.72e6 26.53 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 1.02e7 24.54 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.47e3 69/49 6.15e6 24.98 50/53 1.60e6 22.40 PCB-45 1.21e6 23.01 Abs. Int. 2.78e6 44/47… 9.14e6 25.44 PCB-42 1.88e6 25.90 0% 22.0 23.0 24.0 25.0 26.0 JS-52 1.74e7 24.52 Rel. Int. 100% 0.00e0 RT 26.0 PCB-48 1.54e6 25.25 PCB-51 5.20e5 23.08 1.09e6 71/40 3.72e6 26.33 PCB-64 4.73e6 26.53 1.39e6 0.00e0 RT Abs. Int. 4.66e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.42e4 2.33e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.19e7 24.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.79e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 8.09e3 2.90e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.73e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2190, 3519 scc: 786-548 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:42 (CEM) Printed: 31-Mar-2014 19:18 Page 8 of 21 139 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 Abs. Int. 2.12e6 61/70... 1.15e7 PCB-66 28.76 6.19e6 29.03 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 2.25e3 PCB-56 2.90e6 29.62 PCB-60 1.25e6 29.81 1.06e6 PCB-77 5.08e5 32.80 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 2.71e6 61/70... 1.44e7 PCB-66 28.76 7.94e6 29.03 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.63e3 PCB-56 3.60e6 29.62 PCB-60 1.50e6 29.81 1.35e6 PCB-77 6.24e5 32.80 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.06e7 32.31 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.69e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 5.36e6 ES-77 2.06e7 32.78 2.68e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 2.53e7 32.31 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 9.59e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 6.52e6 ES-77 2.57e7 32.78 3.26e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.23e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.11e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9567, 1947 scc: 786-548 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:43 (CEM) Printed: 31-Mar-2014 19:18 Page 9 of 21 140 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-96 6.66e4 25.73 Rel. Int. 100% Abs. Int. 1.83e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 8.31e2 9.16e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 1.08e5 25.73 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.15e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 5.64e2 1.58e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.97e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.24e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.62e3 2.62e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.21e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.32e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.24e3 1.66e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.73e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7748, 6799 scc: 786-548 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:44 (CEM) Printed: 31-Mar-2014 19:18 Page 10 of 21 141 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.43e3 113/90… 2.48e6 30.53 PCB-95 2.06e6 27.99 PCB-91 5.26e5 28.75 PCB-84 7.51e5 28.94 PCB-110 3.26e6 32.23 Abs. Int. 8.14e5 PCB-118 2.19e6 34.78 PCB-99 1.44e6108/119... 31.04 1.96e6 116/85 31.51 7.05e5 32.09 PCB-92 4.01e5 30.02 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-82 3.21e5 32.51 PCB-105 1.07e6 35.79 PCB-109 1.99e5 34.39 4.07e5 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.35e3 32.0 113/90… 4.03e6 30.53 PCB-95 3.29e6 27.99 PCB-91 8.48e5 28.75 PCB-84 1.15e6 28.94 36.0 38.0 PCB-110 5.49e6 32.23 PCB-99 2.31e6108/119... 31.04 3.24e6 116/85 31.51 1.10e6 32.09 PCB-92 6.69e5 30.02 34.0 Abs. Int. 1.38e6 PCB-118 3.50e6 34.78 PCB-82 5.24e5 32.51 PCB-109 3.31e5 34.39 6.92e5 PCB-105 1.76e6 35.79 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 2.60e7 32.80 JS-101 2.24e7 30.51 0.00e0 RT PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.46e3 ES-123 2.42e7 34.48 36.0 ES-114 2.47e7 35.22 38.0 0.00e0 RT Abs. Int. 6.62e6 ES-105 2.39e7 35.76 3.31e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.61e7 32.80 JS-101 1.40e7 30.51 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 1.49e3 ES-118 ES-114 1.50e7 1.53e7 ES-123 34.76 35.22 1.50e7 34.48 36.0 38.0 0.00e0 RT Abs. Int. 4.05e6 ES-105 1.53e7 35.76 2.02e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.23e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.11e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9082, 0821 scc: 786-548 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:34 (CEM) Printed: 31-Mar-2014 19:18 Page 11 of 21 142 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 Rel. Int. 100% Abs. Int. 3.67e4 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 8.88e2 1.84e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 7.51e4 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 9.48e2 3.75e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.09e6 ES-126 2.09e7 38.37 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 4.36e3 2.54e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.27e6 ES-126 1.34e7 38.37 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 3.83e3 1.64e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.73e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5514, 2360 scc: 786-548 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 15:26 Printed: 31-Mar-2014 19:18 Page 12 of 21 143 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Rel. Int. 100% Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 153/168 1.53e6 36.36 147/149 1.31e6 33.80 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.38e2 PCB-136 2.99e5 30.97 PCB-132 4.86e5 34.88 151/135 4.93e5 33.03 163/138… 1.68e6 37.43 Abs. Int. 3.92e5 PCB-141 PCB-158 2.32e5 PCB-164 1.87e5 1.38e5 36.53 37.76 37.15 PCB-146 2.75e5 35.84 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% 36.0 153/168 1.21e6 36.36 147/149 9.72e5 33.80 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 5.90e2 PCB-136 2.21e5 30.97 38.0 PCB-132 3.87e5 34.88 151/135 3.70e5 33.03 163/138… 1.36e6 37.43 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.31e7 30.34 Rel. Int. 100% ES-153 1.62e7 36.34 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.07e3 0.00e0 RT Abs. Int. 3.22e5 PCB-141 1.91e5 PCB-164 PCB-158 1.68e5 1.13e5 36.53 37.76 37.15 PCB-146 1.97e5 35.84 1.96e5 1.61e5 0.00e0 RT Abs. Int. 5.78e6 JS-138 1.59e7 37.40 2.89e6 0% 28.0 30.0 32.0 34.0 ES-155 1.80e7 30.34 Rel. Int. 100% 36.0 ES-153 1.30e7 36.34 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.35e3 38.0 0.00e0 RT Abs. Int. 4.72e6 JS-138 1.23e7 37.40 2.36e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.23e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.11e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6678, 4574 scc: 786-548 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:45 (CEM) Printed: 31-Mar-2014 19:18 Page 13 of 21 144 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 Abs. Int. 5.63e4 128/166 2.63e5 38.51 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 8.31e2 PCB-167 6.85e4 39.96 156/157 1.85e5 40.93 2.81e4 0% 39.0 Rel. Int. 100% 40.0 128/166 2.23e5 38.51 41.0 42.0 43.0 44.0 45.0 Abs. Int. 5.19e4 156/157 1.64e5 40.93 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 8.57e2 PCB-167 6.41e4 39.96 2.60e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.04e7 39.94 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 5.55e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.86e7 40.92 0.00e0 RT Abs. Int. 6.79e6 ES-169 1.79e7 43.64 3.39e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.66e7 39.94 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 5.17e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.06e7 40.92 0.00e0 RT Abs. Int. 5.51e6 ES-169 1.41e7 43.63 2.76e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.73e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6537, 4243 scc: 786-548 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:47 (CEM) Printed: 31-Mar-2014 19:18 Page 14 of 21 145 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-179 1.28e5 35.52 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 5.00e2 Abs. Int. 3.09e4 PCB-178 4.02e4 37.80 PCB-176 3.74e4 36.27 1.55e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 1.23e5 35.52 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 5.35e2 Abs. Int. 3.47e4 PCB-178 4.54e4 37.80 PCB-176 3.56e4 36.27 1.73e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.50e7 35.22 Rel. Int. 100% CS/SS-178 9.08e6 37.78 1.87e6 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.38e7 35.22 Rel. Int. 100% CS/SS-178 8.72e6 37.78 1.66e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 3.32e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.22e3 31.0 0.00e0 RT Abs. Int. 3.73e6 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.55e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.23e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.11e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1029, 1496 scc: 786-548 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:45 (CEM) Printed: 31-Mar-2014 19:18 Page 15 of 21 146 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 180/193 5.42e5 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 1.01e3 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-187 3.39e5 38.57 PCB-174 PCB-177 PCB-183 1.93e5 39.29 1.44e5 1.58e5 39.67 39.10 PCB-185 1.96e4 39.18 171/173 7.07e4 40.21 Abs. Int. 1.19e5 PCB-170 1.73e5 43.17 PCB-172 4.03e4 41.54 5.94e4 PCB-190 4.91e4 43.62 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 5.09e5 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 9.41e2 43.0 PCB-187 3.23e5 38.57 PCB-183 1.49e5 39.10 PCB-174 2.00e5 39.29 PCB-177 1.31e5 39.67 171/173 7.16e4 40.20 Abs. Int. 1.22e5 PCB-170 1.73e5 43.16 PCB-172 3.87e4 41.55 6.12e4 PCB-190 5.17e4 43.62 0% 39.0 40.0 41.0 42.0 ES-180 1.37e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.40e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.30e6 ES-170 1.10e7 43.15 1.65e6 0% 39.0 40.0 41.0 42.0 ES-180 1.22e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 2.20e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.98e6 ES-170 1.02e7 43.15 1.49e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.73e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0804, 9005 scc: 786-548 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:45 (CEM) Printed: 31-Mar-2014 19:18 Page 16 of 21 147 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-189 1.35e4 45.78 Abs. Int. 3.96e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 1.11e3 1.98e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.41e4 45.78 Abs. Int. 3.22e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 5.66e2 1.61e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.54e7 45.76 0.00e0 RT Abs. Int. 3.62e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.00e3 1.81e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.49e7 45.76 0.00e0 RT Abs. Int. 3.59e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 3.32e3 1.80e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.73e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.36e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3574, 2952 scc: 786-548 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:37 (CEM) Printed: 31-Mar-2014 19:18 Page 17 of 21 148 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 198/199 9.09e4 43.75 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 6.46e2 PCB-202 2.86e4 39.78 Abs. Int. 2.21e4 PCB-196 3.62e4 44.31 PCB-201 1.88e4 40.56 PCB-203 5.01e4 44.48 1.10e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 9.70e4 43.75 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 5.68e2 PCB-202 3.47e4 39.77 Abs. Int. 2.60e4 PCB-196 4.23e4 44.31 PCB-201 2.28e4 40.55 PCB-203 4.67e4 44.48 1.30e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.30e7 39.75 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 3.15e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.66e3 1.58e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.41e7 39.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.34e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.05e3 1.67e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.73e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6336, 5065 scc: 786-548 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:37 (CEM) Printed: 31-Mar-2014 19:18 Page 18 of 21 149 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 PCB-194 6.71e4 47.54 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 7.21e2 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 Abs. Int. 1.94e4 PCB-195 2.43e4 45.60 9.68e3 0% 46.0 47.0 49.0 50.0 PCB-194 6.29e4 47.54 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 7.12e2 48.0 0.00e0 RT Abs. Int. 1.86e4 PCB-195 2.45e4 45.60 9.28e3 0% 46.0 47.0 48.0 JS-194 9.81e6 47.52 Rel. Int. 100% 49.0 50.0 ES-205 1.01e7 47.92 0.00e0 RT Abs. Int. 2.40e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.27e3 1.20e6 0% 46.0 47.0 48.0 JS-194 1.07e7 47.52 Rel. Int. 100% 49.0 50.0 ES-205 1.15e7 47.92 0.00e0 RT Abs. Int. 2.58e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.54e3 1.29e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.73e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.36e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2014, 7828 scc: 786-548 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:38 (CEM) Printed: 31-Mar-2014 19:18 Page 19 of 21 150 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.16e3 PCB-208 5.26e4 45.40 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-206 4.77e4 49.41 Abs. Int. 1.57e4 PCB-207 4.69e4 46.18 7.87e3 0% 46.0 Rel. Int. 100% PCB-208 6.19e4 45.40 47.0 48.0 49.0 PCB-207 6.22e4 46.18 50.0 Abs. Int. 1.68e4 PCB-206 5.32e4 49.40 NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 1.57e3 8.38e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 2.65e6 ES-208 1.10e7 45.38 ES-206 6.69e6 49.39 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.54e3 1.32e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.34e6 ES-208 1.40e7 45.38 ES-206 8.49e6 49.39 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.89e3 1.67e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.73e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.36e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8035, 9968 scc: 786-548 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:38 (CEM) Printed: 31-Mar-2014 19:18 Page 20 of 21 151 of 711 SGS-AP ID: A6504_11892_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB047.3-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 36 Acq: 26-Mar-2014 23:52:48 User: LKB Datafile: 140326X11 PCB-209 1.17e6 50.84 Rel. Int. 100% Abs. Int. 2.69e5 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 6.75e2 1.35e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.00e6 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.11e5 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 5.76e2 1.05e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 9.83e6 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.04e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.14e3 1.02e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 8.22e6 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.71e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 8.27e2 8.55e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.42e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.21e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_003.utp_res, saved 31-Mar-2014 16:04 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9577, 7101 scc: 786-548 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 15:38 (CEM) Printed: 31-Mar-2014 19:18 Page 21 of 21 152 of 711 Lab ID: A6504_11892_PCB_004 ACQ: 27-Mar-2014 00:47:55 LKB Wt/Vol: 0.97 L Client ID: PB056_C-1SWMID-140313-N (TOTAL) UTP: 31-Mar-2014 16:17 CEM J-level: 10.4 pg/L Datafile: 140326X12 RPT: 31-Mar-2014 18:58 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.82 32.34 35.80 35.26 34.79 34.51 38.41 40.94 39.97 NotFnd 45.80 50.86 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.89 14.18 14.43 20.15 17.52 26.47 20.43 32.80 32.32 25.40 35.78 35.24 34.77 34.49 38.39 36.36 30.36 40.94 39.95 43.65 43.16 42.10 35.23 45.77 39.77 47.94 49.40 45.39 50.83 QC C J EMPC Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0006 1.0006 1.0006 1.0006 1.0006 1.0004 1.0002 1.0005 1.0005 1.0004 0 +0.2 -0.2 0 0 -0.2 -0.2 -0.7 -0.2 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7246 0.8640 0.8794 1.2274 1.0673 1.0789 0.8327 1.3367 1.3173 0.8323 1.1722 1.1545 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8856 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Split: 1 Checkcode: 848-343-NKY Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.79 0.79 0.61 0.61 0.61 0.63 0.60 1.28 1.17 +0.3 0 9.92E+06 4.85E+05 2.66E+07 1.67E+06 4.76E+07 1.44E+06 2.45E+05 2.51E+06 8.06E+05 0.00E+00 1.00E+05 6.70E+06 1.25 1.16 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 298 15.4 977 56 1,660 48.8 10.7 108 31 ND 5.03 545 7.05E+03 7.05E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 3.09E+03 2.28E+03 2.28E+03 2.28E+03 1.89E+03 1.38E+03 2.23 2.2 1.66 1.57 1.62 1.55 1.39 1.34 0.922 1.11 0.959 1.29 +0.1 +0.1 0 +0.1 0 +0.2 -0.1 +0.2 +0.2 -0.2 +0.2 +0.2 0 0 0 0 0 0 0 0 0 +0.3 0 0 0 0 0 0 0 6.12E+07 6.82E+07 3.93E+07 9.24E+07 4.25E+07 7.09E+07 4.19E+07 5.98E+07 5.83E+07 4.05E+07 5.07E+07 5.13E+07 5.00E+07 5.05E+07 4.28E+07 3.70E+07 5.21E+07 8.75E+07 4.63E+07 4.00E+07 2.67E+07 3.27E+07 3.65E+07 3.85E+07 3.40E+07 2.74E+07 1.91E+07 3.12E+07 2.29E+07 3.28 3.35 1.58 1.57 1.07 1.09 0.75 0.80 0.79 1.64 1.57 1.61 1.59 1.58 1.55 1.31 1.26 1.26 1.27 1.27 1.06 1.07 1.05 1.03 0.90 0.90 0.80 0.78 1.18 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 56.8 % 69.5 % 83.2 % 98.3 % 93.1 % 87.8 % 100 % 89 % 87.8 % 111 % 93.2 % 93.1 % 95.4 % 94.1 % 92.1 % 94 % 93.3 % 77.8 % 79 % 73.1 % 95.8 % 97.8 % 110 % 98.6 % 99.7 % 89.5 % 93.3 % 108 % 83.6 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Page 1 of 5 Printed: 3/31/2014 7:04 PM 153 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.92 32.81 37.79 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 7.83E+07 5.13E+07 2.27E+07 1.10 1.59 1.09 1.11 1.03 0.62 99.4 % 98.6 % 101 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.92 32.81 37.79 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 7.83E+07 5.13E+07 2.27E+07 1.10 1.59 1.09 1.85 1.22 0.58 87.3 % 92.8 % 111 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.41 24.54 30.52 37.42 47.54 9.04E+07 4.86E+07 4.53E+07 3.52E+07 2.46E+07 1.56 0.80 1.58 1.26 0.88 6.59E+03 6.59E+03 6.59E+03 6.77E+03 6.77E+03 8.57E+03 8.57E+03 8.57E+03 8.57E+03 8.57E+03 8.57E+03 8.57E+03 8.57E+03 8.57E+03 5.34E+03 5.34E+03 5.34E+03 5.34E+03 5.34E+03 5.34E+03 1.41 1.36 1.5 2.15 1.38 1.8 1.57 1.7 1.71 1.62 1.42 1.62 1.64 1.69 1.89 1.41 1.65 1.21 1.26 2.21 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.91 NotFnd 14.19 14.45 14.63 16.43 16.60 16.82 NotFnd 17.25 NotFnd 19.58 19.86 20.16 17.54 19.30 19.70 19.89 20.02 20.12 J EMPC J J B C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 1.0011 1.0002 1.0011 1.0135 1.0010 1.0110 1.0249 1.0506 0.9721 0.9856 1.0006 1.0010 1.1019 1.1244 1.1354 1.1427 1.1486 0 -0.7 0 0 0 -0.1 0 +0.1 0 -1.2 -0.2 0 +0.5 0 0 -0.4 +0.1 Page 2 of 5 NON-EMPC 33.7 747 10,400 32,500 14,900 3,730 1,070 253 85.4 9.49E+05 0.00E+00 2.57E+05 5.10E+06 2.99E+05 6.19E+05 2.89E+05 2.45E+06 0.00E+00 1.10E+07 0.00E+00 1.47E+06 1.05E+06 7.27E+06 3.66E+06 5.68E+07 1.69E+07 3.64E+06 4.03E+05 1.25E+07 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 41.4 747 10,400 32,500 14,900 3,780 1,080 253 85.4 3.39 5.33 1.56 1.64 1.66 SI 1.62 1.65 1.65 1.63 1.62 1.03 1.05 1.05 1.03 0.99 1.04 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 1.45 1.92 1.74 1.42 1.37 0.944 1.01 1.08 2.64 33.7 ND 7.73 218 8.21 14.5 5.88 54.3 ND 233 ND 30.9 22.4 160 155 1,790 625 98.7 11.4 623 Printed: 3/31/2014 7:04 PM 154 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.60 21.75 NotFnd 22.16 22.39 22.66 22.94 23.15 23.50 NotFnd 25.25 25.75 26.13 26.49 20.45 22.41 23.03 23.10 23.31 24.56 NotFnd 24.77 25.00 25.26 25.45 25.74 25.92 26.25 26.35 26.55 27.26 27.52 27.89 28.11 28.25 28.48 28.78 29.05 NotFnd 29.63 29.83 NotFnd 31.49 NotFnd NotFnd 25.74 27.44 27.62 SGS Evironmental Services QC J C C C J J C C C C C J EMPC C Pred RRT Actual RRT Diff Secs 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1760 0.8216 0.8372 0.8457 0.8561 0.8665 0.8745 0.8879 0.9540 0.9729 0.9870 1.0009 1.0010 0.9134 0.9385 0.9416 0.9498 1.0009 1.0097 1.0189 1.0295 1.0374 1.0492 1.0564 1.0699 1.0739 1.0819 0.8435 0.8514 0.8628 0.8696 0.8741 0.8811 0.8903 0.8988 0.9168 0.9228 0.9743 1.0134 0.8988 0.9050 +0.1 -0.3 -1.3 0 -0.1 -0.6 +1.0 0 +2.7 +0.9 -0.2 +0.3 0 -1.5 0 +0.3 -0.1 0 -0.4 +1.2 -0.2 -1.5 -0.8 +0.2 -0.2 +0.2 0 0 0 -0.3 +0.7 0 0 +0.3 0 0 0 +1.1 0 -0.2 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 2.21E+07 3.72E+05 0.00E+00 1.42E+07 5.81E+06 9.86E+07 8.99E+07 3.04E+07 2.41E+07 0.00E+00 1.20E+06 2.85E+05 1.56E+06 1.65E+07 2.69E+05 1.76E+07 1.53E+07 4.12E+06 5.19E+06 1.22E+08 0.00E+00 3.66E+06 7.66E+07 2.12E+07 1.10E+08 1.04E+07 2.42E+07 7.44E+06 4.70E+07 6.26E+07 8.07E+05 1.14E+06 4.66E+05 1.61E+05 2.96E+06 4.77E+06 2.14E+08 1.19E+08 0.00E+00 5.56E+07 2.66E+07 0.00E+00 1.18E+06 0.00E+00 0.00E+00 1.11E+06 4.58E+05 4.70E+05 1.05 1.06 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 559 8.85 ND 327 133 2,170 2,130 702 594 ND 26 6.85 39 447 9.82 690 661 167 251 4,870 ND 170 2,500 846 4,100 298 1,050 353 1,840 1,690 22.6 30.5 13.7 4.67 81.2 125 6,230 3,610 ND 1,710 809 ND 31.8 ND ND 48.8 19.7 24.1 1.02 1.02 1.00 1.01 1.00 1.00 1.02 1.01 1.02 1.01 0.79 0.80 0.79 0.80 0.80 0.79 0.78 0.79 0.78 0.79 0.78 0.79 0.77 0.79 0.79 0.83 0.75 0.79 0.93 0.78 0.82 0.79 0.80 0.80 0.79 0.71 0.68 0.61 0.62 Noise / Recv. Low DL / Recv. High 5.34E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 6.12E+03 2.12E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 7.05E+03 1.26E+03 1.26E+03 4.45E+03 4.45E+03 1.13 1.39 1.37 1.35 1.34 1.29 1.39 1.35 1.45 1.32 1.28 1.41 1.47 1.59 0.678 0.987 1.09 1.02 1.22 1 0.761 1.17 0.821 1 0.944 0.72 1.1 1.2 0.987 0.682 1.94 1.86 2.04 2.02 1.91 1.81 2.02 2.1 2.14 2.13 2.11 1.78 1.87 2.22 0.408 0.502 1.97 2.35 Printed: 3/31/2014 7:04 PM 155 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 28.01 28.23 28.33 NotFnd NotFnd 28.76 28.96 29.38 NotFnd 30.04 30.54 30.95 31.05 NotFnd 31.53 32.03 32.11 32.24 NotFnd 32.52 NotFnd NotFnd 34.20 34.41 NotFnd 35.09 NotFnd NotFnd NotFnd NotFnd 30.99 NotFnd NotFnd 33.04 33.25 33.52 33.82 34.00 NotFnd 34.34 34.51 NotFnd 34.89 35.30 NotFnd 35.85 NotFnd 36.38 SGS Evironmental Services QC C C C C C C C J C C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9175 0.9247 0.9282 0.9424 0.9487 0.9624 0.9840 1.0007 1.0141 1.0173 1.0329 1.0494 1.0520 1.0564 1.0655 0.9916 0.9976 1.0090 1.0208 1.0885 1.0955 1.1043 1.1141 1.1201 1.1312 1.1370 1.1495 1.1628 0.9581 0.9722 -0.2 +0.2 0 -0.2 0 0 -0.2 +1.5 -0.2 0 +1.7 -0.2 -1.0 +0.2 -0.2 +0.2 0 -0.2 +0.2 -0.2 0 +0.2 -0.2 +0.4 -0.2 0 0 0 -0.2 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 3.40E+07 8.28E+05 2.96E+06 0.00E+00 0.00E+00 9.76E+06 1.28E+07 1.39E+06 0.00E+00 7.35E+06 4.62E+07 2.36E+06 2.79E+07 0.00E+00 4.04E+07 1.82E+06 1.34E+07 6.51E+07 0.00E+00 7.07E+06 0.00E+00 0.00E+00 2.18E+06 4.02E+06 0.00E+00 1.00E+06 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.77E+06 0.00E+00 0.00E+00 4.55E+06 2.42E+05 7.87E+05 1.20E+07 8.16E+05 0.00E+00 3.75E+05 2.77E+05 0.00E+00 5.32E+06 2.31E+05 0.00E+00 2.38E+06 0.00E+00 1.47E+07 0.62 0.60 0.63 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 1,600 38.7 138 ND ND 467 731 73.3 ND 357 1,950 146 1,160 ND 1,700 68.5 566 2,430 ND 417 ND ND 81.2 135 ND 40.1 ND ND ND ND 107 ND ND 240 10.8 39.9 608 56.1 ND 18.9 16.4 ND 306 12.5 ND 115 ND 593 0.62 0.61 0.65 0.61 0.62 0.60 0.62 0.62 0.60 0.60 0.62 0.62 0.62 0.64 0.65 1.27 1.23 1.11 1.35 1.29 1.30 1.27 1.34 1.23 1.17 1.20 1.26 Noise / Recv. Low DL / Recv. High 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 2.16 2.15 2.14 2.2 2.22 2.19 2.62 2.41 1.54 2.23 1.93 2.85 1.91 1.63 1.93 1.73 1.94 1.71 1.68 2.71 1.56 1.54 1.71 1.54 1.74 1.87 1.73 0.405 0.47 0.456 0.499 0.492 0.621 0.659 0.556 0.633 0.634 0.858 0.638 0.629 0.74 0.757 0.719 0.673 0.529 0.603 0.491 0.504 Printed: 3/31/2014 7:04 PM 156 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.54 36.89 37.09 37.17 37.44 NotFnd 37.78 38.52 39.31 39.56 NotFnd 35.53 NotFnd 36.29 NotFnd 37.81 38.36 38.59 NotFnd 39.11 39.20 39.31 39.68 40.03 40.22 41.56 NotFnd 42.11 42.41 43.18 43.63 39.79 40.57 NotFnd 41.34 41.43 43.77 44.32 44.49 45.61 47.56 47.96 45.41 46.20 49.42 SGS Evironmental Services QC EMPC C C J J J J EMPC C C J J J J C J Pred RRT Actual RRT Diff Secs 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 0.9859 0.9912 0.9935 1.0007 1.0096 0.9643 0.9840 0.9902 1.0086 1.0300 1.0733 1.0888 1.0953 1.1102 1.1127 1.1157 1.1263 1.1361 1.1416 0.9080 0.9200 0.9265 0.9434 0.9532 1.0005 1.0203 1.0395 1.0419 1.1007 1.1146 1.1189 0.9516 0.9921 1.0005 1.0005 1.0178 1.0004 -0.2 0 0 +0.2 -0.9 0 +0.7 -0.7 -0.2 0 0 0 0 0 +0.2 +0.5 +0.2 0 -0.2 +0.5 +0.2 +1.8 -0.3 0 -0.3 0 0 0 +0.2 +1.3 -0.3 0 0 0 +0.3 0 0 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 2.77E+06 1.12E+06 9.08E+05 1.49E+06 1.86E+07 0.00E+00 2.49E+06 3.14E+06 1.62E+05 8.48E+04 0.00E+00 1.12E+06 0.00E+00 3.51E+05 0.00E+00 3.92E+05 1.10E+05 2.97E+06 0.00E+00 1.46E+06 2.12E+05 2.06E+06 1.25E+06 3.16E+04 7.24E+05 3.99E+05 0.00E+00 5.12E+06 1.36E+05 1.91E+06 5.12E+05 2.89E+05 1.76E+05 0.00E+00 7.70E+04 1.36E+05 8.17E+05 3.79E+05 4.56E+05 2.21E+05 5.90E+05 4.22E+04 4.39E+05 3.62E+05 3.94E+05 1.27 1.25 1.47 1.17 1.28 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 154 68.7 44.2 60.7 926 ND 93.6 159 6.72 3.54 ND 58.6 ND 17.3 ND 29.5 6.36 161 ND 75.4 12.8 129 82.9 1.85 48.5 25.5 ND 263 6.36 133 25.7 16.7 9.6 ND 4.31 7.64 68.9 30.2 35.6 22.2 54.9 3.01 25.9 21.1 38.3 1.20 1.19 1.33 1.11 1.01 1.04 1.08 1.14 1.02 1.01 1.14 1.06 1.01 0.87 1.06 1.01 1.08 1.09 1.05 1.07 0.97 0.97 0.85 0.84 0.87 0.90 0.85 0.92 0.87 1.00 0.76 0.74 0.81 Noise / Recv. Low DL / Recv. High 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 2.28E+03 2.28E+03 2.28E+03 1.10E+03 1.10E+03 1.10E+03 1.10E+03 1.10E+03 1.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 2.10E+03 1.37E+03 1.37E+03 1.37E+03 1.37E+03 1.37E+03 1.37E+03 1.37E+03 1.37E+03 1.83E+03 1.83E+03 1.83E+03 3.14E+03 3.14E+03 3.14E+03 0.693 0.768 0.608 0.509 0.621 0.551 0.469 1.21 0.998 1 0.49 0.573 0.597 0.54 0.576 0.825 1.22 1.15 1.12 1.09 1.27 1.33 1.4 1.24 1.42 1.35 1.04 1.09 0.991 1.57 1.13 0.813 0.767 0.825 0.786 0.789 1.19 1.12 1.1 1.9 1.75 1.34 1.93 1.9 3.36 Printed: 3/31/2014 7:04 PM 157 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.44e7 2.72e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.52e7 7.60e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.33e7 6.64e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.17e7 1.08e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.22e7 6.09e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.47e6 1.24e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.41e6 1.20e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 848-343 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:18 Page 1 of 21 158 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-1 7.33e5 11.91 Rel. Int. 100% Abs. Int. 3.05e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.74e3 PCB-3 3.32e5 14.19 1.52e5 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.16e5 11.91 Rel. Int. 100% Abs. Int. 1.03e5 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.85e3 5.16e4 PCB-3 6.22e4 14.19 0% 11.0 12.0 13.0 ES-1 4.69e7 11.89 Rel. Int. 100% 0.00e0 16.0 RT 14.0 15.0 ES-3 5.25e7 14.18 0.00e0 16.0 RT Abs. Int. 1.95e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.88e3 9.76e6 0% 11.0 12.0 13.0 ES-1 1.43e7 11.89 Rel. Int. 100% 14.0 15.0 ES-3 1.57e7 14.18 0.00e0 16.0 RT Abs. Int. 6.03e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.39e4 3.01e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.44e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.72e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6432, 4941 scc: 848-343 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:04 (CEM) Printed: 31-Mar-2014 19:18 Page 2 of 21 159 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 Rel. Int. 100% Abs. Int. 1.05e6 PCB-4 3.10e6 14.45 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 4.12e3 5.26e5 PCB-10 1.86e5 14.63 0% 11.0 12.0 13.0 14.0 Rel. Int. 100% 15.0 Abs. Int. 6.84e5 PCB-4 1.99e6 14.45 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.33e4 0.00e0 16.0 RT 3.42e5 PCB-10 1.13e5 14.63 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.40e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.10e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.75e3 4.05e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.53e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.30e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.62e3 2.65e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.44e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.72e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0449, 2391 scc: 848-343 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:04 (CEM) Printed: 31-Mar-2014 19:18 Page 3 of 21 160 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-8 6.88e6 17.25 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 5.22e3 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-9 3.87e5 16.43 Abs. Int. 2.16e6 PCB-15 4.49e6 20.16 PCB-6 1.52e6 16.82 PCB-11 9.14e5 19.58 1.08e6 13/12 6.49e5 19.86 0% 17.0 19.0 20.0 21.0 PCB-8 4.16e6 17.24 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.81e4 18.0 PCB-9 2.33e5 16.43 Abs. Int. 1.31e6 PCB-15 2.78e6 20.16 PCB-6 9.38e5 16.82 PCB-11 5.55e5 19.58 6.53e5 13/12 3.99e5 19.85 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 5.51e7 16.41 20.0 21.0 ES-15 5.64e7 20.15 0.00e0 RT Abs. Int. 1.72e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.98e4 8.61e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 3.53e7 16.41 20.0 21.0 ES-15 3.60e7 20.15 0.00e0 RT Abs. Int. 1.11e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 4.52e3 5.55e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.60e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1566, 5394 scc: 848-343 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:05 (CEM) Printed: 31-Mar-2014 19:18 Page 4 of 21 161 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 Abs. Int. 8.35e6 30/18 2.91e7 19.30 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.83e3 PCB-17 8.67e6 19.70 PCB-19 1.86e6 17.54 PCB-27 1.84e6 19.89 PCB-16 6.39e6 20.12 PCB-32 1.13e7 20.60 4.17e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 7.99e6 30/18 2.77e7 19.30 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.51e3 PCB-17 8.24e6 19.70 PCB-19 1.80e6 17.54 PCB-27 1.79e6 19.89 PCB-16 6.15e6 20.12 PCB-32 1.08e7 20.60 4.00e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.20e7 17.52 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 6.68e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.27e4 3.34e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.06e7 17.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.43e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.98e4 3.22e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.60e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4714, 1047 scc: 848-343 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:06 (CEM) Printed: 31-Mar-2014 19:18 Page 5 of 21 162 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-31 4.94e7 28/20 22.66 4.53e7 22.94 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 3.07e3 26/29 7.16e6 22.16 0% Abs. Int. 1.32e7 21/33 1.52e7 23.15 PCB-25 2.93e6 22.39 22.0 PCB-22 1.20e7 23.50 23.0 PCB-37 8.29e6 26.49 24.0 25.0 26/29 7.01e6 22.16 0% 22.0 PCB-25 2.88e6 22.39 Abs. Int. 1.33e7 21/33 1.52e7 23.15 23.0 PCB-22 1.20e7 23.50 PCB-37 8.21e6 26.49 24.0 25.0 6.63e6 0.00e0 RT 26.0 CS/SS-28 4.10e7 22.92 Rel. Int. 100% 6.61e6 0.00e0 RT 26.0 PCB-31 4.93e7 28/20 22.66 4.47e7 22.94 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 3.05e3 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 ES-37 3.70e7 26.47 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.79e4 Abs. Int. 1.08e7 5.41e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 3.73e7 22.91 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.39e7 26.47 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.76e4 Abs. Int. 1.00e7 5.00e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.64e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4485, 3882 scc: 848-343 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:04 Printed: 31-Mar-2014 19:18 Page 6 of 21 163 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-54 1.19e5 20.45 Rel. Int. 100% Abs. Int. 3.22e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 9.42e2 1.61e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.50e5 20.45 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.82e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.17e3 2.41e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.80e7 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.14e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 6.07e3 2.57e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.39e7 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.67e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 5.02e3 3.34e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.60e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1238, 5529 scc: 848-343 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:04 (CEM) Printed: 31-Mar-2014 19:18 Page 7 of 21 164 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PCB-52 5.39e7 24.56 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 9.18e2 69/49 3.39e7 25.00 50/53 7.81e6 22.41 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 44/47… 4.82e7 25.45 PCB-48 9.30e6 25.26 PCB-45 6.77e6 23.03 Abs. Int. 1.46e7 PCB-42 1.07e7 25.92 71/40 2.08e7 26.35 PCB-64 2.76e7 26.55 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 6.84e7 24.56 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.64e3 69/49 4.27e7 25.00 50/53 9.81e6 22.41 PCB-48 1.19e7 25.26 PCB-45 8.53e6 23.03 Abs. Int. 1.84e7 PCB-42 1.35e7 25.92 59/62… 5.85e6 25.74 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.16e7 24.54 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 6.13e7 25.45 7.32e6 71/40 2.62e7 26.35 PCB-41 4.20e6 26.25 PCB-64 3.50e7 26.55 9.21e6 0.00e0 RT Abs. Int. 5.79e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.38e4 2.89e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.70e7 24.54 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.99e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.12e4 3.49e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.64e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2826, 9062 scc: 848-343 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:04 Printed: 31-Mar-2014 19:18 Page 8 of 21 165 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 Abs. Int. 1.77e7 61/70... 9.48e7 PCB-66 28.78 5.29e7 29.05 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 2.93e3 PCB-56 2.48e7 29.63 PCB-60 1.17e7 29.83 8.85e6 PCB-77 4.38e6 32.82 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 2.19e7 61/70... 1.19e8 PCB-66 28.78 6.64e7 29.05 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 4.12e3 PCB-56 3.08e7 29.63 PCB-60 1.48e7 29.83 1.09e7 PCB-77 5.54e6 32.81 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.57e7 32.32 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.33e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 6.54e6 ES-77 2.65e7 32.80 3.27e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.26e7 32.32 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.00e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 8.03e6 ES-77 3.33e7 32.80 4.02e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.08e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5409, 4613 scc: 848-343 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:06 (CEM) Printed: 31-Mar-2014 19:18 Page 9 of 21 166 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-96 4.50e5 25.74 Rel. Int. 100% Abs. Int. 1.22e5 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 5.82e2 6.10e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 6.63e5 25.74 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e5 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 6.82e2 9.42e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.52e7 25.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.95e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.26e3 3.47e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.53e7 25.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 2.62e3 2.05e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.64e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1083, 4956 scc: 848-343 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:04 Printed: 31-Mar-2014 19:18 Page 10 of 21 167 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 2.04e3 113/90… 1.76e7 30.54 PCB-95 1.30e7 28.01 PCB-91 3.74e6 28.76 PCB-84 4.85e6 28.96 PCB-110 2.49e7 32.24 Abs. Int. 6.13e6 PCB-118 1.81e7 34.79 PCB-99 1.07e7108/119... 31.05 1.55e7 116/85 31.53 5.04e6 32.11 PCB-92 2.78e6 30.04 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-82 2.71e6 32.52 PCB-109 1.56e6 34.41 PCB-105 1.01e7 35.80 3.06e6 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 2.40e3 32.0 113/90… 2.86e7 30.54 PCB-95 2.10e7 28.01 PCB-91 6.02e6 28.76 PCB-84 7.98e6 28.96 36.0 38.0 PCB-110 4.03e7 32.24 PCB-99 1.73e7108/119... 31.05 2.50e7 116/85 31.53 8.34e6 32.11 PCB-92 4.57e6 30.04 34.0 Abs. Int. 9.75e6 PCB-118 2.95e7 34.79 PCB-82 4.36e6 32.52 PCB-109 2.46e6 34.41 PCB-105 1.66e7 35.80 4.88e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 3.15e7 32.81 JS-101 2.77e7 30.52 0.00e0 RT PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.57e3 ES-118 ES-114 3.16e7 ES-123 3.07e7 35.24 3.09e7 34.77 34.49 36.0 38.0 0.00e0 RT Abs. Int. 7.91e6 ES-105 3.10e7 35.78 3.96e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.98e7 32.81 JS-101 1.75e7 30.52 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.26e3 ES-118 ES-114 1.97e7 ES-123 1.93e7 35.24 1.96e7 34.77 34.49 36.0 38.0 0.00e0 RT Abs. Int. 5.04e6 ES-105 1.97e7 35.78 2.52e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.08e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0043, 8981 scc: 848-343 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:09 (CEM) Printed: 31-Mar-2014 19:18 Page 11 of 21 168 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 Rel. Int. 100% PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 1.10e3 Abs. Int. 1.70e5 8.51e4 PCB-126 9.24e4 38.41 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 1.99e3 Abs. Int. 3.86e5 1.93e5 PCB-126 1.53e5 38.41 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.34e6 ES-126 2.61e7 38.39 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 4.03e3 3.17e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.17e6 ES-126 1.68e7 38.39 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 6.44e3 2.08e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.09e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0429, 3833 scc: 848-343 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:11 (CEM) Printed: 31-Mar-2014 19:18 Page 12 of 21 169 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 153/168 8.17e6 36.38 147/149 6.73e6 33.82 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.99e2 PCB-136 1.55e6 30.99 PCB-132 2.94e6 34.89 151/135 2.51e6 33.04 PCB-141 1.55e6 PCB-137 36.54 5.92e5 37.09 PCB-146 1.30e6 35.85 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PCB-136 1.22e6 30.99 1.25e6 38.0 153/168 6.50e6 36.38 PCB-132 2.38e6 34.89 151/135 2.04e6 33.04 Abs. Int. 2.50e6 PCB-158 1.36e6 37.78 36.0 147/149 5.24e6 33.82 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 5.63e2 163/138… 1.05e7 37.44 163/138… 8.17e6 37.44 Abs. Int. 1.91e6 PCB-141 PCB-158 1.22e6 PCB-164 1.13e6 6.88e5 36.54 37.78 37.17 PCB-146 1.08e6 35.85 0% 28.0 30.0 32.0 34.0 ES-155 2.90e7 30.36 Rel. Int. 100% 36.0 ES-153 2.10e7 36.36 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.44e3 0.00e0 RT 38.0 9.56e5 0.00e0 RT Abs. Int. 7.12e6 JS-138 1.96e7 37.42 3.56e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.31e7 30.36 Rel. Int. 100% ES-153 1.60e7 36.36 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.40e3 0.00e0 RT Abs. Int. 5.94e6 JS-138 1.56e7 37.42 2.97e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.08e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9715, 4517 scc: 848-343 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:12 (CEM) Printed: 31-Mar-2014 19:18 Page 13 of 21 170 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 128/166 1.70e6 38.52 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 Abs. Int. 4.02e5 156/157 1.41e6 40.94 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 9.96e2 PCB-159 9.21e4 39.31 2.01e5 PCB-167 4.35e5 39.97 0% 39.0 Rel. Int. 100% 40.0 128/166 1.44e6 38.52 41.0 42.0 43.0 44.0 45.0 Abs. Int. 3.25e5 156/157 1.10e6 40.94 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 1.29e3 PCB-159 6.95e4 39.31 PCB-167 3.72e5 39.97 1.63e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.88e7 40.94 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.96e6 ES-167 2.59e7 39.95 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 5.30e3 0.00e0 RT ES-169 2.24e7 43.65 4.48e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.04e7 39.95 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 6.06e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.87e7 40.94 0.00e0 RT Abs. Int. 7.10e6 ES-169 1.76e7 43.65 3.55e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.09e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7430, 4431 scc: 848-343 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:12 (CEM) Printed: 31-Mar-2014 19:18 Page 14 of 21 171 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-179 5.62e5 35.53 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 5.26e2 Abs. Int. 1.39e5 PCB-176 1.79e5 36.29 PCB-178 2.04e5 37.81 6.94e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 5.59e5 35.53 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 5.76e2 Abs. Int. 1.41e5 PCB-176 1.72e5 36.29 PCB-178 1.88e5 37.81 7.06e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.87e7 35.23 Rel. Int. 100% CS/SS-178 1.19e7 37.79 2.35e6 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.78e7 35.23 Rel. Int. 100% CS/SS-178 1.09e7 37.79 2.20e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 4.40e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.03e3 31.0 0.00e0 RT Abs. Int. 4.71e6 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.37e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.08e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0040, 1462 scc: 848-343 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:13 (CEM) Printed: 31-Mar-2014 19:18 Page 15 of 21 172 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 180/193 2.65e6 42.11 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 9.87e2 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-187 1.50e6 38.59 PCB-174 1.06e6 PCB-177 PCB-183 39.31 6.31e5 7.34e5 39.68 39.11 PCB-185 1.13e5 39.20 171/173 3.72e5 40.22 Abs. Int. 6.07e5 PCB-170 9.78e5 43.18 PCB-172 2.01e5 41.56 3.03e5 PCB-190 2.65e5 43.63 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 2.47e6 42.11 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 1.11e3 43.0 PCB-187 1.47e6 38.59 PCB-174 1.00e6 PCB-183 39.31 7.29e5 39.11 PCB-185 9.92e4 39.20 PCB-177 6.23e5 39.68 171/173 3.52e5 40.22 Abs. Int. 5.55e5 PCB-170 9.28e5 43.18 PCB-172 1.98e5 41.56 2.78e5 PCB-190 2.47e5 43.63 0% 39.0 40.0 41.0 42.0 ES-180 1.69e7 42.10 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 3.13e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.18e6 ES-170 1.38e7 43.16 2.09e6 0% 39.0 40.0 41.0 42.0 ES-180 1.58e7 42.10 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 2.89e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.02e6 ES-170 1.29e7 43.16 2.01e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.09e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3761, 1911 scc: 848-343 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:13 (CEM) Printed: 31-Mar-2014 19:18 Page 16 of 21 173 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-189 6.17e4 45.80 Abs. Int. 1.65e4 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 1.00e3 8.24e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 4.92e4 45.79 Abs. Int. 1.34e4 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 8.93e2 6.69e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.95e7 45.77 0.00e0 RT Abs. Int. 4.83e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.38e3 2.41e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.90e7 45.77 0.00e0 RT Abs. Int. 4.57e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 3.59e3 2.29e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.47e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.24e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4363, 2841 scc: 848-343 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:14 (CEM) Printed: 31-Mar-2014 19:18 Page 17 of 21 174 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 198/199 3.81e5 43.77 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 8.06e2 PCB-202 1.43e5 39.79 PCB-201 8.66e4 40.57 PCB-197 3.53e4 41.34 Abs. Int. 8.41e4 PCB-196 1.79e5 44.32 PCB-200 6.22e4 41.43 PCB-203 2.10e5 44.49 4.20e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 4.36e5 43.77 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 5.67e2 PCB-202 1.47e5 39.78 PCB-201 8.93e4 40.57 Abs. Int. 1.04e5 PCB-196 2.00e5 44.33 PCB-197 PCB-200 7.39e4 4.17e4 41.43 41.34 PCB-203 2.47e5 44.49 5.20e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.61e7 39.77 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 3.94e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.73e3 1.97e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.79e7 39.77 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.21e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.50e3 2.11e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.09e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6486, 2932 scc: 848-343 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:14 (CEM) Printed: 31-Mar-2014 19:18 Page 18 of 21 175 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-194 2.75e5 47.56 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 8.42e2 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-195 1.06e5 45.61 Abs. Int. 6.52e4 3.26e4 PCB-205 2.11e4 47.96 0% 46.0 47.0 49.0 50.0 PCB-194 3.15e5 47.56 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 9.86e2 48.0 PCB-195 1.15e5 45.61 0.00e0 RT Abs. Int. 7.46e4 3.73e4 PCB-205 2.11e4 47.96 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.16e7 47.54 49.0 50.0 ES-205 1.29e7 47.94 0.00e0 RT Abs. Int. 3.14e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.17e3 1.57e6 0% 46.0 47.0 48.0 JS-194 1.31e7 47.54 Rel. Int. 100% 49.0 50.0 ES-205 1.45e7 47.94 0.00e0 RT Abs. Int. 3.44e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 3.01e3 1.72e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.47e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.24e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1209, 5548 scc: 848-343 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:14 (CEM) Printed: 31-Mar-2014 19:18 Page 19 of 21 176 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-208 1.90e5 45.41 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.03e3 Abs. Int. 5.03e4 PCB-206 1.76e5 49.42 PCB-207 1.54e5 46.20 2.52e4 0% 46.0 Rel. Int. 100% PCB-208 2.49e5 45.41 47.0 48.0 49.0 PCB-207 2.08e5 46.20 NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.11e3 50.0 Abs. Int. 6.54e4 PCB-206 2.18e5 49.42 3.27e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.29e6 ES-208 1.37e7 45.39 ES-206 8.45e6 49.40 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.57e3 1.65e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 4.28e6 ES-208 1.76e7 45.39 ES-206 1.06e7 49.40 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.67e3 2.14e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.47e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.24e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1857, 9272 scc: 848-343 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:04 Printed: 31-Mar-2014 19:18 Page 20 of 21 177 of 711 SGS-AP ID: A6504_11892_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 27-Mar-2014 00:47:55 User: LKB Datafile: 140326X12 PCB-209 3.60e6 50.86 Rel. Int. 100% Abs. Int. 7.35e5 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 4.56e2 3.67e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 3.11e6 50.86 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.62e5 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 9.24e2 3.31e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.24e7 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.70e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 9.86e2 1.35e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.05e7 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.29e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 1.08e3 1.14e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.41e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.20e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_004.utp_res, saved 31-Mar-2014 16:17 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3735, 4564 scc: 848-343 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:04 (CEM) Printed: 31-Mar-2014 19:18 Page 21 of 21 178 of 711 Lab ID: A6504_11892_PCB_005 ACQ: 27-Mar-2014 01:43:07 LKB Wt/Vol: 0.96 L Client ID: PB056_C-1SWMID-140313-N (DISSOLVED) UTP: 31-Mar-2014 16:34 CEM J-level: 10.4 pg/L Datafile: 140326X13 RPT: 31-Mar-2014 18:58 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.80 NotFnd 35.79 35.24 34.78 34.51 NotFnd 40.93 39.96 NotFnd NotFnd 50.85 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.88 14.17 14.43 20.14 17.51 26.46 20.42 32.79 32.31 25.39 35.77 35.22 34.76 34.48 38.38 36.34 30.34 40.92 39.94 43.64 43.15 42.08 35.22 45.76 39.75 47.92 49.39 45.38 50.82 QC J J J C J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0006 1.0006 1.0006 1.0008 1.0002 1.0004 1.0004 0 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7244 0.8640 0.8793 1.2275 1.0673 1.0789 0.8327 1.3368 1.3174 0.8323 1.1723 1.1545 1.1393 1.1301 1.2578 0.9716 0.8112 1.0941 1.0678 1.1666 0.9080 0.8855 0.7410 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Split: 1 Checkcode: 681-037-MXQ Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.80 0 1.37E+06 0.00E+00 2.59E+06 1.74E+05 5.01E+06 1.37E+05 0.00E+00 1.99E+05 7.02E+04 0.00E+00 0.00E+00 7.65E+05 1.16 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 46.6 ND 110 6.7 199 5.35 ND 9.76 3.06 ND ND 65 4.45E+03 4.45E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 1.79E+03 1.32E+03 1.32E+03 1.32E+03 1.53E+03 1.17E+03 1.58 1.67 1.18 1.08 1.13 1.04 0.899 0.933 0.621 0.701 0.874 1.19 0 +0.1 -0.1 +0.2 0 +0.2 -0.1 +0.4 +0.4 -0.2 +0.4 +0.2 +0.2 +0.2 +0.2 0 -0.2 +0.2 +0.2 0 0 0 -0.2 0 0 0 0 0 0 5.19E+07 5.78E+07 3.06E+07 7.98E+07 3.53E+07 6.24E+07 3.60E+07 5.32E+07 5.14E+07 3.56E+07 4.42E+07 4.49E+07 4.40E+07 4.42E+07 3.86E+07 3.20E+07 4.66E+07 7.74E+07 4.10E+07 3.56E+07 2.43E+07 3.00E+07 3.23E+07 3.46E+07 3.13E+07 2.53E+07 1.78E+07 2.88E+07 2.20E+07 3.29 3.35 1.60 1.56 1.07 1.09 0.75 0.81 0.80 1.59 1.56 1.56 1.59 1.55 1.57 1.29 1.30 1.29 1.29 1.27 1.04 1.07 1.08 1.03 0.91 0.91 0.80 0.80 1.18 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 54 % 66.2 % 72.8 % 95.2 % 86.6 % 84.6 % 94.2 % 86.7 % 84.8 % 110 % 91.3 % 91.4 % 94.2 % 92.4 % 93.2 % 92.3 % 94.8 % 78.2 % 79.5 % 74 % 91.7 % 94.4 % 111 % 93.5 % 104 % 86.8 % 91.8 % 105 % 84.7 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% -0.2 0 0 +0.2 -0.7 -0.5 Page 1 of 5 0.62 0.62 0.62 0.61 1.25 1.35 Printed: 3/31/2014 7:04 PM 179 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0101 0 +0.2 +0.2 6.92E+07 4.63E+07 2.00E+07 1.10 1.56 1.08 1.11 1.03 0.62 99.9 % 102 % 100 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0101 0 +0.2 +0.2 6.92E+07 4.63E+07 2.00E+07 1.10 1.56 1.08 1.85 1.22 0.58 84.5 % 94.1 % 111 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.41 24.52 30.51 37.41 47.52 8.05E+07 4.43E+07 4.03E+07 3.09E+07 2.34E+07 1.56 0.79 1.63 1.26 0.88 5.28E+03 5.28E+03 5.28E+03 5.46E+03 5.46E+03 8.68E+03 8.68E+03 8.68E+03 8.68E+03 8.68E+03 8.68E+03 8.68E+03 8.68E+03 8.68E+03 6.06E+03 6.06E+03 6.06E+03 6.06E+03 6.06E+03 6.06E+03 1.37 1.21 1.34 2.2 1.41 2.1 1.83 1.99 1.99 1.9 1.66 1.9 1.92 1.98 2.62 1.95 2.28 1.67 1.75 3.06 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.90 NotFnd 14.19 14.44 14.62 NotFnd NotFnd 16.81 NotFnd 17.24 NotFnd 19.58 19.85 20.15 17.53 19.29 19.69 19.88 20.01 20.11 J J B J C C J EMPC 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 1.0012 1.0009 1.0011 1.0135 1.0248 1.0506 0.9721 0.9857 1.0006 1.0011 1.1019 1.1245 1.1355 1.1429 1.1486 +0.1 -0.1 0 0 -0.1 +0.1 0 -1.1 -0.2 +0.1 +0.5 +0.1 +0.1 -0.1 +0.1 Page 2 of 5 NON-EMPC 31.4 463 4,650 8,380 2,140 357 65.2 7.41 11.9 6.27E+05 0.00E+00 1.39E+05 3.09E+06 2.10E+05 0.00E+00 0.00E+00 1.31E+06 0.00E+00 5.53E+06 0.00E+00 9.93E+05 4.65E+05 3.13E+06 1.88E+06 2.60E+07 7.15E+06 1.69E+06 1.67E+05 5.65E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 31.4 463 4,660 8,380 2,170 368 88.5 17.2 11.9 3.09 3.18 1.53 SI 1.52 1.64 1.44 1.37 1.55 1.12 1.05 1.03 1.09 0.85 1.06 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 1.36 2.09 2.24 1.26 0.983 0.675 0.924 0.982 2.63 26.4 ND 4.96 170 7.43 ND ND 33.7 ND 136 ND 24.3 11.6 80 96.7 995 321 55.5 5.73 340 Printed: 3/31/2014 7:04 PM 180 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.59 21.74 NotFnd 22.15 22.37 22.65 22.93 23.14 23.49 NotFnd NotFnd NotFnd 26.12 26.48 20.44 22.40 23.02 23.09 23.29 24.55 NotFnd 24.76 24.99 25.25 25.44 25.73 25.91 26.24 26.34 26.53 27.25 27.51 27.88 NotFnd 28.24 28.47 28.76 29.04 NotFnd 29.62 29.81 NotFnd NotFnd NotFnd NotFnd 25.73 NotFnd NotFnd SGS Evironmental Services QC J C C C J C C C C C J J C J Pred RRT Actual RRT Diff Secs 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1761 0.8215 0.8372 0.8456 0.8561 0.8664 0.8745 0.8879 0.9870 1.0009 1.0008 0.9134 0.9385 0.9415 0.9498 1.0009 1.0098 1.0189 1.0295 1.0373 1.0491 1.0564 1.0699 1.0739 1.0819 0.8435 0.8514 0.8629 0.8740 0.8810 0.8902 0.8987 0.9168 0.9228 1.0134 - +0.2 -0.4 -1.3 -0.1 -0.1 -0.7 +1.0 0 -0.2 +0.3 -0.2 -1.5 0 +0.1 -0.1 0 -0.3 +1.2 -0.2 -1.7 -0.9 +0.2 -0.2 +0.2 0 0 0 -0.2 -0.2 -0.2 +0.2 -0.2 0 0 0 Page 3 of 5 Response Ra RRF Conc. / Recv. 8.96E+06 1.34E+05 0.00E+00 5.17E+06 2.03E+06 3.56E+07 3.02E+07 1.05E+07 8.47E+06 0.00E+00 0.00E+00 0.00E+00 4.31E+05 4.42E+06 8.94E+04 5.34E+06 4.62E+06 1.27E+06 1.51E+06 3.29E+07 0.00E+00 8.86E+05 1.88E+07 5.32E+06 2.73E+07 2.59E+06 5.74E+06 1.72E+06 1.14E+07 1.49E+07 1.44E+05 5.46E+05 9.89E+04 0.00E+00 5.90E+05 9.09E+05 3.99E+07 2.11E+07 0.00E+00 1.00E+07 4.84E+06 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.79E+05 0.00E+00 0.00E+00 1.06 1.04 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 275 3.65 ND 136 53.3 894 818 277 239 ND ND ND 12.3 137 3.83 238 227 58.4 83.3 1,490 ND 47 697 242 1,170 84.3 285 93.2 510 461 4.59 16.7 3.32 ND 18.5 27.1 1,330 729 ND 350 168 ND ND ND ND 8.95 ND ND 1.03 1.01 1.00 1.00 1.00 1.04 1.09 0.97 0.86 0.78 0.78 0.80 0.80 0.79 0.80 0.77 0.77 0.79 0.78 0.80 0.80 0.78 0.79 0.76 0.78 0.83 0.75 0.78 0.79 0.80 0.78 0.81 0.68 Noise / Recv. Low DL / Recv. High 6.06E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 2.07E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 2.51E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 4.45E+03 1.52E+03 1.52E+03 2.70E+03 2.70E+03 1.56 1.63 1.61 1.58 1.57 1.51 1.62 1.58 1.69 1.55 1.49 1.65 1.71 1.86 0.704 1.17 1.29 1.21 1.44 1.18 0.899 1.38 0.97 1.19 1.11 0.851 1.29 1.41 1.17 0.805 1.48 1.41 1.55 1.53 1.45 1.38 1.54 1.6 1.63 1.62 1.61 1.36 1.42 1.69 0.576 0.708 1.33 1.58 Printed: 3/31/2014 7:04 PM 181 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.99 28.20 28.32 NotFnd NotFnd 28.75 28.95 29.37 NotFnd 30.02 30.53 30.94 31.04 NotFnd 31.51 32.00 32.10 32.23 NotFnd 32.51 NotFnd NotFnd 34.19 34.40 NotFnd 35.08 NotFnd NotFnd NotFnd NotFnd 30.97 NotFnd NotFnd 33.03 NotFnd 33.51 33.80 33.99 NotFnd NotFnd NotFnd NotFnd 34.88 NotFnd NotFnd 35.84 NotFnd 36.36 SGS Evironmental Services QC J EMPC C C EMPC C J C J C J EMPC C J C J C C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9175 0.9242 0.9282 0.9424 0.9487 0.9625 0.9840 1.0007 1.0140 1.0174 1.0329 1.0489 1.0520 1.0564 1.0656 0.9917 0.9977 1.0091 1.0208 1.0885 1.1043 1.1141 1.1203 1.1495 0.9581 0.9721 -0.2 -0.7 0 -0.2 0 +0.2 -0.2 +1.5 -0.4 +0.2 +1.7 -1.2 -1.0 +0.2 0 +0.4 +0.2 0 +0.2 -0.2 +0.2 -0.2 +0.8 0 -0.2 -1.5 Page 4 of 5 Response Ra RRF Conc. / Recv. 5.39E+06 1.05E+05 4.44E+05 0.00E+00 0.00E+00 1.29E+06 1.90E+06 2.14E+05 0.00E+00 9.87E+05 6.09E+06 2.83E+05 3.42E+06 0.00E+00 5.11E+06 1.50E+05 1.55E+06 8.32E+06 0.00E+00 8.29E+05 0.00E+00 0.00E+00 2.21E+05 4.33E+05 0.00E+00 1.16E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.58E+05 0.00E+00 0.00E+00 4.31E+05 0.00E+00 6.72E+04 1.07E+06 7.29E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.50E+05 0.00E+00 0.00E+00 2.12E+05 0.00E+00 1.27E+06 0.60 0.72 0.63 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 292 5.66 23.8 ND ND 70.7 125 13 ND 55.1 295 20.2 164 ND 247 6.51 75.6 357 ND 56.2 ND ND 9.47 16.7 ND 5.32 ND ND ND ND 11.3 ND ND 26.5 ND 3.96 63.4 5.83 ND ND ND ND 30.2 ND ND 11.9 ND 59.7 0.60 0.61 0.65 0.64 0.62 0.71 0.62 0.62 0.70 0.61 0.61 0.63 0.61 0.59 0.60 1.45 1.29 1.30 1.29 1.14 1.24 1.24 1.19 Noise / Recv. Low DL / Recv. High 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.45 1.44 1.44 1.48 1.49 1.47 1.76 1.62 1.04 1.5 1.3 1.91 1.29 1.09 1.3 1.16 1.3 1.15 1.13 1.82 1.05 1.03 1.15 1.04 1.17 1.28 1.23 0.443 0.513 0.499 0.545 0.538 0.74 0.784 0.662 0.754 0.755 1.02 0.76 0.748 0.881 0.901 0.856 0.801 0.63 0.718 0.584 0.601 Printed: 3/31/2014 7:04 PM 182 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.53 36.88 37.06 37.15 37.43 NotFnd 37.76 38.51 NotFnd NotFnd NotFnd 35.52 NotFnd 36.28 NotFnd 37.81 NotFnd 38.57 NotFnd 39.10 NotFnd 39.29 39.67 NotFnd 40.21 NotFnd NotFnd 42.10 NotFnd 43.17 43.62 39.77 NotFnd NotFnd NotFnd NotFnd 43.77 44.30 44.49 NotFnd 47.54 NotFnd 45.40 46.18 49.41 SGS Evironmental Services QC J J J C J J C J J J EMPC J EMPC J J C C J J J EMPC C J J J EMPC J J J Pred RRT Actual RRT Diff Secs 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 0.9859 0.9908 0.9933 1.0007 1.0096 0.9643 1.0085 1.0301 1.0736 1.0953 1.1102 1.1157 1.1263 1.1416 0.9200 0.9434 0.9532 1.0004 1.1009 1.1145 1.1191 0.9920 1.0005 1.0178 1.0005 -0.2 0 -0.9 -0.2 -0.9 0 +0.7 -0.2 +0.2 +0.7 0 +0.2 +0.2 0 +0.5 +1.8 0 -0.3 -0.2 +1.8 -0.5 +0.5 -0.3 0 0 +0.3 Page 5 of 5 Response Ra RRF Conc. / Recv. 2.26E+05 9.58E+04 7.58E+04 1.34E+05 1.51E+06 0.00E+00 2.19E+05 2.36E+05 0.00E+00 0.00E+00 0.00E+00 9.78E+04 0.00E+00 2.97E+04 0.00E+00 3.39E+04 0.00E+00 2.18E+05 0.00E+00 1.15E+05 0.00E+00 1.51E+05 1.05E+05 0.00E+00 6.69E+04 0.00E+00 0.00E+00 3.95E+05 0.00E+00 1.49E+05 3.71E+04 2.76E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.62E+04 3.19E+04 3.38E+04 0.00E+00 3.67E+04 0.00E+00 4.56E+04 4.74E+04 5.73E+04 1.29 1.31 1.41 1.25 1.27 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 14.6 6.86 4.29 6.38 87.4 ND 9.56 13.5 ND ND ND 5.81 ND 1.66 ND 2.9 ND 13 ND 6.5 ND 10.4 7.6 ND 4.92 ND ND 22.3 ND 11.4 2.06 1.74 ND ND ND ND 6.1 2.78 2.89 ND 3.71 ND 2.93 3.01 6 1.29 1.30 1.12 0.92 0.90 1.20 0.91 1.37 1.10 0.90 1.05 0.95 1.10 0.93 1.16 0.83 0.85 1.16 0.85 0.80 0.82 Noise / Recv. Low DL / Recv. High 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.24E+03 1.32E+03 1.32E+03 1.32E+03 1.09E+03 1.09E+03 1.09E+03 1.09E+03 1.09E+03 1.09E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.68E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.29E+03 1.29E+03 1.29E+03 2.92E+03 2.92E+03 2.92E+03 0.825 0.914 0.724 0.606 0.739 0.656 0.558 0.815 0.672 0.675 0.553 0.647 0.673 0.609 0.65 0.931 1.08 1.01 0.985 0.959 1.12 1.17 1.23 1.09 1.25 1.19 0.917 0.956 0.872 1.34 0.964 0.888 0.838 0.901 0.859 0.862 1.3 1.23 1.2 1.52 1.4 1.08 1.98 1.96 3.27 Printed: 3/31/2014 7:04 PM 183 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.50e7 2.75e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.56e7 7.78e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.33e7 6.64e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.08e7 1.04e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.15e7 5.73e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.56e6 1.28e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.48e6 1.24e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 681-037 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:19 Page 1 of 21 184 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-1 4.74e5 11.90 Rel. Int. 100% Abs. Int. 1.83e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.48e3 9.14e4 PCB-3 1.06e5 14.19 0% 11.0 Rel. Int. 100% 12.0 13.0 14.0 15.0 Abs. Int. 7.91e4 PCB-1 1.53e5 11.90 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 2.80e3 3.95e4 PCB-3 3.33e4 14.18 0% 11.0 12.0 13.0 ES-1 3.98e7 11.88 Rel. Int. 100% 0.00e0 16.0 RT 14.0 15.0 ES-3 4.45e7 14.17 0.00e0 16.0 RT Abs. Int. 1.62e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 4.77e3 8.08e6 0% 11.0 12.0 13.0 ES-1 1.21e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 1.33e7 14.17 0.00e0 16.0 RT Abs. Int. 5.01e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.80e4 2.51e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.50e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.75e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3420, 1465 scc: 681-037 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:22 (CEM) Printed: 31-Mar-2014 19:19 Page 2 of 21 185 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 Abs. Int. 6.49e5 PCB-4 1.87e6 14.44 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 3.33e3 3.24e5 PCB-10 1.28e5 SI 14.62 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 1.22e6 14.44 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.33e5 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.42e4 2.17e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.88e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.45e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.20e3 3.23e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.18e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.14e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.02e3 2.07e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.50e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.75e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2106, 7287 scc: 681-037 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:22 (CEM) Printed: 31-Mar-2014 19:19 Page 3 of 21 186 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-8 3.43e6 17.24 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 5.29e3 Abs. Int. 1.09e6 PCB-6 7.87e5 16.81 PCB-11 5.85e5 19.58 PCB-15 1.90e6 20.15 5.46e5 13/12 2.69e5 19.85 0% 17.0 18.0 19.0 20.0 21.0 PCB-8 2.09e6 17.23 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.91e4 Abs. Int. 6.70e5 PCB-6 5.19e5 16.81 PCB-11 4.07e5 19.57 PCB-15 1.23e6 20.15 3.35e5 13/12 1.96e5 19.84 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 4.91e7 16.41 20.0 21.0 ES-15 4.86e7 20.14 0.00e0 RT Abs. Int. 1.48e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.53e4 7.41e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 3.14e7 16.40 20.0 21.0 ES-15 3.11e7 20.14 0.00e0 RT Abs. Int. 9.65e6 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.60e3 4.83e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.56e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.78e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1618, 3242 scc: 681-037 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:23 (CEM) Printed: 31-Mar-2014 19:19 Page 4 of 21 187 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 Abs. Int. 3.82e6 30/18 1.33e7 19.29 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.20e3 PCB-17 3.64e6 19.69 PCB-19 9.93e5 17.53 PCB-27 8.80e5 19.88 PCB-16 2.91e6 20.11 PCB-32 4.62e6 20.59 1.91e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 3.69e6 30/18 1.27e7 19.29 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.86e3 PCB-17 3.52e6 19.69 PCB-19 8.86e5 17.53 PCB-27 8.05e5 19.88 PCB-16 2.75e6 20.11 PCB-32 4.35e6 20.59 1.84e6 0% 17.0 18.0 19.0 0.00e0 RT 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e7 ES-19 1.82e7 17.51 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.61e4 5.13e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.70e7 17.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.12e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.85e4 2.56e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.56e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.78e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9140, 1335 scc: 681-037 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:23 (CEM) Printed: 31-Mar-2014 19:19 Page 5 of 21 188 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-31 1.78e7 28/20 22.65 1.51e7 22.93 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 3.83e3 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 26/29 2.62e6 22.15 Abs. Int. 4.74e6 21/33 5.25e6 23.14 PCB-25 1.02e6 22.37 2.37e6 PCB-22 4.32e6 23.49 PCB-37 2.18e6 26.48 0% 22.0 23.0 PCB-31 1.78e7 22.65 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.31e3 26/29 2.55e6 22.15 PCB-25 1.01e6 22.37 24.0 25.0 0.00e0 RT 26.0 Abs. Int. 4.74e6 28/20 1.51e7 22.92 21/33 5.25e6 23.14 2.37e6 PCB-22 4.15e6 23.49 PCB-37 2.24e6 26.48 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 3.62e7 22.90 Rel. Int. 100% ES-37 3.25e7 26.46 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 6.21e4 Abs. Int. 9.65e6 4.83e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 3.30e7 22.90 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 2.99e7 26.46 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 3.13e4 Abs. Int. 8.85e6 4.42e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.64e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9829, 5263 scc: 681-037 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:21 Printed: 31-Mar-2014 19:19 Page 6 of 21 189 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-54 4.12e4 20.44 Rel. Int. 100% Abs. Int. 9.82e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.03e3 4.91e3 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 4.82e4 20.44 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.04e3 7.60e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.54e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.87e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 7.20e3 2.43e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.05e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.24e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 5.22e3 3.12e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.56e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.78e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3972, 7652 scc: 681-037 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:29 (CEM) Printed: 31-Mar-2014 19:19 Page 7 of 21 190 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-52 1.45e7 24.55 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.13e3 50/53 2.34e6 22.40 69/49 8.18e6 24.99 PCB-45 2.03e6 23.02 44/47… 1.21e7 25.44 PCB-48 2.32e6 25.25 PCB-51 5.63e5 23.09 Abs. Int. 3.87e6 PCB-42 2.55e6 25.91 71/40 4.99e6 26.34 PCB-64 6.57e6 26.53 0% 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 PCB-52 1.84e7 24.55 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.38e3 50/53 3.00e6 22.40 69/49 1.06e7 24.99 PCB-45 2.59e6 23.02 44/47… 1.53e7 25.44 PCB-48 3.00e6 25.25 PCB-51 7.03e5 23.09 Abs. Int. 4.98e6 PCB-42 3.19e6 25.91 59/62… 1.45e6 25.73 23.0 24.0 25.0 26.0 JS-52 1.96e7 24.52 Rel. Int. 100% 71/40 6.42e6 26.34 PCB-64 8.37e6 26.53 2.49e6 PCB-41 9.55e5 26.24 0% 22.0 1.94e6 0.00e0 RT Abs. Int. 5.34e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.45e4 2.67e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.48e7 24.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.47e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 7.93e3 3.24e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.64e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6113, 3027 scc: 681-037 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:23 (CEM) Printed: 31-Mar-2014 19:19 Page 8 of 21 191 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 Abs. Int. 3.30e6 61/70... 1.76e7 PCB-66 28.76 9.39e6 29.04 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.51e3 PCB-56 4.41e6 29.62 PCB-60 2.16e6 29.81 1.65e6 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 4.13e6 61/70... 2.23e7 PCB-66 28.76 1.17e7 29.04 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.95e3 PCB-56 5.62e6 29.62 PCB-60 2.68e6 29.81 2.07e6 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.29e7 32.31 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.50e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 5.69e6 ES-77 2.37e7 32.79 2.84e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 2.86e7 32.31 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.07e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.17e6 ES-77 2.94e7 32.79 3.58e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.08e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.04e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1083, 1794 scc: 681-037 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:24 (CEM) Printed: 31-Mar-2014 19:19 Page 9 of 21 192 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-96 7.25e4 25.73 Rel. Int. 100% Abs. Int. 2.36e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 7.29e2 1.18e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 1.06e5 25.73 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.14e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 7.89e2 1.57e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.19e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.88e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.50e3 2.94e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.37e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.77e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.52e3 1.89e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.64e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3519, 4847 scc: 681-037 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:21 Printed: 31-Mar-2014 19:19 Page 10 of 21 193 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.01e3 113/90… 2.33e6 30.53 PCB-95 2.03e6 27.99 PCB-91 4.81e5 28.75 PCB-84 7.24e5 28.95 PCB-92 3.84e5 30.02 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-110 3.14e6 32.23 Abs. Int. 7.88e5 PCB-118 1.91e6 34.78 PCB-99 1.31e6108/119... 31.04 1.95e6 116/85 31.51 5.90e5 PCB-83 32.10 1.25e5 30.94 PCB-82 3.21e5 32.51 PCB-109 1.61e5 34.40 PCB-105 9.89e5 35.79 3.94e5 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.69e3 32.0 113/90… 3.77e6 30.53 PCB-95 3.36e6 27.99 PCB-84 PCB-91 1.18e6 8.06e5 28.94 28.75 36.0 38.0 PCB-110 5.18e6 32.23 PCB-99 2.11e6108/119... 31.04 3.16e6 116/85 31.51 9.65e5 32.09 PCB-92 6.03e5 30.02 34.0 Abs. Int. 1.25e6 PCB-118 3.10e6 34.78 PCB-82 5.08e5 32.51 PCB-109 2.72e5 34.40 PCB-105 1.60e6 35.79 6.25e5 0% 28.0 30.0 32.0 34.0 CS/SS-111 2.82e7 32.80 JS-101 2.50e7 30.51 Rel. Int. 100% 0.00e0 RT PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.87e3 ES-123 2.69e7 34.48 36.0 ES-114 2.74e7 35.22 38.0 0.00e0 RT Abs. Int. 7.16e6 ES-105 2.69e7 35.77 3.58e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.81e7 32.80 JS-101 1.53e7 30.51 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 1.72e3 ES-123 ES-118 1.73e7 1.70e7 34.48 34.76 36.0 38.0 0.00e0 RT Abs. Int. 4.58e6 ES-105 1.73e7 35.77 2.29e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.08e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.04e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0322, 3762 scc: 681-037 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:27 (CEM) Printed: 31-Mar-2014 19:19 Page 11 of 21 194 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 Rel. Int. 100% Abs. Int. 3.15e4 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 8.36e2 1.58e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 5.96e4 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 9.56e2 2.98e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.73e6 ES-126 2.36e7 38.38 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 3.25e3 2.86e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.76e6 ES-126 1.50e7 38.38 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 4.85e3 1.88e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.15e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.73e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2255, 9659 scc: 681-037 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:21 Printed: 31-Mar-2014 19:19 Page 12 of 21 195 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 153/168 6.90e5 36.36 147/149 6.05e5 33.80 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.07e2 PCB-136 1.66e5 30.97 PCB-132 2.50e5 34.88 151/135 2.43e5 33.03 163/138… 8.46e5 37.43 PCB-141 1.27e5 PCB-137 36.53 4.43e4 37.06 PCB-146 1.17e5 35.84 Abs. Int. 2.14e5 PCB-158 1.23e5 37.76 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% 36.0 153/168 5.80e5 36.36 147/149 4.67e5 33.80 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 6.28e2 PCB-132 2.01e5 34.88 151/135 1.88e5 33.03 PCB-136 1.15e5 30.97 38.0 163/138… 6.64e5 37.43 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.63e7 30.34 Rel. Int. 100% ES-153 1.80e7 36.34 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.60e3 0.00e0 RT Abs. Int. 1.68e5 PCB-141 PCB-158 9.88e4 PCB-164 9.56e4 5.96e4 36.53 37.76 37.15 PCB-146 9.49e4 35.84 1.07e5 8.38e4 0.00e0 RT Abs. Int. 6.50e6 JS-138 1.72e7 37.41 3.25e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.03e7 30.34 Rel. Int. 100% ES-153 1.40e7 36.34 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.39e3 0.00e0 RT Abs. Int. 5.11e6 JS-138 1.37e7 37.41 2.56e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.08e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.04e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7812, 0743 scc: 681-037 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:27 (CEM) Printed: 31-Mar-2014 19:19 Page 13 of 21 196 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 Abs. Int. 3.16e4 156/157 1.11e5 40.93 128/166 1.33e5 38.51 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 7.02e2 PCB-167 4.03e4 39.96 1.58e4 0% 39.0 Rel. Int. 100% 40.0 128/166 1.03e5 38.51 41.0 42.0 43.0 44.0 45.0 Abs. Int. 2.57e4 156/157 8.83e4 40.93 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 6.20e2 PCB-167 2.99e4 39.96 1.29e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.31e7 39.94 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 4.46e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.36e7 40.92 0.00e0 RT Abs. Int. 7.57e6 ES-169 1.99e7 43.64 3.78e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.79e7 39.94 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 2.67e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.38e7 40.92 0.00e0 RT Abs. Int. 5.93e6 ES-169 1.57e7 43.64 2.96e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.15e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.73e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1242, 7711 scc: 681-037 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:27 (CEM) Printed: 31-Mar-2014 19:19 Page 14 of 21 197 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-179 5.16e4 35.52 Rel. Int. 100% Abs. Int. 1.47e4 PCB-176 1.42e4 36.28 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 4.43e2 PCB-178 1.60e4 37.81 7.33e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 4.62e4 35.52 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.51e2 Abs. Int. 1.52e4 PCB-176 1.55e4 36.28 PCB-178 1.79e4 37.80 7.59e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.68e7 35.22 Rel. Int. 100% CS/SS-178 1.04e7 37.78 2.11e6 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.55e7 35.22 Rel. Int. 100% CS/SS-178 9.63e6 37.78 2.05e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 4.10e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.57e3 31.0 0.00e0 RT Abs. Int. 4.21e6 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.17e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.02e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1535, 6028 scc: 681-037 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:28 (CEM) Printed: 31-Mar-2014 19:19 Page 15 of 21 198 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 180/193 2.03e5 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 8.42e2 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-187 1.29e5 38.57 PCB-174 1.01e5 39.29 PCB-177 5.50e4 PCB-183 39.67 5.49e4 39.10 Abs. Int. 4.68e4 PCB-170 7.26e4 43.17 171/173 3.17e4 40.21 2.34e4 PCB-190 1.94e4 43.62 0% 39.0 40.0 41.0 43.0 44.0 45.0 180/193 1.93e5 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 8.34e2 42.0 PCB-187 1.07e5 38.57 PCB-174 PCB-183 7.38e4 6.01e4 39.29 39.10 PCB-177 4.98e4 39.67 Abs. Int. 4.80e4 PCB-170 7.62e4 43.17 171/173 3.52e4 40.21 2.40e4 PCB-190 1.77e4 43.62 0% 39.0 40.0 41.0 42.0 ES-180 1.55e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.46e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.83e6 ES-170 1.24e7 43.15 1.92e6 0% 39.0 40.0 41.0 42.0 ES-180 1.44e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 1.58e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.70e6 ES-170 1.19e7 43.15 1.85e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.15e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.73e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4378, 5939 scc: 681-037 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:28 (CEM) Printed: 31-Mar-2014 19:19 Page 16 of 21 199 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 Rel. Int. 100% Abs. Int. 2.97e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 8.66e2 1.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 2.68e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 6.60e2 1.34e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.75e7 45.76 0.00e0 RT Abs. Int. 4.29e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 3.48e3 2.14e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.71e7 45.76 0.00e0 RT Abs. Int. 4.10e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.98e3 2.05e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.56e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.28e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8084, 3192 scc: 681-037 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:28 (CEM) Printed: 31-Mar-2014 19:19 Page 17 of 21 200 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 198/199 4.07e4 43.77 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 6.84e2 PCB-202 1.33e4 39.77 Abs. Int. 9.98e3 PCB-196 1.44e4 44.30 PCB-203 1.56e4 44.49 4.99e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 3.51e4 43.75 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.61e2 Abs. Int. 9.76e3 PCB-196 1.75e4 44.30 PCB-202 1.43e4 39.77 PCB-203 1.83e4 44.48 4.88e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.49e7 39.75 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 3.56e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.73e3 1.78e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.64e7 39.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.81e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.17e3 1.90e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.15e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.73e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7206, 8907 scc: 681-037 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:28 (CEM) Printed: 31-Mar-2014 19:19 Page 18 of 21 201 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-194 2.25e4 47.54 Rel. Int. 100% Abs. Int. 7.72e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 5.77e2 3.86e3 0% 46.0 47.0 48.0 49.0 50.0 PCB-194 1.94e4 47.54 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.69e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 7.17e2 3.85e3 0% 46.0 47.0 48.0 JS-194 1.10e7 47.52 Rel. Int. 100% 49.0 50.0 ES-205 1.20e7 47.92 0.00e0 RT Abs. Int. 2.81e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 1.97e3 1.41e6 0% 46.0 47.0 48.0 JS-194 1.24e7 47.52 Rel. Int. 100% 49.0 50.0 ES-205 1.32e7 47.92 0.00e0 RT Abs. Int. 3.05e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.91e3 1.52e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.56e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.28e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7779, 5913 scc: 681-037 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:29 (CEM) Printed: 31-Mar-2014 19:19 Page 19 of 21 202 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 8.88e2 PCB-208 2.09e4 45.40 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-206 2.58e4 49.41 PCB-207 2.10e4 46.18 Abs. Int. 8.65e3 4.33e3 0% 46.0 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.03e3 PCB-208 2.47e4 45.40 47.0 48.0 49.0 50.0 PCB-206 3.14e4 49.41 PCB-207 2.64e4 46.18 Abs. Int. 8.34e3 4.17e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.03e6 ES-208 1.28e7 45.38 ES-206 7.90e6 49.39 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.71e3 1.51e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.73e6 ES-208 1.60e7 45.38 ES-206 9.91e6 49.39 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.75e3 1.87e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.56e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.28e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1899, 7566 scc: 681-037 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:29 (CEM) Printed: 31-Mar-2014 19:19 Page 20 of 21 203 of 711 SGS-AP ID: A6504_11892_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB056_C-1SWMID-140313-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 27-Mar-2014 01:43:07 User: LKB Datafile: 140326X13 PCB-209 4.11e5 50.85 Rel. Int. 100% Abs. Int. 8.84e4 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 5.72e2 4.42e4 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 3.54e5 50.85 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.81e4 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.02e2 3.90e4 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.19e7 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.49e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 6.50e2 1.25e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.01e7 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.18e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 1.03e3 1.09e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.48e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.24e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_005.utp_res, saved 31-Mar-2014 16:34 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5966, 3407 scc: 681-037 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:29 (CEM) Printed: 31-Mar-2014 19:19 Page 21 of 21 204 of 711 Lab ID: A6504_11892_PCB_006 ACQ: 27-Mar-2014 02:38:21 LKB Wt/Vol: 0.93 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Client ID: EF006.1-1SWMID-140313-N (TOTAL) UTP: 31-Mar-2014 18:01 CEM J-level: 10.7 pg/L Datafile: 140326X14 RPT: 31-Mar-2014 18:58 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.80 NotFnd 35.78 35.24 34.78 NotFnd NotFnd 40.93 39.95 NotFnd NotFnd 50.84 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.88 14.16 14.42 20.13 17.50 26.45 20.41 32.78 32.30 25.39 35.76 35.22 34.75 34.47 38.37 36.34 30.34 40.92 39.94 43.63 43.15 42.08 35.21 45.76 39.75 47.92 49.38 45.37 50.82 QC J EMPC J C J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0007 1.0004 1.0006 1.0003 1.0005 1.0004 0 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7243 0.8639 0.8793 1.2276 1.0673 1.0789 0.8326 1.3370 1.3176 0.8322 1.1723 1.1546 1.1394 1.1302 1.2579 0.9716 0.8111 1.0941 1.0678 1.1666 0.9080 0.8855 0.7410 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 Split: 1 Checkcode: 889-569-FHN Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.75 0 3.77E+05 0.00E+00 1.21E+06 6.48E+04 2.22E+06 0.00E+00 0.00E+00 2.40E+05 9.33E+04 0.00E+00 0.00E+00 4.32E+05 1.15 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 11.4 ND 43.9 2.2 76.9 ND ND 10.8 3.58 ND ND 41.4 4.06E+03 4.06E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.46E+03 1.86E+03 1.86E+03 1.86E+03 1.80E+03 1.15E+03 1.26 1.25 0.833 0.778 0.78 0.779 1.07 1.17 0.744 0.971 1.03 1.27 -0.1 0 -0.1 +0.4 0 +0.2 -0.2 +0.8 +0.8 -0.3 +0.4 +0.4 +0.4 +0.4 +0.5 0 -0.4 +0.2 +0.2 0 0 0 -0.2 0 0 0 0 0 0 4.98E+07 5.48E+07 2.85E+07 8.28E+07 3.30E+07 7.05E+07 3.59E+07 6.18E+07 6.01E+07 3.86E+07 5.30E+07 5.26E+07 5.20E+07 5.11E+07 4.50E+07 3.74E+07 5.23E+07 8.72E+07 4.81E+07 3.90E+07 2.73E+07 3.37E+07 3.65E+07 3.69E+07 3.57E+07 2.48E+07 1.69E+07 3.10E+07 2.01E+07 3.27 3.40 1.61 1.55 1.06 1.13 0.77 0.80 0.81 1.61 1.58 1.57 1.59 1.59 1.55 1.29 1.30 1.26 1.28 1.26 1.09 1.06 1.10 1.04 0.92 0.90 0.80 0.80 1.19 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 42.1 % 51 % 55.1 % 80.3 % 65.9 % 79.4 % 78 % 83.6 % 82.3 % 99.9 % 91.7 % 89.8 % 93.3 % 89.5 % 91 % 87.6 % 86.5 % 71.5 % 75.7 % 65.7 % 89.2 % 92 % 102 % 86.3 % 96.7 % 73.9 % 75.5 % 97.8 % 67.1 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 0 -0.4 0 -0.5 -0.2 Page 1 of 5 0.64 0.74 0.64 1.21 1.20 Printed: 3/31/2014 7:04 PM 205 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 8.36E+07 5.67E+07 2.48E+07 1.09 1.59 1.07 1.11 1.03 0.62 107 % 108 % 110 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 8.36E+07 5.67E+07 2.48E+07 1.09 1.59 1.07 1.85 1.22 0.58 84.7 % 96.4 % 112 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.40 24.52 30.50 37.40 47.52 9.91E+07 5.34E+07 4.81E+07 3.81E+07 2.70E+07 1.56 0.78 1.57 1.27 0.90 5.21E+03 5.21E+03 5.21E+03 6.52E+03 6.52E+03 6.77E+03 6.77E+03 6.77E+03 6.77E+03 6.77E+03 6.77E+03 6.77E+03 6.77E+03 6.77E+03 5.78E+03 5.78E+03 5.78E+03 5.78E+03 5.78E+03 5.78E+03 1.45 1.32 1.47 2.95 1.89 1.61 1.41 1.53 1.53 1.46 1.28 1.45 1.47 1.52 2.77 2.07 2.42 1.77 1.85 3.24 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services NotFnd NotFnd NotFnd 14.43 NotFnd NotFnd NotFnd NotFnd NotFnd 17.23 NotFnd 19.57 NotFnd 20.14 17.52 19.29 19.68 19.87 NotFnd 20.10 J J B C J J C J 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 1.0012 1.0507 0.9722 1.0008 1.0012 1.1020 1.1247 1.1354 1.1486 +0.1 +0.2 +0.1 0 +0.2 +0.6 +0.4 0 +0.1 Page 2 of 5 Noise / Recv. Low DL / Recv. High EMPC 0 43.7 276 1,000 638 337 123 26.6 6.67 NON-EMPC 0 43.7 276 997 634 334 120 10.7 4.15 0.00E+00 0.00E+00 0.00E+00 1.42E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.09E+05 0.00E+00 9.51E+05 0.00E+00 2.65E+05 1.44E+05 1.26E+06 3.71E+05 1.31E+05 0.00E+00 2.57E+05 RRF Conc. / Recv. SI SI 1.52 SI 1.07 1.07 1.11 0.96 0.99 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 1.46 2.23 2.21 0.978 0.785 0.818 0.865 1.05 2.87 ND ND ND 8.69 ND ND ND ND ND 5.1 ND 23.1 ND 6.74 8.17 53.2 18.3 4.75 ND 17 Printed: 3/31/2014 7:04 PM 206 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.58 NotFnd NotFnd 22.14 22.36 22.64 22.92 23.13 23.48 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 22.39 23.00 23.07 23.29 24.54 NotFnd NotFnd 24.98 25.24 25.44 25.73 25.90 26.23 26.33 26.53 NotFnd 27.50 NotFnd NotFnd NotFnd NotFnd 28.77 29.03 NotFnd 29.61 29.81 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J C J C J C J C J C C J C J EMPC C C Pred RRT Actual RRT Diff Secs 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1761 0.8371 0.8454 0.8560 0.8663 0.8743 0.8878 0.9134 0.9380 0.9411 0.9498 1.0009 1.0189 1.0295 1.0377 1.0493 1.0565 1.0698 1.0740 1.0820 0.8513 0.8905 0.8987 0.9167 0.9228 - +0.2 -1.5 -0.4 -0.3 -0.8 +0.7 -0.1 -1.5 -0.7 -0.4 -0.1 0 +1.2 -0.2 -1.1 -0.6 +0.3 -0.3 +0.3 +0.2 -0.2 +0.7 -0.2 -0.2 0 Page 3 of 5 Response Ra RRF Conc. / Recv. 5.72E+05 0.00E+00 0.00E+00 3.93E+05 2.54E+05 2.04E+06 2.74E+06 4.65E+05 5.38E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.61E+05 3.20E+05 5.34E+05 1.20E+05 4.54E+06 0.00E+00 0.00E+00 2.51E+06 3.52E+05 3.73E+06 3.85E+05 6.02E+05 1.15E+05 1.32E+06 2.15E+06 0.00E+00 8.68E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.05E+06 3.89E+06 0.00E+00 1.38E+06 9.09E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.95 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 19.3 ND ND 9.45 6.08 46.7 67.7 11.2 13.9 ND ND ND ND ND ND 18.2 13.9 21.7 5.86 182 ND ND 82.4 14.1 140 11.1 26.3 5.49 51.8 58.3 ND 23.4 ND ND ND ND 148 118 ND 42.5 27.8 ND ND ND ND ND ND ND 0.92 1.07 1.01 0.98 1.11 1.04 0.84 0.74 0.83 0.77 0.76 0.80 0.88 0.79 0.75 0.76 0.92 0.84 0.77 0.81 0.79 0.80 0.80 0.85 Noise / Recv. Low DL / Recv. High 5.78E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 5.89E+03 2.00E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 2.15E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 4.06E+03 1.28E+03 1.28E+03 2.22E+03 2.22E+03 1.65 1.44 1.42 1.4 1.39 1.33 1.43 1.4 1.5 1.37 1.32 1.46 1.51 1.64 0.732 0.817 0.901 0.845 1.01 0.83 0.63 0.97 0.68 0.831 0.781 0.596 0.908 0.99 0.818 0.564 1.1 1.06 1.16 1.15 1.08 1.03 1.15 1.19 1.22 1.21 1.2 1.01 1.06 1.26 0.472 0.58 0.991 1.18 Printed: 3/31/2014 7:04 PM 207 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.99 NotFnd 28.31 NotFnd NotFnd 28.75 28.94 29.35 NotFnd 30.02 30.53 30.94 31.03 NotFnd 31.51 NotFnd 32.08 32.22 NotFnd 32.50 NotFnd NotFnd 34.18 34.40 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.96 NotFnd NotFnd 33.03 NotFnd 33.51 33.80 33.99 NotFnd NotFnd NotFnd NotFnd 34.88 NotFnd NotFnd 35.84 NotFnd 36.36 SGS Evironmental Services QC C J J EMPC C J C C J C J J J C J EMPC C J C C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9175 0.9280 0.9425 0.9488 0.9623 0.9840 1.0007 1.0142 1.0174 1.0330 1.0518 1.0564 1.0656 0.9915 0.9977 1.0207 1.0886 1.1045 1.1142 1.1203 1.1497 0.9581 0.9722 -0.2 -0.3 0 +0.2 -0.2 -0.2 +1.5 0 +0.2 +1.9 -1.3 +0.2 0 0 +0.2 0 0 +0.6 0 +0.8 +0.4 -0.2 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.37E+06 0.00E+00 8.95E+04 0.00E+00 0.00E+00 3.40E+05 4.54E+05 3.46E+04 0.00E+00 3.64E+05 2.07E+06 1.05E+05 1.23E+06 0.00E+00 1.57E+06 0.00E+00 6.24E+05 3.01E+06 0.00E+00 2.08E+05 0.00E+00 0.00E+00 8.83E+04 2.13E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.69E+05 0.00E+00 0.00E+00 3.60E+05 0.00E+00 4.37E+04 9.38E+05 7.68E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.07E+05 0.00E+00 0.00E+00 2.44E+05 0.00E+00 1.44E+06 0.65 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 66 ND 4.27 ND ND 16.7 26.5 1.86 ND 18.1 89.2 6.69 52.5 ND 67.4 ND 27 115 ND 12.6 ND ND 3.37 7.32 ND ND ND ND ND ND 6.76 ND ND 19.5 ND 2.27 48.9 5.42 ND ND ND ND 24 ND ND 12.1 ND 59.6 0.69 0.63 0.62 0.72 0.63 0.62 0.66 0.64 0.60 0.63 0.61 0.55 0.65 0.59 1.15 1.18 1.76 1.31 1.34 1.35 1.12 1.26 Noise / Recv. Low DL / Recv. High 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 2.22E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.09 1.08 1.07 1.11 1.12 1.1 1.31 1.21 0.775 1.12 0.97 1.43 0.96 0.816 0.967 0.868 0.974 0.859 0.842 1.36 0.785 0.773 0.859 0.773 0.872 0.927 0.871 0.389 0.451 0.438 0.478 0.472 0.625 0.663 0.559 0.636 0.638 0.863 0.642 0.632 0.744 0.761 0.723 0.677 0.532 0.606 0.494 0.507 Printed: 3/31/2014 7:04 PM 208 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.53 36.87 37.06 37.15 37.43 NotFnd 37.76 38.51 NotFnd NotFnd NotFnd 35.52 NotFnd 36.27 NotFnd 37.79 NotFnd 38.57 NotFnd 39.10 NotFnd 39.29 39.66 NotFnd 40.20 41.54 NotFnd 42.10 NotFnd 43.17 43.62 39.77 NotFnd NotFnd NotFnd NotFnd 43.75 44.31 44.48 NotFnd 47.54 NotFnd 45.40 46.18 NotFnd SGS Evironmental Services QC J J J C J J C J J J J J J C J C J EMPC J J EMPC C J J J EMPC J J EMPC Pred RRT Actual RRT Diff Secs 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 0.9859 0.9910 0.9933 1.0007 1.0096 0.9643 1.0086 1.0299 1.0732 1.0953 1.1103 1.1157 1.1263 1.1416 0.9078 0.9200 0.9433 0.9533 1.0005 1.1007 1.1148 1.1190 0.9920 1.0005 1.0178 - -0.2 0 -0.4 -0.2 -0.9 0 +0.7 0 -0.2 -0.2 0 +0.5 +0.2 0 +0.5 -0.2 +1.8 -0.3 0 0 +1.3 +0.3 +0.3 -0.3 0 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 2.15E+05 1.08E+05 8.72E+04 1.46E+05 1.77E+06 0.00E+00 2.25E+05 2.99E+05 0.00E+00 0.00E+00 0.00E+00 1.02E+05 0.00E+00 2.58E+04 0.00E+00 5.09E+04 0.00E+00 3.35E+05 0.00E+00 1.69E+05 0.00E+00 2.18E+05 1.26E+05 0.00E+00 8.14E+04 5.39E+04 0.00E+00 6.40E+05 0.00E+00 2.55E+05 5.76E+04 4.47E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.04E+05 5.07E+04 5.42E+04 0.00E+00 6.79E+04 0.00E+00 6.74E+04 4.15E+04 0.00E+00 1.41 1.13 1.31 1.11 1.32 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 12.2 6.79 4.35 6.1 90.5 ND 8.68 15.1 ND ND ND 5.55 ND 1.32 ND 3.97 ND 18.3 ND 8.74 ND 13.8 8.34 ND 5.48 3.46 ND 33 ND 18 2.93 2.55 ND ND ND ND 8.64 3.99 4.18 ND 7.22 ND 4.15 2.52 ND 1.31 1.30 0.89 0.96 1.06 0.96 0.98 0.96 1.08 1.01 1.01 1.06 0.97 1.42 0.76 1.11 1.00 0.87 1.10 0.70 0.90 Noise / Recv. Low DL / Recv. High 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.18E+03 1.86E+03 1.86E+03 1.86E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.50E+03 1.50E+03 1.50E+03 3.12E+03 3.12E+03 3.12E+03 0.697 0.772 0.611 0.512 0.624 0.554 0.471 0.977 0.805 0.809 0.541 0.632 0.659 0.596 0.636 0.91 0.897 0.841 0.82 0.798 0.933 0.974 1.02 0.908 1.04 0.991 0.763 0.796 0.726 1.07 0.772 0.793 0.748 0.805 0.767 0.77 1.16 1.09 1.07 1.86 1.71 1.31 2.06 2.04 3.69 Printed: 3/31/2014 7:04 PM 209 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.64e7 2.82e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.54e7 7.71e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.29e7 6.47e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.05e7 1.02e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.13e7 5.67e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.45e6 1.23e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.36e6 1.18e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 889-569 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:19 Page 1 of 21 210 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Rel. Int. 100% Abs. Int. 3.92e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: B 4σ 2.06e3 1.96e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.72e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: B 4σ 3.15e3 3.36e4 0% 11.0 12.0 13.0 ES-1 3.81e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 4.24e7 14.16 0.00e0 16.0 RT Abs. Int. 1.55e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 6.96e3 7.76e6 0% 11.0 12.0 13.0 ES-1 1.17e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 1.25e7 14.16 0.00e0 16.0 RT Abs. Int. 4.75e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.02e4 2.38e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.64e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.82e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4925, 9824 scc: 889-569 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:40 Printed: 31-Mar-2014 19:19 Page 2 of 21 211 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 PCB-4 8.68e4 SI 14.43 Rel. Int. 100% Abs. Int. 3.97e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 3.97e3 1.99e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.69e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 1.29e4 1.84e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.76e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.94e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.14e3 2.97e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.09e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.74e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.61e3 1.87e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.64e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.82e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1538, 9240 scc: 889-569 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:40 (CEM) Printed: 31-Mar-2014 19:19 Page 3 of 21 212 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 PCB-11 5.73e5 19.57 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.13e3 PCB-8 1.27e5 SI 17.23 Abs. Int. 1.41e5 PCB-15 1.62e5 SI 20.14 7.07e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% Abs. Int. 2.52e5 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.92e4 PCB-11 3.78e5 19.57 1.26e5 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 6.04e7 16.40 20.0 21.0 0.00e0 RT Abs. Int. 1.86e7 ES-15 5.03e7 20.13 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 2.18e4 9.28e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 3.87e7 16.40 20.0 21.0 Abs. Int. 1.18e7 ES-15 3.24e7 20.13 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 4.09e3 0.00e0 RT 5.92e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.54e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.71e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2500, 1152 scc: 889-569 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:59 (CEM) Printed: 31-Mar-2014 19:19 Page 4 of 21 213 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Abs. Int. 1.85e5 30/18 6.52e5 19.29 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.52e3 PCB-17 1.96e5 19.68 PCB-19 7.44e4 17.52 PCB-27 6.43e4 19.87 PCB-16 1.28e5 20.10 PCB-32 2.78e5 20.58 9.24e4 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 1.87e5 30/18 6.08e5 19.28 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.26e3 PCB-17 1.76e5 19.68 PCB-19 6.99e4 17.52 PCB-27 6.67e4 19.87 PCB-16 1.29e5 20.11 PCB-32 2.93e5 20.58 9.37e4 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 6.78e6 ES-19 1.70e7 17.50 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.03e4 0.00e0 RT 3.39e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.60e7 17.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.69e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 3.01e4 2.34e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.54e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.71e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2553, 1852 scc: 889-569 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:59 (CEM) Printed: 31-Mar-2014 19:19 Page 5 of 21 214 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 28/20 1.36e6 PCB-31 22.92 1.02e6 22.64 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 3.28e3 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 26/29 1.88e5 22.14 Abs. Int. 3.54e5 21/33 2.44e5 23.13 PCB-25 1.32e5 22.36 1.77e5 PCB-22 2.75e5 23.48 0% 22.0 23.0 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.60e3 PCB-31 1.02e6 22.64 26/29 2.05e5 22.14 PCB-25 1.23e5 22.36 24.0 25.0 0.00e0 RT 26.0 28/20 1.39e6 22.92 21/33 2.21e5 23.13 Abs. Int. 3.74e5 1.87e5 PCB-22 2.64e5 23.49 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 4.37e7 22.90 Rel. Int. 100% ES-37 3.74e7 26.45 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.29e4 Abs. Int. 1.23e7 6.14e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 3.99e7 22.90 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.32e7 26.45 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 3.67e4 Abs. Int. 1.11e7 5.54e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.47e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5102, 0620 scc: 889-569 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:42 (CEM) Printed: 31-Mar-2014 19:19 Page 6 of 21 215 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Rel. Int. 100% Abs. Int. 3.16e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 8.90e2 1.58e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.45e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 1.11e3 1.72e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.57e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 6.18e3 2.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.02e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.07e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 3.92e3 3.03e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.54e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.71e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3426, 4949 scc: 889-569 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:40 (CEM) Printed: 31-Mar-2014 19:19 Page 7 of 21 216 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Abs. Int. 5.05e5 PCB-52 1.97e6 24.54 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.03e3 69/49 1.11e6 24.98 50/53 2.11e5 22.39 PCB-45 1.36e5 23.00 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 PCB-51 2.42e5 23.07 44/47… 1.65e6 25.44 PCB-48 1.65e5 25.24 71/40 6.00e5 26.33 59/62… 1.65e5 25.73 PCB-64 9.30e5 26.53 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 0.00e0 RT 26.0 Abs. Int. 6.76e5 PCB-52 2.57e6 24.54 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.12e3 69/49 1.40e6 24.98 50/53 2.50e5 22.39 PCB-45 1.84e5 23.00 PCB-51 2.91e5 23.07 44/47… 2.08e6 25.44 PCB-48 1.87e5 25.24 PCB-42 3.42e5 25.90 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.35e7 24.52 Rel. Int. 100% 2.53e5 71/40 7.16e5 26.33 PCB-64 1.21e6 26.53 3.38e5 0.00e0 RT Abs. Int. 6.24e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.49e4 3.12e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.99e7 24.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.91e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 8.79e3 3.96e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.47e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5837, 5732 scc: 889-569 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:43 (CEM) Printed: 31-Mar-2014 19:19 Page 8 of 21 217 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.20e3 61/70... 2.23e6 28.77 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 PCB-66 1.73e6 29.03 Abs. Int. 4.40e5 PCB-56 6.13e5 29.61 PCB-60 4.17e5 29.81 PCB-68 3.87e5 27.50 2.20e5 PCB-77 1.62e5 32.80 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.86e3 30.0 61/70... 2.81e6 28.77 PCB-68 4.80e5 27.50 32.0 34.0 36.0 38.0 PCB-66 2.16e6 29.03 Abs. Int. 5.22e5 PCB-56 7.65e5 29.61 PCB-60 4.91e5 29.81 2.61e5 PCB-77 2.15e5 32.80 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.69e7 32.30 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.38e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 6.99e6 ES-77 2.76e7 32.78 3.49e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.32e7 32.30 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.39e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 8.42e6 ES-77 3.42e7 32.78 4.21e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.05e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7612, 7469 scc: 889-569 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 16:43 (CEM) Printed: 31-Mar-2014 19:19 Page 9 of 21 218 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Rel. Int. 100% Abs. Int. 4.12e3 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PB 4σ 7.44e2 2.06e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.52e3 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PB 4σ 5.32e2 3.76e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.38e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.24e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.62e3 3.12e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.48e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.98e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 2.19e3 1.99e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.47e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1968, 9321 scc: 889-569 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:40 Printed: 31-Mar-2014 19:19 Page 10 of 21 219 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 9.94e2 113/90… 7.92e5 30.53 PCB-95 5.39e5 27.99 PCB-91 1.31e5 28.75 PCB-84 1.74e5 28.94 PCB-110 1.14e6 32.22 Abs. Int. 2.98e5 PCB-118 8.66e5 34.78 PCB-99 4.81e5108/119... 31.03 5.86e5 116/85 2.42e5 31.51 32.08 PCB-92 1.41e5 30.02 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 PCB-82 7.38e4 32.50 PCB-109 7.90e4 34.40 PCB-105 4.70e5 35.78 1.49e5 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.22e3 32.0 113/90… 1.27e6 30.53 PCB-95 8.27e5 27.99 PCB-91 2.09e5 28.75 PCB-84 2.80e5 28.94 PCB-92 2.23e5 30.02 34.0 36.0 38.0 PCB-110 1.87e6 32.22 PCB-99 7.49e5108/119... 31.03 9.80e5 116/85 31.51 3.81e5 32.08 Abs. Int. 4.49e5 PCB-118 1.35e6 34.78 PCB-82 1.34e5 32.51 PCB-109 1.34e5 34.40 PCB-105 7.36e5 35.78 2.25e5 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 3.48e7 32.80 JS-101 2.94e7 30.50 0.00e0 RT PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 3.18e3 ES-123 3.13e7 34.47 36.0 ES-118 ES-114 3.20e7 3.21e7 34.75 35.22 38.0 0.00e0 RT Abs. Int. 8.49e6 ES-105 3.25e7 35.76 4.24e6 0% 28.0 30.0 32.0 CS/SS-111 2.19e7 32.80 JS-101 1.87e7 30.50 Rel. Int. 100% 34.0 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.94e3 ES-118 ES-114 2.05e7 ES-123 2.01e7 1.98e7 34.76 35.22 34.47 36.0 38.0 0.00e0 RT Abs. Int. 5.26e6 ES-105 2.06e7 35.76 2.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.05e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3808, 5968 scc: 889-569 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:00 (CEM) Printed: 31-Mar-2014 19:19 Page 11 of 21 220 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Rel. Int. 100% Abs. Int. 1.92e4 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 1.28e3 9.62e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 4.31e4 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.18e3 2.16e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.80e6 ES-126 2.73e7 38.37 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 8.09e3 3.40e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.39e6 ES-126 1.76e7 38.37 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 3.27e3 2.19e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.67e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5816, 8881 scc: 889-569 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:55 (CEM) Printed: 31-Mar-2014 19:19 Page 12 of 21 221 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Rel. Int. 100% 153/168 8.00e5 36.36 147/149 5.33e5 33.80 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 5.49e2 PCB-132 2.34e5 34.88 151/135 1.95e5 33.03 PCB-136 9.04e4 30.96 163/138… 1.01e6 37.43 PCB-141 1.26e5 PCB-137 36.53 4.94e4 37.06 PCB-146 1.29e5 35.84 Abs. Int. 2.38e5 PCB-158 1.28e5 37.76 0% 28.0 30.0 32.0 34.0 36.0 38.0 153/168 6.37e5 36.36 Rel. Int. 100% 163/138… 7.66e5 37.43 1.19e5 0.00e0 RT Abs. Int. 1.80e5 147/149 4.05e5 33.80 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 6.31e2 PCB-132 1.73e5 34.87 151/135 1.65e5 33.02 PCB-136 7.84e4 30.97 PCB-141 PCB-164 PCB-158 9.76e4 8.91e4 6.92e4 37.76 36.53 37.15 PCB-146 1.15e5 35.83 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.96e7 30.34 Rel. Int. 100% ES-153 2.10e7 36.34 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.74e3 9.00e4 0.00e0 RT Abs. Int. 7.30e6 JS-138 2.13e7 37.40 3.65e6 0% 28.0 30.0 32.0 34.0 36.0 ES-155 2.28e7 30.34 Rel. Int. 100% ES-153 1.64e7 36.34 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.29e3 38.0 0.00e0 RT Abs. Int. 5.65e6 JS-138 1.68e7 37.40 2.83e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.05e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5167, 5240 scc: 889-569 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:00 (CEM) Printed: 31-Mar-2014 19:19 Page 13 of 21 222 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Abs. Int. 4.18e4 128/166 1.69e5 38.51 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 9.99e2 PCB-167 5.09e4 39.95 156/157 1.31e5 40.93 2.09e4 0% 39.0 Rel. Int. 100% 40.0 128/166 1.30e5 38.51 41.0 42.0 43.0 44.0 45.0 Abs. Int. 3.22e4 156/157 1.08e5 40.93 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 8.56e2 PCB-167 4.24e4 39.96 1.61e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.70e7 39.94 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 5.55e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.86e7 40.92 0.00e0 RT Abs. Int. 8.66e6 ES-169 2.17e7 43.63 4.33e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.11e7 39.94 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 5.80e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.86e7 40.92 0.00e0 RT Abs. Int. 6.90e6 ES-169 1.72e7 43.63 3.45e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.67e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6198, 7097 scc: 889-569 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:56 (CEM) Printed: 31-Mar-2014 19:19 Page 14 of 21 223 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 PCB-179 4.84e4 35.52 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 4.50e2 Abs. Int. 1.58e4 PCB-178 2.62e4 37.79 PCB-176 1.27e4 36.27 7.88e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 5.41e4 35.52 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 7.11e2 Abs. Int. 1.77e4 PCB-178 2.47e4 37.80 PCB-176 1.32e4 36.27 8.86e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.91e7 35.21 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 4.76e6 CS/SS-178 1.28e7 37.78 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.34e3 2.38e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.74e7 35.21 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.35e6 CS/SS-178 1.20e7 37.78 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.13e3 2.17e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 9.78e6 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3586, 7869 scc: 889-569 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:57 (CEM) Printed: 31-Mar-2014 19:19 Page 15 of 21 224 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 180/193 3.29e5 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 7.10e2 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 PCB-187 1.64e5 38.57 PCB-174 PCB-183 1.07e5 8.34e4 39.29 39.10 PCB-177 6.52e4 39.66 171/173 4.10e4 40.20 Abs. Int. 7.37e4 PCB-170 1.25e5 43.17 PCB-172 2.70e4 41.54 3.68e4 PCB-190 4.01e4 43.62 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 3.11e5 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 7.82e2 43.0 PCB-187 1.70e5 38.57 PCB-174 PCB-183 1.12e5 8.55e4 39.29 39.10 PCB-177 6.05e4 39.66 171/173 4.04e4 40.20 Abs. Int. 7.92e4 PCB-170 1.29e5 43.17 PCB-172 2.69e4 41.55 3.96e4 PCB-190 2.82e4 43.61 0% 39.0 40.0 41.0 42.0 ES-180 1.74e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.45e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.20e6 ES-170 1.42e7 43.15 2.10e6 0% 39.0 40.0 41.0 42.0 ES-180 1.64e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 3.60e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.98e6 ES-170 1.31e7 43.15 1.99e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.67e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0186, 1901 scc: 889-569 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:57 (CEM) Printed: 31-Mar-2014 19:19 Page 16 of 21 225 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Rel. Int. 100% Abs. Int. 3.40e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 1.10e3 1.70e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 3.71e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 7.03e2 1.86e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.88e7 45.76 0.00e0 RT Abs. Int. 4.44e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 3.50e3 2.22e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.81e7 45.76 0.00e0 RT Abs. Int. 4.37e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.65e3 2.18e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.45e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.23e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1234, 3473 scc: 889-569 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 16:40 Printed: 31-Mar-2014 19:19 Page 17 of 21 226 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 198/199 6.09e4 43.75 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 8.44e2 PCB-202 1.93e4 39.77 Abs. Int. 1.66e4 PCB-196 2.53e4 44.31 PCB-203 2.53e4 44.48 8.28e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 5.49e4 43.75 Rel. Int. 100% PCB-202 2.54e4 39.77 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.09e2 Abs. Int. 1.19e4 PCB-196 2.54e4 44.31 PCB-203 2.89e4 44.48 5.93e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.71e7 39.75 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 4.47e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.47e3 2.24e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.86e7 39.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.66e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.52e3 2.33e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.67e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2887, 7561 scc: 889-569 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:58 (CEM) Printed: 31-Mar-2014 19:19 Page 18 of 21 227 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 PCB-194 3.95e4 47.54 Rel. Int. 100% Abs. Int. 1.17e4 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 9.11e2 5.87e3 0% 46.0 47.0 48.0 49.0 50.0 PCB-194 3.59e4 47.54 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e4 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 5.89e2 5.47e3 0% 46.0 47.0 48.0 JS-194 1.28e7 47.52 Rel. Int. 100% 49.0 50.0 ES-205 1.17e7 47.92 0.00e0 RT Abs. Int. 3.07e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 3.08e3 1.53e6 0% 46.0 47.0 48.0 JS-194 1.42e7 47.52 Rel. Int. 100% 49.0 50.0 ES-205 1.31e7 47.92 0.00e0 RT Abs. Int. 3.41e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 3.02e3 1.71e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.45e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.23e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1566, 9047 scc: 889-569 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:58 (CEM) Printed: 31-Mar-2014 19:19 Page 19 of 21 228 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-208 2.77e4 45.40 NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.15e3 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 Abs. Int. 1.04e4 PCB-207 2.11e4 46.18 5.20e3 0% 46.0 Rel. Int. 100% PCB-208 3.97e4 45.39 NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 1.97e3 47.0 48.0 49.0 50.0 Abs. Int. 1.24e4 PCB-207 2.33e4 46.18 6.22e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.21e6 ES-208 1.38e7 45.37 ES-206 7.54e6 49.38 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.07e3 1.61e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 4.04e6 ES-208 1.73e7 45.37 ES-206 9.39e6 49.38 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.18e3 2.02e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.45e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.23e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1580, 7461 scc: 889-569 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:58 (CEM) Printed: 31-Mar-2014 19:19 Page 20 of 21 229 of 711 SGS-AP ID: A6504_11892_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: EF006.1-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 27-Mar-2014 02:38:21 User: LKB Datafile: 140326X14 PCB-209 2.30e5 50.84 Rel. Int. 100% Abs. Int. 5.33e4 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 5.33e2 2.67e4 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.01e5 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.28e4 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.17e2 2.14e4 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.09e7 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.37e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 8.03e2 1.18e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 9.19e6 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.00e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 7.11e2 9.98e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.36e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.18e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_006.utp_res, saved 31-Mar-2014 18:01 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8706, 5312 scc: 889-569 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 17:58 (CEM) Printed: 31-Mar-2014 19:19 Page 21 of 21 230 of 711 Lab ID: A6504_11892_PCB_007 ACQ: 27-Mar-2014 03:33:35 LKB Wt/Vol: 0.94 L Client ID: PB119_B-1SWMID-140313-N (TOTAL) UTP: 31-Mar-2014 18:09 CEM J-level: 10.6 pg/L Datafile: 140326X15 RPT: 31-Mar-2014 18:59 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.81 NotFnd 35.79 NotFnd 34.78 NotFnd NotFnd 40.93 NotFnd NotFnd NotFnd 50.84 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.89 14.18 14.43 20.14 17.51 26.46 20.42 32.79 32.31 25.40 35.77 35.23 34.76 34.48 38.38 36.35 30.35 40.93 39.94 43.64 43.16 42.09 35.22 45.76 39.76 47.93 49.39 45.38 50.82 QC J J EMPC B J C J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0007 1.0006 1.0006 1.0002 1.0003 +0.2 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7245 0.8640 0.8794 1.2275 1.0673 1.0789 0.8326 1.3368 1.3174 0.8323 1.1722 1.1545 1.1393 1.1301 1.2578 0.9716 0.8112 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Split: 1 Checkcode: 251-126-RZF Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.73 -0.3 1.05E+05 0.00E+00 1.05E+05 0.00E+00 3.40E+05 0.00E+00 0.00E+00 3.54E+04 0.00E+00 0.00E+00 0.00E+00 2.89E+04 1.08 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 3.49 ND 4.26 ND 13.2 ND ND 1.69 ND ND ND 2.49 4.02E+03 4.02E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 3.19E+03 1.28E+03 1.28E+03 1.28E+03 1.34E+03 1.08E+03 1.35 1.44 0.851 0.788 0.804 0.814 1.6 0.832 0.547 0.711 0.781 1.09 +0.1 +0.1 0 +0.2 0 +0.2 -0.2 +0.4 +0.4 -0.2 +0.2 +0.2 +0.2 +0.2 +0.2 0 -0.2 0 0 0 0 0 0 0 0 0 0 0 0 4.42E+07 5.01E+07 2.69E+07 7.58E+07 3.13E+07 6.34E+07 3.32E+07 5.56E+07 5.34E+07 3.51E+07 4.70E+07 4.71E+07 4.60E+07 4.63E+07 4.04E+07 3.43E+07 4.72E+07 8.14E+07 4.28E+07 3.66E+07 2.50E+07 3.11E+07 3.42E+07 3.64E+07 3.29E+07 2.54E+07 1.81E+07 2.99E+07 2.22E+07 3.28 3.34 1.56 1.58 1.08 1.10 0.76 0.81 0.80 1.62 1.62 1.62 1.63 1.60 1.60 1.32 1.27 1.25 1.24 1.26 1.08 1.10 1.08 1.03 0.91 0.89 0.80 0.78 1.17 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 44.9 % 55.8 % 62.4 % 88.1 % 74.9 % 82.7 % 83.5 % 87.2 % 84.7 % 101 % 90.8 % 89.8 % 92.2 % 90.6 % 91.4 % 90.2 % 87.5 % 75 % 75.6 % 69.4 % 90.9 % 94.3 % 107 % 94.6 % 100 % 84 % 89.6 % 105 % 82.1 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% -0.2 0 -0.7 Page 1 of 5 0.50 0.62 1.16 Printed: 3/31/2014 7:04 PM 231 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.91 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 7.31E+07 5.00E+07 2.21E+07 1.09 1.58 1.09 1.11 1.03 0.62 104 % 105 % 104 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.91 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 7.31E+07 5.00E+07 2.21E+07 1.09 1.58 1.09 1.85 1.22 0.58 85.9 % 95.1 % 112 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.41 24.53 30.51 37.41 47.53 8.27E+07 4.61E+07 4.30E+07 3.39E+07 2.43E+07 1.54 0.80 1.59 1.28 0.90 5.42E+03 5.42E+03 5.42E+03 5.45E+03 5.45E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 5.19E+03 1.7 1.49 1.65 2.45 1.57 1.62 1.42 1.54 1.54 1.47 1.28 1.46 1.48 1.53 2.54 1.89 2.21 1.62 1.7 2.97 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services NotFnd NotFnd NotFnd 14.45 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 19.58 NotFnd 20.16 NotFnd 19.30 19.69 NotFnd NotFnd 20.12 J B C J J C J 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 1.0012 0.9721 1.0008 1.1019 1.1244 1.1488 +0.1 0 0 +0.5 0 +0.4 Page 2 of 5 Noise / Recv. Low DL / Recv. High EMPC 0 30.4 85.4 189 108 77.1 34.6 9.64 0 NON-EMPC 0 30.4 85.4 187 83.3 75.4 32.4 8.39 0 0.00E+00 0.00E+00 0.00E+00 1.10E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.70E+05 0.00E+00 3.02E+05 0.00E+00 3.07E+05 2.20E+05 0.00E+00 0.00E+00 1.00E+05 RRF Conc. / Recv. SI 1.77 SI 0.98 0.91 1.06 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 1.67 1.99 2.14 1.05 0.91 0.646 0.78 0.916 2.68 ND ND ND 7.04 ND ND ND ND ND ND ND 15 ND 8.3 ND 13.5 11.3 ND ND 6.94 Printed: 3/31/2014 7:04 PM 232 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.59 NotFnd NotFnd 22.15 22.37 22.66 22.93 23.14 23.49 NotFnd NotFnd NotFnd NotFnd 26.48 NotFnd 22.40 NotFnd 23.08 NotFnd 24.55 NotFnd NotFnd 24.99 25.25 25.47 NotFnd 25.91 NotFnd 26.34 26.53 NotFnd 27.51 NotFnd NotFnd NotFnd NotFnd 28.77 29.04 NotFnd 29.62 29.82 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J J C J B J B C J C J J J EMPC C B J B C J C C J J C J J B C J J J Pred RRT Actual RRT Diff Secs 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1760 0.8371 0.8454 0.8561 0.8664 0.8743 0.8878 1.0007 0.9131 0.9410 1.0009 1.0189 1.0294 1.0384 1.0565 1.0738 1.0818 0.8514 0.8903 0.8987 0.9168 0.9228 - +0.1 -1.5 -0.4 -0.1 -0.7 +0.7 -0.1 0 -1.9 -0.6 0 +1.2 -0.3 0 +0.3 0 -0.2 0 +0.3 -0.2 0 0 Page 3 of 5 Response Ra RRF Conc. / Recv. 1.31E+05 0.00E+00 0.00E+00 1.04E+05 1.74E+05 4.86E+05 5.48E+05 1.22E+05 1.17E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.54E+05 0.00E+00 4.86E+04 0.00E+00 5.79E+05 0.00E+00 5.27E+05 0.00E+00 0.00E+00 2.52E+05 6.91E+04 8.00E+05 0.00E+00 7.64E+04 0.00E+00 1.75E+05 2.01E+05 0.00E+00 1.00E+06 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.18E+05 2.61E+05 0.00E+00 1.31E+05 8.70E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.06 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 4.63 ND ND 2.75 4.58 12.2 14.9 3.24 3.33 ND ND ND ND 7.91 ND 2.13 ND 26.3 ND 23.5 ND ND 9.2 3.09 33.6 ND 3.73 ND 7.71 6.1 ND 30.1 ND ND ND ND 23.4 8.86 ND 4.52 2.97 ND ND ND ND ND ND ND 1.11 1.01 1.02 1.13 1.13 0.96 0.89 1.25 0.87 0.80 0.71 0.83 0.80 0.78 0.77 0.72 0.77 0.80 0.84 0.85 0.68 Noise / Recv. Low DL / Recv. High 5.19E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 5.67E+03 1.77E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 2.00E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 4.02E+03 1.50E+03 1.50E+03 2.04E+03 2.04E+03 1.51 1.54 1.52 1.49 1.48 1.42 1.53 1.49 1.6 1.46 1.41 1.55 1.62 1.75 0.678 0.884 0.975 0.914 1.09 0.898 0.681 1.05 0.736 0.899 0.845 0.645 0.982 1.07 0.884 0.61 1.27 1.22 1.34 1.32 1.25 1.19 1.32 1.38 1.4 1.39 1.38 1.17 1.23 1.45 0.604 0.742 1.03 1.23 Printed: 3/31/2014 7:04 PM 233 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 28.00 NotFnd NotFnd NotFnd NotFnd 28.76 28.95 NotFnd NotFnd 30.03 30.54 NotFnd 31.05 NotFnd 31.52 NotFnd 32.10 32.24 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.38 NotFnd NotFnd 30.98 NotFnd NotFnd 33.03 NotFnd NotFnd 33.81 NotFnd NotFnd NotFnd NotFnd NotFnd 34.88 NotFnd NotFnd 35.84 NotFnd 36.37 SGS Evironmental Services QC B C J J EMPC J J B C J J EMPC C J EMPC C B C J J J C J B C C J J J B C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9176 0.9426 0.9487 0.9843 1.0007 1.0174 1.0329 1.0520 1.0565 1.0009 1.0209 1.0885 1.1141 1.1494 0.9582 0.9722 0 +0.2 0 +0.4 +1.5 +0.2 +1.7 -1.0 +0.4 +0.4 +0.4 -0.2 -0.2 -0.2 0 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 3.03E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.51E+04 8.50E+04 0.00E+00 0.00E+00 6.15E+04 4.10E+05 0.00E+00 1.73E+05 0.00E+00 2.72E+05 0.00E+00 5.57E+04 4.88E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.91E+04 0.00E+00 0.00E+00 5.92E+04 0.00E+00 0.00E+00 1.27E+05 0.00E+00 0.00E+00 2.62E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 8.11E+04 0.00E+00 0.00E+00 5.66E+04 0.00E+00 3.65E+05 0.67 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 16 ND ND ND ND 2.95 5.43 ND ND 3.34 19.3 ND 8.09 ND 12.8 ND 2.64 20.4 ND ND ND ND ND ND ND ND ND 1.4 ND ND 2.61 ND ND 7.43 ND ND 14.7 ND ND ND ND ND 5.17 ND ND 3.02 ND 16.3 0.57 0.72 0.59 0.61 0.66 0.52 0.72 0.62 1.23 1.35 1.27 1.36 1.14 1.16 1.22 Noise / Recv. Low DL / Recv. High 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 2.04E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.13 1.13 1.12 1.15 1.17 1.15 1.37 1.26 0.809 1.17 1.01 1.49 1 0.852 1.01 0.906 1.02 0.897 0.879 1.42 0.82 0.807 0.897 0.807 0.91 0.939 0.89 0.494 0.573 0.556 0.608 0.6 0.824 0.874 0.737 0.839 0.841 1.14 0.846 0.834 0.981 1 0.953 0.892 0.701 0.799 0.651 0.669 Printed: 3/31/2014 7:04 PM 234 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.53 NotFnd NotFnd NotFnd 37.43 NotFnd 37.76 38.52 NotFnd NotFnd NotFnd 35.53 35.99 NotFnd NotFnd NotFnd NotFnd 38.58 NotFnd 39.10 NotFnd 39.30 39.67 NotFnd NotFnd NotFnd NotFnd 42.10 NotFnd 43.18 NotFnd 39.78 NotFnd NotFnd NotFnd NotFnd 43.77 NotFnd 44.48 NotFnd 47.55 NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J J B C J EMPC J C J J J J J J EMPC C J C J J EMPC J C J J Pred RRT Actual RRT Diff Secs 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 1.0007 1.0094 0.9645 1.0086 1.0218 1.0953 1.1101 1.1157 1.1263 0.9200 0.9434 1.0006 1.1009 1.1189 0.9921 - -0.2 -0.9 -0.5 +1.2 0 +0.4 0 0 +0.2 0 +1.8 0 +0.2 +1.8 0 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 5.32E+04 0.00E+00 0.00E+00 0.00E+00 3.07E+05 0.00E+00 4.12E+04 5.06E+04 0.00E+00 0.00E+00 0.00E+00 5.11E+04 5.01E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.14E+05 0.00E+00 4.83E+04 0.00E+00 5.30E+04 3.02E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.77E+05 0.00E+00 4.91E+04 0.00E+00 2.05E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.70E+04 0.00E+00 2.65E+04 0.00E+00 1.93E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.16 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 3.27 ND ND ND 16.9 ND 1.71 2.84 ND ND ND 2.93 2.99 ND ND ND ND 6.65 ND 2.69 ND 3.59 2.15 ND ND ND ND 9.83 ND 3.74 ND 1.25 ND ND ND ND 4.21 ND 2.2 ND 1.98 ND ND ND ND 1.30 1.45 1.37 0.94 1.05 1.09 0.95 1.02 0.85 0.93 1.12 1.28 0.94 0.84 0.85 Noise / Recv. Low DL / Recv. High 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.28E+03 1.28E+03 1.28E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 1.26E+03 1.26E+03 1.26E+03 3.01E+03 3.01E+03 3.01E+03 0.919 1.02 0.806 0.675 0.823 0.731 0.622 0.718 0.592 0.594 0.581 0.679 0.707 0.639 0.682 0.977 0.836 0.783 0.764 0.744 0.869 0.907 0.954 0.846 0.967 0.924 0.711 0.742 0.677 0.982 0.71 0.755 0.712 0.766 0.73 0.733 1.1 1.04 1.02 1.52 1.41 1.08 1.99 1.96 3.37 Printed: 3/31/2014 7:04 PM 235 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.59e7 2.80e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.50e7 7.50e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.23e7 6.15e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 1.93e7 9.64e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.21e7 6.04e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.63e6 1.31e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.50e6 1.25e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 251-126 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:19 Page 1 of 21 236 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Rel. Int. 100% Abs. Int. 1.46e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 2.87e3 7.30e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.11e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 2.55e3 2.55e4 0% 11.0 12.0 13.0 ES-1 3.39e7 11.89 Rel. Int. 100% 14.0 15.0 ES-3 3.86e7 14.18 0.00e0 16.0 RT Abs. Int. 1.36e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.88e3 6.81e6 0% 11.0 12.0 13.0 ES-1 1.03e7 11.89 Rel. Int. 100% 14.0 15.0 ES-3 1.16e7 14.18 0.00e0 16.0 RT Abs. Int. 4.41e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.35e4 2.20e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.59e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.80e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5899, 7253 scc: 251-126 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:01 Printed: 31-Mar-2014 19:19 Page 2 of 21 237 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 PCB-4 6.70e4 SI 14.45 Rel. Int. 100% Abs. Int. 2.71e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 3.32e3 1.35e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.53e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 1.31e4 1.76e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.64e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.86e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.57e3 2.93e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.05e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.70e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.48e3 1.85e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.59e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.80e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7059, 5330 scc: 251-126 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:02 (CEM) Printed: 31-Mar-2014 19:19 Page 3 of 21 238 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 PCB-11 3.64e5 19.58 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 3.92e3 Abs. Int. 1.02e5 PCB-15 1.84e5 SI 20.16 5.10e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% Abs. Int. 2.56e5 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.59e4 PCB-11 2.06e5 19.58 1.28e5 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 5.02e7 16.41 20.0 21.0 0.00e0 RT Abs. Int. 1.55e7 ES-15 4.64e7 20.14 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.90e4 7.75e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 3.25e7 16.41 20.0 21.0 0.00e0 RT Abs. Int. 9.94e6 ES-15 2.93e7 20.14 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 6.69e3 4.97e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.50e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.50e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0900, 4488 scc: 251-126 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:02 (CEM) Printed: 31-Mar-2014 19:20 Page 4 of 21 239 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% 30/18 1.52e5 19.30 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.56e3 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Abs. Int. 4.42e4 PCB-17 1.04e5 19.69 PCB-16 5.18e4 20.12 PCB-32 6.76e4 20.59 2.21e4 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 1.55e5 19.30 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.64e3 21.0 Abs. Int. 4.79e4 PCB-17 1.15e5 19.69 PCB-16 4.86e4 20.11 PCB-32 6.38e4 20.59 2.40e4 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 6.05e6 ES-19 1.62e7 17.51 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.37e4 0.00e0 RT 3.03e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.51e7 17.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.54e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.74e4 2.27e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.50e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.50e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4412, 7633 scc: 251-126 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:03 (CEM) Printed: 31-Mar-2014 19:20 Page 5 of 21 240 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 2.99e3 PCB-31 2.45e5 22.66 26/29 5.47e4 22.15 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 28/20 2.91e5 22.93 PCB-25 8.73e4 22.37 Abs. Int. 9.12e4 21/33 6.49e4 23.14 PCB-37 1.20e5 26.48 PCB-22 5.76e4 23.49 0% 22.0 23.0 25.0 0.00e0 RT 26.0 28/20 PCB-31 2.57e5 2.40e5 22.93 22.65 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.68e3 24.0 PCB-25 8.66e4 22.37 26/29 4.93e4 22.16 Abs. Int. 6.91e4 21/33 5.75e4 23.14 PCB-37 1.34e5 26.48 PCB-22 5.99e4 23.50 23.0 24.0 25.0 26.0 CS/SS-28 3.82e7 22.91 Rel. Int. 100% ES-37 3.31e7 26.46 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.37e4 3.46e4 0.00e0 RT 0% 22.0 4.56e4 Abs. Int. 1.06e7 5.28e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 3.49e7 22.91 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.03e7 26.46 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.95e4 Abs. Int. 9.51e6 4.75e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.23e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.15e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5759, 0503 scc: 251-126 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:03 (CEM) Printed: 31-Mar-2014 19:20 Page 6 of 21 241 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Rel. Int. 100% Abs. Int. 2.28e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 8.28e2 1.14e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.25e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 9.46e2 2.13e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.43e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.44e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 5.44e3 2.22e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.89e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.69e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 4.65e3 2.85e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.50e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.50e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9183, 9402 scc: 251-126 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:01 Printed: 31-Mar-2014 19:20 Page 7 of 21 242 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-51 2.69e5 23.08 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.02e3 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 PCB-52 2.33e5 24.55 69/49 1.04e5 24.99 50/53 3.42e4 22.40 Abs. Int. 6.60e4 44/47… 3.57e5 25.47 PCB-48 3.14e4 25.25 PCB-42 3.35e4 25.91 71/40 7.65e4 26.34 PCB-64 8.43e4 26.53 0% 22.0 23.0 Rel. Int. 100% 24.0 PCB-52 2.93e5 24.55 PCB-51 3.10e5 23.08 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 9.73e2 25.0 50/53 2.73e4 22.40 PCB-48 3.77e4 25.25 Abs. Int. 8.01e4 PCB-42 4.29e4 25.91 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.05e7 24.53 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 4.43e5 25.47 69/49 1.47e5 24.99 3.30e4 71/40 9.89e4 26.34 PCB-64 1.17e5 26.53 4.01e4 0.00e0 RT Abs. Int. 5.34e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.16e4 2.67e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.57e7 24.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.75e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.23e4 3.37e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.23e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.15e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0026, 8221 scc: 251-126 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:04 (CEM) Printed: 31-Mar-2014 19:20 Page 8 of 21 243 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Abs. Int. 1.14e5 PCB-68 4.36e5 27.51 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.45e3 61/70... 3.18e5 PCB-66 28.77 1.19e5 29.04 5.68e4 PCB-56 6.02e4 PCB-60 29.62 3.53e4 29.82 PCB-77 4.44e4 32.81 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 1.59e5 PCB-68 5.64e5 27.51 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.58e3 61/70... 4.00e5 PCB-66 28.76 1.42e5 PCB-56 PCB-60 29.04 7.12e4 5.18e4 29.62 29.82 7.95e4 PCB-77 6.07e4 32.81 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.37e7 32.31 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.36e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 6.77e6 ES-77 2.49e7 32.79 3.38e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 2.97e7 32.31 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 9.33e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.65e6 ES-77 3.07e7 32.79 3.82e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.93e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 9.64e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8728, 5058 scc: 251-126 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:04 (CEM) Printed: 31-Mar-2014 19:20 Page 9 of 21 244 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Rel. Int. 100% Abs. Int. 3.26e3 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PB 4σ 7.18e2 1.63e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.01e3 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PB 4σ 7.85e2 2.00e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.16e7 25.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.70e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.54e3 2.85e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.34e7 25.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.50e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.60e3 1.75e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.23e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.15e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6995, 6096 scc: 251-126 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:01 (CEM) Printed: 31-Mar-2014 19:20 Page 10 of 21 245 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 113/90… 1.55e5 30.54 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.01e3 PCB-95 1.22e5 28.00 PCB-91 2.01e4 28.76 PCB-84 3.77e4 28.95 PCB-110 1.86e5 32.24 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 PCB-99108/119... 6.91e4 1.04e5 31.05 31.52 116/85 2.47e4 32.10 PCB-92 2.29e4 30.03 Abs. Int. 4.42e4 PCB-118 1.31e5 34.78 PCB-105 4.01e4 35.79 2.21e4 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.03e3 32.0 113/90… 2.55e5 30.54 PCB-95 1.81e5 28.00 PCB-91 3.50e4 28.75 PCB-84 5.25e4 28.95 PCB-110 3.02e5 32.23 PCB-99108/119... 1.04e5 2.01e5 31.04 31.52 PCB-92 3.86e4 30.03 34.0 36.0 38.0 Abs. Int. 7.21e4 PCB-118 2.09e5 34.78 PCB-105 7.99e4 35.79 116/85 3.44e4 32.09 3.60e4 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 3.06e7 32.80 JS-101 2.64e7 30.51 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.03e3 34.0 ES-123 2.85e7 34.48 36.0 ES-118 ES-114 2.85e7 2.91e7 34.76 35.23 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 8.04e6 ES-105 2.91e7 35.77 4.02e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.93e7 32.81 JS-101 1.66e7 30.51 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.47e3 ES-118 ES-114 ES-123 1.75e7 1.79e7 1.78e7 34.76 35.23 34.48 36.0 38.0 0.00e0 RT Abs. Int. 4.98e6 ES-105 1.79e7 35.77 2.49e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.93e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 9.64e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6368, 1709 scc: 251-126 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:05 (CEM) Printed: 31-Mar-2014 19:20 Page 11 of 21 246 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Rel. Int. 100% Abs. Int. 1.46e6 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 1.42e3 7.30e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 3.00e6 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.77e3 1.50e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.90e6 ES-126 2.49e7 38.38 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 5.36e3 2.95e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.71e6 ES-126 1.56e7 38.38 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 4.03e3 1.86e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.04e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1916, 2661 scc: 251-126 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:01 Printed: 31-Mar-2014 19:20 Page 12 of 21 247 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 153/168 2.01e5 36.37 147/149 1.51e5 33.81 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.24e2 PCB-155 2.16e4 30.38 PCB-132 4.31e4 34.88 151/135 7.12e4 33.03 PCB-136 3.40e4 30.98 163/138… 1.73e5 37.43 Abs. Int. 5.11e4 2.55e4 PCB-146 3.03e4 35.84 PCB-141 2.86e4 36.53 PCB-158 2.66e4 37.76 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% 36.0 153/168 1.64e5 36.37 147/149 1.11e5 33.81 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 8.07e2 PCB-155 1.75e4 30.37 151/135 5.60e4 33.03 PCB-136 2.52e4 30.98 38.0 PCB-132 3.80e4 34.88 PCB-146 2.62e4 35.85 PCB-141 2.46e4 36.53 Abs. Int. 4.02e4 163/138… 1.34e5 37.43 PCB-158 1.83e4 37.76 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.64e7 30.35 Rel. Int. 100% ES-153 1.95e7 36.35 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.80e3 0.00e0 RT 2.01e4 0.00e0 RT Abs. Int. 6.83e6 JS-138 1.90e7 37.41 3.42e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.08e7 30.35 Rel. Int. 100% ES-153 1.48e7 36.35 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.69e3 0.00e0 RT Abs. Int. 5.29e6 JS-138 1.49e7 37.41 2.64e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.93e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 9.64e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8679, 3005 scc: 251-126 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:06 (CEM) Printed: 31-Mar-2014 19:20 Page 13 of 21 248 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 128/166 2.92e4 38.52 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Abs. Int. 8.04e3 156/157 1.90e4 40.93 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 5.88e2 4.02e3 0% 39.0 Rel. Int. 100% 40.0 128/166 2.13e4 38.52 41.0 42.0 43.0 44.0 45.0 Abs. Int. 5.57e3 156/157 1.64e4 40.93 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 6.95e2 0.00e0 RT 2.79e3 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.37e7 39.94 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 6.35e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.53e7 40.93 0.00e0 RT Abs. Int. 8.31e6 ES-169 2.04e7 43.64 4.15e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.91e7 39.94 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 5.32e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.61e7 40.93 0.00e0 RT Abs. Int. 6.44e6 ES-169 1.62e7 43.64 3.22e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.04e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2615, 5330 scc: 251-126 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:07 (CEM) Printed: 31-Mar-2014 19:20 Page 14 of 21 249 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% PCB-179 2.48e4 35.53 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 5.56e2 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Abs. Int. 8.58e3 PCB-184 2.56e4 35.99 4.29e3 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-179 2.63e4 35.53 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.09e2 37.0 38.0 0.00e0 RT Abs. Int. 7.03e3 PCB-184 2.45e4 35.99 3.51e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.77e7 35.22 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.36e6 CS/SS-178 1.15e7 37.78 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.65e3 2.18e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.65e7 35.22 Rel. Int. 100% Abs. Int. 4.20e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.29e3 CS/SS-178 1.06e7 37.78 2.10e6 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.93e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 9.64e6 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6719, 0345 scc: 251-126 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:07 (CEM) Printed: 31-Mar-2014 19:20 Page 15 of 21 250 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 6.31e2 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 180/193 8.53e4 42.10 PCB-187 5.92e4 38.58 PCB-174 PCB-183 2.67e4 2.36e4 39.30 39.10 Abs. Int. 2.16e4 PCB-170 2.59e4 43.18 PCB-177 1.54e4 39.67 1.08e4 0% 39.0 40.0 41.0 43.0 44.0 45.0 180/193 9.19e4 42.11 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 6.58e2 42.0 PCB-187 5.45e4 38.57 PCB-174 PCB-183 2.63e4 2.48e4 39.30 39.10 Abs. Int. 2.06e4 PCB-170 2.32e4 43.18 PCB-177 1.82e4 39.68 1.03e4 0% 39.0 40.0 41.0 42.0 ES-180 1.63e7 42.09 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.41e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.93e6 ES-170 1.30e7 43.16 1.96e6 0% 39.0 40.0 41.0 42.0 ES-180 1.48e7 42.09 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 1.88e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.51e6 ES-170 1.20e7 43.15 1.76e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.04e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1731, 9509 scc: 251-126 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:07 (CEM) Printed: 31-Mar-2014 19:20 Page 16 of 21 251 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Rel. Int. 100% Abs. Int. 4.06e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 7.11e2 2.03e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 1.70e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 6.25e2 8.50e2 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.85e7 45.76 0.00e0 RT Abs. Int. 4.29e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.85e3 2.15e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.80e7 45.76 0.00e0 RT Abs. Int. 4.16e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 3.52e3 2.08e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.63e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.31e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9120, 2637 scc: 251-126 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:01 Printed: 31-Mar-2014 19:20 Page 17 of 21 252 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 198/199 2.28e4 43.77 Rel. Int. 100% Abs. Int. 6.43e3 PCB-202 1.38e4 39.78 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 5.91e2 PCB-203 1.21e4 44.48 3.22e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 2.43e4 43.76 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 5.99e2 Abs. Int. 6.53e3 PCB-203 1.44e4 44.48 PCB-202 1.08e4 39.77 0.00e0 RT 3.27e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.57e7 39.76 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.80e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.30e3 1.90e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.72e7 39.76 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.09e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.35e3 2.05e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.04e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6801, 8377 scc: 251-126 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:08 (CEM) Printed: 31-Mar-2014 19:20 Page 18 of 21 253 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 PCB-194 8.85e3 47.55 Rel. Int. 100% Abs. Int. 3.71e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 6.54e2 1.85e3 0% 46.0 47.0 48.0 49.0 50.0 PCB-194 1.04e4 47.55 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.05e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 6.06e2 1.53e3 0% 46.0 47.0 48.0 JS-194 1.15e7 47.53 Rel. Int. 100% 49.0 50.0 ES-205 1.20e7 47.93 0.00e0 RT Abs. Int. 2.76e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 3.11e3 1.38e6 0% 46.0 47.0 48.0 JS-194 1.28e7 47.53 Rel. Int. 100% 49.0 50.0 ES-205 1.35e7 47.93 0.00e0 RT Abs. Int. 3.17e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.92e3 1.59e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.63e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.31e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3229, 5420 scc: 251-126 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:08 (CEM) Printed: 31-Mar-2014 19:20 Page 19 of 21 254 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 Rel. Int. 100% Abs. Int. 5.28e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 9.21e2 2.64e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 5.87e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 2.09e3 2.93e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.15e6 ES-208 1.31e7 45.38 ES-206 8.04e6 49.39 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.94e3 1.57e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 4.03e6 ES-208 1.67e7 45.38 ES-206 1.00e7 49.39 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.63e3 2.02e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.63e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.31e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9894, 1975 scc: 251-126 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:08 (CEM) Printed: 31-Mar-2014 19:20 Page 20 of 21 255 of 711 SGS-AP ID: A6504_11892_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB119_B-1SWMID-140313-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 27-Mar-2014 03:33:35 User: LKB Datafile: 140326X15 PCB-209 1.50e4 50.84 Rel. Int. 100% Abs. Int. 3.96e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 5.69e2 1.98e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.39e4 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.76e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 5.15e2 2.88e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.19e7 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.56e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 5.80e2 1.28e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.02e7 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.24e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 7.50e2 1.12e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.50e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.25e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_007.utp_res, saved 31-Mar-2014 18:09 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4505, 0449 scc: 251-126 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:02 (CEM) Printed: 31-Mar-2014 19:20 Page 21 of 21 256 of 711 Lab ID: A6504_11892_PCB_008 ACQ: 27-Mar-2014 04:28:49 LKB Wt/Vol: 0.97 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Client ID: EB1-01 (TOTAL) UTP: 31-Mar-2014 18:28 CEM J-level: 10.4 pg/L Datafile: 140326X16 RPT: 31-Mar-2014 18:59 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB NotFnd NotFnd NotFnd NotFnd 34.78 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.89 14.18 14.43 20.15 17.52 26.47 20.43 32.79 32.31 25.40 35.77 35.23 34.76 34.48 38.38 36.35 30.35 40.93 39.94 43.64 43.16 42.09 35.22 45.77 39.76 47.93 49.39 45.38 50.83 QC J B C Pred RRT Actual RRT 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0005 - 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7246 0.8641 0.8794 1.2274 1.0671 1.0789 0.8327 1.3367 1.3172 0.8323 1.1722 1.1545 1.1392 1.1300 1.2578 0.9716 0.8112 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 Diff Secs -0.2 +0.1 +0.2 0 +0.1 -0.2 +0.2 -0.1 +0.2 0 -0.2 +0.2 +0.2 0 0 +0.2 0 -0.2 0 0 0 0 0 0 0 0 0 0 0 0 Page 1 of 5 Split: 1 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.81E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.56E+07 2.98E+07 1.63E+07 4.38E+07 1.92E+07 3.44E+07 1.92E+07 3.04E+07 2.89E+07 1.95E+07 2.51E+07 2.54E+07 2.49E+07 2.47E+07 2.18E+07 1.86E+07 2.62E+07 4.38E+07 2.38E+07 2.03E+07 1.39E+07 1.66E+07 1.84E+07 2.01E+07 1.74E+07 1.44E+07 9.88E+06 1.63E+07 1.26E+07 Checkcode: 842-903-YGS Ra 0.69 3.25 3.36 1.59 1.54 1.07 1.09 0.75 0.79 0.80 1.60 1.61 1.60 1.56 1.64 1.55 1.28 1.30 1.26 1.25 1.25 1.08 1.06 1.02 1.02 0.91 0.89 0.80 0.80 1.20 Method 1668A RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ND ND ND ND 2.66 ND ND ND ND ND ND ND 2.70E+03 2.70E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.90E+03 1.37E+03 1.37E+03 1.37E+03 1.47E+03 1.02E+03 1.6 1.75 1.22 1.04 1.1 1.11 1.73 1.63 1.06 1.34 1.5 1.69 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 47.8 % 61.2 % 69.7 % 94 % 84.7 % 83.6 % 90.2 % 88.7 % 85.5 % 108 % 92.8 % 92.7 % 95.4 % 92.2 % 94.2 % 95.4 % 94.9 % 78.9 % 82.3 % 75.1 % 99.4 % 98.8 % 113 % 102 % 104 % 93.1 % 96 % 112 % 91.4 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Printed: 3/31/2014 7:04 PM 257 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.91 32.81 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 3.94E+07 2.63E+07 1.15E+07 1.08 1.60 1.05 1.11 1.03 0.62 103 % 103 % 100 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.91 32.81 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 3.94E+07 2.63E+07 1.15E+07 1.08 1.60 1.05 1.85 1.22 0.58 86.3 % 95.4 % 113 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.41 24.53 30.52 37.41 47.53 4.49E+07 2.47E+07 2.25E+07 1.74E+07 1.24E+07 1.56 0.81 1.54 1.31 0.87 5.70E+03 5.70E+03 5.70E+03 6.34E+03 6.34E+03 8.15E+03 8.15E+03 8.15E+03 8.15E+03 8.15E+03 8.15E+03 8.15E+03 8.15E+03 8.15E+03 5.60E+03 5.60E+03 5.60E+03 5.60E+03 5.60E+03 5.60E+03 3.34 2.49 2.76 4.8 3.08 3.45 3 3.26 3.27 3.11 2.72 3.1 3.15 3.24 4.32 3.22 3.76 2.76 2.89 5.05 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 17.24 NotFnd 19.58 NotFnd NotFnd NotFnd NotFnd 19.69 NotFnd NotFnd NotFnd J B C C J 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 1.0504 0.9722 1.1240 - -0.1 +0.1 -0.5 Page 2 of 5 Noise / Recv. Low DL / Recv. High EMPC 0 16.1 21 155 16.1 11.1 4.69 0 0 NON-EMPC 0 16.1 16.5 151 16.1 0 2.84 0 0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.04E+04 0.00E+00 2.93E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.02E+05 0.00E+00 0.00E+00 0.00E+00 RRF Conc. / Recv. SI SI 1.18 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 3.05 4.02 3.61 1.63 1.18 1.2 1.34 1.53 4.13 ND ND ND ND ND ND ND ND ND 3.13 ND 13 ND ND ND ND 8.35 ND ND ND Printed: 3/31/2014 7:04 PM 258 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB NotFnd NotFnd NotFnd NotFnd NotFnd 22.66 22.93 23.12 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 23.09 NotFnd 24.55 NotFnd NotFnd 24.99 NotFnd 25.49 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 27.51 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC C J B J B C J EMPC C C J B EMPC J B C J B C C C C Pred RRT Actual RRT 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.8562 0.8663 0.8737 0.9413 1.0009 1.0188 1.0389 0.8514 - Diff Secs 0 -0.8 -0.1 -0.1 0 +1.0 +0.8 0 Page 3 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.27E+04 9.92E+04 9.49E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.00E+06 0.00E+00 5.55E+04 0.00E+00 0.00E+00 4.34E+04 0.00E+00 3.87E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.85E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.11 1.18 1.25 0.76 1.16 0.70 0.81 0.81 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 ND ND ND ND ND 3.3 4.85 4.52 ND ND ND ND ND ND ND ND ND 81.8 ND 4.45 ND ND 2.85 ND 29.3 ND ND ND ND ND ND 37.1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.60E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 5.30E+03 1.96E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.12E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 2.70E+03 1.23E+03 1.23E+03 1.59E+03 1.59E+03 2.58 2.55 2.51 2.47 2.46 2.36 2.54 2.48 2.65 2.42 2.34 2.58 2.68 2.91 1.38 1.7 1.87 1.76 2.1 1.73 1.31 2.02 1.41 1.73 1.62 1.24 1.89 2.06 1.7 1.17 1.54 1.48 1.62 1.6 1.51 1.44 1.61 1.67 1.7 1.69 1.68 1.42 1.49 1.76 0.864 1.06 1.41 1.68 Printed: 3/31/2014 7:04 PM 259 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 28.00 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.53 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 32.24 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 33.82 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 36.38 SGS Evironmental Services QC J B C J B C C C J B C C J B EMPC C C J B EMPC C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9175 1.0006 1.0566 1.1144 0.9724 -0.2 +1.3 +0.6 +0.4 -0.9 Page 4 of 5 Response Ra RRF Conc. / Recv. 4.82E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.82E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.97E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.51E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.88E+04 0.71 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 4.66 ND ND ND ND ND ND ND ND ND 4.16 ND ND ND ND ND ND 4.57 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4.57 ND ND ND ND ND ND ND ND ND ND 2.32 0.66 0.71 1.44 1.70 Noise / Recv. Low DL / Recv. High 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.59E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.55 1.54 1.53 1.57 1.59 1.57 1.87 1.72 1.1 1.59 1.38 2.04 1.37 1.16 1.38 1.24 1.39 1.22 1.2 1.94 1.12 1.1 1.22 1.1 1.24 1.23 1.27 0.777 0.901 0.875 0.956 0.944 1.25 1.33 1.12 1.28 1.28 1.73 1.29 1.27 1.49 1.53 1.45 1.36 1.07 1.22 0.991 1.02 Printed: 3/31/2014 7:04 PM 260 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB NotFnd NotFnd NotFnd NotFnd 37.43 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 38.59 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 42.11 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J B EMPC C C J EMPC C J C C Pred RRT Actual RRT 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 1.0005 1.0957 0.9200 - Diff Secs -1.3 +0.9 +1.8 Page 5 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.21E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.74E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.80E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.05 0.83 1.13 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 ND ND ND ND 4.18 ND ND ND ND ND ND ND ND ND ND ND ND 1.86 ND ND ND ND ND ND ND ND ND 2.84 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.37E+03 1.37E+03 1.37E+03 1.04E+03 1.04E+03 1.04E+03 1.04E+03 1.04E+03 1.04E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.17E+03 1.23E+03 1.23E+03 1.23E+03 2.52E+03 2.52E+03 2.52E+03 1.4 1.55 1.23 1.03 1.25 1.11 0.946 1.4 1.15 1.16 0.936 1.09 1.14 1.03 1.1 1.58 1.39 1.31 1.27 1.24 1.45 1.51 1.59 1.41 1.61 1.54 1.19 1.24 1.13 1.63 1.18 1.28 1.21 1.3 1.24 1.24 1.87 1.77 1.73 2.51 2.31 1.77 3.07 3.03 5.2 Printed: 3/31/2014 7:04 PM 261 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.57e7 2.78e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.41e7 7.07e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.17e7 5.83e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.01e7 1.00e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.26e7 6.28e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.68e6 1.34e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.53e6 1.26e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 842-903 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:20 Page 1 of 21 262 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 9.63e3 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 2.60e3 4.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.13e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 3.10e3 2.07e4 0% 11.0 Rel. Int. 100% 12.0 13.0 14.0 15.0 ES-3 2.29e7 14.18 ES-1 1.96e7 11.89 0.00e0 16.0 RT Abs. Int. 8.17e6 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 4.84e3 4.08e6 0% 11.0 12.0 13.0 15.0 ES-3 6.84e6 14.18 ES-1 6.01e6 11.89 Rel. Int. 100% 14.0 0.00e0 16.0 RT Abs. Int. 2.56e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.35e4 1.28e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.57e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.78e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6229, 5604 scc: 842-903 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:24 Printed: 31-Mar-2014 19:20 Page 2 of 21 263 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 9.40e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 3.86e3 4.70e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.97e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 1.07e4 1.48e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.00e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.42e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.42e3 1.71e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 6.29e6 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.14e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.31e3 1.07e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.57e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.78e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7500, 9890 scc: 842-903 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:24 (CEM) Printed: 31-Mar-2014 19:20 Page 3 of 21 264 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 PCB-11 1.78e5 SI 19.58 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.96e3 Abs. Int. 5.36e4 PCB-8 4.29e4 SI 17.24 2.68e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% Abs. Int. 1.55e5 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PB 4σ 1.60e4 7.74e4 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 2.73e7 16.41 20.0 21.0 ES-15 2.66e7 20.15 0.00e0 RT Abs. Int. 8.55e6 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.68e4 4.27e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 1.75e7 16.41 20.0 21.0 0.00e0 RT Abs. Int. 5.57e6 ES-15 1.72e7 20.14 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 7.56e3 2.79e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.07e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1514, 5980 scc: 842-903 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:24 (CEM) Printed: 31-Mar-2014 19:20 Page 4 of 21 265 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 PCB-17 5.52e4 19.69 Rel. Int. 100% Abs. Int. 1.32e4 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.87e3 6.62e3 0% 17.0 18.0 19.0 20.0 21.0 PCB-17 4.67e4 19.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e4 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.72e3 7.17e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.91e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.32e4 ES-19 9.93e6 17.52 4.46e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 9.28e6 17.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.84e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.96e4 1.42e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.07e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1032, 8358 scc: 842-903 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:24 (CEM) Printed: 31-Mar-2014 19:20 Page 5 of 21 266 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 28/20 5.36e4 22.93 Rel. Int. 100% PCB-31 3.83e4 22.66 TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 2.94e3 Abs. Int. 1.75e4 21/33 5.83e4 23.12 8.77e3 0% 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 28/20 4.56e4 22.93 Rel. Int. 100% 21/33 4.65e4 23.12 PCB-31 3.44e4 22.66 TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.36e3 Abs. Int. 1.46e4 7.30e3 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 2.05e7 22.91 Rel. Int. 100% ES-37 1.79e7 26.47 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.62e4 Abs. Int. 5.77e6 2.88e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 1.90e7 22.91 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 1.64e7 26.47 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.89e4 Abs. Int. 5.23e6 2.61e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.83e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7587, 0037 scc: 842-903 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:25 (CEM) Printed: 31-Mar-2014 19:20 Page 6 of 21 267 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 3.22e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 1.09e3 1.61e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.13e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 8.76e2 1.57e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 8.24e6 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.34e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 5.56e3 1.17e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.10e7 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.99e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 3.76e3 1.50e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.07e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5742, 9949 scc: 842-903 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:23 (CEM) Printed: 31-Mar-2014 19:20 Page 7 of 21 268 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 PCB-51 4.31e5 23.09 Rel. Int. 100% Abs. Int. 1.19e5 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.04e3 44/47… 1.74e5 25.49 PCB-52 3.62e4 24.55 5.94e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-51 5.69e5 23.09 Rel. Int. 100% Abs. Int. 1.77e5 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.08e3 44/47… 2.14e5 25.49 PCB-52 3.12e4 24.56 8.83e4 0% 22.0 23.0 0.00e0 RT 24.0 25.0 26.0 JS-52 1.11e7 24.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.02e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.03e4 1.51e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 1.36e7 24.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.57e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 7.70e3 1.78e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.83e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3778, 8404 scc: 842-903 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:25 (CEM) Printed: 31-Mar-2014 19:20 Page 8 of 21 269 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Abs. Int. 8.69e4 PCB-68 3.07e5 27.51 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.34e3 4.34e4 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Abs. Int. 9.56e4 PCB-68 3.78e5 27.51 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 1.36e3 4.78e4 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.29e7 32.31 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.51e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 3.38e6 ES-77 1.34e7 32.79 1.69e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.61e7 32.31 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 9.72e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 4.24e6 ES-77 1.69e7 32.79 2.12e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.00e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8610, 4284 scc: 842-903 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:25 (CEM) Printed: 31-Mar-2014 19:20 Page 9 of 21 270 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 1.77e3 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PB 4σ 5.54e2 8.84e2 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.41e3 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PB 4σ 6.72e2 1.21e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.20e7 25.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.16e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 2.06e3 1.58e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 7.49e6 25.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.15e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.73e3 1.07e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.83e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3002, 4833 scc: 842-903 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:24 Printed: 31-Mar-2014 19:20 Page 10 of 21 271 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-95 2.00e4 28.00 113/90… 1.91e4 30.53 PCB-110 2.47e4 32.24 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Abs. Int. 7.56e3 PCB-118 1.55e4 34.78 PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 6.98e2 3.78e3 0% 28.0 Rel. Int. 100% 30.0 32.0 113/90… 2.91e4 30.54 PCB-95 2.82e4 28.00 34.0 36.0 38.0 PCB-110 3.50e4 32.23 0.00e0 RT Abs. Int. 1.05e4 PCB-118 2.26e4 34.79 PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 8.93e2 5.27e3 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.61e7 32.81 JS-101 1.36e7 30.52 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 1.44e3 ES-123 1.53e7 34.48 36.0 ES-118 ES-114 1.52e7 1.57e7 34.76 35.23 38.0 0.00e0 RT Abs. Int. 4.07e6 ES-105 1.55e7 35.77 2.04e6 0% 28.0 30.0 32.0 CS/SS-111 1.01e7 32.81 JS-101 8.88e6 30.52 Rel. Int. 100% 34.0 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.06e3 ES-123 9.35e6 34.48 36.0 ES-118 ES-114 9.73e6 9.80e6 34.76 35.23 38.0 0.00e0 RT Abs. Int. 2.53e6 ES-105 9.64e6 35.77 1.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.00e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4367, 7565 scc: 842-903 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:26 (CEM) Printed: 31-Mar-2014 19:20 Page 11 of 21 272 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 7.80e3 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 8.91e2 3.90e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 1.51e4 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.01e3 7.56e3 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.12e6 ES-126 1.32e7 38.38 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 4.99e3 1.56e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.04e6 ES-126 8.57e6 38.38 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 3.81e3 1.02e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.26e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.28e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3687, 1243 scc: 842-903 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:24 Printed: 31-Mar-2014 19:20 Page 12 of 21 273 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 147/149 2.89e4 33.82 Rel. Int. 100% Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 153/168 2.17e4 36.38 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.77e2 Abs. Int. 8.50e3 163/138… 2.34e4 37.43 4.25e3 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 36.0 38.0 163/138… 2.23e4 37.43 147/149 2.00e4 33.81 Abs. Int. 6.19e3 153/168 1.28e4 36.37 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 5.80e2 0.00e0 RT 3.10e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 1.48e7 30.35 Rel. Int. 100% ES-153 1.04e7 36.35 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.69e3 0.00e0 RT Abs. Int. 3.76e6 JS-138 9.84e6 37.41 1.88e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 1.14e7 30.35 Rel. Int. 100% ES-153 8.15e6 36.35 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.40e3 0.00e0 RT Abs. Int. 2.82e6 JS-138 7.52e6 37.41 1.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.00e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6898, 0697 scc: 842-903 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:26 (CEM) Printed: 31-Mar-2014 19:20 Page 13 of 21 274 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 2.97e3 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PB 4σ 7.78e2 1.48e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.55e3 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PB 4σ 5.88e2 2.27e3 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.33e7 39.94 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 3.74e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 2.45e7 40.93 0.00e0 RT Abs. Int. 4.43e6 ES-169 1.13e7 43.64 2.21e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.06e7 39.94 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 3.84e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.94e7 40.93 0.00e0 RT Abs. Int. 3.49e6 ES-169 9.03e6 43.64 1.74e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.26e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.28e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3522, 6855 scc: 842-903 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:27 (CEM) Printed: 31-Mar-2014 19:20 Page 14 of 21 275 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 2.13e3 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PB 4σ 4.32e2 1.06e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e3 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PB 4σ 6.10e2 1.29e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 9.31e6 35.22 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.30e6 CS/SS-178 5.86e6 37.78 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.24e3 1.15e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 9.12e6 35.22 Rel. Int. 100% Abs. Int. 2.27e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.38e3 CS/SS-178 5.59e6 37.79 1.13e6 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.00e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9936, 2640 scc: 842-903 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:24 Printed: 31-Mar-2014 19:20 Page 15 of 21 276 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 180/193 1.49e4 42.11 PCB-187 8.86e3 38.59 Abs. Int. 4.33e3 HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 6.86e2 2.16e3 0% 39.0 Rel. Int. 100% 40.0 41.0 PCB-187 1.07e4 38.58 42.0 43.0 44.0 45.0 Abs. Int. 4.93e3 180/193 1.32e4 42.10 HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 4.80e2 0.00e0 RT 2.47e3 0% 39.0 40.0 41.0 42.0 ES-180 8.57e6 42.09 Rel. Int. 100% 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.04e6 ES-170 7.25e6 43.16 HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 1.68e3 1.02e6 0% 39.0 40.0 41.0 42.0 ES-180 8.06e6 42.09 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 2.83e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.98e6 ES-170 6.69e6 43.16 9.89e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.26e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.28e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8050, 9649 scc: 842-903 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:27 (CEM) Printed: 31-Mar-2014 19:20 Page 16 of 21 277 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 1.54e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 8.27e2 7.69e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 2.02e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 6.41e2 1.01e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.02e7 45.77 0.00e0 RT Abs. Int. 2.39e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 3.00e3 1.19e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 9.96e6 45.77 0.00e0 RT Abs. Int. 2.36e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.51e3 1.18e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.68e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.34e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5130, 6083 scc: 842-903 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:24 Printed: 31-Mar-2014 19:20 Page 17 of 21 278 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 1.76e3 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PB 4σ 5.32e2 8.81e2 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.24e3 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PB 4σ 6.37e2 1.62e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 8.31e6 39.76 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.14e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.15e3 1.07e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 9.12e6 39.76 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.16e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.31e3 1.08e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.26e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.28e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4809, 5026 scc: 842-903 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:24 Printed: 31-Mar-2014 19:20 Page 18 of 21 279 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 1.65e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PB 4σ 6.56e2 8.24e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.48e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PB 4σ 5.75e2 7.42e2 0% 46.0 47.0 48.0 JS-194 5.78e6 47.53 Rel. Int. 100% 49.0 50.0 ES-205 6.77e6 47.93 0.00e0 RT Abs. Int. 1.60e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 1.98e3 7.99e5 0% 46.0 47.0 48.0 JS-194 6.62e6 47.53 Rel. Int. 100% 49.0 50.0 ES-205 7.59e6 47.93 0.00e0 RT Abs. Int. 1.78e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.65e3 8.92e5 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.68e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.34e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5717, 3517 scc: 842-903 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:24 Printed: 31-Mar-2014 19:20 Page 19 of 21 280 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 2.81e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 1.03e3 1.41e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 5.22e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 1.49e3 2.61e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 1.69e6 ES-208 7.27e6 45.38 ES-206 4.38e6 49.39 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.30e3 8.44e5 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 2.15e6 ES-208 9.06e6 45.38 ES-206 5.50e6 49.39 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.72e3 1.08e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.68e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.34e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0725, 8471 scc: 842-903 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:24 Printed: 31-Mar-2014 19:20 Page 20 of 21 281 of 711 SGS-AP ID: A6504_11892_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 27-Mar-2014 04:28:49 User: LKB Datafile: 140326X16 Rel. Int. 100% Abs. Int. 1.94e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: PB 4σ 4.56e2 9.70e2 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.70e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: PB 4σ 5.63e2 8.51e2 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 6.84e6 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.53e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 8.45e2 7.65e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 5.73e6 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.21e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 8.14e2 6.03e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.53e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.26e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_008.utp_res, saved 31-Mar-2014 18:28 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0288, 0318 scc: 842-903 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:23 (CEM) Printed: 31-Mar-2014 19:20 Page 21 of 21 282 of 711 Lab ID: A6504_11892_PCB_009-RJ2 ACQ: 28-Mar-2014 14:24:30 LKB Wt/Vol: 0.90 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XA Client ID: EB1-01 (DISSOLVED) UTP: 31-Mar-2014 18:44 CEM J-level: 11.1 pg/L Datafile: 140328X05 RPT: 31-Mar-2014 19:02 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB NotFnd NotFnd NotFnd NotFnd 34.75 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.87 14.16 14.41 20.11 17.48 26.43 20.39 32.75 32.28 25.36 35.73 35.19 34.72 34.44 38.34 36.31 30.31 40.89 39.90 43.60 43.11 42.04 35.18 45.72 39.71 47.88 49.34 45.34 50.77 QC J B EMPC C Pred RRT Actual RRT 1.0006 1.0005 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0007 - 0.7244 0.8639 0.8794 1.2273 1.0673 1.0788 0.8328 1.3366 1.3172 0.8324 1.1721 1.1544 1.1392 1.1300 1.2577 0.9716 0.8113 1.0940 1.0677 1.1666 0.9080 0.8855 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0.7245 0.8642 0.8793 1.2277 1.0673 1.0792 0.8326 1.3372 1.3178 0.8322 1.1725 1.1547 1.1394 1.1302 1.2582 0.9716 0.8110 1.0941 1.0678 1.1667 0.9079 0.8855 0.7409 0.9629 0.8364 1.0084 1.0392 0.9548 1.0693 Diff Secs +0.2 +0.1 +0.3 -0.1 +0.5 0 +0.6 -0.2 +1.2 +1.2 -0.3 +0.9 +0.6 +0.4 +0.4 +1.2 0 -0.5 +0.2 +0.2 +0.3 -0.3 0 -0.4 0 -0.2 0 0 0 -0.3 Page 1 of 5 Split: 1 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.38E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.66E+07 4.18E+07 2.27E+07 6.14E+07 2.56E+07 5.07E+07 2.72E+07 4.52E+07 4.45E+07 2.84E+07 3.75E+07 3.76E+07 3.67E+07 3.64E+07 3.22E+07 2.67E+07 3.87E+07 6.38E+07 3.44E+07 2.91E+07 1.97E+07 2.34E+07 2.58E+07 2.97E+07 2.48E+07 2.11E+07 1.46E+07 2.36E+07 1.85E+07 Checkcode: 477-807-FJT Ra 0.73 3.28 3.37 1.66 1.58 1.04 1.10 0.77 0.82 0.80 1.65 1.61 1.60 1.62 1.58 1.55 1.29 1.25 1.29 1.27 1.33 1.11 1.08 1.11 1.05 0.92 0.89 0.83 0.80 1.18 Method 1668A RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ND ND ND ND 1.73 ND ND ND ND ND ND ND 3.00E+03 3.00E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.42E+03 1.42E+03 1.42E+03 1.44E+03 1.05E+03 1.37 1.37 0.915 0.82 0.852 0.844 1.05 1.32 0.815 1.02 1.08 1.31 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 46.1 % 57.8 % 65.4 % 88.7 % 76.1 % 87 % 90.1 % 93.1 % 92.8 % 108 % 95.5 % 94.7 % 97.1 % 94 % 96 % 92.6 % 94.7 % 77.4 % 80 % 72.8 % 92.1 % 91.4 % 107 % 99.5 % 99.4 % 89.8 % 93.6 % 107 % 88.3 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Printed: 3/31/2014 7:04 PM 283 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.87 32.77 37.74 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 5.70E+07 3.95E+07 1.66E+07 1.09 1.58 1.07 1.11 1.03 0.62 101 % 105 % 104 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.87 32.77 37.74 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 5.70E+07 3.95E+07 1.66E+07 1.09 1.58 1.07 1.85 1.22 0.58 88.1 % 99.2 % 111 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.38 24.49 30.47 37.37 47.48 6.65E+07 3.51E+07 3.26E+07 2.57E+07 1.89E+07 1.58 0.80 1.60 1.27 0.91 4.09E+03 4.09E+03 4.09E+03 5.27E+03 5.27E+03 6.47E+03 6.47E+03 6.47E+03 6.47E+03 6.47E+03 6.47E+03 6.47E+03 6.47E+03 6.47E+03 5.36E+03 5.36E+03 5.36E+03 5.36E+03 5.36E+03 5.36E+03 1.67 1.38 1.61 3.07 1.98 2.2 1.87 1.99 1.96 1.91 1.68 1.98 1.99 2.07 3.28 2.42 2.84 2.08 2.18 3.62 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 19.55 NotFnd NotFnd NotFnd NotFnd 19.66 NotFnd NotFnd NotFnd B C C J 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0505 0.9333 0.9721 0.9866 1.0008 1.0010 1.1015 1.1244 1.1354 1.1430 1.1485 0.9722 1.1245 - +0.1 +0.1 Page 2 of 5 NON-EMPC 0 11.6 16.8 117 6.83 4.86 0 0 0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.39E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 9.12E+04 0.00E+00 0.00E+00 0.00E+00 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 0 11.6 23.1 121 12 4.86 0 0 0 1.79 0.95 0.95 1.18 1.01 1.23 1.91 0.96 1.13 1.06 1.08 1.10 1.26 1.06 1.06 1.02 1.15 1.56 1.33 1.81 1.72 1.04 DL 1.64 2.57 2.54 1.25 0.866 0.935 1.15 1.37 3.24 ND ND ND ND ND ND ND ND ND ND ND 11.6 ND ND ND ND 5.99 ND ND ND Printed: 3/31/2014 7:04 PM 284 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB NotFnd NotFnd NotFnd NotFnd 22.34 22.62 22.89 23.09 23.46 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 23.05 NotFnd 24.51 NotFnd NotFnd 24.96 NotFnd 25.44 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 27.48 NotFnd NotFnd NotFnd NotFnd 28.73 29.01 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC C J J B J B C J EMPC C J EMPC C J B EMPC J B C J B C C C J B C J Pred RRT Actual RRT 1.1759 0.8218 0.8275 0.8382 0.8457 0.8562 0.8669 0.8738 0.8879 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9385 0.9414 0.9499 1.0009 1.0062 1.0100 1.0181 1.0296 1.0384 1.0497 1.0563 1.0700 1.0738 1.0819 0.8435 0.8514 0.8630 0.8692 0.8741 0.8811 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.8452 0.8558 0.8661 0.8735 0.8875 0.9412 1.0007 1.0189 1.0388 0.8513 0.8901 0.8987 - Diff Secs -0.7 -0.5 -1.1 -0.4 -0.6 -0.3 -0.3 +1.2 +0.6 -0.2 0 -0.2 Page 3 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 9.32E+04 9.96E+04 1.41E+05 1.33E+05 5.57E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.02E+06 0.00E+00 7.45E+04 0.00E+00 0.00E+00 5.53E+04 0.00E+00 4.38E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 9.39E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.15E+05 6.06E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.05 0.98 0.90 1.23 1.30 0.86 1.07 0.83 0.81 0.80 0.77 0.68 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.93 1.33 1.35 1.38 1.37 1.42 1.30 1.35 1.26 1.34 1.40 1.26 1.18 1.08 1.35 0.97 0.82 0.98 0.78 0.92 1.23 0.79 1.13 0.94 0.99 1.28 0.85 0.77 0.96 1.35 1.36 1.42 1.28 1.33 1.36 1.43 1.29 1.23 1.22 1.20 1.20 1.43 1.36 1.14 1.43 1.18 1.03 0.87 ND ND ND ND 2.98 3.09 4.76 4.35 1.95 ND ND ND ND ND ND ND ND 52.5 ND 4.05 ND ND 2.45 ND 22.2 ND ND ND ND ND ND 33.1 ND ND ND ND 4.48 2.47 ND ND ND ND ND ND ND ND ND ND 5.36E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 4.43E+03 1.63E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 2.48E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 3.00E+03 1.38E+03 1.38E+03 1.65E+03 1.65E+03 1.95 1.46 1.44 1.41 1.41 1.37 1.49 1.44 1.55 1.45 1.39 1.55 1.65 1.8 0.84 1.31 1.55 1.3 1.63 1.37 1.03 1.6 1.12 1.35 1.28 0.989 1.49 1.66 1.33 0.936 1.13 1.08 1.2 1.15 1.13 1.07 1.19 1.24 1.26 1.28 1.27 1.07 1.12 1.34 0.709 0.861 0.997 1.18 Printed: 3/31/2014 7:04 PM 285 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.96 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.48 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 32.20 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 33.77 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 36.33 SGS Evironmental Services QC J B EMPC C J B C C C J B C C J B C C J B C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9304 0.9404 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0207 1.0320 1.0495 1.0525 1.0563 1.0592 1.0656 1.0758 1.0888 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0207 1.0297 1.0715 1.0886 1.0955 1.1042 1.1142 1.1199 1.1225 1.1313 1.1370 1.1418 1.1495 1.1628 0.9524 0.9582 0.9614 0.9728 0.9174 1.0003 1.0565 1.1142 0.9721 -0.3 +0.7 +0.4 0 -1.5 Page 4 of 5 Response Ra RRF Conc. / Recv. 5.14E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.60E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.53E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.37E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.77E+04 0.48 0.91 0.93 1.09 0.78 0.85 0.99 0.78 0.81 1.31 0.89 1.03 0.76 0.96 1.25 1.03 1.09 0.93 1.14 1.22 0.73 1.25 1.27 1.12 1.26 1.11 1.03 1.14 1.26 1.08 1.08 0.99 1.03 1.14 1.10 1.30 1.11 1.10 0.79 1.13 1.14 0.95 0.94 0.97 1.04 1.32 1.14 1.43 1.38 3.45 ND ND ND ND ND ND ND ND ND 3.32 ND ND ND ND ND ND 3.51 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.57 ND ND ND ND ND ND ND ND ND ND 2.29 0.67 0.59 1.34 1.37 Noise / Recv. Low DL / Recv. High 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.12 1.11 0.942 1.3 1.21 1.03 1.32 1.26 0.782 1.16 0.99 1.35 1.07 0.82 0.997 0.936 1.1 0.898 0.837 1.4 0.818 0.808 0.915 0.809 0.925 0.955 0.893 0.588 0.69 0.689 0.75 0.722 0.914 0.946 0.8 0.931 0.943 1.31 0.915 0.913 1.09 1.11 1.07 0.995 0.788 0.906 0.726 0.754 Printed: 3/31/2014 7:04 PM 286 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC C C C C C Pred RRT Actual RRT 0.9767 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0888 1.0953 1.1003 1.1101 1.1125 1.1156 1.1263 1.1362 1.1414 0.9079 0.9133 0.9193 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 - Diff Secs Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Page 5 of 5 Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.00 0.90 1.12 1.34 1.10 1.27 1.48 0.88 1.08 1.07 1.27 1.07 1.03 1.13 1.04 0.74 1.11 1.20 1.22 1.28 1.06 1.00 0.98 1.11 0.96 1.00 1.31 1.26 1.36 1.09 1.52 1.05 1.10 1.04 1.13 1.04 0.70 0.74 0.78 0.82 0.84 1.06 1.12 1.15 1.11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.26E+03 1.42E+03 1.42E+03 1.42E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.50E+03 1.50E+03 1.50E+03 2.84E+03 2.84E+03 2.84E+03 1.04 1.15 0.925 0.773 0.947 0.815 0.701 1.07 0.879 0.887 0.837 0.992 1.03 0.937 1.02 1.43 1.26 1.17 1.15 1.1 1.33 1.4 1.42 1.26 1.45 1.4 1.07 1.11 1.03 1.43 1.03 1.18 1.13 1.2 1.1 1.19 1.78 1.67 1.6 2.03 1.98 1.57 2.53 2.48 3.94 Printed: 3/31/2014 7:04 PM 287 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.47e7 2.24e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 9.10e6 4.55e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 7.57e6 3.78e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.11 330.9792 Fn4 Flags: 0% Abs. Int. 1.45e7 7.24e6 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 Rel. Int. QC chk 100% 38.13-45.15 380.9760 Fn5 Flags: 0% Abs. Int. 8.28e6 4.14e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.41e6 7.04e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.33e6 6.67e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 477-807 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:22 Page 1 of 21 288 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 1.34e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 2.35e3 6.69e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.87e3 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 1.74e3 3.44e3 0% 11.0 12.0 13.0 ES-1 2.80e7 11.87 Rel. Int. 100% 14.0 15.0 ES-3 3.22e7 14.16 0.00e0 16.0 RT Abs. Int. 1.10e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 7.38e3 5.48e6 0% 11.0 12.0 13.0 ES-1 8.54e6 11.87 Rel. Int. 100% 14.0 15.0 ES-3 9.57e6 14.16 0.00e0 16.0 RT Abs. Int. 3.50e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.66e4 1.75e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.47e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.24e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1440, 1618 scc: 477-807 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 2 of 21 289 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 8.34e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 3.21e3 4.17e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.24e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 1.03e4 1.12e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.42e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.85e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.63e3 2.43e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 8.55e6 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.93e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.03e3 1.47e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.47e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.24e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2771, 8411 scc: 477-807 Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 3 of 21 290 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 PCB-11 2.18e5 19.55 Rel. Int. 100% Abs. Int. 6.12e4 DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 3.94e3 3.06e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-11 1.22e5 19.55 Rel. Int. 100% Abs. Int. 4.68e4 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.04e4 2.34e4 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 4.08e7 16.38 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.96e4 20.0 21.0 (3.75e7 + 2.38e7) * 2000 pg * 100 = 88.5% (4.08e7 + 2.58e7) *2000 pg * 1.04 CEM 31-Mar-2014 19:14 0.00e0 RT Abs. Int. 1.31e7 ES-15 3.75e7 20.11 Recv(ES-15) = 6.53e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 2.58e7 16.38 20.0 21.0 Abs. Int. 8.24e6 ES-15 2.38e7 20.11 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 7.66e3 0.00e0 RT 4.12e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.10e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.55e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9715, 9463 scc: 477-807 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 4 of 21 291 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 PCB-17 4.45e4 19.66 Rel. Int. 100% Abs. Int. 1.34e4 (4.45e4 + 4.67e4) * 2000 pg = 5.97 pg/L (1.31e7 + 1.25e7) * 1.33 * 0.897L CEM 31-Mar-2014 19:13 Conc(PCB-17) = TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.83e3 6.72e3 0% 17.0 18.0 19.0 20.0 21.0 PCB-17 4.67e4 19.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.36e4 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.54e3 6.80e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.44e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 3.54e4 ES-19 1.31e7 17.48 4.22e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.25e7 17.48 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.93e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 1.99e4 1.96e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.10e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.55e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2218, 1685 scc: 477-807 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 5 of 21 292 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-25 4.77e4 22.34 TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 2.78e3 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 28/20 PCB-31 6.67e4 4.94e4 22.89 22.62 Abs. Int. 1.75e4 PCB-22 3.56e4 23.46 8.73e3 0% 22.0 23.0 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 1.65e3 PCB-25 4.55e4 22.34 PCB-31 5.02e4 22.62 24.0 25.0 0.00e0 RT 26.0 28/20 7.43e4 22.90 21/33 6.52e4 23.08 Abs. Int. 1.97e4 PCB-22 2.73e4 23.46 9.86e3 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 2.98e7 22.87 Rel. Int. 100% ES-37 2.66e7 26.43 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.60e4 Abs. Int. 8.24e6 4.12e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 2.72e7 22.87 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 2.41e7 26.43 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.88e4 Abs. Int. 7.46e6 3.73e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.57e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.78e6 0% 22.0 23.0 24.0 25.0 26.0 0.00e0 RT Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7735, 8018 scc: 477-807 Revised: 31-Mar-2014 18:43 (CEM) Printed: 31-Mar-2014 19:22 Page 6 of 21 293 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 3.53e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 6.92e2 1.76e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.20e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 9.38e2 1.10e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.19e7 20.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.49e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 3.89e3 1.75e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.53e7 20.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.36e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 2.27e3 2.18e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.10e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.55e6 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0405, 0375 scc: 477-807 Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 7 of 21 294 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 PCB-51 4.71e5 23.05 Rel. Int. 100% Abs. Int. 1.30e5 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.12e3 PCB-52 4.47e4 24.51 44/47… 1.96e5 25.44 6.52e4 69/49 2.50e4 24.96 0% 22.0 23.0 24.0 25.0 26.0 PCB-51 5.51e5 23.05 Rel. Int. 100% Abs. Int. 1.56e5 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.36e3 PCB-52 4.19e4 24.51 69/49 3.02e4 24.96 44/47… 2.42e5 25.44 7.80e4 0% 22.0 23.0 0.00e0 RT 24.0 25.0 26.0 JS-52 1.56e7 24.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.27e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 6.45e3 2.14e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 1.95e7 24.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.15e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 5.53e3 2.57e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.57e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.78e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5724, 1447 scc: 477-807 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 8 of 21 295 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Abs. Int. 1.00e5 PCB-68 4.17e5 27.48 TeCB-4 26.97-38.11 289.9224 Fn4 Flags: PBM 4σ 1.23e3 5.01e4 61/70... 5.01e4 28.73 PCB-66 2.45e4 29.01 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 Abs. Int. 1.39e5 PCB-68 5.22e5 27.47 TeCB-4 26.97-38.11 291.9194 Fn4 Flags: PBM 4σ 1.77e3 0.00e0 38.0 RT 6.95e4 61/70... 6.52e4 28.73 PCB-66 3.61e4 29.01 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.98e7 32.28 TeCB Std. 26.97-38.11 301.9626 Fn4 Flags: PBM 4σ 9.65e3 34.0 36.0 0.00e0 38.0 RT Abs. Int. 4.86e6 ES-77 2.03e7 32.75 2.43e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 2.47e7 32.28 TeCB Std. 26.97-38.11 303.9597 Fn4 Flags: PBM 4σ 4.91e3 34.0 36.0 0.00e0 38.0 RT Abs. Int. 5.94e6 ES-77 2.48e7 32.75 2.97e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.45e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.24e6 0% 28.0 30.0 32.0 34.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8936, 8952 scc: 477-807 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 9 of 21 296 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 2.30e3 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PB 4σ 7.52e2 1.15e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.19e3 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PB 4σ 6.30e2 1.09e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.77e7 25.36 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.71e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.89e3 2.36e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.07e7 25.36 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.90e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.36e3 1.45e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.57e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.78e6 0% 22.0 23.0 24.0 25.0 26.0 0.00e0 RT Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5462, 8375 scc: 477-807 Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 10 of 21 297 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.97-38.11 323.8834 Fn4 Flags: PBM 4σ 8.44e2 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 113/90… 2.26e4 30.48 PCB-95 1.97e4 27.96 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Abs. Int. 9.09e3 PCB-110 2.43e4 32.20 PCB-118 1.53e4 34.75 4.55e3 0% 28.0 Rel. Int. 100% 30.0 PCB-95 4.06e4 27.96 32.0 113/90… 3.34e4 30.50 PeCB-4 26.97-38.11 325.8804 Fn4 Flags: PBM 4σ 8.05e2 34.0 36.0 PCB-110 4.11e4 32.19 0.00e0 38.0 RT Abs. Int. 1.19e4 PCB-118 2.09e4 34.74 5.97e3 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 2.42e7 32.77 JS-101 2.01e7 30.47 PeCB Std. 26.97-38.11 337.9207 Fn4 Flags: PBM 4σ 2.37e3 ES-123 2.23e7 34.44 36.0 ES-118 ES-114 2.27e7 2.32e7 34.72 35.19 ES-105 2.31e7 35.73 0.00e0 38.0 RT Abs. Int. 5.85e6 2.93e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.53e7 32.76 JS-101 1.26e7 30.47 PeCB Std. 26.97-38.11 339.9177 Fn4 Flags: PBM 4σ 2.27e3 36.0 ES-118 ES-114 1.45e7 ES-123 1.40e7 35.19 1.41e7 34.72 34.44 ES-105 1.43e7 35.73 0.00e0 38.0 RT Abs. Int. 3.71e6 1.86e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.45e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.24e6 0% 28.0 30.0 32.0 34.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5587, 8633 scc: 477-807 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 11 of 21 298 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 9.66e3 PeCB-5 38.13-45.15 323.8834 Fn5 Flags: PB 4σ 8.69e2 4.83e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 1.65e4 PeCB-5 38.13-45.15 325.8804 Fn5 Flags: PB 4σ 7.85e2 8.26e3 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.82e6 ES-126 1.96e7 38.34 PeCB Std. 38.13-45.15 337.9207 Fn5 Flags: PBM 4σ 3.83e3 2.41e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.11e6 ES-126 1.26e7 38.34 PeCB Std. 38.13-45.15 339.9177 Fn5 Flags: PBM 4σ 3.63e3 1.55e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.28e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8722, 0872 scc: 477-807 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 12 of 21 299 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 147/149 1.93e4 33.77 Rel. Int. 100% Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 153/168 2.18e4 36.33 Abs. Int. 6.35e3 HxCB-4 26.97-38.11 359.8415 Fn4 Flags: PBM 4σ 6.16e2 3.17e3 0% 28.0 30.0 32.0 34.0 147/149 1.44e4 33.76 Rel. Int. 100% 0.00e0 38.0 RT 36.0 153/168 1.59e4 36.33 Abs. Int. 5.01e3 HxCB-4 26.97-38.11 361.8385 Fn4 Flags: PBM 4σ 6.40e2 2.50e3 0.00e0 38.0 RT 0% 28.0 30.0 32.0 34.0 ES-155 2.15e7 30.31 Rel. Int. 100% 36.0 ES-153 1.50e7 36.31 HxCB Std. 26.97-38.11 371.8817 Fn4 Flags: PBM 4σ 1.20e3 JS-138 1.44e7 37.37 Abs. Int. 5.25e6 2.62e6 0% 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 ES-155 1.72e7 30.31 Rel. Int. 100% ES-153 1.17e7 36.31 HxCB Std. 26.97-38.11 373.8788 Fn4 Flags: PBM 4σ 1.42e3 JS-138 1.13e7 37.37 Abs. Int. 4.25e6 2.12e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.45e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.24e6 0% 28.0 30.0 32.0 34.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7503, 6456 scc: 477-807 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 13 of 21 300 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 1.81e3 HxCB-5 38.13-45.15 359.8415 Fn5 Flags: PB 4σ 5.32e2 9.03e2 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e3 HxCB-5 38.13-45.15 361.8385 Fn5 Flags: PB 4σ 8.90e2 1.01e3 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.92e7 39.90 HxCB Std. 38.13-45.15 371.8817 Fn5 Flags: PBM 4σ 3.25e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.60e7 40.89 0.00e0 RT Abs. Int. 6.17e6 ES-169 1.66e7 43.60 3.08e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.51e7 39.90 HxCB Std. 38.13-45.15 373.8788 Fn5 Flags: PBM 4σ 5.75e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 2.78e7 40.89 0.00e0 RT Abs. Int. 4.86e6 ES-169 1.25e7 43.60 2.43e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.28e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6486, 6275 scc: 477-807 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 14 of 21 301 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 1.93e3 HpCB-4 30.00-38.11 393.8025 Fn4 Flags: PB 4σ 6.18e2 9.66e2 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.98e3 HpCB-4 30.00-38.11 395.7995 Fn4 Flags: PB 4σ 5.90e2 9.91e2 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.36e7 35.18 Rel. Int. 100% Abs. Int. 3.34e6 CS/SS-178 8.57e6 37.74 HpCB Std. 30.00-38.11 405.8428 Fn4 Flags: PBM 4σ 1.31e3 1.67e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.22e7 35.18 Rel. Int. 100% CS/SS-178 8.04e6 37.74 1.56e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 3.11e6 HpCB Std. 30.00-38.11 407.8398 Fn4 Flags: PBM 4σ 1.35e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.45e7 QC Check 30.00-38.11 330.9792 Fn4 Flags: - 7.24e6 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3196, 1614 scc: 477-807 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 15 of 21 302 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 2.62e3 HpCB-5 38.13-45.15 393.8025 Fn5 Flags: PB 4σ 7.77e2 1.31e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e3 HpCB-5 38.13-45.15 395.7995 Fn5 Flags: PB 4σ 5.98e2 1.09e3 0% 39.0 40.0 41.0 42.0 ES-180 1.22e7 42.04 Rel. Int. 100% 43.0 44.0 45.0 ES-170 1.04e7 43.11 0.00e0 RT Abs. Int. 2.84e6 HpCB-5 Std. 38.13-45.15 405.8428 Fn5 Flags: PBM 4σ 1.90e3 1.42e6 0% 39.0 40.0 41.0 42.0 ES-180 1.12e7 42.04 Rel. Int. 100% HpCB-5 Std. 38.13-45.15 407.8398 Fn5 Flags: PBM 4σ 3.07e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.60e6 ES-170 9.33e6 43.11 1.30e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.28e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6540, 1353 scc: 477-807 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 16 of 21 303 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 2.26e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 7.42e2 1.13e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 1.61e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 7.02e2 8.06e2 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.52e7 45.72 0.00e0 RT Abs. Int. 3.57e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.28e3 1.78e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.45e7 45.72 0.00e0 RT Abs. Int. 3.48e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.83e3 1.74e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 7.04e5 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4185, 2655 scc: 477-807 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 17 of 21 304 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 2.11e3 OcCB-5 38.13-45.15 427.7635 Fn5 Flags: PB 4σ 7.15e2 1.06e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.64e3 OcCB-5 38.13-45.15 429.7606 Fn5 Flags: PB 4σ 5.98e2 8.20e2 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.19e7 39.71 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.82e6 OcCB Std. 38.13-45.15 439.8038 Fn5 Flags: PBM 4σ 1.39e3 1.41e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.29e7 39.71 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.15e6 OcCB Std. 38.13-45.15 441.8008 Fn5 Flags: PBM 4σ 1.51e3 1.58e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.28e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3193, 5765 scc: 477-807 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 18 of 21 305 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 1.87e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PB 4σ 7.58e2 9.36e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.48e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PB 4σ 7.39e2 7.39e2 0% 46.0 47.0 48.0 JS-194 9.00e6 47.48 Rel. Int. 100% 49.0 50.0 ES-205 9.93e6 47.88 0.00e0 RT Abs. Int. 2.37e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 3.49e3 1.18e6 0% 46.0 47.0 48.0 JS-194 9.87e6 47.48 Rel. Int. 100% 49.0 50.0 ES-205 1.11e7 47.88 0.00e0 RT Abs. Int. 2.57e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.18e3 1.29e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 7.04e5 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6490, 2547 scc: 477-807 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 19 of 21 306 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 2.76e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 1.15e3 1.38e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 4.68e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 1.70e3 2.34e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 1.05e7 45.34 50.0 0.00e0 RT Abs. Int. 2.47e6 ES-206 6.63e6 49.34 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.26e3 1.24e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.09e6 ES-208 1.31e7 45.34 ES-206 8.02e6 49.34 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.21e3 1.55e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 7.04e5 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6705, 8778 scc: 477-807 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 20 of 21 307 of 711 SGS-AP ID: A6504_11892_PCB_009-RJ2 Instr: AutoSpec-Premier MM7 Sample ID: EB1-01 (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 28-Mar-2014 14:24:30 User: LKB Datafile: 140328X05 Rel. Int. 100% Abs. Int. 2.17e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: PB 4σ 5.40e2 1.09e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.21e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: PB 4σ 5.11e2 1.61e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 9.99e6 50.77 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.18e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.10e3 1.09e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 8.50e6 50.77 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.82e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 1.09e3 9.10e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.33e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 6.67e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\A6504_11892_PCB_009-RJ2.utp_res, saved 31-Mar-2014 19:15 (CEM) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4154, 2623 scc: 477-807 Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 21 of 21 308 of 711 SGS Analytical Perspectives — Run Log Project: A6504_11892_PCB Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Wt/Vol Client/Sample ID Analyst(s) Checkcode Acq Date Datafile Vial# Lab ID Acq Time 5 140326X05 Tray1:03 CS3_140326_PCB_XC 1.00 SIL 13-73-3 LKB, CEM 507-144 26-Mar-2014 18:21:41 6 140326X06 Tray1:32 OPR1_11892_PCB-RJ 1.00 0_11892_OPR001 LKB, CEM 678-882 26-Mar-2014 19:16:37 7 140326X07 Tray1:02 SBS_140326_PCB_XB 1.00 SIL 13-42-1 LKB, CEM 654-631 26-Mar-2014 20:11:52 8 140326X08 Tray1:33 MB1_11892_PCB_TLX 1.00 Method Blank LKB, CEM 967-196 26-Mar-2014 21:07:05 9 140326X09 Tray1:34 A6504_11892_PCB_001 0.97 PB020-1SWMID-140313-N (TOTAL) LKB, CEM 320-870 26-Mar-2014 22:02:20 10 140326X10 Tray1:35 A6504_11892_PCB_002 0.98 PB031.1-1SWMID-140313-N (TOTAL) LKB, CEM 645-564 26-Mar-2014 22:57:34 11 140326X11 Tray1:36 A6504_11892_PCB_003 0.97 PB047.3-1SWMID-140313-N (TOTAL) LKB, CEM 786-548 26-Mar-2014 23:52:48 12 140326X12 Tray1:37 A6504_11892_PCB_004 0.97 PB056_C-1SWMID-140313-N (TOTAL) LKB, CEM 848-343 27-Mar-2014 00:47:55 13 140326X13 Tray1:38 A6504_11892_PCB_005 0.96 PB056_C-1SWMID-140313-N (DISSOLVED) LKB, CEM 681-037 27-Mar-2014 01:43:07 14 140326X14 Tray1:39 A6504_11892_PCB_006 0.93 EF006.1-1SWMID-140313-N (TOTAL) LKB, CEM 889-569 27-Mar-2014 02:38:21 15 140326X15 Tray1:40 A6504_11892_PCB_007 0.94 PB119_B-1SWMID-140313-N (TOTAL) LKB, CEM 251-126 27-Mar-2014 03:33:35 16 140326X16 Tray1:41 A6504_11892_PCB_008 0.97 EB1-01 (TOTAL) LKB, CEM 842-903 27-Mar-2014 04:28:49 17 140326X17 Tray1:42 A6504_11892_PCB_009 0.90 EB1-01 (DISSOLVED) LKB, CEM 490-847 27-Mar-2014 05:24:04 1 140328X01 Tray1:03 CS3_140328_PCB_XA 1.00 SIL 13-73-3 LKB, CEM 523-232 28-Mar-2014 10:43:57 3 140328X03 Tray1:02 SBS_140328_PCB_XA 1.00 SIL 13-42-1 LKB, CEM 851-325 28-Mar-2014 12:34:10 5 140328X05 Tray1:42 A6504_11892_PCB_009-RJ2 0.90 EB1-01 (DISSOLVED) LKB, CEM 477-807 28-Mar-2014 14:24:30 Project file: not saved AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 Printed: 31-Mar-2014 19:24 309 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services CS3_140326_PCB_XC 26-MAR-2014 18:21 140326X05 Processed: 31-Mar-2014 18:49 ICAL: MM7_PCB_10292013_20DEC2013 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.82 32.34 35.80 35.26 34.80 34.52 38.41 40.96 39.98 43.67 45.80 50.86 4.03E+07 3.97E+07 3.18E+07 3.46E+07 3.26E+07 3.39E+07 2.96E+07 5.34E+07 3.02E+07 2.58E+07 2.60E+07 1.64E+07 0.80 Y 0.79 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.64 Y 1.21 Y 1.22 Y 1.22 Y 1.05 Y 1.17 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.18 1.17 1.09 1.20 1.14 1.19 1.20 1.08 1.15 1.13 1.11 1.06 2.6% 4.4% -2.4% 0.1% -4.1% -1.6% 8.6% -1.8% -1.4% 0.8% 3.2% -5.1% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 11.89 14.18 14.44 20.15 17.52 26.47 20.44 32.80 32.32 25.41 35.78 35.24 34.78 34.49 38.39 36.36 30.36 40.94 39.96 43.65 43.17 42.10 35.23 45.78 39.77 47.94 49.41 45.39 50.84 1.14E+08 1.06E+08 5.84E+07 1.09E+08 5.35E+07 8.06E+07 5.10E+07 6.82E+07 6.80E+07 4.81E+07 5.86E+07 5.75E+07 5.71E+07 5.69E+07 4.93E+07 4.30E+07 6.09E+07 9.92E+07 5.28E+07 4.55E+07 3.21E+07 3.85E+07 4.30E+07 4.69E+07 4.03E+07 3.49E+07 2.45E+07 3.79E+07 3.09E+07 3.31 Y 3.36 Y 1.59 Y 1.58 Y 1.06 Y 1.09 Y 0.77 Y 0.81 Y 0.81 Y 1.58 Y 1.57 Y 1.61 Y 1.61 Y 1.55 Y 1.53 Y 1.31 Y 1.32 Y 1.28 Y 1.27 Y 1.26 Y 1.08 Y 1.05 Y 1.07 Y 1.04 Y 0.92 Y 0.90 Y 0.78 Y 0.78 Y 1.18 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.10 1.02 0.57 1.06 0.52 1.48 0.94 1.25 1.25 0.98 1.19 1.17 1.16 1.15 1.00 1.12 1.59 1.29 1.38 1.19 1.13 1.36 1.12 1.65 1.05 1.23 0.87 1.34 1.09 -7.5% -5.6% 8.6% 1.7% 2.8% -10.7% 9.0% -9.3% -8.5% 21.4% -1.1% -4.2% 0.0% -2.8% -2.8% 0.6% -0.1% -19.2% -17.6% -23.8% 19.5% 19.4% 19.2% 4.5% 8.3% -0.9% 4.3% 13.8% -1.6% Page 1 of 6 310 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services Processed: 31-Mar-2014 18:49 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC 26-MAR-2014 18:21 140326X05 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 22.92 32.82 37.80 8.96E+07 5.99E+07 2.58E+07 1.08 Y 1.57 Y 1.05 Y 1.11 1.03 0.62 1.11 1.05 0.60 0.1% 2.3% -3.0% CS PCB-28 CS PCB-111 CS PCB-178 22.92 32.82 37.80 8.96E+07 5.99E+07 2.58E+07 1.08 Y 1.57 Y 1.05 Y 1.85 1.22 0.58 1.65 1.22 0.67 -10.6% -0.5% 15.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.42 24.54 30.53 37.42 47.54 1.03E+08 5.43E+07 4.93E+07 3.84E+07 2.83E+07 1.56 Y 0.80 Y 1.58 Y 1.29 Y 0.92 Y - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 11.91 14.20 14.45 20.17 17.54 26.49 20.46 25.43 30.38 35.26 39.79 47.96 45.42 49.43 6.03E+07 5.82E+07 3.45E+07 5.80E+07 2.99E+07 4.83E+07 3.39E+07 3.28E+07 3.63E+07 2.48E+07 2.03E+07 1.76E+07 2.09E+07 1.31E+07 3.30 Y 3.34 Y 1.61 Y 1.66 Y 1.04 Y 1.00 Y 0.81 Y 0.64 Y 1.27 Y 1.07 Y 0.92 Y 0.93 Y 0.79 Y 0.78 Y 1.06 1.10 1.18 1.07 1.12 1.20 1.33 1.37 1.19 1.15 1.01 1.01 1.10 1.07 11.5% 9.4% -4.1% 4.5% -2.8% 11.2% -1.7% -4.7% -5.4% -9.1% -4.1% -5.1% -1.9% -3.8% 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 - Page 2 of 6 - 311 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB Processed: 31-Mar-2014 18:49 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC 26-MAR-2014 18:21 140326X05 RT Response RA 11.91 14.02 14.20 14.45 14.63 16.44 16.60 16.83 17.13 17.25 18.81 19.59 19.88 20.17 17.54 19.30 19.70 19.90 20.03 20.13 20.61 21.76 21.91 22.19 22.39 22.67 22.95 23.13 23.51 24.89 25.21 25.74 26.13 26.49 20.46 22.44 23.03 23.10 23.31 24.56 24.69 6.03E+07 5.90E+07 5.82E+07 3.45E+07 5.60E+07 5.22E+07 5.99E+07 5.51E+07 5.51E+07 5.79E+07 6.61E+07 5.80E+07 1.14E+08 5.80E+07 2.99E+07 8.25E+07 3.52E+07 4.80E+07 4.59E+07 2.62E+07 5.15E+07 4.96E+07 5.02E+07 1.02E+08 5.13E+07 5.36E+07 9.94E+07 1.02E+08 4.77E+07 5.22E+07 5.40E+07 4.90E+07 4.71E+07 4.83E+07 3.39E+07 6.16E+07 2.79E+07 2.98E+07 2.50E+07 3.03E+07 3.99E+07 3.30 Y 3.25 Y 3.34 Y 1.61 Y 1.58 Y 1.65 Y 1.64 Y 1.64 Y 1.63 Y 1.64 Y 1.66 Y 1.64 Y 1.64 Y 1.66 Y 1.04 Y 1.04 Y 1.04 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.01 Y 1.01 Y 1.01 Y 1.00 Y 1.00 Y 1.01 Y 1.00 Y 1.01 Y 1.01 Y 1.00 Y 1.00 Y 1.01 Y 1.00 Y 0.81 Y 0.78 Y 0.77 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 RRF 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 1.12 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.54 1.32 1.79 1.72 0.98 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 0.91 0.82 0.88 0.73 0.89 1.18 8.1% -3.2% 1.4% 5.1% 1.7% 0.9% 2.9% 2.9% 5.3% 6.1% 0.3% 0.9% -1.3% -0.5% -2.5% 0.3% 8.3% 7.9% 8.1% 10.1% 8.5% 8.9% 7.8% 9.6% 10.6% 10.7% 10.0% 12.3% 3.4% 7.1% 2.0% 5.1% 5.7% 5.7% 312 of 711 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeC PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB Processed: 31-Mar-2014 18:49 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC 26-MAR-2014 18:21 140326X05 RT Response RA 24.79 24.98 25.27 25.48 25.76 25.92 26.26 26.35 26.55 27.26 27.52 27.89 28.10 28.25 28.48 28.77 29.05 29.20 29.64 29.83 30.15 31.47 31.96 25.43 25.75 27.44 27.63 28.01 28.22 28.33 28.40 28.71 28.77 28.96 29.38 29.72 30.04 30.52 30.96 2.60E+07 7.40E+07 3.03E+07 9.66E+07 1.27E+08 2.77E+07 2.54E+07 6.16E+07 4.46E+07 4.31E+07 4.50E+07 4.10E+07 4.15E+07 4.39E+07 4.62E+07 1.66E+08 3.98E+07 3.91E+07 3.93E+07 3.96E+07 4.69E+07 4.47E+07 3.77E+07 3.28E+07 2.80E+07 2.71E+07 2.28E+07 2.47E+07 4.98E+07 2.50E+07 2.43E+07 2.41E+07 2.44E+07 2.05E+07 2.22E+07 3.47E+07 2.40E+07 8.31E+07 1.88E+07 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.80 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.80 Y 0.79 Y 0.79 Y 0.79 Y 0.80 Y 0.79 Y 0.79 Y 0.80 Y 0.79 Y 0.81 Y 0.64 Y 0.64 Y 0.61 Y 0.61 Y 0.60 Y 0.61 Y 0.62 Y 0.63 Y 0.61 Y 0.63 Y 0.61 Y 0.61 Y 0.63 Y 0.62 Y 0.61 Y 0.62 Y Page 4 of 6 RRF 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.17 0.95 0.80 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 7.5% 6.5% 6.2% 4.9% 6.6% 7.0% 7.7% 5.5% 7.5% 4.8% 3.7% 3.7% 3.6% 2.7% 4.6% 1.8% 6.4% 2.8% 4.2% 2.7% 5.1% 0.7% 4.7% -5.0% 2.4% 0.0% 0.3% 1.4% -9.1% 12.6% 6.0% -9.2% 0.5% 2.1% 1.5% 2.9% -1.3% -7.6% 313 of 711 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Processed: 31-Mar-2014 18:49 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC 26-MAR-2014 18:21 140326X05 Name PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB RT Response RA 31.05 31.16 31.50 32.04 32.13 32.25 32.33 32.53 32.84 33.24 34.20 34.41 34.63 35.09 37.03 30.38 30.54 30.68 30.99 31.26 32.53 33.05 33.26 33.52 33.82 34.00 34.08 34.34 34.52 34.66 34.90 35.30 35.64 35.86 35.97 36.40 36.55 36.89 37.09 37.17 37.46 2.80E+07 3.29E+07 1.67E+08 3.09E+07 5.51E+07 3.13E+07 3.19E+07 1.98E+07 3.42E+07 3.48E+07 6.25E+07 3.47E+07 3.08E+07 2.90E+07 3.12E+07 3.63E+07 3.31E+07 3.41E+07 3.12E+07 3.16E+07 2.42E+07 4.56E+07 2.70E+07 2.37E+07 4.74E+07 1.75E+07 2.35E+07 4.78E+07 2.03E+07 1.98E+07 2.09E+07 2.23E+07 2.84E+07 2.49E+07 3.06E+07 5.95E+07 2.17E+07 1.96E+07 2.47E+07 2.95E+07 7.26E+07 0.62 Y 0.62 Y 0.61 Y 0.60 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.61 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.28 Y 1.26 Y 1.27 Y 1.26 Y 1.25 Y 1.27 Y 1.25 Y 1.27 Y 1.28 Y 1.26 Y 1.27 Y 1.27 Y 1.28 Y 1.28 Y 1.24 Y 1.26 Y 1.26 Y 1.27 Y 1.25 Y 1.25 Y 1.28 Y 1.26 Y Page 5 of 6 RRF 0.92 1.17 0.98 1.14 0.94 1.12 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 1.01 0.91 1.15 1.37 1.12 6.8% -0.9% -0.3% -4.4% 3.0% -1.7% -3.3% -0.3% -1.5% 0.9% 0.1% -2.5% -2.0% 1.5% -2.8% -7.2% -4.8% -3.9% -6.9% -5.0% -7.0% -6.5% -6.8% -6.4% -12.0% -3.1% -7.9% -8.0% -6.9% -5.8% -8.4% -6.3% -3.6% -6.5% -5.0% -7.5% -6.6% -1.3% -8.5% -5.5% 314 of 711 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB Processed: 31-Mar-2014 18:49 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC 26-MAR-2014 18:21 140326X05 RT Response RA 37.60 37.78 38.52 39.33 39.57 35.26 35.54 36.00 36.29 36.69 37.82 38.36 38.59 38.77 39.11 39.20 39.31 39.68 40.03 40.21 41.56 41.81 42.09 42.42 43.19 43.64 39.79 40.57 41.15 41.34 41.43 43.75 44.33 44.50 45.62 47.56 47.96 45.42 46.20 49.43 2.72E+07 3.20E+07 4.67E+07 2.83E+07 2.82E+07 2.48E+07 2.33E+07 2.24E+07 2.48E+07 2.32E+07 1.62E+07 2.10E+07 2.24E+07 2.30E+07 2.36E+07 2.02E+07 1.94E+07 1.84E+07 2.08E+07 3.64E+07 1.90E+07 2.47E+07 4.74E+07 2.60E+07 1.79E+07 2.48E+07 2.03E+07 2.25E+07 2.09E+07 2.20E+07 2.19E+07 2.91E+07 1.54E+07 1.57E+07 1.31E+07 1.42E+07 1.76E+07 2.09E+07 2.15E+07 1.31E+07 1.27 Y 1.25 Y 1.21 Y 1.22 Y 1.20 Y 1.07 Y 1.06 Y 1.07 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 1.05 Y 1.07 Y 1.05 Y 1.07 Y 1.06 Y 1.06 Y 1.07 Y 1.06 Y 1.07 Y 1.06 Y 1.04 Y 1.06 Y 1.05 Y 0.92 Y 0.90 Y 0.91 Y 0.90 Y 0.92 Y 0.90 Y 0.91 Y 0.92 Y 0.92 Y 0.92 Y 0.93 Y 0.79 Y 0.78 Y 0.78 Y Page 6 of 6 RRF 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 1.27 1.49 0.89 1.07 1.07 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.14 - -16.4% -10.4% -1.6% -3.7% -0.3% -6.6% -7.6% -6.5% -4.1% -10.6% 1.9% 2.5% 1.8% 2.0% -0.9% 1.9% 0.8% -0.7% -0.3% 0.1% -0.1% -2.3% -3.2% -1.8% -7.0% -8.6% -7.0% -8.5% -2.0% -10.8% -8.5% -10.8% -2.1% -3.6% -4.5% - 315 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.78e7 2.89e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.59e7 7.96e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.28e7 6.42e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.20e7 1.10e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.33e7 6.67e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 3.10e6 1.55e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.91e6 1.45e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 507-144 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:15 Page 1 of 21 316 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-1 4.63e7 11.91 Rel. Int. 100% Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-2 4.51e7 14.02 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.54e3 Abs. Int. 1.85e7 PCB-3 4.48e7 14.20 9.26e6 0% 11.0 12.0 13.0 PCB-1 1.40e7 11.91 Rel. Int. 100% 14.0 PCB-2 1.39e7 14.01 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.27e3 15.0 0.00e0 16.0 RT Abs. Int. 5.70e6 PCB-3 1.34e7 14.20 2.85e6 0% 11.0 12.0 13.0 14.0 ES-1 8.72e7 11.89 Rel. Int. 100% 15.0 Abs. Int. 3.53e7 ES-3 8.13e7 14.18 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.89e3 0.00e0 16.0 RT 1.77e7 0% 11.0 12.0 13.0 14.0 ES-1 2.64e7 11.89 Rel. Int. 100% 15.0 Abs. Int. 1.07e7 ES-3 2.42e7 14.18 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.33e4 0.00e0 16.0 RT 5.36e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.78e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.89e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7332, 0806 scc: 507-144 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 2 of 21 317 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 Rel. Int. 100% Abs. Int. 1.18e7 PCB-10 3.43e7 14.63 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 3.87e3 PCB-4 2.13e7 14.45 5.88e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 7.48e6 PCB-10 2.17e7 14.63 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.31e4 PCB-4 1.33e7 14.45 3.74e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.59e7 14.44 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 1.26e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.83e3 6.29e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.25e7 14.44 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.91e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 2.40e3 3.95e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.78e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.89e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3451, 0312 scc: 507-144 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 3 of 21 318 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.37e3 PCB-9 3.25e7 16.44 PCB-7 PCB-6 3.72e7 3.43e7 16.60 16.83 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-14 4.12e7 18.81 PCB-5 3.42e7 PCB-8 17.13 3.59e7 17.25 PCB-11 3.60e7 19.59 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 13/12 7.10e7 19.88 Abs. Int. 1.21e7 PCB-15 3.62e7 20.17 6.05e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.65e4 PCB-9 1.97e7 16.44 PCB-7 PCB-6 2.27e7 2.09e7 16.60 16.83 18.0 19.0 PCB-14 2.49e7 18.81 PCB-5 2.09e7 PCB-8 17.13 2.19e7 17.25 20.0 PCB-11 2.19e7 19.59 13/12 4.34e7 19.88 21.0 Abs. Int. 7.37e6 PCB-15 2.18e7 20.17 3.69e6 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 6.28e7 16.42 20.0 21.0 ES-15 6.67e7 20.15 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.78e4 (6.67e7 + 4.22e7) * 2000 pg = 1.06 (6.28e7 + 4.02e7) * 2000 pg CEM 31-Mar-2014 19:06 RRF(ES-15) = 17.0 18.0 19.0 JS-9 4.02e7 16.42 0.00e0 RT Abs. Int. 2.05e7 1.03e7 0% Rel. Int. 100% 0.00e0 RT 20.0 21.0 ES-15 4.22e7 20.15 0.00e0 RT Abs. Int. 1.31e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 6.76e3 6.57e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.59e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.96e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5427, 6371 scc: 507-144 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 4 of 21 319 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 30/18 4.21e7 19.30 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.41e3 PCB-19 1.52e7 17.54 PCB-17 1.80e7 19.70 PCB-27 2.46e7 19.90 PCB-24 2.34e7 20.03 PCB-16 1.35e7 20.13 Abs. Int. 1.20e7 PCB-32 2.63e7 20.61 6.02e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 4.04e7 19.30 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 1.48e3 PCB-19 1.46e7 17.54 PCB-17 1.73e7 19.70 21.0 PCB-24 2.25e7 20.03 PCB-27 2.34e7 19.90 Abs. Int. 1.16e7 PCB-16 1.28e7 20.13 PCB-32 2.52e7 20.61 5.79e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 1.22e7 ES-19 2.76e7 17.52 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.99e4 0.00e0 RT 6.11e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.14e7 ES-19 2.59e7 17.52 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.48e4 0.00e0 RT 5.69e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.59e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.96e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8775, 1198 scc: 507-144 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 5 of 21 320 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 28/20 4.99e7 22.95 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 4.58e3 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-23 PCB-34 2.53e7 2.49e7 21.91 21.76 26/29 5.12e7 22.19 PCB-31 2.68e7 22.67 Abs. Int. 1.21e7 PCB-39 2.71e7 25.21 PCB-36 2.62e7 24.89 PCB-22 2.39e7 23.51 PCB-38 2.45e7 25.74 PCB-35 2.36e7 26.13 PCB-37 2.42e7 26.49 0% 22.0 24.0 25.0 0.00e0 RT 26.0 28/20 4.95e7 22.95 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 3.67e3 23.0 PCB-23 PCB-34 2.50e7 2.46e7 21.91 21.75 26/29 5.09e7 22.19 PCB-31 2.67e7 22.67 Abs. Int. 1.19e7 PCB-39 2.70e7 25.21 PCB-36 2.60e7 24.89 PCB-22 2.38e7 23.51 PCB-38 2.45e7 25.74 PCB-35 2.34e7 26.13 PCB-37 2.41e7 26.49 23.0 24.0 25.0 26.0 CS/SS-28 4.66e7 22.92 Rel. Int. 100% 5.96e6 0.00e0 RT 0% 22.0 6.06e6 ES-37 4.21e7 26.47 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 6.26e4 Abs. Int. 1.30e7 6.52e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 4.30e7 22.92 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.85e7 26.47 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 3.45e4 Abs. Int. 1.20e7 5.98e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.42e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0724, 5868 scc: 507-144 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 6 of 21 321 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-54 1.52e7 20.46 Rel. Int. 100% Abs. Int. 4.23e6 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.10e3 2.11e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.88e7 20.46 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.21e3 2.63e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.23e7 20.44 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.88e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 7.13e3 3.44e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.88e7 20.44 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.57e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 4.92e3 4.29e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.59e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.96e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1029, 1338 scc: 507-144 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 7 of 21 322 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.41e3 50/53 2.70e7 22.44 PCB-51 1.31e7 23.10 PCB-45 1.22e7 23.03 PCB-73 1.76e7 PCB-52 24.69 1.34e7 24.56 PCB-46 1.10e7 23.31 69/49 3.27e7 24.98 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 44/47… 4.27e7 25.48 PCB-48 1.34e7 25.27 59/62… 5.59e7 25.76 71/40 2.72e7 26.35 PCB-42 1.23e7 25.92 PCB-41 1.12e7 26.26 Abs. Int. 1.03e7 PCB-64 1.96e7 26.55 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.34e3 50/53 3.45e7 22.44 24.0 PCB-51 1.67e7 23.10 PCB-45 1.58e7 23.03 25.0 PCB-73 2.23e7 PCB-52 24.69 1.70e7 24.56 PCB-46 1.40e7 23.31 69/49 4.13e7 24.98 PCB-48 1.69e7 25.27 59/62… 7.07e7 25.76 71/40 3.43e7 26.35 PCB-42 1.54e7 25.92 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.41e7 24.54 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 5.40e7 25.48 5.15e6 PCB-41 1.43e7 26.26 Abs. Int. 1.30e7 PCB-64 2.50e7 26.55 6.51e6 0.00e0 RT Abs. Int. 6.72e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.38e4 3.36e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.02e7 24.54 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.28e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.04e4 4.14e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.42e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7925, 2286 scc: 507-144 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 8 of 21 323 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 4.70e4 61/70... 7.32e7 28.77 PCB-68 1.99e7 27.52 PCB-72 1.90e7 27.26 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-67 1.95e7 28.25 PCB-55 1.74e7 29.20 PCB-60 PCB-80 1.75e7 2.08e7 29.83 30.15 PCB-79 1.98e7 31.47 PCB-78 1.69e7 31.96 PCB-81 1.76e7 32.34 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 Abs. Int. 9.19e6 PCB-77 1.79e7 32.82 4.59e6 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 3.48e4 30.0 61/70... 9.25e7 PCB-60 PCB-57 28.77 2.21e7 2.30e7 29.83 27.89 PCB-68 PCB-63 PCB-80 2.51e7 2.57e7 PCB-66 PCB-56 2.22e7 2.19e7 2.61e7 27.52 28.48 29.64 29.05 30.15 32.0 PCB-79 2.49e7 31.47 PCB-78 2.09e7 31.96PCB-81 2.21e7 32.34 34.0 36.0 38.0 Abs. Int. 1.15e7 PCB-77 2.24e7 32.82 5.74e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.05e7 32.32 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.60e4 0.00e0 RT 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.97e6 ES-77 3.06e7 32.80 3.99e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.75e7 32.32 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.15e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.04e7 ES-77 3.76e7 32.80 5.19e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.20e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.10e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8327, 5242 scc: 507-144 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:37 (CEM) Printed: 31-Mar-2014 19:15 Page 9 of 21 324 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-104 1.29e7 25.43 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 5.94e2 PCB-96 1.09e7 25.75 Abs. Int. 3.40e6 1.70e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.00e7 25.43 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 7.98e2 PCB-96 1.71e7 25.75 0.00e0 RT Abs. Int. 5.29e6 2.65e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.95e7 25.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.74e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.85e3 3.87e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.86e7 25.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.83e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.49e3 2.42e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.42e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4867, 4849 scc: 507-144 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 10 of 21 325 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 108/119... 6.34e7 31.50 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 2.06e3 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 100/93 1.89e7 28.22 PCB-88 9.15e6 28.71 PCB-103 1.03e7 27.44 PCB-121 1.34e7 29.72 113/90… 3.16e7 30.52 116/85 2.10e7 32.13 PCB-99 1.07e7 31.05 PCB-111 1.30e7 PCB-120 1.32e7 32.84 33.24 107/124 PCB-118 1.24e7 2.38e7 34.80 34.20 PCB-123 PCB-114 1.29e7 1.32e7 34.52 35.26 Abs. Int. 9.24e6 PCB-105 1.21e7 35.80 PCB-127 1.18e7 37.03 4.62e6 0% 28.0 30.0 32.0 36.0 38.0 108/119... 1.03e8 31.50 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.68e3 34.0 PCB-94 1.41e7 27.63 100/93 3.09e7 28.22 PCB-91 1.49e7 28.77 PCB-89 1.38e7 29.38 113/90… 5.15e7 30.52 PCB-112 PCB-92 2.03e7 1.48e7 31.16 30.04 116/85 PCB-115 3.42e7 1.98e7 32.13 32.33 PCB-117 PCB-110 PCB-111 PCB-120 2.12e7 1.93e7 1.93e7 2.16e7 32.84 32.04 32.25 33.24 107/124 PCB-118 2.02e7 3.87e7 34.80 34.20 PCB-123 PCB-114 2.11e7 2.14e7 34.52 35.26 Abs. Int. 1.51e7 PCB-105 1.97e7 35.80 PCB-127 1.93e7 37.03 7.55e6 0% 28.0 30.0 32.0 CS/SS-111 3.66e7 32.82 JS-101 3.02e7 30.53 Rel. Int. 100% 34.0 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.93e3 ES-123 3.46e7 34.49 36.0 ES-114 3.55e7 35.24 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 9.07e6 ES-105 3.58e7 35.78 4.54e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 2.33e7 32.82 JS-101 1.91e7 30.53 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.91e3 34.0 ES-118 ES-123 2.19e7 2.23e7 34.78 34.49 36.0 38.0 0.00e0 RT Abs. Int. 5.96e6 ES-105 2.28e7 35.78 2.98e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.20e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.10e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3793, 7473 scc: 507-144 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:33 (LKB) Printed: 31-Mar-2014 19:15 Page 11 of 21 326 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 Abs. Int. 2.81e6 PCB-126 1.15e7 38.41 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 2.54e3 (1.15e7 + 1.81e7) * 2000 pg = 1.20 (2.98e7 + 1.95e7) * 1000 pg CEM 31-Mar-2014 19:05 RRF (PCB-126) = 1.41e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 4.44e6 PCB-126 1.81e7 38.41 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 2.41e3 2.22e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.33e6 ES-126 2.98e7 38.39 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 5.26e3 3.66e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.55e6 ES-126 1.95e7 38.39 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 3.93e3 2.27e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.67e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4532, 5331 scc: 507-144 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 12 of 21 327 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-136 1.74e7 30.99 PCB-150 PCB-155 1.91e7 PCB-145 2.03e7 30.68 1.78e7 30.38 31.26 Rel. Int. 100% HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 8.17e2 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 147/149 139/140 2.65e7 2.68e7 33.82 34.34 PCB-148 1.35e7 32.53 153/168 3.32e7 36.40 151/135PCB-144 2.55e7 1.32e7 PCB-143 PCB-142 PCB-133 PCB-146 1.31e7 1.25e7 1.38e7 33.05 33.52 35.86 1.11e7 34.08 35.30 34.66 PCB-141 1.21e7 36.55 163/138… 4.05e7 37.46 Abs. Int. 7.31e6 PCB-164 1.66e7PCB-160 37.17 1.52e7 37.60 0% 28.0 30.0 32.0 PCB-152 1.46e7 30.54 PCB-136 PCB-155 1.38e7 PCB-145 1.60e7 30.99 1.39e7 30.38 31.26 Rel. Int. 100% HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 7.04e2 PCB-148 1.07e7 32.53 34.0 147/149 139/140 151/135 2.09e7 2.09e7 2.01e7 33.82 34.34 33.05 PCB-154 1.19e7 PCB-143 PCB-132 33.26 1.04e7 9.19e6 34.08 34.90 36.0 38.0 153/168 2.63e7 36.40 PCB-165 1.25e7 35.64 163/138… 3.21e7 37.46 PCB-141 PCB-137 9.56e6 1.10e7 37.09 36.55 30.0 32.0 34.0 PCB-158 1.42e7 37.78 2.90e6 36.0 38.0 ES-155 3.47e7 30.36 Rel. Int. 100% ES-153 2.44e7 36.36 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.50e3 0.00e0 RT Abs. Int. 5.80e6 0% 28.0 3.65e6 0.00e0 RT Abs. Int. 8.69e6 JS-138 2.16e7 37.42 4.34e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.63e7 30.36 Rel. Int. 100% ES-153 1.86e7 36.36 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 2.04e3 0.00e0 RT Abs. Int. 6.71e6 JS-138 1.67e7 37.42 3.36e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.20e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.10e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2006, 5608 scc: 507-144 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 13 of 21 328 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 2.56e7 38.52 PCB-159 1.56e7 39.33 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 3.26e3 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-162 1.54e7 39.57 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 156/157 2.92e7 40.96 Abs. Int. 5.80e6 PCB-169 1.42e7 43.67 PCB-167 1.66e7 39.98 2.90e6 0% 39.0 Rel. Int. 100% HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 3.34e3 128/166 2.11e7 38.52 PCB-162 PCB-159 1.28e7 39.57 1.28e7 39.33 40.0 41.0 42.0 43.0 44.0 45.0 156/157 2.42e7 40.96 Abs. Int. 4.81e6 PCB-169 1.16e7 43.67 PCB-167 1.36e7 39.98 2.41e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.96e7 39.96 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 8.97e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 5.57e7 40.94 0.00e0 RT Abs. Int. 9.91e6 ES-169 2.53e7 43.65 4.95e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.35e7 40.94 Rel. Int. 100% Abs. Int. 7.84e6 ES-167 2.32e7 39.96 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 4.84e3 0.00e0 RT ES-169 2.02e7 43.65 3.92e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.67e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6661, 1876 scc: 507-144 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 14 of 21 329 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% PCB-188 1.28e7 35.26 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 5.81e2 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-179 PCB-184 1.16e7 1.20e7 36.00 35.54 PCB-186 1.19e7 36.69 Abs. Int. 3.11e6 PCB-178 8.35e6 37.82 1.56e6 0% 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 36.0 PCB-188 1.20e7 35.25 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 7.98e2 PCB-179 1.13e7 35.54 PCB-176 1.20e7 36.29 37.0 PCB-186 1.13e7 36.69 38.0 Abs. Int. 2.96e6 PCB-178 7.86e6 37.82 1.48e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.22e7 35.23 Rel. Int. 100% CS/SS-178 1.32e7 37.80 2.69e6 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.07e7 35.23 Rel. Int. 100% CS/SS-178 1.26e7 37.80 2.58e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 5.15e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.22e3 31.0 0.00e0 RT Abs. Int. 5.37e6 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.38e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.20e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.10e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4757, 7783 scc: 507-144 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:33 (LKB) Printed: 31-Mar-2014 19:15 Page 15 of 21 330 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 4.53e3 PCB-175 1.08e7 38.36 PCB-182 PCB-183 1.18e7 1.22e7 38.77 39.11 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 171/173 1.88e7 PCB-181 40.21 PCB-177 1.07e7 9.48e6 40.03 39.68 180/193 2.44e7 42.09 PCB-172 9.78e6 41.56 PCB-191 1.32e7 42.42 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-170 9.18e6 43.19 Abs. Int. 4.40e6 PCB-190 1.27e7 43.64 2.20e6 0% 39.0 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 3.33e3 PCB-182 1.12e7 38.77 PCB-183 PCB-187 1.14e7 1.09e7 39.11 38.59 40.0 41.0 42.0 180/193 2.30e7 42.09 171/173 1.76e7 40.21 PCB-177 PCB-181 1.01e7 8.95e6 40.03 39.68 PCB-172 9.26e6 41.56 43.0 PCB-191 1.27e7 42.42 PCB-170 8.70e6 43.19 44.0 45.0 Abs. Int. 4.08e6 PCB-190 1.21e7 43.64 2.04e6 0% 39.0 40.0 41.0 42.0 ES-180 1.97e7 42.10 Rel. Int. 100% 43.0 0.00e0 RT 44.0 45.0 ES-170 1.67e7 43.17 0.00e0 RT Abs. Int. 4.76e6 HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 3.06e3 2.38e6 0% 39.0 40.0 41.0 42.0 ES-180 1.87e7 42.10 Rel. Int. 100% 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.54e6 ES-170 1.54e7 43.17 HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 3.23e3 2.27e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.67e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6619, 4898 scc: 507-144 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:33 (LKB) Printed: 31-Mar-2014 19:15 Page 16 of 21 331 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-189 1.33e7 45.80 Abs. Int. 3.26e6 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 2.13e3 1.63e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.26e7 45.80 Abs. Int. 3.07e6 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 1.54e3 1.54e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 2.39e7 45.78 0.00e0 RT Abs. Int. 5.85e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.02e3 2.93e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 2.30e7 45.78 0.00e0 RT Abs. Int. 5.51e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.58e3 2.76e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.10e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.55e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2306, 7677 scc: 507-144 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:33 (LKB) Printed: 31-Mar-2014 19:15 Page 17 of 21 332 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-202 9.73e6 39.79 Rel. Int. 100% PCB-201 1.06e7 40.57 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 5.36e2 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-197 1.04e7 PCB-204 41.34 PCB-200 1.05e7 9.94e6 41.43 41.15 198/199 1.38e7 43.75 Abs. Int. 2.56e6 PCB-196 7.30e6 44.33 PCB-203 7.52e6 44.50 1.28e6 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.06e7 39.79 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.04e2 41.0 PCB-201 1.19e7 40.57 42.0 43.0 PCB-197 1.15e7 PCB-204 41.34 PCB-200 1.10e7 1.14e7 41.15 41.43 44.0 45.0 198/199 1.53e7 43.75 0.00e0 RT Abs. Int. 2.91e6 PCB-196 8.07e6 44.33 PCB-203 8.19e6 44.50 1.46e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.94e7 39.77 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.76e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.61e3 2.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.09e7 39.77 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.08e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.12e3 2.54e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.67e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0803, 5321 scc: 507-144 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 18 of 21 333 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 1.63e3 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-194 6.81e6 47.56 PCB-195 6.29e6 45.62 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-205 8.46e6 47.96 Abs. Int. 1.99e6 9.93e5 0% 46.0 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 1.62e3 47.0 48.0 PCB-194 7.39e6 47.56 PCB-195 6.83e6 45.62 49.0 50.0 PCB-205 9.12e6 47.96 0.00e0 RT Abs. Int. 2.13e6 1.06e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.35e7 47.54 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.59e3 49.0 50.0 ES-205 1.65e7 47.94 0.00e0 RT Abs. Int. 4.02e6 2.01e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.48e7 47.54 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 3.14e3 49.0 50.0 ES-205 1.84e7 47.94 0.00e0 RT Abs. Int. 4.37e6 2.19e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.10e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.55e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3508, 6948 scc: 507-144 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 19 of 21 334 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.77e3 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-207 9.45e6 46.20 PCB-208 9.18e6 45.42 Abs. Int. 2.26e6 PCB-206 5.76e6 49.43 1.13e6 0% 46.0 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.04e3 47.0 48.0 49.0 50.0 PCB-207 1.21e7 46.20 PCB-208 1.17e7 45.41 Abs. Int. 2.91e6 PCB-206 7.38e6 49.42 1.46e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 1.67e7 45.39 50.0 0.00e0 RT Abs. Int. 3.92e6 ES-206 1.07e7 49.41 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.67e3 1.96e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 2.12e7 45.39 50.0 Abs. Int. 4.90e6 ES-206 1.38e7 49.40 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.77e3 0.00e0 RT 2.45e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.10e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.55e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7320, 8949 scc: 507-144 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 20 of 21 335 of 711 SGS-AP ID: CS3_140326_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 26-Mar-2014 18:21:41 User: LKB Datafile: 140326X05 PCB-209 8.82e6 50.86 Rel. Int. 100% Abs. Int. 1.88e6 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 7.17e2 9.40e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 7.54e6 50.86 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.58e6 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 5.79e2 7.90e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.68e7 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.58e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 7.21e2 1.79e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.42e7 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.98e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 8.42e2 1.49e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.91e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.45e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140326_PCB_XC.utp_res, saved 31-Mar-2014 19:06 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1177, 5778 scc: 507-144 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:32 (LKB) Printed: 31-Mar-2014 19:15 Page 21 of 21 336 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services CS3_140328_PCB_XA 28-MAR-2014 10:43 140328X01 Processed: 31-Mar-2014 19:01 ICAL: MM7_PCB_10292013_20DEC2013 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.78 32.30 35.76 35.22 34.75 34.47 38.36 40.91 39.93 43.62 45.75 50.80 1.35E+07 1.38E+07 1.09E+07 1.21E+07 1.17E+07 1.19E+07 9.40E+06 1.77E+07 1.03E+07 8.27E+06 8.56E+06 5.35E+06 0.81 Y 0.80 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.66 Y 1.25 Y 1.24 Y 1.23 Y 1.07 Y 1.16 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.16 1.16 1.13 1.23 1.19 1.20 1.16 1.07 1.16 1.09 1.08 1.06 0.6% 3.3% 1.8% 2.0% -0.4% -0.6% 5.2% -2.2% -0.5% -2.7% 0.6% -4.5% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 11.88 14.17 14.42 20.12 17.50 26.44 20.40 32.76 32.28 25.37 35.74 35.20 34.73 34.45 38.35 36.31 30.31 40.89 39.91 43.60 43.12 42.05 35.19 45.73 39.72 47.89 49.35 45.34 50.78 4.26E+07 3.83E+07 2.15E+07 4.02E+07 1.98E+07 2.85E+07 1.88E+07 2.34E+07 2.39E+07 1.73E+07 1.92E+07 1.97E+07 1.98E+07 1.98E+07 1.61E+07 1.49E+07 2.23E+07 3.30E+07 1.78E+07 1.51E+07 1.07E+07 1.28E+07 1.52E+07 1.59E+07 1.36E+07 1.13E+07 7.83E+06 1.28E+07 1.00E+07 3.27 Y 3.31 Y 1.58 Y 1.60 Y 1.06 Y 1.09 Y 0.78 Y 0.79 Y 0.81 Y 1.64 Y 1.59 Y 1.64 Y 1.64 Y 1.54 Y 1.51 Y 1.28 Y 1.26 Y 1.28 Y 1.28 Y 1.25 Y 1.07 Y 1.07 Y 1.09 Y 1.00 Y 0.89 Y 0.88 Y 0.83 Y 0.82 Y 1.16 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.12 1.01 0.56 1.06 0.52 1.42 0.94 1.17 1.19 0.97 1.08 1.10 1.11 1.11 0.90 1.12 1.67 1.24 1.33 1.13 1.13 1.36 1.14 1.68 1.02 1.20 0.83 1.36 1.07 -6.4% -7.4% 7.8% 1.5% 2.5% -14.4% 8.9% -15.7% -12.8% 20.6% -10.5% -9.4% -4.3% -6.6% -12.1% 0.3% 5.1% -22.8% -20.1% -27.4% 19.8% 19.3% 21.3% 6.4% 5.0% -3.9% 0.2% 16.0% -3.9% Page 1 of 6 337 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services Processed: 31-Mar-2014 19:01 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XA 28-MAR-2014 10:43 140328X01 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 22.89 32.77 37.75 3.33E+07 2.15E+07 8.91E+06 1.10 Y 1.60 Y 1.08 Y 1.11 1.03 0.62 1.17 1.09 0.58 5.1% 5.6% -5.5% CS PCB-28 CS PCB-111 CS PCB-178 22.89 32.77 37.75 3.33E+07 2.15E+07 8.91E+06 1.10 Y 1.60 Y 1.08 Y 1.85 1.22 0.58 1.66 1.20 0.67 -10.0% -1.4% 14.6% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.39 24.50 30.48 37.37 47.49 3.81E+07 2.00E+07 1.79E+07 1.34E+07 9.42E+06 1.58 Y 0.83 Y 1.67 Y 1.27 Y 0.91 Y - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 11.89 14.18 14.43 20.14 17.51 26.46 20.42 25.39 30.34 35.21 39.74 47.91 45.36 49.37 2.32E+07 2.25E+07 1.26E+07 2.18E+07 1.12E+07 1.75E+07 1.24E+07 1.20E+07 1.30E+07 8.64E+06 6.70E+06 5.83E+06 7.08E+06 4.32E+06 3.26 Y 3.25 Y 1.58 Y 1.65 Y 1.08 Y 1.00 Y 0.81 Y 0.64 Y 1.25 Y 1.07 Y 0.89 Y 0.91 Y 0.77 Y 0.75 Y 1.09 1.17 1.17 1.08 1.13 1.23 1.32 1.38 1.17 1.13 0.99 1.04 1.10 1.10 14.3% 16.3% -4.8% 6.3% -1.5% 13.7% -2.6% -3.6% -7.3% -10.6% -6.4% -2.2% -1.7% -1.0% 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 - Page 2 of 6 - 338 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB Processed: 31-Mar-2014 19:01 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XA 28-MAR-2014 10:43 140328X01 RT Response RA 11.89 14.00 14.18 14.43 14.61 16.41 16.58 16.80 17.11 17.22 18.78 19.56 19.85 20.14 17.51 19.27 19.67 19.87 20.00 20.09 20.57 21.72 21.87 22.16 22.36 22.63 22.92 23.10 23.47 24.85 25.17 25.71 26.10 26.46 20.42 22.41 22.99 23.06 23.27 24.53 24.65 2.32E+07 2.27E+07 2.25E+07 1.26E+07 2.05E+07 1.93E+07 2.27E+07 2.13E+07 2.17E+07 2.22E+07 2.53E+07 2.14E+07 4.26E+07 2.18E+07 1.12E+07 3.08E+07 1.31E+07 1.79E+07 1.70E+07 1.03E+07 1.91E+07 1.90E+07 1.92E+07 3.94E+07 1.96E+07 2.02E+07 3.71E+07 3.83E+07 1.79E+07 1.91E+07 1.99E+07 1.79E+07 1.68E+07 1.75E+07 1.24E+07 2.31E+07 9.77E+06 1.16E+07 9.28E+06 1.10E+07 1.46E+07 3.26 Y 3.28 Y 3.25 Y 1.58 Y 1.61 Y 1.67 Y 1.64 Y 1.69 Y 1.68 Y 1.66 Y 1.63 Y 1.64 Y 1.67 Y 1.65 Y 1.08 Y 1.06 Y 1.04 Y 1.06 Y 1.05 Y 1.05 Y 1.07 Y 1.02 Y 1.00 Y 1.01 Y 1.00 Y 1.00 Y 1.02 Y 1.01 Y 1.01 Y 1.01 Y 1.00 Y 1.02 Y 1.00 Y 1.00 Y 0.81 Y 0.79 Y 0.77 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y Page 3 of 6 RRF 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 1.18 1.91 0.96 1.13 1.06 1.08 1.10 1.26 1.06 1.06 1.56 1.33 1.81 1.72 1.04 1.93 1.33 1.35 1.38 1.37 1.42 1.30 1.35 1.26 1.34 1.40 1.26 1.18 0.97 0.82 0.98 0.78 0.92 1.23 14.5% -3.7% 1.5% 7.7% 6.1% 7.6% 6.7% 6.6% 5.2% 7.0% 1.5% 1.6% -0.2% 0.1% 3.3% 0.5% 17.3% 17.0% 18.0% 18.8% 15.7% 15.1% 14.7% 16.5% 14.7% 15.7% 13.6% 13.2% 10.6% 6.8% 13.6% 11.3% 9.4% 10.3% 339 of 711 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeC PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB Processed: 31-Mar-2014 19:01 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XA 28-MAR-2014 10:43 140328X01 RT Response RA 24.75 24.95 25.23 25.44 25.72 25.89 26.22 26.31 26.51 27.23 27.48 27.85 28.06 28.21 28.44 28.73 29.01 29.16 29.60 29.79 30.11 31.43 31.92 25.39 25.71 27.40 27.59 27.97 28.18 28.30 28.36 28.66 28.73 28.92 29.34 29.68 30.00 30.48 30.92 9.44E+06 2.70E+07 1.12E+07 3.55E+07 4.59E+07 1.01E+07 9.13E+06 2.28E+07 1.62E+07 1.62E+07 1.70E+07 1.53E+07 1.58E+07 1.62E+07 1.70E+07 6.16E+07 1.47E+07 1.45E+07 1.43E+07 1.44E+07 1.71E+07 1.63E+07 1.36E+07 1.20E+07 1.02E+07 1.02E+07 8.57E+06 9.05E+06 1.83E+07 1.07E+07 7.77E+06 8.39E+06 9.79E+06 7.69E+06 8.02E+06 1.29E+07 8.77E+06 3.07E+07 7.51E+06 0.78 Y 0.79 Y 0.77 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.80 Y 0.79 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.64 Y 0.64 Y 0.61 Y 0.61 Y 0.63 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.63 Y 0.61 Y 0.61 Y 0.62 Y 0.61 Y Page 4 of 6 RRF 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.79 1.13 0.94 0.99 1.28 0.85 0.77 0.96 1.35 1.36 1.42 1.28 1.33 1.36 1.43 1.29 1.23 1.22 1.20 1.20 1.43 1.36 1.14 1.18 1.03 0.87 0.91 0.93 1.09 0.78 0.85 0.99 0.78 0.81 1.31 0.89 1.03 0.76 11.4% 10.8% 12.0% 9.6% 10.0% 11.3% 10.1% 11.3% 10.9% 12.2% 11.3% 9.9% 12.5% 7.7% 10.1% 7.7% 11.5% 8.7% 7.7% 6.1% 8.9% 4.4% 7.2% -3.8% 10.2% 8.2% 5.5% 7.1% 12.2% 3.5% 6.2% 4.8% 8.6% 6.2% 9.0% 8.0% 4.8% 6.1% 340 of 711 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Processed: 31-Mar-2014 19:01 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XA 28-MAR-2014 10:43 140328X01 Name PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB RT Response RA 31.01 31.12 31.46 31.99 32.09 32.20 32.29 32.48 32.80 33.19 34.16 34.37 34.59 35.05 36.99 30.34 30.50 30.64 30.95 31.22 32.48 33.01 33.21 33.48 33.78 33.95 34.03 34.30 34.47 34.62 34.85 35.26 35.59 35.81 35.93 36.36 36.50 36.85 37.04 37.13 37.42 9.46E+06 1.23E+07 6.10E+07 1.08E+07 1.84E+07 1.13E+07 1.21E+07 7.25E+06 1.24E+07 1.25E+07 2.21E+07 1.25E+07 1.10E+07 1.02E+07 1.10E+07 1.30E+07 1.20E+07 1.20E+07 1.10E+07 1.15E+07 8.48E+06 1.64E+07 9.69E+06 8.32E+06 1.64E+07 5.94E+06 8.47E+06 1.70E+07 7.09E+06 7.00E+06 7.27E+06 7.78E+06 9.84E+06 8.55E+06 1.07E+07 2.06E+07 7.49E+06 6.72E+06 8.38E+06 1.00E+07 2.45E+07 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.61 Y 0.63 Y 0.61 Y 0.62 Y 0.61 Y 0.61 Y 0.63 Y 0.61 Y 0.63 Y 1.25 Y 1.29 Y 1.25 Y 1.26 Y 1.30 Y 1.24 Y 1.26 Y 1.26 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.29 Y 1.26 Y 1.28 Y 1.27 Y 1.25 Y 1.27 Y 1.26 Y 1.25 Y 1.26 Y 1.27 Y 1.27 Y Page 5 of 6 RRF 0.92 1.17 0.98 1.14 0.94 1.12 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 0.96 1.25 1.03 1.09 0.93 1.14 1.22 0.73 1.25 1.27 1.12 1.26 1.11 1.03 1.14 1.08 1.08 0.99 1.03 1.14 1.10 1.30 1.11 1.10 0.79 1.13 1.14 0.95 0.94 0.97 1.04 1.32 1.14 1.43 1.38 1.00 0.90 1.12 1.34 1.10 3.7% 6.8% 4.8% -3.9% -1.0% 2.0% 5.5% 5.1% 2.4% 4.5% 1.9% 0.9% 0.1% 3.8% 4.1% -8.3% -8.5% -7.3% -7.9% -4.0% -3.7% -3.4% -5.8% -6.5% -14.0% 0.5% -5.8% -7.5% -5.3% -5.6% -7.9% -6.5% -4.7% -6.0% -5.5% -8.0% -7.5% -3.6% -10.4% -7.9% 341 of 711 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB Processed: 31-Mar-2014 19:01 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XA 28-MAR-2014 10:43 140328X01 RT Response RA 37.56 37.74 38.47 39.28 39.52 35.21 35.49 35.95 36.25 36.64 37.77 38.31 38.54 38.72 39.07 39.15 39.26 39.64 39.98 40.17 41.51 41.76 42.04 42.37 43.14 43.59 39.74 40.53 41.10 41.29 41.38 43.70 44.28 44.45 45.57 47.51 47.91 45.36 46.15 49.37 9.51E+06 1.10E+07 1.57E+07 9.60E+06 9.51E+06 8.64E+06 8.15E+06 7.83E+06 8.63E+06 7.94E+06 5.65E+06 7.09E+06 7.68E+06 7.78E+06 8.16E+06 6.75E+06 6.40E+06 6.29E+06 7.09E+06 1.23E+07 6.38E+06 8.36E+06 1.61E+07 8.69E+06 5.84E+06 8.09E+06 6.70E+06 7.49E+06 7.04E+06 7.68E+06 7.09E+06 9.48E+06 5.04E+06 5.29E+06 4.61E+06 4.73E+06 5.83E+06 7.08E+06 7.37E+06 4.32E+06 1.25 Y 1.24 Y 1.23 Y 1.22 Y 1.20 Y 1.07 Y 1.06 Y 1.07 Y 1.05 Y 1.06 Y 1.06 Y 1.04 Y 1.05 Y 1.06 Y 1.05 Y 1.07 Y 1.07 Y 1.05 Y 1.02 Y 1.04 Y 1.05 Y 1.06 Y 1.04 Y 1.07 Y 1.09 Y 1.04 Y 0.89 Y 0.92 Y 0.88 Y 0.89 Y 0.90 Y 0.93 Y 0.92 Y 0.93 Y 0.92 Y 0.90 Y 0.91 Y 0.77 Y 0.78 Y 0.75 Y Page 6 of 6 RRF 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 1.27 1.48 0.88 1.08 1.07 1.07 1.03 1.13 1.04 0.74 1.11 1.20 1.22 1.28 1.06 1.00 0.98 1.11 0.96 1.00 1.31 1.26 1.36 1.09 1.52 1.10 1.04 1.13 1.04 0.70 0.74 0.78 0.82 0.84 1.15 - -16.0% -11.0% -1.8% -3.4% -0.5% -7.9% -8.8% -8.1% -7.4% -12.0% 3.4% 5.6% 3.7% 6.0% -0.5% 1.2% 3.5% 1.9% 1.7% 0.9% 1.7% -0.2% -2.5% -3.7% -8.8% -9.8% -7.2% -5.2% -5.8% -13.9% -11.1% -11.1% 6.8% -0.4% -3.4% - 342 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 6.51e7 3.25e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.32e7 6.59e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.13e7 5.65e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.12e7 1.06e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.17e7 5.84e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.89e6 9.43e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.74e6 8.69e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 523-232 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:21 Page 1 of 21 343 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-1 1.77e7 11.89 Rel. Int. 100% Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-2 1.74e7 14.00 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.00e3 Abs. Int. 6.29e6 PCB-3 1.72e7 14.18 3.14e6 0% 11.0 12.0 13.0 PCB-1 5.44e6 11.89 Rel. Int. 100% 14.0 PCB-2 5.29e6 14.00 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 2.51e3 15.0 0.00e0 16.0 RT Abs. Int. 1.93e6 PCB-3 5.29e6 14.18 9.63e5 0% 11.0 12.0 13.0 ES-1 3.26e7 11.88 Rel. Int. 100% 14.0 15.0 Abs. Int. 1.16e7 ES-3 2.94e7 14.17 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 4.03e3 0.00e0 16.0 RT 5.78e6 0% 11.0 12.0 13.0 ES-1 9.96e6 11.88 Rel. Int. 100% 14.0 15.0 Abs. Int. 3.58e6 ES-3 8.88e6 14.17 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.33e4 0.00e0 16.0 RT 1.79e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.51e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 3.25e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8412, 4226 scc: 523-232 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:29 Printed: 31-Mar-2014 19:21 Page 2 of 21 344 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 Rel. Int. 100% Abs. Int. 4.26e6 PCB-10 1.26e7 14.61 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 4.60e3 PCB-4 7.71e6 14.43 2.13e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 2.65e6 PCB-10 7.85e6 14.61 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.15e4 PCB-4 4.89e6 14.43 1.33e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.32e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 4.39e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 4.80e3 2.20e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 8.33e6 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.83e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 2.74e3 1.42e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.51e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 3.25e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2883, 1871 scc: 523-232 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:29 Printed: 31-Mar-2014 19:21 Page 3 of 21 345 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 5.64e3 PCB-9 1.21e7 16.41 PCB-7 1.41e7 PCB-6 16.58 1.34e7 16.80 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-14 1.57e7 18.78 PCB-5 1.36e7 PCB-8 17.11 1.38e7 17.22 PCB-11 1.33e7 19.56 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 13/12 2.67e7 19.85 Abs. Int. 4.61e6 PCB-15 1.36e7 20.14 2.31e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.23e4 PCB-9 7.23e6 16.41 PCB-7 8.58e6 PCB-6 16.58 7.92e6 16.80 18.0 19.0 20.0 PCB-14 9.62e6 18.78 PCB-5 8.10e6 PCB-8 17.10 8.33e6 17.22 PCB-11 8.12e6 19.56 13/12 1.59e7 19.85 21.0 Abs. Int. 2.83e6 PCB-15 8.22e6 20.14 1.41e6 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 2.34e7 16.39 20.0 21.0 ES-15 2.48e7 20.12 0.00e0 RT Abs. Int. 7.82e6 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.27e4 3.91e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 1.48e7 16.39 20.0 21.0 ES-15 1.55e7 20.12 0.00e0 RT Abs. Int. 4.99e6 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 4.61e3 2.49e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.32e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.59e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3806, 1394 scc: 523-232 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:30 (CEM) Printed: 31-Mar-2014 19:21 Page 4 of 21 346 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 30/18 1.59e7 19.27 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.26e3 PCB-19 5.80e6 17.51 PCB-17 6.70e6 19.67 PCB-24 8.71e6 20.00 PCB-27 9.21e6 19.87 Abs. Int. 4.47e6 PCB-16 5.27e6 20.09 PCB-32 9.85e6 20.57 2.24e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 1.49e7 19.27 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 1.99e3 PCB-19 5.38e6 17.51 PCB-17 6.41e6 19.67 PCB-24 8.33e6 20.00 PCB-27 8.72e6 19.86 21.0 Abs. Int. 4.17e6 PCB-16 5.00e6 20.09 PCB-32 9.22e6 20.57 2.08e6 0% 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.26e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 3.57e4 ES-19 1.02e7 17.50 4.63e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 4.27e6 ES-19 9.62e6 17.50 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.81e4 0.00e0 RT 2.14e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.32e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.59e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9317, 9381 scc: 523-232 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:29 Printed: 31-Mar-2014 19:21 Page 5 of 21 347 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 28/20 1.87e7 22.92 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 6.50e3 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-23 PCB-34 9.63e6 9.58e6 21.87 21.72 26/29 1.98e7 22.16 PCB-31 1.01e7 22.63 Abs. Int. 4.40e6 PCB-36 9.58e6 24.85 PCB-22 9.00e6 23.47 PCB-39 9.99e6 25.17 PCB-38 9.01e6 25.71 PCB-35 8.38e6 26.10 PCB-37 8.73e6 26.46 0% 22.0 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 3.96e3 PCB-23 PCB-34 9.62e6 9.37e6 21.87 21.72 26/29 1.96e7 22.16 23.0 24.0 25.0 0.00e0 RT 26.0 28/20 1.84e7 22.92 PCB-31 1.01e7 22.63 Abs. Int. 4.32e6 PCB-36 9.52e6 24.85 PCB-22 8.90e6 23.47 PCB-39 9.95e6 25.17 PCB-38 8.86e6 25.71 PCB-35 8.38e6 26.10 PCB-37 8.73e6 26.46 23.0 24.0 25.0 26.0 CS/SS-28 1.74e7 22.89 Rel. Int. 100% ES-37 1.48e7 26.44 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.11e4 2.16e6 0.00e0 RT 0% 22.0 2.20e6 Abs. Int. 4.84e6 2.42e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 1.58e7 22.88 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 1.36e7 26.44 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.71e4 Abs. Int. 4.37e6 2.18e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.65e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5510, 3957 scc: 523-232 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:36 (CEM) Printed: 31-Mar-2014 19:21 Page 6 of 21 348 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-54 5.53e6 20.42 Rel. Int. 100% Abs. Int. 1.61e6 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 5.94e2 8.04e5 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 6.83e6 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.05e6 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 8.35e2 1.02e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 8.24e6 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.40e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 3.84e3 1.20e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.05e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.08e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 2.71e3 1.54e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.32e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.59e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5260, 7040 scc: 523-232 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:36 (CEM) Printed: 31-Mar-2014 19:21 Page 7 of 21 349 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 9.95e2 50/53 1.02e7 22.41 PCB-51 5.16e6 23.06 PCB-45 4.25e6 22.99 PCB-73 6.47e6 PCB-52 24.65 4.82e6 24.53 PCB-46 4.10e6 23.27 69/49 1.19e7 24.95 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 44/47… 1.56e7 25.44 PCB-48 4.87e6 25.23 59/62… 2.02e7 25.72 71/40 1.01e7 26.31 PCB-42 4.48e6 25.89 PCB-41 4.04e6 26.22 Abs. Int. 3.71e6 PCB-64 7.13e6 26.51 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 9.04e2 50/53 1.29e7 22.41 24.0 PCB-51 6.49e6 23.06 PCB-45 5.53e6 22.99 25.0 PCB-73 PCB-52 8.17e6 6.19e6 24.65 24.52 PCB-46 5.18e6 23.27 69/49 1.51e7 24.95 PCB-48 6.34e6 25.23 59/62… 2.57e7 25.72 71/40 1.27e7 26.31 PCB-42 5.65e6 25.88 0% 22.0 23.0 24.0 25.0 26.0 JS-52 9.05e6 24.50 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 1.99e7 25.44 1.85e6 PCB-41 5.09e6 26.22 Abs. Int. 4.81e6 PCB-64 9.02e6 26.51 2.40e6 0.00e0 RT Abs. Int. 2.50e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 8.78e3 1.25e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 1.10e7 24.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.15e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 5.69e3 1.57e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.65e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7910, 2010 scc: 523-232 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:29 Printed: 31-Mar-2014 19:21 Page 8 of 21 350 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 2.68e3 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 61/70... 2.70e7 PCB-58 28.73 6.95e6 28.06 PCB-68 PCB-67 PCB-55 7.47e6 7.10e6 6.38e6 27.48 28.21 29.16 PCB-60 PCB-80 6.36e6 7.50e6 30.11 29.79 PCB-79 7.23e6 31.43 PCB-78 5.98e6 31.92 PCB-81 6.13e6 32.30 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 Abs. Int. 3.42e6 PCB-77 6.05e6 32.78 (6.05e6 + 7.47e6) * 2000 pg = 1.16 (1.03e7 + 1.31e7) * 1000 pg CEM 31-Mar-2014 19:07 1.71e6 RRF (PCB-77) = 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 3.02e3 PCB-68 9.48e6 27.48 61/70... 3.45e7 PCB-67 28.73 9.07e6 28.21 PCB-63 9.59e6 PCB-66 28.44 8.25e6 29.01 30.0 32.0 PCB-60 8.01e6 29.79 PCB-56 7.99e6 29.60 PCB-80 9.57e6 30.11 PCB-79 9.04e6 31.43 PCB-78 7.60e6 31.92 PCB-81 7.65e6 32.30 34.0 36.0 38.0 Abs. Int. 4.23e6 PCB-77 7.47e6 32.78 2.12e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.06e7 32.28 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 8.88e3 0.00e0 RT 34.0 36.0 38.0 0.00e0 RT Abs. Int. 2.90e6 ES-77 1.03e7 32.76 1.45e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.32e7 32.28 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 6.12e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 3.85e6 ES-77 1.31e7 32.76 1.92e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.12e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.06e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4361, 4381 scc: 523-232 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 19:07 (CEM) Printed: 31-Mar-2014 19:21 Page 9 of 21 351 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-104 4.67e6 25.39 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 4.34e2 PCB-96 3.99e6 25.71 Abs. Int. 1.26e6 6.29e5 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 7.28e6 25.39 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 6.61e2 PCB-96 6.24e6 25.71 0.00e0 RT Abs. Int. 1.93e6 9.67e5 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.07e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.88e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.20e3 1.44e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 6.57e6 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.69e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 9.61e2 8.47e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.65e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5163, 6821 scc: 523-232 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:30 (CEM) Printed: 31-Mar-2014 19:21 Page 10 of 21 352 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 108/119... 2.33e7 31.46 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 8.29e2 PCB-103 3.86e6 27.40 100/93 6.97e6 28.18 PCB-88 3.19e6 28.66 PCB-121 4.93e6 29.68 113/90… 1.17e7 30.48 116/85 7.07e6 32.09 PCB-99 3.64e6 31.01 PCB-111 PCB-120 4.69e6 4.81e6 32.80 33.19 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-118 107/124 4.50e6 8.42e6 34.75 34.16 PCB-123 PCB-114 4.57e6 4.59e6 34.47 35.22 Abs. Int. 3.47e6 PCB-105 4.17e6 35.76 PCB-127 4.23e6 36.99 1.73e6 0% 28.0 30.0 32.0 36.0 38.0 108/119... 3.76e7 31.46 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.16e3 34.0 PCB-94 5.34e6 27.59 100/93 1.13e7 28.18 PCB-91 6.03e6 28.73 PCB-89 4.92e6 29.34 113/90… 1.90e7 30.48 PCB-112 PCB-92 7.61e6 5.45e6 31.12 30.00 116/85 PCB-115 1.14e7 7.52e6 PCB-111 32.09 32.29 7.69e6 32.79 PCB-117 PCB-110 PCB-120 6.65e6 6.95e6 7.72e6 PCB-82 31.99 32.20 33.19 4.46e6 32.48 107/124 PCB-118 7.24e6 1.37e7 34.75 34.16 PCB-123 PCB-114 7.36e6 7.52e6 34.47 35.22 Abs. Int. 5.51e6 PCB-105 6.72e6 35.76 PCB-127 6.72e6 36.99 2.75e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.33e7 32.77 JS-101 1.12e7 30.48 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 1.71e3 ES-123 1.20e7 34.45 36.0 ES-118 ES-114 1.23e7 1.22e7 34.73 35.20 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 3.32e6 ES-105 1.18e7 35.74 1.66e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 8.27e6 32.77 JS-101 6.70e6 30.48 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.35e3 34.0 ES-118 ES-114 ES-123 7.51e6 7.48e6 7.79e6 34.73 35.20 34.45 36.0 38.0 0.00e0 RT Abs. Int. 2.10e6 ES-105 7.41e6 35.74 1.05e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.12e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.06e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9489, 8406 scc: 523-232 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 19:00 (CEM) Printed: 31-Mar-2014 19:21 Page 11 of 21 353 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 Abs. Int. 8.51e5 PCB-126 3.72e6 38.36 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 1.74e3 4.25e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.32e6 PCB-126 5.68e6 38.37 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 1.77e3 6.59e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.36e6 ES-126 9.71e6 38.35 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 4.42e3 1.18e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.55e6 ES-126 6.44e6 38.35 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 3.24e3 7.77e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.84e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6979, 7827 scc: 523-232 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:37 (CEM) Printed: 31-Mar-2014 19:21 Page 12 of 21 354 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-150 PCB-155 6.67e6 7.24e6 30.64 30.34 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.60e2 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 147/149 139/140 9.19e6 9.48e6 33.78 34.30 PCB-145 6.48e6 31.22 PCB-148 4.70e6 32.48 151/135 9.13e6 PCB-144 PCB-143 PCB-142 PCB-133 PCB-146 33.01 4.64e6 4.74e6 4.34e6 4.78e6 3.91e6 35.81 33.48 34.03 35.26 34.62 153/168 1.15e7 36.36 PCB-141 4.18e6 36.50 163/138… 1.37e7 37.42 Abs. Int. 2.52e6 PCB-164 5.60e6PCB-160 37.13 5.28e6 37.56 1.26e6 0% 28.0 30.0 PCB-152 5.25e6 30.50 PCB-136 PCB-155 4.89e6 PCB-145 5.79e6 30.95 4.98e6 30.34 31.22 Rel. Int. 100% HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 4.74e2 32.0 PCB-148 3.78e6 32.48 34.0 147/149 139/140 151/135 7.24e6 7.49e6 7.26e6 33.78 34.30 33.01 PCB-154 PCB-143 4.28e6 PCB-132 3.74e6 33.21 3.18e6 34.03 34.85 36.0 PCB-165 4.32e6 35.59 38.0 153/168 9.06e6 36.36 163/138… 1.08e7 37.42 PCB-141 PCB-137 3.31e6 3.71e6 37.04 36.50 Abs. Int. 2.02e6 PCB-158 4.93e6 37.73 1.01e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 1.25e7 30.31 Rel. Int. 100% ES-153 8.37e6 36.31 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.20e3 30.0 32.0 34.0 JS-138 7.48e6 37.37 1.62e6 36.0 38.0 ES-155 9.87e6 30.32 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.24e6 0% 28.0 0.00e0 RT 0.00e0 RT Abs. Int. 2.62e6 ES-153 6.57e6 36.31 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.08e3 JS-138 5.88e6 37.37 1.31e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.12e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.06e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6883, 2783 scc: 523-232 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:37 (CEM) Printed: 31-Mar-2014 19:21 Page 13 of 21 355 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 8.67e6 38.47 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 3.19e3 PCB-159 5.27e6 39.28 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-162 5.19e6 39.52 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 156/157 9.84e6 40.91 Abs. Int. 1.98e6 PCB-167 5.69e6 39.93 PCB-169 4.56e6 43.62 9.91e5 0% 39.0 Rel. Int. 100% HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 1.99e3 128/166 7.06e6 38.47 PCB-162 PCB-159 4.31e6 4.33e6 39.52 39.28 40.0 41.0 42.0 43.0 44.0 45.0 156/157 7.87e6 40.91 0.00e0 RT Abs. Int. 1.59e6 PCB-167 4.60e6 39.93 PCB-169 3.70e6 43.62 7.93e5 0% 39.0 Rel. Int. 100% 40.0 ES-167 9.99e6 39.91 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 5.01e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.85e7 40.89 0.00e0 RT Abs. Int. 3.29e6 ES-169 8.39e6 43.60 1.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.45e7 40.89 Rel. Int. 100% Abs. Int. 2.75e6 ES-167 7.82e6 39.91 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 2.74e3 0.00e0 RT ES-169 6.72e6 43.60 1.37e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.84e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1034, 8083 scc: 523-232 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:29 Printed: 31-Mar-2014 19:21 Page 14 of 21 356 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% PCB-188 4.46e6 35.21 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-179 PCB-184 4.20e6 4.05e6 35.49 35.95 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 5.28e2 PCB-186 4.08e6 36.64 Abs. Int. 1.09e6 PCB-178 2.91e6 37.77 5.44e5 0% 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 36.0 PCB-188 4.18e6 35.21 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 4.83e2 PCB-179 3.95e6 35.49 PCB-176 4.21e6 36.24 37.0 PCB-186 3.86e6 36.64 38.0 Abs. Int. 1.05e6 PCB-178 2.74e6 37.77 5.27e5 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 7.96e6 35.19 Rel. Int. 100% CS/SS-178 4.62e6 37.75 1.00e6 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 7.27e6 35.19 Rel. Int. 100% CS/SS-178 4.29e6 37.75 9.14e5 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 1.83e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.16e3 31.0 0.00e0 RT Abs. Int. 2.01e6 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.12e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.12e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.06e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1881, 0480 scc: 523-232 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:37 (CEM) Printed: 31-Mar-2014 19:21 Page 15 of 21 357 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 2.83e3 PCB-183 4.18e6 PCB-182 39.07 PCB-185 4.01e6 3.49e6 38.72 39.15 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 180/193 8.20e6 42.04 171/173 6.27e6 PCB-181 40.17 PCB-177 3.58e6 3.23e6 39.98 39.64 PCB-172 3.26e6 41.51 PCB-191 4.48e6 42.37 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-170 3.04e6 43.14 Abs. Int. 1.41e6 PCB-190 4.13e6 43.59 7.05e5 0% 39.0 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 2.62e3 40.0 41.0 PCB-182 PCB-185 3.77e6 3.26e6 171/173 38.72 39.15 6.05e6 PCB-187 PCB-183 40.17 PCB-181 3.74e6 3.98e6 PCB-174 PCB-177 3.51e6 38.54 39.073.10e6 3.06e6 39.98 39.26 39.64 42.0 180/193 7.89e6 42.04 PCB-172 3.11e6 41.51 43.0 PCB-191 4.21e6 42.37 PCB-170 2.79e6 43.14 44.0 45.0 Abs. Int. 1.37e6 PCB-190 3.96e6 43.59 6.86e5 0% 39.0 40.0 41.0 42.0 ES-180 6.60e6 42.05 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 1.45e3 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 1.72e6 ES-170 5.53e6 43.12 8.59e5 0% 39.0 40.0 41.0 42.0 ES-180 6.18e6 42.05 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 3.42e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.53e6 ES-170 5.15e6 43.12 7.67e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.84e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0781, 9401 scc: 523-232 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:29 Printed: 31-Mar-2014 19:21 Page 16 of 21 358 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-189 4.42e6 45.75 Abs. Int. 1.08e6 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 1.17e3 5.38e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 4.14e6 45.75 Abs. Int. 1.00e6 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 1.42e3 5.02e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 7.91e6 45.73 0.00e0 RT Abs. Int. 1.82e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 2.76e3 9.09e5 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 7.94e6 45.73 0.00e0 RT Abs. Int. 1.88e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.71e3 9.42e5 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 9.43e5 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3195, 7494 scc: 523-232 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:37 (CEM) Printed: 31-Mar-2014 19:21 Page 17 of 21 359 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-201 3.59e6 40.53 PCB-202 3.16e6 39.74 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 6.90e2 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-197 3.62e6 PCB-204 41.29 PCB-200 3.36e6 3.30e6 41.38 41.10 198/199 4.56e6 43.70 Abs. Int. 8.61e5 PCB-196 2.42e6 44.28 PCB-203 2.55e6 44.45 4.30e5 0% 39.0 40.0 PCB-201 3.90e6 40.53 PCB-202 3.54e6 39.74 Rel. Int. 100% 41.0 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.83e2 42.0 43.0 PCB-197 4.06e6 PCB-204 41.29 PCB-200 3.73e6 3.75e6 41.38 41.10 44.0 45.0 198/199 4.92e6 43.70 Abs. Int. 9.66e5 PCB-196 2.62e6 44.28 PCB-203 2.74e6 44.45 4.83e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 6.42e6 39.72 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 1.53e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.12e3 7.66e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 7.18e6 39.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.70e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.07e3 8.52e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.84e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4745, 0579 scc: 523-232 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:38 (CEM) Printed: 31-Mar-2014 19:21 Page 18 of 21 360 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 1.27e3 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-195 2.21e6 45.57 PCB-194 2.24e6 47.51 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-205 2.77e6 47.91 Abs. Int. 6.60e5 3.30e5 0% 46.0 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 1.13e3 47.0 48.0 PCB-194 2.49e6 47.51 PCB-195 2.40e6 45.57 49.0 50.0 PCB-205 3.06e6 47.91 0.00e0 RT Abs. Int. 7.20e5 3.60e5 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 4.49e6 47.49 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 1.52e3 49.0 50.0 ES-205 5.29e6 47.89 Abs. Int. 1.30e6 (5.29e6 + 5.97e6) * 2000 pg = 1.20 (4.49e6 + 4.93e6) * 2000 pg CEM 31-Mar-2014 19:08 6.50e5 RRF (ES-205) = 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 4.93e6 47.49 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.28e3 0.00e0 RT 49.0 50.0 ES-205 5.97e6 47.89 0.00e0 RT Abs. Int. 1.46e6 7.29e5 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 9.43e5 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6493, 7537 scc: 523-232 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:29 Printed: 31-Mar-2014 19:21 Page 19 of 21 361 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.03e3 PCB-208 3.09e6 45.36 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-207 3.23e6 46.15 Abs. Int. 7.93e5 PCB-206 1.86e6 49.37 3.96e5 0% 46.0 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.26e3 PCB-208 3.99e6 45.36 47.0 48.0 49.0 50.0 PCB-207 4.14e6 46.15 Abs. Int. 1.03e6 PCB-206 2.46e6 49.37 5.13e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 1.44e6 ES-208 5.76e6 45.34 ES-206 3.56e6 49.35 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.48e3 7.19e5 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 1.78e6 ES-208 7.07e6 45.34 ES-206 4.27e6 49.35 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.59e3 8.90e5 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 9.43e5 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9249, 3885 scc: 523-232 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:38 (CEM) Printed: 31-Mar-2014 19:21 Page 20 of 21 362 of 711 SGS-AP ID: CS3_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-73-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 10:43:57 User: LKB Datafile: 140328X01 PCB-209 2.87e6 50.80 Rel. Int. 100% Abs. Int. 6.09e5 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 7.46e2 3.04e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.47e6 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.30e5 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 5.36e2 2.65e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 5.39e6 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.21e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 7.91e2 6.07e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 4.66e6 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.01e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.66e2 5.06e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.74e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 8.69e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\CS3_140328_PCB_XA.utp_res, saved 31-Mar-2014 19:08 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5661, 6729 scc: 523-232 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:38 (CEM) Printed: 31-Mar-2014 19:21 Page 21 of 21 363 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.97e7 2.98e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.70e7 8.51e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.43e7 7.17e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.27e7 1.14e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.23e7 6.15e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.68e6 1.34e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.54e6 1.27e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 654-631 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:16 Page 1 of 21 364 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 2.75e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 3.18e3 1.37e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.00e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 2.96e3 3.00e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.87e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 5.03e3 9.37e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.01e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.28e4 5.05e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.97e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.98e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5497, 0011 scc: 654-631 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:38 Printed: 31-Mar-2014 19:16 Page 2 of 21 365 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 8.22e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 3.43e3 4.11e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.86e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 1.29e4 1.43e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.53e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 8.07e3 1.26e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.02e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.70e3 3.01e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.97e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.98e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8599, 8662 scc: 654-631 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:37 (CEM) Printed: 31-Mar-2014 19:16 Page 3 of 21 366 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 8.46e3 DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PB 4σ 4.02e3 4.23e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.50e4 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PB 4σ 1.36e4 1.75e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.52e4 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PB 4σ 1.66e4 3.26e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e4 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PB 4σ 4.62e3 6.44e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.70e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 8.51e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9278, 1974 scc: 654-631 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:37 (CEM) Printed: 31-Mar-2014 19:16 Page 4 of 21 367 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 9.77e3 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PB 4σ 3.02e3 4.88e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PB 4σ 2.55e3 2.36e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PB 4σ 4.91e4 1.70e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.33e5 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PB 4σ 3.48e4 2.17e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.70e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 8.51e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8005, 7487 scc: 654-631 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:38 Printed: 31-Mar-2014 19:16 Page 5 of 21 368 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 PCB-36 5.49e5 24.87 Rel. Int. 100% Abs. Int. 1.41e5 TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 2.93e3 7.05e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-36 5.71e5 24.87 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.49e5 TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.54e3 7.43e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.56e6 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PB 4σ 5.59e4 7.81e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.13e5 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PB 4σ 3.19e4 1.06e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 7.17e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9288, 9345 scc: 654-631 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:38 Printed: 31-Mar-2014 19:16 Page 6 of 21 369 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 2.96e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 1.24e3 1.48e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.07e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 1.16e3 1.53e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.70e4 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PB 4σ 6.36e3 8.52e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.60e3 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PB 4σ 6.13e3 4.80e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.70e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 8.51e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4719, 5124 scc: 654-631 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:37 (CEM) Printed: 31-Mar-2014 19:16 Page 7 of 21 370 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 5.84e3 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PB 4σ 1.02e3 2.92e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.78e3 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PB 4σ 1.41e3 1.89e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.15e4 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PB 4σ 1.41e4 1.57e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.42e4 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PB 4σ 9.06e3 1.21e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 7.17e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4885, 4360 scc: 654-631 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:37 (CEM) Printed: 31-Mar-2014 19:16 Page 8 of 21 371 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 4.06e5 27.25 PCB-79 4.18e5 31.46 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.81e3 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Abs. Int. 1.01e5 PCB-78 3.77e5 31.95 5.03e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 5.34e5 27.25 32.0 PCB-79 5.06e5 31.46 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.33e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.26e5 PCB-78 4.82e5 31.95 6.32e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.98e4 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PB 4σ 1.65e4 1.49e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.84e4 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PB 4σ 8.10e3 9.20e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.27e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.14e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3190, 5077 scc: 654-631 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:38 (CEM) Printed: 31-Mar-2014 19:16 Page 9 of 21 372 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 PCB-96 2.44e5 25.74 Rel. Int. 100% Abs. Int. 6.47e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 7.02e2 3.24e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 3.71e5 25.73 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.22e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 7.00e2 4.61e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e4 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PB 4σ 1.54e3 5.31e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.83e3 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PB 4σ 1.88e3 2.92e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 7.17e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5818, 9218 scc: 654-631 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:38 (CEM) Printed: 31-Mar-2014 19:16 Page 10 of 21 373 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 1.99e5 28.39 PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 7.99e2 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 2.62e5 34.19 PCB-89 1.91e5 29.37 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Abs. Int. 7.34e4 PCB-106 2.54e5 34.62 3.67e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 3.13e5 28.39 PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 7.01e2 32.0 34.0 107/124 4.33e5 34.19 PCB-89 3.14e5 29.37 36.0 38.0 0.00e0 RT Abs. Int. 1.00e5 PCB-106 4.14e5 34.62 5.02e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.64e3 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PB 4σ 2.51e3 3.82e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.17e3 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PB 4σ 1.51e3 4.58e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.27e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.14e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5503, 1770 scc: 654-631 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:38 (CEM) Printed: 31-Mar-2014 19:16 Page 11 of 21 374 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 3.74e3 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 8.85e2 1.87e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.41e3 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.19e3 3.21e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.89e3 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PB 4σ 2.44e3 3.44e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.62e3 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PB 4σ 1.91e3 3.81e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.23e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.15e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4127, 9440 scc: 654-631 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:38 Printed: 31-Mar-2014 19:16 Page 12 of 21 375 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 PCB-152 4.30e5 30.53 Rel. Int. 100% Abs. Int. 1.00e5 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 8.29e2 5.02e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 3.35e5 30.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.06e4 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 6.65e2 4.03e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.13e3 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PB 4σ 1.32e3 3.57e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e4 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PB 4σ 1.52e3 5.07e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.27e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.14e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0649, 0291 scc: 654-631 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:38 Printed: 31-Mar-2014 19:16 Page 13 of 21 376 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Abs. Int. 7.99e4 128/166 3.25e5 38.51 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 1.04e3 4.00e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.32e4 128/166 2.68e5 38.51 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 8.20e2 3.16e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.62e3 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PB 4σ 1.75e3 3.31e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e4 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PB 4σ 2.21e3 5.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.23e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.15e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2348, 5407 scc: 654-631 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:38 Printed: 31-Mar-2014 19:16 Page 14 of 21 377 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 PCB-184 2.49e5 35.99 Rel. Int. 100% Abs. Int. 6.42e4 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 4.93e2 3.21e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.53e5 35.99 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.81e4 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.06e2 3.40e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.84e3 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PB 4σ 9.62e2 3.42e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.99e3 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PB 4σ 1.20e3 3.00e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.22e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.11e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3402, 2014 scc: 654-631 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:38 (CEM) Printed: 31-Mar-2014 19:16 Page 15 of 21 378 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 PCB-182 2.73e5 38.76 Abs. Int. 6.46e4 HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 9.26e2 3.23e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 2.31e5 38.76 0.00e0 RT Abs. Int. 5.60e4 HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 8.26e2 2.80e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.38e4 HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PB 4σ 1.73e3 6.92e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.54e3 HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PB 4σ 1.26e3 2.27e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.23e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.15e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5924, 7832 scc: 654-631 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 13:38 Printed: 31-Mar-2014 19:16 Page 16 of 21 379 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 2.68e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 9.96e2 1.34e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.05e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 8.19e2 1.03e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.42e3 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PB 4σ 2.23e3 2.71e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.64e3 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PB 4σ 1.41e3 1.82e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.68e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.34e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1262, 1452 scc: 654-631 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:37 (CEM) Printed: 31-Mar-2014 19:16 Page 17 of 21 380 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 PCB-204 2.42e5 41.15 Rel. Int. 100% Abs. Int. 5.57e4 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 6.22e2 2.78e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 2.43e5 41.15 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.06e4 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 7.50e2 3.03e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.66e3 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PB 4σ 1.47e3 2.33e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.19e3 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PB 4σ 1.20e3 3.10e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.23e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.15e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5140, 4597 scc: 654-631 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:38 (CEM) Printed: 31-Mar-2014 19:16 Page 18 of 21 381 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 2.50e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PB 4σ 7.59e2 1.25e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.75e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PB 4σ 7.56e2 1.38e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.09e3 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PB 4σ 1.01e3 2.55e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.84e3 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PB 4σ 9.07e2 1.92e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.68e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.34e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2496, 5706 scc: 654-631 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:37 (CEM) Printed: 31-Mar-2014 19:16 Page 19 of 21 382 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 3.59e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 1.22e3 1.80e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.92e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 1.74e3 2.46e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.37e3 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PB 4σ 8.17e2 1.69e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.21e3 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PB 4σ 1.10e3 1.60e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.68e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.34e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2679, 5659 scc: 654-631 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:37 (CEM) Printed: 31-Mar-2014 19:16 Page 20 of 21 383 of 711 SGS-AP ID: SBS_140326_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 26-Mar-2014 20:11:52 User: LKB Datafile: 140326X07 Rel. Int. 100% Abs. Int. 2.33e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: PB 4σ 5.64e2 1.17e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.26e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: PB 4σ 6.08e2 1.13e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.93e3 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PB 4σ 7.41e2 1.47e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.83e3 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PB 4σ 9.54e2 1.91e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.54e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.27e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140326_PCB_XB.utp_res, saved 31-Mar-2014 13:40 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6603, 7972 scc: 654-631 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:37 (CEM) Printed: 31-Mar-2014 19:16 Page 21 of 21 384 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.92e7 2.46e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.01e7 5.03e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 8.24e6 4.12e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.11 330.9792 Fn4 Flags: 0% Abs. Int. 1.62e7 8.11e6 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 Rel. Int. QC chk 100% 38.13-45.16 380.9760 Fn5 Flags: 0% Abs. Int. 9.66e6 4.83e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.18-50.15 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.54e6 7.69e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.42e6 7.11e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 851-325 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:21 Page 1 of 21 385 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 6.63e3 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 2.31e3 3.32e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.63e3 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 2.70e3 2.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.51e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 4.25e3 7.54e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.77e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.54e4 8.86e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.92e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.46e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1714, 1525 scc: 851-325 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 2 of 21 386 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 7.51e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 2.62e3 3.75e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.31e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 9.40e3 1.15e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.43e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 6.55e3 1.21e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.94e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.32e3 2.97e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.92e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.46e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2259, 9721 scc: 851-325 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 3 of 21 387 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 7.92e3 DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PB 4σ 4.55e3 3.96e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.69e4 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PB 4σ 1.19e4 1.35e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.28e4 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PB 4σ 1.66e4 4.14e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e4 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PB 4σ 5.71e3 7.62e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 5.03e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5991, 5357 scc: 851-325 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 4 of 21 388 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 7.06e3 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PB 4σ 2.03e3 3.53e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.82e3 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PB 4σ 2.00e3 2.41e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.93e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PB 4σ 4.08e4 9.65e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.39e5 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PB 4σ 2.34e4 1.20e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 5.03e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4187, 9036 scc: 851-325 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 5 of 21 389 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 PCB-36 5.74e5 24.85 Rel. Int. 100% Abs. Int. 1.52e5 TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 2.57e3 7.60e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-36 5.68e5 24.85 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e5 TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.25e3 7.55e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.64e5 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PB 4σ 5.20e4 4.82e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.70e5 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PB 4σ 2.46e4 4.35e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.24e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.12e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5100, 9674 scc: 851-325 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 6 of 21 390 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 3.99e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 1.09e3 2.00e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.24e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 7.30e2 1.12e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.72e3 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PB 4σ 3.42e3 4.36e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.91e3 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PB 4σ 3.41e3 4.46e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 5.03e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8618, 6692 scc: 851-325 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 7 of 21 391 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 2.90e3 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PB 4σ 9.33e2 1.45e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.84e3 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PB 4σ 1.09e3 2.42e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.31e4 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PB 4σ 5.82e3 6.56e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.66e3 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PB 4σ 4.70e3 4.33e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.24e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.12e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6521, 5886 scc: 851-325 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 8 of 21 392 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 4.27e5 27.22 PCB-79 4.03e5 31.44 TeCB-4 26.97-38.11 289.9224 Fn4 Flags: PBM 4σ 1.75e3 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Abs. Int. 1.06e5 PCB-78 3.77e5 31.93 5.28e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 5.38e5 27.22 32.0 PCB-79 5.24e5 31.44 TeCB-4 26.97-38.11 291.9194 Fn4 Flags: PBM 4σ 2.56e3 34.0 36.0 0.00e0 38.0 RT Abs. Int. 1.33e5 PCB-78 4.85e5 31.93 6.66e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.58e4 TeCB Std. 26.97-38.11 301.9626 Fn4 Flags: PB 4σ 8.34e3 7.91e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.23e4 TeCB Std. 26.97-38.11 303.9597 Fn4 Flags: PB 4σ 5.02e3 6.14e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.62e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 8.11e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 7734, 6020 scc: 851-325 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 9 of 21 393 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 PCB-96 2.37e5 25.71 Rel. Int. 100% Abs. Int. 5.89e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 7.33e2 2.94e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 3.51e5 25.71 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.50e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 8.12e2 4.25e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.32e3 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PB 4σ 1.25e3 2.66e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.84e3 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PB 4σ 1.33e3 1.92e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.24e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.12e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5714, 4104 scc: 851-325 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 10 of 21 394 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.97-38.11 323.8834 Fn4 Flags: PBM 4σ 1.06e3 PCB-102 1.97e5 28.36 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 2.66e5 34.16 PCB-89 1.89e5 29.33 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Abs. Int. 7.41e4 PCB-106 2.64e5 34.59 3.71e4 0% 28.0 Rel. Int. 100% PeCB-4 26.97-38.11 325.8804 Fn4 Flags: PBM 4σ 9.70e2 PCB-102 3.05e5 28.36 30.0 32.0 34.0 107/124 4.33e5 34.16 PCB-89 3.06e5 29.34 36.0 0.00e0 38.0 RT Abs. Int. 1.10e5 PCB-106 4.12e5 34.59 5.52e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.47e4 PeCB Std. 26.97-38.11 337.9207 Fn4 Flags: PB 4σ 1.88e3 7.34e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 5.39e3 PeCB Std. 26.97-38.11 339.9177 Fn4 Flags: PB 4σ 1.72e3 2.70e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.62e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 8.11e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2311, 9596 scc: 851-325 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 11 of 21 395 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 4.02e3 PeCB-5 38.13-45.16 323.8834 Fn5 Flags: PB 4σ 8.83e2 2.01e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.08e3 PeCB-5 38.13-45.16 325.8804 Fn5 Flags: PB 4σ 8.02e2 3.04e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e4 PeCB Std. 38.13-45.16 337.9207 Fn5 Flags: PB 4σ 1.66e3 5.48e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.07e3 PeCB Std. 38.13-45.16 339.9177 Fn5 Flags: PB 4σ 2.35e3 4.54e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.66e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.83e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8561, 2049 scc: 851-325 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 12 of 21 396 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 PCB-152 4.04e5 30.50 Rel. Int. 100% Abs. Int. 9.86e4 HxCB-4 26.97-38.11 359.8415 Fn4 Flags: PBM 4σ 6.60e2 4.93e4 0% 28.0 30.0 32.0 34.0 36.0 PCB-152 3.17e5 30.50 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 7.54e4 HxCB-4 26.97-38.11 361.8385 Fn4 Flags: PBM 4σ 6.37e2 3.77e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 8.15e3 HxCB Std. 26.97-38.11 371.8817 Fn4 Flags: PB 4σ 1.23e3 4.07e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 3.93e3 HxCB Std. 26.97-38.11 373.8788 Fn4 Flags: PB 4σ 1.22e3 1.96e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.62e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 8.11e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0330, 6155 scc: 851-325 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 13 of 21 397 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Abs. Int. 7.94e4 128/166 3.23e5 38.47 HxCB-5 38.13-45.16 359.8415 Fn5 Flags: PBM 4σ 7.68e2 3.97e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.86e4 128/166 2.59e5 38.47 HxCB-5 38.13-45.16 361.8385 Fn5 Flags: PBM 4σ 9.49e2 2.93e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.05e3 HxCB Std. 38.13-45.16 371.8817 Fn5 Flags: PB 4σ 1.30e3 4.02e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.58e3 HxCB Std. 38.13-45.16 373.8788 Fn5 Flags: PB 4σ 1.46e3 3.79e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.66e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.83e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8780, 6415 scc: 851-325 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 14 of 21 398 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 PCB-184 2.29e5 35.95 Rel. Int. 100% Abs. Int. 5.65e4 HpCB-4 30.00-38.11 393.8025 Fn4 Flags: PBM 4σ 6.12e2 2.82e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.33e5 35.95 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.26e4 HpCB-4 30.00-38.11 395.7995 Fn4 Flags: PBM 4σ 6.99e2 3.13e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.91e3 HpCB Std. 30.00-38.11 405.8428 Fn4 Flags: PB 4σ 1.50e3 3.45e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.46e3 HpCB Std. 30.00-38.11 407.8398 Fn4 Flags: PB 4σ 1.02e3 2.73e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 QC Check 30.00-38.11 330.9792 Fn4 Flags: - 8.11e6 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 8601, 5195 scc: 851-325 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 15 of 21 399 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 PCB-182 2.55e5 38.72 Abs. Int. 5.99e4 HpCB-5 38.13-45.16 393.8025 Fn5 Flags: PBM 4σ 8.28e2 2.99e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 2.52e5 38.72 0.00e0 RT Abs. Int. 5.94e4 HpCB-5 38.13-45.16 395.7995 Fn5 Flags: PBM 4σ 1.06e3 2.97e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.17e4 HpCB-5 Std. 38.13-45.16 405.8428 Fn5 Flags: PB 4σ 2.08e3 2.08e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.11e3 HpCB-5 Std. 38.13-45.16 407.8398 Fn5 Flags: PB 4σ 1.71e3 4.55e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.66e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.83e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6416, 8151 scc: 851-325 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 16 of 21 400 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 2.43e3 HpCB-6 45.18-50.15 393.8025 Fn6 Flags: PB 4σ 9.35e2 1.21e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.77e3 HpCB-6 45.18-50.15 395.7995 Fn6 Flags: PB 4σ 5.38e2 8.87e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.64e3 HpCB Std. 45.18-50.15 405.8428 Fn6 Flags: PB 4σ 2.36e3 2.82e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.71e3 HpCB Std. 45.18-50.15 407.8398 Fn6 Flags: PB 4σ 8.61e2 1.86e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.54e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 7.69e5 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5499, 4028 scc: 851-325 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 17 of 21 401 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 PCB-204 2.16e5 41.11 Rel. Int. 100% Abs. Int. 5.54e4 OcCB-5 38.13-45.16 427.7635 Fn5 Flags: PBM 4σ 8.11e2 2.77e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 2.27e5 41.11 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.29e4 OcCB-5 38.13-45.16 429.7606 Fn5 Flags: PBM 4σ 6.24e2 2.65e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.65e3 OcCB Std. 38.13-45.16 439.8038 Fn5 Flags: PB 4σ 1.29e3 1.83e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.78e3 OcCB Std. 38.13-45.16 441.8008 Fn5 Flags: PB 4σ 1.43e3 2.89e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.66e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.83e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1175, 7405 scc: 851-325 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 18 of 21 402 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 1.98e3 OcCB-6 45.18-50.15 427.7635 Fn6 Flags: PB 4σ 6.08e2 9.90e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e3 OcCB-6 45.18-50.15 429.7606 Fn6 Flags: PB 4σ 7.00e2 9.36e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.94e3 OcCB Std. 45.18-50.15 439.8038 Fn6 Flags: PB 4σ 9.31e2 2.47e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.58e3 OcCB Std. 45.18-50.15 441.8008 Fn6 Flags: PB 4σ 7.94e2 1.79e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.54e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 7.69e5 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6666, 9238 scc: 851-325 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 19 of 21 403 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 2.53e3 NoCB 45.18-50.15 461.7245 Fn6 Flags: PB 4σ 1.25e3 1.27e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.46e3 NoCB 45.18-50.15 463.7216 Fn6 Flags: PB 4σ 1.92e3 2.23e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.74e3 NoCB Std. 45.18-50.15 473.7648 Fn6 Flags: PB 4σ 9.67e2 1.87e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.37e3 NoCB Std. 45.18-50.15 475.7619 Fn6 Flags: PB 4σ 1.16e3 2.19e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.54e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 7.69e5 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4494, 0343 scc: 851-325 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 31-Mar-2014 18:42 Printed: 31-Mar-2014 19:22 Page 20 of 21 404 of 711 SGS-AP ID: SBS_140328_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 12:34:10 User: LKB Datafile: 140328X03 Rel. Int. 100% Abs. Int. 1.81e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: PB 4σ 7.03e2 9.03e2 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.53e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: PB 4σ 7.68e2 7.65e2 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.46e3 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PB 4σ 8.92e2 1.73e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.06e3 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PB 4σ 9.44e2 1.53e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.42e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 7.11e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\SBS_140328_PCB_XA.utp_res, saved 31-Mar-2014 18:42 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0950, 3837 scc: 851-325 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 18:42 (CEM) Printed: 31-Mar-2014 19:22 Page 21 of 21 Resolution Check Report Printed: 405 of 711 Page 1 of 5 MassLynx 4.1 SCN 881 Wednesday, March 26, 2014 18:21:38 Eastern Daylight Time M 180.9888 R 11264 M 204.9888 R 13225 180.9 M 218.9856 R 12378 204.9 1.00e0 x16 1.100 x16 230.9 1.00e0 x16 0.600 0.032 1.000 M 230.9856 R 11876 218.9 1.00e0 0.034 1.00e0 x16 0.650 0.550 0.600 0.500 0.550 0.450 0.500 0.030 0.028 0.900 0.026 0.800 0.024 0.450 0.400 0.022 0.700 0.400 0.350 0.020 0.600 0.350 0.018 0.300 0.016 0.300 0.500 0.250 0.014 0.250 0.400 0.012 0.200 0.200 0.010 0.300 0.150 0.008 0.200 0.150 0.006 0.100 0.100 0.004 0.100 0.050 0.050 -0.000 -0.000 0.002 -0.000 -0.000 180.88 180.89 180.90 204.86 M 242.9856 R 12728 204.87 204.88 204.89 218.84 M 218.9856 R 12565 242.8 218.85 218.86 x16 218.88 230.83 M 230.9856 R 11792 218.9 1.00e0 218.87 230.84 230.85 x16 230.87 M 242.9856 R 12376 230.9 1.00e0 230.86 242.9 1.00e0 x16 1.00e0 x16 0.160 0.150 0.160 0.600 0.550 0.150 0.550 0.140 0.500 0.140 0.130 0.500 0.130 0.450 0.120 0.120 0.450 0.110 0.400 0.110 0.400 0.100 0.100 0.350 0.090 0.350 0.090 0.300 0.080 0.080 0.300 0.070 0.250 0.070 0.250 0.060 0.060 0.200 0.200 0.050 0.150 0.040 0.030 0.050 0.040 0.150 0.030 0.100 0.100 0.020 0.020 0.050 0.050 -0.000 -0.000 0.010 0.010 -0.000 242.82 242.83 242.84 242.85 242.86 218.87 M 254.9856 R 12107 218.88 218.89 218.90 230.86 M 268.9824 R 12325 254.9 -0.000 230.87 x16 230.89 242.85 M 280.9824 R 12378 268.8 1.00e0 230.88 x16 242.87 242.88 242.89 M 292.9824 R 11685 280.8 1.00e0 292.8 1.00e0 x16 0.220 0.070 242.86 1.00e0 x16 0.120 0.360 0.065 0.340 0.200 0.110 0.320 0.060 0.100 0.180 0.300 0.055 0.280 0.090 0.160 0.050 0.260 0.080 0.240 0.140 0.045 0.220 0.070 0.040 0.120 0.200 0.035 0.060 0.180 0.100 0.160 0.030 0.050 0.140 0.080 0.025 0.040 0.120 0.020 0.060 0.100 0.030 0.080 0.015 0.040 0.020 0.060 0.010 0.040 0.020 0.010 0.005 0.020 -0.000 -0.000 254.84 254.85 254.86 254.87 254.88 268.82 268.83 268.84 268.85 268.86 268.87 -0.000 280.81 -0.000 280.82 280.83 280.84 280.85 280.86 292.81 292.82 292.83 292.84 292.85 Resolution Check Report Printed: 406 of 711 Page 2 of 5 MassLynx 4.1 SCN 881 Wednesday, March 26, 2014 18:21:38 Eastern Daylight Time M 304.9824 R 11993 M 242.9856 R 12106 304.8 M 254.9856 R 12317 242.9 1.00e0 x16 M 268.9824 R 12755 254.9 1.00e0 x16 268.9 1.00e0 x16 1.00e0 x16 0.180 0.075 0.170 0.055 0.200 0.070 0.160 0.050 0.045 0.150 0.065 0.140 0.060 0.040 0.180 0.160 0.130 0.055 0.120 0.050 0.140 0.110 0.035 0.045 0.100 0.030 0.120 0.040 0.090 0.025 0.080 0.035 0.070 0.030 0.100 0.080 0.020 0.060 0.025 0.050 0.015 0.060 0.020 0.040 0.015 0.010 0.040 0.030 0.010 0.020 0.020 0.005 0.005 0.010 -0.000 -0.000 304.80 304.81 304.82 304.83 304.84 304.85 -0.000 242.86 M 280.9824 R 11966 242.87 242.88 242.89 242.90 M 292.9824 R 12377 280.9 -0.000 254.85 254.86 254.87 x16 254.89 268.84 M 304.9824 R 12322 292.8 1.00e0 254.88 268.85 268.86 x16 268.88 M 316.9824 R 13278 304.8 1.00e0 268.87 316.8 1.00e0 x16 1.00e0 x16 0.140 0.360 0.070 0.030 0.065 0.028 0.060 0.026 0.055 0.024 0.130 0.340 0.320 0.120 0.300 0.110 0.280 0.100 0.260 0.240 0.022 0.050 0.090 0.020 0.045 0.220 0.018 0.080 0.040 0.200 0.180 0.016 0.070 0.035 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.010 0.005 0.002 -0.000 -0.000 -0.000 0.014 0.160 0.012 0.140 0.010 0.120 0.100 0.008 0.080 0.060 0.006 0.004 0.040 0.020 -0.000 280.83 280.84 280.85 280.86 280.87 280.88 M 330.9792 R 11636 292.82 292.83 292.84 292.85 292.86 292.87 304.81 M 342.9792 R 12481 330.8 304.82 304.83 x16 304.85 304.86 316.80 M 280.9824 R 12345 342.8 1.00e0 304.84 316.81 316.82 x16 316.84 316.85 M 292.9824 R 11654 280.9 1.00e0 316.83 292.9 1.00e0 x16 1.00e0 x16 0.400 0.190 0.140 0.075 0.380 0.180 0.360 0.070 0.170 0.130 0.340 0.160 0.120 0.065 0.320 0.150 0.060 0.110 0.300 0.140 0.055 0.280 0.100 0.130 0.260 0.050 0.120 0.090 0.240 0.045 0.110 0.080 0.220 0.100 0.040 0.200 0.090 0.070 0.180 0.035 0.080 0.060 0.160 0.030 0.070 0.140 0.060 0.025 0.050 0.020 0.100 0.015 0.080 0.050 0.120 0.040 0.040 0.030 0.030 0.060 0.020 0.010 0.020 0.040 0.010 0.005 0.010 -0.000 0.020 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 330.85 -0.000 342.79 342.80 342.81 342.82 342.83 342.84 342.85 -0.000 280.84 280.85 280.86 280.87 280.88 280.89 292.83 292.84 292.85 292.86 292.87 292.88 Resolution Check Report Printed: 407 of 711 Page 3 of 5 MassLynx 4.1 SCN 881 Wednesday, March 26, 2014 18:21:38 Eastern Daylight Time M 304.9824 R 11990 M 316.9824 R 13230 304.8 M 330.9792 R 12019 316.8 1.00e0 x16 M 342.9792 R 11904 330.8 1.00e0 x16 342.8 1.00e0 x16 1.00e0 x16 0.100 0.070 0.026 0.200 0.065 0.024 0.090 0.180 0.060 0.022 0.080 0.055 0.160 0.020 0.050 0.070 0.018 0.140 0.045 0.016 0.060 0.120 0.040 0.014 0.050 0.035 0.100 0.012 0.030 0.040 0.080 0.010 0.025 0.008 0.030 0.060 0.020 0.006 0.015 0.020 0.040 0.010 0.004 0.005 0.002 0.010 0.020 -0.000 304.82 304.83 304.84 304.85 304.86 304.87 304.88 M 366.9792 R 13054 -0.000 316.81 -0.000 316.82 316.83 316.84 316.85 316.86 330.80 M 380.9760 R 11765 366.8 -0.000 316.87 330.81 330.82 330.83 x16 330.85 330.86 342.79 M 392.9760 R 13328 380.8 1.00e0 330.84 342.80 342.81 342.82 x16 342.84 342.85 M 404.9760 R 12570 392.8 1.00e0 342.83 404.8 1.00e0 x16 1.00e0 x16 0.030 0.024 0.110 0.028 0.045 0.022 0.026 0.100 0.020 0.040 0.024 0.090 0.022 0.018 0.035 0.080 0.020 0.016 0.070 0.030 0.060 0.025 0.018 0.014 0.016 0.012 0.014 0.050 0.010 0.020 0.012 0.040 0.008 0.010 0.015 0.008 0.030 0.006 0.010 0.004 0.020 0.002 0.010 -0.000 -0.000 0.006 0.004 0.005 0.002 366.77 366.78 366.79 366.80 366.81 366.82 366.83 366.84 -0.000 380.76 M 430.9728 R 12019 380.77 380.78 380.79 380.80 380.81 380.82 380.83 392.76 M 316.9824 R 13021 430.8 -0.000 392.77 392.78 392.79 x16 392.81 392.82 392.83 404.76 M 330.9792 R 12383 316.8 1.00e0 392.80 404.77 404.78 404.79 x16 404.81 404.82 404.83 M 342.9792 R 12056 330.8 1.00e0 404.80 342.8 1.00e0 x16 1.00e0 x16 0.045 0.200 0.030 0.100 0.028 0.040 0.180 0.026 0.035 0.090 0.160 0.024 0.080 0.022 0.140 0.030 0.020 0.070 0.120 0.018 0.025 0.060 0.016 0.100 0.050 0.014 0.020 0.080 0.012 0.040 0.015 0.010 0.060 0.030 0.008 0.010 0.006 0.040 0.020 0.004 0.005 0.020 0.010 0.002 -0.000 -0.000 430.75 430.76 430.77 430.78 430.79 430.80 430.81 430.82 430.83 -0.000 316.80 316.81 316.82 316.83 316.84 316.85 316.86 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 342.78 342.79 342.80 342.81 342.82 342.83 342.84 Resolution Check Report Printed: 408 of 711 Page 4 of 5 MassLynx 4.1 SCN 881 Wednesday, March 26, 2014 18:21:38 Eastern Daylight Time M 366.9792 R 13273 M 380.9760 R 12112 366.8 M 392.9760 R 12051 380.8 1.00e0 x16 M 404.9760 R 12367 392.8 1.00e0 x16 404.8 1.00e0 x16 0.026 x16 0.036 0.120 0.055 0.024 1.00e0 0.038 0.060 0.034 0.110 0.032 0.050 0.022 0.030 0.100 0.045 0.020 0.028 0.090 0.026 0.018 0.040 0.024 0.080 0.016 0.022 0.035 0.070 0.020 0.014 0.030 0.018 0.060 0.012 0.016 0.025 0.050 0.014 0.010 0.020 0.040 0.012 0.008 0.006 0.010 0.015 0.030 0.008 0.004 0.020 0.010 0.010 0.005 0.006 0.004 0.002 0.002 -0.000 -0.000 366.76 366.77 366.78 366.79 366.80 366.81 366.82 -0.000 380.74 M 430.9728 R 11932 380.75 380.76 380.77 380.78 380.79 380.80 380.81 M 442.9728 R 12412 430.7 -0.000 392.73 392.74 392.75 392.76 392.77 x16 392.79 392.80 404.72 M 380.9760 R 12383 442.7 1.00e0 392.78 404.74 404.75 x16 404.76 404.77 404.78 404.79 M 392.9760 R 12284 380.8 1.00e0 392.7 1.00e0 x16 0.036 0.060 404.73 1.00e0 0.130 0.060 0.120 0.055 0.110 0.050 x16 0.034 0.032 0.055 0.030 0.050 0.028 0.100 0.045 0.045 0.026 0.024 0.090 0.022 0.080 0.040 0.040 0.035 0.035 0.020 0.070 0.018 0.030 0.030 0.060 0.016 0.025 0.025 0.014 0.050 0.012 0.020 0.020 0.040 0.010 0.015 0.015 0.030 0.008 0.006 0.010 0.010 0.020 0.004 0.005 0.005 0.010 0.002 -0.000 -0.000 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 -0.000 430.78 M 404.9760 R 12995 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 380.73 M 430.9728 R 11995 404.7 380.74 380.75 380.76 x16 380.78 -0.000 392.71 380.79 M 442.9728 R 12565 430.7 1.00e0 0.040 380.77 392.72 392.73 392.74 x16 392.76 392.77 392.78 M 454.9728 R 12919 442.7 1.00e0 392.75 454.7 1.00e0 x16 1.00e0 x16 0.065 0.036 0.045 0.038 0.060 0.036 0.034 0.032 0.040 0.034 0.055 0.030 0.032 0.050 0.030 0.028 0.028 0.035 0.026 0.045 0.026 0.024 0.030 0.040 0.024 0.022 0.022 0.020 0.025 0.035 0.020 0.018 0.030 0.018 0.016 0.020 0.016 0.025 0.014 0.014 0.012 0.015 0.020 0.012 0.010 0.010 0.015 0.008 0.010 0.008 0.006 0.010 0.006 0.004 0.005 0.004 0.005 0.002 0.002 -0.000 -0.000 404.70 404.71 404.72 404.73 404.74 404.75 404.76 404.77 -0.000 430.68 430.69 430.70 430.71 430.72 430.73 430.74 430.75 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 Resolution Check Report Printed: 409 of 711 Page 5 of 5 MassLynx 4.1 SCN 881 Wednesday, March 26, 2014 18:21:38 Eastern Daylight Time M 466.9728 R 13797 M 480.9696 R 12775 466.7 M 430.9728 R 12929 480.7 1.00e0 x16 M 442.9728 R 12583 430.7 1.00e0 x16 442.7 1.00e0 x16 1.00e0 x16 0.045 0.080 0.045 0.019 0.075 0.018 0.040 0.040 0.070 0.017 0.016 0.065 0.035 0.015 0.035 0.060 0.014 0.055 0.030 0.013 0.030 0.050 0.012 0.025 0.011 0.045 0.010 0.025 0.040 0.009 0.020 0.035 0.020 0.008 0.030 0.007 0.015 0.015 0.025 0.006 0.005 0.020 0.010 0.010 0.004 0.015 0.003 0.010 0.005 0.002 0.005 0.005 0.001 -0.000 -0.000 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 -0.000 466.72 480.63 M 454.9728 R 12570 480.64 480.65 480.66 480.67 480.68 480.69 480.70 430.70 M 466.9728 R 13545 454.7 -0.000 480.71 430.71 430.72 430.73 x16 430.75 430.76 430.77 442.69 442.70 442.71 442.72 x16 442.73 442.74 442.75 442.76 442.77 M 492.9696 R 12319 480.7 1.00e0 492.7 1.00e0 x16 0.019 0.032 430.78 M 480.9696 R 12661 466.7 1.00e0 430.74 1.00e0 x16 0.030 0.018 0.040 0.028 0.017 0.030 0.026 0.016 0.028 0.035 0.015 0.026 0.024 0.014 0.024 0.022 0.030 0.013 0.020 0.022 0.012 0.020 0.011 0.018 0.010 0.016 0.009 0.014 0.008 0.018 0.025 0.016 0.020 0.014 0.012 0.007 0.012 0.015 0.010 0.006 0.010 0.005 0.008 0.008 0.010 0.004 0.006 0.006 0.003 0.004 0.002 0.002 0.001 -0.000 -0.000 454.68 454.69 454.70 454.71 454.72 454.73 454.74 454.75 454.76 M 504.9696 R 13481 0.002 -0.000 466.66 466.67 466.68 466.69 466.70 466.71 466.72 466.73 466.74 516.7 x16 1.00e0 x16 0.018 0.017 0.026 0.016 0.024 0.015 0.014 0.022 0.013 0.020 0.012 0.018 0.011 0.016 0.010 0.009 0.014 0.008 0.012 0.007 0.010 0.006 0.008 0.005 0.004 0.006 0.003 0.004 0.002 0.002 0.001 -0.000 -0.000 504.63 504.64 504.65 504.66 504.67 466.75 M 516.9697 R 13335 504.7 1.00e0 0.028 504.68 504.69 504.70 504.71 504.72 0.004 0.005 516.62 516.63 516.64 516.65 516.66 516.67 516.68 516.69 516.70 -0.000 480.65 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 492.64 492.65 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 Resolution Check Report Printed: 410 of 711 Page 1 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 06:31:08 Eastern Daylight Time M 180.9888 R 10666 M 204.9888 R 11775 180.9 M 218.9856 R 11574 204.9 1.00e0 x16 M 230.9856 R 11764 218.9 1.00e0 x16 230.8 1.00e0 x16 1.00e0 x16 0.650 0.038 0.036 1.000 0.550 0.600 0.500 0.550 0.034 0.032 0.900 0.030 0.500 0.450 0.028 0.800 0.450 0.026 0.700 0.400 0.024 0.400 0.350 0.022 0.600 0.350 0.020 0.300 0.018 0.500 0.300 0.016 0.250 0.250 0.014 0.400 0.200 0.012 0.300 0.200 0.010 0.150 0.150 0.008 0.200 0.100 0.006 0.100 0.004 0.100 0.050 0.050 0.002 -0.000 -0.000 180.87 180.88 180.89 -0.000 180.90 204.85 M 242.9856 R 11633 204.86 204.87 218.84 M 218.9856 R 11944 242.8 -0.000 204.88 218.85 218.86 x16 230.83 M 230.9856 R 11908 218.9 1.00e0 218.87 230.84 230.85 M 242.9856 R 12109 230.9 1.00e0 x16 230.86 242.9 1.00e0 x16 0.600 1.00e0 x16 0.150 0.550 0.130 0.140 0.550 0.120 0.500 0.130 0.500 0.110 0.120 0.450 0.450 0.100 0.110 0.400 0.090 0.400 0.100 0.350 0.090 0.350 0.080 0.070 0.300 0.060 0.250 0.080 0.300 0.070 0.250 0.060 0.050 0.200 0.200 0.050 0.040 0.150 0.040 0.150 0.030 0.030 0.100 0.100 0.050 0.050 -0.000 -0.000 0.020 0.020 0.010 -0.000 242.82 242.83 242.84 242.85 242.86 218.86 M 254.9856 R 12705 218.87 218.88 218.89 218.90 230.85 M 268.9824 R 11628 254.9 0.010 -0.000 230.86 230.87 x16 230.89 242.84 M 280.9824 R 11338 268.8 1.00e0 230.88 242.85 242.86 x16 242.88 M 292.9824 R 12106 280.8 1.00e0 242.87 292.8 1.00e0 x16 1.00e0 x16 0.360 0.060 0.110 0.340 0.200 0.320 0.055 0.100 0.300 0.180 0.050 0.090 0.280 0.160 0.045 0.260 0.080 0.240 0.040 0.140 0.220 0.035 0.070 0.200 0.120 0.060 0.180 0.030 0.100 0.160 0.025 0.050 0.140 0.080 0.040 0.120 0.020 0.100 0.060 0.030 0.015 0.080 0.040 0.020 0.060 0.010 0.040 0.020 0.005 0.010 0.020 -0.000 -0.000 254.83 254.84 254.85 254.86 254.87 -0.000 268.82 268.83 268.84 268.85 268.86 -0.000 280.81 280.82 280.83 280.84 280.85 280.86 292.80 292.81 292.82 292.83 292.84 292.85 Resolution Check Report Printed: 411 of 711 Page 2 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 06:31:08 Eastern Daylight Time M 304.9824 R 12056 M 242.9856 R 11825 304.8 M 254.9856 R 12383 242.9 1.00e0 x16 M 268.9824 R 11937 254.9 1.00e0 x16 268.9 1.00e0 x16 1.00e0 x16 0.060 0.150 0.200 0.050 0.055 0.140 0.180 0.045 0.130 0.050 0.120 0.160 0.040 0.045 0.110 0.035 0.090 0.030 0.140 0.040 0.100 0.120 0.035 0.080 0.030 0.025 0.100 0.070 0.025 0.060 0.020 0.080 0.020 0.050 0.060 0.015 0.040 0.015 0.030 0.010 0.040 0.010 0.020 0.005 0.020 0.005 0.010 -0.000 304.79 -0.000 304.80 304.81 304.82 304.83 304.84 -0.000 304.85 M 280.9824 R 11911 242.86 242.87 242.88 242.89 M 292.9824 R 11995 280.8 -0.000 242.90 254.85 254.86 x16 0.340 254.88 254.89 268.83 M 304.9824 R 11737 292.8 1.00e0 254.87 268.84 268.85 x16 268.88 316.8 1.00e0 x16 1.00e0 x16 0.028 0.060 0.120 268.87 M 316.9824 R 13160 304.8 1.00e0 268.86 0.320 0.026 0.055 0.110 0.300 0.024 0.280 0.050 0.100 0.022 0.260 0.090 0.045 0.080 0.040 0.070 0.035 0.016 0.060 0.030 0.014 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.010 0.005 0.002 -0.000 -0.000 -0.000 316.79 0.020 0.240 0.220 0.200 0.018 0.180 0.160 0.012 0.140 0.010 0.120 0.100 0.008 0.080 0.006 0.060 0.004 0.040 0.020 -0.000 280.82 280.83 280.84 280.85 280.86 280.87 292.81 M 330.9792 R 11580 292.82 292.83 292.84 292.85 292.86 304.80 M 342.9792 R 11848 330.8 304.81 304.82 x16 304.84 304.85 M 280.9824 R 11746 342.8 1.00e0 304.83 316.80 316.81 x16 316.83 316.84 316.85 M 292.9824 R 12077 280.9 1.00e0 0.070 316.82 292.9 1.00e0 x16 1.00e0 x16 0.380 0.160 0.360 0.065 0.120 0.340 0.150 0.110 0.060 0.320 0.140 0.300 0.055 0.130 0.100 0.280 0.050 0.120 0.090 0.260 0.110 0.045 0.240 0.100 0.080 0.220 0.040 0.070 0.090 0.200 0.035 0.080 0.180 0.030 0.070 0.060 0.160 0.050 0.060 0.140 0.025 0.120 0.050 0.040 0.020 0.100 0.040 0.030 0.015 0.080 0.030 0.060 0.010 0.020 0.020 0.040 0.010 0.005 0.010 0.020 -0.000 -0.000 330.78 330.79 330.80 330.81 330.82 330.83 330.84 -0.000 342.78 342.79 342.80 342.81 342.82 342.83 342.84 -0.000 280.84 280.85 280.86 280.87 280.88 292.83 292.84 292.85 292.86 292.87 292.88 Resolution Check Report Printed: 412 of 711 Page 3 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 06:31:08 Eastern Daylight Time M 304.9824 R 12380 M 316.9824 R 13698 304.8 M 330.9792 R 12407 316.8 1.00e0 x16 M 342.9792 R 11876 330.8 1.00e0 x16 342.8 1.00e0 x16 1.00e0 x16 0.095 0.065 0.024 0.200 0.090 0.060 0.085 0.022 0.180 0.055 0.080 0.020 0.075 0.050 0.160 0.070 0.018 0.045 0.065 0.140 0.016 0.060 0.040 0.055 0.120 0.014 0.035 0.050 0.012 0.100 0.030 0.045 0.040 0.010 0.025 0.080 0.035 0.008 0.020 0.030 0.060 0.025 0.015 0.006 0.010 0.004 0.005 0.002 0.020 0.040 0.015 0.010 0.020 0.005 -0.000 -0.000 304.82 304.83 304.84 304.85 304.86 -0.000 304.87 316.81 M 366.9792 R 13652 316.82 316.83 316.84 316.85 316.86 M 380.9760 R 11879 366.8 -0.000 330.79 330.80 330.81 330.82 x16 330.84 330.85 342.78 M 392.9760 R 11473 380.8 1.00e0 330.83 342.79 342.80 342.81 x16 342.83 342.84 M 404.9760 R 13143 392.8 1.00e0 342.82 404.8 1.00e0 x16 1.00e0 x16 0.110 0.026 0.045 0.022 0.100 0.024 0.020 0.040 0.090 0.022 0.018 0.080 0.035 0.070 0.030 0.020 0.016 0.018 0.014 0.016 0.060 0.025 0.012 0.014 0.050 0.012 0.010 0.020 0.010 0.040 0.008 0.015 0.008 0.030 0.006 0.006 0.010 0.020 0.004 0.004 0.002 0.010 -0.000 -0.000 366.77 366.78 366.79 366.80 366.81 366.82 366.83 0.005 0.002 -0.000 380.75 M 430.9728 R 11688 380.76 380.77 380.78 380.79 380.80 380.81 380.82 392.75 M 316.9824 R 13487 430.8 -0.000 392.76 392.77 392.78 x16 392.80 392.81 392.82 404.75 M 330.9792 R 11659 316.8 1.00e0 392.79 404.77 404.78 x16 x16 404.81 404.82 1.00e0 x16 0.090 0.180 0.085 0.170 0.080 0.160 0.022 404.80 342.8 1.00e0 0.190 0.024 404.79 M 342.9792 R 11908 330.8 1.00e0 0.026 0.040 404.76 0.075 0.035 0.150 0.070 0.020 0.140 0.065 0.030 0.018 0.130 0.060 0.120 0.016 0.055 0.025 0.110 0.050 0.014 0.100 0.045 0.020 0.090 0.012 0.040 0.080 0.010 0.035 0.070 0.015 0.030 0.060 0.008 0.025 0.050 0.010 0.006 0.004 0.005 0.040 0.020 0.030 0.015 0.010 0.020 0.002 0.005 0.010 -0.000 -0.000 430.74 430.75 430.76 430.77 430.78 430.79 430.80 430.81 430.82 -0.000 316.80 316.81 316.82 316.83 316.84 316.85 -0.000 330.78 330.79 330.80 330.81 330.82 330.83 330.84 342.77 342.78 342.79 342.80 342.81 342.82 342.83 Resolution Check Report Printed: 413 of 711 Page 4 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 06:31:08 Eastern Daylight Time M 366.9792 R 13021 M 380.9760 R 12595 366.8 M 392.9760 R 13367 380.8 1.00e0 x16 M 404.9760 R 12747 392.8 1.00e0 x16 404.7 1.00e0 x16 0.055 1.00e0 x16 0.034 0.120 0.024 0.032 0.050 0.110 0.030 0.022 0.100 0.045 0.090 0.040 0.028 0.020 0.026 0.018 0.024 0.080 0.022 0.035 0.016 0.020 0.070 0.014 0.030 0.018 0.060 0.012 0.016 0.025 0.050 0.010 0.014 0.020 0.012 0.040 0.008 0.010 0.015 0.006 0.030 0.004 0.020 0.002 0.010 0.005 -0.000 -0.000 -0.000 0.008 0.010 0.006 0.004 0.002 366.75 366.76 366.77 366.78 366.79 366.80 366.81 380.73 M 430.9728 R 11783 380.74 380.75 380.76 380.77 380.78 380.79 380.80 392.72 M 442.9728 R 12338 430.7 -0.000 392.73 392.74 392.75 392.76 x16 392.78 392.79 404.71 M 380.9760 R 12170 442.7 1.00e0 392.77 404.72 404.73 404.74 404.75 x16 404.77 404.78 M 392.9760 R 12078 380.8 1.00e0 0.065 404.76 392.7 1.00e0 x16 1.00e0 x16 0.120 0.030 0.060 0.050 0.110 0.028 0.055 0.026 0.050 0.100 0.045 0.090 0.040 0.024 0.045 0.022 0.080 0.035 0.020 0.040 0.070 0.018 0.030 0.035 0.016 0.060 0.030 0.025 0.014 0.050 0.025 0.012 0.020 0.010 0.020 0.040 0.015 0.008 0.030 0.015 0.006 0.010 0.020 0.010 0.004 0.005 0.010 0.005 0.002 -0.000 -0.000 430.69 430.70 430.71 430.72 430.73 430.74 430.75 -0.000 430.76 442.69 M 404.9760 R 12954 442.70 442.71 442.72 442.73 442.74 442.75 380.72 M 430.9728 R 12680 404.7 -0.000 442.76 380.73 380.74 380.75 x16 380.77 380.78 380.79 M 442.9728 R 12898 430.7 1.00e0 0.032 380.76 392.71 392.72 392.73 392.74 x16 392.76 392.77 392.78 M 454.9728 R 12362 442.7 1.00e0 392.75 454.7 1.00e0 x16 0.060 1.00e0 x16 0.028 0.040 0.030 0.026 0.055 0.028 0.024 0.035 0.050 0.026 0.022 0.024 0.045 0.030 0.020 0.022 0.040 0.018 0.020 0.025 0.035 0.018 0.016 0.016 0.030 0.014 0.020 0.014 0.012 0.025 0.012 0.015 0.010 0.020 0.010 0.008 0.008 0.015 0.010 0.006 0.006 0.010 0.004 0.004 0.005 0.005 0.002 0.002 -0.000 -0.000 404.70 404.71 404.72 404.73 404.74 404.75 404.76 404.77 -0.000 430.67 430.68 430.69 430.70 430.71 430.72 430.73 430.74 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 -0.000 454.64 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 Resolution Check Report Printed: 414 of 711 Page 5 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 06:31:08 Eastern Daylight Time M 466.9728 R 12588 M 480.9696 R 12059 466.7 M 430.9728 R 12019 480.7 1.00e0 x16 M 442.9728 R 12961 430.7 1.00e0 x16 442.7 1.00e0 x16 1.00e0 x16 0.075 0.040 0.016 0.070 0.015 0.038 0.040 0.036 0.065 0.014 0.034 0.060 0.032 0.035 0.013 0.030 0.055 0.012 0.028 0.030 0.011 0.050 0.026 0.010 0.045 0.024 0.025 0.009 0.022 0.040 0.020 0.008 0.035 0.020 0.018 0.007 0.030 0.016 0.025 0.014 0.006 0.015 0.005 0.012 0.020 0.010 0.004 0.010 0.015 0.008 0.003 0.006 0.010 0.002 0.005 0.004 0.005 0.001 -0.000 -0.000 466.63 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 M 454.9728 R 12634 0.002 -0.000 480.62 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 430.69 M 466.9728 R 13736 454.7 -0.000 430.70 430.71 430.72 430.73 x16 430.75 430.76 430.77 442.68 M 480.9696 R 12301 466.7 1.00e0 430.74 442.69 442.70 442.71 442.72 x16 0.032 442.74 442.75 442.76 M 492.9696 R 12756 480.7 1.00e0 442.73 492.7 1.00e0 x16 1.00e0 x16 0.040 0.028 0.014 0.030 0.026 0.013 0.028 0.035 0.024 0.012 0.026 0.022 0.011 0.024 0.022 0.010 0.020 0.009 0.018 0.008 0.016 0.030 0.020 0.018 0.025 0.016 0.020 0.007 0.014 0.014 0.012 0.006 0.012 0.015 0.005 0.010 0.010 0.008 0.004 0.008 0.010 0.003 0.006 0.006 0.002 0.004 0.002 0.001 -0.000 -0.000 454.67 454.68 454.69 454.70 454.71 454.72 454.73 454.74 0.002 -0.000 454.75 466.66 M 504.9696 R 12241 466.67 466.68 466.69 466.70 466.71 466.72 466.73 1.00e0 x16 0.014 0.024 0.013 0.022 0.012 0.020 0.011 0.018 0.010 0.016 0.009 0.014 0.008 0.007 0.012 0.006 0.010 0.005 0.008 0.004 0.006 0.003 0.004 0.002 0.002 0.001 -0.000 -0.000 504.63 504.64 504.65 504.66 504.67 504.68 504.69 504.70 504.71 516.61 516.62 516.63 516.64 516.65 516.66 516.67 516.68 516.69 -0.000 480.64 516.7 x16 0.026 504.62 466.74 M 516.9697 R 13961 504.7 1.00e0 0.004 0.005 480.65 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 492.63 492.64 492.65 492.66 492.67 492.68 492.69 492.70 492.71 492.72 Experiment Calibration Report 415 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 1 @ 200 (ppm) Printed: Friday, March 28, 2014 10:40:38 Eastern Daylight Time M 180.9888 R 12310 M 204.9888 R 11794 242.8 M 218.9856 R 11964 180.9 1.00e0 x16 M 230.9856 R 12018 204.9 1.00e0 x16 218.9 1.00e0 x16 0.600 0.900 1.00e0 x16 0.500 0.024 0.850 0.475 0.550 0.022 0.800 0.450 0.425 0.500 0.750 0.020 0.400 0.700 0.450 0.375 0.018 0.650 0.350 0.600 0.400 0.016 0.325 0.550 0.500 0.300 0.350 0.014 0.275 0.450 0.300 0.012 0.250 0.225 0.400 0.250 0.010 0.350 0.300 0.200 0.008 0.200 0.006 0.150 0.004 0.100 0.002 0.050 0.175 0.150 0.250 0.125 0.200 0.100 0.150 0.075 0.100 0.050 0.050 0.025 -0.000 180.88 180.89 180.90 180.91 204.86 M 242.9856 R 11261 230.9 1.00e0 x16 0.110 0.100 0.090 0.080 0.070 0.060 0.050 0.040 0.030 0.020 0.010 -0.000 242.83 242.84 242.85 242.86 242.87 204.87 204.88 204.89 218.85 218.86 218.87 218.88 230.84 230.85 230.86 230.87 Experiment Calibration Report 416 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 2 @ 200 (ppm) Printed: Friday, March 28, 2014 10:41:00 Eastern Daylight Time M 218.9856 R 12755 M 230.9856 R 11905 304.8 M 242.9856 R 11846 218.9 1.00e0 x16 M 254.9856 R 12193 230.9 1.00e0 x16 242.9 1.00e0 x16 1.00e0 x16 0.045 0.120 0.600 0.500 0.110 0.550 0.040 0.450 0.100 0.500 0.035 0.400 0.090 0.450 0.350 0.080 0.350 0.300 0.070 0.300 0.250 0.400 0.030 0.025 0.060 0.020 0.050 0.250 0.200 0.015 0.040 0.200 0.150 0.030 0.150 0.010 0.100 0.020 0.100 0.005 0.050 0.050 0.010 -0.000 218.88 218.89 218.90 -0.000 218.91 230.87 M 268.9824 R 11961 230.88 230.89 242.86 M 280.9824 R 11419 254.9 -0.000 230.90 242.87 x16 0.180 242.89 242.90 254.85 M 292.9824 R 11112 268.9 1.00e0 0.200 242.88 254.86 254.87 x16 292.8 1.00e0 x16 1.00e0 0.085 0.034 0.280 0.080 0.032 0.260 0.075 0.030 0.240 0.070 0.028 0.065 0.026 0.060 0.024 0.055 0.022 0.050 0.020 0.045 0.018 0.140 0.040 0.016 0.120 0.035 0.014 0.030 0.012 0.025 0.010 0.020 0.008 0.015 0.006 0.160 0.220 254.89 M 304.9824 R 12017 280.8 1.00e0 254.88 x16 0.200 0.140 0.180 0.120 0.160 0.100 0.080 0.100 0.060 0.080 0.060 0.040 0.040 0.010 0.004 0.020 0.020 -0.000 268.83 0.005 0.002 -0.000 268.84 268.85 268.86 268.87 268.88 280.83 280.84 280.85 280.86 280.87 -0.000 292.82 292.83 292.84 292.85 292.86 304.81 304.82 304.83 304.84 304.85 304.86 Experiment Calibration Report 417 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 3 @ 200 (ppm) Printed: Friday, March 28, 2014 10:41:28 Eastern Daylight Time M 242.9856 R 12498 M 254.9856 R 11960 342.8 M 268.9824 R 12255 242.9 1.00e0 x16 M 280.9824 R 11965 254.9 1.00e0 x16 268.9 1.00e0 x16 1.00e0 x16 0.320 0.130 0.045 0.200 0.300 0.120 0.280 0.040 0.180 0.035 0.160 0.110 0.260 0.100 0.240 0.220 0.090 0.140 0.030 0.200 0.080 0.120 0.180 0.025 0.070 0.160 0.100 0.060 0.140 0.020 0.050 0.080 0.120 0.015 0.040 0.100 0.060 0.080 0.030 0.010 0.040 0.060 0.020 0.040 0.005 0.020 0.010 0.020 -0.000 -0.000 242.87 242.88 242.89 242.90 -0.000 242.91 254.86 M 292.9824 R 12072 254.87 254.88 254.89 254.90 268.85 M 304.9824 R 12436 280.9 268.86 268.87 x16 268.89 280.84 M 316.9824 R 12372 292.9 1.00e0 268.88 280.86 x16 280.87 280.88 280.89 M 330.9792 R 11682 304.8 1.00e0 316.8 1.00e0 x16 1.00e0 0.018 0.150 0.090 0.017 0.140 0.085 0.016 0.095 280.85 x16 0.040 0.130 0.035 0.080 0.015 0.120 0.075 0.014 0.030 0.070 0.065 0.060 0.110 0.013 0.025 0.012 0.100 0.011 0.090 0.055 0.010 0.080 0.050 0.009 0.020 0.045 0.070 0.008 0.040 0.060 0.007 0.035 0.015 0.006 0.050 0.005 0.040 0.030 0.025 0.010 0.004 0.020 0.030 0.003 0.015 0.020 0.005 0.010 0.002 0.010 0.001 0.005 -0.000 -0.000 292.83 292.84 292.85 292.86 292.87 292.88 M 342.9792 R 11419 330.8 1.00e0 x16 0.055 0.050 0.045 0.040 0.035 0.030 0.025 0.020 0.015 0.010 0.005 -0.000 342.80 342.81 342.82 342.83 342.84 342.85 -0.000 304.82 304.83 304.84 304.85 304.86 304.87 -0.000 316.81 316.82 316.83 316.84 316.85 316.86 330.80 330.81 330.82 330.83 330.84 330.85 Experiment Calibration Report 418 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 4 @ 200 (ppm) Printed: Friday, March 28, 2014 10:42:07 Eastern Daylight Time M 280.9824 R 12688 M 292.9824 R 12822 430.8 M 304.9824 R 12689 280.9 1.00e0 x16 M 316.9824 R 12559 292.9 1.00e0 x16 304.9 1.00e0 x16 1.00e0 x16 0.340 0.016 0.320 0.100 0.040 0.015 0.300 0.090 0.280 0.014 0.035 0.013 0.260 0.080 0.012 0.240 0.030 0.011 0.070 0.220 0.010 0.200 0.025 0.060 0.009 0.180 0.160 0.008 0.050 0.020 0.007 0.140 0.040 0.120 0.006 0.015 0.100 0.005 0.030 0.080 0.004 0.010 0.020 0.060 0.003 0.040 0.002 0.005 0.010 0.020 0.001 -0.000 -0.000 280.85 280.86 280.87 280.88 280.89 -0.000 280.90 292.84 M 330.9792 R 12078 292.85 292.86 292.87 292.88 292.89 M 342.9792 R 12753 316.9 -0.000 304.83 304.84 304.85 304.86 x16 304.88 316.82 M 366.9792 R 12562 330.8 1.00e0 304.87 316.83 316.84 316.85 x16 316.87 316.88 M 380.9760 R 11361 342.8 1.00e0 316.86 366.8 1.00e0 x16 1.00e0 x16 0.095 0.180 0.075 0.015 0.090 0.170 0.070 0.065 0.150 0.140 0.060 0.130 0.055 0.085 0.014 0.160 0.080 0.013 0.075 0.012 0.070 0.120 0.011 0.050 0.065 0.010 0.060 0.045 0.009 0.055 0.040 0.008 0.035 0.007 0.070 0.030 0.006 0.060 0.025 0.005 0.030 0.020 0.004 0.025 0.015 0.003 0.010 0.002 0.005 0.001 0.110 0.100 0.090 0.050 0.045 0.080 0.040 0.050 0.035 0.040 0.020 0.030 0.015 0.020 0.010 0.010 -0.000 -0.000 330.81 330.82 330.83 330.84 330.85 330.86 M 392.9760 R 11905 0.005 -0.000 330.87 342.80 342.81 342.82 342.83 342.84 342.85 342.86 M 404.9760 R 12437 380.8 -0.000 366.78 366.79 366.80 366.81 x16 x16 366.85 1.00e0 x16 0.038 0.032 0.017 0.036 0.030 0.016 0.034 0.028 0.015 0.032 0.026 0.014 0.030 0.024 0.013 0.028 0.012 0.026 0.024 0.011 0.020 366.84 404.8 1.00e0 0.018 0.022 366.83 M 430.9728 R 12074 392.8 1.00e0 0.034 366.82 0.022 0.010 0.018 0.020 0.009 0.016 0.018 0.008 0.014 0.016 0.007 0.014 0.012 0.006 0.012 0.010 0.005 0.008 0.010 0.004 0.006 0.008 0.003 0.004 0.002 0.002 0.001 -0.000 392.77 392.78 392.79 392.80 392.81 392.82 392.83 -0.000 404.76 0.006 0.004 0.002 404.77 404.78 404.79 404.80 404.81 404.82 404.83 404.84 -0.000 430.75 430.76 430.77 430.78 430.79 430.80 430.81 430.82 430.83 380.77 380.78 380.79 380.80 380.81 380.82 380.83 380.84 Experiment Calibration Report 419 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 5 @ 200 (ppm) Printed: Friday, March 28, 2014 10:42:32 Eastern Daylight Time M 316.9824 R 11850 M 330.9792 R 12315 442.7 M 342.9792 R 12193 316.8 1.00e0 x16 M 366.9792 R 12504 330.8 1.00e0 x16 342.8 1.00e0 x16 1.00e0 x16 0.016 0.020 0.180 0.019 0.170 0.018 0.075 0.015 0.070 0.014 0.160 0.065 0.017 0.013 0.150 0.016 0.060 0.140 0.012 0.015 0.014 0.013 0.130 0.055 0.120 0.050 0.011 0.010 0.012 0.110 0.011 0.100 0.010 0.090 0.045 0.009 0.040 0.008 0.035 0.009 0.007 0.080 0.008 0.007 0.070 0.030 0.060 0.025 0.006 0.005 0.006 0.050 0.005 0.020 0.004 0.015 0.003 0.010 0.002 0.040 0.004 0.030 0.003 0.020 0.002 0.005 0.010 0.001 -0.000 -0.000 316.81 316.82 316.83 316.84 316.85 316.86 330.79 M 380.9760 R 11571 330.80 330.81 330.82 330.83 330.84 M 392.9760 R 11521 366.8 0.001 -0.000 342.78 330.85 342.79 342.80 342.81 x16 342.83 -0.000 366.76 342.84 M 404.9760 R 11576 380.8 1.00e0 342.82 366.77 366.78 366.79 366.80 x16 366.82 366.83 M 430.9728 R 11260 392.8 1.00e0 366.81 404.8 1.00e0 x16 1.00e0 x16 0.040 0.100 0.090 0.035 0.022 0.055 0.020 0.050 0.018 0.045 0.016 0.040 0.014 0.035 0.012 0.030 0.010 0.025 0.008 0.020 0.006 0.015 0.004 0.010 0.080 0.030 0.070 0.025 0.060 0.020 0.050 0.040 0.015 0.030 0.010 0.020 0.005 0.010 0.002 -0.000 -0.000 380.75 380.76 380.77 380.78 380.79 380.80 380.81 380.82 M 442.9728 R 11518 430.7 1.00e0 x16 0.022 0.020 0.018 0.016 0.014 0.012 0.010 0.008 0.006 0.004 0.002 -0.000 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 442.78 0.005 -0.000 392.74 392.75 392.76 392.77 392.78 392.79 392.80 392.81 -0.000 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 430.71 430.72 430.73 430.74 430.75 430.76 430.77 430.78 Experiment Calibration Report 420 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 6 @ 200 (ppm) Printed: Friday, March 28, 2014 10:42:53 Eastern Daylight Time M 380.9760 R 11958 M 392.9760 R 12077 480.7 M 404.9760 R 12374 380.8 1.00e0 x16 M 430.9728 R 12314 392.8 1.00e0 x16 404.7 1.00e0 x16 1.00e0 x16 0.026 0.120 0.060 0.024 0.110 0.040 0.055 0.022 0.100 0.035 0.020 0.050 0.018 0.045 0.016 0.040 0.014 0.035 0.012 0.030 0.010 0.025 0.008 0.020 0.006 0.015 0.004 0.010 0.090 0.030 0.080 0.070 0.025 0.060 0.020 0.050 0.015 0.040 0.030 0.010 0.020 0.005 0.010 0.005 0.002 -0.000 -0.000 380.73 380.74 380.75 380.76 380.77 380.78 380.79 380.80 -0.000 392.72 M 442.9728 R 12497 392.73 392.74 392.75 392.76 392.77 392.78 392.79 404.71 M 454.9728 R 12194 430.7 404.72 404.73 404.74 404.75 x16 404.77 430.69 430.70 430.71 430.72 x16 430.73 430.74 430.75 430.76 M 480.9696 R 11013 454.7 1.00e0 466.7 1.00e0 x16 0.011 0.032 -0.000 430.68 404.78 M 466.9728 R 13809 442.7 1.00e0 404.76 1.00e0 x16 0.038 0.020 0.036 0.010 0.030 0.034 0.018 0.028 0.032 0.009 0.026 0.030 0.016 0.008 0.024 0.028 0.026 0.014 0.022 0.007 0.024 0.020 0.012 0.022 0.006 0.018 0.020 0.016 0.010 0.018 0.005 0.014 0.016 0.008 0.004 0.012 0.014 0.012 0.010 0.006 0.003 0.010 0.008 0.006 0.008 0.004 0.002 0.002 0.001 0.006 0.004 0.004 0.002 0.002 -0.000 -0.000 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 442.75 -0.000 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 454.74 -0.000 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 466.73 480.64 480.65 480.66 480.67 480.68 480.69 480.70 480.71 480.72 Experiment Calibration Report 421 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 7 @ 200 (ppm) Printed: Friday, March 28, 2014 10:43:18 Eastern Daylight Time M 430.9728 R 12375 M 442.9728 R 12439 516.7 M 454.9728 R 12376 430.7 1.00e0 x16 M 466.9728 R 12378 442.7 1.00e0 x16 454.7 1.00e0 x16 0.030 1.00e0 0.024 0.012 0.022 0.011 0.020 0.010 0.018 0.009 0.016 0.008 0.014 0.007 0.012 0.006 0.012 0.010 0.005 0.010 0.008 0.004 0.006 0.003 0.004 0.002 0.070 x16 0.028 0.065 0.026 0.060 0.024 0.055 0.022 0.050 0.020 0.045 0.018 0.040 0.016 0.035 0.014 0.030 0.025 0.020 0.008 0.015 0.006 0.010 0.004 0.005 0.002 -0.000 0.002 -0.000 430.71 430.72 430.73 430.74 430.75 430.76 430.77 430.78 442.70 M 480.9696 R 11738 442.71 442.72 442.73 442.74 442.75 442.76 M 492.9696 R 11311 466.7 0.001 -0.000 454.68 442.77 -0.000 454.69 454.70 454.71 454.72 x16 454.74 454.75 454.76 454.77 M 504.9696 R 11959 480.7 1.00e0 454.73 466.67 466.68 466.69 466.70 466.71 x16 466.73 466.74 466.75 504.7 1.00e0 x16 1.00e0 x16 0.038 0.016 0.009 0.020 0.036 0.015 0.034 0.018 0.032 0.014 0.008 0.013 0.030 0.016 0.028 0.007 0.012 0.026 0.011 0.014 0.006 0.024 0.010 0.022 0.012 0.009 0.005 0.020 0.008 0.010 0.018 0.007 0.016 0.008 0.014 0.004 0.006 0.012 0.003 0.005 0.006 0.010 0.004 0.002 0.008 0.004 0.003 0.006 0.002 0.004 0.001 0.002 0.001 0.002 -0.000 -0.000 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 480.74 -0.000 492.65 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 492.74 -0.000 504.64 504.65 504.66 504.67 504.68 466.76 M 516.9697 R 12563 492.7 1.00e0 466.72 504.69 504.70 504.71 504.72 504.73 516.63 516.64 516.65 516.66 516.67 516.68 516.69 516.70 516.71 Experiment Calibration Report 422 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 1 @ 200 (ppm) Printed: Friday, March 28, 2014 15:24:32 Eastern Daylight Time M 180.9888 R 11844 M 204.9888 R 13086 242.9 M 218.9856 R 12135 180.9 1.00e0 x16 M 230.9856 R 11261 204.9 1.00e0 x16 218.9 1.00e0 x16 0.018 1.00e0 x16 0.360 0.425 0.650 0.017 0.340 0.400 0.016 0.600 0.320 0.375 0.015 0.300 0.550 0.350 0.014 0.280 0.325 0.500 0.013 0.260 0.300 0.012 0.450 0.240 0.275 0.011 0.220 0.400 0.250 0.010 0.350 0.180 0.200 0.008 0.300 0.200 0.225 0.009 0.160 0.175 0.007 0.140 0.250 0.200 0.150 0.006 0.150 0.005 0.125 0.004 0.100 0.080 0.003 0.075 0.060 0.002 0.050 0.001 0.025 0.120 0.100 0.100 0.050 -0.000 180.89 180.90 180.91 180.92 M 242.9856 R 11465 230.9 1.00e0 x16 0.080 0.075 0.070 0.065 0.060 0.055 0.050 0.045 0.040 0.035 0.030 0.025 0.020 0.015 0.010 0.005 -0.000 242.84 242.85 242.86 242.87 242.88 0.040 0.020 -0.000 204.88 204.89 204.90 204.91 -0.000 218.86 218.87 218.88 218.89 218.90 230.85 230.86 230.87 230.88 230.89 Experiment Calibration Report 423 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 2 @ 200 (ppm) Printed: Friday, March 28, 2014 15:24:47 Eastern Daylight Time M 218.9856 R 12691 M 230.9856 R 11793 304.8 M 242.9856 R 11365 218.9 1.00e0 x16 M 254.9856 R 11573 230.9 1.00e0 x16 242.9 1.00e0 x16 1.00e0 x16 0.380 0.450 0.032 0.080 0.360 0.425 0.340 0.030 0.075 0.400 0.320 0.028 0.070 0.375 0.300 0.026 0.065 0.350 0.280 0.024 0.060 0.325 0.260 0.300 0.022 0.055 0.240 0.050 0.020 0.200 0.045 0.018 0.180 0.040 0.016 0.160 0.035 0.014 0.030 0.012 0.025 0.010 0.020 0.008 0.015 0.006 0.275 0.220 0.250 0.225 0.200 0.175 0.140 0.150 0.120 0.125 0.100 0.100 0.080 0.075 0.060 0.050 0.040 0.025 0.020 0.004 0.010 0.002 0.005 -0.000 -0.000 218.89 218.90 218.91 218.92 230.88 M 268.9824 R 11363 230.89 230.90 242.87 M 280.9824 R 11310 254.9 -0.000 230.91 242.88 242.89 x16 242.91 254.86 M 292.9824 R 11212 268.9 1.00e0 242.90 254.87 254.88 x16 254.90 M 304.9824 R 11012 280.9 1.00e0 0.150 254.89 292.9 1.00e0 x16 1.00e0 0.060 0.024 0.055 0.022 0.050 0.020 0.045 0.018 0.040 0.016 0.035 0.014 0.030 0.012 0.025 0.010 0.020 0.008 0.015 0.006 0.010 0.004 x16 0.200 0.140 0.180 0.130 0.120 0.160 0.110 0.140 0.100 0.090 0.120 0.080 0.100 0.070 0.060 0.080 0.050 0.060 0.040 0.030 0.040 0.020 0.020 0.005 0.010 -0.000 -0.000 268.85 268.86 268.87 268.88 268.89 0.002 -0.000 280.84 280.85 280.86 280.87 280.88 -0.000 292.83 292.84 292.85 292.86 292.87 292.88 304.82 304.83 304.84 304.85 304.86 304.87 Experiment Calibration Report 424 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 3 @ 200 (ppm) Printed: Friday, March 28, 2014 15:25:05 Eastern Daylight Time M 242.9856 R 11964 M 254.9856 R 12135 342.8 M 268.9824 R 11849 242.9 1.00e0 x16 M 280.9824 R 11368 254.9 1.00e0 x16 0.032 268.9 1.00e0 x16 0.160 1.00e0 x16 0.220 0.090 0.030 0.150 0.028 0.140 0.026 0.130 0.070 0.024 0.120 0.065 0.022 0.110 0.020 0.100 0.018 0.090 0.016 0.080 0.014 0.070 0.035 0.012 0.060 0.030 0.010 0.050 0.008 0.040 0.006 0.030 0.004 0.020 0.002 0.010 0.085 0.200 0.080 0.075 0.180 0.160 0.060 0.140 0.055 0.120 0.050 0.045 0.040 0.100 0.080 0.060 0.025 0.020 0.040 0.015 0.010 0.020 0.005 -0.000 -0.000 242.88 242.89 242.90 242.91 -0.000 242.92 254.87 M 292.9824 R 12197 254.88 254.89 254.90 268.86 M 304.9824 R 11791 280.9 -0.000 254.91 268.87 x16 268.89 268.90 280.85 M 316.9824 R 12198 292.9 1.00e0 268.88 280.86 280.87 x16 280.89 280.90 M 330.9792 R 10965 304.9 1.00e0 280.88 316.9 1.00e0 x16 1.00e0 x16 0.014 0.070 0.110 0.028 0.013 0.065 0.026 0.100 0.012 0.060 0.024 0.055 0.022 0.050 0.020 0.045 0.018 0.040 0.016 0.035 0.014 0.030 0.012 0.025 0.010 0.020 0.008 0.015 0.006 0.003 0.010 0.004 0.002 0.005 0.002 0.001 0.090 0.011 0.010 0.080 0.009 0.070 0.008 0.060 0.007 0.050 0.006 0.005 0.040 0.004 0.030 0.020 0.010 -0.000 -0.000 292.84 292.85 292.86 292.87 292.88 292.89 M 342.9792 R 10826 330.8 1.00e0 x16 0.038 0.036 0.034 0.032 0.030 0.028 0.026 0.024 0.022 0.020 0.018 0.016 0.014 0.012 0.010 0.008 0.006 0.004 0.002 -0.000 342.81 342.82 342.83 342.84 342.85 342.86 342.87 -0.000 304.83 304.84 304.85 304.86 304.87 304.88 -0.000 316.82 316.83 316.84 316.85 316.86 316.87 316.88 330.81 330.82 330.83 330.84 330.85 330.86 330.87 Experiment Calibration Report 425 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 4 @ 200 (ppm) Printed: Friday, March 28, 2014 15:25:27 Eastern Daylight Time M 280.9824 R 11681 M 292.9824 R 11630 430.8 M 304.9824 R 12437 280.9 1.00e0 x16 M 316.9824 R 12074 292.9 1.00e0 x16 304.9 1.00e0 x16 0.034 0.070 0.240 1.00e0 x16 0.012 0.032 0.011 0.065 0.030 0.060 0.028 0.220 0.010 0.200 0.026 0.055 0.180 0.009 0.024 0.050 0.008 0.022 0.160 0.045 0.020 0.140 0.007 0.040 0.018 0.006 0.120 0.100 0.035 0.016 0.030 0.014 0.005 0.012 0.025 0.004 0.080 0.010 0.020 0.060 0.003 0.008 0.015 0.006 0.002 0.040 0.010 0.020 0.004 0.001 0.005 -0.000 0.002 -0.000 280.86 280.87 280.88 280.89 280.90 280.91 -0.000 292.85 M 330.9792 R 11793 292.86 292.87 292.88 292.89 304.85 M 342.9792 R 11904 316.9 -0.000 292.90 304.86 304.87 x16 304.89 304.90 M 366.9792 R 11962 330.9 1.00e0 316.84 316.85 316.86 x16 316.87 316.88 316.89 M 380.9760 R 11159 342.8 1.00e0 366.8 1.00e0 x16 1.00e0 x16 0.070 0.011 0.050 0.130 304.88 0.065 0.120 0.010 0.045 0.060 0.110 0.009 0.040 0.055 0.100 0.008 0.050 0.035 0.090 0.045 0.007 0.080 0.030 0.040 0.006 0.070 0.035 0.025 0.060 0.005 0.030 0.020 0.050 0.004 0.040 0.025 0.015 0.020 0.003 0.030 0.015 0.010 0.002 0.020 0.010 0.005 0.001 0.010 -0.000 -0.000 330.82 330.83 330.84 330.85 330.86 330.87 342.82 M 392.9760 R 12751 0.005 -0.000 330.88 342.83 342.84 342.85 342.86 366.80 M 404.9760 R 12562 380.8 -0.000 342.87 366.81 366.82 x16 366.84 366.85 366.86 404.8 1.00e0 x16 1.00e0 x16 0.014 0.028 0.022 0.013 0.026 0.020 0.012 0.024 0.011 0.018 0.022 0.010 0.020 0.016 0.009 0.018 0.014 0.008 0.012 0.016 0.007 0.010 0.014 0.006 0.012 0.005 0.008 0.010 0.004 0.008 0.003 0.006 0.002 0.004 0.006 0.004 0.002 0.001 -0.000 0.002 -0.000 392.78 392.79 392.80 392.81 392.82 392.83 392.84 392.85 -0.000 404.78 404.79 404.80 404.81 404.82 380.79 M 430.9728 R 10731 392.8 1.00e0 366.83 404.83 404.84 404.85 430.77 430.78 430.79 430.80 430.81 430.82 430.83 430.84 430.85 380.80 380.81 380.82 380.83 380.84 380.85 Experiment Calibration Report 426 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 5 @ 200 (ppm) Printed: Friday, March 28, 2014 15:25:52 Eastern Daylight Time M 316.9824 R 11625 M 330.9792 R 11262 442.8 M 342.9792 R 11903 316.8 1.00e0 x16 M 366.9792 R 11110 330.8 1.00e0 x16 342.8 1.00e0 x16 1.00e0 x16 0.130 0.014 0.050 0.120 0.010 0.013 0.045 0.110 0.012 0.011 0.100 0.010 0.090 0.009 0.080 0.009 0.040 0.008 0.035 0.007 0.030 0.008 0.006 0.070 0.007 0.025 0.060 0.005 0.006 0.050 0.020 0.004 0.005 0.040 0.004 0.015 0.003 0.010 0.002 0.030 0.003 0.020 0.002 0.005 0.010 0.001 -0.000 -0.000 316.82 316.83 316.84 316.85 316.86 330.81 M 380.9760 R 11361 0.001 -0.000 316.87 330.82 330.83 330.84 330.85 342.80 M 392.9760 R 12136 366.8 -0.000 330.86 342.81 342.82 x16 342.84 342.85 342.86 M 404.9760 R 12022 380.8 1.00e0 342.83 366.78 366.79 366.80 x16 366.82 366.83 366.84 M 430.9728 R 11013 392.8 1.00e0 366.81 404.8 1.00e0 x16 0.030 1.00e0 x16 0.040 0.075 0.016 0.038 0.028 0.070 0.015 0.036 0.014 0.034 0.026 0.065 0.024 0.032 0.013 0.060 0.030 0.022 0.012 0.020 0.011 0.018 0.010 0.024 0.016 0.009 0.022 0.055 0.028 0.050 0.026 0.045 0.040 0.020 0.008 0.014 0.035 0.018 0.007 0.012 0.030 0.016 0.006 0.014 0.010 0.025 0.020 0.008 0.015 0.006 0.010 0.004 0.005 0.002 0.005 0.012 0.004 0.010 0.008 0.003 0.006 0.002 0.004 -0.000 0.001 -0.000 380.77 380.78 380.79 380.80 380.81 380.82 380.83 M 442.9728 R 11015 430.8 1.00e0 x16 0.019 0.018 0.017 0.016 0.015 0.014 0.013 0.012 0.011 0.010 0.009 0.008 0.007 0.006 0.005 0.004 0.003 0.002 0.001 -0.000 442.72 442.73 442.74 442.75 442.76 442.77 442.78 442.79 442.80 0.002 -0.000 392.76 392.77 392.78 392.79 392.80 392.81 392.82 -0.000 404.75 404.76 404.77 404.78 404.79 404.80 404.81 404.82 430.72 430.73 430.74 430.75 430.76 430.77 430.78 430.79 430.80 Experiment Calibration Report 427 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 6 @ 200 (ppm) Printed: Friday, March 28, 2014 15:26:09 Eastern Daylight Time M 380.9760 R 11684 M 392.9760 R 11211 480.7 M 404.9760 R 11466 380.8 1.00e0 x16 M 430.9728 R 11012 392.8 1.00e0 x16 404.8 1.00e0 x16 1.00e0 x16 0.080 0.030 0.020 0.040 0.075 0.028 0.070 0.018 0.026 0.035 0.065 0.024 0.016 0.060 0.030 0.022 0.055 0.014 0.020 0.050 0.025 0.018 0.012 0.045 0.016 0.040 0.010 0.020 0.014 0.035 0.012 0.030 0.008 0.015 0.010 0.025 0.006 0.008 0.020 0.010 0.015 0.006 0.010 0.004 0.004 0.005 0.002 0.002 0.005 -0.000 -0.000 380.75 380.76 380.77 380.78 380.79 380.80 380.81 -0.000 380.82 M 442.9728 R 12017 392.74 392.75 392.76 392.77 392.78 392.79 392.80 404.73 M 454.9728 R 11844 430.7 -0.000 392.81 404.74 404.75 404.76 x16 404.78 404.79 404.80 430.71 M 466.9728 R 11960 442.7 1.00e0 404.77 430.72 430.73 430.74 x16 430.76 430.77 430.78 M 480.9696 R 11364 454.7 1.00e0 430.75 466.7 1.00e0 x16 1.00e0 x16 0.028 0.014 0.020 0.007 0.013 0.018 0.026 0.024 0.012 0.006 0.022 0.011 0.016 0.020 0.010 0.014 0.005 0.018 0.009 0.012 0.016 0.008 0.004 0.014 0.007 0.010 0.012 0.006 0.003 0.008 0.010 0.005 0.006 0.004 0.008 0.002 0.006 0.003 0.004 0.002 0.004 0.001 0.002 0.001 -0.000 442.69 0.002 -0.000 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 -0.000 454.68 454.69 454.70 454.71 454.72 454.73 454.74 454.75 454.76 -0.000 466.67 466.68 466.69 466.70 466.71 466.72 466.73 466.74 466.75 466.76 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 480.74 Experiment Calibration Report 428 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 7 @ 200 (ppm) Printed: Friday, March 28, 2014 15:26:30 Eastern Daylight Time M 430.9728 R 11682 M 442.9728 R 12134 516.7 M 454.9728 R 11468 430.8 1.00e0 x16 M 466.9728 R 12135 442.8 1.00e0 x16 454.7 1.00e0 x16 1.00e0 x16 0.016 0.022 0.015 0.050 0.008 0.020 0.014 0.045 0.018 0.013 0.007 0.012 0.040 0.016 0.011 0.006 0.035 0.014 0.030 0.010 0.005 0.009 0.012 0.008 0.025 0.010 0.020 0.004 0.007 0.006 0.008 0.003 0.005 0.015 0.006 0.004 0.002 0.010 0.004 0.005 0.002 0.003 0.002 0.001 0.001 -0.000 -0.000 430.73 430.74 430.75 430.76 430.77 430.78 430.79 -0.000 430.80 442.72 M 480.9696 R 11060 442.73 442.74 442.75 442.76 442.77 442.78 454.71 M 492.9696 R 11574 466.7 -0.000 442.79 454.72 454.73 454.74 x16 0.014 0.026 0.013 0.024 0.012 0.022 0.011 0.020 0.010 0.018 0.009 0.016 0.008 0.014 0.007 0.012 0.006 0.010 0.005 0.008 0.004 0.006 0.003 454.77 454.78 454.79 466.70 466.71 466.72 466.73 x16 466.74 466.75 466.76 466.77 466.78 M 516.9697 R 11416 492.7 1.00e0 0.028 454.76 M 504.9696 R 12134 480.7 1.00e0 454.75 504.7 1.00e0 x16 1.00e0 x16 0.011 0.006 0.010 0.009 0.005 0.008 0.007 0.004 0.006 0.003 0.005 0.004 0.002 0.003 0.002 0.004 0.002 0.002 0.001 0.001 0.001 -0.000 -0.000 480.68 480.69 480.70 480.71 480.72 480.73 480.74 480.75 480.76 480.77 -0.000 492.67 492.68 492.69 492.70 492.71 492.72 492.73 492.74 492.75 492.76 -0.000 504.66 504.67 504.68 504.69 504.70 504.71 504.72 504.73 504.74 504.75 516.65 516.66 516.67 516.68 516.69 516.70 516.71 516.72 516.73 516.74 PCB ICAL PAGE RANGE: 429 TO 683 PCB ICAL Summary 429 of 711 Printed: 3 Jan 2014 16:53 SGS Analytical Perspectives ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 Date Processed: 3 Jan 2014 16:52 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB Mean 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 % RSD 4.1% 3.1% 5.1% 4.8% 4.2% 2.4% 5.8% 4.0% 4.0% 3.5% 5.0% 3.9% 131220X02 0.5 CS0 1.17 1.08 1.13 1.14 1.20 1.20 1.05 1.07 1.11 1.12 1.08 1.18 131220X03 1 CS1 1.11 1.13 1.02 1.16 1.13 1.20 1.07 1.07 1.13 1.07 1.00 1.10 131220X04 5 CS2 1.09 1.08 1.07 1.15 1.13 1.16 1.05 1.05 1.12 1.09 1.03 1.06 131220X05 50 CS3 1.14 1.12 1.13 1.23 1.22 1.23 1.12 1.12 1.20 1.16 1.07 1.09 131220X06 400 CS4 1.17 1.14 1.15 1.24 1.22 1.23 1.14 1.11 1.18 1.14 1.10 1.10 131220X08 2000 CS5 1.22 1.17 1.18 1.29 1.25 1.25 1.21 1.17 1.23 1.17 1.16 1.15 3.7% 2.3% 0.7% 1.1% 1.4% 1.8% 1.0% 1.8% 2.5% 1.7% 2.5% 2.3% 2.4% 1.2% 3.2% 1.4% 3.0% 2.0% 2.0% 2.3% 1.9% 3.6% 1.9% 1.1% 1.2% 0.9% 1.4% 1.25 1.12 0.52 1.04 0.50 1.69 0.86 1.38 1.37 0.82 1.22 1.24 1.19 1.19 1.07 1.14 1.66 1.60 1.68 1.54 0.92 1.11 0.97 1.61 0.96 1.24 0.83 1.22 1.09 0.52 1.04 0.50 1.64 0.86 1.37 1.35 0.80 1.21 1.22 1.17 1.20 1.02 1.11 1.60 1.57 1.65 1.53 0.93 1.10 0.93 1.57 0.96 1.23 0.82 1.21 1.10 0.53 1.05 0.51 1.68 0.88 1.42 1.36 0.82 1.25 1.26 1.19 1.20 1.07 1.13 1.63 1.63 1.71 1.58 0.96 1.13 0.96 1.60 0.99 1.26 0.85 1.18 1.06 0.52 1.02 0.50 1.61 0.85 1.34 1.32 0.80 1.18 1.19 1.13 1.16 0.99 1.10 1.56 1.56 1.62 1.51 0.95 1.11 0.92 1.57 0.97 1.24 0.83 1.17 1.08 0.52 1.05 0.51 1.66 0.86 1.38 1.38 0.79 1.18 1.21 1.14 1.19 1.01 1.11 1.56 1.64 1.70 1.60 0.95 1.16 0.93 1.57 0.97 1.25 0.83 1.13 1.06 0.53 1.05 0.52 1.69 0.85 1.40 1.42 0.78 1.17 1.19 1.14 1.18 1.01 1.10 1.52 1.61 1.65 1.58 0.97 1.21 0.93 1.58 0.97 1.25 0.82 PCB ICAL PAGE RANGE: 429 TO 683 PCB ICAL Summary 430 of 711 Printed: 3 Jan 2014 16:53 SGS Analytical Perspectives ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 131220X03 1 CS1 1.16 1.10 131220X04 5 CS2 1.20 1.14 131220X05 50 CS3 1.17 1.11 131220X06 400 CS4 1.18 1.11 131220X08 2000 CS5 1.19 1.08 Name ES PCB-208 ES PCB-209 Mean 1.17 1.11 % RSD 1.4% 1.9% 131220X02 0.5 CS0 1.16 1.12 SS PCB-28 SS PCB-111 SS PCB-178 1.11 1.03 0.62 1.2% 1.6% 2.7% 1.12 1.04 0.64 1.12 1.02 0.61 1.11 1.03 0.61 1.12 1.05 0.61 1.11 1.00 0.61 1.09 1.03 0.64 CS PCB-28 CS PCB-111 CS PCB-178 1.85 1.22 0.58 1.4% 1.4% 3.7% 1.89 1.24 0.62 1.84 1.22 0.57 1.86 1.23 0.58 1.81 1.22 0.56 1.84 1.19 0.57 1.83 1.21 0.60 PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-153/168 ...-HxCB PCB-155 22'44'66'-HxCB PCB-170 22'33'44'5-HpCB PCB-180/193 ...-HpCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.46 1.26 1.14 1.26 1.27 1.05 1.06 1.12 1.11 3.4% 2.9% 3.8% 3.8% 2.5% 4.7% 2.1% 1.5% 3.7% 2.3% 6.1% 2.7% 3.1% 3.2% 4.0% 3.8% 3.0% 0.99 1.00 1.17 1.01 1.13 1.02 1.40 1.44 1.38 1.23 1.09 1.26 1.23 1.05 1.07 1.09 1.09 0.94 0.98 1.20 0.98 1.12 1.05 1.34 1.41 1.42 1.25 1.06 1.22 1.32 1.05 1.03 1.11 1.11 0.92 0.98 1.20 0.98 1.12 1.05 1.31 1.40 1.43 1.23 1.09 1.23 1.22 1.00 1.01 1.07 1.08 0.97 1.04 1.27 1.03 1.17 1.10 1.36 1.45 1.48 1.27 1.15 1.27 1.26 1.06 1.06 1.13 1.11 0.98 1.05 1.27 1.04 1.16 1.10 1.35 1.45 1.50 1.29 1.19 1.27 1.28 1.06 1.07 1.14 1.12 0.91 1.00 1.29 1.08 1.19 1.16 1.36 1.46 1.53 1.29 1.24 1.31 1.31 1.10 1.13 1.19 1.18 431 of 711 PCB ICAL Summary - Ax2 Detail SGS Analytical Perspectives Printed: 3 Jan 2014 16:53 ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB Mean 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 % RSD 3.4% 3.8% 2.9% 3.8% 3.9% 2.8% 5.7% 4.5% 4.8% 3.2% 3.9% 4.5% 6.8% 3.8% 2.5% 3.5% 4.4% 3.6% 3.4% 4.3% 2.4% 3.0% 4.1% 3.0% 2.6% 3.3% 3.6% 3.3% 2.8% 4.4% 4.1% 3.7% 4.6% 4.7% 2.1% 2.7% 5.4% 5.9% 2.5% 1.7% 0.5 CS0 0.99 1.02 1.00 1.17 1.91 0.93 0.95 0.97 1.03 1.07 1.14 0.98 0.88 1.01 1.13 1.49 1.23 1.77 1.67 0.99 1.90 1.11 1.20 1.15 1.13 1.25 1.13 1.15 1.08 1.13 1.18 1.07 1.01 1.02 1.40 0.89 0.78 0.80 0.70 0.85 1 CS1 0.94 1.01 0.98 1.20 1.90 0.95 1.03 0.94 0.92 0.99 1.14 0.95 0.96 0.98 1.12 1.47 1.28 1.76 1.69 0.94 1.91 1.09 1.09 1.14 1.14 1.16 1.08 1.14 1.05 1.12 1.16 1.08 0.98 1.05 1.34 0.85 0.76 0.82 0.68 0.83 5 CS2 0.92 0.98 0.98 1.20 1.93 0.90 1.02 0.96 0.96 1.00 1.15 0.99 0.97 0.98 1.12 1.51 1.27 1.77 1.67 1.00 1.85 1.11 1.10 1.13 1.13 1.19 1.08 1.13 1.04 1.13 1.16 1.06 1.00 1.05 1.31 0.84 0.70 0.89 0.68 0.82 50 CS3 0.97 1.08 1.04 1.27 2.05 0.96 1.09 1.03 1.02 1.04 1.20 1.03 1.02 1.03 1.17 1.57 1.33 1.83 1.74 1.00 1.93 1.15 1.18 1.20 1.18 1.26 1.17 1.21 1.09 1.19 1.24 1.14 1.08 1.10 1.36 0.90 0.74 0.93 0.72 0.86 400 CS4 0.98 1.08 1.05 1.27 2.04 0.96 1.08 1.03 1.02 1.03 1.21 1.04 1.03 1.04 1.16 1.59 1.34 1.87 1.73 1.05 1.93 1.18 1.19 1.21 1.18 1.24 1.17 1.21 1.10 1.21 1.25 1.16 1.07 1.10 1.35 0.89 0.78 0.88 0.71 0.85 2000 CS5 0.91 1.02 1.00 1.29 2.06 0.97 1.11 1.05 1.05 1.07 1.25 1.07 1.07 1.08 1.19 1.60 1.38 1.92 1.83 1.06 1.99 1.16 1.17 1.21 1.18 1.25 1.17 1.21 1.12 1.24 1.27 1.11 1.10 1.16 1.36 0.89 0.83 0.84 0.71 0.85 432 of 711 PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB 1.11 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 1.16 4.0% 4.5% 3.4% 3.5% 3.3% 3.7% 2.8% 4.3% 3.9% 3.9% 2.1% 2.7% 2.6% 2.9% 1.9% 3.1% 2.4% 3.3% 2.3% 2.9% 1.8% 2.3% 2.5% 4.2% 1.5% 4.7% 2.7% 3.3% 3.9% 3.5% 6.3% 8.5% 11.9% 10.7% 4.5% 3.8% 3.2% 2.3% 2.4% 4.0% 6.0% 3.9% 3.2% 6.9% 6.2% 6.3% 4.4% 1.13 0.68 0.99 0.83 0.89 1.13 0.76 0.68 0.84 1.17 1.19 1.26 1.18 1.17 1.23 1.30 1.20 1.06 1.09 1.13 1.13 1.30 1.26 1.04 1.44 1.12 0.91 0.79 0.89 0.84 0.97 0.73 0.96 0.76 0.71 0.73 1.18 0.82 0.98 0.77 0.88 1.12 0.98 1.02 1.02 1.09 1.18 1.06 0.68 0.98 0.79 0.88 1.13 0.73 0.66 0.82 1.18 1.18 1.24 1.11 1.13 1.25 1.26 1.16 1.06 1.10 1.05 1.12 1.29 1.33 0.99 1.41 1.24 0.91 0.76 0.80 0.83 0.93 0.68 0.72 0.95 0.66 0.74 1.15 0.81 0.96 0.70 0.88 1.12 0.94 1.15 0.87 1.07 1.11 1.06 0.72 0.99 0.83 0.86 1.13 0.75 0.69 0.83 1.18 1.19 1.24 1.16 1.15 1.23 1.24 1.16 1.09 1.12 1.10 1.11 1.28 1.28 1.04 1.40 1.20 0.91 0.79 0.85 0.85 0.99 0.71 0.73 0.94 0.70 0.75 1.16 0.79 0.96 0.71 0.88 1.16 0.95 1.15 0.88 1.06 1.16 1.12 0.77 1.05 0.87 0.93 1.21 0.79 0.73 0.87 1.27 1.25 1.31 1.20 1.20 1.29 1.33 1.23 1.14 1.14 1.13 1.15 1.35 1.31 1.10 1.45 1.26 0.96 0.83 0.89 0.88 1.03 0.80 0.74 1.04 0.75 0.80 1.23 0.84 1.00 0.72 0.91 1.24 1.01 1.17 0.94 1.25 1.10 1.12 0.72 1.05 0.85 0.93 1.22 0.77 0.68 0.90 1.25 1.22 1.31 1.16 1.19 1.27 1.32 1.22 1.14 1.12 1.12 1.14 1.32 1.35 1.08 1.45 1.28 0.95 0.81 0.87 0.90 0.87 0.86 0.85 0.95 0.73 0.78 1.23 0.83 1.01 0.70 0.98 1.17 1.02 1.09 0.99 1.11 1.16 1.17 0.70 1.06 0.87 0.93 1.18 0.78 0.73 0.89 1.28 1.23 1.30 1.17 1.23 1.28 1.34 1.21 1.13 1.15 1.13 1.16 1.34 1.32 1.11 1.46 1.27 0.95 0.82 0.89 0.89 1.02 0.77 0.78 1.03 0.74 0.79 1.24 0.84 1.01 0.69 1.00 1.18 0.97 1.25 0.95 1.13 1.24 433 of 711 PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 3.4% 2.9% 4.3% 4.7% 8.6% 3.3% 4.1% 5.5% 2.3% 4.1% 3.7% 6.5% 3.0% 4.0% 2.4% 3.1% 3.1% 3.5% 4.3% 3.3% 3.3% 2.7% 4.9% 2.0% 2.8% 1.5% 3.4% 3.6% 3.7% 2.5% 1.8% 5.1% 5.4% 4.0% 2.3% 2.4% 5.7% 3.3% 5.3% 3.1% 1.6% 2.7% 1.7% 1.5% 3.8% 4.2% 4.0% 0.69 1.23 1.18 1.07 1.26 1.12 0.97 1.09 1.23 1.16 1.18 1.01 1.13 1.14 1.11 1.38 1.22 1.12 0.97 1.07 1.20 1.02 0.96 1.03 1.13 1.41 1.19 1.50 1.38 1.10 0.97 1.19 1.35 1.18 1.49 1.69 0.86 1.09 1.03 1.23 1.19 1.14 1.21 1.14 0.88 1.02 1.08 0.67 1.17 1.14 1.03 1.05 1.08 0.96 1.04 1.25 1.12 1.10 0.98 1.09 1.14 1.13 1.29 1.12 1.15 0.90 1.10 1.16 1.02 0.92 1.01 1.11 1.39 1.16 1.44 1.42 1.05 0.95 1.14 1.48 1.15 1.48 1.64 0.86 1.11 1.01 1.32 1.16 1.09 1.22 1.11 0.80 1.05 1.12 0.67 1.19 1.18 1.07 1.26 1.04 0.95 1.03 1.23 1.13 1.15 1.04 1.06 1.16 1.12 1.30 1.17 1.16 0.88 1.14 1.17 0.98 0.97 1.01 1.09 1.40 1.17 1.50 1.43 1.07 0.96 1.10 1.52 1.14 1.49 1.62 0.85 1.07 1.03 1.22 1.13 1.10 1.22 1.10 0.82 1.05 1.11 0.70 1.25 1.24 1.14 1.33 1.12 1.01 1.11 1.27 1.16 1.20 1.09 1.12 1.19 1.14 1.33 1.19 1.18 0.89 1.18 1.20 1.03 1.01 1.03 1.13 1.42 1.19 1.54 1.48 1.10 0.97 1.10 1.58 1.17 1.55 1.63 0.91 1.13 1.11 1.26 1.17 1.13 1.25 1.14 0.84 1.08 1.15 0.72 1.23 1.25 1.12 1.26 1.13 1.02 1.12 1.29 1.23 1.21 1.12 1.14 1.23 1.16 1.37 1.20 1.21 0.96 1.12 1.24 1.04 1.03 1.03 1.16 1.39 1.24 1.55 1.50 1.10 0.98 1.22 1.51 1.23 1.56 1.67 0.93 1.12 1.10 1.28 1.16 1.13 1.24 1.12 0.84 1.10 1.17 0.73 1.26 1.28 1.17 1.36 1.14 1.06 1.19 1.29 1.23 1.22 1.16 1.16 1.25 1.18 1.38 1.20 1.23 0.94 1.16 1.27 1.06 1.06 1.06 1.17 1.44 1.26 1.60 1.53 1.12 1.00 1.24 1.55 1.27 1.52 1.72 0.98 1.17 1.15 1.31 1.15 1.17 1.26 1.14 0.88 1.15 1.21 434 of 711 PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 4.7% 3.5% 9.3% 4.3% 2.6% 4.9% 5.3% 3.7% 5.1% 2.7% 2.6% 6.1% 5.4% 3.2% 3.2% 2.5% 5.1% 5.6% 3.2% 2.8% 2.5% 4.3% 3.5% 4.0% 3.8% 3.1% 3.0% 1.09 1.16 0.95 0.93 0.93 1.03 0.90 0.96 1.17 1.26 1.41 1.09 1.63 1.05 1.16 1.10 1.26 1.03 0.80 0.84 0.87 0.79 0.88 1.07 1.09 1.20 1.09 1.14 1.18 1.03 1.04 0.94 1.07 0.90 0.97 1.27 1.22 1.40 1.06 1.58 1.05 1.22 1.13 1.16 1.04 0.79 0.80 0.85 0.74 0.82 1.03 1.11 1.16 1.11 1.16 1.21 0.99 0.96 0.93 1.04 0.92 0.95 1.28 1.23 1.33 1.09 1.58 1.00 1.19 1.08 1.11 1.12 0.78 0.82 0.85 0.73 0.81 1.01 1.07 1.14 1.08 1.22 1.28 1.03 1.00 0.95 1.11 0.97 1.02 1.32 1.27 1.40 1.15 1.66 1.06 1.24 1.12 1.15 1.16 0.80 0.84 0.88 0.75 0.84 1.06 1.13 1.20 1.11 1.21 1.18 1.15 0.98 0.96 1.12 0.98 1.00 1.32 1.27 1.40 1.19 1.69 1.06 1.27 1.12 1.21 1.12 0.82 0.84 0.88 0.77 0.85 1.07 1.14 1.20 1.12 1.23 1.22 1.21 1.03 0.99 1.17 1.03 1.04 1.36 1.31 1.44 1.24 1.82 1.10 1.24 1.16 1.26 1.17 0.86 0.87 0.91 0.82 0.88 1.13 1.19 1.24 1.18 1668A/B ICALs Air Historica Data Ax RSD Mean sd 77 10.6 1.04 0.11 1.11 1.13 1.34 81 9.6 1.08 0.10 1.13 1.13 1.13 105 4.6 0.96 0.04 1.11 1.09 1.15 1.11 2.1 1.11 0.02 114 4.9 0.96 0.05 1.18 1.16 1.22 1.2 2.1 1.19 0.02 118 6.8 0.95 0.06 1.11 1.11 1.17 1.19 3.7 1.15 0.04 123 3.9 0.97 0.04 1.08 1.19 1.27 1.21 6.5 1.19 0.08 126 8.6 1.00 0.09 1.07 1.06 1.12 1.11 2.9 1.09 0.03 156/157 6.4 0.99 0.06 1.09 1.11 1.18 1.1 3.7 1.12 0.04 167 5.8 0.98 0.06 1.14 1.14 1.23 1.16 3.8 1.17 0.04 169 4.5 0.97 0.04 1.09 1.11 1.19 1.12 3.7 1.13 0.04 189 14.7 0.95 0.14 1.07 1.06 1.09 1.07 1.3 1.07 0.01 1 9.3 1.16 0.11 1.02 1.03 0.93 0.95 5.1 0.98 0.05 3 9.5 1.16 0.11 0.98 1.04 0.97 1.01 3.4 1.00 0.03 435 of 711 MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd 1.15 8.8 1.18 0.10 1.12 0.4 1.13 0.00 4 4.7 1.03 0.05 1.11 1.17 1.13 1.23 4.5 1.16 0.05 15 11.8 1.02 0.12 0.99 1.08 1.05 1.02 3.9 1.03 0.04 19 4.7 1.04 0.05 1.10 1.09 1.10 1.15 2.3 1.11 0.03 37 12.1 1.06 0.13 1.00 1.10 1.05 1.08 4.2 1.06 0.04 54 104 4.3 1.06 0.05 1.18 1.21 1.24 1.35 6.0 1.25 0.07 5.4 1.01 0.05 1.11 1.25 1.31 1.43 10.2 1.28 0.13 1.19 1.22 1.38 1.46 9.8 1.31 0.13 1.08 1.09 1.22 1.26 7.8 1.16 0.09 170 1.06 1.07 1.11 1.14 3.3 1.09 0.04 180 188 1.08 1.16 1.21 1.26 6.6 1.18 0.08 4.2 1.02 0.04 1.03 1.03 1.01 1.27 11.4 1.09 0.12 202 3.0 0.91 0.03 0.93 0.91 0.97 1.05 6.4 0.97 0.06 205 5.4 0.96 0.05 1.07 1.09 1.11 1.06 1.8 1.08 0.02 208 2.3 0.93 0.02 1.02 1.02 1.07 1.12 4.7 1.06 0.05 206 3.2 0.97 0.03 0.99 0.98 0.92 1.11 7.9 1.00 0.08 209 7.0 0.95 0.07 1.07 1.07 1.13 1.11 2.6 1.10 0.03 1 6.7 1.01 0.07 1.08 1.08 1.20 1.19 6.0 1.14 0.07 3 5.5 1.02 0.06 1.14 1.08 1.14 1.09 2.7 1.11 0.03 153 155 3.2 1.02 0.03 PD from Mean -4.3% 0.1% -1.9% -2.4% -3.4% 0.2% -2.6% -1.2% -2.8% -1.5% -1.4% 4.9% 4.4% 0.8% 4.5% -1.7% 4.3% -3.0% -1.7% -7.0% -6.2% -1.9% -1.6% -4.8% -5.3% 0.6% -3.8% -2.2% -2.1% ES 4 10.0 0.69 0.07 0.50 0.49 0.57 0.52 6.8 0.52 0.04 15 4.2 1.06 0.04 1.18 1.11 1.07 1.04 5.5 1.10 0.06 19 6.3 0.62 0.04 0.53 0.55 0.57 0.51 4.8 0.54 0.03 37 10.4 1.36 0.14 1.64 1.64 1.55 1.66 2.9 1.62 0.05 54 7.3 1.18 0.09 0.87 0.94 0.86 0.86 4.4 0.88 0.04 77 11.1 1.23 0.14 1.26 1.35 1.11 1.38 9.6 1.27 0.12 81 9.4 1.19 0.11 1.20 1.29 1.26 1.37 5.6 1.28 0.07 104 8.0 1.33 0.11 1.08 0.99 0.89 0.8 13.2 0.94 0.12 105 4.1 1.27 0.05 1.22 1.23 1.23 1.2 1.2 1.22 0.02 114 4.2 1.31 0.05 1.24 1.25 1.24 1.22 1.0 1.24 0.01 118 5.3 1.31 0.07 1.28 1.28 1.26 1.16 4.6 1.24 0.06 123 3.9 1.24 0.05 1.35 1.22 1.21 1.19 5.9 1.24 0.07 126 6.7 1.30 0.09 1.22 1.20 1.09 1.03 7.9 1.14 0.09 1.10 1.14 1.15 1.11 2.1 1.13 0.02 153 155 7.0 1.42 0.10 1.41 1.50 1.56 1.59 5.1 1.51 0.08 156/157 7.7 1.22 0.09 1.41 1.45 1.59 1.6 6.4 1.51 0.10 167 7.6 1.25 0.09 1.43 1.49 1.68 1.67 8.1 1.57 0.13 169 8.1 1.23 0.10 1.37 1.40 1.42 1.56 5.8 1.44 0.08 170 1.04 1.00 0.93 0.95 5.1 0.98 0.05 180 1.28 1.16 1.12 1.14 6.3 1.17 0.07 188 8.5 1.27 0.11 1.12 1.18 1.23 0.94 11.4 1.12 0.13 189 7.8 1.52 0.12 1.53 1.49 1.46 1.58 3.5 1.51 0.05 202 6.6 1.18 0.08 1.07 1.14 1.10 0.97 6.7 1.07 0.07 205 3.9 1.27 0.05 1.26 1.20 1.22 1.24 2.0 1.23 0.02 206 11.3 0.97 0.11 0.90 0.87 0.95 0.83 5.9 0.89 0.05 208 10.2 1.27 0.13 1.22 1.19 1.19 1.17 1.7 1.19 0.02 MM7 Comparing ICAL RRFs 20DEC2013.xlsx -5.0% -2.7% -6.0% 0.8% 2.3% 0.8% 6.5% 5.7% 0.7% 5.6% 1.1% 0.7% 3.0% -2.0% 5.6% 1.3% -1.2% -3.9% -4.6% -2.4% 2.1% -1.3% 5.3% -1.8% 6.4% -2.2% -2.1% -0.2% 1668A/B ICALs Air Historica Data Ax RSD Mean sd 209 8.3 1.20 0.10 436 of 711 MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 1.06 1.00 1.12 1.11 PD from Mean RSD Mean sd 5.1 1.07 0.06 -6.8% 0.8% 0.2% 3.1% SS 28 3.6 1.05 0.04 0.98 1.07 1.10 1.11 5.6 1.07 0.06 111 4.0 1.05 0.04 0.90 1.01 1.08 1.03 7.5 1.00 0.07 178 3.9 0.71 0.03 0.62 0.63 0.57 0.62 4.4 0.61 0.03 Additional Ax RSD Mean sd PCB-1 2-MoCB 1.02 1.03 0.93 0.95 5.1 0.98 0.05 PCB-2 3-MoCB 0.97 1.04 0.97 1.03 3.7 1.00 0.04 PCB-3 4-MoCB 0.98 1.04 0.97 1.01 3.4 1.00 0.03 PCB-4 22'-DiCB 1.11 1.17 1.13 1.23 4.5 1.16 0.05 PCB-10 26-DiCB 1.71 1.83 1.75 1.98 6.5 1.82 0.12 PCB-9 25-DiCB 0.83 0.89 0.90 0.95 5.7 0.89 0.05 PCB-7 24-DiCB 0.95 1.02 1.02 1.05 4.3 1.01 0.04 PCB-6 23'-DiCB 0.89 0.95 0.96 1.00 4.7 0.95 0.04 PCB-5 23-DiCB 0.89 0.97 0.97 1.00 4.7 0.96 0.05 PCB-8 24'-DiCB 0.93 0.98 1.00 1.03 4.3 0.99 0.04 PCB-14 35-DiCB 1.07 1.16 1.15 1.18 4.2 1.14 0.05 PCB-11 33'-DiCB 0.94 1.00 0.99 1.01 3.3 0.98 0.03 PCB-13/12 34'-/34-DiCB 0.95 1.02 0.99 0.99 2.8 0.99 0.03 PCB-15 44'-DiCB 0.99 1.08 1.05 1.02 3.9 1.03 0.04 0.03 PCB-19 22'6-TrCB 1.10 1.09 1.10 1.15 2.3 1.11 PCB-30/18 246-/22'5-TrCB 1.48 1.46 1.45 1.54 2.6 1.48 0.04 PCB-17 22'4-TrCB 1.28 1.25 1.26 1.31 2.0 1.28 0.03 PCB-27 23'6-TrCB 1.70 1.69 1.68 1.82 3.8 1.72 0.07 PCB-24 236-TrCB 1.63 1.63 1.60 1.72 3.1 1.65 0.05 PCB-16 22'3-TrCB 0.97 0.95 0.96 1.01 2.6 0.97 0.03 PCB-32 24'6-TrCB 1.81 1.79 1.84 1.92 3.1 1.84 0.06 PCB-34 2'35-TrCB 0.98 1.05 1.04 1.14 6.4 1.05 0.07 PCB-23 235-TrCB 0.98 1.06 1.07 1.16 6.9 1.07 0.07 PCB-26/29 23'5-/245-TrCB 1.00 1.09 1.07 1.17 6.3 1.08 0.07 PCB-25 23'4-TrCB 0.99 1.07 1.09 1.16 6.5 1.08 0.07 PCB-31 24'5-TrCB 1.03 1.11 1.13 1.23 7.2 1.13 0.08 PCB-28/20 244'-/233'-TrCB 0.98 1.07 1.06 1.13 5.6 1.06 0.06 PCB-21/33 234-/2'34-TrCB 1.01 1.09 1.08 1.17 6.0 1.09 0.06 PCB-22 234'-TrCB 0.93 1.02 1.00 1.08 6.0 1.01 0.06 PCB-36 33'5-TrCB 1.03 1.13 1.09 1.17 5.4 1.10 0.06 PCB-39 34'5-TrCB 1.10 1.17 1.13 1.21 4.1 1.15 0.05 PCB-38 345-TrCB 0.95 1.03 1.02 1.10 5.9 1.02 0.06 PCB-35 33'4-TrCB 0.96 1.04 1.00 1.04 4.0 1.01 0.04 PCB-37 344'-TrCB 1.00 1.10 1.05 1.08 4.2 1.06 0.04 PCB-54 22'66'-TeCB 1.18 1.21 1.24 1.35 6.0 1.25 0.07 PCB-50/53 22'46-/22'56'TeCB 0.85 0.86 0.88 0.88 2.0 0.87 0.02 PCB-45 22'36-TeCB 0.75 0.73 0.76 0.77 2.2 0.75 0.02 PCB-51 22'46'-TeCB 0.85 0.88 0.91 0.86 3.2 0.87 0.03 PCB-46 22'36'-TeCB 0.68 0.70 0.71 0.70 1.6 0.70 0.01 PCB-52 22'55'-TeCB 0.82 0.84 0.86 0.84 2.0 0.84 0.02 PCB-73 23'5'6TeCB 1.10 1.09 1.13 1.11 1.4 1.11 0.02 0.03 PCB-43 22'35-TeCB 0.66 0.72 0.72 0.71 4.5 0.70 PCB-69/49 23'46-/22'45'TeCB 1.00 1.01 1.05 1.02 2.1 1.02 0.02 PCB-48 22'45-TeCB 0.83 0.85 0.87 0.84 1.7 0.85 0.01 0.01 PCB-44/47/65 22'35'-/22'44'- 0.88 0.89 0.91 0.90 1.5 0.90 PCB-59/62/75 233'6-/2346-/24 1.12 1.14 1.18 1.17 2.4 1.15 0.03 PCB-42 22'34'-TeCB 0.77 0.76 2.9 0.78 0.02 0.77 0.81 MM7 Comparing ICAL RRFs 20DEC2013.xlsx PCB-41 22'34-TeCB 0.72 0.73 0.71 0.69 2.2 0.71 0.02 PCB-71/40 23'4'6/22'33'-TeCB 0.85 0.87 0.88 0.86 1.5 0.86 0.01 PCB-64 234'6-TeCB 1.21 1.24 1.26 1.22 1.7 1.23 0.02 PD from Historical Mean 4.9% 3.8% 4.4% 0.8% 0.7% 0.4% 1.4% -0.2% 1.4% -0.2% 1.5% 1.7% 3.2% 4.5% -1.7% -1.6% -1.9% -1.8% -0.7% -2.1% -2.8% -0.3% -0.8% 0.3% -0.3% -1.3% 0.7% 0.3% 0.8% 2.1% 1.2% 0.7% 3.2% 4.3% -3.0% -1.1% -2.8% 0.6% -0.3% 0.3% -1.5% 3.0% -0.8% 0.4% -0.8% -1.2% -0.8% 2.1% 0.2% 0.5% 1668A/B ICALs Air Historica Data Ax RSD 437 of 711 Mean sd MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd PCB-72 23'55'-TeCB 1.13 1.14 1.17 1.21 3.0 1.16 0.03 PCB-68 23'45'-TeCB 1.21 1.21 1.26 1.28 2.8 1.24 0.04 PCB-57 233'5-TeCB 1.10 1.11 1.12 1.16 2.3 1.12 0.03 PCB-58 233'5-TeCB 1.11 1.10 1.16 1.18 3.4 1.14 0.04 PCB-67 23'45-TeCB 1.15 1.16 1.20 1.26 4.2 1.19 0.05 PCB-63 234'5-TeCB 1.22 1.22 1.25 1.30 3.1 1.25 0.04 PCB-61/70/74/76 2345-/23'4'5 1.13 1.13 1.17 1.20 2.8 1.16 0.03 PCB-66 23'44'-TeCB 1.06 1.08 1.10 1.10 1.7 1.09 0.02 PCB-55 233'4-TeCB 1.09 1.10 1.11 1.12 1.3 1.10 0.01 PCB-56 233'4'-TeCB 1.05 1.06 1.07 1.11 2.4 1.07 0.03 PCB-60 2344'-TeCB 1.12 1.11 1.15 1.14 1.5 1.13 0.02 PCB-80 33'55'-TeCB 1.26 1.25 1.27 1.31 2.1 1.27 0.03 PCB-79 33'45'-TeCB 1.26 1.23 1.28 1.31 2.6 1.27 0.03 PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6-/22'356-P PCB-102 22'456'-PeCB PCB-98 22'3'46-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 233'5'6-/22'3 PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125/87 233 PCB-117 234'56-PeCB PCB-116/85 23456-/22'344'-Pe PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 233'4'5-/2'3455' PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 2'33'45-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'HxCB PCB-148 22'34'56'-HxCB PCB-151/135 22'355'6-/22'33' PCB-154 22'44'5'6-HxCB PCB-144 22'345'6-HxCB PCB-147/149 22'34'56-/22'34' PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 22'344'6-/22'344' PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB 1.09 1.08 1.05 1.06 1.6 1.07 0.02 1.11 1.25 1.31 1.43 10.2 1.28 0.13 0.98 1.08 1.12 1.23 9.5 1.10 0.10 0.80 0.90 0.95 0.93 7.2 0.90 0.06 0.70 0.78 0.81 0.80 6.6 0.77 0.05 0.75 0.83 0.88 0.87 7.5 0.83 0.06 0.76 0.84 0.90 0.86 6.9 0.84 0.06 0.82 0.90 0.98 0.97 8.1 0.92 0.07 0.69 0.77 0.80 0.76 5.9 0.76 0.04 0.67 0.79 0.77 0.80 7.8 0.76 0.06 0.84 0.88 1.00 0.94 7.5 0.91 0.07 0.65 0.71 0.72 0.72 5.2 0.70 0.04 0.68 0.76 0.78 0.76 6.0 0.75 0.04 1.02 1.14 1.20 1.20 7.4 1.14 0.08 0.73 0.80 0.84 0.82 6.0 0.80 0.05 0.85 0.93 0.99 0.99 7.0 0.94 0.07 0.63 0.71 0.72 0.71 5.7 0.69 0.04 0.82 0.87 0.95 0.92 6.5 0.89 0.06 1.01 1.13 1.17 1.17 6.7 1.12 0.07 0.87 0.95 1.01 0.98 6.4 0.95 0.06 0.96 1.04 1.05 1.14 7.2 1.05 0.08 0.87 0.97 1.03 0.94 7.0 0.95 0.07 0.95 1.02 1.11 1.12 7.7 1.05 0.08 1.02 1.16 1.21 1.16 6.9 1.14 0.08 0.63 0.69 0.72 0.70 5.5 0.68 0.04 1.05 1.15 1.22 1.22 7.0 1.16 0.08 1.05 1.16 1.22 1.21 6.5 1.16 0.08 0.99 1.07 1.11 1.10 5.3 1.07 0.06 1.05 1.14 1.18 1.25 7.1 1.16 0.08 0.98 1.07 1.11 1.11 5.6 1.07 0.06 1.01 1.00 1.01 0.99 1.0 1.00 0.01 1.12 1.10 1.08 1.10 1.5 1.10 0.02 1.08 1.09 1.22 1.26 7.8 1.16 0.09 1.00 1.01 1.14 1.17 8.0 1.08 0.09 1.03 1.00 1.15 1.18 7.9 1.09 0.09 0.95 0.95 1.07 1.07 6.8 1.01 0.07 0.98 0.96 1.09 1.11 7.4 1.03 0.08 0.96 0.97 1.12 1.18 10.5 1.06 0.11 0.94 0.96 1.11 1.14 9.8 1.04 0.10 1.05 1.09 1.26 1.34 11.7 1.19 0.14 0.96 0.98 1.13 1.18 10.1 1.06 0.11 0.96 0.99 1.14 1.18 10.3 1.07 0.11 0.78 0.80 0.90 0.92 8.1 0.85 0.07 0.92 0.95 1.09 1.13 10.0 1.02 0.10 0.99 1.00 1.14 1.21 10.1 1.09 0.11 0.84 0.85 0.98 1.03 10.4 0.93 0.10 0.99 7.4 0.93 0.07 0.86 MM7 Comparing ICAL RRFs 20DEC2013.xlsx 0.87 0.98 0.87 0.89 1.02 1.03 8.8 0.95 0.08 0.92 0.91 1.04 1.13 10.2 1.00 0.10 PD from Mean -1.8% -2.5% -1.4% -3.4% -2.8% -2.6% -2.3% -0.9% -0.6% -1.7% -1.5% -1.5% -2.9% 0.9% -1.7% -2.4% 0.6% 0.4% -0.7% 0.2% -1.9% 2.4% 4.7% -3.8% 1.4% 1.9% 0.2% 0.2% -0.9% 2.8% -2.1% 0.7% -0.1% -0.7% 2.2% -2.6% 1.8% 0.9% -0.5% -0.1% 0.6% -1.2% 0.1% -0.2% -0.1% -6.2% -6.4% -8.0% -5.7% -7.0% -8.2% -7.2% -8.1% -7.7% -7.8% -5.8% -6.8% -7.9% -8.2% -5.7% -6.7% -8.7% 1668A/B ICALs Air Historica Data Ax PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 22'44'55'-/23'44' PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 233'4'56-/22' PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 22'33'44'-/2344'5 PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'4'56-HpCB PCB-181 22'344'56-HpCB PCB-171/173 22'33'44'6-/22'3 PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 22'344'55'-/233' PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 22'33'455'6-/22' PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB RSD 438 of 711 Mean sd MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd 1.12 1.13 1.32 1.41 11.4 1.24 0.14 0.99 1.01 1.16 1.20 10.0 1.09 0.11 1.24 1.25 1.41 1.52 9.8 1.36 0.13 1.19 1.22 1.38 1.46 9.8 1.31 0.13 0.92 0.93 1.06 1.09 8.9 1.00 0.09 0.82 0.85 0.95 0.97 8.2 0.90 0.07 1.00 1.04 1.08 1.16 6.3 1.07 0.07 1.21 1.22 1.45 1.50 11.2 1.35 0.15 1.01 1.02 1.14 1.19 8.1 1.09 0.09 1.18 1.21 1.32 1.52 11.9 1.31 0.16 1.30 1.34 1.50 1.66 11.4 1.45 0.17 0.91 0.90 0.95 0.90 2.7 0.92 0.02 1.07 1.06 1.14 1.11 3.0 1.10 0.03 1.09 1.08 1.14 1.07 2.7 1.09 0.03 1.03 1.03 1.01 1.27 11.4 1.09 0.12 0.95 0.97 0.92 1.16 10.8 1.00 0.11 0.94 0.93 0.90 1.13 10.6 0.98 0.10 1.05 1.05 1.00 1.23 9.4 1.08 0.10 0.98 0.98 0.94 1.13 8.3 1.01 0.08 0.73 0.74 0.69 0.84 8.6 0.75 0.06 0.95 1.01 1.09 1.07 6.1 1.03 0.06 0.99 1.06 1.17 1.14 7.4 1.09 0.08 1.02 1.11 1.19 1.18 6.9 1.12 0.08 1.06 1.13 1.17 1.20 5.4 1.14 0.06 0.95 1.02 1.13 1.06 7.3 1.04 0.08 0.83 0.93 0.99 0.99 8.0 0.93 0.07 0.85 0.91 0.97 0.95 5.7 0.92 0.05 0.98 1.06 1.10 1.09 4.9 1.06 0.05 0.85 0.93 0.96 0.95 5.4 0.92 0.05 0.88 0.95 0.99 0.99 5.5 0.95 0.05 1.12 1.24 1.26 1.29 6.0 1.23 0.07 1.08 1.16 1.21 1.26 6.6 1.18 0.08 1.20 1.30 1.32 1.40 6.4 1.31 0.08 1.06 1.07 1.11 1.14 3.3 1.09 0.04 1.42 1.45 1.54 1.66 7.2 1.52 0.11 0.93 0.91 0.97 1.05 6.4 0.97 0.06 1.04 1.02 1.07 1.22 8.3 1.09 0.09 0.99 0.98 1.02 1.12 6.3 1.03 0.07 1.03 1.06 1.13 1.19 6.3 1.10 0.07 1.02 0.96 1.02 1.11 6.0 1.03 0.06 0.74 0.72 0.73 0.81 5.7 0.75 0.04 0.77 0.73 0.76 0.83 5.5 0.77 0.04 0.80 0.76 0.79 0.87 5.7 0.80 0.05 0.79 0.80 0.82 0.77 2.7 0.80 0.02 0.87 0.87 0.89 0.84 2.3 0.87 0.02 1.07 1.09 1.11 1.06 1.8 1.08 0.02 1.02 1.02 1.07 1.12 4.7 1.06 0.05 1.07 1.06 1.10 1.19 5.4 1.10 0.06 0.99 0.98 0.92 1.11 7.9 1.00 0.08 MM7 Comparing ICAL RRFs 20DEC2013.xlsx PD from Mean -9.0% -7.6% -7.6% -7.0% -7.3% -5.7% -2.7% -9.1% -6.2% -7.6% -7.7% -1.9% -3.0% -1.7% -4.8% -3.1% -4.6% -3.2% -2.6% -1.8% -2.0% -2.5% -1.2% -0.6% -2.0% -0.7% -1.3% 0.3% 0.6% 0.3% 1.0% -1.6% -0.3% -1.9% -4.3% -5.3% -6.2% -4.9% -3.6% -6.4% -4.2% -5.3% -5.1% 0.5% 0.7% 0.6% -3.8% -4.3% -2.0% 439 of 711 SGS Analytical Perspectives — Run Log Project: 131220 QC MM7 Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Datafile Vial# Wt/Vol Client/Sample ID Analyst(s) Checkcode Acq Date 2 131220X02 Tray1:37 CS0_131220_PCB_XA 1.00 SIL 13-79-6 LKB 067-110 20-Dec-2013 14:56:33 3 131220X03 Tray1:38 CS1_131220_PCB_XA 1.00 SIL 13-79-5 LKB 983-753 20-Dec-2013 16:14:56 Lab ID Acq Time 4 131220X04 Tray1:39 CS2_131220_PCB_XA 1.00 SIL 13-79-4 LKB 288-489 20-Dec-2013 17:09:38 5 131220X05 Tray1:40 CS3_131220_PCB_XA 1.00 SIL 13-79-3 LKB 297-225 20-Dec-2013 18:04:38 20-Dec-2013 18:59:38 6 131220X06 Tray1:41 CS4_131220_PCB_XA 1.00 SIL 13-79-2 LKB 186-257 7 131220X07 Tray1:02 SBS_131220_PCB_XB 1.00 SIL 9-42-1 LKB 307-094 20-Dec-2013 19:54:39 8 131220X08 Tray1:42 CS5_131220_PCB_XA 1.00 SIL 13-84-1 LKB 807-075 20-Dec-2013 20:49:35 9 131220X09 Tray1:02 SBS_131220_PCB_XC 1.00 SIL 9-42-1 LKB 023-880 20-Dec-2013 21:57:30 10 131220X10 Tray1:02 SBS_131220_PCB_XD 1.00 SIL 9-42-1 LKB 979-518 20-Dec-2013 22:52:16 Project file: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\131220 QC MM7.utp_prj, saved 03-Jan-2014 17:08 AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 Printed: 03-Jan-2014 17:17 440 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.12 32.64 36.11 35.57 35.10 34.82 38.73 41.28 40.30 44.00 46.13 51.25 6.82E+05 6.25E+05 5.30E+05 5.44E+05 5.47E+05 5.49E+05 4.31E+05 8.79E+05 4.81E+05 4.43E+05 4.42E+05 3.36E+05 0.76 Y 0.76 Y 0.63 Y 0.67 Y 0.67 Y 0.63 Y 0.61 Y 1.18 Y 1.11 Y 1.39 Y 1.03 Y 1.21 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.08 1.13 1.14 1.20 1.20 1.05 1.07 1.11 1.12 1.08 1.18 1.8% -3.1% 1.5% -5.0% 0.6% -0.6% -5.2% -2.5% -4.2% -0.5% 0.2% 6.0% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.05 14.37 14.63 20.39 17.75 26.75 20.68 33.10 32.62 25.69 36.09 35.55 35.08 34.80 38.71 36.67 30.66 41.26 40.28 43.98 43.50 42.43 35.54 46.11 40.09 48.28 49.75 45.73 51.23 2.32E+08 2.09E+08 9.70E+07 1.92E+08 9.22E+07 1.42E+08 7.28E+07 1.16E+08 1.15E+08 6.25E+07 9.38E+07 9.51E+07 9.14E+07 9.13E+07 8.22E+07 5.84E+07 8.51E+07 1.64E+08 8.65E+07 7.92E+07 4.71E+07 5.69E+07 4.97E+07 8.21E+07 4.94E+07 6.33E+07 4.24E+07 5.90E+07 5.69E+07 3.31 Y 3.36 Y 1.64 Y 1.56 Y 1.08 Y 1.09 Y 0.79 Y 0.80 Y 0.81 Y 1.64 Y 1.62 Y 1.64 Y 1.64 Y 1.59 Y 1.56 Y 1.32 Y 1.30 Y 1.31 Y 1.29 Y 1.29 Y 1.09 Y 1.07 Y 1.11 Y 1.04 Y 0.92 Y 0.90 Y 0.81 Y 0.81 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.25 1.12 0.52 1.04 0.50 1.69 0.86 1.38 1.37 0.82 1.22 1.24 1.19 1.19 1.07 1.14 1.66 1.60 1.68 1.54 0.92 1.11 0.97 1.61 0.96 1.24 0.83 1.16 1.12 5.1% 3.5% 0.1% -0.4% -1.7% 1.7% 0.4% -0.1% 0.2% 1.5% 1.8% 1.8% 2.9% 0.4% 4.3% 2.1% 4.3% 0.0% 0.9% -1.0% -2.5% -2.0% 2.9% 1.7% -0.9% -0.3% 0.3% -1.6% 0.5% Page 1 of 6 441 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.18 33.12 38.11 1.59E+08 9.52E+07 3.17E+07 1.09 Y 1.60 Y 1.06 Y 1.11 1.03 0.62 1.12 1.04 0.64 0.5% 1.3% 3.0% CS PCB-28 CS PCB-111 CS PCB-178 23.18 33.12 38.11 1.59E+08 9.52E+07 3.17E+07 1.09 Y 1.60 Y 1.06 Y 1.85 1.22 0.58 1.89 1.24 0.62 2.2% 1.7% 6.0% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.63 24.81 30.82 37.74 47.88 1.86E+08 8.42E+07 7.67E+07 5.14E+07 5.10E+07 1.57 Y 0.81 Y 1.63 Y 1.34 Y 0.93 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.06 14.39 14.64 20.41 17.77 26.77 20.70 25.71 30.68 35.56 40.11 48.30 45.75 49.77 1.15E+06 1.04E+06 5.70E+05 9.73E+05 5.22E+05 7.24E+05 5.08E+05 4.49E+05 5.21E+05 3.05E+05 2.58E+05 3.40E+05 3.21E+05 2.31E+05 3.25 Y 3.26 Y 0.00 S 0.00 S 1.03 Y 1.07 Y 0.86 Y 0.64 Y 1.33 Y 1.15 Y 0.94 Y 0.94 Y 0.83 Y 0.73 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.99 1.00 1.17 1.01 1.13 1.02 1.40 1.44 1.23 1.23 1.05 1.07 1.09 1.09 3.9% -0.9% -4.7% -0.7% -1.3% -5.6% 3.4% 0.3% -2.8% -3.2% -0.7% 1.3% -3.0% -2.5% Page 2 of 6 442 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 12.06 14.20 14.39 14.64 14.83 16.65 16.82 17.04 17.35 17.47 19.04 19.83 20.12 20.41 17.77 19.54 19.95 20.14 20.27 20.37 20.86 22.01 22.16 22.45 22.65 22.92 23.21 23.39 23.77 25.16 25.48 26.02 26.41 26.77 20.70 22.70 23.29 23.37 23.57 24.83 24.96 25.06 25.26 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.15E+06 1.07E+06 1.04E+06 5.70E+05 9.26E+05 8.91E+05 9.13E+05 9.28E+05 9.94E+05 1.02E+06 1.10E+06 9.44E+05 1.69E+06 9.73E+05 5.22E+05 1.37E+06 5.65E+05 8.14E+05 7.72E+05 4.55E+05 8.78E+05 7.89E+05 8.53E+05 1.63E+06 8.01E+05 8.89E+05 1.61E+06 1.63E+06 7.71E+05 8.01E+05 8.42E+05 7.61E+05 7.19E+05 7.24E+05 5.08E+05 1.02E+06 4.52E+05 4.59E+05 4.01E+05 4.90E+05 6.54E+05 3.93E+05 1.15E+06 RA 3.25 Y 3.22 Y 3.26 Y 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 1.03 Y 1.04 Y 1.04 Y 1.08 Y 1.06 Y 1.10 Y 1.08 Y 1.08 Y 0.94 Y 1.01 Y 0.97 Y 1.01 Y 1.02 Y 0.98 Y 1.00 Y 1.00 Y 1.02 Y 0.93 Y 1.01 Y 1.07 Y 0.86 Y 0.81 Y 0.79 Y 0.83 Y 0.83 Y 0.76 Y 0.81 Y 0.85 Y 0.76 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.99 1.02 1.00 1.17 1.91 0.93 0.95 0.97 1.03 1.07 1.14 0.98 0.88 1.01 1.13 1.49 1.23 1.77 1.67 0.99 1.90 1.11 1.20 1.15 1.13 1.25 1.13 1.15 1.08 1.13 1.18 1.07 1.01 1.02 1.40 0.89 0.78 0.80 0.70 0.85 1.13 0.68 0.99 Dev'n 3.9% -0.9% -0.9% -4.7% -3.6% -2.0% -9.2% -3.0% 3.2% 3.2% -3.4% -2.8% -11.2% -0.7% -1.3% -3.2% -6.1% -2.9% -2.9% -2.0% -0.8% -2.3% 3.8% -2.1% -2.7% 2.0% -0.1% -2.4% 0.4% -3.7% -2.3% -3.2% -2.8% -5.6% 3.4% 1.3% 2.2% -7.3% -0.4% 0.7% 2.0% -4.1% -2.8% 443 of 711 PCB QC Summary - Ax2 Detail Lab ID: CS0_131220_PCB_XA Acquired: 20-DEC-2013 14:56 Datafile: 131220X02 Name RT PCB-48 22'45-TeCB 25.54 PCB-44/47/65 ...-TeCB 25.76 PCB-59/62/75 ...-TeCB 26.03 PCB-42 22'34'-TeCB 26.20 PCB-41 22'34-TeCB 26.54 PCB-71/40 23'4'6/22'33'-TeCB 26.63 PCB-64 234'6-TeCB 26.83 PCB-72 23'55'-TeCB 27.55 PCB-68 23'45'-TeCB 27.80 PCB-57 233'5-TeCB 28.18 PCB-58 233'5'-TeCB 28.38 PCB-67 23'45-TeCB 28.54 PCB-63 234'5-TeCB 28.77 PCB-61/70/74/76 ...-TeCB 29.06 PCB-66 23'44'-TeCB 29.34 PCB-55 233'4-TeCB 29.49 PCB-56 233'4'-TeCB 29.93 PCB-60 2344'-TeCB 30.12 PCB-80 33'55'-TeCB 30.44 PCB-79 33'45'-TeCB 31.77 PCB-78 33'45-TeCB 32.26 PCB-104 22'466'-PeCB 25.71 PCB-96 22'366'-PeCB 26.03 PCB-103 22'45'6-PeCB 27.72 PCB-94 22'356'-PeCB 27.91 PCB-95 22'35'6-PeCB 28.29 PCB-100/93 22'44'6/22'356-PeCB 28.51 PCB-102 22'456'-PeCB 28.62 PCB-98 22'34'6'-PeCB 28.70 PCB-88 22'346-PeCB 29.00 PCB-91 22'34'6-PeCB 29.06 PCB-84 22'33'6-PeCB 29.25 PCB-89 22'346'-PeCB 29.67 PCB-121 23'45'6-PeCB 30.01 PCB-92 22'355'-PeCB 30.33 PCB-113/90/101 ...-PeCB 30.82 PCB-83 22'33'5-PeCB 31.26 PCB-99 22'44'5-PeCB 31.36 PCB-112 233'56-PeCB 31.46 PCB-108/119/86/97/125...-PeCB 31.80 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.43 PCB-110 233'4'6-PeCB 32.54 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 4.76E+05 1.54E+06 1.95E+06 4.38E+05 3.93E+05 9.69E+05 6.74E+05 6.87E+05 7.26E+05 6.81E+05 6.76E+05 7.09E+05 7.50E+05 2.77E+06 6.11E+05 6.26E+05 6.53E+05 6.55E+05 7.47E+05 7.25E+05 6.00E+05 4.49E+05 3.51E+05 4.14E+05 3.59E+05 4.07E+05 7.64E+05 4.42E+05 3.31E+05 4.40E+05 3.45E+05 3.22E+05 3.31E+05 5.39E+05 3.73E+05 1.35E+06 3.50E+05 4.00E+05 5.12E+05 2.69E+06 4.64E+05 9.28E+05 4.96E+05 RA 0.82 Y 0.78 Y 0.80 Y 0.81 Y 0.87 Y 0.82 Y 0.82 Y 0.78 Y 0.84 Y 0.73 Y 0.76 Y 0.78 Y 0.82 Y 0.77 Y 0.79 Y 0.78 Y 0.82 Y 0.79 Y 0.82 Y 0.81 Y 0.82 Y 0.64 Y 0.75 N 0.64 Y 0.70 Y 0.58 Y 0.61 Y 0.64 Y 0.63 Y 0.66 Y 0.56 Y 0.60 Y 0.70 Y 0.64 Y 0.62 Y 0.62 Y 0.64 Y 0.61 Y 0.65 Y 0.63 Y 0.55 Y 0.58 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.83 0.89 1.13 0.76 0.68 0.84 1.17 1.19 1.26 1.18 1.17 1.23 1.30 1.20 1.06 1.09 1.13 1.13 1.30 1.26 1.04 1.44 1.12 0.91 0.79 0.89 0.84 0.97 0.73 0.96 0.76 0.71 0.73 1.18 0.82 0.98 0.77 0.88 1.12 0.98 1.02 1.02 1.09 Dev'n -1.5% -1.8% -3.2% -0.5% -2.0% -2.2% -4.3% -1.5% -1.4% 1.5% -0.6% -2.3% 0.2% 0.2% -3.9% -3.1% 2.0% 0.0% -1.4% -3.8% -2.0% 0.3% -8.6% -2.6% -1.5% 3.0% -3.1% 0.0% -4.3% 20.8% -19.9% -1.3% -4.9% -1.7% -0.4% -0.3% 7.3% -4.7% -4.0% 0.2% -10.6% 8.1% -2.7% 444 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 32.63 32.83 33.14 33.54 34.51 34.72 34.94 35.40 37.35 30.68 30.84 30.98 31.29 31.56 32.83 33.35 33.56 33.83 34.13 34.30 34.39 34.65 34.82 34.97 35.21 35.61 35.95 36.16 36.28 36.72 36.86 37.20 37.41 37.49 37.78 37.92 38.10 38.84 39.65 39.89 35.56 35.84 36.31 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 5.39E+05 3.15E+05 5.61E+05 5.37E+05 9.78E+05 5.73E+05 5.10E+05 4.64E+05 5.10E+05 5.21E+05 4.93E+05 5.01E+05 4.28E+05 4.79E+05 3.33E+05 6.47E+05 4.03E+05 3.56E+05 6.56E+05 2.84E+05 3.14E+05 7.00E+05 2.97E+05 2.79E+05 3.02E+05 3.31E+05 4.11E+05 3.49E+05 4.37E+05 8.08E+05 3.22E+05 2.84E+05 3.47E+05 3.94E+05 1.03E+06 4.35E+05 4.94E+05 7.41E+05 4.73E+05 4.43E+05 3.05E+05 2.95E+05 2.83E+05 RA 0.59 Y 0.59 Y 0.65 Y 0.66 Y 0.64 Y 0.63 Y 0.69 Y 0.65 Y 0.62 Y 1.33 Y 1.27 Y 1.36 Y 1.35 Y 1.26 Y 1.20 Y 1.21 Y 1.25 Y 1.23 Y 1.34 Y 1.23 Y 1.30 Y 1.27 Y 1.27 Y 1.25 Y 1.27 Y 1.25 Y 1.27 Y 1.21 Y 1.25 Y 1.27 Y 1.27 Y 1.16 Y 1.24 Y 1.20 Y 1.26 Y 1.23 Y 1.30 Y 1.33 Y 1.12 Y 1.33 Y 1.15 Y 1.06 Y 0.94 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.18 0.69 1.23 1.18 1.07 1.26 1.12 0.97 1.09 1.23 1.16 1.18 1.01 1.13 1.14 1.11 1.38 1.22 1.12 0.97 1.07 1.20 1.02 0.96 1.03 1.13 1.41 1.19 1.50 1.38 1.10 0.97 1.19 1.35 1.18 1.49 1.69 0.86 1.09 1.03 1.23 1.19 1.14 Dev'n 1.8% -1.1% 0.6% -2.8% -2.4% 0.2% 1.0% -2.0% -0.8% -2.8% -1.3% 0.1% -5.7% 0.9% -3.7% -2.9% 2.8% 3.1% -4.6% 5.0% -4.7% -0.6% -0.8% -3.4% 0.2% 0.1% -0.2% -0.7% -1.6% -5.0% 1.3% 0.0% 2.0% -10.0% -1.1% -1.7% 1.8% -4.7% -1.9% -4.3% -3.2% 2.3% 1.1% 445 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 36.60 37.00 38.13 38.68 38.91 39.09 39.43 39.52 39.63 40.00 40.35 40.54 41.89 42.14 42.41 42.74 43.51 43.97 40.11 40.90 41.48 41.67 41.76 44.08 44.66 44.83 45.95 47.90 48.30 45.75 46.54 49.77 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 3.00E+05 2.82E+05 2.19E+05 2.90E+05 3.08E+05 3.10E+05 3.29E+05 2.70E+05 2.63E+05 2.64E+05 2.93E+05 5.11E+05 2.73E+05 3.33E+05 7.15E+05 3.99E+05 2.56E+05 3.84E+05 2.58E+05 2.87E+05 2.72E+05 3.10E+05 2.54E+05 3.97E+05 2.07E+05 2.16E+05 2.51E+05 2.77E+05 3.40E+05 3.21E+05 3.55E+05 2.31E+05 RA 1.06 Y 1.10 Y 1.14 Y 1.08 Y 1.11 Y 1.13 Y 1.06 Y 1.04 Y 1.16 Y 1.06 Y 1.17 Y 1.09 Y 1.07 Y 1.10 Y 1.02 Y 1.10 Y 1.10 Y 1.02 Y 0.94 Y 1.04 N 0.90 Y 0.94 Y 1.01 Y 1.02 Y 0.90 Y 0.86 Y 0.94 Y 0.96 Y 0.94 Y 0.83 Y 0.76 Y 0.73 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.21 1.14 0.88 1.02 1.08 1.09 1.16 0.95 0.93 0.93 1.03 0.90 0.96 1.17 1.26 1.41 1.09 1.63 1.05 1.16 1.10 1.26 1.03 0.80 0.84 0.87 0.79 0.88 1.07 1.09 1.20 1.09 Dev'n -1.8% 1.0% 4.6% -4.9% -4.8% -7.2% -4.0% -10.4% -6.3% -2.5% -5.4% -5.3% -3.0% -9.0% -0.4% 0.7% -4.3% -1.8% -0.7% -4.7% -1.4% 5.5% -7.2% -0.6% 0.6% 0.0% 3.5% 3.8% 1.3% -3.0% 1.1% -2.5% 446 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.34e7 2.67e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.66e7 1.33e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.89e7 9.45e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.92e7 9.60e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.07e7 5.34e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.41e6 2.71e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.18e6 2.59e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 067-110 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:09 Page 1 of 21 447 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-1 8.80e5 12.06 Rel. Int. 100% Abs. Int. 3.62e5 PCB-2 8.15e5 14.20 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.75e3 PCB-3 7.98e5 14.39 1.81e5 0% 11.0 12.0 13.0 14.0 PCB-1 2.71e5 12.06 Rel. Int. 100% PCB-2 2.53e5 14.20 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 4.15e3 15.0 0.00e0 16.0 RT Abs. Int. 1.13e5 PCB-3 2.45e5 14.38 5.63e4 0% 11.0 12.0 13.0 14.0 ES-1 1.79e8 12.05 Rel. Int. 100% 15.0 Abs. Int. 7.29e7 ES-3 1.61e8 14.37 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.78e3 0.00e0 16.0 RT 3.65e7 0% 11.0 12.0 13.0 14.0 ES-1 5.39e7 12.05 Rel. Int. 100% 15.0 Abs. Int. 2.20e7 ES-3 4.79e7 14.37 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.76e4 0.00e0 16.0 RT 1.10e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.34e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.67e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4953, 9453 scc: 067-110 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 2 of 21 448 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Rel. Int. 100% PCB-4 3.47e5 SI 14.64 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 8.63e3 PCB-10 5.64e5 SI 14.83 9.85e4 0% 11.0 12.0 13.0 14.0 Abs. Int. 1.97e5 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.66e5 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: B 4σ 2.45e4 8.28e4 PFK INTERFERENCE 0% 11.0 12.0 13.0 14.0 15.0 ES-4 6.03e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.00e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 9.69e3 1.00e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.67e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.22e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.99e3 6.10e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.34e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.67e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4218, 8363 scc: 067-110 Revised: 20-Dec-2013 16:07 (LKB) Printed: 03-Jan-2014 17:09 Page 3 of 21 449 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.03e4 PCB-9 5.43e5 SI 16.65 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-14 6.67e5 SI 19.04 PCB-6 5.66e5 SI PCB-5 17.04 6.06e5 SI 17.35 PCB-8 6.24e5 SI 17.47 PCB-11 5.75e5 SI 19.83 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 13/12 1.03e6 SI 20.12 Abs. Int. 2.00e5 PCB-15 5.93e5 SI 20.41 1.00e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% Abs. Int. 2.04e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: B 4σ 4.98e4 PFK INTERFERENCE 1.02e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.13e8 16.63 21.0 0.00e0 RT Abs. Int. 3.67e7 ES-15 1.17e8 20.39 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.06e4 1.83e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.22e7 16.63 21.0 ES-15 7.51e7 20.39 0.00e0 RT Abs. Int. 2.31e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.56e3 1.16e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7888, 3701 scc: 067-110 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 4 of 21 450 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 30/18 6.99e5 19.54 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 4.59e3 PCB-19 2.65e5 17.77 Abs. Int. 1.97e5 PCB-27 4.22e5 20.14 PCB-17 2.89e5 19.95 PCB-16 2.38e5 20.37 PCB-32 4.55e5 20.86 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.74e5 19.54 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 2.66e3 PCB-19 2.58e5 17.77 PCB-17 2.76e5 19.94 PCB-24 3.75e5 20.27 PCB-27 3.92e5 20.14 PCB-16 2.16e5 20.37 21.0 Rel. Int. 100% 18.0 19.0 20.0 PCB-32 4.23e5 20.85 21.0 9.50e4 0.00e0 RT Abs. Int. 1.93e7 ES-19 4.80e7 17.75 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 8.60e4 0.00e0 RT Abs. Int. 1.90e5 0% 17.0 9.86e4 9.63e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.74e7 ES-19 4.42e7 17.75 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 4.22e4 0.00e0 RT 8.69e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5150, 2161 scc: 067-110 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 5 of 21 451 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 28/20 8.12e5 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.52e3 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-23 PCB-34 4.13e5 4.09e5 22.16 22.01 26/29 8.20e5 22.45 PCB-31 4.46e5 22.92 21/33 8.09e5 23.39 Abs. Int. 2.07e5 PCB-22 3.85e5 23.77 PCB-36 4.01e5 25.16 PCB-39 4.25e5 25.48 PCB-38 3.67e5 26.02 PCB-35 3.62e5 26.41 PCB-37 3.75e5 26.77 0% 22.0 24.0 25.0 26.0 27.0 28/20 7.97e5 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 4.06e3 23.0 PCB-23 4.41e5 PCB-34 22.16 3.80e5 22.01 26/29 8.12e5 22.45 PCB-31 4.43e5 22.92 23.0 PCB-22 3.86e5 23.77 PCB-36 4.00e5 25.16 PCB-39 4.16e5 25.48 PCB-38 3.93e5 26.02 24.0 25.0 PCB-35 3.57e5 26.41 PCB-37 3.50e5 26.77 26.0 CS/SS-28 8.29e7 23.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e5 0% 22.0 1.03e5 27.0 0.00e0 RT Abs. Int. 2.37e7 ES-37 7.42e7 26.75 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 1.09e5 1.02e5 1.19e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 7.59e7 23.18 Rel. Int. 100% 27.0 Abs. Int. 2.19e7 ES-37 6.81e7 26.75 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 3.46e4 0.00e0 RT 1.09e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3489, 3011 scc: 067-110 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 6 of 21 452 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-54 2.35e5 20.70 Rel. Int. 100% Abs. Int. 6.46e4 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.55e3 3.23e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.74e5 20.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.82e4 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.17e3 3.91e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.22e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.63e6 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.64e4 4.31e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.06e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 7.86e3 5.58e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5717, 8453 scc: 067-110 Revised: 20-Dec-2013 16:06 (LKB) Printed: 03-Jan-2014 17:09 Page 7 of 21 453 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.01e3 50/53 4.58e5 22.70 PCB-51 2.08e5 23.37 PCB-45 1.99e5 23.29 PCB-73 2.92e5 PCB-52 24.96 2.11e5 24.83 PCB-46 1.82e5 23.57 69/49 4.95e5 25.26 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 44/47… 6.71e5 25.76 59/62… 8.68e5 26.03 PCB-48 2.15e5 25.54 PCB-42 1.96e5 26.20 71/40 4.36e5 26.63 PCB-41 1.83e5 26.54 Abs. Int. 1.53e5 PCB-64 3.04e5 26.83 7.63e4 27.0 0.00e0 RT 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.48e3 50/53 5.66e5 22.70 24.0 PCB-51 2.51e5 23.37 PCB-45 2.53e5 23.29 25.0 PCB-73 3.62e5 PCB-52 24.96 2.79e5 24.83 PCB-46 2.19e5 23.57 26.0 69/49 6.51e5 25.26 59/62… 44/47… 1.08e6 8.65e5 26.03 25.76 PCB-48 2.62e5 25.54 PCB-42 2.42e5 26.20 71/40 5.32e5 26.63 PCB-41 2.10e5 26.54 Abs. Int. 1.85e5 PCB-64 3.70e5 26.83 9.27e4 27.0 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.78e7 24.81 Rel. Int. 100% Abs. Int. 1.00e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 3.08e4 5.01e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 4.64e7 24.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.96e4 6.40e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6598, 8859 scc: 067-110 Revised: 03-Jan-2014 11:21 (LKB) Printed: 03-Jan-2014 17:09 Page 8 of 21 454 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 61/70... 1.21e6 29.06 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.26e3 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-68 3.31e5 27.80 PCB-67 3.10e5 28.54 (2.70e5 + 3.56e5) * 100 pg/uL PCB-78= 1.08 2.71e5 (5.16e7 + 6.38e7) * .5 pg/uL 32.26 PCB-79 03-Jan-2014 11:20 PCB-55LKBPCB-60 PCB-80 PCB-81 2.89e5 3.24e5 2.74e5 3.36e5 2.70e5 30.12 31.77 29.49 30.44 32.64 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 1.49e5 RRF(PCB-81) = PCB-77 2.95e5 33.12 7.45e4 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 2.42e3 PCB-57 3.94e5 28.18 PCB-68 3.96e5 27.80 30.0 61/70... 1.56e6 29.06 PCB-63 4.12e5 PCB-66 3.42e5 28.77 29.34 32.0 PCB-60 3.65e5 30.12 PCB-56 3.60e5 29.93 PCB-80 4.12e5 30.45 PCB-79 4.01e5 31.77 34.0 PCB-78 3.29e5 32.26PCB-81 3.56e5 32.64 36.0 38.0 Abs. Int. 1.90e5 PCB-77 3.88e5 33.12 9.52e4 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 5.16e7 32.62 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.10e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.47e7 ES-77 5.18e7 33.10 7.37e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.38e7 32.62 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 2.52e4 36.0 38.0 0.00e0 RT Abs. Int. 1.79e7 ES-77 6.46e7 33.10 8.96e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0219, 8038 scc: 067-110 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 9 of 21 455 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-104 1.75e5 25.71 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 8.14e2 Abs. Int. 4.89e4 PCB-96 1.63e5 26.03 2.44e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.74e5 25.71 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 9.29e2 27.0 0.00e0 RT Abs. Int. 7.44e4 PCB-96 2.17e5 26.02 3.72e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 3.88e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.91e6 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.55e3 4.96e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.37e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.05e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.87e3 3.03e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5253, 4725 scc: 067-110 Revised: 20-Dec-2013 16:06 (LKB) Printed: 03-Jan-2014 17:09 Page 10 of 21 456 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 108/119... 1.04e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 2.21e3 PCB-103 1.61e5 27.72 100/93 2.88e5 28.51 PCB-88 1.75e5 29.00 PCB-121 2.11e5 30.01 113/90… 5.12e5 30.82 116/85 3.42e5 32.43 PCB-99 1.52e5 31.36 PCB-111 2.21e5 PCB-120 2.13e5 33.14 33.54 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-118 107/124 2.20e5 3.81e5 35.10 34.51 PCB-114 PCB-123 2.18e5 2.12e5 35.57 34.82 Abs. Int. 1.54e5 PCB-105 2.05e5 36.11 PCB-127 1.96e5 37.35 7.68e4 0% 28.0 30.0 32.0 108/119... 1.64e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 4.66e3 34.0 PCB-94 2.12e5 27.91 100/93 4.76e5 28.51 PCB-91 2.21e5 29.06 PCB-121 3.28e5 30.01 113/90… 8.33e5 30.82 PCB-112 3.11e5 31.45 116/85 PCB-115 5.86e5 3.38e5 32.43 32.63 PCB-117 PCB-110 PCB-111 PCB-120 3.40e5 3.00e5 3.06e5 3.24e5 33.14 32.34 32.54 33.54 36.0 PCB-118 107/124 3.27e5 5.97e5 35.10 34.51 PCB-123 PCB-114 3.37e5 3.26e5 34.82 35.57 38.0 Abs. Int. 2.29e5 PCB-105 3.25e5 36.11 PCB-127 3.14e5 37.35 1.14e5 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.86e7 33.12 JS-101 4.75e7 30.82 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.00e3 34.0 36.0 ES-123 5.61e7 34.80 ES-118 ES-114 5.68e7 5.90e7 35.08 35.55 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.47e7 ES-105 5.80e7 36.09 7.34e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 3.66e7 33.12 JS-101 2.91e7 30.82 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.10e3 34.0 36.0 ES-118 ES-114 3.61e7 ES-123 3.46e7 35.55 3.52e7 35.08 34.80 38.0 0.00e0 RT Abs. Int. 9.50e6 ES-105 3.59e7 36.09 4.75e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7393, 8355 scc: 067-110 Revised: 03-Jan-2014 16:46 (LKB) Printed: 03-Jan-2014 17:09 Page 11 of 21 457 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 3.76e4 PCB-126 1.64e5 38.73 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.18e3 1.88e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.47e4 PCB-126 2.67e5 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.48e3 3.23e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.25e7 ES-126 5.01e7 38.71 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 5.64e3 6.27e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.77e6 ES-126 3.21e7 38.71 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 4.88e3 3.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4712, 3338 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 12 of 21 458 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PCB-155 PCB-150 2.97e5 2.89e5 30.98 30.68 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.52e2 PCB-145 2.67e5 31.56 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 163/138… 5.74e5 153/168 PCB-13737.78 4.52e5 1.92e5 36.72 37.41 PCB-160 151/135PCB-144 PCB-164 3.54e5 1.97e5 PCB-143 PCB-142 PCB-133 PCB-146 PCB-141 2.14e5 2.40e5 1.80e5 37.92 1.78e5 1.55e5 33.35 33.83 37.49 1.84e5 1.91e5 36.86 36.16 34.39 34.97 35.61 147/149 139/140 3.75e5 3.92e5 34.65 34.13 PCB-148 1.82e5 32.83 0% 28.0 30.0 32.0 PCB-152 2.17e5 30.84 PCB-136 PCB-155 1.82e5 PCB-145 2.24e5 31.28 2.11e5 30.68 31.56 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 8.44e2 34.0 PCB-148 1.51e5 32.83 139/140 147/149 3.08e5 151/135 2.80e5 34.65 2.92e5 34.13 33.35 PCB-154 PCB-143 PCB-131 1.79e5 1.37e5 1.31e5 33.56 34.39 34.82 36.0 PCB-133 1.47e5 PCB-165 35.61 1.81e5 35.95 38.0 153/168 3.56e5 36.72 163/138… 4.56e5 37.78 PCB-141 PCB-137 1.42e5 1.55e5 37.40 36.86 PCB-158 2.14e5 38.10 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.81e7 30.66 Rel. Int. 100% ES-153 3.32e7 36.67 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.51e3 Abs. Int. 1.11e5 5.57e4 0.00e0 RT Abs. Int. 8.34e4 4.17e4 0.00e0 RT Abs. Int. 1.25e7 JS-138 2.94e7 37.74 6.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.70e7 30.66 Rel. Int. 100% ES-153 2.52e7 36.67 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.03e3 0.00e0 RT Abs. Int. 9.38e6 JS-138 2.20e7 37.74 4.69e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6209, 6582 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 13 of 21 459 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.23e5 38.84 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.22e3 PCB-159 2.50e5 39.65 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-162 2.53e5 39.89 156/157 4.75e5 41.28 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 1.04e5 PCB-169 2.58e5 44.00 PCB-167 2.54e5 40.30 5.20e4 0% 39.0 Rel. Int. 100% 128/166 3.18e5 38.83 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.11e3 40.0 41.0 42.0 43.0 44.0 45.0 156/157 4.04e5 41.28 PCB-159 PCB-162 2.23e5 1.90e5 39.65 39.89 Abs. Int. 7.56e4 PCB-169 1.85e5 44.00 PCB-167 2.28e5 40.30 3.78e4 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 4.87e7 40.28 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 9.39e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 9.32e7 41.26 0.00e0 RT Abs. Int. 1.67e7 ES-169 4.45e7 43.98 8.34e6 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 3.78e7 40.28 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 6.54e3 42.0 43.0 44.0 45.0 ES-156/157 7.11e7 41.26 0.00e0 RT Abs. Int. 1.29e7 ES-169 3.46e7 43.98 6.47e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3213, 6781 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 14 of 21 460 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PCB-188 1.63e5 35.56 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-179 1.52e5 PCB-184 35.84 1.37e5 36.31 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.36e2 PCB-186 1.48e5 37.00 PCB-178 1.17e5 38.13 Abs. Int. 4.15e4 2.08e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.42e5 35.56 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.81e2 PCB-179 1.44e5 35.84 37.0 PCB-176 1.46e5 36.60 PCB-186 1.35e5 37.00 38.0 Abs. Int. 3.92e4 PCB-178 1.02e5 38.13 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.61e7 35.54 Rel. Int. 100% CS/SS-178 1.63e7 38.11 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.35e7 35.54 Rel. Int. 100% CS/SS-178 1.53e7 38.11 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.47e6 0.00e0 RT Abs. Int. 5.99e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.39e3 31.0 1.96e4 Abs. Int. 6.93e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.30e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 2.99e6 0.00e0 RT Abs. Int. 1.89e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.45e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6881, 0191 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 15 of 21 461 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.06e3 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-185 1.38e5 171/173 39.52 2.66e5 PCB-182 1.65e5 PCB-183 PCB-174 PCB-177 PCB-181 40.54 1.69e5 1.35e5 1.58e5 39.09 1.42e5 39.4339.63 40.00 40.35 180/193 3.61e5 42.41 PCB-172 1.41e5 41.89 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-191 2.09e5 42.74 PCB-170 1.34e5 43.51 Abs. Int. 5.93e4 PCB-190 1.94e5 43.97 2.96e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 9.28e2 40.0 PCB-182 1.45e5 39.09 PCB-183 1.60e5 PCB-187 39.43 1.46e5 38.91 41.0 42.0 43.0 180/193 3.54e5 42.41 171/173 PCB-177 PCB-181 2.44e5 1.28e5 1.35e5 40.54 40.00 40.35 PCB-191 1.90e5 42.74 PCB-172 1.32e5 41.89 44.0 45.0 PCB-190 1.90e5 43.97 Abs. Int. 5.34e4 PCB-170 1.22e5 43.52 2.67e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 ES-180 2.95e7 42.43 (2.46e7 + 2.25e7) 8 100 pg/uL RRF(ES-170) = = 0.924 (2.46e7 + 2.64e7) * 100 pg/uL LKB 03-Jan-2014 11:42 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.94e3 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 7.54e6 ES-170 2.46e7 43.50 3.77e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.74e7 42.43 Rel. Int. 100% 44.0 45.0 Abs. Int. 6.83e6 ES-170 2.25e7 43.50 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 1.82e3 0.00e0 RT 3.42e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3799, 6132 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 16 of 21 462 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-189 2.24e5 46.13 Abs. Int. 5.27e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.21e3 2.63e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.18e5 46.13 Abs. Int. 5.43e4 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 7.69e2 2.72e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.19e7 46.11 0.00e0 RT Abs. Int. 1.03e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 3.48e3 5.16e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.02e7 46.11 0.00e0 RT Abs. Int. 9.81e6 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 5.08e3 4.90e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2597, 5520 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 17 of 21 463 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-202 1.25e5 40.11 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 5.85e2 PCB-201 1.58e5 40.90 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 198/199 2.01e5 44.08 PCB-197 1.51e5 PCB-204 41.67 PCB-200 1.28e5 1.29e5 41.76 41.48 Abs. Int. 4.15e4 PCB-196 9.79e4 44.66 PCB-203 9.97e4 44.83 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.33e5 40.11 41.0 PCB-201 1.52e5 40.90 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 8.32e2 42.0 43.0 PCB-197 1.60e5 PCB-204 41.67 PCB-200 1.26e5 1.43e5 41.76 41.48 44.0 198/199 1.96e5 44.08 45.0 2.08e4 0.00e0 RT Abs. Int. 4.09e4 PCB-196 1.09e5 44.66 PCB-203 1.16e5 44.83 2.04e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.37e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.85e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.16e3 2.92e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.57e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.36e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 2.16e3 3.18e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3435, 2261 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 18 of 21 464 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 6.43e2 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-195 1.22e5 45.95 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-205 1.65e5 48.30 PCB-194 1.36e5 47.90 Abs. Int. 3.94e4 1.97e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 9.26e2 47.0 48.0 50.0 PCB-205 1.75e5 48.30 PCB-194 1.41e5 47.90 PCB-195 1.30e5 45.95 49.0 0.00e0 RT Abs. Int. 4.19e4 2.10e4 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.00e7 48.28 JS-194 2.46e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 4.05e3 49.0 0.00e0 RT Abs. Int. 7.11e6 3.56e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.33e7 48.28 Rel. Int. 100% Abs. Int. 7.81e6 JS-194 2.64e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.43e3 0.00e0 RT 3.91e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3437, 5090 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 19 of 21 465 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.06e3 PCB-208 1.46e5 45.75 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-207 1.53e5 46.54 Abs. Int. 3.84e4 PCB-206 9.77e4 49.77 1.92e4 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.83e3 PCB-208 1.75e5 45.74 47.0 48.0 49.0 PCB-207 2.02e5 46.54 50.0 Abs. Int. 4.66e4 PCB-206 1.33e5 49.77 2.33e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.64e7 45.73 50.0 0.00e0 RT Abs. Int. 6.27e6 ES-206 1.90e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.29e3 3.13e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.25e7 45.73 50.0 Abs. Int. 7.77e6 ES-206 2.34e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.08e3 0.00e0 RT 3.89e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6144, 7443 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 20 of 21 466 of 711 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-209 1.84e5 51.25 Rel. Int. 100% Abs. Int. 4.31e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 4.82e2 2.16e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.52e5 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.02e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.04e2 1.51e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.09e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.59e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 8.47e2 3.29e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.60e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.33e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.14e2 2.66e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.18e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.59e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4095, 3490 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 21 of 21 467 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.15e7 2.57e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.58e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.83e7 9.14e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.88e7 9.41e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.05e7 5.26e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.25e6 2.63e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.06e6 2.53e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 983-753 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:09 Page 1 of 21 468 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.12 32.64 36.12 35.58 35.11 34.82 38.73 41.29 40.30 44.01 46.14 51.26 1.44E+06 1.43E+06 1.07E+06 1.23E+06 1.13E+06 1.24E+06 9.39E+05 1.93E+06 1.07E+06 9.43E+05 8.81E+05 6.80E+05 0.79 Y 0.81 Y 0.63 Y 0.64 Y 0.62 Y 0.61 Y 0.63 Y 1.26 Y 1.25 Y 1.29 Y 1.07 Y 1.22 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.11 1.13 1.02 1.16 1.13 1.20 1.07 1.07 1.13 1.07 1.00 1.10 -3.6% 0.8% -7.9% -3.3% -5.3% -1.2% -3.3% -2.5% -2.8% -4.8% -6.6% -1.1% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.05 14.37 14.63 20.39 17.75 26.75 20.68 33.10 32.63 25.69 36.09 35.55 35.09 34.80 38.71 36.68 30.66 41.27 40.28 43.99 43.50 42.43 35.55 46.12 40.09 48.29 49.76 45.73 51.23 2.45E+08 2.19E+08 1.05E+08 2.08E+08 1.01E+08 1.55E+08 8.14E+07 1.30E+08 1.27E+08 6.93E+07 1.04E+08 1.06E+08 1.01E+08 1.03E+08 8.78E+07 6.38E+07 9.19E+07 1.81E+08 9.51E+07 8.81E+07 5.21E+07 6.14E+07 5.38E+07 8.78E+07 5.52E+07 6.89E+07 4.58E+07 6.49E+07 6.17E+07 3.30 Y 3.33 Y 1.62 Y 1.56 Y 1.09 Y 1.10 Y 0.81 Y 0.82 Y 0.82 Y 1.68 Y 1.61 Y 1.64 Y 1.61 Y 1.61 Y 1.58 Y 1.31 Y 1.28 Y 1.29 Y 1.28 Y 1.26 Y 1.09 Y 1.09 Y 1.11 Y 1.03 Y 0.93 Y 0.90 Y 0.81 Y 0.80 Y 1.20 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.22 1.09 0.52 1.04 0.50 1.64 0.86 1.37 1.35 0.80 1.21 1.22 1.17 1.20 1.02 1.11 1.60 1.57 1.65 1.53 0.93 1.10 0.93 1.57 0.96 1.23 0.82 1.16 1.10 2.1% 0.4% -0.1% -0.5% -0.8% -1.1% 0.2% -0.7% -1.5% 0.0% 0.7% 0.5% 0.8% 0.9% -0.9% -0.4% 0.6% -1.9% -1.0% -1.6% -1.8% -3.7% -0.5% -1.0% -1.1% -1.2% -1.4% -1.4% -0.7% Page 1 of 6 469 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.18 33.12 38.12 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.58 Y 1.10 Y 1.11 1.03 0.62 1.12 1.02 0.61 0.7% -0.8% -1.9% CS PCB-28 CS PCB-111 CS PCB-178 23.18 33.12 38.12 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.58 Y 1.10 Y 1.85 1.22 0.58 1.84 1.22 0.57 -0.4% 0.1% -2.4% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.63 24.81 30.82 37.74 47.89 2.01E+08 9.43E+07 8.62E+07 5.75E+07 5.60E+07 1.58 Y 0.81 Y 1.61 Y 1.31 Y 0.90 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.06 14.39 14.65 20.41 17.77 26.77 20.70 25.71 30.68 35.57 40.11 48.31 45.75 49.78 2.30E+06 2.16E+06 1.26E+06 2.04E+06 1.13E+06 1.62E+06 1.09E+06 9.78E+05 1.15E+06 7.09E+05 5.78E+05 7.06E+05 7.23E+05 5.11E+05 3.36 Y 3.09 Y 1.52 Y 1.55 Y 1.07 Y 1.01 Y 0.81 Y 0.64 Y 1.32 Y 1.05 Y 0.95 Y 0.90 Y 0.82 Y 0.79 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.94 0.98 1.20 0.98 1.12 1.05 1.34 1.41 1.25 1.32 1.05 1.03 1.11 1.11 -1.3% -2.5% -2.4% -4.0% -2.6% -3.0% -0.7% -1.5% -1.1% 3.9% -0.5% -3.2% -0.7% 0.0% Page 2 of 6 470 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 12.06 14.20 14.39 14.65 14.83 16.65 16.82 17.04 17.35 17.47 19.04 19.83 20.12 20.41 17.77 19.54 19.95 20.14 20.28 20.37 20.85 22.01 22.16 22.45 22.64 22.93 23.21 23.39 23.77 25.16 25.48 26.02 26.41 26.77 20.70 22.70 23.29 23.37 23.57 24.83 24.97 25.06 25.26 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 2.30E+06 2.22E+06 2.16E+06 1.26E+06 1.99E+06 1.98E+06 2.15E+06 1.96E+06 1.92E+06 2.06E+06 2.37E+06 1.97E+06 4.01E+06 2.04E+06 1.13E+06 2.96E+06 1.29E+06 1.77E+06 1.71E+06 9.51E+05 1.93E+06 1.70E+06 1.69E+06 3.54E+06 1.76E+06 1.79E+06 3.35E+06 3.53E+06 1.63E+06 1.74E+06 1.81E+06 1.68E+06 1.52E+06 1.62E+06 1.09E+06 2.16E+06 9.68E+05 1.04E+06 8.57E+05 1.06E+06 1.35E+06 8.63E+05 2.50E+06 RA 3.36 Y 3.19 Y 3.09 Y 1.52 Y 1.53 Y 1.52 Y 1.55 Y 1.59 Y 1.63 Y 1.64 Y 1.53 Y 1.60 Y 1.64 Y 1.55 Y 1.07 Y 1.02 Y 1.05 Y 1.07 Y 1.05 Y 1.08 Y 1.04 Y 1.01 Y 1.02 Y 1.00 Y 0.93 Y 1.00 Y 0.97 Y 1.00 Y 0.98 Y 0.96 Y 0.98 Y 1.02 Y 0.97 Y 1.01 Y 0.81 Y 0.78 Y 0.81 Y 0.82 Y 0.74 Y 0.77 Y 0.75 Y 0.75 Y 0.75 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.94 1.01 0.98 1.20 1.90 0.95 1.03 0.94 0.92 0.99 1.14 0.95 0.96 0.98 1.12 1.47 1.28 1.76 1.69 0.94 1.91 1.09 1.09 1.14 1.14 1.16 1.08 1.14 1.05 1.12 1.16 1.08 0.98 1.05 1.34 0.85 0.76 0.82 0.68 0.83 1.06 0.68 0.98 Dev'n -1.3% -2.1% -2.5% -2.4% -4.3% 0.8% -1.3% -5.2% -7.9% -4.3% -3.6% -6.2% -2.7% -4.0% -2.6% -4.3% -1.9% -3.4% -1.8% -6.2% -0.2% -3.6% -5.7% -2.6% -1.8% -5.5% -4.5% -3.0% -2.5% -4.1% -3.9% -1.9% -5.4% -3.0% -0.7% -2.9% -0.6% -4.6% -3.4% -1.4% -4.6% -4.4% -3.8% 471 of 711 PCB QC Summary - Ax2 Detail Lab ID: CS1_131220_PCB_XA Acquired: 20-DEC-2013 16:14 Datafile: 131220X03 Name RT PCB-48 22'45-TeCB 25.54 PCB-44/47/65 ...-TeCB 25.76 PCB-59/62/75 ...-TeCB 26.04 PCB-42 22'34'-TeCB 26.20 PCB-41 22'34-TeCB 26.54 PCB-71/40 23'4'6/22'33'-TeCB 26.63 PCB-64 234'6-TeCB 26.83 PCB-72 23'55'-TeCB 27.55 PCB-68 23'45'-TeCB 27.81 PCB-57 233'5-TeCB 28.18 PCB-58 233'5'-TeCB 28.38 PCB-67 23'45-TeCB 28.54 PCB-63 234'5-TeCB 28.77 PCB-61/70/74/76 ...-TeCB 29.06 PCB-66 23'44'-TeCB 29.34 PCB-55 233'4-TeCB 29.49 PCB-56 233'4'-TeCB 29.93 PCB-60 2344'-TeCB 30.12 PCB-80 33'55'-TeCB 30.45 PCB-79 33'45'-TeCB 31.78 PCB-78 33'45-TeCB 32.27 PCB-104 22'466'-PeCB 25.71 PCB-96 22'366'-PeCB 26.03 PCB-103 22'45'6-PeCB 27.72 PCB-94 22'356'-PeCB 27.91 PCB-95 22'35'6-PeCB 28.30 PCB-100/93 22'44'6/22'356-PeCB 28.51 PCB-102 22'456'-PeCB 28.63 PCB-98 22'34'6'-PeCB 28.69 PCB-88 22'346-PeCB 28.99 PCB-91 22'34'6-PeCB 29.06 PCB-84 22'33'6-PeCB 29.25 PCB-89 22'346'-PeCB 29.67 PCB-121 23'45'6-PeCB 30.02 PCB-92 22'355'-PeCB 30.33 PCB-113/90/101 ...-PeCB 30.82 PCB-83 22'33'5-PeCB 31.26 PCB-99 22'44'5-PeCB 31.36 PCB-112 233'56-PeCB 31.46 PCB-108/119/86/97/125...-PeCB 31.80 PCB-117 234'56-PeCB 32.34 PCB-116/85 23456/22'344'-PeCB 32.43 PCB-110 233'4'6-PeCB 32.54 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.01E+06 3.36E+06 4.29E+06 9.26E+05 8.37E+05 2.09E+06 1.50E+06 1.50E+06 1.57E+06 1.41E+06 1.44E+06 1.59E+06 1.60E+06 5.90E+06 1.35E+06 1.40E+06 1.33E+06 1.42E+06 1.64E+06 1.69E+06 1.26E+06 9.78E+05 8.58E+05 9.36E+05 7.83E+05 8.29E+05 1.71E+06 9.57E+05 7.04E+05 7.38E+05 9.82E+05 6.84E+05 7.66E+05 1.19E+06 8.33E+05 2.96E+06 7.27E+05 9.10E+05 1.16E+06 5.82E+06 1.19E+06 1.79E+06 1.10E+06 RA 0.77 Y 0.79 Y 0.80 Y 0.75 Y 0.80 Y 0.82 Y 0.75 Y 0.80 Y 0.77 Y 0.85 Y 0.79 Y 0.76 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.78 Y 0.78 Y 0.76 Y 0.80 Y 0.77 Y 0.64 Y 0.71 Y 0.64 Y 0.65 Y 0.59 Y 0.59 Y 0.62 Y 0.64 Y 0.59 Y 0.56 Y 0.58 Y 0.63 Y 0.67 Y 0.61 Y 0.62 Y 0.67 Y 0.63 Y 0.65 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.79 0.88 1.13 0.73 0.66 0.82 1.18 1.18 1.24 1.11 1.13 1.25 1.26 1.16 1.06 1.10 1.05 1.12 1.29 1.33 0.99 1.41 1.24 0.91 0.76 0.80 0.83 0.93 0.68 0.72 0.95 0.66 0.74 1.15 0.81 0.96 0.70 0.88 1.12 0.94 1.15 0.87 1.07 Dev'n -5.5% -2.5% -3.3% -4.4% -5.2% -4.1% -3.1% -2.1% -3.0% -4.3% -4.0% -0.7% -3.2% -3.0% -3.5% -1.8% -5.4% -1.4% -1.8% 1.6% -6.5% -1.5% 0.8% -2.5% -5.2% -7.3% -4.0% -4.2% -10.0% -10.4% 0.8% -7.4% -2.8% -3.9% -1.6% -2.9% -1.5% -4.2% -3.8% -4.0% 1.3% -7.6% -4.4% 472 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 32.63 32.83 33.15 33.54 34.51 34.72 34.94 35.40 37.35 30.68 30.84 30.98 31.29 31.56 32.83 33.36 33.57 33.83 34.13 34.31 34.39 34.66 34.83 34.98 35.21 35.61 35.95 36.17 36.29 36.72 36.86 37.21 37.41 37.49 37.78 37.92 38.10 38.84 39.65 39.89 35.57 35.85 36.32 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.15E+06 6.91E+05 1.20E+06 1.18E+06 2.12E+06 1.09E+06 1.12E+06 1.01E+06 1.08E+06 1.15E+06 1.03E+06 1.02E+06 8.99E+05 1.00E+06 7.25E+05 1.44E+06 8.24E+05 7.12E+05 1.47E+06 5.72E+05 7.05E+05 1.49E+06 6.51E+05 5.89E+05 6.45E+05 7.07E+05 8.89E+05 7.40E+05 9.19E+05 1.81E+06 6.67E+05 6.08E+05 7.27E+05 9.46E+05 2.21E+06 9.44E+05 1.05E+06 1.64E+06 1.05E+06 9.62E+05 7.09E+05 6.25E+05 5.87E+05 RA 0.66 Y 0.62 Y 0.64 Y 0.65 Y 0.63 Y 0.61 Y 0.63 Y 0.63 Y 0.63 Y 1.32 Y 1.37 Y 1.19 Y 1.33 Y 1.26 Y 1.41 Y 1.27 Y 1.31 Y 1.24 Y 1.29 Y 1.37 Y 1.29 Y 1.23 Y 1.25 Y 1.28 Y 1.26 Y 1.26 Y 1.25 Y 1.25 Y 1.24 Y 1.24 Y 1.26 Y 1.33 Y 1.30 Y 1.33 Y 1.21 Y 1.29 Y 1.33 Y 1.18 Y 1.27 Y 1.13 Y 1.05 Y 1.09 Y 1.02 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.11 0.67 1.17 1.14 1.03 1.05 1.08 0.96 1.04 1.25 1.12 1.10 0.98 1.09 1.14 1.13 1.29 1.12 1.15 0.90 1.10 1.16 1.02 0.92 1.01 1.11 1.39 1.16 1.44 1.42 1.05 0.95 1.14 1.48 1.15 1.48 1.64 0.86 1.11 1.01 1.32 1.16 1.09 Dev'n -4.2% -4.0% -4.5% -5.6% -6.4% -16.1% -2.0% -3.7% -5.5% -1.1% -4.2% -6.1% -8.3% -2.4% -3.9% -1.1% -3.8% -5.7% -2.3% -3.0% -2.2% -3.5% -0.6% -6.8% -2.0% -2.1% -1.1% -3.5% -5.3% -2.7% -4.0% -2.0% -2.1% -1.0% -3.2% -2.3% -1.2% -4.3% -0.8% -5.6% 3.9% 0.1% -3.2% 473 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 36.61 37.01 38.14 38.69 38.91 39.09 39.44 39.52 39.63 40.01 40.36 40.54 41.89 42.14 42.42 42.75 43.52 43.98 40.11 40.90 41.48 41.67 41.76 44.09 44.67 44.84 45.96 47.91 48.31 45.75 46.54 49.78 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 6.55E+05 5.96E+05 4.31E+05 6.43E+05 6.87E+05 6.98E+05 7.24E+05 6.34E+05 6.37E+05 5.78E+05 6.58E+05 1.11E+06 5.95E+05 7.80E+05 1.50E+06 8.57E+05 5.51E+05 8.22E+05 5.78E+05 6.75E+05 6.21E+05 6.41E+05 5.73E+05 8.75E+05 4.40E+05 4.68E+05 5.10E+05 5.61E+05 7.06E+05 7.23E+05 7.50E+05 5.11E+05 RA 1.14 Y 1.00 Y 1.08 Y 1.04 Y 1.08 Y 1.03 Y 1.15 Y 1.02 Y 1.07 Y 1.13 Y 1.09 Y 1.08 Y 1.09 Y 1.06 Y 0.95 Y 1.12 Y 0.98 Y 1.07 Y 0.95 Y 0.92 Y 0.94 Y 0.90 Y 0.90 Y 0.91 Y 0.99 Y 0.92 Y 0.94 Y 0.90 Y 0.90 Y 0.82 Y 0.80 Y 0.79 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.22 1.11 0.80 1.05 1.12 1.14 1.18 1.03 1.04 0.94 1.07 0.90 0.97 1.27 1.22 1.40 1.06 1.58 1.05 1.22 1.13 1.16 1.04 0.79 0.80 0.85 0.74 0.82 1.03 1.11 1.16 1.11 Dev'n -1.2% -1.5% -4.9% -2.3% -1.7% -3.2% -2.1% -2.6% 4.9% -1.0% -1.4% -4.7% -2.0% -1.3% -3.0% 0.1% -6.8% -5.0% -0.5% 0.1% 0.8% -2.4% -6.2% -2.0% -4.4% -3.0% -3.4% -3.3% -3.2% -0.7% -2.9% 0.0% 474 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-1 1.77e6 12.06 Rel. Int. 100% PCB-2 1.69e6 14.20 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.00e3 Abs. Int. 7.15e5 PCB-3 1.63e6 14.39 3.57e5 0% 11.0 12.0 13.0 PCB-1 5.28e5 12.06 Rel. Int. 100% 14.0 PCB-2 5.29e5 14.20 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.63e3 15.0 0.00e0 16.0 RT Abs. Int. 2.17e5 PCB-3 5.27e5 14.38 1.08e5 0% 11.0 12.0 13.0 14.0 ES-1 1.88e8 12.05 Rel. Int. 100% 15.0 Abs. Int. 7.30e7 ES-3 1.69e8 14.37 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.69e3 0.00e0 16.0 RT 3.65e7 0% 11.0 12.0 13.0 14.0 ES-1 5.69e7 12.05 Rel. Int. 100% 15.0 Abs. Int. 2.24e7 ES-3 5.06e7 14.37 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.35e4 0.00e0 16.0 RT 1.12e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2722, 6482 scc: 983-753 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 2 of 21 475 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Rel. Int. 100% PCB-4 7.61e5 14.65 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.83e3 PCB-10 1.20e6 14.83 2.01e5 0% 11.0 12.0 13.0 14.0 Rel. Int. 100% 15.0 PCB-4 5.00e5 14.64 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.52e4 PCB-10 7.85e5 14.83 0% 12.0 13.0 0.00e0 16.0 RT Abs. Int. 2.69e5 1.35e5 PFK INTERFERENCE 11.0 Abs. Int. 4.03e5 14.0 15.0 ES-4 6.48e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.20e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 1.02e4 1.10e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.00e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.35e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.10e3 6.77e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9174, 6214 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:09 Page 3 of 21 476 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 8.83e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-6 1.21e6 17.04 PCB-9 1.20e6 16.65 PCB-14 1.43e6 19.04 PCB-5 1.19e6 17.35 PCB-8 1.28e6 17.47 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-11 1.22e6 19.83 13/12 2.49e6 20.12 Abs. Int. 4.02e5 PCB-15 1.24e6 20.41 2.01e5 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.29e4 PCB-9 7.88e5 16.65 PCB-7 8.44e5 16.82 18.0 19.0 PCB-14 9.38e5 19.04 PCB-5 7.31e5 PCB-8 17.35 7.79e5 17.47 PFK INTERFERENCE 20.0 PCB-11 7.59e5 19.83 13/12 1.52e6 20.12 21.0 Abs. Int. 3.35e5 PCB-15 7.98e5 20.41 1.67e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.23e8 16.63 21.0 0.00e0 RT Abs. Int. 3.85e7 ES-15 1.27e8 20.39 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.10e4 1.93e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.80e7 16.63 21.0 ES-15 8.13e7 20.39 0.00e0 RT Abs. Int. 2.48e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.06e3 1.24e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9567, 5816 scc: 983-753 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 4 of 21 477 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 30/18 1.50e6 19.54 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.85e3 PCB-19 5.82e5 17.77 Abs. Int. 4.10e5 PCB-27 9.13e5 20.14 PCB-17 6.61e5 19.95 PCB-16 4.95e5 20.37 PCB-32 9.84e5 20.85 2.05e5 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 1.47e6 19.54 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 2.47e3 PCB-19 5.45e5 17.76 PCB-17 6.30e5 19.95 21.0 Abs. Int. 4.07e5 PCB-27 8.57e5 20.14 PCB-16 4.56e5 20.37 PCB-32 9.46e5 20.85 2.04e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 2.14e7 ES-19 5.26e7 17.75 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 7.23e4 0.00e0 RT 1.07e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.97e7 ES-19 4.83e7 17.75 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 4.38e4 0.00e0 RT 9.86e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7724, 7248 scc: 983-753 Revised: 27-Dec-2013 11:30 (LKB) Printed: 03-Jan-2014 17:09 Page 5 of 21 478 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 28/20 1.65e6 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.02e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-23 PCB-34 8.55e5 8.51e5 22.16 22.01 26/29 1.77e6 22.45 PCB-31 8.95e5 22.93 Abs. Int. 4.21e5 PCB-22 8.08e5 23.77 PCB-36 8.50e5 25.16 PCB-39 8.93e5 25.48 PCB-38 8.46e5 26.02 PCB-35 7.51e5 26.41 PCB-37 8.13e5 26.77 0% 22.0 24.0 25.0 26.0 27.0 28/20 1.70e6 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.84e3 23.0 PCB-23 PCB-34 8.35e5 8.46e5 22.16 22.01 26/29 1.77e6 22.45 PCB-31 9.00e5 22.92 23.0 PCB-22 8.24e5 23.77 PCB-36 8.89e5 25.16 PCB-39 9.12e5 25.48 PCB-38 8.33e5 26.02 24.0 25.0 PCB-35 7.74e5 26.41 PCB-37 8.08e5 26.77 26.0 CS/SS-28 9.06e7 23.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.28e5 0% 22.0 2.11e5 27.0 0.00e0 RT Abs. Int. 2.54e7 ES-37 8.13e7 26.75 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 1.13e5 2.14e5 1.27e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.29e7 23.18 Rel. Int. 100% 27.0 Abs. Int. 2.36e7 ES-37 7.38e7 26.75 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 3.74e4 0.00e0 RT 1.18e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2047, 2588 scc: 983-753 Revised: 27-Dec-2013 11:30 (LKB) Printed: 03-Jan-2014 17:09 Page 6 of 21 479 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-54 4.89e5 20.70 Rel. Int. 100% Abs. Int. 1.37e5 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.36e3 6.83e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 6.03e5 20.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e5 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.17e3 9.39e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.65e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 2.02e4 5.12e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.49e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 8.82e3 6.20e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7968, 7088 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:09 Page 7 of 21 480 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 1.58e3 50/53 9.50e5 22.70 PCB-51 4.70e5 23.37 PCB-45 4.32e5 23.29 PCB-73 PCB-52 5.78e5 4.59e5 24.97 24.83 PCB-46 3.64e5 23.57 69/49 1.07e6 25.26 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 44/47… 1.48e6 25.76 59/62… 1.91e6 26.04 PCB-48 4.38e5 25.54 PCB-42 3.97e5 26.20 71/40 9.42e5 26.63 PCB-41 3.71e5 26.54 Abs. Int. 3.53e5 PCB-64 6.46e5 26.83 1.77e5 27.0 0.00e0 RT 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.72e3 50/53 1.21e6 22.70 24.0 PCB-51 5.71e5 23.37 PCB-45 5.36e5 23.29 25.0 PCB-73 7.69e5 PCB-52 24.97 5.98e5 24.83 PCB-46 4.93e5 23.57 26.0 69/49 1.42e6 25.26 59/62… 44/47… 2.38e6 1.87e6 26.04 25.76 PCB-48 5.68e5 25.54 PCB-42 5.29e5 26.20 71/40 1.15e6 26.63 PCB-41 4.66e5 26.54 Abs. Int. 4.32e5 PCB-64 8.56e5 26.83 2.16e5 27.0 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.22e7 24.81 Rel. Int. 100% Abs. Int. 1.13e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.67e4 5.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.21e7 24.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.42e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 2.28e4 7.10e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4359, 5676 scc: 983-753 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 8 of 21 481 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 61/70... 2.59e6 29.06 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 3.33e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-57 6.50e5 28.18 PCB-63 7.04e5 28.77 PCB-55 6.16e5 29.49 Abs. Int. 3.24e5 PCB-60 6.21e5 PCB-80 7.09e5 30.12 30.45 PCB-81 6.42e5 32.64 PCB-79 7.50e5 31.78 PCB-77 6.36e5 33.12 1.62e5 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 2.68e3 PCB-68 8.90e5 27.81 30.0 61/70... 3.32e6 PCB-60 PCB-67 29.06 8.00e5 9.01e5 30.12 28.54 PCB-63 PCB-66 PCB-80 PCB-56 8.91e5 7.50e5 9.28e5 7.48e5 28.77 29.34 30.45 29.93 32.0 34.0 36.0 38.0 Abs. Int. 4.24e5 PCB-81 7.90e5 32.64 PCB-79 9.35e5 31.78 PCB-77 8.03e5 33.12 2.12e5 0% 28.0 30.0 0.00e0 RT 32.0 Rel. Int. 100% 34.0 ES-81 5.70e7 32.63 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.49e4 36.0 38.0 0.00e0 RT Abs. Int. 1.53e7 ES-77 5.83e7 33.10 7.63e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.00e7 32.63 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.91e4 36.0 38.0 0.00e0 RT Abs. Int. 1.88e7 ES-77 7.13e7 33.10 9.38e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8043, 1494 scc: 983-753 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:31 Printed: 03-Jan-2014 17:10 Page 9 of 21 482 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-104 3.83e5 25.71 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 9.09e2 Abs. Int. 9.50e4 PCB-96 3.57e5 26.03 4.75e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 5.96e5 25.71 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 8.81e2 27.0 0.00e0 RT Abs. Int. 1.52e5 PCB-96 5.01e5 26.03 7.58e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.34e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.97e3 5.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.59e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.60e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 1.70e3 3.30e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7311, 3592 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:10 Page 10 of 21 483 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 5.53e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 108/119... 2.22e6 31.80 (4.35e5 + 6.99e5) * 100 pg/uL RRF(PCB-118) = = 1.13 (6.20e7 + 3.86e7) * 1.0 pg/uL 113/90… 100/9311:45 LKB 03-Jan-2014 1.13e6 6.34e5 30.82 PCB-121 PCB-99 28.51 PCB-88 PCB-103 4.78e5 3.53e5 3.66e5 30.02 2.75e5 31.36 27.72 28.99 116/85 6.89e5 32.43 PCB-111 4.71e5 PCB-120 33.15 4.66e5 33.54 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-118 107/124 4.35e5 8.23e5 35.11 34.51 PCB-123 PCB-114 4.68e5 4.77e5 34.82 35.58 Abs. Int. 3.39e5 PCB-105 4.12e5 36.12 PCB-127 4.20e5 37.35 1.70e5 0% 28.0 30.0 32.0 108/119... 3.61e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 7.14e3 34.0 PCB-94 4.74e5 27.91 100/93 1.08e6 28.51 PCB-91 6.28e5 29.06 PCB-89 4.69e5 29.67 113/90… 1.83e6 30.82 PCB-112 PCB-92 7.02e5 5.18e5 31.46 30.33 116/85 PCB-115 1.10e6 6.93e5 32.43 32.63 PCB-110 PCB-111 PCB-117 7.33e5 PCB-120 6.81e5 7.35e5 7.14e5 33.14 32.54 32.34 33.54 36.0 PCB-118 107/124 6.99e5 1.30e6 35.11 34.51 PCB-123 PCB-114 7.67e5 7.51e5 34.82 35.58 38.0 Abs. Int. 5.56e5 PCB-105 6.57e5 36.12 PCB-127 6.61e5 37.35 2.78e5 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 6.46e7 33.12 JS-101 5.31e7 30.82 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.82e3 34.0 36.0 ES-123 6.36e7 34.80 ES-114 6.56e7 35.55 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.61e7 ES-105 6.43e7 36.09 8.07e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.08e7 33.12 JS-101 3.31e7 30.82 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.71e3 34.0 36.0 ES-118 ES-123 3.86e7 3.96e7 35.09 34.80 38.0 0.00e0 RT Abs. Int. 1.02e7 ES-105 4.00e7 36.09 5.09e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7344, 6760 scc: 983-753 Revised: 30-Dec-2013 13:07 (LKB) Printed: 03-Jan-2014 17:10 Page 11 of 21 484 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Abs. Int. 9.23e4 PCB-126 3.63e5 38.73 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.27e3 4.61e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.52e5 PCB-126 5.76e5 38.73 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.57e3 7.61e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.28e7 ES-126 5.38e7 38.71 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.43e3 6.40e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.29e6 ES-126 3.40e7 38.71 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 7.41e3 4.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0821, 7826 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 12 of 21 485 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-136 5.13e5 31.29 PCB-155 PCB-150 5.51e5 PCB-145 6.53e5 30.98 5.58e5 30.68 31.56 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.22e2 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 147/149 139/140 8.25e5 8.18e5 34.13 34.66 PCB-148 4.24e5 32.83 151/135 8.04e5 PCB-144 PCB-143 PCB-133 PCB-146 33.36 3.94e5 3.96e5 PCB-142 3.94e5 4.11e5 3.30e5 36.17 33.83 34.39 35.61 34.98 153/168 1.00e6 36.72 PCB-141 3.72e5 36.86 163/138… 1.21e6 37.78 PCB-164 PCB-160 5.40e5 5.32e5 37.49 37.92 1.11e5 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PCB-150 PCB-155 4.64e5 4.93e5 30.98 30.68 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 8.63e2 PCB-145 4.42e5 31.56 PCB-148 3.01e5 32.83 147/149 139/140 151/135 6.41e5 6.67e5 6.33e5 34.66 34.13 33.35 PCB-154 PCB-143 PCB-132 3.56e5 3.08e5 2.85e5 33.57 34.39 35.21 36.0 38.0 153/168 8.09e5 36.72 PCB-165 3.96e5 35.95 163/138… 1.00e6 37.78 PCB-137 PCB-141 3.17e5 2.95e5 37.41 36.86 30.0 32.0 34.0 36.0 ES-155 5.16e7 30.66 Rel. Int. 100% HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.53e3 Abs. Int. 1.88e5 9.41e4 38.0 ES-153 3.62e7 36.68 0.00e0 RT PCB-158 4.50e5 38.10 0% 28.0 Abs. Int. 2.21e5 JS-138 3.26e7 37.74 0.00e0 RT Abs. Int. 1.25e7 6.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.04e7 30.66 Rel. Int. 100% ES-153 2.76e7 36.68 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.37e3 0.00e0 RT Abs. Int. 9.99e6 JS-138 2.49e7 37.74 4.99e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4865, 1501 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 13 of 21 486 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 8.84e5 38.84 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.56e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-162 PCB-159 5.10e5 5.87e5 39.89 39.65 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 156/157 1.08e6 41.29 Abs. Int. 2.09e5 PCB-167 5.96e5 40.30 PCB-169 5.31e5 44.01 1.04e5 0% 39.0 Rel. Int. 100% 128/166 7.52e5 38.84 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.20e3 40.0 PCB-162 PCB-159 4.52e5 39.89 4.64e5 39.65 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.82e5 156/157 8.55e5 41.28 PCB-169 4.12e5 44.00 PCB-167 4.78e5 40.30 9.11e4 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.33e7 40.28 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 8.34e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.02e8 41.27 (1.02e8 + 7.90e7) * 100 pg/uL RRF(ES-156/157) = = 1.57 (3.26e7 + 2.49e7) * 200 pg/uL LKB 03-Jan-2014 11:48 0.00e0 RT Abs. Int. 1.85e7 ES-169 4.92e7 43.99 9.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 7.90e7 41.27 Rel. Int. 100% ES-167 4.18e7 40.28 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 9.96e3 0.00e0 RT Abs. Int. 1.47e7 ES-169 3.89e7 43.99 7.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2729, 9872 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 14 of 21 487 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% PCB-188 3.62e5 35.57 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.15e2 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-179 3.26e5 PCB-184 2.97e5 35.85 36.32 PCB-186 2.98e5 37.01 Abs. Int. 8.73e4 PCB-178 2.24e5 38.14 4.37e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 3.46e5 35.57 PCB-179 2.99e5 35.85 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.25e2 37.0 PCB-176 3.06e5 36.61 PCB-186 2.98e5 37.01 38.0 Abs. Int. 8.68e4 PCB-178 2.07e5 38.14 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.82e7 35.55 Rel. Int. 100% CS/SS-178 1.71e7 38.12 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.55e7 35.55 Rel. Int. 100% CS/SS-178 1.56e7 38.12 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.55e6 0.00e0 RT Abs. Int. 6.62e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.42e3 31.0 4.34e4 Abs. Int. 7.11e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.34e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 3.31e6 0.00e0 RT Abs. Int. 1.88e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6233, 0370 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 15 of 21 488 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.17e3 PCB-182 PCB-183 3.55e5 3.87e5 39.44 39.09 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-177 PCB-181 3.06e5 3.43e5 40.01 40.36 171/173 5.75e5 40.54 PCB-172 3.10e5 41.89 180/193 7.33e5 42.42 PCB-192 4.01e5 42.14 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Abs. Int. 1.52e5 PCB-191 4.53e5 42.75 PCB-170 2.72e5 43.52 PCB-190 4.24e5 43.98 7.59e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.47e3 40.0 41.0 PCB-182 PCB-185 3.14e5 3.43e5 171/173 39.52 39.09 5.34e5 PCB-187 PCB-181 40.54 PCB-183 3.31e5 PCB-174 PCB-177 3.15e5 3.37e5 38.91 3.08e5 40.36 2.71e5 39.4439.63 40.01 42.0 43.0 180/193 7.69e5 42.42 PCB-172 2.85e5 41.89 PCB-191 4.05e5 42.75 44.0 45.0 Abs. Int. 1.26e5 PCB-190 3.97e5 43.98 PCB-170 2.79e5 43.52 6.28e4 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.20e7 42.43 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 8.23e6 ES-170 2.71e7 43.50 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 2.53e3 0.00e0 RT 4.12e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.93e7 42.43 Rel. Int. 100% 44.0 45.0 Abs. Int. 7.29e6 ES-170 2.50e7 43.50 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.41e3 0.00e0 RT 3.64e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7891, 3827 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 16 of 21 489 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-189 4.54e5 46.14 Abs. Int. 1.16e5 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.02e3 5.81e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 4.26e5 46.14 Abs. Int. 1.09e5 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 8.26e2 5.43e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.46e7 46.12 0.00e0 RT Abs. Int. 1.06e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 6.63e3 5.31e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.32e7 46.12 0.00e0 RT Abs. Int. 1.01e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.18e3 5.03e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5887, 3655 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 17 of 21 490 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-202 2.82e5 40.11 Rel. Int. 100% PCB-201 3.23e5 40.90 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 7.19e2 PCB-197 3.04e5 PCB-204 41.67 PCB-200 3.00e5 2.72e5 41.48 41.76 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 198/199 4.18e5 44.09 Abs. Int. 8.33e4 PCB-196 2.19e5 44.67 PCB-203 2.24e5 44.84 0% 39.0 Rel. Int. 100% 40.0 PCB-202 2.96e5 40.11 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.84e2 41.0 PCB-201 3.52e5 40.90 42.0 43.0 44.0 45.0 198/199 4.57e5 44.09 PCB-197 3.38e5PCB-200 PCB-204 41.67 3.01e5 3.20e5 41.76 41.48 40.0 41.0 42.0 PCB-196 2.21e5 44.66 43.0 44.0 PCB-203 2.44e5 44.84 4.51e4 45.0 ES-202 2.66e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.01e4 0% 39.0 4.17e4 0.00e0 RT Abs. Int. 6.53e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.52e3 3.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.85e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.30e3 3.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3815, 7054 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 18 of 21 491 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 8.34e2 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-205 3.35e5 48.31 PCB-195 2.47e5 45.96 Abs. Int. 7.93e4 PCB-194 2.65e5 47.91 3.97e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 7.51e2 47.0 48.0 49.0 50.0 PCB-205 3.71e5 48.31 PCB-195 2.63e5 45.96 0.00e0 RT Abs. Int. 9.00e4 PCB-194 2.96e5 47.91 4.50e4 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.26e7 48.29 Rel. Int. 100% Abs. Int. 7.66e6 JS-194 2.66e7 47.89 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.09e3 0.00e0 RT 3.83e6 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.63e7 48.29 JS-194 2.94e7 47.89 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.82e3 49.0 0.00e0 RT Abs. Int. 8.37e6 4.19e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1382, 4116 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 19 of 21 492 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.01e3 PCB-208 3.26e5 45.75 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-207 3.34e5 46.54 Abs. Int. 8.61e4 PCB-206 2.25e5 49.78 4.30e4 0% 46.0 Rel. Int. 100% PCB-208 3.97e5 45.75 47.0 48.0 49.0 PCB-207 4.16e5 46.54 50.0 Abs. Int. 1.01e5 PCB-206 2.86e5 49.78 NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.89e3 5.06e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.87e7 45.73 50.0 0.00e0 RT Abs. Int. 6.89e6 ES-206 2.06e7 49.76 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.22e3 3.45e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.61e7 45.73 50.0 Abs. Int. 8.47e6 ES-206 2.53e7 49.76 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.67e3 0.00e0 RT 4.24e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0808, 5245 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 20 of 21 493 of 711 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-209 3.74e5 51.26 Rel. Int. 100% Abs. Int. 7.55e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.21e2 3.77e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 3.06e5 51.26 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.81e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.94e2 3.41e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.36e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.01e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 8.10e2 3.50e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.81e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.76e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.63e2 2.88e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.06e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.53e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6986, 0137 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 21 of 21 494 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.11 32.63 36.11 35.56 35.10 34.82 38.72 41.28 40.29 44.00 46.13 51.25 7.18E+06 6.81E+06 5.68E+06 6.19E+06 5.72E+06 5.95E+06 4.77E+06 9.62E+06 5.42E+06 4.85E+06 4.61E+06 3.38E+06 0.79 Y 0.77 Y 0.64 Y 0.62 Y 0.60 Y 0.63 Y 0.62 Y 1.25 Y 1.21 Y 1.23 Y 1.02 Y 1.17 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.09 1.08 1.07 1.15 1.13 1.16 1.05 1.05 1.12 1.09 1.03 1.06 -5.2% -3.8% -4.0% -4.1% -5.1% -3.9% -5.1% -4.7% -3.2% -3.1% -3.6% -4.8% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.04 14.36 14.61 20.38 17.73 26.74 20.66 33.09 32.61 25.67 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.26 40.27 43.98 43.49 42.42 35.54 46.11 40.08 48.28 49.75 45.73 51.23 2.39E+08 2.19E+08 1.04E+08 2.08E+08 1.01E+08 1.56E+08 8.13E+07 1.31E+08 1.27E+08 7.00E+07 1.06E+08 1.07E+08 1.01E+08 1.02E+08 9.09E+07 6.37E+07 9.19E+07 1.84E+08 9.64E+07 8.90E+07 5.32E+07 6.31E+07 5.40E+07 8.91E+07 5.60E+07 7.02E+07 4.73E+07 6.67E+07 6.37E+07 3.26 Y 3.37 Y 1.62 Y 1.56 Y 1.08 Y 1.09 Y 0.82 Y 0.80 Y 0.80 Y 1.67 Y 1.61 Y 1.65 Y 1.61 Y 1.58 Y 1.58 Y 1.31 Y 1.33 Y 1.30 Y 1.30 Y 1.30 Y 1.08 Y 1.09 Y 1.06 Y 1.03 Y 0.94 Y 0.89 Y 0.81 Y 0.80 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.21 1.10 0.53 1.05 0.51 1.68 0.88 1.42 1.36 0.82 1.25 1.26 1.19 1.20 1.07 1.13 1.63 1.63 1.71 1.58 0.96 1.13 0.96 1.60 0.99 1.26 0.85 1.20 1.14 1.3% 1.5% 0.5% 0.9% 0.4% 1.0% 1.7% 2.5% -0.2% 2.2% 3.7% 3.3% 2.4% 1.1% 3.7% 1.3% 2.5% 1.9% 2.3% 1.3% 1.0% -0.4% 1.8% 1.0% 2.3% 1.3% 2.3% 1.9% 3.2% Page 1 of 6 495 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.11 38.10 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.62 Y 1.12 Y 1.11 1.03 0.62 1.11 1.03 0.61 -0.2% 0.0% -2.3% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.11 38.10 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.62 Y 1.12 Y 1.85 1.22 0.58 1.86 1.23 0.58 0.9% 1.1% -0.5% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.81 37.73 47.88 1.98E+08 9.28E+07 8.53E+07 5.64E+07 5.57E+07 1.57 Y 0.79 Y 1.59 Y 1.31 Y 0.92 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.05 14.37 14.63 20.39 17.75 26.76 20.68 25.69 30.67 35.56 40.10 48.30 45.75 49.78 1.11E+07 1.07E+07 6.23E+06 1.02E+07 5.64E+06 8.15E+06 5.32E+06 4.90E+06 5.67E+06 3.30E+06 2.80E+06 3.53E+06 3.57E+06 2.55E+06 3.29 Y 3.19 Y 1.60 Y 1.65 Y 1.05 Y 0.98 Y 0.81 Y 0.65 Y 1.29 Y 1.10 Y 0.89 Y 0.93 Y 0.81 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.92 0.98 1.20 0.98 1.12 1.05 1.31 1.40 1.23 1.22 1.00 1.01 1.07 1.08 -2.9% -3.0% -2.9% -4.3% -2.5% -2.9% -3.2% -2.3% -2.2% -3.7% -5.1% -5.1% -4.7% -3.2% Page 2 of 6 496 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 12.05 14.18 14.37 14.63 14.81 16.63 16.80 17.03 17.33 17.45 19.02 19.81 20.11 20.39 17.75 19.52 19.93 20.12 20.26 20.35 20.84 21.99 22.14 22.43 22.63 22.91 23.19 23.38 23.75 25.14 25.46 26.00 26.39 26.76 20.68 22.68 23.27 23.34 23.55 24.82 24.94 25.04 25.24 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 1.11E+07 1.07E+07 1.07E+07 6.23E+06 1.01E+07 9.38E+06 1.06E+07 9.98E+06 1.00E+07 1.05E+07 1.19E+07 1.03E+07 2.02E+07 1.02E+07 5.64E+06 1.52E+07 6.40E+06 8.92E+06 8.42E+06 5.03E+06 9.31E+06 8.68E+06 8.57E+06 1.76E+07 8.79E+06 9.29E+06 1.69E+07 1.76E+07 8.06E+06 8.80E+06 9.00E+06 8.25E+06 7.78E+06 8.15E+06 5.32E+06 1.07E+07 4.46E+06 5.62E+06 4.33E+06 5.19E+06 6.70E+06 4.56E+06 1.26E+07 RA 3.29 Y 3.30 Y 3.19 Y 1.60 Y 1.59 Y 1.58 Y 1.65 Y 1.58 Y 1.62 Y 1.60 Y 1.61 Y 1.64 Y 1.61 Y 1.65 Y 1.05 Y 1.08 Y 1.08 Y 1.07 Y 1.05 Y 1.05 Y 1.07 Y 0.97 Y 1.00 Y 0.99 Y 0.95 Y 0.97 Y 1.00 Y 0.99 Y 1.00 Y 0.98 Y 0.97 Y 0.97 Y 1.00 Y 0.98 Y 0.81 Y 0.80 Y 0.79 Y 0.80 Y 0.78 Y 0.79 Y 0.79 Y 0.75 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.92 0.98 0.98 1.20 1.93 0.90 1.02 0.96 0.96 1.00 1.15 0.99 0.97 0.98 1.12 1.51 1.27 1.77 1.67 1.00 1.85 1.11 1.10 1.13 1.13 1.19 1.08 1.13 1.04 1.13 1.16 1.06 1.00 1.05 1.31 0.84 0.70 0.89 0.68 0.82 1.06 0.72 0.99 Dev'n -2.9% -5.2% -3.0% -2.9% -2.5% -4.6% -2.9% -3.7% -3.7% -2.7% -2.9% -1.9% -1.7% -4.3% -2.5% -1.8% -2.7% -2.6% -3.0% -0.7% -3.7% -1.9% -4.7% -3.4% -2.4% -2.7% -4.3% -3.7% -4.1% -3.4% -4.5% -4.0% -3.9% -2.9% -3.2% -3.9% -8.2% 3.3% -2.0% -2.8% -4.8% 1.4% -2.8% 497 of 711 PCB QC Summary - Ax2 Detail Lab ID: CS2_131220_PCB_XA Acquired: 20-DEC-2013 17:09 Datafile: 131220X04 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.02 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.52 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.79 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.37 PCB-67 23'45-TeCB 28.52 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.05 PCB-66 23'44'-TeCB 29.33 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.11 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.76 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.01 PCB-103 22'45'6-PeCB 27.71 PCB-94 22'356'-PeCB 27.90 PCB-95 22'35'6-PeCB 28.28 PCB-100/93 22'44'6/22'356-PeCB 28.50 PCB-102 22'456'-PeCB 28.61 PCB-98 22'34'6'-PeCB 28.68 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.24 PCB-89 22'346'-PeCB 29.66 PCB-121 23'45'6-PeCB 30.00 PCB-92 22'355'-PeCB 30.32 PCB-113/90/101 ...-PeCB 30.81 PCB-83 22'33'5-PeCB 31.25 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.79 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.42 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.24E+06 1.64E+07 2.14E+07 4.75E+06 4.38E+06 1.05E+07 7.49E+06 7.51E+06 7.85E+06 7.33E+06 7.30E+06 7.81E+06 7.85E+06 2.94E+07 6.87E+06 7.07E+06 6.96E+06 7.00E+06 8.09E+06 8.10E+06 6.61E+06 4.90E+06 4.21E+06 4.65E+06 4.04E+06 4.36E+06 8.64E+06 5.08E+06 3.64E+06 3.75E+06 4.80E+06 3.58E+06 3.81E+06 5.96E+06 4.05E+06 1.47E+07 3.64E+06 4.49E+06 5.95E+06 2.92E+07 5.88E+06 9.01E+06 5.43E+06 RA 0.81 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.81 Y 0.79 Y 0.80 Y 0.75 Y 0.77 Y 0.76 Y 0.77 Y 0.76 Y 0.79 Y 0.76 Y 0.79 Y 0.77 Y 0.78 Y 0.80 Y 0.78 Y 0.79 Y 0.65 Y 0.65 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.63 Y 0.64 Y 0.65 Y 0.63 Y 0.61 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.59 Y 0.64 Y 0.63 Y 0.62 Y 0.62 Y 0.64 Y 0.63 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.83 0.86 1.13 0.75 0.69 0.83 1.18 1.19 1.24 1.16 1.15 1.23 1.24 1.16 1.09 1.12 1.10 1.11 1.28 1.28 1.04 1.40 1.20 0.91 0.79 0.85 0.85 0.99 0.71 0.73 0.94 0.70 0.75 1.16 0.79 0.96 0.71 0.88 1.16 0.95 1.15 0.88 1.06 Dev'n -1.3% -4.4% -3.2% -1.7% -0.5% -3.8% -3.0% -1.9% -2.8% -0.5% -2.1% -2.0% -4.4% -3.0% -1.5% -0.3% -1.0% -2.5% -2.7% -2.0% -1.6% -2.3% -2.0% -2.2% -1.3% -1.5% -2.1% 2.6% -6.0% -8.2% -0.5% -2.1% -2.3% -2.9% -3.5% -2.5% -0.4% -4.7% -0.4% -2.9% 1.1% -6.3% -5.0% 498 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 32.62 32.82 33.13 33.53 34.50 34.71 34.93 35.39 37.34 30.67 30.82 30.97 31.27 31.55 32.82 33.34 33.55 33.82 34.12 34.29 34.38 34.64 34.82 34.96 35.20 35.60 35.94 36.16 36.28 36.71 36.85 37.20 37.40 37.48 37.77 37.91 38.09 38.83 39.64 39.88 35.56 35.84 36.30 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.94E+06 3.45E+06 6.10E+06 6.04E+06 1.09E+07 6.46E+06 5.32E+06 5.09E+06 5.46E+06 5.67E+06 5.18E+06 5.27E+06 4.80E+06 4.89E+06 3.69E+06 7.14E+06 4.14E+06 3.74E+06 7.38E+06 2.81E+06 3.63E+06 7.45E+06 3.13E+06 3.09E+06 3.22E+06 3.47E+06 4.45E+06 3.72E+06 4.78E+06 9.14E+06 3.40E+06 3.05E+06 3.51E+06 4.84E+06 1.09E+07 4.74E+06 5.15E+06 8.23E+06 5.14E+06 4.97E+06 3.30E+06 3.06E+06 2.96E+06 RA 0.60 Y 0.62 Y 0.63 Y 0.64 Y 0.62 Y 0.62 Y 0.64 Y 0.64 Y 0.62 Y 1.29 Y 1.28 Y 1.27 Y 1.26 Y 1.31 Y 1.28 Y 1.23 Y 1.24 Y 1.28 Y 1.29 Y 1.29 Y 1.26 Y 1.28 Y 1.29 Y 1.24 Y 1.28 Y 1.26 Y 1.24 Y 1.30 Y 1.30 Y 1.28 Y 1.30 Y 1.25 Y 1.28 Y 1.28 Y 1.27 Y 1.26 Y 1.28 Y 1.25 Y 1.24 Y 1.21 Y 1.10 Y 1.09 Y 1.03 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.16 0.67 1.19 1.18 1.07 1.26 1.04 0.95 1.03 1.23 1.13 1.15 1.04 1.06 1.16 1.12 1.30 1.17 1.16 0.88 1.14 1.17 0.98 0.97 1.01 1.09 1.40 1.17 1.50 1.43 1.07 0.96 1.10 1.52 1.14 1.49 1.62 0.85 1.07 1.03 1.22 1.13 1.10 Dev'n 0.3% -3.3% -2.3% -2.5% -2.9% 0.8% -5.8% -4.5% -6.2% -2.2% -3.8% -2.5% -2.1% -4.5% -2.2% -1.6% -3.2% -0.8% -1.6% -4.5% 0.8% -3.0% -4.2% -1.9% -2.1% -3.9% -0.9% -2.9% -1.4% -1.6% -2.0% -1.7% -5.3% 1.3% -3.9% -1.7% -2.7% -5.1% -4.4% -3.7% -3.7% -2.3% -2.6% 499 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 36.60 37.00 38.13 38.67 38.90 39.08 39.43 39.52 39.62 40.00 40.35 40.53 41.88 42.13 42.41 42.74 43.51 43.97 40.10 40.89 41.47 41.66 41.75 44.08 44.66 44.83 45.95 47.90 48.30 45.75 46.54 49.78 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 3.29E+06 2.98E+06 2.21E+06 3.31E+06 3.49E+06 3.67E+06 3.83E+06 3.13E+06 3.03E+06 2.93E+06 3.27E+06 5.79E+06 2.98E+06 4.03E+06 7.75E+06 4.20E+06 2.91E+06 4.21E+06 2.80E+06 3.33E+06 3.01E+06 3.09E+06 3.13E+06 4.38E+06 2.29E+06 2.39E+06 2.57E+06 2.84E+06 3.53E+06 3.57E+06 3.79E+06 2.55E+06 RA 1.07 Y 1.06 Y 1.08 Y 1.06 Y 0.96 Y 1.07 Y 1.05 Y 1.08 Y 1.07 Y 1.10 Y 1.08 Y 1.06 Y 1.07 Y 1.06 Y 1.08 Y 1.05 Y 1.04 Y 1.06 Y 0.89 Y 0.92 Y 0.94 Y 0.91 Y 0.89 Y 0.92 Y 0.94 Y 0.93 Y 0.90 Y 0.87 Y 0.93 Y 0.81 Y 0.76 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.22 1.10 0.82 1.05 1.11 1.16 1.21 0.99 0.96 0.93 1.04 0.92 0.95 1.28 1.23 1.33 1.09 1.58 1.00 1.19 1.08 1.11 1.12 0.78 0.82 0.85 0.73 0.81 1.01 1.07 1.14 1.08 Dev'n -1.2% -1.9% -2.7% -2.3% -2.9% -1.0% 0.7% -6.4% -2.8% -2.3% -4.9% -3.1% -4.3% -0.7% -2.6% -4.6% -3.7% -4.7% -5.1% -2.7% -3.6% -7.1% 1.0% -3.4% -1.8% -2.2% -4.5% -4.1% -5.1% -4.7% -4.4% -3.2% 500 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.95e7 2.47e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.50e7 1.25e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.78e7 8.90e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.83e7 9.17e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.06e7 5.32e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.51e6 2.75e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.31e6 2.65e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 288-489 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:10 Page 1 of 21 501 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-1 8.49e6 12.05 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-2 8.22e6 14.18 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.63e3 Abs. Int. 3.53e6 PCB-3 8.15e6 14.37 1.77e6 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.58e6 12.05 Rel. Int. 100% PCB-2 2.50e6 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.76e3 0.00e0 16.0 RT Abs. Int. 1.06e6 PCB-3 2.55e6 14.37 5.29e5 0% 11.0 12.0 13.0 14.0 ES-1 1.83e8 12.04 Rel. Int. 100% 15.0 Abs. Int. 7.14e7 ES-3 1.69e8 14.36 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.48e3 0.00e0 16.0 RT 3.57e7 0% 11.0 12.0 13.0 14.0 ES-1 5.63e7 12.04 Rel. Int. 100% 15.0 Abs. Int. 2.26e7 ES-3 5.01e7 14.36 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.97e4 0.00e0 16.0 RT 1.13e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.47e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5986, 8076 scc: 288-489 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 2 of 21 502 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. 100% PCB-4 3.84e6 14.63 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.13e3 PCB-10 6.17e6 14.81 1.01e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.89e6 14.81 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.22e4 PCB-4 2.39e6 14.63 12.0 13.0 14.0 15.0 ES-4 6.43e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.30e6 6.50e5 0% 11.0 Abs. Int. 2.02e6 0.00e0 16.0 RT Abs. Int. 2.12e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 1.16e4 1.06e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.98e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.35e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.62e3 6.76e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.47e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2760, 4750 scc: 288-489 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 3 of 21 503 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.04e4 PCB-9 5.75e6 16.63 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-7 6.57e6 PCB-6 16.80 6.12e6 17.03 PCB-14 7.35e6 19.02 PCB-5 6.20e6 PCB-8 17.33 6.43e6 17.45 PCB-11 6.41e6 19.81 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 13/12 1.25e7 20.11 Abs. Int. 2.17e6 PCB-15 6.32e6 20.39 1.09e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.28e4 PCB-9 3.64e6 16.63 PCB-7 3.99e6 16.80 18.0 19.0 PCB-14 4.57e6 19.02 PCB-5 3.84e6 PCB-8 17.33 4.02e6 17.45 20.0 PCB-11 3.91e6 19.81 13/12 7.75e6 20.10 21.0 Abs. Int. 1.40e6 PCB-15 3.83e6 20.39 7.00e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.21e8 16.61 21.0 0.00e0 RT Abs. Int. 3.98e7 ES-15 1.27e8 20.38 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.35e4 1.99e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.71e7 16.61 21.0 0.00e0 RT Abs. Int. 2.51e7 ES-15 8.13e7 20.38 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 1.09e4 1.26e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0673, 3078 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 4 of 21 504 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 30/18 7.88e6 19.52 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.57e3 PCB-19 2.89e6 17.75 PCB-17 3.33e6 19.93 PCB-27 4.61e6 20.12 PCB-24 4.30e6 20.26 PCB-16 2.58e6 20.35 Abs. Int. 2.14e6 PCB-32 4.81e6 20.84 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 7.32e6 19.52 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 4.49e3 PCB-19 2.75e6 17.75 PCB-17 3.07e6 19.93 21.0 Rel. Int. 100% 18.0 19.0 PCB-16 2.45e6 20.35 20.0 PCB-32 4.50e6 20.84 21.0 1.01e6 0.00e0 RT Abs. Int. 2.17e7 ES-19 5.22e7 17.73 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 7.41e4 0.00e0 RT Abs. Int. 2.01e6 PCB-24 4.11e6 20.26 PCB-27 4.31e6 20.12 0% 17.0 1.07e6 1.09e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.98e7 ES-19 4.85e7 17.73 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.71e4 0.00e0 RT 9.91e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9474, 8467 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 5 of 21 505 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.73e3 PCB-23 PCB-34 4.29e6 4.28e6 22.14 21.99 26/29 8.76e6 22.43 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 28/20 8.42e6 23.19 PCB-31 4.58e6 22.91 Abs. Int. 1.95e6 PCB-22 4.03e6 23.75 PCB-36 4.36e6 25.14 PCB-39 4.43e6 25.46 PCB-38 4.07e6 26.00 PCB-35 3.89e6 26.39 PCB-37 4.03e6 26.76 9.75e5 0% 22.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.67e3 PCB-34 PCB-23 4.40e6 4.28e6 22.14 21.99 23.0 26/29 8.87e6 22.43 24.0 25.0 26.0 27.0 28/20 8.46e6 23.19 PCB-31 4.70e6 22.91 Abs. Int. 2.01e6 PCB-22 4.03e6 23.75 PCB-36 4.44e6 25.14 PCB-39 4.58e6 25.46 PCB-38 4.19e6 26.00 PCB-35 3.89e6 26.39 PCB-37 4.12e6 26.76 1.00e6 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 9.02e7 23.16 Rel. Int. 100% 0.00e0 RT 27.0 0.00e0 RT Abs. Int. 2.37e7 ES-37 8.14e7 26.74 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.65e4 1.19e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.25e7 23.16 Rel. Int. 100% 27.0 0.00e0 RT Abs. Int. 2.20e7 ES-37 7.44e7 26.74 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.85e4 1.10e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1479, 2682 scc: 288-489 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 6 of 21 506 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-54 2.39e6 20.68 Rel. Int. 100% Abs. Int. 6.38e5 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.54e3 3.19e5 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.93e6 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.02e5 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.39e3 4.01e5 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.66e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.66e4 5.03e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.47e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 9.99e3 6.01e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6205, 6671 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 7 of 21 507 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.15e3 50/53 4.73e6 22.68 PCB-51 2.50e6 23.34 PCB-45 1.96e6 23.27 PCB-73 PCB-52 2.96e6 2.29e6 24.94 24.82 PCB-46 1.90e6 23.55 69/49 5.55e6 25.24 44/47… 7.19e6 25.74 PCB-48 2.34e6 25.52 59/62… 9.47e6 26.02 71/40 4.67e6 26.61 PCB-42 2.09e6 26.18 PCB-41 1.93e6 26.52 Abs. Int. 1.80e6 PCB-64 3.30e6 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.66e3 50/53 5.93e6 22.68 24.0 PCB-51 3.11e6 23.34 PCB-45 2.49e6 23.27 25.0 PCB-73 3.74e6 PCB-52 24.94 2.90e6 24.82 PCB-46 2.44e6 23.56 26.0 44/47… 9.21e6 25.74 69/49 7.04e6 25.24 PCB-48 2.89e6 25.52 59/62… 1.19e7 26.02 PCB-42 2.66e6 26.18 27.0 71/40 5.78e6 26.61 PCB-41 2.45e6 26.52 23.0 24.0 25.0 26.0 PCB-64 4.19e6 26.81 27.0 JS-52 4.09e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.14e6 0% 22.0 9.00e5 1.07e6 0.00e0 RT Abs. Int. 1.09e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.65e4 5.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.18e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.53e4 6.74e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7645, 3266 scc: 288-489 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 8 of 21 508 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 61/70... 1.30e7 29.05 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 1.09e4 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-57 3.19e6 28.16 PCB-63 3.39e6 28.75 PCB-55 3.12e6 29.47 PCB-60 PCB-80 3.07e6 3.59e6 30.43 30.11 PCB-79 3.56e6 31.76 PCB-78 2.91e6 32.25 PCB-81 2.96e6 32.63 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Abs. Int. 1.61e6 PCB-77 3.16e6 33.11 8.04e5 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 7.51e3 PCB-57 4.13e6 28.16 PCB-68 4.48e6 27.79 30.0 61/70... 1.64e7 29.04 32.0 PCB-60 3.93e6 30.11 PCB-63 4.46e6 PCB-66 PCB-56 3.90e6 3.93e6 28.75 29.33 29.91 PCB-80 4.50e6 30.43 PCB-79 4.54e6 31.76 34.0 PCB-78 3.70e6 32.25PCB-81 3.85e6 32.63 36.0 38.0 Abs. Int. 2.10e6 PCB-77 4.02e6 33.11 1.05e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 5.62e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.57e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.52e7 ES-77 5.84e7 33.09 7.62e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.04e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.96e4 36.0 38.0 0.00e0 RT Abs. Int. 1.93e7 ES-77 7.31e7 33.09 9.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6185, 5150 scc: 288-489 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 9 of 21 509 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-104 1.93e6 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.00e3 Abs. Int. 5.05e5 PCB-96 1.65e6 26.01 2.53e5 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.97e6 25.69 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.05e3 27.0 0.00e0 RT Abs. Int. 8.18e5 PCB-96 2.56e6 26.01 4.09e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.38e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 3.73e3 5.63e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.62e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.64e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 1.51e3 3.32e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5147, 8237 scc: 288-489 Revised: 30-Dec-2013 12:10 (LKB) Printed: 03-Jan-2014 17:10 Page 10 of 21 510 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 108/119... 1.11e7 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 4.67e4 PCB-103 1.79e6 27.71 100/93 3.34e6 28.50 PCB-88 1.48e6 28.98 PCB-121 2.30e6 30.00 113/90… 5.72e6 30.81 116/85 3.51e6 32.42 PCB-99 1.74e6 31.34 PCB-111 2.37e6 PCB-120 2.36e6 33.13 33.53 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 107/124 PCB-118 2.15e6 4.19e6 35.10 34.50 PCB-123 PCB-114 2.30e6 2.37e6 34.82 35.56 Abs. Int. 1.65e6 PCB-105 2.21e6 36.11 PCB-127 2.09e6 37.34 8.24e5 0% 28.0 30.0 32.0 108/119... 1.81e7 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 7.48e4 34.0 PCB-94 2.47e6 27.90 100/93 5.30e6 28.49 PCB-91 2.94e6 29.04 PCB-89 2.35e6 29.65 113/90… 9.02e6 30.80 PCB-112 PCB-92 3.65e6 2.50e6 31.44 30.32 116/85 PCB-115 5.50e6 3.71e6 32.42 32.62 PCB-111 PCB-117 PCB-110 3.73e6 PCB-120 3.63e6 3.34e6 3.68e6 33.13 32.33 32.53 33.53 36.0 PCB-118 107/124 3.56e6 6.71e6 35.10 34.50 PCB-123 PCB-114 3.66e6 3.82e6 34.82 35.56 38.0 Abs. Int. 2.65e6 PCB-105 3.47e6 36.11 PCB-127 3.36e6 37.34 1.33e6 0% 28.0 Rel. Int. 100% PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.45e3 30.0 32.0 34.0 CS/SS-111 6.50e7 33.11 JS-101 5.23e7 (6.56e7 + 4.07e7) * 100 pg/uL RRF(ES-105) = = 1.25 30.81 (5.23e7 + 3.30e7) * 100 pg/uL LKB 03-Jan-2014 11:50 36.0 ES-123 6.26e7 34.79 ES-114 ES-118 6.68e7 6.24e7 35.54 35.07 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.62e7 ES-105 6.56e7 36.08 8.09e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 4.02e7 33.11 JS-101 3.30e7 30.81 36.0 ES-123 3.97e7 34.79 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 1.58e3 ES-118 ES-114 3.88e7 4.05e7 35.07 35.54 38.0 0.00e0 RT Abs. Int. 9.82e6 ES-105 4.07e7 36.08 4.91e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6550, 0341 scc: 288-489 Revised: 03-Jan-2014 16:44 (LKB) Printed: 03-Jan-2014 17:10 Page 11 of 21 511 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-126 1.83e6 38.72 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.16e3 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Abs. Int. 4.48e5 (1.83e6 + 2.94e6) * 100 pg/uL RRF(PCB-126) = = 1.05 (5.56e7 + 3.53e7) * 5 pg/uL LKB 03-Jan-2014 11:49 2.24e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.89e5 PCB-126 2.94e6 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.88e3 3.44e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.35e7 ES-126 5.56e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.79e3 6.76e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.80e6 ES-126 3.53e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 5.68e3 4.40e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3455, 1978 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 12 of 21 512 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% PCB-155 PCB-150 3.19e6 2.94e6 30.97 30.67 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 8.82e2 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 147/149 139/140 4.16e6 4.18e6 34.12 34.64 PCB-145 2.77e6 31.55 PCB-148 2.07e6 32.82 153/168 5.13e6 36.71 151/135PCB-144 3.94e6 2.10e6 PCB-143 PCB-142 PCB-133 PCB-146 2.02e6 33.34 33.82 1.94e6 2.10e6 1.71e6 36.16 34.38 35.60 34.96 PCB-141 1.92e6 36.85 163/138… 6.11e6 37.77 PCB-164 PCB-160 2.71e6 2.64e6 37.48 37.91 0% 28.0 30.0 32.0 PCB-136 2.12e6 31.27 PCB-150 PCB-155 2.32e6 PCB-145 2.47e6 30.97 2.12e6 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 6.38e2 34.0 PCB-148 1.62e6 32.82 147/149 139/140 151/135 3.22e6 3.27e6 3.20e6 34.12 33.34 34.64 PCB-154 PCB-143 1.84e6 1.60e6PCB-131 33.55 34.38 1.37e6 34.81 36.0 PCB-165 1.99e6 35.94 38.0 153/168 4.00e6 36.71 163/138… 4.82e6 37.77 PCB-141 PCB-137 1.48e6 1.54e6 37.39 36.85 PCB-158 2.26e6 38.09 0% 28.0 30.0 32.0 34.0 36.0 ES-155 5.24e7 30.64 Rel. Int. 100% 38.0 ES-153 3.62e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.74e3 Abs. Int. 1.15e6 5.77e5 0.00e0 RT Abs. Int. 9.25e5 4.62e5 0.00e0 RT Abs. Int. 1.29e7 JS-138 3.20e7 37.73 6.47e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.95e7 30.64 Rel. Int. 100% ES-153 2.75e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 1.30e3 0.00e0 RT Abs. Int. 9.93e6 JS-138 2.44e7 37.73 4.96e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8742, 2751 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 13 of 21 513 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.57e6 38.83 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.74e3 PCB-159 2.84e6 39.64 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-162 2.72e6 39.88 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 156/157 5.34e6 41.28 Abs. Int. 1.12e6 PCB-169 2.67e6 44.00 PCB-167 2.97e6 40.29 5.58e5 0% 39.0 Rel. Int. 100% 40.0 128/166 3.66e6 38.83 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.62e3 PCB-159 2.30e6 39.64 PCB-162 2.25e6 39.88 41.0 42.0 43.0 44.0 45.0 Abs. Int. 8.94e5 156/157 4.28e6 41.28 PCB-169 2.18e6 44.00 PCB-167 2.45e6 40.29 4.47e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.04e8 41.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 ES-167 5.44e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 1.17e4 0.00e0 RT ES-169 5.02e7 43.98 9.59e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 8.00e7 41.26 Rel. Int. 100% Abs. Int. 1.48e7 ES-167 4.20e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 7.32e3 0.00e0 RT ES-169 3.88e7 43.98 7.39e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3801, 7947 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 14 of 21 514 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% PCB-188 1.73e6 35.56 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-179 PCB-184 1.60e6 1.50e6 35.84 36.30 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.31e2 PCB-186 1.53e6 37.00 Abs. Int. 4.22e5 PCB-178 1.15e6 38.13 2.11e5 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.57e6 35.56 PCB-179 1.47e6 35.84 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 5.34e2 37.0 PCB-176 1.59e6 36.59 PCB-186 1.45e6 37.00 38.0 0.00e0 RT Abs. Int. 3.84e5 PCB-178 1.06e6 38.12 1.92e5 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.78e7 35.54 Rel. Int. 100% Abs. Int. 6.94e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.23e3 CS/SS-178 1.72e7 38.10 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.62e7 35.54 Rel. Int. 100% CS/SS-178 1.54e7 38.10 0% 32.0 33.0 34.0 35.0 3.47e6 0.00e0 RT Abs. Int. 6.31e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.34e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 3.15e6 0.00e0 RT Abs. Int. 1.83e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2821, 9130 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 15 of 21 515 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.67e3 PCB-182 1.90e6 39.08 PCB-185 1.62e6 39.52 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 180/193 4.02e6 42.41 171/173 2.98e6 40.53 PCB-181 PCB-177 1.53e6 1.69e6 40.35 40.00 PCB-172 1.54e6 41.88 PCB-191 2.15e6 42.74 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-170 1.49e6 43.51 Abs. Int. 6.84e5 PCB-190 2.17e6 43.97 3.42e5 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.83e3 PCB-182 1.77e6 39.08 PCB-187 PCB-183 1.78e6 1.87e6 38.90 39.43 40.0 41.0 42.0 43.0 180/193 3.73e6 42.41 171/173 2.82e6 PCB-181 40.53 PCB-177 1.57e6 1.40e6 40.35 40.00 PCB-172 1.44e6 41.88 PCB-191 2.05e6 42.74 44.0 PCB-170 1.42e6 43.51 45.0 Abs. Int. 6.33e5 PCB-190 2.05e6 43.97 3.17e5 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.29e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 7.97e6 ES-170 2.76e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.75e3 0.00e0 RT 3.98e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.02e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 7.41e6 ES-170 2.56e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.23e3 0.00e0 RT 3.70e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6498, 0239 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 16 of 21 516 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-189 2.33e6 46.13 Abs. Int. 5.42e5 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.05e3 2.71e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.28e6 46.13 Abs. Int. 5.54e5 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 7.55e2 2.77e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.53e7 46.11 0.00e0 RT Abs. Int. 1.08e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 5.40e3 5.39e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.38e7 46.11 0.00e0 RT Abs. Int. 1.06e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 4.80e3 5.28e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0018, 8768 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 17 of 21 517 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-202 1.32e6 40.10 PCB-201 1.60e6 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.62e2 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 198/199 2.09e6 44.08 PCB-197 1.48e6 PCB-204 41.66 PCB-200 1.46e6 1.47e6 41.47 41.75 Abs. Int. 3.82e5 PCB-196 1.11e6 44.66 PCB-203 1.15e6 44.83 1.91e5 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.48e6 40.10 41.0 PCB-201 1.73e6 40.89 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.89e2 42.0 43.0 44.0 45.0 198/199 2.28e6 44.08 PCB-197 1.62e6 41.66 PCB-200 PCB-204 1.66e6 1.55e6 41.75 41.47 0.00e0 RT Abs. Int. 4.14e5 PCB-196 1.18e6 44.66 PCB-203 1.24e6 44.83 2.07e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.72e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.70e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.49e3 3.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.88e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.04e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.76e3 3.52e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9441, 6444 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 18 of 21 518 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.06e3 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-205 1.70e6 48.30 PCB-195 1.22e6 45.95 Abs. Int. 4.21e5 PCB-194 1.32e6 47.90 2.11e5 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.03e3 47.0 PCB-195 1.35e6 45.95 48.0 49.0 50.0 PCB-205 1.83e6 48.30 PCB-194 1.52e6 47.90 0.00e0 RT Abs. Int. 4.31e5 2.15e5 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.31e7 48.28 Rel. Int. 100% Abs. Int. 7.84e6 JS-194 2.67e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.61e3 0.00e0 RT 3.92e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.71e7 48.28 Rel. Int. 100% Abs. Int. 8.92e6 JS-194 2.90e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 4.69e3 0.00e0 RT 4.46e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1137, 3820 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 19 of 21 519 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 6.72e2 PCB-208 1.60e6 45.75 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-207 1.64e6 46.54 Abs. Int. 3.86e5 PCB-206 1.12e6 49.78 1.93e5 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 2.48e3 PCB-208 1.97e6 45.75 47.0 48.0 49.0 50.0 PCB-207 2.15e6 46.54 Abs. Int. 5.02e5 PCB-206 1.43e6 49.77 2.51e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.97e7 45.73 50.0 0.00e0 RT Abs. Int. 7.00e6 ES-206 2.11e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 1.84e3 3.50e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.69e7 45.73 50.0 Abs. Int. 8.58e6 ES-206 2.61e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.64e3 0.00e0 RT 4.29e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6056, 4422 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 20 of 21 520 of 711 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-209 1.82e6 51.25 Rel. Int. 100% Abs. Int. 3.69e5 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.61e2 1.84e5 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.56e6 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.28e5 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 4.70e2 1.64e5 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.46e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.08e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 9.58e2 3.54e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.92e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.03e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.69e2 3.01e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.31e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.65e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6862, 7261 scc: 288-489 Revised: 30-Dec-2013 12:10 (LKB) Printed: 03-Jan-2014 17:10 Page 21 of 21 521 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.10 32.62 36.09 35.55 35.08 34.80 38.71 41.26 40.28 43.98 46.12 51.23 6.72E+07 6.46E+07 5.36E+07 5.90E+07 5.55E+07 5.75E+07 4.48E+07 9.35E+07 5.18E+07 4.66E+07 4.39E+07 3.15E+07 0.78 Y 0.78 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 1.23 Y 1.21 Y 1.24 Y 1.04 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.14 1.12 1.13 1.23 1.22 1.23 1.12 1.12 1.20 1.16 1.07 1.09 -0.9% -0.2% 1.3% 2.2% 2.5% 1.5% 1.1% 2.3% 2.9% 2.8% -0.2% -2.1% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.02 14.34 14.60 20.36 17.72 26.72 20.65 33.08 32.60 25.66 36.07 35.53 35.06 34.78 38.69 36.65 30.63 41.24 40.26 43.96 43.48 42.41 35.52 46.10 40.07 48.27 49.74 45.71 51.21 2.19E+08 1.97E+08 9.59E+07 1.90E+08 9.32E+07 1.42E+08 7.49E+07 1.18E+08 1.16E+08 6.47E+07 9.52E+07 9.60E+07 9.11E+07 9.36E+07 8.01E+07 5.89E+07 8.37E+07 1.67E+08 8.66E+07 8.06E+07 4.93E+07 5.80E+07 4.92E+07 8.18E+07 5.16E+07 6.45E+07 4.32E+07 6.09E+07 5.77E+07 3.31 Y 3.36 Y 1.62 Y 1.57 Y 1.08 Y 1.09 Y 0.82 Y 0.79 Y 0.81 Y 1.68 Y 1.57 Y 1.64 Y 1.63 Y 1.59 Y 1.60 Y 1.29 Y 1.30 Y 1.28 Y 1.28 Y 1.28 Y 1.09 Y 1.09 Y 1.11 Y 1.01 Y 0.93 Y 0.89 Y 0.80 Y 0.80 Y 1.21 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.18 1.06 0.52 1.02 0.50 1.61 0.85 1.34 1.32 0.80 1.18 1.19 1.13 1.16 0.99 1.10 1.56 1.56 1.62 1.51 0.95 1.11 0.92 1.57 0.97 1.24 0.83 1.17 1.11 -1.3% -2.5% -1.2% -1.9% -0.9% -2.9% -0.9% -2.9% -3.5% 0.0% -1.7% -2.1% -2.4% -2.1% -3.2% -1.2% -1.6% -2.7% -3.0% -3.2% -0.1% -2.2% -2.1% -0.9% -0.5% -0.6% -0.1% -0.5% -0.3% Page 1 of 6 522 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.15 33.09 38.09 1.59E+08 9.83E+07 3.00E+07 1.09 Y 1.61 Y 1.10 Y 1.11 1.03 0.62 1.12 1.05 0.61 1.0% 2.1% -1.7% CS PCB-28 CS PCB-111 CS PCB-178 23.15 33.09 38.09 1.59E+08 9.83E+07 3.00E+07 1.09 Y 1.61 Y 1.10 Y 1.85 1.22 0.58 1.81 1.22 0.56 -1.8% 0.0% -3.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.60 24.78 30.80 37.72 47.87 1.86E+08 8.78E+07 8.05E+07 5.35E+07 5.22E+07 1.55 Y 0.82 Y 1.58 Y 1.28 Y 0.91 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.04 14.36 14.62 20.38 17.73 26.74 20.67 25.68 30.65 35.54 40.09 48.28 45.73 49.76 1.06E+08 1.02E+08 6.07E+07 9.79E+07 5.43E+07 7.81E+07 5.09E+07 4.68E+07 5.34E+07 3.10E+07 2.75E+07 3.40E+07 3.44E+07 2.40E+07 3.22 Y 3.25 Y 1.59 Y 1.64 Y 1.06 Y 0.99 Y 0.82 Y 0.64 Y 1.27 Y 1.06 Y 0.92 Y 0.92 Y 0.77 Y 0.79 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.97 1.04 1.27 1.03 1.17 1.10 1.36 1.45 1.27 1.26 1.06 1.06 1.13 1.11 1.7% 2.8% 2.7% 1.2% 1.5% 2.2% 0.6% 0.9% 1.2% -0.6% 1.0% -0.5% 0.6% -0.3% Page 2 of 6 523 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 12.04 14.17 14.36 14.62 14.80 16.62 16.78 17.01 17.32 17.44 19.01 19.80 20.09 20.38 17.73 19.51 19.91 20.11 20.24 20.34 20.82 21.98 22.13 22.42 22.61 22.89 23.18 23.36 23.74 25.13 25.45 25.99 26.38 26.74 20.67 22.67 23.26 23.33 23.54 24.80 24.93 25.03 25.23 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 1.06E+08 1.07E+08 1.02E+08 6.07E+07 9.81E+07 9.11E+07 1.03E+08 9.79E+07 9.70E+07 9.83E+07 1.14E+08 9.79E+07 1.94E+08 9.79E+07 5.43E+07 1.46E+08 6.21E+07 8.52E+07 8.13E+07 4.64E+07 8.97E+07 8.15E+07 8.33E+07 1.69E+08 8.39E+07 8.91E+07 1.65E+08 1.71E+08 7.72E+07 8.43E+07 8.82E+07 8.09E+07 7.62E+07 7.81E+07 5.09E+07 1.04E+08 4.29E+07 5.41E+07 4.19E+07 4.97E+07 6.50E+07 4.44E+07 1.22E+08 RA 3.22 Y 3.26 Y 3.25 Y 1.59 Y 1.61 Y 1.64 Y 1.63 Y 1.63 Y 1.62 Y 1.64 Y 1.62 Y 1.64 Y 1.63 Y 1.64 Y 1.06 Y 1.05 Y 1.05 Y 1.06 Y 1.04 Y 1.06 Y 1.06 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.99 Y 0.99 Y 0.97 Y 0.98 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.82 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.97 1.08 1.04 1.27 2.05 0.96 1.09 1.03 1.02 1.04 1.20 1.03 1.02 1.03 1.17 1.57 1.33 1.83 1.74 1.00 1.93 1.15 1.18 1.20 1.18 1.26 1.17 1.21 1.09 1.19 1.24 1.14 1.08 1.10 1.36 0.90 0.74 0.93 0.72 0.86 1.12 0.77 1.05 Dev'n 1.7% 4.8% 2.8% 2.7% 3.2% 1.6% 4.1% 3.6% 2.0% 0.3% 1.9% 2.0% 3.1% 1.2% 1.5% 1.9% 2.2% 0.7% 1.2% -1.0% 0.3% 1.4% 1.8% 2.1% 2.3% 2.6% 3.0% 2.8% 0.9% 1.6% 2.8% 3.4% 3.5% 2.2% 0.6% 2.6% -3.3% 8.7% 3.5% 1.6% 0.9% 7.9% 3.2% 524 of 711 PCB QC Summary - Ax2 Detail Lab ID: CS3_131220_PCB_XA Acquired: 20-DEC-2013 18:04 Datafile: 131220X05 Name RT PCB-48 22'45-TeCB 25.51 PCB-44/47/65 ...-TeCB 25.73 PCB-59/62/75 ...-TeCB 26.01 PCB-42 22'34'-TeCB 26.17 PCB-41 22'34-TeCB 26.51 PCB-71/40 23'4'6/22'33'-TeCB 26.60 PCB-64 234'6-TeCB 26.80 PCB-72 23'55'-TeCB 27.52 PCB-68 23'45'-TeCB 27.78 PCB-57 233'5-TeCB 28.15 PCB-58 233'5'-TeCB 28.35 PCB-67 23'45-TeCB 28.51 PCB-63 234'5-TeCB 28.74 PCB-61/70/74/76 ...-TeCB 29.03 PCB-66 23'44'-TeCB 29.32 PCB-55 233'4-TeCB 29.46 PCB-56 233'4'-TeCB 29.90 PCB-60 2344'-TeCB 30.09 PCB-80 33'55'-TeCB 30.42 PCB-79 33'45'-TeCB 31.75 PCB-78 33'45-TeCB 32.24 PCB-104 22'466'-PeCB 25.68 PCB-96 22'366'-PeCB 26.00 PCB-103 22'45'6-PeCB 27.69 PCB-94 22'356'-PeCB 27.89 PCB-95 22'35'6-PeCB 28.27 PCB-100/93 22'44'6/22'356-PeCB 28.48 PCB-102 22'456'-PeCB 28.59 PCB-98 22'34'6'-PeCB 28.66 PCB-88 22'346-PeCB 28.96 PCB-91 22'34'6-PeCB 29.03 PCB-84 22'33'6-PeCB 29.22 PCB-89 22'346'-PeCB 29.64 PCB-121 23'45'6-PeCB 29.99 PCB-92 22'355'-PeCB 30.31 PCB-113/90/101 ...-PeCB 30.79 PCB-83 22'33'5-PeCB 31.23 PCB-99 22'44'5-PeCB 31.33 PCB-112 233'56-PeCB 31.43 PCB-108/119/86/97/125...-PeCB 31.78 PCB-117 234'56-PeCB 32.31 PCB-116/85 23456/22'344'-PeCB 32.41 PCB-110 233'4'6-PeCB 32.52 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 5.03E+07 1.61E+08 2.11E+08 4.56E+07 4.24E+07 1.01E+08 7.33E+07 7.21E+07 7.57E+07 6.97E+07 6.93E+07 7.46E+07 7.70E+07 2.84E+08 6.58E+07 6.61E+07 6.57E+07 6.65E+07 7.84E+07 7.58E+07 6.37E+07 4.68E+07 4.07E+07 4.49E+07 3.89E+07 4.15E+07 8.23E+07 4.80E+07 3.74E+07 3.48E+07 4.85E+07 3.51E+07 3.72E+07 5.76E+07 3.91E+07 1.40E+08 3.39E+07 4.26E+07 5.82E+07 2.85E+08 5.48E+07 8.79E+07 5.86E+07 RA 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.77 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.64 Y 0.65 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.87 0.93 1.21 0.79 0.73 0.87 1.27 1.25 1.31 1.20 1.20 1.29 1.33 1.23 1.14 1.14 1.13 1.15 1.35 1.31 1.10 1.45 1.26 0.96 0.83 0.89 0.88 1.03 0.80 0.74 1.04 0.75 0.80 1.23 0.84 1.00 0.72 0.91 1.24 1.01 1.17 0.94 1.25 Dev'n 3.5% 2.8% 4.0% 3.2% 5.4% 1.7% 3.7% 3.0% 2.4% 3.4% 1.6% 2.3% 2.5% 2.3% 3.1% 1.9% 2.2% 1.2% 3.1% 0.3% 3.6% 0.9% 2.3% 3.1% 3.9% 2.5% 1.9% 6.0% 5.5% -6.9% 9.9% 4.8% 4.3% 2.6% 1.9% 1.0% 1.2% -1.2% 6.6% 3.6% 2.9% -0.1% 12.0% 525 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 32.61 32.80 33.12 33.52 34.49 34.69 34.91 35.38 37.33 30.65 30.81 30.96 31.26 31.53 32.81 33.33 33.54 33.80 34.11 34.28 34.36 34.63 34.80 34.95 35.18 35.59 35.93 36.14 36.26 36.69 36.84 37.18 37.38 37.46 37.76 37.89 38.08 38.81 39.63 39.87 35.54 35.82 36.29 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 5.15E+07 3.29E+07 5.86E+07 5.80E+07 1.06E+08 6.23E+07 5.24E+07 4.86E+07 5.29E+07 5.34E+07 4.87E+07 5.03E+07 4.58E+07 4.68E+07 3.50E+07 6.71E+07 3.92E+07 3.50E+07 6.95E+07 2.62E+07 3.47E+07 7.06E+07 3.02E+07 2.97E+07 3.05E+07 3.33E+07 4.19E+07 3.49E+07 4.54E+07 8.69E+07 3.24E+07 2.87E+07 3.23E+07 4.64E+07 1.04E+08 4.57E+07 4.80E+07 7.91E+07 4.91E+07 4.82E+07 3.10E+07 2.89E+07 2.78E+07 RA 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 1.27 Y 1.29 Y 1.27 Y 1.28 Y 1.28 Y 1.29 Y 1.28 Y 1.27 Y 1.28 Y 1.26 Y 1.29 Y 1.29 Y 1.29 Y 1.28 Y 1.27 Y 1.29 Y 1.27 Y 1.29 Y 1.26 Y 1.29 Y 1.27 Y 1.26 Y 1.26 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.29 Y 1.23 Y 1.23 Y 1.22 Y 1.06 Y 1.08 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.10 0.70 1.25 1.24 1.14 1.33 1.12 1.01 1.11 1.27 1.16 1.20 1.09 1.12 1.19 1.14 1.33 1.19 1.18 0.89 1.18 1.20 1.03 1.01 1.03 1.13 1.42 1.19 1.54 1.48 1.10 0.97 1.10 1.58 1.17 1.55 1.63 0.91 1.13 1.11 1.26 1.17 1.13 Dev'n -5.0% 0.8% 2.6% 2.4% 3.4% 6.3% 1.3% 1.9% 1.5% 1.2% -0.8% 2.2% 2.6% 0.3% 0.6% 0.1% -0.9% 0.5% 0.4% -3.9% 4.3% -0.5% 0.0% 1.8% 0.4% -0.2% 1.0% -1.3% 1.3% 1.3% 1.2% 0.2% -5.5% 5.2% -1.4% 2.4% -1.8% 1.5% 1.7% 3.8% -0.6% 0.9% 0.2% 526 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 36.58 36.98 38.11 38.66 38.89 39.07 39.42 39.50 39.61 39.98 40.33 40.52 41.87 42.12 42.39 42.73 43.50 43.95 40.09 40.88 41.46 41.65 41.73 44.06 44.64 44.81 45.94 47.89 48.28 45.73 46.52 49.76 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 3.08E+07 2.82E+07 2.06E+07 3.12E+07 3.32E+07 3.55E+07 3.70E+07 2.99E+07 2.90E+07 2.76E+07 3.21E+07 5.60E+07 2.94E+07 3.83E+07 7.38E+07 4.06E+07 2.83E+07 4.10E+07 2.75E+07 3.19E+07 2.88E+07 2.98E+07 3.01E+07 4.14E+07 2.18E+07 2.26E+07 2.41E+07 2.69E+07 3.40E+07 3.44E+07 3.65E+07 2.40E+07 RA 1.08 Y 1.09 Y 1.08 Y 1.07 Y 1.07 Y 1.06 Y 1.06 Y 1.07 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 1.05 Y 1.07 Y 1.06 Y 1.08 Y 1.08 Y 1.05 Y 0.92 Y 0.91 Y 0.93 Y 0.91 Y 0.93 Y 0.91 Y 0.91 Y 0.91 Y 0.93 Y 0.91 Y 0.92 Y 0.77 Y 0.78 Y 0.79 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.25 1.14 0.84 1.08 1.15 1.22 1.28 1.03 1.00 0.95 1.11 0.97 1.02 1.32 1.27 1.40 1.15 1.66 1.06 1.24 1.12 1.15 1.16 0.80 0.84 0.88 0.75 0.84 1.06 1.13 1.20 1.11 Dev'n 1.6% 1.7% -0.7% 0.3% 0.7% 4.2% 6.0% -2.8% 1.1% 0.0% 1.7% 1.8% 2.7% 2.5% 1.0% 0.4% 1.0% 0.2% 1.0% 1.2% 0.0% -3.2% 5.1% -0.8% 1.1% 0.2% -2.5% -0.9% -0.5% 0.6% 0.7% -0.3% 527 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.31e7 2.66e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.72e7 1.36e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.99e7 9.97e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.02e7 1.01e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.14e7 5.71e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.75e6 2.88e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.38e6 2.69e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 297-225 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:10 Page 1 of 21 528 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-1 8.10e7 12.04 Rel. Int. 100% PCB-2 8.16e7 14.17 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.95e3 Abs. Int. 3.37e7 PCB-3 7.81e7 14.36 1.68e7 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.51e7 12.04 Rel. Int. 100% PCB-2 2.50e7 14.17 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 4.61e3 0.00e0 16.0 RT Abs. Int. 1.02e7 PCB-3 2.40e7 14.36 5.12e6 0% 11.0 12.0 13.0 14.0 ES-1 1.68e8 12.02 Rel. Int. 100% 15.0 Abs. Int. 6.63e7 ES-3 1.52e8 14.34 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 8.09e3 0.00e0 16.0 RT 3.32e7 0% 11.0 12.0 13.0 14.0 ES-1 5.08e7 12.02 Rel. Int. 100% 15.0 Abs. Int. 2.10e7 ES-3 4.52e7 14.34 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.05e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.31e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1305, 6088 scc: 297-225 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:10 Page 2 of 21 529 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Rel. Int. 100% PCB-10 6.05e7 14.80 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.28e3 PCB-4 3.73e7 14.62 1.01e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.76e7 14.80 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.69e4 PCB-4 2.35e7 14.61 12.0 13.0 14.0 15.0 ES-4 5.93e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.25e7 6.24e6 0% 11.0 Abs. Int. 2.01e7 0.00e0 16.0 RT Abs. Int. 1.97e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.17e3 9.87e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.66e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.25e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.04e3 6.25e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.31e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0655, 5434 scc: 297-225 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 3 of 21 530 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.09e4 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-6 6.06e7 17.01 PCB-9 5.66e7 16.62 PCB-14 7.06e7 19.01 PCB-5 6.00e7 17.32 PCB-8 6.10e7 17.44 PCB-11 6.08e7 19.80 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 13/12 1.20e8 20.09 Abs. Int. 2.06e7 PCB-15 6.08e7 20.38 1.03e7 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.56e4 PCB-9 3.46e7 16.62 PCB-7 3.94e7 16.78 18.0 19.0 PCB-14 4.35e7 19.01 PCB-5 3.70e7 17.32 PCB-8 3.73e7 17.44 20.0 PCB-11 3.71e7 19.80 13/12 7.35e7 20.09 21.0 Abs. Int. 1.26e7 PCB-15 3.71e7 20.38 6.30e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.13e8 16.60 21.0 ES-15 1.16e8 20.36 0.00e0 RT Abs. Int. 3.59e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.60e4 1.79e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.28e7 16.60 21.0 0.00e0 RT Abs. Int. 2.31e7 ES-15 7.40e7 20.36 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 1.25e4 1.15e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4598, 0207 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 4 of 21 531 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 30/18 7.47e7 19.51 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.64e3 PCB-19 2.79e7 17.73 PCB-17 3.19e7 19.91 PCB-27 4.38e7 20.11 PCB-24 4.15e7 20.24 PCB-16 2.39e7 20.34 Abs. Int. 2.03e7 PCB-32 4.61e7 20.82 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 7.11e7 19.51 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 4.04e3 PCB-19 2.64e7 17.73 PCB-17 3.03e7 19.91 21.0 PCB-24 3.98e7 20.24 PCB-27 4.15e7 20.11 Rel. Int. 100% 18.0 19.0 PCB-16 2.25e7 20.34 20.0 PCB-32 4.36e7 20.82 21.0 9.59e6 0.00e0 RT Abs. Int. 1.95e7 ES-19 4.84e7 17.72 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 8.84e4 0.00e0 RT Abs. Int. 1.92e7 0% 17.0 1.01e7 9.76e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.80e7 ES-19 4.48e7 17.72 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.99e4 0.00e0 RT 9.01e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2677, 3721 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 5 of 21 532 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 28/20 8.20e7 23.18 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 7.46e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-23 PCB-34 4.15e7 4.05e7 22.13 21.98 26/29 8.42e7 22.42 PCB-31 4.44e7 22.89 Abs. Int. 1.93e7 PCB-22 3.82e7 23.74 PCB-36 4.19e7 25.13 PCB-39 4.39e7 25.45 PCB-38 4.03e7 25.99 PCB-35 3.79e7 26.38 PCB-37 3.89e7 26.74 9.66e6 0% 22.0 24.0 25.0 26.0 27.0 28/20 8.32e7 23.18 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 6.03e3 23.0 PCB-23 PCB-34 4.18e7 4.10e7 22.13 21.98 26/29 8.52e7 22.42 PCB-31 4.47e7 22.89 Abs. Int. 1.94e7 PCB-22 3.90e7 23.74 PCB-36 4.24e7 25.13 PCB-39 4.43e7 25.45 PCB-38 4.06e7 25.99 PCB-35 3.84e7 26.38 PCB-37 3.92e7 26.74 9.69e6 0% 22.0 23.0 CS/SS-28 8.29e7 23.15 Rel. Int. 100% TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.92e4 24.0 25.0 26.0 27.0 23.0 24.0 1.13e7 25.0 26.0 CS/SS-28 7.62e7 23.15 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.27e7 ES-37 7.38e7 26.72 (8.29e7 + 7.62e7) RRF(CS-28) = = 1.81 (3.96e7 + 4.82e7) LKB 03-Jan-2014 15:10 0% 22.0 0.00e0 RT 27.0 Abs. Int. 2.07e7 ES-37 6.79e7 26.72 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 4.37e4 0.00e0 RT 1.04e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2630, 0050 scc: 297-225 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 6 of 21 533 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-54 2.30e7 20.67 Rel. Int. 100% Abs. Int. 6.33e6 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.43e3 3.17e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.80e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.75e6 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.25e3 3.87e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.37e7 20.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.21e6 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.87e4 4.60e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.12e7 20.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.10e4 5.62e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5811, 4868 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 7 of 21 534 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.05e3 50/53 4.60e7 22.67 PCB-51 2.40e7 23.33 PCB-45 1.89e7 23.26 PCB-73 PCB-52 2.87e7 2.19e7 24.93 24.80 PCB-46 1.84e7 23.54 69/49 5.38e7 25.23 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 44/47… 7.13e7 25.73 PCB-48 2.21e7 25.51 59/62… 9.32e7 26.01 71/40 4.48e7 26.60 PCB-42 2.01e7 26.17 PCB-41 1.85e7 26.51 Abs. Int. 1.68e7 PCB-64 3.24e7 26.80 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 2.01e3 50/53 5.81e7 22.67 24.0 PCB-51 3.01e7 23.33 PCB-45 2.41e7 23.26 25.0 PCB-73 3.63e7 PCB-52 24.93 2.78e7 24.80 PCB-46 2.35e7 23.54 26.0 69/49 6.83e7 25.23 44/47… 9.00e7 25.73 PCB-48 2.81e7 25.51 27.0 59/62… 1.17e8 26.00 71/40 5.63e7 26.60 PCB-42 2.55e7 26.17 PCB-41 2.39e7 26.51 23.0 24.0 25.0 26.0 PCB-64 4.09e7 26.80 27.0 JS-52 3.96e7 24.78 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.12e7 0% 22.0 8.42e6 1.06e7 0.00e0 RT Abs. Int. 1.03e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 3.01e4 5.16e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 4.82e7 24.78 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.93e4 6.39e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6030, 5973 scc: 297-225 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 8 of 21 535 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 61/70... 1.24e8 29.03 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 8.75e4 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-68 3.33e7 27.78 PCB-67 3.27e7 28.51 PCB-55 2.90e7 29.46 PCB-60 PCB-80 2.92e7 3.46e7 30.42 30.09 PCB-79 3.33e7 31.75 PCB-78 2.80e7 32.24PCB-81 2.83e7 32.62 Abs. Int. 1.54e7 PCB-77 2.95e7 33.10 7.71e6 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 5.75e4 PCB-57 3.91e7 28.15 PCB-68 4.24e7 27.78 30.0 61/70... 1.59e8 29.03 32.0 PCB-60 3.73e7 30.09 PCB-63 PCB-66 4.34e7 3.69e7 PCB-56 3.69e7 28.74 29.31 29.90 PCB-80 4.38e7 30.42 PCB-79 4.25e7 31.74 34.0 PCB-78 3.56e7 32.24PCB-81 3.63e7 32.62 36.0 38.0 Abs. Int. 1.98e7 PCB-77 3.77e7 33.10 9.88e6 0% 28.0 Rel. Int. 100% TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.69e4 30.0 32.0 34.0 ES-81 5.16e7 32.60 (5.16e7 + 6.42e7) * 100 pg/uL = 1.32 (3.96e7 + 4.82e7) * 100 pg/uL LKB 03-Jan-2014 15:09 RRF(ES-81) = 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.42e7 ES-77 5.20e7 33.08 7.08e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.42e7 32.60 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 2.60e4 36.0 38.0 0.00e0 RT Abs. Int. 1.77e7 ES-77 6.59e7 33.08 8.85e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8755, 8946 scc: 297-225 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 9 of 21 536 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-104 1.83e7 25.68 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 8.52e2 Abs. Int. 4.64e6 PCB-96 1.60e7 26.00 2.32e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.84e7 25.68 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.03e3 27.0 0.00e0 RT Abs. Int. 7.28e6 PCB-96 2.46e7 25.99 3.64e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.06e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 1.98e3 5.07e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.41e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.06e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.06e3 3.03e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9856, 2300 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 10 of 21 537 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 108/119... 1.09e8 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 1.43e5 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-103 1.72e7 27.69 PCB-91 1.86e7 100/93 29.03 3.15e7 28.48 PCB-88 1.32e7 28.96 PCB-121 2.21e7 29.99 113/90… 5.36e7 30.79 116/85 3.39e7 32.41 PCB-99 1.63e7 31.33 PCB-111 2.24e7 PCB-120 2.22e7 33.12 33.52 107/124 PCB-118 2.13e7 4.05e7 35.08 34.49 PCB-114 PCB-123 2.27e7 2.21e7 35.55 34.80 Abs. Int. 1.58e7 PCB-105 2.05e7 36.09 PCB-127 2.01e7 37.33 7.92e6 0% 28.0 30.0 32.0 36.0 38.0 108/119... 1.76e8 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 1.25e5 34.0 PCB-94 2.39e7 27.88 100/93 5.08e7 28.48 PCB-91 2.99e7 29.03 PCB-89 2.31e7 29.64 113/90… 8.61e7 30.79 PCB-112 3.59e7 PCB-92 31.43 2.43e7 30.31 116/85 PCB-115 5.40e7 3.18e7 PCB-111 32.40 32.61 3.62e7 33.12 PCB-117 PCB-110 PCB-120 3.38e7 3.61e7 PCB-82 3.58e7 32.31 32.52 2.03e7 33.52 32.80 107/124 PCB-118 3.42e7 6.57e7 35.08 34.49 PCB-114 PCB-123 3.63e7 3.54e7 35.55 34.80 Abs. Int. 2.53e7 PCB-105 3.31e7 36.09 PCB-127 3.28e7 37.33 1.27e7 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 6.07e7 33.09 JS-101 4.93e7 30.80 36.0 ES-118 ES-114 5.96e7 35.53 ES-123 5.64e7 5.74e7 35.06 34.78 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.18e3 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.48e7 ES-105 5.82e7 36.07 7.42e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 3.77e7 33.10 JS-101 3.12e7 30.80 36.0 ES-118 ES-114 ES-123 3.47e7 3.63e7 3.62e7 35.06 35.53 34.78 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.13e3 38.0 0.00e0 RT Abs. Int. 9.26e6 ES-105 3.70e7 36.07 4.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4291, 2615 scc: 297-225 Revised: 03-Jan-2014 16:45 (LKB) Printed: 03-Jan-2014 17:11 Page 11 of 21 538 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Abs. Int. 3.89e6 PCB-126 1.72e7 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 2.70e3 1.94e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.44e6 PCB-126 2.76e7 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 3.20e3 3.22e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.21e7 ES-126 4.93e7 38.69 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.26e3 6.04e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.54e6 ES-126 3.09e7 38.69 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 8.80e3 3.77e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5774, 8779 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 12 of 21 539 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% PCB-150 PCB-155 2.82e7 2.99e7 30.96 30.65 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.06e2 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 147/149 139/140 3.88e7 3.97e7 34.11 34.63 PCB-145 2.62e7 31.53 PCB-148 1.97e7 32.81 153/168 4.86e7 36.69 151/135PCB-144 3.76e7 1.97e7 PCB-143 PCB-142 PCB-133 PCB-146 1.95e7 1.86e7 1.95e7 33.33 33.80 1.66e7 36.14 34.36 35.59 34.95 PCB-141 1.81e7 36.84 163/138… 5.81e7 37.76 PCB-160 PCB-164 2.60e7 2.56e7 37.46 37.89 0% 28.0 30.0 32.0 PCB-152 2.13e7 30.81 PCB-150 PCB-155 2.21e7 2.35e7 30.95 30.65 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.05e3 PCB-145 2.06e7 31.53 34.0 PCB-148 1.53e7 32.81 147/149 139/140 151/135 3.08e7 3.09e7 2.95e7 34.11 34.63 33.33 PCB-154 PCB-143 1.73e7 1.51e7PCB-131 33.54 34.36 1.32e7 34.80 36.0 38.0 153/168 3.83e7 36.69 PCB-165 1.83e7 35.93 163/138… 4.56e7 37.75 PCB-141 PCB-137 1.43e7 1.43e7 37.38 36.84 PCB-158 2.10e7 38.08 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.73e7 30.63 Rel. Int. 100% ES-153 3.32e7 36.65 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.52e3 Abs. Int. 1.10e7 5.51e6 0.00e0 RT Abs. Int. 8.70e6 4.35e6 0.00e0 RT Abs. Int. 1.17e7 JS-138 3.00e7 37.72 5.87e6 0% 28.0 30.0 32.0 34.0 36.0 ES-155 3.64e7 30.63 Rel. Int. 100% 38.0 ES-153 2.57e7 36.65 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 1.83e3 0.00e0 RT Abs. Int. 8.88e6 JS-138 2.35e7 37.72 4.44e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0360, 4999 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 13 of 21 540 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.35e7 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.95e3 PCB-159 2.71e7 39.63 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-162 2.65e7 39.87 156/157 5.15e7 41.26 Abs. Int. 1.02e7 (2.84e7 + 2.34e7) * 100 pg/uL = 1.20 (4.86e7 + 3.80e7) * 50 pg/uL LKB 03-Jan-2014 11:58 RRF(PCB-167) = PCB-167 2.84e7 40.28 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-169 2.58e7 43.98 5.09e6 0% 39.0 Rel. Int. 100% 128/166 3.55e7 38.81 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 3.14e3 40.0 PCB-162 PCB-159 2.17e7 2.20e7 39.87 39.63 41.0 42.0 43.0 44.0 45.0 156/157 4.20e7 41.26 Abs. Int. 8.23e6 PCB-169 2.08e7 43.98 PCB-167 2.34e7 40.28 4.11e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 9.34e7 41.24 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.68e7 ES-167 4.86e7 40.26 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 7.61e3 0.00e0 RT ES-169 4.52e7 43.96 8.40e6 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 3.80e7 40.26 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 8.72e3 42.0 43.0 44.0 45.0 ES-156/157 7.32e7 41.24 0.00e0 RT Abs. Int. 1.31e7 ES-169 3.54e7 43.96 6.56e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6303, 7049 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 14 of 21 541 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% PCB-188 1.60e7 35.54 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-179 PCB-184 1.50e7 1.45e7 35.82 36.29 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.15e2 PCB-186 1.47e7 36.98 Abs. Int. 3.96e6 PCB-178 1.07e7 38.11 1.98e6 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.50e7 35.54 PCB-179 1.39e7 35.82 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.04e2 37.0 PCB-176 1.48e7 36.58 PCB-186 1.35e7 36.98 38.0 Abs. Int. 3.73e6 PCB-178 9.89e6 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.59e7 35.52 Rel. Int. 100% CS/SS-178 1.57e7 38.09 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.33e7 35.52 Rel. Int. 100% CS/SS-178 1.42e7 38.09 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.20e6 0.00e0 RT Abs. Int. 5.64e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.22e3 31.0 1.86e6 Abs. Int. 6.41e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.23e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 2.82e6 0.00e0 RT Abs. Int. 2.02e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9174, 9814 scc: 297-225 PKD: 30-Dec-2013 12:20 Printed: 03-Jan-2014 17:11 Page 15 of 21 542 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 4.43e3 PCB-183 1.91e7 PCB-182 39.42 PCB-185 1.83e7 1.54e7 39.07 39.50 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 180/193 3.80e7 42.39 171/173 2.87e7 PCB-181 40.52 PCB-177 1.65e7 1.42e7 40.33 39.98 PCB-172 1.51e7 41.87 PCB-191 2.11e7 42.73 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-170 1.47e7 43.50 Abs. Int. 6.40e6 PCB-190 2.10e7 43.95 3.20e6 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 3.72e3 PCB-182 1.72e7 39.07 PCB-183 PCB-187 1.79e7 1.61e7 39.42 38.89 40.0 41.0 42.0 43.0 180/193 3.58e7 42.39 171/173 2.72e7 PCB-181 40.52 PCB-177 1.56e7 1.34e7 40.33 39.98 PCB-172 1.43e7 41.87 PCB-191 1.95e7 42.73 44.0 45.0 Abs. Int. 6.07e6 PCB-190 2.01e7 43.95 PCB-170 1.36e7 43.50 3.04e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.02e7 42.41 Rel. Int. 100% 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 7.37e6 ES-170 2.58e7 43.48 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.18e3 3.69e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.77e7 42.41 Rel. Int. 100% 44.0 45.0 Abs. Int. 6.77e6 ES-170 2.36e7 43.48 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.05e3 0.00e0 RT 3.39e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1388, 8460 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 16 of 21 543 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-189 2.24e7 46.12 Abs. Int. 5.28e6 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.74e3 2.64e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.15e7 46.12 Abs. Int. 5.00e6 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 2.13e3 2.50e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.12e7 46.10 0.00e0 RT Abs. Int. 1.01e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 3.83e3 5.04e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.06e7 46.10 0.00e0 RT Abs. Int. 9.92e6 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.31e3 4.96e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7725, 6868 scc: 297-225 PKD: 30-Dec-2013 12:20 Printed: 03-Jan-2014 17:11 Page 17 of 21 544 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-202 1.32e7 40.09 Rel. Int. 100% PCB-201 1.52e7 40.88 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.54e2 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 198/199 1.98e7 44.06 PCB-197 1.42e7 PCB-204 41.65 PCB-200 1.39e7 1.45e7 41.46 41.73 Abs. Int. 3.62e6 PCB-196 1.04e7 44.64 PCB-203 1.08e7 44.81 1.81e6 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.43e7 40.09 41.0 PCB-201 1.67e7 40.88 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.75e2 42.0 43.0 44.0 45.0 198/199 2.17e7 44.06 PCB-197 1.55e7 PCB-204 41.65 PCB-200 1.49e7 1.56e7 41.46 41.73 0.00e0 RT Abs. Int. 3.99e6 PCB-196 1.14e7 44.64 PCB-203 1.18e7 44.81 1.99e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.49e7 40.07 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.20e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.53e3 3.10e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.68e7 40.07 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.66e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.32e3 3.33e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2479, 9839 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 18 of 21 545 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.61e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-205 1.63e7 48.28 PCB-195 1.16e7 45.94 Abs. Int. 3.80e6 PCB-194 1.29e7 47.89 1.90e6 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 2.48e3 47.0 48.0 49.0 50.0 PCB-205 1.77e7 48.28 PCB-195 1.25e7 45.94 0.00e0 RT Abs. Int. 4.16e6 PCB-194 1.41e7 47.88 2.08e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.04e7 48.27 Rel. Int. 100% Abs. Int. 7.24e6 JS-194 2.49e7 47.87 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.67e3 0.00e0 RT 3.62e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.40e7 48.27 Rel. Int. 100% Abs. Int. 8.13e6 JS-194 2.73e7 47.87 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.23e3 0.00e0 RT 4.07e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9372, 9268 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 19 of 21 546 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.22e3 PCB-208 1.50e7 45.73 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-207 1.60e7 46.52 Abs. Int. 3.79e6 PCB-206 1.06e7 49.76 1.89e6 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.78e3 PCB-208 1.94e7 45.73 47.0 48.0 49.0 50.0 PCB-207 2.05e7 46.52 Abs. Int. 4.79e6 PCB-206 1.34e7 49.76 2.40e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.71e7 45.71 50.0 0.00e0 RT Abs. Int. 6.38e6 ES-206 1.92e7 49.74 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.45e3 3.19e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.39e7 45.71 50.0 Abs. Int. 8.08e6 ES-206 2.40e7 49.74 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 3.05e3 0.00e0 RT 4.04e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5390, 1741 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 20 of 21 547 of 711 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-209 1.71e7 51.23 Rel. Int. 100% Abs. Int. 3.49e6 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 6.63e2 1.74e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.44e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.92e6 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.15e2 1.46e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.16e7 51.21 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.46e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 7.77e2 3.23e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.62e7 51.21 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.44e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.95e2 2.72e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.38e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.69e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6160, 7361 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 21 of 21 548 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.10 32.62 36.10 35.56 35.09 34.81 38.71 41.27 40.29 43.99 46.13 51.25 6.61E+08 6.42E+08 5.26E+08 5.80E+08 5.38E+08 5.67E+08 4.45E+08 9.01E+08 4.96E+08 4.52E+08 4.15E+08 2.92E+08 0.78 Y 0.78 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.63 Y 1.22 Y 1.23 Y 1.24 Y 1.05 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.14 1.15 1.24 1.22 1.23 1.14 1.11 1.18 1.14 1.10 1.10 1.7% 1.9% 3.3% 3.3% 2.6% 1.3% 2.8% 1.1% 1.4% 1.2% 2.3% -1.4% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.03 14.35 14.61 20.37 17.72 26.73 20.66 33.08 32.61 25.66 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.25 40.27 43.97 43.49 42.42 35.53 46.11 40.08 48.28 49.75 45.72 51.22 2.53E+08 2.32E+08 1.12E+08 2.25E+08 1.10E+08 1.69E+08 8.74E+07 1.41E+08 1.41E+08 7.69E+07 1.14E+08 1.17E+08 1.10E+08 1.15E+08 9.79E+07 6.88E+07 9.70E+07 2.03E+08 1.05E+08 9.92E+07 5.71E+07 6.95E+07 5.77E+07 9.44E+07 6.04E+07 7.51E+07 5.00E+07 7.07E+07 6.66E+07 3.29 Y 3.37 Y 1.64 Y 1.54 Y 1.08 Y 1.08 Y 0.83 Y 0.79 Y 0.77 Y 1.65 Y 1.60 Y 1.63 Y 1.63 Y 1.60 Y 1.53 Y 1.31 Y 1.30 Y 1.29 Y 1.27 Y 1.27 Y 1.09 Y 1.09 Y 1.13 Y 1.04 Y 0.94 Y 0.90 Y 0.81 Y 0.80 Y 1.18 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.17 1.08 0.52 1.05 0.51 1.66 0.86 1.38 1.38 0.79 1.18 1.21 1.14 1.19 1.01 1.11 1.56 1.64 1.70 1.60 0.95 1.16 0.93 1.57 0.97 1.25 0.83 1.18 1.11 -1.5% -0.6% -0.1% 0.6% 0.9% -0.4% -0.5% 0.0% 1.1% -1.2% -1.7% -1.1% -1.8% 0.4% -1.7% -0.6% -1.7% 2.3% 1.7% 2.7% 0.6% 2.0% -1.0% -0.5% 0.4% 0.7% 0.6% 0.4% 0.1% Page 1 of 6 549 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.10 38.10 1.88E+08 1.16E+08 3.54E+07 1.09 Y 1.60 Y 1.11 Y 1.11 1.03 0.62 1.11 1.00 0.61 0.2% -2.6% -1.0% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.10 38.10 1.88E+08 1.16E+08 3.54E+07 1.09 Y 1.60 Y 1.11 Y 1.85 1.22 0.58 1.84 1.19 0.57 -0.1% -2.2% -2.0% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.80 37.72 47.88 2.15E+08 1.02E+08 9.69E+07 6.21E+07 6.00E+07 1.55 Y 0.80 Y 1.60 Y 1.30 Y 0.91 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.04 14.36 14.62 20.38 17.74 26.75 20.68 25.69 30.66 35.55 40.10 48.30 45.74 49.77 9.92E+08 9.76E+08 5.69E+08 9.40E+08 5.10E+08 7.43E+08 4.71E+08 4.46E+08 5.02E+08 2.95E+08 2.56E+08 3.22E+08 3.23E+08 2.24E+08 3.21 Y 3.28 Y 1.58 Y 1.62 Y 1.05 Y 0.98 Y 0.83 Y 0.64 Y 1.27 Y 1.08 Y 0.92 Y 0.91 Y 0.78 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.98 1.05 1.27 1.04 1.16 1.10 1.35 1.45 1.29 1.28 1.06 1.07 1.14 1.12 3.0% 4.2% 2.9% 2.4% 1.2% 2.0% -0.4% 1.0% 2.6% 0.6% 0.6% 1.2% 1.7% 0.5% Page 2 of 6 550 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 12.04 14.18 14.36 14.62 14.80 16.62 16.79 17.02 17.32 17.44 19.01 19.80 20.10 20.38 17.74 19.51 19.92 20.11 20.25 20.34 20.83 21.98 22.14 22.42 22.62 22.90 23.19 23.37 23.75 25.14 25.46 25.99 26.39 26.75 20.68 22.68 23.27 23.34 23.55 24.81 24.94 25.04 25.23 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 9.92E+08 1.00E+09 9.76E+08 5.69E+08 9.17E+08 8.62E+08 9.69E+08 9.24E+08 9.17E+08 9.28E+08 1.09E+09 9.34E+08 1.86E+09 9.40E+08 5.10E+08 1.39E+09 5.88E+08 8.20E+08 7.60E+08 4.62E+08 8.47E+08 7.98E+08 8.06E+08 1.63E+09 8.00E+08 8.40E+08 1.58E+09 1.64E+09 7.44E+08 8.17E+08 8.41E+08 7.83E+08 7.26E+08 7.43E+08 4.71E+08 1.00E+09 4.42E+08 4.96E+08 3.98E+08 4.82E+08 6.34E+08 4.03E+08 1.18E+09 RA 3.21 Y 3.28 Y 3.28 Y 1.58 Y 1.60 Y 1.63 Y 1.64 Y 1.65 Y 1.63 Y 1.63 Y 1.64 Y 1.64 Y 1.64 Y 1.62 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.06 Y 1.05 Y 0.99 Y 0.98 Y 0.98 Y 0.97 Y 0.97 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.99 Y 0.99 Y 0.98 Y 0.83 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.98 1.08 1.05 1.27 2.04 0.96 1.08 1.03 1.02 1.03 1.21 1.04 1.03 1.04 1.16 1.59 1.34 1.87 1.73 1.05 1.93 1.18 1.19 1.21 1.18 1.24 1.17 1.21 1.10 1.21 1.25 1.16 1.07 1.10 1.35 0.89 0.78 0.88 0.71 0.85 1.12 0.72 1.05 Dev'n 3.0% 4.2% 4.2% 2.9% 3.1% 1.3% 2.9% 3.0% 1.7% -0.2% 2.2% 2.7% 4.5% 2.4% 1.2% 3.3% 2.6% 2.8% 0.5% 4.7% 0.6% 4.1% 3.3% 2.9% 2.4% 1.5% 3.0% 3.3% 2.0% 3.4% 2.8% 4.9% 3.4% 2.0% -0.4% 1.4% 2.2% 2.5% 1.0% 1.3% 1.1% 0.7% 2.5% 551 of 711 PCB QC Summary - Ax2 Detail Lab ID: CS4_131220_PCB_XA Acquired: 20-DEC-2013 18:59 Datafile: 131220X06 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.01 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.51 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.78 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.36 PCB-67 23'45-TeCB 28.52 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.04 PCB-66 23'44'-TeCB 29.32 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.10 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.75 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.00 PCB-103 22'45'6-PeCB 27.70 PCB-94 22'356'-PeCB 27.89 PCB-95 22'35'6-PeCB 28.27 PCB-100/93 22'44'6/22'356-PeCB 28.49 PCB-102 22'456'-PeCB 28.60 PCB-98 22'34'6'-PeCB 28.67 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.23 PCB-89 22'346'-PeCB 29.65 PCB-121 23'45'6-PeCB 29.99 PCB-92 22'355'-PeCB 30.31 PCB-113/90/101 ...-PeCB 30.80 PCB-83 22'33'5-PeCB 31.24 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.78 PCB-117 234'56-PeCB 32.32 PCB-116/85 23456/22'344'-PeCB 32.41 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 4.79E+08 1.57E+09 2.05E+09 4.36E+08 3.81E+08 1.02E+09 7.02E+08 6.86E+08 7.41E+08 6.53E+08 6.72E+08 7.17E+08 7.44E+08 2.76E+09 6.42E+08 6.33E+08 6.29E+08 6.41E+08 7.47E+08 7.60E+08 6.10E+08 4.46E+08 3.93E+08 4.37E+08 3.75E+08 4.04E+08 8.29E+08 4.01E+08 3.96E+08 3.93E+08 4.40E+08 3.38E+08 3.62E+08 5.66E+08 3.81E+08 1.39E+09 3.22E+08 4.51E+08 5.42E+08 2.82E+09 5.03E+08 9.15E+08 5.11E+08 RA 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.64 Y 0.65 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.85 0.93 1.22 0.77 0.68 0.90 1.25 1.22 1.31 1.16 1.19 1.27 1.32 1.22 1.14 1.12 1.12 1.14 1.32 1.35 1.08 1.45 1.28 0.95 0.81 0.87 0.90 0.87 0.86 0.85 0.95 0.73 0.78 1.23 0.83 1.01 0.70 0.98 1.17 1.02 1.09 0.99 1.11 Dev'n 1.4% 3.0% 4.3% 1.5% -2.7% 4.9% 2.0% 0.7% 2.9% -0.5% 1.1% 1.1% 1.7% 2.2% 3.3% 0.3% 0.6% 0.2% 0.9% 3.2% 1.9% 1.0% 3.9% 1.6% 1.6% 0.9% 3.9% -10.2% 13.2% 6.8% 0.9% 2.3% 2.8% 2.2% 0.7% 2.0% -2.5% 6.1% 0.5% 3.8% -4.3% 5.3% -1.0% 552 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 32.62 32.81 33.12 33.52 34.49 34.70 34.92 35.38 37.34 30.66 30.82 30.96 31.27 31.54 32.82 33.34 33.55 33.81 34.11 34.29 34.37 34.64 34.81 34.96 35.19 35.59 35.94 36.15 36.27 36.70 36.85 37.19 37.39 37.47 37.76 37.90 38.09 38.82 39.64 39.88 35.55 35.83 36.30 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.34E+08 3.31E+08 5.66E+08 5.76E+08 1.03E+09 5.82E+08 5.22E+08 4.75E+08 5.12E+08 5.02E+08 4.78E+08 4.68E+08 4.35E+08 4.41E+08 3.38E+08 6.39E+08 3.76E+08 3.29E+08 6.68E+08 2.65E+08 3.08E+08 6.80E+08 2.87E+08 2.82E+08 2.84E+08 3.19E+08 3.83E+08 3.42E+08 4.26E+08 8.26E+08 3.01E+08 2.69E+08 3.35E+08 4.16E+08 1.01E+09 4.29E+08 4.60E+08 7.86E+08 4.70E+08 4.62E+08 2.95E+08 2.67E+08 2.61E+08 RA 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.63 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.28 Y 1.27 Y 1.26 Y 1.28 Y 1.27 Y 1.28 Y 1.29 Y 1.30 Y 1.28 Y 1.28 Y 1.27 Y 1.28 Y 1.27 Y 1.29 Y 1.27 Y 1.27 Y 1.29 Y 1.27 Y 1.27 Y 1.28 Y 1.23 Y 1.23 Y 1.22 Y 1.08 Y 1.10 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.16 0.72 1.23 1.25 1.12 1.26 1.13 1.02 1.12 1.29 1.23 1.21 1.12 1.14 1.23 1.16 1.37 1.20 1.21 0.96 1.12 1.24 1.04 1.03 1.03 1.16 1.39 1.24 1.55 1.50 1.10 0.98 1.22 1.51 1.23 1.56 1.67 0.93 1.12 1.10 1.28 1.16 1.13 Dev'n -0.2% 3.0% 0.5% 2.9% 2.0% 0.6% 2.4% 2.2% 2.2% 2.6% 5.1% 2.7% 5.1% 2.1% 3.8% 1.9% 1.9% 1.2% 3.2% 4.4% -1.0% 2.6% 1.8% 3.6% 0.3% 2.4% -1.3% 3.4% 1.8% 3.0% 0.7% 0.6% 4.6% 0.9% 3.3% 2.8% 0.5% 3.7% 0.1% 2.4% 0.6% -0.3% 0.2% 553 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 36.59 36.99 38.12 38.67 38.90 39.08 39.42 39.51 39.62 39.99 40.34 40.53 41.88 42.13 42.40 42.74 43.51 43.96 40.10 40.89 41.47 41.66 41.75 44.07 44.65 44.82 45.95 47.90 48.30 45.74 46.53 49.77 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 2.85E+08 2.59E+08 1.94E+08 3.05E+08 3.25E+08 3.35E+08 3.29E+08 3.20E+08 2.73E+08 2.68E+08 3.10E+08 5.43E+08 2.79E+08 3.67E+08 7.06E+08 3.88E+08 2.72E+08 3.86E+08 2.56E+08 3.08E+08 2.70E+08 2.93E+08 2.71E+08 3.95E+08 2.03E+08 2.13E+08 2.31E+08 2.54E+08 3.22E+08 3.23E+08 3.40E+08 2.24E+08 RA 1.09 Y 1.08 Y 1.08 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 0.92 Y 0.92 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.92 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.78 Y 0.79 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.24 1.12 0.84 1.10 1.17 1.21 1.18 1.15 0.98 0.96 1.12 0.98 1.00 1.32 1.27 1.40 1.19 1.69 1.06 1.27 1.12 1.21 1.12 0.82 0.84 0.88 0.77 0.85 1.07 1.14 1.20 1.12 Dev'n 0.3% -0.3% -0.6% 2.1% 2.6% 2.7% -1.8% 8.5% -0.9% 1.4% 2.5% 3.1% 1.6% 2.6% 0.7% 0.1% 4.9% 1.7% 0.6% 4.3% 0.3% 1.7% 1.3% 0.9% 0.6% 1.0% 0.4% 0.4% 1.2% 1.7% 1.2% 0.5% 554 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.95e7 2.48e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.59e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.85e7 9.24e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.88e7 9.40e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.07e7 5.35e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.31e6 2.66e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.17e6 2.58e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 186-257 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:11 Page 1 of 21 555 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-1 7.57e8 12.04 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-2 7.66e8 14.18 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.55e3 Abs. Int. 3.12e8 PCB-3 7.48e8 14.36 1.56e8 0% 11.0 12.0 13.0 14.0 PCB-1 2.36e8 12.04 Rel. Int. 100% PCB-2 2.34e8 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.14e3 15.0 0.00e0 16.0 RT Abs. Int. 9.75e7 PCB-3 2.28e8 14.36 4.88e7 0% 11.0 12.0 13.0 14.0 ES-1 1.94e8 12.03 Rel. Int. 100% 15.0 Abs. Int. 7.70e7 ES-3 1.79e8 14.35 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 8.48e3 0.00e0 16.0 RT 3.85e7 0% 11.0 12.0 13.0 14.0 ES-1 5.88e7 12.03 Rel. Int. 100% 15.0 Abs. Int. 2.33e7 ES-3 5.31e7 14.35 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.17e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.48e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2447, 4248 scc: 186-257 Revised: 30-Dec-2013 12:40 (LKB) Printed: 03-Jan-2014 17:11 Page 2 of 21 556 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Rel. Int. 100% PCB-10 5.64e8 14.80 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.96e3 PCB-4 3.49e8 14.62 9.54e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.53e8 14.80 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.22e4 PCB-4 2.20e8 14.62 12.0 13.0 14.0 15.0 ES-4 6.97e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.20e8 6.02e7 0% 11.0 Abs. Int. 1.91e8 0.00e0 16.0 RT Abs. Int. 2.32e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.94e3 1.16e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.25e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.42e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.42e3 7.11e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.48e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5797, 8154 scc: 186-257 Revised: 30-Dec-2013 12:40 (LKB) Printed: 03-Jan-2014 17:11 Page 3 of 21 557 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.19e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-6 5.75e8 17.02 PCB-9 5.35e8 16.62 PCB-14 6.74e8 19.01 PCB-5 5.69e8 PCB-8 17.32 5.76e8 17.44 PCB-11 5.80e8 19.80 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 13/12 1.16e9 20.10 Abs. Int. 1.91e8 PCB-15 5.81e8 20.38 9.54e7 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.01e4 PCB-9 3.28e8 16.62 PCB-7 3.67e8 16.79 18.0 19.0 PCB-14 4.11e8 19.01 PCB-5 3.48e8 17.32 PCB-8 3.52e8 17.44 20.0 PCB-11 3.54e8 19.80 13/12 7.06e8 20.10 21.0 Abs. Int. 1.16e8 PCB-15 3.59e8 20.38 5.81e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.31e8 16.61 21.0 ES-15 1.36e8 20.37 0.00e0 RT Abs. Int. 4.21e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.87e4 2.11e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 8.44e7 16.61 21.0 ES-15 8.87e7 20.37 0.00e0 RT Abs. Int. 2.68e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 9.39e3 1.34e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2386, 7567 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 4 of 21 558 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 30/18 7.14e8 19.51 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 4.23e3 PCB-19 2.62e8 17.74 PCB-17 3.01e8 19.92 PCB-27 4.20e8 20.11 PCB-24 3.89e8 20.25 PCB-16 2.37e8 20.34 Abs. Int. 1.99e8 PCB-32 4.34e8 20.83 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.80e8 19.51 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 5.06e3 PCB-19 2.48e8 17.74 PCB-17 2.86e8 19.92 21.0 PCB-24 3.71e8 20.25 PCB-27 4.00e8 20.11 Rel. Int. 100% 18.0 19.0 PCB-16 2.25e8 20.34 20.0 PCB-32 4.13e8 20.83 21.0 9.49e7 0.00e0 RT Abs. Int. 2.38e7 ES-19 5.69e7 17.72 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 9.15e4 0.00e0 RT Abs. Int. 1.90e8 0% 17.0 9.97e7 1.19e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.16e7 ES-19 5.28e7 17.72 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.57e4 0.00e0 RT 1.08e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0138, 7970 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 5 of 21 559 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 1.75e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 28/20 7.84e8 23.19 26/29 PCB-23 8.07e8 PCB-34 3.99e8 22.42 3.98e8 22.14 21.98 PCB-31 4.13e8 22.90 Abs. Int. 1.95e8 PCB-22 3.70e8 23.75 PCB-36 4.06e8 25.14 PCB-39 4.17e8 25.46 PCB-38 3.90e8 25.99 PCB-35 3.61e8 26.39 PCB-37 3.69e8 26.75 0% 22.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 1.49e4 23.0 24.0 25.0 26.0 27.0 28/20 7.92e8 23.19 26/29 PCB-23 8.21e8 PCB-34 4.07e8 22.42 4.00e8 22.14 21.98 PCB-31 4.27e8 22.90 23.0 PCB-22 3.73e8 23.75 PCB-36 4.11e8 25.14 PCB-39 4.24e8 25.46 PCB-38 3.93e8 25.99 24.0 25.0 PCB-35 3.65e8 26.39 PCB-37 3.74e8 26.75 26.0 CS/SS-28 9.79e7 23.16 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e8 0% 22.0 9.74e7 27.0 0.00e0 RT Abs. Int. 2.75e7 ES-37 8.75e7 26.73 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.98e4 9.79e7 1.38e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 9.01e7 23.16 Rel. Int. 100% 27.0 0.00e0 RT Abs. Int. 2.57e7 ES-37 8.13e7 26.73 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.64e4 1.28e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3897, 4503 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 6 of 21 560 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-54 2.13e8 20.68 Rel. Int. 100% Abs. Int. 5.71e7 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 2.07e3 2.86e7 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.58e8 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.61e7 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.18e3 3.30e7 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.96e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.83e4 5.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.78e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.07e4 6.63e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0111, 4665 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 7 of 21 561 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 3.31e3 50/53 4.42e8 22.68 PCB-51 2.20e8 23.34 PCB-45 1.94e8 23.27 PCB-73 2.79e8 PCB-52 24.94 2.12e8 24.81 PCB-46 1.76e8 23.55 69/49 5.22e8 25.23 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 44/47… 6.94e8 25.74 PCB-48 2.12e8 25.52 59/62… 9.08e8 26.01 71/40 4.50e8 26.61 PCB-42 1.93e8 26.18 PCB-41 1.67e8 26.51 Abs. Int. 1.64e8 PCB-64 3.10e8 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 2.77e3 50/53 5.60e8 22.67 24.0 PCB-51 2.76e8 23.34 PCB-45 2.48e8 23.27 25.0 PCB-73 3.55e8 PCB-52 24.94 2.70e8 24.81 PCB-46 2.22e8 23.55 26.0 69/49 6.59e8 25.23 44/47… 8.79e8 25.73 PCB-48 2.68e8 25.52 27.0 59/62… 1.15e9 26.01 71/40 5.65e8 26.61 PCB-42 2.44e8 26.18 PCB-41 2.14e8 26.51 23.0 24.0 25.0 26.0 PCB-64 3.92e8 26.81 27.0 JS-52 4.53e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.06e8 0% 22.0 8.18e7 1.03e8 0.00e0 RT Abs. Int. 1.25e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.94e4 6.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.67e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.88e4 8.02e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6634, 9311 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 8 of 21 562 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 7.08e5 PCB-58 2.95e8 PCB-68 28.36 PCB-67 3.24e8 3.15e8 27.78 28.52 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 61/70... 1.21e9 29.04 PCB-55 2.78e8 29.47 PCB-60 PCB-80 2.82e8 3.28e8 30.10 30.43 PCB-79 3.33e8 31.75 PCB-78 2.67e8 32.25PCB-81 2.81e8 32.62 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 1.50e8 PCB-77 2.90e8 33.10 7.49e7 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 4.30e5 PCB-57 3.67e8 28.16 PCB-68 4.16e8 27.78 30.0 61/70... 1.55e9 29.04 PCB-63 4.18e8 PCB-66 3.61e8 28.74 29.32 32.0 PCB-60 3.59e8 30.10 PCB-56 3.53e8 29.91 PCB-80 4.19e8 30.43 PCB-79 4.27e8 31.75 34.0 PCB-78 3.43e8 32.24PCB-81 3.61e8 32.62 36.0 38.0 Abs. Int. 1.90e8 PCB-77 3.71e8 33.10 9.49e7 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.15e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.32e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.63e7 ES-77 6.25e7 33.08 8.16e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.94e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.92e4 36.0 38.0 0.00e0 RT Abs. Int. 2.16e7 ES-77 7.87e7 33.08 1.08e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9214, 1956 scc: 186-257 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 9 of 21 563 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-104 1.74e8 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.22e3 Abs. Int. 4.45e7 PCB-96 1.55e8 26.00 2.22e7 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.71e8 25.68 27.0 0.00e0 RT Abs. Int. 6.94e7 PCB-96 2.38e8 26.00 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.22e3 3.47e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.79e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.06e3 6.19e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.90e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.31e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 3.99e3 3.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9179, 1685 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 10 of 21 564 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 108/119... 1.09e9 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 4.02e5 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-103 1.67e8 27.70 PCB-91 1.70e8 100/93 29.04 3.16e8 28.49 PCB-88 PCB-84 1.50e8 1.30e8 28.98 29.23 PCB-121 2.18e8 29.99 113/90… 5.34e8 30.80 116/85 3.49e8 32.41 PCB-99 1.73e8 31.34 PCB-111 PCB-120 2.17e8 2.20e8 33.12 33.52 PCB-118 107/124 2.07e8 3.96e8 35.09 34.49 PCB-114 PCB-123 2.24e8 2.17e8 35.56 34.81 Abs. Int. 1.63e8 PCB-105 2.01e8 36.10 PCB-127 1.97e8 37.34 8.15e7 0% 28.0 30.0 32.0 36.0 38.0 108/119... 1.73e9 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 3.81e5 34.0 PCB-94 2.32e8 27.89 100/93 5.12e8 28.49 PCB-91 2.69e8 29.04 PCB-89 2.23e8 29.65 113/90… 8.58e8 30.80 PCB-112 3.34e8 PCB-92 31.44 2.35e8 30.31 116/85 PCB-115 5.66e8 3.29e8 PCB-111 32.41 32.62 3.49e8 33.12 PCB-117 PCB-110 PCB-120 3.10e8 3.14e8 PCB-82 3.55e8 32.32 32.53 2.05e8 33.52 32.81 PCB-118 107/124 3.31e8 6.37e8 35.09 34.49 PCB-114 PCB-123 3.56e8 3.50e8 35.56 34.81 Abs. Int. 2.59e8 PCB-105 3.25e8 36.10 PCB-127 3.15e8 37.33 1.30e8 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 7.11e7 33.10 JS-101 5.96e7 30.80 36.0 ES-114 ES-118 7.24e7 ES-123 6.82e7 35.54 7.10e7 35.07 34.79 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 5.01e3 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.77e7 ES-105 7.03e7 36.08 8.86e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.46e7 33.10 JS-101 3.72e7 30.80 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.24e3 34.0 36.0 ES-118 ES-114 ES-123 4.20e7 4.43e7 4.45e7 35.07 35.54 34.79 38.0 0.00e0 RT Abs. Int. 1.12e7 ES-105 4.41e7 36.08 5.59e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5110, 9189 scc: 186-257 Revised: 03-Jan-2014 16:45 (LKB) Printed: 03-Jan-2014 17:11 Page 11 of 21 565 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 4.01e7 PCB-126 1.72e8 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 7.09e3 2.01e7 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.56e7 PCB-126 2.74e8 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.06e4 3.28e7 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.43e7 ES-126 5.92e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.98e3 7.15e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 9.49e6 ES-126 3.86e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 6.20e3 4.75e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6238, 0621 scc: 186-257 Revised: 30-Dec-2013 12:42 (LKB) Printed: 03-Jan-2014 17:11 Page 12 of 21 566 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-136 2.43e8 31.27 PCB-150 PCB-155 2.62e8 PCB-145 2.81e8 30.96 2.47e8 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.99e3 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 147/149 139/140 3.74e8 3.81e8 34.11 34.64 PCB-148 1.89e8 32.82 151/135 3.58e8 PCB-144PCB-134 33.34 1.85e8 1.48e8 33.81 34.29 153/168 4.62e8 36.70 PCB-146 PCB-142 PCB-133 1.79e8 1.91e8 1.59e8 36.15 35.59 34.96 PCB-141 1.70e8 36.85 163/138… 5.67e8 37.76 PCB-164 PCB-160 2.34e8 2.40e8 37.47 37.90 0% 28.0 30.0 32.0 PCB-152 PCB-136 2.10e8 1.91e8 30.82 31.26 PCB-155 PCB-150 PCB-145 2.21e8 2.06e8 30.96 1.95e8 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 2.00e3 34.0 PCB-148 1.49e8 32.81 36.0 38.0 163/138… 4.47e8 147/149 139/140 37.76 153/168 151/135 2.94e8 3.00e8 PCB-142 3.63e8 2.80e8 34.11 34.641.23e8 36.70 33.34 PCB-158 34.96 PCB-154 2.02e8 PCB-133 PCB-146 PCB-141 PCB-137 PCB-143 1.66e8 38.08 PCB-131 1.40e8 1.51e8 1.35e8 1.26e8 33.55 1.31e8 1.47e8 36.15 37.39 35.59 34.37 34.81 36.85 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 5.48e7 30.64 Rel. Int. 100% ES-153 3.90e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 2.47e3 JS-138 3.51e7 37.72 Abs. Int. 1.07e8 5.37e7 0.00e0 RT Abs. Int. 8.44e7 4.22e7 0.00e0 RT Abs. Int. 1.34e7 6.72e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.22e7 30.64 Rel. Int. 100% ES-153 2.98e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.62e3 0.00e0 RT Abs. Int. 1.05e7 JS-138 2.69e7 37.72 5.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1491, 6768 scc: 186-257 Revised: 30-Dec-2013 12:42 (LKB) Printed: 03-Jan-2014 17:11 Page 13 of 21 567 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.33e8 38.82 PCB-159 2.59e8 39.64 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.38e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-162 2.54e8 39.88 156/157 4.95e8 41.27 PCB-167 2.73e8 40.29 (2.50e8 + 2.02e8) * 100 pg/uL RRF(PCB-169) = = 1.14 (5.54e7 + 4.38e7) * 400 pg/uL LKB 03-Jan-2014 15:13 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 1.01e8 PCB-169 2.50e8 43.99 5.03e7 0% 39.0 Rel. Int. 100% 128/166 3.53e8 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.35e4 40.0 PCB-162 PCB-159 2.08e8 2.11e8 39.88 39.64 41.0 42.0 43.0 44.0 45.0 156/157 4.05e8 41.27 Abs. Int. 8.13e7 PCB-169 2.02e8 43.99 PCB-167 2.23e8 40.29 4.06e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.89e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 6.07e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.14e8 41.25 0.00e0 RT Abs. Int. 2.04e7 ES-169 5.54e7 43.97 1.02e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 4.65e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 1.15e4 42.0 43.0 44.0 45.0 ES-156/157 8.87e7 41.25 0.00e0 RT Abs. Int. 1.58e7 ES-169 4.38e7 43.97 7.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0329, 5135 scc: 186-257 PKD: 30-Dec-2013 12:43 Printed: 03-Jan-2014 17:11 Page 14 of 21 568 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-184 PCB-188 PCB-179 1.36e8 1.40e8 1.53e8 36.30 35.83 35.55 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.20e3 PCB-186 1.35e8 36.99 Abs. Int. 3.81e7 PCB-178 1.01e8 38.12 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 PCB-179 1.27e8 1.41e8 35.83 35.55 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 1.40e3 37.0 PCB-176 1.36e8 36.59 PCB-186 1.24e8 36.99 38.0 32.0 33.0 34.0 35.0 36.0 37.0 PCB-178 9.30e7 38.12 38.0 ES-188 3.06e7 35.53 Rel. Int. 100% CS/SS-178 1.86e7 38.10 RRF(CS/SS-178) = 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.72e7 35.53 Rel. Int. 100% CS/SS-178 1.68e7 38.10 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.93e6 0.00e0 RT Abs. Int. 6.93e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.88e3 31.0 1.81e7 Abs. Int. 7.87e6 (1.86e7 + 1.68e7) = 0.571 (3.51e7 + 2.69e7) LKB 03-Jan-2014 15:12 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.68e3 0.00e0 RT Abs. Int. 3.61e7 0% 31.0 1.91e7 36.0 37.0 38.0 Rel. Int. 100% 3.47e6 0.00e0 RT Abs. Int. 1.88e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5850, 9481 scc: 186-257 Revised: 30-Dec-2013 12:43 (LKB) Printed: 03-Jan-2014 17:11 Page 15 of 21 569 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.32e4 PCB-183 1.69e8 39.42 PCB-182 PCB-185 1.72e8 1.65e8 39.08 39.51 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 180/193 3.63e8 42.40 171/173 2.79e8 PCB-181 40.53 PCB-177 1.59e8 1.38e8 40.34 39.99 PCB-172 1.44e8 41.88 PCB-191 2.00e8 42.74 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-170 1.39e8 43.51 Abs. Int. 6.46e7 PCB-190 1.98e8 43.96 3.23e7 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.40e4 40.0 PCB-182 1.63e8 39.07 PCB-187 1.58e8 38.89 PCB-183 1.60e8 39.42 41.0 171/173 2.64e8 PCB-181 40.53 PCB-177 1.51e8 1.30e8 40.34 39.99 42.0 43.0 180/193 3.43e8 42.40 PCB-172 1.36e8 41.88 PCB-191 1.88e8 42.73 44.0 PCB-170 1.33e8 43.51 45.0 Abs. Int. 6.16e7 PCB-190 1.88e8 43.96 3.08e7 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.62e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 9.22e6 ES-170 2.97e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 4.39e3 0.00e0 RT 4.61e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.33e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 8.14e6 ES-170 2.73e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.64e3 0.00e0 RT 4.07e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3134, 7737 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 16 of 21 570 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-189 2.13e8 46.13 Abs. Int. 5.10e7 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 7.35e3 2.55e7 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.02e8 46.12 Abs. Int. 4.99e7 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 5.38e3 2.50e7 0% 46.0 Rel. Int. 100% ES-189 4.82e7 46.11 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 5.63e3 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 1.16e7 (4.82e7 + 4.62e7) * 100 pg/uL RRF(ES-189) = = 1.58 (2.85e7 + 3.14e7) * 100 pg/uL LKB 03-Jan-2014 15:12 5.79e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.62e7 46.11 0.00e0 RT Abs. Int. 1.12e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 5.14e3 5.60e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6642, 3679 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 17 of 21 571 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-202 1.23e8 40.10 PCB-201 1.47e8 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 2.30e3 PCB-197 1.40e8 41.66 PCB-200 PCB-204 1.30e8 1.29e8 41.75 41.47 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 198/199 1.88e8 44.07 Abs. Int. 3.66e7 PCB-196 9.72e7 44.65 PCB-203 1.02e8 44.82 1.83e7 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.34e8 40.10 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.91e3 41.0 PCB-201 1.61e8 40.89 42.0 43.0 PCB-197 1.53e8 PCB-204 41.66 PCB-200 1.41e8 1.41e8 41.75 41.47 44.0 45.0 198/199 2.07e8 44.07 Abs. Int. 4.04e7 PCB-196 1.06e8 44.65 PCB-203 1.11e8 44.82 2.02e7 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.93e7 40.08 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.00e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.98e3 3.50e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.12e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.46e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 2.00e3 3.73e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0058, 7129 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 18 of 21 572 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 4.72e3 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-205 1.54e8 48.30 PCB-195 1.10e8 45.95 Abs. Int. 3.56e7 PCB-194 1.22e8 47.90 1.78e7 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 6.42e3 47.0 48.0 49.0 50.0 PCB-205 1.68e8 48.30 PCB-195 1.21e8 45.95 0.00e0 RT Abs. Int. 3.85e7 PCB-194 1.32e8 47.89 1.93e7 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.55e7 48.28 JS-194 2.85e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 4.99e3 49.0 0.00e0 RT Abs. Int. 8.26e6 4.13e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.96e7 48.28 Rel. Int. 100% Abs. Int. 9.37e6 JS-194 3.14e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.69e3 0.00e0 RT 4.68e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0147, 9308 scc: 186-257 Revised: 30-Dec-2013 12:43 (LKB) Printed: 03-Jan-2014 17:12 Page 19 of 21 573 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 3.76e3 PCB-208 1.42e8 45.74 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-207 1.50e8 46.53 Abs. Int. 3.60e7 PCB-206 9.85e7 49.77 1.80e7 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 5.22e3 PCB-208 1.81e8 45.74 47.0 48.0 49.0 50.0 PCB-207 1.90e8 46.53 Abs. Int. 4.58e7 PCB-206 1.25e8 49.77 2.29e7 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 3.15e7 45.72 50.0 0.00e0 RT Abs. Int. 7.52e6 ES-206 2.24e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.53e3 3.76e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.92e7 45.72 50.0 Abs. Int. 9.31e6 ES-206 2.77e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.58e3 0.00e0 RT 4.65e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9272, 3360 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:12 Page 20 of 21 574 of 711 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-209 1.58e8 51.25 Rel. Int. 100% Abs. Int. 3.32e7 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 7.36e2 1.66e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.34e8 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.80e7 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 8.28e2 1.40e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.60e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.71e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 1.07e3 3.86e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.05e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.37e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.97e2 3.18e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.17e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.58e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0022, 9026 scc: 186-257 PKD: 30-Dec-2013 12:40 Printed: 03-Jan-2014 17:12 Page 21 of 21 575 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.11 32.63 36.10 35.56 35.09 34.82 38.72 41.27 40.29 43.99 46.12 51.24 3.92E+09 3.81E+09 3.11E+09 3.45E+09 3.20E+09 3.32E+09 2.76E+09 5.55E+09 3.01E+09 2.75E+09 2.52E+09 1.71E+09 0.79 Y 0.78 Y 0.62 Y 0.63 Y 0.63 Y 0.62 Y 0.63 Y 1.23 Y 1.22 Y 1.24 Y 1.05 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.22 1.17 1.18 1.29 1.25 1.25 1.21 1.17 1.23 1.17 1.16 1.15 6.1% 4.4% 5.9% 6.9% 4.7% 3.0% 9.8% 6.3% 5.8% 4.3% 7.9% 3.3% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.03 14.35 14.61 20.38 17.73 26.74 20.67 33.09 32.61 25.67 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.25 40.27 43.97 43.49 42.42 35.53 46.11 40.08 48.27 49.75 45.72 51.22 2.62E+08 2.47E+08 1.23E+08 2.45E+08 1.20E+08 1.94E+08 9.79E+07 1.61E+08 1.63E+08 8.86E+07 1.32E+08 1.34E+08 1.28E+08 1.33E+08 1.14E+08 8.16E+07 1.13E+08 2.38E+08 1.22E+08 1.17E+08 6.70E+07 8.32E+07 6.88E+07 1.09E+08 7.17E+07 8.57E+07 5.62E+07 8.18E+07 7.42E+07 3.21 Y 3.30 Y 1.63 Y 1.53 Y 1.07 Y 1.09 Y 0.83 Y 0.79 Y 0.79 Y 1.66 Y 1.58 Y 1.60 Y 1.60 Y 1.59 Y 1.54 Y 1.32 Y 1.29 Y 1.27 Y 1.26 Y 1.27 Y 1.09 Y 1.09 Y 1.10 Y 1.01 Y 0.94 Y 0.89 Y 0.81 Y 0.80 Y 1.20 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.13 1.06 0.53 1.05 0.52 1.69 0.85 1.40 1.42 0.78 1.17 1.19 1.14 1.18 1.01 1.10 1.52 1.61 1.65 1.58 0.97 1.21 0.93 1.58 0.97 1.25 0.82 1.19 1.08 -5.6% -2.3% 0.9% 1.3% 2.2% 1.6% -0.9% 1.2% 4.0% -2.5% -2.9% -2.5% -1.9% -0.8% -2.2% -1.2% -4.1% 0.4% -1.0% 1.8% 2.9% 6.3% -1.1% -0.3% -0.2% 0.1% -1.6% 1.2% -2.8% Page 1 of 6 576 of 711 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.10 38.10 2.10E+08 1.37E+08 4.42E+07 1.08 Y 1.60 Y 1.12 Y 1.11 1.03 0.62 1.09 1.03 0.64 -2.3% 0.0% 3.8% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.10 38.10 2.10E+08 1.37E+08 4.42E+07 1.08 Y 1.60 Y 1.12 Y 1.85 1.22 0.58 1.83 1.21 0.60 -0.7% -0.7% 2.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.81 37.73 47.87 2.33E+08 1.15E+08 1.13E+08 7.41E+07 6.88E+07 1.55 Y 0.81 Y 1.60 Y 1.32 Y 0.90 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.05 14.37 14.63 20.39 17.75 26.76 20.69 25.69 30.66 35.55 40.10 48.29 45.74 49.77 4.77E+09 4.95E+09 3.16E+09 5.27E+09 2.86E+09 4.48E+09 2.66E+09 2.58E+09 2.91E+09 1.80E+09 1.58E+09 1.93E+09 1.95E+09 1.32E+09 2.71 Y 2.98 Y 1.59 Y 1.63 Y 1.05 Y 0.99 Y 0.82 Y 0.65 Y 1.29 Y 1.08 Y 0.92 Y 0.93 Y 0.79 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.91 1.00 1.29 1.08 1.19 1.16 1.36 1.46 1.29 1.31 1.10 1.13 1.19 1.18 -4.4% -0.6% 4.4% 5.5% 3.6% 7.4% 0.3% 1.6% 2.3% 3.0% 4.7% 6.3% 6.1% 5.5% Page 2 of 6 577 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 12.05 14.18 14.37 14.63 14.81 16.63 16.80 17.02 17.33 17.45 19.02 19.81 20.10 20.39 17.75 19.52 19.93 20.12 20.26 20.35 20.84 21.99 22.14 22.43 22.63 22.91 23.20 23.38 23.75 25.14 25.46 26.00 26.39 26.76 20.69 22.68 23.28 23.35 23.56 24.82 24.95 25.05 25.24 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 4.77E+09 5.06E+09 4.95E+09 3.16E+09 5.06E+09 4.77E+09 5.47E+09 5.14E+09 5.14E+09 5.25E+09 6.12E+09 5.26E+09 1.05E+10 5.27E+09 2.86E+09 7.69E+09 3.33E+09 4.61E+09 4.39E+09 2.55E+09 4.79E+09 4.49E+09 4.54E+09 9.34E+09 4.59E+09 4.84E+09 9.02E+09 9.35E+09 4.32E+09 4.81E+09 4.93E+09 4.32E+09 4.24E+09 4.48E+09 2.66E+09 5.80E+09 2.69E+09 2.73E+09 2.31E+09 2.76E+09 3.82E+09 2.28E+09 6.91E+09 RA 2.71 Y 2.92 Y 2.98 Y 1.59 Y 1.58 Y 1.62 Y 1.65 Y 1.63 Y 1.64 Y 1.64 Y 1.60 Y 1.63 Y 1.63 Y 1.63 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.00 Y 0.98 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.97 Y 0.98 Y 0.99 Y 0.98 Y 1.00 Y 0.99 Y 0.99 Y 0.82 Y 0.79 Y 0.79 Y 0.80 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.91 1.02 1.00 1.29 2.06 0.97 1.11 1.05 1.05 1.07 1.25 1.07 1.07 1.08 1.19 1.60 1.38 1.92 1.83 1.06 1.99 1.16 1.17 1.21 1.18 1.25 1.17 1.21 1.12 1.24 1.27 1.11 1.10 1.16 1.36 0.89 0.83 0.84 0.71 0.85 1.17 0.70 1.06 Dev'n -4.4% -0.9% -0.6% 4.4% 4.1% 2.9% 6.5% 5.3% 4.7% 3.7% 5.8% 6.2% 8.0% 5.5% 3.6% 4.0% 6.0% 5.5% 5.9% 5.3% 3.8% 2.3% 1.5% 3.0% 2.4% 2.1% 2.9% 2.9% 3.4% 6.2% 5.1% 0.9% 5.3% 7.4% 0.3% 1.5% 7.6% -2.6% 1.2% 0.5% 5.5% -1.5% 3.6% 578 of 711 PCB QC Summary - Ax2 Detail Lab ID: CS5_131220_PCB_XA Acquired: 20-DEC-2013 20:49 Datafile: 131220X08 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.02 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.52 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.79 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.37 PCB-67 23'45-TeCB 28.53 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.05 PCB-66 23'44'-TeCB 29.33 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.10 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.76 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.01 PCB-103 22'45'6-PeCB 27.71 PCB-94 22'356'-PeCB 27.90 PCB-95 22'35'6-PeCB 28.28 PCB-100/93 22'44'6/22'356-PeCB 28.50 PCB-102 22'456'-PeCB 28.61 PCB-98 22'34'6'-PeCB 28.68 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.24 PCB-89 22'346'-PeCB 29.65 PCB-121 23'45'6-PeCB 30.00 PCB-92 22'355'-PeCB 30.32 PCB-113/90/101 ...-PeCB 30.80 PCB-83 22'33'5-PeCB 31.24 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.79 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.42 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 2.83E+09 9.10E+09 1.15E+10 2.53E+09 2.38E+09 5.79E+09 4.17E+09 4.01E+09 4.24E+09 3.81E+09 4.00E+09 4.17E+09 4.37E+09 1.58E+10 3.68E+09 3.76E+09 3.68E+09 3.79E+09 4.36E+09 4.29E+09 3.62E+09 2.58E+09 2.25E+09 2.54E+09 2.18E+09 2.36E+09 4.75E+09 2.73E+09 2.05E+09 2.08E+09 2.73E+09 1.98E+09 2.09E+09 3.31E+09 2.25E+09 8.09E+09 1.82E+09 2.67E+09 3.15E+09 1.55E+10 3.32E+09 5.04E+09 3.01E+09 RA 0.79 Y 0.79 Y 0.81 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.65 Y 0.65 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.64 Y 0.61 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.68 Y 0.62 Y 0.63 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.87 0.93 1.18 0.78 0.73 0.89 1.28 1.23 1.30 1.17 1.23 1.28 1.34 1.21 1.13 1.15 1.13 1.16 1.34 1.32 1.11 1.46 1.27 0.95 0.82 0.89 0.89 1.02 0.77 0.78 1.03 0.74 0.79 1.24 0.84 1.01 0.69 1.00 1.18 0.97 1.25 0.95 1.13 Dev'n 3.4% 3.0% 1.4% 1.9% 5.0% 3.5% 4.8% 1.8% 1.9% 0.4% 4.1% 1.6% 3.2% 1.4% 2.4% 3.0% 1.6% 2.6% 1.9% 0.8% 4.6% 1.6% 3.5% 2.6% 2.5% 2.4% 3.4% 5.8% 1.6% -2.2% 8.9% 3.7% 3.0% 3.7% 2.9% 2.8% -4.1% 8.8% 1.3% -0.7% 9.6% 0.6% 1.1% 579 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 32.62 32.81 33.13 33.53 34.50 34.71 34.93 35.39 37.34 30.66 30.82 30.97 31.27 31.54 32.82 33.34 33.55 33.81 34.12 34.29 34.37 34.64 34.81 34.96 35.19 35.60 35.94 36.15 36.27 36.70 36.85 37.19 37.39 37.47 37.77 37.90 38.09 38.82 39.64 39.88 35.55 35.83 36.30 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 3.31E+09 1.94E+09 3.35E+09 3.41E+09 6.21E+09 3.61E+09 3.03E+09 2.83E+09 3.14E+09 2.91E+09 2.78E+09 2.75E+09 2.61E+09 2.61E+09 2.03E+09 3.85E+09 2.26E+09 1.97E+09 4.02E+09 1.54E+09 1.89E+09 4.13E+09 1.73E+09 1.72E+09 1.74E+09 1.91E+09 2.36E+09 2.06E+09 2.61E+09 4.99E+09 1.83E+09 1.63E+09 2.02E+09 2.53E+09 6.19E+09 2.49E+09 2.80E+09 4.79E+09 2.87E+09 2.82E+09 1.80E+09 1.59E+09 1.62E+09 RA 0.63 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 1.29 Y 1.26 Y 1.26 Y 1.27 Y 1.28 Y 1.30 Y 1.28 Y 1.26 Y 1.28 Y 1.26 Y 1.26 Y 1.28 Y 1.28 Y 1.28 Y 1.26 Y 1.27 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.26 Y 1.27 Y 1.29 Y 1.26 Y 1.29 Y 1.28 Y 1.22 Y 1.23 Y 1.22 Y 1.08 Y 1.11 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.24 0.73 1.26 1.28 1.17 1.36 1.14 1.06 1.19 1.29 1.23 1.22 1.16 1.16 1.25 1.18 1.38 1.20 1.23 0.94 1.16 1.27 1.06 1.06 1.06 1.17 1.44 1.26 1.60 1.53 1.12 1.00 1.24 1.55 1.27 1.52 1.72 0.98 1.17 1.15 1.31 1.15 1.17 Dev'n 7.2% 4.5% 3.1% 5.7% 6.2% 8.2% 3.1% 6.1% 8.8% 2.3% 5.0% 3.6% 8.4% 3.7% 5.4% 3.6% 3.2% 1.8% 4.9% 2.0% 2.7% 5.1% 3.7% 6.7% 3.2% 3.7% 2.5% 5.0% 5.3% 5.0% 2.9% 3.0% 6.3% 3.5% 6.4% 0.6% 3.4% 8.8% 5.3% 7.5% 3.0% -0.7% 4.2% 580 of 711 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 36.59 36.99 38.12 38.67 38.90 39.08 39.42 39.51 39.62 39.99 40.34 40.53 41.88 42.13 42.40 42.73 43.51 43.96 40.10 40.89 41.47 41.66 41.75 44.07 44.65 44.82 45.95 47.89 48.29 45.74 46.53 49.77 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 1.74E+09 1.57E+09 1.21E+09 1.91E+09 2.01E+09 2.05E+09 2.03E+09 2.01E+09 1.71E+09 1.65E+09 1.95E+09 3.42E+09 1.73E+09 2.27E+09 4.38E+09 2.40E+09 1.66E+09 2.44E+09 1.58E+09 1.78E+09 1.66E+09 1.80E+09 1.68E+09 2.46E+09 1.24E+09 1.30E+09 1.40E+09 1.50E+09 1.93E+09 1.95E+09 2.03E+09 1.32E+09 RA 1.08 Y 1.09 Y 1.09 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 0.92 Y 0.92 Y 0.92 Y 0.92 Y 0.92 Y 0.91 Y 0.91 Y 0.92 Y 0.92 Y 0.93 Y 0.93 Y 0.79 Y 0.79 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.26 1.14 0.88 1.15 1.21 1.23 1.22 1.21 1.03 0.99 1.17 1.03 1.04 1.36 1.31 1.44 1.24 1.82 1.10 1.24 1.16 1.26 1.17 0.86 0.87 0.91 0.82 0.88 1.13 1.19 1.24 1.18 Dev'n 2.3% 1.1% 4.2% 7.1% 6.2% 4.6% 1.1% 13.9% 4.0% 4.3% 7.5% 8.3% 5.0% 5.9% 4.3% 3.3% 9.0% 9.7% 4.7% 1.8% 3.8% 5.5% 6.1% 5.9% 3.9% 4.0% 6.5% 4.1% 6.3% 6.1% 4.2% 5.5% 581 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.74e7 2.37e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.57e7 1.28e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.87e7 9.33e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.96e7 9.79e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.14e7 5.71e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.71e6 2.86e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.37e6 2.68e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 807-075 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:13 Page 1 of 21 582 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-1 3.48e9 12.05 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-2 3.77e9 14.18 Abs. Int. 1.07e9 PCB-3 3.71e9 14.37 MoCB 10.03-16.00 188.0393 Fn1 Flags: OPBM 4σ 4.15e3 5.37e8 0% 11.0 12.0 13.0 PCB-1 1.29e9 12.05 Rel. Int. 100% 14.0 PCB-2 1.29e9 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.52e3 15.0 0.00e0 16.0 RT Abs. Int. 5.17e8 PCB-3 1.25e9 14.37 2.58e8 0% 11.0 12.0 13.0 14.0 ES-1 2.00e8 12.03 Rel. Int. 100% 15.0 Abs. Int. 7.82e7 ES-3 1.89e8 14.35 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 7.14e3 0.00e0 16.0 RT 3.91e7 0% 11.0 12.0 13.0 14.0 ES-1 6.21e7 12.03 Rel. Int. 100% 15.0 Abs. Int. 2.45e7 ES-3 5.75e7 14.35 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.23e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.74e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.37e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7909, 8443 scc: 807-075 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 2 of 21 583 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Rel. Int. 100% PCB-4 1.94e9 14.63 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: OPBM 4σ 5.76e3 PCB-10 3.10e9 14.81 5.11e8 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 1.96e9 14.81 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.26e4 PCB-4 1.22e9 14.63 12.0 13.0 14.0 15.0 ES-4 7.59e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.47e8 3.23e8 0% 11.0 Abs. Int. 1.02e9 0.00e0 16.0 RT Abs. Int. 2.55e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.86e3 1.27e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.67e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.50e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.71e3 7.49e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.74e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.37e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9558, 1963 scc: 807-075 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 3 of 21 584 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: OPBM 4σ 1.34e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-6 3.19e9 17.02 PCB-9 2.95e9 16.63 PCB-14 3.77e9 19.02 PCB-5 3.19e9 17.33 PCB-8 3.26e9 17.45 PCB-11 3.26e9 19.81 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 13/12 6.49e9 20.10 Abs. Int. 1.07e9 PCB-15 3.27e9 20.39 5.36e8 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 3.90e4 PCB-9 1.82e9 16.63 18.0 PCB-14 2.35e9 19.02 PCB-5 1.95e9 PCB-8 17.33 1.99e9 17.45 PCB-7 2.06e9 16.80 19.0 20.0 PCB-11 2.00e9 19.81 13/12 3.99e9 20.10 21.0 Abs. Int. 6.86e8 PCB-15 2.01e9 20.39 3.43e8 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.42e8 16.61 21.0 ES-15 1.48e8 20.38 0.00e0 RT Abs. Int. 4.57e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.73e4 2.28e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 9.12e7 16.61 21.0 ES-15 9.71e7 20.38 0.00e0 RT Abs. Int. 2.93e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.93e3 1.46e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3253, 5347 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 4 of 21 585 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 30/18 3.92e9 19.52 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: OPBM 4σ 4.61e3 PCB-19 1.46e9 17.75 PCB-17 1.71e9 19.93 PCB-27 2.36e9 20.12 PCB-24 2.24e9 20.26 PCB-16 1.30e9 20.35 Abs. Int. 1.05e9 PCB-32 2.46e9 20.84 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 3.78e9 19.52 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: OPBM 4σ 3.65e3 PCB-19 1.40e9 17.75 PCB-17 1.62e9 19.93 PCB-24 2.15e9 20.26 PCB-27 2.25e9 20.12 PCB-16 1.24e9 20.35 21.0 Rel. Int. 100% 18.0 19.0 20.0 PCB-32 2.34e9 20.83 21.0 5.20e8 0.00e0 RT Abs. Int. 2.64e7 ES-19 6.21e7 17.73 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 9.95e4 0.00e0 RT Abs. Int. 1.04e9 0% 17.0 5.26e8 1.32e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.45e7 ES-19 5.82e7 17.73 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.48e4 0.00e0 RT 1.22e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8073, 3622 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 5 of 21 586 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 28/20 4.47e9 23.20 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: OPBM 4σ 4.92e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-23 PCB-34 2.25e9 2.24e9 22.14 21.99 26/29 4.64e9 22.43 PCB-31 2.40e9 22.91 Abs. Int. 1.07e9 PCB-22 2.14e9 23.75 PCB-36 2.39e9 25.14 PCB-39 2.44e9 25.46 PCB-38 2.15e9 26.00 PCB-35 2.11e9 26.39 PCB-37 2.23e9 26.76 0% 22.0 24.0 25.0 26.0 27.0 28/20 4.55e9 23.20 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: OPBM 4σ 5.05e4 23.0 PCB-23 PCB-34 2.29e9 2.25e9 22.14 21.99 26/29 4.70e9 22.43 PCB-31 2.44e9 22.91 23.0 PCB-22 2.18e9 23.75 PCB-36 2.42e9 25.14 PCB-39 2.49e9 25.46 PCB-38 2.16e9 26.00 24.0 25.0 PCB-35 2.13e9 26.39 PCB-37 2.25e9 26.75 26.0 CS/SS-28 1.09e8 23.16 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e9 5.32e8 0% 22.0 5.35e8 27.0 ES-37 1.01e8 26.74 0.00e0 RT Abs. Int. 2.96e7 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 8.57e4 1.48e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 1.01e8 23.16 Rel. Int. 100% 27.0 ES-37 9.28e7 26.74 0.00e0 RT Abs. Int. 2.82e7 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.96e4 1.41e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3047, 4081 scc: 807-075 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 6 of 21 587 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-54 1.20e9 20.69 Rel. Int. 100% Abs. Int. 3.45e8 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 2.02e3 1.72e8 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.46e9 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.14e8 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.44e3 2.07e8 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.43e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.72e4 6.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 5.36e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.53e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.34e4 7.63e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0340, 6239 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 7 of 21 588 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 5.68e3 50/53 2.56e9 22.68 PCB-51 1.21e9 23.35 PCB-45 1.19e9 23.28 PCB-73 1.69e9 PCB-52 24.95 1.22e9 24.82 PCB-46 1.02e9 23.56 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 59/62… 44/47… 5.18e9 4.02e9 26.02 25.74 69/49 3.05e9 25.24 PCB-48 1.25e9 25.52 PCB-42 1.12e9 26.18 71/40 2.56e9 26.61 PCB-41 1.04e9 26.52 Abs. Int. 9.33e8 PCB-64 1.85e9 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: OPBM 4σ 6.24e3 50/53 3.24e9 22.68 24.0 PCB-51 1.52e9 23.35 PCB-45 1.50e9 23.28 25.0 PCB-73 2.13e9 PCB-52 24.95 1.54e9 24.82 PCB-46 1.29e9 23.56 26.0 44/47… 59/62… 5.08e9 6.37e9 26.02 25.74 69/49 3.85e9 25.24 PCB-48 1.58e9 25.52 PCB-42 1.41e9 26.18 27.0 PCB-64 2.32e9 26.81 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.11e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e9 71/40 3.23e9 26.61 PCB-41 1.33e9 26.52 4.66e8 5.33e8 0.00e0 RT Abs. Int. 1.44e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.50e4 7.22e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 6.35e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.80e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 2.42e4 9.02e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7633, 4971 scc: 807-075 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 8 of 21 589 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 3.46e6 PCB-58 1.77e9 PCB-68 28.37 PCB-67 1.86e9 1.83e9 27.79 28.53 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 61/70... 7.00e9 29.05 PCB-55 1.66e9 29.47 PCB-60 PCB-80 1.67e9 1.92e9 30.10 30.43 PCB-79 1.89e9 31.76 PCB-78 1.60e9 32.25PCB-81 1.67e9 32.63 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Abs. Int. 8.48e8 PCB-77 1.73e9 33.11 4.24e8 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: OPBM 4σ 2.54e6 PCB-68 2.38e9 27.79 30.0 61/70... 8.84e9 PCB-60 PCB-67 29.05 2.13e9 2.34e9 30.10 28.53 PCB-63 PCB-80 2.44e9 PCB-66 PCB-56 2.06e9 2.05e9 2.44e9 28.75 29.91 29.33 30.43 32.0 PCB-79 2.40e9 31.76 34.0 PCB-78 2.02e9 32.25PCB-81 2.13e9 32.63 36.0 38.0 Abs. Int. 1.07e9 PCB-77 2.19e9 33.11 5.33e8 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.18e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.65e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 2.00e7 ES-77 7.10e7 33.09 9.98e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 9.11e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.84e4 36.0 38.0 0.00e0 RT Abs. Int. 2.45e7 ES-77 8.96e7 33.09 1.23e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3954, 5702 scc: 807-075 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 9 of 21 590 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-104 1.01e9 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.69e3 Abs. Int. 2.66e8 PCB-96 8.84e8 26.01 1.33e8 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 1.57e9 25.69 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.74e3 27.0 0.00e0 RT Abs. Int. 4.07e8 PCB-96 1.37e9 26.01 2.04e8 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 5.53e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.48e3 7.06e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 3.33e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.34e3 4.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6832, 9715 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 10 of 21 591 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 108/119... 6.27e9 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 6.54e6 PCB-103 9.76e8 27.71 100/93 1.82e9 28.50 PCB-88 7.91e8 28.98 PCB-121 1.27e9 30.00 113/90… 3.10e9 30.80 116/85 1.94e9 32.42 PCB-99 1.03e9 31.34 PCB-111 PCB-120 1.29e9 1.30e9 33.13 33.53 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-118 107/124 1.23e9 2.39e9 35.09 34.50 PCB-114 PCB-123 1.33e9 1.27e9 35.56 34.82 Abs. Int. 8.81e8 PCB-105 1.20e9 36.10 PCB-127 1.21e9 37.34 4.40e8 0% 28.0 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: OPBM 4σ 5.33e6 30.0 100/93 2.93e9 28.50 PCB-94 1.34e9 27.90 PCB-91 1.68e9 29.04 PCB-121 2.05e9 30.00 32.0 113/90… 4.99e9 30.80 34.0 108/119... 9.26e9 31.79 PCB-112 1.93e9 31.44 116/85 PCB-115 3.10e9 2.03e9 32.42 32.62 PCB-111 2.06e9 PCB-117 PCB-110 33.13 PCB-120 2.05e9 1.85e9 2.11e9 32.33 PCB-82 32.53 33.53 1.20e9 32.81 36.0 107/124 PCB-118 3.82e9 1.97e9 34.50 35.09 PCB-114 PCB-123 2.12e9 2.05e9 35.56 34.82 38.0 Abs. Int. 1.07e9 PCB-105 1.91e9 36.10 PCB-127 1.94e9 37.34 5.37e8 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 8.44e7 33.10 JS-101 6.96e7 30.81 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 9.28e3 34.0 36.0 ES-123 8.16e7 34.79 ES-114 8.27e7 35.54 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 2.13e7 ES-105 8.08e7 36.08 1.07e7 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.27e7 33.11 JS-101 4.34e7 30.81 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 6.82e3 34.0 36.0 ES-118 ES-123 4.95e7 5.15e7 35.07 34.79 38.0 0.00e0 RT Abs. Int. 1.32e7 ES-105 5.11e7 36.08 6.61e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0782, 2709 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 11 of 21 592 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Abs. Int. 2.63e8 PCB-126 1.07e9 38.72 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.64e4 1.32e8 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 4.19e8 PCB-126 1.69e9 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 2.44e4 2.09e8 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.65e7 ES-126 6.89e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.99e3 8.25e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.08e7 ES-126 4.48e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 8.23e3 5.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1246, 7147 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 12 of 21 593 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% PCB-150 PCB-155 1.54e9 1.64e9 30.97 30.66 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.19e4 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 147/149 139/140 2.24e9 2.32e9 34.64 34.12 PCB-145 1.46e9 31.54 PCB-148 1.15e9 32.82 153/168 2.80e9 36.70 151/135PCB-144 2.16e9 1.10e9 PCB-143 PCB-142 PCB-133 PCB-146 1.06e9 9.62e8 1.07e9 1.15e9 33.34 33.81 36.15 34.37 35.60 34.96 PCB-141 1.02e9 36.85 163/138… 3.46e9 37.77 PCB-164 PCB-160 1.42e9 1.40e9 37.47 37.90 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PCB-150 PCB-155 1.22e9 1.27e9 30.97 30.66 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.03e4 PCB-145 1.15e9 31.54 PCB-148 8.85e8 32.82 147/149 139/140 151/135 1.78e9 1.81e9 1.69e9 34.12 34.64 33.34 PCB-154 9.99e8 PCB-143 PCB-131 33.55 8.28e8 7.60e8 34.37 34.81 36.0 38.0 153/168 2.19e9 36.70 PCB-165 1.04e9 35.94 163/138… 2.74e9 37.77 PCB-137 PCB-141 8.87e8 8.04e8 37.39 36.85 30.0 32.0 34.0 36.0 38.0 ES-153 4.65e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.02e4 0.00e0 RT Abs. Int. 5.14e8 2.57e8 ES-155 6.35e7 30.64 Rel. Int. 100% 3.23e8 PCB-158 1.23e9 38.09 0% 28.0 Abs. Int. 6.47e8 0.00e0 RT Abs. Int. 1.67e7 JS-138 4.21e7 37.73 8.33e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.94e7 30.64 Rel. Int. 100% ES-153 3.51e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 9.67e3 0.00e0 RT Abs. Int. 1.26e7 JS-138 3.19e7 37.73 6.31e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2850, 7769 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 13 of 21 594 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 2.63e9 38.82 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.24e4 PCB-159 1.58e9 39.64 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-162 1.55e9 39.88 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 156/157 3.06e9 41.27 Abs. Int. 6.29e8 PCB-169 1.52e9 43.99 PCB-167 1.65e9 40.29 3.15e8 0% 39.0 Rel. Int. 100% 40.0 128/166 2.16e9 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 3.49e4 PCB-159 1.29e9 39.64 PCB-162 1.27e9 39.88 41.0 42.0 43.0 44.0 45.0 156/157 2.49e9 41.27 Abs. Int. 5.14e8 PCB-169 1.23e9 43.99 PCB-167 1.35e9 40.29 2.57e8 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 6.83e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 9.18e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.33e8 41.25 0.00e0 RT Abs. Int. 2.38e7 ES-169 6.57e7 43.97 1.19e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.40e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 1.04e4 42.0 43.0 44.0 45.0 ES-156/157 1.05e8 41.25 0.00e0 RT Abs. Int. 1.92e7 ES-169 5.16e7 43.97 9.61e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1763, 4652 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 14 of 21 595 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-184 PCB-188 PCB-179 8.43e8 8.35e8 9.36e8 36.30 35.83 35.55 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.64e3 PCB-186 8.18e8 36.99 Abs. Int. 2.32e8 PCB-178 6.30e8 38.12 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 PCB-179 7.54e8 8.64e8 35.83 35.55 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.12e3 37.0 PCB-176 8.33e8 36.59 PCB-186 7.49e8 36.99 38.0 1.16e8 0.00e0 RT Abs. Int. 2.17e8 PCB-178 5.80e8 38.12 1.09e8 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.60e7 35.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.14e6 CS/SS-178 2.33e7 38.10 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 7.77e3 4.57e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.28e7 35.53 Rel. Int. 100% Abs. Int. 8.50e6 CS/SS-178 2.09e7 38.10 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 8.62e3 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 4.25e6 0.00e0 RT Abs. Int. 1.96e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2899, 3493 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 15 of 21 596 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 3.40e4 PCB-183 1.04e9 39.42 PCB-182 PCB-185 1.05e9 1.03e9 39.08 39.51 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 171/173 1.76e9 PCB-181 40.53 PCB-177 1.00e9 8.47e8 40.34 39.99 180/193 2.25e9 42.40 PCB-172 8.89e8 41.88 PCB-191 1.23e9 42.73 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-170 8.50e8 43.51 Abs. Int. 4.06e8 PCB-190 1.25e9 43.96 2.03e8 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 3.24e4 PCB-182 9.93e8 39.08 PCB-187 9.76e8 38.90 40.0 41.0 PCB-185 9.75e8 171/173 39.51 1.66e9 PCB-183 PCB-181 40.53 9.87e8 PCB-174 PCB-177 9.47e8 39.428.30e8 40.34 8.03e8 39.62 39.99 42.0 43.0 180/193 2.13e9 42.40 PCB-172 8.40e8 41.88 PCB-191 1.16e9 42.73 44.0 PCB-170 8.08e8 43.51 45.0 Abs. Int. 3.84e8 PCB-190 1.19e9 43.96 1.92e8 0% 39.0 40.0 41.0 42.0 43.0 ES-180 4.34e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 1.07e7 ES-170 3.49e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 4.84e3 0.00e0 RT 5.36e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.98e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 9.63e6 ES-170 3.21e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 5.08e3 0.00e0 RT 4.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2041, 8697 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 16 of 21 597 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-189 1.29e9 46.12 Abs. Int. 3.12e8 (1.29e9 + 1.23e9) * 100 pg/uL RRF(PCB-189) = = 1.16 (5.47e7 + 5.39e7) * 2000 pg/uL LKB 03-Jan-2014 15:14 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.63e4 1.56e8 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.23e9 46.12 Abs. Int. 3.06e8 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 1.40e4 1.53e8 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 5.47e7 46.11 0.00e0 RT Abs. Int. 1.27e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 4.44e3 6.36e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 5.39e7 46.11 0.00e0 RT Abs. Int. 1.27e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.76e3 6.37e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2216, 7571 scc: 807-075 PKD: 30-Dec-2013 12:54 Printed: 03-Jan-2014 17:13 Page 17 of 21 598 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-202 7.56e8 40.10 Rel. Int. 100% PCB-201 8.55e8 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.48e4 PCB-197 8.62e8 PCB-204 41.66 PCB-200 8.05e8 7.97e8 41.75 41.47 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 198/199 1.17e9 44.07 Abs. Int. 2.15e8 PCB-196 5.92e8 44.65 PCB-203 6.25e8 44.82 1.08e8 0% 39.0 Rel. Int. 100% 40.0 PCB-202 8.24e8 40.10 41.0 PCB-201 9.27e8 40.89 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.08e4 42.0 43.0 44.0 45.0 198/199 1.28e9 44.07 PCB-197 9.38e8 PCB-204 41.66 PCB-200 8.78e8 8.63e8 41.75 41.47 0.00e0 RT Abs. Int. 2.36e8 PCB-196 6.50e8 44.65 PCB-203 6.78e8 44.82 1.18e8 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.48e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.29e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 3.12e3 4.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.68e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.97e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 3.99e3 4.48e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0215, 8218 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 18 of 21 599 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.20e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-205 9.28e8 48.29 PCB-195 6.71e8 45.95 Abs. Int. 2.26e8 PCB-194 7.24e8 47.89 1.13e8 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.62e4 47.0 48.0 49.0 50.0 PCB-205 1.00e9 48.29 PCB-195 7.29e8 45.94 0.00e0 RT Abs. Int. 2.44e8 PCB-194 7.81e8 47.89 1.22e8 0% 46.0 47.0 48.0 49.0 50.0 ES-205 4.04e7 48.27 Rel. Int. 100% Abs. Int. 9.47e6 JS-194 3.26e7 47.87 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.58e3 0.00e0 RT 4.73e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 4.53e7 48.27 Rel. Int. 100% Abs. Int. 1.07e7 JS-194 3.62e7 47.87 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.24e3 0.00e0 RT 5.36e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5003, 9428 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 19 of 21 600 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.01e4 PCB-208 8.58e8 45.74 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-207 8.96e8 46.53 Abs. Int. 2.14e8 PCB-206 5.80e8 49.77 1.07e8 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 9.96e3 PCB-208 1.09e9 45.74 47.0 48.0 49.0 50.0 PCB-207 1.14e9 46.53 Abs. Int. 2.72e8 PCB-206 7.39e8 49.77 1.36e8 0% 46.0 Rel. Int. 100% ES-208 3.65e7 45.72 47.0 48.0 49.0 (2.51e7 + 3.11e7) * 100 pg/uL RRF(ES-206) = = 0.817 (3.26e7 + 3.62e7) * 100 pg/uL LKB 03-Jan-2014 15:15 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.91e3 50.0 0.00e0 RT Abs. Int. 8.88e6 ES-206 2.51e7 49.75 4.44e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 4.54e7 45.72 50.0 Abs. Int. 1.10e7 ES-206 3.11e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 3.68e3 0.00e0 RT 5.50e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9164, 3773 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 20 of 21 601 of 711 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-209 9.25e8 51.24 Rel. Int. 100% Abs. Int. 1.91e8 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.67e2 9.53e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 7.84e8 51.24 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.62e8 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 7.64e2 8.12e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 4.05e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 8.58e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 9.63e2 4.29e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.38e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.95e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 9.42e2 3.48e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.37e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.68e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2549, 9998 scc: 807-075 PKD: 30-Dec-2013 12:54 Printed: 03-Jan-2014 17:13 Page 21 of 21 602 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.22e7 2.61e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.72e7 1.36e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 2.01e7 1.00e7 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.04e7 1.02e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.13e7 5.65e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.41e6 2.71e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.01e6 2.51e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 307-094 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:20 Page 1 of 21 603 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.16e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 3.94e3 1.58e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.54e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 4.69e3 7.70e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.27e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.36e3 6.37e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.24e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.44e4 1.62e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7343, 4554 scc: 307-094 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 2 of 21 604 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.28e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 5.78e3 6.40e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.33e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.40e4 2.67e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.06e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 1.15e4 1.53e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.13e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.54e3 4.07e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5268, 6714 scc: 307-094 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:20 Page 3 of 21 605 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 4.54e4 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PB 4σ 1.00e4 2.27e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PB 4σ 3.46e4 5.29e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PB 4σ 2.39e4 6.65e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.80e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 5.74e3 8.99e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7794, 8414 scc: 307-094 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 4 of 21 606 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.24e4 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PB 4σ 3.92e3 1.62e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.45e4 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PB 4σ 3.55e3 7.26e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e7 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PB 4σ 8.60e4 8.24e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e6 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 3.76e4 9.38e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9784, 2296 scc: 307-094 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 5 of 21 607 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-36 2.93e5 25.14 Abs. Int. 7.96e4 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.38e3 3.98e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-36 2.95e5 25.14 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.83e4 TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.71e3 4.42e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.09e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PB 4σ 1.03e5 3.54e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.88e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PB 4σ 2.46e4 4.44e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3148, 7222 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 6 of 21 608 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.93e3 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.09e3 1.96e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.96e3 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 2.52e3 2.48e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.40e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.94e4 1.70e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.28e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 1.07e4 1.14e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0991, 8988 scc: 307-094 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:20 Page 7 of 21 609 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.17e4 TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PB 4σ 2.25e3 5.84e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.15e4 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PB 4σ 2.67e3 5.76e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.91e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 2.82e4 2.96e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.07e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.92e4 1.53e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7948, 8617 scc: 307-094 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 8 of 21 610 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-79 2.26e5 31.75 PCB-72 2.07e5 27.52 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 6.17e4 PCB-78 1.97e5 32.24 TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.66e3 3.08e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 2.56e5 27.52 32.0 PCB-79 2.68e5 31.75 TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 3.32e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.90e4 PCB-78 2.72e5 32.24 3.95e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e5 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.37e4 5.49e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.25e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 2.33e4 2.12e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7736, 9764 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 9 of 21 611 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-96 1.05e5 26.00 Rel. Int. 100% Abs. Int. 3.40e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.14e3 1.70e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 1.64e5 26.00 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e4 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.87e3 2.36e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.13e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 1.83e3 4.07e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e4 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 3.05e3 6.03e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0353, 9971 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 10 of 21 612 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 1.10e5 28.67 PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 1.82e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 1.77e5 34.49 PCB-89 1.08e5 29.65 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 4.57e4 PCB-106 1.42e5 34.92 2.29e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 1.77e5 28.66 PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 2.25e3 32.0 34.0 107/124 2.62e5 34.49 PCB-89 1.65e5 29.65 36.0 38.0 0.00e0 RT Abs. Int. 6.64e4 PCB-106 2.46e5 34.92 3.32e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.39e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PB 4σ 2.97e3 4.19e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.10e4 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 3.35e3 1.05e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0422, 7587 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 11 of 21 613 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.14e4 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PB 4σ 1.38e3 5.68e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e4 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PB 4σ 2.07e3 5.82e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e4 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PB 4σ 3.86e3 5.35e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.79e3 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 3.22e3 4.40e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8143, 7330 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 12 of 21 614 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-152 1.98e5 30.81 Rel. Int. 100% Abs. Int. 5.01e4 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.45e3 2.51e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 1.63e5 30.82 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.90e4 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.20e3 2.45e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.02e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.13e3 3.51e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.52e3 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 1.46e3 4.26e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9006, 0485 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 13 of 21 615 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 4.57e4 128/166 1.94e5 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.70e3 2.29e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.57e4 128/166 1.54e5 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.45e3 1.78e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e4 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.35e3 5.83e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e4 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 2.67e3 6.86e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3751, 1283 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 14 of 21 616 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-184 1.12e5 36.29 Rel. Int. 100% Abs. Int. 2.62e4 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.47e2 1.31e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 9.31e4 36.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e4 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.58e2 1.29e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.56e3 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.34e3 3.28e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.66e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.42e3 2.83e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2030, 9921 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 15 of 21 617 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-182 1.14e5 39.07 Abs. Int. 3.24e4 HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.43e3 1.62e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 1.15e5 39.07 0.00e0 RT Abs. Int. 3.09e4 HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.38e3 1.55e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.25e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 2.06e3 3.63e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.88e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.65e3 4.44e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9648, 6911 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 16 of 21 618 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.01e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PB 4σ 1.19e3 5.03e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.51e3 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PB 4σ 1.11e3 4.26e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.79e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.59e3 3.90e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.31e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.83e3 3.16e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7686, 7875 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 17 of 21 619 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-204 9.83e4 41.46 Rel. Int. 100% Abs. Int. 2.26e4 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.80e2 1.13e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 1.07e5 41.46 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.65e4 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 9.64e2 1.33e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.22e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.43e3 2.61e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.84e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.17e3 2.42e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7434, 5203 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 18 of 21 620 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 5.92e3 OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PB 4σ 9.45e2 2.96e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.14e3 OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PB 4σ 1.03e3 3.57e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.89e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 9.26e2 1.95e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.29e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 1.20e3 2.14e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3968, 5793 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 19 of 21 621 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 6.43e3 NoCB 45.52-50.76 461.7245 Fn6 Flags: PB 4σ 8.92e2 3.21e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.70e3 NoCB 45.52-50.76 463.7216 Fn6 Flags: PB 4σ 1.80e3 4.35e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 7.83e2 1.70e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.03e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 9.21e2 1.52e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1314, 4053 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 20 of 21 622 of 711 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 9.53e3 DeCB 50.77-52.00 497.6826 Fn7 Flags: PB 4σ 6.42e2 4.77e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 8.19e3 DeCB 50.77-52.00 499.6797 Fn7 Flags: PB 4σ 5.71e2 4.09e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.38e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 8.45e2 3.69e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.06e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 9.91e2 2.03e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.01e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.51e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2056, 2173 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 21 of 21 623 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.22e7 2.61e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.70e7 1.35e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.95e7 9.77e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.02e7 1.01e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.16e7 5.82e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.65e6 2.82e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.37e6 2.69e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 023-880 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:21 Page 1 of 21 624 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% PCB-2 2.54e5 14.19 PCB-1 9.53e4 12.05 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 5.93e3 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 8.74e4 PCB-3 2.45e5 14.37 4.37e4 0% 11.0 12.0 13.0 Rel. Int. 100% PCB-2 7.20e4 14.19 PCB-1 3.41e4 12.05 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.60e3 14.0 15.0 0.00e0 16.0 RT Abs. Int. 3.18e4 PCB-3 8.20e4 14.37 1.59e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.47e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.84e3 7.33e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.77e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.83e4 1.39e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0471, 6660 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:21 Page 2 of 21 625 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. 100% Abs. Int. 2.84e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: B 4σ 9.07e3 1.42e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.71e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.21e4 2.35e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.27e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 9.85e3 1.63e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.15e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.73e3 4.07e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6955, 1198 scc: 023-880 Revised: 03-Jan-2014 10:42 (LKB) Printed: 03-Jan-2014 15:21 Page 3 of 21 626 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 13/12 7.84e5 20.10 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 7.95e3 Abs. Int. 1.62e5 PCB-15 5.54e5 20.40 8.10e4 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 13/12 4.79e5 20.11 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 3.56e4 21.0 0.00e0 RT Abs. Int. 1.68e5 PCB-15 2.92e5 20.40 8.40e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.47e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PB 4σ 2.95e4 7.34e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 8.05e3 8.91e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1004, 1945 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:21 Page 4 of 21 627 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 30/18 1.02e5 19.51 Rel. Int. 100% PCB-32 9.86e4 20.83 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 5.05e3 Abs. Int. 3.37e4 1.69e4 0% 17.0 18.0 19.0 20.0 30/18 8.90e4 19.51 Rel. Int. 100% 21.0 PCB-32 9.05e4 20.83 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 5.21e3 0.00e0 RT Abs. Int. 2.80e4 1.40e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.62e6 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PB 4σ 7.41e4 1.81e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e5 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 4.02e4 2.37e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7330, 0490 scc: 023-880 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 5 of 21 628 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 6.17e3 PCB-25 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 28/20 1.95e5 4.56e5 22.62 23.19 21/33 PCB-31 26/29 PCB-22 3.54e5 PCB-34 PCB-23 2.70e5 2.18e5 2.16e5 23.37 1.14e5 1.01e5 22.90 22.42 23.75 21.99 22.13 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 2.29e5 PCB-36 8.79e5 25.14 PCB-39 2.73e5 25.46 PCB-38 2.32e5 26.00 PCB-35 3.72e5 26.39 PCB-37 4.64e5 26.75 0% 22.0 23.0 24.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 5.69e3 25.0 26.0 27.0 PCB-34 PCB-23 1.21e5 8.99e4 21.99 22.14 PCB-31 2.22e5 22.90 28/20 4.74e5 23.19 PCB-39 2.84e5 25.46 PCB-22 2.14e5 23.75 PCB-38 2.31e5 25.99 PCB-35 3.67e5 26.39 PCB-37 4.75e5 26.75 0% 22.0 23.0 24.0 25.0 0.00e0 RT Abs. Int. 2.33e5 PCB-36 8.72e5 25.14 26/29 3.42e5 22.42 1.14e5 26.0 27.0 Rel. Int. 100% 1.16e5 0.00e0 RT Abs. Int. 1.82e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: B 4σ 1.01e5 9.12e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.65e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: B 4σ 2.14e4 2.33e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0081, 4527 scc: 023-880 Revised: 03-Jan-2014 10:43 (LKB) Printed: 03-Jan-2014 15:21 Page 6 of 21 629 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. 100% Abs. Int. 1.05e4 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.87e3 5.23e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e4 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 3.46e3 6.85e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.13e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.79e4 2.07e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 1.31e4 1.01e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1788, 2188 scc: 023-880 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 7 of 21 630 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 4.08e3 50/53 8.82e4 22.66 PCB-51 3.01e4 23.35 PCB-45 6.53e4 23.26 PCB-52 5.23e4 24.80 PCB-46 5.27e4 23.53 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 59/62… 2.93e5 44/47… 26.01 69/49 2.20e5 1.62e5 25.73 25.22 PCB-48 PCB-42 7.08e4 PCB-43 6.47e4 25.51 3.75e4 26.16 25.02 71/40 1.63e5 26.60 PCB-41 5.55e4 26.50 Abs. Int. 5.11e4 PCB-64 1.31e5 26.81 2.55e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 44/47… 2.62e5 25.73 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 3.91e3 50/53 1.15e5 22.66 PCB-45 9.74e4 PCB-51 23.26 3.49e4 23.34 PCB-73 PCB-52 8.10e4 8.34e4 24.93 24.81 PCB-46 5.48e4 23.53 69/49 1.69e5 25.23 PCB-48 8.01e4 25.51 59/62… 3.86e5 26.01 PCB-42 9.68e4 26.17 27.0 Abs. Int. 6.43e4 71/40 2.00e5 26.60 PCB-41 8.18e4 26.50 PCB-64 1.45e5 26.81 0% 22.0 23.0 24.0 25.0 26.0 0.00e0 RT 27.0 Rel. Int. 100% 3.22e4 0.00e0 RT Abs. Int. 5.61e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 3.21e4 2.80e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.20e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.50e4 2.10e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9260, 1022 scc: 023-880 Revised: 03-Jan-2014 10:45 (LKB) Printed: 03-Jan-2014 15:21 Page 8 of 21 631 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 4.14e3 PCB-79 6.64e5 31.75 PCB-68 1.40e5 27.78 61/70... 6.48e5 PCB-67 29.04 1.47e5 28.51 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-78 6.28e5 32.25 PCB-81 2.16e5 32.63 PCB-60 2.09e5 PCB-80 30.10 1.57e5 30.42 Abs. Int. 1.64e5 PCB-77 3.03e5 33.11 8.19e4 0% 28.0 30.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 5.02e3 PCB-68 1.72e5 27.78 61/70... 8.54e5 29.04 PCB-58 1.60e5 28.36 32.0 PCB-79 8.37e5 31.75 PCB-60 2.92e5 30.10 PCB-56 2.45e5 29.91 34.0 36.0 38.0 PCB-78 7.88e5 32.25 PCB-81 2.81e5 32.62 PCB-80 2.05e5 30.42 Abs. Int. 2.07e5 PCB-77 3.76e5 33.10 1.03e5 0% 28.0 30.0 32.0 0.00e0 RT 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.26e5 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.26e4 6.29e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 2.39e4 2.68e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9272, 0996 scc: 023-880 Revised: 03-Jan-2014 10:45 (LKB) Printed: 03-Jan-2014 15:21 Page 9 of 21 632 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-96 2.95e5 26.00 Rel. Int. 100% Abs. Int. 7.59e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 2.73e3 3.80e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 4.53e5 26.00 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e5 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 2.97e3 5.85e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.19e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 2.88e3 3.10e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e4 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 2.00e3 5.50e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9067, 8571 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 10 of 21 633 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 3.58e3 PCB-94 2.95e4 27.88 PCB-103 3.75e4 27.70 PCB-98 3.00e5 28.67 PCB-89 2.73e5 29.65 PCB-88 PCB-102 2.92e43.71e4 28.58 28.96 PCB-115PCB-111 116/85 108/119... 1.26e5 8.89e4 7.52e4 3.82e5 32.61 33.12 32.40 31.78 113/90… PCB-110 PCB-117 PCB-120 PCB-112 1.59e5 PCB-82 PCB-92 9.55e4 8.60e4 1.01e5 6.31e4 6.21e4 4.31e4 30.80 32.52 32.31 33.52 31.44 32.80 30.31 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 107/124 5.07e5 34.49 PCB-106 4.17e5 34.92 PCB-123 1.05e5 34.81 Abs. Int. 1.18e5 PCB-114 1.30e5 35.56 PCB-105 1.53e5 36.10 5.89e4 PCB-127 1.03e5 37.33 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 4.75e3 PCB-98 4.78e5 28.67 PCB-94 4.70e4 27.88 100/93 PCB-91 1.17e5 7.93e4 28.48 29.03 PCB-89 4.33e5 29.65 PCB-121 8.53e4 29.99 113/90… 2.82e5 30.80 108/119... 5.90e5 31.78 116/85 2.08e5 32.41 PCB-111 PCB-120 1.40e5 1.62e5 33.12 33.52 36.0 107/124 8.47e5PCB-106 34.49 6.54e5 34.92 PCB-118 2.21e5 35.09 PCB-114 PCB-123 2.15e5 1.84e5 35.56 34.80 38.0 Abs. Int. 2.03e5 PCB-105 2.46e5 36.10 1.01e5 PCB-127 1.72e5 37.33 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.74e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: B 4σ 3.01e3 4.87e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.22e3 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 2.81e3 4.11e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8550, 9289 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 11 of 21 634 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 3.44e4 PCB-126 1.41e5 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 3.09e3 1.72e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.47e4 PCB-126 2.22e5 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 3.11e3 2.73e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e4 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: B 4σ 2.86e3 6.96e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.66e4 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 4.68e3 8.28e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7286, 3128 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 12 of 21 635 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-152 5.29e5 30.82 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 2.53e3 Abs. Int. 1.36e5 PCB-136 7.72e4 31.26 PCB-155 PCB-150 5.62e4 6.03e4 30.95 30.65 147/149 1.25e5 34.10 PCB-145 7.39e4 31.54 PCB-148 4.67e4 32.81 151/135PCB-144 1.23e5 6.19e4 33.33 33.81 139/140 1.26e5 34.63 163/138… 153/168 2.49e5 1.85e5 PCB-130 37.76 36.69 7.31e4 37.18 PCB-133 6.22e4 35.59 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 4.18e5 30.82 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 2.89e3 PCB-155 5.10e4 30.65 30.0 0.00e0 RT Abs. Int. 9.83e4 PCB-136PCB-145 6.77e4 5.42e4 31.26 31.53 PCB-148 3.62e4 32.80 151/135 9.81e4 33.33 147/149 139/140 PCB-154 8.16e4 1.08e5 PCB-132 34.11 34.63 7.32e4 4.19e4 35.18 33.54 PCB-165 6.42e4 35.92 153/168 1.45e5 PCB-130 36.69 5.76e4 37.18 163/138… 2.19e5 37.76 0% 28.0 6.78e4 32.0 34.0 36.0 38.0 Rel. Int. 100% 4.91e4 0.00e0 RT Abs. Int. 7.03e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.12e3 3.52e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e4 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 2.03e3 5.60e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9259, 3315 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 13 of 21 636 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 1.39e5 128/166 6.14e5 38.82 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.34e3 PCB-159 PCB-162 1.16e5 1.26e5 39.87 39.63 156/157 3.32e5 41.27 PCB-167 1.57e5 40.28 PCB-169 2.14e5 43.99 6.96e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.22e5 128/166 4.95e5 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 2.96e3 PCB-159 PCB-162 8.70e4 9.27e4 39.87 39.64 156/157 2.77e5 41.26 PCB-167 1.32e5 40.28 PCB-169 1.69e5 43.99 6.08e4 0% 39.0 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.95e3 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.33e3 4.97e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.04e3 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 3.23e3 4.52e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8276, 7547 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 14 of 21 637 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-184 2.68e5 36.29 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.58e3 PCB-176 4.45e4 36.58 PCB-188 PCB-179 4.57e4 4.46e4 35.54 35.82 Abs. Int. 6.82e4 3.41e4 PCB-186 4.22e4 36.98 PCB-178 2.67e4 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.47e5 36.29 Rel. Int. 100% HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 1.40e3 PCB-188 3.07e4 35.54 PCB-179 4.09e4 35.82 PCB-176 3.65e4 36.58 Abs. Int. 6.26e4 3.13e4 PCB-186 3.84e4 36.98 PCB-178 3.29e4 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 0.00e0 RT 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.97e3 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.36e3 4.99e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.60e3 2.36e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4826, 4197 scc: 023-880 Revised: 03-Jan-2014 10:41 (LKB) Printed: 03-Jan-2014 15:21 Page 15 of 21 638 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 2.77e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Abs. Int. 8.38e4 PCB-182 3.66e5 39.07 PCB-187 6.01e4 38.89 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 180/193 1.45e5 42.40 PCB-181 6.17e4 40.33 PCB-172 PCB-192 7.81e4 6.05e4 42.12 41.88 171/173 9.70e4 40.52 PCB-191 1.03e5 42.73 PCB-170 7.09e4 43.50 PCB-190 1.20e5 43.96 4.19e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 2.37e3 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 9.23e4 PCB-182 3.30e5 39.07 PCB-187 4.62e4 38.89 PCB-181 5.19e4 40.34 171/173 1.09e5 40.52 180/193 1.66e5 42.40 PCB-172 6.22e4 41.87 PCB-191 8.30e4 42.74 PCB-170 7.42e4 43.50 PCB-190 1.10e5 43.96 4.62e4 0% 39.0 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.33e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 2.04e3 3.17e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.17e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.47e3 2.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4824, 0790 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 16 of 21 639 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-189 1.86e5 46.12 Abs. Int. 4.41e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 2.14e3 2.20e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.80e5 46.12 0.00e0 RT Abs. Int. 3.90e4 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 1.55e3 1.95e4 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.95e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.80e3 3.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.98e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.26e3 2.99e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9412, 0969 scc: 023-880 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:21 Page 17 of 21 640 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 7.23e4 PCB-204 2.75e5 41.47 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.73e3 PCB-202 3.27e4 40.09 198/199 8.41e4 44.07 PCB-197PCB-200 5.44e4 4.31e4 41.65 41.74 PCB-201 4.24e4 40.88 PCB-196 3.54e4 44.64 PCB-203 5.07e4 44.81 0% 39.0 40.0 41.0 Rel. Int. 100% 42.0 43.0 44.0 45.0 PCB-202 3.20e4 40.10 PCB-201 4.63e4 40.88 198/199 9.16e4 44.07 PCB-197 5.35e4PCB-200 41.65 3.24e4 41.74 PCB-196 5.46e4 44.65 4.03e4 PCB-203 5.63e4 44.82 0% 39.0 40.0 41.0 0.00e0 RT Abs. Int. 8.06e4 PCB-204 2.97e5 41.46 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.53e3 3.61e4 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.40e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.09e3 2.20e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.81e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.39e3 2.41e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3025, 8975 scc: 023-880 Revised: 03-Jan-2014 11:04 (LKB) Printed: 03-Jan-2014 15:21 Page 18 of 21 641 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.24e3 PCB-205 1.41e5 48.29 PCB-194 1.24e5 47.89 PCB-195 7.30e4 45.94 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 3.02e4 1.51e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.81e3 47.0 48.0 50.0 PCB-205 1.59e5 48.29 PCB-194 1.34e5 47.88 PCB-195 8.40e4 45.94 49.0 0.00e0 RT Abs. Int. 3.19e4 1.60e4 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.72e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 9.24e2 1.86e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.30e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 1.09e3 2.15e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4721, 5462 scc: 023-880 Revised: 03-Jan-2014 10:41 (LKB) Printed: 03-Jan-2014 15:22 Page 19 of 21 642 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.18e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-206 1.29e5 49.76 PCB-207 9.69e4 46.52 Abs. Int. 2.57e4 PCB-208 8.35e4 45.73 1.28e4 0% 46.0 48.0 49.0 50.0 PCB-206 1.73e5 49.76 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 2.42e3 47.0 PCB-208 9.91e4 45.73 Abs. Int. 4.00e4 PCB-207 1.16e5 46.52 2.00e4 0% 46.0 0.00e0 RT 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.41e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 9.48e2 1.20e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.76e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 8.46e2 1.38e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3085, 2852 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:22 Page 20 of 21 643 of 711 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-209 2.67e5 51.24 Rel. Int. 100% Abs. Int. 4.95e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 7.44e2 2.47e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.36e5 51.24 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.55e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.79e2 2.27e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.81e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 8.32e2 1.91e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.08e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 7.81e2 2.54e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.37e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.69e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6138, 0081 scc: 023-880 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 21 of 21 644 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.15e7 2.57e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.57e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.83e7 9.14e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.86e7 9.28e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.12e7 5.60e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.71e6 2.85e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.51e6 2.76e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 979-518 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:22 Page 1 of 21 645 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 3.05e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: B 4σ 4.17e3 1.52e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.64e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: B 4σ 4.11e3 8.18e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.16e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.27e3 5.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.96e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 4.32e4 1.48e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5489, 8194 scc: 979-518 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 2 of 21 646 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.27e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 7.90e3 6.34e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.88e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.37e4 2.44e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.49e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 9.74e3 1.74e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.63e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 4.20e3 3.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7629, 0428 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 3 of 21 647 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 5.56e4 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: B 4σ 8.46e3 2.78e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PB 4σ 3.25e4 5.50e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: B 4σ 2.86e4 6.38e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.63e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 8.50e3 8.13e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8027, 5868 scc: 979-518 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 4 of 21 648 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.85e4 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PB 4σ 4.38e3 9.27e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e4 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PB 4σ 5.38e3 8.02e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.40e6 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: B 4σ 8.60e4 4.70e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e6 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 3.91e4 5.47e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0214, 1156 scc: 979-518 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 5 of 21 649 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-36 7.19e5 25.13 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.14e3 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.86e5 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 9.28e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-36 7.38e5 25.13 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e5 TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.70e3 9.30e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.09e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PB 4σ 9.16e4 2.54e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.78e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PB 4σ 2.79e4 2.89e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5941, 5542 scc: 979-518 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 6 of 21 650 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 6.01e3 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.17e3 3.00e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.11e3 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 2.42e3 3.56e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.72e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.83e4 1.86e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 9.43e3 9.97e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0820, 5379 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 7 of 21 651 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.58e4 TeCB-3 21.52-27.30 289.9224 Fn3 Flags: B 4σ 3.16e3 7.90e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.18e4 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PB 4σ 2.98e3 1.09e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.82e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 2.93e4 2.41e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.23e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.52e4 1.62e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8350, 9425 scc: 979-518 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 8 of 21 652 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 5.47e5 27.52 PCB-79 5.36e5 31.74 TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.89e3 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.43e5 PCB-78 5.18e5 32.24 7.14e4 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 4.42e3 30.0 32.0 PCB-79 7.00e5 31.74 PCB-72 6.98e5 27.51 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.76e5 PCB-78 6.62e5 32.24 8.82e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.97e4 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.92e4 3.99e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.63e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 1.73e4 2.31e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2818, 5309 scc: 979-518 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 9 of 21 653 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-96 2.82e5 25.99 Rel. Int. 100% Abs. Int. 7.28e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 2.12e3 3.64e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 4.29e5 25.99 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e5 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.71e3 5.88e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.59e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 1.81e3 4.29e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.60e3 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 2.46e3 3.80e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8819, 8478 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 10 of 21 654 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 2.64e5 28.66 PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 2.65e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 3.94e5 34.48 PCB-89 2.48e5 29.64 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 8.72e4 PCB-106 3.37e5 34.91 4.36e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 4.27e5 28.66 PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 2.41e3 32.0 34.0 107/124 6.21e5 34.48 PCB-89 4.17e5 29.64 36.0 38.0 0.00e0 RT Abs. Int. 1.58e5 PCB-106 5.67e5 34.91 7.89e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.87e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PB 4σ 2.55e3 3.93e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e4 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 3.22e3 6.44e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9704, 3378 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 11 of 21 655 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.12e4 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PB 4σ 1.59e3 5.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e4 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PB 4σ 2.77e3 1.01e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.73e3 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PB 4σ 2.80e3 4.36e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e4 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 3.82e3 6.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2883, 5187 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 12 of 21 656 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-152 4.83e5 30.81 Rel. Int. 100% Abs. Int. 1.18e5 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.87e3 5.91e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 3.94e5 30.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.51e4 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.90e3 4.75e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.12e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.86e3 4.06e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e3 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 1.70e3 4.24e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0506, 2521 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 13 of 21 657 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.20e5 128/166 4.76e5 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 2.12e3 6.00e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.02e5 128/166 3.90e5 38.81 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 2.33e3 5.11e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.60e3 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.45e3 4.80e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.66e4 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 3.23e3 8.31e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2148, 6219 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 14 of 21 658 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-184 2.50e5 36.28 Rel. Int. 100% Abs. Int. 6.09e4 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.13e3 3.04e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.25e5 36.28 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.52e4 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.66e2 2.76e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e4 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.64e3 7.92e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.24e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.38e3 2.12e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4369, 5758 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 15 of 21 659 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-182 3.17e5 39.06 Abs. Int. 7.81e4 HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.82e3 3.90e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 2.99e5 39.06 0.00e0 RT Abs. Int. 7.31e4 HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.86e3 3.66e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.19e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 1.88e3 4.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.22e3 4.24e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1213, 4954 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 16 of 21 660 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 9.62e3 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PB 4σ 1.27e3 4.81e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.53e3 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PB 4σ 1.44e3 3.76e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.39e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.56e3 2.69e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.29e3 2.36e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7659, 9371 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 17 of 21 661 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-204 2.39e5 41.45 Rel. Int. 100% Abs. Int. 6.07e4 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.15e3 3.04e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 2.84e5 41.45 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.24e4 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.08e3 3.62e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.33e3 2.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.83e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.25e3 2.92e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8871, 8933 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 18 of 21 662 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 5.29e3 OcCB-6 45.52-50.76 427.7635 Fn6 Flags: B 4σ 1.16e3 2.65e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.96e3 OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PB 4σ 1.12e3 2.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.04e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 7.05e2 1.52e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 8.79e2 1.29e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4309, 5142 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 19 of 21 663 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 4.42e3 NoCB 45.52-50.76 461.7245 Fn6 Flags: PB 4σ 1.08e3 2.21e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.67e3 NoCB 45.52-50.76 463.7216 Fn6 Flags: PB 4σ 1.77e3 2.84e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.46e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 8.65e2 1.73e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.81e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 7.98e2 1.40e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8411, 8296 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 20 of 21 664 of 711 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 4.94e3 DeCB 50.77-52.00 497.6826 Fn7 Flags: PB 4σ 4.11e2 2.47e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.97e3 DeCB 50.77-52.00 499.6797 Fn7 Flags: PB 4σ 6.24e2 2.48e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.05e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 5.08e2 1.02e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.19e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 9.76e2 1.09e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.51e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.76e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9640, 2741 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 21 of 21 Experiment Calibration Report 665 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 1 @ 200 (ppm) Printed: Friday, December 20, 2013 14:51:56 Eastern Standard Time M 180.9888 R 11467 M 192.9888 R 9920 242.8 M 204.9888 R 12316 180.9 1.00e0 x16 1.200 M 218.9856 R 11902 192.9 1.00e0 x16 204.9 1.00e0 x16 x16 0.425 0.065 0.100 1.00e0 0.400 0.060 1.100 0.375 0.090 0.055 1.000 0.080 0.350 0.325 0.050 0.900 0.070 0.300 0.045 0.800 0.275 0.040 0.060 0.700 0.250 0.035 0.600 0.225 0.050 0.200 0.030 0.500 0.175 0.040 0.025 0.150 0.400 0.030 0.300 0.020 0.125 0.015 0.100 0.020 0.075 0.200 0.010 0.050 0.010 0.100 -0.000 0.005 -0.000 180.87 180.88 180.89 180.90 192.86 M 230.9856 R 11523 192.87 192.88 192.89 230.8 x16 1.00e0 x16 0.600 0.170 0.550 0.160 0.150 0.500 0.140 0.450 0.130 0.120 0.400 0.110 0.350 0.100 0.090 0.300 0.080 0.250 0.070 0.060 0.200 0.050 0.150 0.040 0.030 0.100 0.020 0.050 0.010 -0.000 -0.000 230.82 230.83 230.84 230.85 242.80 242.81 242.82 242.83 242.84 -0.000 204.85 M 242.9856 R 11311 218.8 1.00e0 0.025 -0.000 204.86 204.87 204.88 218.83 218.84 218.85 218.86 Experiment Calibration Report 666 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 2 @ 200 (ppm) Printed: Friday, December 20, 2013 14:52:25 Eastern Standard Time M 218.9856 R 11415 M 230.9856 R 11111 304.8 M 242.9856 R 10549 218.9 1.00e0 x16 0.400 M 254.9856 R 10639 230.9 1.00e0 x16 242.9 1.00e0 x16 0.600 1.00e0 x16 0.110 0.200 0.375 0.550 0.100 0.350 0.180 0.500 0.325 0.090 0.300 0.450 0.160 0.400 0.140 0.080 0.275 0.250 0.070 0.350 0.225 0.120 0.060 0.200 0.300 0.100 0.050 0.175 0.250 0.080 0.150 0.040 0.200 0.125 0.060 0.100 0.030 0.150 0.075 0.040 0.020 0.100 0.050 0.050 0.025 -0.000 -0.000 218.86 218.87 218.88 218.89 230.85 M 268.9824 R 10161 230.86 230.87 230.88 0.010 -0.000 -0.000 230.89 M 280.9824 R 10871 254.8 0.020 242.84 242.85 x16 242.87 242.88 M 292.9824 R 10203 268.8 1.00e0 242.86 254.83 254.84 254.85 x16 0.280 254.87 M 304.9824 R 10820 280.8 1.00e0 254.86 292.8 1.00e0 x16 1.00e0 x16 0.120 0.150 0.070 0.260 0.140 0.110 0.065 0.100 0.060 0.240 0.130 0.220 0.120 0.055 0.090 0.110 0.200 0.100 0.180 0.090 0.160 0.070 0.140 0.060 0.050 0.080 0.045 0.040 0.080 0.035 0.070 0.120 0.030 0.050 0.060 0.100 0.025 0.040 0.050 0.080 0.020 0.040 0.030 0.060 0.015 0.030 0.020 0.040 0.020 0.010 0.010 0.020 0.010 -0.000 -0.000 268.81 268.82 268.83 268.84 268.85 0.005 -0.000 280.80 280.81 280.82 280.83 280.84 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 304.78 304.79 304.80 304.81 304.82 304.83 Experiment Calibration Report 667 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 3 @ 200 (ppm) Printed: Friday, December 20, 2013 14:52:57 Eastern Standard Time M 242.9856 R 11208 M 254.9856 R 10868 342.8 M 268.9824 R 10822 242.9 1.00e0 x16 M 280.9824 R 10819 254.9 1.00e0 x16 268.8 1.00e0 x16 1.00e0 x16 0.110 0.200 0.100 0.180 0.090 0.160 0.080 0.160 0.320 0.150 0.300 0.140 0.280 0.130 0.260 0.120 0.240 0.110 0.220 0.100 0.200 0.090 0.180 0.080 0.160 0.070 0.140 0.060 0.120 0.050 0.100 0.040 0.080 0.030 0.060 0.020 0.040 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.010 0.010 -0.000 -0.000 242.85 242.86 242.87 242.88 242.89 254.84 M 292.9824 R 11364 254.85 254.86 254.87 M 304.9824 R 10328 280.8 0.020 -0.000 268.82 254.88 268.83 268.84 x16 0.160 268.86 -0.000 280.81 268.87 M 316.9824 R 10549 292.8 1.00e0 268.85 280.82 280.83 280.84 x16 280.86 M 330.9792 R 9803 304.8 1.00e0 280.85 316.8 1.00e0 x16 1.00e0 x16 0.110 0.100 0.045 0.150 0.100 0.090 0.040 0.140 0.090 0.130 0.080 0.035 0.120 0.080 0.070 0.110 0.030 0.070 0.100 0.060 0.090 0.060 0.025 0.080 0.050 0.070 0.050 0.020 0.040 0.060 0.040 0.015 0.050 0.030 0.030 0.040 0.010 0.020 0.030 0.020 0.020 0.005 0.010 0.010 0.010 -0.000 -0.000 292.80 292.81 292.82 292.83 292.84 292.85 304.79 M 342.9792 R 10375 330.8 1.00e0 x16 0.075 0.070 0.065 0.060 0.055 0.050 0.045 0.040 0.035 0.030 0.025 0.020 0.015 0.010 0.005 -0.000 342.76 342.77 342.78 342.79 342.80 342.81 -0.000 342.82 304.80 304.81 304.82 304.83 304.84 316.78 316.79 316.80 316.81 316.82 316.83 -0.000 330.76 330.77 330.78 330.79 330.80 330.81 330.82 Experiment Calibration Report 668 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 4 @ 200 (ppm) Printed: Friday, December 20, 2013 14:53:27 Eastern Standard Time M 280.9824 R 11901 M 292.9824 R 10771 416.8 M 304.9824 R 11159 280.8 1.00e0 x16 0.320 0.160 0.300 0.150 0.280 0.140 M 316.9824 R 10777 292.8 1.00e0 x16 304.8 1.00e0 x16 0.130 0.240 0.120 0.220 0.110 0.200 0.100 0.180 0.090 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 x16 0.045 0.110 0.040 0.100 0.260 1.00e0 0.120 0.090 0.035 0.080 0.030 0.070 0.025 0.060 0.020 0.050 0.040 0.015 0.030 0.010 0.020 0.005 0.010 0.020 0.010 -0.000 -0.000 280.83 280.84 280.85 280.86 -0.000 280.87 292.82 M 330.9792 R 11627 292.83 292.84 292.85 292.86 304.81 M 342.9792 R 10375 316.8 -0.000 304.82 304.83 x16 0.160 304.85 304.86 M 354.9792 R 10965 330.8 1.00e0 304.84 316.79 316.80 316.81 316.82 x16 x16 1.00e0 x16 0.034 0.032 0.060 0.150 316.85 354.8 1.00e0 0.065 0.120 316.84 M 366.9792 R 10868 342.8 1.00e0 316.83 0.110 0.030 0.140 0.055 0.028 0.100 0.130 0.050 0.120 0.026 0.090 0.024 0.045 0.110 0.080 0.022 0.040 0.100 0.020 0.070 0.090 0.080 0.035 0.018 0.030 0.016 0.060 0.070 0.014 0.050 0.025 0.060 0.012 0.040 0.050 0.040 0.020 0.030 0.030 0.010 0.008 0.015 0.006 0.020 0.010 0.010 0.005 -0.000 -0.000 0.020 0.004 0.010 -0.000 330.78 330.79 330.80 330.81 330.82 330.83 342.77 M 380.9760 R 10685 342.78 342.79 342.80 342.81 342.82 342.83 M 392.9760 R 10869 366.8 0.002 -0.000 354.76 354.77 354.78 x16 354.80 354.81 354.82 M 404.9760 R 10290 380.8 1.00e0 354.79 366.74 366.75 366.76 366.77 x16 366.79 366.80 366.81 M 416.9760 R 11464 392.8 1.00e0 366.78 404.8 1.00e0 x16 1.00e0 x16 0.028 0.065 0.015 0.045 0.026 0.014 0.060 0.024 0.040 0.013 0.055 0.022 0.012 0.035 0.050 0.045 0.030 0.040 0.020 0.011 0.018 0.010 0.016 0.009 0.025 0.035 0.008 0.014 0.030 0.007 0.012 0.020 0.006 0.025 0.010 0.005 0.015 0.020 0.008 0.015 0.006 0.004 0.010 0.003 0.010 0.004 0.002 0.005 0.005 0.002 -0.000 -0.000 380.73 380.74 380.75 380.76 380.77 380.78 380.79 0.001 -0.000 392.72 392.73 392.74 392.75 392.76 392.77 392.78 392.79 404.72 404.73 404.74 404.75 404.76 404.77 404.78 404.79 -0.000 416.71 416.72 416.73 416.74 416.75 416.76 416.77 416.78 416.79 Experiment Calibration Report 669 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 5 @ 200 (ppm) Printed: Friday, December 20, 2013 14:54:02 Eastern Standard Time M 316.9824 R 10870 M 330.9792 R 10775 442.7 M 342.9792 R 10285 316.8 1.00e0 x16 M 354.9792 R 10121 330.8 1.00e0 x16 342.8 1.00e0 x16 0.150 x16 0.065 0.130 0.045 1.00e0 0.140 0.060 0.120 0.130 0.040 0.055 0.110 0.120 0.035 0.100 0.050 0.100 0.090 0.045 0.090 0.080 0.040 0.080 0.070 0.035 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.110 0.030 0.025 0.070 0.020 0.060 0.050 0.015 0.040 0.010 0.030 0.020 0.005 -0.000 -0.000 316.78 316.79 316.80 316.81 316.82 -0.000 316.83 330.76 M 366.9792 R 10872 0.005 0.010 0.010 330.77 330.78 330.79 330.80 330.81 342.75 M 380.9760 R 10122 354.8 -0.000 330.82 342.76 342.77 342.78 x16 342.81 354.74 354.75 354.76 x16 354.77 354.78 354.79 354.80 M 404.9760 R 9840 380.7 1.00e0 0.100 0.040 342.80 M 392.9760 R 10775 366.8 1.00e0 342.79 392.7 1.00e0 x16 1.00e0 x16 0.070 0.045 0.065 0.090 0.035 0.060 0.080 0.040 0.055 0.030 0.035 0.050 0.070 0.045 0.025 0.030 0.060 0.040 0.025 0.050 0.020 0.035 0.030 0.020 0.040 0.015 0.025 0.015 0.030 0.020 0.010 0.015 0.020 0.010 0.010 0.005 0.005 0.010 0.005 -0.000 -0.000 366.73 366.74 366.75 366.76 366.77 366.78 -0.000 366.79 380.71 M 416.9760 R 10964 380.72 380.73 380.74 380.75 380.76 380.77 392.70 M 430.9728 R 10332 404.7 -0.000 392.71 392.72 392.73 x16 392.75 392.76 404.68 M 442.9728 R 10204 416.7 1.00e0 392.74 430.7 1.00e0 x16 0.040 1.00e0 x16 0.030 0.026 0.028 0.024 0.035 0.026 0.022 0.024 0.030 0.020 0.022 0.020 0.018 0.025 0.018 0.016 0.016 0.014 0.020 0.014 0.012 0.012 0.015 0.010 0.010 0.008 0.008 0.010 0.006 0.006 0.004 0.004 0.005 0.002 0.002 -0.000 416.67 416.68 416.69 416.70 416.71 416.72 416.73 416.74 -0.000 430.65 -0.000 430.66 430.67 430.68 430.69 430.70 430.71 430.72 430.73 442.65 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 404.69 404.70 404.71 404.72 404.73 404.74 404.75 Experiment Calibration Report 670 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 6 @ 200 (ppm) Printed: Friday, December 20, 2013 14:55:29 Eastern Standard Time M 380.9760 R 10121 M 392.9760 R 10333 480.6 M 404.9760 R 10730 380.7 1.00e0 x16 M 416.9760 R 10825 392.7 1.00e0 x16 404.7 1.00e0 x16 1.00e0 x16 0.080 0.090 0.075 0.050 0.035 0.070 0.080 0.045 0.065 0.030 0.060 0.070 0.040 0.055 0.025 0.035 0.060 0.050 0.045 0.030 0.050 0.020 0.040 0.025 0.035 0.040 0.030 0.030 0.015 0.020 0.025 0.015 0.010 0.020 0.020 0.015 0.010 0.005 0.010 0.010 0.005 0.005 -0.000 -0.000 380.69 380.70 380.71 380.72 380.73 380.74 380.75 -0.000 380.76 M 430.9728 R 9958 392.68 392.69 392.70 392.71 392.72 392.73 392.74 M 442.9728 R 10204 416.7 -0.000 404.66 404.67 404.68 404.69 404.70 x16 404.72 404.73 416.65 M 454.9728 R 10286 430.7 1.00e0 404.71 416.66 416.67 416.68 x16 416.70 416.71 416.72 M 466.9728 R 10246 442.7 1.00e0 416.69 454.6 1.00e0 x16 1.00e0 x16 0.026 0.050 0.045 0.024 0.050 0.045 0.022 0.040 0.045 0.040 0.020 0.040 0.035 0.018 0.035 0.035 0.030 0.016 0.030 0.030 0.014 0.025 0.025 0.025 0.012 0.020 0.020 0.010 0.020 0.015 0.015 0.015 0.010 0.010 0.008 0.006 0.010 0.004 0.005 0.005 0.005 0.002 -0.000 -0.000 430.63 430.64 430.65 430.66 430.67 430.68 430.69 430.70 430.71 M 480.9696 R 10165 466.6 1.00e0 x16 0.028 0.026 0.024 0.022 0.020 0.018 0.016 0.014 0.012 0.010 0.008 0.006 0.004 0.002 -0.000 480.57 480.58 480.59 480.60 480.61 480.62 480.63 480.64 480.65 480.66 -0.000 442.62 442.63 442.64 442.65 442.66 442.67 442.68 442.69 442.70 -0.000 454.61 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 466.59 466.60 466.61 466.62 466.63 466.64 466.65 466.66 466.67 466.68 Experiment Calibration Report 671 of 711 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 7 @ 200 (ppm) Printed: Friday, December 20, 2013 14:56:11 Eastern Standard Time M 430.9728 R 10591 M 442.9728 R 11468 516.6 M 454.9728 R 10774 430.7 1.00e0 x16 M 466.9728 R 11625 442.7 1.00e0 x16 454.7 1.00e0 x16 0.055 1.00e0 x16 0.032 0.050 0.045 0.030 0.050 0.045 0.028 0.040 0.045 0.026 0.040 0.024 0.035 0.040 0.022 0.035 0.035 0.030 0.020 0.030 0.018 0.030 0.025 0.016 0.025 0.025 0.014 0.020 0.020 0.012 0.020 0.015 0.010 0.015 0.015 0.008 0.010 0.010 0.010 0.006 0.004 0.005 0.005 0.005 0.002 -0.000 -0.000 430.66 430.67 430.68 430.69 430.70 430.71 430.72 430.73 -0.000 442.64 M 480.9696 R 9999 442.65 442.66 442.67 442.68 442.69 442.70 442.71 454.63 M 492.9696 R 11060 466.7 -0.000 442.72 454.64 454.65 454.66 x16 454.68 454.69 454.70 454.71 466.62 M 504.9696 R 10504 480.6 1.00e0 454.67 466.63 466.64 466.65 x16 466.67 466.68 466.69 504.6 1.00e0 x16 0.040 1.00e0 x16 0.020 0.034 0.032 0.032 0.018 0.030 0.035 0.030 0.028 0.028 0.026 0.016 0.030 0.026 0.024 0.014 0.024 0.022 0.022 0.025 0.012 0.020 0.020 0.018 0.018 0.016 0.020 0.010 0.016 0.014 0.008 0.014 0.015 0.012 0.012 0.010 0.010 0.008 0.008 0.006 0.006 0.004 0.004 0.006 0.010 0.004 0.002 0.002 -0.000 -0.000 480.60 480.61 480.62 480.63 480.64 480.65 480.66 480.67 480.68 0.005 0.002 -0.000 492.59 492.60 492.61 492.62 492.63 492.64 492.65 492.66 492.67 -0.000 504.57 504.58 504.59 504.60 504.61 504.62 466.70 M 516.9697 R 11012 492.6 1.00e0 0.034 466.66 504.63 504.64 504.65 504.66 516.56 516.57 516.58 516.59 516.60 516.61 516.62 516.63 516.64 Resolution Check Report Printed: 672 of 711 Page 1 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 180.9888 R 11709 M 192.9888 R 10531 180.9 M 204.9888 R 11823 192.9 1.00e0 x16 M 218.9856 R 12380 204.9 1.00e0 x16 218.9 1.00e0 x16 1.00e0 x16 0.130 0.075 1.300 0.450 0.120 0.070 1.200 0.110 0.065 0.100 0.060 0.400 1.100 0.350 1.000 0.055 0.090 0.900 0.050 0.300 0.080 0.800 0.045 0.070 0.700 0.250 0.040 0.060 0.035 0.050 0.030 0.600 0.200 0.500 0.025 0.040 0.400 0.150 0.020 0.030 0.300 0.100 0.015 0.200 0.020 0.100 0.010 0.010 0.050 -0.000 0.005 -0.000 180.87 180.88 180.89 -0.000 180.90 192.86 M 230.9856 R 11709 192.87 192.88 204.85 M 242.9856 R 11344 230.8 -0.000 192.89 204.86 204.87 x16 218.83 M 218.9856 R 11709 242.8 1.00e0 204.88 218.84 218.85 x16 218.87 M 230.9856 R 11709 218.9 1.00e0 218.86 230.9 1.00e0 x16 1.00e0 x16 0.650 0.200 0.450 0.650 0.600 0.425 0.180 0.550 0.400 0.600 0.375 0.550 0.160 0.500 0.350 0.500 0.450 0.325 0.140 0.450 0.300 0.400 0.275 0.120 0.400 0.250 0.350 0.350 0.100 0.225 0.300 0.300 0.200 0.080 0.250 0.175 0.250 0.150 0.200 0.060 0.200 0.125 0.150 0.150 0.100 0.040 0.075 0.100 0.020 0.050 -0.000 -0.000 0.100 0.050 0.050 0.025 -0.000 230.82 230.83 230.84 230.85 230.86 242.81 M 242.9856 R 11737 242.82 242.83 242.84 242.85 218.86 M 254.9856 R 11378 242.9 -0.000 218.87 218.88 x16 230.85 M 268.9824 R 11848 254.8 1.00e0 218.89 x16 0.110 0.100 230.89 280.8 x16 1.00e0 x16 0.320 0.160 0.200 230.88 M 280.9824 R 11210 1.00e0 0.170 0.220 230.87 268.8 1.00e0 0.120 0.240 230.86 0.300 0.150 0.280 0.140 0.260 0.130 0.180 0.090 0.160 0.080 0.140 0.070 0.240 0.120 0.220 0.110 0.200 0.100 0.180 0.090 0.120 0.060 0.100 0.050 0.080 0.040 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.060 0.030 0.040 0.020 0.040 0.080 0.030 0.060 0.040 0.020 0.010 0.020 -0.000 -0.000 242.84 242.85 242.86 242.87 242.88 254.83 254.84 254.85 254.86 254.87 0.010 0.020 -0.000 -0.000 268.81 268.82 268.83 268.84 268.85 268.86 280.80 280.81 280.82 280.83 280.84 280.85 Resolution Check Report Printed: 673 of 711 Page 2 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 292.9824 R 11577 M 304.9824 R 11389 292.8 M 242.9856 R 11827 304.8 1.00e0 x16 M 254.9856 R 11793 242.9 1.00e0 x16 254.9 1.00e0 x16 1.00e0 x16 0.090 0.240 0.120 0.085 0.140 0.220 0.080 0.130 0.110 0.075 0.200 0.120 0.100 0.070 0.110 0.180 0.065 0.100 0.060 0.090 0.055 0.090 0.160 0.080 0.140 0.050 0.070 0.080 0.045 0.120 0.070 0.060 0.040 0.060 0.035 0.050 0.030 0.040 0.025 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.030 0.015 0.020 0.010 0.020 0.010 0.010 0.005 -0.000 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 -0.000 304.78 M 268.9824 R 11467 304.79 304.80 304.81 304.82 304.83 M 280.9824 R 11683 268.8 -0.000 242.85 242.86 242.87 x16 242.89 254.84 M 292.9824 R 11337 280.8 1.00e0 242.88 254.85 254.86 x16 254.88 M 304.9824 R 11548 292.8 1.00e0 254.87 304.8 1.00e0 x16 1.00e0 x16 0.360 0.170 0.180 0.110 0.340 0.160 0.320 0.160 0.100 0.150 0.300 0.140 0.280 0.140 0.090 0.130 0.260 0.080 0.120 0.240 0.120 0.110 0.220 0.070 0.100 0.200 0.100 0.080 0.060 0.040 0.020 0.180 0.090 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.010 0.060 0.050 0.040 0.030 0.020 0.010 -0.000 -0.000 268.83 268.84 268.85 268.86 -0.000 268.87 280.82 M 316.9824 R 11605 280.83 280.84 280.85 292.81 M 330.9792 R 11186 316.8 -0.000 280.86 292.82 292.83 x16 292.85 x16 0.110 304.83 304.84 304.85 280.9 x16 1.00e0 x16 0.375 0.085 0.120 304.82 M 280.9824 R 11876 1.00e0 0.090 0.130 0.045 304.81 342.8 1.00e0 0.050 304.80 M 342.9792 R 11340 330.8 1.00e0 0.055 292.84 0.350 0.080 0.325 0.075 0.300 0.070 0.100 0.040 0.065 0.275 0.060 0.250 0.090 0.035 0.080 0.055 0.225 0.050 0.030 0.070 0.200 0.045 0.025 0.175 0.060 0.040 0.050 0.020 0.035 0.150 0.030 0.125 0.040 0.025 0.015 0.030 0.075 0.010 0.015 0.020 0.050 0.010 0.005 -0.000 316.78 0.100 0.020 0.010 -0.000 316.79 316.80 316.81 316.82 316.83 316.84 330.77 330.78 330.79 330.80 330.81 330.82 330.83 0.005 0.025 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 280.83 280.84 280.85 280.86 280.87 280.88 Resolution Check Report Printed: 674 of 711 Page 3 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 292.9824 R 12107 M 304.9824 R 11576 292.8 M 316.9824 R 11932 304.8 1.00e0 x16 M 330.9792 R 11547 316.8 1.00e0 x16 330.8 1.00e0 x16 1.00e0 x16 0.200 0.180 0.055 0.130 0.170 0.180 0.120 0.050 0.160 0.150 0.110 0.160 0.045 0.140 0.100 0.140 0.130 0.040 0.090 0.120 0.035 0.120 0.110 0.080 0.100 0.070 0.030 0.060 0.025 0.100 0.090 0.080 0.080 0.070 0.050 0.020 0.060 0.060 0.040 0.050 0.015 0.030 0.040 0.040 0.010 0.030 0.020 0.020 0.020 0.005 0.010 -0.000 0.010 -0.000 292.82 292.83 292.84 292.85 292.86 -0.000 292.87 304.81 M 342.9792 R 11458 304.82 304.83 304.84 304.85 316.80 M 354.9792 R 11569 342.8 -0.000 304.86 316.81 316.82 316.83 x16 316.85 330.78 M 366.9792 R 12588 354.8 1.00e0 316.84 330.79 330.80 330.81 x16 330.83 330.84 M 380.9760 R 11628 366.8 1.00e0 330.82 380.8 1.00e0 x16 1.00e0 x16 0.080 0.075 0.130 0.075 0.070 0.040 0.120 0.070 0.065 0.110 0.065 0.035 0.060 0.060 0.100 0.055 0.055 0.030 0.090 0.050 0.050 0.080 0.045 0.025 0.045 0.040 0.070 0.040 0.035 0.060 0.020 0.035 0.030 0.030 0.050 0.015 0.025 0.025 0.040 0.020 0.020 0.010 0.030 0.015 0.020 0.015 0.010 0.010 0.005 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 342.83 0.005 -0.000 354.76 M 392.9760 R 11554 0.010 0.005 354.77 354.78 354.79 354.80 354.81 354.82 366.75 M 404.9760 R 11821 392.8 -0.000 366.76 366.77 x16 366.79 366.80 366.81 380.74 M 416.9760 R 11574 404.8 1.00e0 0.065 366.78 380.75 380.76 x16 380.78 380.79 380.80 M 316.9824 R 11467 416.8 1.00e0 0.040 380.77 316.8 1.00e0 x16 1.00e0 x16 0.060 0.020 0.060 0.055 0.018 0.035 0.055 0.050 0.016 0.050 0.030 0.045 0.045 0.014 0.040 0.025 0.040 0.012 0.035 0.010 0.030 0.035 0.020 0.030 0.025 0.008 0.025 0.015 0.020 0.020 0.006 0.010 0.015 0.015 0.004 0.010 0.010 0.005 0.002 0.005 0.005 -0.000 -0.000 392.73 392.74 392.75 392.76 392.77 392.78 392.79 392.80 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 -0.000 416.72 -0.000 416.73 416.74 416.75 416.76 416.77 416.78 416.79 416.80 316.78 316.79 316.80 316.81 316.82 316.83 316.84 Resolution Check Report Printed: 675 of 711 Page 4 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 330.9792 R 12118 M 342.9792 R 11633 330.8 M 354.9792 R 11643 342.8 1.00e0 x16 M 366.9792 R 11396 354.8 1.00e0 x16 366.8 1.00e0 x16 1.00e0 x16 0.075 0.170 0.150 0.045 0.070 0.160 0.140 0.065 0.150 0.040 0.130 0.140 0.060 0.120 0.130 0.035 0.055 0.110 0.120 0.050 0.100 0.110 0.100 0.090 0.090 0.080 0.080 0.070 0.030 0.045 0.025 0.040 0.035 0.020 0.070 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.060 0.050 0.015 0.040 0.010 0.030 0.020 0.005 0.005 0.010 0.010 -0.000 -0.000 330.77 330.78 330.79 330.80 330.81 -0.000 330.82 342.76 M 380.9760 R 11086 342.77 342.78 342.79 342.80 342.81 M 392.9760 R 10917 380.7 -0.000 354.74 354.75 354.76 354.77 x16 354.79 354.80 366.73 M 404.9760 R 11685 392.7 1.00e0 354.78 x16 0.080 366.76 366.77 366.78 366.79 366.80 M 416.9760 R 11737 416.7 1.00e0 x16 1.00e0 x16 0.032 0.055 0.030 0.075 0.050 0.028 0.070 0.090 0.026 0.045 0.065 0.080 366.75 404.7 1.00e0 0.110 0.100 366.74 0.024 0.060 0.040 0.022 0.055 0.070 0.035 0.050 0.060 0.020 0.018 0.045 0.030 0.016 0.040 0.050 0.025 0.035 0.040 0.030 0.014 0.012 0.020 0.010 0.025 0.030 0.015 0.008 0.020 0.020 0.015 0.006 0.010 0.004 0.010 0.010 0.005 0.005 -0.000 380.72 380.73 380.74 380.75 380.76 380.77 0.002 -0.000 392.70 380.78 M 430.9728 R 11418 -0.000 392.71 392.72 392.73 392.74 392.75 392.76 392.77 404.69 M 442.9728 R 11628 430.7 -0.000 404.70 404.71 404.72 x16 404.74 404.75 404.76 416.68 M 380.9760 R 11522 442.7 1.00e0 404.73 416.69 416.70 416.71 x16 416.73 416.74 416.75 M 392.9760 R 11852 380.7 1.00e0 0.045 416.72 392.7 1.00e0 x16 1.00e0 x16 0.110 0.090 0.100 0.040 0.035 0.090 0.080 0.080 0.070 0.035 0.030 0.030 0.070 0.025 0.060 0.025 0.060 0.050 0.020 0.050 0.020 0.040 0.015 0.040 0.015 0.030 0.030 0.010 0.010 0.020 0.020 0.005 0.005 0.010 0.010 -0.000 430.66 -0.000 430.67 430.68 430.69 430.70 430.71 430.72 430.73 430.74 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 -0.000 380.70 380.71 380.72 380.73 380.74 380.75 380.76 380.77 392.69 392.70 392.71 392.72 392.73 392.74 392.75 392.76 Resolution Check Report Printed: 676 of 711 Page 5 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 404.9760 R 11798 M 416.9760 R 11962 404.7 M 430.9728 R 11403 416.7 1.00e0 x16 M 442.9728 R 12348 430.7 1.00e0 x16 0.065 442.7 1.00e0 x16 0.040 0.060 0.055 0.035 1.00e0 x16 0.055 0.060 0.055 0.050 0.050 0.045 0.045 0.040 0.050 0.030 0.045 0.040 0.035 0.040 0.035 0.025 0.030 0.035 0.030 0.030 0.020 0.025 0.025 0.025 0.020 0.015 0.020 0.020 0.015 0.015 0.015 0.010 0.010 0.010 0.010 0.005 0.005 0.005 0.005 -0.000 404.68 404.69 404.70 404.71 404.72 404.73 404.74 -0.000 416.66 404.75 M 454.9728 R 11665 -0.000 416.67 416.68 416.69 416.70 416.71 416.72 416.73 430.65 M 466.9728 R 11529 454.7 -0.000 416.74 430.66 430.67 430.68 x16 430.70 430.71 430.72 442.64 M 480.9696 R 11402 466.7 1.00e0 0.060 430.69 442.65 442.66 442.67 x16 442.69 442.70 442.71 M 430.9728 R 11904 480.6 1.00e0 442.68 430.7 1.00e0 x16 1.00e0 x16 0.036 0.032 0.070 0.034 0.030 0.055 0.032 0.065 0.030 0.060 0.028 0.050 0.026 0.028 0.045 0.024 0.040 0.055 0.026 0.050 0.022 0.024 0.020 0.022 0.045 0.018 0.020 0.040 0.016 0.018 0.035 0.030 0.025 0.035 0.016 0.014 0.030 0.014 0.012 0.025 0.012 0.020 0.010 0.010 0.015 0.020 0.008 0.008 0.006 0.010 0.015 0.006 0.010 0.004 0.004 0.005 -0.000 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 0.002 0.002 -0.000 -0.000 454.70 466.61 M 442.9728 R 12063 466.62 466.63 466.64 466.65 466.66 466.67 466.68 466.69 480.59 M 454.9728 R 11740 442.7 0.005 -0.000 480.60 480.61 480.62 480.63 x16 480.65 480.66 480.67 480.68 M 466.9728 R 11628 454.7 1.00e0 480.64 430.67 430.68 430.69 430.70 x16 430.72 430.73 430.74 430.75 M 480.9696 R 12053 466.7 1.00e0 430.71 480.7 1.00e0 x16 1.00e0 x16 0.060 0.055 0.055 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.050 0.050 0.045 0.045 0.040 0.040 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 -0.000 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 0.005 0.005 -0.000 -0.000 480.61 466.63 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 480.62 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 Resolution Check Report Printed: 677 of 711 Page 6 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 492.9696 R 11688 M 504.9696 R 11467 492.6 M 516.9697 R 12194 504.6 1.00e0 x16 516.6 1.00e0 x16 0.045 1.00e0 x16 0.024 0.040 0.022 0.040 0.020 0.035 0.035 0.018 0.030 0.030 0.016 0.014 0.025 0.025 0.012 0.020 0.020 0.010 0.015 0.015 0.010 0.010 0.005 0.005 0.008 0.006 0.004 0.002 -0.000 -0.000 492.60 492.61 492.62 492.63 492.64 492.65 492.66 492.67 492.68 492.69 -0.000 504.59 504.60 504.61 504.62 504.63 504.64 504.65 504.66 504.67 504.68 516.58 516.59 516.60 516.61 516.62 516.63 516.64 516.65 516.66 516.67 Resolution Check Report Printed: 678 of 711 Page 1 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 180.9888 R 11682 M 192.9888 R 9510 180.9 M 204.9888 R 12347 192.9 1.00e0 x16 M 218.9856 R 11961 204.9 1.00e0 x16 218.9 1.00e0 x16 1.300 1.200 0.110 1.100 0.100 1.000 0.090 1.00e0 x16 0.500 0.075 0.070 0.450 0.065 0.400 0.060 0.055 0.900 0.350 0.080 0.050 0.800 0.070 0.300 0.045 0.700 0.040 0.060 0.250 0.600 0.035 0.050 0.200 0.030 0.500 0.040 0.025 0.030 0.020 0.400 0.150 0.300 0.100 0.015 0.020 0.200 0.010 0.050 0.010 0.100 -0.000 0.005 -0.000 180.87 180.88 180.89 -0.000 180.90 192.86 M 230.9856 R 11520 192.87 192.88 204.85 M 242.9856 R 11312 230.8 -0.000 192.89 204.86 204.87 x16 218.83 M 218.9856 R 11315 242.8 1.00e0 204.88 218.84 218.85 x16 230.9 1.00e0 x16 0.450 0.650 218.87 M 230.9856 R 11522 218.9 1.00e0 218.86 1.00e0 x16 0.650 0.425 0.180 0.600 0.400 0.600 0.375 0.160 0.550 0.550 0.350 0.500 0.500 0.325 0.140 0.450 0.300 0.450 0.275 0.120 0.400 0.400 0.250 0.350 0.350 0.100 0.225 0.300 0.080 0.200 0.300 0.175 0.250 0.250 0.150 0.060 0.200 0.200 0.125 0.150 0.150 0.100 0.040 0.075 0.100 0.100 0.020 0.050 -0.000 -0.000 0.050 0.050 0.025 -0.000 230.82 230.83 230.84 230.85 230.86 242.81 M 242.9856 R 11628 242.82 242.83 242.84 242.85 218.86 M 254.9856 R 11961 242.9 -0.000 218.87 218.88 x16 230.85 M 268.9824 R 11118 254.8 1.00e0 218.89 230.86 230.87 M 280.9824 R 11012 268.8 1.00e0 x16 230.88 280.8 1.00e0 x16 0.140 1.00e0 x16 0.320 0.180 0.240 0.300 0.130 0.220 0.280 0.160 0.120 0.260 0.200 0.110 0.140 0.180 0.100 0.160 0.090 0.240 0.220 0.120 0.200 0.080 0.140 0.180 0.100 0.070 0.160 0.120 0.140 0.080 0.060 0.100 0.120 0.050 0.060 0.080 0.100 0.040 0.080 0.060 0.040 0.030 0.060 0.040 0.020 0.040 0.020 0.020 0.010 -0.000 -0.000 242.84 242.85 242.86 242.87 242.88 0.020 -0.000 254.83 254.84 254.85 254.86 254.87 -0.000 268.81 268.82 268.83 268.84 268.85 268.86 280.80 280.81 280.82 280.83 280.84 280.85 Resolution Check Report Printed: 679 of 711 Page 2 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 292.9824 R 11427 M 304.9824 R 11317 292.8 M 242.9856 R 11601 304.8 1.00e0 x16 M 254.9856 R 11717 242.9 1.00e0 x16 254.9 1.00e0 x16 1.00e0 x16 0.120 0.085 0.140 0.220 0.080 0.110 0.130 0.075 0.200 0.100 0.120 0.070 0.180 0.110 0.065 0.100 0.060 0.090 0.160 0.080 0.055 0.090 0.140 0.070 0.050 0.080 0.045 0.070 0.120 0.060 0.040 0.100 0.060 0.035 0.050 0.030 0.050 0.080 0.040 0.025 0.040 0.060 0.030 0.040 0.020 0.020 0.030 0.015 0.020 0.010 0.020 0.010 0.010 0.005 -0.000 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 -0.000 304.78 M 268.9824 R 11601 304.79 304.80 304.81 304.82 242.85 M 280.9824 R 11468 268.8 -0.000 304.83 242.86 242.87 x16 242.89 254.84 M 292.9824 R 11375 280.8 1.00e0 242.88 x16 0.375 0.160 0.150 x16 0.110 0.100 0.140 0.300 1.00e0 0.120 0.180 0.325 254.88 304.8 x16 0.170 0.350 254.87 M 304.9824 R 11295 1.00e0 0.180 0.160 254.86 292.8 1.00e0 0.400 0.200 254.85 0.090 0.130 0.140 0.275 0.080 0.120 0.250 0.110 0.120 0.070 0.225 0.100 0.100 0.200 0.090 0.175 0.080 0.150 0.070 0.060 0.050 0.080 0.040 0.060 0.125 0.060 0.050 0.100 0.030 0.040 0.040 0.075 0.020 0.030 0.050 0.020 0.020 0.010 0.025 -0.000 0.010 -0.000 268.82 268.83 268.84 268.85 268.86 268.87 -0.000 280.81 M 316.9824 R 11720 280.82 280.83 280.84 280.85 280.86 M 330.9792 R 11212 316.8 -0.000 292.80 292.81 292.82 x16 292.84 292.85 304.79 M 342.9792 R 10706 330.8 1.00e0 292.83 304.80 304.81 304.82 x16 0.050 304.84 M 280.9824 R 11548 342.8 1.00e0 0.130 304.83 280.9 1.00e0 x16 1.00e0 0.090 0.360 0.085 0.340 x16 0.120 0.080 0.045 0.110 0.100 0.040 0.090 0.035 0.080 0.030 0.320 0.075 0.300 0.070 0.280 0.065 0.260 0.060 0.240 0.055 0.220 0.050 0.200 0.045 0.180 0.040 0.160 0.035 0.140 0.030 0.120 0.025 0.100 0.020 0.080 0.015 0.060 0.070 0.025 0.060 0.050 0.020 0.040 0.015 0.030 0.010 0.020 0.010 0.005 0.040 0.010 0.005 -0.000 -0.000 316.78 316.79 316.80 316.81 316.82 316.83 0.020 -0.000 330.77 330.78 330.79 330.80 330.81 330.82 -0.000 342.76 342.77 342.78 342.79 342.80 342.81 342.82 280.83 280.84 280.85 280.86 280.87 280.88 Resolution Check Report Printed: 680 of 711 Page 3 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 292.9824 R 11417 M 304.9824 R 11746 292.8 M 316.9824 R 11860 304.8 1.00e0 x16 M 330.9792 R 11399 316.8 1.00e0 x16 330.8 1.00e0 x16 1.00e0 x16 0.140 0.055 0.180 0.130 0.180 0.120 0.050 0.110 0.045 0.160 0.160 0.140 0.100 0.140 0.040 0.090 0.120 0.120 0.035 0.080 0.100 0.030 0.070 0.100 0.025 0.060 0.080 0.080 0.050 0.020 0.060 0.060 0.040 0.015 0.030 0.040 0.040 0.010 0.020 0.020 -0.000 -0.000 292.82 292.83 292.84 292.85 292.86 -0.000 292.87 304.81 M 342.9792 R 11424 0.020 0.005 0.010 304.82 304.83 304.84 304.85 316.80 M 354.9792 R 11788 342.8 -0.000 304.86 316.81 316.82 316.83 x16 316.85 330.78 M 366.9792 R 11879 354.8 1.00e0 316.84 330.79 330.80 x16 330.82 330.83 330.84 M 380.9760 R 11573 366.8 1.00e0 330.81 380.8 1.00e0 x16 1.00e0 x16 0.075 0.140 0.080 0.040 0.070 0.075 0.130 0.065 0.120 0.060 0.110 0.055 0.070 0.035 0.065 0.060 0.030 0.100 0.050 0.090 0.045 0.080 0.040 0.070 0.035 0.060 0.030 0.055 0.050 0.025 0.045 0.040 0.020 0.035 0.030 0.015 0.050 0.025 0.040 0.020 0.025 0.020 0.010 0.030 0.015 0.020 0.010 0.010 0.005 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 342.83 0.015 0.010 -0.000 -0.000 0.005 354.76 M 392.9760 R 11520 0.005 354.77 354.78 354.79 354.80 354.81 354.82 366.75 M 404.9760 R 10823 392.8 366.76 366.77 366.78 x16 0.060 366.80 366.81 380.74 M 416.9760 R 11908 404.8 1.00e0 366.79 380.75 380.76 x16 0.032 0.017 380.79 380.80 316.8 1.00e0 0.018 380.78 M 316.9824 R 11415 416.8 1.00e0 0.034 380.77 x16 1.00e0 x16 0.050 0.016 0.030 0.055 0.015 0.028 0.050 0.040 0.013 0.024 0.045 0.045 0.014 0.026 0.012 0.022 0.035 0.040 0.011 0.020 0.010 0.035 0.030 0.018 0.009 0.030 0.016 0.025 0.008 0.014 0.025 0.007 0.020 0.012 0.006 0.020 0.010 0.015 0.005 0.008 0.015 0.004 0.006 0.003 0.004 0.002 0.002 0.001 0.010 0.010 0.005 0.005 -0.000 -0.000 392.73 392.74 392.75 392.76 392.77 392.78 392.79 392.80 -0.000 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 416.72 416.73 416.74 416.75 416.76 416.77 416.78 416.79 416.80 -0.000 316.78 316.79 316.80 316.81 316.82 316.83 316.84 Resolution Check Report Printed: 681 of 711 Page 4 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 330.9792 R 10964 M 342.9792 R 11765 330.8 M 354.9792 R 11187 342.8 1.00e0 x16 M 366.9792 R 11482 354.8 1.00e0 x16 366.8 1.00e0 x16 1.00e0 x16 0.075 0.150 0.170 0.050 0.160 0.070 0.140 0.150 0.130 0.065 0.120 0.060 0.110 0.055 0.100 0.050 0.090 0.045 0.090 0.080 0.040 0.080 0.070 0.035 0.070 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.140 0.045 0.040 0.130 0.120 0.035 0.110 0.100 0.060 0.030 0.025 0.020 0.050 0.015 0.040 0.010 0.030 0.020 0.005 0.010 0.010 -0.000 0.005 -0.000 330.77 330.78 330.79 330.80 330.81 330.82 342.76 M 380.9760 R 11186 342.77 342.78 342.79 342.80 -0.000 354.74 342.81 M 392.9760 R 11378 380.7 -0.000 354.75 354.76 354.77 x16 354.79 354.80 354.81 M 404.9760 R 11235 392.7 1.00e0 354.78 366.73 366.74 366.75 366.76 x16 366.78 366.79 366.80 M 416.9760 R 11174 404.7 1.00e0 366.77 416.7 1.00e0 x16 1.00e0 x16 0.085 0.110 0.028 0.050 0.080 0.026 0.100 0.075 0.045 0.024 0.070 0.090 0.065 0.022 0.040 0.080 0.060 0.020 0.035 0.055 0.070 0.018 0.050 0.060 0.030 0.016 0.045 0.014 0.025 0.040 0.050 0.012 0.035 0.020 0.040 0.030 0.010 0.025 0.015 0.030 0.008 0.020 0.006 0.020 0.010 0.015 0.004 0.010 0.005 0.010 0.002 0.005 -0.000 -0.000 380.72 380.73 380.74 380.75 380.76 380.77 -0.000 380.78 392.71 M 430.9728 R 11476 392.72 392.73 392.74 392.75 392.76 392.77 404.69 M 442.9728 R 11163 430.7 -0.000 404.70 404.71 404.72 x16 404.74 404.75 404.76 416.68 M 380.9760 R 11287 442.7 1.00e0 404.73 416.69 416.70 416.71 x16 416.73 416.74 416.75 M 392.9760 R 11340 380.7 1.00e0 416.72 392.7 1.00e0 x16 1.00e0 x16 0.036 0.050 0.085 0.034 0.100 0.080 0.032 0.045 0.075 0.090 0.030 0.070 0.040 0.028 0.080 0.065 0.026 0.035 0.060 0.024 0.070 0.055 0.022 0.030 0.050 0.060 0.020 0.045 0.018 0.025 0.050 0.040 0.016 0.020 0.035 0.014 0.040 0.030 0.012 0.015 0.010 0.025 0.030 0.020 0.008 0.010 0.020 0.006 0.015 0.010 0.004 0.005 0.010 0.005 0.002 -0.000 -0.000 430.67 430.68 430.69 430.70 430.71 430.72 430.73 430.74 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 -0.000 380.70 380.71 380.72 380.73 380.74 380.75 380.76 380.77 392.69 392.70 392.71 392.72 392.73 392.74 392.75 392.76 Resolution Check Report Printed: 682 of 711 Page 5 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 404.9760 R 11765 M 416.9760 R 11990 404.7 M 430.9728 R 11174 416.7 1.00e0 x16 M 442.9728 R 11086 430.7 1.00e0 x16 0.060 442.7 1.00e0 x16 1.00e0 x16 0.055 0.060 0.040 0.055 0.050 0.035 0.045 0.055 0.050 0.050 0.045 0.045 0.040 0.030 0.040 0.040 0.035 0.025 0.035 0.035 0.030 0.030 0.030 0.020 0.025 0.025 0.025 0.020 0.015 0.020 0.020 0.015 0.015 0.015 0.010 0.010 0.010 0.010 0.005 0.005 0.005 0.005 -0.000 -0.000 404.68 404.69 404.70 404.71 404.72 404.73 404.74 -0.000 404.75 416.67 M 454.9728 R 11171 416.68 416.69 416.70 416.71 416.72 416.73 416.74 430.65 M 466.9728 R 12194 454.7 430.66 430.67 430.68 x16 430.70 430.71 -0.000 442.63 430.72 M 480.9696 R 11753 466.7 1.00e0 430.69 442.64 442.65 442.66 442.67 x16 442.69 442.70 442.71 M 430.9728 R 11116 480.6 1.00e0 0.028 442.68 430.7 1.00e0 x16 1.00e0 x16 0.036 0.060 0.050 0.034 0.026 0.055 0.032 0.024 0.045 0.030 0.050 0.022 0.028 0.020 0.026 0.040 0.045 0.024 0.035 0.040 0.018 0.022 0.016 0.030 0.035 0.020 0.014 0.018 0.030 0.025 0.016 0.012 0.025 0.014 0.020 0.010 0.012 0.015 0.008 0.010 0.006 0.008 0.020 0.015 0.010 0.006 0.010 0.004 0.004 0.005 0.005 0.002 -0.000 0.002 -0.000 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 454.70 -0.000 466.61 M 442.9728 R 11717 466.62 466.63 466.64 466.65 466.66 466.67 466.68 466.69 M 454.9728 R 11627 442.7 -0.000 480.59 480.60 480.61 480.62 480.63 x16 480.65 480.66 480.67 480.68 M 466.9728 R 12498 454.7 1.00e0 480.64 x16 0.050 0.045 430.69 430.70 430.71 430.72 430.73 430.74 430.75 M 480.9696 R 11221 480.7 1.00e0 x16 0.036 0.050 430.68 466.7 1.00e0 0.055 430.67 1.00e0 x16 0.040 0.034 0.032 0.035 0.030 0.045 0.028 0.040 0.030 0.026 0.040 0.035 0.024 0.035 0.025 0.022 0.030 0.020 0.030 0.018 0.025 0.020 0.016 0.025 0.014 0.020 0.020 0.015 0.012 0.015 0.010 0.015 0.010 0.008 0.010 0.010 0.006 0.005 0.005 -0.000 -0.000 0.005 0.004 0.002 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 -0.000 466.63 -0.000 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 480.62 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 Resolution Check Report Printed: 683 of 711 Page 6 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 492.9696 R 10752 M 504.9696 R 11338 492.7 M 516.9697 R 11848 504.6 1.00e0 x16 516.6 1.00e0 x16 1.00e0 x16 0.040 0.022 0.035 0.020 0.035 0.018 0.030 0.030 0.016 0.025 0.025 0.014 0.012 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 0.010 0.008 0.006 0.004 0.002 -0.000 -0.000 492.61 492.62 492.63 492.64 492.65 492.66 492.67 492.68 492.69 -0.000 504.59 504.60 504.61 504.62 504.63 504.64 504.65 504.66 504.67 504.68 516.58 516.59 516.60 516.61 516.62 516.63 516.64 516.65 516.66 516.67 684 of 711 Lab ID: OPR1_11892_PCB-RJ ACQ: 26-Mar-2014 19:16:37 LKB Wt/Vol: 1 µL Client ID: 0_11892_OPR001 UTP: 31-Mar-2014 13:19 CEM J-level: 10 pg/uL Datafile: 140326X06 RPT: 31-Mar-2014 18:50 CM Stds (pg): JS: 100 ES: 100 CS/SS: 100 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.82 32.34 35.81 35.26 34.80 34.52 38.41 40.96 39.98 43.67 45.80 50.86 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES 11.89 14.18 14.43 20.14 17.52 26.47 20.43 32.80 32.32 25.41 35.78 35.24 34.78 34.50 38.39 36.36 30.36 40.94 39.96 43.65 43.17 42.10 35.23 45.78 39.77 47.94 49.41 45.40 50.84 PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services QC C ICAL: MM7_PCB_10292013_20DEC2013 CS3_140326_PCB_XC Split: 1 Checkcode: 678-882-ZZP Method 1668A Pred RRT Actual RRT Diff Secs Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0006 1.0007 1.0006 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 0 +0.2 +0.2 -0.2 0 +0.2 0 0 0 0 0 0 3.50E+07 3.40E+07 2.72E+07 2.96E+07 2.86E+07 2.96E+07 2.62E+07 4.67E+07 2.61E+07 2.26E+07 2.24E+07 1.35E+07 0.80 0.79 0.61 0.61 0.62 0.61 0.64 1.22 1.23 1.24 1.06 1.17 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 50 51.9 47.5 48.5 47.8 48.6 53.9 95.7 48 49.2 52.9 48.5 7.06E+04 7.06E+04 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.24E+03 6.11E+03 6.11E+03 6.11E+03 3.20E+03 1.54E+03 1.03 1.08 0.0961 0.0919 0.0897 0.089 0.112 0.172 0.115 0.139 0.0805 0.0649 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7245 0.8640 0.8794 1.2274 1.0673 1.0789 0.8326 1.3368 1.3174 0.8323 1.1723 1.1546 1.1393 1.1301 1.2578 0.9716 0.8112 1.0940 1.0677 1.1665 0.9080 0.8856 0.7411 0.9629 0.8365 1.0084 1.0392 0.9548 1.0694 0 0 -0.1 +0.4 0 +0.3 -0.2 +0.8 +0.8 -0.3 +0.6 +0.6 +0.4 +0.4 +0.7 0 -0.4 +0.2 0 +0.3 -0.3 0 -0.4 0 -0.2 0 0 -0.3 0 8.18E+07 7.85E+07 4.35E+07 8.63E+07 4.16E+07 6.90E+07 4.06E+07 6.08E+07 5.86E+07 4.00E+07 5.15E+07 5.08E+07 5.02E+07 5.03E+07 4.39E+07 3.71E+07 5.21E+07 8.89E+07 4.68E+07 4.09E+07 2.67E+07 3.29E+07 3.56E+07 3.95E+07 3.44E+07 2.87E+07 2.02E+07 3.20E+07 2.50E+07 3.31 3.35 1.60 1.57 1.08 1.10 0.77 0.81 0.81 1.61 1.60 1.64 1.54 1.56 1.58 1.29 1.26 1.27 1.26 1.25 1.08 1.11 1.06 1.03 0.90 0.89 0.80 0.79 1.17 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 73.9 % 77.8 % 89.5 % 89.3 % 88.6 % 80.4 % 91.3 % 85.1 % 83 % 101 % 87 % 84.8 % 88.1 % 86.2 % 86.8 % 85.3 % 84.5 % 71.6 % 72.3 % 67.8 % 85 % 87.2 % 97.7 % 89.8 % 91.5 % 83.1 % 87.8 % 98 % 81.2 % 15% 15% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% Page 1 of 5 Printed: 3/31/2014 7:04 PM 685 of 711 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.91 32.82 37.80 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 8.08E+07 5.66E+07 2.45E+07 1.09 1.57 1.07 1.11 1.03 0.62 105 % 109 % 111 % 40% 40% 40% 125% 125% 125% CS PCB-28 CS PCB-111 CS PCB-178 22.91 32.82 37.80 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 8.08E+07 5.66E+07 2.45E+07 1.09 1.57 1.07 1.85 1.22 0.58 84.8 % 94.3 % 109 % 40% 40% 40% 125% 125% 125% JS JS JS JS JS 16.41 24.54 30.52 37.42 47.54 9.29E+07 5.16E+07 4.92E+07 3.88E+07 2.78E+07 1.54 0.79 1.61 1.28 0.91 6.14E+03 6.14E+03 6.14E+03 8.41E+03 8.41E+03 7.53E+03 7.53E+03 7.53E+03 7.53E+03 7.53E+03 7.53E+03 7.53E+03 7.53E+03 7.53E+03 5.36E+03 5.36E+03 5.36E+03 5.36E+03 5.36E+03 5.36E+03 0.0501 0.0523 0.058 0.116 0.0743 0.0834 0.0727 0.079 0.0791 0.0753 0.0659 0.0751 0.0762 0.0784 0.0924 0.0688 0.0805 0.0591 0.0618 0.108 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.90 14.01 14.19 14.45 14.63 16.43 16.59 16.82 17.12 17.24 18.80 19.58 19.87 20.16 17.53 19.29 19.70 19.89 20.02 20.12 C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0434 1.0506 0.9333 0.9720 0.9866 1.0008 1.0010 1.1015 1.1244 1.1355 1.1431 1.1485 0 0 0 0 0 0 0 0 +0.1 0 -0.1 -0.1 0 0 0 +0.1 +0.1 +0.2 +0.1 +0.1 Page 2 of 5 NON-EMPC 160 588 1,170 2,050 2,240 2,090 1,230 604 150 4.30E+07 4.42E+07 4.29E+07 2.55E+07 4.16E+07 3.93E+07 4.58E+07 4.28E+07 4.24E+07 4.38E+07 5.15E+07 4.58E+07 8.98E+07 4.55E+07 2.31E+07 6.40E+07 2.75E+07 3.74E+07 3.54E+07 2.16E+07 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 160 588 1,170 2,050 2,240 2,090 1,230 604 150 3.30 3.35 3.34 1.61 1.59 1.65 1.67 1.64 1.65 1.67 1.65 1.64 1.65 1.63 1.04 1.04 1.05 1.04 1.05 1.06 0.95 1.12 1.01 1.23 1.92 0.96 1.10 1.01 1.01 1.06 1.21 1.06 1.05 1.02 1.15 1.54 1.32 1.79 1.72 0.98 DL 0.054 0.097 0.103 0.454 0.084 0.112 0.143 0.068 0.146 55.1 50.4 54.2 47.6 49.9 47.5 48.3 49 48.6 47.7 49.2 49.8 99.1 51.8 48.2 99.8 50.1 50 49.6 52.8 Printed: 3/31/2014 7:04 PM 686 of 711 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.60 21.75 21.90 22.18 22.38 22.66 22.95 23.13 23.50 24.88 25.20 25.74 26.13 26.49 20.45 22.44 23.02 23.09 23.30 24.56 24.69 24.78 24.98 25.26 25.48 25.75 25.92 26.25 26.35 26.55 27.26 27.52 27.89 28.09 28.25 28.48 28.77 29.05 29.20 29.63 29.83 30.15 31.47 31.96 25.43 25.75 27.44 27.63 SGS Evironmental Services QC C C C C C C C C C Pred RRT Actual RRT Diff Secs Response Ra 1.1758 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1760 0.8216 0.8274 0.8381 0.8455 0.8561 0.8668 0.8737 0.8878 0.9401 0.9521 0.9723 0.9871 1.0008 1.0010 0.9144 0.9383 0.9412 0.9498 1.0009 1.0062 1.0101 1.0181 1.0296 1.0384 1.0497 1.0564 1.0699 1.0738 1.0820 0.8434 0.8514 0.8629 0.8691 0.8740 0.8810 0.8901 0.8988 0.9033 0.9168 0.9228 0.9328 0.9737 0.9889 1.0009 1.0134 0.8988 0.9051 +0.2 -0.3 -0.1 -0.3 -0.1 -0.1 -0.3 -0.1 -0.3 0 -0.2 0 0 +0.2 0 -0.1 0 -0.1 -0.1 0 0 0 0 +0.2 0 +0.2 +0.2 +0.2 +0.2 +0.2 -0.3 -0.2 -0.2 -0.3 -0.2 -0.2 -0.2 -0.2 -0.2 -0.2 -0.2 -0.2 0 0 0 0 -0.2 0 4.01E+07 4.03E+07 3.98E+07 8.19E+07 4.05E+07 4.28E+07 8.07E+07 8.36E+07 3.92E+07 4.31E+07 4.44E+07 4.06E+07 3.95E+07 4.06E+07 2.62E+07 4.97E+07 2.06E+07 2.62E+07 2.03E+07 2.52E+07 3.37E+07 2.08E+07 6.11E+07 2.49E+07 8.02E+07 1.04E+08 2.35E+07 1.96E+07 5.37E+07 3.73E+07 3.64E+07 3.80E+07 3.51E+07 3.63E+07 3.66E+07 3.92E+07 1.44E+08 3.43E+07 3.36E+07 3.38E+07 3.41E+07 3.95E+07 3.89E+07 3.31E+07 2.71E+07 2.32E+07 2.28E+07 1.96E+07 1.05 1.00 1.00 1.01 1.01 1.00 1.01 1.01 1.01 1.00 1.00 1.01 1.01 1.01 0.80 0.79 0.77 0.80 0.78 0.79 0.78 0.79 0.79 0.79 0.79 0.79 0.78 0.76 0.78 0.79 0.79 0.79 0.80 0.80 0.78 0.79 0.79 0.80 0.80 0.80 0.80 0.79 0.80 0.80 0.64 0.63 0.62 0.62 Page 3 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.92 1.23 1.25 1.27 1.27 1.33 1.23 1.27 1.18 1.29 1.34 1.22 1.17 1.08 1.35 0.91 0.82 0.88 0.73 0.89 1.18 0.76 1.09 0.89 0.95 1.24 0.82 0.75 0.91 1.31 1.27 1.32 1.21 1.22 1.29 1.36 1.22 1.17 1.15 1.16 1.17 1.38 1.32 1.11 1.43 1.17 0.95 0.80 50 47.5 46.2 93.7 46 46.6 94.8 95.7 48 48.2 47.9 48.3 49 54.5 47.8 93.6 42.7 51 47.2 48.3 49 46.4 95.9 47.7 145 142 49.1 44.6 101 48.6 49 49 49.7 50.7 48.4 49.3 201 50 49.8 49.8 49.9 48.9 50.5 50.9 47.3 49.8 47.6 48.7 5.36E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 8.81E+03 2.33E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 7.06E+04 1.60E+03 1.60E+03 5.39E+03 5.39E+03 0.0551 0.0997 0.0984 0.0969 0.0963 0.0923 0.0994 0.0969 0.104 0.0948 0.0915 0.101 0.105 0.114 0.0375 0.0622 0.0686 0.0643 0.0768 0.0632 0.048 0.0738 0.0518 0.0633 0.0595 0.0454 0.0691 0.0754 0.0623 0.043 0.954 0.914 1 0.991 0.936 0.891 0.992 1.03 1.05 1.05 1.04 0.876 0.92 1.09 0.0256 0.0314 0.113 0.135 Printed: 3/31/2014 7:04 PM 687 of 711 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 28.01 28.22 28.33 28.40 28.71 28.77 28.96 29.38 29.72 30.04 30.52 30.96 31.05 31.16 31.50 32.04 32.13 32.25 32.33 32.53 32.84 33.24 34.20 34.41 34.63 35.09 37.04 30.38 30.54 30.68 30.99 31.26 32.53 33.05 33.26 33.52 33.83 34.00 34.08 34.34 34.52 34.66 34.90 35.30 35.64 35.86 35.98 36.40 SGS Evironmental Services QC C C C C C C C C C Pred RRT Actual RRT Diff Secs Response Ra 0.9176 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9176 0.9245 0.9281 0.9304 0.9405 0.9425 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0174 1.0207 1.0321 1.0495 1.0526 1.0564 1.0592 1.0656 1.0758 1.0889 0.9915 0.9976 1.0039 1.0091 1.0351 1.0007 1.0060 1.0107 1.0208 1.0297 1.0715 1.0887 1.0956 1.1043 1.1142 1.1199 1.1226 1.1314 1.1371 1.1419 1.1496 1.1629 0.9524 0.9582 0.9613 0.9728 0 -0.2 -0.2 -0.2 +0.3 +0.2 0 0 0 0 0 0 +0.2 +0.2 +0.2 0 +0.2 +0.6 +0.4 +0.2 +0.2 +0.4 -0.2 0 +0.2 0 +0.2 0 0 0 +0.2 +0.2 +0.2 +0.2 +0.4 +0.4 +0.2 0 +0.2 +0.4 +0.4 +0.6 +0.4 +0.6 -0.2 0 0 0 2.12E+07 4.05E+07 2.35E+07 1.99E+07 2.12E+07 2.07E+07 1.77E+07 1.92E+07 2.95E+07 2.01E+07 7.14E+07 1.64E+07 2.41E+07 2.80E+07 1.43E+08 2.67E+07 4.72E+07 2.76E+07 2.74E+07 1.71E+07 2.98E+07 3.00E+07 5.45E+07 3.10E+07 2.62E+07 2.54E+07 2.73E+07 3.04E+07 2.84E+07 2.88E+07 2.68E+07 2.70E+07 2.08E+07 3.97E+07 2.32E+07 2.04E+07 4.12E+07 1.51E+07 2.03E+07 4.16E+07 1.76E+07 1.73E+07 1.82E+07 1.93E+07 2.45E+07 2.13E+07 2.66E+07 5.24E+07 0.60 0.61 0.62 0.61 0.62 0.63 0.62 0.61 0.61 0.62 0.61 0.61 0.61 0.61 0.62 0.61 0.61 0.61 0.62 0.62 0.61 0.61 0.62 0.61 0.61 0.62 0.61 1.27 1.26 1.27 1.26 1.28 1.25 1.26 1.28 1.24 1.27 1.26 1.28 1.26 1.26 1.29 1.27 1.27 1.28 1.26 1.26 1.27 Page 4 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.87 0.88 0.88 0.85 0.85 0.86 0.72 0.78 1.22 0.84 0.97 0.66 0.98 1.16 0.98 1.09 0.97 1.10 1.12 0.69 1.20 1.22 1.10 1.22 1.08 1.01 1.06 1.26 1.09 1.12 1.02 1.04 1.12 1.06 1.26 1.10 1.10 0.81 1.09 1.11 0.94 0.92 0.97 1.04 1.32 1.16 1.42 1.38 48.5 92 53.1 46.4 49.7 48 48.9 48.9 48.1 47.3 146 49.3 48.7 48.1 292 48.8 96.8 50 48.7 48.9 49.4 48.9 98.6 50.4 48.1 49.5 49.8 46.4 50.1 49.4 50.2 50 50 101 49.8 49.8 101 50.2 50 101 50.3 50.5 50.6 50.2 50.1 49.5 50.3 102 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 5.39E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 0.124 0.123 0.122 0.126 0.127 0.126 0.15 0.138 0.0885 0.128 0.111 0.163 0.11 0.0932 0.11 0.0991 0.111 0.0981 0.0961 0.155 0.0897 0.0882 0.0981 0.0883 0.0995 0.109 0.1 0.0244 0.0283 0.0275 0.03 0.0296 0.0412 0.0437 0.0369 0.042 0.0421 0.0569 0.0423 0.0417 0.0491 0.0502 0.0477 0.0446 0.0351 0.04 0.0326 0.0335 Printed: 3/31/2014 7:04 PM 688 of 711 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.55 36.89 37.09 37.17 37.46 37.60 37.78 38.52 39.33 39.57 35.26 35.54 36.00 36.29 36.69 37.82 38.36 38.59 38.77 39.12 39.20 39.31 39.68 40.03 40.22 41.56 41.81 42.09 42.42 43.19 43.64 39.79 40.58 41.15 41.34 41.43 43.75 44.33 44.50 45.62 47.56 47.96 45.42 46.20 49.43 SGS Evironmental Services QC C C C C C Pred RRT Actual RRT Diff Secs Response Ra 0.9766 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 0.9859 0.9912 0.9934 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0217 1.0300 1.0414 1.0733 1.0888 1.0953 1.1004 1.1102 1.1126 1.1157 1.1263 1.1362 1.1414 0.9079 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0395 1.0418 1.1002 1.1147 1.1189 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0 0 +0.2 +0.2 0 0 0 -0.2 -0.2 0 0 0 +0.2 0 +0.2 0 +0.2 +0.2 +0.5 +0.2 +0.2 +0.2 +0.2 +0.2 +0.2 -0.2 0 0 0 0 0 0 0 0 -0.2 0 +0.3 +0.3 +0.3 0 0 0 0 0 0 1.88E+07 1.70E+07 2.10E+07 2.58E+07 6.27E+07 2.40E+07 2.82E+07 4.02E+07 2.46E+07 2.47E+07 2.15E+07 2.04E+07 1.93E+07 2.15E+07 1.99E+07 1.41E+07 1.83E+07 1.94E+07 1.99E+07 2.03E+07 1.86E+07 1.58E+07 1.59E+07 1.78E+07 3.17E+07 1.64E+07 2.09E+07 4.12E+07 2.29E+07 1.54E+07 2.17E+07 1.75E+07 1.94E+07 1.78E+07 1.87E+07 1.90E+07 2.49E+07 1.32E+07 1.34E+07 1.14E+07 1.23E+07 1.50E+07 1.77E+07 1.85E+07 1.12E+07 1.25 1.25 1.23 1.28 1.27 1.28 1.26 1.21 1.22 1.22 1.08 1.07 1.07 1.07 1.05 1.06 1.08 1.07 1.06 1.04 1.06 1.07 1.04 1.05 1.06 1.05 1.05 1.05 1.06 1.04 1.04 0.91 0.90 0.93 0.92 0.90 0.90 0.90 0.92 0.91 0.92 0.92 0.78 0.79 0.79 Page 5 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.01 0.91 1.15 1.37 1.12 1.27 1.49 0.89 1.07 1.07 1.27 1.09 1.04 1.15 1.08 0.75 1.09 1.17 1.20 1.23 1.05 1.01 0.96 1.08 0.95 0.99 1.29 1.23 1.35 1.12 1.54 1.05 1.12 1.04 1.09 1.09 0.72 0.76 0.78 0.75 0.81 1.06 1.12 1.14 1.11 50.3 50.4 49.2 50.7 150 51 51.1 97 48.9 49.3 47.6 52.7 51.9 52.3 51.8 52.6 51 50.7 50.6 50.3 53.7 47.6 50.4 50.2 102 50.5 49.6 102 51.5 51.9 52.5 48.3 50.4 49.9 50 50.9 100 50.1 50 52.9 52.6 49.2 49.3 50.9 49.7 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 1.64E+03 6.11E+03 6.11E+03 6.11E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 7.39E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 1.19E+03 3.08E+03 3.08E+03 3.08E+03 3.79E+03 3.79E+03 3.79E+03 0.046 0.0509 0.0403 0.0338 0.0412 0.0365 0.0311 0.15 0.124 0.125 0.0272 0.0318 0.0331 0.03 0.032 0.0458 0.221 0.207 0.202 0.197 0.23 0.24 0.252 0.224 0.256 0.244 0.188 0.196 0.179 0.255 0.184 0.0334 0.0315 0.0339 0.0323 0.0324 0.0487 0.0461 0.0451 0.145 0.134 0.103 0.113 0.112 0.179 Printed: 3/31/2014 7:04 PM 689 of 711 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140326X06 Analysis Date: Lab ID: OPR1_11892_PCB-RJ NATIVE ANALYTES PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-104 22'466'-PeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-155 22'44'66'-HxCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-188 22'34'566'-HpCB PCB-189 233'44'55'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-206 22'33'44'55'6-NoCB PCB-208 22'33'455'66'-NoCB PCB-209 DeCB Processed: 31 Mar 2014 18:50 26-MAR-2014 19:16:37 SPIKE CONC. RECOVERY RANGE (%) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 110 108 95.1 104 96.5 109 95.5 100 104 94.7 95 97 95.7 97.1 108 92.8 95.7 95.9 98.3 95.1 106 96.6 98.3 99.5 98.7 97.1 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 Contract-required recovery limits for OPR as specified in Table 6, Method 1668A. Analyst: CM FORM 8A OK - 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 690 of 711 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140326X06 Analysis Date: Lab ID: OPR1_11892_PCB-RJ LABELED STANDARDS ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 FORM 8B 26-MAR-2014 19:16:37 SPIKE CONC. RECOVERY RANGE (%) 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 73.9 77.8 89.5 89.3 88.6 80.4 91.3 85.1 83 101 87 84.8 88.1 86.2 86.8 85.3 84.5 71.6 72.3 67.8 85 87.2 97.7 89.8 91.5 83.1 87.8 98 81.2 15 15 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 - 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 100 100 100 84.8 94.3 109 40 40 40 - 125 125 125 Y Y Y OK CLEANUP STANDARDS CS PCB-28 CS PCB-111 CS PCB-178 Processed: 31 Mar 2014 18:50 Analyst: CM 691 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.39e7 2.70e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.60e7 7.99e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.39e7 6.95e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 2.39e7 1.20e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.39e7 6.94e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.91e6 1.45e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.58e6 1.29e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 scc: 678-882 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 19:15 Page 1 of 21 692 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 PCB-1 3.30e7 11.90 Rel. Int. 100% Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-2 3.40e7 14.01 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.01e3 Abs. Int. 1.40e7 PCB-3 3.30e7 14.19 7.00e6 0% 11.0 12.0 13.0 PCB-1 1.00e7 11.90 Rel. Int. 100% 14.0 0.00e0 16.0 RT Abs. Int. 4.23e6 PCB-3 9.90e6 14.19 PCB-2 1.02e7 14.01 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 4.14e3 15.0 2.12e6 0% 11.0 12.0 13.0 ES-1 6.28e7 11.89 Rel. Int. 100% 14.0 15.0 Abs. Int. 2.47e7 ES-3 6.04e7 14.18 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.93e3 0.00e0 16.0 RT 1.24e7 0% 11.0 12.0 13.0 ES-1 1.90e7 11.89 Rel. Int. 100% 14.0 15.0 Abs. Int. 7.62e6 ES-3 1.81e7 14.18 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.31e4 0.00e0 16.0 RT 3.81e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.39e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.70e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3681, 8558 scc: 678-882 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:56 (LKB) Printed: 31-Mar-2014 19:15 Page 2 of 21 693 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 Rel. Int. 100% Abs. Int. 8.57e6 PCB-10 2.55e7 14.63 PCB-4 1.57e7 14.45 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.13e3 4.29e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 5.48e6 PCB-10 1.61e7 14.63 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.28e4 PCB-4 9.78e6 14.45 2.74e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.68e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 9.09e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.97e3 4.55e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.67e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.65e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.36e3 2.82e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.39e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.70e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2442, 1917 scc: 678-882 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:15 Page 3 of 21 694 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.59e3 PCB-9 2.45e7 16.43 PCB-7 PCB-6 2.87e7 2.66e7 16.59 16.82 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 PCB-14 3.20e7 18.80 PCB-5 2.64e7 PCB-8 17.12 2.74e7 17.24 PCB-11 2.84e7 19.58 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 13/12 5.59e7 19.87 Abs. Int. 9.76e6 PCB-15 2.82e7 20.16 4.88e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.81e4 PCB-9 1.48e7 16.43 PCB-7 PCB-6 1.71e7 1.62e7 16.59 16.82 18.0 19.0 20.0 PCB-14 1.95e7 18.80 PCB-5 1.60e7 PCB-8 17.12 1.64e7 17.24 PCB-11 1.73e7 19.58 13/12 3.39e7 19.87 21.0 Abs. Int. 6.05e6 PCB-15 1.73e7 20.16 3.03e6 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 5.64e7 16.41 20.0 21.0 0.00e0 RT Abs. Int. 1.78e7 ES-15 5.27e7 20.14 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.75e4 8.89e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 3.65e7 16.41 20.0 21.0 Abs. Int. 1.16e7 ES-15 3.36e7 20.14 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.42e3 0.00e0 RT 5.79e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.99e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2161, 8633 scc: 678-882 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:15 Page 4 of 21 695 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Rel. Int. 100% Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 30/18 3.27e7 19.29 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.45e3 PCB-19 1.18e7 17.53 PCB-17 1.41e7 19.70 PCB-27 1.91e7 19.89 PCB-24 1.82e7 20.02 PCB-16 1.11e7 20.12 Abs. Int. 9.10e6 PCB-32 2.05e7 20.60 4.55e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 3.13e7 19.29 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 1.91e3 PCB-19 1.13e7 17.53 PCB-17 1.34e7 19.70 21.0 PCB-24 1.73e7 20.02 PCB-27 1.83e7 19.89 Abs. Int. 8.75e6 PCB-16 1.05e7 20.12 PCB-32 1.96e7 20.60 4.38e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.17e7 17.52 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 6.67e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 6.14e4 3.34e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.00e7 17.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.11e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.35e4 3.06e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.99e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 3428, 7843 scc: 678-882 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:15 Page 5 of 21 696 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 4.69e3 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 28/20 4.05e7 22.95 26/29 4.11e7 PCB-34 PCB-23 22.18 2.02e7 1.99e7 21.90 21.75 PCB-31 2.13e7 22.66 Abs. Int. 9.60e6 PCB-39 2.22e7 25.20 PCB-36 2.16e7 24.88 PCB-22 1.97e7 23.50 PCB-38 2.04e7 25.74 PCB-35 1.99e7 26.13 PCB-37 2.04e7 26.49 0% 22.0 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 4.12e3 23.0 24.0 25.0 0.00e0 RT 26.0 28/20 4.02e7 22.94 26/29 PCB-23 4.08e7 PCB-34 1.98e7 22.18 2.01e7 21.90 21.75 PCB-31 2.14e7 22.66 Abs. Int. 9.45e6 PCB-39 2.22e7 25.20 PCB-36 2.15e7 24.88 PCB-22 1.95e7 23.50 PCB-38 2.02e7 25.74 PCB-35 1.96e7 26.13 PCB-37 2.02e7 26.49 23.0 24.0 25.0 26.0 CS/SS-28 4.22e7 22.91 Rel. Int. 100% 4.72e6 0.00e0 RT 0% 22.0 4.80e6 ES-37 3.61e7 26.47 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 7.08e4 Abs. Int. 1.12e7 5.61e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 3.86e7 22.91 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.29e7 26.47 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.84e4 Abs. Int. 1.02e7 5.10e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.95e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2637, 6311 scc: 678-882 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:15 Page 6 of 21 697 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-54 1.17e7 20.45 Rel. Int. 100% Abs. Int. 3.25e6 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.22e3 1.63e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.45e7 20.45 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.96e6 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.11e3 1.98e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.76e7 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.99e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 6.35e3 2.49e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.30e7 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.48e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 5.28e3 3.24e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 7.99e6 0% 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5083, 6431 scc: 678-882 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:15 Page 7 of 21 698 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.33e3 50/53 2.19e7 22.44 PCB-51 1.16e7 23.09 PCB-45 8.94e6 23.02 PCB-73 1.48e7 PCB-52 24.69 1.11e7 24.56 PCB-46 8.90e6 23.30 69/49 2.70e7 24.98 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 44/47… 3.53e7 25.48 PCB-48 1.09e7 25.26 59/62… 4.57e7 25.75 71/40 2.36e7 26.35 PCB-42 1.03e7 25.92 PCB-41 8.46e6 26.25 Abs. Int. 8.36e6 PCB-64 1.64e7 26.55 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.96e3 50/53 2.78e7 22.43 24.0 PCB-51 1.46e7 23.09 PCB-45 1.16e7 23.02 25.0 PCB-73 1.89e7 PCB-52 24.69 1.41e7 24.56 PCB-46 1.14e7 23.30 69/49 3.42e7 24.98 PCB-48 1.39e7 25.26 59/62… 5.79e7 25.75 71/40 3.01e7 26.35 PCB-42 1.32e7 25.92 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.28e7 24.54 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 4.49e7 25.48 4.18e6 PCB-41 1.11e7 26.25 Abs. Int. 1.04e7 PCB-64 2.09e7 26.55 5.19e6 0.00e0 RT Abs. Int. 6.13e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.65e4 3.06e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.88e7 24.54 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.36e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 9.88e3 3.68e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.95e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 1969, 9329 scc: 678-882 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:15 Page 8 of 21 699 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 61/70... 6.35e7 28.77 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 3.99e4 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 PCB-72 1.61e7 27.26 PCB-57 1.56e7 27.89 PCB-63 1.74e7 28.48 PCB-55 1.49e7 29.20 PCB-60 PCB-80 1.52e7 1.75e7 29.83 30.15 PCB-79 1.73e7 31.47 PCB-78 1.47e7 31.96 PCB-81 1.50e7 32.34 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 Abs. Int. 7.94e6 PCB-77 1.55e7 32.82 3.97e6 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 3.07e4 PCB-57 1.95e7 27.89 PCB-68 2.12e7 27.52 30.0 61/70... 8.00e7 28.77 32.0 PCB-60 1.90e7 29.83 PCB-63 PCB-66 2.19e7 1.91e7 PCB-56 1.88e7 28.47 29.05 29.63 PCB-80 2.21e7 30.15 PCB-79 2.17e7 31.47 PCB-78 1.84e7 31.96PCB-81 1.90e7 32.34 34.0 36.0 38.0 Abs. Int. 9.93e6 PCB-77 1.94e7 32.82 4.97e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 2.62e7 32.32 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.77e4 0.00e0 RT 34.0 36.0 38.0 0.00e0 RT Abs. Int. 6.71e6 ES-77 2.72e7 32.80 3.35e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.24e7 32.32 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 9.42e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 8.21e6 ES-77 3.35e7 32.80 4.11e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.39e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.20e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4451, 9470 scc: 678-882 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:19 (CEM) Printed: 31-Mar-2014 19:15 Page 9 of 21 700 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Rel. Int. 100% Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-104 1.06e7 25.43 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 6.98e2 PCB-96 9.00e6 25.75 Abs. Int. 2.82e6 1.41e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 1.66e7 25.43 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 8.98e2 PCB-96 1.42e7 25.74 0.00e0 RT Abs. Int. 4.36e6 2.18e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.47e7 25.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.73e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.51e3 3.36e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.53e7 25.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.12e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.48e3 2.06e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 6.95e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0215, 7263 scc: 678-882 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:57 (LKB) Printed: 31-Mar-2014 19:15 Page 10 of 21 701 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 108/119... 5.46e7 31.50 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.95e3 PCB-103 8.70e6 27.44 100/93 1.53e7 28.22 PCB-88 8.13e6 28.71 PCB-121 1.12e7 29.72 113/90… 2.71e7 30.52 116/85 1.79e7 32.13 PCB-99 9.13e6 31.05 PCB-111 PCB-120 1.14e7 1.14e7 32.84 33.24 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-118 107/124 1.09e7 2.08e7 34.80 34.20 PCB-123 PCB-114 1.12e7 1.12e7 34.52 35.26 Abs. Int. 8.13e6 PCB-105 1.03e7 35.81 PCB-127 1.03e7 37.04 4.06e6 0% 28.0 30.0 32.0 108/119... 8.85e7 31.50 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 3.44e3 34.0 PCB-94 1.21e7 27.63 100/93 2.52e7 28.22 PCB-91 1.27e7 28.77 PCB-89 1.19e7 29.38 113/90… 4.43e7 30.52 PCB-112 PCB-92 1.73e7 1.24e7 31.16 30.04 116/85 PCB-115 2.92e7 1.70e7 32.13 32.33 PCB-110 PCB-111 PCB-120 PCB-117 1.85e7 1.71e7 1.66e7 1.87e7 32.84 32.25 32.04 33.24 36.0 107/124 PCB-118 1.77e7 3.37e7 34.80 34.20 PCB-123 PCB-114 1.84e7 1.84e7 34.52 35.26 38.0 Abs. Int. 1.30e7 PCB-105 1.68e7 35.80 PCB-127 1.70e7 37.04 6.50e6 0% 28.0 30.0 32.0 CS/SS-111 3.46e7 32.82 JS-101 3.03e7 30.52 Rel. Int. 100% 34.0 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.55e3 36.0 ES-118 ES-114 3.15e7 ES-123 3.05e7 3.07e7 34.78 35.24 34.50 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 8.64e6 ES-105 3.17e7 35.78 4.32e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 2.20e7 32.82 JS-101 1.89e7 30.52 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 1.99e3 ES-123 1.96e7 34.50 36.0 ES-118 1.98e7 ES-114 34.78 1.93e7 35.24 38.0 0.00e0 RT Abs. Int. 5.56e6 ES-105 1.98e7 35.78 2.78e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.39e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.20e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 6453, 4290 scc: 678-882 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:59 (LKB) Printed: 31-Mar-2014 19:15 Page 11 of 21 702 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 Abs. Int. 2.38e6 PCB-126 1.02e7 38.41 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 2.17e3 1.19e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 3.81e6 PCB-126 1.60e7 38.41 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 3.06e3 1.90e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.48e6 ES-126 2.69e7 38.39 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 6.74e3 3.24e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.94e6 ES-126 1.70e7 38.39 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 3.52e3 1.97e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.94e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0204, 9065 scc: 678-882 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:15 Page 12 of 21 703 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 PCB-150 PCB-155 1.61e7 1.70e7 30.68 30.38 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 8.57e2 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 147/149 139/140 2.30e7 2.32e7 33.83 34.34 PCB-145 1.52e7 31.26 PCB-148 1.16e7 32.53 153/168 2.93e7 36.40 151/135 PCB-146 2.21e7 PCB-144 PCB-143 PCB-142 PCB-133 1.19e7 33.05 1.13e7 1.14e7 1.08e7 9.73e6 35.86 33.52 34.08 35.30 34.66 PCB-141 1.05e7 36.55 163/138… 3.50e7 37.46 Abs. Int. 6.54e6 PCB-164 1.45e7PCB-160 37.17 1.34e7 37.60 0% 28.0 30.0 32.0 PCB-152 PCB-136 1.25e7 1.18e7 30.54 30.99 PCB-150 PCB-155 1.27e7 PCB-145 1.34e7 30.68 1.19e7 30.38 31.26 Rel. Int. 100% HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 7.84e2 PCB-148 9.27e6 32.53 34.0 36.0 147/149 139/140 151/135 1.82e7 1.84e7 1.76e7 33.82 34.34 33.05 PCB-154 PCB-143 1.02e7 PCB-132 8.88e6 33.26 8.02e6 34.08 34.90 38.0 153/168 2.31e7 36.40 PCB-146 9.39e6 35.86 163/138… 2.76e7 37.46 PCB-141 PCB-137 8.35e6 9.38e6 37.09 36.55 30.0 32.0 34.0 PCB-158 1.25e7 37.78 2.55e6 36.0 38.0 ES-155 2.90e7 30.36 Rel. Int. 100% ES-153 2.09e7 36.36 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.43e3 0.00e0 RT Abs. Int. 5.10e6 0% 28.0 3.27e6 0.00e0 RT Abs. Int. 7.43e6 JS-138 2.18e7 37.42 3.72e6 0% 28.0 30.0 32.0 34.0 36.0 ES-155 2.31e7 30.36 Rel. Int. 100% ES-153 1.62e7 36.36 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.36e3 38.0 0.00e0 RT Abs. Int. 5.84e6 JS-138 1.70e7 37.42 2.92e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.39e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 1.20e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2600, 5088 scc: 678-882 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:15 Page 13 of 21 704 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 2.20e7 38.52 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 3.22e3 PCB-162 PCB-159 1.36e7 39.57 1.35e7 39.33 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 156/157 2.56e7 40.96 Abs. Int. 5.05e6 PCB-169 1.25e7 43.67 PCB-167 1.44e7 39.98 2.52e6 0% 39.0 Rel. Int. 100% HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 2.89e3 128/166 1.81e7 38.52 PCB-162 PCB-159 1.11e7 39.57 1.11e7 39.33 40.0 41.0 42.0 43.0 44.0 45.0 156/157 2.10e7 40.96 Abs. Int. 4.14e6 PCB-169 1.01e7 43.67 PCB-167 1.17e7 39.98 2.07e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.61e7 39.96 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 5.46e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.98e7 40.94 0.00e0 RT Abs. Int. 9.07e6 ES-169 2.27e7 43.65 4.53e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.07e7 39.96 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 4.01e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.92e7 40.94 0.00e0 RT Abs. Int. 7.19e6 ES-169 1.82e7 43.65 3.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.94e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5856, 0615 scc: 678-882 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:16 Page 14 of 21 705 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Rel. Int. 100% PCB-188 1.11e7 35.26 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-179 1.05e7 PCB-184 9.95e6 35.54 36.00 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 5.97e2 PCB-186 1.02e7 36.69 Abs. Int. 2.72e6 PCB-178 7.26e6 37.82 1.36e6 0% 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 36.0 PCB-188 1.04e7 35.26 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.13e2 PCB-179 9.84e6 35.54 PCB-176 1.04e7 36.29 37.0 PCB-186 9.70e6 36.69 38.0 Abs. Int. 2.56e6 PCB-178 6.85e6 37.82 1.28e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.83e7 35.23 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 4.50e6 CS/SS-178 1.27e7 37.80 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.37e3 2.25e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.73e7 35.23 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.32e6 CS/SS-178 1.18e7 37.80 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.34e3 2.16e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.39e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 1.20e7 0% 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 9424, 8766 scc: 678-882 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:57 (LKB) Printed: 31-Mar-2014 19:16 Page 15 of 21 706 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 4.42e3 PCB-175 9.54e6 38.36 PCB-183 1.04e7 PCB-182 39.12 PCB-185 1.02e7 9.57e6 38.77 39.20 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 PCB-181 PCB-177 9.14e6 8.11e6 40.03 39.68 180/193 2.11e7 42.09 PCB-192 1.07e7 41.81 PCB-172 8.43e6 41.56 171/173 1.63e7 40.22 PCB-191 1.18e7 42.42 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-170 7.89e6 43.19 Abs. Int. 3.77e6 PCB-190 1.11e7 43.64 1.89e6 0% 39.0 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 2.97e3 PCB-182 9.67e6 38.77 PCB-183 PCB-187 9.96e6 9.38e6 39.12 38.59 40.0 PCB-177 PCB-181 7.76e6 8.68e6 40.03 39.68 41.0 42.0 180/193 2.02e7 42.09 171/173 1.54e7 40.22 PCB-172 8.00e6 41.56 43.0 PCB-191 1.11e7 42.42 PCB-170 7.56e6 43.19 44.0 45.0 Abs. Int. 3.55e6 PCB-190 1.06e7 43.64 1.77e6 0% 39.0 40.0 41.0 42.0 ES-180 1.73e7 42.10 Rel. Int. 100% 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 4.02e6 ES-170 1.38e7 43.17 HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.83e3 2.01e6 0% 39.0 40.0 41.0 42.0 ES-180 1.56e7 42.10 Rel. Int. 100% 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.72e6 ES-170 1.29e7 43.17 HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 2.55e3 1.86e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.94e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5214, 8318 scc: 678-882 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:57 (LKB) Printed: 31-Mar-2014 19:16 Page 16 of 21 707 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-189 1.15e7 45.80 Abs. Int. 2.69e6 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 1.48e3 1.34e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.09e7 45.80 Abs. Int. 2.55e6 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 1.71e3 1.28e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 2.00e7 45.78 0.00e0 RT Abs. Int. 4.69e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 3.96e3 2.35e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.94e7 45.78 0.00e0 RT Abs. Int. 4.60e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 3.30e3 2.30e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.91e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.45e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4743, 7697 scc: 678-882 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:58 (LKB) Printed: 31-Mar-2014 19:16 Page 17 of 21 708 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 PCB-202 8.36e6 39.79 Rel. Int. 100% PCB-201 9.20e6 40.58 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 6.00e2 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-197 8.98e6 PCB-204 41.34 PCB-200 8.58e6 9.03e6 41.15 41.43 198/199 1.18e7 43.75 Abs. Int. 2.20e6 PCB-196 6.25e6 44.33 PCB-203 6.43e6 44.50 1.10e6 0% 39.0 40.0 PCB-202 9.16e6 39.79 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 5.89e2 41.0 PCB-201 1.02e7 40.58 42.0 43.0 PCB-197 9.77e6 PCB-204 41.34 PCB-200 9.99e6 9.25e6 41.43 41.15 44.0 45.0 198/199 1.31e7 43.75 0.00e0 RT Abs. Int. 2.44e6 PCB-196 6.91e6 44.33 PCB-203 6.98e6 44.50 1.22e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.63e7 39.77 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.01e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.85e3 2.01e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.81e7 39.77 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.55e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.19e3 2.27e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 6.94e6 0% 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 2900, 1413 scc: 678-882 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:16 Page 18 of 21 709 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 1.41e3 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 PCB-194 5.88e6 47.56 PCB-195 5.45e6 45.62 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-205 7.18e6 47.96 Abs. Int. 1.74e6 8.68e5 0% 46.0 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 1.66e3 47.0 48.0 PCB-194 6.39e6 47.56 PCB-195 5.96e6 45.62 49.0 50.0 PCB-205 7.78e6 47.96 0.00e0 RT Abs. Int. 1.86e6 9.30e5 0% 46.0 47.0 48.0 JS-194 1.32e7 47.54 Rel. Int. 100% 49.0 50.0 ES-205 1.36e7 47.94 0.00e0 RT Abs. Int. 3.34e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.10e3 1.67e6 0% 46.0 47.0 48.0 JS-194 1.45e7 47.54 Rel. Int. 100% 49.0 50.0 ES-205 1.52e7 47.94 0.00e0 RT Abs. Int. 3.77e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.41e3 1.89e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.91e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.45e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 4214, 3532 scc: 678-882 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 13:19 (CEM) Printed: 31-Mar-2014 19:16 Page 19 of 21 710 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.32e3 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-207 8.15e6 46.20 PCB-208 7.78e6 45.42 Abs. Int. 1.92e6 PCB-206 4.95e6 49.43 9.61e5 0% 46.0 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.47e3 47.0 48.0 49.0 50.0 PCB-207 1.04e7 46.20 PCB-208 9.93e6 45.42 Abs. Int. 2.46e6 PCB-206 6.26e6 49.42 1.23e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 1.41e7 45.40 50.0 0.00e0 RT Abs. Int. 3.30e6 ES-206 8.99e6 49.41 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.01e3 1.65e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 4.29e6 ES-208 1.78e7 45.40 ES-206 1.12e7 49.40 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.94e3 2.14e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.91e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.45e6 0% 46.0 47.0 48.0 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 0703, 7657 scc: 678-882 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 10:56 Printed: 31-Mar-2014 19:16 Page 20 of 21 711 of 711 SGS-AP ID: OPR1_11892_PCB-RJ Instr: AutoSpec-Premier MM7 Sample ID: 0_11892_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 32 Acq: 26-Mar-2014 19:16:37 User: LKB Datafile: 140326X06 PCB-209 7.30e6 50.86 Rel. Int. 100% Abs. Int. 1.58e6 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 9.15e2 7.88e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 6.22e6 50.86 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.34e6 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.21e2 6.70e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.35e7 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.86e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 9.57e2 1.43e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.15e7 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.48e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 8.51e2 1.24e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.58e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.29e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6504_11892 PCB\Resources\OPR1_11892_PCB-RJ.utp_res, saved 31-Mar-2014 13:19 (CEM) AP UltraTrace-Pro V4.81 User/System: CEM/US0007762 cc: 5638, 2751 scc: 678-882 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 10:49 (LKB) Printed: 31-Mar-2014 19:16 Page 21 of 21 1 of 622 1 APRIL 2014 DELANEY PETERSON ANCHOR QEA 7200 Olive Way, Ste 300 Seattle WA 98101 t. 206-287-9130 e. DPeterson@anchorqea.com SUBJECT: CERTIFICATE OF RESULTS Dear Delaney; Attached to this narrative are the analytical results for sample(s) submitted for the determination of polychlorinated biphenyl congeners. The insert below summarizes information about the project. If applicable, QC annotations below highlight specific analytical observations and assessments made during the sample handling and data interpretation phases. Results reported relate only to the items tested. PROJECT INFORMATION SUMMARY (When applicable, see QC Annotations for details) Client Project Patrick Bayou Superfund Ste SGS Project # A6506 Analytical Protocol(s) Method 1668A No. Samples Submitted 7 (+2 for filtration – 1 filtration on “hold”) – 8 samples analyzed Additional QC Sample(s) 0 No. Laboratory Method Blanks 1 No. OPRs / Batch CS3 1 Date Received 20-Feb-2014 Condition Received good Temperature upon Receipt (C) 1,4 Extraction within Holding Time yes Analysis within Holding Time yes SGS Environmental Services 5500 Business Drive Wilmington, NC 28405 +1 910 350 1903 +1 866 846 8290 www.sgs.com Member of the SGS Group (SGS SA) 2 of 622 QC ANNOTATIONS: 1. Please see Appendices attached for data qualifier/attribute and lab identifier descriptions which may be contained in the project. 2. Samples noted as “DISSOLVED” in the sample IDs were filtered with a 0.45µm filter prior to extraction. SGS remains committed to serving you in the most effective manner. Should you have any questions or need additional information and technical support, please do not hesitate to contact us. The management and staff of SGS welcomes customer feedback, both positive and negative, as we continually improve our services. Please visit our web site at www.sgs.com/ultratrace and click on the 'Email Us' link or go to our survey here. Thank you for choosing SGS. Sincerely, Todd Vilen Project Manager Page 2 of 5 3 of 622 APPENDIX A: GENERAL DATA QUALIFIERS / DATA ATTRIBUTES B The analyte was found in the method blank, at a concentration that was at least 10% of the concentration in the sample. C Two or more congeners co-elute. In EDDs, C denotes the lowest IUPAC congener in a co-elution group and additional co-eluters for the group are shown with the number of the lowest IUPAC co-eluter. E The reported concentration exceeds the calibration range (upper point of the calibration curve) and is an estimated value. EMPC Represents an Estimated Maximum Possible Concentration. EMPCs arise in cases where the signal/noise ratio is not sufficient for peak identification (the determined ion-abundance ratio is outside the allowed theoretical range), or where there is a co-eluting interference. H/h If the standard recovery is below the method or SOP specified value “H” is assigned. If the obtained value is less than half the specified value “h” is assigned.1 J Indicates that an analyte has a concentration below the reporting limit (lowest point of the calibration curve) and is an estimated value. ND Indicates a non-detect. NR Indicates a value that is not reportable. PR Due to interference, the associated congener is poorly resolved. QI Indicates the presence of a quantitative interference. SI Denotes “Single Ion Mode” and is utilized for PCBs where the secondary ion trace has a significantly elevated noise level due to background PFK. Responses for such peaks are calculated using an EMPC approach based solely on the primary ion area(s) and may be considered estimates.1 U The analyte was not detected. The estimated detection limit (EDL) may be reported for this analyte. V The labeled standard recovery was found to be outside of the method control limits. Page 3 of 5 4 of 622 APPENDIX B: DRBC/TMDL SPECIFIC DATA QUALIFIERS / DATA ATTRIBUTES J The reported result is an estimate. The value is less than the minimum calibration level but greater than the estimated detection limit (EDL). U The analyte was not detected in the sample at the estimated detection limit (EDL). E The reported concentration is an estimate. The value exceeds the upper calibration range (upper point of the calibration curve). D Dilution Data. Result was obtained from the analysis of a dilution. B Analyte found in the sample and associated method blank. C Co-eluting congener Cxx Co-elutes with the indicated congener, data is reported under the lowest IUPAC congener. ‘Xx’ denotes the IUPAC number with the lowest numerical designated congener. NR Analyte is not reportable because of problems in sample preparation or analysis. V Labeled standard recovery is not within method control limits. X Results from re-injection/repeat/second-column analysis. EMPC Estimated maximum possible concentration. Indicates that a peak is identified but did not meet the method specified ion-abundance ratio. APPENDIX C: LAB IDENTIFIERS AR Indicates use of the archived portion of the sample extract. CU Indicates a sample that required additional clean-up prior to MS injection/processing. D Indicates a dilution of the sample extract. The number that follows the “D” indicates the dilution factor. DE Indicates a dilution performed with the addition of ES (extraction standard) solution. DUP Designation for a duplicate sample. MS Designation for a matrix spike. MSD Designation for a matrix spike duplicate. RJ Indicates a reinjection of the sample extract. S Indicates a sample split. The number that follows the “S” indicates the split factor. Page 4 of 5 5 of 622 SGS CERTIFICATIONS California 07255CA Connecticut PH-0258 Florida (primary NELAP) E87634 ISO17025 2726.01 Kansas E-10330 Louisiana 04115 Maryland (DW only) 299 New Jersey NC100 New York 11685 North Carolina DENR 481 North Carolina DHHS (DW only) 37776 North Dakota R-197 Oregon NC200002 Pennsylvania 68-03675 South Carolina 99029 Texas T104704260-13-5 Utah NC009192013-3 Virginia (DW only) 00235 Virginia 460214 Washington State C913 West Virginia 293 Page 5 of 5 6 of 622 Sample ID: Method 1668A PB070_B-2SWMID-140314-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 14-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 268 PCB-81 344'5-TeCB 13.2 PCB-105 233'44'-PeCB 804 PCB-114 2344'5-PeCB 48.5 PCB-118 23'44'5-PeCB 1,410 PCB-123 23'44'5'-PeCB 43.1 PCB-126 33'44'5-PeCB EMPC PCB-156/157 233'44'5/233'44'5'-HxCB 81.3 PCB-167 23'44'55'-HxCB 22.5 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB EMPC Aqueous 0.92 L 6 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11899 Qualifier 8.33 J C 3.81 J 1.8 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.103 0.23 0 357 0.357 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 79 1,430 16,400 36,300 13,900 2,780 662 149 37.1 332 Total PCB (Mono-Deca) 72,100 Checkcode: 561-113-BSP SGS Environmental Services - PCB 2014 Rev. 4.03 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6506 0.936 0.963 0 99 0.99 13,900 666 155 49.7 72,100 Date Received: A6506_11899_PCB_001 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 15-Mar-2014 19-Mar-2014 27-Mar-2014 Recovery % 50.6 61.4 70.3 86.3 78.9 77.9 91.5 82.7 80 99.6 85.2 83.1 85.9 83.6 81.9 84.4 89 1 89.1 70.9 73.3 67.8 86.3 87.2 103 90 93.9 81.5 84.6 98.8 80.2 87.9 95.4 116 Report Created: 30-Mar-2014 14:29 Analyst: LB 7 of 622 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 14-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. PCB-1 70.1 PCB-2 (1.82) PCB-3 8.95 Conc. 79 EMPC 79 Di Conc. Qualifiers Qualifiers Project No.: A6506 Date Received: 0.92 L Sample ID: A6506_11899_PCB_001 Date Extracted: 19-Mar-2014 11899 Date Analyzed: 27-Mar-2014 561-113-BSP Time Analyzed: pg/L Tri PCB-19 J Aqueous 6 Units Mono Method 1668A Laboratory Data Conc. 3,410 PCB-17 1,100 Checkcode: Qualifiers 356 PCB-30/18 QC Batch No.: C Tetra Conc. PCB-54 15.4 PCB-50/53 945 PCB-45 979 Qualifiers Tetra PCB-72 C 15-Mar-2014 14:18:19 Conc. 20.8 PCB-68 27.7 PCB-57 14.7 PCB-27 191 PCB-51 198 PCB-58 7.23 PCB-24 22.6 PCB-46 373 PCB-67 79.5 PCB-16 1,180 PCB-52 5,850 PCB-32 1,020 PCB-73 10.2 PCB-34 9.81 J PCB-43 188 (2.94) PCB-69/49 2,850 C PCB-48 1,000 PCB-63 J 6,050 PCB-66 3,670 521 PCB-23 PCB-10 22.1 PCB-26/29 PCB-9 29.3 PCB-25 183 PCB-44/47/65 4,870 C PCB-60 790 PCB-7 10.9 PCB-31 3,110 PCB-59/62/75 362 C PCB-80 (2.86) PCB-28/20 3,010 C PCB-42 1,230 PCB-79 26.8 PCB-21/33 893 C PCB-41 444 PCB-78 (3.52) PCB-81 13.2 PCB 77 PCB-77 268 PCB-6 98.2 PCB-5 7.67 J PCB-8 399 PCB-22 832 PCB 14 PCB-14 (2 46) (2.46) PCB 36 PCB-36 (2 84) (2.84) PCB-11 36.3 B PCB-39 29.1 PCB-13/12 32.8 C PCB-15 268 PCB-38 7.03 PCB-35 40.5 PCB-37 534 PCB-71/40 2,150 PCB 64 PCB-64 1 940 1,940 C C J 120 PCB-61/70/74/76 PCB-4 471 Qualifiers PCB-55 34.1 PCB-56 1,760 C J Conc. 1,430 Conc. 16,400 Conc. 36,300 EMPC 1,430 EMPC 16,400 EMPC 36,300 Totals Conc. EMPC Mono-Tri 17,900 17,900 Tel: +1 910 794-1613 Tetra-Hexa 53,000 53,000 www.us.sgs.com Hepta-Deca 1,180 1,200 Mono-Deca 72,100 72,100 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 8 of 622 Sample ID: Penta PB070_B-2SWMID-140314-N (TOTAL) Conc. Qualifiers Conc. Qualifiers PCB-108/119/86/97/125/87 1,600 C PCB-155 (0.836) PCB-152 (0.953) PCB-146 80.5 C PCB-150 (0.94) PCB-161 (1.15) PCB-104 (0.986) PCB-96 53.3 PCB-117 66 PCB-103 16.6 PCB-116/85 492 Hexa Method 1668A Penta Conc. PCB-94 25.6 PCB-110 2,160 PCB-136 84.1 PCB-95 1,670 PCB-115 75.3 PCB-145 (1) PCB-100/93 39.3 PCB-148 (1.46) PCB-102 114 C J EMPC PCB-82 426 PCB-111 (2.69) PCB-120 (2.65) PCB-98 [4.61] PCB-88 15.8 PCB-107/124 71.9 PCB-91 410 PCB-109 118 PCB-84 781 PCB-123 43.1 PCB-89 83.3 PCB-106 3.41 PCB-121 (2.66) PCB-118 PCB-92 331 PCB-113/90/101 C J PCB-154 7.78 28 PCB-147/149 440 42 682 (1.26) PCB-158 66.2 PCB-128/166 120 PCB-159 4.39 J J PCB-122 35.4 PCB-131 11.7 PCB-162 2.51 PCB-167 22.5 PCB-99 1,140 PCB-127 (2.81) PCB-133 9.04 PCB-112 8.57 PCB-126 [8.33] J PCB-156/157 81.3 PCB-169 (1.8) 13,900 Conc. 2,780 EMPC 13,900 EMPC 2,780 Hepta Conc. Nona Conc. PCB-174 PCB-179 36.8 PCB-184 (1.09) PCB-176 10.2 Qualifiers Octa Conc. Qualifiers 84.8 PCB-202 PCB-177 50.1 PCB-201 5.92 PCB-181 (1.72) PCB-204 (1.59) PCB-197 [2.05] J EMPC PCB-200 [4.15] J EMPC Conc. 37.1 PCB-198/199 44.6 C EMPC 49.7 Deca Conc. PCB-171/173 28.1 PCB-186 (1.05) PCB-172 14.6 PCB-178 16.9 PCB-192 (1.45) C 11.2 PCB-175 3.98 PCB-180/193 160 C PCB-196 17 PCB-187 99 PCB-191 3.63 J PCB-203 23.5 PCB-182 (1.54) PCB-170 85 PCB-195 14 PCB-183 44.7 PCB-185 8.33 PCB-190 15.8 PCB-189 [3.81] C C J EMPC Conc. (0.88) C PCB-160 JC 243 C C 15.7 (1.77) J PCB-164 PCB-163/138/129 PCB-139/140 PCB-132 J 48.1 39.3 1,410 PCB-142 J PCB-130 PCB-137 J 804 Qualifiers 416 111 43.4 48.5 Conc. PCB-153/168 PCB-141 4.91 PCB-105 Qualifiers (1.25) PCB-134 PCB-114 J Conc. PCB-143 J 129 Hepta C 177 PCB-144 Hexa PCB-165 PCB-151/135 PCB-83 PCB-188 1,750 C Qualifiers J EMPC PCB-194 33 PCB-205 (2.37) Conc. 662 Conc. 149 EMPC 666 EMPC 155 209 Congener PCB Summary Page 2 of 2 J PCB-208 [12.6] PCB-207 13.1 PCB-206 24 PCB-209 332 Qualifiers EMPC Qualifiers 9 of 622 Sample ID: Method 1668A PB070_B-1SWMID-140314-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 14-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 241 PCB-81 344'5-TeCB 10.1 PCB-105 233'44'-PeCB 714 PCB-114 2344'5-PeCB 41 PCB-118 23'44'5-PeCB 1,270 PCB-123 23'44'5'-PeCB 34.2 PCB-126 33'44'5-PeCB 7.34 PCB-156/157 233'44'5/233'44'5'-HxCB 67.7 PCB-167 23'44'55'-HxCB 19.7 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB 2.96 Aqueous 0.94 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11899 Qualifier J J C 0.615 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.826 0.835 0 844 0.844 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 72.7 1,390 16,700 33,400 12,700 2,440 559 127 35.5 249 Total PCB (Mono-Deca) 67,700 Checkcode: 505-842-NMR SGS Environmental Services - PCB 2014 Rev. 4.03 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6506 0.826 0.835 0 844 0.844 2,440 565 67,800 Date Received: A6506_11899_PCB_002 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 15-Mar-2014 19-Mar-2014 27-Mar-2014 Recovery % 52.6 64.4 71.9 98.9 79.4 87.4 80.9 93.8 92.1 103 93.9 91.7 94.3 92.4 96.3 93.8 94 9 94.9 80.7 81.1 76.2 93.5 94.4 112 101 103 90.7 90.8 106 84.7 90 101 120 Report Created: 30-Mar-2014 14:29 Analyst: LB 10 of 622 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 14-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers Aqueous Project No.: A6506 Date Received: 0.94 L Sample ID: A6506_11899_PCB_002 Date Extracted: 19-Mar-2014 11899 Date Analyzed: 27-Mar-2014 505-842-NMR Time Analyzed: 7 Units Mono pg/L Tri PCB-19 Method 1668A Laboratory Data Conc. PCB-1 61.8 PCB-2 2.74 J PCB-30/18 3,930 PCB-3 8.23 J PCB-17 1,310 QC Batch No.: Checkcode: Qualifiers 391 C Tetra Conc. PCB-54 16.6 PCB-50/53 874 PCB-45 907 Qualifiers Tetra PCB-72 C 15-Mar-2014 15:13:30 Conc. 18.6 PCB-68 28 PCB-57 12.8 PCB-27 226 PCB-51 198 PCB-58 7.46 Conc. 72.7 PCB-24 26.4 PCB-46 364 PCB-67 71.2 EMPC 72.7 PCB-16 1,430 PCB-52 5,340 PCB-32 1,190 PCB-73 10.2 PCB-34 9.61 J PCB-43 182 (1.47) C PCB-48 Di Conc. Qualifiers PCB-4 531 PCB-23 PCB-10 21.6 PCB-26/29 PCB-9 24 PCB-7 8.76 PCB-6 88.7 PCB-5 6.26 2,610 C 936 5,500 PCB-66 3,320 PCB-55 34.9 PCB-56 1,610 PCB-25 165 PCB-44/47/65 4,590 C PCB-60 687 PCB-31 2,780 PCB-59/62/75 329 C PCB-80 (1.14) PCB-28/20 2,740 C PCB-42 1,170 PCB-79 20.3 J PCB-21/33 778 C PCB-41 410 PCB-78 (1.4) PCB-81 10.1 PCB 77 PCB-77 241 362 PCB-22 732 PCB 14 PCB-14 (1 07) (1.07) PCB 36 PCB-36 (1 42) (1.42) 35 B PCB-39 27 PCB-13/12 33.1 C PCB-38 6.27 PCB-15 279 PCB-35 40 PCB-37 482 PCB-71/40 2,060 PCB 64 PCB-64 1 780 1,780 C J 107 PCB-61/70/74/76 J PCB-8 PCB-11 PCB-69/49 425 PCB-63 J Qualifiers C J J Conc. 1,390 Conc. 16,700 Conc. 33,400 EMPC 1,390 EMPC 16,700 EMPC 33,400 Totals Conc. EMPC Mono-Tri 18,100 18,100 Tel: +1 910 794-1613 Tetra-Hexa 48,600 48,600 www.us.sgs.com Hepta-Deca 970 976 Mono-Deca 67,700 67,800 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 11 of 622 Sample ID: Penta PB070_B-1SWMID-140314-N (TOTAL) Conc. Qualifiers Penta Conc. Qualifiers PCB-108/119/86/97/125/87 1,460 C PCB-104 (0.385) PCB-96 53.2 PCB-117 51.6 PCB-103 16.3 PCB-116/85 456 C Hexa PCB-155 Method 1668A Conc. (0.254) [1.02] J EMPC PCB-146 71.3 J EMPC PCB-161 (0.328) PCB-153/168 357 J PCB-141 93.4 22.5 PCB-110 1,940 PCB-136 75.3 PCB-115 50.2 PCB-145 0.514 PCB-100/93 37.4 PCB-148 PCB-102 110 PCB-98 7.38 PCB-88 (1.79) PCB-91 397 J 385 (1.17) PCB-120 3.14 PCB-107/124 60.6 PCB-109 108 PCB-84 761 PCB-123 34.2 PCB-89 78.1 PCB-106 2.12 PCB-121 (1.16) PCB-118 PCB-92 310 PCB-122 PCB-113/90/101 J PCB-130 42.1 161 C PCB-137 33.6 J PCB-154 6.26 J PCB-164 37.7 C PCB-144 25.9 PCB-147/149 395 J 31.9 PCB-131 11.8 PCB-162 PCB-167 19.7 PCB-156/157 67.7 PCB-99 1,040 PCB-127 (1.28) PCB-133 7.94 PCB-112 5.28 [7.34] J PCB-169 C J 12,700 Conc. 2,440 EMPC 12,700 EMPC 2,440 Hepta Conc. Nona Conc. Qualifiers PCB-174 71.6 PCB-179 32.3 PCB-177 43.5 PCB-184 (0.426) PCB-181 1.1 J C Octa Conc. Qualifiers 8.68 J PCB-208 9.81 Qualifiers J PCB-201 5.05 J PCB-207 8.13 J PCB-204 (0.475) PCB-206 17.5 PCB-197 1.69 PCB-200 4.14 J Conc. 35.5 PCB-198/199 34.7 C EMPC 35.5 14.9 Deca Conc. PCB-202 PCB-176 8.88 PCB-171/173 24.6 PCB-186 (0.409) PCB-172 12.2 PCB-178 15.1 PCB-192 (0.541) PCB-175 [3.06] 135 C PCB-196 PCB-187 84.1 PCB-191 [2.55] J EMPC PCB-203 18.7 PCB-182 (0.573) PCB-170 69 PCB-195 10.8 PCB-183 38.2 PCB-190 12.9 PCB-194 26.6 PCB-185 8 PCB-189 2.96 PCB-205 1.39 PCB-180/193 C (0.615) Conc. (0.345) J J 2.14 JC 217 J EMPC 3.28 14.2 (0.502) J 103 PCB-159 PCB-139/140 PCB-132 Qualifiers 58.9 1,270 PCB-142 Conc. PCB-158 PCB-128/166 J 41 C (0.357) 41.4 714 PCB-126 589 C PCB-160 3.56 PCB-105 Qualifiers C PCB-134 PCB-114 J PCB-163/138/129 PCB-143 J 112 Hepta C 0.868 PCB-151/135 PCB-83 PCB-188 1,610 Conc. (0.355) [0.654] 1,560 PCB-82 PCB-165 PCB-150 PCB-95 PCB-111 Hexa PCB-152 PCB-94 C Qualifiers J Conc. 559 Conc. 127 EMPC 565 EMPC 127 209 Congener PCB Summary Page 2 of 2 J PCB-209 J 249 Qualifiers 12 of 622 Sample ID: Method 1668A PB079-1SWMID-140314-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 14-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 101 PCB-81 344'5-TeCB 4.33 PCB-105 233'44'-PeCB 320 PCB-114 2344'5-PeCB 18.1 PCB-118 23'44'5-PeCB 571 PCB-123 23'44'5'-PeCB 16.7 PCB-126 33'44'5-PeCB 3.1 PCB-156/157 233'44'5/233'44'5'-HxCB 30.9 PCB-167 23'44'55'-HxCB 9.03 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB 1.56 Aqueous 0.96 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11899 Qualifier J J C J 0.533 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.351 0.359 0 367 0.367 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 61.2 746 7,160 14,100 5,540 1,170 271 63.8 18.5 121 Total PCB (Mono-Deca) 29,200 Checkcode: 109-950-QPX SGS Environmental Services - PCB 2014 Rev. 4.03 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6506 0.351 0.359 0 367 0.367 7,170 1,180 282 66.1 29,300 Date Received: A6506_11899_PCB_003 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 15-Mar-2014 19-Mar-2014 27-Mar-2014 Recovery % 42.5 56.3 63.4 95.1 75.1 82.5 75.1 92.1 89.5 93.2 93 90.9 92.2 90.5 92.6 85.4 82 3 82.3 75.6 76.6 71.7 88.1 87.7 99.1 94.4 93.5 86 85.7 100 79.8 88.5 103 117 Report Created: 30-Mar-2014 14:29 Analyst: LB 13 of 622 Sample ID: PB079-1SWMID-140314-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 14-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers Aqueous Project No.: A6506 Date Received: 0.96 L Sample ID: A6506_11899_PCB_003 Date Extracted: 19-Mar-2014 11899 Date Analyzed: 27-Mar-2014 109-950-QPX Time Analyzed: 7 Units Mono pg/L Tri PCB-19 Method 1668A Laboratory Data Conc. QC Batch No.: Checkcode: Qualifiers 192 Tetra Conc. Qualifiers Tetra 15-Mar-2014 16:08:42 Conc. Qualifiers J PCB-1 49.8 PCB-2 3.36 J PCB-30/18 PCB-3 8.1 J PCB-17 564 PCB-45 370 PCB-57 5.56 J PCB-27 102 PCB-51 82.3 PCB-58 3.14 J PCB-46 143 PCB-67 29.2 1,660 C 8.1 J PCB-72 8.43 351 C PCB-68 25.6 Conc. 61.2 PCB-24 9.1 EMPC 61.2 PCB-16 585 PCB-52 2,260 PCB-32 543 PCB-73 4.14 PCB-34 5.08 J PCB-43 72 (1.14) C PCB-48 Di Conc. Qualifiers J PCB-54 PCB-50/53 PCB-69/49 1,110 J 47.4 2,350 PCB-66 1,420 PCB-55 12.6 PCB-56 697 PCB-4 300 PCB-23 PCB-10 11.6 PCB-26/29 198 PCB-9 12 PCB-25 105 PCB-44/47/65 1,930 C PCB-60 299 PCB-7 5.81 J PCB-31 1,160 PCB-59/62/75 140 C PCB-80 (0.841) PCB-28/20 1,180 C PCB-42 490 PCB-79 (0.834) J PCB-21/33 320 C PCB-41 144 PCB-78 (1.04) PCB-81 4.33 PCB 77 PCB-77 101 367 PCB-6 69.1 PCB-5 3.05 PCB-8 177 PCB-22 318 PCB-71/40 874 PCB 14 PCB-14 (1 05) (1.05) PCB 36 PCB-36 (1 1) (1.1) PCB 64 PCB-64 752 PCB-11 28.1 B PCB-39 9.9 J PCB-13/12 23.1 C PCB-38 [2.95] J EMPC PCB-15 116 PCB-35 16.8 PCB-37 203 C PCB-63 PCB-61/70/74/76 C Conc. 746 Conc. 7,160 Conc. 14,100 EMPC 746 EMPC 7,170 EMPC 14,100 C J Totals Conc. Mono-Tri 7,970 7,970 Tel: +1 910 794-1613 Tetra-Hexa 20,800 20,800 www.us.sgs.com Hepta-Deca 475 488 Mono-Deca 29,200 29,300 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 EMPC 14 of 622 Sample ID: Penta PCB-104 PB079-1SWMID-140314-N (TOTAL) Conc. Qualifiers (0.379) PCB-96 23.8 PCB-103 6.78 J PCB-94 9.94 J PCB-95 655 PCB-100/93 13.2 PCB-102 47.3 PCB-98 2.09 PCB-88 (1.08) PCB-91 169 JC J Penta Conc. Qualifiers PCB-108/119/86/97/125/87 630 C PCB-155 PCB-117 26.2 PCB-116/85 203 C PCB-120 (0.702) PCB-107/124 26.4 PCB-109 46.2 PCB-118 PCB-92 134 PCB-113/90/101 695 PCB-83 53 Qualifiers 34.7 PCB-161 (0.335) (0.422) 170 (0.713) (0.704) Conc. PCB-146 J PCB-148 PCB-82 PCB-111 PCB-121 (0.325) J 36.7 16.7 Hepta 0.801 0.557 (0.327) 1.41 PCB-188 PCB-152 PCB-150 PCB-136 PCB-123 J PCB-165 PCB-145 PCB-106 447 J EMPC 860 311 2.01 [0.433] 30.1 31.3 PCB-99 Qualifiers PCB-110 PCB-84 PCB-112 Method 1668A Conc. PCB-115 PCB-89 C Hexa C PCB-130 21.1 PCB-137 14.5 J PCB-164 20 PCB-163/138/129 290 PCB-154 2.93 PCB-144 12.8 PCB-147/149 188 571 PCB-139/140 6.4 JC PCB-159 2.1 J PCB-122 14.2 PCB-131 [4.63] J EMPC PCB-162 1.3 J PCB-114 18.1 PCB-142 (0.513) PCB-167 9.03 J PCB-105 320 PCB-132 101 PCB-156/157 30.9 C PCB-127 (0.744) PCB-133 3.74 PCB-126 3.1 J PCB-169 (0.533) Conc. 5,540 Conc. 1,170 EMPC 5,540 EMPC 1,180 Hepta Conc. Nona Conc. Qualifiers 36.5 Octa PCB-202 Conc. Qualifiers 4.71 J J EMPC PCB-201 [2.27] PCB-204 (0.452) PCB-208 4.79 PCB-207 4.31 J 9.42 J [10.9] J EMPC C PCB-197 0.781 J PCB-172 6.01 J PCB-200 2.2 J Conc. 18.5 J PCB-192 (0.533) PCB-198/199 18.6 JC EMPC 18.5 J PCB-180/193 68.3 C PCB-196 8.37 J J PCB-203 10.6 Deca Conc. PCB-195 5.36 PCB-187 41.5 PCB-191 1.44 (0.565) PCB-170 34.2 PCB-183 19.9 PCB-185 3.12 J PCB-190 6.69 J PCB-194 13.2 PCB-189 1.56 J PCB-205 (0.564) Conc. 271 Conc. 63.8 EMPC 282 EMPC 66.1 209 Congener PCB Summary Page 2 of 2 J Qualifiers J PCB-206 PCB-171/173 PCB-182 C J 21.1 1.94 28.9 48.9 J (0.629) PCB-175 PCB-158 PCB-128/166 C (0.364) 19.3 PCB-177 7.84 PCB-160 1.47 PCB-181 PCB-178 C C PCB-134 PCB-174 J Qualifiers PCB-143 J 16.3 4.9 179 45.7 C (0.403) (0.387) PCB-153/168 PCB-141 74.2 PCB-179 PCB-186 Conc. (0.363) PCB-151/135 PCB-184 PCB-176 Hexa PCB-209 121 Qualifiers 15 of 622 Sample ID: Method 1668A PB081_A-1SWMID-140314-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 14-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 80.1 PCB-81 344'5-TeCB EMPC PCB-105 233'44'-PeCB 250 PCB-114 2344'5-PeCB 13.4 PCB-118 23'44'5-PeCB 445 PCB-123 23'44'5'-PeCB 13.7 PCB-126 33'44'5-PeCB 2.12 PCB-156/157 233'44'5/233'44'5'-HxCB 23.7 PCB-167 23'44'55'-HxCB 7.15 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB 1.22 Aqueous 0.96 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 2.81 11899 Qualifier J J C J 0.545 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.243 0.251 0 259 0.259 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 47 576 5,490 11,400 4,470 889 199 45.8 8.74 54 Total PCB (Mono-Deca) 23,200 Checkcode: 761-905-WTS SGS Environmental Services - PCB 2014 Rev. 4.03 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6506 0.243 0.252 0 26 0.26 11,400 901 46.3 10.3 23,200 Date Received: A6506_11899_PCB_004 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 15-Mar-2014 19-Mar-2014 27-Mar-2014 Recovery % 28.2 44.1 49 92.2 65.1 90.8 77.4 97.1 94.8 106 100 99 101 98.6 99.4 94.4 93 9 93.9 83.1 83.4 79.1 96.6 96.7 112 103 103 93.7 94.8 110 89.3 94.6 107 121 Report Created: 30-Mar-2014 14:30 Analyst: LB 16 of 622 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 14-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers PCB-1 38.7 PCB-2 3.14 J PCB-3 5.17 J Aqueous Project No.: A6506 Date Received: 0.96 L Sample ID: A6506_11899_PCB_004 Date Extracted: 19-Mar-2014 11899 Date Analyzed: 27-Mar-2014 761-905-WTS Time Analyzed: 7 Units Mono pg/L Tri PCB-19 Conc. 1,340 QC Batch No.: Checkcode: Qualifiers 187 PCB-30/18 Method 1668A Laboratory Data C Tetra Conc. Qualifiers Tetra 15-Mar-2014 17:03:52 Conc. Qualifiers J PCB-54 7.25 J PCB-72 6.31 PCB-50/53 306 C PCB-68 31.8 PCB-17 482 PCB-45 315 PCB-57 4.15 J PCB-27 91.5 PCB-51 82 PCB-58 [1.73] J EMPC 23.4 Conc. 47 PCB-24 7.41 PCB-46 123 PCB-67 EMPC 47 PCB-16 470 PCB-52 1,880 PCB-63 35.7 PCB-32 508 PCB-73 3.48 PCB-61/70/74/76 1,800 PCB-34 3.73 PCB-43 60.4 PCB-66 1,120 PCB-23 (0.973) PCB-69/49 933 PCB-55 8.28 PCB-48 301 PCB-56 539 Di Conc. Qualifiers J J J PCB-4 245 PCB-10 9.5 J PCB-26/29 150 PCB-9 8.4 J PCB-25 94.9 PCB-44/47/65 1,600 C PCB-60 205 PCB-7 3.72 J PCB-31 782 PCB-59/62/75 113 C PCB-80 (0.944) PCB-6 63.7 PCB-28/20 839 C PCB-42 409 PCB-79 5.4 PCB-5 2.44 J PCB-21/33 181 C PCB-41 115 PCB-78 (1.16) PCB-81 [2.81] PCB 77 PCB-77 80 1 80.1 C PCB-8 107 PCB-22 202 PCB 14 PCB-14 (1 17) (1.17) PCB 36 PCB-36 (0 942) (0.942) PCB-11 PCB-13/12 PCB-15 29 B PCB-39 8.13 21.8 C PCB-38 (1.02) PCB-35 12.5 PCB-37 130 86 PCB-71/40 742 PCB 64 PCB-64 594 C C C J J J EMPC J Conc. 576 Conc. 5,490 Conc. 11,400 EMPC 576 EMPC 5,490 EMPC 11,400 Totals Conc. Mono-Tri 6,120 6,120 Tel: +1 910 794-1613 Tetra-Hexa 16,800 16,800 www.us.sgs.com Hepta-Deca 308 310 Mono-Deca 23,200 23,200 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 EMPC 17 of 622 Sample ID: Penta PCB-104 PB081_A-1SWMID-140314-N (TOTAL) Conc. Qualifiers (0.405) PCB-96 20 PCB-103 5.35 J PCB-94 8.82 J PCB-95 533 JC Conc. Qualifiers PCB-108/119/86/97/125/87 506 C PCB-155 PCB-117 20.3 PCB-152 [0.546] J EMPC PCB-146 27.2 PCB-116/85 163 C PCB-150 [0.423] J EMPC PCB-161 (0.378) PCB-136 28.8 PCB-145 (0.333) PCB-148 (0.476) PCB-82 142 PCB-111 (0.689) PCB-98 (1.14) PCB-120 (0.678) PCB-88 (1.05) PCB-107/124 21.6 PCB-91 143 PCB-109 36.4 PCB-84 267 PCB-123 13.7 PCB-89 27.4 PCB-106 1.03 PCB-121 (0.681) PCB-118 445 PCB-83 41.4 PCB-99 361 PCB-112 1.63 Hepta PCB-188 Conc. C J Qualifiers C J PCB-151/135 58.1 C Hexa PCB-165 Conc. PCB-153/168 133 PCB-141 35.6 PCB-130 16 PCB-137 13 PCB-164 13.9 PCB-154 [2.18] J EMPC 9.07 J PCB-163/138/129 PCB-147/149 144 C PCB-160 (0.411) PCB-158 22.5 PCB-134 16.2 PCB-143 [1.13] J EMPC PCB-139/140 5.34 JC J EMPC PCB-122 11 PCB-131 [4.18] 13.4 PCB-142 (0.578) PCB-105 250 PCB-132 80.1 PCB-127 (0.774) PCB-133 [2.54] PCB-126 [2.12] J EMPC PCB-128/166 219 35.7 C J EMPC J PCB-162 0.722 PCB-167 7.15 J PCB-156/157 23.7 C PCB-169 (0.545) J 4,470 Conc. 889 4,470 EMPC 901 Hepta Conc. Nona Conc. 11.4 PCB-184 (0.455) PCB-176 3.29 Qualifiers Octa Conc. Qualifiers 3.14 J PCB-208 2.44 Qualifiers J PCB-201 1.89 J PCB-207 [1.51] J EMPC PCB-204 (0.488) PCB-206 6.3 J PCB-197 [0.495] 25 PCB-202 PCB-177 14.4 PCB-181 (0.632) J PCB-171/173 8.58 JC J PCB-186 (0.436) PCB-172 4.87 PCB-178 5.86 J PCB-192 (0.536) PCB-175 1.23 J PCB-180/193 47.4 PCB-187 30.3 PCB-191 1.18 PCB-182 (0.568) PCB-170 24.5 PCB-183 13.1 PCB-185 2.52 C [0.963] Conc. PCB-179 C PCB-159 EMPC PCB-174 Qualifiers (0.409) PCB-144 PCB-114 (0.367) J J EMPC 702 11.1 110 [0.44] 16.5 41.5 559 Qualifiers PCB-110 PCB-100/93 PCB-92 Conc. PCB-115 PCB-102 PCB-113/90/101 Hexa Method 1668A Penta J EMPC PCB-200 1.71 J Conc. 8.74 PCB-198/199 13.4 JC EMPC 10.3 C PCB-196 5.97 J J PCB-203 7.04 J Deca Conc. PCB-195 3.57 J J PCB-190 4.48 J PCB-194 9.06 PCB-189 1.22 J PCB-205 (0.589) Conc. 199 Conc. 45.8 EMPC 199 EMPC 46.3 209 Congener PCB Summary Page 2 of 2 PCB-209 54 Qualifiers 18 of 622 Sample ID: Method 1668A PB081_A-1SWMID-140314-N (DISSOLVED) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 14-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 15.9 PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB 40.1 PCB-114 2344'5-PeCB 2.22 PCB-118 23'44'5-PeCB 73.3 PCB-123 23'44'5'-PeCB EMPC PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB EMPC PCB-167 23'44'55'-HxCB 1.11 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 0.93 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB J 2.05 J 3.11 JC J 1.2 0.884 0.97 0.00509 0.0788 0 153 0.153 0.00524 0.0789 0 153 0.153 44.3 495 2,680 3,230 802 116 12.6 ND 11.9 2,680 3,230 816 144 28.1 2.9 3.23 Total PCB (Mono-Deca) 7,390 Checkcode: 223-376-PJM SGS Environmental Services - PCB 2014 Rev. 4.03 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11899 Qualifier 1.36 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6506 7,460 Date Received: A6506_11899_PCB_005 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 15-Mar-2014 19-Mar-2014 27-Mar-2014 Recovery % 30.8 41 44.7 65.1 52.3 75 61.6 77.4 78 92.5 83.9 82.1 84.6 83.2 83.8 82.4 83 1 83.1 70.4 72.3 66.6 80.3 78.7 96.1 82.3 90.6 65.5 65.5 85.3 57.9 89.5 100 119 Report Created: 30-Mar-2014 14:30 Analyst: LB 19 of 622 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 14-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. PCB-1 38.8 PCB-2 (2.02) PCB-3 5.52 Qualifiers J Project No.: A6506 Date Received: 0.93 L Sample ID: A6506_11899_PCB_005 Date Extracted: 19-Mar-2014 11899 Date Analyzed: 27-Mar-2014 223-376-PJM Time Analyzed: pg/L Tri Conc. PCB-19 116 PCB-30/18 689 PCB-17 240 PCB-27 46.8 Conc. 44.3 PCB-24 [5.04] EMPC 44.3 PCB-16 249 Di Conc. Qualifiers Aqueous 7 Units Mono Method 1668A Laboratory Data QC Batch No.: Checkcode: Qualifiers Tetra PCB-54 C J EMPC Conc. Qualifiers Tetra 15-Mar-2014 17:59:02 Conc. [3.22] J EMPC PCB-72 PCB-50/53 115 C PCB-68 31.6 PCB-45 109 PCB-57 (1.24) PCB-51 47.9 PCB-58 (1.21) PCB-46 45.7 PCB-67 5.69 J PCB-52 599 PCB-63 8.38 J PCB-61/70/74/76 408 C PCB-66 245 PCB-55 2.19 PCB-56 120 PCB-32 240 PCB-73 1.24 PCB-34 (1.76) PCB-43 18.7 PCB-23 (1.76) PCB-69/49 276 PCB-48 84.9 J C (1.18) PCB-4 213 PCB-10 8.88 J PCB-26/29 74.8 PCB-9 8.3 J PCB-25 61.6 PCB-44/47/65 487 C PCB-60 50.1 PCB-7 3.97 J PCB-31 356 PCB-59/62/75 34.8 C PCB-80 (1.11) C PCB-6 62.3 PCB-28/20 364 C PCB-42 114 PCB-79 (1.1) PCB-5 (2.76) PCB-21/33 89.3 C PCB-41 32.2 PCB-78 (1.37) PCB-81 (1.36) PCB 77 PCB-77 15 9 15.9 PCB-8 93 PCB-22 99.8 PCB-71/40 212 PCB 14 PCB-14 (2 32) (2.32) PCB 36 PCB-36 (1 7) (1.7) PCB 64 PCB-64 167 PCB-11 34.5 B PCB-39 (1.65) PCB-13/12 18.4 JC PCB-38 (1.85) PCB-15 52.9 PCB-35 3.6 PCB-37 47.2 Qualifiers C J J Conc. 495 Conc. 2,680 Conc. 3,230 EMPC 495 EMPC 2,680 EMPC 3,230 Totals Conc. EMPC Mono-Tri 3,220 3,220 Tel: +1 910 794-1613 Tetra-Hexa 4,150 4,190 www.us.sgs.com Hepta-Deca 24.4 42.9 Mono-Deca 7,390 7,460 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 20 of 622 Sample ID: Penta PCB-104 PB081_A-1SWMID-140314-N (DISSOLVED) Conc. Qualifiers (0.743) PCB-96 [4.21] PCB-103 (1.48) J EMPC Conc. Qualifiers PCB-108/119/86/97/125/87 90.3 C PCB-117 [3.37] J EMPC PCB-152 (0.557) PCB-146 5.28 PCB-116/85 26.8 C PCB-150 (0.549) PCB-161 (0.637) PCB-136 5.52 PCB-153/168 23.8 BC J PCB-145 (0.587) PCB-141 6.33 J PCB-148 (0.804) PCB-130 2.96 J PCB-137 2.2 J PCB-94 (1.76) PCB-110 127 PCB-95 118 PCB-115 3.88 PCB-100/93 (1.6) C PCB-82 22.7 PCB-102 7.94 J PCB-111 (1.16) (1.14) PCB-98 (1.92) PCB-120 PCB-88 (1.76) PCB-107/124 Hexa PCB-155 PCB-151/135 3.85 JC Conc. Method 1668A Penta Qualifiers (0.489) 10.6 Hexa PCB-165 JB JC PCB-154 (0.724) PCB-144 [1.89] J EMPC Conc. Qualifiers (0.69) J PCB-164 2.16 J PCB-163/138/129 33.9 C PCB-91 26.6 PCB-109 [4.6] J EMPC PCB-147/149 [21.4] J B EMPC C PCB-160 PCB-84 53.4 PCB-123 [2.05] J EMPC PCB-134 [2.38] J EMPC PCB-158 3.8 J PCB-89 5.16 PCB-106 (1.3) PCB-143 (0.818) PCB-128/166 5.65 JC PCB-139/140 (0.813) PCB-159 (0.759) PCB-131 (0.961) PCB-162 (0.765) PCB-142 (0.975) PCB-167 1.11 J PCB-156/157 [3.11] J EMPC C J PCB-121 (1.15) PCB-118 73.3 PCB-92 21.6 PCB-122 (1.35) PCB-113/90/101 106 C PCB-114 2.22 PCB-83 8.18 J PCB-105 40.1 PCB-132 12.3 PCB-133 (0.865) PCB-99 64.6 PCB-127 (1.25) PCB-112 (1.19) PCB-126 (1.2) Hepta PCB-188 Conc. Qualifiers (0.768) PCB-179 [2.03] PCB-184 (0.95) (0.884) 802 Conc. 116 816 EMPC 144 Hepta Conc. Qualifiers Nona Conc. 4.59 J PCB-177 [2.36] J EMPC PCB-181 (1.35) Conc. (0.823) PCB-207 (2.14) (0.885) PCB-206 (4.29) PCB-171/173 (1.53) PCB-197 (0.826) (1.49) PCB-200 (0.87) PCB-178 (1.28) PCB-192 (1.15) PCB-198/199 PCB-175 (1.34) PCB-187 [4.8] PCB-182 (1.22) PCB-183 [2.54] PCB-185 (1.4) 7.97 PCB-170 [3.85] JBC J EMPC [2.9] PCB-196 (1.22) PCB-203 (1.21) PCB-195 (1.58) PCB-190 (1.17) PCB-194 (1.47) PCB-189 (0.97) PCB-205 (1.18) Conc. 12.6 Conc. 0 EMPC 28.1 EMPC 2.9 209 Congener PCB Summary Page 2 of 2 J EMPC C Conc. 0 EMPC 0 Deca Conc. PCB-209 Qualifiers (2.16) PCB-201 PCB-172 (1.07) PCB-208 PCB-204 (0.855) PCB-191 Qualifiers (0.887) (0.912) PCB-180/193 C Octa PCB-202 PCB-176 J EMPC PCB-169 Conc. PCB-186 J EMPC B EMPC PCB-174 J EMPC J C (0.693) 11.9 Qualifiers 21 of 622 Sample ID: Method 1668A PB089-1SWMID-140314-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 14-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 33.7 PCB-81 344'5-TeCB 1.79 PCB-105 233'44'-PeCB 107 PCB-114 2344'5-PeCB 5.96 PCB-118 23'44'5-PeCB 206 PCB-123 23'44'5'-PeCB 5.43 PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB 14.3 PCB-167 23'44'55'-HxCB EMPC PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 0.96 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11899 Qualifier J J J 1.42 3.75 0.68 0.723 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.014 0.0953 0 177 0.177 0.0142 0.0954 0 177 0.177 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 21.9 339 2,090 4,050 1,920 539 146 27.2 ND 11.5 2,090 4,050 1,930 546 149 32.7 Total PCB (Mono-Deca) 9,140 Checkcode: 431-600-JCR SGS Environmental Services - PCB 2014 Rev. 4.03 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6506 2.03 9,180 Date Received: A6506_11899_PCB_006 Date Extracted: JC J Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 15-Mar-2014 19-Mar-2014 27-Mar-2014 Recovery % 31.3 42.5 47.8 76.3 58.3 76.2 74.5 82.4 81 93.1 85.1 84.2 87.1 83.1 87 82.7 80 9 80.9 71.1 71.5 66.4 84.6 84 98.4 88.4 90.8 76.9 77.3 92 69.8 87 98.8 114 Report Created: 30-Mar-2014 14:31 Analyst: LB 22 of 622 Sample ID: PB089-1SWMID-140314-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 14-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. PCB-1 17.6 PCB-2 (1.44) PCB-3 4.25 Qualifiers J Project No.: A6506 Date Received: 0.96 L Sample ID: A6506_11899_PCB_006 Date Extracted: 19-Mar-2014 11899 Date Analyzed: 27-Mar-2014 431-600-JCR Time Analyzed: pg/L Tri Conc. PCB-19 82.4 PCB-30/18 389 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. Qualifiers Tetra 15-Mar-2014 18:54:13 Conc. Qualifiers J PCB-54 3.06 J PCB-72 4.52 PCB-50/53 113 C PCB-68 29.5 PCB-17 180 PCB-45 77.1 PCB-57 3.22 J PCB-27 32.1 PCB-51 59.2 PCB-58 [1.28] J EMPC PCB-46 42.1 PCB-67 10.4 PCB-52 666 PCB-63 18.2 Conc. 21.9 PCB-24 [2.93] EMPC 21.9 PCB-16 118 Di Conc. Qualifiers Aqueous 7 Units Mono Method 1668A Laboratory Data PCB-32 195 PCB-34 3.37 PCB-23 (1.71) PCB-4 125 PCB-10 4.8 J PCB-26/29 97.9 PCB-9 4.53 J PCB-25 PCB-7 2.63 J PCB-31 J EMPC J PCB-73 1.62 PCB-43 20.6 J 600 PCB-66 403 PCB-55 5.32 PCB-56 182 PCB-69/49 372 PCB-48 74.5 110 PCB-44/47/65 574 C PCB-60 77.1 315 PCB-59/62/75 40 C PCB-80 (1.05) C C PCB-61/70/74/76 PCB-6 60.3 PCB-28/20 366 C PCB-42 147 PCB-79 2.73 PCB-5 (2.39) PCB-21/33 56.7 C PCB-41 27.3 PCB-78 (1.3) PCB-71/40 251 PCB-81 1.79 PCB 64 PCB-64 210 PCB 77 PCB-77 33 7 33.7 PCB-8 46.8 PCB-22 88.5 PCB 14 PCB-14 (2 02) (2.02) PCB 36 PCB-36 (1 65) (1.65) PCB-11 37.4 B PCB-39 2.69 22 C PCB-38 (1.8) PCB-35 6.89 PCB-37 47.6 PCB-13/12 PCB-15 35.6 C C J J J J J Conc. 339 Conc. 2,090 Conc. 4,050 EMPC 339 EMPC 2,090 EMPC 4,050 Totals Conc. EMPC Mono-Tri 2,450 2,450 Tel: +1 910 794-1613 Tetra-Hexa 6,500 6,530 www.us.sgs.com Hepta-Deca 185 193 Mono-Deca 9,140 9,180 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 23 of 622 Sample ID: Penta PB089-1SWMID-140314-N (TOTAL) Conc. PCB-104 (0.495) Qualifiers Penta Conc. Qualifiers PCB-108/119/86/97/125/87 209 C Hexa PCB-155 Method 1668A Conc. Qualifiers [0.733] J EMPC Hexa PCB-165 Conc. PCB-96 [5.99] J EMPC PCB-117 10.3 J PCB-152 (0.405) PCB-146 18 PCB-103 [3.2] J EMPC PCB-116/85 64.2 C PCB-150 (0.399) PCB-161 (0.425) PCB-94 3.28 J PCB-136 17.3 PCB-95 220 J PCB-145 (0.426) PCB-148 (0.536) JC PCB-110 316 PCB-115 5.63 PCB-100/93 5.39 PCB-82 50.9 PCB-102 15.9 PCB-111 (0.935) PCB-98 (1.55) PCB-120 (0.921) PCB-88 (1.42) PCB-107/124 9.76 PCB-91 60.4 PCB-109 17.5 PCB-84 106 PCB-123 5.43 PCB-89 [9.09] PCB-106 (1.05) PCB-121 (0.924) PCB-118 206 PCB-92 52.8 PCB-113/90/101 257 PCB-83 J EMPC PCB-151/135 PCB-130 8.89 J 6.64 J PCB-154 1.48 J PCB-164 9.2 J JC PCB-144 5.12 J PCB-163/138/129 136 C PCB-147/149 88.2 C PCB-160 J PCB-134 9.02 J PCB-158 12.8 PCB-143 (0.546) PCB-128/166 21.1 PCB-139/140 PCB-159 (0.633) J EMPC PCB-162 (0.638) PCB-167 [3.75] J EMPC PCB-156/157 14.3 JC J PCB-131 [2.03] PCB-142 (0.651) 20.8 PCB-105 107 PCB-132 44.7 PCB-99 163 PCB-127 (0.95) PCB-133 1.51 PCB-112 (0.962) PCB-126 (1.42) Qualifiers 1,920 Conc. 539 EMPC 546 Hepta Conc. Nona Conc. Qualifiers Octa 19.5 PCB-202 Conc. Qualifiers 2.89 J PCB-208 (1.51) J PCB-207 (1.49) PCB-206 (2.55) 8.93 J PCB-177 10.7 PCB-201 1.47 2.25 J PCB-181 (0.876) PCB-204 (0.694) PCB-176 2.28 J PCB-171/173 PCB-197 (0.648) J (0.553) 3.91 PCB-175 (0.867) 6.1 JC PCB-172 2.66 J PCB-192 (0.742) PCB-180/193 36.3 C PCB-200 1.07 J Conc. 0 PCB-198/199 9.96 JC EMPC 0 PCB-196 [3.34] J EMPC Deca Conc. PCB-187 23.5 PCB-191 (0.694) PCB-203 5.14 J PCB-182 (0.787) PCB-170 17.2 PCB-195 [2.18] J EMPC PCB-183 10.6 PCB-194 6.68 J PCB-185 1.93 PCB-205 (0.93) J (0.68) 1,930 PCB-179 PCB-186 PCB-169 EMPC PCB-184 PCB-178 J Conc. PCB-174 PCB-190 [3.08] PCB-189 (0.723) J EMPC Conc. 146 Conc. 27.2 EMPC 149 EMPC 32.7 209 Congener PCB Summary Page 2 of 2 C JC J Conc. (0.463) 2.83 3.94 (0.466) C PCB-137 5.96 Hepta 86.5 19.3 C PCB-122 PCB-188 PCB-153/168 PCB-141 35.8 PCB-114 C Qualifiers (0.461) PCB-209 11.5 Qualifiers Qualifiers 24 of 622 Sample ID: Method 1668A PB085-1SWMID-140314-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 14-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 19.1 PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB 60.1 PCB-114 2344'5-PeCB EMPC PCB-118 23'44'5-PeCB 116 PCB-123 23'44'5'-PeCB 3.38 PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB 7.42 PCB-167 23'44'55'-HxCB 2.49 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 0.97 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 3.67 J J 1.14 JC J 0.643 0.723 0.00759 0.0743 0 141 0.141 0.0077 0.0744 0 141 0.141 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 353 1,890 2,830 1,130 313 75.4 14 ND 12 Total PCB (Mono-Deca) 6,620 Checkcode: 507-769-DWM SGS Environmental Services - PCB 2014 Rev. 4.03 28.6 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11899 Qualifier 1.26 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6506 2,840 1,130 86.9 19.7 1.98 6,680 Date Received: A6506_11899_PCB_007 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 15-Mar-2014 19-Mar-2014 27-Mar-2014 Recovery % 29.8 40.9 44.8 70.6 51.8 72.7 61.1 80.3 77.5 81.2 82.1 79.2 82 79.7 82.6 78.4 74 4 74.4 69.2 69.4 66.3 79.9 79 91.1 86.1 86.6 78 80.4 88.2 75.8 90.1 101 120 Report Created: 30-Mar-2014 14:31 Analyst: LB 25 of 622 Sample ID: PB085-1SWMID-140314-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 14-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers PCB-1 [23.3] EMPC PCB-2 (1.48) PCB-3 [5.34] J EMPC Project No.: A6506 Date Received: 0.97 L Sample ID: A6506_11899_PCB_007 Date Extracted: 19-Mar-2014 11899 Date Analyzed: 27-Mar-2014 507-769-DWM Time Analyzed: pg/L Tri Conc. PCB-19 91.2 PCB-30/18 418 QC Batch No.: Checkcode: Qualifiers Tetra PCB-54 C PCB-50/53 Conc. Qualifiers [2.32] J EMPC 87 C Tetra 15-Mar-2014 19:49:23 Conc. Qualifiers PCB-72 1.86 J PCB-68 26.7 PCB-17 176 PCB-45 65.1 PCB-57 1.24 PCB-27 34 PCB-51 54.5 PCB-58 (1.12) Conc. 0 PCB-24 3.55 EMPC 28.6 PCB-16 138 Di Conc. Qualifiers Aqueous 7 Units Mono Method 1668A Laboratory Data PCB-32 186 PCB-34 2.13 PCB-23 (1.76) J PCB-46 35 PCB-67 5.26 J PCB-52 473 PCB-63 10.3 J C PCB-73 1.35 J PCB-43 14 PCB-69/49 253 C PCB-48 58.7 J C PCB-61/70/74/76 394 PCB-66 253 PCB-55 2.97 PCB-56 122 PCB-4 145 PCB-10 4.88 J PCB-26/29 68.3 PCB-9 5.08 J PCB-25 71.8 PCB-44/47/65 418 C PCB-60 51 PCB-7 (3.07) PCB-31 253 PCB-59/62/75 29.7 JC PCB-80 (1.03) PCB-6 57 PCB-28/20 283 C PCB-42 105 PCB-79 1.46 PCB-5 (3.26) PCB-21/33 52.9 C PCB-41 22 PCB-78 (1.27) PCB-71/40 179 PCB-81 (1.26) PCB 64 PCB-64 151 PCB 77 PCB-77 19 1 19.1 PCB-8 57.1 PCB-22 73.6 PCB 14 PCB-14 (2 75) (2.75) PCB 36 PCB-36 (1 71) (1.71) PCB-11 30.7 B PCB-39 (1.66) PCB-13/12 18.9 JC PCB-38 (1.85) PCB-15 34.5 PCB-35 3.97 PCB-37 36.5 J C J J J Conc. 353 Conc. 1,890 Conc. 2,830 EMPC 353 EMPC 1,890 EMPC 2,840 Totals Conc. EMPC Mono-Tri 2,240 2,270 Tel: +1 910 794-1613 Tetra-Hexa 4,280 4,280 www.us.sgs.com Hepta-Deca 101 119 Mono-Deca 6,620 6,680 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 26 of 622 Sample ID: Penta PCB-104 PB085-1SWMID-140314-N (TOTAL) Conc. Qualifiers (0.564) PCB-96 4.31 J PCB-103 [1.43] J EMPC PCB-94 [1.82] J EMPC PCB-95 135 Conc. Qualifiers PCB-108/119/86/97/125/87 122 C PCB-155 PCB-117 3.64 J PCB-116/85 41.4 C PCB-136 10 J PCB-145 (0.506) PCB-148 (0.652) PCB-110 186 PCB-115 2.41 PCB-100/93 2.86 JC PCB-82 31.2 PCB-102 9.42 J PCB-111 (0.719) (0.708) PCB-98 (1.19) PCB-120 PCB-88 (1.09) PCB-107/124 5.89 Hexa Method 1668A Penta Qualifiers Hexa Conc. (0.421) PCB-165 PCB-152 (0.48) PCB-146 9.9 PCB-150 (0.474) PCB-161 (0.517) PCB-151/135 JC Conc. 21 J Qualifiers (0.56) PCB-153/168 50.4 PCB-141 11.9 J C PCB-130 5.15 J C PCB-137 3.5 J PCB-164 4.48 J PCB-163/138/129 77.6 C PCB-154 (0.588) PCB-144 3.1 J PCB-91 34.1 PCB-109 10.2 J PCB-147/149 51.3 C PCB-160 (0.563) PCB-84 64.3 PCB-123 3.38 J PCB-134 5.73 J PCB-158 7.84 J PCB-89 5.57 PCB-106 (0.804) PCB-143 (0.664) PCB-128/166 11.8 JC PCB-121 (0.711) PCB-118 116 PCB-139/140 1.9 JC PCB-159 (0.593) PCB-92 31.3 PCB-122 2.98 J PCB-131 1.33 J PCB-162 (0.598) PCB-114 [3.67] J EMPC PCB-142 (0.792) PCB-167 2.49 J PCB-105 60.1 PCB-132 26.4 PCB-156/157 7.42 JC PCB-133 (0.702) PCB-113/90/101 149 PCB-83 11.6 J C PCB-99 94.1 PCB-127 (0.767) PCB-112 (0.74) PCB-126 (1.14) Hepta PCB-188 Conc. Qualifiers (0.516) PCB-179 5.21 PCB-184 (0.638) PCB-176 [1.64] PCB-186 (0.613) PCB-178 2.48 PCB-175 (0.906) J EMPC J Conc. 1,130 Conc. 313 1,130 EMPC 313 Hepta Conc. Nona Conc. PCB-177 5.68 PCB-181 (0.915) PCB-171/173 Qualifiers 10.8 J [3.85] J EMPC C PCB-172 1.9 J PCB-192 (0.776) PCB-180/193 21.9 C Conc. Qualifiers PCB-202 Octa 1.68 J PCB-201 PCB-204 PCB-197 (0.715) PCB-200 (0.753) PCB-208 (1.53) (0.712) PCB-207 (1.52) (0.766) PCB-206 (2.43) PCB-198/199 6.53 JC PCB-196 [2.49] J EMPC PCB-187 13.4 PCB-191 (0.725) PCB-203 [3.15] J EMPC PCB-182 (0.822) PCB-170 12 PCB-195 1.74 J PCB-194 4.06 J PCB-205 (0.828) PCB-183 [5.97] PCB-185 (0.948) J EMPC (0.643) EMPC PCB-174 J PCB-169 PCB-190 2.09 PCB-189 (0.723) J Conc. 75.4 Conc. 14 EMPC 86.9 EMPC 19.7 209 Congener PCB Summary Page 2 of 2 Conc. 0 EMPC 0 Deca Conc. PCB-209 12 Qualifiers Qualifiers 27 of 622 Sample ID: Method 1668A PB097_A-1SWMID-140314-N (TOTAL) Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 14-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 8.1 PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB 23.4 PCB-114 2344'5-PeCB EMPC PCB-118 23'44'5-PeCB 45.9 PCB-123 23'44'5'-PeCB EMPC PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB 3.58 PCB-167 23'44'55'-HxCB 1.16 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 0.96 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L A6506 11899 Qualifier J 0.718 1.5 J 1.16 J 0.633 JC J 0.435 0.489 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.00303 0.0413 0 0796 0.0796 0.00311 0.0414 0 0797 0.0797 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 13.7 159 768 1,090 450 127 17.4 4.67 ND 2.81 16.8 174 770 1,090 456 132 33.7 8.77 Total PCB (Mono-Deca) 2,630 Checkcode: 581-063-DWJ SGS Environmental Services - PCB 2014 Rev. 4.03 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 1.31 J 2,690 Date Received: A6506_11899_PCB_008 Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 15-Mar-2014 19-Mar-2014 27-Mar-2014 Recovery % 31.3 44.1 49.4 84.7 61.5 78.8 67.4 85.6 83.2 95.7 88 88 89.2 86.9 87.3 85.4 85 3 85.3 73.3 74.8 69 85.6 84.7 101 89.5 94.3 78.7 80.4 95.9 74.5 86.9 98.4 116 Report Created: 30-Mar-2014 14:31 Analyst: LB 28 of 622 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 14-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers PCB-1 12 PCB-2 1.76 J PCB-3 [3.04] J EMPC Aqueous Project No.: A6506 Date Received: 0.96 L Sample ID: A6506_11899_PCB_008 Date Extracted: 19-Mar-2014 11899 Date Analyzed: 27-Mar-2014 581-063-DWJ Time Analyzed: 7 Units Mono pg/L Tri Method 1668A Laboratory Data Conc. PCB-19 35.9 PCB-30/18 157 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. Qualifiers Tetra 15-Mar-2014 20:44:35 Conc. Qualifiers J PCB-54 1.37 J PCB-72 1.05 PCB-50/53 33.3 C PCB-68 16.7 PCB-17 76.1 PCB-45 24 PCB-57 (0.652) PCB-27 13.3 PCB-51 24.2 PCB-58 (0.637) Conc. 13.7 PCB-24 [1.95] PCB-46 12.6 PCB-67 [2.34] EMPC 16.8 PCB-16 49.7 PCB-52 186 PCB-63 5.02 J PCB-32 74.5 PCB-73 [0.711] PCB-61/70/74/76 142 C PCB-43 5.72 J PCB-66 88.3 PCB-69/49 104 C PCB-55 1.33 PCB-48 20.1 PCB-56 45.2 Di Conc. PCB-4 64.5 PCB-10 (1.83) PCB-9 2.34 PCB-7 1.52 Qualifiers J EMPC PCB-34 1.04 PCB-23 (0.828) J C J EMPC PCB-26/29 34.6 J PCB-25 42.9 PCB-44/47/65 168 C PCB-60 17.5 J PCB-31 99.7 PCB-59/62/75 11.7 JC PCB-80 (0.587) PCB-6 31.9 PCB-28/20 117 C PCB-42 41.2 PCB-5 (1.24) PCB-21/33 16.8 JC PCB-41 8.24 J PCB-71/40 68.8 C PCB 64 PCB-64 56 4 56.4 PCB-8 23.7 PCB-22 30.1 PCB 14 PCB-14 (1 04) (1.04) PCB 36 PCB-36 (0 801) (0.801) PCB-11 24.1 B PCB-39 (0.778) PCB-13/12 10.8 JC PCB-38 (0.87) PCB-15 [15.3] EMPC PCB-35 3.04 PCB-37 15.8 PCB-79 0.891 PCB-78 (0.723) PCB-81 (0.718) PCB 77 PCB-77 81 8.1 J EMPC J J J J Conc. 159 Conc. 768 Conc. 1,090 EMPC 174 EMPC 770 EMPC 1,090 Totals Conc. Mono-Tri 941 961 Tel: +1 910 794-1613 Tetra-Hexa 1,670 1,680 www.us.sgs.com Hepta-Deca 24.9 45.3 Mono-Deca 2,630 2,690 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 EMPC 29 of 622 Sample ID: Penta PCB-104 PB097_A-1SWMID-140314-N (TOTAL) Conc. Qualifiers (0.363) J EMPC Penta Conc. Qualifiers PCB-108/119/86/97/125/87 50.3 JC PCB-96 [1.56] PCB-103 (0.699) PCB-94 (0.833) PCB-110 73.9 PCB-95 56.5 PCB-115 2.25 PCB-100/93 1.51 JC PCB-82 12.5 J Hexa PCB-155 Method 1668A Conc. Qualifiers 0.64 J 3.48 J PCB-152 (0.284) PCB-146 4.65 JC PCB-150 (0.281) PCB-161 (0.308) PCB-136 4.17 J PCB-145 (0.3) PCB-141 4.67 J PCB-148 (0.388) PCB-130 [1.92] J EMPC PCB-111 (0.55) PCB-151/135 PCB-120 (0.541) PCB-154 (0.35) PCB-88 (0.836) PCB-107/124 2.47 JC PCB-144 [1.21] J EMPC PCB-91 14.1 PCB-109 4.45 J PCB-147/149 20.6 JBC PCB-123 [1.16] J EMPC PCB-134 2.34 J PCB-106 (0.615) PCB-143 (0.395) J EMPC PCB-121 (0.543) PCB-118 45.9 PCB-92 12.5 PCB-122 0.968 J PCB-113/90/101 59.8 C PCB-114 [1.5] J EMPC PCB-83 4.89 J PCB-105 23.4 PCB-133 PCB-99 37.1 PCB-127 (0.602) PCB-112 (0.566) PCB-126 (0.633) Hepta PCB-188 Conc. Qualifiers (0.335) PCB-171/173 PCB-183 [2.49] PCB-185 (0.599) JC PCB-159 (0.375) J PCB-162 (0.378) PCB-142 (0.471) PCB-167 1.16 J PCB-132 10.9 B PCB-156/157 3.58 JC 0.634 J PCB-169 [1.22] J EMPC C Conc. Qualifiers PCB-202 Octa [0.712] J EMPC (0.435) (0.432) PCB-207 (0.953) (0.464) PCB-206 (1.66) PCB-197 (0.433) (0.456) (0.637) PCB-200 (0.49) PCB-198/199 [3.38] J EMPC C PCB-196 1.11 J J JBC Conc. (0.961) PCB-201 PCB-172 8.74 Nona PCB-208 PCB-204 PCB-192 PCB-180/193 J EMPC 0.835 0.706 J EMPC J EMPC J EMPC PCB-139/140 PCB-131 J [0.581] [5.53] J JC Qualifiers PCB-176 (0.52) 3.04 5.02 4.48 [2.03] PCB-182 PCB-158 PCB-128/166 Conc. (0.578) PCB-187 (0.335) Hepta PCB-181 (0.572) C PCB-160 127 PCB-177 PCB-175 32.3 PCB-163/138/129 132 J J J J EMPC Conc. J EMPC 1.12 1.41 [1.79] EMPC 2.25 BC PCB-137 450 PCB-174 J PCB-164 456 [0.846] (0.398) 21 Conc. PCB-184 PCB-186 JC PCB-153/168 EMPC PCB-179 PCB-178 9.19 JB 3.59 25.9 Qualifiers 13.9 (0.911) [2.05] Conc. (0.333) PCB-117 PCB-102 PCB-84 PCB-165 PCB-116/85 PCB-98 PCB-89 Hexa PCB-191 (0.458) PCB-203 1.64 PCB-170 [3.63] J EMPC PCB-195 (0.73) PCB-190 0.829 J PCB-194 1.93 PCB-189 (0.489) PCB-205 (0.548) Conc. 17.4 Conc. 4.67 EMPC 33.7 EMPC 8.77 209 Congener PCB Summary Page 2 of 2 Conc. 0 EMPC 0 Deca Conc. Qualifiers 2.81 J PCB-209 J Qualifiers 30 of 622 Sample ID: Method 1668A Method Blank A6506 Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: n/a pH Conc. pg/L PCB-77 33'44'-TeCB ND PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB 1.06 PCB-114 2344'5-PeCB ND PCB-118 23'44'5-PeCB 2.29 PCB-123 23'44'5'-PeCB ND PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB ND PCB-167 23'44'55'-HxCB ND PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 1.00 L n/a DL pg/L 0.969 1.04 Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L J J 0.543 0.763 0.929 0.614 0.71 0.784 0.0001 0.0491 0 0982 0.0982 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB ND 9.36 6.48 9.73 16.7 11.5 1.57 ND ND ND Total PCB (Mono-Deca) 55.4 Checkcode: 733-035-NQY C 0.0001 0.0491 0 0982 0.0982 0.949 8.82 12.5 20.4 0.678 2.16 0.863 64.1 SGS Environmental Services - PCB 2014 Rev. 4.03 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11899 Qualifier 0.542 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6506 Date Received: MB1_11899_PCB_TLX Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 n/a 19-Mar-2014 27-Mar-2014 Recovery % 59.7 70.1 81 91.1 85.8 83.1 90.3 90.4 90 97.6 92.2 89.8 93.6 92.5 92.9 89.2 90 7 90.7 74.9 76.7 72.4 90.3 89.3 107 96.9 97.7 88.4 92.4 104 87.4 89.2 103 115 Report Created: 30-Mar-2014 14:28 Analyst: LB 31 of 622 Sample ID: Method Blank A6506 Client Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site n/a Date Collected: Mono Method 1668A Sample Data Conc. Laboratory Data Matrix: Weight/Volume: Aqueous Project No.: A6506 Date Received: n/a 1.00 L Sample ID: MB1_11899_PCB_TLX Date Extracted: 19-Mar-2014 11899 Date Analyzed: 27-Mar-2014 733-035-NQY Time Analyzed: pH n/a QC Batch No.: Units pg/L Checkcode: Qualifiers Tri PCB-1 (0.923) PCB-19 PCB-2 (0.822) PCB-30/18 PCB-3 (0.975) PCB-17 PCB-27 Conc. Qualifiers (1.59) Tetra Conc. PCB-54 (0.708) PCB-50/53 (0.752) (1.37) PCB-45 (1.01) PCB-51 (1.07) PCB-46 2.66 JC Qualifiers Tetra 13:23:08 Conc. PCB-72 (0.905) PCB-68 (0.854) (0.869) PCB-57 (0.949) (0.752) PCB-58 (0.927) (0.95) PCB-67 (0.893) PCB-63 (0.858) C Qualifiers Conc. 0 PCB-24 EMPC 0 PCB-16 (1.8) PCB-52 3.95 PCB-32 (0.957) PCB-73 (0.59) PCB-61/70/74/76 [2.76] J EMPC C PCB-34 (0.943) PCB-43 (0.902) PCB-66 1.4 J (2.09) PCB-23 (0.942) PCB-69/49 JC PCB-55 (0.994) PCB-10 (1.35) PCB-26/29 (0.933) PCB-9 (0.881) PCB-25 (0.937) PCB-7 (0.783) PCB-31 2.29 J PCB-6 (0.838) PCB-28/20 [2.34] J EMPC C PCB-5 (0.831) PCB-21/33 1.53 JC PCB-8 1.64 PCB 14 PCB-14 (0 699) (0.699) PCB-11 Di PCB-4 Conc. Qualifiers J PCB-22 (1) PCB 36 PCB-36 (0 912) (0.912) 7.71 JB PCB-39 (0.886) PCB-13/12 (0.813) C PCB-15 (0.874) PCB-38 (0.99) PCB-35 (1.04) PCB-37 (1.12) C 1.78 PCB-48 J PCB-56 (1) PCB-44/47/65 (0.767) 2.6 JC PCB-60 (0.993) PCB-59/62/75 (0.558) C PCB-80 (0.854) PCB-42 (0.837) PCB-79 (0.847) PCB-41 (0.953) PCB-78 (1.05) PCB-71/40 (0.748) PCB-81 (1.04) PCB 64 PCB-64 (0 528) (0.528) PCB 77 PCB-77 (0 969) (0.969) C Conc. 9.36 Conc. 6.48 Conc. 9.73 EMPC 9.36 EMPC 8.82 EMPC 12.5 Totals Conc. EMPC Mono-Tri 15.8 18.2 Tel: +1 910 794-1613 Tetra-Hexa 37.9 44.4 www.us.sgs.com Hepta-Deca 1.57 1.57 Mono-Deca 55.4 64.1 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 32 of 622 Sample ID: Penta PCB-104 Method Blank A6506 Conc. Qualifiers (0.473) Method 1668A Penta Conc. Qualifiers PCB-108/119/86/97/125/87 [2.7] J EMPC C PCB-155 PCB-152 (0.388) PCB-146 (0.57) 0.686 JC PCB-150 (0.382) PCB-161 (0.458) J (0.626) Hexa Conc. (0.34) PCB-96 (0.567) PCB-117 PCB-103 (0.695) PCB-116/85 PCB-94 (0.828) PCB-110 3.95 PCB-136 0.87 PCB-95 3.4 J PCB-115 (0.574) PCB-145 (0.408) PCB-100/93 (0.752) C PCB-82 (0.95) PCB-148 (0.577) PCB-102 (0.631) PCB-111 (0.546) PCB-151/135 (0.609) (0.538) PCB-98 (0.905) PCB-120 PCB-88 (0.831) PCB-107/124 (0.6) PCB-91 (0.719) PCB-109 (0.53) Hexa PCB-165 J PCB-153/168 PCB-141 C (0.706) (0.571) (0.47) (0.52) PCB-164 (0.588) PCB-163/138/129 3.22 JC 2.53 PCB-130 PCB-154 PCB-160 3.12 [0.983] PCB-123 (0.543) PCB-134 (0.824) PCB-158 (0.434) (0.861) PCB-106 (0.611) PCB-143 (0.588) PCB-128/166 (0.798) PCB-121 (0.54) PCB-118 2.29 PCB-139/140 (0.584) PCB-159 (0.665) PCB-92 (0.797) 3.6 PCB-83 (0.921) PCB-99 1.71 PCB-112 (0.562) Hepta PCB-188 Conc. (0.405) C PCB-122 (0.65) PCB-131 (0.69) PCB-162 (0.67) JC PCB-114 (0.542) PCB-142 (0.701) PCB-167 (0.614) PCB-105 1.06 PCB-156/157 (0.929) J PCB-127 (0.615) PCB-169 (0.71) PCB-126 (0.763) Qualifiers J PCB-132 1.79 PCB-133 (0.621) J Conc. 16.7 Conc. 11.5 EMPC 20.4 EMPC 11.5 Nona Conc. Hepta PCB-174 Conc. Qualifiers (0.948) Octa PCB-202 Conc. Qualifiers (0.626) PCB-208 PCB-179 (0.476) PCB-177 (0.984) PCB-201 (0.581) PCB-207 (1.63) (0.501) PCB-181 (0.871) PCB-204 (0.625) PCB-206 (2.67) PCB-176 (0.451) PCB-171/173 (0.984) PCB-197 (0.583) PCB-186 (0.482) PCB-172 (0.959) PCB-200 (0.614) PCB-178 (0.678) PCB-192 (0.738) PCB-198/199 (0.915) PCB-175 (0.862) PCB-180/193 PCB-196 (0.862) PCB-187 (0.81) PCB-191 (0.689) PCB-203 (0.854) PCB-182 (0.782) PCB-170 (0.941) PCB-195 (0.972) 1.57 JC PCB-183 (0.762) PCB-190 (0.687) PCB-194 (0.908) PCB-185 (0.901) PCB-189 (0.784) PCB-205 (0.73) Conc. 1.57 Conc. 0 EMPC 1.57 EMPC 0 209 Congener PCB Summary Page 2 of 2 C Conc. 0 EMPC 0 Deca PCB-209 JC C C Qualifiers (1.65) PCB-184 C JC (0.498) PCB-89 J Qualifiers (0.627) PCB-137 PCB-144 PCB-147/149 Conc. (0.496) PCB-84 PCB-113/90/101 J EMPC C Qualifiers Conc. (0.863) Qualifiers 33 of 622 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140327X02 Analysis Date: Lab ID: OPR1_11899_PCB NATIVE ANALYTES PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-104 22'466'-PeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-155 22'44'66'-HxCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-188 22'34'566'-HpCB PCB-189 233'44'55'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-206 22'33'44'55'6-NoCB PCB-208 22'33'455'66'-NoCB PCB-209 DeCB Processed: 30 Mar 2014 14:24 27-MAR-2014 11:32:47 SPIKE CONC. RECOVERY RANGE (%) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 115 114 94.1 108 95.1 111 95.8 98.5 101 96.1 93.8 97.1 95.4 95.3 107 92.1 97 97 97 92.3 104 94.9 98.1 97.8 98.8 96.2 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 Contract-required recovery limits for OPR as specified in Table 6, Method 1668A. Analyst: LB FORM 8A OK - 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 34 of 622 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140327X02 Analysis Date: Lab ID: OPR1_11899_PCB LABELED STANDARDS ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 FORM 8B 27-MAR-2014 11:32:47 SPIKE CONC. RECOVERY RANGE (%) 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 74.5 78.6 91.7 95.2 90.7 84.2 91.5 94.4 92.9 98.5 93.3 91.1 95.2 92.6 94.7 92.7 92.6 77.5 78.3 75.8 90.1 90.7 109 96.9 101 88 91.5 102 86.4 15 15 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 - 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 100 100 100 86.7 101 119 40 40 40 - 125 125 125 Y Y Y OK CLEANUP STANDARDS CS PCB-28 CS PCB-111 CS PCB-178 Processed: 30 Mar 2014 14:24 Analyst: LB 35 of 622 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: Amy Boehm 15-Mar-14 at 10:30 A6506 21 days 7-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com AP Smp ID Sample Condition & Notes Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Quantity Size Sampling Date Delaney Peterson ANCHOR QEA Partick Bayou Superfund Site N/A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Sampling Time Received Temp Container # PB070_B-2SWMID-140314-N (TOTAL) A6506_001 WS 2 1.25 L Amber 14-Mar-14 09:10 1.4 1, 2, 3 PB070_B-1SWMID-140314-N (TOTAL) A6506_002 WS 2 1.25 L Amber 14-Mar-14 13:15 1.4 1, 2, 3 PB079-1SWMID-140314-N (TOTAL) A6506_003 WS 2 1.25 L Amber 14-Mar-14 14:00 1.4 1, 2, 3 PB081_A-1SWMID-140314-N (TOTAL) A6506_004 WS 2 1.25 L Amber 14-Mar-14 15:05 1.4 1, 2, 3 PB081_A-1SWMID-140314-N (DISSOLVED) A6506_005 WS 2 1.25 L Amber 14-Mar-14 15:05 1.4 1, 2, 3 PB089-1SWMID-140314-N (TOTAL) A6506_006 WS 2 1.25 L Amber 14-Mar-14 17:25 1.4 1, 2, 3 PB085-1SWMID-140314-N (TOTAL) A6506_007 WS 2 1.25 L Amber 14-Mar-14 16:54 1.4 1, 2, 3 PB097_A-1SWMID-140314-N (TOTAL) A6506_008 WS 2 1.25 L Amber 14-Mar-14 17:54 1.4 1, 2, 3 PB097_A-1SWMID-140314-N (DISSOLVED) A6506_009 WS 2 1.25 L Amber 14-Mar-14 17:54 1.4 1, 2, 3 Preservation Type: Notes/Comments: Ice - Good Condition+Ice - Sample Seals: 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. Samples received intact Received by: Christina Newkirk Shipping # Logged in by: Christina Newkirk QC'ed by: AK 17 Mar 14 SGS Analytical Perspectives 36 of 622 MSW CHAIN OF CUSTODY CONVENTIONAL 81 SHALE PROJECT INFO: SEND DOCUMENTATION I RESULTS TO: SPECIAL PROJECT {6 IC 31100 TEMPANY ?nc?a/ 635/4 P.O CONTACT: 27? /a trl'UZo/l LOUOTE ADDRESS. 720 0 0% 3530 PRESERVATWE SITE REF PHONE 54%. 5% 00,4 ?55- TURN mg 5/ EMAIL: 20? 5 ?71'7/REPORT LEVEL. (see reverse) LI Level Level IlatEVel IV INVOICE I) atmf?g 69.65" a SPECIAL DELIVERABLES: State of Origin: COMPANY: CON-rpm ?g 5 ANALYSIS 3.355: Other: ADDRESS: [97) [fads/5' PHONE: Q/q .935: 0934/ Mu" TYPE M8 M80 DUP (0.6) . (a CONT. MATRIX QTY fig/,1? Ufa/I ramp)? 75$ - 79m nice-pf :u rn 2D :5 7: SAMPLE ID I DESCRIPTION DATE TIME 5 5 DAT RECEIVED BY: 3 PI loll? TIME: RELINOUISHED BY (2): DATE: RECEIVED BY: Page of SOS NORTH AMERICA INC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 910 350 1903 910 794 1613 I Member of the SGS Group (568 37 of 622 Project Initiation Form Project Number: A6506 Client Name: ANCHOR QEA 1668A Analysis Method: Initiation Date: Sample Matrix: TAT: Project Manager: 17-Mar-14 Aqueous 21 days Amy Special Instructions 1668A w/ OPR Dissolved samples need to be filtered before extraction Reporting Instructions 1668A w/ OPR Anchor Equis EDD PM Initials: akornega Date: 17-Mar-2014 38 of 622 Prep Sheet IL.-\ II~_ TRAN~FER: J/v/~ I 1\6506 I'rojeclll 113aleh II 11899 I Extract Init!Dale: \-\.'l. ~\\q I Water 1668'\ I I ll.4 11...1 II U Transler Init/DataJ"O I i\ I' Sample I () Client Volume Sample 111 (mI.) ~\ ~ '5 - I'H070_B-ISWMID-14OJ 14-N (TOTAL) ~I.-\~ ~ - (TOTAL) 1'1l081_A-ISWMIIJ-140J 14-N (TOTAL) I'B081_A-ISWMIIl.140J14.N(DISSOI.VFDI ~~o 1 ~ (TOTAL) 0\ ~D ~ I'B08S-1 SWMID-140314-N (TOTAL) ~VS ~ I'B097_A-ISWMID-140J14-N(lJISSOI.VI'D) 1899 l\l,~ ~5S s- I'B089-ISWM([)-140314-N I'B097_A-ISWMIIJ-140J 14-N (TOTAL) OI'RU S()S /I 1'1l070_1l-2SWMID-140J14-N (TOTAL) I'B079-1 SWMID-140314-N MBI_11899 Talex /I Method q (,0- '\~'8 \OO{) Blank \OOD 0- 1 1899_01'ROOI -- •.•... ...- ,~ , La ./ I).. - RV /I o/B - 0-:> l 7'B 7- '11/3 - O-J '2.. I 1.- , L '2.- - I 1668A wi OI'R Dissolved samples need to he liltered hdclre extraction ()-) ~ I i~ 1b - l 2- o--J ~B vp~ - m 7B - 113 - 11:5 Ohsen'ations \It,~~\ ()O\ s:-u- Cot I ~JL ~ Start: <;JU..... ~OOS ~~~ ~ 1:- \\eD -co..,\.L\-: ~ •• SUllllly - Toluene 'S'$ ~""" - Sand Ilexane Silica Stop: -r.. \\-vO 3\-U 11'1 \0 : \'1 0.-...\ ~ I 00 \ OO?- - Florisil Start: I ..) \ 00 2- CII2C1'2 Stop: c.\ ( Cyclc Timc Instructions: S\~ \t\-~ C\o ~j" ,,~\\.ow', S ~ cY 0-J , OIM k- 'i.U- r \~ \~~\~w'\S\.J\\b..{.\-\~ dov-!~ , CY o-J YJ .•.•... 51-loiN Sllccial ('lean-up (Td) Initials II>s Acid Silica IlydroMatrix Tetradecane ~ --" 0'"2,\'-\.1.0 \U Base Silica K Silicate - -- 39 of 622 1668A A6506 Project # Batch # 11899 Inter-Department Communication Sheet 005 o.~ Oe)'\ ~~~ ,/ Special Instructions 1668A wi OPR Dissolved samples need to be filtered before extraction Aqueous 40 of 622 TSS % TSS Determination WorkSheet ...Ili!Oii ~ Tan: Balance I' rueed II rcs: Add boat & 0.45 lun IiIter and weigh. Record "Iloa! WI." Place filter in glass filling funnel Filler 10 mL or aqueous sample through IiIll:!' into a waste jar Rinse filter with 20 mi. or \)1 water Dry in oven overnight@ 107 C Return dish to top loader and record "Dry WI." A6506 Project: Chcmist: 11899 Batch: AI' Sample III lluatWT. Prep Date: l>ry WT. 'Y"TSS Inil/l)atc tJJL icilit n\\ c.\" 0 n.l 'b \.1~ L(q, \,IC\ f),1 ( A6506_11899_003 \'1' \'l\ 0 1 0 A6506 _11899_004 \."1\ 1,lt () "1 0 A6506_11899_005 \.\q \JL. Amount: Amount: ~(.. Observer Initials Observer Initials 1(:1 AX 209 PCB ES ~D-'llJ CS Amount: lDv'L Observer Initials " •• \ '.Zl.Il{ PCB.IS ,0 I\mount: iAL Observer Initials 1\6506 - 11899001 P13070_13-2SWMID-140314-N tTOTAL) ~'L --. 1\6506 - 11899 002 1'8070_13-1 SWMID-140314-N (TOTAL) \'l\'t 1\6506 - 11899 003 PH079-ISWMID-140314-N (TOTAL) ~~ - 1\6506 - 11899 004 P8081_A-ISWMID-140314-N (TOTAL) V\'<- - G--J OJ 1\6506 - 11899 005 1'1l081_A-ISWMID-14OJ \\'L - C)-J 1\6506 - 11899 006 PIl089-! SWMID-140314-N (TOTAL) ~~ - o-J et-J A6506 - 11899 007 PIl085-1SWMID-140314-N (TOTAL) ~'\.- oJ C\-' PB097_A-1SWMID-140314-N (TOTAL.) ~X- 1\6506 - 11899008 1\6506 - 11899 009 MBI OPRI - 11899 1'1l097 .A-ISWMID-14OJ Method 14-N (DISSOLVED) 14-N (DISSOLVED) Blank 0 - I 1899 OPROO 1 - 11899 ~'(" - ~~ - Standard Std. Type Spike ID lo1,.."'t"UJ\>~ \1-%-\ Concentration Units Exp. Date Spike amount (~I.) ~- 1\Lrt\t~ PCB ES ~ ~ ~ CA-' ...If ~ Cl-" 00 et-> 0\lOh4, ~1.1..\/1U Information AX 209 \ \)1..S\. "LO \ "" \1-"\~-\ 100 50 lW.li.tL .pg/uL \1.-\\'\ ,,~ \oT')..'1rt 20 ~ rAJ ~¥- ~~ ~\t,llt{ SIL# r~ - Observer Initials etJ ~ - I\mount: 20 PCB CS/SS PCB ,IS 11)(..c\1D\"'~ lDZ.q 1.()\" "~;;a-f&V •.•.. ~ 100 pg /~tL \1...-\"-IU 20 r~ '- (\ t:> •-l'~;:. 200 pg/uL 10-1 ~-\L1 10 Final Solvcnt 42 of 622 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: Amy Boehm 15-Mar-14 at 10:30 A6506 21 days 7-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com AP Smp ID Sample Condition & Notes Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Quantity Size Sampling Date Delaney Peterson ANCHOR QEA Partick Bayou Superfund Site N/A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Sampling Time Received Temp Container # PB070_B-2SWMID-140314-N (TOTAL) A6506_001 WS 2 1.25 L Amber 14-Mar-14 09:10 1.4 1, 2, 3 PB070_B-1SWMID-140314-N (TOTAL) A6506_002 WS 2 1.25 L Amber 14-Mar-14 13:15 1.4 1, 2, 3 PB079-1SWMID-140314-N (TOTAL) A6506_003 WS 2 1.25 L Amber 14-Mar-14 14:00 1.4 1, 2, 3 PB081_A-1SWMID-140314-N (TOTAL) A6506_004 WS 2 1.25 L Amber 14-Mar-14 15:05 1.4 1, 2, 3 PB081_A-1SWMID-140314-N (DISSOLVED) A6506_005 WS 2 1.25 L Amber 14-Mar-14 15:05 1.4 1, 2, 3 PB089-1SWMID-140314-N (TOTAL) A6506_006 WS 2 1.25 L Amber 14-Mar-14 17:25 1.4 1, 2, 3 PB085-1SWMID-140314-N (TOTAL) A6506_007 WS 2 1.25 L Amber 14-Mar-14 16:54 1.4 1, 2, 3 PB097_A-1SWMID-140314-N (TOTAL) A6506_008 WS 2 1.25 L Amber 14-Mar-14 17:54 1.4 1, 2, 3 PB097_A-1SWMID-140314-N (DISSOLVED) A6506_009 WS 2 1.25 L Amber 14-Mar-14 17:54 1.4 1, 2, 3 Preservation Type: Notes/Comments: Ice - Good Condition+Ice - Sample Seals: 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 798228909281, 798228909270, 875887997273 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. Samples received intact Received by: Christina Newkirk Shipping # Logged in by: Christina Newkirk QC'ed by: AK 17 Mar 14 SGS Analytical Perspectives ,. 43 of 622 I CONVENTIONAL CHAIN OF CUSTODY 12 PROJECT INFO: P4 of I~ f' t"" k. ~"V SPECIAL INSTRUCTIONS / COMMENTS: SEND DOCUMENTATION / RE~LTS TO: PO.#: AF"lt;ho/ QI="A CONTACT:])t:!:.-/er"etf 1Jt:!lcrsol1 QUOTE #. ADDRESS: PROJECT: r )G 62 f:J'1-0). 0 SITE REF:CJt.{ TURN AROUNDTIME: :;)Vpd~~ J.~MPANY: B 5+-e-. ctJ 120 0 f.~ $k 300 t."\1 •••• ~ ~ 1\ II t. 1\1/ '.1' L I \ e:t \~ \ \ \ I \ I I' fl 1A7';- 111411"1 IC,!>-4 \ ~~ ~ \J v,\j \.: L'S MATRIX ?1A.h tf- tJ 7,J/"1'''' 1"J1_<' -i403.J'f \ \ 5UHI S w q \ il ,\ II I II I II II \ \ /" ~~SHED TIME: BY (1): 'Of If? "/S:~~!~~ RELINQUISHEDBY (2): pageLOf~ MS U' Pf3b7J'1-lSWIYIIO-j'-((/'lJ'i-;J ott¥) TIME 1'100 -;N z.lll.IJ14 130 b Q;Q-43s ---~'1:5~1 bob o e/;)r;P'1 r"c!-ne..v(ct>..h, D- PBo~S--/ j/.,UWlI ~~ f:'/l/ ~IA.JJ~ (. ~1C4J411)5 PBb1-q-J~WIVJJn-JqtJ3J'f-AJ -i PRESERVATIVE ~ CONTACT: • SAMPLE ID / DESCRIPTION Ii") I INVOlCE~iS~~ff~l'lc-hb./'~e:o..~G"'1 DLevelll~ellV - I S'~i&<~ o Level I i~ ~ PHONE: REPORTLEVEL:(seereverse) J7Mf.)J_ IJ- & SHALE DATE: TIME: RECEIVEDBY: SGS NORTH AMERICA INC. ~NVIRONMENTAl SERVICES 5500 Business Drive Wilmington, NC 28405 910350 1903 1910794 1613 Member www.sgs.com of the SGS GrouP ISGS SAl 44 of 622 SGS Analytical Perspectives — Run Log Project: A6506_11899_PCB Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Wt/Vol Client/Sample ID Analyst(s) Datafile Vial# Lab ID Checkcode Acq Date Acq Time 1 140327X01 Tray1:03 CS3_140327_PCB_XA 1.00 SIL 13-79-3 LKB 702-497 27-Mar-2014 10:37:58 2 140327X02 Tray1:47 OPR1_11899_PCB 1.00 0_11899_OPR001 LKB 756-952 27-Mar-2014 11:32:47 3 140327X03 Tray1:02 SBS_140327_PCB_XA 1.00 SIL 13-42-1 LKB 169-929 27-Mar-2014 12:27:58 4 140327X04 Tray1:48 MB1_11899_PCB_TLX 1.00 Method Blank LKB 733-035 27-Mar-2014 13:23:08 5 140327X05 Tray1:49 A6506_11899_PCB_001 0.92 PB070_B-2SWMID-140314-N (TOTAL) LKB 561-113 27-Mar-2014 14:18:19 6 140327X06 Tray1:50 A6506_11899_PCB_002 0.94 PB070_B-1SWMID-140314-N (TOTAL) LKB 505-842 27-Mar-2014 15:13:30 7 140327X07 Tray1:51 A6506_11899_PCB_003 0.96 PB079-1SWMID-140314-N (TOTAL) LKB 109-950 27-Mar-2014 16:08:42 8 140327X08 Tray1:52 A6506_11899_PCB_004 0.96 PB081_A-1SWMID-140314-N (TOTAL) LKB 761-905 27-Mar-2014 17:03:52 9 140327X09 Tray1:53 A6506_11899_PCB_005 0.93 PB081_A-1SWMID-140314-N (DISSOLVED) LKB 223-376 27-Mar-2014 17:59:02 10 140327X10 Tray1:54 A6506_11899_PCB_006 0.96 PB089-1SWMID-140314-N (TOTAL) LKB 431-600 27-Mar-2014 18:54:13 11 140327X11 Tray1:55 A6506_11899_PCB_007 0.97 PB085-1SWMID-140314-N (TOTAL) LKB 507-769 27-Mar-2014 19:49:23 12 140327X12 Tray1:56 A6506_11899_PCB_008 0.96 PB097_A-1SWMID-140314-N (TOTAL) LKB 581-063 27-Mar-2014 20:44:35 Project file: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB.utp_prj, saved 30-Mar-2014 14:51 AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 Printed: 30-Mar-2014 14:51 45 of 622 Lab ID: MB1_11899_PCB_TLX ACQ: 27-Mar-2014 13:23:08 LKB Wt/Vol: 1.00 L Client ID: Method Blank A6506 UTP: 30-Mar-2014 14:25 LKB J-level: 10 pg/L Datafile: 140327X04 RPT: 30-Mar-2014 14:28 LB Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services Actual RT NotFnd NotFnd 35.78 NotFnd 34.77 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 11.88 14.17 14.42 20.13 17.50 26.45 20.41 32.78 32.30 25.38 35.76 35.21 34.75 34.47 38.37 36.33 30.33 40.91 39.93 43.63 43.14 42.07 35.21 45.75 39.74 47.91 49.37 45.36 50.81 QC J J C Pred RRT Actual RRT 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0008 1.0007 - 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7245 0.8641 0.8794 1.2276 1.0673 1.0790 0.8326 1.3371 1.3176 0.8322 1.1724 1.1546 1.1394 1.1302 1.2579 0.9716 0.8111 1.0941 1.0678 1.1666 0.9080 0.8855 0.7410 0.9629 0.8364 1.0084 1.0392 0.9548 1.0694 Diff Secs +0.4 +0.2 0 +0.1 -0.1 +0.6 0 +0.5 -0.2 +1.4 +1.2 -0.5 +0.9 +0.6 +0.6 +0.6 +0.9 0 -0.5 +0.5 +0.2 +0.5 -0.3 -0.3 -0.6 0 -0.5 0 0 -0.3 0 Page 1 of 5 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Split: 1 Response 0.00E+00 0.00E+00 3.34E+04 0.00E+00 7.55E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.98E+07 7.46E+07 4.15E+07 9.29E+07 4.25E+07 7.36E+07 4.14E+07 6.67E+07 6.55E+07 4.02E+07 5.67E+07 5.60E+07 5.56E+07 5.62E+07 4.89E+07 4.02E+07 5.76E+07 9.58E+07 5.12E+07 4.50E+07 3.01E+07 3.59E+07 4.03E+07 4.41E+07 3.79E+07 3.16E+07 2.20E+07 3.50E+07 2.79E+07 Checkcode: 733-035-NQY Ra 0.58 0.69 3.24 3.28 1.59 1.57 1.05 1.11 0.76 0.80 0.78 1.56 1.62 1.60 1.58 1.59 1.56 1.31 1.30 1.27 1.27 1.29 1.08 1.05 1.07 1.06 0.93 0.88 0.80 0.79 1.18 Method 1668A RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ND ND 1.06 ND 2.29 ND ND ND ND ND ND ND 3.66E+03 3.66E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 2.05E+03 1.77E+03 1.77E+03 1.77E+03 1.78E+03 1.19E+03 0.969 1.04 0.6 0.542 0.567 0.543 0.763 0.929 0.614 0.71 0.784 0.863 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 59.7 % 70.1 % 81 % 91.1 % 85.8 % 83.1 % 90.3 % 90.4 % 90 % 97.6 % 92.2 % 89.8 % 93.6 % 92.5 % 92.9 % 89.2 % 90.7 % 74.9 % 76.7 % 72.4 % 90.3 % 89.3 % 107 % 96.9 % 97.7 % 88.4 % 92.4 % 104 % 87.4 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Printed: 3/30/2014 2:32 PM 46 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.89 32.79 37.77 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 8.77E+07 6.45E+07 2.68E+07 1.09 1.60 1.06 1.11 1.03 0.62 107 % 111 % 108 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.89 32.79 37.77 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 8.77E+07 6.45E+07 2.68E+07 1.09 1.60 1.06 1.85 1.22 0.58 89.2 % 103 % 115 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.39 24.51 30.50 37.40 47.51 9.80E+07 5.33E+07 5.12E+07 4.00E+07 2.87E+07 1.57 0.79 1.59 1.30 0.90 4.90E+03 4.90E+03 4.90E+03 7.16E+03 7.16E+03 4.54E+03 4.54E+03 4.54E+03 4.54E+03 4.54E+03 4.54E+03 4.54E+03 4.54E+03 4.54E+03 4.63E+03 4.63E+03 4.63E+03 4.63E+03 4.63E+03 4.63E+03 4.63E+03 0.923 0.822 0.975 2.09 1.35 0.881 0.783 0.838 0.831 0.81 0.699 0.81 0.813 0.874 1.59 1.19 1.37 1.01 1.07 1.8 0.957 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 17.23 NotFnd 19.57 NotFnd NotFnd NotFnd 19.28 NotFnd NotFnd NotFnd NotFnd NotFnd J J B C J C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0511 0.9721 1.1020 - +0.5 0 +0.7 Page 2 of 5 Noise / Recv. Low DL / Recv. High EMPC 0 9.36 8.82 12.5 20.4 11.5 1.57 0 0 NON-EMPC 0 9.36 6.48 9.73 16.7 11.5 1.57 0 0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 8.39E+04 0.00E+00 3.94E+05 0.00E+00 0.00E+00 0.00E+00 8.67E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 RRF Conc. / Recv. SI SI 1.14 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 0.949 1.48 1.35 0.85 0.581 0.648 0.753 0.678 2.16 ND ND ND ND ND ND ND ND ND 1.64 ND 7.71 ND ND ND 2.66 ND ND ND ND ND Printed: 3/30/2014 2:32 PM 47 of 622 Name PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB SGS Evironmental Services Actual RT NotFnd NotFnd NotFnd NotFnd 22.64 22.91 23.13 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 24.54 NotFnd NotFnd 24.98 NotFnd 25.43 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 28.75 29.02 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 27.99 QC C J J EMPC C J C C J J C J C C C J EMPC C J J Pred RRT Actual RRT 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8560 0.8663 0.8745 1.0010 1.0189 1.0374 0.8903 0.8985 0.9176 Diff Secs -0.3 -1.0 +1.0 +0.1 +1.2 -1.5 +0.2 -0.7 0 Page 3 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.14E+05 1.08E+05 7.24E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.16E+05 0.00E+00 0.00E+00 6.40E+04 0.00E+00 8.22E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.13E+05 5.36E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 8.25E+04 Ra 1.19 0.80 1.04 0.79 0.75 0.67 0.90 0.89 0.54 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 ND ND ND ND 2.29 2.34 1.53 ND ND ND ND ND ND ND ND ND ND ND 3.95 ND ND 1.78 ND 2.6 ND ND ND ND ND ND ND ND ND ND ND 2.76 1.4 ND ND ND ND ND ND ND ND ND ND 3.4 4.65E+03 4.65E+03 4.65E+03 4.65E+03 4.65E+03 4.65E+03 4.65E+03 4.65E+03 4.65E+03 4.65E+03 4.65E+03 4.65E+03 4.65E+03 2.28E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 2.18E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 3.66E+03 1.41E+03 1.41E+03 1.83E+03 1.83E+03 1.83E+03 0.943 0.942 0.933 0.937 0.895 0.96 0.934 1 0.912 0.886 0.99 1.04 1.12 0.708 0.752 0.869 0.752 0.95 0.778 0.59 0.902 0.633 0.767 0.721 0.558 0.837 0.953 0.748 0.528 0.905 0.854 0.949 0.927 0.893 0.858 0.939 1 0.994 1 0.993 0.854 0.847 1.05 0.473 0.567 0.695 0.828 0.761 Printed: 3/30/2014 2:32 PM 48 of 622 Name PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB SGS Evironmental Services Actual RT NotFnd NotFnd NotFnd NotFnd NotFnd 28.94 NotFnd NotFnd NotFnd 30.52 NotFnd 31.03 NotFnd 31.50 NotFnd 32.08 32.22 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.96 NotFnd NotFnd NotFnd NotFnd NotFnd 33.79 NotFnd NotFnd NotFnd NotFnd NotFnd 34.88 NotFnd NotFnd NotFnd NotFnd 36.35 NotFnd QC C J EMPC J C J J EMPC C J C J C J C J C C J J C Pred RRT Actual RRT 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9488 1.0006 1.0173 1.0330 1.0519 1.0564 1.0207 1.1142 1.1499 0.9720 - Diff Secs +0.2 +1.3 0 +1.9 -1.2 +0.6 0 +0.2 +1.0 -1.7 Page 4 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.00E+04 0.00E+00 0.00E+00 0.00E+00 9.93E+04 0.00E+00 4.36E+04 0.00E+00 7.55E+04 0.00E+00 1.90E+04 1.24E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.57E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.15E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.50E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.06E+04 0.00E+00 Ra 1.02 0.63 0.55 0.74 0.63 0.64 1.12 1.23 1.18 1.27 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 ND ND ND ND ND 0.983 ND ND ND 3.6 ND 1.71 ND 2.7 ND 0.686 3.95 ND ND ND ND ND ND ND ND ND ND ND ND 0.87 ND ND ND ND ND 3.22 ND ND ND ND ND 1.79 ND ND ND ND 2.53 ND 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.83E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 0.752 0.631 0.905 0.831 0.719 0.91 0.861 0.54 0.797 0.67 0.921 0.725 0.562 0.66 0.626 0.669 0.59 0.574 0.95 0.546 0.538 0.6 0.53 0.611 0.65 0.615 0.34 0.388 0.382 0.418 0.408 0.577 0.609 0.52 0.588 0.587 0.824 0.588 0.584 0.69 0.701 0.669 0.621 0.496 0.57 0.458 0.467 0.627 Printed: 3/30/2014 2:32 PM 49 of 622 Name PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB SGS Evironmental Services Actual RT NotFnd NotFnd NotFnd 37.42 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 42.09 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd QC J C C C J C C Pred RRT Actual RRT 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 1.0006 0.9199 - Diff Secs -1.1 +1.3 Page 5 of 5 Response 0.00E+00 0.00E+00 0.00E+00 6.97E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.51E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.41 0.99 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 ND ND ND 3.12 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.57 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.77E+03 1.77E+03 1.77E+03 9.99E+02 9.99E+02 9.99E+02 9.99E+02 9.99E+02 9.99E+02 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.16E+03 1.16E+03 1.16E+03 3.07E+03 3.07E+03 3.07E+03 0.706 0.571 0.47 0.584 0.498 0.434 0.798 0.665 0.67 0.405 0.476 0.501 0.451 0.482 0.678 0.862 0.81 0.782 0.762 0.901 0.948 0.984 0.871 0.984 0.959 0.738 0.75 0.689 0.941 0.687 0.626 0.581 0.625 0.583 0.614 0.915 0.862 0.854 0.972 0.908 0.73 1.65 1.63 2.67 Printed: 3/30/2014 2:32 PM 50 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.42e7 2.21e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.19e7 5.94e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.02e7 5.09e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 1.77e7 8.85e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.03e7 5.15e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.17e6 1.09e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.93e6 9.63e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 733-035 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:43 Page 1 of 21 51 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 1.12e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 2.53e3 5.58e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.27e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 2.37e3 6.36e3 0% 11.0 12.0 13.0 ES-1 5.33e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 5.72e7 14.17 0.00e0 16.0 RT Abs. Int. 2.13e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 2.64e3 1.06e7 0% 11.0 12.0 13.0 ES-1 1.65e7 11.88 Rel. Int. 100% 14.0 15.0 0.00e0 16.0 RT Abs. Int. 6.69e6 ES-3 1.74e7 14.17 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.59e4 3.35e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.42e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.21e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3548, 2246 scc: 733-035 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 2 of 21 52 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 8.74e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 4.36e3 4.37e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.95e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 1.09e4 1.48e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.55e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.55e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 5.62e3 4.28e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.60e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.42e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 2.56e3 2.71e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.42e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.21e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8522, 9384 scc: 733-035 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:44 (LKB) Printed: 30-Mar-2014 14:44 Page 3 of 21 53 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 PCB-11 2.40e5 SI 19.57 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 2.77e3 Abs. Int. 7.19e4 3.59e4 PCB-8 5.12e4 SI 17.23 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 6.12e4 PFK INTERFERENCE DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PB 4σ 1.72e4 3.06e4 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 5.99e7 16.39 20.0 21.0 0.00e0 RT Abs. Int. 1.81e7 ES-15 5.68e7 20.13 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.26e4 9.07e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 3.81e7 16.39 20.0 21.0 Abs. Int. 1.20e7 ES-15 3.61e7 20.13 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.20e3 0.00e0 RT 6.01e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.19e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 5.94e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6101, 8652 scc: 733-035 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 4 of 21 54 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 30/18 4.62e4 19.28 Rel. Int. 100% Abs. Int. 1.79e4 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.08e3 8.95e3 0% 17.0 18.0 19.0 20.0 21.0 30/18 4.05e4 19.28 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e4 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.55e3 5.84e3 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.18e7 17.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.59e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 3.73e4 3.30e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.07e7 17.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.20e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.10e4 3.10e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.19e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 5.94e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7308, 6824 scc: 733-035 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 5 of 21 55 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 PCB-31 6.18e4 22.64 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Abs. Int. 1.85e4 28/20 5.51e4 22.91 TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 2.69e3 21/33 3.69e4 23.13 9.25e3 0% 22.0 Rel. Int. 100% 23.0 PCB-31 5.17e4 22.64 TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 1.96e3 24.0 25.0 0.00e0 RT 26.0 28/20 6.87e4 22.91 Abs. Int. 1.81e4 21/33 3.55e4 23.13 9.06e3 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 4.58e7 22.89 Rel. Int. 100% ES-37 3.88e7 26.45 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.94e4 Abs. Int. 1.24e7 6.22e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 4.19e7 22.89 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.48e7 26.45 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.71e4 Abs. Int. 1.14e7 5.68e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.09e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4057, 1406 scc: 733-035 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 6 of 21 56 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 3.19e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 1.15e3 1.60e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.24e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 1.14e3 2.12e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.79e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.16e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 5.70e3 2.58e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.35e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.69e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 4.50e3 3.34e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.19e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 5.94e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5234, 2325 scc: 733-035 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 7 of 21 57 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Rel. Int. 100% PCB-52 5.10e4 24.54 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 8.29e2 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Abs. Int. 1.53e4 69/49 2.75e4 24.98 44/47… 3.28e4 25.43 7.67e3 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 6.48e4 24.54 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.35e3 26.0 Abs. Int. 2.11e4 69/49 3.65e4 24.98 44/47… 4.94e4 25.43 1.05e4 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.36e7 24.51 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 6.19e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 9.59e3 3.10e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.97e7 24.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.85e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 7.57e3 3.93e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.09e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7491, 2552 scc: 733-035 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 8 of 21 58 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Abs. Int. 1.36e4 61/70... 5.70e4 28.75 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.43e3 PCB-66 2.52e4 29.02 6.81e3 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 1.57e4 61/70... 6.32e4 28.75 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.23e3 PCB-66 2.84e4 29.03 7.84e3 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.88e7 32.30 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.36e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.28e6 ES-77 2.96e7 32.78 3.64e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.67e7 32.30 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.02e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 9.49e6 ES-77 3.71e7 32.78 4.75e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.77e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.85e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2971, 2893 scc: 733-035 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 9 of 21 59 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 2.69e3 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PB 4σ 6.66e2 1.34e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.69e3 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PB 4σ 7.42e2 1.34e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.45e7 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.33e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 2.07e3 3.16e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.57e7 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.06e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.51e3 2.03e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.09e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2709, 0913 scc: 733-035 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:43 (LKB) Printed: 30-Mar-2014 14:44 Page 10 of 21 60 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 7.69e2 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 113/90… 3.85e4 30.52 PCB-95 2.89e4 27.99 PCB-84 1.26e4 28.94 PCB-110 4.85e4 32.22 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 PCB-118 3.09e4 34.77 108/119... PCB-99 3.43e4 1.55e4 31.50 116/85 31.03 7.32e3 32.08 Abs. Int. 1.31e4 PCB-105 1.22e4 35.78 6.55e3 0% 28.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.06e3 30.0 PCB-95 5.37e4 27.98 32.0 113/90… 6.07e4 30.52 PCB-84 1.23e4 28.93 34.0 36.0 38.0 Abs. Int. 2.47e4 PCB-110 7.54e4 32.22 PCB-118 4.46e4 34.77 PCB-99108/119... 2.82e4 4.66e4 31.03 31.50 116/85 1.16e4 32.08 PCB-105 2.11e4 35.77 1.23e4 0% 28.0 30.0 Rel. Int. 100% PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.18e3 32.0 (3.51e7 + 2.17e7) * 2000 pg * 100 % (3.14e7 + 1.98e7) * 2000 pg * 1.20 LKB 30-Mar-2014 14:38 Recv(ES-105) = 34.0 CS/SS-111 3.97e7 32.79 JS-101 3.14e7 30.50 36.0 ES-118 ES-114 ES-123 3.40e7 3.45e7 3.45e7 34.75 35.21 34.47 38.0 5.00e6 = 92.4 % 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 2.48e7 32.79 JS-101 1.98e7 30.50 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.02e3 0.00e0 RT Abs. Int. 9.99e6 ES-105 3.51e7 35.76 0% 28.0 0.00e0 RT ES-123 2.17e7 34.47 36.0 ES-118 ES-114 2.15e7 2.16e7 34.75 35.21 38.0 0.00e0 RT Abs. Int. 6.38e6 ES-105 2.17e7 35.76 3.19e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.77e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.85e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9863, 1553 scc: 733-035 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 11 of 21 61 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 1.69e4 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 8.84e2 8.44e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 2.35e4 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.17e3 1.18e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.41e6 ES-126 2.98e7 38.37 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 5.05e3 3.70e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.57e6 ES-126 1.91e7 38.37 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 3.65e3 2.28e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.15e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2369, 0187 scc: 733-035 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 12 of 21 62 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 147/149 3.94e4 33.79 Rel. Int. 100% HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.85e2 PCB-132 1.89e4 34.88 PCB-136 1.36e4 30.96 153/168 3.96e4 36.35 Abs. Int. 1.36e4 163/138… 4.08e4 37.42 6.80e3 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 36.0 153/168 3.10e4 36.35 147/149 3.21e4 33.79 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 5.83e2 38.0 163/138… 2.89e4 37.42 Abs. Int. 1.07e4 PCB-132 1.61e4 34.87 PCB-136 1.21e4 30.96 5.36e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.26e7 30.33 Rel. Int. 100% ES-153 2.28e7 36.33 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.58e3 0.00e0 RT 0.00e0 RT Abs. Int. 8.36e6 JS-138 2.26e7 37.40 4.18e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 2.51e7 30.33 Rel. Int. 100% ES-153 1.74e7 36.33 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.31e3 0.00e0 RT Abs. Int. 6.40e6 JS-138 1.74e7 37.40 3.20e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.77e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.85e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0314, 4903 scc: 733-035 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 13 of 21 63 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 3.64e3 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PB 4σ 7.70e2 1.82e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.09e3 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PB 4σ 9.96e2 1.54e3 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.86e7 39.93 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 7.07e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 5.36e7 40.91 0.00e0 RT Abs. Int. 9.70e6 ES-169 2.54e7 43.63 4.85e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.26e7 39.93 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 4.38e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.22e7 40.91 0.00e0 RT Abs. Int. 7.53e6 ES-169 1.97e7 43.63 3.77e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.15e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3992, 8879 scc: 733-035 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 14 of 21 64 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 4.30e3 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PB 4σ 4.96e2 2.15e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.46e3 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PB 4σ 5.03e2 1.73e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.08e7 35.21 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.02e6 CS/SS-178 1.38e7 37.77 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.08e3 2.51e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.95e7 35.21 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.63e6 CS/SS-178 1.30e7 37.77 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.23e3 2.32e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.77e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 8.84e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5853, 1962 scc: 733-035 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 15 of 21 65 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 180/193 1.75e4 42.09 Rel. Int. 100% Abs. Int. 5.44e3 HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 9.02e2 2.72e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 180/193 1.76e4 42.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.18e3 HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 6.70e2 2.09e3 0% 39.0 40.0 41.0 42.0 ES-180 1.84e7 42.07 Rel. Int. 100% 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.33e6 ES-170 1.56e7 43.14 HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.34e3 2.17e6 0% 39.0 40.0 41.0 42.0 ES-180 1.75e7 42.07 Rel. Int. 100% 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.04e6 ES-170 1.45e7 43.14 HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 3.79e3 2.02e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.15e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0776, 6917 scc: 733-035 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 14:25 (LKB) Printed: 30-Mar-2014 14:44 Page 16 of 21 66 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 1.78e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 8.36e2 8.92e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 1.56e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 9.48e2 7.79e2 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 2.27e7 45.75 0.00e0 RT Abs. Int. 5.45e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.02e3 2.73e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 2.14e7 45.75 0.00e0 RT Abs. Int. 5.10e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 3.92e3 2.55e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.09e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3022, 5375 scc: 733-035 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 17 of 21 67 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 1.89e3 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PB 4σ 6.25e2 9.46e2 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e3 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PB 4σ 5.71e2 1.25e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.82e7 39.74 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.37e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.29e3 2.18e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.96e7 39.74 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.74e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.52e3 2.37e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.15e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2899, 5687 scc: 733-035 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 18 of 21 68 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 2.67e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PB 4σ 6.41e2 1.33e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PB 4σ 5.16e2 6.47e2 0% 46.0 47.0 48.0 JS-194 1.36e7 47.51 Rel. Int. 100% 49.0 50.0 ES-205 1.48e7 47.91 0.00e0 RT Abs. Int. 3.50e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 3.61e3 1.75e6 0% 46.0 47.0 48.0 JS-194 1.51e7 47.51 Rel. Int. 100% 49.0 50.0 ES-205 1.68e7 47.91 0.00e0 RT Abs. Int. 4.04e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.97e3 2.02e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.09e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9820, 9229 scc: 733-035 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 19 of 21 69 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 1.97e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 1.18e3 9.85e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 5.26e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 1.88e3 2.63e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.65e6 ES-208 1.54e7 45.36 ES-206 9.78e6 49.37 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.43e3 1.83e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 4.83e6 ES-208 1.95e7 45.36 ES-206 1.22e7 49.37 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.85e3 2.41e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.09e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0534, 3426 scc: 733-035 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:54 Printed: 30-Mar-2014 14:44 Page 20 of 21 70 of 622 SGS-AP ID: MB1_11899_PCB_TLX Instr: AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 48 Acq: 27-Mar-2014 13:23:08 User: LKB Datafile: 140327X04 Rel. Int. 100% Abs. Int. 3.49e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: B 4σ 4.50e2 1.74e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.15e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: B 4σ 7.36e2 1.08e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.51e7 50.81 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.34e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 9.57e2 1.67e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.28e7 50.81 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.72e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 1.22e3 1.36e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.93e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 9.63e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\MB1_11899_PCB_TLX.utp_res, saved 30-Mar-2014 14:38 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1881, 7410 scc: 733-035 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:54 (LKB) Printed: 30-Mar-2014 14:44 Page 21 of 21 71 of 622 Lab ID: A6506_11899_PCB_001 ACQ: 27-Mar-2014 14:18:19 LKB Wt/Vol: 0.92 L Client ID: PB070_B-2SWMID-140314-N (TOTAL) UTP: 30-Mar-2014 13:53 LKB J-level: 10.9 pg/L Datafile: 140327X05 RPT: 30-Mar-2014 14:29 LB Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.79 32.31 35.77 35.23 34.76 34.48 38.38 40.91 39.94 NotFnd 45.76 50.82 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES 11.87 14.16 14.41 20.13 17.50 26.44 20.41 32.77 32.29 25.38 35.75 35.21 34.74 34.46 38.36 36.33 30.32 40.91 39.92 43.62 43.13 42.07 35.20 45.74 39.74 47.91 49.37 45.36 50.80 PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services QC J EMPC C J EMPC Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0005 1.0006 1.0006 1.0006 1.0006 1.0006 1.0005 1.0001 1.0005 1.0004 1.0004 -0.2 +0.2 0 -0.2 0 0 0 -1.0 -0.2 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7244 0.8640 0.8793 1.2277 1.0673 1.0790 0.8326 1.3371 1.3176 0.8322 1.1724 1.1546 1.1394 1.1302 1.2580 0.9716 0.8111 1.0941 1.0678 1.1667 0.9080 0.8855 0.7410 0.9629 0.8364 1.0084 1.0392 0.9548 1.0694 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Split: 1 Checkcode: 561-113-BSP Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.82 0.78 0.60 0.61 0.61 0.67 0.77 1.22 1.38 0 0 4.81E+06 2.19E+05 1.15E+07 7.43E+05 2.10E+07 6.52E+05 9.77E+04 9.68E+05 3.06E+05 0.00E+00 3.98E+04 2.24E+06 1.25 1.16 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 268 13.2 804 48.5 1,410 43.1 8.33 81.3 22.5 ND 3.81 332 5.86E+03 5.86E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 2.42E+03 1.85E+03 1.85E+03 1.85E+03 1.69E+03 1.25E+03 3.5 3.5 2.74 2.57 2.7 2.68 2 2.16 1.41 1.8 1.77 2.2 -0.1 0 -0.2 +0.7 0 +0.5 -0.2 +1.4 +1.2 -0.5 +0.9 +0.6 +0.6 +0.6 +1.2 0 -0.5 +0.5 +0.2 +0.8 -0.3 -0.3 -0.6 0 -0.5 0 0 -0.3 0 3.39E+07 3.75E+07 2.06E+07 5.05E+07 2.24E+07 3.85E+07 2.34E+07 3.40E+07 3.25E+07 2.20E+07 2.81E+07 2.78E+07 2.74E+07 2.73E+07 2.32E+07 1.99E+07 2.96E+07 4.74E+07 2.56E+07 2.20E+07 1.49E+07 1.82E+07 2.03E+07 2.13E+07 1.90E+07 1.51E+07 1.05E+07 1.73E+07 1.33E+07 3.23 3.27 1.59 1.56 1.08 1.09 0.77 0.82 0.82 1.62 1.61 1.65 1.59 1.57 1.57 1.29 1.28 1.29 1.27 1.29 1.07 1.09 1.09 1.04 0.94 0.89 0.81 0.80 1.19 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 50.6 % 61.4 % 70.3 % 86.3 % 78.9 % 77.9 % 91.5 % 82.7 % 80 % 99.6 % 85.2 % 83.1 % 85.9 % 83.6 % 81.9 % 84.4 % 89.1 % 70.9 % 73.3 % 67.8 % 86.3 % 87.2 % 103 % 90 % 93.9 % 81.5 % 84.6 % 98.8 % 80.2 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Page 1 of 5 Printed: 3/30/2014 2:33 PM 72 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.89 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 4.83E+07 3.21E+07 1.40E+07 1.08 1.60 1.11 1.11 1.03 0.62 113 % 114 % 112 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.89 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 4.83E+07 3.21E+07 1.40E+07 1.08 1.60 1.11 1.85 1.22 0.58 87.9 % 95.4 % 116 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.39 24.51 30.49 37.39 47.51 5.62E+07 2.97E+07 2.75E+07 2.09E+07 1.49E+07 1.56 0.81 1.62 1.27 0.89 4.89E+03 4.89E+03 4.89E+03 5.65E+03 5.65E+03 8.00E+03 8.00E+03 8.00E+03 8.00E+03 8.00E+03 8.00E+03 8.00E+03 8.00E+03 8.00E+03 5.09E+03 5.09E+03 5.09E+03 5.09E+03 5.09E+03 5.09E+03 5.09E+03 2.12 1.82 2.16 3.59 2.33 3.11 2.76 2.95 2.93 2.86 2.46 2.85 2.86 3.08 3.44 2.57 2.98 2.19 2.31 3.9 2.08 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services 11.89 NotFnd 14.18 14.43 14.61 16.41 16.57 16.80 17.10 17.22 NotFnd 19.56 19.84 20.14 17.51 19.28 19.68 19.87 20.00 20.10 20.58 J J B C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0011 1.0009 1.0011 1.0135 1.0010 1.0111 1.0249 1.0431 1.0507 0.9721 0.9857 1.0006 1.0010 1.1019 1.1245 1.1355 1.1428 1.1486 1.1761 0 -0.1 0 0 0 0 0 -0.2 +0.1 0 -1.1 -0.2 0 +0.6 +0.2 +0.2 -0.2 +0.2 +0.4 Page 2 of 5 NON-EMPC 79 1,430 16,400 36,300 13,900 2,780 662 149 37.1 1.04E+06 0.00E+00 1.55E+05 6.07E+06 3.98E+05 6.83E+05 2.87E+05 2.41E+06 1.90E+05 1.01E+07 0.00E+00 9.23E+05 8.29E+05 6.32E+06 4.20E+06 5.38E+07 1.50E+07 3.53E+06 3.96E+05 1.23E+07 2.00E+07 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 79 1,430 16,400 36,300 13,900 2,780 666 155 49.7 3.29 3.58 1.57 1.61 1.48 1.63 1.56 SI 1.62 1.54 1.56 1.62 1.06 1.03 1.06 1.05 1.08 1.04 1.04 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 2.14 3.34 3.46 2.3 2.28 1.55 1.56 1.98 4.7 70.1 ND 8.95 521 22.1 29.3 10.9 98.2 7.67 399 ND 36.3 32.8 268 356 3,410 1,100 191 22.6 1,180 1,020 Printed: 3/30/2014 2:33 PM 73 of 622 Name PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB SGS Evironmental Services Actual RT 21.73 NotFnd 22.14 22.36 22.64 22.91 23.12 23.48 NotFnd 25.23 25.72 26.10 26.47 20.43 22.39 23.00 23.08 23.28 24.53 24.65 24.76 24.97 25.23 25.42 25.72 25.89 26.22 26.32 26.52 27.23 27.49 27.86 28.06 28.22 28.45 28.75 29.02 29.17 29.60 29.80 NotFnd 31.46 NotFnd NotFnd 25.72 27.41 27.60 27.98 QC J C C C J C J C C C C J C Pred RRT Actual RRT Diff Secs 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8215 0.8371 0.8456 0.8560 0.8664 0.8744 0.8878 0.9541 0.9725 0.9871 1.0009 1.0011 0.9134 0.9385 0.9416 0.9499 1.0009 1.0059 1.0101 1.0189 1.0296 1.0374 1.0492 1.0564 1.0700 1.0739 1.0820 0.8434 0.8513 0.8629 0.8691 0.8740 0.8810 0.8902 0.8987 0.9034 0.9167 0.9228 0.9742 1.0134 0.8988 0.9050 0.9175 -0.4 -1.6 0 -0.3 -0.8 +0.8 -0.3 +2.9 +0.3 0 +0.3 +0.1 -1.5 +0.3 +0.4 0 0 -0.4 0 +1.2 +0.2 -1.5 -0.6 +0.2 +0.3 +0.3 +0.2 -0.3 -0.3 -0.2 -0.3 -0.2 -0.2 0 -0.3 0 -0.4 -0.2 +0.9 0 -0.2 -0.2 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 2.20E+05 0.00E+00 1.07E+07 4.15E+06 7.36E+07 6.65E+07 2.03E+07 1.76E+07 0.00E+00 6.97E+05 1.50E+05 8.25E+05 1.01E+07 2.23E+05 1.30E+07 1.17E+07 2.73E+06 4.07E+06 7.79E+07 1.79E+05 2.15E+06 4.66E+07 1.35E+07 6.99E+07 6.72E+06 1.52E+07 4.82E+06 2.98E+07 3.80E+07 4.00E+05 5.63E+05 2.70E+05 1.36E+05 1.55E+06 2.43E+06 1.12E+08 6.38E+07 5.97E+05 3.05E+07 1.38E+07 0.00E+00 5.51E+05 0.00E+00 0.00E+00 6.42E+05 1.96E+05 2.54E+05 1.80E+07 1.01 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 9.81 ND 471 183 3,110 3,010 893 832 ND 29.1 7.03 40.5 534 15.4 945 979 198 373 5,850 10.2 188 2,850 1,000 4,870 362 1,230 444 2,150 1,940 20.8 27.7 14.7 7.23 79.5 120 6,050 3,670 34.1 1,760 790 ND 26.8 ND ND 53.3 16.6 25.6 1,670 1.02 0.98 1.01 1.01 1.00 1.00 0.99 0.98 0.98 1.04 0.72 0.79 0.77 0.78 0.81 0.79 0.84 0.78 0.79 0.80 0.78 0.78 0.79 0.79 0.79 0.80 0.86 0.89 0.85 0.80 0.78 0.82 0.79 0.79 0.78 0.78 0.79 0.78 0.67 0.65 0.63 0.62 Noise / Recv. Low DL / Recv. High 6.88E+03 6.88E+03 6.88E+03 6.88E+03 6.88E+03 6.88E+03 6.88E+03 6.88E+03 6.88E+03 6.88E+03 6.88E+03 6.88E+03 6.88E+03 1.91E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 2.26E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 5.86E+03 1.47E+03 1.47E+03 3.88E+03 3.88E+03 3.88E+03 2.94 2.94 2.91 2.92 2.79 2.99 2.91 3.12 2.84 2.76 3.09 3.24 3.48 1.17 1.63 1.89 1.63 2.06 1.69 1.28 1.96 1.38 1.67 1.57 1.21 1.82 2.07 1.63 1.15 3.03 2.86 3.18 3.1 2.99 2.88 3.14 3.35 3.33 3.36 3.33 2.86 2.84 3.52 0.986 1.18 3.43 4.08 3.75 Printed: 3/30/2014 2:33 PM 74 of 622 Name PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB SGS Evironmental Services Actual RT 28.19 28.30 28.38 28.67 28.74 28.93 29.35 NotFnd 30.01 30.51 30.92 31.02 31.13 31.50 32.00 32.08 32.21 32.30 32.49 NotFnd NotFnd 34.17 34.38 34.60 35.06 NotFnd NotFnd NotFnd NotFnd 30.96 NotFnd NotFnd 33.01 33.22 33.49 33.79 33.96 34.04 34.30 34.49 NotFnd 34.86 35.27 NotFnd 35.82 NotFnd 36.35 36.51 QC C J EMPC C J C C C J C J C J J C J C Pred RRT Actual RRT Diff Secs 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9246 0.9281 0.9307 0.9402 0.9424 0.9487 0.9625 0.9840 1.0007 1.0141 1.0174 1.0210 1.0329 1.0495 1.0521 1.0563 1.0592 1.0656 0.9916 0.9976 1.0039 1.0091 1.0208 1.0886 1.0955 1.1044 1.1142 1.1200 1.1225 1.1311 1.1372 1.1497 1.1630 0.9581 0.9721 0.9766 0 -0.2 +0.3 -0.2 0 0 +0.2 -0.2 +1.5 -0.2 +0.2 +0.7 +1.7 0 -0.8 +0.4 +0.4 +0.2 0 0 +0.2 0 +0.2 0 +0.2 +0.6 +0.2 +0.2 0 -0.2 +0.6 +0.6 +0.8 -0.2 -1.5 0 Page 4 of 5 Response Ra RRF Conc. / Recv. 4.29E+05 1.49E+06 4.19E+04 1.56E+05 4.68E+06 7.05E+06 7.95E+05 0.00E+00 3.41E+06 2.14E+07 1.15E+06 1.29E+07 1.25E+05 1.98E+07 8.65E+05 6.04E+06 3.01E+07 1.08E+06 3.68E+06 0.00E+00 0.00E+00 9.83E+05 1.83E+06 4.58E+04 4.52E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.17E+06 0.00E+00 0.00E+00 1.72E+06 8.83E+04 2.81E+05 4.43E+06 3.11E+05 4.93E+04 1.59E+05 1.00E+05 0.00E+00 2.14E+06 8.59E+04 0.00E+00 8.35E+05 0.00E+00 5.25E+06 1.04E+06 0.63 0.60 0.50 0.64 0.63 0.61 0.59 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 39.3 114 4.61 15.8 410 781 83.3 ND 331 1,750 129 1,140 8.57 1,600 66 492 2,160 75.3 426 ND ND 71.9 118 3.41 35.4 ND ND ND ND 84.1 ND ND 177 7.78 28 440 43.4 4.91 15.7 11.7 ND 243 9.04 ND 80.5 ND 416 111 0.63 0.62 0.61 0.62 0.67 0.62 0.62 0.62 0.62 0.65 0.64 0.62 0.61 0.62 0.61 1.27 1.24 1.17 1.21 1.26 1.16 1.21 1.31 1.10 1.27 1.26 1.25 1.25 1.22 Noise / Recv. Low DL / Recv. High 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 3.88E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 3.71 3.11 4.46 4.1 3.55 4.49 4.24 2.66 3.93 3.3 4.54 3.57 2.77 3.26 3.09 3.3 2.91 2.83 4.69 2.69 2.65 2.96 2.62 3.01 3.08 2.81 0.836 0.953 0.94 1.03 1 1.46 1.54 1.31 1.48 1.48 2.08 1.48 1.47 1.74 1.77 1.69 1.57 1.25 1.44 1.15 1.18 1.58 Printed: 3/30/2014 2:33 PM 75 of 622 Name Actual RT PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.86 37.06 37.14 37.41 NotFnd 37.75 38.49 39.28 39.54 NotFnd 35.51 NotFnd 36.26 NotFnd 37.78 38.33 38.56 NotFnd 39.08 39.15 39.27 39.65 NotFnd 40.19 41.53 NotFnd 42.08 42.38 43.15 43.61 39.75 40.54 NotFnd 41.30 41.41 43.74 44.30 44.46 45.58 47.53 NotFnd 45.38 46.17 49.39 SGS Evironmental Services QC C C J J J J J C C J J J EMPC J EMPC C EMPC Pred RRT Actual RRT Diff Secs 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9859 0.9912 0.9934 1.0007 1.0096 0.9642 0.9840 0.9904 1.0087 1.0302 1.0733 1.0890 1.0954 1.1102 1.1123 1.1158 1.1264 1.1416 0.9079 0.9200 0.9265 0.9434 0.9533 1.0005 1.0203 1.0394 1.0421 1.1007 1.1148 1.1190 0.9515 0.9921 1.0005 1.0178 1.0004 0 +0.2 +0.2 -0.9 0 +0.2 -0.9 +0.2 +0.2 +0.4 0 +0.7 +0.5 +0.2 -0.5 +0.5 +0.5 +0.7 -0.2 +1.5 -0.3 0 0 0 0 -0.5 +0.7 +1.6 +0.5 +0.5 -0.3 0 0 0 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 4.02E+05 4.06E+05 5.28E+05 6.90E+06 0.00E+00 9.00E+05 1.26E+06 5.51E+04 3.13E+04 0.00E+00 3.69E+05 0.00E+00 1.07E+05 0.00E+00 1.19E+05 3.58E+04 9.47E+05 0.00E+00 4.54E+05 7.16E+04 6.93E+05 3.95E+05 0.00E+00 2.21E+05 1.18E+05 0.00E+00 1.65E+06 4.08E+04 6.59E+05 1.68E+05 1.02E+05 5.84E+04 0.00E+00 2.02E+04 3.88E+04 2.80E+05 1.13E+05 1.58E+05 7.71E+04 1.94E+05 0.00E+00 1.12E+05 1.18E+05 1.28E+05 1.31 1.15 1.19 1.27 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 48.1 39.3 42 682 ND 66.2 120 4.39 2.51 ND 36.8 ND 10.2 ND 16.9 3.98 99 ND 44.7 8.33 84.8 50.1 ND 28.1 14.6 ND 160 3.63 85 15.8 11.2 5.92 ND 2.05 4.15 44.6 17 23.5 14 33 ND 12.6 13.1 24 1.25 1.22 1.21 1.41 1.13 1.10 0.97 1.04 1.04 1.05 1.04 1.02 0.92 0.97 1.05 1.07 1.18 1.12 0.93 0.90 0.77 1.41 0.66 0.99 0.87 0.82 0.82 0.84 0.98 0.82 0.82 Noise / Recv. Low DL / Recv. High 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.85E+03 1.85E+03 1.85E+03 1.07E+03 1.07E+03 1.07E+03 1.07E+03 1.07E+03 1.07E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.73E+03 1.73E+03 1.73E+03 3.04E+03 3.04E+03 3.04E+03 1.78 1.44 1.19 1.47 1.26 1.09 1.84 1.53 1.54 0.88 1.03 1.09 0.98 1.05 1.47 1.7 1.6 1.54 1.5 1.78 1.87 1.94 1.72 1.94 1.89 1.45 1.48 1.36 1.99 1.46 1.6 1.48 1.59 1.49 1.57 2.34 2.2 2.18 3.16 2.95 2.37 3.59 3.56 5.82 Printed: 3/30/2014 2:33 PM 76 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.38e7 2.19e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.13e7 5.64e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 9.40e6 4.70e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 1.62e7 8.09e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 9.69e6 4.85e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.98e6 9.92e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.96e6 9.82e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 561-113 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:44 Page 1 of 21 77 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 PCB-1 7.94e5 11.89 Rel. Int. 100% Abs. Int. 3.10e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 1.89e3 1.55e5 PCB-3 1.21e5 14.18 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.41e5 11.89 Rel. Int. 100% Abs. Int. 9.34e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.00e3 4.67e4 PCB-3 3.38e4 14.18 0% 11.0 12.0 13.0 ES-1 2.59e7 11.87 Rel. Int. 100% 0.00e0 16.0 RT 14.0 15.0 ES-3 2.87e7 14.16 0.00e0 16.0 RT Abs. Int. 1.01e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 4.51e3 5.06e6 0% 11.0 12.0 13.0 ES-1 8.01e6 11.87 Rel. Int. 100% 14.0 15.0 ES-3 8.77e6 14.16 0.00e0 16.0 RT Abs. Int. 3.21e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.22e4 1.61e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.38e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.19e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0766, 9412 scc: 561-113 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:39 Printed: 30-Mar-2014 14:44 Page 2 of 21 78 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 Rel. Int. 100% Abs. Int. 1.28e6 PCB-4 3.71e6 14.43 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 3.44e3 6.42e5 PCB-10 2.45e5 14.61 0% 11.0 12.0 13.0 14.0 Rel. Int. 100% 15.0 Abs. Int. 8.10e5 PCB-4 2.36e6 14.43 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.12e4 0.00e0 16.0 RT 4.05e5 PCB-10 1.53e5 14.61 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.27e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.29e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.01e3 2.14e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 7.97e6 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.68e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 2.90e3 1.34e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.38e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.19e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2272, 7877 scc: 561-113 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:38 (LKB) Printed: 30-Mar-2014 14:44 Page 3 of 21 79 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 PCB-8 6.25e6 17.22 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.88e3 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 PCB-9 4.07e5 16.41 Abs. Int. 1.85e6 PCB-15 3.91e6 20.14 PCB-6 1.47e6 16.80 PCB-11 5.59e5 19.56 9.26e5 13/12 5.05e5 19.84 0% 17.0 19.0 20.0 21.0 PCB-8 3.86e6 17.22 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.25e4 18.0 PCB-9 2.76e5 16.41 Abs. Int. 1.16e6 PCB-15 2.41e6 20.14 PFK INTERFERENCE PCB-6 9.42e5 16.80 PCB-11 3.64e5 19.56 5.79e5 13/12 3.24e5 19.84 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 3.42e7 16.39 20.0 21.0 0.00e0 RT Abs. Int. 1.12e7 ES-15 3.07e7 20.13 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.91e4 5.58e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 2.20e7 16.39 20.0 21.0 Abs. Int. 7.15e6 ES-15 1.97e7 20.12 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.24e3 0.00e0 RT 3.57e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 5.64e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4058, 6471 scc: 561-113 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:38 (LKB) Printed: 30-Mar-2014 14:44 Page 4 of 21 80 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Rel. Int. 100% Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 Abs. Int. 7.83e6 30/18 2.73e7 19.28 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.93e3 PCB-17 7.73e6 19.68 PCB-19 2.16e6 17.51 PCB-27 1.81e6 19.87 PCB-16 6.26e6 20.10 PCB-32 1.02e7 20.58 3.92e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 7.74e6 30/18 2.65e7 19.28 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.15e3 PCB-17 7.29e6 19.67 PCB-19 2.04e6 17.51 PCB-27 1.73e6 19.87 PCB-16 6.01e6 20.10 PCB-32 9.79e6 20.58 3.87e6 0% 17.0 18.0 19.0 0.00e0 RT 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.23e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 3.25e4 ES-19 1.16e7 17.50 3.61e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.08e7 17.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.63e4 1.71e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 5.64e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5640, 0135 scc: 561-113 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:38 (LKB) Printed: 30-Mar-2014 14:44 Page 5 of 21 81 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 PCB-31 3.70e7 28/20 22.64 3.35e7 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 4.64e3 26/29 5.39e6 22.14 0% Abs. Int. 9.94e6 21/33 1.01e7 23.12 PCB-25 2.05e6 22.36 22.0 4.97e6 PCB-22 8.83e6 23.48 23.0 PCB-37 5.17e6 26.47 24.0 25.0 0.00e0 RT 26.0 PCB-31 3.66e7 28/20 22.64 3.31e7 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.24e3 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 26/29 5.30e6 22.14 PCB-25 2.10e6 22.36 Abs. Int. 9.78e6 21/33 1.01e7 23.12 4.89e6 PCB-22 8.79e6 23.48 PCB-37 4.97e6 26.47 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 2.51e7 22.89 Rel. Int. 100% ES-37 2.01e7 26.44 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.14e4 Abs. Int. 6.90e6 3.45e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 2.32e7 22.89 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 1.84e7 26.44 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.53e4 Abs. Int. 6.32e6 3.16e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.40e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.70e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6042, 6656 scc: 561-113 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:39 (LKB) Printed: 30-Mar-2014 14:44 Page 6 of 21 82 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 PCB-54 9.35e4 20.43 Rel. Int. 100% Abs. Int. 2.63e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 9.34e2 1.31e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.29e5 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.86e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 9.73e2 1.93e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.02e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.89e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 4.98e3 1.44e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.32e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.69e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 3.96e3 1.85e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 5.64e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9229, 1631 scc: 561-113 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 16:07 (LKB) Printed: 30-Mar-2014 14:44 Page 7 of 21 83 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Rel. Int. 100% PCB-52 3.43e7 24.53 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.11e3 69/49 2.05e7 24.97 50/53 5.74e6 22.39 PCB-45 5.08e6 23.00 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 44/47… 3.07e7 25.42 PCB-48 5.98e6 25.23 PCB-46 1.82e6 23.28 Abs. Int. 9.18e6 PCB-42 6.73e6 25.89 59/62… 2.94e6 25.72 71/40 1.31e7 26.32 PCB-41 2.12e6 26.22 PCB-64 1.69e7 26.52 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 4.36e7 24.53 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.15e3 69/49 2.60e7 24.97 50/53 7.27e6 22.38 PCB-45 6.58e6 23.00 PCB-46 2.25e6 23.28 Abs. Int. 1.17e7 44/47… 3.92e7 25.42 PCB-42 8.51e6 25.89 0% 22.0 23.0 24.0 25.0 26.0 JS-52 1.33e7 24.51 Rel. Int. 100% 0.00e0 RT 26.0 PCB-48 7.52e6 25.23 4.59e6 71/40 1.66e7 26.32 PCB-41 2.70e6 26.22 PCB-64 2.12e7 26.52 5.84e6 0.00e0 RT Abs. Int. 3.64e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 9.64e3 1.82e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 1.64e7 24.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.37e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 7.75e3 2.18e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.40e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.70e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0367, 2120 scc: 561-113 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:39 (LKB) Printed: 30-Mar-2014 14:44 Page 8 of 21 84 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 Abs. Int. 9.48e6 61/70... 4.95e7 PCB-66 28.75 2.81e7 29.02 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 3.24e3 PCB-56 1.34e7 29.60 PCB-60 6.12e6 29.80 4.74e6 PCB-77 2.16e6 32.79 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 1.19e7 61/70... 6.25e7 PCB-66 28.75 3.57e7 29.02 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.63e3 PCB-56 1.71e7 29.60 PCB-60 7.71e6 29.80 5.96e6 PCB-77 2.65e6 32.79 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 1.47e7 32.29 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 9.36e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 3.70e6 ES-77 1.53e7 32.77 1.85e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.78e7 32.29 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.01e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 4.65e6 ES-77 1.87e7 32.77 2.32e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.09e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9854, 0440 scc: 561-113 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:10 Printed: 30-Mar-2014 14:44 Page 9 of 21 85 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 PCB-96 2.59e5 25.72 Rel. Int. 100% Abs. Int. 6.85e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 7.37e2 3.43e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 3.83e5 25.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.04e5 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 7.32e2 5.18e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.36e7 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.51e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.48e3 1.76e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 8.41e6 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.19e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.37e3 1.10e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.40e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.70e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8144, 2444 scc: 561-113 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:10 Printed: 30-Mar-2014 14:44 Page 10 of 21 86 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.89e3 113/90… 8.19e6 30.51 PCB-95 6.88e6 27.98 PCB-91 1.81e6 28.74 PCB-84 2.67e6 28.93 PCB-110 1.15e7 32.21 PCB-99 4.93e6108/119... 31.02 7.59e6 116/85 31.50 2.32e6 PCB-115PCB-82 32.08 4.23e5 1.44e6 32.30 32.49 PCB-92 1.32e6 30.01 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 Abs. Int. 2.81e6 PCB-118 7.97e6 34.76 PCB-109 6.93e5 34.38 PCB-105 4.34e6 35.77 1.41e6 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.99e3 32.0 113/90… 1.32e7 30.51 PCB-95 1.11e7 27.98 PCB-91 PCB-84 2.87e6 4.37e6 28.74 28.93 34.0 38.0 PCB-110 1.86e7 32.21 PCB-99108/119... 8.00e6 1.22e7 31.02 31.50 116/85 3.72e6 PCB-115PCB-82 32.08 6.54e5 2.24e6 32.30 32.49 PCB-92 2.09e6 30.01 36.0 Abs. Int. 4.59e6 PCB-118 1.30e7 34.76 PCB-109 1.14e6 34.38 PCB-105 7.19e6 35.77 2.29e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 1.97e7 32.78 JS-101 1.70e7 30.49 ES-123 1.67e7 34.46 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 1.57e3 0.00e0 RT 36.0 ES-114 1.73e7 35.21 38.0 0.00e0 RT Abs. Int. 4.88e6 ES-105 1.74e7 35.75 2.44e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 1.23e7 32.78 JS-101 1.05e7 30.49 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 1.76e3 34.0 ES-118 ES-123 1.06e7 1.06e7 34.74 34.46 36.0 38.0 0.00e0 RT Abs. Int. 3.03e6 ES-105 1.08e7 35.75 1.52e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.09e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5451, 1871 scc: 561-113 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 16:10 (LKB) Printed: 30-Mar-2014 14:44 Page 11 of 21 87 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 Rel. Int. 100% PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 1.17e3 Abs. Int. 9.60e4 4.80e4 PCB-126 4.66e4 38.38 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 1.25e3 Abs. Int. 2.52e5 1.26e5 PCB-126 6.03e4 38.38 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.65e6 ES-126 1.42e7 38.36 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 4.69e3 1.83e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.27e6 ES-126 9.00e6 38.36 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 3.67e3 1.13e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.69e6 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 4.85e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6525, 1259 scc: 561-113 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 16:11 (LKB) Printed: 30-Mar-2014 14:44 Page 12 of 21 88 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Rel. Int. 100% Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 153/168 2.92e6 36.35 147/149 2.47e6 33.79 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 7.67e2 PCB-136 6.54e5 30.96 PCB-132 1.20e6 34.86 151/135 9.52e5 33.01 163/138… 3.86e6 37.41 Abs. Int. 8.79e5 PCB-141 PCB-158 5.75e5 PCB-164 5.01e5 2.87e5 36.51 37.75 37.14 PCB-146 4.64e5 35.82 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 153/168 2.33e6 36.35 147/149 1.96e6 33.79 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 6.65e2 PCB-136 5.14e5 30.95 151/135 7.67e5 33.01 38.0 PCB-134 1.44e5 33.97 PCB-132 9.43e5 34.86 163/138… 3.04e6 37.41 PCB-141 4.70e5 PCB-137 36.51 1.89e5 37.06 PCB-146 3.71e5 35.82 30.0 32.0 34.0 PCB-158 3.99e5 37.75 36.0 38.0 ES-155 1.66e7 30.32 Rel. Int. 100% ES-153 1.12e7 36.33 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.33e3 0.00e0 RT Abs. Int. 7.01e5 0% 28.0 4.40e5 3.50e5 0.00e0 RT Abs. Int. 4.17e6 JS-138 1.17e7 37.39 2.08e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 1.30e7 30.32 Rel. Int. 100% ES-153 8.70e6 36.33 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.65e3 0.00e0 RT Abs. Int. 3.26e6 JS-138 9.20e6 37.39 1.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.09e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2279, 0114 scc: 561-113 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:39 (LKB) Printed: 30-Mar-2014 14:44 Page 13 of 21 89 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 Abs. Int. 1.67e5 128/166 6.91e5 38.49 156/157 5.32e5 40.91 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 1.03e3 8.35e4 PCB-167 1.77e5 39.94 0% 39.0 Rel. Int. 100% 40.0 128/166 5.64e5 38.49 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.33e5 156/157 4.36e5 40.91 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 8.18e2 PCB-159 2.49e4 39.28 6.67e4 PCB-167 1.28e5 39.94 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.43e7 39.92 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 5.71e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 2.67e7 40.91 0.00e0 RT Abs. Int. 4.79e6 ES-169 1.24e7 43.62 2.40e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.12e7 39.92 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 6.04e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 2.07e7 40.91 0.00e0 RT Abs. Int. 3.62e6 ES-169 9.61e6 43.62 1.81e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.69e6 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 4.85e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6602, 9360 scc: 561-113 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 16:12 (LKB) Printed: 30-Mar-2014 14:44 Page 14 of 21 90 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 PCB-179 1.96e5 35.51 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 5.34e2 Abs. Int. 5.33e4 PCB-176 5.62e4 36.26 2.67e4 PCB-178 5.87e4 37.78 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 1.73e5 35.50 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 5.36e2 Abs. Int. 4.82e4 PCB-178 6.04e4 37.78 PCB-176 5.13e4 36.25 2.41e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.06e7 35.20 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 2.73e6 CS/SS-178 7.37e6 37.76 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.53e3 1.37e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 9.70e6 35.20 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.48e6 CS/SS-178 6.67e6 37.76 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.40e3 1.24e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 8.09e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0928, 1901 scc: 561-113 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:10 Printed: 30-Mar-2014 14:44 Page 15 of 21 91 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 180/193 8.56e5 42.08 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 8.02e2 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 PCB-187 4.82e5 38.56 PCB-174 3.50e5 PCB-183 39.27 2.33e5 39.08 PCB-185 3.65e4 39.15 PCB-177 1.89e5 39.65 171/173 1.09e5 40.19 Abs. Int. 1.93e5 PCB-170 3.48e5 43.15 PCB-172 6.06e4 41.53 9.66e4 PCB-190 8.06e4 43.61 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 7.99e5 42.08 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 7.29e2 43.0 PCB-187 4.65e5 38.56 PCB-174 3.42e5 39.27 PCB-183 2.22e5 39.08 PCB-185 3.50e4 39.15 PCB-177 2.06e5 39.65 171/173 1.12e5 40.19 Abs. Int. 1.92e5 PCB-170 3.12e5 43.15 PCB-172 5.76e4 41.53 9.61e4 PCB-190 8.70e4 43.60 0% 39.0 40.0 41.0 42.0 ES-180 9.46e6 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.81e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.37e6 ES-170 7.70e6 43.13 1.19e6 0% 39.0 40.0 41.0 42.0 ES-180 8.72e6 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 1.65e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.13e6 ES-170 7.21e6 43.13 1.07e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.69e6 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 4.85e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7110, 1600 scc: 561-113 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:14 Printed: 30-Mar-2014 14:44 Page 16 of 21 92 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 PCB-189 2.43e4 45.76 Abs. Int. 5.93e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 1.06e3 2.96e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.95e4 45.76 Abs. Int. 6.82e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 6.37e2 3.41e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.09e7 45.74 0.00e0 RT Abs. Int. 2.49e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 3.68e3 1.24e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.04e7 45.74 0.00e0 RT Abs. Int. 2.38e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.18e3 1.19e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.98e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 9.92e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2551, 1711 scc: 561-113 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:39 Printed: 30-Mar-2014 14:44 Page 17 of 21 93 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 198/199 1.39e5 43.74 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 7.32e2 PCB-202 4.85e4 39.75 PCB-201 2.54e4 40.54 Abs. Int. 3.75e4 PCB-196 5.29e4 44.30 PCB-197 PCB-200 1.83e4 1.50e4 41.41 41.30 PCB-203 7.12e4 44.46 1.87e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 1.41e5 43.74 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.75e2 PCB-202 5.40e4 39.75 PCB-201 3.30e4 40.54 Abs. Int. 3.58e4 PCB-196 6.06e4 44.29 PCB-197 PCB-200 2.75e4 1.07e4 41.39 41.29 PCB-203 8.71e4 44.46 1.79e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 9.23e6 39.74 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 2.22e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.54e3 1.11e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 9.80e6 39.73 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.37e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.76e3 1.18e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.69e6 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 4.85e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6175, 7025 scc: 561-113 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 16:13 (LKB) Printed: 30-Mar-2014 14:44 Page 18 of 21 94 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 PCB-194 8.89e4 47.53 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 6.79e2 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 Abs. Int. 2.35e4 PCB-195 3.47e4 45.58 1.18e4 0% 46.0 47.0 49.0 50.0 PCB-194 1.05e5 47.52 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 1.05e3 48.0 0.00e0 RT Abs. Int. 2.52e4 PCB-195 4.25e4 45.59 1.26e4 0% 46.0 47.0 48.0 JS-194 7.01e6 47.51 Rel. Int. 100% 49.0 50.0 ES-205 7.13e6 47.91 0.00e0 RT Abs. Int. 1.78e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.16e3 8.89e5 0% 46.0 47.0 48.0 JS-194 7.92e6 47.51 Rel. Int. 100% 49.0 50.0 ES-205 7.99e6 47.91 0.00e0 RT Abs. Int. 1.91e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.32e3 9.53e5 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.98e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 9.92e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4725, 7470 scc: 561-113 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:39 (LKB) Printed: 30-Mar-2014 14:44 Page 19 of 21 95 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-208 6.17e4 45.38 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 PCB-207 5.29e4 46.17 PCB-206 5.78e4 49.39 Abs. Int. 1.55e4 NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.06e3 7.77e3 0% 46.0 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 1.98e3 PCB-208 6.30e4 45.38 47.0 48.0 49.0 50.0 PCB-206 7.03e4 49.39 PCB-207 6.48e4 46.16 Abs. Int. 2.24e4 1.12e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 1.84e6 ES-208 7.72e6 45.36 ES-206 4.70e6 49.37 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.06e3 9.19e5 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 2.34e6 ES-208 9.60e6 45.36 ES-206 5.78e6 49.37 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.48e3 1.17e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.98e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 9.92e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7924, 9671 scc: 561-113 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:39 (LKB) Printed: 30-Mar-2014 14:44 Page 20 of 21 96 of 622 SGS-AP ID: A6506_11899_PCB_001 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-2SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 49 Acq: 27-Mar-2014 14:18:19 User: LKB Datafile: 140327X05 PCB-209 1.21e6 50.82 Rel. Int. 100% Abs. Int. 2.54e5 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 6.06e2 1.27e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.04e6 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.19e5 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.47e2 1.09e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 7.21e6 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.52e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.07e3 7.59e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 6.07e6 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.29e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.46e2 6.47e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.96e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 9.82e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_001.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1164, 4257 scc: 561-113 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 16:07 (LKB) Printed: 30-Mar-2014 14:44 Page 21 of 21 97 of 622 Lab ID: A6506_11899_PCB_002 ACQ: 27-Mar-2014 15:13:30 LKB Wt/Vol: 0.94 L Client ID: PB070_B-1SWMID-140314-N (TOTAL) UTP: 30-Mar-2014 13:53 LKB J-level: 10.6 pg/L Datafile: 140327X06 RPT: 30-Mar-2014 14:29 LB Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services Actual RT 32.79 32.32 35.78 35.23 34.77 34.49 38.38 40.92 39.95 NotFnd 45.77 50.83 11.87 14.16 14.41 20.12 17.50 26.45 20.41 32.77 32.30 25.38 35.75 35.21 34.75 34.47 38.37 36.33 30.33 40.91 39.93 43.63 43.14 42.07 35.21 45.75 39.74 47.91 49.37 45.37 50.81 QC J J C J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0005 1.0007 1.0006 1.0006 1.0006 1.0008 1.0004 1.0002 1.0005 1.0004 1.0004 -0.2 +0.4 0 -0.2 0 +0.4 -0.2 -0.7 -0.2 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7243 0.8639 0.8792 1.2276 1.0674 1.0790 0.8326 1.3371 1.3177 0.8322 1.1724 1.1546 1.1394 1.1302 1.2580 0.9716 0.8111 1.0941 1.0678 1.1666 0.9080 0.8855 0.7410 0.9629 0.8364 1.0084 1.0392 0.9548 1.0693 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Split: 1 Checkcode: 505-842-NMR Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.80 0.79 0.62 0.64 0.62 0.62 0.69 1.22 1.26 0 0 1.64E+07 6.48E+05 3.84E+07 2.36E+06 7.10E+07 1.95E+06 3.45E+05 3.09E+06 9.99E+05 0.00E+00 1.18E+05 6.07E+06 1.06 1.16 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 241 10.1 714 41 1,270 34.2 7.34 67.7 19.7 ND 2.96 249 8.35E+03 8.35E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 4.04E+03 2.60E+03 2.60E+03 2.60E+03 2.55E+03 1.38E+03 1.26 1.39 1.25 1.14 1.2 1.17 0.875 0.813 0.527 0.615 0.659 0.649 -0.1 -0.1 -0.3 +0.6 +0.1 +0.5 -0.2 +1.4 +1.4 -0.5 +0.9 +0.6 +0.6 +0.6 +1.2 0 -0.5 +0.5 +0.2 +0.5 -0.3 -0.3 -0.6 0 -0.5 0 0 -0.3 -0.3 9.83E+07 1.10E+08 5.88E+07 1.61E+08 6.29E+07 1.40E+08 6.71E+07 1.25E+08 1.21E+08 7.49E+07 1.02E+08 1.01E+08 9.93E+07 9.95E+07 8.99E+07 7.22E+07 1.03E+08 1.76E+08 9.24E+07 8.11E+07 5.35E+07 6.51E+07 7.17E+07 7.88E+07 6.80E+07 5.56E+07 3.72E+07 6.13E+07 4.63E+07 3.22 3.30 1.59 1.58 1.06 1.09 0.79 0.80 0.80 1.57 1.59 1.61 1.60 1.59 1.54 1.30 1.26 1.27 1.29 1.27 1.09 1.08 1.08 1.05 0.90 0.90 0.81 0.79 1.19 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 52.6 % 64.4 % 71.9 % 98.9 % 79.4 % 87.4 % 80.9 % 93.8 % 92.1 % 103 % 93.9 % 91.7 % 94.3 % 92.4 % 96.3 % 93.8 % 94.9 % 80.7 % 81.1 % 76.2 % 93.5 % 94.4 % 112 % 101 % 103 % 90.7 % 90.8 % 106 % 84.7 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Page 1 of 5 Printed: 3/30/2014 2:33 PM 98 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.89 32.79 37.77 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 1.60E+08 1.12E+08 4.78E+07 1.08 1.60 1.07 1.11 1.03 0.62 103 % 110 % 108 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.89 32.79 37.77 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 1.60E+08 1.12E+08 4.78E+07 1.08 1.60 1.07 1.85 1.22 0.58 90 % 101 % 120 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.39 24.51 30.50 37.40 47.51 1.57E+08 9.63E+07 9.08E+07 6.83E+07 4.94E+07 1.57 0.82 1.58 1.27 0.90 6.48E+03 6.48E+03 6.48E+03 9.48E+03 9.48E+03 1.06E+04 1.06E+04 1.06E+04 1.06E+04 1.06E+04 1.06E+04 1.06E+04 1.06E+04 1.06E+04 7.48E+03 7.48E+03 7.48E+03 7.48E+03 7.48E+03 7.48E+03 7.48E+03 0.901 0.776 0.921 2.17 1.41 1.35 1.2 1.28 1.27 1.24 1.07 1.24 1.25 1.34 1.96 1.47 1.7 1.25 1.32 2.22 1.18 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services 11.89 13.99 14.18 14.43 14.61 16.41 16.57 16.80 17.10 17.22 NotFnd 19.56 19.83 20.14 17.52 19.28 19.68 19.87 19.99 20.10 20.58 J J J J B C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0011 0.9881 1.0010 1.0011 1.0138 1.0010 1.0111 1.0249 1.0432 1.0507 0.9720 0.9855 1.0006 1.0010 1.1020 1.1245 1.1355 1.1427 1.1486 1.1761 0 +0.1 0 0 +0.3 0 0 0 -0.1 +0.1 -0.1 -1.3 -0.2 0 +0.7 +0.2 +0.2 -0.4 +0.2 +0.4 Page 2 of 5 NON-EMPC 72.7 1,390 16,700 33,400 12,700 2,440 559 127 35.5 2.73E+06 1.69E+05 4.30E+05 1.82E+07 1.14E+06 1.85E+06 7.60E+05 7.19E+06 5.11E+05 3.03E+07 0.00E+00 2.93E+06 2.77E+06 2.16E+07 1.33E+07 1.79E+08 5.15E+07 1.21E+07 1.34E+06 4.29E+07 6.74E+07 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 72.7 1,390 16,700 33,400 12,700 2,440 565 127 35.5 3.17 3.21 3.25 1.57 1.79 1.63 SI 1.69 SI 1.63 1.60 1.51 1.66 1.05 1.03 1.04 1.05 1.10 1.05 1.04 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 0.911 1.75 1.85 0.919 1 0.553 0.584 0.537 1.47 61.8 2.74 8.23 531 21.6 24 8.76 88.7 6.26 362 ND 35 33.1 279 391 3,930 1,310 226 26.4 1,430 1,190 Printed: 3/30/2014 2:33 PM 99 of 622 Name PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB SGS Evironmental Services Actual RT 21.73 NotFnd 22.14 22.36 22.64 22.91 23.13 23.48 NotFnd 25.23 25.73 26.11 26.47 20.43 22.39 23.00 23.08 23.28 24.53 24.65 24.76 24.97 25.24 25.43 25.72 25.89 26.23 26.32 26.52 27.24 27.49 27.87 28.07 28.23 28.45 28.75 29.03 29.17 29.61 29.80 NotFnd 31.46 NotFnd NotFnd 25.72 27.41 27.60 27.98 QC J C C C J C J C C C C J C Pred RRT Actual RRT Diff Secs 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8216 0.8371 0.8456 0.8560 0.8664 0.8744 0.8878 0.9540 0.9728 0.9872 1.0009 1.0010 0.9134 0.9384 0.9416 0.9498 1.0009 1.0057 1.0101 1.0189 1.0296 1.0374 1.0493 1.0564 1.0700 1.0739 1.0820 0.8433 0.8513 0.8629 0.8692 0.8740 0.8810 0.8902 0.8987 0.9031 0.9167 0.9227 0.9741 1.0134 0.8988 0.9050 0.9175 -0.3 -1.6 0 -0.3 -0.8 +0.8 -0.3 +2.7 +0.8 +0.2 +0.3 0 -1.5 +0.1 +0.4 -0.1 0 -0.7 0 +1.2 +0.2 -1.5 -0.5 +0.2 +0.3 +0.3 +0.2 -0.5 -0.3 -0.2 -0.2 -0.2 -0.2 0 -0.3 -0.5 -0.4 -0.4 +0.8 0 -0.2 -0.2 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 8.09E+05 0.00E+00 3.62E+07 1.40E+07 2.47E+08 2.26E+08 6.61E+07 5.80E+07 0.00E+00 2.42E+06 5.02E+05 3.05E+06 3.43E+07 7.10E+05 4.62E+07 4.15E+07 1.05E+07 1.53E+07 2.73E+08 6.86E+05 8.01E+06 1.64E+08 4.86E+07 2.53E+08 2.35E+07 5.55E+07 1.71E+07 1.09E+08 1.34E+08 1.38E+06 2.19E+06 9.00E+05 5.38E+05 5.32E+06 8.34E+06 3.92E+08 2.21E+08 2.35E+06 1.07E+08 4.62E+07 0.00E+00 1.61E+06 0.00E+00 0.00E+00 2.25E+06 7.27E+05 8.40E+05 6.34E+07 1.00 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 9.61 ND 425 165 2,780 2,740 778 732 ND 27 6.27 40 482 16.6 874 907 198 364 5,340 10.2 182 2,610 936 4,590 329 1,170 410 2,060 1,780 18.6 28 12.8 7.46 71.2 107 5,500 3,320 34.9 1,610 687 ND 20.3 ND ND 53.2 16.3 22.5 1,560 1.00 1.00 1.01 1.00 1.01 1.00 0.99 1.13 1.00 1.01 0.88 0.78 0.77 0.80 0.80 0.79 0.80 0.79 0.79 0.79 0.79 0.79 0.79 0.79 0.79 0.79 0.80 0.77 0.74 0.82 0.79 0.78 0.79 0.79 0.81 0.79 0.79 0.71 0.64 0.64 0.61 0.61 Noise / Recv. Low DL / Recv. High 1.22E+04 1.22E+04 1.22E+04 1.22E+04 1.22E+04 1.22E+04 1.22E+04 1.22E+04 1.22E+04 1.22E+04 1.22E+04 1.22E+04 1.22E+04 2.81E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 3.13E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 8.35E+03 1.89E+03 1.89E+03 6.43E+03 6.43E+03 6.43E+03 1.47 1.47 1.46 1.46 1.4 1.5 1.46 1.56 1.42 1.38 1.55 1.62 1.74 0.664 0.631 0.729 0.631 0.797 0.652 0.495 0.757 0.531 0.643 0.605 0.468 0.702 0.799 0.628 0.443 1.21 1.14 1.26 1.23 1.19 1.14 1.25 1.33 1.32 1.34 1.32 1.14 1.13 1.4 0.385 0.461 1.49 1.78 1.64 Printed: 3/30/2014 2:33 PM 100 of 622 Name PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB SGS Evironmental Services Actual RT 28.19 28.30 28.38 NotFnd 28.74 28.93 29.35 NotFnd 30.01 30.52 30.92 31.03 31.14 31.50 32.00 32.09 32.22 32.31 32.50 NotFnd 33.21 34.18 34.39 34.61 35.07 NotFnd NotFnd 30.51 30.65 30.96 31.23 32.51 33.02 33.23 33.50 33.79 33.97 34.06 34.31 34.49 NotFnd 34.87 35.27 NotFnd 35.83 NotFnd 36.35 36.52 QC C J C J C C J C J J EMPC J EMPC J J C J C J J C J C Pred RRT Actual RRT Diff Secs 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9244 0.9280 0.9306 0.9424 0.9487 0.9624 0.9841 1.0007 1.0140 1.0173 1.0212 1.0329 1.0493 1.0520 1.0563 1.0595 1.0656 1.0890 0.9916 0.9977 1.0041 1.0091 1.0060 1.0107 1.0208 1.0297 1.0718 1.0886 1.0956 1.1044 1.1142 1.1202 1.1229 1.1313 1.1373 1.1497 1.1629 0.9581 0.9721 0.9766 -0.3 -0.3 +0.2 0 0 0 0 +1.5 -0.4 0 +1.1 +1.7 -0.4 -1.0 +0.4 +1.0 +0.2 +0.6 0 +0.2 +0.6 0 0 0 +0.2 +0.2 +0.8 0 +0.4 +0.6 +0.2 +0.6 +0.8 +0.2 +0.8 +0.6 +0.6 -0.2 -1.5 0 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.54E+06 5.38E+06 2.52E+05 0.00E+00 1.71E+07 2.58E+07 2.80E+06 0.00E+00 1.20E+07 7.45E+07 3.76E+06 4.42E+07 2.90E+05 6.84E+07 2.55E+06 2.11E+07 1.02E+08 2.70E+06 1.25E+07 0.00E+00 1.81E+05 3.12E+06 6.26E+06 1.07E+05 1.53E+06 0.00E+00 0.00E+00 5.46E+04 3.56E+04 3.76E+06 2.62E+04 3.32E+04 5.83E+06 2.66E+05 9.74E+05 1.49E+07 1.11E+06 1.34E+05 5.38E+05 3.78E+05 0.00E+00 7.17E+06 2.83E+05 0.00E+00 2.77E+06 0.00E+00 1.69E+07 3.30E+06 0.58 0.62 0.61 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 37.4 110 7.38 ND 397 761 78.1 ND 310 1,610 112 1,040 5.28 1,460 51.6 456 1,940 50.2 385 ND 3.14 60.6 108 2.12 31.9 ND ND 1.02 0.654 75.3 0.514 0.868 161 6.26 25.9 395 41.4 3.56 14.2 11.8 ND 217 7.94 ND 71.3 ND 357 93.4 0.61 0.61 0.61 0.61 0.62 0.61 0.62 0.62 0.62 0.60 0.62 0.62 0.62 0.62 0.64 0.62 0.63 0.64 0.61 0.91 1.49 1.29 1.13 1.27 1.25 1.22 1.26 1.27 1.30 1.17 1.19 1.38 1.27 1.25 1.29 1.26 1.27 Noise / Recv. Low DL / Recv. High 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 6.43E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.62 1.36 1.95 1.79 1.55 1.96 1.85 1.16 1.71 1.44 1.98 1.56 1.21 1.42 1.35 1.44 1.27 1.23 2.04 1.17 1.16 1.29 1.14 1.31 1.37 1.28 0.254 0.29 0.286 0.312 0.305 0.414 0.437 0.373 0.422 0.421 0.591 0.421 0.419 0.495 0.502 0.479 0.445 0.355 0.408 0.328 0.335 0.45 Printed: 3/30/2014 2:33 PM 101 of 622 Name Actual RT PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.87 37.06 37.15 37.42 NotFnd 37.75 38.50 39.29 39.54 NotFnd 35.51 NotFnd 36.26 NotFnd 37.79 38.33 38.56 NotFnd 39.09 39.18 39.28 39.66 40.01 40.20 41.54 NotFnd 42.09 42.39 43.16 43.61 39.76 40.55 NotFnd 41.32 41.40 43.75 44.30 44.47 45.59 47.53 47.94 45.39 46.17 49.40 SGS Evironmental Services QC C C J J J J EMPC J J C C J EMPC J J J J C J J J Pred RRT Actual RRT Diff Secs 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9859 0.9911 0.9933 1.0007 1.0096 0.9642 0.9840 0.9902 1.0087 1.0300 1.0734 1.0888 1.0954 1.1102 1.1128 1.1158 1.1264 1.1363 1.1417 0.9079 0.9200 0.9265 0.9434 0.9533 1.0006 1.0204 1.0396 1.0418 1.1007 1.1147 1.1190 0.9515 0.9921 1.0005 1.0004 1.0178 1.0005 0 0 0 -0.9 0 +0.2 -0.9 -0.2 +0.2 0 +0.2 +0.2 +0.5 +0.2 +0.7 +0.5 +0.5 +0.5 +1.0 -0.2 +1.5 -0.3 0 0 +0.2 +0.2 0 0 +1.6 +0.3 +0.5 -0.3 0 +0.3 -0.3 0 +0.3 Page 5 of 5 Response Ra RRF Conc. / Recv. 1.32E+06 1.30E+06 1.77E+06 2.23E+07 0.00E+00 3.00E+06 4.03E+06 1.53E+05 9.93E+04 0.00E+00 1.18E+06 0.00E+00 3.42E+05 0.00E+00 3.88E+05 1.02E+05 2.97E+06 0.00E+00 1.43E+06 2.54E+05 2.16E+06 1.27E+06 3.60E+04 7.16E+05 3.62E+05 0.00E+00 5.14E+06 1.06E+05 1.98E+06 5.06E+05 2.93E+05 1.84E+05 0.00E+00 6.13E+04 1.43E+05 8.03E+05 3.65E+05 4.63E+05 2.26E+05 5.95E+05 3.88E+04 3.19E+05 2.67E+05 3.43E+05 1.27 1.29 1.27 1.24 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 42.1 33.6 37.7 589 ND 58.9 103 3.28 2.14 ND 32.3 ND 8.88 ND 15.1 3.06 84.1 ND 38.2 8 71.6 43.5 1.1 24.6 12.2 ND 135 2.55 69 12.9 8.68 5.05 ND 1.69 4.14 34.7 14.9 18.7 10.8 26.6 1.39 9.81 8.13 17.5 1.30 1.24 1.34 1.06 1.07 1.16 1.13 0.86 1.05 1.04 1.03 1.04 1.02 1.19 1.03 1.10 1.03 1.26 1.08 1.14 0.89 0.82 0.93 0.86 0.86 0.88 0.97 0.85 0.96 0.98 0.84 0.71 0.77 Noise / Recv. Low DL / Recv. High 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 2.60E+03 2.60E+03 2.60E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 1.41E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 1.50E+03 1.50E+03 1.50E+03 1.50E+03 1.50E+03 1.50E+03 1.50E+03 1.50E+03 1.63E+03 1.63E+03 1.63E+03 3.39E+03 3.39E+03 3.39E+03 0.506 0.41 0.337 0.418 0.357 0.311 0.686 0.572 0.576 0.345 0.405 0.426 0.384 0.409 0.577 0.632 0.593 0.573 0.559 0.661 0.695 0.721 0.638 0.721 0.703 0.541 0.55 0.505 0.752 0.549 0.476 0.442 0.475 0.443 0.466 0.695 0.655 0.649 0.798 0.745 0.599 1.1 1.09 1.83 Printed: 3/30/2014 2:33 PM 102 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 1.98e8 9.91e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 4.95e7 2.47e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 4.07e7 2.04e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 7.10e7 3.55e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 4.20e7 2.10e7 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 7.79e6 3.90e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 7.16e6 3.58e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 505-842 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:44 Page 1 of 21 103 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-1 2.08e6 11.89 Rel. Int. 100% Abs. Int. 8.39e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.95e3 4.19e5 PCB-3 3.29e5 14.18 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 6.54e5 11.89 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.65e5 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.53e3 1.32e5 PCB-3 1.01e5 14.18 0% 11.0 12.0 13.0 ES-1 7.50e7 11.87 Rel. Int. 100% 14.0 15.0 ES-3 8.41e7 14.16 0.00e0 16.0 RT Abs. Int. 3.05e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.95e3 1.53e7 0% 11.0 12.0 13.0 ES-1 2.33e7 11.87 Rel. Int. 100% 14.0 15.0 ES-3 2.55e7 14.16 0.00e0 16.0 RT Abs. Int. 9.46e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.82e4 4.73e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.98e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 9.91e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5790, 9487 scc: 505-842 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:38 Printed: 30-Mar-2014 14:44 Page 2 of 21 104 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 Rel. Int. 100% Abs. Int. 3.67e6 PCB-4 1.11e7 14.43 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.78e3 1.83e6 PCB-10 7.35e5 14.61 0% 11.0 12.0 13.0 14.0 Rel. Int. 100% 15.0 Abs. Int. 2.48e6 PCB-4 7.07e6 14.43 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.56e4 0.00e0 16.0 RT 1.24e6 PCB-10 4.10e5 14.62 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.61e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.15e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.28e3 5.77e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.27e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.41e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.99e3 3.71e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.98e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 9.91e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5204, 2182 scc: 505-842 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:36 (LKB) Printed: 30-Mar-2014 14:44 Page 3 of 21 105 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 PCB-8 1.88e7 17.22 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 6.46e3 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-9 1.14e6 16.41 Abs. Int. 5.45e6 PCB-15 1.35e7 20.14 PCB-6 4.51e6 16.80 PCB-11 1.80e6 19.56 2.72e6 13/12 1.67e6 19.83 0% 17.0 19.0 20.0 21.0 PCB-8 1.16e7 17.22 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 5.86e4 18.0 PCB-9 7.02e5 16.41 Abs. Int. 3.47e6 PCB-15 8.14e6 20.14 PCB-6 2.67e6 16.80 PFK INTERFERENCE PCB-11 1.12e6 19.56 1.74e6 13/12 1.10e6 19.83 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 9.57e7 16.39 20.0 21.0 ES-15 9.87e7 20.12 0.00e0 RT Abs. Int. 2.75e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.57e4 1.38e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 6.11e7 16.39 20.0 21.0 ES-15 6.26e7 20.12 0.00e0 RT Abs. Int. 1.73e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 9.53e3 8.67e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.95e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 2.47e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1768, 8216 scc: 505-842 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:36 (LKB) Printed: 30-Mar-2014 14:44 Page 4 of 21 106 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Rel. Int. 100% Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 Abs. Int. 2.44e7 30/18 9.11e7 19.28 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.50e3 PCB-17 2.63e7 19.68 PCB-19 6.83e6 17.52 PCB-27 6.20e6 19.87 PCB-16 2.20e7 20.10 PCB-32 3.44e7 20.58 1.22e7 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 2.34e7 30/18 8.80e7 19.28 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 3.99e3 PCB-17 2.52e7 19.68 PCB-19 6.50e6 17.51 PCB-27 5.88e6 19.87 PCB-16 2.09e7 20.10 PCB-32 3.30e7 20.58 1.17e7 0% 17.0 18.0 19.0 20.0 21.0 ES-19 3.24e7 17.50 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 9.25e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 7.45e4 4.62e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 3.06e7 17.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.64e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 6.21e4 4.32e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.95e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 2.47e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5803, 2278 scc: 505-842 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:22 Printed: 30-Mar-2014 14:44 Page 5 of 21 107 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 PCB-31 1.24e8 28/20 22.64 1.13e8 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 5.67e3 26/29 1.81e7 22.14 0% Abs. Int. 3.11e7 21/33 3.31e7 23.13 PCB-25 6.98e6 22.36 22.0 1.56e7 PCB-22 2.90e7 23.48 23.0 PCB-37 1.73e7 26.47 24.0 25.0 0.00e0 RT 26.0 PCB-31 1.23e8 28/20 22.64 1.13e8 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 6.56e3 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 26/29 1.81e7 22.14 0% 22.0 PCB-25 7.00e6 22.36 Abs. Int. 3.07e7 21/33 3.29e7 23.13 23.0 1.53e7 PCB-22 2.90e7 23.48 PCB-37 1.70e7 26.47 24.0 25.0 CS/SS-28 8.30e7 22.89 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 7.30e7 26.45 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 8.74e4 Abs. Int. 2.11e7 1.06e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 7.69e7 22.89 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 6.67e7 26.45 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 5.03e4 Abs. Int. 1.95e7 9.76e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.07e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 2.04e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3876, 7325 scc: 505-842 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:36 (LKB) Printed: 30-Mar-2014 14:44 Page 6 of 21 108 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-54 3.32e5 20.43 Rel. Int. 100% Abs. Int. 8.28e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.51e3 4.14e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 3.78e5 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.84e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.30e3 4.92e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.96e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.31e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 1.16e4 3.65e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.75e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.31e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 6.86e3 4.65e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.95e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 2.47e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5114, 5363 scc: 505-842 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 16:16 (LKB) Printed: 30-Mar-2014 14:44 Page 7 of 21 109 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 PCB-52 1.20e8 24.53 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.37e3 69/49 7.22e7 24.97 50/53 2.03e7 22.39 0% 22.0 PCB-45 1.81e7 PCB-51 23.00 4.66e6 23.08 24.0 25.0 PCB-52 1.53e8 24.53 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.76e3 69/49 9.19e7 24.97 50/53 2.60e7 22.39 0% 22.0 PCB-45 2.34e7 PCB-51 23.00 5.81e6 23.08 23.0 44/47… 1.12e8 25.43 PCB-48 2.15e7 25.24 PCB-46 6.80e6 23.28 23.0 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 24.0 25.0 PCB-42 2.45e7 25.89 59/62… 1.04e7 25.72 PCB-64 5.90e7 26.52 1.49e7 0.00e0 RT Abs. Int. 3.78e7 44/47… 1.42e8 25.43 PCB-42 3.11e7 25.89 26.0 JS-52 4.35e7 24.51 Rel. Int. 100% 71/40 4.85e7 26.32 PCB-41 7.54e6 26.23 26.0 PCB-48 2.71e7 25.24 PCB-46 8.46e6 23.28 Abs. Int. 2.98e7 71/40 6.10e7 26.32 PCB-41 9.60e6 26.23 PCB-64 7.50e7 26.52 1.89e7 0.00e0 RT Abs. Int. 1.04e7 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 2.20e4 5.20e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 5.28e7 24.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.67e4 6.37e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.07e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 2.04e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1939, 9123 scc: 505-842 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:37 (LKB) Printed: 30-Mar-2014 14:44 Page 8 of 21 110 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 Abs. Int. 2.99e7 61/70... 1.73e8 PCB-66 28.75 9.80e7 29.03 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 4.13e3 PCB-56 4.71e7 29.61 PCB-60 2.03e7 29.80 1.49e7 PCB-77 7.30e6 32.79 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 3.69e7 61/70... PCB-66 2.18e8 1.23e8 28.75 29.02 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 4.22e3 PCB-56 5.99e7 29.61 PCB-60 2.59e7 29.80 1.84e7 PCB-77 9.09e6 32.79 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 5.38e7 32.30 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 2.35e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.36e7 ES-77 5.55e7 32.77 6.79e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 6.74e7 32.30 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.77e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.69e7 ES-77 6.95e7 32.77 8.45e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.10e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 3.55e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0251, 6569 scc: 505-842 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:37 (LKB) Printed: 30-Mar-2014 14:44 Page 9 of 21 111 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-96 8.82e5 25.72 Rel. Int. 100% Abs. Int. 2.13e5 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 9.74e2 1.07e5 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 1.37e6 25.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.59e5 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 9.14e2 1.80e5 0% 22.0 23.0 24.0 25.0 26.0 ES-104 4.58e7 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.11e7 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 3.25e3 5.54e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.91e7 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.04e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.76e3 3.52e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.07e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 2.04e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3600, 5723 scc: 505-842 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:37 (LKB) Printed: 30-Mar-2014 14:44 Page 10 of 21 112 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 2.84e3 PCB-95 2.41e7 27.98 0% PCB-91 6.48e6 28.74 PCB-84 9.82e6 PCB-102 28.93 2.07e6 28.30 28.0 113/90… 2.85e7 30.52 PCB-92 4.56e6 30.01 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 3.60e3 0% PCB-95 3.93e7 27.98 PCB-91 1.06e7 28.74 PCB-84 1.60e7 PCB-102 28.93 3.32e6 28.30 28.0 PCB-92 7.44e6 30.01 30.0 Rel. Int. 100% PCB-110 3.88e7 32.22 PCB-118 2.72e7 34.77 PCB-99 1.68e7108/119... 31.03 2.62e7 116/85 31.50 8.06e6 32.09 PCB-82 4.79e6 32.50 PCB-109 2.41e6 34.39 34.0 PCB-105 1.47e7 35.78 36.0 4.71e6 38.0 PCB-110 6.31e7 32.22 PCB-99 2.74e7108/119... 31.03 4.22e7 116/85 31.50 1.30e7 32.08 0.00e0 RT Abs. Int. 1.57e7 PCB-118 4.38e7 34.77 PCB-82 7.74e6 32.50 32.0 PCB-109 3.85e6 34.39 34.0 CS/SS-111 6.92e7 32.79 JS-101 5.56e7 30.50 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 3.85e3 Abs. Int. 9.41e6 32.0 113/90… 4.60e7 30.52 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-105 2.38e7 35.78 36.0 ES-118 ES-114 6.27e7 ES-123 6.11e7 35.21 6.12e7 34.75 34.47 7.86e6 38.0 0.00e0 RT Abs. Int. 1.68e7 ES-105 6.29e7 35.75 8.41e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.32e7 32.79 JS-101 3.53e7 30.50 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.36e3 34.0 36.0 ES-118 ES-114 ES-123 3.82e7 3.88e7 3.84e7 34.75 35.21 34.47 38.0 0.00e0 RT Abs. Int. 1.07e7 ES-105 3.96e7 35.76 5.33e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.10e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 3.55e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6412, 3067 scc: 505-842 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:22 Printed: 30-Mar-2014 14:44 Page 11 of 21 113 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 Rel. Int. 100% PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 2.17e3 Abs. Int. 4.27e5 2.14e5 PCB-126 1.40e5 38.38 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 9.43e5 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 1.87e3 4.72e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.34e7 ES-126 5.45e7 38.37 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 8.18e3 6.69e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.44e6 ES-126 3.54e7 38.37 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 5.45e3 4.22e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.20e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 2.10e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5701, 7828 scc: 505-842 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:22 Printed: 30-Mar-2014 14:44 Page 12 of 21 114 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Rel. Int. 100% Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 153/168 9.42e6 36.35 147/149 8.33e6 33.79 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.35e2 PCB-136 2.11e6 30.96 151/135 3.24e6 33.02 0% 28.0 30.0 PCB-144 5.43e5 33.50 32.0 PCB-134 6.28e5 33.97 PCB-132 4.01e6 34.87 34.0 36.0 PCB-136 1.64e6 30.96 151/135 2.59e6 33.02 38.0 153/168 7.48e6 36.35 147/149 6.57e6 33.79 PCB-134 4.82e5 33.97 PCB-132 3.16e6 34.87 Abs. Int. 2.78e6 PCB-141 PCB-158 1.84e6 PCB-164 1.70e6 9.92e5 36.52 37.75 37.15 PCB-146 1.56e6 35.83 Rel. Int. 100% HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 9.11e2 163/138… 1.24e7 37.42 163/138… 9.94e6 37.42 PCB-141 1.45e6 PCB-137 36.52 5.67e5 37.06 PCB-146 1.21e6 35.83 30.0 32.0 34.0 ES-155 5.74e7 30.33 Rel. Int. 100% 1.15e6 PCB-158 1.31e6 37.75 36.0 ES-153 4.08e7 36.33 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.89e3 0.00e0 RT Abs. Int. 2.30e6 0% 28.0 1.39e6 38.0 0.00e0 RT Abs. Int. 1.43e7 JS-138 3.82e7 37.40 7.13e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.55e7 30.33 Rel. Int. 100% ES-153 3.14e7 36.33 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.98e3 0.00e0 RT Abs. Int. 1.12e7 JS-138 3.01e7 37.39 5.59e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.10e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 3.55e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7550, 4267 scc: 505-842 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:37 (LKB) Printed: 30-Mar-2014 14:44 Page 13 of 21 115 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 128/166 2.23e6 38.50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 Abs. Int. 5.33e5 156/157 1.70e6 40.92 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 9.61e2 PCB-167 5.57e5 39.95 2.66e5 0% 39.0 Rel. Int. 100% 40.0 128/166 1.80e6 38.50 41.0 42.0 43.0 44.0 45.0 Abs. Int. 4.47e5 156/157 1.40e6 40.92 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 1.64e3 2.23e5 PCB-167 4.42e5 39.95 0% 39.0 Rel. Int. 100% 40.0 ES-167 5.21e7 39.93 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 1.04e4 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 9.88e7 40.91 0.00e0 RT Abs. Int. 1.73e7 ES-169 4.54e7 43.63 8.65e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 4.03e7 39.93 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 1.11e4 41.0 42.0 43.0 44.0 45.0 ES-156/157 7.77e7 40.91 0.00e0 RT Abs. Int. 1.38e7 ES-169 3.57e7 43.63 6.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.20e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 2.10e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7853, 8949 scc: 505-842 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:37 (LKB) Printed: 30-Mar-2014 14:44 Page 14 of 21 116 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-179 6.10e5 35.51 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 7.67e2 Abs. Int. 1.46e5 PCB-178 2.06e5 37.79 PCB-176 1.84e5 36.26 7.29e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 5.72e5 35.51 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.42e2 Abs. Int. 1.43e5 PCB-178 1.82e5 37.79 PCB-176 1.59e5 36.27 7.17e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.72e7 35.21 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 8.85e6 CS/SS-178 2.47e7 37.77 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.46e3 4.43e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.45e7 35.21 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.38e6 CS/SS-178 2.31e7 37.77 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.57e3 4.19e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.09e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 3.54e7 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1058, 0315 scc: 505-842 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:37 (LKB) Printed: 30-Mar-2014 14:45 Page 15 of 21 117 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 180/193 2.61e6 42.09 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 1.31e3 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-187 1.52e6 38.56 PCB-174 1.10e6 PCB-183 39.28 7.28e5 39.09 PCB-185 1.29e5 39.18 PCB-177 6.38e5 39.66 171/173 3.63e5 40.20 Abs. Int. 5.90e5 PCB-170 1.03e6 43.16 PCB-172 1.90e5 41.54 2.95e5 PCB-190 2.70e5 43.61 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 2.53e6 42.09 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 7.33e2 43.0 PCB-187 1.45e6 38.56 PCB-174 1.06e6 39.28 PCB-177 PCB-183 7.03e5 6.27e5 39.09 PCB-185 39.65 1.25e5 39.18 171/173 3.53e5 40.19 Abs. Int. 6.04e5 PCB-170 9.51e5 43.16 PCB-172 1.72e5 41.54 3.02e5 PCB-190 2.37e5 43.61 0% 39.0 40.0 41.0 42.0 ES-180 3.37e7 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 4.36e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.24e6 ES-170 2.79e7 43.14 4.12e6 0% 39.0 40.0 41.0 42.0 ES-180 3.13e7 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 4.31e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.51e6 ES-170 2.56e7 43.14 3.75e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.20e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 2.10e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1598, 1314 scc: 505-842 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:22 Printed: 30-Mar-2014 14:45 Page 16 of 21 118 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-189 6.08e4 45.77 Abs. Int. 1.76e4 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 1.48e3 8.80e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 5.75e4 45.77 Abs. Int. 1.65e4 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 1.06e3 8.23e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.03e7 45.75 0.00e0 RT Abs. Int. 9.74e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.26e3 4.87e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 3.85e7 45.75 0.00e0 RT Abs. Int. 9.45e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 5.25e3 4.72e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.79e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 3.90e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1877, 5068 scc: 505-842 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 16:22 (LKB) Printed: 30-Mar-2014 14:45 Page 17 of 21 119 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 198/199 3.72e5 43.75 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 6.93e2 PCB-202 1.38e5 39.76 PCB-201 8.30e4 40.55 Abs. Int. 9.08e4 PCB-196 1.71e5 44.30 PCB-203 2.27e5 44.47 4.54e4 PCB-197 PCB-200 2.95e4 6.60e4 41.40 41.32 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 4.30e5 43.74 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 8.06e2 PCB-202 1.56e5 39.77 PCB-201 1.01e5 40.55 PCB-197 3.18e4 41.31 Abs. Int. 9.35e4 PCB-196 1.94e5 44.30 PCB-200 7.68e4 41.41 PCB-203 2.35e5 44.47 4.67e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.23e7 39.74 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.52e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.66e3 3.76e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.57e7 39.74 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.47e3 4.24e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.20e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 2.10e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6087, 9228 scc: 505-842 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 16:23 (LKB) Printed: 30-Mar-2014 14:45 Page 18 of 21 120 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 PCB-194 2.92e5 47.53 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 6.59e2 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-195 1.04e5 45.59 Abs. Int. 6.73e4 3.36e4 PCB-205 1.92e4 47.94 0% 46.0 47.0 49.0 50.0 PCB-194 3.03e5 47.53 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 9.71e2 48.0 0.00e0 RT Abs. Int. 7.00e4 PCB-195 1.22e5 45.59 3.50e4 PCB-205 1.96e4 47.93 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.33e7 47.51 49.0 50.0 ES-205 2.64e7 47.91 0.00e0 RT Abs. Int. 6.46e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 3.79e3 3.23e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.60e7 47.51 49.0 50.0 ES-205 2.92e7 47.91 0.00e0 RT Abs. Int. 7.14e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 3.73e3 3.57e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.79e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 3.90e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4907, 3980 scc: 505-842 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:24 Printed: 30-Mar-2014 14:45 Page 19 of 21 121 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-208 1.46e5 45.39 NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.05e3 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-206 1.49e5 49.40 PCB-207 1.10e5 46.17 Abs. Int. 3.46e4 1.73e4 0% 46.0 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.34e3 PCB-208 1.73e5 45.39 47.0 48.0 49.0 50.0 PCB-206 1.94e5 49.40 PCB-207 1.56e5 46.17 Abs. Int. 5.16e4 2.58e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 6.42e6 ES-208 2.71e7 45.37 ES-206 1.67e7 49.37 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.30e3 3.21e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 8.10e6 ES-208 3.42e7 45.37 ES-206 2.05e7 49.38 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 3.13e3 4.05e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.79e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 3.90e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3320, 5089 scc: 505-842 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:38 (LKB) Printed: 30-Mar-2014 14:45 Page 20 of 21 122 of 622 SGS-AP ID: A6506_11899_PCB_002 Instr: AutoSpec-Premier MM7 Sample ID: PB070_B-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 50 Acq: 27-Mar-2014 15:13:30 User: LKB Datafile: 140327X06 PCB-209 3.26e6 50.83 Rel. Int. 100% Abs. Int. 6.94e5 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 7.25e2 3.47e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.80e6 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.99e5 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.57e2 3.00e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.52e7 50.81 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.50e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 8.73e2 2.75e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.12e7 50.81 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.56e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 1.25e3 2.28e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.16e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 3.58e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_002.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1989, 2957 scc: 505-842 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 16:24 Printed: 30-Mar-2014 14:45 Page 21 of 21 123 of 622 Lab ID: A6506_11899_PCB_003 ACQ: 27-Mar-2014 16:08:42 LKB Wt/Vol: 0.96 L Client ID: PB079-1SWMID-140314-N (TOTAL) UTP: 30-Mar-2014 13:53 LKB J-level: 10.4 pg/L Datafile: 140327X07 RPT: 30-Mar-2014 14:29 LB Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services Actual RT 32.79 32.32 35.77 35.23 34.76 34.49 38.38 40.91 39.94 NotFnd 45.76 50.82 11.87 14.16 14.41 20.12 17.49 26.44 20.40 32.77 32.29 25.37 35.75 35.21 34.74 34.46 38.36 36.33 30.32 40.91 39.92 43.62 43.13 42.07 35.20 45.74 39.74 47.91 49.37 45.36 50.80 QC J J C J J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0008 1.0006 1.0006 1.0006 1.0007 1.0005 1.0002 1.0005 1.0004 1.0004 0 +0.6 0 -0.2 0 +0.2 0 -0.7 -0.2 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7245 0.8640 0.8793 1.2277 1.0673 1.0790 0.8325 1.3371 1.3177 0.8322 1.1724 1.1547 1.1394 1.1302 1.2580 0.9716 0.8111 1.0941 1.0678 1.1667 0.9080 0.8855 0.7410 0.9629 0.8364 1.0084 1.0392 0.9548 1.0694 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Split: 1 Checkcode: 109-950-QPX Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.78 0.72 0.62 0.64 0.61 0.59 0.70 1.26 1.18 0 0 7.49E+06 2.98E+05 1.92E+07 1.16E+06 3.50E+07 1.05E+06 1.57E+05 1.55E+06 5.07E+05 0.00E+00 6.86E+04 3.29E+06 0.92 1.20 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 101 4.33 320 18.1 571 16.7 3.1 30.9 9.03 ND 1.56 121 6.85E+03 6.85E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 3.61E+03 2.42E+03 2.42E+03 2.42E+03 2.02E+03 1.28E+03 0.959 1.03 0.727 0.693 0.725 0.709 0.746 0.675 0.462 0.533 0.487 0.553 0 0 -0.2 +0.7 0 +0.5 -0.4 +1.4 +1.4 -0.5 +0.9 +0.8 +0.6 +0.6 +1.2 0 -0.5 +0.5 +0.2 +0.8 -0.3 -0.3 -0.6 0 -0.5 0 0 -0.3 0 8.19E+07 9.88E+07 5.35E+07 1.60E+08 6.14E+07 1.44E+08 6.78E+07 1.34E+08 1.28E+08 7.50E+07 1.12E+08 1.11E+08 1.07E+08 1.08E+08 9.53E+07 7.57E+07 1.03E+08 1.90E+08 1.01E+08 8.78E+07 5.84E+07 7.02E+07 7.33E+07 8.55E+07 7.14E+07 6.12E+07 4.07E+07 6.72E+07 5.07E+07 3.26 3.30 1.60 1.59 1.06 1.10 0.78 0.81 0.79 1.59 1.62 1.60 1.57 1.57 1.59 1.28 1.29 1.28 1.28 1.27 1.08 1.08 1.07 1.04 0.90 0.89 0.80 0.79 1.17 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 42.5 % 56.3 % 63.4 % 95.1 % 75.1 % 82.5 % 75.1 % 92.1 % 89.5 % 93.2 % 93 % 90.9 % 92.2 % 90.5 % 92.6 % 85.4 % 82.3 % 75.6 % 76.6 % 71.7 % 88.1 % 87.7 % 99.1 % 94.4 % 93.5 % 86 % 85.7 % 100 % 79.8 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Page 1 of 5 Printed: 3/30/2014 2:33 PM 124 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.89 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 1.71E+08 1.25E+08 5.34E+07 1.08 1.59 1.06 1.11 1.03 0.62 107 % 113 % 118 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.89 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 1.71E+08 1.25E+08 5.34E+07 1.08 1.59 1.06 1.85 1.22 0.58 88.5 % 103 % 117 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.39 24.51 30.49 37.39 47.51 1.62E+08 1.05E+08 1.00E+08 7.87E+07 5.73E+07 1.56 0.79 1.60 1.32 0.90 5.82E+03 5.82E+03 5.82E+03 9.63E+03 9.63E+03 1.12E+04 1.12E+04 1.12E+04 1.12E+04 1.12E+04 1.12E+04 1.12E+04 1.12E+04 1.12E+04 6.86E+03 6.86E+03 6.86E+03 6.86E+03 6.86E+03 6.86E+03 6.86E+03 0.952 0.743 0.881 2.27 1.47 1.33 1.18 1.26 1.25 1.22 1.05 1.22 1.23 1.32 1.7 1.27 1.48 1.09 1.15 1.93 1.03 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services 11.89 13.99 14.17 14.43 14.61 16.41 16.57 16.80 17.10 17.22 NotFnd 19.56 19.83 20.13 17.51 19.28 19.67 19.86 19.99 20.09 20.57 J J J J B C C J 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0011 0.9879 1.0010 1.0011 1.0136 1.0010 1.0112 1.0249 1.0433 1.0507 0.9720 0.9855 1.0006 1.0010 1.1020 1.1246 1.1356 1.1426 1.1487 1.1762 0 -0.1 0 0 +0.1 0 +0.1 0 0 +0.1 -0.1 -1.3 -0.2 0 +0.7 +0.4 +0.4 -0.5 +0.4 +0.5 Page 2 of 5 NON-EMPC 61.2 746 7,160 14,100 5,540 1,170 271 63.8 18.5 1.87E+06 1.91E+05 3.88E+05 9.50E+06 5.69E+05 9.35E+05 5.08E+05 5.65E+06 2.52E+05 1.50E+07 0.00E+00 2.38E+06 1.95E+06 9.12E+06 6.51E+06 7.50E+07 2.20E+07 5.44E+06 4.58E+05 1.75E+07 3.04E+07 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 61.2 746 7,170 14,100 5,540 1,180 282 66.1 18.5 3.27 3.21 3.25 1.57 SI SI SI 1.63 SI 1.64 1.62 1.54 1.65 1.02 1.04 1.06 1.08 1.07 1.05 1.07 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 0.916 1.79 1.53 0.758 0.663 0.486 0.532 0.508 1.18 49.8 3.36 8.1 300 11.6 12 5.81 69.1 3.05 177 ND 28.1 23.1 116 192 1,660 564 102 9.1 585 543 Printed: 3/30/2014 2:33 PM 125 of 622 Name PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB SGS Evironmental Services Actual RT 21.72 NotFnd 22.13 22.36 22.63 22.91 23.12 23.48 NotFnd 25.22 25.72 26.10 26.46 20.42 22.38 23.00 23.08 23.28 24.53 24.66 24.75 24.97 25.23 25.42 25.71 25.89 26.22 26.32 26.52 27.23 27.49 27.86 28.07 28.22 28.45 28.75 29.02 29.17 29.60 29.80 NotFnd NotFnd NotFnd NotFnd 25.72 27.40 27.59 27.98 QC J C C C J J EMPC J C J C C C C J J J C J J Pred RRT Actual RRT Diff Secs 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8215 0.8371 0.8455 0.8560 0.8664 0.8744 0.8878 0.9540 0.9728 0.9871 1.0009 1.0009 0.9134 0.9385 0.9416 0.9498 1.0009 1.0061 1.0101 1.0189 1.0296 1.0374 1.0493 1.0564 1.0698 1.0739 1.0820 0.8433 0.8513 0.8628 0.8693 0.8740 0.8810 0.8902 0.8987 0.9033 0.9167 0.9227 1.0134 0.8988 0.9050 0.9175 -0.4 -1.6 -0.1 -0.3 -0.8 +0.8 -0.3 +2.7 +0.8 0 +0.3 -0.1 -1.5 +0.3 +0.4 -0.1 0 -0.1 0 +1.2 +0.2 -1.5 -0.5 +0.2 0 +0.3 +0.2 -0.5 -0.3 -0.3 0 -0.2 -0.2 0 -0.3 -0.2 -0.4 -0.4 0 -0.2 -0.2 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 4.47E+05 0.00E+00 1.76E+07 9.35E+06 1.08E+08 1.02E+08 2.84E+07 2.64E+07 0.00E+00 9.28E+05 2.47E+05 1.34E+06 1.51E+07 3.56E+05 2.00E+07 1.82E+07 4.69E+06 6.46E+06 1.24E+08 3.00E+05 3.42E+06 7.50E+07 2.05E+07 1.14E+08 1.08E+07 2.51E+07 6.48E+06 5.00E+07 6.11E+07 6.70E+05 2.15E+06 4.21E+05 2.44E+05 2.35E+06 3.97E+06 1.80E+08 1.02E+08 9.15E+05 4.99E+07 2.16E+07 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.03E+06 3.32E+05 4.08E+05 2.93E+07 1.07 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 5.08 ND 198 105 1,160 1,180 320 318 ND 9.9 2.95 16.8 203 8.1 351 370 82.3 143 2,260 4.14 72 1,110 367 1,930 140 490 144 874 752 8.43 25.6 5.56 3.14 29.2 47.4 2,350 1,420 12.6 697 299 ND ND ND ND 23.8 6.78 9.94 655 1.02 0.99 1.01 1.01 1.01 1.00 1.02 1.48 1.07 1.03 0.85 0.80 0.78 0.82 0.78 0.79 0.79 0.78 0.79 0.78 0.79 0.80 0.80 0.77 0.80 0.78 0.67 0.79 0.74 0.88 0.77 0.78 0.79 0.79 0.75 0.79 0.78 0.62 0.54 0.61 0.62 Noise / Recv. Low DL / Recv. High 9.88E+03 9.88E+03 9.88E+03 9.88E+03 9.88E+03 9.88E+03 9.88E+03 9.88E+03 9.88E+03 9.88E+03 9.88E+03 9.88E+03 9.88E+03 2.78E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 3.32E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 6.85E+03 2.05E+03 2.05E+03 4.29E+03 4.29E+03 4.29E+03 1.14 1.14 1.13 1.13 1.08 1.16 1.13 1.21 1.1 1.07 1.19 1.26 1.35 0.575 0.602 0.696 0.602 0.76 0.623 0.472 0.722 0.507 0.614 0.577 0.446 0.67 0.763 0.599 0.423 0.891 0.842 0.935 0.913 0.88 0.846 0.925 0.987 0.979 0.989 0.979 0.841 0.834 1.04 0.379 0.453 0.907 1.08 0.993 Printed: 3/30/2014 2:33 PM 126 of 622 Name Actual RT PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB 28.19 28.30 28.38 NotFnd 28.73 28.93 29.34 NotFnd 30.01 30.51 30.92 31.02 31.14 31.50 32.00 32.08 32.21 32.30 32.49 NotFnd NotFnd 34.17 34.38 34.59 35.06 NotFnd 30.35 30.51 30.65 30.95 NotFnd NotFnd 33.01 33.22 33.49 33.79 33.97 34.06 34.30 34.49 NotFnd 34.86 35.27 NotFnd 35.82 NotFnd 36.35 36.51 SGS Evironmental Services QC J C J C J C C C J J EMPC J J C J C J J C J EMPC J C Pred RRT Actual RRT Diff Secs 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9246 0.9280 0.9308 0.9423 0.9487 0.9624 0.9841 1.0007 1.0141 1.0174 1.0213 1.0329 1.0495 1.0521 1.0563 1.0592 1.0657 0.9916 0.9976 1.0038 1.0090 1.0009 1.0061 1.0107 1.0208 1.0886 1.0956 1.1043 1.1142 1.1201 1.1231 1.1312 1.1372 1.1497 1.1630 0.9581 0.9721 0.9766 0 -0.3 +0.5 -0.2 0 0 0 +1.5 -0.2 +0.2 +1.3 +1.7 0 -0.8 +0.4 +0.4 +0.4 0 0 0 -0.2 +0.4 +0.2 0 +0.2 0 +0.4 +0.4 +0.2 +0.4 +1.2 0 +0.6 +0.6 +0.8 -0.2 -1.5 0 Page 4 of 5 Response Ra RRF Conc. / Recv. 5.96E+05 2.55E+06 7.85E+04 0.00E+00 7.99E+06 1.16E+07 1.24E+06 0.00E+00 5.70E+06 3.53E+07 1.96E+06 2.10E+07 1.21E+05 3.24E+07 1.42E+06 1.03E+07 4.95E+07 1.78E+06 6.09E+06 0.00E+00 0.00E+00 1.49E+06 2.96E+06 7.87E+04 7.57E+05 0.00E+00 2.70E+04 4.38E+04 3.09E+04 1.86E+06 0.00E+00 0.00E+00 2.88E+06 1.33E+05 5.13E+05 7.58E+06 5.52E+05 5.91E+04 2.59E+05 1.58E+05 0.00E+00 3.57E+06 1.42E+05 0.00E+00 1.44E+06 0.00E+00 9.03E+06 1.72E+06 0.58 0.62 0.57 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 13.2 47.3 2.09 ND 169 311 31.3 ND 134 695 53 447 2.01 630 26.2 203 860 30.1 170 ND ND 26.4 46.2 1.41 14.2 ND 0.433 0.801 0.557 36.7 ND ND 74.2 2.93 12.8 188 19.3 1.47 6.4 4.63 ND 101 3.74 ND 34.7 ND 179 45.7 0.62 0.61 0.60 0.61 0.62 0.60 0.62 0.59 0.61 0.59 0.62 0.61 0.62 0.62 0.65 0.61 0.58 0.62 0.97 1.07 1.16 1.24 1.32 1.38 1.21 1.26 1.39 1.27 1.25 1.03 1.29 1.23 1.35 1.27 1.27 Noise / Recv. Low DL / Recv. High 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 4.29E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 0.981 0.824 1.18 1.08 0.939 1.19 1.12 0.704 1.04 0.874 1.2 0.946 0.734 0.862 0.817 0.873 0.77 0.749 1.24 0.713 0.702 0.784 0.692 0.797 0.83 0.744 0.272 0.31 0.306 0.334 0.327 0.422 0.446 0.381 0.431 0.429 0.603 0.43 0.428 0.505 0.513 0.49 0.455 0.363 0.417 0.335 0.342 0.459 Printed: 3/30/2014 2:33 PM 127 of 622 Name Actual RT PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.86 37.05 37.14 37.41 NotFnd 37.75 38.49 39.28 39.54 NotFnd 35.50 NotFnd 36.26 NotFnd 37.79 38.33 38.56 NotFnd 39.08 39.17 39.28 39.65 NotFnd 40.19 41.53 NotFnd 42.08 42.38 43.15 43.61 39.76 40.54 NotFnd 41.30 41.40 43.74 44.30 44.46 45.58 47.53 NotFnd 45.38 46.17 49.40 SGS Evironmental Services QC C C J J J J J J J EMPC C J C J J J J EMPC J J J C J J J J J Pred RRT Actual RRT Diff Secs 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9859 0.9910 0.9933 1.0007 1.0096 0.9642 0.9839 0.9904 1.0086 1.0301 1.0734 1.0890 1.0954 1.1102 1.1128 1.1158 1.1264 1.1416 0.9079 0.9200 0.9265 0.9434 0.9533 1.0005 1.0201 1.0395 1.0418 1.1007 1.1149 1.1190 0.9516 0.9921 1.0005 1.0178 1.0006 0 -0.2 0 -0.9 0 +0.2 -1.2 +0.2 0 +0.2 +0.2 +0.7 +0.5 +0.2 +0.7 +0.5 +0.5 +0.7 -0.2 +1.5 -0.3 0 0 0 -0.5 -0.2 0 +1.6 +0.8 +0.5 0 0 0 0 +0.6 Page 5 of 5 Response Ra RRF Conc. / Recv. 7.04E+05 5.99E+05 1.01E+06 1.17E+07 0.00E+00 1.57E+06 2.11E+06 1.09E+05 6.71E+04 0.00E+00 6.20E+05 0.00E+00 1.97E+05 0.00E+00 2.09E+05 7.08E+04 1.61E+06 0.00E+00 8.22E+05 1.09E+05 1.21E+06 6.72E+05 0.00E+00 3.46E+05 1.97E+05 0.00E+00 2.86E+06 6.57E+04 1.09E+06 2.92E+05 1.70E+05 8.84E+04 0.00E+00 3.03E+04 8.12E+04 4.59E+05 2.19E+05 2.81E+05 1.26E+05 3.30E+05 0.00E+00 1.74E+05 1.58E+05 2.05E+05 1.17 1.25 1.33 1.28 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 21.1 14.5 20 290 ND 28.9 48.9 2.1 1.3 ND 16.3 ND 4.9 ND 7.84 1.94 41.5 ND 19.9 3.12 36.5 21.1 ND 10.9 6.01 ND 68.3 1.44 34.2 6.69 4.71 2.27 ND 0.781 2.2 18.6 8.37 10.6 5.36 13.2 ND 4.79 4.31 9.42 1.27 1.23 1.25 1.26 0.98 1.05 1.05 1.12 1.08 1.14 1.03 1.06 1.06 1.20 0.96 1.08 1.15 1.02 1.00 0.80 0.73 0.88 0.97 0.94 0.95 0.82 0.89 0.87 0.88 0.78 0.70 Noise / Recv. Low DL / Recv. High 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 2.42E+03 2.42E+03 2.42E+03 1.42E+03 1.42E+03 1.42E+03 1.42E+03 1.42E+03 1.42E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 2.25E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.57E+03 1.67E+03 1.67E+03 1.67E+03 3.08E+03 3.08E+03 3.08E+03 0.517 0.418 0.344 0.427 0.364 0.317 0.602 0.501 0.505 0.325 0.382 0.403 0.362 0.387 0.545 0.623 0.585 0.565 0.551 0.651 0.685 0.711 0.629 0.711 0.693 0.533 0.542 0.498 0.752 0.549 0.452 0.42 0.452 0.421 0.444 0.661 0.623 0.617 0.751 0.702 0.564 0.888 0.88 1.48 Printed: 3/30/2014 2:33 PM 128 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 1.80e8 8.98e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 4.28e7 2.14e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 3.52e7 1.76e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 6.33e7 3.16e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 3.74e7 1.87e7 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 6.76e6 3.38e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 6.20e6 3.10e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 109-950 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:45 Page 1 of 21 129 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 PCB-1 1.43e6 11.89 Rel. Int. 100% Abs. Int. 5.89e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.29e3 2.94e5 PCB-3 2.97e5 14.17 PCB-2 1.46e5 13.99 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 4.37e5 11.88 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.93e5 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 2.53e3 9.67e4 PCB-3 9.14e4 14.17 PCB-2 4.53e4 13.99 0% 11.0 12.0 13.0 15.0 ES-3 7.59e7 14.16 ES-1 6.27e7 11.87 Rel. Int. 100% 14.0 0.00e0 16.0 RT Abs. Int. 2.62e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 6.89e3 1.31e7 0% 11.0 12.0 13.0 ES-1 1.92e7 11.87 Rel. Int. 100% 14.0 15.0 ES-3 2.30e7 14.16 0.00e0 16.0 RT Abs. Int. 8.08e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 5.01e4 4.04e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.80e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 8.98e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8459, 3561 scc: 109-950 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 17:16 (LKB) Printed: 30-Mar-2014 14:45 Page 2 of 21 130 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Rel. Int. 100% Abs. Int. 1.99e6 PCB-4 5.80e6 14.43 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.87e3 9.94e5 PCB-10 3.47e5 SI 14.61 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 3.70e6 14.43 Rel. Int. 100% DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 3.04e4 0.00e0 16.0 RT Abs. Int. 1.29e6 6.43e5 PFK INTERFERENCE 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.29e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.10e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.08e3 5.52e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.06e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.85e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.12e3 3.42e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.80e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 8.98e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9701, 9144 scc: 109-950 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:34 (LKB) Printed: 30-Mar-2014 14:45 Page 3 of 21 131 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 PCB-8 9.28e6 17.22 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 6.85e3 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Abs. Int. 2.75e6 PCB-15 5.68e6 20.13 PCB-6 3.50e6 16.80 PCB-11 1.47e6 19.56 PCB-9 5.70e5 SI 16.41 1.38e6 13/12 1.18e6 19.83 0% 17.0 19.0 20.0 21.0 PCB-8 5.67e6 17.22 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 4.85e4 18.0 Abs. Int. 1.83e6 PCB-6 2.15e6 PFK INTERFERENCE 16.80 PCB-11 9.07e5 19.56 PCB-15 3.45e6 20.13 13/12 7.67e5 19.83 9.15e5 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 9.85e7 16.39 20.0 21.0 ES-15 9.82e7 20.12 0.00e0 RT Abs. Int. 3.01e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.91e4 1.50e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 6.32e7 16.39 20.0 21.0 0.00e0 RT Abs. Int. 1.95e7 ES-15 6.18e7 20.12 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 6.05e3 9.75e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.28e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 2.14e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0178, 0618 scc: 109-950 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:35 (LKB) Printed: 30-Mar-2014 14:45 Page 4 of 21 132 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Rel. Int. 100% Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Abs. Int. 1.08e7 30/18 3.83e7 19.28 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.90e3 PCB-17 1.13e7 19.67 PCB-19 3.28e6 17.51 PCB-27 2.83e6 19.86 PCB-16 8.95e6 20.09 PCB-32 1.57e7 20.57 5.41e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 1.04e7 30/18 3.67e7 19.28 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.97e3 PCB-17 1.07e7 19.67 PCB-19 3.23e6 17.51 PCB-27 2.61e6 19.86 PCB-16 8.53e6 20.09 PCB-32 1.47e7 20.57 5.22e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 3.16e7 17.49 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 9.54e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 8.34e4 4.77e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.98e7 17.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.64e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 6.06e4 4.32e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.28e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 2.14e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9796, 2948 scc: 109-950 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 17:16 (LKB) Printed: 30-Mar-2014 14:45 Page 5 of 21 133 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 PCB-31 5.40e7 28/20 22.63 5.10e7 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 5.69e3 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 26/29 8.86e6 22.13 Abs. Int. 1.45e7 21/33 1.43e7 23.12 PCB-25 4.65e6 22.36 7.26e6 PCB-22 1.32e7 23.48 PCB-37 7.64e6 26.46 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 5.37e7 28/20 22.63 5.06e7 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 4.19e3 24.0 26/29 8.73e6 22.13 PCB-25 4.70e6 22.36 Abs. Int. 1.45e7 21/33 1.42e7 23.12 7.25e6 PCB-22 1.32e7 23.47 PCB-37 7.45e6 26.46 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.87e7 22.89 Rel. Int. 100% ES-37 7.52e7 26.44 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 7.99e4 Abs. Int. 2.29e7 1.15e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 8.24e7 22.89 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 6.85e7 26.44 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 5.44e4 Abs. Int. 2.12e7 1.06e7 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.52e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.76e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7997, 4226 scc: 109-950 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 17:16 (LKB) Printed: 30-Mar-2014 14:45 Page 6 of 21 134 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 PCB-54 1.64e5 20.42 Rel. Int. 100% Abs. Int. 4.43e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.30e3 2.22e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.93e5 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.52e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.48e3 3.26e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.96e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.15e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 9.53e3 4.07e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.81e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 7.82e3 5.25e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.28e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 2.14e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4375, 6394 scc: 109-950 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 17:16 Printed: 30-Mar-2014 14:45 Page 7 of 21 135 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Rel. Int. 100% PCB-52 5.47e7 24.53 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.45e3 50/53 8.86e6 22.38 PCB-51 2.11e6 23.08 PCB-45 8.02e6 23.00 69/49 3.30e7 24.97 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 PCB-48 8.99e6 25.23 PCB-46 2.83e6 23.28 Abs. Int. 1.44e7 44/47… 5.04e7 25.42 PCB-42 1.12e7 25.89 71/40 2.22e7 26.32 PCB-41 2.82e6 26.22 PCB-64 2.68e7 26.52 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 6.95e7 24.53 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.87e3 50/53 1.11e7 22.38 PCB-51 2.58e6 23.08 PCB-45 1.02e7 23.00 69/49 4.20e7 24.97 PCB-46 3.62e6 23.28 Abs. Int. 1.80e7 44/47… 6.41e7 25.42 PCB-42 1.39e7 25.89 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.63e7 24.51 Rel. Int. 100% 0.00e0 RT 26.0 PCB-48 1.15e7 25.23 7.18e6 71/40 2.79e7 26.32 PCB-41 3.66e6 26.22 PCB-64 3.42e7 26.52 9.01e6 0.00e0 RT Abs. Int. 1.23e7 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.59e4 6.14e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 5.84e7 24.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.57e4 7.59e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.52e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.76e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2925, 5381 scc: 109-950 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 17:16 (LKB) Printed: 30-Mar-2014 14:45 Page 8 of 21 136 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Abs. Int. 1.49e7 61/70... 7.94e7 PCB-66 28.75 4.48e7 29.02 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 3.40e3 PCB-56 2.20e7 29.60 PCB-60 9.52e6 29.80 7.46e6 PCB-77 3.28e6 32.79 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 1.89e7 61/70... 1.00e8 PCB-66 28.74 5.69e7 29.02 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 3.44e3 PCB-56 2.79e7 29.60 PCB-60 1.21e7 29.80 9.43e6 PCB-77 4.22e6 32.79 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 5.67e7 32.29 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 2.24e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.45e7 ES-77 5.99e7 32.77 7.24e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 7.14e7 32.29 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.68e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.78e7 ES-77 7.36e7 32.77 8.92e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.33e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 3.16e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5502, 0913 scc: 109-950 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 17:16 Printed: 30-Mar-2014 14:45 Page 9 of 21 137 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 PCB-96 3.93e5 25.72 Rel. Int. 100% Abs. Int. 1.04e5 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 9.09e2 5.20e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 6.33e5 25.71 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e5 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 1.14e3 8.24e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 4.61e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e7 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 2.88e3 6.04e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.89e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.18e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 2.71e3 3.59e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.52e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.76e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4040, 0833 scc: 109-950 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 17:16 Printed: 30-Mar-2014 14:45 Page 10 of 21 138 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.72e3 PCB-95 1.12e7 27.98 0% 113/90… 1.35e7 30.51 PCB-91 3.05e6 28.73 PCB-84 4.43e6 PCB-102 28.93 9.78e5 28.30 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 2.57e3 32.0 113/90… 2.18e7 30.51 PCB-95 1.81e7 27.98 PCB-91 4.94e6 28.73 PCB-84 7.21e6 28.93 PCB-110 1.88e7 32.21 PCB-99108/119... 8.00e6 1.24e7 31.02 31.50 116/85 3.93e6 PCB-115PCB-82 32.08 6.81e5 2.33e6 32.30 32.49 PCB-92 2.15e6 30.01 Abs. Int. 4.63e6 PCB-118 1.33e7 34.76 PCB-109 1.12e6 34.38 34.0 PCB-105 7.32e6 35.77 36.0 2.32e6 38.0 PCB-110 3.07e7 32.21 PCB-99108/119... 1.30e7 2.01e7 31.02 31.49 116/85 6.37e6 PCB-115PCB-82 32.08 1.10e6 3.76e6 32.30 32.49 PCB-92 3.55e6 30.00 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Abs. Int. 7.70e6 PCB-118 2.17e7 34.76 PCB-109 1.84e6 34.38 PCB-105 1.18e7 35.77 3.85e6 0% 28.0 30.0 Rel. Int. 100% 32.0 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 3.63e3 34.0 36.0 CS/SS-111 7.70e7 32.78 JS-101 6.17e7 30.49 0.00e0 RT ES-114 6.82e7 35.21 ES-123 6.58e7 34.46 38.0 0.00e0 RT Abs. Int. 1.92e7 ES-105 6.93e7 35.75 9.60e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.85e7 32.78 JS-101 3.85e7 30.49 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 3.56e3 34.0 36.0 ES-118 ES-123 4.16e7 4.18e7 34.74 34.46 38.0 0.00e0 RT Abs. Int. 1.20e7 ES-105 4.27e7 35.75 6.00e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.33e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 3.16e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5748, 4337 scc: 109-950 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 17:16 Printed: 30-Mar-2014 14:45 Page 11 of 21 139 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Rel. Int. 100% Abs. Int. 5.79e5 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 1.27e3 2.89e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 1.29e6 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 2.34e3 6.46e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.40e7 ES-126 5.86e7 38.36 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 8.42e3 6.99e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 9.00e6 ES-126 3.68e7 38.36 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 7.94e3 4.50e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.74e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.87e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9955, 1910 scc: 109-950 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 17:16 Printed: 30-Mar-2014 14:45 Page 12 of 21 140 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Rel. Int. 100% Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 153/168 5.06e6 36.35 147/149 4.23e6 33.79 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 8.64e2 PCB-136 1.03e6 30.95 PCB-132 2.01e6 34.86 151/135 1.64e6 33.01 163/138… 6.58e6 37.41 PCB-141 9.61e5 PCB-137 36.51 3.33e5 37.05 PCB-146 8.25e5 35.82 Abs. Int. 1.57e6 7.86e5 PCB-158 8.79e5 37.75 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% 36.0 153/168 3.97e6 36.35 147/149 3.35e6 33.79 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 8.49e2 PCB-136 8.31e5 30.95 38.0 PCB-132 1.56e6 34.86 151/135 1.24e6 33.01 163/138… 5.16e6 37.41 Abs. Int. 1.20e6 PCB-141 PCB-158 7.58e5 PCB-164 6.93e5 4.32e5 36.51 37.75 37.13 PCB-146 6.11e5 35.82 0% 28.0 30.0 32.0 34.0 ES-155 5.81e7 30.32 Rel. Int. 100% 36.0 ES-153 4.26e7 36.33 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.54e3 0.00e0 RT 38.0 6.01e5 0.00e0 RT Abs. Int. 1.47e7 JS-138 4.47e7 37.39 7.33e6 0% 28.0 30.0 32.0 34.0 ES-155 4.49e7 30.32 Rel. Int. 100% 36.0 ES-153 3.32e7 36.33 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.93e3 38.0 0.00e0 RT Abs. Int. 1.15e7 JS-138 3.40e7 37.39 5.76e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.33e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 3.16e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7206, 4779 scc: 109-950 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:35 (LKB) Printed: 30-Mar-2014 14:45 Page 13 of 21 141 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 128/166 1.17e6 38.49 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Abs. Int. 2.67e5 156/157 8.64e5 40.91 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 1.34e3 PCB-159 6.05e4 39.28 PCB-167 2.75e5 39.94 1.33e5 0% 39.0 Rel. Int. 100% 40.0 128/166 9.48e5 38.49 41.0 42.0 43.0 44.0 45.0 Abs. Int. 2.13e5 156/157 6.88e5 40.91 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 1.08e3 PCB-159 4.85e4 39.28 0% 39.0 1.07e5 PCB-167 2.32e5 39.94 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.07e8 40.91 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.90e7 ES-167 5.65e7 39.92 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 9.92e3 0.00e0 RT ES-169 4.91e7 43.62 9.52e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 4.42e7 39.92 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 1.01e4 41.0 42.0 43.0 44.0 45.0 ES-156/157 8.36e7 40.91 0.00e0 RT Abs. Int. 1.48e7 ES-169 3.87e7 43.62 7.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.74e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.87e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1626, 0365 scc: 109-950 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 30-Mar-2014 14:45 Page 14 of 21 142 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 PCB-179 3.07e5 35.50 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 7.25e2 Abs. Int. 6.95e4 PCB-176 1.00e5 36.26 PCB-178 1.07e5 37.79 3.47e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 3.13e5 35.50 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.95e2 Abs. Int. 7.70e4 PCB-178 1.02e5 37.78 PCB-176 9.61e4 36.26 3.85e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.80e7 35.20 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 9.27e6 CS/SS-178 2.75e7 37.76 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.59e3 4.63e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.53e7 35.20 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.56e6 CS/SS-178 2.59e7 37.76 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.95e3 4.28e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.28e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 3.14e7 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0765, 6647 scc: 109-950 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:35 (LKB) Printed: 30-Mar-2014 14:45 Page 15 of 21 143 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 180/193 1.48e6 42.08 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 1.10e3 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 PCB-187 8.34e5 38.56 PCB-174 6.23e5 PCB-183 39.28 4.37e5 39.08 PCB-185 5.52e4 39.17 PCB-177 3.46e5 39.65 171/173 2.04e5 40.19 Abs. Int. 3.49e5 PCB-170 5.50e5 43.15 PCB-172 9.61e4 41.53 1.75e5 PCB-190 1.46e5 43.61 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 1.37e6 42.08 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 1.14e3 43.0 PCB-187 7.75e5 38.56 PCB-174 5.85e5 39.28 PCB-183 3.85e5 39.08 PCB-185 5.35e4 39.17 PCB-177 3.26e5 39.65 171/173 1.70e5 40.19 Abs. Int. 3.19e5 PCB-170 5.41e5 43.15 PCB-172 1.01e5 41.53 1.60e5 PCB-190 1.46e5 43.60 0% 39.0 40.0 41.0 42.0 ES-180 3.65e7 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 6.30e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 9.04e6 ES-170 3.03e7 43.13 4.52e6 0% 39.0 40.0 41.0 42.0 ES-180 3.37e7 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 2.05e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.27e6 ES-170 2.82e7 43.13 4.14e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.74e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.87e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0907, 0148 scc: 109-950 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 17:16 Printed: 30-Mar-2014 14:45 Page 16 of 21 144 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 PCB-189 3.30e4 45.76 Abs. Int. 8.19e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 9.82e2 4.10e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 3.57e4 45.76 Abs. Int. 9.28e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 1.04e3 4.64e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.37e7 45.74 0.00e0 RT Abs. Int. 1.03e7 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 5.67e3 5.14e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.19e7 45.74 0.00e0 RT Abs. Int. 9.65e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 5.30e3 4.83e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 3.38e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6018, 6420 scc: 109-950 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 17:16 Printed: 30-Mar-2014 14:45 Page 17 of 21 145 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 198/199 2.23e5 43.74 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 8.01e2 PCB-202 7.59e4 39.76 PCB-201 4.16e4 40.54 Abs. Int. 5.01e4 PCB-196 1.07e5 44.30 PCB-197 1.42e4 41.30 PCB-203 1.27e5 44.46 2.51e4 PCB-200 4.00e4 41.40 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 2.36e5 43.74 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 7.66e2 PCB-202 9.43e4 39.76 PCB-201 5.71e4 40.54 Abs. Int. 5.59e4 PCB-196 1.12e5 44.29 PCB-197 PCB-200 4.11e4 1.61e4 41.39 41.31 PCB-203 1.54e5 44.46 2.79e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.38e7 39.74 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 8.10e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.23e3 4.05e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.76e7 39.74 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.05e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.68e3 4.52e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.74e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.87e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1406, 6150 scc: 109-950 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 17:17 (LKB) Printed: 30-Mar-2014 14:45 Page 18 of 21 146 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 PCB-194 1.54e5 47.53 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 7.96e2 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Abs. Int. 3.69e4 PCB-195 5.91e4 45.58 1.85e4 0% 46.0 47.0 49.0 50.0 PCB-194 1.77e5 47.53 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 8.69e2 48.0 0.00e0 RT Abs. Int. 4.17e4 PCB-195 6.65e4 45.58 2.09e4 0% 46.0 47.0 48.0 JS-194 2.71e7 47.51 Rel. Int. 100% 49.0 50.0 ES-205 2.89e7 47.91 0.00e0 RT Abs. Int. 6.84e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 3.19e3 3.42e6 0% 46.0 47.0 48.0 JS-194 3.01e7 47.51 Rel. Int. 100% 49.0 50.0 ES-205 3.23e7 47.91 0.00e0 RT Abs. Int. 7.72e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 4.92e3 3.86e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 3.38e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7940, 4712 scc: 109-950 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 17:17 (LKB) Printed: 30-Mar-2014 14:45 Page 19 of 21 147 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-208 8.13e4 45.38 NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 8.82e2 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 Abs. Int. 2.11e4 PCB-206 8.44e4 49.40 PCB-207 6.92e4 46.17 1.06e4 0% 46.0 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.20e3 PCB-208 9.25e4 45.38 47.0 48.0 49.0 50.0 PCB-206 1.21e5 49.39 PCB-207 8.87e4 46.17 Abs. Int. 2.97e4 1.49e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 7.10e6 ES-208 2.97e7 45.36 ES-206 1.81e7 49.37 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.94e3 3.55e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 8.81e6 ES-208 3.75e7 45.36 ES-206 2.26e7 49.37 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.81e3 4.40e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 3.38e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9636, 6700 scc: 109-950 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 17:17 (LKB) Printed: 30-Mar-2014 14:45 Page 20 of 21 148 of 622 SGS-AP ID: A6506_11899_PCB_003 Instr: AutoSpec-Premier MM7 Sample ID: PB079-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 51 Acq: 27-Mar-2014 16:08:42 User: LKB Datafile: 140327X07 PCB-209 1.80e6 50.82 Rel. Int. 100% Abs. Int. 3.84e5 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 6.20e2 1.92e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.50e6 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.16e5 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.61e2 1.58e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.74e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.84e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.11e3 2.92e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.33e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.02e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.18e2 2.51e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.20e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 3.10e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_003.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4673, 0565 scc: 109-950 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 17:16 Printed: 30-Mar-2014 14:45 Page 21 of 21 149 of 622 Lab ID: A6506_11899_PCB_004 ACQ: 27-Mar-2014 17:03:52 LKB Wt/Vol: 0.96 L Client ID: PB081_A-1SWMID-140314-N (TOTAL) UTP: 30-Mar-2014 13:53 LKB J-level: 10.5 pg/L Datafile: 140327X08 RPT: 30-Mar-2014 14:30 LB Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services Actual RT 32.79 32.32 35.77 35.23 34.77 34.49 38.38 40.92 39.94 NotFnd 45.76 50.83 11.87 14.16 14.41 20.12 17.49 26.44 20.40 32.77 32.29 25.38 35.75 35.21 34.74 34.46 38.36 36.33 30.33 40.91 39.92 43.62 43.14 42.07 35.20 45.75 39.74 47.91 49.37 45.36 50.80 QC J EMPC J C J J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0008 1.0006 1.0006 1.0006 1.0006 1.0005 1.0002 1.0005 1.0002 1.0004 0 +0.6 0 -0.2 0 0 0 -0.7 -0.2 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7245 0.8641 0.8793 1.2277 1.0673 1.0790 0.8325 1.3372 1.3177 0.8322 1.1724 1.1547 1.1394 1.1302 1.2580 0.9716 0.8111 1.0941 1.0678 1.1667 0.9080 0.8855 0.7410 0.9629 0.8364 1.0084 1.0392 0.9548 1.0694 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Split: 1 Checkcode: 761-905-WTS Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.77 0.61 0.62 0.64 0.62 0.65 0.59 1.20 1.10 -0.5 0 5.22E+06 1.72E+05 1.30E+07 7.53E+05 2.40E+07 7.55E+05 9.31E+04 1.04E+06 3.48E+05 0.00E+00 4.67E+04 1.30E+06 1.02 1.14 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 80.1 2.81 250 13.4 445 13.7 2.12 23.7 7.15 ND 1.22 54 7.09E+03 7.09E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.16E+03 2.16E+03 2.16E+03 2.16E+03 1.76E+03 1.28E+03 1.15 1.15 0.755 0.706 0.716 0.685 0.75 0.697 0.455 0.545 0.465 0.627 0 +0.1 -0.2 +0.7 0 +0.5 -0.4 +1.6 +1.4 -0.5 +0.9 +0.8 +0.6 +0.6 +1.2 0 -0.5 +0.5 +0.2 +0.8 -0.3 -0.3 -0.6 0 -0.5 0 0 -0.3 0 4.84E+07 6.90E+07 3.69E+07 1.38E+08 4.75E+07 1.33E+08 5.88E+07 1.18E+08 1.14E+08 6.91E+07 9.79E+07 9.81E+07 9.51E+07 9.52E+07 8.31E+07 6.71E+07 9.40E+07 1.68E+08 8.77E+07 7.76E+07 5.13E+07 6.20E+07 6.65E+07 7.49E+07 6.33E+07 5.34E+07 3.60E+07 5.92E+07 4.54E+07 3.26 3.31 1.61 1.57 1.07 1.10 0.78 0.80 0.82 1.62 1.59 1.62 1.62 1.57 1.55 1.30 1.28 1.27 1.28 1.29 1.09 1.08 1.06 1.04 0.93 0.90 0.79 0.81 1.18 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 28.2 % 44.1 % 49 % 92.2 % 65.1 % 90.8 % 77.4 % 97.1 % 94.8 % 106 % 100 % 99 % 101 % 98.6 % 99.4 % 94.4 % 93.9 % 83.1 % 83.4 % 79.1 % 96.6 % 96.7 % 112 % 103 % 103 % 93.7 % 94.8 % 110 % 89.3 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Page 1 of 5 Printed: 3/30/2014 2:33 PM 150 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.89 32.79 37.77 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 1.54E+08 1.06E+08 4.46E+07 1.08 1.60 1.09 1.11 1.03 0.62 104 % 108 % 108 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.89 32.79 37.77 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 1.54E+08 1.06E+08 4.46E+07 1.08 1.60 1.09 1.85 1.22 0.58 94.6 % 107 % 121 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.39 24.51 30.49 37.39 47.51 1.44E+08 8.82E+07 8.14E+07 6.30E+07 4.58E+07 1.57 0.80 1.60 1.29 0.88 6.71E+03 6.71E+03 6.71E+03 7.60E+03 7.60E+03 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 1.89 1.22 1.45 2.51 1.62 1.47 1.31 1.4 1.39 1.35 1.17 1.35 1.36 1.46 2.24 1.68 1.94 1.43 1.51 2.54 1.35 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services 11.89 13.99 14.17 14.43 14.61 16.41 16.57 16.80 17.09 17.22 NotFnd 19.56 19.83 20.13 17.51 19.28 19.67 19.86 19.99 20.09 20.57 J J J J J J B C C J 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0011 0.9878 1.0009 1.0011 1.0136 1.0010 1.0114 1.0250 1.0430 1.0507 0.9721 0.9854 1.0006 1.0010 1.1020 1.1246 1.1356 1.1425 1.1487 1.1762 0 -0.2 -0.1 0 +0.1 0 +0.3 +0.1 -0.3 +0.1 0 -1.4 -0.2 0 +0.7 +0.4 +0.4 -0.6 +0.4 +0.5 Page 2 of 5 NON-EMPC 47 576 5,490 11,400 4,470 889 199 45.8 8.74 8.53E+05 1.24E+05 1.72E+05 5.31E+06 3.19E+05 5.61E+05 2.80E+05 4.47E+06 1.73E+05 7.79E+06 0.00E+00 2.11E+06 1.58E+06 5.79E+06 4.86E+06 4.68E+07 1.45E+07 3.74E+06 2.87E+05 1.08E+07 2.19E+07 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 47 576 5,490 11,400 4,470 901 199 46.3 10.3 3.40 3.44 3.34 1.59 SI SI SI 1.60 SI 1.58 1.45 1.52 1.46 1.09 1.05 1.05 1.05 1.11 1.06 1.05 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 1.67 1.98 1.7 0.824 0.669 0.493 0.539 0.539 1.47 38.7 3.14 5.17 245 9.5 8.4 3.72 63.7 2.44 107 ND 29 21.8 86 187 1,340 482 91.5 7.41 470 508 Printed: 3/30/2014 2:33 PM 151 of 622 Name PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB SGS Evironmental Services Actual RT 21.72 NotFnd 22.13 22.36 22.63 22.91 23.12 23.48 NotFnd 25.23 NotFnd 26.09 26.47 20.42 22.38 23.00 23.08 23.28 24.53 24.65 24.75 24.97 25.23 25.42 25.72 25.89 26.22 26.32 26.52 27.23 27.49 27.86 28.08 28.23 28.45 28.75 29.02 29.17 29.60 29.80 NotFnd 31.45 NotFnd NotFnd 25.72 27.40 27.60 27.98 QC J C C C J J C J C C C C J J J EMPC C J J J J Pred RRT Actual RRT Diff Secs 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8215 0.8370 0.8455 0.8559 0.8663 0.8744 0.8878 0.9539 0.9867 1.0009 1.0010 0.9134 0.9385 0.9416 0.9498 1.0009 1.0060 1.0101 1.0189 1.0296 1.0374 1.0493 1.0564 1.0698 1.0739 1.0821 0.8433 0.8513 0.8628 0.8694 0.8740 0.8810 0.8902 0.8987 0.9032 0.9167 0.9227 0.9740 1.0135 0.8987 0.9051 0.9175 -0.4 -1.7 -0.1 -0.4 -1.0 +0.8 -0.3 +2.6 -0.6 +0.3 0 -1.5 +0.3 +0.4 -0.1 0 -0.3 0 +1.2 +0.2 -1.5 -0.5 +0.2 0 +0.3 +0.3 -0.5 -0.3 -0.3 +0.2 -0.2 -0.2 0 -0.3 -0.4 -0.4 -0.4 +0.6 +0.2 -0.3 0 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 3.02E+05 0.00E+00 1.23E+07 7.75E+06 6.68E+07 6.68E+07 1.48E+07 1.54E+07 0.00E+00 7.02E+05 0.00E+00 9.21E+05 8.93E+06 2.75E+05 1.54E+07 1.37E+07 4.14E+06 4.91E+06 9.16E+07 2.24E+05 2.54E+06 5.59E+07 1.49E+07 8.41E+07 7.67E+06 1.86E+07 4.59E+06 3.76E+07 4.27E+07 4.45E+05 2.38E+06 2.79E+05 1.19E+05 1.67E+06 2.65E+06 1.22E+08 7.14E+07 5.31E+05 3.42E+07 1.31E+07 0.00E+00 4.06E+05 0.00E+00 0.00E+00 7.89E+05 2.30E+05 3.19E+05 2.09E+07 1.09 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 3.73 ND 150 94.9 782 839 181 202 ND 8.13 ND 12.5 130 7.25 306 315 82 123 1,880 3.48 60.4 933 301 1,600 113 409 115 742 594 6.31 31.8 4.15 1.73 23.4 35.7 1,800 1,120 8.28 539 205 ND 5.4 ND ND 20 5.35 8.82 533 0.99 1.01 1.01 1.01 1.00 1.00 0.99 1.18 1.01 0.77 0.79 0.77 0.78 0.79 0.79 0.74 0.79 0.79 0.79 0.79 0.80 0.79 0.78 0.79 0.78 0.71 0.78 0.86 0.59 0.76 0.76 0.79 0.78 0.80 0.79 0.79 0.66 0.65 0.56 0.57 0.61 Noise / Recv. Low DL / Recv. High 8.05E+03 8.05E+03 8.05E+03 8.05E+03 8.05E+03 8.05E+03 8.05E+03 8.05E+03 8.05E+03 8.05E+03 8.05E+03 8.05E+03 8.05E+03 2.31E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 3.14E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 7.09E+03 1.97E+03 1.97E+03 3.78E+03 3.78E+03 3.78E+03 0.974 0.973 0.964 0.967 0.924 0.992 0.965 1.03 0.942 0.915 1.02 1.07 1.15 0.55 0.619 0.716 0.619 0.782 0.64 0.485 0.743 0.521 0.631 0.594 0.459 0.689 0.784 0.616 0.434 1 0.945 1.05 1.02 0.988 0.949 1.04 1.11 1.1 1.11 1.1 0.944 0.936 1.16 0.405 0.485 0.876 1.04 0.959 Printed: 3/30/2014 2:33 PM 152 of 622 Name PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB SGS Evironmental Services Actual RT 28.19 28.30 NotFnd NotFnd 28.74 28.93 29.35 NotFnd 30.01 30.52 30.92 31.02 31.14 31.50 32.00 32.08 32.21 32.31 32.50 NotFnd NotFnd 34.18 34.38 34.59 35.06 NotFnd 30.34 30.51 30.65 30.96 NotFnd NotFnd 33.01 33.23 33.49 33.79 33.97 34.06 34.30 34.48 NotFnd 34.87 35.27 NotFnd 35.82 NotFnd 36.35 36.52 QC J C C J C C C J J EMPC J EMPC J EMPC C J EMPC J C J EMPC J C J EMPC J EMPC C Pred RRT Actual RRT Diff Secs 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9245 0.9281 0.9424 0.9487 0.9624 0.9841 1.0007 1.0140 1.0174 1.0212 1.0329 1.0494 1.0521 1.0564 1.0596 1.0657 0.9917 0.9976 1.0037 1.0090 1.0004 1.0062 1.0106 1.0207 1.0886 1.0956 1.1044 1.1142 1.1201 1.1231 1.1312 1.1370 1.1497 1.1631 0.9581 0.9722 0.9767 -0.2 -0.2 0 0 0 0 +1.5 -0.4 +0.2 +1.1 +1.7 -0.2 -0.8 +0.6 +1.2 +0.4 +0.2 0 -0.2 -0.2 -0.5 +0.4 -0.2 0 0 +0.4 +0.6 +0.2 +0.4 +1.2 0 +0.2 +0.6 +1.1 -0.2 -1.3 +0.2 Page 4 of 5 Response Ra RRF Conc. / Recv. 4.40E+05 1.97E+06 0.00E+00 0.00E+00 5.93E+06 8.76E+06 9.54E+05 0.00E+00 4.11E+06 2.50E+07 1.34E+06 1.49E+07 8.69E+04 2.29E+07 9.68E+05 7.29E+06 3.56E+07 8.61E+05 4.48E+06 0.00E+00 0.00E+00 1.08E+06 2.05E+06 5.03E+04 5.17E+05 0.00E+00 2.49E+04 2.71E+04 2.13E+04 1.33E+06 0.00E+00 0.00E+00 1.98E+06 8.70E+04 3.20E+05 5.11E+06 4.09E+05 4.01E+04 1.90E+05 1.26E+05 0.00E+00 2.49E+06 8.48E+04 0.00E+00 9.92E+05 0.00E+00 5.89E+06 1.18E+06 0.61 0.61 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 11.1 41.5 ND ND 143 267 27.4 ND 110 559 41.4 361 1.63 506 20.3 163 702 16.5 142 ND ND 21.6 36.4 1.03 11 ND 0.44 0.546 0.423 28.8 ND ND 58.1 2.18 9.07 144 16.2 1.13 5.34 4.18 ND 80.1 2.54 ND 27.2 ND 133 35.6 0.62 0.62 0.65 0.62 0.62 0.60 0.62 0.58 0.61 0.59 0.62 0.62 0.66 0.64 0.63 0.64 0.60 0.59 1.00 0.94 0.97 1.22 1.25 1.49 1.34 1.29 1.42 1.57 1.22 1.49 1.28 1.04 1.36 1.25 1.29 Noise / Recv. Low DL / Recv. High 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 3.78E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 0.948 0.796 1.14 1.05 0.907 1.15 1.09 0.681 1.01 0.844 1.16 0.914 0.709 0.833 0.79 0.843 0.744 0.724 1.2 0.689 0.678 0.757 0.669 0.77 0.846 0.774 0.278 0.316 0.312 0.341 0.333 0.476 0.503 0.429 0.486 0.484 0.68 0.485 0.482 0.57 0.578 0.552 0.513 0.409 0.47 0.378 0.386 0.518 Printed: 3/30/2014 2:33 PM 153 of 622 Name Actual RT PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.86 37.06 37.14 37.42 NotFnd 37.75 38.50 39.29 39.55 NotFnd 35.51 NotFnd 36.26 NotFnd 37.78 38.33 38.56 NotFnd 39.08 39.17 39.28 39.65 NotFnd 40.19 41.53 NotFnd 42.09 42.39 43.16 43.61 39.76 40.55 NotFnd 41.32 41.40 43.74 44.30 44.46 45.59 47.53 NotFnd 45.38 46.17 49.39 SGS Evironmental Services QC C C J EMPC J J J J J J C J C J J J J J EMPC J J C J J J J J J EMPC J Pred RRT Actual RRT Diff Secs 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9859 0.9912 0.9934 1.0007 1.0096 0.9642 0.9840 0.9905 1.0086 1.0301 1.0733 1.0889 1.0953 1.1103 1.1127 1.1157 1.1263 1.1417 0.9079 0.9200 0.9266 0.9434 0.9532 1.0004 1.0203 1.0398 1.0419 1.1007 1.1147 1.1189 0.9515 0.9920 1.0005 1.0178 1.0004 0 +0.2 +0.2 -0.9 0 +0.2 -0.9 +0.5 0 +0.2 0 +0.5 +0.2 +0.5 +0.5 +0.2 +0.2 +1.0 -0.2 +1.5 0 0 -0.3 -0.2 0 +0.5 +0.2 +1.6 +0.3 +0.3 -0.3 -0.3 0 0 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 4.71E+05 4.73E+05 6.15E+05 7.78E+06 0.00E+00 1.08E+06 1.34E+06 4.32E+04 3.22E+04 0.00E+00 3.92E+05 0.00E+00 1.19E+05 0.00E+00 1.41E+05 3.94E+04 1.03E+06 0.00E+00 4.73E+05 7.70E+04 7.26E+05 4.04E+05 0.00E+00 2.40E+05 1.40E+05 0.00E+00 1.74E+06 4.70E+04 6.83E+05 1.71E+05 9.99E+04 6.47E+04 0.00E+00 1.69E+04 5.53E+04 2.92E+05 1.38E+05 1.64E+05 7.24E+04 1.97E+05 0.00E+00 7.76E+04 4.84E+04 1.21E+05 1.21 1.19 1.31 1.28 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 16 13 13.9 219 ND 22.5 35.7 0.963 0.722 ND 11.4 ND 3.29 ND 5.86 1.23 30.3 ND 13.1 2.52 25 14.4 ND 8.58 4.87 ND 47.4 1.18 24.5 4.48 3.14 1.89 ND 0.495 1.71 13.4 5.97 7.04 3.57 9.06 ND 2.44 1.51 6.3 1.28 1.27 0.92 1.43 1.10 1.06 1.00 0.93 1.04 1.10 1.11 1.04 1.09 1.09 1.00 1.01 0.95 1.11 0.94 0.83 0.87 1.27 0.78 0.93 0.89 0.83 0.90 0.97 0.78 1.08 0.74 Noise / Recv. Low DL / Recv. High 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 2.16E+03 2.16E+03 2.16E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.88E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.55E+03 1.55E+03 1.55E+03 3.40E+03 3.40E+03 3.40E+03 0.583 0.472 0.388 0.482 0.411 0.358 0.591 0.493 0.496 0.367 0.431 0.455 0.409 0.436 0.615 0.626 0.588 0.568 0.554 0.655 0.688 0.714 0.632 0.715 0.696 0.536 0.545 0.501 0.672 0.491 0.489 0.453 0.488 0.455 0.479 0.714 0.673 0.666 0.785 0.733 0.589 1.12 1.11 1.81 Printed: 3/30/2014 2:33 PM 154 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 1.65e8 8.26e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 4.11e7 2.05e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 3.41e7 1.71e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 6.25e7 3.12e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 3.47e7 1.73e7 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.93e6 2.97e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.55e6 2.77e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 761-905 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:45 Page 1 of 21 155 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 PCB-1 6.59e5 11.89 Rel. Int. 100% Abs. Int. 2.60e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.52e3 1.30e5 PCB-3 1.32e5 14.17 PCB-2 9.61e4 13.99 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 1.94e5 11.89 Rel. Int. 100% Abs. Int. 8.01e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.19e3 4.00e4 PCB-3 3.96e4 14.17 PCB-2 2.79e4 13.99 0% 11.0 Rel. Int. 100% 12.0 13.0 14.0 15.0 ES-3 5.30e7 14.16 ES-1 3.70e7 11.87 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 8.70e3 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 1.84e7 9.22e6 0% 11.0 Rel. Int. 100% 12.0 13.0 14.0 15.0 ES-3 1.60e7 14.16 ES-1 1.14e7 11.87 0.00e0 16.0 RT Abs. Int. 5.72e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.71e4 2.86e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.65e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 8.26e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9751, 3753 scc: 761-905 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:35 (LKB) Printed: 30-Mar-2014 14:45 Page 2 of 21 156 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Rel. Int. 100% Abs. Int. 1.07e6 PCB-4 3.26e6 14.43 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 4.63e3 5.35e5 PCB-10 1.94e5 SI 14.61 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 2.05e6 14.43 Rel. Int. 100% DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.84e4 0.00e0 16.0 RT Abs. Int. 7.34e5 PFK INTERFERENCE 3.67e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.27e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.96e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 6.58e3 3.98e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.41e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.82e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.42e3 2.41e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.65e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 8.26e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1026, 2835 scc: 761-905 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:35 (LKB) Printed: 30-Mar-2014 14:45 Page 3 of 21 157 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 PCB-8 4.77e6 17.22 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 6.59e3 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Abs. Int. 1.43e6 PCB-6 2.76e6 16.80 PCB-11 1.25e6 19.56 PCB-9 3.42e5 SI 16.41 PCB-15 3.44e6 20.13 7.17e5 13/12 9.51e5 19.83 0% 17.0 18.0 19.0 20.0 21.0 PCB-8 3.02e6 17.22 Rel. Int. 100% Abs. Int. 1.01e6 PCB-6 1.72e6 16.80 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 4.46e4 PCB-11 8.59e5 19.56 PFK INTERFERENCE PCB-15 2.35e6 20.13 13/12 6.25e5 19.83 5.04e5 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 8.82e7 16.39 20.0 21.0 0.00e0 RT Abs. Int. 2.69e7 ES-15 8.44e7 20.12 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.80e4 1.34e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 5.60e7 16.39 20.0 21.0 0.00e0 RT Abs. Int. 1.70e7 ES-15 5.39e7 20.12 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.34e3 8.51e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 2.05e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2968, 8520 scc: 761-905 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:35 (LKB) Printed: 30-Mar-2014 14:45 Page 4 of 21 158 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Rel. Int. 100% Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Abs. Int. 6.79e6 30/18 2.40e7 19.28 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.87e3 PCB-17 7.43e6 19.67 PCB-19 2.53e6 17.51 PCB-27 1.91e6 19.86 PCB-16 5.56e6 20.09 PCB-32 1.12e7 20.57 3.39e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 6.42e6 30/18 2.28e7 19.28 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.87e3 PCB-17 7.04e6 19.67 PCB-19 2.32e6 17.51 PCB-27 1.82e6 19.86 PCB-16 5.23e6 20.09 PCB-32 1.07e7 20.57 3.21e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.45e7 17.49 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.21e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 7.03e4 3.61e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.30e7 17.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.89e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 6.72e4 3.44e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 2.05e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3282, 1946 scc: 761-905 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:35 (LKB) Printed: 30-Mar-2014 14:45 Page 5 of 21 159 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 PCB-31 28/20 3.35e7 3.36e7 22.63 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 4.25e3 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 26/29 6.12e6 22.13 Abs. Int. 8.83e6 21/33 7.42e6 23.12 PCB-25 3.88e6 22.36 4.42e6 PCB-22 7.70e6 23.48 PCB-37 4.49e6 26.47 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 28/20 3.33e7 3.33e7 22.63 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 3.80e3 24.0 26/29 6.20e6 22.13 PCB-25 3.86e6 22.36 Abs. Int. 8.78e6 21/33 7.39e6 23.12 4.39e6 PCB-22 7.72e6 23.48 PCB-37 4.43e6 26.47 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.01e7 22.89 Rel. Int. 100% ES-37 6.99e7 26.44 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 8.82e4 Abs. Int. 2.10e7 1.05e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 7.39e7 22.89 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 6.33e7 26.44 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 5.20e4 Abs. Int. 1.94e7 9.69e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.71e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7856, 1995 scc: 761-905 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:37 Printed: 30-Mar-2014 14:45 Page 6 of 21 160 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 PCB-54 1.19e5 20.42 Rel. Int. 100% Abs. Int. 3.26e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.14e3 1.63e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.56e5 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.31e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.16e3 2.15e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.57e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.10e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 9.64e3 3.55e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.31e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.87e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 6.17e3 4.44e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 2.05e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7776, 0593 scc: 761-905 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:35 (LKB) Printed: 30-Mar-2014 14:45 Page 7 of 21 161 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Rel. Int. 100% PCB-52 4.05e7 24.53 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.53e3 50/53 6.82e6 22.38 PCB-51 1.82e6 23.08 PCB-45 5.99e6 23.00 69/49 2.47e7 24.97 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 44/47… 3.70e7 25.42 PCB-48 6.59e6 25.23 PCB-46 2.16e6 23.28 Abs. Int. 1.07e7 PCB-42 8.21e6 25.89 59/62… 3.41e6 25.72 71/40 1.66e7 26.32 PCB-41 2.01e6 26.22 PCB-64 1.88e7 26.52 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 5.11e7 24.53 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.61e3 50/53 8.62e6 22.38 PCB-51 2.32e6 23.08 PCB-45 7.75e6 23.00 69/49 3.13e7 24.97 Abs. Int. 1.34e7 44/47… 4.71e7 25.42 PCB-42 1.03e7 25.89 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.91e7 24.51 Rel. Int. 100% 0.00e0 RT 26.0 PCB-48 8.31e6 25.23 PCB-46 2.75e6 23.28 5.34e6 71/40 2.10e7 26.32 PCB-41 2.58e6 26.22 PCB-64 2.39e7 26.52 6.68e6 0.00e0 RT Abs. Int. 1.03e7 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.92e4 5.14e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.91e7 24.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.26e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.29e4 6.31e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.71e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3215, 0018 scc: 761-905 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:33 (LKB) Printed: 30-Mar-2014 14:45 Page 8 of 21 162 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Abs. Int. 1.02e7 61/70... PCB-66 5.42e7 3.14e7 28.75 29.02 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 2.49e3 PCB-56 1.51e7 29.60 5.11e6 PCB-60 5.78e6 29.80 PCB-77 2.28e6 32.79 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 38.0 Abs. Int. 1.28e7 61/70... PCB-66 6.82e7 4.00e7 28.75 29.02 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 4.60e3 PCB-56 1.91e7 29.60 6.38e6 PCB-60 7.35e6 29.80 PCB-77 2.94e6 32.79 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 5.14e7 32.29 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 2.16e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.29e7 ES-77 5.26e7 32.77 6.46e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 6.29e7 32.29 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.38e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.58e7 ES-77 6.59e7 32.77 7.88e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.25e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 3.12e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4607, 5120 scc: 761-905 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:36 (LKB) Printed: 30-Mar-2014 14:45 Page 9 of 21 163 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 PCB-96 3.10e5 25.72 Rel. Int. 100% Abs. Int. 8.43e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 9.97e2 4.22e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 4.79e5 25.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.23e5 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 9.75e2 6.14e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 4.27e7 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e7 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 2.66e3 5.51e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.63e7 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.90e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 2.65e3 3.45e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.71e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3313, 2769 scc: 761-905 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:34 Printed: 30-Mar-2014 14:45 Page 10 of 21 164 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.94e3 PCB-95 7.97e6 27.98 0% PCB-91 2.27e6 28.74 PCB-84 3.36e6 PCB-102 28.93 7.44e5 28.30 28.0 113/90… 9.56e6 30.52 PCB-92 1.57e6 30.01 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.84e3 PCB-95 1.30e7 27.98 PCB-91 3.67e6 28.74 PCB-84 5.41e6 28.93 PCB-110 1.36e7 32.21 Abs. Int. 3.36e6 PCB-118 9.19e6 34.77 PCB-99 5.72e6108/119... 31.02 8.72e6 116/85 31.50 2.79e6 32.08 PCB-82 1.75e6 32.50 32.0 113/90… 1.54e7 30.52 PCB-92 2.54e6 30.01 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 PCB-109 8.01e5 34.38 34.0 PCB-105 4.96e6 35.77 36.0 1.68e6 38.0 PCB-110 2.20e7 32.21 PCB-99 9.19e6108/119... 31.02 1.42e7 116/85 31.50 4.50e6 32.08 Abs. Int. 5.44e6 PCB-118 1.49e7 34.77 PCB-82 2.73e6 32.49 PCB-109 1.25e6 34.38 PCB-105 8.06e6 35.77 2.72e6 0% 28.0 30.0 Rel. Int. 100% 32.0 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 4.73e3 34.0 CS/SS-111 6.54e7 32.79 JS-101 5.00e7 30.49 0.00e0 RT ES-118 ES-114 ES-123 5.88e7 6.07e7 5.81e7 34.74 35.21 34.46 36.0 38.0 0.00e0 RT Abs. Int. 1.67e7 ES-105 6.01e7 35.75 8.35e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.08e7 32.79 JS-101 3.13e7 30.49 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.97e3 34.0 ES-118 ES-114 3.74e7 ES-123 3.63e7 3.71e7 34.75 35.21 34.46 36.0 38.0 0.00e0 RT Abs. Int. 1.06e7 ES-105 3.79e7 35.75 5.29e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.25e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 3.12e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1325, 6172 scc: 761-905 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:36 (LKB) Printed: 30-Mar-2014 14:45 Page 11 of 21 165 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Rel. Int. 100% Abs. Int. 6.57e5 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 1.56e3 3.28e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 1.49e6 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 1.60e3 7.47e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.21e7 ES-126 5.05e7 38.36 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 8.79e3 6.06e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.82e6 ES-126 3.26e7 38.36 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 5.78e3 3.91e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.47e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.73e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4995, 6817 scc: 761-905 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:34 Printed: 30-Mar-2014 14:45 Page 12 of 21 166 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Rel. Int. 100% 153/168 3.28e6 36.35 147/149 2.87e6 33.79 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 9.47e2 PCB-136 7.30e5 30.96 151/135 1.10e6 33.01 PCB-134 2.40e5 33.97 PCB-132 1.40e6 34.87 163/138… 4.36e6 37.42 PCB-141 6.64e5 PCB-137 36.52 2.57e5 37.06 PCB-146 5.72e5 35.82 Abs. Int. 1.03e6 PCB-158 6.05e5 37.75 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 153/168 2.62e6 36.35 147/149 2.23e6 33.79 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 6.83e2 PCB-136 5.96e5 30.95 151/135 8.80e5 33.01 38.0 PCB-134 1.69e5 33.97 PCB-132 1.09e6 34.87 163/138… 3.42e6 37.42 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 5.29e7 30.33 Rel. Int. 100% ES-153 3.79e7 36.33 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.52e3 0.00e0 RT Abs. Int. 7.94e5 PCB-141 PCB-158 5.14e5 PCB-164 4.73e5 2.67e5 36.51 37.75 37.14 PCB-146 4.20e5 35.82 5.14e5 3.97e5 0.00e0 RT Abs. Int. 1.37e7 JS-138 3.55e7 37.39 6.86e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.12e7 30.33 Rel. Int. 100% ES-153 2.92e7 36.33 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.53e3 0.00e0 RT Abs. Int. 1.03e7 JS-138 2.76e7 37.39 5.14e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.25e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 3.12e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1554, 3684 scc: 761-905 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:36 (LKB) Printed: 30-Mar-2014 14:45 Page 13 of 21 167 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 128/166 7.47e5 38.50 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Abs. Int. 1.60e5 156/157 5.68e5 40.92 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 1.09e3 PCB-167 1.83e5 39.94 8.00e4 0% 39.0 Rel. Int. 100% 40.0 128/166 5.90e5 38.50 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.43e5 156/157 4.73e5 40.92 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 1.06e3 PCB-159 2.61e4 39.28 PCB-167 1.65e5 39.94 7.13e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 4.92e7 39.92 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 8.83e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 9.37e7 40.91 0.00e0 RT Abs. Int. 1.66e7 ES-169 4.37e7 43.62 8.28e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 3.85e7 39.93 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 7.68e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 7.38e7 40.91 0.00e0 RT Abs. Int. 1.31e7 ES-169 3.39e7 43.62 6.53e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.47e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.73e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2842, 6666 scc: 761-905 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:34 Printed: 30-Mar-2014 14:45 Page 14 of 21 168 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 PCB-179 2.06e5 35.51 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 8.57e2 Abs. Int. 4.71e4 PCB-178 7.06e4 37.78 PCB-176 6.11e4 36.26 2.36e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 1.86e5 35.50 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 5.90e2 Abs. Int. 4.53e4 PCB-178 7.04e4 37.79 PCB-176 5.77e4 36.26 2.27e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.42e7 35.20 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 8.37e6 CS/SS-178 2.32e7 37.77 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.30e3 4.19e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.22e7 35.20 Rel. Int. 100% Abs. Int. 8.07e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.44e3 CS/SS-178 2.14e7 37.77 4.03e6 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.19e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 3.09e7 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9351, 8262 scc: 761-905 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:34 Printed: 30-Mar-2014 14:45 Page 15 of 21 169 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 180/193 8.77e5 42.09 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 1.23e3 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 PCB-187 5.26e5 38.56 PCB-174 3.71e5 39.28 PCB-177 PCB-183 2.11e5 2.48e5 39.65 PCB-185 39.08 4.05e4 39.17 171/173 1.26e5 40.19 Abs. Int. 1.90e5 PCB-170 3.59e5 43.16 PCB-172 7.00e4 41.53 9.49e4 PCB-190 8.27e4 43.61 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 8.66e5 42.09 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 6.43e2 43.0 PCB-187 5.05e5 38.56 PCB-174 3.55e5 39.28 PCB-177 PCB-183 1.93e5 2.25e5PCB-185 39.65 39.08 3.65e4 39.17 171/173 1.15e5 40.19 Abs. Int. 2.11e5 PCB-170 3.24e5 43.16 PCB-172 6.98e4 41.53 1.05e5 PCB-190 8.78e4 43.61 0% 39.0 40.0 41.0 42.0 ES-180 3.22e7 42.07 Rel. Int. 100% 0.00e0 RT 43.0 44.0 45.0 ES-170 2.68e7 43.14 0.00e0 RT Abs. Int. 7.56e6 HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 3.60e3 3.78e6 0% 39.0 40.0 41.0 42.0 ES-180 2.97e7 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 4.29e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.24e6 ES-170 2.45e7 43.14 3.62e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.47e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.73e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7853, 3336 scc: 761-905 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:34 Printed: 30-Mar-2014 14:45 Page 16 of 21 170 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 PCB-189 2.35e4 45.76 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Abs. Int. 7.76e3 (2.35e4 + 2.31e4) * 2000 pg = 1.22 pg/L (3.82e7 + 3.67e7) * 1.07 * 0.96 L LKB 30-Mar-2014 14:39 Conc(PCB-189) = HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 9.26e2 3.88e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.31e4 45.76 Abs. Int. 8.02e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 8.34e2 4.01e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 3.82e7 45.75 0.00e0 RT Abs. Int. 9.42e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.25e3 4.71e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 3.67e7 45.75 0.00e0 RT Abs. Int. 9.09e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 4.49e3 4.55e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.93e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.97e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7540, 4112 scc: 761-905 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:34 (LKB) Printed: 30-Mar-2014 14:45 Page 17 of 21 171 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 198/199 1.41e5 43.74 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 8.77e2 PCB-202 4.53e4 39.76 PCB-201 3.01e4 40.55 Abs. Int. 3.41e4 PCB-196 6.50e4 44.30 PCB-197 PCB-200 1.14e4 2.43e4 41.40 41.32 PCB-203 7.43e4 44.46 1.71e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 1.51e5 43.74 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.52e2 PCB-202 5.46e4 39.76 PCB-201 3.47e4 40.55 PCB-196 7.28e4 44.30 PCB-200 3.11e4 PCB-197 41.40 8.95e3 41.31 Abs. Int. 3.25e4 PCB-203 9.00e4 44.47 1.62e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.05e7 39.74 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.49e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.90e3 3.75e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.28e7 39.74 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.99e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.08e3 3.99e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.47e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.73e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7632, 9619 scc: 761-905 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:34 Printed: 30-Mar-2014 14:45 Page 18 of 21 172 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 PCB-194 9.70e4 47.53 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 6.85e2 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 Abs. Int. 2.33e4 PCB-195 3.43e4 45.59 1.16e4 0% 46.0 47.0 49.0 50.0 PCB-194 9.99e4 47.53 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 8.62e2 48.0 0.00e0 RT Abs. Int. 2.31e4 PCB-195 3.81e4 45.59 1.16e4 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.15e7 47.51 49.0 50.0 ES-205 2.53e7 47.91 0.00e0 RT Abs. Int. 6.14e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.91e3 3.07e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.43e7 47.51 49.0 50.0 ES-205 2.81e7 47.91 0.00e0 RT Abs. Int. 6.86e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 3.33e3 3.43e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.93e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.97e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1877, 3857 scc: 761-905 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:37 (LKB) Printed: 30-Mar-2014 14:45 Page 19 of 21 173 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.31e3 PCB-208 3.41e4 45.38 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 PCB-206 5.12e4 49.39 Abs. Int. 1.37e4 PCB-207 2.93e4 46.17 6.85e3 0% 46.0 47.0 48.0 49.0 PCB-206 6.96e4 49.39 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.09e3 50.0 PCB-208 4.35e4 45.39 Abs. Int. 1.98e4 PCB-207 2.72e4 46.17 9.88e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 6.31e6 ES-208 2.64e7 45.36 ES-206 1.59e7 49.37 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.97e3 3.16e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 7.97e6 ES-208 3.28e7 45.36 ES-206 2.01e7 49.37 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 3.04e3 3.99e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.93e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.97e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8597, 1494 scc: 761-905 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:37 (LKB) Printed: 30-Mar-2014 14:45 Page 20 of 21 174 of 622 SGS-AP ID: A6506_11899_PCB_004 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 52 Acq: 27-Mar-2014 17:03:52 User: LKB Datafile: 140327X08 PCB-209 6.95e5 50.83 Rel. Int. 100% Abs. Int. 1.57e5 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 5.41e2 7.83e4 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 6.10e5 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.33e5 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 7.35e2 6.63e4 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.46e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.18e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 9.84e2 2.59e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.08e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.49e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.97e2 2.25e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.55e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 2.77e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_004.utp_res, saved 30-Mar-2014 14:40 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4915, 7170 scc: 761-905 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:34 Printed: 30-Mar-2014 14:45 Page 21 of 21 175 of 622 Lab ID: A6506_11899_PCB_005 ACQ: 27-Mar-2014 17:59:02 LKB Wt/Vol: 0.93 L Client ID: PB081_A-1SWMID-140314-N (DISSOLVED) UTP: 30-Mar-2014 13:53 LKB J-level: 10.8 pg/L Datafile: 140327X09 RPT: 30-Mar-2014 14:30 LB Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services Actual RT 32.78 NotFnd 35.77 35.23 34.76 34.48 NotFnd 40.91 39.93 NotFnd NotFnd 50.82 11.87 14.16 14.41 20.12 17.49 26.44 20.40 32.77 32.29 25.37 35.75 35.20 34.74 34.46 38.36 36.32 30.32 40.90 39.92 43.62 43.13 42.06 35.20 45.74 39.73 47.90 49.37 45.36 50.80 QC J J EMPC J EMPC C J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0006 1.0006 1.0007 1.0007 1.0002 1.0004 1.0004 0 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7245 0.8641 0.8793 1.2277 1.0673 1.0790 0.8326 1.3371 1.3176 0.8322 1.1724 1.1546 1.1394 1.1302 1.2580 0.9716 0.8111 1.0941 1.0678 1.1667 0.9079 0.8855 0.7410 0.9629 0.8364 1.0084 1.0392 0.9548 1.0694 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Split: 1 Checkcode: 223-376-PJM Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.79 0 4.74E+05 0.00E+00 9.64E+05 5.71E+04 1.83E+06 5.25E+04 0.00E+00 6.21E+04 2.51E+04 0.00E+00 0.00E+00 1.03E+05 1.09 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 15.9 ND 40.1 2.22 73.3 2.05 ND 3.11 1.11 ND ND 11.9 3.79E+03 3.79E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.20E+03 1.52E+03 1.52E+03 1.52E+03 1.53E+03 1.22E+03 1.31 1.36 1.22 1.13 1.2 1.15 1.2 1.08 0.7 0.884 0.97 1.71 0 +0.1 -0.2 +0.7 0 +0.5 -0.2 +1.4 +1.2 -0.5 +0.9 +0.6 +0.6 +0.6 +1.2 0 -0.5 +0.5 +0.2 +0.8 -0.5 -0.3 -0.6 0 -0.5 0 0 -0.3 0 3.51E+07 4.26E+07 2.23E+07 6.47E+07 2.53E+07 6.50E+07 2.77E+07 5.58E+07 5.56E+07 3.42E+07 4.64E+07 4.60E+07 4.51E+07 4.54E+07 3.96E+07 3.22E+07 4.58E+07 7.82E+07 4.19E+07 3.60E+07 2.41E+07 2.85E+07 3.13E+07 3.38E+07 3.05E+07 2.11E+07 1.41E+07 2.60E+07 1.67E+07 3.24 3.33 1.64 1.56 1.07 1.10 0.80 0.79 0.80 1.61 1.60 1.61 1.60 1.60 1.51 1.31 1.28 1.26 1.25 1.29 1.07 1.06 1.08 1.03 0.91 0.89 0.80 0.79 1.19 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 30.8 % 41 % 44.7 % 65.1 % 52.3 % 75 % 61.6 % 77.4 % 78 % 92.5 % 83.9 % 82.1 % 84.6 % 83.2 % 83.8 % 82.4 % 83.1 % 70.4 % 72.3 % 66.6 % 80.3 % 78.7 % 96.1 % 82.3 % 90.6 % 65.5 % 65.5 % 85.3 % 57.9 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 0 -0.2 +0.2 +0.2 -0.7 -0.5 Page 1 of 5 0.63 0.60 0.62 0.72 0.94 1.40 Printed: 3/30/2014 2:32 PM 176 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.89 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 8.62E+07 5.64E+07 2.40E+07 1.08 1.58 1.07 1.11 1.03 0.62 119 % 121 % 124 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.89 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 8.62E+07 5.64E+07 2.40E+07 1.08 1.58 1.07 1.85 1.22 0.58 89.5 % 100 % 119 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.39 24.51 30.49 37.39 47.50 9.56E+07 5.21E+07 4.60E+07 3.47E+07 2.59E+07 1.57 0.81 1.59 1.28 0.91 6.39E+03 6.39E+03 6.39E+03 7.79E+03 7.79E+03 9.71E+03 9.71E+03 9.71E+03 9.71E+03 9.71E+03 9.71E+03 9.71E+03 9.71E+03 9.71E+03 6.58E+03 6.58E+03 6.58E+03 6.58E+03 6.58E+03 6.58E+03 6.58E+03 2.61 2.02 2.4 4.36 2.82 2.93 2.6 2.78 2.76 2.69 2.32 2.69 2.7 2.9 3.99 2.98 3.45 2.54 2.68 4.52 2.4 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services 11.89 NotFnd 14.17 14.43 14.61 16.40 16.57 16.80 NotFnd 17.22 NotFnd 19.56 19.83 20.13 17.51 19.28 19.67 19.86 19.99 20.09 20.57 J J J J B J C C J EMPC 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0011 1.0010 1.0011 1.0137 1.0010 1.0112 1.0249 1.0507 0.9721 0.9855 1.0006 1.0011 1.1020 1.1246 1.1355 1.1426 1.1488 1.1763 0 0 0 +0.2 0 +0.1 0 +0.1 0 -1.3 -0.2 +0.1 +0.7 +0.4 +0.2 -0.5 +0.5 +0.6 Page 2 of 5 NON-EMPC 44.3 495 2,680 3,230 802 116 12.6 0 0 6.03E+05 0.00E+00 1.10E+05 2.73E+06 1.76E+05 2.52E+05 1.36E+05 2.00E+06 0.00E+00 3.08E+06 0.00E+00 1.14E+06 6.07E+05 1.62E+06 1.57E+06 1.24E+07 3.73E+06 9.91E+05 1.01E+05 2.96E+06 5.38E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 44.3 495 2,680 3,230 816 144 28.1 2.9 0 3.37 2.73 1.56 SI SI SI 1.58 1.61 1.36 SI 1.60 1.06 1.03 1.08 1.10 1.31 1.06 1.04 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 2.5 3.63 3.03 1.32 1.11 0.789 1.14 1.04 3.23 38.8 ND 5.52 213 8.88 8.3 3.97 62.3 ND 93 ND 34.5 18.4 52.9 116 689 240 46.8 5.04 249 240 Printed: 3/30/2014 2:32 PM 177 of 622 Name PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB SGS Evironmental Services Actual RT NotFnd NotFnd 22.13 22.35 22.63 22.91 23.12 23.47 NotFnd NotFnd NotFnd 26.10 26.46 20.42 22.38 23.00 23.07 23.28 24.53 24.65 24.76 24.97 25.23 25.42 25.71 25.89 26.22 26.32 26.52 NotFnd 27.49 NotFnd NotFnd 28.22 28.44 28.75 29.02 29.16 29.60 29.80 NotFnd NotFnd NotFnd NotFnd 25.72 NotFnd NotFnd 27.97 QC C C C J J EMPC C J C C C C J J C J J EMPC Pred RRT Actual RRT 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8370 0.8454 0.8560 0.8663 0.8744 0.8878 0.9870 1.0008 1.0008 0.9134 0.9384 0.9414 0.9498 1.0009 1.0060 1.0102 1.0189 1.0296 1.0373 1.0493 1.0564 1.0698 1.0739 1.0820 0.8513 0.8739 0.8809 0.8902 0.8987 0.9031 0.9167 0.9227 1.0135 0.9175 Diff Secs -1.7 -0.3 -0.3 -1.0 +0.8 -0.3 -0.2 +0.2 -0.2 -1.5 +0.1 +0.1 -0.1 0 -0.3 +0.1 +1.2 +0.2 -1.7 -0.5 +0.2 0 +0.3 +0.2 -0.3 -0.3 -0.3 0 -0.3 -0.5 -0.4 -0.4 +0.2 -0.2 Page 3 of 5 Response 0.00E+00 0.00E+00 2.91E+06 2.39E+06 1.45E+07 1.38E+07 3.47E+06 3.63E+06 0.00E+00 0.00E+00 0.00E+00 1.26E+05 1.54E+06 5.60E+04 2.75E+06 2.25E+06 1.15E+06 8.66E+05 1.39E+07 3.79E+04 3.73E+05 7.84E+06 1.99E+06 1.21E+07 1.12E+06 2.45E+06 6.08E+05 5.09E+06 5.70E+06 0.00E+00 1.12E+06 0.00E+00 0.00E+00 1.93E+05 2.95E+05 1.31E+07 7.39E+06 6.64E+04 3.61E+06 1.52E+06 0.00E+00 0.00E+00 0.00E+00 0.00E+00 8.01E+04 0.00E+00 0.00E+00 2.16E+06 Ra 1.03 1.01 1.02 1.00 1.02 1.03 1.04 1.00 0.96 0.80 0.79 0.84 0.79 0.80 0.87 0.82 0.79 0.79 0.79 0.83 0.81 0.77 0.78 0.80 0.75 0.74 0.83 0.78 0.79 0.88 0.79 0.78 0.80 0.60 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 ND ND 74.8 61.6 356 364 89.3 99.8 ND ND ND 3.6 47.2 3.22 115 109 47.9 45.7 599 1.24 18.7 276 84.9 487 34.8 114 32.2 212 167 ND 31.6 ND ND 5.69 8.38 408 245 2.19 120 50.1 ND ND ND ND 4.21 ND ND 118 6.95E+03 6.95E+03 6.95E+03 6.95E+03 6.95E+03 6.95E+03 6.95E+03 6.95E+03 6.95E+03 6.95E+03 6.95E+03 6.95E+03 6.95E+03 2.59E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 2.95E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 3.79E+03 1.87E+03 1.87E+03 2.90E+03 2.90E+03 2.90E+03 1.76 1.76 1.74 1.75 1.67 1.79 1.75 1.87 1.7 1.65 1.85 1.94 2.08 1.33 1.28 1.48 1.28 1.62 1.33 1 1.54 1.08 1.31 1.23 0.95 1.43 1.62 1.27 0.899 1.18 1.11 1.24 1.21 1.17 1.12 1.22 1.31 1.3 1.31 1.3 1.11 1.1 1.37 0.743 0.89 1.48 1.76 1.62 Printed: 3/30/2014 2:32 PM 178 of 622 Name PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB SGS Evironmental Services Actual RT NotFnd 28.30 NotFnd NotFnd 28.73 28.93 29.34 NotFnd 30.00 30.51 30.92 31.02 NotFnd 31.49 32.00 32.08 32.21 32.29 32.49 NotFnd NotFnd 34.17 34.38 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.96 NotFnd NotFnd 33.01 NotFnd 33.49 33.79 33.97 NotFnd NotFnd NotFnd NotFnd 34.86 NotFnd NotFnd 35.82 NotFnd 36.34 36.51 QC C J J C J C J EMPC C J J C J EMPC J B J C J EMPC J B EMPC C J EMPC C B J B C J Pred RRT Actual RRT 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9282 0.9424 0.9487 0.9624 0.9840 1.0007 1.0140 1.0174 1.0329 1.0495 1.0521 1.0563 1.0592 1.0657 0.9917 0.9978 1.0209 1.0885 1.1044 1.1142 1.1202 1.1498 0.9581 0.9721 0.9766 Diff Secs 0 0 0 0 -0.2 +1.5 -0.4 +0.2 +1.7 0 -0.8 +0.4 +0.4 +0.4 +0.2 +0.4 +0.4 -0.2 +0.6 +0.2 +0.6 +0.8 -0.2 -1.5 0 Page 4 of 5 Response 0.00E+00 1.75E+05 0.00E+00 0.00E+00 5.15E+05 8.15E+05 8.33E+04 0.00E+00 3.76E+05 2.19E+06 1.23E+05 1.24E+06 0.00E+00 1.90E+06 7.48E+04 5.57E+05 3.00E+06 9.40E+04 3.33E+05 0.00E+00 0.00E+00 8.91E+04 1.21E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.21E+05 0.00E+00 0.00E+00 1.70E+05 0.00E+00 3.12E+04 3.54E+05 2.81E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.79E+05 0.00E+00 0.00E+00 9.02E+04 0.00E+00 4.96E+05 9.81E+04 Ra 0.58 0.54 0.62 0.66 0.59 0.62 0.68 0.63 0.62 0.76 0.60 0.61 0.71 0.64 0.54 0.49 1.15 1.17 1.46 1.55 0.78 1.26 1.30 1.36 1.15 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 ND 7.94 ND ND 26.6 53.4 5.16 ND 21.6 106 8.18 64.6 ND 90.3 3.37 26.8 127 3.88 22.7 ND ND 3.85 4.6 ND ND ND ND ND ND 5.52 ND ND 10.6 ND 1.89 21.4 2.38 ND ND ND ND 12.3 ND ND 5.28 ND 23.8 6.33 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 2.90E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.6 1.34 1.92 1.76 1.53 1.93 1.83 1.15 1.69 1.42 1.95 1.54 1.19 1.4 1.33 1.42 1.25 1.22 2.02 1.16 1.14 1.27 1.13 1.3 1.35 1.25 0.489 0.557 0.549 0.6 0.587 0.804 0.848 0.724 0.819 0.817 1.15 0.818 0.813 0.961 0.975 0.931 0.865 0.69 0.793 0.637 0.651 0.873 Printed: 3/30/2014 2:32 PM 179 of 622 Name PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB SGS Evironmental Services Actual RT 36.86 37.05 37.14 37.41 NotFnd 37.74 38.49 NotFnd NotFnd NotFnd 35.50 NotFnd NotFnd NotFnd NotFnd NotFnd 38.55 NotFnd 39.09 NotFnd 39.27 39.64 NotFnd NotFnd NotFnd NotFnd 42.08 NotFnd 43.15 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 43.74 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd QC J J J C J J C J EMPC J EMPC J EMPC J J EMPC C J B C J EMPC J EMPC C Pred RRT Actual RRT Diff Secs 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9858 0.9911 0.9934 1.0007 1.0096 0.9641 1.0086 1.0952 1.1105 1.1157 1.1262 0.9200 0.9435 1.1009 - -0.2 0 +0.2 -0.9 0 0 0 0 +0.9 +0.2 0 +1.5 +0.3 +2.1 Page 5 of 5 Response Ra RRF Conc. / Recv. 4.07E+04 3.75E+04 4.47E+04 5.65E+05 0.00E+00 8.52E+04 9.82E+04 0.00E+00 0.00E+00 0.00E+00 3.20E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.32E+04 0.00E+00 4.12E+04 0.00E+00 5.98E+04 2.96E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.31E+05 0.00E+00 4.91E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.96E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.17 1.06 1.07 1.29 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 2.96 2.2 2.16 33.9 ND 3.8 5.65 ND ND ND 2.03 ND ND ND ND ND 4.8 ND 2.54 ND 4.59 2.36 ND ND ND ND 7.97 ND 3.85 ND ND ND ND ND ND 2.9 ND ND ND ND ND ND ND ND 1.14 1.32 1.23 1.29 1.60 1.15 1.38 0.99 1.44 1.05 Noise / Recv. Low DL / Recv. High 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.52E+03 1.52E+03 1.52E+03 1.44E+03 1.44E+03 1.44E+03 1.44E+03 1.44E+03 1.44E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.29E+03 1.17E+03 1.17E+03 1.17E+03 2.96E+03 2.96E+03 2.96E+03 0.983 0.796 0.654 0.813 0.693 0.604 0.911 0.759 0.765 0.768 0.901 0.95 0.855 0.912 1.28 1.34 1.26 1.22 1.19 1.4 1.47 1.53 1.35 1.53 1.49 1.15 1.17 1.07 1.6 1.17 0.887 0.823 0.885 0.826 0.87 1.3 1.22 1.21 1.58 1.47 1.18 2.16 2.14 4.29 Printed: 3/30/2014 2:32 PM 180 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 1.53e8 7.66e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 3.58e7 1.79e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 2.93e7 1.47e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 5.36e7 2.68e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 3.36e7 1.68e7 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.93e6 2.97e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.52e6 2.76e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 223-376 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:45 Page 1 of 21 181 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 PCB-1 4.65e5 11.89 Rel. Int. 100% Abs. Int. 1.86e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.76e3 9.31e4 PCB-3 8.07e4 14.17 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 1.38e5 11.88 Rel. Int. 100% Abs. Int. 5.76e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 2.63e3 2.88e4 PCB-3 2.96e4 14.17 0% 11.0 12.0 13.0 14.0 15.0 ES-3 3.27e7 14.16 ES-1 2.68e7 11.87 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 1.09e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 4.91e3 5.47e6 0% 11.0 12.0 13.0 15.0 ES-3 9.84e6 14.16 ES-1 8.28e6 11.87 Rel. Int. 100% 14.0 0.00e0 16.0 RT Abs. Int. 3.46e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.08e4 1.73e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.53e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 7.66e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7379, 7042 scc: 223-376 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:46 (LKB) Printed: 30-Mar-2014 14:45 Page 2 of 21 182 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Rel. Int. 100% Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Abs. Int. 5.81e5 PCB-4 1.66e6 14.43 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 4.75e3 2.90e5 PCB-10 1.07e5 SI 14.61 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 1.07e6 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.98e5 PFK INTERFERENCE DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.43e4 1.99e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.39e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.85e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 6.22e3 2.42e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 8.47e6 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.99e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.71e3 1.49e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.53e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 7.66e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9018, 6790 scc: 223-376 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:45 Page 3 of 21 183 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 PCB-8 1.90e6 17.22 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 5.92e3 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Abs. Int. 5.95e5 PCB-6 1.22e6 16.80 PCB-11 6.58e5 19.56 PCB-9 1.54e5 SI 16.40 PCB-15 1.00e6 20.13 13/12 3.70e5 SI 19.83 2.98e5 0% 17.0 Rel. Int. 100% 19.0 20.0 21.0 PCB-8 1.18e6 17.22 PCB-6 7.73e5 16.80 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 3.20e4 18.0 Abs. Int. 4.39e5 PCB-11 4.83e5 19.56 PCB-15 6.24e5 20.13 2.19e5 PFK INTERFERENCE 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 JS-9 5.84e7 16.39 0.00e0 RT Abs. Int. 1.84e7 ES-15 3.95e7 20.12 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.59e4 9.22e6 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 21.0 JS-9 3.72e7 16.39 0.00e0 RT Abs. Int. 1.18e7 ES-15 2.52e7 20.12 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 6.11e3 5.91e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.58e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.79e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3176, 4011 scc: 223-376 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:46 (LKB) Printed: 30-Mar-2014 14:45 Page 4 of 21 184 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Rel. Int. 100% Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Abs. Int. 1.83e6 30/18 6.31e6 19.28 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.45e3 PCB-17 1.94e6 19.67 PCB-19 8.07e5 17.51 PCB-27 5.20e5 19.86 PCB-16 1.53e6 20.09 PCB-32 2.75e6 20.57 9.14e5 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 1.83e6 30/18 6.14e6 19.28 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 3.14e3 PCB-17 1.79e6 19.67 PCB-19 7.62e5 17.51 PCB-27 4.71e5 19.86 PCB-16 1.44e6 20.09 PCB-32 2.63e6 20.57 9.16e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 5.29e6 ES-19 1.31e7 17.49 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 6.18e4 0.00e0 RT 2.65e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.22e7 17.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.79e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 4.58e4 1.89e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.58e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.79e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7354, 4097 scc: 223-376 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:45 Page 5 of 21 185 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 PCB-31 7.30e6 28/20 22.63 6.90e6 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 3.81e3 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 26/29 1.48e6 22.13 Abs. Int. 2.05e6 21/33 1.75e6 23.12 PCB-25 1.20e6 22.35 1.03e6 PCB-22 1.84e6 23.47 PCB-37 7.69e5 26.46 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 7.19e6 28/20 22.63 6.90e6 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 3.15e3 24.0 26/29 1.44e6 22.13 PCB-25 1.19e6 22.35 Abs. Int. 1.96e6 21/33 1.72e6 23.12 9.81e5 PCB-22 1.79e6 23.47 PCB-37 7.68e5 26.46 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 4.48e7 22.89 Rel. Int. 100% ES-37 3.41e7 26.44 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 6.60e4 Abs. Int. 1.21e7 6.06e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 4.14e7 22.89 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.09e7 26.44 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 4.89e4 Abs. Int. 1.11e7 5.55e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.93e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.47e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2099, 7899 scc: 223-376 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:46 (LKB) Printed: 30-Mar-2014 14:45 Page 6 of 21 186 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 PCB-54 3.01e4 20.42 Rel. Int. 100% Abs. Int. 1.14e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.13e3 5.70e3 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 3.15e4 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.60e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.46e3 4.30e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.23e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.44e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 8.81e3 1.72e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.54e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.45e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 5.85e3 2.23e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.58e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.79e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1422, 3063 scc: 223-376 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:41 (LKB) Printed: 30-Mar-2014 14:45 Page 7 of 21 187 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Rel. Int. 100% PCB-52 6.15e6 24.53 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.36e3 50/53 1.22e6 22.38 PCB-51 5.24e5 23.07 PCB-45 9.90e5 23.00 69/49 3.46e6 24.97 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 44/47… 5.38e6 25.42 PCB-48 8.79e5 25.23 PCB-46 3.81e5 23.28 Abs. Int. 1.65e6 PCB-42 1.09e6 25.89 59/62… 5.09e5 25.71 PCB-41 2.64e5 26.22 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 7.71e6 24.53 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.59e3 50/53 1.53e6 22.38 PCB-51 6.23e5 23.07 PCB-45 1.26e6 23.00 69/49 4.38e6 24.97 23.0 24.0 25.0 Abs. Int. 2.05e6 PCB-42 1.36e6 25.89 26.0 JS-52 2.33e7 24.51 Rel. Int. 100% 8.26e5 0.00e0 RT 44/47… 6.77e6 25.42 0% 22.0 PCB-64 2.53e6 26.52 26.0 PCB-48 1.11e6 25.23 PCB-46 4.85e5 23.28 71/40 2.22e6 26.32 71/40 2.87e6 26.32 PCB-64 3.17e6 26.52 1.03e6 0.00e0 RT Abs. Int. 6.50e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.87e4 3.25e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.88e7 24.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.95e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 9.22e3 3.98e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.93e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.47e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8918, 4480 scc: 223-376 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:47 (LKB) Printed: 30-Mar-2014 14:46 Page 8 of 21 188 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.76e3 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Abs. Int. 1.03e6 61/70... 5.73e6 PCB-66 28.75 3.25e6 29.02 PCB-56 1.59e6 29.60 PCB-68 4.78e5 27.49 5.16e5 PCB-60 6.67e5 29.80 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.03e3 30.0 32.0 34.0 36.0 38.0 Abs. Int. 1.32e6 61/70... 7.39e6 PCB-66 28.74 4.14e6 29.02 PCB-68 6.38e5 27.49 PCB-56 2.02e6 29.60 6.59e5 PCB-60 8.56e5 29.79 PCB-77 2.64e5 32.78 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.47e7 32.29 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.57e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.66e6 ES-77 2.46e7 32.77 3.83e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.10e7 32.29 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.08e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.76e6 ES-77 3.12e7 32.77 3.88e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.68e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3735, 6101 scc: 223-376 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:46 Page 9 of 21 189 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 PCB-96 3.94e4 25.72 Rel. Int. 100% Abs. Int. 1.07e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 8.68e2 5.37e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 4.95e4 25.71 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 1.00e3 7.88e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.11e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.84e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 2.14e3 2.92e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.31e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.44e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 3.24e3 1.72e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.93e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.47e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8257, 0474 scc: 223-376 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:38 (LKB) Printed: 30-Mar-2014 14:46 Page 10 of 21 190 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.41e3 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 113/90… 8.39e5 30.51 PCB-95 8.11e5 27.97 PCB-84 PCB-91 3.13e5 1.82e5 28.93 28.73 PCB-110 1.14e6 32.21 PCB-118 7.01e5 34.76 PCB-99108/119... 4.81e5 7.29e5 31.02 31.49 116/85 2.08e5 PCB-115PCB-82 PCB-83 32.08 3.90e4 1.29e5 5.00e4 32.29 32.49 30.92 PCB-92 1.40e5 30.00 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Abs. Int. 2.77e5 PCB-105 3.72e5 35.77 1.38e5 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.49e3 PCB-95 1.35e6 27.97 PCB-91 3.33e5 28.73 PCB-84 5.02e5 PCB-102 28.93 1.11e5 28.30 32.0 113/90… 1.35e6 30.51 34.0 38.0 PCB-110 1.86e6 32.21 PCB-99108/119... 7.58e5 1.17e6 116/85 31.02 31.49 3.49e5 PCB-115PCB-82 32.08 5.49e4 2.03e5 32.29 32.49 PCB-92 2.36e5 30.00 36.0 Abs. Int. 4.69e5 PCB-118 1.13e6 34.76 PCB-109 9.50e4 34.38 PCB-105 5.92e5 35.77 2.35e5 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 3.46e7 32.78 JS-101 2.83e7 30.49 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 3.32e3 0.00e0 RT 36.0 ES-118 ES-114 2.84e7 ES-123 2.77e7 35.20 2.80e7 34.74 34.46 38.0 0.00e0 RT Abs. Int. 8.16e6 ES-105 2.86e7 35.75 4.08e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 2.19e7 32.78 JS-101 1.77e7 30.49 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 3.69e3 34.0 36.0 ES-114 ES-118 1.76e7 ES-123 1.74e7 35.20 1.75e7 34.74 34.46 38.0 0.00e0 RT Abs. Int. 5.41e6 ES-105 1.78e7 35.75 2.71e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.68e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8630, 6592 scc: 223-376 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:46 Page 11 of 21 191 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Rel. Int. 100% Abs. Int. 8.71e4 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 1.02e3 4.35e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 1.96e5 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.18e3 9.78e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.33e6 ES-126 2.38e7 38.36 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 4.77e3 2.67e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.62e6 ES-126 1.58e7 38.36 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 4.29e3 1.81e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.36e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.68e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1682, 5677 scc: 223-376 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:46 Page 12 of 21 192 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Rel. Int. 100% Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 153/168 2.85e5 36.34 147/149 2.44e5 33.79 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 7.78e2 PCB-136 6.45e4 30.96 151/135 9.13e4 33.01 PCB-144 2.02e4 33.49 PCB-134 1.56e4 33.97 PCB-132 9.99e4 34.86 163/138… 3.19e5 37.41 PCB-141 5.25e4 PCB-137 36.51 1.93e4 37.05 PCB-146 5.09e4 35.82 Abs. Int. 6.94e4 PCB-158 4.54e4 37.74 0% 28.0 30.0 32.0 34.0 36.0 153/168 2.11e5 36.34 Rel. Int. 100% 147/149 1.57e5 33.78 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 5.57e2 PCB-136 5.63e4 30.96 151/135 7.82e4 33.01 PCB-144 1.39e4 33.49 PCB-134 2.00e4 33.97 38.0 PCB-132 7.94e4 34.86 163/138… 2.46e5 37.41 0% 28.0 30.0 32.0 34.0 36.0 ES-155 2.57e7 30.32 Rel. Int. 100% ES-153 1.83e7 36.32 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 2.08e3 0.00e0 RT Abs. Int. 5.70e4 PCB-137 1.82e4 PCB-141 37.05 PCB-158 4.56e4 PCB-164 3.99e4 2.16e4 36.51 37.74 37.14 PCB-146 3.93e4 35.82 3.47e4 38.0 2.85e4 0.00e0 RT Abs. Int. 6.55e6 JS-138 1.95e7 37.39 3.27e6 0% 28.0 30.0 32.0 34.0 ES-155 2.01e7 30.32 Rel. Int. 100% 36.0 ES-153 1.40e7 36.32 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.49e3 38.0 0.00e0 RT Abs. Int. 4.93e6 JS-138 1.53e7 37.39 2.46e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.68e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9459, 0169 scc: 223-376 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:46 Page 13 of 21 193 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Abs. Int. 1.53e4 128/166 5.59e4 38.49 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 9.87e2 PCB-167 1.47e4 39.93 156/157 3.45e4 40.91 7.63e3 0% 39.0 Rel. Int. 100% 40.0 128/166 4.24e4 38.49 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.28e4 156/157 3.68e4 40.91 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 5.29e2 PCB-167 1.04e4 39.93 6.39e3 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.32e7 39.92 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 3.55e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.36e7 40.90 0.00e0 RT Abs. Int. 7.66e6 ES-169 2.03e7 43.62 3.83e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.86e7 39.92 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 4.04e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.46e7 40.90 0.00e0 RT Abs. Int. 6.16e6 ES-169 1.57e7 43.62 3.08e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.36e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.68e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4411, 0060 scc: 223-376 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:47 (LKB) Printed: 30-Mar-2014 14:46 Page 14 of 21 194 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 PCB-179 1.93e4 35.50 Rel. Int. 100% Abs. Int. 5.83e3 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 8.13e2 2.91e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 1.57e4 35.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.35e3 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.29e2 2.67e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.63e7 35.20 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.13e6 CS/SS-178 1.24e7 37.76 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.75e3 2.07e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.51e7 35.20 Rel. Int. 100% Abs. Int. 3.83e6 CS/SS-178 1.16e7 37.76 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.52e3 0.00e0 RT 1.92e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 2.68e7 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8818, 3714 scc: 223-376 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:38 (LKB) Printed: 30-Mar-2014 14:46 Page 15 of 21 195 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 180/193 6.54e4 42.08 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 1.18e3 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 PCB-187 4.63e4 38.55 PCB-174 PCB-183 3.19e4 3.23e4 39.27 39.09 Abs. Int. 2.15e4 PCB-170 3.46e4 43.15 PCB-177 2.00e4 39.64 1.07e4 0% 39.0 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 7.38e2 PCB-187 3.59e4 38.55 40.0 41.0 42.0 43.0 44.0 45.0 180/193 6.60e4 42.08 PCB-174 2.78e4 PCB-183 39.27 2.02e4 39.08 Abs. Int. 1.57e4 PCB-170 2.41e4 43.15 PCB-177 1.45e4 39.65 7.83e3 0% 39.0 40.0 41.0 42.0 ES-180 1.47e7 42.06 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.07e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.67e6 ES-170 1.25e7 43.13 1.83e6 0% 39.0 40.0 41.0 42.0 ES-180 1.38e7 42.06 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 2.80e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.38e6 ES-170 1.17e7 43.13 1.69e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.36e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.68e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7871, 5525 scc: 223-376 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:47 (LKB) Printed: 30-Mar-2014 14:46 Page 16 of 21 196 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Rel. Int. 100% Abs. Int. 2.78e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 7.62e2 1.39e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 1.91e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 7.69e2 9.56e2 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.72e7 45.74 0.00e0 RT Abs. Int. 4.02e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.37e3 2.01e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.66e7 45.74 0.00e0 RT Abs. Int. 3.88e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 1.94e3 1.94e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.93e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.97e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7609, 8799 scc: 223-376 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:46 Page 17 of 21 197 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 198/199 1.64e4 43.74 Rel. Int. 100% Abs. Int. 4.23e3 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 7.38e2 2.12e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 1.57e4 43.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.31e3 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 5.49e2 3.16e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.45e7 39.73 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.53e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.39e3 1.77e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.60e7 39.73 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.83e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.78e3 1.92e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.36e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.68e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0419, 5958 scc: 223-376 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:46 Page 18 of 21 198 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Rel. Int. 100% Abs. Int. 2.68e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PB 4σ 5.93e2 1.34e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.96e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PB 4σ 5.73e2 1.48e3 0% 46.0 47.0 48.0 JS-194 1.24e7 47.50 Rel. Int. 100% OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 1.38e3 49.0 50.0 0.00e0 RT Abs. Int. 2.93e6 ES-205 9.95e6 47.90 1.46e6 0% 46.0 47.0 48.0 JS-194 1.36e7 47.50 Rel. Int. 100% 49.0 50.0 0.00e0 RT Abs. Int. 3.19e6 ES-205 1.12e7 47.90 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 1.65e3 1.59e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.93e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.97e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5896, 2548 scc: 223-376 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:46 Page 19 of 21 199 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 Rel. Int. 100% Abs. Int. 2.99e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 1.08e3 1.50e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 4.32e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 1.88e3 2.16e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 2.89e6 ES-208 1.14e7 45.36 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.97e3 ES-206 6.28e6 49.37 1.44e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.59e6 ES-208 1.46e7 45.36 ES-206 7.81e6 49.37 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.59e3 1.79e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.93e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.97e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8621, 0498 scc: 223-376 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:46 Printed: 30-Mar-2014 14:46 Page 20 of 21 200 of 622 SGS-AP ID: A6506_11899_PCB_005 Instr: AutoSpec-Premier MM7 Sample ID: PB081_A-1SWMID-140314-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 53 Acq: 27-Mar-2014 17:59:02 User: LKB Datafile: 140327X09 PCB-209 5.34e4 50.82 Rel. Int. 100% Abs. Int. 1.38e4 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 5.84e2 6.90e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 4.91e4 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.46e4 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.32e2 7.31e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 9.06e6 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.86e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 8.69e2 9.32e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 7.61e6 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.66e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 8.90e2 8.29e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.52e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 2.76e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_005.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2822, 8912 scc: 223-376 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:47 (LKB) Printed: 30-Mar-2014 14:46 Page 21 of 21 201 of 622 Lab ID: A6506_11899_PCB_006 ACQ: 27-Mar-2014 18:54:13 LKB Wt/Vol: 0.96 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Client ID: PB089-1SWMID-140314-N (TOTAL) UTP: 30-Mar-2014 13:53 LKB J-level: 10.4 pg/L Datafile: 140327X10 RPT: 30-Mar-2014 14:31 LB Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services Actual RT 32.80 32.32 35.78 35.24 34.78 34.50 NotFnd 40.93 39.95 NotFnd NotFnd 50.84 11.88 14.17 14.42 20.13 17.50 26.45 20.41 32.78 32.30 25.39 35.76 35.22 34.76 34.47 38.37 36.34 30.34 40.92 39.93 43.63 43.15 42.08 35.21 45.76 39.75 47.92 49.38 45.37 50.81 QC J J J J C J EMPC Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0005 1.0006 1.0006 1.0006 1.0008 1.0002 1.0005 1.0005 0 0 0 -0.2 0 +0.4 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7247 0.8641 0.8794 1.2276 1.0673 1.0790 0.8326 1.3370 1.3176 0.8322 1.1723 1.1546 1.1394 1.1302 1.2579 0.9716 0.8111 1.0941 1.0678 1.1666 0.9080 0.8855 0.7410 0.9629 0.8365 1.0084 1.0392 0.9548 1.0693 Split: 1 Checkcode: 431-600-JCR Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.82 0.82 0.60 0.65 0.60 0.64 +0.3 1.37E+06 6.87E+04 3.47E+06 2.11E+05 7.07E+06 1.86E+05 0.00E+00 3.99E+05 1.16E+05 0.00E+00 0.00E+00 1.58E+05 1.12 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 33.7 1.79 107 5.96 206 5.43 ND 14.3 3.75 ND ND 11.5 4.99E+03 4.99E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.93E+03 1.73E+03 1.73E+03 1.73E+03 1.67E+03 1.15E+03 1.29 1.29 0.927 0.896 0.892 0.929 1.42 0.87 0.584 0.68 0.723 0.979 +0.1 +0.1 -0.1 +0.6 0 +0.5 -0.2 +1.2 +1.2 -0.5 +0.6 +0.6 +0.6 +0.6 +0.9 0 -0.5 +0.5 +0.2 +0.5 -0.3 -0.3 -0.6 0 -0.2 0 0 -0.3 -0.3 4.23E+07 5.24E+07 2.83E+07 9.00E+07 3.34E+07 8.17E+07 4.14E+07 7.35E+07 7.15E+07 4.46E+07 6.10E+07 6.12E+07 6.02E+07 5.88E+07 5.33E+07 4.34E+07 5.99E+07 1.06E+08 5.56E+07 4.82E+07 3.25E+07 3.89E+07 4.31E+07 4.64E+07 4.10E+07 3.17E+07 2.13E+07 3.58E+07 2.57E+07 3.25 3.32 1.59 1.56 1.06 1.09 0.78 0.81 0.81 1.62 1.58 1.62 1.58 1.58 1.55 1.27 1.28 1.29 1.31 1.27 1.09 1.10 1.07 1.02 0.90 0.89 0.79 0.79 1.19 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 31.3 % 42.5 % 47.8 % 76.3 % 58.3 % 76.2 % 74.5 % 82.4 % 81 % 93.1 % 85.1 % 84.2 % 87.1 % 83.1 % 87 % 82.7 % 80.9 % 71.1 % 71.5 % 66.4 % 84.6 % 84 % 98.4 % 88.4 % 90.8 % 76.9 % 77.3 % 92 % 69.8 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% -0.7 -0.2 Page 1 of 5 1.14 1.01 Printed: 3/30/2014 2:32 PM 202 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 1.04E+08 7.19E+07 3.09E+07 1.09 1.59 1.08 1.11 1.03 0.62 114 % 119 % 116 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.90 32.80 37.78 0.9339 1.0750 1.0100 0.9339 1.0751 1.0100 0 +0.2 0 1.04E+08 7.19E+07 3.09E+07 1.09 1.59 1.08 1.85 1.22 0.58 87 % 98.8 % 114 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.40 24.52 30.50 37.40 47.52 1.13E+08 6.45E+07 5.96E+07 4.66E+07 3.31E+07 1.55 0.80 1.61 1.30 0.93 5.74E+03 5.74E+03 5.74E+03 8.27E+03 8.27E+03 1.25E+04 1.25E+04 1.25E+04 1.25E+04 1.25E+04 1.25E+04 1.25E+04 1.25E+04 1.25E+04 6.78E+03 6.78E+03 6.78E+03 6.78E+03 6.78E+03 6.78E+03 6.78E+03 1.82 1.44 1.71 3.67 2.37 2.54 2.26 2.41 2.39 2.34 2.02 2.33 2.34 2.52 3.27 2.45 2.84 2.09 2.2 3.71 1.98 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services 11.90 NotFnd 14.19 14.44 14.61 16.42 16.58 16.81 NotFnd 17.23 NotFnd 19.57 19.84 20.15 17.52 19.29 19.68 19.87 19.99 20.11 20.58 J J J J B C C J EMPC 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0010 1.0011 1.0011 1.0133 1.0010 1.0111 1.0249 1.0507 0.9721 0.9853 1.0007 1.0011 1.1020 1.1245 1.1355 1.1423 1.1487 1.1761 -0.1 +0.1 0 -0.2 0 0 0 +0.1 0 -1.5 -0.1 +0.1 +0.7 +0.2 +0.2 -0.8 +0.4 +0.4 Page 2 of 5 NON-EMPC 21.9 339 2,090 4,050 1,920 539 146 27.2 0 3.41E+05 0.00E+00 1.08E+05 2.09E+06 1.24E+05 1.98E+05 1.29E+05 2.77E+06 0.00E+00 2.22E+06 0.00E+00 1.78E+06 1.04E+06 1.57E+06 1.52E+06 9.59E+06 3.82E+06 9.30E+05 8.02E+04 1.92E+06 5.95E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 21.9 339 2,090 4,050 1,930 546 149 32.7 0 3.20 2.96 1.51 SI SI SI 1.58 1.62 1.49 1.53 1.65 1.06 1.04 1.07 1.11 1.47 1.05 1.03 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 1.76 3.09 2.65 1.04 0.927 0.622 0.755 0.813 2.03 17.6 ND 4.25 125 4.8 4.53 2.63 60.3 ND 46.8 ND 37.4 22 35.6 82.4 389 180 32.1 2.93 118 195 Printed: 3/30/2014 2:32 PM 203 of 622 Name PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB SGS Evironmental Services Actual RT 21.74 NotFnd 22.14 22.36 22.65 22.92 23.13 23.49 NotFnd 25.22 NotFnd 26.10 26.48 20.43 22.39 23.01 23.08 23.29 24.54 24.67 24.77 24.98 25.24 25.44 25.73 25.90 26.23 26.33 26.53 27.24 27.50 27.87 28.08 28.23 28.46 28.76 29.03 29.17 29.61 29.81 NotFnd 31.46 NotFnd NotFnd 25.72 27.42 27.61 27.99 QC J C C C J J J C J C C C C J J J EMPC C J J J EMPC J EMPC J Pred RRT Actual RRT Diff Secs 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8217 0.8371 0.8454 0.8560 0.8664 0.8744 0.8878 0.9535 0.9868 1.0009 1.0010 0.9134 0.9383 0.9412 0.9498 1.0009 1.0062 1.0101 1.0189 1.0296 1.0376 1.0494 1.0564 1.0699 1.0739 1.0820 0.8434 0.8514 0.8628 0.8693 0.8739 0.8810 0.8903 0.8987 0.9031 0.9167 0.9227 0.9738 1.0134 0.8989 0.9050 0.9175 -0.1 -1.6 -0.3 -0.3 -0.8 +0.8 -0.3 +2.0 -0.5 +0.3 0 -1.5 0 -0.1 -0.1 0 0 0 +1.2 +0.2 -1.2 -0.3 +0.2 +0.2 +0.3 +0.2 -0.3 -0.2 -0.3 0 -0.3 -0.2 +0.2 -0.3 -0.5 -0.4 -0.4 +0.2 0 0 -0.2 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 1.69E+05 0.00E+00 4.95E+06 5.52E+06 1.66E+07 1.80E+07 2.86E+06 4.17E+06 0.00E+00 1.43E+05 0.00E+00 3.12E+05 2.01E+06 8.21E+04 3.57E+06 2.12E+06 1.88E+06 1.06E+06 2.04E+07 6.54E+04 5.45E+05 1.40E+07 2.32E+06 1.90E+07 1.71E+06 4.20E+06 6.83E+05 8.01E+06 9.49E+06 2.00E+05 1.38E+06 1.36E+05 5.52E+04 4.65E+05 8.48E+05 2.56E+07 1.61E+07 2.14E+05 7.26E+06 3.11E+06 0.00E+00 1.29E+05 0.00E+00 0.00E+00 1.53E+05 8.54E+04 7.35E+04 5.38E+06 0.91 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 3.37 ND 97.9 110 315 366 56.7 88.5 ND 2.69 ND 6.89 47.6 3.06 113 77.1 59.2 42.1 666 1.62 20.6 372 74.5 574 40 147 27.3 251 210 4.52 29.5 3.22 1.28 10.4 18.2 600 403 5.32 182 77.1 ND 2.73 ND ND 5.99 3.2 3.28 220 0.99 1.01 1.00 1.01 0.97 1.02 1.12 1.19 1.03 0.80 0.82 0.79 0.78 0.80 0.79 0.87 0.76 0.78 0.73 0.79 0.77 0.79 0.76 0.80 0.78 0.71 0.78 0.75 0.64 0.78 0.79 0.78 0.80 0.84 0.78 0.83 0.77 0.77 0.74 0.59 0.62 Noise / Recv. Low DL / Recv. High 8.72E+03 8.72E+03 8.72E+03 8.72E+03 8.72E+03 8.72E+03 8.72E+03 8.72E+03 8.72E+03 8.72E+03 8.72E+03 8.72E+03 8.72E+03 2.51E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 2.88E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 4.99E+03 1.68E+03 1.68E+03 3.06E+03 3.06E+03 3.06E+03 1.71 1.71 1.69 1.7 1.62 1.74 1.7 1.82 1.65 1.61 1.8 1.89 2.03 0.798 0.9 1.04 0.9 1.14 0.931 0.706 1.08 0.758 0.918 0.863 0.667 1 1.14 0.895 0.632 1.12 1.05 1.17 1.14 1.1 1.06 1.16 1.23 1.22 1.24 1.22 1.05 1.04 1.3 0.495 0.592 1.19 1.42 1.3 Printed: 3/30/2014 2:32 PM 204 of 622 Name PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB SGS Evironmental Services Actual RT 28.20 28.31 NotFnd NotFnd 28.75 28.94 29.36 NotFnd 30.02 30.53 30.93 31.03 NotFnd 31.51 32.02 32.09 32.22 32.32 32.51 NotFnd NotFnd 34.19 34.39 NotFnd 35.07 NotFnd 30.36 NotFnd NotFnd 30.97 NotFnd NotFnd 33.02 33.24 33.51 33.80 33.99 NotFnd 34.32 34.49 NotFnd 34.88 35.28 NotFnd 35.84 NotFnd 36.36 36.53 QC J C J EMPC C C J C J J C J J EMPC C J J C J J C J EMPC J C Pred RRT Actual RRT Diff Secs 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9245 0.9282 0.9424 0.9487 0.9624 0.9840 1.0007 1.0141 1.0174 1.0329 1.0495 1.0521 1.0564 1.0596 1.0656 0.9917 0.9977 1.0090 1.0008 1.0208 1.0886 1.0956 1.1045 1.1142 1.1204 1.1314 1.1370 1.1497 1.1629 0.9581 0.9722 0.9766 -0.2 0 0 0 0 -0.2 +1.5 -0.2 +0.2 +1.7 0 -0.8 +0.6 +1.2 +0.2 +0.2 +0.2 -0.2 +0.2 +0.2 0 +0.4 +0.8 +0.2 +1.0 +0.4 +0.2 +0.6 +0.6 -0.2 -1.3 0 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.33E+05 4.67E+05 0.00E+00 0.00E+00 1.56E+06 2.16E+06 1.96E+05 0.00E+00 1.23E+06 7.12E+06 4.19E+05 4.18E+06 0.00E+00 5.88E+06 3.06E+05 1.78E+06 9.96E+06 1.82E+05 9.95E+05 0.00E+00 0.00E+00 3.02E+05 6.13E+05 0.00E+00 1.16E+05 0.00E+00 2.66E+04 0.00E+00 0.00E+00 5.09E+05 0.00E+00 0.00E+00 7.94E+05 3.83E+04 1.18E+05 2.03E+06 1.48E+05 0.00E+00 6.55E+04 3.98E+04 0.00E+00 9.02E+05 3.28E+04 0.00E+00 4.27E+05 0.00E+00 2.50E+06 4.15E+05 0.62 0.57 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 5.39 15.9 ND ND 60.4 106 9.09 ND 52.8 257 20.8 163 ND 209 10.3 64.2 316 5.63 50.9 ND ND 9.76 17.5 ND 3.94 ND 0.733 ND ND 17.3 ND ND 35.8 1.48 5.12 88.2 9.02 ND 2.83 2.03 ND 44.7 1.51 ND 18 ND 86.5 19.3 0.61 0.62 0.72 0.61 0.63 0.62 0.62 0.63 0.59 0.63 0.63 0.55 0.67 0.68 0.61 0.68 0.81 1.29 1.23 1.36 1.26 1.23 1.21 1.42 1.63 1.26 1.20 1.29 1.27 1.26 Noise / Recv. Low DL / Recv. High 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.29 1.08 1.55 1.42 1.23 1.56 1.47 0.924 1.36 1.15 1.58 1.24 0.962 1.13 1.07 1.14 1.01 0.983 1.63 0.935 0.921 1.03 0.908 1.05 1.07 0.95 0.355 0.405 0.399 0.436 0.426 0.536 0.566 0.483 0.547 0.545 0.766 0.546 0.543 0.641 0.651 0.621 0.577 0.461 0.529 0.425 0.434 0.583 Printed: 3/30/2014 2:32 PM 205 of 622 Name PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB SGS Evironmental Services Actual RT 36.87 37.07 37.15 37.43 NotFnd 37.76 38.51 NotFnd NotFnd NotFnd 35.52 35.97 36.27 NotFnd 37.79 NotFnd 38.57 NotFnd 39.09 39.16 39.29 39.66 NotFnd 40.20 41.54 NotFnd 42.10 NotFnd 43.17 43.62 39.78 40.54 NotFnd NotFnd 41.41 43.75 44.30 44.48 45.60 47.54 NotFnd NotFnd NotFnd NotFnd QC J J J C C J J J J J J C J C J EMPC J J J J C J EMPC J J EMPC J Pred RRT Actual RRT Diff Secs 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9859 0.9911 0.9932 1.0007 1.0096 0.9642 1.0087 1.0215 1.0300 1.0733 1.0953 1.1101 1.1122 1.1157 1.1263 1.1417 0.9078 0.9200 0.9434 0.9533 1.0007 1.0200 1.0417 1.1007 1.1146 1.1190 0.9517 0.9921 - 0 0 -0.2 -0.9 0 +0.2 +0.2 -0.2 0 0 +0.2 0 -0.7 +0.2 +0.2 +1.0 -0.5 +1.5 0 0 +0.5 -0.7 -0.2 +1.6 0 +0.5 +0.3 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 1.70E+05 1.57E+05 2.65E+05 3.16E+06 0.00E+00 4.00E+05 5.03E+05 0.00E+00 0.00E+00 0.00E+00 2.00E+05 4.77E+04 5.36E+04 0.00E+00 6.13E+04 0.00E+00 5.04E+05 0.00E+00 2.42E+05 3.72E+04 3.57E+05 1.90E+05 0.00E+00 1.08E+05 4.83E+04 0.00E+00 8.42E+05 0.00E+00 3.04E+05 7.46E+04 6.00E+04 3.30E+04 0.00E+00 0.00E+00 2.26E+04 1.41E+05 5.02E+04 7.82E+04 2.64E+04 8.65E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.07 1.40 1.16 1.27 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 8.89 6.64 9.2 136 ND 12.8 21.1 ND ND ND 8.93 2.25 2.28 ND 3.91 ND 23.5 ND 10.6 1.93 19.5 10.7 ND 6.1 2.66 ND 36.3 ND 17.2 3.08 2.89 1.47 ND ND 1.07 9.96 3.34 5.14 2.18 6.68 ND ND ND ND 1.11 1.29 0.95 1.20 0.94 1.12 1.03 1.07 1.13 1.14 1.19 1.08 1.04 1.06 1.14 1.33 0.82 0.86 0.99 0.93 1.11 0.92 1.37 0.86 Noise / Recv. Low DL / Recv. High 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.73E+03 1.73E+03 1.73E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.70E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.45E+03 1.39E+03 1.39E+03 1.39E+03 2.74E+03 2.74E+03 2.74E+03 0.656 0.531 0.437 0.542 0.463 0.403 0.76 0.633 0.638 0.466 0.547 0.576 0.519 0.553 0.78 0.867 0.815 0.787 0.767 0.907 0.954 0.99 0.876 0.99 0.965 0.742 0.755 0.694 0.981 0.716 0.696 0.646 0.694 0.648 0.682 1.02 0.958 0.949 1.24 1.16 0.93 1.51 1.49 2.55 Printed: 3/30/2014 2:32 PM 206 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 1.44e8 7.20e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 3.24e7 1.62e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 2.73e7 1.37e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 5.33e7 2.67e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 3.22e7 1.61e7 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.15e6 2.58e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 4.72e6 2.36e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 431-600 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:46 Page 1 of 21 207 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 PCB-1 2.60e5 11.90 Rel. Int. 100% Abs. Int. 1.05e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.41e3 5.26e4 PCB-3 8.05e4 14.19 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 8.13e4 11.90 Rel. Int. 100% Abs. Int. 2.81e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.33e3 PCB-3 2.72e4 14.18 1.41e4 0% 11.0 12.0 13.0 14.0 15.0 ES-3 4.03e7 14.17 ES-1 3.24e7 11.88 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 1.34e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.86e3 6.68e6 0% 11.0 12.0 13.0 15.0 ES-3 1.21e7 14.17 ES-1 9.96e6 11.88 Rel. Int. 100% 14.0 0.00e0 16.0 RT Abs. Int. 4.24e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.10e4 2.12e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.44e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 7.20e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8987, 3262 scc: 431-600 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 10:20 (LKB) Printed: 30-Mar-2014 14:46 Page 2 of 21 208 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Rel. Int. 100% Abs. Int. 4.39e5 PCB-4 1.26e6 14.44 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.04e3 2.20e5 PCB-10 7.57e4 SI 14.61 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 8.33e5 14.44 Rel. Int. 100% DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.29e4 0.00e0 16.0 RT Abs. Int. 3.11e5 1.56e5 PFK INTERFERENCE 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.74e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.85e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.82e3 2.93e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.10e7 14.42 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.76e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 2.95e3 1.88e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.44e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 7.20e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2970, 4500 scc: 431-600 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 10:20 (LKB) Printed: 30-Mar-2014 14:46 Page 3 of 21 209 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 PCB-6 1.70e6 16.81 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 7.60e3 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Abs. Int. 5.34e5 PCB-8 1.37e6 17.23 PCB-11 1.06e6 19.57 PCB-9 1.21e5 SI 16.42 PCB-15 9.76e5 20.15 13/12 6.30e5 19.84 2.67e5 0% 17.0 PCB-6 1.08e6 16.81 Rel. Int. 100% 18.0 19.0 21.0 PCB-11 7.14e5 19.57 PFK INTERFERENCE PCB-15 5.93e5 20.14 13/12 4.11e5 19.84 2.06e5 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 6.89e7 16.40 20.0 21.0 0.00e0 RT Abs. Int. 2.09e7 ES-15 5.49e7 20.13 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.75e4 1.05e7 0% 17.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.12e5 PCB-8 8.46e5 17.23 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 3.10e4 20.0 18.0 19.0 JS-9 4.45e7 16.40 20.0 21.0 Abs. Int. 1.36e7 ES-15 3.51e7 20.13 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 7.77e3 0.00e0 RT 6.78e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.24e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.62e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4843, 5008 scc: 431-600 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:21 Printed: 30-Mar-2014 14:46 Page 4 of 21 210 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Rel. Int. 100% Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Abs. Int. 1.36e6 30/18 4.90e6 19.29 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.46e3 PCB-17 1.97e6 19.68 PCB-19 7.80e5 17.52 PCB-32 3.02e6 20.58 PCB-27 4.89e5 19.87 6.80e5 PCB-16 9.86e5 20.11 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 1.32e6 30/18 4.69e6 19.29 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 3.32e3 PCB-17 1.85e6 19.68 PCB-19 7.38e5 17.52 PCB-32 2.93e6 20.58 PCB-27 4.40e5 19.87 6.61e5 PCB-16 9.38e5 20.10 0% 17.0 Rel. Int. 100% 18.0 19.0 0.00e0 RT 20.0 21.0 0.00e0 RT Abs. Int. 5.70e6 ES-19 1.72e7 17.50 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 6.00e4 2.85e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.62e7 17.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 4.65e4 2.37e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.24e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.62e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1878, 2037 scc: 431-600 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:32 (LKB) Printed: 30-Mar-2014 14:46 Page 5 of 21 211 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 PCB-31 28/20 8.28e6 9.03e6 22.65 22.92 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 4.52e3 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 26/29 2.47e6 22.14 PCB-25 2.77e6 22.36 Abs. Int. 2.23e6 21/33 1.41e6 23.13 1.11e6 PCB-22 2.10e6 23.49 PCB-37 1.02e6 26.48 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 28/20 8.31e6 8.96e6 22.92 22.64 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 4.20e3 24.0 26/29 2.49e6 22.14 PCB-25 2.74e6 22.36 Abs. Int. 2.24e6 21/33 1.46e6 23.13 1.12e6 PCB-22 2.07e6 23.49 PCB-37 9.88e5 26.48 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 5.41e7 22.90 Rel. Int. 100% ES-37 4.27e7 26.45 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 6.07e4 Abs. Int. 1.37e7 6.83e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 4.95e7 22.90 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.90e7 26.45 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 5.31e4 Abs. Int. 1.27e7 6.36e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.73e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.37e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3218, 8192 scc: 431-600 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 17:09 (LKB) Printed: 30-Mar-2014 14:46 Page 6 of 21 212 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 PCB-54 3.65e4 20.43 Rel. Int. 100% Abs. Int. 1.18e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.03e3 5.89e3 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 4.56e4 20.44 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.48e3 6.36e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.81e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.32e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 8.13e3 2.66e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.33e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.43e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 6.07e3 3.22e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.24e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.62e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2958, 4758 scc: 431-600 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 28-Mar-2014 16:54 Printed: 30-Mar-2014 14:46 Page 7 of 21 213 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Rel. Int. 100% PCB-52 9.02e6 24.54 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.56e3 50/53 1.61e6 22.39 PCB-51 8.21e5 23.08 PCB-45 9.33e5 23.01 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Abs. Int. 2.37e6 69/49 6.13e6 24.98 44/47… 8.37e6 25.44 PCB-48 9.75e5 25.24 PCB-46 4.71e5 23.29 71/40 3.55e6 26.33 PCB-64 4.16e6 26.53 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 1.14e7 24.54 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.32e3 50/53 1.97e6 22.39 PCB-45 1.18e6 23.00 23.0 Abs. Int. 3.04e6 69/49 7.89e6 24.98 44/47… 1.06e7 25.44 PCB-48 1.34e6 25.24 PCB-51 1.06e6 23.08 24.0 PCB-42 2.34e6 25.90 25.0 26.0 JS-52 2.87e7 24.52 Rel. Int. 100% 0.00e0 RT 26.0 0% 22.0 1.19e6 59/62… 7.47e5 25.73 71/40 4.46e6 26.33 PCB-64 5.33e6 26.53 1.52e6 0.00e0 RT Abs. Int. 7.60e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.92e4 3.80e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.58e7 24.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.43e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.10e4 4.71e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.73e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.37e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7620, 1969 scc: 431-600 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:32 (LKB) Printed: 30-Mar-2014 14:46 Page 8 of 21 214 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Abs. Int. 1.87e6 PCB-56 3.18e6 29.61 PCB-68 6.07e5 27.50 0% PCB-63 3.74e5 28.46 28.0 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 3.05e3 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 61/70... 1.12e7 28.76 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.94e3 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 9.37e5 PCB-60 1.41e6 29.81 30.0 PCB-77 6.16e5 32.80 32.0 34.0 36.0 38.0 Abs. Int. 2.43e6 61/70... PCB-66 1.44e7 8.93e6 28.76 29.03 PCB-56 4.08e6 29.61 PCB-68 7.77e5 27.50 1.22e6 PCB-60 1.70e6 29.81 PCB-77 7.55e5 32.80 0% 28.0 0.00e0 RT 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.77e7 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.73e4 ES-81 3.21e7 32.30 ES-77 3.30e7 32.78 8.87e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.68e7 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.51e4 ES-81 3.94e7 32.30 ES-77 4.06e7 32.78 8.40e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.33e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.67e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9157, 4169 scc: 431-600 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:54 (LKB) Printed: 30-Mar-2014 14:46 Page 9 of 21 215 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 PCB-96 7.33e4 25.72 Rel. Int. 100% Abs. Int. 1.88e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 8.68e2 9.42e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 9.47e4 25.73 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.26e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 8.10e2 1.13e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.76e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.62e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.58e3 3.81e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.71e7 25.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.49e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.74e3 2.25e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.73e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.37e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5746, 9445 scc: 431-600 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:54 (LKB) Printed: 30-Mar-2014 14:46 Page 10 of 21 216 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.47e3 113/90… 2.75e6 30.53 PCB-95 2.05e6 27.99 PCB-91 5.91e5 28.75 PCB-84 8.25e5 28.94 PCB-110 3.85e6 32.22 Abs. Int. 9.05e5 PCB-118 2.67e6 34.78 PCB-99 1.60e6108/119... 31.03 2.27e6 116/85 31.51 6.91e5 PCB-83 32.09 1.60e5 30.93 PCB-92 4.64e5 30.02 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 PCB-82 3.98e5 32.51 PCB-109 2.31e5 34.39 PCB-105 1.30e6 35.78 4.53e5 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.59e3 32.0 113/90… 4.37e6 30.53 PCB-95 3.33e6 27.99 PCB-91 9.67e5 28.75 PCB-84 1.34e6 28.94 0% 28.0 30.0 Rel. Int. 100% 36.0 38.0 PCB-110 6.11e6 32.22 PCB-99 2.58e6108/119... 31.03 3.61e6 116/85 31.51 1.09e6 PCB-83 32.09 2.60e5 30.94 PCB-92 7.66e5 30.02 34.0 Abs. Int. 1.43e6 PCB-118 4.41e6 34.78 PCB-82 5.96e5 32.50 32.0 PCB-105 2.17e6 35.78 PCB-109 3.82e5 34.39 34.0 CS/SS-111 4.41e7 32.80 JS-101 3.68e7 30.50 0.00e0 RT ES-123 3.60e7 34.47 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.95e3 36.0 ES-118 ES-114 3.69e7 3.79e7 34.76 35.22 7.16e5 38.0 0.00e0 RT Abs. Int. 1.08e7 ES-105 3.74e7 35.76 5.42e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 2.78e7 32.80 JS-101 2.29e7 30.50 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.55e3 36.0 ES-118 ES-114 2.33e7 ES-123 2.33e7 35.22 2.28e7 34.76 34.47 38.0 0.00e0 RT Abs. Int. 6.87e6 ES-105 2.36e7 35.76 3.44e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.33e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.67e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7132, 4438 scc: 431-600 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:20 Printed: 30-Mar-2014 14:46 Page 11 of 21 217 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Rel. Int. 100% Abs. Int. 9.59e5 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: B 4σ 1.66e3 4.80e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 2.22e6 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: B 4σ 2.26e3 1.11e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.91e6 ES-126 3.24e7 38.37 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 6.81e3 3.96e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.53e6 ES-126 2.09e7 38.37 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 6.08e3 2.77e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.22e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.61e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5601, 6272 scc: 431-600 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:56 (LKB) Printed: 30-Mar-2014 14:46 Page 12 of 21 218 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Rel. Int. 100% Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 153/168 1.40e6 36.36 147/149 1.12e6 33.80 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.07e2 PCB-136 2.87e5 30.97 PCB-132 5.03e5 34.88 151/135 4.38e5 33.02 163/138… 1.77e6 37.43 Abs. Int. 4.12e5 PCB-141 PCB-164 PCB-158 2.10e5 2.32e5 1.42e5 37.76 36.53 37.15 PCB-146 2.41e5 35.84 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% 36.0 153/168 1.10e6 36.36 147/149 9.13e5 33.80 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 6.43e2 PCB-136 2.22e5 30.96 38.0 PCB-132 3.99e5 34.88 151/135 3.56e5 33.02 PCB-146 1.86e5 35.84 163/138… 1.39e6 37.43 PCB-141 1.83e5 PCB-137 36.53 6.54e4 37.07 30.0 32.0 34.0 PCB-158 1.90e5 37.76 ES-155 3.36e7 30.34 Rel. Int. 100% 36.0 ES-153 2.43e7 36.34 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.53e3 0.00e0 RT Abs. Int. 3.27e5 0% 28.0 2.06e5 38.0 1.64e5 0.00e0 RT Abs. Int. 8.18e6 JS-138 2.63e7 37.40 4.09e6 0% 28.0 30.0 32.0 34.0 ES-155 2.62e7 30.34 Rel. Int. 100% 36.0 ES-153 1.91e7 36.34 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.48e3 38.0 0.00e0 RT Abs. Int. 6.52e6 JS-138 2.03e7 37.40 3.26e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.33e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.67e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1057, 7707 scc: 431-600 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 10:20 (LKB) Printed: 30-Mar-2014 14:46 Page 13 of 21 219 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 128/166 2.83e5 38.51 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Abs. Int. 6.82e4 156/157 2.13e5 40.93 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 9.24e2 PCB-167 6.46e4 39.95 3.41e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 4.94e4 156/157 1.86e5 40.92 128/166 2.20e5 38.50 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 8.09e2 PCB-167 6.39e4 39.95 2.47e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 3.15e7 39.93 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 8.63e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 5.96e7 40.92 0.00e0 RT Abs. Int. 1.06e7 ES-169 2.69e7 43.63 5.32e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.41e7 39.94 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 5.26e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.64e7 40.92 0.00e0 RT Abs. Int. 8.23e6 ES-169 2.12e7 43.63 4.11e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.22e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.61e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8141, 7039 scc: 431-600 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 17:10 (LKB) Printed: 30-Mar-2014 14:46 Page 14 of 21 220 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Rel. Int. 100% Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Abs. Int. 2.55e4 PCB-179 9.71e4 35.52 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 6.41e2 PCB-184 2.60e4 35.97 PCB-178 3.24e4 37.79 PCB-176 2.59e4 36.27 1.28e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 37.0 38.0 Abs. Int. 2.27e4 PCB-179 1.03e5 35.52 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 5.82e2 PCB-184 2.17e4 35.97 PCB-176 2.77e4 36.27 PCB-178 2.90e4 37.80 1.13e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.23e7 35.21 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 5.58e6 CS/SS-178 1.60e7 37.78 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.12e3 2.79e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.08e7 35.21 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.17e6 CS/SS-178 1.49e7 37.78 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 2.25e3 2.58e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.33e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 2.67e7 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5798, 7960 scc: 431-600 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 10:21 (LKB) Printed: 30-Mar-2014 14:46 Page 15 of 21 221 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 180/193 4.34e5 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 9.76e2 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 PCB-187 2.56e5 38.57 PCB-174 1.90e5 39.29 PCB-183 1.25e5 39.09 PCB-185 1.97e4 39.16 PCB-177 1.03e5 39.66 171/173 5.61e4 40.20 Abs. Int. 9.71e4 PCB-170 1.62e5 43.17 PCB-172 2.46e4 41.54 4.86e4 PCB-190 4.86e4 43.62 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 4.08e5 42.10 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 7.26e2 43.0 PCB-187 2.48e5 38.57 PCB-174 PCB-183 1.67e5 39.29 1.17e5 39.09 PCB-185 1.75e4 39.17 PCB-177 8.67e4 39.66 171/173 5.17e4 40.20 Abs. Int. 9.83e4 PCB-170 1.42e5 43.17 PCB-172 2.37e4 41.54 4.91e4 PCB-190 3.66e4 43.62 0% 39.0 40.0 41.0 42.0 ES-180 2.04e7 42.08 Rel. Int. 100% 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.96e6 ES-170 1.70e7 43.15 HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 3.60e3 2.48e6 0% 39.0 40.0 41.0 42.0 ES-180 1.85e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 2.70e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.43e6 ES-170 1.55e7 43.15 2.22e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.22e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.61e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0783, 2265 scc: 431-600 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 10:21 (LKB) Printed: 30-Mar-2014 14:46 Page 16 of 21 222 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Rel. Int. 100% Abs. Int. 3.62e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 9.98e2 1.81e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 4.16e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 6.72e2 2.08e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 2.35e7 45.76 0.00e0 RT Abs. Int. 5.66e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 3.93e3 2.83e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 2.29e7 45.76 0.00e0 RT Abs. Int. 5.71e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 3.03e3 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.15e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.58e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1003, 1697 scc: 431-600 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 10:21 (LKB) Printed: 30-Mar-2014 14:46 Page 17 of 21 223 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 198/199 6.81e4 43.75 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 8.04e2 PCB-202 2.71e4 39.78 PCB-196 2.95e4 44.30 PCB-200 1.12e4 41.41 PCB-201 1.53e4 40.54 Abs. Int. 1.74e4 PCB-203 3.74e4 44.48 8.69e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 7.33e4 43.75 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.45e2 PCB-202 3.29e4 39.77 PCB-201 1.77e4 40.55 Abs. Int. 1.96e4 PCB-196 2.66e4 44.31 PCB-200 1.13e4 41.41 PCB-203 4.08e4 44.47 9.82e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.95e7 39.75 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 4.89e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.90e3 2.44e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.16e7 39.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.40e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.33e3 2.70e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.22e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.61e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8487, 4061 scc: 431-600 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 10:21 (LKB) Printed: 30-Mar-2014 14:46 Page 18 of 21 224 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 6.02e2 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 PCB-194 4.00e4 47.54 Abs. Int. 9.66e3 PCB-195 1.91e4 45.60 4.83e3 0% 46.0 47.0 49.0 50.0 PCB-194 4.65e4 47.53 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 7.92e2 48.0 0.00e0 RT Abs. Int. 1.11e4 PCB-195 1.40e4 45.59 5.56e3 0% 46.0 47.0 48.0 JS-194 1.60e7 47.52 Rel. Int. 100% 49.0 50.0 ES-205 1.50e7 47.92 0.00e0 RT Abs. Int. 3.82e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.26e3 1.91e6 0% 46.0 47.0 48.0 JS-194 1.72e7 47.52 Rel. Int. 100% 49.0 50.0 ES-205 1.67e7 47.92 0.00e0 RT Abs. Int. 4.10e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.93e3 2.05e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.15e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.58e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7492, 1382 scc: 431-600 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:20 Printed: 30-Mar-2014 14:46 Page 19 of 21 225 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 Rel. Int. 100% Abs. Int. 5.92e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: B 4σ 9.63e2 < S/N 2.96e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 7.64e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: B 4σ 1.78e3 3.82e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 3.73e6 ES-208 1.58e7 45.37 ES-206 9.40e6 49.38 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.29e3 1.86e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 4.83e6 ES-208 2.00e7 45.37 ES-206 1.19e7 49.38 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.70e3 2.42e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.15e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.58e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1313, 0122 scc: 431-600 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:21 Printed: 30-Mar-2014 14:46 Page 20 of 21 226 of 622 SGS-AP ID: A6506_11899_PCB_006 Instr: AutoSpec-Premier MM7 Sample ID: PB089-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 54 Acq: 27-Mar-2014 18:54:13 User: LKB Datafile: 140327X10 PCB-209 8.36e4 50.84 Rel. Int. 100% Abs. Int. 1.92e4 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 6.35e2 9.62e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 7.44e4 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.16e4 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 5.12e2 1.08e4 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.39e7 50.81 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.98e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 8.82e2 1.49e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.17e7 50.81 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.55e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.17e2 1.27e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.72e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 2.36e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_006.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5147, 5155 scc: 431-600 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 28-Mar-2014 16:51 (LKB) Printed: 30-Mar-2014 14:46 Page 21 of 21 227 of 622 Lab ID: A6506_11899_PCB_007 ACQ: 27-Mar-2014 19:49:23 LKB Wt/Vol: 0.97 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Client ID: PB085-1SWMID-140314-N (TOTAL) UTP: 30-Mar-2014 14:27 LKB J-level: 10.4 pg/L Datafile: 140327X11 RPT: 30-Mar-2014 14:31 LB Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services Actual RT 32.79 NotFnd 35.77 35.23 34.76 34.48 NotFnd 40.92 39.95 NotFnd NotFnd 50.82 11.87 14.16 14.41 20.12 17.49 26.44 20.40 32.77 32.29 25.37 35.75 35.21 34.74 34.46 38.36 36.33 30.32 40.91 39.92 43.62 43.14 42.07 35.20 45.74 39.74 47.91 49.37 45.36 50.80 QC J EMPC J J C J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0006 1.0006 1.0006 1.0006 1.0002 1.0006 1.0004 0 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7245 0.8640 0.8793 1.2277 1.0673 1.0790 0.8325 1.3372 1.3177 0.8322 1.1724 1.1546 1.1394 1.1302 1.2580 0.9716 0.8111 1.0941 1.0678 1.1667 0.9080 0.8855 0.7410 0.9629 0.8364 1.0084 1.0392 0.9548 1.0693 Split: 1 Checkcode: 507-769-DWM Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.79 0 7.73E+05 0.00E+00 1.93E+06 1.25E+05 3.84E+06 1.14E+05 0.00E+00 2.02E+05 7.51E+04 0.00E+00 0.00E+00 1.86E+05 1.21 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 19.1 ND 60.1 3.67 116 3.38 ND 7.42 2.49 ND ND 12 4.67E+03 4.67E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 3.02E+03 1.60E+03 1.60E+03 1.60E+03 1.67E+03 1.39E+03 1.19 1.26 0.749 0.73 0.728 0.715 1.14 0.831 0.547 0.643 0.723 1.04 0 0 -0.2 +0.7 0 +0.5 -0.4 +1.6 +1.4 -0.5 +0.9 +0.6 +0.6 +0.6 +1.2 0 -0.5 +0.5 +0.2 +0.8 -0.3 -0.3 -0.6 0 -0.5 0 0 -0.3 -0.3 4.00E+07 5.00E+07 2.63E+07 8.27E+07 2.95E+07 7.94E+07 3.46E+07 7.30E+07 6.97E+07 3.96E+07 5.99E+07 5.86E+07 5.77E+07 5.74E+07 5.15E+07 4.10E+07 5.49E+07 1.03E+08 5.37E+07 4.79E+07 3.18E+07 3.79E+07 3.97E+07 4.67E+07 3.90E+07 3.33E+07 2.29E+07 3.56E+07 2.89E+07 3.24 3.34 1.61 1.57 1.07 1.09 0.78 0.81 0.80 1.65 1.62 1.60 1.62 1.58 1.60 1.28 1.26 1.30 1.28 1.28 1.06 1.07 1.08 1.02 0.90 0.87 0.80 0.79 1.18 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 29.8 % 40.9 % 44.8 % 70.6 % 51.8 % 72.7 % 61.1 % 80.3 % 77.5 % 81.2 % 82.1 % 79.2 % 82 % 79.7 % 82.6 % 78.4 % 74.4 % 69.2 % 69.4 % 66.3 % 79.9 % 79 % 91.1 % 86.1 % 86.6 % 78 % 80.4 % 88.2 % 75.8 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 0 -0.2 0 0 -0.7 0 Page 1 of 5 0.60 0.79 0.62 0.53 1.27 1.37 Printed: 3/30/2014 2:32 PM 228 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.89 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0751 1.0101 0 +0.2 +0.2 1.09E+08 7.51E+07 3.24E+07 1.07 1.59 1.07 1.11 1.03 0.62 124 % 127 % 132 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.89 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0751 1.0101 0 +0.2 +0.2 1.09E+08 7.51E+07 3.24E+07 1.07 1.59 1.07 1.85 1.22 0.58 90.1 % 101 % 120 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.39 24.51 30.49 37.39 47.51 1.13E+08 6.58E+07 6.07E+07 4.64E+07 3.43E+07 1.57 0.81 1.58 1.30 0.90 5.70E+03 5.70E+03 5.70E+03 8.63E+03 8.63E+03 1.55E+04 1.55E+04 1.55E+04 1.55E+04 1.55E+04 1.55E+04 1.55E+04 1.55E+04 1.55E+04 5.76E+03 5.76E+03 5.76E+03 5.76E+03 5.76E+03 5.76E+03 5.76E+03 1.92 1.48 1.75 3.98 2.58 3.46 3.07 3.29 3.26 3.18 2.75 3.18 3.19 3.43 2.91 2.17 2.52 1.85 1.95 3.3 1.75 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services 11.89 NotFnd 14.16 14.43 14.61 16.40 NotFnd 16.80 NotFnd 17.22 NotFnd 19.56 19.82 20.13 17.51 19.28 19.67 19.86 19.99 20.09 20.57 EMPC J EMPC J J B J C C J 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0011 0.9996 1.0012 1.0136 1.0010 1.0250 1.0507 0.9721 0.9853 1.0007 1.0010 1.1020 1.1245 1.1356 1.1428 1.1487 1.1762 0 -1.2 +0.1 +0.1 0 +0.1 +0.1 0 -1.5 -0.1 0 +0.7 +0.2 +0.4 -0.2 +0.4 +0.5 Page 2 of 5 NON-EMPC 0 353 1,890 2,830 1,130 313 75.4 14 0 4.28E+05 0.00E+00 1.30E+05 2.27E+06 1.18E+05 2.05E+05 0.00E+00 2.42E+06 0.00E+00 2.50E+06 0.00E+00 1.35E+06 8.29E+05 1.40E+06 1.49E+06 9.13E+06 3.32E+06 8.71E+05 8.62E+04 1.98E+06 5.04E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 28.6 353 1,890 2,840 1,130 313 86.9 19.7 0 3.68 9.87 1.56 SI SI 1.65 1.60 1.66 1.63 1.67 1.05 1.05 1.09 1.05 1.07 1.11 1.03 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 1.84 3.71 2.5 1.05 0.77 0.611 0.788 0.798 1.98 23.3 ND 5.34 145 4.88 5.08 ND 57 ND 57.1 ND 30.7 18.9 34.5 91.2 418 176 34 3.55 138 186 Printed: 3/30/2014 2:32 PM 229 of 622 Name PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB SGS Evironmental Services Actual RT 21.72 NotFnd 22.13 22.35 22.63 22.91 23.12 23.47 NotFnd NotFnd NotFnd 26.10 26.47 20.42 22.38 22.99 23.06 23.28 24.53 24.66 24.75 24.97 25.23 25.43 25.71 25.89 26.22 26.32 26.52 27.24 27.49 27.86 NotFnd 28.22 28.45 28.75 29.02 29.16 29.60 29.80 NotFnd 31.46 NotFnd NotFnd 25.72 27.40 27.59 27.98 QC J C C C J J EMPC C J C C J C C J J J J C J J J J EMPC J EMPC Pred RRT Actual RRT Diff Secs 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8215 0.8370 0.8454 0.8560 0.8663 0.8744 0.8877 0.9870 1.0009 1.0010 0.9134 0.9383 0.9411 0.9499 1.0009 1.0064 1.0101 1.0189 1.0296 1.0375 1.0493 1.0564 1.0699 1.0739 1.0820 0.8434 0.8513 0.8628 0.8739 0.8810 0.8903 0.8986 0.9031 0.9167 0.9227 0.9741 1.0134 0.8987 0.9048 0.9175 -0.4 -1.7 -0.3 -0.3 -1.0 +0.8 -0.4 -0.2 +0.3 0 -1.5 0 -0.3 0 0 +0.3 0 +1.2 +0.2 -1.4 -0.5 +0.2 +0.2 +0.3 +0.2 -0.3 -0.3 -0.3 -0.3 -0.2 +0.2 -0.5 -0.5 -0.4 -0.4 +0.8 0 -0.3 -0.5 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 1.04E+05 0.00E+00 3.37E+06 3.54E+06 1.30E+07 1.36E+07 2.61E+06 3.39E+06 0.00E+00 0.00E+00 0.00E+00 1.76E+05 1.51E+06 5.24E+04 2.70E+06 1.75E+06 1.70E+06 8.62E+05 1.42E+07 5.35E+04 3.62E+05 9.35E+06 1.79E+06 1.36E+07 1.25E+06 2.93E+06 5.39E+05 5.58E+06 6.67E+06 8.07E+04 1.23E+06 5.11E+04 0.00E+00 2.31E+05 4.71E+05 1.65E+07 9.92E+06 1.17E+05 4.76E+06 2.02E+06 0.00E+00 6.75E+04 0.00E+00 0.00E+00 9.86E+04 3.76E+04 4.01E+04 3.24E+06 1.00 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 2.13 ND 68.3 71.8 253 283 52.9 73.6 ND ND ND 3.97 36.5 2.32 87 65.1 54.5 35 473 1.35 14 253 58.7 418 29.7 105 22 179 151 1.86 26.7 1.24 ND 5.26 10.3 394 253 2.97 122 51 ND 1.46 ND ND 4.31 1.43 1.82 135 1.00 1.02 0.99 1.01 1.01 0.98 1.03 1.00 0.52 0.79 0.79 0.80 0.84 0.79 0.79 0.83 0.80 0.76 0.80 0.81 0.76 0.78 0.79 0.79 0.83 0.79 0.88 0.75 0.81 0.77 0.77 0.79 0.78 0.82 0.67 0.59 0.78 0.73 0.63 Noise / Recv. Low DL / Recv. High 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 1.97E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 2.98E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 4.67E+03 1.64E+03 1.64E+03 2.35E+03 2.35E+03 2.35E+03 1.77 1.76 1.75 1.75 1.68 1.8 1.75 1.87 1.71 1.66 1.85 1.95 2.09 0.807 0.971 1.12 0.97 1.23 1 0.761 1.16 0.817 0.99 0.93 0.719 1.08 1.23 0.965 0.681 1.09 1.03 1.15 1.12 1.08 1.04 1.13 1.21 1.2 1.21 1.2 1.03 1.02 1.27 0.564 0.676 0.915 1.09 1 Printed: 3/30/2014 2:32 PM 230 of 622 Name PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB SGS Evironmental Services Actual RT 28.19 28.30 NotFnd NotFnd 28.73 28.93 29.35 NotFnd 30.01 30.52 30.92 31.02 NotFnd 31.50 31.99 32.08 32.21 32.32 32.49 NotFnd NotFnd 34.17 34.38 NotFnd 35.06 NotFnd NotFnd NotFnd NotFnd 30.96 NotFnd NotFnd 33.01 NotFnd 33.49 33.79 33.97 NotFnd 34.30 34.48 NotFnd 34.86 NotFnd NotFnd 35.82 NotFnd 36.35 36.52 QC J C J J C C J C J J C J J J C J C J J C J J C Pred RRT Actual RRT Diff Secs 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9245 0.9281 0.9423 0.9486 0.9624 0.9842 1.0007 1.0141 1.0174 1.0329 1.0491 1.0520 1.0564 1.0600 1.0656 0.9916 0.9976 1.0092 1.0208 1.0886 1.1044 1.1142 1.1201 1.1312 1.1370 1.1497 0.9581 0.9722 0.9767 -0.2 -0.2 -0.2 -0.2 0 +0.2 +1.5 -0.2 +0.2 +1.7 -0.8 -1.0 +0.6 +1.9 +0.2 0 0 +0.2 +0.2 0 +0.6 +0.2 +0.4 0 +0.2 +0.6 -0.2 -1.3 +0.2 Page 4 of 5 Response Ra RRF Conc. / Recv. 6.93E+04 2.72E+05 0.00E+00 0.00E+00 8.65E+05 1.29E+06 1.18E+05 0.00E+00 7.16E+05 4.05E+06 2.29E+05 2.37E+06 0.00E+00 3.37E+06 1.06E+05 1.13E+06 5.76E+06 7.65E+04 5.99E+05 0.00E+00 0.00E+00 1.79E+05 3.51E+05 0.00E+00 8.47E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.72E+05 0.00E+00 0.00E+00 4.43E+05 0.00E+00 6.77E+04 1.12E+06 8.93E+04 0.00E+00 4.17E+04 2.48E+04 0.00E+00 5.06E+05 0.00E+00 0.00E+00 2.23E+05 0.00E+00 1.39E+06 2.43E+05 0.58 0.58 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 2.86 9.42 ND ND 34.1 64.3 5.57 ND 31.3 149 11.6 94.1 ND 122 3.64 41.4 186 2.41 31.2 ND ND 5.89 10.2 ND 2.98 ND ND ND ND 10 ND ND 21 ND 3.1 51.3 5.73 ND 1.9 1.33 ND 26.4 ND ND 9.9 ND 50.4 11.9 0.61 0.62 0.62 0.61 0.61 0.59 0.61 0.58 0.57 0.60 0.60 0.58 0.61 0.68 0.66 0.62 1.19 1.24 1.42 1.27 1.21 1.07 1.09 1.37 1.16 1.31 1.16 Noise / Recv. Low DL / Recv. High 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 2.35E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 0.99 0.831 1.19 1.09 0.947 1.2 1.13 0.711 1.05 0.882 1.21 0.954 0.74 0.87 0.825 0.88 0.777 0.756 1.25 0.719 0.708 0.791 0.698 0.804 0.875 0.767 0.421 0.48 0.474 0.517 0.506 0.652 0.689 0.588 0.665 0.663 0.932 0.664 0.66 0.78 0.792 0.756 0.702 0.56 0.644 0.517 0.528 0.709 Printed: 3/30/2014 2:32 PM 231 of 622 Name PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB SGS Evironmental Services Actual RT 36.86 37.06 37.14 37.41 NotFnd 37.75 38.49 NotFnd NotFnd NotFnd 35.51 NotFnd 36.26 NotFnd 37.77 NotFnd 38.56 NotFnd 39.09 NotFnd 39.28 39.65 NotFnd 40.19 41.53 NotFnd 42.09 NotFnd 43.15 43.60 39.76 NotFnd NotFnd NotFnd NotFnd 43.74 44.30 44.47 45.58 47.52 NotFnd NotFnd NotFnd NotFnd QC J J J C J J C J J EMPC J J EMPC J J EMPC C J C J J J C J EMPC J EMPC J J Pred RRT Actual RRT Diff Secs 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9859 0.9913 0.9933 1.0007 1.0096 0.9642 1.0087 1.0301 1.0729 1.0953 1.1105 1.1158 1.1263 1.1418 0.9079 0.9200 0.9434 0.9532 1.0006 1.1007 1.1148 1.1191 0.9514 0.9920 - 0 +0.4 0 -0.9 0 +0.2 +0.2 +0.2 -0.9 +0.2 +0.9 +0.5 +0.2 +1.2 -0.2 +1.5 0 -0.3 +0.2 +1.6 +0.5 +0.8 -0.5 -0.3 Page 5 of 5 Response Ra RRF Conc. / Recv. 9.36E+04 7.86E+04 1.22E+05 1.71E+06 0.00E+00 2.32E+05 2.74E+05 0.00E+00 0.00E+00 0.00E+00 1.08E+05 0.00E+00 3.58E+04 0.00E+00 3.60E+04 0.00E+00 2.81E+05 0.00E+00 1.33E+05 0.00E+00 1.94E+05 9.82E+04 0.00E+00 6.65E+04 3.37E+04 0.00E+00 4.97E+05 0.00E+00 2.09E+05 4.98E+04 3.32E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 8.84E+04 3.58E+04 4.57E+04 2.23E+04 5.56E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.20 1.11 1.21 1.28 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 5.15 3.5 4.48 77.6 ND 7.84 11.8 ND ND ND 5.21 ND 1.64 ND 2.48 ND 13.4 ND 5.97 ND 10.8 5.68 ND 3.85 1.9 ND 21.9 ND 12 2.09 1.68 ND ND ND ND 6.53 2.49 3.15 1.74 4.06 ND ND ND ND 1.24 1.40 1.00 1.23 0.91 1.13 1.28 1.06 1.08 1.22 0.94 1.00 0.93 0.92 0.99 0.96 0.60 1.10 0.82 1.00 Noise / Recv. Low DL / Recv. High 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.60E+03 1.60E+03 1.60E+03 1.28E+03 1.28E+03 1.28E+03 1.28E+03 1.28E+03 1.28E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.36E+03 1.36E+03 1.36E+03 2.82E+03 2.82E+03 2.82E+03 0.798 0.646 0.531 0.66 0.563 0.49 0.712 0.593 0.598 0.516 0.606 0.638 0.574 0.613 0.863 0.906 0.851 0.822 0.802 0.948 0.997 1.03 0.915 1.03 1.01 0.776 0.789 0.725 1.05 0.765 0.768 0.712 0.766 0.715 0.753 1.12 1.06 1.05 1.1 1.03 0.828 1.53 1.52 2.43 Printed: 3/30/2014 2:32 PM 232 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 1.26e8 6.32e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 2.99e7 1.50e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 2.66e7 1.33e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 5.05e7 2.53e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 2.79e7 1.39e7 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 4.38e6 2.19e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 4.09e6 2.04e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 507-769 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:46 Page 1 of 21 233 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 PCB-1 3.81e5 11.89 Rel. Int. 100% Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Abs. Int. 1.60e5 PCB-3 3.11e5 14.16 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.68e3 8.01e4 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 1.04e5 11.88 Rel. Int. 100% Abs. Int. 4.72e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.02e3 PCB-3 3.15e4 14.17 2.36e4 0% 11.0 12.0 13.0 14.0 15.0 ES-3 3.85e7 14.16 ES-1 3.06e7 11.87 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 1.28e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.63e3 6.42e6 0% 11.0 12.0 13.0 15.0 ES-3 1.15e7 14.16 ES-1 9.44e6 11.87 Rel. Int. 100% 14.0 0.00e0 16.0 RT Abs. Int. 4.08e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.94e4 2.04e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.26e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 6.32e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8939, 3146 scc: 507-769 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:30 (LKB) Printed: 30-Mar-2014 14:46 Page 2 of 21 234 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Rel. Int. 100% Abs. Int. 4.82e5 PCB-4 1.38e6 14.43 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.26e3 2.41e5 PCB-10 7.20e4 SI 14.61 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 8.88e5 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.32e5 PFK INTERFERENCE DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.97e4 1.66e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.63e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.63e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 6.90e3 2.82e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.01e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.49e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.09e3 1.75e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.26e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 6.32e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4142, 4077 scc: 507-769 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:20 (LKB) Printed: 30-Mar-2014 14:46 Page 3 of 21 235 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 PCB-8 1.54e6 17.22 PCB-6 1.51e6 16.80 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 9.45e3 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Abs. Int. 5.25e5 PCB-11 8.41e5 19.56 PCB-9 1.25e5 SI 16.40 PCB-15 8.77e5 20.13 13/12 5.14e5 19.82 2.63e5 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 2.68e4 18.0 19.0 20.0 21.0 PCB-8 9.63e5 17.22 PCB-6 9.12e5 16.80 Abs. Int. 3.87e5 PCB-11 5.06e5 19.56 PFK INTERFERENCE PCB-15 5.26e5 20.14 13/12 3.15e5 19.82 1.94e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 JS-9 6.87e7 16.39 0.00e0 RT Abs. Int. 2.17e7 ES-15 5.05e7 20.12 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.77e4 1.08e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 21.0 JS-9 4.38e7 16.39 Abs. Int. 1.37e7 ES-15 3.21e7 20.12 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 6.88e3 0.00e0 RT 6.87e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.99e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.50e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8580, 1307 scc: 507-769 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 4 of 21 236 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Rel. Int. 100% Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Abs. Int. 1.37e6 30/18 4.67e6 19.28 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.03e3 PCB-17 1.73e6 19.67 PCB-19 7.62e5 17.51 PCB-27 4.47e5 19.86 PCB-16 1.04e6 20.09 PCB-32 2.55e6 20.57 6.85e5 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 1.29e6 30/18 4.46e6 19.28 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.73e3 PCB-17 1.59e6 19.67 PCB-19 7.28e5 17.51 PCB-27 4.24e5 19.86 PCB-16 9.40e5 20.09 PCB-32 2.49e6 20.57 6.46e5 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.52e7 17.49 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 4.84e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 6.92e4 2.42e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.43e7 17.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.29e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 4.80e4 2.14e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.99e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.50e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2734, 2177 scc: 507-769 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 5 of 21 237 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 PCB-31 28/20 6.48e6 6.82e6 22.63 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 4.93e3 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 26/29 1.69e6 22.13 PCB-25 1.79e6 22.35 Abs. Int. 1.78e6 21/33 1.31e6 23.12 8.89e5 PCB-22 1.67e6 23.47 PCB-37 7.54e5 26.47 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 28/20 6.54e6 6.77e6 22.91 22.63 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 3.80e3 24.0 26/29 1.69e6 22.13 PCB-25 1.75e6 22.35 Abs. Int. 1.77e6 21/33 1.30e6 23.12 8.85e5 PCB-22 1.72e6 23.47 PCB-37 7.52e5 26.47 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 5.66e7 22.89 Rel. Int. 100% ES-37 4.14e7 26.44 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 7.43e4 Abs. Int. 1.47e7 7.37e6 0% 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 CS/SS-28 5.28e7 22.89 Rel. Int. 100% ES-37 3.80e7 26.44 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 4.59e4 Abs. Int. 1.44e7 7.20e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.33e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5766, 4083 scc: 507-769 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 6 of 21 238 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 PCB-54 2.29e4 20.42 Rel. Int. 100% Abs. Int. 6.45e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 8.15e2 3.23e3 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 4.44e4 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.16e3 6.21e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.52e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 7.62e3 2.05e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.94e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 4.82e3 2.68e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.99e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.50e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9501, 1512 scc: 507-769 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:22 (LKB) Printed: 30-Mar-2014 14:46 Page 7 of 21 239 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Rel. Int. 100% PCB-52 6.27e6 24.53 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.41e3 PCB-51 7.53e5 23.06 50/53 1.20e6 22.38 PCB-45 7.72e5 22.99 69/49 4.15e6 24.97 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 PCB-48 7.72e5 25.23 PCB-46 3.94e5 23.28 Abs. Int. 1.65e6 44/47… 6.01e6 25.43 PCB-42 1.27e6 25.89 71/40 2.46e6 26.32 PCB-64 2.95e6 26.52 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 7.96e6 24.53 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.57e3 50/53 1.51e6 22.38 69/49 5.20e6 24.97 PCB-51 9.43e5 23.07 PCB-45 9.79e5 22.99 Abs. Int. 2.16e6 44/47… 7.56e6 25.42 PCB-42 1.66e6 25.89 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.94e7 24.51 Rel. Int. 100% 0.00e0 RT 26.0 PCB-48 1.02e6 25.23 PCB-46 4.68e5 23.28 8.23e5 71/40 3.12e6 26.32 PCB-64 3.72e6 26.52 1.08e6 0.00e0 RT Abs. Int. 7.84e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.38e4 3.92e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.63e7 24.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.87e6 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.27e4 4.93e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.33e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9494, 2979 scc: 507-769 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 8 of 21 240 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.65e3 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Abs. Int. 1.38e6 61/70... PCB-66 7.17e6 4.31e6 28.75 29.02 PCB-56 2.08e6 29.60 PCB-60 9.05e5 29.80 PCB-68 5.44e5 27.49 6.89e5 PCB-77 3.41e5 32.79 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 3.02e3 30.0 32.0 34.0 36.0 38.0 Abs. Int. 1.74e6 61/70... PCB-66 9.30e6 5.61e6 28.75 29.02 PCB-56 2.68e6 29.60 PCB-68 6.85e5 27.49 8.69e5 PCB-60 1.11e6 29.80 PCB-77 4.32e5 32.79 0% 28.0 0.00e0 RT 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e7 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.73e4 ES-81 3.09e7 32.29 ES-77 3.27e7 32.77 7.18e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 ES-81 3.88e7 32.29 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.34e4 ES-77 4.03e7 32.77 6.74e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.05e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.53e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8902, 4420 scc: 507-769 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 9 of 21 241 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 PCB-96 3.65e4 25.72 Rel. Int. 100% PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 7.53e2 Abs. Int. 1.06e4 5.29e3 PR 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 6.21e4 25.71 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 8.85e2 9.41e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.46e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.54e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.75e3 3.27e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.50e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.12e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.96e3 2.06e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.33e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9835, 1028 scc: 507-769 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:30 (LKB) Printed: 30-Mar-2014 14:46 Page 10 of 21 242 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.09e3 113/90… 1.53e6 30.52 PCB-95 1.26e6 27.98 PCB-91 3.28e5 28.73 PCB-84 4.93e5 28.93 PCB-92 2.70e5 30.01 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 PCB-110 2.15e6 32.21 Abs. Int. 5.38e5 PCB-118 1.47e6 34.76 PCB-99 8.97e5108/119... 31.02 1.23e6 116/85 31.50 4.22e5 PCB-83 32.08 8.53e4 30.92 PCB-82 2.28e5 32.49 PCB-109 1.39e5 34.38 PCB-105 7.26e5 35.77 2.69e5 0% 28.0 30.0 34.0 36.0 38.0 PCB-110 3.60e6 32.21 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.26e3 32.0 PCB-91 5.37e5 28.73 PCB-84 7.97e5 28.93 PCB-92 4.45e5 30.01 0% 28.0 Abs. Int. 9.18e5 113/90… 2.52e6 30.51 PCB-95 1.99e6 27.98 PCB-99 1.47e6108/119... 31.02 2.14e6 116/85 31.50 7.06e5 PCB-83 32.08 1.43e5 30.92 30.0 Rel. Int. 100% PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 4.00e3 PCB-118 2.37e6 34.76 PCB-82 3.71e5 32.49 32.0 PCB-109 2.12e5 34.38 34.0 CS/SS-111 4.61e7 32.78 JS-101 3.72e7 30.49 0.00e0 RT ES-123 3.52e7 34.46 PCB-105 1.21e6 35.77 36.0 ES-114 3.60e7 35.21 4.59e5 38.0 0.00e0 RT Abs. Int. 1.12e7 ES-105 3.71e7 35.75 5.62e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 2.90e7 32.78 JS-101 2.35e7 30.49 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.46e3 34.0 ES-118 ES-123 2.21e7 2.22e7 34.74 34.46 36.0 38.0 0.00e0 RT Abs. Int. 7.14e6 ES-105 2.29e7 35.75 3.57e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.05e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.53e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2985, 1964 scc: 507-769 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:31 (LKB) Printed: 30-Mar-2014 14:46 Page 11 of 21 243 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Rel. Int. 100% Abs. Int. 5.16e5 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 1.59e3 2.58e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 1.16e6 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.43e3 5.79e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.66e6 ES-126 3.17e7 38.36 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 6.47e3 3.83e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.76e6 ES-126 1.98e7 38.36 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 6.24e3 2.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.39e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0343, 8362 scc: 507-769 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 12 of 21 244 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Rel. Int. 100% 153/168 7.84e5 36.35 147/149 6.27e5 33.79 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.94e2 PCB-136 1.48e5 30.96 151/135 2.45e5 33.01 PCB-134 4.89e4 33.97 PCB-132 2.93e5 34.86 163/138… 9.58e5 37.41 Abs. Int. 2.23e5 PCB-141 PCB-158 1.31e5 PCB-164 1.28e5 6.70e4 36.52 37.75 37.14 PCB-146 1.20e5 35.82 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% 36.0 153/168 6.01e5 36.35 147/149 4.95e5 33.79 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 7.35e2 PCB-136 1.24e5 30.95 PCB-132 2.13e5 34.86 151/135 1.98e5 33.01 38.0 163/138… 7.48e5 37.41 0% 28.0 30.0 32.0 34.0 ES-155 3.06e7 30.32 Rel. Int. 100% 36.0 ES-153 2.30e7 36.33 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.49e3 0.00e0 RT Abs. Int. 1.85e5 PCB-141 PCB-158 1.12e5 PCB-164 1.04e5 5.55e4 36.51 37.75 37.14 PCB-146 1.03e5 35.82 1.12e5 38.0 9.26e4 0.00e0 RT Abs. Int. 7.77e6 JS-138 2.62e7 37.39 3.89e6 0% 28.0 30.0 32.0 34.0 ES-155 2.43e7 30.32 Rel. Int. 100% 36.0 ES-153 1.80e7 36.33 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.57e3 38.0 0.00e0 RT Abs. Int. 6.14e6 JS-138 2.02e7 37.39 3.07e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.05e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.53e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0895, 7290 scc: 507-769 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 13 of 21 245 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 128/166 1.59e5 38.49 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Abs. Int. 3.97e4 156/157 1.13e5 40.92 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 8.67e2 PCB-167 4.34e4 39.95 1.99e4 0% 39.0 Rel. Int. 100% 40.0 128/166 1.14e5 38.49 41.0 42.0 43.0 44.0 45.0 Abs. Int. 3.05e4 156/157 8.87e4 40.92 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 7.32e2 PCB-167 3.17e4 39.94 1.53e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 3.02e7 39.92 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 7.26e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 5.80e7 40.91 0.00e0 RT Abs. Int. 1.03e7 ES-169 2.69e7 43.62 5.13e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 2.35e7 39.92 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 8.26e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 4.47e7 40.91 0.00e0 RT Abs. Int. 7.78e6 ES-169 2.10e7 43.62 3.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.39e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7642, 9025 scc: 507-769 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 14 of 21 246 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 PCB-179 5.40e4 35.51 Rel. Int. 100% HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 6.40e2 Abs. Int. 1.42e4 PCB-176 2.16e4 36.26 PCB-178 1.71e4 37.77 7.09e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-179 5.38e4 35.51 Rel. Int. 100% HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.40e2 Abs. Int. 1.25e4 PCB-176 1.76e4 36.26 PCB-178 1.88e4 37.78 6.23e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.06e7 35.20 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 CS/SS-178 1.67e7 37.76 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.13e3 0.00e0 RT 2.63e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.91e7 35.20 Rel. Int. 100% Abs. Int. 4.77e6 CS/SS-178 1.56e7 37.76 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.62e3 0.00e0 RT 2.39e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.01e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 2.51e7 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8472, 6706 scc: 507-769 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 15 of 21 247 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 180/193 2.48e5 42.09 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 9.55e2 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 PCB-187 1.49e5 38.56 PCB-174 PCB-183 9.95e4 8.39e4 39.28 39.09 PCB-177 5.10e4 39.65 171/173 3.99e4 40.19 Abs. Int. 5.98e4 PCB-170 1.01e5 43.15 PCB-172 1.63e4 41.53 2.99e4 PCB-190 2.38e4 43.60 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 2.49e5 42.09 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 8.07e2 43.0 PCB-187 1.32e5 38.56 PCB-183 6.53e4 39.10 PCB-174 9.41e4 39.28 PCB-177 4.72e4 39.65 171/173 3.26e4 40.19 Abs. Int. 5.42e4 PCB-170 1.08e5 43.15 PCB-172 1.73e4 41.54 2.71e4 PCB-190 2.59e4 43.60 0% 39.0 40.0 41.0 42.0 ES-180 1.95e7 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 1.65e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.82e6 ES-170 1.64e7 43.14 2.41e6 0% 39.0 40.0 41.0 42.0 ES-180 1.83e7 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 3.24e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.63e6 ES-170 1.54e7 43.13 2.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.39e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1101, 4346 scc: 507-769 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 14:27 (LKB) Printed: 30-Mar-2014 14:46 Page 16 of 21 248 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Rel. Int. 100% Abs. Int. 2.55e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 7.57e2 1.28e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 2.82e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 9.16e2 1.41e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 2.36e7 45.74 0.00e0 RT Abs. Int. 5.65e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.44e3 2.83e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 2.31e7 45.74 0.00e0 RT Abs. Int. 5.63e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 3.22e3 2.81e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.38e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.19e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2273, 8406 scc: 507-769 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 17 of 21 249 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 198/199 4.32e4 43.74 Rel. Int. 100% OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 8.14e2 PCB-202 1.65e4 39.76 Abs. Int. 1.17e4 PCB-196 1.69e4 44.30 PCB-203 2.65e4 44.47 5.84e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 4.52e4 43.74 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.55e2 Abs. Int. 1.17e4 PCB-196 2.82e4 44.29 PCB-202 1.67e4 39.75 PCB-203 2.42e4 44.46 5.86e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.84e7 39.74 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 4.45e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.88e3 2.23e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.05e7 39.74 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.87e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 2.08e3 2.43e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.39e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1808, 7911 scc: 507-769 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:31 (LKB) Printed: 30-Mar-2014 14:46 Page 18 of 21 250 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 PCB-194 2.78e4 47.52 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 7.49e2 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Abs. Int. 7.64e3 PCB-195 1.00e4 45.58 3.82e3 0% 46.0 47.0 49.0 50.0 PCB-194 2.78e4 47.53 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 6.08e2 48.0 0.00e0 RT Abs. Int. 8.25e3 PCB-195 1.22e4 45.57 4.12e3 0% 46.0 47.0 48.0 JS-194 1.62e7 47.51 Rel. Int. 100% 49.0 50.0 ES-205 1.55e7 47.91 0.00e0 RT Abs. Int. 3.91e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.62e3 1.96e6 0% 46.0 47.0 48.0 JS-194 1.81e7 47.51 Rel. Int. 100% 49.0 50.0 ES-205 1.77e7 47.91 0.00e0 RT Abs. Int. 4.15e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.80e3 2.08e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.38e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.19e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8967, 1815 scc: 507-769 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:30 Printed: 30-Mar-2014 14:46 Page 19 of 21 251 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 Rel. Int. 100% Abs. Int. 4.96e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: B 4σ 1.06e3 2.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 8.45e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: B 4σ 1.76e3 4.22e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 1.57e7 45.36 50.0 0.00e0 RT Abs. Int. 3.76e6 ES-206 1.02e7 49.37 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.20e3 1.88e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 1.98e7 45.36 50.0 Abs. Int. 4.63e6 ES-206 1.27e7 49.37 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.93e3 0.00e0 RT 2.32e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.38e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.19e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1474, 8827 scc: 507-769 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 14:27 (LKB) Printed: 30-Mar-2014 14:46 Page 20 of 21 252 of 622 SGS-AP ID: A6506_11899_PCB_007 Instr: AutoSpec-Premier MM7 Sample ID: PB085-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 55 Acq: 27-Mar-2014 19:49:23 User: LKB Datafile: 140327X11 PCB-209 1.02e5 50.82 Rel. Int. 100% Abs. Int. 2.30e4 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 5.49e2 1.15e4 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 8.45e4 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.20e4 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 8.44e2 1.10e4 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.56e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.36e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.21e3 1.68e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.32e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.85e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.60e2 1.42e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.09e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 2.04e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_007.utp_res, saved 30-Mar-2014 14:28 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6859, 8078 scc: 507-769 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:20 (LKB) Printed: 30-Mar-2014 14:46 Page 21 of 21 253 of 622 Lab ID: A6506_11899_PCB_008 ACQ: 27-Mar-2014 20:44:35 LKB Wt/Vol: 0.96 L Client ID: PB097_A-1SWMID-140314-N (TOTAL) UTP: 30-Mar-2014 13:53 LKB J-level: 10.4 pg/L Datafile: 140327X12 RPT: 30-Mar-2014 14:31 LB Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services Actual RT 32.79 NotFnd 35.77 35.22 34.76 34.48 NotFnd 40.91 39.94 NotFnd NotFnd 50.82 11.87 14.16 14.41 20.12 17.49 26.44 20.40 32.77 32.29 25.37 35.75 35.21 34.74 34.46 38.36 36.32 30.32 40.90 39.92 43.62 43.13 42.07 35.20 45.74 39.73 47.90 49.37 45.36 50.80 QC J J EMPC J EMPC J C J J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0006 1.0004 1.0007 1.0007 1.0001 1.0005 1.0004 0 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7245 0.8641 0.8793 1.2277 1.0673 1.0790 0.8325 1.3372 1.3178 0.8321 1.1724 1.1546 1.1394 1.1302 1.2580 0.9716 0.8111 1.0941 1.0678 1.1667 0.9080 0.8855 0.7409 0.9629 0.8364 1.0084 1.0392 0.9548 1.0694 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Split: 1 Checkcode: 581-063-DWJ Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.78 0 5.52E+05 0.00E+00 1.26E+06 8.87E+04 2.59E+06 6.64E+04 0.00E+00 1.62E+05 5.93E+04 0.00E+00 0.00E+00 6.68E+04 1.11 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 8.1 ND 23.4 1.5 45.9 1.16 ND 3.58 1.16 ND ND 2.81 4.61E+03 4.61E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 2.88E+03 1.76E+03 1.76E+03 1.76E+03 1.85E+03 1.15E+03 0.708 0.718 0.587 0.523 0.546 0.546 0.633 0.55 0.346 0.435 0.489 0.564 0 +0.1 -0.2 +0.7 0 +0.5 -0.4 +1.6 +1.5 -0.6 +0.9 +0.6 +0.6 +0.6 +1.2 0 -0.5 +0.5 +0.2 +0.8 -0.3 -0.3 -0.8 0 -0.5 0 0 -0.3 0 6.08E+07 7.81E+07 4.20E+07 1.44E+08 5.06E+07 1.36E+08 6.04E+07 1.23E+08 1.18E+08 7.32E+07 1.01E+08 1.02E+08 9.83E+07 9.81E+07 8.54E+07 7.03E+07 9.90E+07 1.71E+08 9.12E+07 7.85E+07 5.32E+07 6.36E+07 6.92E+07 7.60E+07 6.68E+07 5.26E+07 3.58E+07 6.04E+07 4.44E+07 3.23 3.33 1.61 1.57 1.06 1.10 0.77 0.80 0.80 1.62 1.61 1.60 1.61 1.58 1.58 1.29 1.27 1.28 1.27 1.27 1.07 1.08 1.11 1.03 0.93 0.89 0.80 0.80 1.18 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 31.3 % 44.1 % 49.4 % 84.7 % 61.5 % 78.8 % 67.4 % 85.6 % 83.2 % 95.7 % 88 % 88 % 89.2 % 86.9 % 87.3 % 85.4 % 85.3 % 73.3 % 74.8 % 69 % 85.6 % 84.7 % 101 % 89.5 % 94.3 % 78.7 % 80.4 % 95.9 % 74.5 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 0 -0.6 +0.2 +0.2 -1.0 -0.2 Page 1 of 5 0.60 0.77 0.62 0.82 1.11 1.06 Printed: 3/30/2014 2:32 PM 254 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.88 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 1.67E+08 1.14E+08 4.94E+07 1.08 1.60 1.06 1.11 1.03 0.62 110 % 113 % 115 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.88 32.78 37.76 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 1.67E+08 1.14E+08 4.94E+07 1.08 1.60 1.06 1.85 1.22 0.58 86.9 % 98.4 % 116 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.39 24.50 30.49 37.39 47.50 1.63E+08 1.04E+08 9.51E+07 7.30E+07 5.37E+07 1.57 0.80 1.61 1.31 0.90 5.96E+03 5.96E+03 5.96E+03 9.58E+03 9.58E+03 9.93E+03 9.93E+03 9.93E+03 9.93E+03 9.93E+03 9.93E+03 9.93E+03 9.93E+03 9.93E+03 5.68E+03 5.68E+03 5.68E+03 5.68E+03 5.68E+03 5.68E+03 5.68E+03 1.33 0.969 1.15 2.82 1.83 1.32 1.17 1.25 1.24 1.21 1.04 1.21 1.21 1.3 1.72 1.28 1.49 1.09 1.15 1.95 1.04 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services 11.88 13.99 14.16 14.42 NotFnd 16.41 16.57 16.80 NotFnd 17.22 NotFnd 19.56 19.83 20.13 17.51 19.27 19.67 19.86 19.98 20.09 20.57 J J EMPC J J B J C EMPC C J EMPC 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0011 0.9880 1.0003 1.0011 1.0012 1.0114 1.0250 1.0507 0.9722 0.9855 1.0007 1.0010 1.1020 1.1246 1.1355 1.1425 1.1488 1.1762 0 0 -0.6 0 +0.2 +0.3 +0.1 +0.1 +0.1 -1.3 -0.1 0 +0.7 +0.4 +0.2 -0.6 +0.5 +0.5 Page 2 of 5 NON-EMPC 13.7 159 768 1,090 450 127 17.4 4.67 0 3.34E+05 7.91E+04 1.15E+05 1.61E+06 0.00E+00 1.64E+05 1.19E+05 2.34E+06 0.00E+00 1.80E+06 0.00E+00 1.83E+06 8.16E+05 1.08E+06 1.00E+06 5.87E+06 2.45E+06 5.82E+05 8.11E+04 1.23E+06 3.45E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 16.8 174 770 1,090 456 132 33.7 8.77 0 2.92 2.95 4.08 1.49 SI SI 1.61 1.64 1.60 1.74 1.81 1.00 1.08 1.06 1.04 1.34 1.11 1.07 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 1.24 2.06 1.35 0.61 0.533 0.395 0.508 0.507 1.31 12 1.76 3.04 64.5 ND 2.34 1.52 31.9 ND 23.7 ND 24.1 10.8 15.3 35.9 157 76.1 13.3 1.95 49.7 74.5 Printed: 3/30/2014 2:32 PM 255 of 622 Name PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB SGS Evironmental Services Actual RT 21.73 NotFnd 22.13 22.35 22.63 22.91 23.12 23.47 NotFnd NotFnd NotFnd 26.09 26.47 20.41 22.38 22.99 23.06 23.27 24.53 24.66 24.75 24.97 25.23 25.42 25.71 25.89 26.22 26.32 26.51 27.23 27.49 NotFnd NotFnd 28.22 28.45 28.75 29.02 29.17 29.60 29.79 NotFnd 31.45 NotFnd NotFnd 25.71 NotFnd NotFnd 27.97 QC J C C J C J J C J EMPC J C C J C J C J J EMPC J C J J J EMPC Pred RRT Actual RRT Diff Secs 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8217 0.8370 0.8454 0.8560 0.8664 0.8743 0.8878 0.9868 1.0010 1.0006 0.9134 0.9383 0.9412 0.9498 1.0009 1.0062 1.0101 1.0189 1.0295 1.0376 1.0494 1.0564 1.0700 1.0740 1.0820 0.8432 0.8512 0.8738 0.8810 0.8903 0.8987 0.9035 0.9167 0.9227 0.9741 1.0133 0.9175 -0.1 -1.7 -0.3 -0.3 -0.8 +0.7 -0.3 -0.5 +0.5 -0.5 -1.5 0 -0.1 -0.1 0 0 0 +1.2 0 -1.2 -0.3 +0.2 +0.3 +0.5 +0.2 -0.7 -0.5 -0.5 -0.2 +0.2 -0.3 +0.2 -0.4 -0.4 +0.8 -0.2 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 8.68E+04 0.00E+00 2.92E+06 3.61E+06 8.78E+06 9.64E+06 1.42E+06 2.37E+06 0.00E+00 0.00E+00 0.00E+00 2.31E+05 1.12E+06 5.38E+04 1.75E+06 1.10E+06 1.28E+06 5.27E+05 9.49E+06 4.77E+04 2.51E+05 6.51E+06 1.04E+06 9.20E+06 8.34E+05 1.95E+06 3.42E+05 3.64E+06 4.23E+06 7.73E+04 1.30E+06 0.00E+00 0.00E+00 1.74E+05 3.89E+05 1.00E+07 5.86E+06 8.90E+04 2.99E+06 1.17E+06 0.00E+00 6.99E+04 0.00E+00 0.00E+00 6.57E+04 0.00E+00 0.00E+00 2.31E+06 0.91 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 1.04 ND 34.6 42.9 99.7 117 16.8 30.1 ND ND ND 3.04 15.8 1.37 33.3 24 24.2 12.6 186 0.711 5.72 104 20.1 168 11.7 41.2 8.24 68.8 56.4 1.05 16.7 ND ND 2.34 5.02 142 88.3 1.33 45.2 17.5 ND 0.891 ND ND 1.56 ND ND 56.5 1.01 1.04 1.00 1.02 0.99 0.99 1.03 1.06 0.87 0.78 0.82 0.77 0.87 0.79 1.09 0.84 0.80 0.89 0.80 0.77 0.82 0.83 0.81 0.80 0.79 0.79 0.95 0.82 0.78 0.78 0.88 0.79 0.82 0.82 0.72 0.61 Noise / Recv. Low DL / Recv. High 7.01E+03 7.01E+03 7.01E+03 7.01E+03 7.01E+03 7.01E+03 7.01E+03 7.01E+03 7.01E+03 7.01E+03 7.01E+03 7.01E+03 7.01E+03 2.42E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 2.82E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 4.61E+03 1.93E+03 1.93E+03 3.06E+03 3.06E+03 3.06E+03 0.829 0.828 0.82 0.823 0.786 0.844 0.821 0.879 0.801 0.778 0.87 0.914 0.981 0.541 0.532 0.614 0.532 0.671 0.55 0.417 0.638 0.448 0.542 0.51 0.394 0.591 0.673 0.529 0.373 0.622 0.587 0.652 0.637 0.614 0.59 0.645 0.688 0.683 0.69 0.683 0.587 0.582 0.723 0.363 0.435 0.699 0.833 0.766 Printed: 3/30/2014 2:32 PM 256 of 622 Name PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB SGS Evironmental Services Actual RT 28.20 28.30 NotFnd NotFnd 28.73 28.92 29.35 NotFnd 30.00 30.51 30.92 31.02 NotFnd 31.49 32.01 32.08 32.21 32.30 32.49 NotFnd NotFnd 34.17 34.38 NotFnd 35.07 NotFnd 30.34 NotFnd NotFnd 30.95 NotFnd NotFnd 33.01 NotFnd 33.48 33.78 33.96 NotFnd 34.30 34.49 NotFnd 34.86 35.26 NotFnd 35.82 NotFnd 36.34 36.51 QC J C J J EMPC C J J C J J C J J C J J J J B J C J EMPC J B C J J C J B J J B C J Pred RRT Actual RRT Diff Secs 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9247 0.9281 0.9423 0.9487 0.9625 0.9841 1.0007 1.0141 1.0174 1.0329 1.0499 1.0523 1.0564 1.0592 1.0657 0.9916 0.9975 1.0094 1.0006 1.0209 1.0885 1.1043 1.1142 1.1200 1.1312 1.1373 1.1497 1.1629 0.9581 0.9722 0.9766 +0.2 -0.2 -0.2 0 +0.2 0 +1.5 -0.2 +0.2 +1.7 +0.8 -0.4 +0.6 +0.4 +0.4 0 -0.2 +0.6 -0.2 +0.4 -0.2 +0.4 +0.2 +0.2 0 +0.8 +0.6 +0.6 -0.2 -1.3 0 Page 4 of 5 Response Ra RRF Conc. / Recv. 6.26E+04 1.76E+05 0.00E+00 0.00E+00 6.07E+05 8.85E+05 7.40E+04 0.00E+00 4.86E+05 2.77E+06 1.65E+05 1.59E+06 0.00E+00 2.36E+06 1.73E+05 6.47E+05 3.89E+06 1.22E+05 4.10E+05 0.00E+00 0.00E+00 1.28E+05 2.60E+05 0.00E+00 4.76E+04 0.00E+00 3.84E+04 0.00E+00 0.00E+00 2.04E+05 0.00E+00 0.00E+00 3.31E+05 0.00E+00 4.52E+04 7.70E+05 6.23E+04 0.00E+00 3.13E+04 2.25E+04 0.00E+00 3.57E+05 2.24E+04 0.00E+00 1.79E+05 0.00E+00 9.85E+05 1.64E+05 0.59 0.65 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 1.51 3.59 ND ND 14.1 25.9 2.05 ND 12.5 59.8 4.89 37.1 ND 50.3 3.48 13.9 73.9 2.25 12.5 ND ND 2.47 4.45 ND 0.968 ND 0.64 ND ND 4.17 ND ND 9.19 ND 1.21 20.6 2.34 ND 0.835 0.706 ND 10.9 0.634 ND 4.65 ND 21 4.67 0.61 0.61 0.83 0.59 0.63 0.58 0.63 0.61 0.57 0.59 0.61 0.68 0.64 0.61 0.62 0.68 1.26 1.24 1.19 1.05 1.24 1.25 1.25 1.39 1.17 1.12 1.23 1.26 1.29 Noise / Recv. Low DL / Recv. High 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 3.06E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 0.757 0.635 0.911 0.836 0.724 0.916 0.866 0.543 0.802 0.674 0.927 0.73 0.566 0.665 0.63 0.673 0.594 0.578 0.956 0.55 0.541 0.604 0.534 0.615 0.626 0.602 0.25 0.284 0.281 0.306 0.3 0.388 0.41 0.35 0.396 0.395 0.554 0.395 0.393 0.464 0.471 0.45 0.418 0.333 0.383 0.308 0.314 0.422 Printed: 3/30/2014 2:32 PM 257 of 622 Name PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB SGS Evironmental Services Actual RT 36.86 37.05 37.13 37.41 NotFnd 37.75 38.49 NotFnd NotFnd NotFnd 35.50 35.96 36.26 NotFnd 37.79 NotFnd 38.55 NotFnd 39.08 NotFnd 39.27 39.65 NotFnd 40.20 NotFnd NotFnd 42.08 NotFnd 43.15 43.59 39.76 NotFnd NotFnd NotFnd NotFnd 43.74 44.29 44.47 NotFnd 47.52 NotFnd NotFnd NotFnd NotFnd QC J EMPC J J EMPC C J J C J J EMPC J EMPC J J EMPC J EMPC J J EMPC J EMPC C J B C J EMPC J J EMPC J EMPC C J J J Pred RRT Actual RRT Diff Secs 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9860 0.9911 0.9932 1.0007 1.0096 0.9642 1.0086 1.0217 1.0303 1.0736 1.0953 1.1102 1.1158 1.1264 1.1421 0.9200 0.9434 0.9530 1.0006 1.1008 1.1146 1.1191 0.9921 - +0.2 0 -0.2 -0.9 0 +0.2 0 +0.2 +0.7 +0.7 +0.2 +0.2 +0.5 +0.5 +1.9 +1.5 0 -0.8 +0.2 +1.8 0 +0.8 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 5.95E+04 5.42E+04 8.36E+04 1.21E+06 0.00E+00 1.54E+05 1.97E+05 0.00E+00 0.00E+00 0.00E+00 8.09E+04 2.89E+04 2.20E+04 0.00E+00 2.82E+04 0.00E+00 1.94E+05 0.00E+00 9.30E+04 0.00E+00 1.34E+05 5.87E+04 0.00E+00 3.54E+04 0.00E+00 0.00E+00 3.32E+05 0.00E+00 1.06E+05 3.30E+04 2.41E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.83E+04 2.72E+04 4.06E+04 0.00E+00 4.15E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.05 1.12 1.04 1.24 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 1.92 1.41 1.79 32.3 ND 3.04 5.02 ND ND ND 2.25 0.846 0.581 ND 1.12 ND 5.53 ND 2.49 ND 4.48 2.03 ND 1.22 ND ND 8.74 ND 3.63 0.829 0.712 ND ND ND ND 3.38 1.11 1.64 ND 1.93 ND ND ND ND 1.16 1.18 0.96 0.74 0.81 1.00 1.24 1.23 1.01 1.47 0.88 1.13 1.28 1.15 1.22 1.08 0.81 0.85 0.89 Noise / Recv. Low DL / Recv. High 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.49E+03 1.76E+03 1.76E+03 1.76E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.86E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.55E+03 1.42E+03 1.42E+03 1.42E+03 3.04E+03 3.04E+03 3.04E+03 0.475 0.384 0.316 0.392 0.335 0.292 0.45 0.375 0.378 0.335 0.394 0.415 0.373 0.398 0.561 0.572 0.538 0.52 0.506 0.599 0.63 0.653 0.578 0.654 0.637 0.49 0.498 0.458 0.672 0.491 0.465 0.432 0.464 0.433 0.456 0.68 0.641 0.635 0.73 0.682 0.548 0.961 0.953 1.66 Printed: 3/30/2014 2:32 PM 258 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 1.34e8 6.71e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 2.86e7 1.43e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 2.28e7 1.14e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 4.21e7 2.11e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 2.56e7 1.28e7 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 4.32e6 2.16e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 4.20e6 2.10e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 581-063 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:47 Page 1 of 21 259 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 PCB-1 2.49e5 11.88 Rel. Int. 100% Abs. Int. 1.09e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.28e3 5.43e4 PCB-3 1.14e5 14.16 PCB-2 5.91e4 13.99 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 8.53e4 11.88 Rel. Int. 100% Abs. Int. 3.38e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 2.67e3 PCB-3 2.79e4 14.17 PCB-2 2.00e4 13.98 1.69e4 0% 11.0 12.0 13.0 14.0 15.0 ES-3 6.00e7 14.16 ES-1 4.65e7 11.87 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 2.05e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 6.12e3 1.03e7 0% 11.0 12.0 13.0 15.0 ES-3 1.80e7 14.16 ES-1 1.44e7 11.87 Rel. Int. 100% 14.0 0.00e0 16.0 RT Abs. Int. 6.15e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.79e4 3.08e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.34e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 6.71e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2239, 1446 scc: 581-063 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:51 (LKB) Printed: 30-Mar-2014 14:47 Page 2 of 21 260 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 PCB-4 9.60e5 14.42 Rel. Int. 100% Abs. Int. 3.41e5 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.84e3 1.70e5 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 6.46e5 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.42e5 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.16e4 1.21e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.59e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.83e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.02e3 4.42e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.61e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.59e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.69e3 2.79e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.34e8 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 6.71e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7962, 3029 scc: 581-063 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:51 (LKB) Printed: 30-Mar-2014 14:47 Page 3 of 21 261 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 6.05e3 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 PCB-6 1.44e6 16.80 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 Abs. Int. 4.77e5 PCB-8 1.12e6 17.22 PCB-11 1.13e6 19.56 PCB-9 PCB-7 9.98e4 SI 7.26e4 SI 16.41 16.57 PCB-15 7.62e5 20.13 13/12 5.18e5 19.83 2.39e5 0% 17.0 PCB-6 8.98e5 16.80 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 2.13e4 18.0 19.0 PCB-8 6.80e5 17.22 20.0 PCB-11 7.04e5 19.56 PFK INTERFERENCE 21.0 Abs. Int. 3.56e5 PCB-15 4.20e5 20.13 13/12 2.97e5 19.82 1.78e5 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 9.95e7 16.39 20.0 21.0 1.54e7 0% 17.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.08e7 ES-15 8.76e7 20.12 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.82e4 0.00e0 RT 18.0 19.0 JS-9 6.33e7 16.39 20.0 21.0 Abs. Int. 1.95e7 ES-15 5.59e7 20.12 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.92e3 0.00e0 RT 9.74e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.43e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4609, 0831 scc: 581-063 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:52 (LKB) Printed: 30-Mar-2014 14:47 Page 4 of 21 262 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Rel. Int. 100% Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 Abs. Int. 9.05e5 30/18 3.05e6 19.27 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.85e3 PCB-17 1.27e6 19.67 PCB-19 5.02e5 17.51 PCB-27 2.96e5 19.86 PCB-16 6.45e5 20.09 PCB-32 1.78e6 20.57 4.53e5 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 8.04e5 30/18 2.82e6 19.27 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.83e3 PCB-17 1.19e6 19.67 PCB-19 5.02e5 17.51 PCB-32 1.67e6 20.57 PCB-27 2.86e5 19.86 4.02e5 PCB-16 5.81e5 20.09 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.61e7 17.49 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.82e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 6.26e4 3.91e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 2.45e7 17.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.27e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 4.30e4 3.63e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.43e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2518, 3931 scc: 581-063 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:48 Printed: 30-Mar-2014 14:47 Page 5 of 21 263 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 PCB-31 28/20 4.39e6 4.87e6 22.63 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 3.58e3 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 26/29 1.47e6 22.13 PCB-25 1.84e6 22.35 Abs. Int. 1.21e6 21/33 7.04e5 23.12 6.05e5 PCB-22 1.18e6 23.47 PCB-37 5.75e5 26.47 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 28/20 4.39e6 4.78e6 22.63 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 3.43e3 24.0 26/29 1.45e6 22.13 PCB-25 1.77e6 22.35 Abs. Int. 1.19e6 21/33 7.12e5 23.12 5.95e5 PCB-22 1.19e6 23.47 PCB-37 5.42e5 26.46 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.67e7 22.88 Rel. Int. 100% ES-37 7.14e7 26.44 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.50e4 Abs. Int. 2.27e7 1.14e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 8.02e7 22.88 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 6.48e7 26.44 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 4.70e4 Abs. Int. 2.11e7 1.05e7 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.28e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.14e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6940, 4646 scc: 581-063 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:48 Printed: 30-Mar-2014 14:47 Page 6 of 21 264 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 PCB-54 2.50e4 20.41 Rel. Int. 100% Abs. Int. 8.73e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.09e3 4.37e3 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.88e4 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.21e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.34e3 4.60e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.63e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.50e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 6.19e3 3.75e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.41e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.38e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 5.81e3 4.69e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 1.43e7 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8220, 9175 scc: 581-063 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:48 Printed: 30-Mar-2014 14:47 Page 7 of 21 265 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Rel. Int. 100% PCB-52 4.19e6 24.53 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.06e3 50/53 7.67e5 22.38 PCB-51 5.54e5 23.06 PCB-45 4.92e5 22.99 69/49 2.89e6 24.97 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 PCB-48 4.88e5 25.23 PCB-46 2.45e5 23.27 Abs. Int. 1.08e6 44/47… 4.08e6 25.42 PCB-42 8.80e5 25.89 71/40 1.62e6 26.32 PCB-64 1.88e6 26.51 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 5.31e6 24.53 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.76e3 50/53 9.86e5 22.38 PCB-51 7.22e5 23.06 PCB-45 6.03e5 22.99 69/49 3.62e6 24.97 Abs. Int. 1.38e6 44/47… 5.12e6 25.42 PCB-42 1.07e6 25.89 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.61e7 24.50 Rel. Int. 100% 0.00e0 RT 26.0 PCB-48 5.50e5 25.23 PCB-46 2.82e5 23.27 5.38e5 71/40 2.02e6 26.32 PCB-64 2.35e6 26.51 6.89e5 0.00e0 RT Abs. Int. 1.23e7 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.45e4 6.16e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 5.79e7 24.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.01e4 7.53e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.28e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.14e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4036, 8203 scc: 581-063 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:48 Printed: 30-Mar-2014 14:47 Page 8 of 21 266 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 61/70... 4.39e6 28.75 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.69e3 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 PCB-68 5.76e5 27.49 PCB-63 1.75e5 28.45 Abs. Int. 7.38e5 PCB-56 1.32e6 29.60 PCB-60 5.27e5 29.79 3.69e5 PCB-77 2.41e5 32.79 0% 28.0 32.0 34.0 36.0 38.0 61/70... 5.65e6 28.75 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.92e3 30.0 PCB-68 7.25e5 27.48 Abs. Int. 9.62e5 PCB-56 1.67e6 29.60 PCB-63 2.13e5 28.45 4.81e5 PCB-60 6.43e5 29.79 PCB-77 3.11e5 32.78 0% 28.0 0.00e0 RT 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.07e7 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.30e4 ES-81 5.25e7 32.29 ES-77 5.48e7 32.77 1.54e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e7 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.38e4 ES-81 6.59e7 32.29 ES-77 6.83e7 32.77 1.43e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.21e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.11e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1131, 7815 scc: 581-063 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:52 (LKB) Printed: 30-Mar-2014 14:47 Page 9 of 21 267 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 PCB-96 2.91e4 25.71 Rel. Int. 100% Abs. Int. 9.03e3 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 1.00e3 4.52e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 4.06e4 25.71 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 9.34e2 5.92e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 4.52e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.19e7 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 2.40e3 5.97e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.79e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.25e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 2.17e3 3.63e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.28e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 1.14e7 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2987, 1326 scc: 581-063 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:48 Printed: 30-Mar-2014 14:47 Page 10 of 21 268 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 1.47e3 PCB-95 8.72e5 27.97 113/90… 1.07e6 30.51 PCB-91 2.31e5 28.73 PCB-84 3.34e5 PCB-102 28.92 6.96e4 28.30 PCB-110 1.47e6 32.21 PCB-99 6.13e5108/119... 31.02 8.99e5 116/85 31.49 2.40e5 PCB-115PCB-82 32.08 4.94e4 1.59e5 32.30 32.49 PCB-92 1.80e5 30.00 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 Abs. Int. 3.53e5 PCB-118 9.90e5 34.76 PCB-109 9.98e4 34.38 PCB-105 4.72e5 35.77 1.76e5 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.59e3 32.0 113/90… 1.70e6 30.51 PCB-95 1.43e6 27.97 PCB-91 3.76e5 28.73 PCB-84 5.51e5 28.92 PCB-92 3.07e5 30.00 30.0 Rel. Int. 100% 36.0 38.0 PCB-110 2.42e6 32.21 PCB-99 9.77e5108/119... 31.02 1.46e6 31.49 PCB-117 PCB-115PCB-82 PCB-83 1.10e5 7.24e4 2.50e5 1.04e5 32.0132.29 32.49 30.92 0% 28.0 34.0 32.0 Abs. Int. 5.89e5 PCB-118 1.60e6 34.76 PCB-109 1.60e5 34.38 34.0 CS/SS-111 7.04e7 32.78 JS-101 5.87e7 30.49 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 3.10e3 0.00e0 RT ES-123 6.00e7 34.46 PCB-105 7.86e5 35.77 36.0 ES-118 ES-114 6.06e7 6.28e7 34.74 35.21 2.94e5 38.0 0.00e0 RT Abs. Int. 1.70e7 ES-105 6.21e7 35.75 8.50e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.39e7 32.78 JS-101 3.64e7 30.49 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 4.21e3 34.0 ES-118 ES-114 3.92e7 ES-123 3.77e7 35.20 3.81e7 34.74 34.46 36.0 38.0 0.00e0 RT Abs. Int. 1.07e7 ES-105 3.86e7 35.75 5.36e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.21e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.11e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5049, 2391 scc: 581-063 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:52 (LKB) Printed: 30-Mar-2014 14:47 Page 11 of 21 269 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 Rel. Int. 100% Abs. Int. 1.19e6 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 1.47e3 5.93e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 2.71e6 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.41e3 1.35e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.31e7 ES-126 5.23e7 38.36 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 6.45e3 6.55e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.25e6 ES-126 3.31e7 38.36 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 5.65e3 4.13e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.56e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.28e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7284, 0282 scc: 581-063 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:52 (LKB) Printed: 30-Mar-2014 14:47 Page 12 of 21 270 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 Rel. Int. 100% 153/168 5.49e5 36.34 147/149 4.26e5 33.78 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 9.22e2 PCB-136 1.13e5 30.95 151/135 1.80e5 33.01 PCB-134 3.47e4 33.96 PCB-132 1.92e5 34.86 PCB-146 9.88e4 35.82 163/138… 6.71e5 37.41 PCB-141 9.21e4 PCB-137 36.51 2.86e4 37.05 Abs. Int. 1.54e5 PCB-158 8.25e4 37.75 0% 28.0 30.0 32.0 34.0 36.0 38.0 153/168 4.36e5 36.34 Rel. Int. 100% 147/149 3.44e5 33.78 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 5.65e2 151/135 1.51e5 33.01 PCB-136 9.11e4 30.95 PCB-134 2.76e4 33.96 PCB-132 1.64e5 34.86 163/138… 5.42e5 37.41 0% 28.0 30.0 32.0 34.0 ES-155 5.53e7 30.32 Rel. Int. 100% 36.0 ES-153 3.96e7 36.32 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.94e3 0.00e0 RT Abs. Int. 1.22e5 PCB-141 PCB-158 7.14e4 PCB-164 7.12e4 4.46e4 36.51 37.75 37.13 PCB-146 8.02e4 35.82 7.69e4 38.0 6.11e4 0.00e0 RT Abs. Int. 1.37e7 JS-138 4.14e7 37.39 6.87e6 0% 28.0 30.0 32.0 34.0 ES-155 4.37e7 30.32 Rel. Int. 100% 36.0 ES-153 3.08e7 36.32 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.73e3 38.0 0.00e0 RT Abs. Int. 1.09e7 JS-138 3.17e7 37.39 5.47e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.21e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 2.11e7 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3757, 1765 scc: 581-063 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:48 Printed: 30-Mar-2014 14:47 Page 13 of 21 271 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 156/157 8.53e4 40.91 128/166 1.07e5 38.49 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 7.90e2 Abs. Int. 2.81e4 PCB-167 3.06e4 39.94 1.41e4 0% 39.0 Rel. Int. 100% 40.0 128/166 9.03e4 38.49 41.0 42.0 43.0 44.0 45.0 Abs. Int. 2.45e4 156/157 7.65e4 40.91 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 9.74e2 PCB-167 2.87e4 39.94 1.22e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 5.11e7 39.92 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 9.98e3 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 9.60e7 40.90 0.00e0 RT Abs. Int. 1.70e7 ES-169 4.39e7 43.62 8.51e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 4.01e7 39.92 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 8.69e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 7.52e7 40.90 0.00e0 RT Abs. Int. 1.34e7 ES-169 3.46e7 43.62 6.69e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.56e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.28e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2883, 3109 scc: 581-063 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:48 Printed: 30-Mar-2014 14:47 Page 14 of 21 272 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Rel. Int. 100% Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 Abs. Int. 1.21e4 PCB-179 3.96e4 35.50 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 8.27e2 PCB-184 1.47e4 35.96 PCB-178 1.41e4 37.79 PCB-176 1.12e4 36.26 6.04e3 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-179 4.13e4 35.50 PCB-184 1.98e4 35.96 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 5.54e2 37.0 38.0 Abs. Int. 1.22e4 PCB-178 1.41e4 37.79 PCB-176 1.39e4 36.26 6.09e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.63e7 35.20 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 8.86e6 CS/SS-178 2.54e7 37.76 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.39e3 4.43e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.29e7 35.20 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.87e6 CS/SS-178 2.40e7 37.76 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.61e3 3.94e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 2.06e7 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9543, 1724 scc: 581-063 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:51 Printed: 30-Mar-2014 14:47 Page 15 of 21 273 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 9.94e2 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 180/193 1.76e5 42.08 PCB-187 1.18e5 38.55 PCB-183 5.61e4 39.08 PCB-174 6.75e4 39.27 PCB-177 4.22e4 39.65 Abs. Int. 4.07e4 PCB-170 6.62e4 43.15 171/173 1.80e4 40.20 2.04e4 PCB-190 1.77e4 43.59 0% 39.0 40.0 41.0 43.0 44.0 45.0 180/193 1.56e5 42.08 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 8.68e2 42.0 PCB-187 9.53e4 38.56 PCB-174 PCB-183 6.69e4 4.56e4 39.27 39.08 PCB-177 2.88e4 39.65 Abs. Int. 3.98e4 PCB-170 5.18e4 43.16 171/173 2.04e4 40.19 1.99e4 PCB-190 1.53e4 43.60 0% 39.0 40.0 41.0 42.0 ES-180 3.30e7 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 3.74e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.12e6 ES-170 2.75e7 43.13 4.06e6 0% 39.0 40.0 41.0 42.0 ES-180 3.06e7 42.07 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 5.26e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.51e6 ES-170 2.57e7 43.13 3.75e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.56e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.28e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7083, 6213 scc: 581-063 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:51 Printed: 30-Mar-2014 14:47 Page 16 of 21 274 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 Rel. Int. 100% Abs. Int. 3.87e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 9.28e2 1.94e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 2.56e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 9.23e2 1.28e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 3.86e7 45.74 0.00e0 RT Abs. Int. 9.29e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.92e3 4.65e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 3.74e7 45.74 0.00e0 RT Abs. Int. 9.00e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 4.12e3 4.50e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.32e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.16e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4026, 4026 scc: 581-063 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:50 (LKB) Printed: 30-Mar-2014 14:47 Page 17 of 21 275 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 198/199 4.47e4 43.74 PCB-202 1.56e4 39.76 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 8.79e2 Abs. Int. 9.54e3 PCB-203 1.87e4 44.47 PCB-196 1.22e4 44.29 4.77e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 4.14e4 43.74 Rel. Int. 100% PCB-202 1.28e4 39.75 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.68e2 Abs. Int. 1.03e4 PCB-196 1.50e4 44.29 PCB-203 2.19e4 44.46 5.14e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.22e7 39.73 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.91e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.73e3 3.96e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.46e7 39.73 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.55e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.53e3 4.28e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.56e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 1.28e7 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6067, 8981 scc: 581-063 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:50 (LKB) Printed: 30-Mar-2014 14:47 Page 18 of 21 276 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 PCB-194 1.96e4 47.52 Rel. Int. 100% Abs. Int. 5.54e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 5.34e2 2.77e3 0% 46.0 47.0 48.0 49.0 50.0 PCB-194 2.20e4 47.52 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.60e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 8.85e2 3.30e3 0% 46.0 47.0 48.0 JS-194 2.55e7 47.50 Rel. Int. 100% 49.0 50.0 ES-205 2.47e7 47.90 0.00e0 RT Abs. Int. 6.12e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 2.88e3 3.06e6 0% 46.0 47.0 48.0 JS-194 2.82e7 47.51 Rel. Int. 100% 49.0 50.0 ES-205 2.78e7 47.90 0.00e0 RT Abs. Int. 6.82e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.76e3 3.41e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.32e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.16e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4306, 9779 scc: 581-063 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:53 Printed: 30-Mar-2014 14:47 Page 19 of 21 277 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 Rel. Int. 100% Abs. Int. 3.63e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 1.13e3 1.82e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 5.22e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 1.91e3 2.61e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 6.50e6 ES-208 2.68e7 45.36 ES-206 1.59e7 49.37 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 1.79e3 3.25e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 8.17e6 ES-208 3.36e7 45.36 ES-206 1.99e7 49.37 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.88e3 4.09e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.32e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 2.16e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6142, 7149 scc: 581-063 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:51 (LKB) Printed: 30-Mar-2014 14:47 Page 20 of 21 278 of 622 SGS-AP ID: A6506_11899_PCB_008 Instr: AutoSpec-Premier MM7 Sample ID: PB097_A-1SWMID-140314-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 56 Acq: 27-Mar-2014 20:44:35 User: LKB Datafile: 140327X12 PCB-209 3.52e4 50.82 Rel. Int. 100% Abs. Int. 8.83e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 6.33e2 4.41e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 3.16e4 50.81 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.05e4 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 5.20e2 5.23e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.40e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.16e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.01e3 2.58e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.04e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.38e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 1.28e3 2.19e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.20e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 2.10e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB_008.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2007, 2566 scc: 581-063 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:51 (LKB) Printed: 30-Mar-2014 14:47 Page 21 of 21 279 of 622 SGS Analytical Perspectives — Run Log Project: A6506_11899_PCB Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Wt/Vol Client/Sample ID Analyst(s) Datafile Vial# Lab ID Checkcode Acq Date Acq Time 1 140327X01 Tray1:03 CS3_140327_PCB_XA 1.00 SIL 13-79-3 LKB 702-497 27-Mar-2014 10:37:58 2 140327X02 Tray1:47 OPR1_11899_PCB 1.00 0_11899_OPR001 LKB 756-952 27-Mar-2014 11:32:47 3 140327X03 Tray1:02 SBS_140327_PCB_XA 1.00 SIL 13-42-1 LKB 169-929 27-Mar-2014 12:27:58 4 140327X04 Tray1:48 MB1_11899_PCB_TLX 1.00 Method Blank LKB 733-035 27-Mar-2014 13:23:08 5 140327X05 Tray1:49 A6506_11899_PCB_001 0.92 PB070_B-2SWMID-140314-N (TOTAL) LKB 561-113 27-Mar-2014 14:18:19 6 140327X06 Tray1:50 A6506_11899_PCB_002 0.94 PB070_B-1SWMID-140314-N (TOTAL) LKB 505-842 27-Mar-2014 15:13:30 7 140327X07 Tray1:51 A6506_11899_PCB_003 0.96 PB079-1SWMID-140314-N (TOTAL) LKB 109-950 27-Mar-2014 16:08:42 8 140327X08 Tray1:52 A6506_11899_PCB_004 0.96 PB081_A-1SWMID-140314-N (TOTAL) LKB 761-905 27-Mar-2014 17:03:52 9 140327X09 Tray1:53 A6506_11899_PCB_005 0.93 PB081_A-1SWMID-140314-N (DISSOLVED) LKB 223-376 27-Mar-2014 17:59:02 10 140327X10 Tray1:54 A6506_11899_PCB_006 0.96 PB089-1SWMID-140314-N (TOTAL) LKB 431-600 27-Mar-2014 18:54:13 11 140327X11 Tray1:55 A6506_11899_PCB_007 0.97 PB085-1SWMID-140314-N (TOTAL) LKB 507-769 27-Mar-2014 19:49:23 12 140327X12 Tray1:56 A6506_11899_PCB_008 0.96 PB097_A-1SWMID-140314-N (TOTAL) LKB 581-063 27-Mar-2014 20:44:35 Project file: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\A6506_11899_PCB.utp_prj, saved 30-Mar-2014 14:51 AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 Printed: 30-Mar-2014 14:51 280 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services CS3_140327_PCB_XA 27-MAR-2014 10:37 140327X01 Processed: 30-Mar-2014 14:23 ICAL: MM7_PCB_10292013_20DEC2013 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.81 32.33 35.79 35.25 34.78 34.50 38.40 40.94 39.96 43.65 45.78 50.84 5.29E+07 5.26E+07 4.07E+07 4.52E+07 4.30E+07 4.51E+07 4.00E+07 7.05E+07 4.00E+07 3.43E+07 3.50E+07 2.17E+07 0.79 Y 0.77 Y 0.63 Y 0.63 Y 0.62 Y 0.61 Y 0.64 Y 1.21 Y 1.22 Y 1.23 Y 1.07 Y 1.16 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.17 1.07 1.18 1.15 1.20 1.24 1.09 1.15 1.13 1.13 1.07 1.5% 4.9% -3.5% -1.5% -3.3% -1.2% 11.9% -0.3% -1.3% 0.3% 4.8% -4.3% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 11.89 14.18 14.43 20.14 17.52 26.46 20.43 32.79 32.31 25.40 35.77 35.23 34.76 34.48 38.38 36.34 30.35 40.92 39.94 43.63 43.15 42.08 35.22 45.76 39.75 47.92 49.38 45.37 50.82 1.44E+08 1.34E+08 7.60E+07 1.45E+08 7.15E+07 1.06E+08 6.65E+07 9.05E+07 8.96E+07 6.18E+07 7.58E+07 7.63E+07 7.48E+07 7.54E+07 6.45E+07 5.66E+07 8.01E+07 1.29E+08 6.98E+07 6.09E+07 4.27E+07 5.15E+07 5.71E+07 6.22E+07 5.32E+07 4.47E+07 3.21E+07 5.06E+07 4.07E+07 3.27 Y 3.29 Y 1.60 Y 1.57 Y 1.06 Y 1.11 Y 0.77 Y 0.81 Y 0.79 Y 1.59 Y 1.59 Y 1.63 Y 1.62 Y 1.59 Y 1.60 Y 1.27 Y 1.29 Y 1.26 Y 1.26 Y 1.27 Y 1.06 Y 1.10 Y 1.08 Y 1.05 Y 0.90 Y 0.88 Y 0.78 Y 0.80 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.04 0.97 0.55 1.05 0.52 1.47 0.92 1.25 1.24 0.93 1.14 1.15 1.12 1.13 0.97 1.13 1.59 1.28 1.39 1.21 1.16 1.40 1.14 1.69 1.06 1.21 0.87 1.37 1.10 -12.9% -10.9% 5.1% 1.0% 2.2% -11.4% 6.9% -9.5% -9.3% 15.6% -5.2% -5.7% -3.0% -4.5% -5.6% 1.1% 0.3% -19.8% -16.8% -22.1% 22.4% 22.9% 20.9% 6.7% 9.2% -2.4% 5.1% 16.9% -0.5% Page 1 of 6 281 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services Processed: 30-Mar-2014 14:23 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA 27-MAR-2014 10:37 140327X01 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 22.91 32.80 37.78 1.18E+08 8.00E+07 3.45E+07 1.09 Y 1.57 Y 1.07 Y 1.11 1.03 0.62 1.11 1.06 0.61 0.0% 3.1% -2.2% CS PCB-28 CS PCB-111 CS PCB-178 22.91 32.80 37.78 1.18E+08 8.00E+07 3.45E+07 1.09 Y 1.57 Y 1.07 Y 1.85 1.22 0.58 1.64 1.20 0.69 -11.4% -1.5% 18.2% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.41 24.53 30.51 37.41 47.52 1.38E+08 7.23E+07 6.65E+07 5.03E+07 3.68E+07 1.57 Y 0.80 Y 1.60 Y 1.28 Y 0.90 Y - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 11.90 14.19 14.45 20.16 17.53 26.49 20.45 25.42 30.37 35.24 39.77 47.94 45.40 49.40 7.90E+07 7.85E+07 4.49E+07 8.12E+07 3.99E+07 6.45E+07 4.44E+07 4.26E+07 4.80E+07 3.28E+07 2.70E+07 2.34E+07 2.78E+07 1.73E+07 3.24 Y 3.25 Y 1.59 Y 1.63 Y 1.04 Y 1.00 Y 0.81 Y 0.64 Y 1.27 Y 1.07 Y 0.91 Y 0.93 Y 0.78 Y 0.79 Y 1.10 1.17 1.18 1.12 1.12 1.21 1.34 1.38 1.20 1.15 1.01 1.05 1.10 1.08 15.3% 16.2% -4.1% 9.5% -2.7% 12.3% -1.2% -3.7% -4.8% -9.4% -3.6% -1.2% -2.1% -3.4% 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 - Page 2 of 6 - 282 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB Processed: 30-Mar-2014 14:23 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA 27-MAR-2014 10:37 140327X01 RT Response RA 11.90 14.01 14.19 14.45 14.63 16.43 16.59 16.82 17.12 17.24 18.80 19.58 19.87 20.16 17.53 19.29 19.69 19.89 20.02 20.12 20.60 21.75 21.90 22.18 22.38 22.66 22.94 23.12 23.50 24.88 25.20 25.73 26.12 26.49 20.45 22.43 23.02 23.09 23.30 24.55 24.68 7.90E+07 8.01E+07 7.85E+07 4.49E+07 7.23E+07 7.35E+07 8.28E+07 7.73E+07 7.80E+07 7.99E+07 9.27E+07 8.00E+07 1.59E+08 8.12E+07 3.99E+07 1.10E+08 4.73E+07 6.44E+07 6.10E+07 3.62E+07 6.80E+07 6.79E+07 6.80E+07 1.37E+08 6.83E+07 7.15E+07 1.33E+08 1.37E+08 6.40E+07 7.02E+07 7.23E+07 6.46E+07 6.15E+07 6.45E+07 4.44E+07 8.28E+07 3.58E+07 4.14E+07 3.28E+07 4.01E+07 5.28E+07 3.24 Y 3.22 Y 3.25 Y 1.59 Y 1.59 Y 1.65 Y 1.63 Y 1.64 Y 1.62 Y 1.64 Y 1.64 Y 1.64 Y 1.62 Y 1.63 Y 1.04 Y 1.05 Y 1.04 Y 1.04 Y 1.03 Y 1.05 Y 1.04 Y 1.01 Y 1.00 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.00 Y 1.02 Y 1.01 Y 1.00 Y 0.81 Y 0.78 Y 0.79 Y 0.80 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 RRF 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 1.20 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.54 1.32 1.80 1.71 1.01 1.90 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 0.92 0.80 0.93 0.73 0.89 1.18 15.8% -3.9% 7.0% 8.8% 6.8% 7.1% 6.5% 8.0% 8.8% 10.8% -0.1% 1.5% -0.9% -0.9% 0.6% -0.9% 12.4% 10.6% 10.1% 11.0% 9.7% 10.7% 9.7% 11.4% 12.8% 12.2% 10.0% 11.2% 5.5% 4.3% 7.7% 4.8% 6.0% 6.1% 283 of 622 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeC PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB Processed: 30-Mar-2014 14:23 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA 27-MAR-2014 10:37 140327X01 RT Response RA 24.78 24.97 25.25 25.47 25.75 25.91 26.25 26.34 26.54 27.25 27.51 27.88 28.08 28.24 28.47 28.76 29.04 29.19 29.63 29.82 30.14 31.46 31.95 25.42 25.74 27.43 27.62 28.00 28.21 28.33 28.39 28.70 28.76 28.95 29.37 29.71 30.03 30.51 30.95 3.45E+07 9.84E+07 4.06E+07 1.30E+08 1.68E+08 3.72E+07 3.27E+07 8.33E+07 5.90E+07 5.78E+07 6.12E+07 5.51E+07 5.65E+07 5.86E+07 6.09E+07 2.23E+08 5.22E+07 5.26E+07 5.21E+07 5.27E+07 6.13E+07 6.18E+07 4.98E+07 4.26E+07 3.70E+07 3.57E+07 3.00E+07 3.26E+07 6.60E+07 3.93E+07 2.74E+07 2.98E+07 3.45E+07 2.72E+07 2.88E+07 4.59E+07 3.11E+07 1.11E+08 2.69E+07 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.80 Y 0.64 Y 0.64 Y 0.61 Y 0.61 Y 0.61 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.60 Y Page 4 of 6 RRF 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.20 0.95 0.79 0.86 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 8.5% 7.4% 8.1% 6.7% 7.1% 9.0% 5.1% 8.3% 7.9% 6.7% 7.1% 5.8% 6.9% 3.8% 4.8% 3.8% 5.8% 4.9% 4.7% 3.6% 4.1% 5.6% 4.7% -2.6% 1.7% -0.6% -0.1% 1.4% 7.7% -4.1% -0.7% -3.1% 1.1% 0.1% 1.6% 0.6% -0.3% -0.1% 284 of 622 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Processed: 30-Mar-2014 14:23 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA 27-MAR-2014 10:37 140327X01 Name PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB RT Response RA 31.04 31.14 31.49 32.02 32.11 32.23 32.32 32.51 32.83 33.22 34.19 34.40 34.62 35.08 37.02 30.37 30.53 30.67 30.98 31.25 32.52 33.04 33.25 33.51 33.81 33.98 34.06 34.33 34.50 34.65 34.88 35.29 35.63 35.84 35.96 36.39 36.53 36.88 37.08 37.16 37.45 3.42E+07 4.41E+07 2.25E+08 3.96E+07 7.42E+07 4.20E+07 4.32E+07 2.61E+07 4.54E+07 4.61E+07 8.26E+07 4.67E+07 4.06E+07 3.83E+07 4.12E+07 4.80E+07 4.43E+07 4.49E+07 4.11E+07 4.20E+07 3.18E+07 6.03E+07 3.53E+07 3.12E+07 6.26E+07 2.23E+07 3.13E+07 6.29E+07 2.66E+07 2.62E+07 2.75E+07 2.96E+07 3.71E+07 3.23E+07 4.01E+07 7.86E+07 2.93E+07 2.60E+07 3.21E+07 3.91E+07 9.44E+07 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.60 Y 0.61 Y 0.62 Y 0.62 Y 0.60 Y 0.62 Y 0.61 Y 0.62 Y 1.27 Y 1.27 Y 1.26 Y 1.27 Y 1.26 Y 1.25 Y 1.26 Y 1.26 Y 1.28 Y 1.26 Y 1.25 Y 1.28 Y 1.27 Y 1.27 Y 1.26 Y 1.29 Y 1.27 Y 1.26 Y 1.25 Y 1.28 Y 1.26 Y 1.26 Y 1.25 Y 1.25 Y 1.28 Y 1.26 Y Page 5 of 6 RRF 0.92 1.17 0.98 1.14 0.94 1.12 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 0.92 1.14 1.38 1.11 -1.5% 0.2% 1.7% -7.7% 4.6% -0.3% -1.1% -0.7% -1.3% 1.0% -0.2% -1.0% -2.5% 0.9% -0.8% -5.7% -4.7% -3.7% -5.8% -5.0% -6.5% -7.1% -6.8% -6.0% -14.8% -2.2% -7.9% -8.3% -6.5% -5.9% -7.7% -7.1% -5.2% -6.8% -4.7% -5.0% -5.6% -2.4% -7.8% -6.6% 285 of 622 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB Processed: 30-Mar-2014 14:23 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA 27-MAR-2014 10:37 140327X01 RT Response RA 37.59 37.77 38.50 39.31 39.55 35.24 35.52 35.98 36.28 36.68 37.80 38.35 38.57 38.75 39.10 39.18 39.29 39.67 40.02 40.20 41.55 41.79 42.07 42.40 43.17 43.62 39.77 40.56 41.13 41.32 41.41 43.73 44.31 44.48 45.60 47.54 47.94 45.40 46.18 49.40 3.69E+07 4.23E+07 6.23E+07 3.74E+07 3.71E+07 3.28E+07 3.08E+07 2.93E+07 3.25E+07 3.05E+07 2.16E+07 2.78E+07 2.96E+07 3.06E+07 3.14E+07 2.66E+07 2.53E+07 2.44E+07 2.75E+07 4.87E+07 2.50E+07 3.25E+07 6.39E+07 3.48E+07 2.42E+07 3.32E+07 2.70E+07 3.02E+07 2.81E+07 3.01E+07 2.86E+07 3.83E+07 2.03E+07 2.05E+07 1.78E+07 1.90E+07 2.34E+07 2.78E+07 2.86E+07 1.73E+07 1.27 Y 1.27 Y 1.20 Y 1.22 Y 1.21 Y 1.07 Y 1.07 Y 1.06 Y 1.07 Y 1.07 Y 1.05 Y 1.05 Y 1.04 Y 1.06 Y 1.04 Y 1.07 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.06 Y 0.91 Y 0.91 Y 0.92 Y 0.89 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.93 Y 0.78 Y 0.78 Y 0.79 Y Page 6 of 6 RRF 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 1.30 1.50 0.89 1.07 1.06 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.13 - -14.0% -10.0% -0.7% -3.8% -0.7% -7.0% -9.1% -7.5% -5.1% -10.1% 0.7% 1.0% 1.3% 1.4% -2.6% -0.7% -0.4% -1.7% -0.2% -1.8% -2.0% -1.6% -3.2% 0.0% -6.4% -7.1% -5.4% -5.0% -3.0% -11.0% -8.3% -11.6% 3.7% 1.0% -4.8% - 286 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.01e7 2.50e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.34e7 6.69e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.09e7 5.47e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 1.79e7 8.96e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.04e7 5.22e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.16e6 1.08e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 2.03e6 1.02e6 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 702-497 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:42 Page 1 of 21 287 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-1 6.04e7 11.90 Rel. Int. 100% Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-2 6.12e7 14.01 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.24e3 Abs. Int. 2.42e7 PCB-3 6.00e7 14.19 1.21e7 0% 11.0 12.0 13.0 PCB-1 1.86e7 11.90 Rel. Int. 100% 14.0 PCB-2 1.90e7 14.01 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 2.34e3 15.0 0.00e0 16.0 RT Abs. Int. 7.38e6 PCB-3 1.85e7 14.19 3.69e6 0% 11.0 12.0 13.0 ES-1 1.10e8 11.89 Rel. Int. 100% 14.0 15.0 0.00e0 16.0 RT Abs. Int. 4.34e7 ES-3 1.03e8 14.18 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.32e3 2.17e7 0% 11.0 12.0 13.0 ES-1 3.36e7 11.89 Rel. Int. 100% 14.0 15.0 Abs. Int. 1.36e7 ES-3 3.12e7 14.18 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.39e4 0.00e0 16.0 RT 6.79e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.01e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.50e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6885, 4339 scc: 702-497 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:42 Page 2 of 21 288 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 Rel. Int. 100% PCB-4 2.76e7 14.45 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 3.21e3 Abs. Int. 1.50e7 PCB-10 4.44e7 14.63 7.49e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-4 1.73e7 14.45 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.29e4 Abs. Int. 9.32e6 PCB-10 2.79e7 14.63 4.66e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.67e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 1.61e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 5.11e3 8.06e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.92e7 14.43 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.00e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 2.46e3 5.00e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.01e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.50e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8276, 6811 scc: 702-497 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 12:15 (LKB) Printed: 30-Mar-2014 14:42 Page 3 of 21 289 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 6.09e3 PCB-9 4.58e7 16.43 PCB-7 5.13e7 PCB-6 16.59 4.80e7 16.82 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-14 5.75e7 18.80 PCB-5 4.83e7 PCB-8 17.12 4.97e7 17.24 PCB-11 4.97e7 19.58 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 13/12 9.86e7 19.87 Abs. Int. 1.68e7 PCB-15 5.04e7 20.16 8.41e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.63e4 PCB-9 2.78e7 16.43 PCB-7 3.14e7 PCB-6 16.59 2.93e7 16.82 18.0 19.0 PCB-14 3.51e7 18.80 PCB-5 2.97e7 PCB-8 17.12 3.03e7 17.24 20.0 PCB-11 3.03e7 19.58 13/12 6.09e7 19.87 21.0 Abs. Int. 1.03e7 PCB-15 3.09e7 20.16 5.15e6 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 8.45e7 16.41 20.0 21.0 ES-15 8.89e7 20.14 0.00e0 RT Abs. Int. 2.71e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.38e4 1.36e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 5.39e7 16.41 20.0 21.0 ES-15 5.65e7 20.14 0.00e0 RT Abs. Int. 1.74e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 6.53e3 8.69e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.34e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.69e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4056, 7244 scc: 702-497 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:42 Page 4 of 21 290 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 30/18 5.62e7 19.29 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.24e3 PCB-19 2.04e7 17.53 PCB-17 2.42e7 19.69 PCB-27 3.29e7 19.89 PCB-24 3.10e7 20.02 PCB-16 1.85e7 20.12 Abs. Int. 1.57e7 PCB-32 3.47e7 20.60 7.85e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 PCB-24 3.00e7 20.02 30/18 5.35e7 19.29 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 1.73e3 PCB-19 1.95e7 17.53 21.0 PCB-17 2.32e7 19.69 PCB-27 3.15e7 19.89 PCB-16 1.76e7 20.12 Abs. Int. 1.48e7 PCB-32 3.33e7 20.60 7.38e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 1.59e7 ES-19 3.68e7 17.52 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 3.94e4 0.00e0 RT 7.93e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.48e7 ES-19 3.47e7 17.51 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.87e4 0.00e0 RT 7.42e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.34e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.69e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2095, 5597 scc: 702-497 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:42 Page 5 of 21 291 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 28/20 6.71e7 22.94 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 6.16e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-23 PCB-34 3.40e7 3.41e7 21.90 21.75 26/29 6.89e7 22.18 PCB-31 3.60e7 22.66 Abs. Int. 1.61e7 PCB-39 3.62e7 25.20 PCB-36 3.52e7 24.88 PCB-22 3.22e7 23.50 PCB-38 3.26e7 25.73 PCB-35 3.09e7 26.12 PCB-37 3.23e7 26.49 0% 22.0 24.0 25.0 0.00e0 RT 26.0 28/20 6.62e7 22.94 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 4.60e3 23.0 PCB-23 PCB-34 3.40e7 3.38e7 21.90 21.75 26/29 6.83e7 22.18 PCB-31 3.56e7 22.66 Abs. Int. 1.61e7 PCB-39 3.61e7 25.20 PCB-36 3.50e7 24.88 PCB-22 3.18e7 23.50 PCB-38 3.20e7 25.73 PCB-35 3.06e7 26.12 PCB-37 3.22e7 26.48 23.0 24.0 25.0 26.0 CS/SS-28 6.16e7 22.91 Rel. Int. 100% 8.06e6 0.00e0 RT 0% 22.0 8.06e6 ES-37 5.59e7 26.46 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.52e4 Abs. Int. 1.68e7 8.38e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 5.66e7 22.91 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 5.05e7 26.46 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.75e4 Abs. Int. 1.56e7 7.79e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.47e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2331, 8315 scc: 702-497 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:42 Page 6 of 21 292 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-54 1.99e7 20.45 Rel. Int. 100% Abs. Int. 5.70e6 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 9.39e2 2.85e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.45e7 20.45 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.93e6 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.04e3 3.47e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.90e7 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.54e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 5.73e3 4.27e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.75e7 20.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.08e7 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 4.29e3 5.42e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.34e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.69e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2699, 4303 scc: 702-497 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 12:17 (LKB) Printed: 30-Mar-2014 14:42 Page 7 of 21 293 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.24e3 50/53 3.64e7 22.43 PCB-51 1.84e7 23.09 PCB-45 1.58e7 23.02 PCB-73 2.34e7 PCB-52 24.68 1.76e7 24.55 PCB-46 1.45e7 23.30 69/49 4.34e7 24.97 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 44/47… 5.72e7 25.47 PCB-48 1.79e7 25.25 59/62… 7.38e7 25.75 71/40 3.66e7 26.34 PCB-42 1.64e7 25.91 PCB-41 1.43e7 26.25 Abs. Int. 1.39e7 PCB-64 2.61e7 26.54 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.31e3 50/53 4.65e7 22.43 24.0 PCB-51 2.31e7 23.09 PCB-45 2.00e7 23.02 25.0 PCB-73 2.95e7 PCB-52 24.68 2.24e7 24.55 PCB-46 1.83e7 23.30 69/49 5.50e7 24.97 PCB-48 2.27e7 25.25 59/62… 9.39e7 25.75 71/40 4.67e7 26.34 PCB-42 2.09e7 25.91 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.22e7 24.53 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 7.24e7 25.47 6.95e6 PCB-41 1.84e7 26.25 Abs. Int. 1.73e7 PCB-64 3.30e7 26.54 8.64e6 0.00e0 RT Abs. Int. 8.52e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.36e4 4.26e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.00e7 24.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 1.00e4 5.37e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.47e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3117, 1790 scc: 702-497 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:42 Page 8 of 21 294 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 61/70... 9.79e7 28.76 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 6.61e4 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-72 2.56e7 27.25 PCB-57 2.42e7 27.88 PCB-63 2.67e7 28.47 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 Abs. Int. 1.26e7 (2.33e7 + 2.95e7) * 100 pg/uL PCB-78 = 1.17 2.21e7* 50 pg/uL (4.04e7 + 5.01e7) 31.95 PCB-80 LKB 30-Mar-2014 14:35 PCB-81 PCB-60 PCB-79 PCB-77 2.29e7 2.30e7 2.70e7 2.72e7 30.14 2.33e7 32.33 29.82 31.46 32.81 RRF(PCB-77) = PCB-55 2.32e7 29.19 6.28e6 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 4.26e4 61/70... 1.25e8 PCB-57 28.76 3.09e7 27.88 PCB-68 PCB-63 3.42e7 3.42e7 PCB-66 2.92e7 27.51 28.47 29.04 30.0 32.0 PCB-60 2.96e7 29.82 PCB-80 3.43e7 30.14 PCB-56 2.91e7 29.62 PCB-79 3.46e7 31.46 PCB-78 2.77e7 31.95 PCB-81 2.96e7 32.33 34.0 36.0 38.0 Abs. Int. 1.59e7 PCB-77 2.95e7 32.81 7.95e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.95e7 32.31 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.26e4 0.00e0 RT 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.11e7 ES-77 4.04e7 32.79 5.55e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 5.01e7 32.31 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.21e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.38e7 ES-77 5.01e7 32.79 6.90e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.79e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.96e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5496, 8504 scc: 702-497 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:42 Page 9 of 21 295 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-104 1.66e7 25.42 Abs. Int. 4.31e6 PCB-96 1.45e7 25.74 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 6.12e2 2.16e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.60e7 25.42 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 8.67e2 PCB-96 2.25e7 25.74 0.00e0 RT Abs. Int. 6.91e6 3.45e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 3.80e7 25.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.96e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.62e3 4.98e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.38e7 25.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.21e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.80e3 3.10e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.47e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4595, 7010 scc: 702-497 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 10 of 21 296 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 108/119... 8.60e7 31.49 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 2.01e5 PCB-103 1.35e7 27.43 100/93 2.49e7 28.21 PCB-88 1.13e7 28.70 PCB-121 1.76e7 29.71 113/90… 4.25e7 30.51 116/85 2.84e7 32.11 PCB-99 1.30e7 31.04 PCB-111 PCB-120 1.71e7 1.76e7 32.83 33.22 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-118 107/124 1.64e7 3.16e7 34.78 34.19 PCB-123 PCB-114 1.71e7 1.74e7 34.50 35.25 Abs. Int. 1.28e7 PCB-105 1.57e7 35.79 PCB-127 1.58e7 37.02 6.38e6 0% 28.0 30.0 32.0 108/119... 1.39e8 31.49 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 2.79e5 34.0 PCB-94 1.87e7 27.62 100/93 4.10e7 28.21 PCB-91 2.13e7 28.76 PCB-89 1.79e7 29.37 113/90… 6.85e7 30.51 PCB-112 PCB-92 2.73e7 1.93e7 31.14 30.03 116/85 PCB-115 4.57e7 2.67e7 PCB-111 32.11 32.32 2.83e7 32.83 PCB-117 PCB-110 PCB-120 2.45e7 2.60e7 PCB-82 2.85e7 32.02 32.23 1.63e7 33.22 32.51 36.0 107/124 PCB-118 2.66e7 5.10e7 34.78 34.19 PCB-123 PCB-114 2.81e7 2.78e7 34.50 35.25 38.0 Abs. Int. 2.03e7 PCB-105 2.50e7 35.79 PCB-127 2.54e7 37.02 1.02e7 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 4.88e7 32.80 JS-101 4.10e7 30.51 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.63e3 36.0 ES-118 ES-114 4.74e7 ES-123 4.63e7 35.23 4.63e7 34.76 34.48 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.23e7 ES-105 4.66e7 35.77 6.13e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 3.12e7 32.80 JS-101 2.55e7 30.51 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 1.96e3 34.0 ES-123 2.91e7 34.48 36.0 ES-118 ES-114 2.85e7 2.90e7 34.76 35.23 38.0 0.00e0 RT Abs. Int. 7.98e6 ES-105 2.92e7 35.77 3.99e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.79e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.96e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3439, 9633 scc: 702-497 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 11 of 21 297 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 Abs. Int. 3.67e6 PCB-126 1.56e7 38.40 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 2.86e3 1.83e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 5.79e6 PCB-126 2.44e7 38.40 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 3.10e3 2.89e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 9.67e6 ES-126 3.97e7 38.38 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 6.84e3 4.84e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.21e6 ES-126 2.48e7 38.38 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 5.75e3 3.10e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.04e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.22e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8922, 1379 scc: 702-497 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 12 of 21 298 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-150 PCB-155 2.51e7 2.69e7 30.67 30.37 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.54e2 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 147/149 139/140 3.49e7 3.51e7 33.81 34.33 PCB-145 2.34e7 31.25 PCB-148 1.77e7 32.52 153/168 4.38e7 36.39 151/135 3.36e7 PCB-144 PCB-143 PCB-142 PCB-133 PCB-146 33.04 1.75e7 1.76e7 1.65e7 1.79e7 1.46e7 35.84 33.51 34.06 35.29 34.65 PCB-141 1.63e7 36.53 163/138… 5.27e7 37.45 Abs. Int. 9.42e6 PCB-164 2.20e7PCB-160 37.16 2.06e7 37.59 4.71e6 0% 28.0 30.0 32.0 PCB-152 1.95e7 30.53 Rel. Int. 100% PCB-155 2.11e7 30.37 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 6.19e2 PCB-136PCB-145 1.81e7 1.86e7 30.98 31.25 PCB-148 1.41e7 32.52 34.0 36.0 147/149 139/140 151/135 2.77e7 2.78e7 2.67e7 33.81 34.33 33.04 PCB-154 PCB-143 1.56e7 PCB-131 1.37e7 1.17e7 33.24 34.06 34.50 38.0 153/168 3.48e7 36.39 PCB-165 1.64e7 35.63 163/138… 4.18e7 37.45 PCB-141 PCB-137 1.30e7 1.43e7 37.08 36.53 Abs. Int. 7.53e6 PCB-158 1.87e7 37.77 3.77e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.51e7 30.35 Rel. Int. 100% ES-153 3.16e7 36.34 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 1.79e3 0.00e0 RT 0.00e0 RT Abs. Int. 1.15e7 JS-138 2.82e7 37.41 5.75e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.49e7 30.35 Rel. Int. 100% ES-153 2.50e7 36.34 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.44e3 0.00e0 RT Abs. Int. 8.82e6 JS-138 2.20e7 37.41 4.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.79e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.96e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3425, 9051 scc: 702-497 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 13 of 21 299 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 3.40e7 38.50 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 4.41e3 PCB-159 2.06e7 39.31 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-162 2.03e7 39.55 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 156/157 3.86e7 40.94 Abs. Int. 7.64e6 PCB-169 1.89e7 43.65 PCB-167 2.20e7 39.96 3.82e6 0% 39.0 Rel. Int. 100% HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 3.43e3 128/166 2.83e7 38.50 PCB-162 PCB-159 1.68e7 39.55 1.68e7 39.31 40.0 41.0 42.0 43.0 44.0 45.0 156/157 3.19e7 40.94 Abs. Int. 6.27e6 PCB-167 1.80e7 39.96 PCB-169 1.54e7 43.65 3.13e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 3.89e7 39.94 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 9.66e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 7.18e7 40.92 (3.41e7 + 2.68e7) * 100 pg/uL RRF(ES-169) = = 1.21 (2.82e7 + 2.20e7) * 100 pg/uL LKB 30-Mar-2014 14:36 Rel. Int. 100% 40.0 ES-167 3.09e7 39.94 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 8.12e3 41.0 42.0 0.00e0 RT Abs. Int. 1.28e7 ES-169 3.41e7 43.63 6.41e6 0% 39.0 0.00e0 RT 43.0 44.0 45.0 ES-156/157 5.71e7 40.92 0.00e0 RT Abs. Int. 1.02e7 ES-169 2.68e7 43.63 5.12e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.04e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.22e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1999, 3404 scc: 702-497 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 14 of 21 300 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% PCB-188 1.69e7 35.24 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-179 1.59e7 PCB-184 1.51e7 35.52 35.98 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 6.32e2 PCB-186 1.58e7 36.68 Abs. Int. 4.19e6 PCB-178 1.11e7 37.80 2.09e6 0% 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 PCB-188 1.59e7 35.24 36.0 PCB-179 1.49e7 35.52 PCB-176 1.57e7 36.28 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.35e2 37.0 PCB-186 1.47e7 36.68 38.0 0.00e0 RT Abs. Int. 3.94e6 PCB-178 1.05e7 37.80 1.97e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.97e7 35.22 Rel. Int. 100% Abs. Int. 7.31e6 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.13e3 CS/SS-178 1.79e7 37.78 3.65e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.74e7 35.22 Rel. Int. 100% CS/SS-178 1.67e7 37.78 3.42e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 6.85e6 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.37e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.79e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 8.95e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4122, 6507 scc: 702-497 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 15 of 21 301 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 4.38e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 180/193 3.27e7 42.07 PCB-192 1.66e7 41.79 PCB-172 1.27e7 41.55 PCB-183 PCB-174 171/173 1.60e7 1.30e7 2.49e7 PCB-182 39.1039.29 PCB-185 PCB-181 40.20 1.57e7 PCB-177 1.37e7 1.41e7 38.75 1.25e7 39.18 40.02 39.67 PCB-191 1.78e7 42.40 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-170 1.24e7 43.17 Abs. Int. 5.69e6 PCB-190 1.71e7 43.62 2.84e6 0% 39.0 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 4.09e3 PCB-182 1.49e7 38.75 PCB-183 PCB-187 1.54e7 1.45e7 39.10 38.57 40.0 41.0 42.0 180/193 3.12e7 42.07 171/173 2.38e7 PCB-181 40.20 PCB-177 1.34e7 1.18e7 40.01 39.67 PCB-172 1.23e7 41.55 43.0 PCB-191 1.70e7 42.40 PCB-170 1.18e7 43.17 44.0 45.0 Abs. Int. 5.44e6 PCB-190 1.61e7 43.62 2.72e6 0% 39.0 40.0 41.0 42.0 ES-180 2.69e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 4.04e3 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 6.70e6 ES-170 2.19e7 43.15 3.35e6 0% 39.0 40.0 41.0 42.0 ES-180 2.45e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 4.09e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.15e6 ES-170 2.07e7 43.15 3.08e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.04e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.22e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7889, 9691 scc: 702-497 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 16 of 21 302 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-189 1.81e7 45.78 Abs. Int. 4.28e6 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 2.34e3 2.14e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.69e7 45.78 Abs. Int. 3.96e6 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 1.70e3 1.98e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 3.19e7 45.76 0.00e0 RT Abs. Int. 7.69e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.65e3 3.85e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 3.03e7 45.76 0.00e0 RT Abs. Int. 7.22e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 4.28e3 3.61e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.16e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.08e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3171, 1040 scc: 702-497 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 17 of 21 303 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-202 1.29e7 39.77 Rel. Int. 100% PCB-201 1.44e7 40.56 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 1.11e3 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-197 1.42e7 PCB-204 41.32 PCB-200 1.37e7 1.35e7 41.41 41.13 198/199 1.83e7 43.73 Abs. Int. 3.54e6 PCB-196 9.73e6 44.31 PCB-203 9.80e6 44.48 1.77e6 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.41e7 39.77 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 8.90e2 41.0 PCB-201 1.58e7 40.56 42.0 43.0 PCB-197 1.59e7 PCB-204 41.32 PCB-200 1.49e7 1.46e7 41.41 41.13 44.0 45.0 198/199 2.00e7 43.73 Abs. Int. 3.86e6 PCB-196 1.06e7 44.31 PCB-203 1.07e7 44.48 1.93e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.51e7 39.75 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 6.36e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.32e3 3.18e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.81e7 39.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.80e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 2.04e3 3.40e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.04e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.22e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8614, 8255 scc: 702-497 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 18 of 21 304 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 2.28e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-194 9.06e6 47.54 PCB-195 8.50e6 45.60 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-205 1.13e7 47.94 Abs. Int. 2.65e6 1.33e6 0% 46.0 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 1.75e3 47.0 48.0 PCB-194 9.97e6 47.54 PCB-195 9.27e6 45.60 49.0 50.0 PCB-205 1.21e7 47.94 0.00e0 RT Abs. Int. 2.90e6 1.45e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.74e7 47.52 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 3.79e3 49.0 50.0 ES-205 2.10e7 47.92 0.00e0 RT Abs. Int. 5.00e6 2.50e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.94e7 47.52 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 3.69e3 49.0 50.0 ES-205 2.37e7 47.92 0.00e0 RT Abs. Int. 5.57e6 2.79e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.16e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.08e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7655, 4936 scc: 702-497 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 19 of 21 305 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.74e3 PCB-208 1.22e7 45.40 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-207 1.26e7 46.18 Abs. Int. 3.11e6 PCB-206 7.63e6 49.40 1.56e6 0% 46.0 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.18e3 PCB-208 1.56e7 45.39 47.0 48.0 49.0 50.0 PCB-207 1.61e7 46.18 Abs. Int. 3.91e6 PCB-206 9.65e6 49.40 1.96e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 5.33e6 ES-208 2.25e7 45.37 ES-206 1.41e7 49.38 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.93e3 2.66e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 6.61e6 ES-208 2.80e7 45.37 ES-206 1.80e7 49.38 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 2.11e3 3.30e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.16e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.08e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2064, 8607 scc: 702-497 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 12:21 Printed: 30-Mar-2014 14:43 Page 20 of 21 306 of 622 SGS-AP ID: CS3_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 27-Mar-2014 10:37:58 User: LKB Datafile: 140327X01 PCB-209 1.16e7 50.84 Rel. Int. 100% Abs. Int. 2.50e6 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 6.08e2 1.25e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.00e7 50.84 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.17e6 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 5.47e2 1.09e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.21e7 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.66e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 9.13e2 2.33e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.86e7 50.82 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.94e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.03e2 1.97e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.03e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 1.02e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\CS3_140327_PCB_XA.utp_res, saved 30-Mar-2014 14:36 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7927, 0391 scc: 702-497 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 12:15 (LKB) Printed: 30-Mar-2014 14:43 Page 21 of 21 307 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.01e7 2.50e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.24e7 6.18e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 9.92e6 4.96e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 1.69e7 8.47e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 9.98e6 4.99e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.13e6 1.06e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.93e6 9.63e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 169-929 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:43 Page 1 of 21 308 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 5.65e3 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 2.94e3 2.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.18e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 2.51e3 5.91e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.07e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 4.29e3 5.34e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.43e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 2.85e4 7.16e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.01e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.50e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8049, 9510 scc: 169-929 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:06 Printed: 30-Mar-2014 14:43 Page 2 of 21 309 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 7.25e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 3.72e3 3.63e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.18e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 1.18e4 1.59e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.15e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 6.41e3 1.07e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.59e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.09e3 3.30e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.01e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.50e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7235, 5540 scc: 169-929 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 3 of 21 310 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 8.24e3 DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PB 4σ 5.18e3 4.12e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.90e4 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PB 4σ 1.26e4 1.95e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.16e4 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PB 4σ 1.72e4 3.08e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.11e4 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PB 4σ 4.55e3 5.55e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.18e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2678, 7532 scc: 169-929 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 4 of 21 311 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 1.02e4 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PB 4σ 2.27e3 5.12e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.73e3 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PB 4σ 2.61e3 1.86e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.61e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PB 4σ 4.37e4 3.31e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.93e5 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PB 4σ 3.33e4 3.96e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.18e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3950, 2728 scc: 169-929 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:06 Printed: 30-Mar-2014 14:43 Page 5 of 21 312 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 PCB-36 5.32e5 24.86 Abs. Int. 1.41e5 SBS spiked with PCBs 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 128, 184, 182, 204 TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 2.98e3 7.03e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-36 5.27e5 24.86 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e5 TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.22e3 7.17e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.08e6 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PB 4σ 4.06e4 1.54e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.58e5 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PB 4σ 2.01e4 2.29e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.92e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.96e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1631, 6685 scc: 169-929 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:06 Printed: 30-Mar-2014 14:43 Page 6 of 21 313 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 2.26e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 8.60e2 1.13e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.46e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 1.33e3 1.73e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e4 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PB 4σ 6.66e3 7.21e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.57e3 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PB 4σ 3.68e3 4.28e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.18e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0587, 9628 scc: 169-929 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 7 of 21 314 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 4.07e3 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PB 4σ 1.06e3 2.03e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e3 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PB 4σ 1.13e3 2.70e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e4 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PB 4σ 1.09e4 1.35e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.48e4 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PB 4σ 7.53e3 7.40e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.92e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.96e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5357, 8691 scc: 169-929 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 8 of 21 315 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 3.80e5 27.24 PCB-79 3.53e5 31.45 TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 1.29e3 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Abs. Int. 9.91e4 PCB-78 3.40e5 31.94 4.96e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 4.65e5 27.24 32.0 PCB-79 4.24e5 31.45 TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.36e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.26e5 PCB-78 4.09e5 31.94 6.31e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.27e4 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PB 4σ 8.38e3 1.64e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.24e4 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PB 4σ 7.34e3 1.12e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.69e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.47e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9406, 4594 scc: 169-929 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:06 Printed: 30-Mar-2014 14:43 Page 9 of 21 316 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 PCB-96 2.06e5 25.72 Rel. Int. 100% Abs. Int. 5.68e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 1.10e3 2.84e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 3.39e5 25.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.83e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 7.87e2 4.92e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.45e3 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PB 4σ 1.31e3 3.23e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e3 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PB 4σ 1.31e3 2.68e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.92e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.96e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2082, 0014 scc: 169-929 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 10 of 21 317 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 1.76e5 28.37 PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 9.78e2 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 2.41e5 34.17 PCB-89 1.62e5 29.35 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Abs. Int. 5.84e4 PCB-106 2.30e5 34.60 2.92e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 2.91e5 28.37 PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.26e3 32.0 34.0 107/124 4.00e5 34.17 PCB-89 2.73e5 29.35 36.0 38.0 0.00e0 RT Abs. Int. 1.03e5 PCB-106 3.76e5 34.60 5.13e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e4 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PB 4σ 2.37e3 5.15e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.84e3 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PB 4σ 2.17e3 4.42e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.69e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.47e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3726, 2857 scc: 169-929 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 11 of 21 318 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 3.96e3 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PB 4σ 9.60e2 1.98e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.52e3 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PB 4σ 1.09e3 2.76e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.54e3 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PB 4σ 2.03e3 4.27e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.37e3 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PB 4σ 2.70e3 4.68e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.98e6 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 4.99e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3323, 4996 scc: 169-929 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:06 Printed: 30-Mar-2014 14:43 Page 12 of 21 319 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 PCB-152 3.71e5 30.51 Rel. Int. 100% Abs. Int. 1.03e5 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 8.87e2 5.14e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 3.07e5 30.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.02e4 HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 8.17e2 4.01e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.08e3 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PB 4σ 1.72e3 3.54e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.89e3 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PB 4σ 1.63e3 3.45e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.69e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.47e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5184, 9227 scc: 169-929 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 13 of 21 320 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Abs. Int. 8.12e4 128/166 3.16e5 38.48 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 7.95e2 4.06e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.74e4 128/166 2.36e5 38.48 HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 1.22e3 2.87e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.94e3 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PB 4σ 1.45e3 4.47e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.76e3 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PB 4σ 1.95e3 3.88e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.98e6 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 4.99e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 3002, 3386 scc: 169-929 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:06 Printed: 30-Mar-2014 14:43 Page 14 of 21 321 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 PCB-184 2.35e5 35.97 Rel. Int. 100% Abs. Int. 6.49e4 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 6.29e2 3.24e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.12e5 35.97 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.93e4 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 6.13e2 2.46e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.80e3 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PB 4σ 1.75e3 4.90e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.21e3 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PB 4σ 1.27e3 2.61e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.69e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 8.47e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2908, 6453 scc: 169-929 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 15 of 21 322 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 PCB-182 2.45e5 38.74 Abs. Int. 6.46e4 HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 8.98e2 3.23e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 2.28e5 38.74 0.00e0 RT Abs. Int. 5.93e4 HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 6.72e2 2.97e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.93e4 HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PB 4σ 2.02e3 9.67e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.17e3 HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PB 4σ 1.58e3 2.58e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.98e6 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 4.99e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8109, 3512 scc: 169-929 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:06 Printed: 30-Mar-2014 14:43 Page 16 of 21 323 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 3.24e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 9.49e2 1.62e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.71e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 8.53e2 1.35e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.39e3 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PB 4σ 2.10e3 3.20e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.33e3 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PB 4σ 9.21e2 3.67e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.13e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.06e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8707, 4180 scc: 169-929 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:06 Printed: 30-Mar-2014 14:43 Page 17 of 21 324 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 PCB-204 2.19e5 41.12 Rel. Int. 100% Abs. Int. 5.84e4 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 8.18e2 2.92e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 2.37e5 41.12 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.57e4 OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 6.22e2 2.78e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.85e3 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PB 4σ 1.37e3 4.43e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.87e3 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PB 4σ 1.30e3 2.44e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.98e6 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 4.99e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9729, 3686 scc: 169-929 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 18 of 21 325 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 2.07e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PB 4σ 7.61e2 1.04e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PB 4σ 8.15e2 9.62e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e4 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PB 4σ 1.05e3 5.52e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.28e3 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PB 4σ 8.88e2 1.64e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.13e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.06e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8709, 1281 scc: 169-929 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 19 of 21 326 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 2.54e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 1.21e3 1.27e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.53e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 1.86e3 2.26e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.27e3 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PB 4σ 9.25e2 2.14e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.81e3 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PB 4σ 7.65e2 1.91e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.13e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.06e6 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8481, 7185 scc: 169-929 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 20 of 21 327 of 622 SGS-AP ID: SBS_140327_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 27-Mar-2014 12:27:58 User: LKB Datafile: 140327X03 Rel. Int. 100% Abs. Int. 1.54e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: PB 4σ 6.26e2 7.72e2 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.34e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: PB 4σ 6.41e2 1.17e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.99e3 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PB 4σ 8.78e2 1.99e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.35e3 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PB 4σ 9.08e2 1.67e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.93e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 9.63e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\SBS_140327_PCB_XA.utp_res, saved 27-Mar-2014 14:06 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9362, 0030 scc: 169-929 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 14:05 (LKB) Printed: 30-Mar-2014 14:43 Page 21 of 21 Experiment Calibration Report 328 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 1 @ 200 (ppm) Printed: Thursday, March 27, 2014 10:34:22 Eastern Daylight Time M 180.9888 R 12437 M 204.9888 R 12496 242.8 M 218.9856 R 12885 180.9 1.00e0 x19 M 230.9856 R 11961 204.9 1.00e0 x19 218.9 1.00e0 x19 1.00e0 x19 0.550 0.950 0.028 0.500 0.900 0.500 0.026 0.850 0.450 0.800 0.024 0.450 0.750 0.400 0.022 0.400 0.700 0.650 0.020 0.600 0.018 0.350 0.350 0.300 0.550 0.016 0.300 0.500 0.450 0.014 0.400 0.012 0.250 0.250 0.200 0.350 0.200 0.010 0.300 0.150 0.008 0.250 0.200 0.006 0.150 0.100 0.100 0.150 0.004 0.100 0.050 0.050 0.002 0.050 -0.000 180.88 180.89 180.90 180.91 204.86 M 242.9856 R 11467 230.9 1.00e0 x19 0.130 0.120 0.110 0.100 0.090 0.080 0.070 0.060 0.050 0.040 0.030 0.020 0.010 242.82 242.83 242.84 242.85 242.86 204.87 204.88 204.89 218.85 218.86 218.87 218.88 230.83 230.84 230.85 230.86 230.87 Experiment Calibration Report 329 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 2 @ 200 (ppm) Printed: Thursday, March 27, 2014 10:34:37 Eastern Daylight Time M 218.9856 R 13157 M 230.9856 R 12136 304.8 M 242.9856 R 12192 218.9 1.00e0 x19 M 254.9856 R 12564 230.9 1.00e0 x19 242.9 1.00e0 x19 1.00e0 x19 0.130 0.500 0.050 0.475 0.500 0.120 0.450 0.110 0.450 0.045 0.425 0.400 0.040 0.100 0.375 0.400 0.350 0.090 0.035 0.350 0.325 0.080 0.300 0.030 0.300 0.275 0.070 0.250 0.025 0.250 0.225 0.060 0.200 0.020 0.050 0.200 0.175 0.040 0.150 0.015 0.150 0.125 0.030 0.100 0.010 0.100 0.020 0.075 0.050 0.005 0.050 0.010 0.025 -0.000 218.87 218.88 218.89 218.90 218.91 230.86 M 268.9824 R 12820 230.87 230.88 230.89 230.90 242.85 M 280.9824 R 12198 254.9 242.86 242.87 x19 0.170 -0.000 254.84 242.89 M 292.9824 R 11364 268.9 1.00e0 0.180 242.88 254.85 254.86 x19 0.280 0.090 0.160 254.89 292.8 1.00e0 0.095 254.88 M 304.9824 R 12825 280.8 1.00e0 0.300 254.87 x19 1.00e0 x19 0.040 0.085 0.260 0.035 0.150 0.080 0.240 0.140 0.130 0.220 0.120 0.200 0.075 0.030 0.070 0.065 0.060 0.110 0.025 0.180 0.055 0.100 0.160 0.050 0.140 0.045 0.090 0.020 0.080 0.040 0.120 0.070 0.015 0.035 0.060 0.100 0.050 0.030 0.080 0.025 0.040 0.010 0.020 0.060 0.030 0.015 0.040 0.005 0.020 0.010 0.020 0.010 0.005 -0.000 -0.000 268.83 268.84 268.85 268.86 268.87 280.82 280.83 280.84 280.85 280.86 280.87 -0.000 292.81 292.82 292.83 292.84 292.85 292.86 304.80 304.81 304.82 304.83 304.84 304.85 Experiment Calibration Report 330 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 3 @ 200 (ppm) Printed: Thursday, March 27, 2014 10:34:56 Eastern Daylight Time M 242.9856 R 12197 M 254.9856 R 11418 342.8 M 268.9824 R 12315 242.9 1.00e0 x19 M 280.9824 R 12192 254.9 1.00e0 x19 268.9 1.00e0 x19 0.180 0.050 0.130 1.00e0 x19 0.320 0.170 0.300 0.160 0.120 0.280 0.045 0.150 0.260 0.110 0.140 0.040 0.240 0.100 0.130 0.080 0.220 0.120 0.035 0.090 0.030 0.070 0.110 0.200 0.100 0.180 0.090 0.160 0.025 0.080 0.060 0.140 0.070 0.020 0.050 0.120 0.060 0.100 0.040 0.015 0.050 0.080 0.040 0.030 0.010 0.060 0.030 0.020 0.040 0.020 0.005 0.010 0.020 0.010 -0.000 -0.000 242.87 242.88 242.89 242.90 -0.000 242.91 254.86 M 292.9824 R 12627 254.87 254.88 254.89 268.85 M 304.9824 R 11909 280.9 -0.000 254.90 268.86 268.87 x19 268.89 280.84 M 316.9824 R 13589 292.9 1.00e0 268.88 280.85 280.86 x19 280.88 M 330.9792 R 11415 304.8 1.00e0 0.120 280.87 316.8 1.00e0 x19 1.00e0 x19 0.022 0.050 0.150 0.110 0.020 0.140 0.045 0.100 0.130 0.018 0.040 0.120 0.090 0.016 0.110 0.035 0.080 0.100 0.014 0.070 0.030 0.090 0.012 0.080 0.060 0.025 0.010 0.070 0.050 0.020 0.060 0.008 0.040 0.050 0.015 0.006 0.040 0.030 0.010 0.030 0.004 0.020 0.020 0.005 0.010 0.002 0.010 -0.000 -0.000 292.83 292.84 292.85 292.86 292.87 292.88 M 342.9792 R 11315 330.8 1.00e0 x19 0.060 0.055 0.050 0.045 0.040 0.035 0.030 0.025 0.020 0.015 0.010 0.005 -0.000 342.79 342.80 342.81 342.82 342.83 342.84 342.85 -0.000 304.82 304.83 304.84 304.85 304.86 304.87 -0.000 316.81 316.82 316.83 316.84 316.85 316.86 330.80 330.81 330.82 330.83 330.84 330.85 Experiment Calibration Report 331 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 4 @ 200 (ppm) Printed: Thursday, March 27, 2014 10:35:18 Eastern Daylight Time M 280.9824 R 12374 M 292.9824 R 11963 430.8 M 304.9824 R 11681 280.9 1.00e0 x19 M 316.9824 R 13023 292.9 1.00e0 x19 304.9 1.00e0 x19 1.00e0 x19 0.110 0.320 0.020 0.055 0.300 0.100 0.280 0.050 0.018 0.045 0.016 0.090 0.260 0.240 0.080 0.040 0.014 0.220 0.070 0.200 0.035 0.012 0.180 0.060 0.030 0.160 0.010 0.050 0.025 0.140 0.008 0.120 0.040 0.020 0.100 0.006 0.030 0.015 0.020 0.010 0.010 0.005 0.080 0.060 0.004 0.040 0.002 0.020 -0.000 -0.000 280.85 280.86 280.87 280.88 -0.000 280.89 292.84 M 330.9792 R 12020 292.85 292.86 292.87 292.88 304.83 M 342.9792 R 11960 316.8 -0.000 292.89 304.84 304.85 x19 0.160 0.017 0.065 0.130 0.060 0.120 0.055 316.83 316.84 316.86 316.87 1.00e0 x19 0.090 0.085 0.080 0.015 0.075 0.014 0.070 0.013 0.065 0.012 0.060 0.011 0.055 0.010 0.050 0.040 0.009 0.045 0.035 0.008 0.040 0.007 0.035 0.006 0.030 0.005 0.025 0.004 0.020 0.003 0.015 0.045 316.85 366.8 x19 0.016 0.050 0.100 316.82 M 380.9760 R 11790 1.00e0 0.075 0.140 0.110 x19 0.018 0.150 304.88 342.8 1.00e0 0.080 0.070 304.87 M 366.9792 R 12754 330.8 1.00e0 0.170 304.86 0.090 0.080 0.070 0.030 0.060 0.025 0.050 0.020 0.040 0.015 0.030 0.020 0.010 0.010 0.005 -0.000 0.002 -0.000 330.81 330.82 330.83 330.84 330.85 0.005 -0.000 330.86 342.80 M 392.9760 R 11624 0.010 0.001 342.81 342.82 342.83 342.84 342.85 366.78 M 404.9760 R 12437 380.8 -0.000 342.86 366.79 366.80 366.81 x19 366.83 366.84 380.77 M 430.9728 R 11733 392.8 1.00e0 404.8 1.00e0 x19 0.020 0.034 366.82 1.00e0 x19 0.036 0.034 0.032 0.018 0.032 0.030 0.030 0.028 0.016 0.028 0.026 0.026 0.024 0.014 0.024 0.022 0.022 0.012 0.020 0.020 0.018 0.010 0.018 0.016 0.016 0.014 0.008 0.014 0.012 0.012 0.006 0.010 0.010 0.008 0.008 0.004 0.006 0.006 0.004 0.004 0.002 0.002 0.002 -0.000 -0.000 392.76 392.77 392.78 392.79 392.80 392.81 392.82 392.83 -0.000 404.76 404.77 404.78 404.79 404.80 404.81 404.82 404.83 430.75 430.76 430.77 430.78 430.79 430.80 430.81 430.82 430.83 380.78 380.79 380.80 380.81 380.82 380.83 Experiment Calibration Report 332 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 5 @ 200 (ppm) Printed: Thursday, March 27, 2014 10:35:43 Eastern Daylight Time M 316.9824 R 12628 M 330.9792 R 12019 442.7 M 342.9792 R 12252 316.8 1.00e0 x19 x19 0.150 0.020 M 366.9792 R 11627 330.8 1.00e0 0.160 0.022 0.140 342.8 1.00e0 x19 1.00e0 0.080 0.019 0.075 0.018 x19 0.017 0.070 0.016 0.130 0.065 0.120 0.060 0.110 0.055 0.013 0.100 0.050 0.012 0.090 0.045 0.080 0.040 0.070 0.035 0.060 0.030 0.007 0.050 0.025 0.006 0.040 0.020 0.005 0.030 0.015 0.020 0.010 0.010 0.005 0.018 0.015 0.016 0.014 0.014 0.011 0.012 0.010 0.009 0.010 0.008 0.008 0.006 0.004 0.004 0.003 0.002 0.002 -0.000 -0.000 316.81 316.82 316.83 316.84 316.85 316.86 M 380.9760 R 12138 0.001 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 330.85 M 392.9760 R 12195 366.8 -0.000 342.78 342.79 342.80 x19 342.82 342.83 342.84 366.76 M 404.9760 R 11903 380.8 1.00e0 342.81 366.77 366.78 366.79 x19 366.81 366.82 366.83 M 430.9728 R 12375 392.8 1.00e0 366.80 404.8 1.00e0 x19 1.00e0 x19 0.028 0.100 0.050 0.095 0.026 0.040 0.090 0.045 0.024 0.085 0.080 0.035 0.022 0.040 0.075 0.020 0.070 0.035 0.030 0.018 0.065 0.060 0.030 0.016 0.025 0.055 0.014 0.050 0.025 0.020 0.045 0.012 0.040 0.020 0.010 0.035 0.015 0.030 0.015 0.008 0.025 0.010 0.006 0.020 0.010 0.015 0.004 0.005 0.010 0.005 0.002 0.005 -0.000 -0.000 380.75 380.76 380.77 380.78 380.79 380.80 380.81 M 442.9728 R 11208 430.7 1.00e0 x19 0.024 0.022 0.020 0.018 0.016 0.014 0.012 0.010 0.008 0.006 0.004 0.002 -0.000 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 -0.000 392.74 442.78 392.75 392.76 392.77 392.78 392.79 392.80 392.81 -0.000 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 430.78 Experiment Calibration Report 333 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 6 @ 200 (ppm) Printed: Thursday, March 27, 2014 10:36:04 Eastern Daylight Time M 380.9760 R 11850 M 392.9760 R 12690 480.7 M 404.9760 R 12440 380.8 1.00e0 x19 0.100 M 430.9728 R 12824 392.8 1.00e0 x19 404.7 1.00e0 x19 1.00e0 x19 0.045 0.028 0.095 0.090 0.050 0.026 0.040 0.085 0.045 0.024 0.080 0.035 0.075 0.040 0.022 0.070 0.020 0.035 0.030 0.065 0.018 0.060 0.055 0.030 0.025 0.016 0.050 0.014 0.045 0.025 0.020 0.012 0.040 0.020 0.035 0.010 0.015 0.030 0.015 0.008 0.025 0.010 0.006 0.020 0.015 0.010 0.004 0.005 0.010 0.005 0.002 0.005 -0.000 -0.000 380.73 380.74 380.75 380.76 380.77 380.78 380.79 -0.000 380.80 392.72 M 442.9728 R 11906 392.73 392.74 392.75 392.76 392.77 392.78 404.71 M 454.9728 R 11792 430.7 -0.000 392.79 404.72 404.73 404.74 x19 404.76 404.77 404.78 430.68 M 466.9728 R 12753 442.7 1.00e0 404.75 430.69 430.70 430.71 430.72 x19 430.75 430.76 466.7 1.00e0 x19 0.030 1.00e0 x19 0.034 0.011 0.022 430.74 M 480.9696 R 11733 454.7 1.00e0 430.73 0.028 0.032 0.026 0.020 0.010 0.018 0.009 0.016 0.008 0.014 0.007 0.012 0.006 0.010 0.005 0.008 0.004 0.006 0.003 0.004 0.002 0.002 0.001 0.030 0.028 0.024 0.026 0.022 0.024 0.020 0.022 0.018 0.020 0.016 0.018 0.014 0.016 0.014 0.012 0.010 0.012 0.010 0.008 0.008 0.006 0.006 0.004 0.004 0.002 0.002 -0.000 -0.000 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 442.75 -0.000 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 454.74 -0.000 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 466.73 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 480.71 480.72 Experiment Calibration Report 334 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 7 @ 200 (ppm) Printed: Thursday, March 27, 2014 10:36:29 Eastern Daylight Time M 430.9728 R 12504 M 442.9728 R 12197 516.7 M 454.9728 R 12563 430.7 1.00e0 x19 M 466.9728 R 12440 442.7 1.00e0 x19 454.7 1.00e0 x19 1.00e0 x19 0.012 0.060 0.030 0.022 0.011 0.028 0.055 0.020 0.026 0.010 0.050 0.024 0.018 0.009 0.045 0.022 0.016 0.008 0.040 0.020 0.014 0.018 0.035 0.007 0.016 0.012 0.006 0.030 0.014 0.010 0.005 0.025 0.012 0.020 0.008 0.004 0.006 0.003 0.004 0.002 0.010 0.008 0.015 0.006 0.010 0.004 0.002 0.005 0.001 0.002 -0.000 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 -0.000 442.69 430.78 M 480.9696 R 12439 -0.000 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 M 492.9696 R 12566 466.7 -0.000 454.68 454.69 454.70 454.71 x19 454.73 454.74 454.75 454.76 466.67 M 504.9696 R 13018 480.7 1.00e0 454.72 466.68 466.69 466.70 466.71 x19 466.73 466.74 466.75 504.7 1.00e0 x19 1.00e0 x19 0.018 0.020 0.032 0.009 0.017 0.030 0.016 0.018 0.008 0.015 0.028 0.016 0.026 0.014 0.007 0.013 0.024 0.014 0.012 0.022 0.006 0.011 0.020 0.012 0.010 0.018 0.005 0.009 0.010 0.016 0.008 0.004 0.014 0.008 0.007 0.012 0.006 0.010 0.006 0.003 0.005 0.008 0.004 0.002 0.004 0.006 0.003 0.004 0.002 0.002 0.002 0.001 0.001 -0.000 -0.000 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 480.74 -0.000 492.65 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 492.74 -0.000 504.64 504.65 504.66 504.67 504.68 466.76 M 516.9697 R 12626 492.7 1.00e0 0.034 466.72 504.69 504.70 504.71 504.72 504.73 516.63 516.64 516.65 516.66 516.67 516.68 516.69 516.70 516.71 Resolution Check Report Printed: 335 of 622 Page 1 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 21:51:39 Eastern Daylight Time M 180.9888 R 11603 M 204.9888 R 12646 180.9 M 218.9856 R 11631 204.9 1.00e0 x19 M 230.9856 R 11337 218.9 1.00e0 x19 230.9 1.00e0 x19 1.00e0 x19 1.300 1.100 2.000 0.050 1.800 0.045 1.600 0.040 1.200 1.000 1.100 0.900 1.000 0.900 0.800 0.800 0.700 1.400 0.035 1.200 0.030 1.000 0.025 0.600 0.800 0.020 0.500 0.600 0.015 0.400 0.010 0.700 0.600 0.500 0.400 0.400 0.300 0.300 0.200 0.200 0.200 0.005 -0.000 -0.000 180.88 180.89 180.90 -0.000 180.91 204.87 M 242.9856 R 11467 0.100 0.100 204.88 204.89 218.85 M 218.9856 R 12019 242.9 -0.000 204.90 218.86 218.87 x19 218.89 M 230.9856 R 11848 218.9 1.00e0 230.84 230.85 230.86 x19 230.87 230.88 M 242.9856 R 11501 230.9 1.00e0 242.9 1.00e0 x19 1.00e0 x19 1.200 1.300 0.240 218.88 0.260 0.220 1.200 1.100 1.100 1.000 0.240 0.200 0.220 1.000 0.900 0.180 0.200 0.900 0.800 0.160 0.180 0.800 0.140 0.700 0.160 0.600 0.140 0.700 0.120 0.600 0.120 0.500 0.100 0.500 0.100 0.400 0.080 0.400 0.080 0.300 0.060 0.300 0.060 0.200 0.040 0.200 0.020 0.100 0.100 -0.000 -0.000 218.87 -0.000 242.83 242.84 242.85 242.86 242.87 M 254.9856 R 11709 0.040 218.88 218.89 218.90 218.91 230.87 M 268.9824 R 11834 254.9 0.020 -0.000 230.88 x19 230.90 242.86 M 280.9824 R 11160 268.9 1.00e0 230.89 242.87 x19 242.89 M 292.9824 R 11286 280.8 1.00e0 242.88 292.8 1.00e0 x19 1.00e0 x19 0.190 0.450 0.090 0.180 0.650 0.425 0.085 0.170 0.400 0.600 0.080 0.160 0.375 0.550 0.075 0.150 0.350 0.070 0.140 0.500 0.325 0.065 0.130 0.300 0.450 0.060 0.120 0.275 0.055 0.400 0.110 0.250 0.050 0.100 0.350 0.225 0.045 0.090 0.200 0.040 0.300 0.080 0.175 0.035 0.070 0.250 0.150 0.030 0.060 0.200 0.025 0.125 0.020 0.100 0.015 0.075 0.010 0.050 0.005 0.025 -0.000 0.050 0.150 254.86 254.87 254.88 254.89 0.030 0.020 0.050 0.010 -0.000 254.85 0.040 0.100 268.83 268.84 268.85 268.86 268.87 268.88 -0.000 280.82 -0.000 280.83 280.84 280.85 280.86 280.87 292.82 292.83 292.84 292.85 292.86 292.87 Resolution Check Report Printed: 336 of 622 Page 2 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 21:51:39 Eastern Daylight Time M 304.9824 R 11767 M 242.9856 R 12019 304.8 M 254.9856 R 11850 242.9 1.00e0 x19 M 268.9824 R 12023 254.9 1.00e0 x19 0.070 0.280 0.065 268.9 1.00e0 x19 0.450 0.095 0.425 0.090 0.260 x19 0.400 0.085 0.060 1.00e0 0.100 0.375 0.240 0.080 0.350 0.055 0.220 0.075 0.325 0.050 0.070 0.200 0.300 0.065 0.045 0.180 0.040 0.160 0.035 0.275 0.060 0.055 0.250 0.050 0.225 0.045 0.200 0.140 0.030 0.025 0.120 0.040 0.100 0.035 0.175 0.150 0.030 0.020 0.125 0.080 0.025 0.015 0.060 0.010 0.040 0.100 0.020 0.075 0.015 0.050 0.010 0.005 0.020 0.025 0.005 -0.000 -0.000 304.81 304.82 304.83 304.84 304.85 -0.000 304.86 242.87 M 280.9824 R 11962 242.88 242.89 242.90 254.86 M 292.9824 R 11794 280.9 -0.000 242.91 254.87 254.88 x19 254.90 268.85 M 304.9824 R 12217 292.9 1.00e0 254.89 268.86 x19 268.88 268.89 M 316.9824 R 11554 304.8 1.00e0 268.87 316.8 1.00e0 x19 1.00e0 x19 0.090 0.700 0.220 0.036 0.085 0.650 0.034 0.080 0.200 0.032 0.600 0.075 0.030 0.180 0.550 0.070 0.028 0.500 0.065 0.160 0.026 0.060 0.024 0.450 0.140 0.055 0.022 0.400 0.050 0.020 0.120 0.350 0.045 0.018 0.040 0.100 0.300 0.016 0.035 0.250 0.014 0.080 0.200 0.060 0.150 0.040 0.030 0.012 0.025 0.010 0.020 0.008 0.015 0.006 0.100 0.010 0.004 0.020 0.050 0.005 -0.000 -0.000 280.84 280.85 280.86 280.87 280.88 M 330.9792 R 10893 0.002 -0.000 280.89 292.83 292.84 292.85 292.86 292.87 292.88 M 342.9792 R 11471 330.8 -0.000 304.82 304.83 304.84 x19 304.86 304.87 316.81 M 280.9824 R 12199 342.8 1.00e0 304.85 316.82 316.83 x19 316.85 316.86 316.87 M 292.9824 R 11684 280.9 1.00e0 316.84 292.9 1.00e0 x19 1.00e0 x19 0.750 0.320 0.220 0.110 0.700 0.300 0.100 0.280 0.260 0.200 0.650 0.600 0.090 0.240 0.180 0.550 0.160 0.080 0.220 0.500 0.200 0.070 0.140 0.450 0.180 0.400 0.060 0.120 0.160 0.350 0.100 0.050 0.140 0.300 0.120 0.040 0.080 0.250 0.100 0.200 0.030 0.080 0.060 0.150 0.060 0.040 0.020 0.100 0.040 0.010 0.020 0.050 0.020 -0.000 -0.000 330.80 330.81 330.82 330.83 330.84 330.85 330.86 -0.000 342.80 342.81 342.82 342.83 342.84 342.85 342.86 -0.000 280.85 280.86 280.87 280.88 280.89 280.90 292.84 292.85 292.86 292.87 292.88 292.89 Resolution Check Report Printed: 337 of 622 Page 3 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 21:51:39 Eastern Daylight Time M 304.9824 R 12106 M 316.9824 R 12109 304.9 M 330.9792 R 11585 316.9 1.00e0 x19 M 342.9792 R 11451 330.8 1.00e0 x19 342.8 1.00e0 x19 0.036 0.100 1.00e0 0.400 0.150 0.375 0.140 0.350 0.130 0.325 0.120 0.300 0.110 x19 0.034 0.090 0.032 0.030 0.080 0.028 0.026 0.070 0.060 0.024 0.275 0.022 0.250 0.020 0.225 0.100 0.090 0.080 0.018 0.050 0.200 0.070 0.016 0.040 0.175 0.060 0.014 0.150 0.012 0.050 0.125 0.030 0.010 0.040 0.100 0.008 0.020 -0.000 304.84 304.85 304.86 304.87 304.88 0.002 0.025 0.010 -0.000 -0.000 -0.000 304.89 M 366.9792 R 12311 0.020 0.050 0.004 0.010 0.030 0.075 0.006 316.83 316.84 316.85 316.86 316.87 316.88 330.81 M 380.9760 R 11389 366.8 330.82 330.83 330.84 x19 330.86 330.87 342.81 M 392.9760 R 11069 380.8 1.00e0 330.85 342.82 342.83 x19 342.85 342.86 M 404.9760 R 11720 392.8 1.00e0 342.84 404.8 1.00e0 x19 1.00e0 x19 0.075 0.036 0.200 0.030 0.070 0.034 0.028 0.180 0.065 0.032 0.026 0.030 0.060 0.160 0.024 0.028 0.055 0.022 0.026 0.140 0.050 0.024 0.020 0.045 0.022 0.040 0.020 0.120 0.018 0.016 0.018 0.100 0.035 0.014 0.016 0.030 0.080 0.012 0.014 0.025 0.012 0.008 0.020 0.010 0.006 0.015 0.010 0.060 0.040 0.008 0.006 0.010 0.004 0.004 0.020 0.005 0.002 -0.000 -0.000 366.79 366.80 366.81 366.82 366.83 366.84 380.78 M 430.9728 R 11171 0.002 -0.000 366.85 380.79 380.80 380.81 380.82 380.83 380.84 M 316.9824 R 12775 430.8 -0.000 392.77 392.78 392.79 392.80 x19 0.090 0.085 0.080 392.83 392.84 404.78 404.79 404.80 x19 0.380 0.360 0.036 0.340 404.82 404.83 404.84 404.85 342.8 1.00e0 0.038 404.81 M 342.9792 R 11881 330.8 1.00e0 0.040 x19 1.00e0 x19 0.160 0.034 0.150 0.140 0.320 0.075 0.032 0.070 0.030 0.065 392.82 M 330.9792 R 11905 316.8 1.00e0 392.81 0.300 0.130 0.280 0.120 0.028 0.260 0.060 0.110 0.026 0.240 0.055 0.100 0.024 0.220 0.050 0.022 0.090 0.200 0.045 0.020 0.040 0.018 0.080 0.180 0.160 0.070 0.140 0.060 0.016 0.035 0.014 0.030 0.120 0.012 0.025 0.020 0.008 0.080 0.006 0.060 0.010 0.004 0.040 0.005 0.002 0.020 0.015 -0.000 430.78 430.79 430.80 430.81 430.82 430.83 430.84 0.040 0.030 -0.000 430.77 0.050 0.100 0.010 0.020 0.010 -0.000 316.82 316.83 316.84 316.85 316.86 316.87 -0.000 330.80 330.81 330.82 330.83 330.84 330.85 330.86 342.79 342.80 342.81 342.82 342.83 342.84 342.85 Resolution Check Report Printed: 338 of 622 Page 4 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 21:51:39 Eastern Daylight Time M 366.9792 R 12322 M 380.9760 R 11406 366.8 M 392.9760 R 11749 380.8 1.00e0 x19 M 404.9760 R 11628 392.8 1.00e0 x19 404.8 1.00e0 x19 1.00e0 x19 0.240 0.095 0.030 0.045 0.090 0.220 0.028 0.085 0.200 0.026 0.040 0.080 0.075 0.024 0.180 0.035 0.070 0.022 0.065 0.160 0.020 0.030 0.060 0.140 0.018 0.016 0.055 0.025 0.050 0.120 0.045 0.014 0.100 0.020 0.040 0.012 0.035 0.080 0.010 0.015 0.030 0.008 0.025 0.060 0.010 0.020 0.006 0.040 0.015 0.004 0.005 0.010 0.020 0.002 0.005 -0.000 -0.000 366.77 366.78 366.79 366.80 366.81 366.82 -0.000 366.83 380.76 M 430.9728 R 11991 380.77 380.78 380.79 380.80 380.81 392.75 M 442.9728 R 11189 430.8 -0.000 380.82 392.76 392.77 392.78 x19 392.80 392.81 392.82 M 380.9760 R 11990 442.8 1.00e0 392.79 404.74 404.75 404.76 404.77 x19 404.79 404.80 404.81 M 392.9760 R 12317 380.8 1.00e0 404.78 392.8 1.00e0 x19 1.00e0 x19 0.090 0.120 0.240 0.050 0.085 0.110 0.080 0.220 0.045 0.075 0.100 0.200 0.070 0.040 0.090 0.180 0.065 0.060 0.035 0.080 0.160 0.055 0.070 0.030 0.140 0.025 0.120 0.060 0.050 0.045 0.040 0.050 0.100 0.035 0.020 0.040 0.030 0.080 0.015 0.025 0.030 0.060 0.020 0.010 0.020 0.015 0.040 0.010 0.005 0.010 0.020 0.005 -0.000 -0.000 430.72 430.73 430.74 430.75 430.76 430.77 430.78 430.79 -0.000 442.71 M 404.9760 R 12671 442.72 442.73 442.74 442.75 442.76 442.77 442.78 442.79 M 430.9728 R 11783 404.8 -0.000 380.74 380.75 380.76 380.77 x19 x19 0.110 0.100 0.040 0.090 380.81 392.73 392.74 392.75 392.76 392.77 392.78 392.79 392.80 M 454.9728 R 12383 454.7 1.00e0 x19 1.00e0 x19 0.045 0.120 0.045 380.80 442.7 1.00e0 0.050 380.79 M 442.9728 R 11757 430.7 1.00e0 0.055 380.78 0.060 0.055 0.040 0.050 0.035 0.045 0.030 0.080 0.040 0.035 0.070 0.035 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.010 0.005 0.025 0.030 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 -0.000 404.72 404.73 404.74 404.75 404.76 404.77 404.78 404.79 -0.000 430.69 -0.000 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 -0.000 442.68 442.69 442.70 442.71 442.72 442.73 442.74 442.75 442.76 454.67 454.68 454.69 454.70 454.71 454.72 454.73 454.74 454.75 Resolution Check Report Printed: 339 of 622 Page 5 of 5 MassLynx 4.1 SCN 881 Thursday, March 27, 2014 21:51:39 Eastern Daylight Time M 466.9728 R 12136 M 480.9696 R 11389 466.7 M 430.9728 R 11932 480.7 1.00e0 x19 M 442.9728 R 12544 430.8 1.00e0 x19 442.7 1.00e0 x19 1.00e0 x19 0.085 0.140 0.080 0.020 0.018 0.075 0.130 0.070 0.120 0.060 0.055 0.050 0.065 0.110 0.016 0.045 0.060 0.100 0.014 0.055 0.040 0.090 0.050 0.012 0.010 0.008 0.035 0.080 0.045 0.040 0.070 0.035 0.060 0.030 0.030 0.025 0.050 0.020 0.025 0.006 0.040 0.015 0.020 0.030 0.004 0.015 0.010 0.020 0.010 0.002 -0.000 -0.000 466.66 466.67 466.68 466.69 466.70 466.71 466.72 466.73 466.74 -0.000 466.75 M 454.9728 R 12251 0.005 0.010 0.005 480.65 480.66 480.67 480.68 480.69 480.70 480.71 480.72 430.72 M 466.9728 R 14200 454.7 -0.000 480.73 430.73 430.74 430.75 430.76 x19 430.78 430.79 430.80 M 480.9696 R 11876 466.7 1.00e0 430.77 442.71 442.72 442.73 442.74 x19 442.76 442.77 442.78 442.79 M 492.9696 R 12297 480.7 1.00e0 0.045 442.75 492.7 1.00e0 x19 1.00e0 x19 0.080 0.028 0.045 0.075 0.026 0.040 0.070 0.040 0.024 0.065 0.035 0.022 0.035 0.060 0.020 0.055 0.030 0.025 0.030 0.018 0.050 0.016 0.045 0.014 0.040 0.025 0.020 0.035 0.012 0.020 0.030 0.010 0.015 0.015 0.025 0.008 0.020 0.010 0.010 0.006 0.015 0.004 0.010 0.005 0.002 -0.000 454.71 454.72 454.73 454.74 454.75 454.76 454.77 -0.000 454.78 M 504.9696 R 12334 466.69 466.70 466.71 466.72 466.73 466.74 466.75 466.76 466.77 516.7 x19 1.00e0 x19 0.019 0.032 0.018 0.030 0.017 0.028 0.016 0.026 0.015 0.024 0.014 0.022 0.013 0.012 0.020 0.011 0.018 0.010 0.016 0.009 0.014 0.008 0.012 0.007 0.010 0.006 0.005 0.008 0.004 0.006 0.003 0.004 0.002 0.002 0.001 -0.000 -0.000 504.65 504.66 504.67 504.68 504.69 504.70 504.71 504.72 504.73 504.74 516.64 516.65 516.66 516.67 516.68 516.69 516.70 516.71 516.72 516.73 -0.000 480.67 M 516.9697 R 12695 504.7 1.00e0 0.005 0.005 -0.000 454.70 480.68 480.69 480.70 480.71 480.72 480.73 480.74 480.75 480.76 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 492.74 492.75 PCB ICAL PAGE RANGE: 340 TO 594 PCB ICAL Summary 340 of 622 Printed: 3 Jan 2014 16:53 SGS Analytical Perspectives ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 Date Processed: 3 Jan 2014 16:52 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB Mean 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 % RSD 4.1% 3.1% 5.1% 4.8% 4.2% 2.4% 5.8% 4.0% 4.0% 3.5% 5.0% 3.9% 131220X02 0.5 CS0 1.17 1.08 1.13 1.14 1.20 1.20 1.05 1.07 1.11 1.12 1.08 1.18 131220X03 1 CS1 1.11 1.13 1.02 1.16 1.13 1.20 1.07 1.07 1.13 1.07 1.00 1.10 131220X04 5 CS2 1.09 1.08 1.07 1.15 1.13 1.16 1.05 1.05 1.12 1.09 1.03 1.06 131220X05 50 CS3 1.14 1.12 1.13 1.23 1.22 1.23 1.12 1.12 1.20 1.16 1.07 1.09 131220X06 400 CS4 1.17 1.14 1.15 1.24 1.22 1.23 1.14 1.11 1.18 1.14 1.10 1.10 131220X08 2000 CS5 1.22 1.17 1.18 1.29 1.25 1.25 1.21 1.17 1.23 1.17 1.16 1.15 3.7% 2.3% 0.7% 1.1% 1.4% 1.8% 1.0% 1.8% 2.5% 1.7% 2.5% 2.3% 2.4% 1.2% 3.2% 1.4% 3.0% 2.0% 2.0% 2.3% 1.9% 3.6% 1.9% 1.1% 1.2% 0.9% 1.4% 1.25 1.12 0.52 1.04 0.50 1.69 0.86 1.38 1.37 0.82 1.22 1.24 1.19 1.19 1.07 1.14 1.66 1.60 1.68 1.54 0.92 1.11 0.97 1.61 0.96 1.24 0.83 1.22 1.09 0.52 1.04 0.50 1.64 0.86 1.37 1.35 0.80 1.21 1.22 1.17 1.20 1.02 1.11 1.60 1.57 1.65 1.53 0.93 1.10 0.93 1.57 0.96 1.23 0.82 1.21 1.10 0.53 1.05 0.51 1.68 0.88 1.42 1.36 0.82 1.25 1.26 1.19 1.20 1.07 1.13 1.63 1.63 1.71 1.58 0.96 1.13 0.96 1.60 0.99 1.26 0.85 1.18 1.06 0.52 1.02 0.50 1.61 0.85 1.34 1.32 0.80 1.18 1.19 1.13 1.16 0.99 1.10 1.56 1.56 1.62 1.51 0.95 1.11 0.92 1.57 0.97 1.24 0.83 1.17 1.08 0.52 1.05 0.51 1.66 0.86 1.38 1.38 0.79 1.18 1.21 1.14 1.19 1.01 1.11 1.56 1.64 1.70 1.60 0.95 1.16 0.93 1.57 0.97 1.25 0.83 1.13 1.06 0.53 1.05 0.52 1.69 0.85 1.40 1.42 0.78 1.17 1.19 1.14 1.18 1.01 1.10 1.52 1.61 1.65 1.58 0.97 1.21 0.93 1.58 0.97 1.25 0.82 PCB ICAL PAGE RANGE: 340 TO 594 PCB ICAL Summary 341 of 622 Printed: 3 Jan 2014 16:53 SGS Analytical Perspectives ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 131220X03 1 CS1 1.16 1.10 131220X04 5 CS2 1.20 1.14 131220X05 50 CS3 1.17 1.11 131220X06 400 CS4 1.18 1.11 131220X08 2000 CS5 1.19 1.08 Name ES PCB-208 ES PCB-209 Mean 1.17 1.11 % RSD 1.4% 1.9% 131220X02 0.5 CS0 1.16 1.12 SS PCB-28 SS PCB-111 SS PCB-178 1.11 1.03 0.62 1.2% 1.6% 2.7% 1.12 1.04 0.64 1.12 1.02 0.61 1.11 1.03 0.61 1.12 1.05 0.61 1.11 1.00 0.61 1.09 1.03 0.64 CS PCB-28 CS PCB-111 CS PCB-178 1.85 1.22 0.58 1.4% 1.4% 3.7% 1.89 1.24 0.62 1.84 1.22 0.57 1.86 1.23 0.58 1.81 1.22 0.56 1.84 1.19 0.57 1.83 1.21 0.60 PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-153/168 ...-HxCB PCB-155 22'44'66'-HxCB PCB-170 22'33'44'5-HpCB PCB-180/193 ...-HpCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.46 1.26 1.14 1.26 1.27 1.05 1.06 1.12 1.11 3.4% 2.9% 3.8% 3.8% 2.5% 4.7% 2.1% 1.5% 3.7% 2.3% 6.1% 2.7% 3.1% 3.2% 4.0% 3.8% 3.0% 0.99 1.00 1.17 1.01 1.13 1.02 1.40 1.44 1.38 1.23 1.09 1.26 1.23 1.05 1.07 1.09 1.09 0.94 0.98 1.20 0.98 1.12 1.05 1.34 1.41 1.42 1.25 1.06 1.22 1.32 1.05 1.03 1.11 1.11 0.92 0.98 1.20 0.98 1.12 1.05 1.31 1.40 1.43 1.23 1.09 1.23 1.22 1.00 1.01 1.07 1.08 0.97 1.04 1.27 1.03 1.17 1.10 1.36 1.45 1.48 1.27 1.15 1.27 1.26 1.06 1.06 1.13 1.11 0.98 1.05 1.27 1.04 1.16 1.10 1.35 1.45 1.50 1.29 1.19 1.27 1.28 1.06 1.07 1.14 1.12 0.91 1.00 1.29 1.08 1.19 1.16 1.36 1.46 1.53 1.29 1.24 1.31 1.31 1.10 1.13 1.19 1.18 342 of 622 PCB ICAL Summary - Ax2 Detail SGS Analytical Perspectives Printed: 3 Jan 2014 16:53 ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB Mean 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 % RSD 3.4% 3.8% 2.9% 3.8% 3.9% 2.8% 5.7% 4.5% 4.8% 3.2% 3.9% 4.5% 6.8% 3.8% 2.5% 3.5% 4.4% 3.6% 3.4% 4.3% 2.4% 3.0% 4.1% 3.0% 2.6% 3.3% 3.6% 3.3% 2.8% 4.4% 4.1% 3.7% 4.6% 4.7% 2.1% 2.7% 5.4% 5.9% 2.5% 1.7% 0.5 CS0 0.99 1.02 1.00 1.17 1.91 0.93 0.95 0.97 1.03 1.07 1.14 0.98 0.88 1.01 1.13 1.49 1.23 1.77 1.67 0.99 1.90 1.11 1.20 1.15 1.13 1.25 1.13 1.15 1.08 1.13 1.18 1.07 1.01 1.02 1.40 0.89 0.78 0.80 0.70 0.85 1 CS1 0.94 1.01 0.98 1.20 1.90 0.95 1.03 0.94 0.92 0.99 1.14 0.95 0.96 0.98 1.12 1.47 1.28 1.76 1.69 0.94 1.91 1.09 1.09 1.14 1.14 1.16 1.08 1.14 1.05 1.12 1.16 1.08 0.98 1.05 1.34 0.85 0.76 0.82 0.68 0.83 5 CS2 0.92 0.98 0.98 1.20 1.93 0.90 1.02 0.96 0.96 1.00 1.15 0.99 0.97 0.98 1.12 1.51 1.27 1.77 1.67 1.00 1.85 1.11 1.10 1.13 1.13 1.19 1.08 1.13 1.04 1.13 1.16 1.06 1.00 1.05 1.31 0.84 0.70 0.89 0.68 0.82 50 CS3 0.97 1.08 1.04 1.27 2.05 0.96 1.09 1.03 1.02 1.04 1.20 1.03 1.02 1.03 1.17 1.57 1.33 1.83 1.74 1.00 1.93 1.15 1.18 1.20 1.18 1.26 1.17 1.21 1.09 1.19 1.24 1.14 1.08 1.10 1.36 0.90 0.74 0.93 0.72 0.86 400 CS4 0.98 1.08 1.05 1.27 2.04 0.96 1.08 1.03 1.02 1.03 1.21 1.04 1.03 1.04 1.16 1.59 1.34 1.87 1.73 1.05 1.93 1.18 1.19 1.21 1.18 1.24 1.17 1.21 1.10 1.21 1.25 1.16 1.07 1.10 1.35 0.89 0.78 0.88 0.71 0.85 2000 CS5 0.91 1.02 1.00 1.29 2.06 0.97 1.11 1.05 1.05 1.07 1.25 1.07 1.07 1.08 1.19 1.60 1.38 1.92 1.83 1.06 1.99 1.16 1.17 1.21 1.18 1.25 1.17 1.21 1.12 1.24 1.27 1.11 1.10 1.16 1.36 0.89 0.83 0.84 0.71 0.85 343 of 622 PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB 1.11 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 1.16 4.0% 4.5% 3.4% 3.5% 3.3% 3.7% 2.8% 4.3% 3.9% 3.9% 2.1% 2.7% 2.6% 2.9% 1.9% 3.1% 2.4% 3.3% 2.3% 2.9% 1.8% 2.3% 2.5% 4.2% 1.5% 4.7% 2.7% 3.3% 3.9% 3.5% 6.3% 8.5% 11.9% 10.7% 4.5% 3.8% 3.2% 2.3% 2.4% 4.0% 6.0% 3.9% 3.2% 6.9% 6.2% 6.3% 4.4% 1.13 0.68 0.99 0.83 0.89 1.13 0.76 0.68 0.84 1.17 1.19 1.26 1.18 1.17 1.23 1.30 1.20 1.06 1.09 1.13 1.13 1.30 1.26 1.04 1.44 1.12 0.91 0.79 0.89 0.84 0.97 0.73 0.96 0.76 0.71 0.73 1.18 0.82 0.98 0.77 0.88 1.12 0.98 1.02 1.02 1.09 1.18 1.06 0.68 0.98 0.79 0.88 1.13 0.73 0.66 0.82 1.18 1.18 1.24 1.11 1.13 1.25 1.26 1.16 1.06 1.10 1.05 1.12 1.29 1.33 0.99 1.41 1.24 0.91 0.76 0.80 0.83 0.93 0.68 0.72 0.95 0.66 0.74 1.15 0.81 0.96 0.70 0.88 1.12 0.94 1.15 0.87 1.07 1.11 1.06 0.72 0.99 0.83 0.86 1.13 0.75 0.69 0.83 1.18 1.19 1.24 1.16 1.15 1.23 1.24 1.16 1.09 1.12 1.10 1.11 1.28 1.28 1.04 1.40 1.20 0.91 0.79 0.85 0.85 0.99 0.71 0.73 0.94 0.70 0.75 1.16 0.79 0.96 0.71 0.88 1.16 0.95 1.15 0.88 1.06 1.16 1.12 0.77 1.05 0.87 0.93 1.21 0.79 0.73 0.87 1.27 1.25 1.31 1.20 1.20 1.29 1.33 1.23 1.14 1.14 1.13 1.15 1.35 1.31 1.10 1.45 1.26 0.96 0.83 0.89 0.88 1.03 0.80 0.74 1.04 0.75 0.80 1.23 0.84 1.00 0.72 0.91 1.24 1.01 1.17 0.94 1.25 1.10 1.12 0.72 1.05 0.85 0.93 1.22 0.77 0.68 0.90 1.25 1.22 1.31 1.16 1.19 1.27 1.32 1.22 1.14 1.12 1.12 1.14 1.32 1.35 1.08 1.45 1.28 0.95 0.81 0.87 0.90 0.87 0.86 0.85 0.95 0.73 0.78 1.23 0.83 1.01 0.70 0.98 1.17 1.02 1.09 0.99 1.11 1.16 1.17 0.70 1.06 0.87 0.93 1.18 0.78 0.73 0.89 1.28 1.23 1.30 1.17 1.23 1.28 1.34 1.21 1.13 1.15 1.13 1.16 1.34 1.32 1.11 1.46 1.27 0.95 0.82 0.89 0.89 1.02 0.77 0.78 1.03 0.74 0.79 1.24 0.84 1.01 0.69 1.00 1.18 0.97 1.25 0.95 1.13 1.24 344 of 622 PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 3.4% 2.9% 4.3% 4.7% 8.6% 3.3% 4.1% 5.5% 2.3% 4.1% 3.7% 6.5% 3.0% 4.0% 2.4% 3.1% 3.1% 3.5% 4.3% 3.3% 3.3% 2.7% 4.9% 2.0% 2.8% 1.5% 3.4% 3.6% 3.7% 2.5% 1.8% 5.1% 5.4% 4.0% 2.3% 2.4% 5.7% 3.3% 5.3% 3.1% 1.6% 2.7% 1.7% 1.5% 3.8% 4.2% 4.0% 0.69 1.23 1.18 1.07 1.26 1.12 0.97 1.09 1.23 1.16 1.18 1.01 1.13 1.14 1.11 1.38 1.22 1.12 0.97 1.07 1.20 1.02 0.96 1.03 1.13 1.41 1.19 1.50 1.38 1.10 0.97 1.19 1.35 1.18 1.49 1.69 0.86 1.09 1.03 1.23 1.19 1.14 1.21 1.14 0.88 1.02 1.08 0.67 1.17 1.14 1.03 1.05 1.08 0.96 1.04 1.25 1.12 1.10 0.98 1.09 1.14 1.13 1.29 1.12 1.15 0.90 1.10 1.16 1.02 0.92 1.01 1.11 1.39 1.16 1.44 1.42 1.05 0.95 1.14 1.48 1.15 1.48 1.64 0.86 1.11 1.01 1.32 1.16 1.09 1.22 1.11 0.80 1.05 1.12 0.67 1.19 1.18 1.07 1.26 1.04 0.95 1.03 1.23 1.13 1.15 1.04 1.06 1.16 1.12 1.30 1.17 1.16 0.88 1.14 1.17 0.98 0.97 1.01 1.09 1.40 1.17 1.50 1.43 1.07 0.96 1.10 1.52 1.14 1.49 1.62 0.85 1.07 1.03 1.22 1.13 1.10 1.22 1.10 0.82 1.05 1.11 0.70 1.25 1.24 1.14 1.33 1.12 1.01 1.11 1.27 1.16 1.20 1.09 1.12 1.19 1.14 1.33 1.19 1.18 0.89 1.18 1.20 1.03 1.01 1.03 1.13 1.42 1.19 1.54 1.48 1.10 0.97 1.10 1.58 1.17 1.55 1.63 0.91 1.13 1.11 1.26 1.17 1.13 1.25 1.14 0.84 1.08 1.15 0.72 1.23 1.25 1.12 1.26 1.13 1.02 1.12 1.29 1.23 1.21 1.12 1.14 1.23 1.16 1.37 1.20 1.21 0.96 1.12 1.24 1.04 1.03 1.03 1.16 1.39 1.24 1.55 1.50 1.10 0.98 1.22 1.51 1.23 1.56 1.67 0.93 1.12 1.10 1.28 1.16 1.13 1.24 1.12 0.84 1.10 1.17 0.73 1.26 1.28 1.17 1.36 1.14 1.06 1.19 1.29 1.23 1.22 1.16 1.16 1.25 1.18 1.38 1.20 1.23 0.94 1.16 1.27 1.06 1.06 1.06 1.17 1.44 1.26 1.60 1.53 1.12 1.00 1.24 1.55 1.27 1.52 1.72 0.98 1.17 1.15 1.31 1.15 1.17 1.26 1.14 0.88 1.15 1.21 345 of 622 PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 4.7% 3.5% 9.3% 4.3% 2.6% 4.9% 5.3% 3.7% 5.1% 2.7% 2.6% 6.1% 5.4% 3.2% 3.2% 2.5% 5.1% 5.6% 3.2% 2.8% 2.5% 4.3% 3.5% 4.0% 3.8% 3.1% 3.0% 1.09 1.16 0.95 0.93 0.93 1.03 0.90 0.96 1.17 1.26 1.41 1.09 1.63 1.05 1.16 1.10 1.26 1.03 0.80 0.84 0.87 0.79 0.88 1.07 1.09 1.20 1.09 1.14 1.18 1.03 1.04 0.94 1.07 0.90 0.97 1.27 1.22 1.40 1.06 1.58 1.05 1.22 1.13 1.16 1.04 0.79 0.80 0.85 0.74 0.82 1.03 1.11 1.16 1.11 1.16 1.21 0.99 0.96 0.93 1.04 0.92 0.95 1.28 1.23 1.33 1.09 1.58 1.00 1.19 1.08 1.11 1.12 0.78 0.82 0.85 0.73 0.81 1.01 1.07 1.14 1.08 1.22 1.28 1.03 1.00 0.95 1.11 0.97 1.02 1.32 1.27 1.40 1.15 1.66 1.06 1.24 1.12 1.15 1.16 0.80 0.84 0.88 0.75 0.84 1.06 1.13 1.20 1.11 1.21 1.18 1.15 0.98 0.96 1.12 0.98 1.00 1.32 1.27 1.40 1.19 1.69 1.06 1.27 1.12 1.21 1.12 0.82 0.84 0.88 0.77 0.85 1.07 1.14 1.20 1.12 1.23 1.22 1.21 1.03 0.99 1.17 1.03 1.04 1.36 1.31 1.44 1.24 1.82 1.10 1.24 1.16 1.26 1.17 0.86 0.87 0.91 0.82 0.88 1.13 1.19 1.24 1.18 1668A/B ICALs Air Historica Data Ax RSD Mean sd 77 10.6 1.04 0.11 1.11 1.13 1.34 81 9.6 1.08 0.10 1.13 1.13 1.13 105 4.6 0.96 0.04 1.11 1.09 1.15 1.11 2.1 1.11 0.02 114 4.9 0.96 0.05 1.18 1.16 1.22 1.2 2.1 1.19 0.02 118 6.8 0.95 0.06 1.11 1.11 1.17 1.19 3.7 1.15 0.04 123 3.9 0.97 0.04 1.08 1.19 1.27 1.21 6.5 1.19 0.08 126 8.6 1.00 0.09 1.07 1.06 1.12 1.11 2.9 1.09 0.03 156/157 6.4 0.99 0.06 1.09 1.11 1.18 1.1 3.7 1.12 0.04 167 5.8 0.98 0.06 1.14 1.14 1.23 1.16 3.8 1.17 0.04 169 4.5 0.97 0.04 1.09 1.11 1.19 1.12 3.7 1.13 0.04 189 14.7 0.95 0.14 1.07 1.06 1.09 1.07 1.3 1.07 0.01 1 9.3 1.16 0.11 1.02 1.03 0.93 0.95 5.1 0.98 0.05 3 9.5 1.16 0.11 0.98 1.04 0.97 1.01 3.4 1.00 0.03 346 of 622 MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd 1.15 8.8 1.18 0.10 1.12 0.4 1.13 0.00 4 4.7 1.03 0.05 1.11 1.17 1.13 1.23 4.5 1.16 0.05 15 11.8 1.02 0.12 0.99 1.08 1.05 1.02 3.9 1.03 0.04 19 4.7 1.04 0.05 1.10 1.09 1.10 1.15 2.3 1.11 0.03 37 12.1 1.06 0.13 1.00 1.10 1.05 1.08 4.2 1.06 0.04 54 104 4.3 1.06 0.05 1.18 1.21 1.24 1.35 6.0 1.25 0.07 5.4 1.01 0.05 1.11 1.25 1.31 1.43 10.2 1.28 0.13 1.19 1.22 1.38 1.46 9.8 1.31 0.13 1.08 1.09 1.22 1.26 7.8 1.16 0.09 170 1.06 1.07 1.11 1.14 3.3 1.09 0.04 180 188 1.08 1.16 1.21 1.26 6.6 1.18 0.08 4.2 1.02 0.04 1.03 1.03 1.01 1.27 11.4 1.09 0.12 202 3.0 0.91 0.03 0.93 0.91 0.97 1.05 6.4 0.97 0.06 205 5.4 0.96 0.05 1.07 1.09 1.11 1.06 1.8 1.08 0.02 208 2.3 0.93 0.02 1.02 1.02 1.07 1.12 4.7 1.06 0.05 206 3.2 0.97 0.03 0.99 0.98 0.92 1.11 7.9 1.00 0.08 209 7.0 0.95 0.07 1.07 1.07 1.13 1.11 2.6 1.10 0.03 1 6.7 1.01 0.07 1.08 1.08 1.20 1.19 6.0 1.14 0.07 3 5.5 1.02 0.06 1.14 1.08 1.14 1.09 2.7 1.11 0.03 153 155 3.2 1.02 0.03 PD from Mean -4.3% 0.1% -1.9% -2.4% -3.4% 0.2% -2.6% -1.2% -2.8% -1.5% -1.4% 4.9% 4.4% 0.8% 4.5% -1.7% 4.3% -3.0% -1.7% -7.0% -6.2% -1.9% -1.6% -4.8% -5.3% 0.6% -3.8% -2.2% -2.1% ES 4 10.0 0.69 0.07 0.50 0.49 0.57 0.52 6.8 0.52 0.04 15 4.2 1.06 0.04 1.18 1.11 1.07 1.04 5.5 1.10 0.06 19 6.3 0.62 0.04 0.53 0.55 0.57 0.51 4.8 0.54 0.03 37 10.4 1.36 0.14 1.64 1.64 1.55 1.66 2.9 1.62 0.05 54 7.3 1.18 0.09 0.87 0.94 0.86 0.86 4.4 0.88 0.04 77 11.1 1.23 0.14 1.26 1.35 1.11 1.38 9.6 1.27 0.12 81 9.4 1.19 0.11 1.20 1.29 1.26 1.37 5.6 1.28 0.07 104 8.0 1.33 0.11 1.08 0.99 0.89 0.8 13.2 0.94 0.12 105 4.1 1.27 0.05 1.22 1.23 1.23 1.2 1.2 1.22 0.02 114 4.2 1.31 0.05 1.24 1.25 1.24 1.22 1.0 1.24 0.01 118 5.3 1.31 0.07 1.28 1.28 1.26 1.16 4.6 1.24 0.06 123 3.9 1.24 0.05 1.35 1.22 1.21 1.19 5.9 1.24 0.07 126 6.7 1.30 0.09 1.22 1.20 1.09 1.03 7.9 1.14 0.09 1.10 1.14 1.15 1.11 2.1 1.13 0.02 153 155 7.0 1.42 0.10 1.41 1.50 1.56 1.59 5.1 1.51 0.08 156/157 7.7 1.22 0.09 1.41 1.45 1.59 1.6 6.4 1.51 0.10 167 7.6 1.25 0.09 1.43 1.49 1.68 1.67 8.1 1.57 0.13 169 8.1 1.23 0.10 1.37 1.40 1.42 1.56 5.8 1.44 0.08 170 1.04 1.00 0.93 0.95 5.1 0.98 0.05 180 1.28 1.16 1.12 1.14 6.3 1.17 0.07 188 8.5 1.27 0.11 1.12 1.18 1.23 0.94 11.4 1.12 0.13 189 7.8 1.52 0.12 1.53 1.49 1.46 1.58 3.5 1.51 0.05 202 6.6 1.18 0.08 1.07 1.14 1.10 0.97 6.7 1.07 0.07 205 3.9 1.27 0.05 1.26 1.20 1.22 1.24 2.0 1.23 0.02 206 11.3 0.97 0.11 0.90 0.87 0.95 0.83 5.9 0.89 0.05 208 10.2 1.27 0.13 1.22 1.19 1.19 1.17 1.7 1.19 0.02 MM7 Comparing ICAL RRFs 20DEC2013.xlsx -5.0% -2.7% -6.0% 0.8% 2.3% 0.8% 6.5% 5.7% 0.7% 5.6% 1.1% 0.7% 3.0% -2.0% 5.6% 1.3% -1.2% -3.9% -4.6% -2.4% 2.1% -1.3% 5.3% -1.8% 6.4% -2.2% -2.1% -0.2% 1668A/B ICALs Air Historica Data Ax RSD Mean sd 209 8.3 1.20 0.10 347 of 622 MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 1.06 1.00 1.12 1.11 PD from Mean RSD Mean sd 5.1 1.07 0.06 -6.8% 0.8% 0.2% 3.1% SS 28 3.6 1.05 0.04 0.98 1.07 1.10 1.11 5.6 1.07 0.06 111 4.0 1.05 0.04 0.90 1.01 1.08 1.03 7.5 1.00 0.07 178 3.9 0.71 0.03 0.62 0.63 0.57 0.62 4.4 0.61 0.03 Additional Ax RSD Mean sd PCB-1 2-MoCB 1.02 1.03 0.93 0.95 5.1 0.98 0.05 PCB-2 3-MoCB 0.97 1.04 0.97 1.03 3.7 1.00 0.04 PCB-3 4-MoCB 0.98 1.04 0.97 1.01 3.4 1.00 0.03 PCB-4 22'-DiCB 1.11 1.17 1.13 1.23 4.5 1.16 0.05 PCB-10 26-DiCB 1.71 1.83 1.75 1.98 6.5 1.82 0.12 PCB-9 25-DiCB 0.83 0.89 0.90 0.95 5.7 0.89 0.05 PCB-7 24-DiCB 0.95 1.02 1.02 1.05 4.3 1.01 0.04 PCB-6 23'-DiCB 0.89 0.95 0.96 1.00 4.7 0.95 0.04 PCB-5 23-DiCB 0.89 0.97 0.97 1.00 4.7 0.96 0.05 PCB-8 24'-DiCB 0.93 0.98 1.00 1.03 4.3 0.99 0.04 PCB-14 35-DiCB 1.07 1.16 1.15 1.18 4.2 1.14 0.05 PCB-11 33'-DiCB 0.94 1.00 0.99 1.01 3.3 0.98 0.03 PCB-13/12 34'-/34-DiCB 0.95 1.02 0.99 0.99 2.8 0.99 0.03 PCB-15 44'-DiCB 0.99 1.08 1.05 1.02 3.9 1.03 0.04 0.03 PCB-19 22'6-TrCB 1.10 1.09 1.10 1.15 2.3 1.11 PCB-30/18 246-/22'5-TrCB 1.48 1.46 1.45 1.54 2.6 1.48 0.04 PCB-17 22'4-TrCB 1.28 1.25 1.26 1.31 2.0 1.28 0.03 PCB-27 23'6-TrCB 1.70 1.69 1.68 1.82 3.8 1.72 0.07 PCB-24 236-TrCB 1.63 1.63 1.60 1.72 3.1 1.65 0.05 PCB-16 22'3-TrCB 0.97 0.95 0.96 1.01 2.6 0.97 0.03 PCB-32 24'6-TrCB 1.81 1.79 1.84 1.92 3.1 1.84 0.06 PCB-34 2'35-TrCB 0.98 1.05 1.04 1.14 6.4 1.05 0.07 PCB-23 235-TrCB 0.98 1.06 1.07 1.16 6.9 1.07 0.07 PCB-26/29 23'5-/245-TrCB 1.00 1.09 1.07 1.17 6.3 1.08 0.07 PCB-25 23'4-TrCB 0.99 1.07 1.09 1.16 6.5 1.08 0.07 PCB-31 24'5-TrCB 1.03 1.11 1.13 1.23 7.2 1.13 0.08 PCB-28/20 244'-/233'-TrCB 0.98 1.07 1.06 1.13 5.6 1.06 0.06 PCB-21/33 234-/2'34-TrCB 1.01 1.09 1.08 1.17 6.0 1.09 0.06 PCB-22 234'-TrCB 0.93 1.02 1.00 1.08 6.0 1.01 0.06 PCB-36 33'5-TrCB 1.03 1.13 1.09 1.17 5.4 1.10 0.06 PCB-39 34'5-TrCB 1.10 1.17 1.13 1.21 4.1 1.15 0.05 PCB-38 345-TrCB 0.95 1.03 1.02 1.10 5.9 1.02 0.06 PCB-35 33'4-TrCB 0.96 1.04 1.00 1.04 4.0 1.01 0.04 PCB-37 344'-TrCB 1.00 1.10 1.05 1.08 4.2 1.06 0.04 PCB-54 22'66'-TeCB 1.18 1.21 1.24 1.35 6.0 1.25 0.07 PCB-50/53 22'46-/22'56'TeCB 0.85 0.86 0.88 0.88 2.0 0.87 0.02 PCB-45 22'36-TeCB 0.75 0.73 0.76 0.77 2.2 0.75 0.02 PCB-51 22'46'-TeCB 0.85 0.88 0.91 0.86 3.2 0.87 0.03 PCB-46 22'36'-TeCB 0.68 0.70 0.71 0.70 1.6 0.70 0.01 PCB-52 22'55'-TeCB 0.82 0.84 0.86 0.84 2.0 0.84 0.02 PCB-73 23'5'6TeCB 1.10 1.09 1.13 1.11 1.4 1.11 0.02 0.03 PCB-43 22'35-TeCB 0.66 0.72 0.72 0.71 4.5 0.70 PCB-69/49 23'46-/22'45'TeCB 1.00 1.01 1.05 1.02 2.1 1.02 0.02 PCB-48 22'45-TeCB 0.83 0.85 0.87 0.84 1.7 0.85 0.01 0.01 PCB-44/47/65 22'35'-/22'44'- 0.88 0.89 0.91 0.90 1.5 0.90 PCB-59/62/75 233'6-/2346-/24 1.12 1.14 1.18 1.17 2.4 1.15 0.03 PCB-42 22'34'-TeCB 0.77 0.76 2.9 0.78 0.02 0.77 0.81 MM7 Comparing ICAL RRFs 20DEC2013.xlsx PCB-41 22'34-TeCB 0.72 0.73 0.71 0.69 2.2 0.71 0.02 PCB-71/40 23'4'6/22'33'-TeCB 0.85 0.87 0.88 0.86 1.5 0.86 0.01 PCB-64 234'6-TeCB 1.21 1.24 1.26 1.22 1.7 1.23 0.02 PD from Historical Mean 4.9% 3.8% 4.4% 0.8% 0.7% 0.4% 1.4% -0.2% 1.4% -0.2% 1.5% 1.7% 3.2% 4.5% -1.7% -1.6% -1.9% -1.8% -0.7% -2.1% -2.8% -0.3% -0.8% 0.3% -0.3% -1.3% 0.7% 0.3% 0.8% 2.1% 1.2% 0.7% 3.2% 4.3% -3.0% -1.1% -2.8% 0.6% -0.3% 0.3% -1.5% 3.0% -0.8% 0.4% -0.8% -1.2% -0.8% 2.1% 0.2% 0.5% 1668A/B ICALs Air Historica Data Ax RSD 348 of 622 Mean sd MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd PCB-72 23'55'-TeCB 1.13 1.14 1.17 1.21 3.0 1.16 0.03 PCB-68 23'45'-TeCB 1.21 1.21 1.26 1.28 2.8 1.24 0.04 PCB-57 233'5-TeCB 1.10 1.11 1.12 1.16 2.3 1.12 0.03 PCB-58 233'5-TeCB 1.11 1.10 1.16 1.18 3.4 1.14 0.04 PCB-67 23'45-TeCB 1.15 1.16 1.20 1.26 4.2 1.19 0.05 PCB-63 234'5-TeCB 1.22 1.22 1.25 1.30 3.1 1.25 0.04 PCB-61/70/74/76 2345-/23'4'5 1.13 1.13 1.17 1.20 2.8 1.16 0.03 PCB-66 23'44'-TeCB 1.06 1.08 1.10 1.10 1.7 1.09 0.02 PCB-55 233'4-TeCB 1.09 1.10 1.11 1.12 1.3 1.10 0.01 PCB-56 233'4'-TeCB 1.05 1.06 1.07 1.11 2.4 1.07 0.03 PCB-60 2344'-TeCB 1.12 1.11 1.15 1.14 1.5 1.13 0.02 PCB-80 33'55'-TeCB 1.26 1.25 1.27 1.31 2.1 1.27 0.03 PCB-79 33'45'-TeCB 1.26 1.23 1.28 1.31 2.6 1.27 0.03 PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6-/22'356-P PCB-102 22'456'-PeCB PCB-98 22'3'46-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 233'5'6-/22'3 PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125/87 233 PCB-117 234'56-PeCB PCB-116/85 23456-/22'344'-Pe PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 233'4'5-/2'3455' PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 2'33'45-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'HxCB PCB-148 22'34'56'-HxCB PCB-151/135 22'355'6-/22'33' PCB-154 22'44'5'6-HxCB PCB-144 22'345'6-HxCB PCB-147/149 22'34'56-/22'34' PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 22'344'6-/22'344' PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB 1.09 1.08 1.05 1.06 1.6 1.07 0.02 1.11 1.25 1.31 1.43 10.2 1.28 0.13 0.98 1.08 1.12 1.23 9.5 1.10 0.10 0.80 0.90 0.95 0.93 7.2 0.90 0.06 0.70 0.78 0.81 0.80 6.6 0.77 0.05 0.75 0.83 0.88 0.87 7.5 0.83 0.06 0.76 0.84 0.90 0.86 6.9 0.84 0.06 0.82 0.90 0.98 0.97 8.1 0.92 0.07 0.69 0.77 0.80 0.76 5.9 0.76 0.04 0.67 0.79 0.77 0.80 7.8 0.76 0.06 0.84 0.88 1.00 0.94 7.5 0.91 0.07 0.65 0.71 0.72 0.72 5.2 0.70 0.04 0.68 0.76 0.78 0.76 6.0 0.75 0.04 1.02 1.14 1.20 1.20 7.4 1.14 0.08 0.73 0.80 0.84 0.82 6.0 0.80 0.05 0.85 0.93 0.99 0.99 7.0 0.94 0.07 0.63 0.71 0.72 0.71 5.7 0.69 0.04 0.82 0.87 0.95 0.92 6.5 0.89 0.06 1.01 1.13 1.17 1.17 6.7 1.12 0.07 0.87 0.95 1.01 0.98 6.4 0.95 0.06 0.96 1.04 1.05 1.14 7.2 1.05 0.08 0.87 0.97 1.03 0.94 7.0 0.95 0.07 0.95 1.02 1.11 1.12 7.7 1.05 0.08 1.02 1.16 1.21 1.16 6.9 1.14 0.08 0.63 0.69 0.72 0.70 5.5 0.68 0.04 1.05 1.15 1.22 1.22 7.0 1.16 0.08 1.05 1.16 1.22 1.21 6.5 1.16 0.08 0.99 1.07 1.11 1.10 5.3 1.07 0.06 1.05 1.14 1.18 1.25 7.1 1.16 0.08 0.98 1.07 1.11 1.11 5.6 1.07 0.06 1.01 1.00 1.01 0.99 1.0 1.00 0.01 1.12 1.10 1.08 1.10 1.5 1.10 0.02 1.08 1.09 1.22 1.26 7.8 1.16 0.09 1.00 1.01 1.14 1.17 8.0 1.08 0.09 1.03 1.00 1.15 1.18 7.9 1.09 0.09 0.95 0.95 1.07 1.07 6.8 1.01 0.07 0.98 0.96 1.09 1.11 7.4 1.03 0.08 0.96 0.97 1.12 1.18 10.5 1.06 0.11 0.94 0.96 1.11 1.14 9.8 1.04 0.10 1.05 1.09 1.26 1.34 11.7 1.19 0.14 0.96 0.98 1.13 1.18 10.1 1.06 0.11 0.96 0.99 1.14 1.18 10.3 1.07 0.11 0.78 0.80 0.90 0.92 8.1 0.85 0.07 0.92 0.95 1.09 1.13 10.0 1.02 0.10 0.99 1.00 1.14 1.21 10.1 1.09 0.11 0.84 0.85 0.98 1.03 10.4 0.93 0.10 0.99 7.4 0.93 0.07 0.86 MM7 Comparing ICAL RRFs 20DEC2013.xlsx 0.87 0.98 0.87 0.89 1.02 1.03 8.8 0.95 0.08 0.92 0.91 1.04 1.13 10.2 1.00 0.10 PD from Mean -1.8% -2.5% -1.4% -3.4% -2.8% -2.6% -2.3% -0.9% -0.6% -1.7% -1.5% -1.5% -2.9% 0.9% -1.7% -2.4% 0.6% 0.4% -0.7% 0.2% -1.9% 2.4% 4.7% -3.8% 1.4% 1.9% 0.2% 0.2% -0.9% 2.8% -2.1% 0.7% -0.1% -0.7% 2.2% -2.6% 1.8% 0.9% -0.5% -0.1% 0.6% -1.2% 0.1% -0.2% -0.1% -6.2% -6.4% -8.0% -5.7% -7.0% -8.2% -7.2% -8.1% -7.7% -7.8% -5.8% -6.8% -7.9% -8.2% -5.7% -6.7% -8.7% 1668A/B ICALs Air Historica Data Ax PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 22'44'55'-/23'44' PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 233'4'56-/22' PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 22'33'44'-/2344'5 PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'4'56-HpCB PCB-181 22'344'56-HpCB PCB-171/173 22'33'44'6-/22'3 PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 22'344'55'-/233' PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 22'33'455'6-/22' PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB RSD 349 of 622 Mean sd MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd 1.12 1.13 1.32 1.41 11.4 1.24 0.14 0.99 1.01 1.16 1.20 10.0 1.09 0.11 1.24 1.25 1.41 1.52 9.8 1.36 0.13 1.19 1.22 1.38 1.46 9.8 1.31 0.13 0.92 0.93 1.06 1.09 8.9 1.00 0.09 0.82 0.85 0.95 0.97 8.2 0.90 0.07 1.00 1.04 1.08 1.16 6.3 1.07 0.07 1.21 1.22 1.45 1.50 11.2 1.35 0.15 1.01 1.02 1.14 1.19 8.1 1.09 0.09 1.18 1.21 1.32 1.52 11.9 1.31 0.16 1.30 1.34 1.50 1.66 11.4 1.45 0.17 0.91 0.90 0.95 0.90 2.7 0.92 0.02 1.07 1.06 1.14 1.11 3.0 1.10 0.03 1.09 1.08 1.14 1.07 2.7 1.09 0.03 1.03 1.03 1.01 1.27 11.4 1.09 0.12 0.95 0.97 0.92 1.16 10.8 1.00 0.11 0.94 0.93 0.90 1.13 10.6 0.98 0.10 1.05 1.05 1.00 1.23 9.4 1.08 0.10 0.98 0.98 0.94 1.13 8.3 1.01 0.08 0.73 0.74 0.69 0.84 8.6 0.75 0.06 0.95 1.01 1.09 1.07 6.1 1.03 0.06 0.99 1.06 1.17 1.14 7.4 1.09 0.08 1.02 1.11 1.19 1.18 6.9 1.12 0.08 1.06 1.13 1.17 1.20 5.4 1.14 0.06 0.95 1.02 1.13 1.06 7.3 1.04 0.08 0.83 0.93 0.99 0.99 8.0 0.93 0.07 0.85 0.91 0.97 0.95 5.7 0.92 0.05 0.98 1.06 1.10 1.09 4.9 1.06 0.05 0.85 0.93 0.96 0.95 5.4 0.92 0.05 0.88 0.95 0.99 0.99 5.5 0.95 0.05 1.12 1.24 1.26 1.29 6.0 1.23 0.07 1.08 1.16 1.21 1.26 6.6 1.18 0.08 1.20 1.30 1.32 1.40 6.4 1.31 0.08 1.06 1.07 1.11 1.14 3.3 1.09 0.04 1.42 1.45 1.54 1.66 7.2 1.52 0.11 0.93 0.91 0.97 1.05 6.4 0.97 0.06 1.04 1.02 1.07 1.22 8.3 1.09 0.09 0.99 0.98 1.02 1.12 6.3 1.03 0.07 1.03 1.06 1.13 1.19 6.3 1.10 0.07 1.02 0.96 1.02 1.11 6.0 1.03 0.06 0.74 0.72 0.73 0.81 5.7 0.75 0.04 0.77 0.73 0.76 0.83 5.5 0.77 0.04 0.80 0.76 0.79 0.87 5.7 0.80 0.05 0.79 0.80 0.82 0.77 2.7 0.80 0.02 0.87 0.87 0.89 0.84 2.3 0.87 0.02 1.07 1.09 1.11 1.06 1.8 1.08 0.02 1.02 1.02 1.07 1.12 4.7 1.06 0.05 1.07 1.06 1.10 1.19 5.4 1.10 0.06 0.99 0.98 0.92 1.11 7.9 1.00 0.08 MM7 Comparing ICAL RRFs 20DEC2013.xlsx PD from Mean -9.0% -7.6% -7.6% -7.0% -7.3% -5.7% -2.7% -9.1% -6.2% -7.6% -7.7% -1.9% -3.0% -1.7% -4.8% -3.1% -4.6% -3.2% -2.6% -1.8% -2.0% -2.5% -1.2% -0.6% -2.0% -0.7% -1.3% 0.3% 0.6% 0.3% 1.0% -1.6% -0.3% -1.9% -4.3% -5.3% -6.2% -4.9% -3.6% -6.4% -4.2% -5.3% -5.1% 0.5% 0.7% 0.6% -3.8% -4.3% -2.0% 350 of 622 SGS Analytical Perspectives — Run Log Project: 131220 QC MM7 Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Datafile Vial# Wt/Vol Client/Sample ID Analyst(s) Checkcode Acq Date 2 131220X02 Tray1:37 CS0_131220_PCB_XA 1.00 SIL 13-79-6 LKB 067-110 20-Dec-2013 14:56:33 3 131220X03 Tray1:38 CS1_131220_PCB_XA 1.00 SIL 13-79-5 LKB 983-753 20-Dec-2013 16:14:56 Lab ID Acq Time 4 131220X04 Tray1:39 CS2_131220_PCB_XA 1.00 SIL 13-79-4 LKB 288-489 20-Dec-2013 17:09:38 5 131220X05 Tray1:40 CS3_131220_PCB_XA 1.00 SIL 13-79-3 LKB 297-225 20-Dec-2013 18:04:38 20-Dec-2013 18:59:38 6 131220X06 Tray1:41 CS4_131220_PCB_XA 1.00 SIL 13-79-2 LKB 186-257 7 131220X07 Tray1:02 SBS_131220_PCB_XB 1.00 SIL 9-42-1 LKB 307-094 20-Dec-2013 19:54:39 8 131220X08 Tray1:42 CS5_131220_PCB_XA 1.00 SIL 13-84-1 LKB 807-075 20-Dec-2013 20:49:35 9 131220X09 Tray1:02 SBS_131220_PCB_XC 1.00 SIL 9-42-1 LKB 023-880 20-Dec-2013 21:57:30 10 131220X10 Tray1:02 SBS_131220_PCB_XD 1.00 SIL 9-42-1 LKB 979-518 20-Dec-2013 22:52:16 Project file: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\131220 QC MM7.utp_prj, saved 03-Jan-2014 17:08 AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 Printed: 03-Jan-2014 17:17 351 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.12 32.64 36.11 35.57 35.10 34.82 38.73 41.28 40.30 44.00 46.13 51.25 6.82E+05 6.25E+05 5.30E+05 5.44E+05 5.47E+05 5.49E+05 4.31E+05 8.79E+05 4.81E+05 4.43E+05 4.42E+05 3.36E+05 0.76 Y 0.76 Y 0.63 Y 0.67 Y 0.67 Y 0.63 Y 0.61 Y 1.18 Y 1.11 Y 1.39 Y 1.03 Y 1.21 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.08 1.13 1.14 1.20 1.20 1.05 1.07 1.11 1.12 1.08 1.18 1.8% -3.1% 1.5% -5.0% 0.6% -0.6% -5.2% -2.5% -4.2% -0.5% 0.2% 6.0% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.05 14.37 14.63 20.39 17.75 26.75 20.68 33.10 32.62 25.69 36.09 35.55 35.08 34.80 38.71 36.67 30.66 41.26 40.28 43.98 43.50 42.43 35.54 46.11 40.09 48.28 49.75 45.73 51.23 2.32E+08 2.09E+08 9.70E+07 1.92E+08 9.22E+07 1.42E+08 7.28E+07 1.16E+08 1.15E+08 6.25E+07 9.38E+07 9.51E+07 9.14E+07 9.13E+07 8.22E+07 5.84E+07 8.51E+07 1.64E+08 8.65E+07 7.92E+07 4.71E+07 5.69E+07 4.97E+07 8.21E+07 4.94E+07 6.33E+07 4.24E+07 5.90E+07 5.69E+07 3.31 Y 3.36 Y 1.64 Y 1.56 Y 1.08 Y 1.09 Y 0.79 Y 0.80 Y 0.81 Y 1.64 Y 1.62 Y 1.64 Y 1.64 Y 1.59 Y 1.56 Y 1.32 Y 1.30 Y 1.31 Y 1.29 Y 1.29 Y 1.09 Y 1.07 Y 1.11 Y 1.04 Y 0.92 Y 0.90 Y 0.81 Y 0.81 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.25 1.12 0.52 1.04 0.50 1.69 0.86 1.38 1.37 0.82 1.22 1.24 1.19 1.19 1.07 1.14 1.66 1.60 1.68 1.54 0.92 1.11 0.97 1.61 0.96 1.24 0.83 1.16 1.12 5.1% 3.5% 0.1% -0.4% -1.7% 1.7% 0.4% -0.1% 0.2% 1.5% 1.8% 1.8% 2.9% 0.4% 4.3% 2.1% 4.3% 0.0% 0.9% -1.0% -2.5% -2.0% 2.9% 1.7% -0.9% -0.3% 0.3% -1.6% 0.5% Page 1 of 6 352 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.18 33.12 38.11 1.59E+08 9.52E+07 3.17E+07 1.09 Y 1.60 Y 1.06 Y 1.11 1.03 0.62 1.12 1.04 0.64 0.5% 1.3% 3.0% CS PCB-28 CS PCB-111 CS PCB-178 23.18 33.12 38.11 1.59E+08 9.52E+07 3.17E+07 1.09 Y 1.60 Y 1.06 Y 1.85 1.22 0.58 1.89 1.24 0.62 2.2% 1.7% 6.0% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.63 24.81 30.82 37.74 47.88 1.86E+08 8.42E+07 7.67E+07 5.14E+07 5.10E+07 1.57 Y 0.81 Y 1.63 Y 1.34 Y 0.93 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.06 14.39 14.64 20.41 17.77 26.77 20.70 25.71 30.68 35.56 40.11 48.30 45.75 49.77 1.15E+06 1.04E+06 5.70E+05 9.73E+05 5.22E+05 7.24E+05 5.08E+05 4.49E+05 5.21E+05 3.05E+05 2.58E+05 3.40E+05 3.21E+05 2.31E+05 3.25 Y 3.26 Y 0.00 S 0.00 S 1.03 Y 1.07 Y 0.86 Y 0.64 Y 1.33 Y 1.15 Y 0.94 Y 0.94 Y 0.83 Y 0.73 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.99 1.00 1.17 1.01 1.13 1.02 1.40 1.44 1.23 1.23 1.05 1.07 1.09 1.09 3.9% -0.9% -4.7% -0.7% -1.3% -5.6% 3.4% 0.3% -2.8% -3.2% -0.7% 1.3% -3.0% -2.5% Page 2 of 6 353 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 12.06 14.20 14.39 14.64 14.83 16.65 16.82 17.04 17.35 17.47 19.04 19.83 20.12 20.41 17.77 19.54 19.95 20.14 20.27 20.37 20.86 22.01 22.16 22.45 22.65 22.92 23.21 23.39 23.77 25.16 25.48 26.02 26.41 26.77 20.70 22.70 23.29 23.37 23.57 24.83 24.96 25.06 25.26 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.15E+06 1.07E+06 1.04E+06 5.70E+05 9.26E+05 8.91E+05 9.13E+05 9.28E+05 9.94E+05 1.02E+06 1.10E+06 9.44E+05 1.69E+06 9.73E+05 5.22E+05 1.37E+06 5.65E+05 8.14E+05 7.72E+05 4.55E+05 8.78E+05 7.89E+05 8.53E+05 1.63E+06 8.01E+05 8.89E+05 1.61E+06 1.63E+06 7.71E+05 8.01E+05 8.42E+05 7.61E+05 7.19E+05 7.24E+05 5.08E+05 1.02E+06 4.52E+05 4.59E+05 4.01E+05 4.90E+05 6.54E+05 3.93E+05 1.15E+06 RA 3.25 Y 3.22 Y 3.26 Y 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 1.03 Y 1.04 Y 1.04 Y 1.08 Y 1.06 Y 1.10 Y 1.08 Y 1.08 Y 0.94 Y 1.01 Y 0.97 Y 1.01 Y 1.02 Y 0.98 Y 1.00 Y 1.00 Y 1.02 Y 0.93 Y 1.01 Y 1.07 Y 0.86 Y 0.81 Y 0.79 Y 0.83 Y 0.83 Y 0.76 Y 0.81 Y 0.85 Y 0.76 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.99 1.02 1.00 1.17 1.91 0.93 0.95 0.97 1.03 1.07 1.14 0.98 0.88 1.01 1.13 1.49 1.23 1.77 1.67 0.99 1.90 1.11 1.20 1.15 1.13 1.25 1.13 1.15 1.08 1.13 1.18 1.07 1.01 1.02 1.40 0.89 0.78 0.80 0.70 0.85 1.13 0.68 0.99 Dev'n 3.9% -0.9% -0.9% -4.7% -3.6% -2.0% -9.2% -3.0% 3.2% 3.2% -3.4% -2.8% -11.2% -0.7% -1.3% -3.2% -6.1% -2.9% -2.9% -2.0% -0.8% -2.3% 3.8% -2.1% -2.7% 2.0% -0.1% -2.4% 0.4% -3.7% -2.3% -3.2% -2.8% -5.6% 3.4% 1.3% 2.2% -7.3% -0.4% 0.7% 2.0% -4.1% -2.8% 354 of 622 PCB QC Summary - Ax2 Detail Lab ID: CS0_131220_PCB_XA Acquired: 20-DEC-2013 14:56 Datafile: 131220X02 Name RT PCB-48 22'45-TeCB 25.54 PCB-44/47/65 ...-TeCB 25.76 PCB-59/62/75 ...-TeCB 26.03 PCB-42 22'34'-TeCB 26.20 PCB-41 22'34-TeCB 26.54 PCB-71/40 23'4'6/22'33'-TeCB 26.63 PCB-64 234'6-TeCB 26.83 PCB-72 23'55'-TeCB 27.55 PCB-68 23'45'-TeCB 27.80 PCB-57 233'5-TeCB 28.18 PCB-58 233'5'-TeCB 28.38 PCB-67 23'45-TeCB 28.54 PCB-63 234'5-TeCB 28.77 PCB-61/70/74/76 ...-TeCB 29.06 PCB-66 23'44'-TeCB 29.34 PCB-55 233'4-TeCB 29.49 PCB-56 233'4'-TeCB 29.93 PCB-60 2344'-TeCB 30.12 PCB-80 33'55'-TeCB 30.44 PCB-79 33'45'-TeCB 31.77 PCB-78 33'45-TeCB 32.26 PCB-104 22'466'-PeCB 25.71 PCB-96 22'366'-PeCB 26.03 PCB-103 22'45'6-PeCB 27.72 PCB-94 22'356'-PeCB 27.91 PCB-95 22'35'6-PeCB 28.29 PCB-100/93 22'44'6/22'356-PeCB 28.51 PCB-102 22'456'-PeCB 28.62 PCB-98 22'34'6'-PeCB 28.70 PCB-88 22'346-PeCB 29.00 PCB-91 22'34'6-PeCB 29.06 PCB-84 22'33'6-PeCB 29.25 PCB-89 22'346'-PeCB 29.67 PCB-121 23'45'6-PeCB 30.01 PCB-92 22'355'-PeCB 30.33 PCB-113/90/101 ...-PeCB 30.82 PCB-83 22'33'5-PeCB 31.26 PCB-99 22'44'5-PeCB 31.36 PCB-112 233'56-PeCB 31.46 PCB-108/119/86/97/125...-PeCB 31.80 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.43 PCB-110 233'4'6-PeCB 32.54 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 4.76E+05 1.54E+06 1.95E+06 4.38E+05 3.93E+05 9.69E+05 6.74E+05 6.87E+05 7.26E+05 6.81E+05 6.76E+05 7.09E+05 7.50E+05 2.77E+06 6.11E+05 6.26E+05 6.53E+05 6.55E+05 7.47E+05 7.25E+05 6.00E+05 4.49E+05 3.51E+05 4.14E+05 3.59E+05 4.07E+05 7.64E+05 4.42E+05 3.31E+05 4.40E+05 3.45E+05 3.22E+05 3.31E+05 5.39E+05 3.73E+05 1.35E+06 3.50E+05 4.00E+05 5.12E+05 2.69E+06 4.64E+05 9.28E+05 4.96E+05 RA 0.82 Y 0.78 Y 0.80 Y 0.81 Y 0.87 Y 0.82 Y 0.82 Y 0.78 Y 0.84 Y 0.73 Y 0.76 Y 0.78 Y 0.82 Y 0.77 Y 0.79 Y 0.78 Y 0.82 Y 0.79 Y 0.82 Y 0.81 Y 0.82 Y 0.64 Y 0.75 N 0.64 Y 0.70 Y 0.58 Y 0.61 Y 0.64 Y 0.63 Y 0.66 Y 0.56 Y 0.60 Y 0.70 Y 0.64 Y 0.62 Y 0.62 Y 0.64 Y 0.61 Y 0.65 Y 0.63 Y 0.55 Y 0.58 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.83 0.89 1.13 0.76 0.68 0.84 1.17 1.19 1.26 1.18 1.17 1.23 1.30 1.20 1.06 1.09 1.13 1.13 1.30 1.26 1.04 1.44 1.12 0.91 0.79 0.89 0.84 0.97 0.73 0.96 0.76 0.71 0.73 1.18 0.82 0.98 0.77 0.88 1.12 0.98 1.02 1.02 1.09 Dev'n -1.5% -1.8% -3.2% -0.5% -2.0% -2.2% -4.3% -1.5% -1.4% 1.5% -0.6% -2.3% 0.2% 0.2% -3.9% -3.1% 2.0% 0.0% -1.4% -3.8% -2.0% 0.3% -8.6% -2.6% -1.5% 3.0% -3.1% 0.0% -4.3% 20.8% -19.9% -1.3% -4.9% -1.7% -0.4% -0.3% 7.3% -4.7% -4.0% 0.2% -10.6% 8.1% -2.7% 355 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 32.63 32.83 33.14 33.54 34.51 34.72 34.94 35.40 37.35 30.68 30.84 30.98 31.29 31.56 32.83 33.35 33.56 33.83 34.13 34.30 34.39 34.65 34.82 34.97 35.21 35.61 35.95 36.16 36.28 36.72 36.86 37.20 37.41 37.49 37.78 37.92 38.10 38.84 39.65 39.89 35.56 35.84 36.31 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 5.39E+05 3.15E+05 5.61E+05 5.37E+05 9.78E+05 5.73E+05 5.10E+05 4.64E+05 5.10E+05 5.21E+05 4.93E+05 5.01E+05 4.28E+05 4.79E+05 3.33E+05 6.47E+05 4.03E+05 3.56E+05 6.56E+05 2.84E+05 3.14E+05 7.00E+05 2.97E+05 2.79E+05 3.02E+05 3.31E+05 4.11E+05 3.49E+05 4.37E+05 8.08E+05 3.22E+05 2.84E+05 3.47E+05 3.94E+05 1.03E+06 4.35E+05 4.94E+05 7.41E+05 4.73E+05 4.43E+05 3.05E+05 2.95E+05 2.83E+05 RA 0.59 Y 0.59 Y 0.65 Y 0.66 Y 0.64 Y 0.63 Y 0.69 Y 0.65 Y 0.62 Y 1.33 Y 1.27 Y 1.36 Y 1.35 Y 1.26 Y 1.20 Y 1.21 Y 1.25 Y 1.23 Y 1.34 Y 1.23 Y 1.30 Y 1.27 Y 1.27 Y 1.25 Y 1.27 Y 1.25 Y 1.27 Y 1.21 Y 1.25 Y 1.27 Y 1.27 Y 1.16 Y 1.24 Y 1.20 Y 1.26 Y 1.23 Y 1.30 Y 1.33 Y 1.12 Y 1.33 Y 1.15 Y 1.06 Y 0.94 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.18 0.69 1.23 1.18 1.07 1.26 1.12 0.97 1.09 1.23 1.16 1.18 1.01 1.13 1.14 1.11 1.38 1.22 1.12 0.97 1.07 1.20 1.02 0.96 1.03 1.13 1.41 1.19 1.50 1.38 1.10 0.97 1.19 1.35 1.18 1.49 1.69 0.86 1.09 1.03 1.23 1.19 1.14 Dev'n 1.8% -1.1% 0.6% -2.8% -2.4% 0.2% 1.0% -2.0% -0.8% -2.8% -1.3% 0.1% -5.7% 0.9% -3.7% -2.9% 2.8% 3.1% -4.6% 5.0% -4.7% -0.6% -0.8% -3.4% 0.2% 0.1% -0.2% -0.7% -1.6% -5.0% 1.3% 0.0% 2.0% -10.0% -1.1% -1.7% 1.8% -4.7% -1.9% -4.3% -3.2% 2.3% 1.1% 356 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 36.60 37.00 38.13 38.68 38.91 39.09 39.43 39.52 39.63 40.00 40.35 40.54 41.89 42.14 42.41 42.74 43.51 43.97 40.11 40.90 41.48 41.67 41.76 44.08 44.66 44.83 45.95 47.90 48.30 45.75 46.54 49.77 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 3.00E+05 2.82E+05 2.19E+05 2.90E+05 3.08E+05 3.10E+05 3.29E+05 2.70E+05 2.63E+05 2.64E+05 2.93E+05 5.11E+05 2.73E+05 3.33E+05 7.15E+05 3.99E+05 2.56E+05 3.84E+05 2.58E+05 2.87E+05 2.72E+05 3.10E+05 2.54E+05 3.97E+05 2.07E+05 2.16E+05 2.51E+05 2.77E+05 3.40E+05 3.21E+05 3.55E+05 2.31E+05 RA 1.06 Y 1.10 Y 1.14 Y 1.08 Y 1.11 Y 1.13 Y 1.06 Y 1.04 Y 1.16 Y 1.06 Y 1.17 Y 1.09 Y 1.07 Y 1.10 Y 1.02 Y 1.10 Y 1.10 Y 1.02 Y 0.94 Y 1.04 N 0.90 Y 0.94 Y 1.01 Y 1.02 Y 0.90 Y 0.86 Y 0.94 Y 0.96 Y 0.94 Y 0.83 Y 0.76 Y 0.73 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.21 1.14 0.88 1.02 1.08 1.09 1.16 0.95 0.93 0.93 1.03 0.90 0.96 1.17 1.26 1.41 1.09 1.63 1.05 1.16 1.10 1.26 1.03 0.80 0.84 0.87 0.79 0.88 1.07 1.09 1.20 1.09 Dev'n -1.8% 1.0% 4.6% -4.9% -4.8% -7.2% -4.0% -10.4% -6.3% -2.5% -5.4% -5.3% -3.0% -9.0% -0.4% 0.7% -4.3% -1.8% -0.7% -4.7% -1.4% 5.5% -7.2% -0.6% 0.6% 0.0% 3.5% 3.8% 1.3% -3.0% 1.1% -2.5% 357 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.34e7 2.67e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.66e7 1.33e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.89e7 9.45e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.92e7 9.60e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.07e7 5.34e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.41e6 2.71e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.18e6 2.59e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 067-110 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:09 Page 1 of 21 358 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-1 8.80e5 12.06 Rel. Int. 100% Abs. Int. 3.62e5 PCB-2 8.15e5 14.20 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.75e3 PCB-3 7.98e5 14.39 1.81e5 0% 11.0 12.0 13.0 14.0 PCB-1 2.71e5 12.06 Rel. Int. 100% PCB-2 2.53e5 14.20 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 4.15e3 15.0 0.00e0 16.0 RT Abs. Int. 1.13e5 PCB-3 2.45e5 14.38 5.63e4 0% 11.0 12.0 13.0 14.0 ES-1 1.79e8 12.05 Rel. Int. 100% 15.0 Abs. Int. 7.29e7 ES-3 1.61e8 14.37 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.78e3 0.00e0 16.0 RT 3.65e7 0% 11.0 12.0 13.0 14.0 ES-1 5.39e7 12.05 Rel. Int. 100% 15.0 Abs. Int. 2.20e7 ES-3 4.79e7 14.37 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.76e4 0.00e0 16.0 RT 1.10e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.34e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.67e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4953, 9453 scc: 067-110 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 2 of 21 359 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Rel. Int. 100% PCB-4 3.47e5 SI 14.64 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 8.63e3 PCB-10 5.64e5 SI 14.83 9.85e4 0% 11.0 12.0 13.0 14.0 Abs. Int. 1.97e5 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.66e5 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: B 4σ 2.45e4 8.28e4 PFK INTERFERENCE 0% 11.0 12.0 13.0 14.0 15.0 ES-4 6.03e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.00e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 9.69e3 1.00e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.67e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.22e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.99e3 6.10e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.34e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.67e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4218, 8363 scc: 067-110 Revised: 20-Dec-2013 16:07 (LKB) Printed: 03-Jan-2014 17:09 Page 3 of 21 360 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.03e4 PCB-9 5.43e5 SI 16.65 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-14 6.67e5 SI 19.04 PCB-6 5.66e5 SI PCB-5 17.04 6.06e5 SI 17.35 PCB-8 6.24e5 SI 17.47 PCB-11 5.75e5 SI 19.83 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 13/12 1.03e6 SI 20.12 Abs. Int. 2.00e5 PCB-15 5.93e5 SI 20.41 1.00e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% Abs. Int. 2.04e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: B 4σ 4.98e4 PFK INTERFERENCE 1.02e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.13e8 16.63 21.0 0.00e0 RT Abs. Int. 3.67e7 ES-15 1.17e8 20.39 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.06e4 1.83e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.22e7 16.63 21.0 ES-15 7.51e7 20.39 0.00e0 RT Abs. Int. 2.31e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.56e3 1.16e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7888, 3701 scc: 067-110 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 4 of 21 361 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 30/18 6.99e5 19.54 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 4.59e3 PCB-19 2.65e5 17.77 Abs. Int. 1.97e5 PCB-27 4.22e5 20.14 PCB-17 2.89e5 19.95 PCB-16 2.38e5 20.37 PCB-32 4.55e5 20.86 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.74e5 19.54 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 2.66e3 PCB-19 2.58e5 17.77 PCB-17 2.76e5 19.94 PCB-24 3.75e5 20.27 PCB-27 3.92e5 20.14 PCB-16 2.16e5 20.37 21.0 Rel. Int. 100% 18.0 19.0 20.0 PCB-32 4.23e5 20.85 21.0 9.50e4 0.00e0 RT Abs. Int. 1.93e7 ES-19 4.80e7 17.75 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 8.60e4 0.00e0 RT Abs. Int. 1.90e5 0% 17.0 9.86e4 9.63e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.74e7 ES-19 4.42e7 17.75 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 4.22e4 0.00e0 RT 8.69e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5150, 2161 scc: 067-110 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 5 of 21 362 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 28/20 8.12e5 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.52e3 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-23 PCB-34 4.13e5 4.09e5 22.16 22.01 26/29 8.20e5 22.45 PCB-31 4.46e5 22.92 21/33 8.09e5 23.39 Abs. Int. 2.07e5 PCB-22 3.85e5 23.77 PCB-36 4.01e5 25.16 PCB-39 4.25e5 25.48 PCB-38 3.67e5 26.02 PCB-35 3.62e5 26.41 PCB-37 3.75e5 26.77 0% 22.0 24.0 25.0 26.0 27.0 28/20 7.97e5 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 4.06e3 23.0 PCB-23 4.41e5 PCB-34 22.16 3.80e5 22.01 26/29 8.12e5 22.45 PCB-31 4.43e5 22.92 23.0 PCB-22 3.86e5 23.77 PCB-36 4.00e5 25.16 PCB-39 4.16e5 25.48 PCB-38 3.93e5 26.02 24.0 25.0 PCB-35 3.57e5 26.41 PCB-37 3.50e5 26.77 26.0 CS/SS-28 8.29e7 23.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e5 0% 22.0 1.03e5 27.0 0.00e0 RT Abs. Int. 2.37e7 ES-37 7.42e7 26.75 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 1.09e5 1.02e5 1.19e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 7.59e7 23.18 Rel. Int. 100% 27.0 Abs. Int. 2.19e7 ES-37 6.81e7 26.75 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 3.46e4 0.00e0 RT 1.09e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3489, 3011 scc: 067-110 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 6 of 21 363 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-54 2.35e5 20.70 Rel. Int. 100% Abs. Int. 6.46e4 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.55e3 3.23e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.74e5 20.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.82e4 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.17e3 3.91e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.22e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.63e6 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.64e4 4.31e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.06e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 7.86e3 5.58e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5717, 8453 scc: 067-110 Revised: 20-Dec-2013 16:06 (LKB) Printed: 03-Jan-2014 17:09 Page 7 of 21 364 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.01e3 50/53 4.58e5 22.70 PCB-51 2.08e5 23.37 PCB-45 1.99e5 23.29 PCB-73 2.92e5 PCB-52 24.96 2.11e5 24.83 PCB-46 1.82e5 23.57 69/49 4.95e5 25.26 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 44/47… 6.71e5 25.76 59/62… 8.68e5 26.03 PCB-48 2.15e5 25.54 PCB-42 1.96e5 26.20 71/40 4.36e5 26.63 PCB-41 1.83e5 26.54 Abs. Int. 1.53e5 PCB-64 3.04e5 26.83 7.63e4 27.0 0.00e0 RT 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.48e3 50/53 5.66e5 22.70 24.0 PCB-51 2.51e5 23.37 PCB-45 2.53e5 23.29 25.0 PCB-73 3.62e5 PCB-52 24.96 2.79e5 24.83 PCB-46 2.19e5 23.57 26.0 69/49 6.51e5 25.26 59/62… 44/47… 1.08e6 8.65e5 26.03 25.76 PCB-48 2.62e5 25.54 PCB-42 2.42e5 26.20 71/40 5.32e5 26.63 PCB-41 2.10e5 26.54 Abs. Int. 1.85e5 PCB-64 3.70e5 26.83 9.27e4 27.0 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.78e7 24.81 Rel. Int. 100% Abs. Int. 1.00e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 3.08e4 5.01e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 4.64e7 24.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.96e4 6.40e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6598, 8859 scc: 067-110 Revised: 03-Jan-2014 11:21 (LKB) Printed: 03-Jan-2014 17:09 Page 8 of 21 365 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 61/70... 1.21e6 29.06 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.26e3 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-68 3.31e5 27.80 PCB-67 3.10e5 28.54 (2.70e5 + 3.56e5) * 100 pg/uL PCB-78= 1.08 2.71e5 (5.16e7 + 6.38e7) * .5 pg/uL 32.26 PCB-79 03-Jan-2014 11:20 PCB-55LKBPCB-60 PCB-80 PCB-81 2.89e5 3.24e5 2.74e5 3.36e5 2.70e5 30.12 31.77 29.49 30.44 32.64 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 1.49e5 RRF(PCB-81) = PCB-77 2.95e5 33.12 7.45e4 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 2.42e3 PCB-57 3.94e5 28.18 PCB-68 3.96e5 27.80 30.0 61/70... 1.56e6 29.06 PCB-63 4.12e5 PCB-66 3.42e5 28.77 29.34 32.0 PCB-60 3.65e5 30.12 PCB-56 3.60e5 29.93 PCB-80 4.12e5 30.45 PCB-79 4.01e5 31.77 34.0 PCB-78 3.29e5 32.26PCB-81 3.56e5 32.64 36.0 38.0 Abs. Int. 1.90e5 PCB-77 3.88e5 33.12 9.52e4 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 5.16e7 32.62 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.10e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.47e7 ES-77 5.18e7 33.10 7.37e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.38e7 32.62 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 2.52e4 36.0 38.0 0.00e0 RT Abs. Int. 1.79e7 ES-77 6.46e7 33.10 8.96e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0219, 8038 scc: 067-110 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 9 of 21 366 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-104 1.75e5 25.71 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 8.14e2 Abs. Int. 4.89e4 PCB-96 1.63e5 26.03 2.44e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.74e5 25.71 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 9.29e2 27.0 0.00e0 RT Abs. Int. 7.44e4 PCB-96 2.17e5 26.02 3.72e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 3.88e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.91e6 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.55e3 4.96e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.37e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.05e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.87e3 3.03e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5253, 4725 scc: 067-110 Revised: 20-Dec-2013 16:06 (LKB) Printed: 03-Jan-2014 17:09 Page 10 of 21 367 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 108/119... 1.04e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 2.21e3 PCB-103 1.61e5 27.72 100/93 2.88e5 28.51 PCB-88 1.75e5 29.00 PCB-121 2.11e5 30.01 113/90… 5.12e5 30.82 116/85 3.42e5 32.43 PCB-99 1.52e5 31.36 PCB-111 2.21e5 PCB-120 2.13e5 33.14 33.54 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-118 107/124 2.20e5 3.81e5 35.10 34.51 PCB-114 PCB-123 2.18e5 2.12e5 35.57 34.82 Abs. Int. 1.54e5 PCB-105 2.05e5 36.11 PCB-127 1.96e5 37.35 7.68e4 0% 28.0 30.0 32.0 108/119... 1.64e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 4.66e3 34.0 PCB-94 2.12e5 27.91 100/93 4.76e5 28.51 PCB-91 2.21e5 29.06 PCB-121 3.28e5 30.01 113/90… 8.33e5 30.82 PCB-112 3.11e5 31.45 116/85 PCB-115 5.86e5 3.38e5 32.43 32.63 PCB-117 PCB-110 PCB-111 PCB-120 3.40e5 3.00e5 3.06e5 3.24e5 33.14 32.34 32.54 33.54 36.0 PCB-118 107/124 3.27e5 5.97e5 35.10 34.51 PCB-123 PCB-114 3.37e5 3.26e5 34.82 35.57 38.0 Abs. Int. 2.29e5 PCB-105 3.25e5 36.11 PCB-127 3.14e5 37.35 1.14e5 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.86e7 33.12 JS-101 4.75e7 30.82 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.00e3 34.0 36.0 ES-123 5.61e7 34.80 ES-118 ES-114 5.68e7 5.90e7 35.08 35.55 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.47e7 ES-105 5.80e7 36.09 7.34e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 3.66e7 33.12 JS-101 2.91e7 30.82 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.10e3 34.0 36.0 ES-118 ES-114 3.61e7 ES-123 3.46e7 35.55 3.52e7 35.08 34.80 38.0 0.00e0 RT Abs. Int. 9.50e6 ES-105 3.59e7 36.09 4.75e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7393, 8355 scc: 067-110 Revised: 03-Jan-2014 16:46 (LKB) Printed: 03-Jan-2014 17:09 Page 11 of 21 368 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 3.76e4 PCB-126 1.64e5 38.73 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.18e3 1.88e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.47e4 PCB-126 2.67e5 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.48e3 3.23e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.25e7 ES-126 5.01e7 38.71 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 5.64e3 6.27e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.77e6 ES-126 3.21e7 38.71 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 4.88e3 3.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4712, 3338 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 12 of 21 369 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PCB-155 PCB-150 2.97e5 2.89e5 30.98 30.68 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.52e2 PCB-145 2.67e5 31.56 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 163/138… 5.74e5 153/168 PCB-13737.78 4.52e5 1.92e5 36.72 37.41 PCB-160 151/135PCB-144 PCB-164 3.54e5 1.97e5 PCB-143 PCB-142 PCB-133 PCB-146 PCB-141 2.14e5 2.40e5 1.80e5 37.92 1.78e5 1.55e5 33.35 33.83 37.49 1.84e5 1.91e5 36.86 36.16 34.39 34.97 35.61 147/149 139/140 3.75e5 3.92e5 34.65 34.13 PCB-148 1.82e5 32.83 0% 28.0 30.0 32.0 PCB-152 2.17e5 30.84 PCB-136 PCB-155 1.82e5 PCB-145 2.24e5 31.28 2.11e5 30.68 31.56 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 8.44e2 34.0 PCB-148 1.51e5 32.83 139/140 147/149 3.08e5 151/135 2.80e5 34.65 2.92e5 34.13 33.35 PCB-154 PCB-143 PCB-131 1.79e5 1.37e5 1.31e5 33.56 34.39 34.82 36.0 PCB-133 1.47e5 PCB-165 35.61 1.81e5 35.95 38.0 153/168 3.56e5 36.72 163/138… 4.56e5 37.78 PCB-141 PCB-137 1.42e5 1.55e5 37.40 36.86 PCB-158 2.14e5 38.10 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.81e7 30.66 Rel. Int. 100% ES-153 3.32e7 36.67 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.51e3 Abs. Int. 1.11e5 5.57e4 0.00e0 RT Abs. Int. 8.34e4 4.17e4 0.00e0 RT Abs. Int. 1.25e7 JS-138 2.94e7 37.74 6.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.70e7 30.66 Rel. Int. 100% ES-153 2.52e7 36.67 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.03e3 0.00e0 RT Abs. Int. 9.38e6 JS-138 2.20e7 37.74 4.69e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6209, 6582 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 13 of 21 370 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.23e5 38.84 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.22e3 PCB-159 2.50e5 39.65 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-162 2.53e5 39.89 156/157 4.75e5 41.28 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 1.04e5 PCB-169 2.58e5 44.00 PCB-167 2.54e5 40.30 5.20e4 0% 39.0 Rel. Int. 100% 128/166 3.18e5 38.83 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.11e3 40.0 41.0 42.0 43.0 44.0 45.0 156/157 4.04e5 41.28 PCB-159 PCB-162 2.23e5 1.90e5 39.65 39.89 Abs. Int. 7.56e4 PCB-169 1.85e5 44.00 PCB-167 2.28e5 40.30 3.78e4 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 4.87e7 40.28 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 9.39e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 9.32e7 41.26 0.00e0 RT Abs. Int. 1.67e7 ES-169 4.45e7 43.98 8.34e6 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 3.78e7 40.28 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 6.54e3 42.0 43.0 44.0 45.0 ES-156/157 7.11e7 41.26 0.00e0 RT Abs. Int. 1.29e7 ES-169 3.46e7 43.98 6.47e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3213, 6781 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 14 of 21 371 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PCB-188 1.63e5 35.56 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-179 1.52e5 PCB-184 35.84 1.37e5 36.31 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.36e2 PCB-186 1.48e5 37.00 PCB-178 1.17e5 38.13 Abs. Int. 4.15e4 2.08e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.42e5 35.56 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.81e2 PCB-179 1.44e5 35.84 37.0 PCB-176 1.46e5 36.60 PCB-186 1.35e5 37.00 38.0 Abs. Int. 3.92e4 PCB-178 1.02e5 38.13 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.61e7 35.54 Rel. Int. 100% CS/SS-178 1.63e7 38.11 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.35e7 35.54 Rel. Int. 100% CS/SS-178 1.53e7 38.11 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.47e6 0.00e0 RT Abs. Int. 5.99e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.39e3 31.0 1.96e4 Abs. Int. 6.93e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.30e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 2.99e6 0.00e0 RT Abs. Int. 1.89e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.45e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6881, 0191 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 15 of 21 372 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.06e3 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-185 1.38e5 171/173 39.52 2.66e5 PCB-182 1.65e5 PCB-183 PCB-174 PCB-177 PCB-181 40.54 1.69e5 1.35e5 1.58e5 39.09 1.42e5 39.4339.63 40.00 40.35 180/193 3.61e5 42.41 PCB-172 1.41e5 41.89 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-191 2.09e5 42.74 PCB-170 1.34e5 43.51 Abs. Int. 5.93e4 PCB-190 1.94e5 43.97 2.96e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 9.28e2 40.0 PCB-182 1.45e5 39.09 PCB-183 1.60e5 PCB-187 39.43 1.46e5 38.91 41.0 42.0 43.0 180/193 3.54e5 42.41 171/173 PCB-177 PCB-181 2.44e5 1.28e5 1.35e5 40.54 40.00 40.35 PCB-191 1.90e5 42.74 PCB-172 1.32e5 41.89 44.0 45.0 PCB-190 1.90e5 43.97 Abs. Int. 5.34e4 PCB-170 1.22e5 43.52 2.67e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 ES-180 2.95e7 42.43 (2.46e7 + 2.25e7) 8 100 pg/uL RRF(ES-170) = = 0.924 (2.46e7 + 2.64e7) * 100 pg/uL LKB 03-Jan-2014 11:42 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.94e3 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 7.54e6 ES-170 2.46e7 43.50 3.77e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.74e7 42.43 Rel. Int. 100% 44.0 45.0 Abs. Int. 6.83e6 ES-170 2.25e7 43.50 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 1.82e3 0.00e0 RT 3.42e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3799, 6132 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 16 of 21 373 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-189 2.24e5 46.13 Abs. Int. 5.27e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.21e3 2.63e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.18e5 46.13 Abs. Int. 5.43e4 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 7.69e2 2.72e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.19e7 46.11 0.00e0 RT Abs. Int. 1.03e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 3.48e3 5.16e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.02e7 46.11 0.00e0 RT Abs. Int. 9.81e6 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 5.08e3 4.90e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2597, 5520 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 17 of 21 374 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-202 1.25e5 40.11 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 5.85e2 PCB-201 1.58e5 40.90 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 198/199 2.01e5 44.08 PCB-197 1.51e5 PCB-204 41.67 PCB-200 1.28e5 1.29e5 41.76 41.48 Abs. Int. 4.15e4 PCB-196 9.79e4 44.66 PCB-203 9.97e4 44.83 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.33e5 40.11 41.0 PCB-201 1.52e5 40.90 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 8.32e2 42.0 43.0 PCB-197 1.60e5 PCB-204 41.67 PCB-200 1.26e5 1.43e5 41.76 41.48 44.0 198/199 1.96e5 44.08 45.0 2.08e4 0.00e0 RT Abs. Int. 4.09e4 PCB-196 1.09e5 44.66 PCB-203 1.16e5 44.83 2.04e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.37e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.85e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.16e3 2.92e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.57e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.36e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 2.16e3 3.18e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3435, 2261 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 18 of 21 375 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 6.43e2 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-195 1.22e5 45.95 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-205 1.65e5 48.30 PCB-194 1.36e5 47.90 Abs. Int. 3.94e4 1.97e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 9.26e2 47.0 48.0 50.0 PCB-205 1.75e5 48.30 PCB-194 1.41e5 47.90 PCB-195 1.30e5 45.95 49.0 0.00e0 RT Abs. Int. 4.19e4 2.10e4 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.00e7 48.28 JS-194 2.46e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 4.05e3 49.0 0.00e0 RT Abs. Int. 7.11e6 3.56e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.33e7 48.28 Rel. Int. 100% Abs. Int. 7.81e6 JS-194 2.64e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.43e3 0.00e0 RT 3.91e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3437, 5090 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 19 of 21 376 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.06e3 PCB-208 1.46e5 45.75 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-207 1.53e5 46.54 Abs. Int. 3.84e4 PCB-206 9.77e4 49.77 1.92e4 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.83e3 PCB-208 1.75e5 45.74 47.0 48.0 49.0 PCB-207 2.02e5 46.54 50.0 Abs. Int. 4.66e4 PCB-206 1.33e5 49.77 2.33e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.64e7 45.73 50.0 0.00e0 RT Abs. Int. 6.27e6 ES-206 1.90e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.29e3 3.13e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.25e7 45.73 50.0 Abs. Int. 7.77e6 ES-206 2.34e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.08e3 0.00e0 RT 3.89e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6144, 7443 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 20 of 21 377 of 622 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-209 1.84e5 51.25 Rel. Int. 100% Abs. Int. 4.31e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 4.82e2 2.16e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.52e5 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.02e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.04e2 1.51e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.09e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.59e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 8.47e2 3.29e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.60e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.33e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.14e2 2.66e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.18e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.59e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4095, 3490 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 21 of 21 378 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.15e7 2.57e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.58e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.83e7 9.14e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.88e7 9.41e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.05e7 5.26e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.25e6 2.63e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.06e6 2.53e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 983-753 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:09 Page 1 of 21 379 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.12 32.64 36.12 35.58 35.11 34.82 38.73 41.29 40.30 44.01 46.14 51.26 1.44E+06 1.43E+06 1.07E+06 1.23E+06 1.13E+06 1.24E+06 9.39E+05 1.93E+06 1.07E+06 9.43E+05 8.81E+05 6.80E+05 0.79 Y 0.81 Y 0.63 Y 0.64 Y 0.62 Y 0.61 Y 0.63 Y 1.26 Y 1.25 Y 1.29 Y 1.07 Y 1.22 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.11 1.13 1.02 1.16 1.13 1.20 1.07 1.07 1.13 1.07 1.00 1.10 -3.6% 0.8% -7.9% -3.3% -5.3% -1.2% -3.3% -2.5% -2.8% -4.8% -6.6% -1.1% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.05 14.37 14.63 20.39 17.75 26.75 20.68 33.10 32.63 25.69 36.09 35.55 35.09 34.80 38.71 36.68 30.66 41.27 40.28 43.99 43.50 42.43 35.55 46.12 40.09 48.29 49.76 45.73 51.23 2.45E+08 2.19E+08 1.05E+08 2.08E+08 1.01E+08 1.55E+08 8.14E+07 1.30E+08 1.27E+08 6.93E+07 1.04E+08 1.06E+08 1.01E+08 1.03E+08 8.78E+07 6.38E+07 9.19E+07 1.81E+08 9.51E+07 8.81E+07 5.21E+07 6.14E+07 5.38E+07 8.78E+07 5.52E+07 6.89E+07 4.58E+07 6.49E+07 6.17E+07 3.30 Y 3.33 Y 1.62 Y 1.56 Y 1.09 Y 1.10 Y 0.81 Y 0.82 Y 0.82 Y 1.68 Y 1.61 Y 1.64 Y 1.61 Y 1.61 Y 1.58 Y 1.31 Y 1.28 Y 1.29 Y 1.28 Y 1.26 Y 1.09 Y 1.09 Y 1.11 Y 1.03 Y 0.93 Y 0.90 Y 0.81 Y 0.80 Y 1.20 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.22 1.09 0.52 1.04 0.50 1.64 0.86 1.37 1.35 0.80 1.21 1.22 1.17 1.20 1.02 1.11 1.60 1.57 1.65 1.53 0.93 1.10 0.93 1.57 0.96 1.23 0.82 1.16 1.10 2.1% 0.4% -0.1% -0.5% -0.8% -1.1% 0.2% -0.7% -1.5% 0.0% 0.7% 0.5% 0.8% 0.9% -0.9% -0.4% 0.6% -1.9% -1.0% -1.6% -1.8% -3.7% -0.5% -1.0% -1.1% -1.2% -1.4% -1.4% -0.7% Page 1 of 6 380 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.18 33.12 38.12 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.58 Y 1.10 Y 1.11 1.03 0.62 1.12 1.02 0.61 0.7% -0.8% -1.9% CS PCB-28 CS PCB-111 CS PCB-178 23.18 33.12 38.12 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.58 Y 1.10 Y 1.85 1.22 0.58 1.84 1.22 0.57 -0.4% 0.1% -2.4% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.63 24.81 30.82 37.74 47.89 2.01E+08 9.43E+07 8.62E+07 5.75E+07 5.60E+07 1.58 Y 0.81 Y 1.61 Y 1.31 Y 0.90 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.06 14.39 14.65 20.41 17.77 26.77 20.70 25.71 30.68 35.57 40.11 48.31 45.75 49.78 2.30E+06 2.16E+06 1.26E+06 2.04E+06 1.13E+06 1.62E+06 1.09E+06 9.78E+05 1.15E+06 7.09E+05 5.78E+05 7.06E+05 7.23E+05 5.11E+05 3.36 Y 3.09 Y 1.52 Y 1.55 Y 1.07 Y 1.01 Y 0.81 Y 0.64 Y 1.32 Y 1.05 Y 0.95 Y 0.90 Y 0.82 Y 0.79 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.94 0.98 1.20 0.98 1.12 1.05 1.34 1.41 1.25 1.32 1.05 1.03 1.11 1.11 -1.3% -2.5% -2.4% -4.0% -2.6% -3.0% -0.7% -1.5% -1.1% 3.9% -0.5% -3.2% -0.7% 0.0% Page 2 of 6 381 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 12.06 14.20 14.39 14.65 14.83 16.65 16.82 17.04 17.35 17.47 19.04 19.83 20.12 20.41 17.77 19.54 19.95 20.14 20.28 20.37 20.85 22.01 22.16 22.45 22.64 22.93 23.21 23.39 23.77 25.16 25.48 26.02 26.41 26.77 20.70 22.70 23.29 23.37 23.57 24.83 24.97 25.06 25.26 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 2.30E+06 2.22E+06 2.16E+06 1.26E+06 1.99E+06 1.98E+06 2.15E+06 1.96E+06 1.92E+06 2.06E+06 2.37E+06 1.97E+06 4.01E+06 2.04E+06 1.13E+06 2.96E+06 1.29E+06 1.77E+06 1.71E+06 9.51E+05 1.93E+06 1.70E+06 1.69E+06 3.54E+06 1.76E+06 1.79E+06 3.35E+06 3.53E+06 1.63E+06 1.74E+06 1.81E+06 1.68E+06 1.52E+06 1.62E+06 1.09E+06 2.16E+06 9.68E+05 1.04E+06 8.57E+05 1.06E+06 1.35E+06 8.63E+05 2.50E+06 RA 3.36 Y 3.19 Y 3.09 Y 1.52 Y 1.53 Y 1.52 Y 1.55 Y 1.59 Y 1.63 Y 1.64 Y 1.53 Y 1.60 Y 1.64 Y 1.55 Y 1.07 Y 1.02 Y 1.05 Y 1.07 Y 1.05 Y 1.08 Y 1.04 Y 1.01 Y 1.02 Y 1.00 Y 0.93 Y 1.00 Y 0.97 Y 1.00 Y 0.98 Y 0.96 Y 0.98 Y 1.02 Y 0.97 Y 1.01 Y 0.81 Y 0.78 Y 0.81 Y 0.82 Y 0.74 Y 0.77 Y 0.75 Y 0.75 Y 0.75 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.94 1.01 0.98 1.20 1.90 0.95 1.03 0.94 0.92 0.99 1.14 0.95 0.96 0.98 1.12 1.47 1.28 1.76 1.69 0.94 1.91 1.09 1.09 1.14 1.14 1.16 1.08 1.14 1.05 1.12 1.16 1.08 0.98 1.05 1.34 0.85 0.76 0.82 0.68 0.83 1.06 0.68 0.98 Dev'n -1.3% -2.1% -2.5% -2.4% -4.3% 0.8% -1.3% -5.2% -7.9% -4.3% -3.6% -6.2% -2.7% -4.0% -2.6% -4.3% -1.9% -3.4% -1.8% -6.2% -0.2% -3.6% -5.7% -2.6% -1.8% -5.5% -4.5% -3.0% -2.5% -4.1% -3.9% -1.9% -5.4% -3.0% -0.7% -2.9% -0.6% -4.6% -3.4% -1.4% -4.6% -4.4% -3.8% 382 of 622 PCB QC Summary - Ax2 Detail Lab ID: CS1_131220_PCB_XA Acquired: 20-DEC-2013 16:14 Datafile: 131220X03 Name RT PCB-48 22'45-TeCB 25.54 PCB-44/47/65 ...-TeCB 25.76 PCB-59/62/75 ...-TeCB 26.04 PCB-42 22'34'-TeCB 26.20 PCB-41 22'34-TeCB 26.54 PCB-71/40 23'4'6/22'33'-TeCB 26.63 PCB-64 234'6-TeCB 26.83 PCB-72 23'55'-TeCB 27.55 PCB-68 23'45'-TeCB 27.81 PCB-57 233'5-TeCB 28.18 PCB-58 233'5'-TeCB 28.38 PCB-67 23'45-TeCB 28.54 PCB-63 234'5-TeCB 28.77 PCB-61/70/74/76 ...-TeCB 29.06 PCB-66 23'44'-TeCB 29.34 PCB-55 233'4-TeCB 29.49 PCB-56 233'4'-TeCB 29.93 PCB-60 2344'-TeCB 30.12 PCB-80 33'55'-TeCB 30.45 PCB-79 33'45'-TeCB 31.78 PCB-78 33'45-TeCB 32.27 PCB-104 22'466'-PeCB 25.71 PCB-96 22'366'-PeCB 26.03 PCB-103 22'45'6-PeCB 27.72 PCB-94 22'356'-PeCB 27.91 PCB-95 22'35'6-PeCB 28.30 PCB-100/93 22'44'6/22'356-PeCB 28.51 PCB-102 22'456'-PeCB 28.63 PCB-98 22'34'6'-PeCB 28.69 PCB-88 22'346-PeCB 28.99 PCB-91 22'34'6-PeCB 29.06 PCB-84 22'33'6-PeCB 29.25 PCB-89 22'346'-PeCB 29.67 PCB-121 23'45'6-PeCB 30.02 PCB-92 22'355'-PeCB 30.33 PCB-113/90/101 ...-PeCB 30.82 PCB-83 22'33'5-PeCB 31.26 PCB-99 22'44'5-PeCB 31.36 PCB-112 233'56-PeCB 31.46 PCB-108/119/86/97/125...-PeCB 31.80 PCB-117 234'56-PeCB 32.34 PCB-116/85 23456/22'344'-PeCB 32.43 PCB-110 233'4'6-PeCB 32.54 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.01E+06 3.36E+06 4.29E+06 9.26E+05 8.37E+05 2.09E+06 1.50E+06 1.50E+06 1.57E+06 1.41E+06 1.44E+06 1.59E+06 1.60E+06 5.90E+06 1.35E+06 1.40E+06 1.33E+06 1.42E+06 1.64E+06 1.69E+06 1.26E+06 9.78E+05 8.58E+05 9.36E+05 7.83E+05 8.29E+05 1.71E+06 9.57E+05 7.04E+05 7.38E+05 9.82E+05 6.84E+05 7.66E+05 1.19E+06 8.33E+05 2.96E+06 7.27E+05 9.10E+05 1.16E+06 5.82E+06 1.19E+06 1.79E+06 1.10E+06 RA 0.77 Y 0.79 Y 0.80 Y 0.75 Y 0.80 Y 0.82 Y 0.75 Y 0.80 Y 0.77 Y 0.85 Y 0.79 Y 0.76 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.78 Y 0.78 Y 0.76 Y 0.80 Y 0.77 Y 0.64 Y 0.71 Y 0.64 Y 0.65 Y 0.59 Y 0.59 Y 0.62 Y 0.64 Y 0.59 Y 0.56 Y 0.58 Y 0.63 Y 0.67 Y 0.61 Y 0.62 Y 0.67 Y 0.63 Y 0.65 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.79 0.88 1.13 0.73 0.66 0.82 1.18 1.18 1.24 1.11 1.13 1.25 1.26 1.16 1.06 1.10 1.05 1.12 1.29 1.33 0.99 1.41 1.24 0.91 0.76 0.80 0.83 0.93 0.68 0.72 0.95 0.66 0.74 1.15 0.81 0.96 0.70 0.88 1.12 0.94 1.15 0.87 1.07 Dev'n -5.5% -2.5% -3.3% -4.4% -5.2% -4.1% -3.1% -2.1% -3.0% -4.3% -4.0% -0.7% -3.2% -3.0% -3.5% -1.8% -5.4% -1.4% -1.8% 1.6% -6.5% -1.5% 0.8% -2.5% -5.2% -7.3% -4.0% -4.2% -10.0% -10.4% 0.8% -7.4% -2.8% -3.9% -1.6% -2.9% -1.5% -4.2% -3.8% -4.0% 1.3% -7.6% -4.4% 383 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 32.63 32.83 33.15 33.54 34.51 34.72 34.94 35.40 37.35 30.68 30.84 30.98 31.29 31.56 32.83 33.36 33.57 33.83 34.13 34.31 34.39 34.66 34.83 34.98 35.21 35.61 35.95 36.17 36.29 36.72 36.86 37.21 37.41 37.49 37.78 37.92 38.10 38.84 39.65 39.89 35.57 35.85 36.32 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.15E+06 6.91E+05 1.20E+06 1.18E+06 2.12E+06 1.09E+06 1.12E+06 1.01E+06 1.08E+06 1.15E+06 1.03E+06 1.02E+06 8.99E+05 1.00E+06 7.25E+05 1.44E+06 8.24E+05 7.12E+05 1.47E+06 5.72E+05 7.05E+05 1.49E+06 6.51E+05 5.89E+05 6.45E+05 7.07E+05 8.89E+05 7.40E+05 9.19E+05 1.81E+06 6.67E+05 6.08E+05 7.27E+05 9.46E+05 2.21E+06 9.44E+05 1.05E+06 1.64E+06 1.05E+06 9.62E+05 7.09E+05 6.25E+05 5.87E+05 RA 0.66 Y 0.62 Y 0.64 Y 0.65 Y 0.63 Y 0.61 Y 0.63 Y 0.63 Y 0.63 Y 1.32 Y 1.37 Y 1.19 Y 1.33 Y 1.26 Y 1.41 Y 1.27 Y 1.31 Y 1.24 Y 1.29 Y 1.37 Y 1.29 Y 1.23 Y 1.25 Y 1.28 Y 1.26 Y 1.26 Y 1.25 Y 1.25 Y 1.24 Y 1.24 Y 1.26 Y 1.33 Y 1.30 Y 1.33 Y 1.21 Y 1.29 Y 1.33 Y 1.18 Y 1.27 Y 1.13 Y 1.05 Y 1.09 Y 1.02 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.11 0.67 1.17 1.14 1.03 1.05 1.08 0.96 1.04 1.25 1.12 1.10 0.98 1.09 1.14 1.13 1.29 1.12 1.15 0.90 1.10 1.16 1.02 0.92 1.01 1.11 1.39 1.16 1.44 1.42 1.05 0.95 1.14 1.48 1.15 1.48 1.64 0.86 1.11 1.01 1.32 1.16 1.09 Dev'n -4.2% -4.0% -4.5% -5.6% -6.4% -16.1% -2.0% -3.7% -5.5% -1.1% -4.2% -6.1% -8.3% -2.4% -3.9% -1.1% -3.8% -5.7% -2.3% -3.0% -2.2% -3.5% -0.6% -6.8% -2.0% -2.1% -1.1% -3.5% -5.3% -2.7% -4.0% -2.0% -2.1% -1.0% -3.2% -2.3% -1.2% -4.3% -0.8% -5.6% 3.9% 0.1% -3.2% 384 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 36.61 37.01 38.14 38.69 38.91 39.09 39.44 39.52 39.63 40.01 40.36 40.54 41.89 42.14 42.42 42.75 43.52 43.98 40.11 40.90 41.48 41.67 41.76 44.09 44.67 44.84 45.96 47.91 48.31 45.75 46.54 49.78 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 6.55E+05 5.96E+05 4.31E+05 6.43E+05 6.87E+05 6.98E+05 7.24E+05 6.34E+05 6.37E+05 5.78E+05 6.58E+05 1.11E+06 5.95E+05 7.80E+05 1.50E+06 8.57E+05 5.51E+05 8.22E+05 5.78E+05 6.75E+05 6.21E+05 6.41E+05 5.73E+05 8.75E+05 4.40E+05 4.68E+05 5.10E+05 5.61E+05 7.06E+05 7.23E+05 7.50E+05 5.11E+05 RA 1.14 Y 1.00 Y 1.08 Y 1.04 Y 1.08 Y 1.03 Y 1.15 Y 1.02 Y 1.07 Y 1.13 Y 1.09 Y 1.08 Y 1.09 Y 1.06 Y 0.95 Y 1.12 Y 0.98 Y 1.07 Y 0.95 Y 0.92 Y 0.94 Y 0.90 Y 0.90 Y 0.91 Y 0.99 Y 0.92 Y 0.94 Y 0.90 Y 0.90 Y 0.82 Y 0.80 Y 0.79 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.22 1.11 0.80 1.05 1.12 1.14 1.18 1.03 1.04 0.94 1.07 0.90 0.97 1.27 1.22 1.40 1.06 1.58 1.05 1.22 1.13 1.16 1.04 0.79 0.80 0.85 0.74 0.82 1.03 1.11 1.16 1.11 Dev'n -1.2% -1.5% -4.9% -2.3% -1.7% -3.2% -2.1% -2.6% 4.9% -1.0% -1.4% -4.7% -2.0% -1.3% -3.0% 0.1% -6.8% -5.0% -0.5% 0.1% 0.8% -2.4% -6.2% -2.0% -4.4% -3.0% -3.4% -3.3% -3.2% -0.7% -2.9% 0.0% 385 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-1 1.77e6 12.06 Rel. Int. 100% PCB-2 1.69e6 14.20 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.00e3 Abs. Int. 7.15e5 PCB-3 1.63e6 14.39 3.57e5 0% 11.0 12.0 13.0 PCB-1 5.28e5 12.06 Rel. Int. 100% 14.0 PCB-2 5.29e5 14.20 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.63e3 15.0 0.00e0 16.0 RT Abs. Int. 2.17e5 PCB-3 5.27e5 14.38 1.08e5 0% 11.0 12.0 13.0 14.0 ES-1 1.88e8 12.05 Rel. Int. 100% 15.0 Abs. Int. 7.30e7 ES-3 1.69e8 14.37 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.69e3 0.00e0 16.0 RT 3.65e7 0% 11.0 12.0 13.0 14.0 ES-1 5.69e7 12.05 Rel. Int. 100% 15.0 Abs. Int. 2.24e7 ES-3 5.06e7 14.37 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.35e4 0.00e0 16.0 RT 1.12e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2722, 6482 scc: 983-753 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 2 of 21 386 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Rel. Int. 100% PCB-4 7.61e5 14.65 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.83e3 PCB-10 1.20e6 14.83 2.01e5 0% 11.0 12.0 13.0 14.0 Rel. Int. 100% 15.0 PCB-4 5.00e5 14.64 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.52e4 PCB-10 7.85e5 14.83 0% 12.0 13.0 0.00e0 16.0 RT Abs. Int. 2.69e5 1.35e5 PFK INTERFERENCE 11.0 Abs. Int. 4.03e5 14.0 15.0 ES-4 6.48e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.20e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 1.02e4 1.10e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.00e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.35e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.10e3 6.77e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9174, 6214 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:09 Page 3 of 21 387 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 8.83e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-6 1.21e6 17.04 PCB-9 1.20e6 16.65 PCB-14 1.43e6 19.04 PCB-5 1.19e6 17.35 PCB-8 1.28e6 17.47 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-11 1.22e6 19.83 13/12 2.49e6 20.12 Abs. Int. 4.02e5 PCB-15 1.24e6 20.41 2.01e5 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.29e4 PCB-9 7.88e5 16.65 PCB-7 8.44e5 16.82 18.0 19.0 PCB-14 9.38e5 19.04 PCB-5 7.31e5 PCB-8 17.35 7.79e5 17.47 PFK INTERFERENCE 20.0 PCB-11 7.59e5 19.83 13/12 1.52e6 20.12 21.0 Abs. Int. 3.35e5 PCB-15 7.98e5 20.41 1.67e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.23e8 16.63 21.0 0.00e0 RT Abs. Int. 3.85e7 ES-15 1.27e8 20.39 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.10e4 1.93e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.80e7 16.63 21.0 ES-15 8.13e7 20.39 0.00e0 RT Abs. Int. 2.48e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.06e3 1.24e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9567, 5816 scc: 983-753 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 4 of 21 388 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 30/18 1.50e6 19.54 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.85e3 PCB-19 5.82e5 17.77 Abs. Int. 4.10e5 PCB-27 9.13e5 20.14 PCB-17 6.61e5 19.95 PCB-16 4.95e5 20.37 PCB-32 9.84e5 20.85 2.05e5 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 1.47e6 19.54 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 2.47e3 PCB-19 5.45e5 17.76 PCB-17 6.30e5 19.95 21.0 Abs. Int. 4.07e5 PCB-27 8.57e5 20.14 PCB-16 4.56e5 20.37 PCB-32 9.46e5 20.85 2.04e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 2.14e7 ES-19 5.26e7 17.75 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 7.23e4 0.00e0 RT 1.07e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.97e7 ES-19 4.83e7 17.75 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 4.38e4 0.00e0 RT 9.86e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7724, 7248 scc: 983-753 Revised: 27-Dec-2013 11:30 (LKB) Printed: 03-Jan-2014 17:09 Page 5 of 21 389 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 28/20 1.65e6 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.02e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-23 PCB-34 8.55e5 8.51e5 22.16 22.01 26/29 1.77e6 22.45 PCB-31 8.95e5 22.93 Abs. Int. 4.21e5 PCB-22 8.08e5 23.77 PCB-36 8.50e5 25.16 PCB-39 8.93e5 25.48 PCB-38 8.46e5 26.02 PCB-35 7.51e5 26.41 PCB-37 8.13e5 26.77 0% 22.0 24.0 25.0 26.0 27.0 28/20 1.70e6 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.84e3 23.0 PCB-23 PCB-34 8.35e5 8.46e5 22.16 22.01 26/29 1.77e6 22.45 PCB-31 9.00e5 22.92 23.0 PCB-22 8.24e5 23.77 PCB-36 8.89e5 25.16 PCB-39 9.12e5 25.48 PCB-38 8.33e5 26.02 24.0 25.0 PCB-35 7.74e5 26.41 PCB-37 8.08e5 26.77 26.0 CS/SS-28 9.06e7 23.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.28e5 0% 22.0 2.11e5 27.0 0.00e0 RT Abs. Int. 2.54e7 ES-37 8.13e7 26.75 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 1.13e5 2.14e5 1.27e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.29e7 23.18 Rel. Int. 100% 27.0 Abs. Int. 2.36e7 ES-37 7.38e7 26.75 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 3.74e4 0.00e0 RT 1.18e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2047, 2588 scc: 983-753 Revised: 27-Dec-2013 11:30 (LKB) Printed: 03-Jan-2014 17:09 Page 6 of 21 390 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-54 4.89e5 20.70 Rel. Int. 100% Abs. Int. 1.37e5 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.36e3 6.83e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 6.03e5 20.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e5 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.17e3 9.39e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.65e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 2.02e4 5.12e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.49e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 8.82e3 6.20e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7968, 7088 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:09 Page 7 of 21 391 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 1.58e3 50/53 9.50e5 22.70 PCB-51 4.70e5 23.37 PCB-45 4.32e5 23.29 PCB-73 PCB-52 5.78e5 4.59e5 24.97 24.83 PCB-46 3.64e5 23.57 69/49 1.07e6 25.26 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 44/47… 1.48e6 25.76 59/62… 1.91e6 26.04 PCB-48 4.38e5 25.54 PCB-42 3.97e5 26.20 71/40 9.42e5 26.63 PCB-41 3.71e5 26.54 Abs. Int. 3.53e5 PCB-64 6.46e5 26.83 1.77e5 27.0 0.00e0 RT 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.72e3 50/53 1.21e6 22.70 24.0 PCB-51 5.71e5 23.37 PCB-45 5.36e5 23.29 25.0 PCB-73 7.69e5 PCB-52 24.97 5.98e5 24.83 PCB-46 4.93e5 23.57 26.0 69/49 1.42e6 25.26 59/62… 44/47… 2.38e6 1.87e6 26.04 25.76 PCB-48 5.68e5 25.54 PCB-42 5.29e5 26.20 71/40 1.15e6 26.63 PCB-41 4.66e5 26.54 Abs. Int. 4.32e5 PCB-64 8.56e5 26.83 2.16e5 27.0 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.22e7 24.81 Rel. Int. 100% Abs. Int. 1.13e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.67e4 5.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.21e7 24.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.42e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 2.28e4 7.10e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4359, 5676 scc: 983-753 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 8 of 21 392 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 61/70... 2.59e6 29.06 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 3.33e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-57 6.50e5 28.18 PCB-63 7.04e5 28.77 PCB-55 6.16e5 29.49 Abs. Int. 3.24e5 PCB-60 6.21e5 PCB-80 7.09e5 30.12 30.45 PCB-81 6.42e5 32.64 PCB-79 7.50e5 31.78 PCB-77 6.36e5 33.12 1.62e5 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 2.68e3 PCB-68 8.90e5 27.81 30.0 61/70... 3.32e6 PCB-60 PCB-67 29.06 8.00e5 9.01e5 30.12 28.54 PCB-63 PCB-66 PCB-80 PCB-56 8.91e5 7.50e5 9.28e5 7.48e5 28.77 29.34 30.45 29.93 32.0 34.0 36.0 38.0 Abs. Int. 4.24e5 PCB-81 7.90e5 32.64 PCB-79 9.35e5 31.78 PCB-77 8.03e5 33.12 2.12e5 0% 28.0 30.0 0.00e0 RT 32.0 Rel. Int. 100% 34.0 ES-81 5.70e7 32.63 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.49e4 36.0 38.0 0.00e0 RT Abs. Int. 1.53e7 ES-77 5.83e7 33.10 7.63e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.00e7 32.63 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.91e4 36.0 38.0 0.00e0 RT Abs. Int. 1.88e7 ES-77 7.13e7 33.10 9.38e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8043, 1494 scc: 983-753 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:31 Printed: 03-Jan-2014 17:10 Page 9 of 21 393 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-104 3.83e5 25.71 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 9.09e2 Abs. Int. 9.50e4 PCB-96 3.57e5 26.03 4.75e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 5.96e5 25.71 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 8.81e2 27.0 0.00e0 RT Abs. Int. 1.52e5 PCB-96 5.01e5 26.03 7.58e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.34e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.97e3 5.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.59e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.60e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 1.70e3 3.30e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7311, 3592 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:10 Page 10 of 21 394 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 5.53e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 108/119... 2.22e6 31.80 (4.35e5 + 6.99e5) * 100 pg/uL RRF(PCB-118) = = 1.13 (6.20e7 + 3.86e7) * 1.0 pg/uL 113/90… 100/9311:45 LKB 03-Jan-2014 1.13e6 6.34e5 30.82 PCB-121 PCB-99 28.51 PCB-88 PCB-103 4.78e5 3.53e5 3.66e5 30.02 2.75e5 31.36 27.72 28.99 116/85 6.89e5 32.43 PCB-111 4.71e5 PCB-120 33.15 4.66e5 33.54 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-118 107/124 4.35e5 8.23e5 35.11 34.51 PCB-123 PCB-114 4.68e5 4.77e5 34.82 35.58 Abs. Int. 3.39e5 PCB-105 4.12e5 36.12 PCB-127 4.20e5 37.35 1.70e5 0% 28.0 30.0 32.0 108/119... 3.61e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 7.14e3 34.0 PCB-94 4.74e5 27.91 100/93 1.08e6 28.51 PCB-91 6.28e5 29.06 PCB-89 4.69e5 29.67 113/90… 1.83e6 30.82 PCB-112 PCB-92 7.02e5 5.18e5 31.46 30.33 116/85 PCB-115 1.10e6 6.93e5 32.43 32.63 PCB-110 PCB-111 PCB-117 7.33e5 PCB-120 6.81e5 7.35e5 7.14e5 33.14 32.54 32.34 33.54 36.0 PCB-118 107/124 6.99e5 1.30e6 35.11 34.51 PCB-123 PCB-114 7.67e5 7.51e5 34.82 35.58 38.0 Abs. Int. 5.56e5 PCB-105 6.57e5 36.12 PCB-127 6.61e5 37.35 2.78e5 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 6.46e7 33.12 JS-101 5.31e7 30.82 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.82e3 34.0 36.0 ES-123 6.36e7 34.80 ES-114 6.56e7 35.55 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.61e7 ES-105 6.43e7 36.09 8.07e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.08e7 33.12 JS-101 3.31e7 30.82 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.71e3 34.0 36.0 ES-118 ES-123 3.86e7 3.96e7 35.09 34.80 38.0 0.00e0 RT Abs. Int. 1.02e7 ES-105 4.00e7 36.09 5.09e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7344, 6760 scc: 983-753 Revised: 30-Dec-2013 13:07 (LKB) Printed: 03-Jan-2014 17:10 Page 11 of 21 395 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Abs. Int. 9.23e4 PCB-126 3.63e5 38.73 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.27e3 4.61e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.52e5 PCB-126 5.76e5 38.73 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.57e3 7.61e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.28e7 ES-126 5.38e7 38.71 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.43e3 6.40e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.29e6 ES-126 3.40e7 38.71 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 7.41e3 4.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0821, 7826 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 12 of 21 396 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-136 5.13e5 31.29 PCB-155 PCB-150 5.51e5 PCB-145 6.53e5 30.98 5.58e5 30.68 31.56 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.22e2 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 147/149 139/140 8.25e5 8.18e5 34.13 34.66 PCB-148 4.24e5 32.83 151/135 8.04e5 PCB-144 PCB-143 PCB-133 PCB-146 33.36 3.94e5 3.96e5 PCB-142 3.94e5 4.11e5 3.30e5 36.17 33.83 34.39 35.61 34.98 153/168 1.00e6 36.72 PCB-141 3.72e5 36.86 163/138… 1.21e6 37.78 PCB-164 PCB-160 5.40e5 5.32e5 37.49 37.92 1.11e5 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PCB-150 PCB-155 4.64e5 4.93e5 30.98 30.68 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 8.63e2 PCB-145 4.42e5 31.56 PCB-148 3.01e5 32.83 147/149 139/140 151/135 6.41e5 6.67e5 6.33e5 34.66 34.13 33.35 PCB-154 PCB-143 PCB-132 3.56e5 3.08e5 2.85e5 33.57 34.39 35.21 36.0 38.0 153/168 8.09e5 36.72 PCB-165 3.96e5 35.95 163/138… 1.00e6 37.78 PCB-137 PCB-141 3.17e5 2.95e5 37.41 36.86 30.0 32.0 34.0 36.0 ES-155 5.16e7 30.66 Rel. Int. 100% HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.53e3 Abs. Int. 1.88e5 9.41e4 38.0 ES-153 3.62e7 36.68 0.00e0 RT PCB-158 4.50e5 38.10 0% 28.0 Abs. Int. 2.21e5 JS-138 3.26e7 37.74 0.00e0 RT Abs. Int. 1.25e7 6.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.04e7 30.66 Rel. Int. 100% ES-153 2.76e7 36.68 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.37e3 0.00e0 RT Abs. Int. 9.99e6 JS-138 2.49e7 37.74 4.99e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4865, 1501 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 13 of 21 397 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 8.84e5 38.84 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.56e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-162 PCB-159 5.10e5 5.87e5 39.89 39.65 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 156/157 1.08e6 41.29 Abs. Int. 2.09e5 PCB-167 5.96e5 40.30 PCB-169 5.31e5 44.01 1.04e5 0% 39.0 Rel. Int. 100% 128/166 7.52e5 38.84 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.20e3 40.0 PCB-162 PCB-159 4.52e5 39.89 4.64e5 39.65 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.82e5 156/157 8.55e5 41.28 PCB-169 4.12e5 44.00 PCB-167 4.78e5 40.30 9.11e4 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.33e7 40.28 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 8.34e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.02e8 41.27 (1.02e8 + 7.90e7) * 100 pg/uL RRF(ES-156/157) = = 1.57 (3.26e7 + 2.49e7) * 200 pg/uL LKB 03-Jan-2014 11:48 0.00e0 RT Abs. Int. 1.85e7 ES-169 4.92e7 43.99 9.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 7.90e7 41.27 Rel. Int. 100% ES-167 4.18e7 40.28 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 9.96e3 0.00e0 RT Abs. Int. 1.47e7 ES-169 3.89e7 43.99 7.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2729, 9872 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 14 of 21 398 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% PCB-188 3.62e5 35.57 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.15e2 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-179 3.26e5 PCB-184 2.97e5 35.85 36.32 PCB-186 2.98e5 37.01 Abs. Int. 8.73e4 PCB-178 2.24e5 38.14 4.37e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 3.46e5 35.57 PCB-179 2.99e5 35.85 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.25e2 37.0 PCB-176 3.06e5 36.61 PCB-186 2.98e5 37.01 38.0 Abs. Int. 8.68e4 PCB-178 2.07e5 38.14 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.82e7 35.55 Rel. Int. 100% CS/SS-178 1.71e7 38.12 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.55e7 35.55 Rel. Int. 100% CS/SS-178 1.56e7 38.12 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.55e6 0.00e0 RT Abs. Int. 6.62e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.42e3 31.0 4.34e4 Abs. Int. 7.11e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.34e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 3.31e6 0.00e0 RT Abs. Int. 1.88e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6233, 0370 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 15 of 21 399 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.17e3 PCB-182 PCB-183 3.55e5 3.87e5 39.44 39.09 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-177 PCB-181 3.06e5 3.43e5 40.01 40.36 171/173 5.75e5 40.54 PCB-172 3.10e5 41.89 180/193 7.33e5 42.42 PCB-192 4.01e5 42.14 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Abs. Int. 1.52e5 PCB-191 4.53e5 42.75 PCB-170 2.72e5 43.52 PCB-190 4.24e5 43.98 7.59e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.47e3 40.0 41.0 PCB-182 PCB-185 3.14e5 3.43e5 171/173 39.52 39.09 5.34e5 PCB-187 PCB-181 40.54 PCB-183 3.31e5 PCB-174 PCB-177 3.15e5 3.37e5 38.91 3.08e5 40.36 2.71e5 39.4439.63 40.01 42.0 43.0 180/193 7.69e5 42.42 PCB-172 2.85e5 41.89 PCB-191 4.05e5 42.75 44.0 45.0 Abs. Int. 1.26e5 PCB-190 3.97e5 43.98 PCB-170 2.79e5 43.52 6.28e4 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.20e7 42.43 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 8.23e6 ES-170 2.71e7 43.50 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 2.53e3 0.00e0 RT 4.12e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.93e7 42.43 Rel. Int. 100% 44.0 45.0 Abs. Int. 7.29e6 ES-170 2.50e7 43.50 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.41e3 0.00e0 RT 3.64e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7891, 3827 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 16 of 21 400 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-189 4.54e5 46.14 Abs. Int. 1.16e5 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.02e3 5.81e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 4.26e5 46.14 Abs. Int. 1.09e5 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 8.26e2 5.43e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.46e7 46.12 0.00e0 RT Abs. Int. 1.06e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 6.63e3 5.31e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.32e7 46.12 0.00e0 RT Abs. Int. 1.01e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.18e3 5.03e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5887, 3655 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 17 of 21 401 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-202 2.82e5 40.11 Rel. Int. 100% PCB-201 3.23e5 40.90 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 7.19e2 PCB-197 3.04e5 PCB-204 41.67 PCB-200 3.00e5 2.72e5 41.48 41.76 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 198/199 4.18e5 44.09 Abs. Int. 8.33e4 PCB-196 2.19e5 44.67 PCB-203 2.24e5 44.84 0% 39.0 Rel. Int. 100% 40.0 PCB-202 2.96e5 40.11 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.84e2 41.0 PCB-201 3.52e5 40.90 42.0 43.0 44.0 45.0 198/199 4.57e5 44.09 PCB-197 3.38e5PCB-200 PCB-204 41.67 3.01e5 3.20e5 41.76 41.48 40.0 41.0 42.0 PCB-196 2.21e5 44.66 43.0 44.0 PCB-203 2.44e5 44.84 4.51e4 45.0 ES-202 2.66e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.01e4 0% 39.0 4.17e4 0.00e0 RT Abs. Int. 6.53e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.52e3 3.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.85e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.30e3 3.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3815, 7054 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 18 of 21 402 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 8.34e2 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-205 3.35e5 48.31 PCB-195 2.47e5 45.96 Abs. Int. 7.93e4 PCB-194 2.65e5 47.91 3.97e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 7.51e2 47.0 48.0 49.0 50.0 PCB-205 3.71e5 48.31 PCB-195 2.63e5 45.96 0.00e0 RT Abs. Int. 9.00e4 PCB-194 2.96e5 47.91 4.50e4 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.26e7 48.29 Rel. Int. 100% Abs. Int. 7.66e6 JS-194 2.66e7 47.89 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.09e3 0.00e0 RT 3.83e6 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.63e7 48.29 JS-194 2.94e7 47.89 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.82e3 49.0 0.00e0 RT Abs. Int. 8.37e6 4.19e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1382, 4116 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 19 of 21 403 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.01e3 PCB-208 3.26e5 45.75 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-207 3.34e5 46.54 Abs. Int. 8.61e4 PCB-206 2.25e5 49.78 4.30e4 0% 46.0 Rel. Int. 100% PCB-208 3.97e5 45.75 47.0 48.0 49.0 PCB-207 4.16e5 46.54 50.0 Abs. Int. 1.01e5 PCB-206 2.86e5 49.78 NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.89e3 5.06e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.87e7 45.73 50.0 0.00e0 RT Abs. Int. 6.89e6 ES-206 2.06e7 49.76 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.22e3 3.45e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.61e7 45.73 50.0 Abs. Int. 8.47e6 ES-206 2.53e7 49.76 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.67e3 0.00e0 RT 4.24e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0808, 5245 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 20 of 21 404 of 622 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-209 3.74e5 51.26 Rel. Int. 100% Abs. Int. 7.55e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.21e2 3.77e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 3.06e5 51.26 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.81e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.94e2 3.41e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.36e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.01e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 8.10e2 3.50e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.81e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.76e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.63e2 2.88e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.06e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.53e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6986, 0137 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 21 of 21 405 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.11 32.63 36.11 35.56 35.10 34.82 38.72 41.28 40.29 44.00 46.13 51.25 7.18E+06 6.81E+06 5.68E+06 6.19E+06 5.72E+06 5.95E+06 4.77E+06 9.62E+06 5.42E+06 4.85E+06 4.61E+06 3.38E+06 0.79 Y 0.77 Y 0.64 Y 0.62 Y 0.60 Y 0.63 Y 0.62 Y 1.25 Y 1.21 Y 1.23 Y 1.02 Y 1.17 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.09 1.08 1.07 1.15 1.13 1.16 1.05 1.05 1.12 1.09 1.03 1.06 -5.2% -3.8% -4.0% -4.1% -5.1% -3.9% -5.1% -4.7% -3.2% -3.1% -3.6% -4.8% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.04 14.36 14.61 20.38 17.73 26.74 20.66 33.09 32.61 25.67 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.26 40.27 43.98 43.49 42.42 35.54 46.11 40.08 48.28 49.75 45.73 51.23 2.39E+08 2.19E+08 1.04E+08 2.08E+08 1.01E+08 1.56E+08 8.13E+07 1.31E+08 1.27E+08 7.00E+07 1.06E+08 1.07E+08 1.01E+08 1.02E+08 9.09E+07 6.37E+07 9.19E+07 1.84E+08 9.64E+07 8.90E+07 5.32E+07 6.31E+07 5.40E+07 8.91E+07 5.60E+07 7.02E+07 4.73E+07 6.67E+07 6.37E+07 3.26 Y 3.37 Y 1.62 Y 1.56 Y 1.08 Y 1.09 Y 0.82 Y 0.80 Y 0.80 Y 1.67 Y 1.61 Y 1.65 Y 1.61 Y 1.58 Y 1.58 Y 1.31 Y 1.33 Y 1.30 Y 1.30 Y 1.30 Y 1.08 Y 1.09 Y 1.06 Y 1.03 Y 0.94 Y 0.89 Y 0.81 Y 0.80 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.21 1.10 0.53 1.05 0.51 1.68 0.88 1.42 1.36 0.82 1.25 1.26 1.19 1.20 1.07 1.13 1.63 1.63 1.71 1.58 0.96 1.13 0.96 1.60 0.99 1.26 0.85 1.20 1.14 1.3% 1.5% 0.5% 0.9% 0.4% 1.0% 1.7% 2.5% -0.2% 2.2% 3.7% 3.3% 2.4% 1.1% 3.7% 1.3% 2.5% 1.9% 2.3% 1.3% 1.0% -0.4% 1.8% 1.0% 2.3% 1.3% 2.3% 1.9% 3.2% Page 1 of 6 406 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.11 38.10 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.62 Y 1.12 Y 1.11 1.03 0.62 1.11 1.03 0.61 -0.2% 0.0% -2.3% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.11 38.10 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.62 Y 1.12 Y 1.85 1.22 0.58 1.86 1.23 0.58 0.9% 1.1% -0.5% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.81 37.73 47.88 1.98E+08 9.28E+07 8.53E+07 5.64E+07 5.57E+07 1.57 Y 0.79 Y 1.59 Y 1.31 Y 0.92 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.05 14.37 14.63 20.39 17.75 26.76 20.68 25.69 30.67 35.56 40.10 48.30 45.75 49.78 1.11E+07 1.07E+07 6.23E+06 1.02E+07 5.64E+06 8.15E+06 5.32E+06 4.90E+06 5.67E+06 3.30E+06 2.80E+06 3.53E+06 3.57E+06 2.55E+06 3.29 Y 3.19 Y 1.60 Y 1.65 Y 1.05 Y 0.98 Y 0.81 Y 0.65 Y 1.29 Y 1.10 Y 0.89 Y 0.93 Y 0.81 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.92 0.98 1.20 0.98 1.12 1.05 1.31 1.40 1.23 1.22 1.00 1.01 1.07 1.08 -2.9% -3.0% -2.9% -4.3% -2.5% -2.9% -3.2% -2.3% -2.2% -3.7% -5.1% -5.1% -4.7% -3.2% Page 2 of 6 407 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 12.05 14.18 14.37 14.63 14.81 16.63 16.80 17.03 17.33 17.45 19.02 19.81 20.11 20.39 17.75 19.52 19.93 20.12 20.26 20.35 20.84 21.99 22.14 22.43 22.63 22.91 23.19 23.38 23.75 25.14 25.46 26.00 26.39 26.76 20.68 22.68 23.27 23.34 23.55 24.82 24.94 25.04 25.24 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 1.11E+07 1.07E+07 1.07E+07 6.23E+06 1.01E+07 9.38E+06 1.06E+07 9.98E+06 1.00E+07 1.05E+07 1.19E+07 1.03E+07 2.02E+07 1.02E+07 5.64E+06 1.52E+07 6.40E+06 8.92E+06 8.42E+06 5.03E+06 9.31E+06 8.68E+06 8.57E+06 1.76E+07 8.79E+06 9.29E+06 1.69E+07 1.76E+07 8.06E+06 8.80E+06 9.00E+06 8.25E+06 7.78E+06 8.15E+06 5.32E+06 1.07E+07 4.46E+06 5.62E+06 4.33E+06 5.19E+06 6.70E+06 4.56E+06 1.26E+07 RA 3.29 Y 3.30 Y 3.19 Y 1.60 Y 1.59 Y 1.58 Y 1.65 Y 1.58 Y 1.62 Y 1.60 Y 1.61 Y 1.64 Y 1.61 Y 1.65 Y 1.05 Y 1.08 Y 1.08 Y 1.07 Y 1.05 Y 1.05 Y 1.07 Y 0.97 Y 1.00 Y 0.99 Y 0.95 Y 0.97 Y 1.00 Y 0.99 Y 1.00 Y 0.98 Y 0.97 Y 0.97 Y 1.00 Y 0.98 Y 0.81 Y 0.80 Y 0.79 Y 0.80 Y 0.78 Y 0.79 Y 0.79 Y 0.75 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.92 0.98 0.98 1.20 1.93 0.90 1.02 0.96 0.96 1.00 1.15 0.99 0.97 0.98 1.12 1.51 1.27 1.77 1.67 1.00 1.85 1.11 1.10 1.13 1.13 1.19 1.08 1.13 1.04 1.13 1.16 1.06 1.00 1.05 1.31 0.84 0.70 0.89 0.68 0.82 1.06 0.72 0.99 Dev'n -2.9% -5.2% -3.0% -2.9% -2.5% -4.6% -2.9% -3.7% -3.7% -2.7% -2.9% -1.9% -1.7% -4.3% -2.5% -1.8% -2.7% -2.6% -3.0% -0.7% -3.7% -1.9% -4.7% -3.4% -2.4% -2.7% -4.3% -3.7% -4.1% -3.4% -4.5% -4.0% -3.9% -2.9% -3.2% -3.9% -8.2% 3.3% -2.0% -2.8% -4.8% 1.4% -2.8% 408 of 622 PCB QC Summary - Ax2 Detail Lab ID: CS2_131220_PCB_XA Acquired: 20-DEC-2013 17:09 Datafile: 131220X04 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.02 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.52 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.79 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.37 PCB-67 23'45-TeCB 28.52 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.05 PCB-66 23'44'-TeCB 29.33 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.11 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.76 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.01 PCB-103 22'45'6-PeCB 27.71 PCB-94 22'356'-PeCB 27.90 PCB-95 22'35'6-PeCB 28.28 PCB-100/93 22'44'6/22'356-PeCB 28.50 PCB-102 22'456'-PeCB 28.61 PCB-98 22'34'6'-PeCB 28.68 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.24 PCB-89 22'346'-PeCB 29.66 PCB-121 23'45'6-PeCB 30.00 PCB-92 22'355'-PeCB 30.32 PCB-113/90/101 ...-PeCB 30.81 PCB-83 22'33'5-PeCB 31.25 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.79 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.42 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.24E+06 1.64E+07 2.14E+07 4.75E+06 4.38E+06 1.05E+07 7.49E+06 7.51E+06 7.85E+06 7.33E+06 7.30E+06 7.81E+06 7.85E+06 2.94E+07 6.87E+06 7.07E+06 6.96E+06 7.00E+06 8.09E+06 8.10E+06 6.61E+06 4.90E+06 4.21E+06 4.65E+06 4.04E+06 4.36E+06 8.64E+06 5.08E+06 3.64E+06 3.75E+06 4.80E+06 3.58E+06 3.81E+06 5.96E+06 4.05E+06 1.47E+07 3.64E+06 4.49E+06 5.95E+06 2.92E+07 5.88E+06 9.01E+06 5.43E+06 RA 0.81 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.81 Y 0.79 Y 0.80 Y 0.75 Y 0.77 Y 0.76 Y 0.77 Y 0.76 Y 0.79 Y 0.76 Y 0.79 Y 0.77 Y 0.78 Y 0.80 Y 0.78 Y 0.79 Y 0.65 Y 0.65 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.63 Y 0.64 Y 0.65 Y 0.63 Y 0.61 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.59 Y 0.64 Y 0.63 Y 0.62 Y 0.62 Y 0.64 Y 0.63 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.83 0.86 1.13 0.75 0.69 0.83 1.18 1.19 1.24 1.16 1.15 1.23 1.24 1.16 1.09 1.12 1.10 1.11 1.28 1.28 1.04 1.40 1.20 0.91 0.79 0.85 0.85 0.99 0.71 0.73 0.94 0.70 0.75 1.16 0.79 0.96 0.71 0.88 1.16 0.95 1.15 0.88 1.06 Dev'n -1.3% -4.4% -3.2% -1.7% -0.5% -3.8% -3.0% -1.9% -2.8% -0.5% -2.1% -2.0% -4.4% -3.0% -1.5% -0.3% -1.0% -2.5% -2.7% -2.0% -1.6% -2.3% -2.0% -2.2% -1.3% -1.5% -2.1% 2.6% -6.0% -8.2% -0.5% -2.1% -2.3% -2.9% -3.5% -2.5% -0.4% -4.7% -0.4% -2.9% 1.1% -6.3% -5.0% 409 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 32.62 32.82 33.13 33.53 34.50 34.71 34.93 35.39 37.34 30.67 30.82 30.97 31.27 31.55 32.82 33.34 33.55 33.82 34.12 34.29 34.38 34.64 34.82 34.96 35.20 35.60 35.94 36.16 36.28 36.71 36.85 37.20 37.40 37.48 37.77 37.91 38.09 38.83 39.64 39.88 35.56 35.84 36.30 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.94E+06 3.45E+06 6.10E+06 6.04E+06 1.09E+07 6.46E+06 5.32E+06 5.09E+06 5.46E+06 5.67E+06 5.18E+06 5.27E+06 4.80E+06 4.89E+06 3.69E+06 7.14E+06 4.14E+06 3.74E+06 7.38E+06 2.81E+06 3.63E+06 7.45E+06 3.13E+06 3.09E+06 3.22E+06 3.47E+06 4.45E+06 3.72E+06 4.78E+06 9.14E+06 3.40E+06 3.05E+06 3.51E+06 4.84E+06 1.09E+07 4.74E+06 5.15E+06 8.23E+06 5.14E+06 4.97E+06 3.30E+06 3.06E+06 2.96E+06 RA 0.60 Y 0.62 Y 0.63 Y 0.64 Y 0.62 Y 0.62 Y 0.64 Y 0.64 Y 0.62 Y 1.29 Y 1.28 Y 1.27 Y 1.26 Y 1.31 Y 1.28 Y 1.23 Y 1.24 Y 1.28 Y 1.29 Y 1.29 Y 1.26 Y 1.28 Y 1.29 Y 1.24 Y 1.28 Y 1.26 Y 1.24 Y 1.30 Y 1.30 Y 1.28 Y 1.30 Y 1.25 Y 1.28 Y 1.28 Y 1.27 Y 1.26 Y 1.28 Y 1.25 Y 1.24 Y 1.21 Y 1.10 Y 1.09 Y 1.03 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.16 0.67 1.19 1.18 1.07 1.26 1.04 0.95 1.03 1.23 1.13 1.15 1.04 1.06 1.16 1.12 1.30 1.17 1.16 0.88 1.14 1.17 0.98 0.97 1.01 1.09 1.40 1.17 1.50 1.43 1.07 0.96 1.10 1.52 1.14 1.49 1.62 0.85 1.07 1.03 1.22 1.13 1.10 Dev'n 0.3% -3.3% -2.3% -2.5% -2.9% 0.8% -5.8% -4.5% -6.2% -2.2% -3.8% -2.5% -2.1% -4.5% -2.2% -1.6% -3.2% -0.8% -1.6% -4.5% 0.8% -3.0% -4.2% -1.9% -2.1% -3.9% -0.9% -2.9% -1.4% -1.6% -2.0% -1.7% -5.3% 1.3% -3.9% -1.7% -2.7% -5.1% -4.4% -3.7% -3.7% -2.3% -2.6% 410 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 36.60 37.00 38.13 38.67 38.90 39.08 39.43 39.52 39.62 40.00 40.35 40.53 41.88 42.13 42.41 42.74 43.51 43.97 40.10 40.89 41.47 41.66 41.75 44.08 44.66 44.83 45.95 47.90 48.30 45.75 46.54 49.78 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 3.29E+06 2.98E+06 2.21E+06 3.31E+06 3.49E+06 3.67E+06 3.83E+06 3.13E+06 3.03E+06 2.93E+06 3.27E+06 5.79E+06 2.98E+06 4.03E+06 7.75E+06 4.20E+06 2.91E+06 4.21E+06 2.80E+06 3.33E+06 3.01E+06 3.09E+06 3.13E+06 4.38E+06 2.29E+06 2.39E+06 2.57E+06 2.84E+06 3.53E+06 3.57E+06 3.79E+06 2.55E+06 RA 1.07 Y 1.06 Y 1.08 Y 1.06 Y 0.96 Y 1.07 Y 1.05 Y 1.08 Y 1.07 Y 1.10 Y 1.08 Y 1.06 Y 1.07 Y 1.06 Y 1.08 Y 1.05 Y 1.04 Y 1.06 Y 0.89 Y 0.92 Y 0.94 Y 0.91 Y 0.89 Y 0.92 Y 0.94 Y 0.93 Y 0.90 Y 0.87 Y 0.93 Y 0.81 Y 0.76 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.22 1.10 0.82 1.05 1.11 1.16 1.21 0.99 0.96 0.93 1.04 0.92 0.95 1.28 1.23 1.33 1.09 1.58 1.00 1.19 1.08 1.11 1.12 0.78 0.82 0.85 0.73 0.81 1.01 1.07 1.14 1.08 Dev'n -1.2% -1.9% -2.7% -2.3% -2.9% -1.0% 0.7% -6.4% -2.8% -2.3% -4.9% -3.1% -4.3% -0.7% -2.6% -4.6% -3.7% -4.7% -5.1% -2.7% -3.6% -7.1% 1.0% -3.4% -1.8% -2.2% -4.5% -4.1% -5.1% -4.7% -4.4% -3.2% 411 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.95e7 2.47e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.50e7 1.25e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.78e7 8.90e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.83e7 9.17e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.06e7 5.32e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.51e6 2.75e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.31e6 2.65e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 288-489 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:10 Page 1 of 21 412 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-1 8.49e6 12.05 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-2 8.22e6 14.18 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.63e3 Abs. Int. 3.53e6 PCB-3 8.15e6 14.37 1.77e6 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.58e6 12.05 Rel. Int. 100% PCB-2 2.50e6 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.76e3 0.00e0 16.0 RT Abs. Int. 1.06e6 PCB-3 2.55e6 14.37 5.29e5 0% 11.0 12.0 13.0 14.0 ES-1 1.83e8 12.04 Rel. Int. 100% 15.0 Abs. Int. 7.14e7 ES-3 1.69e8 14.36 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.48e3 0.00e0 16.0 RT 3.57e7 0% 11.0 12.0 13.0 14.0 ES-1 5.63e7 12.04 Rel. Int. 100% 15.0 Abs. Int. 2.26e7 ES-3 5.01e7 14.36 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.97e4 0.00e0 16.0 RT 1.13e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.47e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5986, 8076 scc: 288-489 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 2 of 21 413 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. 100% PCB-4 3.84e6 14.63 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.13e3 PCB-10 6.17e6 14.81 1.01e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.89e6 14.81 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.22e4 PCB-4 2.39e6 14.63 12.0 13.0 14.0 15.0 ES-4 6.43e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.30e6 6.50e5 0% 11.0 Abs. Int. 2.02e6 0.00e0 16.0 RT Abs. Int. 2.12e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 1.16e4 1.06e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.98e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.35e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.62e3 6.76e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.47e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2760, 4750 scc: 288-489 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 3 of 21 414 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.04e4 PCB-9 5.75e6 16.63 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-7 6.57e6 PCB-6 16.80 6.12e6 17.03 PCB-14 7.35e6 19.02 PCB-5 6.20e6 PCB-8 17.33 6.43e6 17.45 PCB-11 6.41e6 19.81 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 13/12 1.25e7 20.11 Abs. Int. 2.17e6 PCB-15 6.32e6 20.39 1.09e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.28e4 PCB-9 3.64e6 16.63 PCB-7 3.99e6 16.80 18.0 19.0 PCB-14 4.57e6 19.02 PCB-5 3.84e6 PCB-8 17.33 4.02e6 17.45 20.0 PCB-11 3.91e6 19.81 13/12 7.75e6 20.10 21.0 Abs. Int. 1.40e6 PCB-15 3.83e6 20.39 7.00e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.21e8 16.61 21.0 0.00e0 RT Abs. Int. 3.98e7 ES-15 1.27e8 20.38 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.35e4 1.99e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.71e7 16.61 21.0 0.00e0 RT Abs. Int. 2.51e7 ES-15 8.13e7 20.38 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 1.09e4 1.26e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0673, 3078 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 4 of 21 415 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 30/18 7.88e6 19.52 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.57e3 PCB-19 2.89e6 17.75 PCB-17 3.33e6 19.93 PCB-27 4.61e6 20.12 PCB-24 4.30e6 20.26 PCB-16 2.58e6 20.35 Abs. Int. 2.14e6 PCB-32 4.81e6 20.84 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 7.32e6 19.52 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 4.49e3 PCB-19 2.75e6 17.75 PCB-17 3.07e6 19.93 21.0 Rel. Int. 100% 18.0 19.0 PCB-16 2.45e6 20.35 20.0 PCB-32 4.50e6 20.84 21.0 1.01e6 0.00e0 RT Abs. Int. 2.17e7 ES-19 5.22e7 17.73 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 7.41e4 0.00e0 RT Abs. Int. 2.01e6 PCB-24 4.11e6 20.26 PCB-27 4.31e6 20.12 0% 17.0 1.07e6 1.09e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.98e7 ES-19 4.85e7 17.73 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.71e4 0.00e0 RT 9.91e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9474, 8467 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 5 of 21 416 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.73e3 PCB-23 PCB-34 4.29e6 4.28e6 22.14 21.99 26/29 8.76e6 22.43 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 28/20 8.42e6 23.19 PCB-31 4.58e6 22.91 Abs. Int. 1.95e6 PCB-22 4.03e6 23.75 PCB-36 4.36e6 25.14 PCB-39 4.43e6 25.46 PCB-38 4.07e6 26.00 PCB-35 3.89e6 26.39 PCB-37 4.03e6 26.76 9.75e5 0% 22.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.67e3 PCB-34 PCB-23 4.40e6 4.28e6 22.14 21.99 23.0 26/29 8.87e6 22.43 24.0 25.0 26.0 27.0 28/20 8.46e6 23.19 PCB-31 4.70e6 22.91 Abs. Int. 2.01e6 PCB-22 4.03e6 23.75 PCB-36 4.44e6 25.14 PCB-39 4.58e6 25.46 PCB-38 4.19e6 26.00 PCB-35 3.89e6 26.39 PCB-37 4.12e6 26.76 1.00e6 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 9.02e7 23.16 Rel. Int. 100% 0.00e0 RT 27.0 0.00e0 RT Abs. Int. 2.37e7 ES-37 8.14e7 26.74 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.65e4 1.19e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.25e7 23.16 Rel. Int. 100% 27.0 0.00e0 RT Abs. Int. 2.20e7 ES-37 7.44e7 26.74 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.85e4 1.10e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1479, 2682 scc: 288-489 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 6 of 21 417 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-54 2.39e6 20.68 Rel. Int. 100% Abs. Int. 6.38e5 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.54e3 3.19e5 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.93e6 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.02e5 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.39e3 4.01e5 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.66e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.66e4 5.03e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.47e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 9.99e3 6.01e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6205, 6671 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 7 of 21 418 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.15e3 50/53 4.73e6 22.68 PCB-51 2.50e6 23.34 PCB-45 1.96e6 23.27 PCB-73 PCB-52 2.96e6 2.29e6 24.94 24.82 PCB-46 1.90e6 23.55 69/49 5.55e6 25.24 44/47… 7.19e6 25.74 PCB-48 2.34e6 25.52 59/62… 9.47e6 26.02 71/40 4.67e6 26.61 PCB-42 2.09e6 26.18 PCB-41 1.93e6 26.52 Abs. Int. 1.80e6 PCB-64 3.30e6 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.66e3 50/53 5.93e6 22.68 24.0 PCB-51 3.11e6 23.34 PCB-45 2.49e6 23.27 25.0 PCB-73 3.74e6 PCB-52 24.94 2.90e6 24.82 PCB-46 2.44e6 23.56 26.0 44/47… 9.21e6 25.74 69/49 7.04e6 25.24 PCB-48 2.89e6 25.52 59/62… 1.19e7 26.02 PCB-42 2.66e6 26.18 27.0 71/40 5.78e6 26.61 PCB-41 2.45e6 26.52 23.0 24.0 25.0 26.0 PCB-64 4.19e6 26.81 27.0 JS-52 4.09e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.14e6 0% 22.0 9.00e5 1.07e6 0.00e0 RT Abs. Int. 1.09e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.65e4 5.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.18e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.53e4 6.74e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7645, 3266 scc: 288-489 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 8 of 21 419 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 61/70... 1.30e7 29.05 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 1.09e4 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-57 3.19e6 28.16 PCB-63 3.39e6 28.75 PCB-55 3.12e6 29.47 PCB-60 PCB-80 3.07e6 3.59e6 30.43 30.11 PCB-79 3.56e6 31.76 PCB-78 2.91e6 32.25 PCB-81 2.96e6 32.63 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Abs. Int. 1.61e6 PCB-77 3.16e6 33.11 8.04e5 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 7.51e3 PCB-57 4.13e6 28.16 PCB-68 4.48e6 27.79 30.0 61/70... 1.64e7 29.04 32.0 PCB-60 3.93e6 30.11 PCB-63 4.46e6 PCB-66 PCB-56 3.90e6 3.93e6 28.75 29.33 29.91 PCB-80 4.50e6 30.43 PCB-79 4.54e6 31.76 34.0 PCB-78 3.70e6 32.25PCB-81 3.85e6 32.63 36.0 38.0 Abs. Int. 2.10e6 PCB-77 4.02e6 33.11 1.05e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 5.62e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.57e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.52e7 ES-77 5.84e7 33.09 7.62e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.04e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.96e4 36.0 38.0 0.00e0 RT Abs. Int. 1.93e7 ES-77 7.31e7 33.09 9.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6185, 5150 scc: 288-489 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 9 of 21 420 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-104 1.93e6 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.00e3 Abs. Int. 5.05e5 PCB-96 1.65e6 26.01 2.53e5 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.97e6 25.69 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.05e3 27.0 0.00e0 RT Abs. Int. 8.18e5 PCB-96 2.56e6 26.01 4.09e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.38e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 3.73e3 5.63e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.62e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.64e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 1.51e3 3.32e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5147, 8237 scc: 288-489 Revised: 30-Dec-2013 12:10 (LKB) Printed: 03-Jan-2014 17:10 Page 10 of 21 421 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 108/119... 1.11e7 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 4.67e4 PCB-103 1.79e6 27.71 100/93 3.34e6 28.50 PCB-88 1.48e6 28.98 PCB-121 2.30e6 30.00 113/90… 5.72e6 30.81 116/85 3.51e6 32.42 PCB-99 1.74e6 31.34 PCB-111 2.37e6 PCB-120 2.36e6 33.13 33.53 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 107/124 PCB-118 2.15e6 4.19e6 35.10 34.50 PCB-123 PCB-114 2.30e6 2.37e6 34.82 35.56 Abs. Int. 1.65e6 PCB-105 2.21e6 36.11 PCB-127 2.09e6 37.34 8.24e5 0% 28.0 30.0 32.0 108/119... 1.81e7 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 7.48e4 34.0 PCB-94 2.47e6 27.90 100/93 5.30e6 28.49 PCB-91 2.94e6 29.04 PCB-89 2.35e6 29.65 113/90… 9.02e6 30.80 PCB-112 PCB-92 3.65e6 2.50e6 31.44 30.32 116/85 PCB-115 5.50e6 3.71e6 32.42 32.62 PCB-111 PCB-117 PCB-110 3.73e6 PCB-120 3.63e6 3.34e6 3.68e6 33.13 32.33 32.53 33.53 36.0 PCB-118 107/124 3.56e6 6.71e6 35.10 34.50 PCB-123 PCB-114 3.66e6 3.82e6 34.82 35.56 38.0 Abs. Int. 2.65e6 PCB-105 3.47e6 36.11 PCB-127 3.36e6 37.34 1.33e6 0% 28.0 Rel. Int. 100% PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.45e3 30.0 32.0 34.0 CS/SS-111 6.50e7 33.11 JS-101 5.23e7 (6.56e7 + 4.07e7) * 100 pg/uL RRF(ES-105) = = 1.25 30.81 (5.23e7 + 3.30e7) * 100 pg/uL LKB 03-Jan-2014 11:50 36.0 ES-123 6.26e7 34.79 ES-114 ES-118 6.68e7 6.24e7 35.54 35.07 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.62e7 ES-105 6.56e7 36.08 8.09e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 4.02e7 33.11 JS-101 3.30e7 30.81 36.0 ES-123 3.97e7 34.79 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 1.58e3 ES-118 ES-114 3.88e7 4.05e7 35.07 35.54 38.0 0.00e0 RT Abs. Int. 9.82e6 ES-105 4.07e7 36.08 4.91e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6550, 0341 scc: 288-489 Revised: 03-Jan-2014 16:44 (LKB) Printed: 03-Jan-2014 17:10 Page 11 of 21 422 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-126 1.83e6 38.72 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.16e3 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Abs. Int. 4.48e5 (1.83e6 + 2.94e6) * 100 pg/uL RRF(PCB-126) = = 1.05 (5.56e7 + 3.53e7) * 5 pg/uL LKB 03-Jan-2014 11:49 2.24e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.89e5 PCB-126 2.94e6 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.88e3 3.44e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.35e7 ES-126 5.56e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.79e3 6.76e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.80e6 ES-126 3.53e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 5.68e3 4.40e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3455, 1978 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 12 of 21 423 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% PCB-155 PCB-150 3.19e6 2.94e6 30.97 30.67 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 8.82e2 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 147/149 139/140 4.16e6 4.18e6 34.12 34.64 PCB-145 2.77e6 31.55 PCB-148 2.07e6 32.82 153/168 5.13e6 36.71 151/135PCB-144 3.94e6 2.10e6 PCB-143 PCB-142 PCB-133 PCB-146 2.02e6 33.34 33.82 1.94e6 2.10e6 1.71e6 36.16 34.38 35.60 34.96 PCB-141 1.92e6 36.85 163/138… 6.11e6 37.77 PCB-164 PCB-160 2.71e6 2.64e6 37.48 37.91 0% 28.0 30.0 32.0 PCB-136 2.12e6 31.27 PCB-150 PCB-155 2.32e6 PCB-145 2.47e6 30.97 2.12e6 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 6.38e2 34.0 PCB-148 1.62e6 32.82 147/149 139/140 151/135 3.22e6 3.27e6 3.20e6 34.12 33.34 34.64 PCB-154 PCB-143 1.84e6 1.60e6PCB-131 33.55 34.38 1.37e6 34.81 36.0 PCB-165 1.99e6 35.94 38.0 153/168 4.00e6 36.71 163/138… 4.82e6 37.77 PCB-141 PCB-137 1.48e6 1.54e6 37.39 36.85 PCB-158 2.26e6 38.09 0% 28.0 30.0 32.0 34.0 36.0 ES-155 5.24e7 30.64 Rel. Int. 100% 38.0 ES-153 3.62e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.74e3 Abs. Int. 1.15e6 5.77e5 0.00e0 RT Abs. Int. 9.25e5 4.62e5 0.00e0 RT Abs. Int. 1.29e7 JS-138 3.20e7 37.73 6.47e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.95e7 30.64 Rel. Int. 100% ES-153 2.75e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 1.30e3 0.00e0 RT Abs. Int. 9.93e6 JS-138 2.44e7 37.73 4.96e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8742, 2751 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 13 of 21 424 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.57e6 38.83 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.74e3 PCB-159 2.84e6 39.64 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-162 2.72e6 39.88 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 156/157 5.34e6 41.28 Abs. Int. 1.12e6 PCB-169 2.67e6 44.00 PCB-167 2.97e6 40.29 5.58e5 0% 39.0 Rel. Int. 100% 40.0 128/166 3.66e6 38.83 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.62e3 PCB-159 2.30e6 39.64 PCB-162 2.25e6 39.88 41.0 42.0 43.0 44.0 45.0 Abs. Int. 8.94e5 156/157 4.28e6 41.28 PCB-169 2.18e6 44.00 PCB-167 2.45e6 40.29 4.47e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.04e8 41.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 ES-167 5.44e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 1.17e4 0.00e0 RT ES-169 5.02e7 43.98 9.59e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 8.00e7 41.26 Rel. Int. 100% Abs. Int. 1.48e7 ES-167 4.20e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 7.32e3 0.00e0 RT ES-169 3.88e7 43.98 7.39e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3801, 7947 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 14 of 21 425 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% PCB-188 1.73e6 35.56 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-179 PCB-184 1.60e6 1.50e6 35.84 36.30 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.31e2 PCB-186 1.53e6 37.00 Abs. Int. 4.22e5 PCB-178 1.15e6 38.13 2.11e5 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.57e6 35.56 PCB-179 1.47e6 35.84 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 5.34e2 37.0 PCB-176 1.59e6 36.59 PCB-186 1.45e6 37.00 38.0 0.00e0 RT Abs. Int. 3.84e5 PCB-178 1.06e6 38.12 1.92e5 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.78e7 35.54 Rel. Int. 100% Abs. Int. 6.94e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.23e3 CS/SS-178 1.72e7 38.10 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.62e7 35.54 Rel. Int. 100% CS/SS-178 1.54e7 38.10 0% 32.0 33.0 34.0 35.0 3.47e6 0.00e0 RT Abs. Int. 6.31e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.34e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 3.15e6 0.00e0 RT Abs. Int. 1.83e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2821, 9130 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 15 of 21 426 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.67e3 PCB-182 1.90e6 39.08 PCB-185 1.62e6 39.52 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 180/193 4.02e6 42.41 171/173 2.98e6 40.53 PCB-181 PCB-177 1.53e6 1.69e6 40.35 40.00 PCB-172 1.54e6 41.88 PCB-191 2.15e6 42.74 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-170 1.49e6 43.51 Abs. Int. 6.84e5 PCB-190 2.17e6 43.97 3.42e5 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.83e3 PCB-182 1.77e6 39.08 PCB-187 PCB-183 1.78e6 1.87e6 38.90 39.43 40.0 41.0 42.0 43.0 180/193 3.73e6 42.41 171/173 2.82e6 PCB-181 40.53 PCB-177 1.57e6 1.40e6 40.35 40.00 PCB-172 1.44e6 41.88 PCB-191 2.05e6 42.74 44.0 PCB-170 1.42e6 43.51 45.0 Abs. Int. 6.33e5 PCB-190 2.05e6 43.97 3.17e5 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.29e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 7.97e6 ES-170 2.76e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.75e3 0.00e0 RT 3.98e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.02e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 7.41e6 ES-170 2.56e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.23e3 0.00e0 RT 3.70e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6498, 0239 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 16 of 21 427 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-189 2.33e6 46.13 Abs. Int. 5.42e5 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.05e3 2.71e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.28e6 46.13 Abs. Int. 5.54e5 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 7.55e2 2.77e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.53e7 46.11 0.00e0 RT Abs. Int. 1.08e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 5.40e3 5.39e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.38e7 46.11 0.00e0 RT Abs. Int. 1.06e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 4.80e3 5.28e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0018, 8768 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 17 of 21 428 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-202 1.32e6 40.10 PCB-201 1.60e6 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.62e2 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 198/199 2.09e6 44.08 PCB-197 1.48e6 PCB-204 41.66 PCB-200 1.46e6 1.47e6 41.47 41.75 Abs. Int. 3.82e5 PCB-196 1.11e6 44.66 PCB-203 1.15e6 44.83 1.91e5 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.48e6 40.10 41.0 PCB-201 1.73e6 40.89 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.89e2 42.0 43.0 44.0 45.0 198/199 2.28e6 44.08 PCB-197 1.62e6 41.66 PCB-200 PCB-204 1.66e6 1.55e6 41.75 41.47 0.00e0 RT Abs. Int. 4.14e5 PCB-196 1.18e6 44.66 PCB-203 1.24e6 44.83 2.07e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.72e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.70e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.49e3 3.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.88e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.04e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.76e3 3.52e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9441, 6444 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 18 of 21 429 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.06e3 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-205 1.70e6 48.30 PCB-195 1.22e6 45.95 Abs. Int. 4.21e5 PCB-194 1.32e6 47.90 2.11e5 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.03e3 47.0 PCB-195 1.35e6 45.95 48.0 49.0 50.0 PCB-205 1.83e6 48.30 PCB-194 1.52e6 47.90 0.00e0 RT Abs. Int. 4.31e5 2.15e5 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.31e7 48.28 Rel. Int. 100% Abs. Int. 7.84e6 JS-194 2.67e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.61e3 0.00e0 RT 3.92e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.71e7 48.28 Rel. Int. 100% Abs. Int. 8.92e6 JS-194 2.90e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 4.69e3 0.00e0 RT 4.46e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1137, 3820 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 19 of 21 430 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 6.72e2 PCB-208 1.60e6 45.75 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-207 1.64e6 46.54 Abs. Int. 3.86e5 PCB-206 1.12e6 49.78 1.93e5 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 2.48e3 PCB-208 1.97e6 45.75 47.0 48.0 49.0 50.0 PCB-207 2.15e6 46.54 Abs. Int. 5.02e5 PCB-206 1.43e6 49.77 2.51e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.97e7 45.73 50.0 0.00e0 RT Abs. Int. 7.00e6 ES-206 2.11e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 1.84e3 3.50e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.69e7 45.73 50.0 Abs. Int. 8.58e6 ES-206 2.61e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.64e3 0.00e0 RT 4.29e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6056, 4422 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 20 of 21 431 of 622 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-209 1.82e6 51.25 Rel. Int. 100% Abs. Int. 3.69e5 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.61e2 1.84e5 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.56e6 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.28e5 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 4.70e2 1.64e5 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.46e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.08e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 9.58e2 3.54e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.92e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.03e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.69e2 3.01e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.31e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.65e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6862, 7261 scc: 288-489 Revised: 30-Dec-2013 12:10 (LKB) Printed: 03-Jan-2014 17:10 Page 21 of 21 432 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.10 32.62 36.09 35.55 35.08 34.80 38.71 41.26 40.28 43.98 46.12 51.23 6.72E+07 6.46E+07 5.36E+07 5.90E+07 5.55E+07 5.75E+07 4.48E+07 9.35E+07 5.18E+07 4.66E+07 4.39E+07 3.15E+07 0.78 Y 0.78 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 1.23 Y 1.21 Y 1.24 Y 1.04 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.14 1.12 1.13 1.23 1.22 1.23 1.12 1.12 1.20 1.16 1.07 1.09 -0.9% -0.2% 1.3% 2.2% 2.5% 1.5% 1.1% 2.3% 2.9% 2.8% -0.2% -2.1% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.02 14.34 14.60 20.36 17.72 26.72 20.65 33.08 32.60 25.66 36.07 35.53 35.06 34.78 38.69 36.65 30.63 41.24 40.26 43.96 43.48 42.41 35.52 46.10 40.07 48.27 49.74 45.71 51.21 2.19E+08 1.97E+08 9.59E+07 1.90E+08 9.32E+07 1.42E+08 7.49E+07 1.18E+08 1.16E+08 6.47E+07 9.52E+07 9.60E+07 9.11E+07 9.36E+07 8.01E+07 5.89E+07 8.37E+07 1.67E+08 8.66E+07 8.06E+07 4.93E+07 5.80E+07 4.92E+07 8.18E+07 5.16E+07 6.45E+07 4.32E+07 6.09E+07 5.77E+07 3.31 Y 3.36 Y 1.62 Y 1.57 Y 1.08 Y 1.09 Y 0.82 Y 0.79 Y 0.81 Y 1.68 Y 1.57 Y 1.64 Y 1.63 Y 1.59 Y 1.60 Y 1.29 Y 1.30 Y 1.28 Y 1.28 Y 1.28 Y 1.09 Y 1.09 Y 1.11 Y 1.01 Y 0.93 Y 0.89 Y 0.80 Y 0.80 Y 1.21 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.18 1.06 0.52 1.02 0.50 1.61 0.85 1.34 1.32 0.80 1.18 1.19 1.13 1.16 0.99 1.10 1.56 1.56 1.62 1.51 0.95 1.11 0.92 1.57 0.97 1.24 0.83 1.17 1.11 -1.3% -2.5% -1.2% -1.9% -0.9% -2.9% -0.9% -2.9% -3.5% 0.0% -1.7% -2.1% -2.4% -2.1% -3.2% -1.2% -1.6% -2.7% -3.0% -3.2% -0.1% -2.2% -2.1% -0.9% -0.5% -0.6% -0.1% -0.5% -0.3% Page 1 of 6 433 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.15 33.09 38.09 1.59E+08 9.83E+07 3.00E+07 1.09 Y 1.61 Y 1.10 Y 1.11 1.03 0.62 1.12 1.05 0.61 1.0% 2.1% -1.7% CS PCB-28 CS PCB-111 CS PCB-178 23.15 33.09 38.09 1.59E+08 9.83E+07 3.00E+07 1.09 Y 1.61 Y 1.10 Y 1.85 1.22 0.58 1.81 1.22 0.56 -1.8% 0.0% -3.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.60 24.78 30.80 37.72 47.87 1.86E+08 8.78E+07 8.05E+07 5.35E+07 5.22E+07 1.55 Y 0.82 Y 1.58 Y 1.28 Y 0.91 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.04 14.36 14.62 20.38 17.73 26.74 20.67 25.68 30.65 35.54 40.09 48.28 45.73 49.76 1.06E+08 1.02E+08 6.07E+07 9.79E+07 5.43E+07 7.81E+07 5.09E+07 4.68E+07 5.34E+07 3.10E+07 2.75E+07 3.40E+07 3.44E+07 2.40E+07 3.22 Y 3.25 Y 1.59 Y 1.64 Y 1.06 Y 0.99 Y 0.82 Y 0.64 Y 1.27 Y 1.06 Y 0.92 Y 0.92 Y 0.77 Y 0.79 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.97 1.04 1.27 1.03 1.17 1.10 1.36 1.45 1.27 1.26 1.06 1.06 1.13 1.11 1.7% 2.8% 2.7% 1.2% 1.5% 2.2% 0.6% 0.9% 1.2% -0.6% 1.0% -0.5% 0.6% -0.3% Page 2 of 6 434 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 12.04 14.17 14.36 14.62 14.80 16.62 16.78 17.01 17.32 17.44 19.01 19.80 20.09 20.38 17.73 19.51 19.91 20.11 20.24 20.34 20.82 21.98 22.13 22.42 22.61 22.89 23.18 23.36 23.74 25.13 25.45 25.99 26.38 26.74 20.67 22.67 23.26 23.33 23.54 24.80 24.93 25.03 25.23 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 1.06E+08 1.07E+08 1.02E+08 6.07E+07 9.81E+07 9.11E+07 1.03E+08 9.79E+07 9.70E+07 9.83E+07 1.14E+08 9.79E+07 1.94E+08 9.79E+07 5.43E+07 1.46E+08 6.21E+07 8.52E+07 8.13E+07 4.64E+07 8.97E+07 8.15E+07 8.33E+07 1.69E+08 8.39E+07 8.91E+07 1.65E+08 1.71E+08 7.72E+07 8.43E+07 8.82E+07 8.09E+07 7.62E+07 7.81E+07 5.09E+07 1.04E+08 4.29E+07 5.41E+07 4.19E+07 4.97E+07 6.50E+07 4.44E+07 1.22E+08 RA 3.22 Y 3.26 Y 3.25 Y 1.59 Y 1.61 Y 1.64 Y 1.63 Y 1.63 Y 1.62 Y 1.64 Y 1.62 Y 1.64 Y 1.63 Y 1.64 Y 1.06 Y 1.05 Y 1.05 Y 1.06 Y 1.04 Y 1.06 Y 1.06 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.99 Y 0.99 Y 0.97 Y 0.98 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.82 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.97 1.08 1.04 1.27 2.05 0.96 1.09 1.03 1.02 1.04 1.20 1.03 1.02 1.03 1.17 1.57 1.33 1.83 1.74 1.00 1.93 1.15 1.18 1.20 1.18 1.26 1.17 1.21 1.09 1.19 1.24 1.14 1.08 1.10 1.36 0.90 0.74 0.93 0.72 0.86 1.12 0.77 1.05 Dev'n 1.7% 4.8% 2.8% 2.7% 3.2% 1.6% 4.1% 3.6% 2.0% 0.3% 1.9% 2.0% 3.1% 1.2% 1.5% 1.9% 2.2% 0.7% 1.2% -1.0% 0.3% 1.4% 1.8% 2.1% 2.3% 2.6% 3.0% 2.8% 0.9% 1.6% 2.8% 3.4% 3.5% 2.2% 0.6% 2.6% -3.3% 8.7% 3.5% 1.6% 0.9% 7.9% 3.2% 435 of 622 PCB QC Summary - Ax2 Detail Lab ID: CS3_131220_PCB_XA Acquired: 20-DEC-2013 18:04 Datafile: 131220X05 Name RT PCB-48 22'45-TeCB 25.51 PCB-44/47/65 ...-TeCB 25.73 PCB-59/62/75 ...-TeCB 26.01 PCB-42 22'34'-TeCB 26.17 PCB-41 22'34-TeCB 26.51 PCB-71/40 23'4'6/22'33'-TeCB 26.60 PCB-64 234'6-TeCB 26.80 PCB-72 23'55'-TeCB 27.52 PCB-68 23'45'-TeCB 27.78 PCB-57 233'5-TeCB 28.15 PCB-58 233'5'-TeCB 28.35 PCB-67 23'45-TeCB 28.51 PCB-63 234'5-TeCB 28.74 PCB-61/70/74/76 ...-TeCB 29.03 PCB-66 23'44'-TeCB 29.32 PCB-55 233'4-TeCB 29.46 PCB-56 233'4'-TeCB 29.90 PCB-60 2344'-TeCB 30.09 PCB-80 33'55'-TeCB 30.42 PCB-79 33'45'-TeCB 31.75 PCB-78 33'45-TeCB 32.24 PCB-104 22'466'-PeCB 25.68 PCB-96 22'366'-PeCB 26.00 PCB-103 22'45'6-PeCB 27.69 PCB-94 22'356'-PeCB 27.89 PCB-95 22'35'6-PeCB 28.27 PCB-100/93 22'44'6/22'356-PeCB 28.48 PCB-102 22'456'-PeCB 28.59 PCB-98 22'34'6'-PeCB 28.66 PCB-88 22'346-PeCB 28.96 PCB-91 22'34'6-PeCB 29.03 PCB-84 22'33'6-PeCB 29.22 PCB-89 22'346'-PeCB 29.64 PCB-121 23'45'6-PeCB 29.99 PCB-92 22'355'-PeCB 30.31 PCB-113/90/101 ...-PeCB 30.79 PCB-83 22'33'5-PeCB 31.23 PCB-99 22'44'5-PeCB 31.33 PCB-112 233'56-PeCB 31.43 PCB-108/119/86/97/125...-PeCB 31.78 PCB-117 234'56-PeCB 32.31 PCB-116/85 23456/22'344'-PeCB 32.41 PCB-110 233'4'6-PeCB 32.52 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 5.03E+07 1.61E+08 2.11E+08 4.56E+07 4.24E+07 1.01E+08 7.33E+07 7.21E+07 7.57E+07 6.97E+07 6.93E+07 7.46E+07 7.70E+07 2.84E+08 6.58E+07 6.61E+07 6.57E+07 6.65E+07 7.84E+07 7.58E+07 6.37E+07 4.68E+07 4.07E+07 4.49E+07 3.89E+07 4.15E+07 8.23E+07 4.80E+07 3.74E+07 3.48E+07 4.85E+07 3.51E+07 3.72E+07 5.76E+07 3.91E+07 1.40E+08 3.39E+07 4.26E+07 5.82E+07 2.85E+08 5.48E+07 8.79E+07 5.86E+07 RA 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.77 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.64 Y 0.65 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.87 0.93 1.21 0.79 0.73 0.87 1.27 1.25 1.31 1.20 1.20 1.29 1.33 1.23 1.14 1.14 1.13 1.15 1.35 1.31 1.10 1.45 1.26 0.96 0.83 0.89 0.88 1.03 0.80 0.74 1.04 0.75 0.80 1.23 0.84 1.00 0.72 0.91 1.24 1.01 1.17 0.94 1.25 Dev'n 3.5% 2.8% 4.0% 3.2% 5.4% 1.7% 3.7% 3.0% 2.4% 3.4% 1.6% 2.3% 2.5% 2.3% 3.1% 1.9% 2.2% 1.2% 3.1% 0.3% 3.6% 0.9% 2.3% 3.1% 3.9% 2.5% 1.9% 6.0% 5.5% -6.9% 9.9% 4.8% 4.3% 2.6% 1.9% 1.0% 1.2% -1.2% 6.6% 3.6% 2.9% -0.1% 12.0% 436 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 32.61 32.80 33.12 33.52 34.49 34.69 34.91 35.38 37.33 30.65 30.81 30.96 31.26 31.53 32.81 33.33 33.54 33.80 34.11 34.28 34.36 34.63 34.80 34.95 35.18 35.59 35.93 36.14 36.26 36.69 36.84 37.18 37.38 37.46 37.76 37.89 38.08 38.81 39.63 39.87 35.54 35.82 36.29 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 5.15E+07 3.29E+07 5.86E+07 5.80E+07 1.06E+08 6.23E+07 5.24E+07 4.86E+07 5.29E+07 5.34E+07 4.87E+07 5.03E+07 4.58E+07 4.68E+07 3.50E+07 6.71E+07 3.92E+07 3.50E+07 6.95E+07 2.62E+07 3.47E+07 7.06E+07 3.02E+07 2.97E+07 3.05E+07 3.33E+07 4.19E+07 3.49E+07 4.54E+07 8.69E+07 3.24E+07 2.87E+07 3.23E+07 4.64E+07 1.04E+08 4.57E+07 4.80E+07 7.91E+07 4.91E+07 4.82E+07 3.10E+07 2.89E+07 2.78E+07 RA 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 1.27 Y 1.29 Y 1.27 Y 1.28 Y 1.28 Y 1.29 Y 1.28 Y 1.27 Y 1.28 Y 1.26 Y 1.29 Y 1.29 Y 1.29 Y 1.28 Y 1.27 Y 1.29 Y 1.27 Y 1.29 Y 1.26 Y 1.29 Y 1.27 Y 1.26 Y 1.26 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.29 Y 1.23 Y 1.23 Y 1.22 Y 1.06 Y 1.08 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.10 0.70 1.25 1.24 1.14 1.33 1.12 1.01 1.11 1.27 1.16 1.20 1.09 1.12 1.19 1.14 1.33 1.19 1.18 0.89 1.18 1.20 1.03 1.01 1.03 1.13 1.42 1.19 1.54 1.48 1.10 0.97 1.10 1.58 1.17 1.55 1.63 0.91 1.13 1.11 1.26 1.17 1.13 Dev'n -5.0% 0.8% 2.6% 2.4% 3.4% 6.3% 1.3% 1.9% 1.5% 1.2% -0.8% 2.2% 2.6% 0.3% 0.6% 0.1% -0.9% 0.5% 0.4% -3.9% 4.3% -0.5% 0.0% 1.8% 0.4% -0.2% 1.0% -1.3% 1.3% 1.3% 1.2% 0.2% -5.5% 5.2% -1.4% 2.4% -1.8% 1.5% 1.7% 3.8% -0.6% 0.9% 0.2% 437 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 36.58 36.98 38.11 38.66 38.89 39.07 39.42 39.50 39.61 39.98 40.33 40.52 41.87 42.12 42.39 42.73 43.50 43.95 40.09 40.88 41.46 41.65 41.73 44.06 44.64 44.81 45.94 47.89 48.28 45.73 46.52 49.76 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 3.08E+07 2.82E+07 2.06E+07 3.12E+07 3.32E+07 3.55E+07 3.70E+07 2.99E+07 2.90E+07 2.76E+07 3.21E+07 5.60E+07 2.94E+07 3.83E+07 7.38E+07 4.06E+07 2.83E+07 4.10E+07 2.75E+07 3.19E+07 2.88E+07 2.98E+07 3.01E+07 4.14E+07 2.18E+07 2.26E+07 2.41E+07 2.69E+07 3.40E+07 3.44E+07 3.65E+07 2.40E+07 RA 1.08 Y 1.09 Y 1.08 Y 1.07 Y 1.07 Y 1.06 Y 1.06 Y 1.07 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 1.05 Y 1.07 Y 1.06 Y 1.08 Y 1.08 Y 1.05 Y 0.92 Y 0.91 Y 0.93 Y 0.91 Y 0.93 Y 0.91 Y 0.91 Y 0.91 Y 0.93 Y 0.91 Y 0.92 Y 0.77 Y 0.78 Y 0.79 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.25 1.14 0.84 1.08 1.15 1.22 1.28 1.03 1.00 0.95 1.11 0.97 1.02 1.32 1.27 1.40 1.15 1.66 1.06 1.24 1.12 1.15 1.16 0.80 0.84 0.88 0.75 0.84 1.06 1.13 1.20 1.11 Dev'n 1.6% 1.7% -0.7% 0.3% 0.7% 4.2% 6.0% -2.8% 1.1% 0.0% 1.7% 1.8% 2.7% 2.5% 1.0% 0.4% 1.0% 0.2% 1.0% 1.2% 0.0% -3.2% 5.1% -0.8% 1.1% 0.2% -2.5% -0.9% -0.5% 0.6% 0.7% -0.3% 438 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.31e7 2.66e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.72e7 1.36e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.99e7 9.97e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.02e7 1.01e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.14e7 5.71e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.75e6 2.88e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.38e6 2.69e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 297-225 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:10 Page 1 of 21 439 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-1 8.10e7 12.04 Rel. Int. 100% PCB-2 8.16e7 14.17 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.95e3 Abs. Int. 3.37e7 PCB-3 7.81e7 14.36 1.68e7 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.51e7 12.04 Rel. Int. 100% PCB-2 2.50e7 14.17 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 4.61e3 0.00e0 16.0 RT Abs. Int. 1.02e7 PCB-3 2.40e7 14.36 5.12e6 0% 11.0 12.0 13.0 14.0 ES-1 1.68e8 12.02 Rel. Int. 100% 15.0 Abs. Int. 6.63e7 ES-3 1.52e8 14.34 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 8.09e3 0.00e0 16.0 RT 3.32e7 0% 11.0 12.0 13.0 14.0 ES-1 5.08e7 12.02 Rel. Int. 100% 15.0 Abs. Int. 2.10e7 ES-3 4.52e7 14.34 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.05e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.31e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1305, 6088 scc: 297-225 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:10 Page 2 of 21 440 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Rel. Int. 100% PCB-10 6.05e7 14.80 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.28e3 PCB-4 3.73e7 14.62 1.01e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.76e7 14.80 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.69e4 PCB-4 2.35e7 14.61 12.0 13.0 14.0 15.0 ES-4 5.93e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.25e7 6.24e6 0% 11.0 Abs. Int. 2.01e7 0.00e0 16.0 RT Abs. Int. 1.97e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.17e3 9.87e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.66e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.25e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.04e3 6.25e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.31e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0655, 5434 scc: 297-225 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 3 of 21 441 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.09e4 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-6 6.06e7 17.01 PCB-9 5.66e7 16.62 PCB-14 7.06e7 19.01 PCB-5 6.00e7 17.32 PCB-8 6.10e7 17.44 PCB-11 6.08e7 19.80 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 13/12 1.20e8 20.09 Abs. Int. 2.06e7 PCB-15 6.08e7 20.38 1.03e7 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.56e4 PCB-9 3.46e7 16.62 PCB-7 3.94e7 16.78 18.0 19.0 PCB-14 4.35e7 19.01 PCB-5 3.70e7 17.32 PCB-8 3.73e7 17.44 20.0 PCB-11 3.71e7 19.80 13/12 7.35e7 20.09 21.0 Abs. Int. 1.26e7 PCB-15 3.71e7 20.38 6.30e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.13e8 16.60 21.0 ES-15 1.16e8 20.36 0.00e0 RT Abs. Int. 3.59e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.60e4 1.79e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.28e7 16.60 21.0 0.00e0 RT Abs. Int. 2.31e7 ES-15 7.40e7 20.36 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 1.25e4 1.15e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4598, 0207 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 4 of 21 442 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 30/18 7.47e7 19.51 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.64e3 PCB-19 2.79e7 17.73 PCB-17 3.19e7 19.91 PCB-27 4.38e7 20.11 PCB-24 4.15e7 20.24 PCB-16 2.39e7 20.34 Abs. Int. 2.03e7 PCB-32 4.61e7 20.82 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 7.11e7 19.51 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 4.04e3 PCB-19 2.64e7 17.73 PCB-17 3.03e7 19.91 21.0 PCB-24 3.98e7 20.24 PCB-27 4.15e7 20.11 Rel. Int. 100% 18.0 19.0 PCB-16 2.25e7 20.34 20.0 PCB-32 4.36e7 20.82 21.0 9.59e6 0.00e0 RT Abs. Int. 1.95e7 ES-19 4.84e7 17.72 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 8.84e4 0.00e0 RT Abs. Int. 1.92e7 0% 17.0 1.01e7 9.76e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.80e7 ES-19 4.48e7 17.72 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.99e4 0.00e0 RT 9.01e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2677, 3721 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 5 of 21 443 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 28/20 8.20e7 23.18 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 7.46e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-23 PCB-34 4.15e7 4.05e7 22.13 21.98 26/29 8.42e7 22.42 PCB-31 4.44e7 22.89 Abs. Int. 1.93e7 PCB-22 3.82e7 23.74 PCB-36 4.19e7 25.13 PCB-39 4.39e7 25.45 PCB-38 4.03e7 25.99 PCB-35 3.79e7 26.38 PCB-37 3.89e7 26.74 9.66e6 0% 22.0 24.0 25.0 26.0 27.0 28/20 8.32e7 23.18 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 6.03e3 23.0 PCB-23 PCB-34 4.18e7 4.10e7 22.13 21.98 26/29 8.52e7 22.42 PCB-31 4.47e7 22.89 Abs. Int. 1.94e7 PCB-22 3.90e7 23.74 PCB-36 4.24e7 25.13 PCB-39 4.43e7 25.45 PCB-38 4.06e7 25.99 PCB-35 3.84e7 26.38 PCB-37 3.92e7 26.74 9.69e6 0% 22.0 23.0 CS/SS-28 8.29e7 23.15 Rel. Int. 100% TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.92e4 24.0 25.0 26.0 27.0 23.0 24.0 1.13e7 25.0 26.0 CS/SS-28 7.62e7 23.15 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.27e7 ES-37 7.38e7 26.72 (8.29e7 + 7.62e7) RRF(CS-28) = = 1.81 (3.96e7 + 4.82e7) LKB 03-Jan-2014 15:10 0% 22.0 0.00e0 RT 27.0 Abs. Int. 2.07e7 ES-37 6.79e7 26.72 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 4.37e4 0.00e0 RT 1.04e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2630, 0050 scc: 297-225 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 6 of 21 444 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-54 2.30e7 20.67 Rel. Int. 100% Abs. Int. 6.33e6 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.43e3 3.17e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.80e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.75e6 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.25e3 3.87e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.37e7 20.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.21e6 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.87e4 4.60e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.12e7 20.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.10e4 5.62e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5811, 4868 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 7 of 21 445 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.05e3 50/53 4.60e7 22.67 PCB-51 2.40e7 23.33 PCB-45 1.89e7 23.26 PCB-73 PCB-52 2.87e7 2.19e7 24.93 24.80 PCB-46 1.84e7 23.54 69/49 5.38e7 25.23 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 44/47… 7.13e7 25.73 PCB-48 2.21e7 25.51 59/62… 9.32e7 26.01 71/40 4.48e7 26.60 PCB-42 2.01e7 26.17 PCB-41 1.85e7 26.51 Abs. Int. 1.68e7 PCB-64 3.24e7 26.80 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 2.01e3 50/53 5.81e7 22.67 24.0 PCB-51 3.01e7 23.33 PCB-45 2.41e7 23.26 25.0 PCB-73 3.63e7 PCB-52 24.93 2.78e7 24.80 PCB-46 2.35e7 23.54 26.0 69/49 6.83e7 25.23 44/47… 9.00e7 25.73 PCB-48 2.81e7 25.51 27.0 59/62… 1.17e8 26.00 71/40 5.63e7 26.60 PCB-42 2.55e7 26.17 PCB-41 2.39e7 26.51 23.0 24.0 25.0 26.0 PCB-64 4.09e7 26.80 27.0 JS-52 3.96e7 24.78 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.12e7 0% 22.0 8.42e6 1.06e7 0.00e0 RT Abs. Int. 1.03e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 3.01e4 5.16e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 4.82e7 24.78 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.93e4 6.39e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6030, 5973 scc: 297-225 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 8 of 21 446 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 61/70... 1.24e8 29.03 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 8.75e4 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-68 3.33e7 27.78 PCB-67 3.27e7 28.51 PCB-55 2.90e7 29.46 PCB-60 PCB-80 2.92e7 3.46e7 30.42 30.09 PCB-79 3.33e7 31.75 PCB-78 2.80e7 32.24PCB-81 2.83e7 32.62 Abs. Int. 1.54e7 PCB-77 2.95e7 33.10 7.71e6 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 5.75e4 PCB-57 3.91e7 28.15 PCB-68 4.24e7 27.78 30.0 61/70... 1.59e8 29.03 32.0 PCB-60 3.73e7 30.09 PCB-63 PCB-66 4.34e7 3.69e7 PCB-56 3.69e7 28.74 29.31 29.90 PCB-80 4.38e7 30.42 PCB-79 4.25e7 31.74 34.0 PCB-78 3.56e7 32.24PCB-81 3.63e7 32.62 36.0 38.0 Abs. Int. 1.98e7 PCB-77 3.77e7 33.10 9.88e6 0% 28.0 Rel. Int. 100% TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.69e4 30.0 32.0 34.0 ES-81 5.16e7 32.60 (5.16e7 + 6.42e7) * 100 pg/uL = 1.32 (3.96e7 + 4.82e7) * 100 pg/uL LKB 03-Jan-2014 15:09 RRF(ES-81) = 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.42e7 ES-77 5.20e7 33.08 7.08e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.42e7 32.60 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 2.60e4 36.0 38.0 0.00e0 RT Abs. Int. 1.77e7 ES-77 6.59e7 33.08 8.85e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8755, 8946 scc: 297-225 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 9 of 21 447 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-104 1.83e7 25.68 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 8.52e2 Abs. Int. 4.64e6 PCB-96 1.60e7 26.00 2.32e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.84e7 25.68 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.03e3 27.0 0.00e0 RT Abs. Int. 7.28e6 PCB-96 2.46e7 25.99 3.64e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.06e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 1.98e3 5.07e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.41e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.06e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.06e3 3.03e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9856, 2300 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 10 of 21 448 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 108/119... 1.09e8 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 1.43e5 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-103 1.72e7 27.69 PCB-91 1.86e7 100/93 29.03 3.15e7 28.48 PCB-88 1.32e7 28.96 PCB-121 2.21e7 29.99 113/90… 5.36e7 30.79 116/85 3.39e7 32.41 PCB-99 1.63e7 31.33 PCB-111 2.24e7 PCB-120 2.22e7 33.12 33.52 107/124 PCB-118 2.13e7 4.05e7 35.08 34.49 PCB-114 PCB-123 2.27e7 2.21e7 35.55 34.80 Abs. Int. 1.58e7 PCB-105 2.05e7 36.09 PCB-127 2.01e7 37.33 7.92e6 0% 28.0 30.0 32.0 36.0 38.0 108/119... 1.76e8 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 1.25e5 34.0 PCB-94 2.39e7 27.88 100/93 5.08e7 28.48 PCB-91 2.99e7 29.03 PCB-89 2.31e7 29.64 113/90… 8.61e7 30.79 PCB-112 3.59e7 PCB-92 31.43 2.43e7 30.31 116/85 PCB-115 5.40e7 3.18e7 PCB-111 32.40 32.61 3.62e7 33.12 PCB-117 PCB-110 PCB-120 3.38e7 3.61e7 PCB-82 3.58e7 32.31 32.52 2.03e7 33.52 32.80 107/124 PCB-118 3.42e7 6.57e7 35.08 34.49 PCB-114 PCB-123 3.63e7 3.54e7 35.55 34.80 Abs. Int. 2.53e7 PCB-105 3.31e7 36.09 PCB-127 3.28e7 37.33 1.27e7 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 6.07e7 33.09 JS-101 4.93e7 30.80 36.0 ES-118 ES-114 5.96e7 35.53 ES-123 5.64e7 5.74e7 35.06 34.78 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.18e3 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.48e7 ES-105 5.82e7 36.07 7.42e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 3.77e7 33.10 JS-101 3.12e7 30.80 36.0 ES-118 ES-114 ES-123 3.47e7 3.63e7 3.62e7 35.06 35.53 34.78 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.13e3 38.0 0.00e0 RT Abs. Int. 9.26e6 ES-105 3.70e7 36.07 4.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4291, 2615 scc: 297-225 Revised: 03-Jan-2014 16:45 (LKB) Printed: 03-Jan-2014 17:11 Page 11 of 21 449 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Abs. Int. 3.89e6 PCB-126 1.72e7 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 2.70e3 1.94e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.44e6 PCB-126 2.76e7 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 3.20e3 3.22e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.21e7 ES-126 4.93e7 38.69 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.26e3 6.04e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.54e6 ES-126 3.09e7 38.69 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 8.80e3 3.77e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5774, 8779 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 12 of 21 450 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% PCB-150 PCB-155 2.82e7 2.99e7 30.96 30.65 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.06e2 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 147/149 139/140 3.88e7 3.97e7 34.11 34.63 PCB-145 2.62e7 31.53 PCB-148 1.97e7 32.81 153/168 4.86e7 36.69 151/135PCB-144 3.76e7 1.97e7 PCB-143 PCB-142 PCB-133 PCB-146 1.95e7 1.86e7 1.95e7 33.33 33.80 1.66e7 36.14 34.36 35.59 34.95 PCB-141 1.81e7 36.84 163/138… 5.81e7 37.76 PCB-160 PCB-164 2.60e7 2.56e7 37.46 37.89 0% 28.0 30.0 32.0 PCB-152 2.13e7 30.81 PCB-150 PCB-155 2.21e7 2.35e7 30.95 30.65 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.05e3 PCB-145 2.06e7 31.53 34.0 PCB-148 1.53e7 32.81 147/149 139/140 151/135 3.08e7 3.09e7 2.95e7 34.11 34.63 33.33 PCB-154 PCB-143 1.73e7 1.51e7PCB-131 33.54 34.36 1.32e7 34.80 36.0 38.0 153/168 3.83e7 36.69 PCB-165 1.83e7 35.93 163/138… 4.56e7 37.75 PCB-141 PCB-137 1.43e7 1.43e7 37.38 36.84 PCB-158 2.10e7 38.08 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.73e7 30.63 Rel. Int. 100% ES-153 3.32e7 36.65 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.52e3 Abs. Int. 1.10e7 5.51e6 0.00e0 RT Abs. Int. 8.70e6 4.35e6 0.00e0 RT Abs. Int. 1.17e7 JS-138 3.00e7 37.72 5.87e6 0% 28.0 30.0 32.0 34.0 36.0 ES-155 3.64e7 30.63 Rel. Int. 100% 38.0 ES-153 2.57e7 36.65 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 1.83e3 0.00e0 RT Abs. Int. 8.88e6 JS-138 2.35e7 37.72 4.44e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0360, 4999 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 13 of 21 451 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.35e7 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.95e3 PCB-159 2.71e7 39.63 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-162 2.65e7 39.87 156/157 5.15e7 41.26 Abs. Int. 1.02e7 (2.84e7 + 2.34e7) * 100 pg/uL = 1.20 (4.86e7 + 3.80e7) * 50 pg/uL LKB 03-Jan-2014 11:58 RRF(PCB-167) = PCB-167 2.84e7 40.28 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-169 2.58e7 43.98 5.09e6 0% 39.0 Rel. Int. 100% 128/166 3.55e7 38.81 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 3.14e3 40.0 PCB-162 PCB-159 2.17e7 2.20e7 39.87 39.63 41.0 42.0 43.0 44.0 45.0 156/157 4.20e7 41.26 Abs. Int. 8.23e6 PCB-169 2.08e7 43.98 PCB-167 2.34e7 40.28 4.11e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 9.34e7 41.24 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.68e7 ES-167 4.86e7 40.26 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 7.61e3 0.00e0 RT ES-169 4.52e7 43.96 8.40e6 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 3.80e7 40.26 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 8.72e3 42.0 43.0 44.0 45.0 ES-156/157 7.32e7 41.24 0.00e0 RT Abs. Int. 1.31e7 ES-169 3.54e7 43.96 6.56e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6303, 7049 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 14 of 21 452 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% PCB-188 1.60e7 35.54 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-179 PCB-184 1.50e7 1.45e7 35.82 36.29 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.15e2 PCB-186 1.47e7 36.98 Abs. Int. 3.96e6 PCB-178 1.07e7 38.11 1.98e6 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.50e7 35.54 PCB-179 1.39e7 35.82 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.04e2 37.0 PCB-176 1.48e7 36.58 PCB-186 1.35e7 36.98 38.0 Abs. Int. 3.73e6 PCB-178 9.89e6 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.59e7 35.52 Rel. Int. 100% CS/SS-178 1.57e7 38.09 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.33e7 35.52 Rel. Int. 100% CS/SS-178 1.42e7 38.09 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.20e6 0.00e0 RT Abs. Int. 5.64e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.22e3 31.0 1.86e6 Abs. Int. 6.41e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.23e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 2.82e6 0.00e0 RT Abs. Int. 2.02e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9174, 9814 scc: 297-225 PKD: 30-Dec-2013 12:20 Printed: 03-Jan-2014 17:11 Page 15 of 21 453 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 4.43e3 PCB-183 1.91e7 PCB-182 39.42 PCB-185 1.83e7 1.54e7 39.07 39.50 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 180/193 3.80e7 42.39 171/173 2.87e7 PCB-181 40.52 PCB-177 1.65e7 1.42e7 40.33 39.98 PCB-172 1.51e7 41.87 PCB-191 2.11e7 42.73 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-170 1.47e7 43.50 Abs. Int. 6.40e6 PCB-190 2.10e7 43.95 3.20e6 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 3.72e3 PCB-182 1.72e7 39.07 PCB-183 PCB-187 1.79e7 1.61e7 39.42 38.89 40.0 41.0 42.0 43.0 180/193 3.58e7 42.39 171/173 2.72e7 PCB-181 40.52 PCB-177 1.56e7 1.34e7 40.33 39.98 PCB-172 1.43e7 41.87 PCB-191 1.95e7 42.73 44.0 45.0 Abs. Int. 6.07e6 PCB-190 2.01e7 43.95 PCB-170 1.36e7 43.50 3.04e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.02e7 42.41 Rel. Int. 100% 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 7.37e6 ES-170 2.58e7 43.48 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.18e3 3.69e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.77e7 42.41 Rel. Int. 100% 44.0 45.0 Abs. Int. 6.77e6 ES-170 2.36e7 43.48 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.05e3 0.00e0 RT 3.39e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1388, 8460 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 16 of 21 454 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-189 2.24e7 46.12 Abs. Int. 5.28e6 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.74e3 2.64e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.15e7 46.12 Abs. Int. 5.00e6 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 2.13e3 2.50e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.12e7 46.10 0.00e0 RT Abs. Int. 1.01e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 3.83e3 5.04e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.06e7 46.10 0.00e0 RT Abs. Int. 9.92e6 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.31e3 4.96e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7725, 6868 scc: 297-225 PKD: 30-Dec-2013 12:20 Printed: 03-Jan-2014 17:11 Page 17 of 21 455 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-202 1.32e7 40.09 Rel. Int. 100% PCB-201 1.52e7 40.88 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.54e2 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 198/199 1.98e7 44.06 PCB-197 1.42e7 PCB-204 41.65 PCB-200 1.39e7 1.45e7 41.46 41.73 Abs. Int. 3.62e6 PCB-196 1.04e7 44.64 PCB-203 1.08e7 44.81 1.81e6 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.43e7 40.09 41.0 PCB-201 1.67e7 40.88 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.75e2 42.0 43.0 44.0 45.0 198/199 2.17e7 44.06 PCB-197 1.55e7 PCB-204 41.65 PCB-200 1.49e7 1.56e7 41.46 41.73 0.00e0 RT Abs. Int. 3.99e6 PCB-196 1.14e7 44.64 PCB-203 1.18e7 44.81 1.99e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.49e7 40.07 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.20e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.53e3 3.10e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.68e7 40.07 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.66e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.32e3 3.33e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2479, 9839 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 18 of 21 456 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.61e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-205 1.63e7 48.28 PCB-195 1.16e7 45.94 Abs. Int. 3.80e6 PCB-194 1.29e7 47.89 1.90e6 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 2.48e3 47.0 48.0 49.0 50.0 PCB-205 1.77e7 48.28 PCB-195 1.25e7 45.94 0.00e0 RT Abs. Int. 4.16e6 PCB-194 1.41e7 47.88 2.08e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.04e7 48.27 Rel. Int. 100% Abs. Int. 7.24e6 JS-194 2.49e7 47.87 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.67e3 0.00e0 RT 3.62e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.40e7 48.27 Rel. Int. 100% Abs. Int. 8.13e6 JS-194 2.73e7 47.87 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.23e3 0.00e0 RT 4.07e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9372, 9268 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 19 of 21 457 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.22e3 PCB-208 1.50e7 45.73 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-207 1.60e7 46.52 Abs. Int. 3.79e6 PCB-206 1.06e7 49.76 1.89e6 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.78e3 PCB-208 1.94e7 45.73 47.0 48.0 49.0 50.0 PCB-207 2.05e7 46.52 Abs. Int. 4.79e6 PCB-206 1.34e7 49.76 2.40e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.71e7 45.71 50.0 0.00e0 RT Abs. Int. 6.38e6 ES-206 1.92e7 49.74 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.45e3 3.19e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.39e7 45.71 50.0 Abs. Int. 8.08e6 ES-206 2.40e7 49.74 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 3.05e3 0.00e0 RT 4.04e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5390, 1741 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 20 of 21 458 of 622 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-209 1.71e7 51.23 Rel. Int. 100% Abs. Int. 3.49e6 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 6.63e2 1.74e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.44e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.92e6 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.15e2 1.46e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.16e7 51.21 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.46e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 7.77e2 3.23e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.62e7 51.21 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.44e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.95e2 2.72e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.38e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.69e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6160, 7361 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 21 of 21 459 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.10 32.62 36.10 35.56 35.09 34.81 38.71 41.27 40.29 43.99 46.13 51.25 6.61E+08 6.42E+08 5.26E+08 5.80E+08 5.38E+08 5.67E+08 4.45E+08 9.01E+08 4.96E+08 4.52E+08 4.15E+08 2.92E+08 0.78 Y 0.78 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.63 Y 1.22 Y 1.23 Y 1.24 Y 1.05 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.14 1.15 1.24 1.22 1.23 1.14 1.11 1.18 1.14 1.10 1.10 1.7% 1.9% 3.3% 3.3% 2.6% 1.3% 2.8% 1.1% 1.4% 1.2% 2.3% -1.4% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.03 14.35 14.61 20.37 17.72 26.73 20.66 33.08 32.61 25.66 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.25 40.27 43.97 43.49 42.42 35.53 46.11 40.08 48.28 49.75 45.72 51.22 2.53E+08 2.32E+08 1.12E+08 2.25E+08 1.10E+08 1.69E+08 8.74E+07 1.41E+08 1.41E+08 7.69E+07 1.14E+08 1.17E+08 1.10E+08 1.15E+08 9.79E+07 6.88E+07 9.70E+07 2.03E+08 1.05E+08 9.92E+07 5.71E+07 6.95E+07 5.77E+07 9.44E+07 6.04E+07 7.51E+07 5.00E+07 7.07E+07 6.66E+07 3.29 Y 3.37 Y 1.64 Y 1.54 Y 1.08 Y 1.08 Y 0.83 Y 0.79 Y 0.77 Y 1.65 Y 1.60 Y 1.63 Y 1.63 Y 1.60 Y 1.53 Y 1.31 Y 1.30 Y 1.29 Y 1.27 Y 1.27 Y 1.09 Y 1.09 Y 1.13 Y 1.04 Y 0.94 Y 0.90 Y 0.81 Y 0.80 Y 1.18 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.17 1.08 0.52 1.05 0.51 1.66 0.86 1.38 1.38 0.79 1.18 1.21 1.14 1.19 1.01 1.11 1.56 1.64 1.70 1.60 0.95 1.16 0.93 1.57 0.97 1.25 0.83 1.18 1.11 -1.5% -0.6% -0.1% 0.6% 0.9% -0.4% -0.5% 0.0% 1.1% -1.2% -1.7% -1.1% -1.8% 0.4% -1.7% -0.6% -1.7% 2.3% 1.7% 2.7% 0.6% 2.0% -1.0% -0.5% 0.4% 0.7% 0.6% 0.4% 0.1% Page 1 of 6 460 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.10 38.10 1.88E+08 1.16E+08 3.54E+07 1.09 Y 1.60 Y 1.11 Y 1.11 1.03 0.62 1.11 1.00 0.61 0.2% -2.6% -1.0% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.10 38.10 1.88E+08 1.16E+08 3.54E+07 1.09 Y 1.60 Y 1.11 Y 1.85 1.22 0.58 1.84 1.19 0.57 -0.1% -2.2% -2.0% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.80 37.72 47.88 2.15E+08 1.02E+08 9.69E+07 6.21E+07 6.00E+07 1.55 Y 0.80 Y 1.60 Y 1.30 Y 0.91 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.04 14.36 14.62 20.38 17.74 26.75 20.68 25.69 30.66 35.55 40.10 48.30 45.74 49.77 9.92E+08 9.76E+08 5.69E+08 9.40E+08 5.10E+08 7.43E+08 4.71E+08 4.46E+08 5.02E+08 2.95E+08 2.56E+08 3.22E+08 3.23E+08 2.24E+08 3.21 Y 3.28 Y 1.58 Y 1.62 Y 1.05 Y 0.98 Y 0.83 Y 0.64 Y 1.27 Y 1.08 Y 0.92 Y 0.91 Y 0.78 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.98 1.05 1.27 1.04 1.16 1.10 1.35 1.45 1.29 1.28 1.06 1.07 1.14 1.12 3.0% 4.2% 2.9% 2.4% 1.2% 2.0% -0.4% 1.0% 2.6% 0.6% 0.6% 1.2% 1.7% 0.5% Page 2 of 6 461 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 12.04 14.18 14.36 14.62 14.80 16.62 16.79 17.02 17.32 17.44 19.01 19.80 20.10 20.38 17.74 19.51 19.92 20.11 20.25 20.34 20.83 21.98 22.14 22.42 22.62 22.90 23.19 23.37 23.75 25.14 25.46 25.99 26.39 26.75 20.68 22.68 23.27 23.34 23.55 24.81 24.94 25.04 25.23 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 9.92E+08 1.00E+09 9.76E+08 5.69E+08 9.17E+08 8.62E+08 9.69E+08 9.24E+08 9.17E+08 9.28E+08 1.09E+09 9.34E+08 1.86E+09 9.40E+08 5.10E+08 1.39E+09 5.88E+08 8.20E+08 7.60E+08 4.62E+08 8.47E+08 7.98E+08 8.06E+08 1.63E+09 8.00E+08 8.40E+08 1.58E+09 1.64E+09 7.44E+08 8.17E+08 8.41E+08 7.83E+08 7.26E+08 7.43E+08 4.71E+08 1.00E+09 4.42E+08 4.96E+08 3.98E+08 4.82E+08 6.34E+08 4.03E+08 1.18E+09 RA 3.21 Y 3.28 Y 3.28 Y 1.58 Y 1.60 Y 1.63 Y 1.64 Y 1.65 Y 1.63 Y 1.63 Y 1.64 Y 1.64 Y 1.64 Y 1.62 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.06 Y 1.05 Y 0.99 Y 0.98 Y 0.98 Y 0.97 Y 0.97 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.99 Y 0.99 Y 0.98 Y 0.83 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.98 1.08 1.05 1.27 2.04 0.96 1.08 1.03 1.02 1.03 1.21 1.04 1.03 1.04 1.16 1.59 1.34 1.87 1.73 1.05 1.93 1.18 1.19 1.21 1.18 1.24 1.17 1.21 1.10 1.21 1.25 1.16 1.07 1.10 1.35 0.89 0.78 0.88 0.71 0.85 1.12 0.72 1.05 Dev'n 3.0% 4.2% 4.2% 2.9% 3.1% 1.3% 2.9% 3.0% 1.7% -0.2% 2.2% 2.7% 4.5% 2.4% 1.2% 3.3% 2.6% 2.8% 0.5% 4.7% 0.6% 4.1% 3.3% 2.9% 2.4% 1.5% 3.0% 3.3% 2.0% 3.4% 2.8% 4.9% 3.4% 2.0% -0.4% 1.4% 2.2% 2.5% 1.0% 1.3% 1.1% 0.7% 2.5% 462 of 622 PCB QC Summary - Ax2 Detail Lab ID: CS4_131220_PCB_XA Acquired: 20-DEC-2013 18:59 Datafile: 131220X06 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.01 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.51 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.78 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.36 PCB-67 23'45-TeCB 28.52 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.04 PCB-66 23'44'-TeCB 29.32 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.10 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.75 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.00 PCB-103 22'45'6-PeCB 27.70 PCB-94 22'356'-PeCB 27.89 PCB-95 22'35'6-PeCB 28.27 PCB-100/93 22'44'6/22'356-PeCB 28.49 PCB-102 22'456'-PeCB 28.60 PCB-98 22'34'6'-PeCB 28.67 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.23 PCB-89 22'346'-PeCB 29.65 PCB-121 23'45'6-PeCB 29.99 PCB-92 22'355'-PeCB 30.31 PCB-113/90/101 ...-PeCB 30.80 PCB-83 22'33'5-PeCB 31.24 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.78 PCB-117 234'56-PeCB 32.32 PCB-116/85 23456/22'344'-PeCB 32.41 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 4.79E+08 1.57E+09 2.05E+09 4.36E+08 3.81E+08 1.02E+09 7.02E+08 6.86E+08 7.41E+08 6.53E+08 6.72E+08 7.17E+08 7.44E+08 2.76E+09 6.42E+08 6.33E+08 6.29E+08 6.41E+08 7.47E+08 7.60E+08 6.10E+08 4.46E+08 3.93E+08 4.37E+08 3.75E+08 4.04E+08 8.29E+08 4.01E+08 3.96E+08 3.93E+08 4.40E+08 3.38E+08 3.62E+08 5.66E+08 3.81E+08 1.39E+09 3.22E+08 4.51E+08 5.42E+08 2.82E+09 5.03E+08 9.15E+08 5.11E+08 RA 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.64 Y 0.65 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.85 0.93 1.22 0.77 0.68 0.90 1.25 1.22 1.31 1.16 1.19 1.27 1.32 1.22 1.14 1.12 1.12 1.14 1.32 1.35 1.08 1.45 1.28 0.95 0.81 0.87 0.90 0.87 0.86 0.85 0.95 0.73 0.78 1.23 0.83 1.01 0.70 0.98 1.17 1.02 1.09 0.99 1.11 Dev'n 1.4% 3.0% 4.3% 1.5% -2.7% 4.9% 2.0% 0.7% 2.9% -0.5% 1.1% 1.1% 1.7% 2.2% 3.3% 0.3% 0.6% 0.2% 0.9% 3.2% 1.9% 1.0% 3.9% 1.6% 1.6% 0.9% 3.9% -10.2% 13.2% 6.8% 0.9% 2.3% 2.8% 2.2% 0.7% 2.0% -2.5% 6.1% 0.5% 3.8% -4.3% 5.3% -1.0% 463 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 32.62 32.81 33.12 33.52 34.49 34.70 34.92 35.38 37.34 30.66 30.82 30.96 31.27 31.54 32.82 33.34 33.55 33.81 34.11 34.29 34.37 34.64 34.81 34.96 35.19 35.59 35.94 36.15 36.27 36.70 36.85 37.19 37.39 37.47 37.76 37.90 38.09 38.82 39.64 39.88 35.55 35.83 36.30 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.34E+08 3.31E+08 5.66E+08 5.76E+08 1.03E+09 5.82E+08 5.22E+08 4.75E+08 5.12E+08 5.02E+08 4.78E+08 4.68E+08 4.35E+08 4.41E+08 3.38E+08 6.39E+08 3.76E+08 3.29E+08 6.68E+08 2.65E+08 3.08E+08 6.80E+08 2.87E+08 2.82E+08 2.84E+08 3.19E+08 3.83E+08 3.42E+08 4.26E+08 8.26E+08 3.01E+08 2.69E+08 3.35E+08 4.16E+08 1.01E+09 4.29E+08 4.60E+08 7.86E+08 4.70E+08 4.62E+08 2.95E+08 2.67E+08 2.61E+08 RA 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.63 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.28 Y 1.27 Y 1.26 Y 1.28 Y 1.27 Y 1.28 Y 1.29 Y 1.30 Y 1.28 Y 1.28 Y 1.27 Y 1.28 Y 1.27 Y 1.29 Y 1.27 Y 1.27 Y 1.29 Y 1.27 Y 1.27 Y 1.28 Y 1.23 Y 1.23 Y 1.22 Y 1.08 Y 1.10 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.16 0.72 1.23 1.25 1.12 1.26 1.13 1.02 1.12 1.29 1.23 1.21 1.12 1.14 1.23 1.16 1.37 1.20 1.21 0.96 1.12 1.24 1.04 1.03 1.03 1.16 1.39 1.24 1.55 1.50 1.10 0.98 1.22 1.51 1.23 1.56 1.67 0.93 1.12 1.10 1.28 1.16 1.13 Dev'n -0.2% 3.0% 0.5% 2.9% 2.0% 0.6% 2.4% 2.2% 2.2% 2.6% 5.1% 2.7% 5.1% 2.1% 3.8% 1.9% 1.9% 1.2% 3.2% 4.4% -1.0% 2.6% 1.8% 3.6% 0.3% 2.4% -1.3% 3.4% 1.8% 3.0% 0.7% 0.6% 4.6% 0.9% 3.3% 2.8% 0.5% 3.7% 0.1% 2.4% 0.6% -0.3% 0.2% 464 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 36.59 36.99 38.12 38.67 38.90 39.08 39.42 39.51 39.62 39.99 40.34 40.53 41.88 42.13 42.40 42.74 43.51 43.96 40.10 40.89 41.47 41.66 41.75 44.07 44.65 44.82 45.95 47.90 48.30 45.74 46.53 49.77 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 2.85E+08 2.59E+08 1.94E+08 3.05E+08 3.25E+08 3.35E+08 3.29E+08 3.20E+08 2.73E+08 2.68E+08 3.10E+08 5.43E+08 2.79E+08 3.67E+08 7.06E+08 3.88E+08 2.72E+08 3.86E+08 2.56E+08 3.08E+08 2.70E+08 2.93E+08 2.71E+08 3.95E+08 2.03E+08 2.13E+08 2.31E+08 2.54E+08 3.22E+08 3.23E+08 3.40E+08 2.24E+08 RA 1.09 Y 1.08 Y 1.08 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 0.92 Y 0.92 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.92 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.78 Y 0.79 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.24 1.12 0.84 1.10 1.17 1.21 1.18 1.15 0.98 0.96 1.12 0.98 1.00 1.32 1.27 1.40 1.19 1.69 1.06 1.27 1.12 1.21 1.12 0.82 0.84 0.88 0.77 0.85 1.07 1.14 1.20 1.12 Dev'n 0.3% -0.3% -0.6% 2.1% 2.6% 2.7% -1.8% 8.5% -0.9% 1.4% 2.5% 3.1% 1.6% 2.6% 0.7% 0.1% 4.9% 1.7% 0.6% 4.3% 0.3% 1.7% 1.3% 0.9% 0.6% 1.0% 0.4% 0.4% 1.2% 1.7% 1.2% 0.5% 465 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.95e7 2.48e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.59e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.85e7 9.24e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.88e7 9.40e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.07e7 5.35e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.31e6 2.66e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.17e6 2.58e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 186-257 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:11 Page 1 of 21 466 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-1 7.57e8 12.04 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-2 7.66e8 14.18 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.55e3 Abs. Int. 3.12e8 PCB-3 7.48e8 14.36 1.56e8 0% 11.0 12.0 13.0 14.0 PCB-1 2.36e8 12.04 Rel. Int. 100% PCB-2 2.34e8 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.14e3 15.0 0.00e0 16.0 RT Abs. Int. 9.75e7 PCB-3 2.28e8 14.36 4.88e7 0% 11.0 12.0 13.0 14.0 ES-1 1.94e8 12.03 Rel. Int. 100% 15.0 Abs. Int. 7.70e7 ES-3 1.79e8 14.35 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 8.48e3 0.00e0 16.0 RT 3.85e7 0% 11.0 12.0 13.0 14.0 ES-1 5.88e7 12.03 Rel. Int. 100% 15.0 Abs. Int. 2.33e7 ES-3 5.31e7 14.35 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.17e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.48e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2447, 4248 scc: 186-257 Revised: 30-Dec-2013 12:40 (LKB) Printed: 03-Jan-2014 17:11 Page 2 of 21 467 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Rel. Int. 100% PCB-10 5.64e8 14.80 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.96e3 PCB-4 3.49e8 14.62 9.54e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.53e8 14.80 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.22e4 PCB-4 2.20e8 14.62 12.0 13.0 14.0 15.0 ES-4 6.97e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.20e8 6.02e7 0% 11.0 Abs. Int. 1.91e8 0.00e0 16.0 RT Abs. Int. 2.32e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.94e3 1.16e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.25e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.42e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.42e3 7.11e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.48e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5797, 8154 scc: 186-257 Revised: 30-Dec-2013 12:40 (LKB) Printed: 03-Jan-2014 17:11 Page 3 of 21 468 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.19e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-6 5.75e8 17.02 PCB-9 5.35e8 16.62 PCB-14 6.74e8 19.01 PCB-5 5.69e8 PCB-8 17.32 5.76e8 17.44 PCB-11 5.80e8 19.80 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 13/12 1.16e9 20.10 Abs. Int. 1.91e8 PCB-15 5.81e8 20.38 9.54e7 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.01e4 PCB-9 3.28e8 16.62 PCB-7 3.67e8 16.79 18.0 19.0 PCB-14 4.11e8 19.01 PCB-5 3.48e8 17.32 PCB-8 3.52e8 17.44 20.0 PCB-11 3.54e8 19.80 13/12 7.06e8 20.10 21.0 Abs. Int. 1.16e8 PCB-15 3.59e8 20.38 5.81e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.31e8 16.61 21.0 ES-15 1.36e8 20.37 0.00e0 RT Abs. Int. 4.21e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.87e4 2.11e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 8.44e7 16.61 21.0 ES-15 8.87e7 20.37 0.00e0 RT Abs. Int. 2.68e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 9.39e3 1.34e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2386, 7567 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 4 of 21 469 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 30/18 7.14e8 19.51 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 4.23e3 PCB-19 2.62e8 17.74 PCB-17 3.01e8 19.92 PCB-27 4.20e8 20.11 PCB-24 3.89e8 20.25 PCB-16 2.37e8 20.34 Abs. Int. 1.99e8 PCB-32 4.34e8 20.83 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.80e8 19.51 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 5.06e3 PCB-19 2.48e8 17.74 PCB-17 2.86e8 19.92 21.0 PCB-24 3.71e8 20.25 PCB-27 4.00e8 20.11 Rel. Int. 100% 18.0 19.0 PCB-16 2.25e8 20.34 20.0 PCB-32 4.13e8 20.83 21.0 9.49e7 0.00e0 RT Abs. Int. 2.38e7 ES-19 5.69e7 17.72 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 9.15e4 0.00e0 RT Abs. Int. 1.90e8 0% 17.0 9.97e7 1.19e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.16e7 ES-19 5.28e7 17.72 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.57e4 0.00e0 RT 1.08e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0138, 7970 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 5 of 21 470 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 1.75e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 28/20 7.84e8 23.19 26/29 PCB-23 8.07e8 PCB-34 3.99e8 22.42 3.98e8 22.14 21.98 PCB-31 4.13e8 22.90 Abs. Int. 1.95e8 PCB-22 3.70e8 23.75 PCB-36 4.06e8 25.14 PCB-39 4.17e8 25.46 PCB-38 3.90e8 25.99 PCB-35 3.61e8 26.39 PCB-37 3.69e8 26.75 0% 22.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 1.49e4 23.0 24.0 25.0 26.0 27.0 28/20 7.92e8 23.19 26/29 PCB-23 8.21e8 PCB-34 4.07e8 22.42 4.00e8 22.14 21.98 PCB-31 4.27e8 22.90 23.0 PCB-22 3.73e8 23.75 PCB-36 4.11e8 25.14 PCB-39 4.24e8 25.46 PCB-38 3.93e8 25.99 24.0 25.0 PCB-35 3.65e8 26.39 PCB-37 3.74e8 26.75 26.0 CS/SS-28 9.79e7 23.16 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e8 0% 22.0 9.74e7 27.0 0.00e0 RT Abs. Int. 2.75e7 ES-37 8.75e7 26.73 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.98e4 9.79e7 1.38e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 9.01e7 23.16 Rel. Int. 100% 27.0 0.00e0 RT Abs. Int. 2.57e7 ES-37 8.13e7 26.73 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.64e4 1.28e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3897, 4503 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 6 of 21 471 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-54 2.13e8 20.68 Rel. Int. 100% Abs. Int. 5.71e7 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 2.07e3 2.86e7 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.58e8 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.61e7 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.18e3 3.30e7 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.96e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.83e4 5.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.78e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.07e4 6.63e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0111, 4665 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 7 of 21 472 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 3.31e3 50/53 4.42e8 22.68 PCB-51 2.20e8 23.34 PCB-45 1.94e8 23.27 PCB-73 2.79e8 PCB-52 24.94 2.12e8 24.81 PCB-46 1.76e8 23.55 69/49 5.22e8 25.23 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 44/47… 6.94e8 25.74 PCB-48 2.12e8 25.52 59/62… 9.08e8 26.01 71/40 4.50e8 26.61 PCB-42 1.93e8 26.18 PCB-41 1.67e8 26.51 Abs. Int. 1.64e8 PCB-64 3.10e8 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 2.77e3 50/53 5.60e8 22.67 24.0 PCB-51 2.76e8 23.34 PCB-45 2.48e8 23.27 25.0 PCB-73 3.55e8 PCB-52 24.94 2.70e8 24.81 PCB-46 2.22e8 23.55 26.0 69/49 6.59e8 25.23 44/47… 8.79e8 25.73 PCB-48 2.68e8 25.52 27.0 59/62… 1.15e9 26.01 71/40 5.65e8 26.61 PCB-42 2.44e8 26.18 PCB-41 2.14e8 26.51 23.0 24.0 25.0 26.0 PCB-64 3.92e8 26.81 27.0 JS-52 4.53e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.06e8 0% 22.0 8.18e7 1.03e8 0.00e0 RT Abs. Int. 1.25e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.94e4 6.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.67e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.88e4 8.02e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6634, 9311 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 8 of 21 473 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 7.08e5 PCB-58 2.95e8 PCB-68 28.36 PCB-67 3.24e8 3.15e8 27.78 28.52 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 61/70... 1.21e9 29.04 PCB-55 2.78e8 29.47 PCB-60 PCB-80 2.82e8 3.28e8 30.10 30.43 PCB-79 3.33e8 31.75 PCB-78 2.67e8 32.25PCB-81 2.81e8 32.62 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 1.50e8 PCB-77 2.90e8 33.10 7.49e7 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 4.30e5 PCB-57 3.67e8 28.16 PCB-68 4.16e8 27.78 30.0 61/70... 1.55e9 29.04 PCB-63 4.18e8 PCB-66 3.61e8 28.74 29.32 32.0 PCB-60 3.59e8 30.10 PCB-56 3.53e8 29.91 PCB-80 4.19e8 30.43 PCB-79 4.27e8 31.75 34.0 PCB-78 3.43e8 32.24PCB-81 3.61e8 32.62 36.0 38.0 Abs. Int. 1.90e8 PCB-77 3.71e8 33.10 9.49e7 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.15e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.32e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.63e7 ES-77 6.25e7 33.08 8.16e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.94e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.92e4 36.0 38.0 0.00e0 RT Abs. Int. 2.16e7 ES-77 7.87e7 33.08 1.08e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9214, 1956 scc: 186-257 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 9 of 21 474 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-104 1.74e8 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.22e3 Abs. Int. 4.45e7 PCB-96 1.55e8 26.00 2.22e7 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.71e8 25.68 27.0 0.00e0 RT Abs. Int. 6.94e7 PCB-96 2.38e8 26.00 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.22e3 3.47e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.79e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.06e3 6.19e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.90e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.31e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 3.99e3 3.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9179, 1685 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 10 of 21 475 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 108/119... 1.09e9 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 4.02e5 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-103 1.67e8 27.70 PCB-91 1.70e8 100/93 29.04 3.16e8 28.49 PCB-88 PCB-84 1.50e8 1.30e8 28.98 29.23 PCB-121 2.18e8 29.99 113/90… 5.34e8 30.80 116/85 3.49e8 32.41 PCB-99 1.73e8 31.34 PCB-111 PCB-120 2.17e8 2.20e8 33.12 33.52 PCB-118 107/124 2.07e8 3.96e8 35.09 34.49 PCB-114 PCB-123 2.24e8 2.17e8 35.56 34.81 Abs. Int. 1.63e8 PCB-105 2.01e8 36.10 PCB-127 1.97e8 37.34 8.15e7 0% 28.0 30.0 32.0 36.0 38.0 108/119... 1.73e9 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 3.81e5 34.0 PCB-94 2.32e8 27.89 100/93 5.12e8 28.49 PCB-91 2.69e8 29.04 PCB-89 2.23e8 29.65 113/90… 8.58e8 30.80 PCB-112 3.34e8 PCB-92 31.44 2.35e8 30.31 116/85 PCB-115 5.66e8 3.29e8 PCB-111 32.41 32.62 3.49e8 33.12 PCB-117 PCB-110 PCB-120 3.10e8 3.14e8 PCB-82 3.55e8 32.32 32.53 2.05e8 33.52 32.81 PCB-118 107/124 3.31e8 6.37e8 35.09 34.49 PCB-114 PCB-123 3.56e8 3.50e8 35.56 34.81 Abs. Int. 2.59e8 PCB-105 3.25e8 36.10 PCB-127 3.15e8 37.33 1.30e8 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 7.11e7 33.10 JS-101 5.96e7 30.80 36.0 ES-114 ES-118 7.24e7 ES-123 6.82e7 35.54 7.10e7 35.07 34.79 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 5.01e3 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.77e7 ES-105 7.03e7 36.08 8.86e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.46e7 33.10 JS-101 3.72e7 30.80 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.24e3 34.0 36.0 ES-118 ES-114 ES-123 4.20e7 4.43e7 4.45e7 35.07 35.54 34.79 38.0 0.00e0 RT Abs. Int. 1.12e7 ES-105 4.41e7 36.08 5.59e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5110, 9189 scc: 186-257 Revised: 03-Jan-2014 16:45 (LKB) Printed: 03-Jan-2014 17:11 Page 11 of 21 476 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 4.01e7 PCB-126 1.72e8 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 7.09e3 2.01e7 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.56e7 PCB-126 2.74e8 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.06e4 3.28e7 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.43e7 ES-126 5.92e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.98e3 7.15e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 9.49e6 ES-126 3.86e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 6.20e3 4.75e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6238, 0621 scc: 186-257 Revised: 30-Dec-2013 12:42 (LKB) Printed: 03-Jan-2014 17:11 Page 12 of 21 477 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-136 2.43e8 31.27 PCB-150 PCB-155 2.62e8 PCB-145 2.81e8 30.96 2.47e8 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.99e3 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 147/149 139/140 3.74e8 3.81e8 34.11 34.64 PCB-148 1.89e8 32.82 151/135 3.58e8 PCB-144PCB-134 33.34 1.85e8 1.48e8 33.81 34.29 153/168 4.62e8 36.70 PCB-146 PCB-142 PCB-133 1.79e8 1.91e8 1.59e8 36.15 35.59 34.96 PCB-141 1.70e8 36.85 163/138… 5.67e8 37.76 PCB-164 PCB-160 2.34e8 2.40e8 37.47 37.90 0% 28.0 30.0 32.0 PCB-152 PCB-136 2.10e8 1.91e8 30.82 31.26 PCB-155 PCB-150 PCB-145 2.21e8 2.06e8 30.96 1.95e8 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 2.00e3 34.0 PCB-148 1.49e8 32.81 36.0 38.0 163/138… 4.47e8 147/149 139/140 37.76 153/168 151/135 2.94e8 3.00e8 PCB-142 3.63e8 2.80e8 34.11 34.641.23e8 36.70 33.34 PCB-158 34.96 PCB-154 2.02e8 PCB-133 PCB-146 PCB-141 PCB-137 PCB-143 1.66e8 38.08 PCB-131 1.40e8 1.51e8 1.35e8 1.26e8 33.55 1.31e8 1.47e8 36.15 37.39 35.59 34.37 34.81 36.85 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 5.48e7 30.64 Rel. Int. 100% ES-153 3.90e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 2.47e3 JS-138 3.51e7 37.72 Abs. Int. 1.07e8 5.37e7 0.00e0 RT Abs. Int. 8.44e7 4.22e7 0.00e0 RT Abs. Int. 1.34e7 6.72e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.22e7 30.64 Rel. Int. 100% ES-153 2.98e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.62e3 0.00e0 RT Abs. Int. 1.05e7 JS-138 2.69e7 37.72 5.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1491, 6768 scc: 186-257 Revised: 30-Dec-2013 12:42 (LKB) Printed: 03-Jan-2014 17:11 Page 13 of 21 478 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.33e8 38.82 PCB-159 2.59e8 39.64 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.38e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-162 2.54e8 39.88 156/157 4.95e8 41.27 PCB-167 2.73e8 40.29 (2.50e8 + 2.02e8) * 100 pg/uL RRF(PCB-169) = = 1.14 (5.54e7 + 4.38e7) * 400 pg/uL LKB 03-Jan-2014 15:13 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 1.01e8 PCB-169 2.50e8 43.99 5.03e7 0% 39.0 Rel. Int. 100% 128/166 3.53e8 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.35e4 40.0 PCB-162 PCB-159 2.08e8 2.11e8 39.88 39.64 41.0 42.0 43.0 44.0 45.0 156/157 4.05e8 41.27 Abs. Int. 8.13e7 PCB-169 2.02e8 43.99 PCB-167 2.23e8 40.29 4.06e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.89e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 6.07e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.14e8 41.25 0.00e0 RT Abs. Int. 2.04e7 ES-169 5.54e7 43.97 1.02e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 4.65e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 1.15e4 42.0 43.0 44.0 45.0 ES-156/157 8.87e7 41.25 0.00e0 RT Abs. Int. 1.58e7 ES-169 4.38e7 43.97 7.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0329, 5135 scc: 186-257 PKD: 30-Dec-2013 12:43 Printed: 03-Jan-2014 17:11 Page 14 of 21 479 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-184 PCB-188 PCB-179 1.36e8 1.40e8 1.53e8 36.30 35.83 35.55 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.20e3 PCB-186 1.35e8 36.99 Abs. Int. 3.81e7 PCB-178 1.01e8 38.12 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 PCB-179 1.27e8 1.41e8 35.83 35.55 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 1.40e3 37.0 PCB-176 1.36e8 36.59 PCB-186 1.24e8 36.99 38.0 32.0 33.0 34.0 35.0 36.0 37.0 PCB-178 9.30e7 38.12 38.0 ES-188 3.06e7 35.53 Rel. Int. 100% CS/SS-178 1.86e7 38.10 RRF(CS/SS-178) = 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.72e7 35.53 Rel. Int. 100% CS/SS-178 1.68e7 38.10 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.93e6 0.00e0 RT Abs. Int. 6.93e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.88e3 31.0 1.81e7 Abs. Int. 7.87e6 (1.86e7 + 1.68e7) = 0.571 (3.51e7 + 2.69e7) LKB 03-Jan-2014 15:12 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.68e3 0.00e0 RT Abs. Int. 3.61e7 0% 31.0 1.91e7 36.0 37.0 38.0 Rel. Int. 100% 3.47e6 0.00e0 RT Abs. Int. 1.88e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5850, 9481 scc: 186-257 Revised: 30-Dec-2013 12:43 (LKB) Printed: 03-Jan-2014 17:11 Page 15 of 21 480 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.32e4 PCB-183 1.69e8 39.42 PCB-182 PCB-185 1.72e8 1.65e8 39.08 39.51 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 180/193 3.63e8 42.40 171/173 2.79e8 PCB-181 40.53 PCB-177 1.59e8 1.38e8 40.34 39.99 PCB-172 1.44e8 41.88 PCB-191 2.00e8 42.74 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-170 1.39e8 43.51 Abs. Int. 6.46e7 PCB-190 1.98e8 43.96 3.23e7 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.40e4 40.0 PCB-182 1.63e8 39.07 PCB-187 1.58e8 38.89 PCB-183 1.60e8 39.42 41.0 171/173 2.64e8 PCB-181 40.53 PCB-177 1.51e8 1.30e8 40.34 39.99 42.0 43.0 180/193 3.43e8 42.40 PCB-172 1.36e8 41.88 PCB-191 1.88e8 42.73 44.0 PCB-170 1.33e8 43.51 45.0 Abs. Int. 6.16e7 PCB-190 1.88e8 43.96 3.08e7 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.62e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 9.22e6 ES-170 2.97e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 4.39e3 0.00e0 RT 4.61e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.33e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 8.14e6 ES-170 2.73e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.64e3 0.00e0 RT 4.07e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3134, 7737 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 16 of 21 481 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-189 2.13e8 46.13 Abs. Int. 5.10e7 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 7.35e3 2.55e7 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.02e8 46.12 Abs. Int. 4.99e7 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 5.38e3 2.50e7 0% 46.0 Rel. Int. 100% ES-189 4.82e7 46.11 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 5.63e3 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 1.16e7 (4.82e7 + 4.62e7) * 100 pg/uL RRF(ES-189) = = 1.58 (2.85e7 + 3.14e7) * 100 pg/uL LKB 03-Jan-2014 15:12 5.79e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.62e7 46.11 0.00e0 RT Abs. Int. 1.12e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 5.14e3 5.60e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6642, 3679 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 17 of 21 482 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-202 1.23e8 40.10 PCB-201 1.47e8 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 2.30e3 PCB-197 1.40e8 41.66 PCB-200 PCB-204 1.30e8 1.29e8 41.75 41.47 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 198/199 1.88e8 44.07 Abs. Int. 3.66e7 PCB-196 9.72e7 44.65 PCB-203 1.02e8 44.82 1.83e7 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.34e8 40.10 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.91e3 41.0 PCB-201 1.61e8 40.89 42.0 43.0 PCB-197 1.53e8 PCB-204 41.66 PCB-200 1.41e8 1.41e8 41.75 41.47 44.0 45.0 198/199 2.07e8 44.07 Abs. Int. 4.04e7 PCB-196 1.06e8 44.65 PCB-203 1.11e8 44.82 2.02e7 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.93e7 40.08 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.00e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.98e3 3.50e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.12e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.46e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 2.00e3 3.73e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0058, 7129 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 18 of 21 483 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 4.72e3 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-205 1.54e8 48.30 PCB-195 1.10e8 45.95 Abs. Int. 3.56e7 PCB-194 1.22e8 47.90 1.78e7 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 6.42e3 47.0 48.0 49.0 50.0 PCB-205 1.68e8 48.30 PCB-195 1.21e8 45.95 0.00e0 RT Abs. Int. 3.85e7 PCB-194 1.32e8 47.89 1.93e7 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.55e7 48.28 JS-194 2.85e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 4.99e3 49.0 0.00e0 RT Abs. Int. 8.26e6 4.13e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.96e7 48.28 Rel. Int. 100% Abs. Int. 9.37e6 JS-194 3.14e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.69e3 0.00e0 RT 4.68e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0147, 9308 scc: 186-257 Revised: 30-Dec-2013 12:43 (LKB) Printed: 03-Jan-2014 17:12 Page 19 of 21 484 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 3.76e3 PCB-208 1.42e8 45.74 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-207 1.50e8 46.53 Abs. Int. 3.60e7 PCB-206 9.85e7 49.77 1.80e7 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 5.22e3 PCB-208 1.81e8 45.74 47.0 48.0 49.0 50.0 PCB-207 1.90e8 46.53 Abs. Int. 4.58e7 PCB-206 1.25e8 49.77 2.29e7 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 3.15e7 45.72 50.0 0.00e0 RT Abs. Int. 7.52e6 ES-206 2.24e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.53e3 3.76e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.92e7 45.72 50.0 Abs. Int. 9.31e6 ES-206 2.77e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.58e3 0.00e0 RT 4.65e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9272, 3360 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:12 Page 20 of 21 485 of 622 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-209 1.58e8 51.25 Rel. Int. 100% Abs. Int. 3.32e7 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 7.36e2 1.66e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.34e8 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.80e7 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 8.28e2 1.40e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.60e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.71e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 1.07e3 3.86e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.05e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.37e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.97e2 3.18e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.17e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.58e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0022, 9026 scc: 186-257 PKD: 30-Dec-2013 12:40 Printed: 03-Jan-2014 17:12 Page 21 of 21 486 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.11 32.63 36.10 35.56 35.09 34.82 38.72 41.27 40.29 43.99 46.12 51.24 3.92E+09 3.81E+09 3.11E+09 3.45E+09 3.20E+09 3.32E+09 2.76E+09 5.55E+09 3.01E+09 2.75E+09 2.52E+09 1.71E+09 0.79 Y 0.78 Y 0.62 Y 0.63 Y 0.63 Y 0.62 Y 0.63 Y 1.23 Y 1.22 Y 1.24 Y 1.05 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.22 1.17 1.18 1.29 1.25 1.25 1.21 1.17 1.23 1.17 1.16 1.15 6.1% 4.4% 5.9% 6.9% 4.7% 3.0% 9.8% 6.3% 5.8% 4.3% 7.9% 3.3% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.03 14.35 14.61 20.38 17.73 26.74 20.67 33.09 32.61 25.67 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.25 40.27 43.97 43.49 42.42 35.53 46.11 40.08 48.27 49.75 45.72 51.22 2.62E+08 2.47E+08 1.23E+08 2.45E+08 1.20E+08 1.94E+08 9.79E+07 1.61E+08 1.63E+08 8.86E+07 1.32E+08 1.34E+08 1.28E+08 1.33E+08 1.14E+08 8.16E+07 1.13E+08 2.38E+08 1.22E+08 1.17E+08 6.70E+07 8.32E+07 6.88E+07 1.09E+08 7.17E+07 8.57E+07 5.62E+07 8.18E+07 7.42E+07 3.21 Y 3.30 Y 1.63 Y 1.53 Y 1.07 Y 1.09 Y 0.83 Y 0.79 Y 0.79 Y 1.66 Y 1.58 Y 1.60 Y 1.60 Y 1.59 Y 1.54 Y 1.32 Y 1.29 Y 1.27 Y 1.26 Y 1.27 Y 1.09 Y 1.09 Y 1.10 Y 1.01 Y 0.94 Y 0.89 Y 0.81 Y 0.80 Y 1.20 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.13 1.06 0.53 1.05 0.52 1.69 0.85 1.40 1.42 0.78 1.17 1.19 1.14 1.18 1.01 1.10 1.52 1.61 1.65 1.58 0.97 1.21 0.93 1.58 0.97 1.25 0.82 1.19 1.08 -5.6% -2.3% 0.9% 1.3% 2.2% 1.6% -0.9% 1.2% 4.0% -2.5% -2.9% -2.5% -1.9% -0.8% -2.2% -1.2% -4.1% 0.4% -1.0% 1.8% 2.9% 6.3% -1.1% -0.3% -0.2% 0.1% -1.6% 1.2% -2.8% Page 1 of 6 487 of 622 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.10 38.10 2.10E+08 1.37E+08 4.42E+07 1.08 Y 1.60 Y 1.12 Y 1.11 1.03 0.62 1.09 1.03 0.64 -2.3% 0.0% 3.8% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.10 38.10 2.10E+08 1.37E+08 4.42E+07 1.08 Y 1.60 Y 1.12 Y 1.85 1.22 0.58 1.83 1.21 0.60 -0.7% -0.7% 2.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.81 37.73 47.87 2.33E+08 1.15E+08 1.13E+08 7.41E+07 6.88E+07 1.55 Y 0.81 Y 1.60 Y 1.32 Y 0.90 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.05 14.37 14.63 20.39 17.75 26.76 20.69 25.69 30.66 35.55 40.10 48.29 45.74 49.77 4.77E+09 4.95E+09 3.16E+09 5.27E+09 2.86E+09 4.48E+09 2.66E+09 2.58E+09 2.91E+09 1.80E+09 1.58E+09 1.93E+09 1.95E+09 1.32E+09 2.71 Y 2.98 Y 1.59 Y 1.63 Y 1.05 Y 0.99 Y 0.82 Y 0.65 Y 1.29 Y 1.08 Y 0.92 Y 0.93 Y 0.79 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.91 1.00 1.29 1.08 1.19 1.16 1.36 1.46 1.29 1.31 1.10 1.13 1.19 1.18 -4.4% -0.6% 4.4% 5.5% 3.6% 7.4% 0.3% 1.6% 2.3% 3.0% 4.7% 6.3% 6.1% 5.5% Page 2 of 6 488 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 12.05 14.18 14.37 14.63 14.81 16.63 16.80 17.02 17.33 17.45 19.02 19.81 20.10 20.39 17.75 19.52 19.93 20.12 20.26 20.35 20.84 21.99 22.14 22.43 22.63 22.91 23.20 23.38 23.75 25.14 25.46 26.00 26.39 26.76 20.69 22.68 23.28 23.35 23.56 24.82 24.95 25.05 25.24 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 4.77E+09 5.06E+09 4.95E+09 3.16E+09 5.06E+09 4.77E+09 5.47E+09 5.14E+09 5.14E+09 5.25E+09 6.12E+09 5.26E+09 1.05E+10 5.27E+09 2.86E+09 7.69E+09 3.33E+09 4.61E+09 4.39E+09 2.55E+09 4.79E+09 4.49E+09 4.54E+09 9.34E+09 4.59E+09 4.84E+09 9.02E+09 9.35E+09 4.32E+09 4.81E+09 4.93E+09 4.32E+09 4.24E+09 4.48E+09 2.66E+09 5.80E+09 2.69E+09 2.73E+09 2.31E+09 2.76E+09 3.82E+09 2.28E+09 6.91E+09 RA 2.71 Y 2.92 Y 2.98 Y 1.59 Y 1.58 Y 1.62 Y 1.65 Y 1.63 Y 1.64 Y 1.64 Y 1.60 Y 1.63 Y 1.63 Y 1.63 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.00 Y 0.98 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.97 Y 0.98 Y 0.99 Y 0.98 Y 1.00 Y 0.99 Y 0.99 Y 0.82 Y 0.79 Y 0.79 Y 0.80 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.91 1.02 1.00 1.29 2.06 0.97 1.11 1.05 1.05 1.07 1.25 1.07 1.07 1.08 1.19 1.60 1.38 1.92 1.83 1.06 1.99 1.16 1.17 1.21 1.18 1.25 1.17 1.21 1.12 1.24 1.27 1.11 1.10 1.16 1.36 0.89 0.83 0.84 0.71 0.85 1.17 0.70 1.06 Dev'n -4.4% -0.9% -0.6% 4.4% 4.1% 2.9% 6.5% 5.3% 4.7% 3.7% 5.8% 6.2% 8.0% 5.5% 3.6% 4.0% 6.0% 5.5% 5.9% 5.3% 3.8% 2.3% 1.5% 3.0% 2.4% 2.1% 2.9% 2.9% 3.4% 6.2% 5.1% 0.9% 5.3% 7.4% 0.3% 1.5% 7.6% -2.6% 1.2% 0.5% 5.5% -1.5% 3.6% 489 of 622 PCB QC Summary - Ax2 Detail Lab ID: CS5_131220_PCB_XA Acquired: 20-DEC-2013 20:49 Datafile: 131220X08 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.02 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.52 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.79 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.37 PCB-67 23'45-TeCB 28.53 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.05 PCB-66 23'44'-TeCB 29.33 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.10 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.76 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.01 PCB-103 22'45'6-PeCB 27.71 PCB-94 22'356'-PeCB 27.90 PCB-95 22'35'6-PeCB 28.28 PCB-100/93 22'44'6/22'356-PeCB 28.50 PCB-102 22'456'-PeCB 28.61 PCB-98 22'34'6'-PeCB 28.68 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.24 PCB-89 22'346'-PeCB 29.65 PCB-121 23'45'6-PeCB 30.00 PCB-92 22'355'-PeCB 30.32 PCB-113/90/101 ...-PeCB 30.80 PCB-83 22'33'5-PeCB 31.24 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.79 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.42 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 2.83E+09 9.10E+09 1.15E+10 2.53E+09 2.38E+09 5.79E+09 4.17E+09 4.01E+09 4.24E+09 3.81E+09 4.00E+09 4.17E+09 4.37E+09 1.58E+10 3.68E+09 3.76E+09 3.68E+09 3.79E+09 4.36E+09 4.29E+09 3.62E+09 2.58E+09 2.25E+09 2.54E+09 2.18E+09 2.36E+09 4.75E+09 2.73E+09 2.05E+09 2.08E+09 2.73E+09 1.98E+09 2.09E+09 3.31E+09 2.25E+09 8.09E+09 1.82E+09 2.67E+09 3.15E+09 1.55E+10 3.32E+09 5.04E+09 3.01E+09 RA 0.79 Y 0.79 Y 0.81 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.65 Y 0.65 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.64 Y 0.61 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.68 Y 0.62 Y 0.63 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.87 0.93 1.18 0.78 0.73 0.89 1.28 1.23 1.30 1.17 1.23 1.28 1.34 1.21 1.13 1.15 1.13 1.16 1.34 1.32 1.11 1.46 1.27 0.95 0.82 0.89 0.89 1.02 0.77 0.78 1.03 0.74 0.79 1.24 0.84 1.01 0.69 1.00 1.18 0.97 1.25 0.95 1.13 Dev'n 3.4% 3.0% 1.4% 1.9% 5.0% 3.5% 4.8% 1.8% 1.9% 0.4% 4.1% 1.6% 3.2% 1.4% 2.4% 3.0% 1.6% 2.6% 1.9% 0.8% 4.6% 1.6% 3.5% 2.6% 2.5% 2.4% 3.4% 5.8% 1.6% -2.2% 8.9% 3.7% 3.0% 3.7% 2.9% 2.8% -4.1% 8.8% 1.3% -0.7% 9.6% 0.6% 1.1% 490 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 32.62 32.81 33.13 33.53 34.50 34.71 34.93 35.39 37.34 30.66 30.82 30.97 31.27 31.54 32.82 33.34 33.55 33.81 34.12 34.29 34.37 34.64 34.81 34.96 35.19 35.60 35.94 36.15 36.27 36.70 36.85 37.19 37.39 37.47 37.77 37.90 38.09 38.82 39.64 39.88 35.55 35.83 36.30 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 3.31E+09 1.94E+09 3.35E+09 3.41E+09 6.21E+09 3.61E+09 3.03E+09 2.83E+09 3.14E+09 2.91E+09 2.78E+09 2.75E+09 2.61E+09 2.61E+09 2.03E+09 3.85E+09 2.26E+09 1.97E+09 4.02E+09 1.54E+09 1.89E+09 4.13E+09 1.73E+09 1.72E+09 1.74E+09 1.91E+09 2.36E+09 2.06E+09 2.61E+09 4.99E+09 1.83E+09 1.63E+09 2.02E+09 2.53E+09 6.19E+09 2.49E+09 2.80E+09 4.79E+09 2.87E+09 2.82E+09 1.80E+09 1.59E+09 1.62E+09 RA 0.63 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 1.29 Y 1.26 Y 1.26 Y 1.27 Y 1.28 Y 1.30 Y 1.28 Y 1.26 Y 1.28 Y 1.26 Y 1.26 Y 1.28 Y 1.28 Y 1.28 Y 1.26 Y 1.27 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.26 Y 1.27 Y 1.29 Y 1.26 Y 1.29 Y 1.28 Y 1.22 Y 1.23 Y 1.22 Y 1.08 Y 1.11 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.24 0.73 1.26 1.28 1.17 1.36 1.14 1.06 1.19 1.29 1.23 1.22 1.16 1.16 1.25 1.18 1.38 1.20 1.23 0.94 1.16 1.27 1.06 1.06 1.06 1.17 1.44 1.26 1.60 1.53 1.12 1.00 1.24 1.55 1.27 1.52 1.72 0.98 1.17 1.15 1.31 1.15 1.17 Dev'n 7.2% 4.5% 3.1% 5.7% 6.2% 8.2% 3.1% 6.1% 8.8% 2.3% 5.0% 3.6% 8.4% 3.7% 5.4% 3.6% 3.2% 1.8% 4.9% 2.0% 2.7% 5.1% 3.7% 6.7% 3.2% 3.7% 2.5% 5.0% 5.3% 5.0% 2.9% 3.0% 6.3% 3.5% 6.4% 0.6% 3.4% 8.8% 5.3% 7.5% 3.0% -0.7% 4.2% 491 of 622 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 36.59 36.99 38.12 38.67 38.90 39.08 39.42 39.51 39.62 39.99 40.34 40.53 41.88 42.13 42.40 42.73 43.51 43.96 40.10 40.89 41.47 41.66 41.75 44.07 44.65 44.82 45.95 47.89 48.29 45.74 46.53 49.77 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 1.74E+09 1.57E+09 1.21E+09 1.91E+09 2.01E+09 2.05E+09 2.03E+09 2.01E+09 1.71E+09 1.65E+09 1.95E+09 3.42E+09 1.73E+09 2.27E+09 4.38E+09 2.40E+09 1.66E+09 2.44E+09 1.58E+09 1.78E+09 1.66E+09 1.80E+09 1.68E+09 2.46E+09 1.24E+09 1.30E+09 1.40E+09 1.50E+09 1.93E+09 1.95E+09 2.03E+09 1.32E+09 RA 1.08 Y 1.09 Y 1.09 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 0.92 Y 0.92 Y 0.92 Y 0.92 Y 0.92 Y 0.91 Y 0.91 Y 0.92 Y 0.92 Y 0.93 Y 0.93 Y 0.79 Y 0.79 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.26 1.14 0.88 1.15 1.21 1.23 1.22 1.21 1.03 0.99 1.17 1.03 1.04 1.36 1.31 1.44 1.24 1.82 1.10 1.24 1.16 1.26 1.17 0.86 0.87 0.91 0.82 0.88 1.13 1.19 1.24 1.18 Dev'n 2.3% 1.1% 4.2% 7.1% 6.2% 4.6% 1.1% 13.9% 4.0% 4.3% 7.5% 8.3% 5.0% 5.9% 4.3% 3.3% 9.0% 9.7% 4.7% 1.8% 3.8% 5.5% 6.1% 5.9% 3.9% 4.0% 6.5% 4.1% 6.3% 6.1% 4.2% 5.5% 492 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.74e7 2.37e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.57e7 1.28e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.87e7 9.33e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.96e7 9.79e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.14e7 5.71e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.71e6 2.86e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.37e6 2.68e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 807-075 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:13 Page 1 of 21 493 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-1 3.48e9 12.05 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-2 3.77e9 14.18 Abs. Int. 1.07e9 PCB-3 3.71e9 14.37 MoCB 10.03-16.00 188.0393 Fn1 Flags: OPBM 4σ 4.15e3 5.37e8 0% 11.0 12.0 13.0 PCB-1 1.29e9 12.05 Rel. Int. 100% 14.0 PCB-2 1.29e9 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.52e3 15.0 0.00e0 16.0 RT Abs. Int. 5.17e8 PCB-3 1.25e9 14.37 2.58e8 0% 11.0 12.0 13.0 14.0 ES-1 2.00e8 12.03 Rel. Int. 100% 15.0 Abs. Int. 7.82e7 ES-3 1.89e8 14.35 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 7.14e3 0.00e0 16.0 RT 3.91e7 0% 11.0 12.0 13.0 14.0 ES-1 6.21e7 12.03 Rel. Int. 100% 15.0 Abs. Int. 2.45e7 ES-3 5.75e7 14.35 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.23e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.74e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.37e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7909, 8443 scc: 807-075 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 2 of 21 494 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Rel. Int. 100% PCB-4 1.94e9 14.63 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: OPBM 4σ 5.76e3 PCB-10 3.10e9 14.81 5.11e8 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 1.96e9 14.81 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.26e4 PCB-4 1.22e9 14.63 12.0 13.0 14.0 15.0 ES-4 7.59e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.47e8 3.23e8 0% 11.0 Abs. Int. 1.02e9 0.00e0 16.0 RT Abs. Int. 2.55e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.86e3 1.27e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.67e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.50e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.71e3 7.49e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.74e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.37e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9558, 1963 scc: 807-075 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 3 of 21 495 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: OPBM 4σ 1.34e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-6 3.19e9 17.02 PCB-9 2.95e9 16.63 PCB-14 3.77e9 19.02 PCB-5 3.19e9 17.33 PCB-8 3.26e9 17.45 PCB-11 3.26e9 19.81 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 13/12 6.49e9 20.10 Abs. Int. 1.07e9 PCB-15 3.27e9 20.39 5.36e8 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 3.90e4 PCB-9 1.82e9 16.63 18.0 PCB-14 2.35e9 19.02 PCB-5 1.95e9 PCB-8 17.33 1.99e9 17.45 PCB-7 2.06e9 16.80 19.0 20.0 PCB-11 2.00e9 19.81 13/12 3.99e9 20.10 21.0 Abs. Int. 6.86e8 PCB-15 2.01e9 20.39 3.43e8 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.42e8 16.61 21.0 ES-15 1.48e8 20.38 0.00e0 RT Abs. Int. 4.57e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.73e4 2.28e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 9.12e7 16.61 21.0 ES-15 9.71e7 20.38 0.00e0 RT Abs. Int. 2.93e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.93e3 1.46e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3253, 5347 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 4 of 21 496 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 30/18 3.92e9 19.52 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: OPBM 4σ 4.61e3 PCB-19 1.46e9 17.75 PCB-17 1.71e9 19.93 PCB-27 2.36e9 20.12 PCB-24 2.24e9 20.26 PCB-16 1.30e9 20.35 Abs. Int. 1.05e9 PCB-32 2.46e9 20.84 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 3.78e9 19.52 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: OPBM 4σ 3.65e3 PCB-19 1.40e9 17.75 PCB-17 1.62e9 19.93 PCB-24 2.15e9 20.26 PCB-27 2.25e9 20.12 PCB-16 1.24e9 20.35 21.0 Rel. Int. 100% 18.0 19.0 20.0 PCB-32 2.34e9 20.83 21.0 5.20e8 0.00e0 RT Abs. Int. 2.64e7 ES-19 6.21e7 17.73 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 9.95e4 0.00e0 RT Abs. Int. 1.04e9 0% 17.0 5.26e8 1.32e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.45e7 ES-19 5.82e7 17.73 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.48e4 0.00e0 RT 1.22e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8073, 3622 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 5 of 21 497 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 28/20 4.47e9 23.20 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: OPBM 4σ 4.92e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-23 PCB-34 2.25e9 2.24e9 22.14 21.99 26/29 4.64e9 22.43 PCB-31 2.40e9 22.91 Abs. Int. 1.07e9 PCB-22 2.14e9 23.75 PCB-36 2.39e9 25.14 PCB-39 2.44e9 25.46 PCB-38 2.15e9 26.00 PCB-35 2.11e9 26.39 PCB-37 2.23e9 26.76 0% 22.0 24.0 25.0 26.0 27.0 28/20 4.55e9 23.20 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: OPBM 4σ 5.05e4 23.0 PCB-23 PCB-34 2.29e9 2.25e9 22.14 21.99 26/29 4.70e9 22.43 PCB-31 2.44e9 22.91 23.0 PCB-22 2.18e9 23.75 PCB-36 2.42e9 25.14 PCB-39 2.49e9 25.46 PCB-38 2.16e9 26.00 24.0 25.0 PCB-35 2.13e9 26.39 PCB-37 2.25e9 26.75 26.0 CS/SS-28 1.09e8 23.16 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e9 5.32e8 0% 22.0 5.35e8 27.0 ES-37 1.01e8 26.74 0.00e0 RT Abs. Int. 2.96e7 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 8.57e4 1.48e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 1.01e8 23.16 Rel. Int. 100% 27.0 ES-37 9.28e7 26.74 0.00e0 RT Abs. Int. 2.82e7 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.96e4 1.41e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3047, 4081 scc: 807-075 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 6 of 21 498 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-54 1.20e9 20.69 Rel. Int. 100% Abs. Int. 3.45e8 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 2.02e3 1.72e8 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.46e9 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.14e8 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.44e3 2.07e8 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.43e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.72e4 6.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 5.36e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.53e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.34e4 7.63e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0340, 6239 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 7 of 21 499 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 5.68e3 50/53 2.56e9 22.68 PCB-51 1.21e9 23.35 PCB-45 1.19e9 23.28 PCB-73 1.69e9 PCB-52 24.95 1.22e9 24.82 PCB-46 1.02e9 23.56 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 59/62… 44/47… 5.18e9 4.02e9 26.02 25.74 69/49 3.05e9 25.24 PCB-48 1.25e9 25.52 PCB-42 1.12e9 26.18 71/40 2.56e9 26.61 PCB-41 1.04e9 26.52 Abs. Int. 9.33e8 PCB-64 1.85e9 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: OPBM 4σ 6.24e3 50/53 3.24e9 22.68 24.0 PCB-51 1.52e9 23.35 PCB-45 1.50e9 23.28 25.0 PCB-73 2.13e9 PCB-52 24.95 1.54e9 24.82 PCB-46 1.29e9 23.56 26.0 44/47… 59/62… 5.08e9 6.37e9 26.02 25.74 69/49 3.85e9 25.24 PCB-48 1.58e9 25.52 PCB-42 1.41e9 26.18 27.0 PCB-64 2.32e9 26.81 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.11e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e9 71/40 3.23e9 26.61 PCB-41 1.33e9 26.52 4.66e8 5.33e8 0.00e0 RT Abs. Int. 1.44e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.50e4 7.22e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 6.35e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.80e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 2.42e4 9.02e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7633, 4971 scc: 807-075 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 8 of 21 500 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 3.46e6 PCB-58 1.77e9 PCB-68 28.37 PCB-67 1.86e9 1.83e9 27.79 28.53 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 61/70... 7.00e9 29.05 PCB-55 1.66e9 29.47 PCB-60 PCB-80 1.67e9 1.92e9 30.10 30.43 PCB-79 1.89e9 31.76 PCB-78 1.60e9 32.25PCB-81 1.67e9 32.63 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Abs. Int. 8.48e8 PCB-77 1.73e9 33.11 4.24e8 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: OPBM 4σ 2.54e6 PCB-68 2.38e9 27.79 30.0 61/70... 8.84e9 PCB-60 PCB-67 29.05 2.13e9 2.34e9 30.10 28.53 PCB-63 PCB-80 2.44e9 PCB-66 PCB-56 2.06e9 2.05e9 2.44e9 28.75 29.91 29.33 30.43 32.0 PCB-79 2.40e9 31.76 34.0 PCB-78 2.02e9 32.25PCB-81 2.13e9 32.63 36.0 38.0 Abs. Int. 1.07e9 PCB-77 2.19e9 33.11 5.33e8 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.18e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.65e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 2.00e7 ES-77 7.10e7 33.09 9.98e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 9.11e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.84e4 36.0 38.0 0.00e0 RT Abs. Int. 2.45e7 ES-77 8.96e7 33.09 1.23e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3954, 5702 scc: 807-075 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 9 of 21 501 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-104 1.01e9 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.69e3 Abs. Int. 2.66e8 PCB-96 8.84e8 26.01 1.33e8 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 1.57e9 25.69 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.74e3 27.0 0.00e0 RT Abs. Int. 4.07e8 PCB-96 1.37e9 26.01 2.04e8 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 5.53e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.48e3 7.06e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 3.33e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.34e3 4.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6832, 9715 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 10 of 21 502 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 108/119... 6.27e9 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 6.54e6 PCB-103 9.76e8 27.71 100/93 1.82e9 28.50 PCB-88 7.91e8 28.98 PCB-121 1.27e9 30.00 113/90… 3.10e9 30.80 116/85 1.94e9 32.42 PCB-99 1.03e9 31.34 PCB-111 PCB-120 1.29e9 1.30e9 33.13 33.53 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-118 107/124 1.23e9 2.39e9 35.09 34.50 PCB-114 PCB-123 1.33e9 1.27e9 35.56 34.82 Abs. Int. 8.81e8 PCB-105 1.20e9 36.10 PCB-127 1.21e9 37.34 4.40e8 0% 28.0 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: OPBM 4σ 5.33e6 30.0 100/93 2.93e9 28.50 PCB-94 1.34e9 27.90 PCB-91 1.68e9 29.04 PCB-121 2.05e9 30.00 32.0 113/90… 4.99e9 30.80 34.0 108/119... 9.26e9 31.79 PCB-112 1.93e9 31.44 116/85 PCB-115 3.10e9 2.03e9 32.42 32.62 PCB-111 2.06e9 PCB-117 PCB-110 33.13 PCB-120 2.05e9 1.85e9 2.11e9 32.33 PCB-82 32.53 33.53 1.20e9 32.81 36.0 107/124 PCB-118 3.82e9 1.97e9 34.50 35.09 PCB-114 PCB-123 2.12e9 2.05e9 35.56 34.82 38.0 Abs. Int. 1.07e9 PCB-105 1.91e9 36.10 PCB-127 1.94e9 37.34 5.37e8 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 8.44e7 33.10 JS-101 6.96e7 30.81 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 9.28e3 34.0 36.0 ES-123 8.16e7 34.79 ES-114 8.27e7 35.54 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 2.13e7 ES-105 8.08e7 36.08 1.07e7 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.27e7 33.11 JS-101 4.34e7 30.81 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 6.82e3 34.0 36.0 ES-118 ES-123 4.95e7 5.15e7 35.07 34.79 38.0 0.00e0 RT Abs. Int. 1.32e7 ES-105 5.11e7 36.08 6.61e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0782, 2709 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 11 of 21 503 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Abs. Int. 2.63e8 PCB-126 1.07e9 38.72 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.64e4 1.32e8 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 4.19e8 PCB-126 1.69e9 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 2.44e4 2.09e8 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.65e7 ES-126 6.89e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.99e3 8.25e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.08e7 ES-126 4.48e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 8.23e3 5.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1246, 7147 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 12 of 21 504 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% PCB-150 PCB-155 1.54e9 1.64e9 30.97 30.66 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.19e4 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 147/149 139/140 2.24e9 2.32e9 34.64 34.12 PCB-145 1.46e9 31.54 PCB-148 1.15e9 32.82 153/168 2.80e9 36.70 151/135PCB-144 2.16e9 1.10e9 PCB-143 PCB-142 PCB-133 PCB-146 1.06e9 9.62e8 1.07e9 1.15e9 33.34 33.81 36.15 34.37 35.60 34.96 PCB-141 1.02e9 36.85 163/138… 3.46e9 37.77 PCB-164 PCB-160 1.42e9 1.40e9 37.47 37.90 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PCB-150 PCB-155 1.22e9 1.27e9 30.97 30.66 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.03e4 PCB-145 1.15e9 31.54 PCB-148 8.85e8 32.82 147/149 139/140 151/135 1.78e9 1.81e9 1.69e9 34.12 34.64 33.34 PCB-154 9.99e8 PCB-143 PCB-131 33.55 8.28e8 7.60e8 34.37 34.81 36.0 38.0 153/168 2.19e9 36.70 PCB-165 1.04e9 35.94 163/138… 2.74e9 37.77 PCB-137 PCB-141 8.87e8 8.04e8 37.39 36.85 30.0 32.0 34.0 36.0 38.0 ES-153 4.65e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.02e4 0.00e0 RT Abs. Int. 5.14e8 2.57e8 ES-155 6.35e7 30.64 Rel. Int. 100% 3.23e8 PCB-158 1.23e9 38.09 0% 28.0 Abs. Int. 6.47e8 0.00e0 RT Abs. Int. 1.67e7 JS-138 4.21e7 37.73 8.33e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.94e7 30.64 Rel. Int. 100% ES-153 3.51e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 9.67e3 0.00e0 RT Abs. Int. 1.26e7 JS-138 3.19e7 37.73 6.31e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2850, 7769 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 13 of 21 505 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 2.63e9 38.82 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.24e4 PCB-159 1.58e9 39.64 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-162 1.55e9 39.88 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 156/157 3.06e9 41.27 Abs. Int. 6.29e8 PCB-169 1.52e9 43.99 PCB-167 1.65e9 40.29 3.15e8 0% 39.0 Rel. Int. 100% 40.0 128/166 2.16e9 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 3.49e4 PCB-159 1.29e9 39.64 PCB-162 1.27e9 39.88 41.0 42.0 43.0 44.0 45.0 156/157 2.49e9 41.27 Abs. Int. 5.14e8 PCB-169 1.23e9 43.99 PCB-167 1.35e9 40.29 2.57e8 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 6.83e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 9.18e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.33e8 41.25 0.00e0 RT Abs. Int. 2.38e7 ES-169 6.57e7 43.97 1.19e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.40e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 1.04e4 42.0 43.0 44.0 45.0 ES-156/157 1.05e8 41.25 0.00e0 RT Abs. Int. 1.92e7 ES-169 5.16e7 43.97 9.61e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1763, 4652 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 14 of 21 506 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-184 PCB-188 PCB-179 8.43e8 8.35e8 9.36e8 36.30 35.83 35.55 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.64e3 PCB-186 8.18e8 36.99 Abs. Int. 2.32e8 PCB-178 6.30e8 38.12 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 PCB-179 7.54e8 8.64e8 35.83 35.55 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.12e3 37.0 PCB-176 8.33e8 36.59 PCB-186 7.49e8 36.99 38.0 1.16e8 0.00e0 RT Abs. Int. 2.17e8 PCB-178 5.80e8 38.12 1.09e8 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.60e7 35.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.14e6 CS/SS-178 2.33e7 38.10 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 7.77e3 4.57e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.28e7 35.53 Rel. Int. 100% Abs. Int. 8.50e6 CS/SS-178 2.09e7 38.10 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 8.62e3 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 4.25e6 0.00e0 RT Abs. Int. 1.96e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2899, 3493 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 15 of 21 507 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 3.40e4 PCB-183 1.04e9 39.42 PCB-182 PCB-185 1.05e9 1.03e9 39.08 39.51 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 171/173 1.76e9 PCB-181 40.53 PCB-177 1.00e9 8.47e8 40.34 39.99 180/193 2.25e9 42.40 PCB-172 8.89e8 41.88 PCB-191 1.23e9 42.73 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-170 8.50e8 43.51 Abs. Int. 4.06e8 PCB-190 1.25e9 43.96 2.03e8 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 3.24e4 PCB-182 9.93e8 39.08 PCB-187 9.76e8 38.90 40.0 41.0 PCB-185 9.75e8 171/173 39.51 1.66e9 PCB-183 PCB-181 40.53 9.87e8 PCB-174 PCB-177 9.47e8 39.428.30e8 40.34 8.03e8 39.62 39.99 42.0 43.0 180/193 2.13e9 42.40 PCB-172 8.40e8 41.88 PCB-191 1.16e9 42.73 44.0 PCB-170 8.08e8 43.51 45.0 Abs. Int. 3.84e8 PCB-190 1.19e9 43.96 1.92e8 0% 39.0 40.0 41.0 42.0 43.0 ES-180 4.34e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 1.07e7 ES-170 3.49e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 4.84e3 0.00e0 RT 5.36e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.98e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 9.63e6 ES-170 3.21e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 5.08e3 0.00e0 RT 4.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2041, 8697 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 16 of 21 508 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-189 1.29e9 46.12 Abs. Int. 3.12e8 (1.29e9 + 1.23e9) * 100 pg/uL RRF(PCB-189) = = 1.16 (5.47e7 + 5.39e7) * 2000 pg/uL LKB 03-Jan-2014 15:14 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.63e4 1.56e8 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.23e9 46.12 Abs. Int. 3.06e8 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 1.40e4 1.53e8 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 5.47e7 46.11 0.00e0 RT Abs. Int. 1.27e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 4.44e3 6.36e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 5.39e7 46.11 0.00e0 RT Abs. Int. 1.27e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.76e3 6.37e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2216, 7571 scc: 807-075 PKD: 30-Dec-2013 12:54 Printed: 03-Jan-2014 17:13 Page 17 of 21 509 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-202 7.56e8 40.10 Rel. Int. 100% PCB-201 8.55e8 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.48e4 PCB-197 8.62e8 PCB-204 41.66 PCB-200 8.05e8 7.97e8 41.75 41.47 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 198/199 1.17e9 44.07 Abs. Int. 2.15e8 PCB-196 5.92e8 44.65 PCB-203 6.25e8 44.82 1.08e8 0% 39.0 Rel. Int. 100% 40.0 PCB-202 8.24e8 40.10 41.0 PCB-201 9.27e8 40.89 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.08e4 42.0 43.0 44.0 45.0 198/199 1.28e9 44.07 PCB-197 9.38e8 PCB-204 41.66 PCB-200 8.78e8 8.63e8 41.75 41.47 0.00e0 RT Abs. Int. 2.36e8 PCB-196 6.50e8 44.65 PCB-203 6.78e8 44.82 1.18e8 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.48e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.29e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 3.12e3 4.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.68e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.97e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 3.99e3 4.48e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0215, 8218 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 18 of 21 510 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.20e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-205 9.28e8 48.29 PCB-195 6.71e8 45.95 Abs. Int. 2.26e8 PCB-194 7.24e8 47.89 1.13e8 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.62e4 47.0 48.0 49.0 50.0 PCB-205 1.00e9 48.29 PCB-195 7.29e8 45.94 0.00e0 RT Abs. Int. 2.44e8 PCB-194 7.81e8 47.89 1.22e8 0% 46.0 47.0 48.0 49.0 50.0 ES-205 4.04e7 48.27 Rel. Int. 100% Abs. Int. 9.47e6 JS-194 3.26e7 47.87 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.58e3 0.00e0 RT 4.73e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 4.53e7 48.27 Rel. Int. 100% Abs. Int. 1.07e7 JS-194 3.62e7 47.87 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.24e3 0.00e0 RT 5.36e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5003, 9428 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 19 of 21 511 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.01e4 PCB-208 8.58e8 45.74 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-207 8.96e8 46.53 Abs. Int. 2.14e8 PCB-206 5.80e8 49.77 1.07e8 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 9.96e3 PCB-208 1.09e9 45.74 47.0 48.0 49.0 50.0 PCB-207 1.14e9 46.53 Abs. Int. 2.72e8 PCB-206 7.39e8 49.77 1.36e8 0% 46.0 Rel. Int. 100% ES-208 3.65e7 45.72 47.0 48.0 49.0 (2.51e7 + 3.11e7) * 100 pg/uL RRF(ES-206) = = 0.817 (3.26e7 + 3.62e7) * 100 pg/uL LKB 03-Jan-2014 15:15 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.91e3 50.0 0.00e0 RT Abs. Int. 8.88e6 ES-206 2.51e7 49.75 4.44e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 4.54e7 45.72 50.0 Abs. Int. 1.10e7 ES-206 3.11e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 3.68e3 0.00e0 RT 5.50e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9164, 3773 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 20 of 21 512 of 622 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-209 9.25e8 51.24 Rel. Int. 100% Abs. Int. 1.91e8 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.67e2 9.53e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 7.84e8 51.24 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.62e8 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 7.64e2 8.12e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 4.05e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 8.58e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 9.63e2 4.29e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.38e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.95e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 9.42e2 3.48e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.37e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.68e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2549, 9998 scc: 807-075 PKD: 30-Dec-2013 12:54 Printed: 03-Jan-2014 17:13 Page 21 of 21 513 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.22e7 2.61e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.72e7 1.36e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 2.01e7 1.00e7 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.04e7 1.02e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.13e7 5.65e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.41e6 2.71e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.01e6 2.51e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 307-094 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:20 Page 1 of 21 514 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.16e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 3.94e3 1.58e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.54e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 4.69e3 7.70e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.27e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.36e3 6.37e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.24e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.44e4 1.62e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7343, 4554 scc: 307-094 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 2 of 21 515 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.28e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 5.78e3 6.40e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.33e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.40e4 2.67e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.06e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 1.15e4 1.53e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.13e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.54e3 4.07e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5268, 6714 scc: 307-094 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:20 Page 3 of 21 516 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 4.54e4 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PB 4σ 1.00e4 2.27e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PB 4σ 3.46e4 5.29e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PB 4σ 2.39e4 6.65e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.80e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 5.74e3 8.99e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7794, 8414 scc: 307-094 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 4 of 21 517 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.24e4 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PB 4σ 3.92e3 1.62e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.45e4 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PB 4σ 3.55e3 7.26e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e7 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PB 4σ 8.60e4 8.24e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e6 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 3.76e4 9.38e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9784, 2296 scc: 307-094 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 5 of 21 518 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-36 2.93e5 25.14 Abs. Int. 7.96e4 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.38e3 3.98e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-36 2.95e5 25.14 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.83e4 TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.71e3 4.42e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.09e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PB 4σ 1.03e5 3.54e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.88e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PB 4σ 2.46e4 4.44e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3148, 7222 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 6 of 21 519 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.93e3 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.09e3 1.96e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.96e3 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 2.52e3 2.48e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.40e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.94e4 1.70e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.28e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 1.07e4 1.14e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0991, 8988 scc: 307-094 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:20 Page 7 of 21 520 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.17e4 TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PB 4σ 2.25e3 5.84e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.15e4 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PB 4σ 2.67e3 5.76e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.91e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 2.82e4 2.96e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.07e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.92e4 1.53e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7948, 8617 scc: 307-094 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 8 of 21 521 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-79 2.26e5 31.75 PCB-72 2.07e5 27.52 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 6.17e4 PCB-78 1.97e5 32.24 TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.66e3 3.08e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 2.56e5 27.52 32.0 PCB-79 2.68e5 31.75 TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 3.32e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.90e4 PCB-78 2.72e5 32.24 3.95e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e5 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.37e4 5.49e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.25e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 2.33e4 2.12e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7736, 9764 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 9 of 21 522 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-96 1.05e5 26.00 Rel. Int. 100% Abs. Int. 3.40e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.14e3 1.70e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 1.64e5 26.00 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e4 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.87e3 2.36e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.13e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 1.83e3 4.07e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e4 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 3.05e3 6.03e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0353, 9971 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 10 of 21 523 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 1.10e5 28.67 PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 1.82e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 1.77e5 34.49 PCB-89 1.08e5 29.65 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 4.57e4 PCB-106 1.42e5 34.92 2.29e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 1.77e5 28.66 PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 2.25e3 32.0 34.0 107/124 2.62e5 34.49 PCB-89 1.65e5 29.65 36.0 38.0 0.00e0 RT Abs. Int. 6.64e4 PCB-106 2.46e5 34.92 3.32e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.39e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PB 4σ 2.97e3 4.19e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.10e4 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 3.35e3 1.05e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0422, 7587 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 11 of 21 524 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.14e4 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PB 4σ 1.38e3 5.68e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e4 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PB 4σ 2.07e3 5.82e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e4 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PB 4σ 3.86e3 5.35e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.79e3 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 3.22e3 4.40e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8143, 7330 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 12 of 21 525 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-152 1.98e5 30.81 Rel. Int. 100% Abs. Int. 5.01e4 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.45e3 2.51e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 1.63e5 30.82 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.90e4 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.20e3 2.45e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.02e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.13e3 3.51e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.52e3 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 1.46e3 4.26e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9006, 0485 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 13 of 21 526 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 4.57e4 128/166 1.94e5 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.70e3 2.29e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.57e4 128/166 1.54e5 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.45e3 1.78e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e4 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.35e3 5.83e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e4 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 2.67e3 6.86e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3751, 1283 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 14 of 21 527 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-184 1.12e5 36.29 Rel. Int. 100% Abs. Int. 2.62e4 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.47e2 1.31e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 9.31e4 36.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e4 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.58e2 1.29e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.56e3 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.34e3 3.28e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.66e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.42e3 2.83e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2030, 9921 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 15 of 21 528 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-182 1.14e5 39.07 Abs. Int. 3.24e4 HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.43e3 1.62e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 1.15e5 39.07 0.00e0 RT Abs. Int. 3.09e4 HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.38e3 1.55e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.25e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 2.06e3 3.63e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.88e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.65e3 4.44e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9648, 6911 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 16 of 21 529 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.01e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PB 4σ 1.19e3 5.03e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.51e3 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PB 4σ 1.11e3 4.26e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.79e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.59e3 3.90e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.31e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.83e3 3.16e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7686, 7875 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 17 of 21 530 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-204 9.83e4 41.46 Rel. Int. 100% Abs. Int. 2.26e4 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.80e2 1.13e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 1.07e5 41.46 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.65e4 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 9.64e2 1.33e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.22e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.43e3 2.61e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.84e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.17e3 2.42e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7434, 5203 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 18 of 21 531 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 5.92e3 OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PB 4σ 9.45e2 2.96e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.14e3 OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PB 4σ 1.03e3 3.57e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.89e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 9.26e2 1.95e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.29e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 1.20e3 2.14e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3968, 5793 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 19 of 21 532 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 6.43e3 NoCB 45.52-50.76 461.7245 Fn6 Flags: PB 4σ 8.92e2 3.21e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.70e3 NoCB 45.52-50.76 463.7216 Fn6 Flags: PB 4σ 1.80e3 4.35e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 7.83e2 1.70e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.03e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 9.21e2 1.52e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1314, 4053 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 20 of 21 533 of 622 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 9.53e3 DeCB 50.77-52.00 497.6826 Fn7 Flags: PB 4σ 6.42e2 4.77e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 8.19e3 DeCB 50.77-52.00 499.6797 Fn7 Flags: PB 4σ 5.71e2 4.09e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.38e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 8.45e2 3.69e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.06e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 9.91e2 2.03e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.01e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.51e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2056, 2173 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 21 of 21 534 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.22e7 2.61e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.70e7 1.35e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.95e7 9.77e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.02e7 1.01e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.16e7 5.82e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.65e6 2.82e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.37e6 2.69e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 023-880 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:21 Page 1 of 21 535 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% PCB-2 2.54e5 14.19 PCB-1 9.53e4 12.05 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 5.93e3 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 8.74e4 PCB-3 2.45e5 14.37 4.37e4 0% 11.0 12.0 13.0 Rel. Int. 100% PCB-2 7.20e4 14.19 PCB-1 3.41e4 12.05 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.60e3 14.0 15.0 0.00e0 16.0 RT Abs. Int. 3.18e4 PCB-3 8.20e4 14.37 1.59e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.47e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.84e3 7.33e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.77e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.83e4 1.39e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0471, 6660 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:21 Page 2 of 21 536 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. 100% Abs. Int. 2.84e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: B 4σ 9.07e3 1.42e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.71e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.21e4 2.35e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.27e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 9.85e3 1.63e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.15e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.73e3 4.07e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6955, 1198 scc: 023-880 Revised: 03-Jan-2014 10:42 (LKB) Printed: 03-Jan-2014 15:21 Page 3 of 21 537 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 13/12 7.84e5 20.10 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 7.95e3 Abs. Int. 1.62e5 PCB-15 5.54e5 20.40 8.10e4 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 13/12 4.79e5 20.11 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 3.56e4 21.0 0.00e0 RT Abs. Int. 1.68e5 PCB-15 2.92e5 20.40 8.40e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.47e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PB 4σ 2.95e4 7.34e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 8.05e3 8.91e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1004, 1945 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:21 Page 4 of 21 538 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 30/18 1.02e5 19.51 Rel. Int. 100% PCB-32 9.86e4 20.83 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 5.05e3 Abs. Int. 3.37e4 1.69e4 0% 17.0 18.0 19.0 20.0 30/18 8.90e4 19.51 Rel. Int. 100% 21.0 PCB-32 9.05e4 20.83 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 5.21e3 0.00e0 RT Abs. Int. 2.80e4 1.40e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.62e6 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PB 4σ 7.41e4 1.81e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e5 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 4.02e4 2.37e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7330, 0490 scc: 023-880 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 5 of 21 539 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 6.17e3 PCB-25 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 28/20 1.95e5 4.56e5 22.62 23.19 21/33 PCB-31 26/29 PCB-22 3.54e5 PCB-34 PCB-23 2.70e5 2.18e5 2.16e5 23.37 1.14e5 1.01e5 22.90 22.42 23.75 21.99 22.13 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 2.29e5 PCB-36 8.79e5 25.14 PCB-39 2.73e5 25.46 PCB-38 2.32e5 26.00 PCB-35 3.72e5 26.39 PCB-37 4.64e5 26.75 0% 22.0 23.0 24.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 5.69e3 25.0 26.0 27.0 PCB-34 PCB-23 1.21e5 8.99e4 21.99 22.14 PCB-31 2.22e5 22.90 28/20 4.74e5 23.19 PCB-39 2.84e5 25.46 PCB-22 2.14e5 23.75 PCB-38 2.31e5 25.99 PCB-35 3.67e5 26.39 PCB-37 4.75e5 26.75 0% 22.0 23.0 24.0 25.0 0.00e0 RT Abs. Int. 2.33e5 PCB-36 8.72e5 25.14 26/29 3.42e5 22.42 1.14e5 26.0 27.0 Rel. Int. 100% 1.16e5 0.00e0 RT Abs. Int. 1.82e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: B 4σ 1.01e5 9.12e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.65e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: B 4σ 2.14e4 2.33e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0081, 4527 scc: 023-880 Revised: 03-Jan-2014 10:43 (LKB) Printed: 03-Jan-2014 15:21 Page 6 of 21 540 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. 100% Abs. Int. 1.05e4 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.87e3 5.23e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e4 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 3.46e3 6.85e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.13e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.79e4 2.07e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 1.31e4 1.01e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1788, 2188 scc: 023-880 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 7 of 21 541 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 4.08e3 50/53 8.82e4 22.66 PCB-51 3.01e4 23.35 PCB-45 6.53e4 23.26 PCB-52 5.23e4 24.80 PCB-46 5.27e4 23.53 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 59/62… 2.93e5 44/47… 26.01 69/49 2.20e5 1.62e5 25.73 25.22 PCB-48 PCB-42 7.08e4 PCB-43 6.47e4 25.51 3.75e4 26.16 25.02 71/40 1.63e5 26.60 PCB-41 5.55e4 26.50 Abs. Int. 5.11e4 PCB-64 1.31e5 26.81 2.55e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 44/47… 2.62e5 25.73 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 3.91e3 50/53 1.15e5 22.66 PCB-45 9.74e4 PCB-51 23.26 3.49e4 23.34 PCB-73 PCB-52 8.10e4 8.34e4 24.93 24.81 PCB-46 5.48e4 23.53 69/49 1.69e5 25.23 PCB-48 8.01e4 25.51 59/62… 3.86e5 26.01 PCB-42 9.68e4 26.17 27.0 Abs. Int. 6.43e4 71/40 2.00e5 26.60 PCB-41 8.18e4 26.50 PCB-64 1.45e5 26.81 0% 22.0 23.0 24.0 25.0 26.0 0.00e0 RT 27.0 Rel. Int. 100% 3.22e4 0.00e0 RT Abs. Int. 5.61e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 3.21e4 2.80e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.20e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.50e4 2.10e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9260, 1022 scc: 023-880 Revised: 03-Jan-2014 10:45 (LKB) Printed: 03-Jan-2014 15:21 Page 8 of 21 542 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 4.14e3 PCB-79 6.64e5 31.75 PCB-68 1.40e5 27.78 61/70... 6.48e5 PCB-67 29.04 1.47e5 28.51 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-78 6.28e5 32.25 PCB-81 2.16e5 32.63 PCB-60 2.09e5 PCB-80 30.10 1.57e5 30.42 Abs. Int. 1.64e5 PCB-77 3.03e5 33.11 8.19e4 0% 28.0 30.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 5.02e3 PCB-68 1.72e5 27.78 61/70... 8.54e5 29.04 PCB-58 1.60e5 28.36 32.0 PCB-79 8.37e5 31.75 PCB-60 2.92e5 30.10 PCB-56 2.45e5 29.91 34.0 36.0 38.0 PCB-78 7.88e5 32.25 PCB-81 2.81e5 32.62 PCB-80 2.05e5 30.42 Abs. Int. 2.07e5 PCB-77 3.76e5 33.10 1.03e5 0% 28.0 30.0 32.0 0.00e0 RT 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.26e5 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.26e4 6.29e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 2.39e4 2.68e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9272, 0996 scc: 023-880 Revised: 03-Jan-2014 10:45 (LKB) Printed: 03-Jan-2014 15:21 Page 9 of 21 543 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-96 2.95e5 26.00 Rel. Int. 100% Abs. Int. 7.59e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 2.73e3 3.80e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 4.53e5 26.00 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e5 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 2.97e3 5.85e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.19e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 2.88e3 3.10e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e4 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 2.00e3 5.50e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9067, 8571 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 10 of 21 544 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 3.58e3 PCB-94 2.95e4 27.88 PCB-103 3.75e4 27.70 PCB-98 3.00e5 28.67 PCB-89 2.73e5 29.65 PCB-88 PCB-102 2.92e43.71e4 28.58 28.96 PCB-115PCB-111 116/85 108/119... 1.26e5 8.89e4 7.52e4 3.82e5 32.61 33.12 32.40 31.78 113/90… PCB-110 PCB-117 PCB-120 PCB-112 1.59e5 PCB-82 PCB-92 9.55e4 8.60e4 1.01e5 6.31e4 6.21e4 4.31e4 30.80 32.52 32.31 33.52 31.44 32.80 30.31 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 107/124 5.07e5 34.49 PCB-106 4.17e5 34.92 PCB-123 1.05e5 34.81 Abs. Int. 1.18e5 PCB-114 1.30e5 35.56 PCB-105 1.53e5 36.10 5.89e4 PCB-127 1.03e5 37.33 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 4.75e3 PCB-98 4.78e5 28.67 PCB-94 4.70e4 27.88 100/93 PCB-91 1.17e5 7.93e4 28.48 29.03 PCB-89 4.33e5 29.65 PCB-121 8.53e4 29.99 113/90… 2.82e5 30.80 108/119... 5.90e5 31.78 116/85 2.08e5 32.41 PCB-111 PCB-120 1.40e5 1.62e5 33.12 33.52 36.0 107/124 8.47e5PCB-106 34.49 6.54e5 34.92 PCB-118 2.21e5 35.09 PCB-114 PCB-123 2.15e5 1.84e5 35.56 34.80 38.0 Abs. Int. 2.03e5 PCB-105 2.46e5 36.10 1.01e5 PCB-127 1.72e5 37.33 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.74e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: B 4σ 3.01e3 4.87e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.22e3 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 2.81e3 4.11e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8550, 9289 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 11 of 21 545 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 3.44e4 PCB-126 1.41e5 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 3.09e3 1.72e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.47e4 PCB-126 2.22e5 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 3.11e3 2.73e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e4 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: B 4σ 2.86e3 6.96e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.66e4 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 4.68e3 8.28e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7286, 3128 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 12 of 21 546 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-152 5.29e5 30.82 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 2.53e3 Abs. Int. 1.36e5 PCB-136 7.72e4 31.26 PCB-155 PCB-150 5.62e4 6.03e4 30.95 30.65 147/149 1.25e5 34.10 PCB-145 7.39e4 31.54 PCB-148 4.67e4 32.81 151/135PCB-144 1.23e5 6.19e4 33.33 33.81 139/140 1.26e5 34.63 163/138… 153/168 2.49e5 1.85e5 PCB-130 37.76 36.69 7.31e4 37.18 PCB-133 6.22e4 35.59 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 4.18e5 30.82 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 2.89e3 PCB-155 5.10e4 30.65 30.0 0.00e0 RT Abs. Int. 9.83e4 PCB-136PCB-145 6.77e4 5.42e4 31.26 31.53 PCB-148 3.62e4 32.80 151/135 9.81e4 33.33 147/149 139/140 PCB-154 8.16e4 1.08e5 PCB-132 34.11 34.63 7.32e4 4.19e4 35.18 33.54 PCB-165 6.42e4 35.92 153/168 1.45e5 PCB-130 36.69 5.76e4 37.18 163/138… 2.19e5 37.76 0% 28.0 6.78e4 32.0 34.0 36.0 38.0 Rel. Int. 100% 4.91e4 0.00e0 RT Abs. Int. 7.03e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.12e3 3.52e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e4 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 2.03e3 5.60e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9259, 3315 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 13 of 21 547 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 1.39e5 128/166 6.14e5 38.82 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.34e3 PCB-159 PCB-162 1.16e5 1.26e5 39.87 39.63 156/157 3.32e5 41.27 PCB-167 1.57e5 40.28 PCB-169 2.14e5 43.99 6.96e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.22e5 128/166 4.95e5 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 2.96e3 PCB-159 PCB-162 8.70e4 9.27e4 39.87 39.64 156/157 2.77e5 41.26 PCB-167 1.32e5 40.28 PCB-169 1.69e5 43.99 6.08e4 0% 39.0 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.95e3 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.33e3 4.97e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.04e3 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 3.23e3 4.52e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8276, 7547 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 14 of 21 548 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-184 2.68e5 36.29 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.58e3 PCB-176 4.45e4 36.58 PCB-188 PCB-179 4.57e4 4.46e4 35.54 35.82 Abs. Int. 6.82e4 3.41e4 PCB-186 4.22e4 36.98 PCB-178 2.67e4 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.47e5 36.29 Rel. Int. 100% HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 1.40e3 PCB-188 3.07e4 35.54 PCB-179 4.09e4 35.82 PCB-176 3.65e4 36.58 Abs. Int. 6.26e4 3.13e4 PCB-186 3.84e4 36.98 PCB-178 3.29e4 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 0.00e0 RT 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.97e3 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.36e3 4.99e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.60e3 2.36e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4826, 4197 scc: 023-880 Revised: 03-Jan-2014 10:41 (LKB) Printed: 03-Jan-2014 15:21 Page 15 of 21 549 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 2.77e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Abs. Int. 8.38e4 PCB-182 3.66e5 39.07 PCB-187 6.01e4 38.89 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 180/193 1.45e5 42.40 PCB-181 6.17e4 40.33 PCB-172 PCB-192 7.81e4 6.05e4 42.12 41.88 171/173 9.70e4 40.52 PCB-191 1.03e5 42.73 PCB-170 7.09e4 43.50 PCB-190 1.20e5 43.96 4.19e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 2.37e3 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 9.23e4 PCB-182 3.30e5 39.07 PCB-187 4.62e4 38.89 PCB-181 5.19e4 40.34 171/173 1.09e5 40.52 180/193 1.66e5 42.40 PCB-172 6.22e4 41.87 PCB-191 8.30e4 42.74 PCB-170 7.42e4 43.50 PCB-190 1.10e5 43.96 4.62e4 0% 39.0 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.33e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 2.04e3 3.17e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.17e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.47e3 2.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4824, 0790 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 16 of 21 550 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-189 1.86e5 46.12 Abs. Int. 4.41e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 2.14e3 2.20e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.80e5 46.12 0.00e0 RT Abs. Int. 3.90e4 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 1.55e3 1.95e4 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.95e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.80e3 3.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.98e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.26e3 2.99e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9412, 0969 scc: 023-880 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:21 Page 17 of 21 551 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 7.23e4 PCB-204 2.75e5 41.47 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.73e3 PCB-202 3.27e4 40.09 198/199 8.41e4 44.07 PCB-197PCB-200 5.44e4 4.31e4 41.65 41.74 PCB-201 4.24e4 40.88 PCB-196 3.54e4 44.64 PCB-203 5.07e4 44.81 0% 39.0 40.0 41.0 Rel. Int. 100% 42.0 43.0 44.0 45.0 PCB-202 3.20e4 40.10 PCB-201 4.63e4 40.88 198/199 9.16e4 44.07 PCB-197 5.35e4PCB-200 41.65 3.24e4 41.74 PCB-196 5.46e4 44.65 4.03e4 PCB-203 5.63e4 44.82 0% 39.0 40.0 41.0 0.00e0 RT Abs. Int. 8.06e4 PCB-204 2.97e5 41.46 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.53e3 3.61e4 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.40e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.09e3 2.20e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.81e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.39e3 2.41e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3025, 8975 scc: 023-880 Revised: 03-Jan-2014 11:04 (LKB) Printed: 03-Jan-2014 15:21 Page 18 of 21 552 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.24e3 PCB-205 1.41e5 48.29 PCB-194 1.24e5 47.89 PCB-195 7.30e4 45.94 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 3.02e4 1.51e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.81e3 47.0 48.0 50.0 PCB-205 1.59e5 48.29 PCB-194 1.34e5 47.88 PCB-195 8.40e4 45.94 49.0 0.00e0 RT Abs. Int. 3.19e4 1.60e4 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.72e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 9.24e2 1.86e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.30e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 1.09e3 2.15e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4721, 5462 scc: 023-880 Revised: 03-Jan-2014 10:41 (LKB) Printed: 03-Jan-2014 15:22 Page 19 of 21 553 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.18e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-206 1.29e5 49.76 PCB-207 9.69e4 46.52 Abs. Int. 2.57e4 PCB-208 8.35e4 45.73 1.28e4 0% 46.0 48.0 49.0 50.0 PCB-206 1.73e5 49.76 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 2.42e3 47.0 PCB-208 9.91e4 45.73 Abs. Int. 4.00e4 PCB-207 1.16e5 46.52 2.00e4 0% 46.0 0.00e0 RT 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.41e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 9.48e2 1.20e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.76e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 8.46e2 1.38e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3085, 2852 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:22 Page 20 of 21 554 of 622 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-209 2.67e5 51.24 Rel. Int. 100% Abs. Int. 4.95e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 7.44e2 2.47e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.36e5 51.24 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.55e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.79e2 2.27e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.81e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 8.32e2 1.91e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.08e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 7.81e2 2.54e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.37e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.69e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6138, 0081 scc: 023-880 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 21 of 21 555 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.15e7 2.57e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.57e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.83e7 9.14e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.86e7 9.28e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.12e7 5.60e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.71e6 2.85e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.51e6 2.76e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 979-518 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:22 Page 1 of 21 556 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 3.05e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: B 4σ 4.17e3 1.52e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.64e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: B 4σ 4.11e3 8.18e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.16e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.27e3 5.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.96e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 4.32e4 1.48e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5489, 8194 scc: 979-518 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 2 of 21 557 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.27e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 7.90e3 6.34e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.88e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.37e4 2.44e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.49e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 9.74e3 1.74e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.63e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 4.20e3 3.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7629, 0428 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 3 of 21 558 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 5.56e4 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: B 4σ 8.46e3 2.78e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PB 4σ 3.25e4 5.50e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: B 4σ 2.86e4 6.38e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.63e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 8.50e3 8.13e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8027, 5868 scc: 979-518 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 4 of 21 559 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.85e4 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PB 4σ 4.38e3 9.27e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e4 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PB 4σ 5.38e3 8.02e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.40e6 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: B 4σ 8.60e4 4.70e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e6 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 3.91e4 5.47e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0214, 1156 scc: 979-518 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 5 of 21 560 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-36 7.19e5 25.13 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.14e3 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.86e5 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 9.28e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-36 7.38e5 25.13 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e5 TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.70e3 9.30e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.09e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PB 4σ 9.16e4 2.54e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.78e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PB 4σ 2.79e4 2.89e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5941, 5542 scc: 979-518 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 6 of 21 561 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 6.01e3 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.17e3 3.00e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.11e3 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 2.42e3 3.56e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.72e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.83e4 1.86e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 9.43e3 9.97e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0820, 5379 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 7 of 21 562 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.58e4 TeCB-3 21.52-27.30 289.9224 Fn3 Flags: B 4σ 3.16e3 7.90e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.18e4 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PB 4σ 2.98e3 1.09e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.82e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 2.93e4 2.41e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.23e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.52e4 1.62e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8350, 9425 scc: 979-518 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 8 of 21 563 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 5.47e5 27.52 PCB-79 5.36e5 31.74 TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.89e3 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.43e5 PCB-78 5.18e5 32.24 7.14e4 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 4.42e3 30.0 32.0 PCB-79 7.00e5 31.74 PCB-72 6.98e5 27.51 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.76e5 PCB-78 6.62e5 32.24 8.82e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.97e4 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.92e4 3.99e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.63e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 1.73e4 2.31e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2818, 5309 scc: 979-518 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 9 of 21 564 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-96 2.82e5 25.99 Rel. Int. 100% Abs. Int. 7.28e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 2.12e3 3.64e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 4.29e5 25.99 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e5 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.71e3 5.88e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.59e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 1.81e3 4.29e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.60e3 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 2.46e3 3.80e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8819, 8478 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 10 of 21 565 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 2.64e5 28.66 PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 2.65e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 3.94e5 34.48 PCB-89 2.48e5 29.64 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 8.72e4 PCB-106 3.37e5 34.91 4.36e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 4.27e5 28.66 PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 2.41e3 32.0 34.0 107/124 6.21e5 34.48 PCB-89 4.17e5 29.64 36.0 38.0 0.00e0 RT Abs. Int. 1.58e5 PCB-106 5.67e5 34.91 7.89e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.87e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PB 4σ 2.55e3 3.93e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e4 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 3.22e3 6.44e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9704, 3378 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 11 of 21 566 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.12e4 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PB 4σ 1.59e3 5.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e4 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PB 4σ 2.77e3 1.01e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.73e3 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PB 4σ 2.80e3 4.36e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e4 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 3.82e3 6.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2883, 5187 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 12 of 21 567 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-152 4.83e5 30.81 Rel. Int. 100% Abs. Int. 1.18e5 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.87e3 5.91e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 3.94e5 30.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.51e4 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.90e3 4.75e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.12e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.86e3 4.06e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e3 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 1.70e3 4.24e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0506, 2521 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 13 of 21 568 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.20e5 128/166 4.76e5 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 2.12e3 6.00e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.02e5 128/166 3.90e5 38.81 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 2.33e3 5.11e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.60e3 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.45e3 4.80e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.66e4 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 3.23e3 8.31e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2148, 6219 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 14 of 21 569 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-184 2.50e5 36.28 Rel. Int. 100% Abs. Int. 6.09e4 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.13e3 3.04e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.25e5 36.28 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.52e4 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.66e2 2.76e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e4 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.64e3 7.92e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.24e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.38e3 2.12e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4369, 5758 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 15 of 21 570 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-182 3.17e5 39.06 Abs. Int. 7.81e4 HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.82e3 3.90e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 2.99e5 39.06 0.00e0 RT Abs. Int. 7.31e4 HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.86e3 3.66e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.19e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 1.88e3 4.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.22e3 4.24e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1213, 4954 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 16 of 21 571 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 9.62e3 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PB 4σ 1.27e3 4.81e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.53e3 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PB 4σ 1.44e3 3.76e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.39e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.56e3 2.69e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.29e3 2.36e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7659, 9371 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 17 of 21 572 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-204 2.39e5 41.45 Rel. Int. 100% Abs. Int. 6.07e4 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.15e3 3.04e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 2.84e5 41.45 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.24e4 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.08e3 3.62e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.33e3 2.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.83e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.25e3 2.92e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8871, 8933 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 18 of 21 573 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 5.29e3 OcCB-6 45.52-50.76 427.7635 Fn6 Flags: B 4σ 1.16e3 2.65e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.96e3 OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PB 4σ 1.12e3 2.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.04e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 7.05e2 1.52e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 8.79e2 1.29e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4309, 5142 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 19 of 21 574 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 4.42e3 NoCB 45.52-50.76 461.7245 Fn6 Flags: PB 4σ 1.08e3 2.21e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.67e3 NoCB 45.52-50.76 463.7216 Fn6 Flags: PB 4σ 1.77e3 2.84e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.46e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 8.65e2 1.73e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.81e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 7.98e2 1.40e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8411, 8296 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 20 of 21 575 of 622 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 4.94e3 DeCB 50.77-52.00 497.6826 Fn7 Flags: PB 4σ 4.11e2 2.47e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.97e3 DeCB 50.77-52.00 499.6797 Fn7 Flags: PB 4σ 6.24e2 2.48e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.05e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 5.08e2 1.02e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.19e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 9.76e2 1.09e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.51e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.76e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9640, 2741 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 21 of 21 Experiment Calibration Report 576 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 1 @ 200 (ppm) Printed: Friday, December 20, 2013 14:51:56 Eastern Standard Time M 180.9888 R 11467 M 192.9888 R 9920 242.8 M 204.9888 R 12316 180.9 1.00e0 x16 1.200 M 218.9856 R 11902 192.9 1.00e0 x16 204.9 1.00e0 x16 x16 0.425 0.065 0.100 1.00e0 0.400 0.060 1.100 0.375 0.090 0.055 1.000 0.080 0.350 0.325 0.050 0.900 0.070 0.300 0.045 0.800 0.275 0.040 0.060 0.700 0.250 0.035 0.600 0.225 0.050 0.200 0.030 0.500 0.175 0.040 0.025 0.150 0.400 0.030 0.300 0.020 0.125 0.015 0.100 0.020 0.075 0.200 0.010 0.050 0.010 0.100 -0.000 0.005 -0.000 180.87 180.88 180.89 180.90 192.86 M 230.9856 R 11523 192.87 192.88 192.89 230.8 x16 1.00e0 x16 0.600 0.170 0.550 0.160 0.150 0.500 0.140 0.450 0.130 0.120 0.400 0.110 0.350 0.100 0.090 0.300 0.080 0.250 0.070 0.060 0.200 0.050 0.150 0.040 0.030 0.100 0.020 0.050 0.010 -0.000 -0.000 230.82 230.83 230.84 230.85 242.80 242.81 242.82 242.83 242.84 -0.000 204.85 M 242.9856 R 11311 218.8 1.00e0 0.025 -0.000 204.86 204.87 204.88 218.83 218.84 218.85 218.86 Experiment Calibration Report 577 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 2 @ 200 (ppm) Printed: Friday, December 20, 2013 14:52:25 Eastern Standard Time M 218.9856 R 11415 M 230.9856 R 11111 304.8 M 242.9856 R 10549 218.9 1.00e0 x16 0.400 M 254.9856 R 10639 230.9 1.00e0 x16 242.9 1.00e0 x16 0.600 1.00e0 x16 0.110 0.200 0.375 0.550 0.100 0.350 0.180 0.500 0.325 0.090 0.300 0.450 0.160 0.400 0.140 0.080 0.275 0.250 0.070 0.350 0.225 0.120 0.060 0.200 0.300 0.100 0.050 0.175 0.250 0.080 0.150 0.040 0.200 0.125 0.060 0.100 0.030 0.150 0.075 0.040 0.020 0.100 0.050 0.050 0.025 -0.000 -0.000 218.86 218.87 218.88 218.89 230.85 M 268.9824 R 10161 230.86 230.87 230.88 0.010 -0.000 -0.000 230.89 M 280.9824 R 10871 254.8 0.020 242.84 242.85 x16 242.87 242.88 M 292.9824 R 10203 268.8 1.00e0 242.86 254.83 254.84 254.85 x16 0.280 254.87 M 304.9824 R 10820 280.8 1.00e0 254.86 292.8 1.00e0 x16 1.00e0 x16 0.120 0.150 0.070 0.260 0.140 0.110 0.065 0.100 0.060 0.240 0.130 0.220 0.120 0.055 0.090 0.110 0.200 0.100 0.180 0.090 0.160 0.070 0.140 0.060 0.050 0.080 0.045 0.040 0.080 0.035 0.070 0.120 0.030 0.050 0.060 0.100 0.025 0.040 0.050 0.080 0.020 0.040 0.030 0.060 0.015 0.030 0.020 0.040 0.020 0.010 0.010 0.020 0.010 -0.000 -0.000 268.81 268.82 268.83 268.84 268.85 0.005 -0.000 280.80 280.81 280.82 280.83 280.84 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 304.78 304.79 304.80 304.81 304.82 304.83 Experiment Calibration Report 578 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 3 @ 200 (ppm) Printed: Friday, December 20, 2013 14:52:57 Eastern Standard Time M 242.9856 R 11208 M 254.9856 R 10868 342.8 M 268.9824 R 10822 242.9 1.00e0 x16 M 280.9824 R 10819 254.9 1.00e0 x16 268.8 1.00e0 x16 1.00e0 x16 0.110 0.200 0.100 0.180 0.090 0.160 0.080 0.160 0.320 0.150 0.300 0.140 0.280 0.130 0.260 0.120 0.240 0.110 0.220 0.100 0.200 0.090 0.180 0.080 0.160 0.070 0.140 0.060 0.120 0.050 0.100 0.040 0.080 0.030 0.060 0.020 0.040 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.010 0.010 -0.000 -0.000 242.85 242.86 242.87 242.88 242.89 254.84 M 292.9824 R 11364 254.85 254.86 254.87 M 304.9824 R 10328 280.8 0.020 -0.000 268.82 254.88 268.83 268.84 x16 0.160 268.86 -0.000 280.81 268.87 M 316.9824 R 10549 292.8 1.00e0 268.85 280.82 280.83 280.84 x16 280.86 M 330.9792 R 9803 304.8 1.00e0 280.85 316.8 1.00e0 x16 1.00e0 x16 0.110 0.100 0.045 0.150 0.100 0.090 0.040 0.140 0.090 0.130 0.080 0.035 0.120 0.080 0.070 0.110 0.030 0.070 0.100 0.060 0.090 0.060 0.025 0.080 0.050 0.070 0.050 0.020 0.040 0.060 0.040 0.015 0.050 0.030 0.030 0.040 0.010 0.020 0.030 0.020 0.020 0.005 0.010 0.010 0.010 -0.000 -0.000 292.80 292.81 292.82 292.83 292.84 292.85 304.79 M 342.9792 R 10375 330.8 1.00e0 x16 0.075 0.070 0.065 0.060 0.055 0.050 0.045 0.040 0.035 0.030 0.025 0.020 0.015 0.010 0.005 -0.000 342.76 342.77 342.78 342.79 342.80 342.81 -0.000 342.82 304.80 304.81 304.82 304.83 304.84 316.78 316.79 316.80 316.81 316.82 316.83 -0.000 330.76 330.77 330.78 330.79 330.80 330.81 330.82 Experiment Calibration Report 579 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 4 @ 200 (ppm) Printed: Friday, December 20, 2013 14:53:27 Eastern Standard Time M 280.9824 R 11901 M 292.9824 R 10771 416.8 M 304.9824 R 11159 280.8 1.00e0 x16 0.320 0.160 0.300 0.150 0.280 0.140 M 316.9824 R 10777 292.8 1.00e0 x16 304.8 1.00e0 x16 0.130 0.240 0.120 0.220 0.110 0.200 0.100 0.180 0.090 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 x16 0.045 0.110 0.040 0.100 0.260 1.00e0 0.120 0.090 0.035 0.080 0.030 0.070 0.025 0.060 0.020 0.050 0.040 0.015 0.030 0.010 0.020 0.005 0.010 0.020 0.010 -0.000 -0.000 280.83 280.84 280.85 280.86 -0.000 280.87 292.82 M 330.9792 R 11627 292.83 292.84 292.85 292.86 304.81 M 342.9792 R 10375 316.8 -0.000 304.82 304.83 x16 0.160 304.85 304.86 M 354.9792 R 10965 330.8 1.00e0 304.84 316.79 316.80 316.81 316.82 x16 x16 1.00e0 x16 0.034 0.032 0.060 0.150 316.85 354.8 1.00e0 0.065 0.120 316.84 M 366.9792 R 10868 342.8 1.00e0 316.83 0.110 0.030 0.140 0.055 0.028 0.100 0.130 0.050 0.120 0.026 0.090 0.024 0.045 0.110 0.080 0.022 0.040 0.100 0.020 0.070 0.090 0.080 0.035 0.018 0.030 0.016 0.060 0.070 0.014 0.050 0.025 0.060 0.012 0.040 0.050 0.040 0.020 0.030 0.030 0.010 0.008 0.015 0.006 0.020 0.010 0.010 0.005 -0.000 -0.000 0.020 0.004 0.010 -0.000 330.78 330.79 330.80 330.81 330.82 330.83 342.77 M 380.9760 R 10685 342.78 342.79 342.80 342.81 342.82 342.83 M 392.9760 R 10869 366.8 0.002 -0.000 354.76 354.77 354.78 x16 354.80 354.81 354.82 M 404.9760 R 10290 380.8 1.00e0 354.79 366.74 366.75 366.76 366.77 x16 366.79 366.80 366.81 M 416.9760 R 11464 392.8 1.00e0 366.78 404.8 1.00e0 x16 1.00e0 x16 0.028 0.065 0.015 0.045 0.026 0.014 0.060 0.024 0.040 0.013 0.055 0.022 0.012 0.035 0.050 0.045 0.030 0.040 0.020 0.011 0.018 0.010 0.016 0.009 0.025 0.035 0.008 0.014 0.030 0.007 0.012 0.020 0.006 0.025 0.010 0.005 0.015 0.020 0.008 0.015 0.006 0.004 0.010 0.003 0.010 0.004 0.002 0.005 0.005 0.002 -0.000 -0.000 380.73 380.74 380.75 380.76 380.77 380.78 380.79 0.001 -0.000 392.72 392.73 392.74 392.75 392.76 392.77 392.78 392.79 404.72 404.73 404.74 404.75 404.76 404.77 404.78 404.79 -0.000 416.71 416.72 416.73 416.74 416.75 416.76 416.77 416.78 416.79 Experiment Calibration Report 580 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 5 @ 200 (ppm) Printed: Friday, December 20, 2013 14:54:02 Eastern Standard Time M 316.9824 R 10870 M 330.9792 R 10775 442.7 M 342.9792 R 10285 316.8 1.00e0 x16 M 354.9792 R 10121 330.8 1.00e0 x16 342.8 1.00e0 x16 0.150 x16 0.065 0.130 0.045 1.00e0 0.140 0.060 0.120 0.130 0.040 0.055 0.110 0.120 0.035 0.100 0.050 0.100 0.090 0.045 0.090 0.080 0.040 0.080 0.070 0.035 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.110 0.030 0.025 0.070 0.020 0.060 0.050 0.015 0.040 0.010 0.030 0.020 0.005 -0.000 -0.000 316.78 316.79 316.80 316.81 316.82 -0.000 316.83 330.76 M 366.9792 R 10872 0.005 0.010 0.010 330.77 330.78 330.79 330.80 330.81 342.75 M 380.9760 R 10122 354.8 -0.000 330.82 342.76 342.77 342.78 x16 342.81 354.74 354.75 354.76 x16 354.77 354.78 354.79 354.80 M 404.9760 R 9840 380.7 1.00e0 0.100 0.040 342.80 M 392.9760 R 10775 366.8 1.00e0 342.79 392.7 1.00e0 x16 1.00e0 x16 0.070 0.045 0.065 0.090 0.035 0.060 0.080 0.040 0.055 0.030 0.035 0.050 0.070 0.045 0.025 0.030 0.060 0.040 0.025 0.050 0.020 0.035 0.030 0.020 0.040 0.015 0.025 0.015 0.030 0.020 0.010 0.015 0.020 0.010 0.010 0.005 0.005 0.010 0.005 -0.000 -0.000 366.73 366.74 366.75 366.76 366.77 366.78 -0.000 366.79 380.71 M 416.9760 R 10964 380.72 380.73 380.74 380.75 380.76 380.77 392.70 M 430.9728 R 10332 404.7 -0.000 392.71 392.72 392.73 x16 392.75 392.76 404.68 M 442.9728 R 10204 416.7 1.00e0 392.74 430.7 1.00e0 x16 0.040 1.00e0 x16 0.030 0.026 0.028 0.024 0.035 0.026 0.022 0.024 0.030 0.020 0.022 0.020 0.018 0.025 0.018 0.016 0.016 0.014 0.020 0.014 0.012 0.012 0.015 0.010 0.010 0.008 0.008 0.010 0.006 0.006 0.004 0.004 0.005 0.002 0.002 -0.000 416.67 416.68 416.69 416.70 416.71 416.72 416.73 416.74 -0.000 430.65 -0.000 430.66 430.67 430.68 430.69 430.70 430.71 430.72 430.73 442.65 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 404.69 404.70 404.71 404.72 404.73 404.74 404.75 Experiment Calibration Report 581 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 6 @ 200 (ppm) Printed: Friday, December 20, 2013 14:55:29 Eastern Standard Time M 380.9760 R 10121 M 392.9760 R 10333 480.6 M 404.9760 R 10730 380.7 1.00e0 x16 M 416.9760 R 10825 392.7 1.00e0 x16 404.7 1.00e0 x16 1.00e0 x16 0.080 0.090 0.075 0.050 0.035 0.070 0.080 0.045 0.065 0.030 0.060 0.070 0.040 0.055 0.025 0.035 0.060 0.050 0.045 0.030 0.050 0.020 0.040 0.025 0.035 0.040 0.030 0.030 0.015 0.020 0.025 0.015 0.010 0.020 0.020 0.015 0.010 0.005 0.010 0.010 0.005 0.005 -0.000 -0.000 380.69 380.70 380.71 380.72 380.73 380.74 380.75 -0.000 380.76 M 430.9728 R 9958 392.68 392.69 392.70 392.71 392.72 392.73 392.74 M 442.9728 R 10204 416.7 -0.000 404.66 404.67 404.68 404.69 404.70 x16 404.72 404.73 416.65 M 454.9728 R 10286 430.7 1.00e0 404.71 416.66 416.67 416.68 x16 416.70 416.71 416.72 M 466.9728 R 10246 442.7 1.00e0 416.69 454.6 1.00e0 x16 1.00e0 x16 0.026 0.050 0.045 0.024 0.050 0.045 0.022 0.040 0.045 0.040 0.020 0.040 0.035 0.018 0.035 0.035 0.030 0.016 0.030 0.030 0.014 0.025 0.025 0.025 0.012 0.020 0.020 0.010 0.020 0.015 0.015 0.015 0.010 0.010 0.008 0.006 0.010 0.004 0.005 0.005 0.005 0.002 -0.000 -0.000 430.63 430.64 430.65 430.66 430.67 430.68 430.69 430.70 430.71 M 480.9696 R 10165 466.6 1.00e0 x16 0.028 0.026 0.024 0.022 0.020 0.018 0.016 0.014 0.012 0.010 0.008 0.006 0.004 0.002 -0.000 480.57 480.58 480.59 480.60 480.61 480.62 480.63 480.64 480.65 480.66 -0.000 442.62 442.63 442.64 442.65 442.66 442.67 442.68 442.69 442.70 -0.000 454.61 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 466.59 466.60 466.61 466.62 466.63 466.64 466.65 466.66 466.67 466.68 Experiment Calibration Report 582 of 622 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 7 @ 200 (ppm) Printed: Friday, December 20, 2013 14:56:11 Eastern Standard Time M 430.9728 R 10591 M 442.9728 R 11468 516.6 M 454.9728 R 10774 430.7 1.00e0 x16 M 466.9728 R 11625 442.7 1.00e0 x16 454.7 1.00e0 x16 0.055 1.00e0 x16 0.032 0.050 0.045 0.030 0.050 0.045 0.028 0.040 0.045 0.026 0.040 0.024 0.035 0.040 0.022 0.035 0.035 0.030 0.020 0.030 0.018 0.030 0.025 0.016 0.025 0.025 0.014 0.020 0.020 0.012 0.020 0.015 0.010 0.015 0.015 0.008 0.010 0.010 0.010 0.006 0.004 0.005 0.005 0.005 0.002 -0.000 -0.000 430.66 430.67 430.68 430.69 430.70 430.71 430.72 430.73 -0.000 442.64 M 480.9696 R 9999 442.65 442.66 442.67 442.68 442.69 442.70 442.71 454.63 M 492.9696 R 11060 466.7 -0.000 442.72 454.64 454.65 454.66 x16 454.68 454.69 454.70 454.71 466.62 M 504.9696 R 10504 480.6 1.00e0 454.67 466.63 466.64 466.65 x16 466.67 466.68 466.69 504.6 1.00e0 x16 0.040 1.00e0 x16 0.020 0.034 0.032 0.032 0.018 0.030 0.035 0.030 0.028 0.028 0.026 0.016 0.030 0.026 0.024 0.014 0.024 0.022 0.022 0.025 0.012 0.020 0.020 0.018 0.018 0.016 0.020 0.010 0.016 0.014 0.008 0.014 0.015 0.012 0.012 0.010 0.010 0.008 0.008 0.006 0.006 0.004 0.004 0.006 0.010 0.004 0.002 0.002 -0.000 -0.000 480.60 480.61 480.62 480.63 480.64 480.65 480.66 480.67 480.68 0.005 0.002 -0.000 492.59 492.60 492.61 492.62 492.63 492.64 492.65 492.66 492.67 -0.000 504.57 504.58 504.59 504.60 504.61 504.62 466.70 M 516.9697 R 11012 492.6 1.00e0 0.034 466.66 504.63 504.64 504.65 504.66 516.56 516.57 516.58 516.59 516.60 516.61 516.62 516.63 516.64 Resolution Check Report Printed: 583 of 622 Page 1 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 180.9888 R 11709 M 192.9888 R 10531 180.9 M 204.9888 R 11823 192.9 1.00e0 x16 M 218.9856 R 12380 204.9 1.00e0 x16 218.9 1.00e0 x16 1.00e0 x16 0.130 0.075 1.300 0.450 0.120 0.070 1.200 0.110 0.065 0.100 0.060 0.400 1.100 0.350 1.000 0.055 0.090 0.900 0.050 0.300 0.080 0.800 0.045 0.070 0.700 0.250 0.040 0.060 0.035 0.050 0.030 0.600 0.200 0.500 0.025 0.040 0.400 0.150 0.020 0.030 0.300 0.100 0.015 0.200 0.020 0.100 0.010 0.010 0.050 -0.000 0.005 -0.000 180.87 180.88 180.89 -0.000 180.90 192.86 M 230.9856 R 11709 192.87 192.88 204.85 M 242.9856 R 11344 230.8 -0.000 192.89 204.86 204.87 x16 218.83 M 218.9856 R 11709 242.8 1.00e0 204.88 218.84 218.85 x16 218.87 M 230.9856 R 11709 218.9 1.00e0 218.86 230.9 1.00e0 x16 1.00e0 x16 0.650 0.200 0.450 0.650 0.600 0.425 0.180 0.550 0.400 0.600 0.375 0.550 0.160 0.500 0.350 0.500 0.450 0.325 0.140 0.450 0.300 0.400 0.275 0.120 0.400 0.250 0.350 0.350 0.100 0.225 0.300 0.300 0.200 0.080 0.250 0.175 0.250 0.150 0.200 0.060 0.200 0.125 0.150 0.150 0.100 0.040 0.075 0.100 0.020 0.050 -0.000 -0.000 0.100 0.050 0.050 0.025 -0.000 230.82 230.83 230.84 230.85 230.86 242.81 M 242.9856 R 11737 242.82 242.83 242.84 242.85 218.86 M 254.9856 R 11378 242.9 -0.000 218.87 218.88 x16 230.85 M 268.9824 R 11848 254.8 1.00e0 218.89 x16 0.110 0.100 230.89 280.8 x16 1.00e0 x16 0.320 0.160 0.200 230.88 M 280.9824 R 11210 1.00e0 0.170 0.220 230.87 268.8 1.00e0 0.120 0.240 230.86 0.300 0.150 0.280 0.140 0.260 0.130 0.180 0.090 0.160 0.080 0.140 0.070 0.240 0.120 0.220 0.110 0.200 0.100 0.180 0.090 0.120 0.060 0.100 0.050 0.080 0.040 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.060 0.030 0.040 0.020 0.040 0.080 0.030 0.060 0.040 0.020 0.010 0.020 -0.000 -0.000 242.84 242.85 242.86 242.87 242.88 254.83 254.84 254.85 254.86 254.87 0.010 0.020 -0.000 -0.000 268.81 268.82 268.83 268.84 268.85 268.86 280.80 280.81 280.82 280.83 280.84 280.85 Resolution Check Report Printed: 584 of 622 Page 2 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 292.9824 R 11577 M 304.9824 R 11389 292.8 M 242.9856 R 11827 304.8 1.00e0 x16 M 254.9856 R 11793 242.9 1.00e0 x16 254.9 1.00e0 x16 1.00e0 x16 0.090 0.240 0.120 0.085 0.140 0.220 0.080 0.130 0.110 0.075 0.200 0.120 0.100 0.070 0.110 0.180 0.065 0.100 0.060 0.090 0.055 0.090 0.160 0.080 0.140 0.050 0.070 0.080 0.045 0.120 0.070 0.060 0.040 0.060 0.035 0.050 0.030 0.040 0.025 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.030 0.015 0.020 0.010 0.020 0.010 0.010 0.005 -0.000 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 -0.000 304.78 M 268.9824 R 11467 304.79 304.80 304.81 304.82 304.83 M 280.9824 R 11683 268.8 -0.000 242.85 242.86 242.87 x16 242.89 254.84 M 292.9824 R 11337 280.8 1.00e0 242.88 254.85 254.86 x16 254.88 M 304.9824 R 11548 292.8 1.00e0 254.87 304.8 1.00e0 x16 1.00e0 x16 0.360 0.170 0.180 0.110 0.340 0.160 0.320 0.160 0.100 0.150 0.300 0.140 0.280 0.140 0.090 0.130 0.260 0.080 0.120 0.240 0.120 0.110 0.220 0.070 0.100 0.200 0.100 0.080 0.060 0.040 0.020 0.180 0.090 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.010 0.060 0.050 0.040 0.030 0.020 0.010 -0.000 -0.000 268.83 268.84 268.85 268.86 -0.000 268.87 280.82 M 316.9824 R 11605 280.83 280.84 280.85 292.81 M 330.9792 R 11186 316.8 -0.000 280.86 292.82 292.83 x16 292.85 x16 0.110 304.83 304.84 304.85 280.9 x16 1.00e0 x16 0.375 0.085 0.120 304.82 M 280.9824 R 11876 1.00e0 0.090 0.130 0.045 304.81 342.8 1.00e0 0.050 304.80 M 342.9792 R 11340 330.8 1.00e0 0.055 292.84 0.350 0.080 0.325 0.075 0.300 0.070 0.100 0.040 0.065 0.275 0.060 0.250 0.090 0.035 0.080 0.055 0.225 0.050 0.030 0.070 0.200 0.045 0.025 0.175 0.060 0.040 0.050 0.020 0.035 0.150 0.030 0.125 0.040 0.025 0.015 0.030 0.075 0.010 0.015 0.020 0.050 0.010 0.005 -0.000 316.78 0.100 0.020 0.010 -0.000 316.79 316.80 316.81 316.82 316.83 316.84 330.77 330.78 330.79 330.80 330.81 330.82 330.83 0.005 0.025 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 280.83 280.84 280.85 280.86 280.87 280.88 Resolution Check Report Printed: 585 of 622 Page 3 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 292.9824 R 12107 M 304.9824 R 11576 292.8 M 316.9824 R 11932 304.8 1.00e0 x16 M 330.9792 R 11547 316.8 1.00e0 x16 330.8 1.00e0 x16 1.00e0 x16 0.200 0.180 0.055 0.130 0.170 0.180 0.120 0.050 0.160 0.150 0.110 0.160 0.045 0.140 0.100 0.140 0.130 0.040 0.090 0.120 0.035 0.120 0.110 0.080 0.100 0.070 0.030 0.060 0.025 0.100 0.090 0.080 0.080 0.070 0.050 0.020 0.060 0.060 0.040 0.050 0.015 0.030 0.040 0.040 0.010 0.030 0.020 0.020 0.020 0.005 0.010 -0.000 0.010 -0.000 292.82 292.83 292.84 292.85 292.86 -0.000 292.87 304.81 M 342.9792 R 11458 304.82 304.83 304.84 304.85 316.80 M 354.9792 R 11569 342.8 -0.000 304.86 316.81 316.82 316.83 x16 316.85 330.78 M 366.9792 R 12588 354.8 1.00e0 316.84 330.79 330.80 330.81 x16 330.83 330.84 M 380.9760 R 11628 366.8 1.00e0 330.82 380.8 1.00e0 x16 1.00e0 x16 0.080 0.075 0.130 0.075 0.070 0.040 0.120 0.070 0.065 0.110 0.065 0.035 0.060 0.060 0.100 0.055 0.055 0.030 0.090 0.050 0.050 0.080 0.045 0.025 0.045 0.040 0.070 0.040 0.035 0.060 0.020 0.035 0.030 0.030 0.050 0.015 0.025 0.025 0.040 0.020 0.020 0.010 0.030 0.015 0.020 0.015 0.010 0.010 0.005 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 342.83 0.005 -0.000 354.76 M 392.9760 R 11554 0.010 0.005 354.77 354.78 354.79 354.80 354.81 354.82 366.75 M 404.9760 R 11821 392.8 -0.000 366.76 366.77 x16 366.79 366.80 366.81 380.74 M 416.9760 R 11574 404.8 1.00e0 0.065 366.78 380.75 380.76 x16 380.78 380.79 380.80 M 316.9824 R 11467 416.8 1.00e0 0.040 380.77 316.8 1.00e0 x16 1.00e0 x16 0.060 0.020 0.060 0.055 0.018 0.035 0.055 0.050 0.016 0.050 0.030 0.045 0.045 0.014 0.040 0.025 0.040 0.012 0.035 0.010 0.030 0.035 0.020 0.030 0.025 0.008 0.025 0.015 0.020 0.020 0.006 0.010 0.015 0.015 0.004 0.010 0.010 0.005 0.002 0.005 0.005 -0.000 -0.000 392.73 392.74 392.75 392.76 392.77 392.78 392.79 392.80 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 -0.000 416.72 -0.000 416.73 416.74 416.75 416.76 416.77 416.78 416.79 416.80 316.78 316.79 316.80 316.81 316.82 316.83 316.84 Resolution Check Report Printed: 586 of 622 Page 4 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 330.9792 R 12118 M 342.9792 R 11633 330.8 M 354.9792 R 11643 342.8 1.00e0 x16 M 366.9792 R 11396 354.8 1.00e0 x16 366.8 1.00e0 x16 1.00e0 x16 0.075 0.170 0.150 0.045 0.070 0.160 0.140 0.065 0.150 0.040 0.130 0.140 0.060 0.120 0.130 0.035 0.055 0.110 0.120 0.050 0.100 0.110 0.100 0.090 0.090 0.080 0.080 0.070 0.030 0.045 0.025 0.040 0.035 0.020 0.070 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.060 0.050 0.015 0.040 0.010 0.030 0.020 0.005 0.005 0.010 0.010 -0.000 -0.000 330.77 330.78 330.79 330.80 330.81 -0.000 330.82 342.76 M 380.9760 R 11086 342.77 342.78 342.79 342.80 342.81 M 392.9760 R 10917 380.7 -0.000 354.74 354.75 354.76 354.77 x16 354.79 354.80 366.73 M 404.9760 R 11685 392.7 1.00e0 354.78 x16 0.080 366.76 366.77 366.78 366.79 366.80 M 416.9760 R 11737 416.7 1.00e0 x16 1.00e0 x16 0.032 0.055 0.030 0.075 0.050 0.028 0.070 0.090 0.026 0.045 0.065 0.080 366.75 404.7 1.00e0 0.110 0.100 366.74 0.024 0.060 0.040 0.022 0.055 0.070 0.035 0.050 0.060 0.020 0.018 0.045 0.030 0.016 0.040 0.050 0.025 0.035 0.040 0.030 0.014 0.012 0.020 0.010 0.025 0.030 0.015 0.008 0.020 0.020 0.015 0.006 0.010 0.004 0.010 0.010 0.005 0.005 -0.000 380.72 380.73 380.74 380.75 380.76 380.77 0.002 -0.000 392.70 380.78 M 430.9728 R 11418 -0.000 392.71 392.72 392.73 392.74 392.75 392.76 392.77 404.69 M 442.9728 R 11628 430.7 -0.000 404.70 404.71 404.72 x16 404.74 404.75 404.76 416.68 M 380.9760 R 11522 442.7 1.00e0 404.73 416.69 416.70 416.71 x16 416.73 416.74 416.75 M 392.9760 R 11852 380.7 1.00e0 0.045 416.72 392.7 1.00e0 x16 1.00e0 x16 0.110 0.090 0.100 0.040 0.035 0.090 0.080 0.080 0.070 0.035 0.030 0.030 0.070 0.025 0.060 0.025 0.060 0.050 0.020 0.050 0.020 0.040 0.015 0.040 0.015 0.030 0.030 0.010 0.010 0.020 0.020 0.005 0.005 0.010 0.010 -0.000 430.66 -0.000 430.67 430.68 430.69 430.70 430.71 430.72 430.73 430.74 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 -0.000 380.70 380.71 380.72 380.73 380.74 380.75 380.76 380.77 392.69 392.70 392.71 392.72 392.73 392.74 392.75 392.76 Resolution Check Report Printed: 587 of 622 Page 5 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 404.9760 R 11798 M 416.9760 R 11962 404.7 M 430.9728 R 11403 416.7 1.00e0 x16 M 442.9728 R 12348 430.7 1.00e0 x16 0.065 442.7 1.00e0 x16 0.040 0.060 0.055 0.035 1.00e0 x16 0.055 0.060 0.055 0.050 0.050 0.045 0.045 0.040 0.050 0.030 0.045 0.040 0.035 0.040 0.035 0.025 0.030 0.035 0.030 0.030 0.020 0.025 0.025 0.025 0.020 0.015 0.020 0.020 0.015 0.015 0.015 0.010 0.010 0.010 0.010 0.005 0.005 0.005 0.005 -0.000 404.68 404.69 404.70 404.71 404.72 404.73 404.74 -0.000 416.66 404.75 M 454.9728 R 11665 -0.000 416.67 416.68 416.69 416.70 416.71 416.72 416.73 430.65 M 466.9728 R 11529 454.7 -0.000 416.74 430.66 430.67 430.68 x16 430.70 430.71 430.72 442.64 M 480.9696 R 11402 466.7 1.00e0 0.060 430.69 442.65 442.66 442.67 x16 442.69 442.70 442.71 M 430.9728 R 11904 480.6 1.00e0 442.68 430.7 1.00e0 x16 1.00e0 x16 0.036 0.032 0.070 0.034 0.030 0.055 0.032 0.065 0.030 0.060 0.028 0.050 0.026 0.028 0.045 0.024 0.040 0.055 0.026 0.050 0.022 0.024 0.020 0.022 0.045 0.018 0.020 0.040 0.016 0.018 0.035 0.030 0.025 0.035 0.016 0.014 0.030 0.014 0.012 0.025 0.012 0.020 0.010 0.010 0.015 0.020 0.008 0.008 0.006 0.010 0.015 0.006 0.010 0.004 0.004 0.005 -0.000 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 0.002 0.002 -0.000 -0.000 454.70 466.61 M 442.9728 R 12063 466.62 466.63 466.64 466.65 466.66 466.67 466.68 466.69 480.59 M 454.9728 R 11740 442.7 0.005 -0.000 480.60 480.61 480.62 480.63 x16 480.65 480.66 480.67 480.68 M 466.9728 R 11628 454.7 1.00e0 480.64 430.67 430.68 430.69 430.70 x16 430.72 430.73 430.74 430.75 M 480.9696 R 12053 466.7 1.00e0 430.71 480.7 1.00e0 x16 1.00e0 x16 0.060 0.055 0.055 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.050 0.050 0.045 0.045 0.040 0.040 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 -0.000 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 0.005 0.005 -0.000 -0.000 480.61 466.63 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 480.62 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 Resolution Check Report Printed: 588 of 622 Page 6 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 492.9696 R 11688 M 504.9696 R 11467 492.6 M 516.9697 R 12194 504.6 1.00e0 x16 516.6 1.00e0 x16 0.045 1.00e0 x16 0.024 0.040 0.022 0.040 0.020 0.035 0.035 0.018 0.030 0.030 0.016 0.014 0.025 0.025 0.012 0.020 0.020 0.010 0.015 0.015 0.010 0.010 0.005 0.005 0.008 0.006 0.004 0.002 -0.000 -0.000 492.60 492.61 492.62 492.63 492.64 492.65 492.66 492.67 492.68 492.69 -0.000 504.59 504.60 504.61 504.62 504.63 504.64 504.65 504.66 504.67 504.68 516.58 516.59 516.60 516.61 516.62 516.63 516.64 516.65 516.66 516.67 Resolution Check Report Printed: 589 of 622 Page 1 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 180.9888 R 11682 M 192.9888 R 9510 180.9 M 204.9888 R 12347 192.9 1.00e0 x16 M 218.9856 R 11961 204.9 1.00e0 x16 218.9 1.00e0 x16 1.300 1.200 0.110 1.100 0.100 1.000 0.090 1.00e0 x16 0.500 0.075 0.070 0.450 0.065 0.400 0.060 0.055 0.900 0.350 0.080 0.050 0.800 0.070 0.300 0.045 0.700 0.040 0.060 0.250 0.600 0.035 0.050 0.200 0.030 0.500 0.040 0.025 0.030 0.020 0.400 0.150 0.300 0.100 0.015 0.020 0.200 0.010 0.050 0.010 0.100 -0.000 0.005 -0.000 180.87 180.88 180.89 -0.000 180.90 192.86 M 230.9856 R 11520 192.87 192.88 204.85 M 242.9856 R 11312 230.8 -0.000 192.89 204.86 204.87 x16 218.83 M 218.9856 R 11315 242.8 1.00e0 204.88 218.84 218.85 x16 230.9 1.00e0 x16 0.450 0.650 218.87 M 230.9856 R 11522 218.9 1.00e0 218.86 1.00e0 x16 0.650 0.425 0.180 0.600 0.400 0.600 0.375 0.160 0.550 0.550 0.350 0.500 0.500 0.325 0.140 0.450 0.300 0.450 0.275 0.120 0.400 0.400 0.250 0.350 0.350 0.100 0.225 0.300 0.080 0.200 0.300 0.175 0.250 0.250 0.150 0.060 0.200 0.200 0.125 0.150 0.150 0.100 0.040 0.075 0.100 0.100 0.020 0.050 -0.000 -0.000 0.050 0.050 0.025 -0.000 230.82 230.83 230.84 230.85 230.86 242.81 M 242.9856 R 11628 242.82 242.83 242.84 242.85 218.86 M 254.9856 R 11961 242.9 -0.000 218.87 218.88 x16 230.85 M 268.9824 R 11118 254.8 1.00e0 218.89 230.86 230.87 M 280.9824 R 11012 268.8 1.00e0 x16 230.88 280.8 1.00e0 x16 0.140 1.00e0 x16 0.320 0.180 0.240 0.300 0.130 0.220 0.280 0.160 0.120 0.260 0.200 0.110 0.140 0.180 0.100 0.160 0.090 0.240 0.220 0.120 0.200 0.080 0.140 0.180 0.100 0.070 0.160 0.120 0.140 0.080 0.060 0.100 0.120 0.050 0.060 0.080 0.100 0.040 0.080 0.060 0.040 0.030 0.060 0.040 0.020 0.040 0.020 0.020 0.010 -0.000 -0.000 242.84 242.85 242.86 242.87 242.88 0.020 -0.000 254.83 254.84 254.85 254.86 254.87 -0.000 268.81 268.82 268.83 268.84 268.85 268.86 280.80 280.81 280.82 280.83 280.84 280.85 Resolution Check Report Printed: 590 of 622 Page 2 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 292.9824 R 11427 M 304.9824 R 11317 292.8 M 242.9856 R 11601 304.8 1.00e0 x16 M 254.9856 R 11717 242.9 1.00e0 x16 254.9 1.00e0 x16 1.00e0 x16 0.120 0.085 0.140 0.220 0.080 0.110 0.130 0.075 0.200 0.100 0.120 0.070 0.180 0.110 0.065 0.100 0.060 0.090 0.160 0.080 0.055 0.090 0.140 0.070 0.050 0.080 0.045 0.070 0.120 0.060 0.040 0.100 0.060 0.035 0.050 0.030 0.050 0.080 0.040 0.025 0.040 0.060 0.030 0.040 0.020 0.020 0.030 0.015 0.020 0.010 0.020 0.010 0.010 0.005 -0.000 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 -0.000 304.78 M 268.9824 R 11601 304.79 304.80 304.81 304.82 242.85 M 280.9824 R 11468 268.8 -0.000 304.83 242.86 242.87 x16 242.89 254.84 M 292.9824 R 11375 280.8 1.00e0 242.88 x16 0.375 0.160 0.150 x16 0.110 0.100 0.140 0.300 1.00e0 0.120 0.180 0.325 254.88 304.8 x16 0.170 0.350 254.87 M 304.9824 R 11295 1.00e0 0.180 0.160 254.86 292.8 1.00e0 0.400 0.200 254.85 0.090 0.130 0.140 0.275 0.080 0.120 0.250 0.110 0.120 0.070 0.225 0.100 0.100 0.200 0.090 0.175 0.080 0.150 0.070 0.060 0.050 0.080 0.040 0.060 0.125 0.060 0.050 0.100 0.030 0.040 0.040 0.075 0.020 0.030 0.050 0.020 0.020 0.010 0.025 -0.000 0.010 -0.000 268.82 268.83 268.84 268.85 268.86 268.87 -0.000 280.81 M 316.9824 R 11720 280.82 280.83 280.84 280.85 280.86 M 330.9792 R 11212 316.8 -0.000 292.80 292.81 292.82 x16 292.84 292.85 304.79 M 342.9792 R 10706 330.8 1.00e0 292.83 304.80 304.81 304.82 x16 0.050 304.84 M 280.9824 R 11548 342.8 1.00e0 0.130 304.83 280.9 1.00e0 x16 1.00e0 0.090 0.360 0.085 0.340 x16 0.120 0.080 0.045 0.110 0.100 0.040 0.090 0.035 0.080 0.030 0.320 0.075 0.300 0.070 0.280 0.065 0.260 0.060 0.240 0.055 0.220 0.050 0.200 0.045 0.180 0.040 0.160 0.035 0.140 0.030 0.120 0.025 0.100 0.020 0.080 0.015 0.060 0.070 0.025 0.060 0.050 0.020 0.040 0.015 0.030 0.010 0.020 0.010 0.005 0.040 0.010 0.005 -0.000 -0.000 316.78 316.79 316.80 316.81 316.82 316.83 0.020 -0.000 330.77 330.78 330.79 330.80 330.81 330.82 -0.000 342.76 342.77 342.78 342.79 342.80 342.81 342.82 280.83 280.84 280.85 280.86 280.87 280.88 Resolution Check Report Printed: 591 of 622 Page 3 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 292.9824 R 11417 M 304.9824 R 11746 292.8 M 316.9824 R 11860 304.8 1.00e0 x16 M 330.9792 R 11399 316.8 1.00e0 x16 330.8 1.00e0 x16 1.00e0 x16 0.140 0.055 0.180 0.130 0.180 0.120 0.050 0.110 0.045 0.160 0.160 0.140 0.100 0.140 0.040 0.090 0.120 0.120 0.035 0.080 0.100 0.030 0.070 0.100 0.025 0.060 0.080 0.080 0.050 0.020 0.060 0.060 0.040 0.015 0.030 0.040 0.040 0.010 0.020 0.020 -0.000 -0.000 292.82 292.83 292.84 292.85 292.86 -0.000 292.87 304.81 M 342.9792 R 11424 0.020 0.005 0.010 304.82 304.83 304.84 304.85 316.80 M 354.9792 R 11788 342.8 -0.000 304.86 316.81 316.82 316.83 x16 316.85 330.78 M 366.9792 R 11879 354.8 1.00e0 316.84 330.79 330.80 x16 330.82 330.83 330.84 M 380.9760 R 11573 366.8 1.00e0 330.81 380.8 1.00e0 x16 1.00e0 x16 0.075 0.140 0.080 0.040 0.070 0.075 0.130 0.065 0.120 0.060 0.110 0.055 0.070 0.035 0.065 0.060 0.030 0.100 0.050 0.090 0.045 0.080 0.040 0.070 0.035 0.060 0.030 0.055 0.050 0.025 0.045 0.040 0.020 0.035 0.030 0.015 0.050 0.025 0.040 0.020 0.025 0.020 0.010 0.030 0.015 0.020 0.010 0.010 0.005 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 342.83 0.015 0.010 -0.000 -0.000 0.005 354.76 M 392.9760 R 11520 0.005 354.77 354.78 354.79 354.80 354.81 354.82 366.75 M 404.9760 R 10823 392.8 366.76 366.77 366.78 x16 0.060 366.80 366.81 380.74 M 416.9760 R 11908 404.8 1.00e0 366.79 380.75 380.76 x16 0.032 0.017 380.79 380.80 316.8 1.00e0 0.018 380.78 M 316.9824 R 11415 416.8 1.00e0 0.034 380.77 x16 1.00e0 x16 0.050 0.016 0.030 0.055 0.015 0.028 0.050 0.040 0.013 0.024 0.045 0.045 0.014 0.026 0.012 0.022 0.035 0.040 0.011 0.020 0.010 0.035 0.030 0.018 0.009 0.030 0.016 0.025 0.008 0.014 0.025 0.007 0.020 0.012 0.006 0.020 0.010 0.015 0.005 0.008 0.015 0.004 0.006 0.003 0.004 0.002 0.002 0.001 0.010 0.010 0.005 0.005 -0.000 -0.000 392.73 392.74 392.75 392.76 392.77 392.78 392.79 392.80 -0.000 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 416.72 416.73 416.74 416.75 416.76 416.77 416.78 416.79 416.80 -0.000 316.78 316.79 316.80 316.81 316.82 316.83 316.84 Resolution Check Report Printed: 592 of 622 Page 4 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 330.9792 R 10964 M 342.9792 R 11765 330.8 M 354.9792 R 11187 342.8 1.00e0 x16 M 366.9792 R 11482 354.8 1.00e0 x16 366.8 1.00e0 x16 1.00e0 x16 0.075 0.150 0.170 0.050 0.160 0.070 0.140 0.150 0.130 0.065 0.120 0.060 0.110 0.055 0.100 0.050 0.090 0.045 0.090 0.080 0.040 0.080 0.070 0.035 0.070 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.140 0.045 0.040 0.130 0.120 0.035 0.110 0.100 0.060 0.030 0.025 0.020 0.050 0.015 0.040 0.010 0.030 0.020 0.005 0.010 0.010 -0.000 0.005 -0.000 330.77 330.78 330.79 330.80 330.81 330.82 342.76 M 380.9760 R 11186 342.77 342.78 342.79 342.80 -0.000 354.74 342.81 M 392.9760 R 11378 380.7 -0.000 354.75 354.76 354.77 x16 354.79 354.80 354.81 M 404.9760 R 11235 392.7 1.00e0 354.78 366.73 366.74 366.75 366.76 x16 366.78 366.79 366.80 M 416.9760 R 11174 404.7 1.00e0 366.77 416.7 1.00e0 x16 1.00e0 x16 0.085 0.110 0.028 0.050 0.080 0.026 0.100 0.075 0.045 0.024 0.070 0.090 0.065 0.022 0.040 0.080 0.060 0.020 0.035 0.055 0.070 0.018 0.050 0.060 0.030 0.016 0.045 0.014 0.025 0.040 0.050 0.012 0.035 0.020 0.040 0.030 0.010 0.025 0.015 0.030 0.008 0.020 0.006 0.020 0.010 0.015 0.004 0.010 0.005 0.010 0.002 0.005 -0.000 -0.000 380.72 380.73 380.74 380.75 380.76 380.77 -0.000 380.78 392.71 M 430.9728 R 11476 392.72 392.73 392.74 392.75 392.76 392.77 404.69 M 442.9728 R 11163 430.7 -0.000 404.70 404.71 404.72 x16 404.74 404.75 404.76 416.68 M 380.9760 R 11287 442.7 1.00e0 404.73 416.69 416.70 416.71 x16 416.73 416.74 416.75 M 392.9760 R 11340 380.7 1.00e0 416.72 392.7 1.00e0 x16 1.00e0 x16 0.036 0.050 0.085 0.034 0.100 0.080 0.032 0.045 0.075 0.090 0.030 0.070 0.040 0.028 0.080 0.065 0.026 0.035 0.060 0.024 0.070 0.055 0.022 0.030 0.050 0.060 0.020 0.045 0.018 0.025 0.050 0.040 0.016 0.020 0.035 0.014 0.040 0.030 0.012 0.015 0.010 0.025 0.030 0.020 0.008 0.010 0.020 0.006 0.015 0.010 0.004 0.005 0.010 0.005 0.002 -0.000 -0.000 430.67 430.68 430.69 430.70 430.71 430.72 430.73 430.74 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 -0.000 380.70 380.71 380.72 380.73 380.74 380.75 380.76 380.77 392.69 392.70 392.71 392.72 392.73 392.74 392.75 392.76 Resolution Check Report Printed: 593 of 622 Page 5 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 404.9760 R 11765 M 416.9760 R 11990 404.7 M 430.9728 R 11174 416.7 1.00e0 x16 M 442.9728 R 11086 430.7 1.00e0 x16 0.060 442.7 1.00e0 x16 1.00e0 x16 0.055 0.060 0.040 0.055 0.050 0.035 0.045 0.055 0.050 0.050 0.045 0.045 0.040 0.030 0.040 0.040 0.035 0.025 0.035 0.035 0.030 0.030 0.030 0.020 0.025 0.025 0.025 0.020 0.015 0.020 0.020 0.015 0.015 0.015 0.010 0.010 0.010 0.010 0.005 0.005 0.005 0.005 -0.000 -0.000 404.68 404.69 404.70 404.71 404.72 404.73 404.74 -0.000 404.75 416.67 M 454.9728 R 11171 416.68 416.69 416.70 416.71 416.72 416.73 416.74 430.65 M 466.9728 R 12194 454.7 430.66 430.67 430.68 x16 430.70 430.71 -0.000 442.63 430.72 M 480.9696 R 11753 466.7 1.00e0 430.69 442.64 442.65 442.66 442.67 x16 442.69 442.70 442.71 M 430.9728 R 11116 480.6 1.00e0 0.028 442.68 430.7 1.00e0 x16 1.00e0 x16 0.036 0.060 0.050 0.034 0.026 0.055 0.032 0.024 0.045 0.030 0.050 0.022 0.028 0.020 0.026 0.040 0.045 0.024 0.035 0.040 0.018 0.022 0.016 0.030 0.035 0.020 0.014 0.018 0.030 0.025 0.016 0.012 0.025 0.014 0.020 0.010 0.012 0.015 0.008 0.010 0.006 0.008 0.020 0.015 0.010 0.006 0.010 0.004 0.004 0.005 0.005 0.002 -0.000 0.002 -0.000 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 454.70 -0.000 466.61 M 442.9728 R 11717 466.62 466.63 466.64 466.65 466.66 466.67 466.68 466.69 M 454.9728 R 11627 442.7 -0.000 480.59 480.60 480.61 480.62 480.63 x16 480.65 480.66 480.67 480.68 M 466.9728 R 12498 454.7 1.00e0 480.64 x16 0.050 0.045 430.69 430.70 430.71 430.72 430.73 430.74 430.75 M 480.9696 R 11221 480.7 1.00e0 x16 0.036 0.050 430.68 466.7 1.00e0 0.055 430.67 1.00e0 x16 0.040 0.034 0.032 0.035 0.030 0.045 0.028 0.040 0.030 0.026 0.040 0.035 0.024 0.035 0.025 0.022 0.030 0.020 0.030 0.018 0.025 0.020 0.016 0.025 0.014 0.020 0.020 0.015 0.012 0.015 0.010 0.015 0.010 0.008 0.010 0.010 0.006 0.005 0.005 -0.000 -0.000 0.005 0.004 0.002 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 -0.000 466.63 -0.000 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 480.62 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 Resolution Check Report Printed: 594 of 622 Page 6 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 492.9696 R 10752 M 504.9696 R 11338 492.7 M 516.9697 R 11848 504.6 1.00e0 x16 516.6 1.00e0 x16 1.00e0 x16 0.040 0.022 0.035 0.020 0.035 0.018 0.030 0.030 0.016 0.025 0.025 0.014 0.012 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 0.010 0.008 0.006 0.004 0.002 -0.000 -0.000 492.61 492.62 492.63 492.64 492.65 492.66 492.67 492.68 492.69 -0.000 504.59 504.60 504.61 504.62 504.63 504.64 504.65 504.66 504.67 504.68 516.58 516.59 516.60 516.61 516.62 516.63 516.64 516.65 516.66 516.67 595 of 622 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140327X02 Analysis Date: Lab ID: OPR1_11899_PCB NATIVE ANALYTES PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-104 22'466'-PeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-155 22'44'66'-HxCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-188 22'34'566'-HpCB PCB-189 233'44'55'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-206 22'33'44'55'6-NoCB PCB-208 22'33'455'66'-NoCB PCB-209 DeCB Processed: 30 Mar 2014 14:24 27-MAR-2014 11:32:47 SPIKE CONC. RECOVERY RANGE (%) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 115 114 94.1 108 95.1 111 95.8 98.5 101 96.1 93.8 97.1 95.4 95.3 107 92.1 97 97 97 92.3 104 94.9 98.1 97.8 98.8 96.2 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 Contract-required recovery limits for OPR as specified in Table 6, Method 1668A. Analyst: LB FORM 8A OK - 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 596 of 622 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140327X02 Analysis Date: Lab ID: OPR1_11899_PCB LABELED STANDARDS ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 FORM 8B 27-MAR-2014 11:32:47 SPIKE CONC. RECOVERY RANGE (%) 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 74.5 78.6 91.7 95.2 90.7 84.2 91.5 94.4 92.9 98.5 93.3 91.1 95.2 92.6 94.7 92.7 92.6 77.5 78.3 75.8 90.1 90.7 109 96.9 101 88 91.5 102 86.4 15 15 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 - 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 100 100 100 86.7 101 119 40 40 40 - 125 125 125 Y Y Y OK CLEANUP STANDARDS CS PCB-28 CS PCB-111 CS PCB-178 Processed: 30 Mar 2014 14:24 Analyst: LB 597 of 622 Lab ID: OPR1_11899_PCB ACQ: 27-Mar-2014 11:32:47 LKB Wt/Vol: 1 µL Client ID: 0_11899_OPR001 UTP: 30-Mar-2014 13:53 LKB J-level: 10 pg/uL Datafile: 140327X02 RPT: 30-Mar-2014 14:23 LB Stds (pg): JS: 100 ES: 100 CS/SS: 100 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.79 32.31 35.78 35.24 34.77 34.49 38.39 40.94 39.95 43.65 45.77 50.83 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES 11.87 14.16 14.41 20.12 17.49 26.45 20.40 32.77 32.30 25.38 35.76 35.22 34.75 34.47 38.37 36.33 30.33 40.92 39.93 43.63 43.14 42.08 35.21 45.75 39.74 47.92 49.38 45.37 50.81 PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services QC C ICAL: MM7_PCB_10292013_20DEC2013 CS3_140327_PCB_XA Split: 1 Checkcode: 756-952-MJJ Method 1668A Pred RRT Actual RRT Diff Secs Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0005 1.0007 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 0 0 +0.2 0 0 0 0 0 0 0 0 0 5.75E+07 5.60E+07 4.39E+07 4.86E+07 4.70E+07 4.76E+07 4.31E+07 7.48E+07 4.18E+07 3.65E+07 3.56E+07 2.13E+07 0.79 0.79 0.62 0.62 0.61 0.62 0.64 1.22 1.21 1.23 1.07 1.17 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 49.3 50.7 46.9 48.6 47.7 47.7 53.3 97 48.5 48.5 52.2 48.1 7.12E+04 7.12E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 6.17E+03 8.65E+03 8.65E+03 8.65E+03 4.58E+03 1.35E+03 0.632 0.707 0.205 0.194 0.186 0.186 0.0828 0.154 0.103 0.121 0.0689 0.036 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7243 0.8639 0.8793 1.2277 1.0674 1.0790 0.8325 1.3372 1.3178 0.8321 1.1724 1.1547 1.1394 1.1302 1.2580 0.9716 0.8111 1.0941 1.0678 1.1667 0.9080 0.8855 0.7410 0.9629 0.8364 1.0084 1.0392 0.9548 1.0694 -0.1 -0.1 -0.2 +0.7 +0.1 +0.5 -0.4 +1.6 +1.6 -0.6 +0.9 +0.8 +0.6 +0.6 +1.2 0 -0.5 +0.5 +0.2 +0.8 -0.3 -0.3 -0.6 0 -0.5 0 0 -0.3 0 1.22E+08 1.17E+08 6.58E+07 1.36E+08 6.30E+07 1.09E+08 6.13E+07 1.01E+08 9.87E+07 5.94E+07 8.41E+07 8.33E+07 8.28E+07 8.24E+07 7.30E+07 5.93E+07 8.35E+07 1.41E+08 7.41E+07 6.70E+07 4.32E+07 5.24E+07 5.81E+07 6.35E+07 5.56E+07 4.53E+07 3.14E+07 4.97E+07 3.97E+07 3.21 3.36 1.60 1.57 1.06 1.11 0.78 0.82 0.80 1.63 1.60 1.59 1.61 1.59 1.58 1.30 1.31 1.27 1.28 1.25 1.07 1.05 1.07 1.04 0.91 0.90 0.78 0.80 1.19 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 74.5 % 78.6 % 91.7 % 95.2 % 90.7 % 84.2 % 91.5 % 94.4 % 92.9 % 98.5 % 93.3 % 91.1 % 95.2 % 92.6 % 94.7 % 92.7 % 92.6 % 77.5 % 78.3 % 75.8 % 90.1 % 90.7 % 109 % 96.9 % 101 % 88 % 91.5 % 102 % 86.4 % 15% 15% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% Page 1 of 5 Printed: 3/30/2014 2:33 PM 598 of 622 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.89 32.79 37.77 0.9339 1.0750 1.0100 0.9338 1.0752 1.0100 -0.1 +0.4 0 1.24E+08 9.27E+07 3.92E+07 1.09 1.59 1.06 1.11 1.03 0.62 103 % 109 % 109 % 40% 40% 40% 125% 125% 125% CS PCB-28 CS PCB-111 CS PCB-178 22.89 32.79 37.77 0.9339 1.0750 1.0100 0.9338 1.0752 1.0100 -0.1 +0.4 0 1.24E+08 9.27E+07 3.92E+07 1.09 1.59 1.06 1.85 1.22 0.58 86.7 % 101 % 119 % 40% 40% 40% 125% 125% 125% JS JS JS JS JS 16.39 24.51 30.50 37.40 47.52 1.37E+08 7.77E+07 7.50E+07 5.67E+07 4.14E+07 1.56 0.81 1.61 1.29 0.91 5.30E+03 5.30E+03 5.30E+03 6.64E+03 6.64E+03 1.36E+04 1.36E+04 1.36E+04 1.36E+04 1.36E+04 1.36E+04 1.36E+04 1.36E+04 1.36E+04 4.50E+03 4.50E+03 4.50E+03 4.50E+03 4.50E+03 4.50E+03 4.50E+03 0.0288 0.0297 0.0352 0.0634 0.0411 0.0982 0.0872 0.0933 0.0925 0.0903 0.0779 0.0902 0.0905 0.0973 0.0566 0.0423 0.049 0.036 0.038 0.0641 0.0341 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB SGS Evironmental Services 11.88 13.99 14.17 14.43 14.61 16.41 16.57 16.80 17.10 17.22 18.78 19.56 19.85 20.14 17.51 19.27 19.67 19.86 20.00 20.10 20.57 C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.1758 1.0011 0.9880 1.0010 1.0011 1.0136 1.0010 1.0112 1.0249 1.0434 1.0507 0.9332 0.9720 0.9866 1.0008 1.0010 1.1016 1.1245 1.1356 1.1434 1.1489 1.1762 0 0 0 0 +0.1 0 +0.1 0 +0.1 +0.1 -0.2 -0.1 0 0 0 +0.2 +0.2 +0.4 +0.5 +0.6 +0.5 Page 2 of 5 NON-EMPC 164 573 1,150 1,910 2,220 2,080 1,220 590 150 6.65E+07 6.90E+07 6.76E+07 3.81E+07 6.18E+07 6.23E+07 7.17E+07 6.73E+07 6.80E+07 6.93E+07 8.23E+07 7.24E+07 1.43E+08 7.46E+07 3.44E+07 9.66E+07 4.19E+07 5.73E+07 5.67E+07 2.95E+07 6.10E+07 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 164 573 1,150 1,910 2,220 2,080 1,220 590 150 3.26 3.24 3.27 1.58 1.59 1.64 1.64 1.65 1.63 1.64 1.64 1.64 1.63 1.62 1.05 1.05 1.04 1.04 1.04 1.05 1.04 0.95 1.20 1.01 1.23 1.90 1.01 1.14 1.06 1.07 1.10 1.27 1.10 1.10 1.02 1.15 1.54 1.32 1.80 1.71 1.01 1.90 DL 0.032 0.0804 0.0745 0.288 0.146 0.0988 0.104 0.0571 0.0985 57.3 49.2 57.1 47 49.4 45.3 46.3 46.5 46.6 46.3 47.5 48.4 95.9 53.8 47.5 99.8 50.3 50.5 52.7 46.3 50.9 Printed: 3/30/2014 2:33 PM 599 of 622 Name Actual RT PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB 21.72 21.88 22.16 22.36 22.64 22.92 23.10 23.48 24.86 25.18 25.71 26.10 26.47 20.42 22.41 22.99 23.07 23.28 24.53 24.66 24.76 24.95 25.23 25.45 25.73 25.89 26.22 26.32 26.52 27.24 27.49 27.87 28.07 28.23 28.45 28.74 29.02 29.17 29.61 29.80 30.12 31.45 31.94 25.40 25.72 27.41 27.60 27.98 SGS Evironmental Services QC C C C C C C C C C Pred RRT Actual RRT Diff Secs Response Ra 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.9176 0.8215 0.8272 0.8379 0.8454 0.8559 0.8667 0.8735 0.8878 0.9400 0.9521 0.9723 0.9871 1.0008 1.0010 0.9143 0.9382 0.9412 0.9498 1.0010 1.0063 1.0102 1.0181 1.0296 1.0384 1.0497 1.0564 1.0700 1.0739 1.0821 0.8433 0.8513 0.8628 0.8690 0.8739 0.8809 0.8899 0.8986 0.9032 0.9167 0.9227 0.9327 0.9737 0.9889 1.0009 1.0134 0.8987 0.9049 0.9175 -0.4 -0.4 -0.5 -0.3 -0.4 -0.4 -0.4 -0.3 -0.1 -0.2 0 0 +0.2 0 -0.3 -0.1 -0.1 -0.1 +0.1 +0.1 +0.1 0 +0.2 0 +0.2 +0.2 +0.3 +0.3 +0.3 -0.5 -0.3 -0.3 -0.5 -0.3 -0.3 -0.5 -0.5 -0.4 -0.4 -0.4 -0.4 0 0 0 0 -0.3 -0.3 -0.2 6.22E+07 6.21E+07 1.27E+08 6.54E+07 6.68E+07 1.26E+08 1.30E+08 6.15E+07 6.91E+07 7.08E+07 6.47E+07 6.27E+07 6.53E+07 3.97E+07 7.60E+07 3.22E+07 3.99E+07 3.10E+07 3.92E+07 5.26E+07 3.16E+07 9.49E+07 3.94E+07 1.25E+08 1.62E+08 3.71E+07 3.11E+07 8.41E+07 5.83E+07 5.72E+07 6.05E+07 5.55E+07 5.79E+07 5.90E+07 6.30E+07 2.29E+08 5.65E+07 5.43E+07 5.44E+07 5.44E+07 6.56E+07 6.51E+07 5.35E+07 4.09E+07 3.59E+07 3.62E+07 3.13E+07 3.42E+07 1.00 1.01 1.00 1.00 1.00 1.00 1.00 1.01 1.01 1.00 1.02 1.01 1.01 0.81 0.79 0.77 0.79 0.79 0.78 0.78 0.79 0.79 0.79 0.79 0.79 0.80 0.78 0.80 0.78 0.79 0.79 0.79 0.79 0.79 0.79 0.79 0.78 0.80 0.78 0.79 0.79 0.78 0.78 0.64 0.64 0.62 0.62 0.62 Page 3 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.28 1.28 1.29 1.28 1.34 1.25 1.29 1.20 1.32 1.36 1.21 1.16 1.08 1.35 0.92 0.80 0.93 0.73 0.89 1.18 0.77 1.10 0.91 0.96 1.25 0.83 0.73 0.93 1.32 1.29 1.37 1.23 1.26 1.31 1.36 1.24 1.17 1.17 1.16 1.18 1.37 1.38 1.11 1.43 1.20 0.95 0.79 0.86 44.9 44.7 90.7 46.9 45.7 92.4 93.1 47 48.2 48 49 49.9 55.7 47.9 83.3 40.8 43.7 42.9 44.5 45.2 41.5 87.6 44.1 131 132 45.2 43.1 91.7 44.8 44.9 44.9 45.7 46.6 45.7 46.9 186 49.1 46.9 47.4 46.9 48.6 47.8 48.8 48 50.5 46.4 47.8 48 1.04E+04 1.04E+04 1.04E+04 1.04E+04 1.04E+04 1.04E+04 1.04E+04 1.04E+04 1.04E+04 1.04E+04 1.04E+04 1.04E+04 1.04E+04 2.17E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 3.03E+03 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 7.12E+04 1.72E+03 1.72E+03 1.83E+04 1.83E+04 1.83E+04 0.0781 0.078 0.0773 0.0776 0.0741 0.0795 0.0774 0.0829 0.0755 0.0734 0.082 0.0862 0.0924 0.0257 0.0364 0.042 0.0364 0.0459 0.0376 0.0285 0.0436 0.0306 0.0371 0.0349 0.027 0.0405 0.0461 0.0362 0.0255 0.613 0.578 0.642 0.627 0.605 0.581 0.635 0.678 0.673 0.68 0.672 0.578 0.573 0.712 0.022 0.0263 0.238 0.283 0.261 Printed: 3/30/2014 2:33 PM 600 of 622 Name Actual RT PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB 28.19 28.31 28.38 28.68 28.74 28.93 29.35 29.69 30.01 30.50 30.93 31.03 31.13 31.48 32.01 32.11 32.22 32.30 32.50 32.81 33.21 34.18 34.38 34.60 35.07 37.01 30.35 30.52 30.66 30.96 31.23 32.50 33.02 33.23 33.50 33.80 33.98 34.06 34.32 34.49 34.64 34.87 35.28 35.62 35.83 35.95 36.38 36.52 SGS Evironmental Services QC C C C C C C C C C Pred RRT Actual RRT Diff Secs Response Ra 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9766 0.9244 0.9282 0.9305 0.9403 0.9424 0.9486 0.9624 0.9736 0.9840 0.9999 1.0143 1.0174 1.0207 1.0321 1.0497 1.0527 1.0563 1.0592 1.0656 1.0759 1.0889 0.9915 0.9975 1.0039 1.0091 1.0351 1.0007 1.0061 1.0108 1.0208 1.0297 1.0716 1.0888 1.0957 1.1044 1.1143 1.1202 1.1229 1.1315 1.1372 1.1420 1.1497 1.1630 0.9524 0.9581 0.9613 0.9728 0.9766 -0.3 0 0 0 0 -0.2 0 0 -0.2 0 +0.2 +0.2 +0.2 +0.2 +0.4 +0.4 +0.4 +0.4 +0.2 +0.4 +0.4 -0.2 -0.2 +0.2 0 +0.2 0 +0.2 +0.2 +0.2 +0.2 +0.4 +0.4 +0.6 +0.6 +0.4 +0.6 +0.8 +0.6 +0.6 +0.8 +0.6 +0.8 -0.2 -0.2 0 0 0 6.78E+07 4.04E+07 2.73E+07 3.23E+07 3.46E+07 2.86E+07 3.09E+07 4.85E+07 3.29E+07 1.17E+08 2.93E+07 3.57E+07 4.62E+07 2.35E+08 4.93E+07 7.03E+07 4.44E+07 4.63E+07 2.84E+07 4.89E+07 4.96E+07 9.00E+07 5.02E+07 4.38E+07 4.19E+07 4.42E+07 4.85E+07 4.56E+07 4.53E+07 4.24E+07 4.31E+07 3.27E+07 6.32E+07 3.69E+07 3.28E+07 6.54E+07 2.70E+07 2.94E+07 6.60E+07 2.79E+07 2.73E+07 2.88E+07 3.06E+07 3.87E+07 3.33E+07 4.26E+07 8.08E+07 3.02E+07 0.62 0.62 0.62 0.61 0.63 0.62 0.62 0.62 0.62 0.62 0.61 0.61 0.62 0.62 0.61 0.62 0.61 0.62 0.63 0.62 0.62 0.62 0.61 0.62 0.63 0.62 1.28 1.27 1.27 1.28 1.27 1.26 1.27 1.28 1.25 1.27 1.26 1.29 1.26 1.27 1.26 1.28 1.25 1.27 1.27 1.28 1.27 1.27 Page 4 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.88 1.04 0.73 0.79 0.91 0.72 0.76 1.22 0.83 0.98 0.71 0.91 1.17 1.00 1.05 0.98 1.12 1.15 0.69 1.20 1.22 1.10 1.24 1.08 1.00 1.09 1.26 1.11 1.12 1.03 1.05 1.12 1.06 1.25 1.10 1.11 0.79 1.10 1.11 0.94 0.93 0.97 1.04 1.31 1.14 1.42 1.39 1.03 94 47.1 45.6 49.5 45.9 47.9 49 48.3 48.4 144 49.8 47.7 47.9 286 57 86.7 48.4 49 49.7 49.2 49.2 99.6 49.1 49.3 50.1 48.4 46.1 49.4 48.4 49.5 49.2 49.1 100 50 50.1 99.8 57.8 45 100 50 49.8 50.1 49.4 49.9 49.3 50.7 98.2 49.2 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.83E+04 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 0.257 0.216 0.31 0.284 0.246 0.312 0.295 0.185 0.273 0.229 0.315 0.248 0.193 0.226 0.214 0.229 0.202 0.197 0.325 0.187 0.184 0.206 0.182 0.209 0.233 0.21 0.0176 0.02 0.0198 0.0216 0.0211 0.026 0.0275 0.0235 0.0265 0.0265 0.0372 0.0265 0.0263 0.0311 0.0316 0.0302 0.028 0.0224 0.0257 0.0206 0.0211 0.0283 Printed: 3/30/2014 2:33 PM 601 of 622 Name Actual RT PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.87 37.06 37.15 37.44 37.58 37.76 38.49 39.31 39.54 35.23 35.51 35.97 36.27 36.67 37.79 38.34 38.57 38.74 39.09 39.17 39.29 39.66 40.01 40.19 41.54 41.79 42.06 42.39 43.16 43.62 39.77 40.55 41.13 41.32 41.41 43.73 44.30 44.47 45.59 47.54 47.94 45.39 46.18 49.40 SGS Evironmental Services QC C C C C C Pred RRT Actual RRT Diff Secs Response Ra 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9640 0.9843 0.9903 1.0006 1.0086 1.0217 1.0300 1.0414 1.0734 1.0889 1.0954 1.1004 1.1102 1.1126 1.1158 1.1264 1.1363 1.1415 0.9079 0.9133 0.9193 0.9265 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0419 1.1003 1.1147 1.1190 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0 0 0 0 0 0 -0.2 -0.2 0 0 0 +0.2 0 +0.2 +0.2 +0.5 +0.5 +0.5 +0.2 +0.2 +0.5 +0.5 +0.5 +0.5 -0.2 -0.3 -0.3 -0.3 0 0 0 0 0 0 +0.2 +0.5 +0.3 +0.5 0 0 0 0 0 0 2.70E+07 3.13E+07 4.27E+07 9.82E+07 3.89E+07 4.41E+07 6.48E+07 3.95E+07 3.93E+07 3.40E+07 3.29E+07 3.05E+07 3.38E+07 3.14E+07 2.25E+07 2.99E+07 3.09E+07 3.15E+07 3.09E+07 2.99E+07 2.57E+07 2.53E+07 2.87E+07 5.06E+07 2.59E+07 3.34E+07 6.60E+07 3.62E+07 2.47E+07 3.53E+07 2.78E+07 3.12E+07 2.93E+07 3.26E+07 2.77E+07 3.97E+07 2.04E+07 2.11E+07 1.79E+07 1.94E+07 2.35E+07 2.76E+07 2.89E+07 1.71E+07 1.27 1.26 1.27 1.27 1.28 1.28 1.20 1.22 1.22 1.07 1.07 1.06 1.07 1.06 1.05 1.06 1.05 1.05 1.03 1.05 1.05 1.06 1.04 1.05 1.06 1.04 1.05 1.06 1.06 1.04 0.92 0.90 0.91 0.90 0.91 0.91 0.90 0.92 0.91 0.91 0.92 0.78 0.78 0.78 Page 5 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.92 1.14 1.38 1.11 1.30 1.50 0.89 1.07 1.06 1.27 1.08 1.03 1.14 1.07 0.76 1.08 1.15 1.19 1.22 1.03 0.98 0.95 1.07 0.95 0.97 1.26 1.24 1.35 1.14 1.56 1.05 1.13 1.06 1.13 1.07 0.72 0.76 0.77 0.80 0.85 1.06 1.12 1.13 1.11 49.6 46.5 52.1 149 50.4 49.7 97.9 49.8 49.8 46.1 52.4 51.1 51.1 50.6 51.2 52.8 51.3 50.4 48.2 55.2 49.8 50.9 51.1 102 50.8 50.5 101 51 50.3 52.5 47.4 49.5 50 51.9 46.4 99.1 48 49.1 49.6 50.2 49 49.4 51.4 48.9 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 1.71E+03 8.65E+03 8.65E+03 8.65E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 1.25E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 8.61E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 3.96E+03 3.96E+03 3.96E+03 4.04E+03 4.04E+03 4.04E+03 0.0318 0.0258 0.0212 0.0263 0.0225 0.0196 0.134 0.112 0.113 0.018 0.0211 0.0223 0.02 0.0214 0.0301 0.156 0.147 0.142 0.138 0.164 0.172 0.179 0.158 0.179 0.174 0.134 0.136 0.125 0.188 0.137 0.0281 0.0261 0.028 0.0261 0.0275 0.041 0.0387 0.0383 0.115 0.107 0.0861 0.0748 0.0741 0.122 Printed: 3/30/2014 2:33 PM 602 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.25e7 2.62e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 1.30e7 6.51e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 1.04e7 5.22e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.16 330.9792 Fn4 Flags: 0% Abs. Int. 1.73e7 8.63e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.17-45.15 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.00e7 5.01e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 2.10e6 1.05e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.93e6 9.67e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 scc: 756-952 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 30-Mar-2014 14:43 Page 1 of 21 603 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 PCB-1 5.09e7 11.88 Rel. Int. 100% Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-2 5.28e7 13.99 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.09e3 Abs. Int. 2.06e7 PCB-3 5.18e7 14.17 1.03e7 0% 11.0 12.0 13.0 PCB-1 1.56e7 11.88 Rel. Int. 100% 14.0 PCB-2 1.63e7 13.99 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.22e3 15.0 0.00e0 16.0 RT Abs. Int. 6.29e6 PCB-3 1.58e7 14.17 3.15e6 0% 11.0 12.0 13.0 ES-1 9.30e7 11.87 Rel. Int. 100% 14.0 15.0 Abs. Int. 3.68e7 ES-3 9.03e7 14.16 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.08e3 0.00e0 16.0 RT 1.84e7 0% 11.0 12.0 13.0 ES-1 2.90e7 11.87 Rel. Int. 100% 14.0 15.0 Abs. Int. 1.16e7 ES-3 2.69e7 14.16 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.18e4 0.00e0 16.0 RT 5.82e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.25e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.62e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7102, 9166 scc: 756-952 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 2 of 21 604 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 Rel. Int. 100% Abs. Int. 1.19e7 PCB-10 3.79e7 14.61 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 4.05e3 PCB-4 2.34e7 14.43 5.93e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 7.57e6 PCB-10 2.39e7 14.60 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 1.32e4 PCB-4 1.48e7 14.43 3.78e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.05e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 1.31e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.03e3 6.54e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.53e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.92e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.02e3 3.96e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.25e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.62e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8716, 1688 scc: 756-952 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 13:56 (LKB) Printed: 30-Mar-2014 14:43 Page 3 of 21 605 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 8.30e3 PCB-9 3.87e7 16.41 PCB-7 4.45e7 PCB-6 16.57 4.19e7 16.80 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 PCB-14 5.11e7 18.78 PCB-5 4.22e7 PCB-8 17.10 4.30e7 17.22 PCB-11 4.50e7 19.56 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 13/12 8.86e7 19.85 Abs. Int. 1.36e7 PCB-15 4.61e7 20.14 6.78e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.72e4 PCB-9 2.36e7 16.40 PCB-7 2.71e7 PCB-6 16.57 2.54e7 16.80 18.0 19.0 13/12 5.44e7 19.85 PCB-14 3.12e7 18.78 PCB-5 2.58e7 PCB-8 17.10 2.63e7 17.22 20.0 21.0 Abs. Int. 8.24e6 PCB-15 2.85e7 20.14 PCB-11 2.74e7 19.56 4.12e6 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 8.37e7 16.39 20.0 21.0 ES-15 8.32e7 20.12 0.00e0 RT Abs. Int. 2.37e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 1.74e4 1.19e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 5.36e7 16.39 20.0 21.0 ES-15 5.28e7 20.12 0.00e0 RT Abs. Int. 1.52e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.91e3 7.61e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.30e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.51e6 0% 17.0 18.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1077, 9931 scc: 756-952 19.0 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 4 of 21 606 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Rel. Int. 100% Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 30/18 4.94e7 19.27 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.60e3 PCB-19 1.76e7 17.51 PCB-17 2.14e7 19.67 PCB-24 2.89e7 20.00 PCB-27 2.92e7 19.86 Abs. Int. 1.25e7 PCB-16 1.51e7 20.10 PCB-32 3.11e7 20.57 6.27e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 4.72e7 19.27 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 1.90e3 PCB-19 1.68e7 17.51 PCB-17 2.05e7 19.67 21.0 PCB-24 2.77e7 20.00 PCB-27 2.81e7 19.86 Abs. Int. 1.19e7 PCB-16 1.44e7 20.10 PCB-32 2.99e7 20.57 5.95e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 3.24e7 17.49 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 8.99e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.43e4 4.49e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 3.06e7 17.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.62e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.82e4 4.31e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.30e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.51e6 0% 17.0 18.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5361, 8007 scc: 756-952 19.0 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 5 of 21 607 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 5.07e3 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 26/29 PCB-23 6.37e7 PCB-34 3.11e7 22.16 3.11e7 21.88 21.72 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 28/20 6.30e7 22.92 PCB-31 3.34e7 22.64 Abs. Int. 1.37e7 PCB-39 3.54e7 25.18 PCB-36 3.48e7 24.86 PCB-22 3.10e7 23.48 PCB-38 3.26e7 25.71 PCB-35 3.15e7 26.10 PCB-37 3.28e7 26.47 0% 22.0 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 5.33e3 26/29 PCB-23 6.34e7 PCB-34 3.09e7 22.16 3.11e7 21.87 21.72 23.0 24.0 25.0 0.00e0 RT 26.0 28/20 6.29e7 22.92 PCB-31 3.34e7 22.63 Abs. Int. 1.35e7 PCB-39 3.54e7 25.18 PCB-36 3.43e7 24.86 PCB-22 3.05e7 23.48 PCB-38 3.21e7 25.71 PCB-35 3.13e7 26.10 PCB-37 3.25e7 26.46 23.0 24.0 25.0 26.0 CS/SS-28 6.49e7 22.89 Rel. Int. 100% 6.76e6 0.00e0 RT 0% 22.0 6.83e6 ES-37 5.71e7 26.45 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.13e4 Abs. Int. 1.58e7 7.89e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 5.95e7 22.89 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 5.16e7 26.45 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.18e4 Abs. Int. 1.43e7 7.15e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.04e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.22e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6735, 9116 scc: 756-952 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 6 of 21 608 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-54 1.77e7 20.42 Rel. Int. 100% Abs. Int. 4.57e6 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 1.15e3 2.29e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.20e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.57e6 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.01e3 2.78e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 2.69e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.84e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 6.03e3 3.42e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.44e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.51e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 4.36e3 4.25e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.30e7 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 6.51e6 0% 17.0 18.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 2937, 6809 scc: 756-952 19.0 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 27-Mar-2014 13:57 (LKB) Printed: 30-Mar-2014 14:43 Page 7 of 21 609 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.39e3 50/53 3.35e7 22.41 PCB-51 1.76e7 23.07 PCB-45 1.40e7 22.99 PCB-73 2.30e7 PCB-52 24.66 1.72e7 24.53 PCB-46 1.37e7 23.28 69/49 4.18e7 24.95 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 59/62… 7.17e7 44/47… 25.73 5.50e7 25.45 PCB-48 1.74e7 25.23 71/40 3.73e7 26.32 PCB-42 1.65e7 25.89 PCB-41 1.36e7 26.22 Abs. Int. 1.28e7 PCB-64 2.56e7 26.52 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.63e3 50/53 4.25e7 22.41 PCB-51 2.23e7 23.07 PCB-45 1.82e7 22.99 PCB-73 2.95e7 PCB-52 24.66 2.20e7 24.53 PCB-46 1.73e7 23.28 69/49 5.31e7 24.95 PCB-48 2.20e7 25.23 59/62… 9.07e7 25.73 71/40 4.68e7 26.32 PCB-42 2.06e7 25.89 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.48e7 24.51 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 6.98e7 25.45 6.41e6 PCB-41 1.74e7 26.22 Abs. Int. 1.63e7 PCB-64 3.27e7 26.52 8.17e6 0.00e0 RT Abs. Int. 8.40e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.31e4 4.20e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.29e7 24.51 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 8.60e3 5.15e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.04e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.22e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 1108, 5436 scc: 756-952 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 8 of 21 610 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 61/70... 1.01e8 28.74 Rel. Int. 100% TeCB-4 26.97-38.16 289.9224 Fn4 Flags: PBM 4σ 4.48e4 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 PCB-57 PCB-63 2.44e7 2.77e7 28.45 27.87 PCB-55 2.41e7 29.17 PCB-60 PCB-80 2.39e7 2.90e7 30.12 29.80 PCB-79 2.86e7 31.45 PCB-78 2.34e7 31.94 PCB-81 2.48e7 32.31 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 Abs. Int. 1.22e7 PCB-77 2.54e7 32.79 6.10e6 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.16 291.9194 Fn4 Flags: PBM 4σ 2.64e4 61/70... 1.28e8 PCB-57 28.74 3.11e7 27.86 PCB-68 PCB-63 3.39e7 3.53e7 PCB-66 3.16e7 27.49 28.45 29.02 30.0 32.0 PCB-60 3.05e7 29.80 PCB-56 3.07e7 29.61 PCB-80 3.67e7 30.12 PCB-79 3.65e7 31.45 PCB-78 3.00e7 31.94 PCB-81 3.12e7 32.31 34.0 36.0 38.0 Abs. Int. 1.53e7 PCB-77 3.21e7 32.79 7.66e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 4.39e7 32.30 TeCB Std. 26.97-38.16 301.9626 Fn4 Flags: PBM 4σ 1.33e4 0.00e0 RT 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.10e7 ES-77 4.56e7 32.77 5.50e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 5.48e7 32.30 TeCB Std. 26.97-38.16 303.9597 Fn4 Flags: PBM 4σ 1.06e4 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.34e7 ES-77 5.58e7 32.77 6.70e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.73e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.63e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0344, 5718 scc: 756-952 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 9 of 21 611 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Rel. Int. 100% Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-104 1.60e7 25.40 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 7.83e2 PCB-96 1.40e7 25.72 Abs. Int. 3.88e6 1.94e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.49e7 25.40 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 9.34e2 PCB-96 2.20e7 25.72 0.00e0 RT Abs. Int. 6.04e6 3.02e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 3.68e7 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.45e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 2.44e3 4.22e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.26e7 25.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.21e3 2.63e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.04e7 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 5.22e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 5876, 7608 scc: 756-952 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 10 of 21 612 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 108/119... 9.00e7 31.48 Rel. Int. 100% PeCB-4 26.97-38.16 323.8834 Fn4 Flags: PBM 4σ 7.14e3 PCB-103 1.38e7 27.41 100/93 2.59e7 28.19 PCB-88 1.22e7 28.68 PCB-121 1.85e7 29.69 113/90… 4.47e7 30.50 116/85 2.68e7 32.11 PCB-99 1.35e7 31.03 PCB-111 1.87e7 PCB-120 1.89e7 32.81 33.21 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 107/124 PCB-118 1.79e7 3.44e7 34.77 34.18 PCB-123 PCB-114 1.81e7 1.87e7 34.49 35.24 Abs. Int. 1.26e7 PCB-105 1.68e7 35.78 PCB-127 1.69e7 37.01 6.32e6 0% 28.0 30.0 32.0 108/119... 1.45e8 31.48 Rel. Int. 100% PeCB-4 26.97-38.16 325.8804 Fn4 Flags: PBM 4σ 1.12e4 34.0 PCB-94 1.93e7 27.60 100/93 4.19e7 28.19 PCB-91 2.13e7 28.74 PCB-89 1.91e7 29.35 113/90… 7.21e7 30.50 PCB-112 PCB-92 2.85e7 2.03e7 31.13 30.01 116/85 PCB-115 4.35e7 2.85e7 PCB-111 32.10 32.30 3.02e7 32.81 PCB-117 PCB-110 PCB-120 3.07e7 2.75e7 3.06e7 PCB-82 32.01 32.22 33.21 1.74e7 32.50 36.0 PCB-118 107/124 2.91e7 5.55e7 34.77 34.18 PCB-123 PCB-114 2.95e7 3.00e7 34.49 35.24 38.0 Abs. Int. 2.04e7 PCB-105 2.71e7 35.78 PCB-127 2.73e7 37.01 1.02e7 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.69e7 32.79 JS-101 4.62e7 30.50 PeCB Std. 26.97-38.16 337.9207 Fn4 Flags: PBM 4σ 2.94e3 34.0 ES-123 5.06e7 34.47 36.0 ES-118 ES-114 5.10e7 5.11e7 34.75 35.22 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.38e7 ES-105 5.18e7 35.76 6.92e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 3.58e7 32.79 JS-101 2.88e7 30.50 PeCB Std. 26.97-38.16 339.9177 Fn4 Flags: PBM 4σ 2.03e3 34.0 36.0 ES-118 ES-114 3.21e7 ES-123 3.18e7 3.18e7 34.75 35.22 34.47 38.0 0.00e0 RT Abs. Int. 8.54e6 ES-105 3.23e7 35.76 4.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.73e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.63e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 4505, 1738 scc: 756-952 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 11 of 21 613 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 Abs. Int. 4.00e6 PCB-126 1.68e7 38.39 PeCB-5 38.17-45.15 323.8834 Fn5 Flags: PBM 4σ 3.26e3 2.00e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.30e6 PCB-126 2.63e7 38.39 PeCB-5 38.17-45.15 325.8804 Fn5 Flags: PBM 4σ 2.91e3 3.15e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.03e7 ES-126 4.47e7 38.37 PeCB Std. 38.17-45.15 337.9207 Fn5 Flags: PBM 4σ 5.71e3 5.15e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.63e6 ES-126 2.83e7 38.37 PeCB Std. 38.17-45.15 339.9177 Fn5 Flags: PBM 4σ 5.29e3 3.31e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.00e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.01e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 9935, 9178 scc: 756-952 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 12 of 21 614 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 PCB-136 2.38e7 30.96 PCB-150 PCB-155 2.54e7 PCB-145 2.72e7 30.66 2.41e7 30.35 31.23 HxCB-4 26.97-38.16 359.8415 Fn4 Flags: PBM 4σ 6.87e2 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 147/149 139/140 3.66e7 3.68e7 33.80 34.32 PCB-148 1.83e7 32.50 151/135 3.53e7 PCB-144 33.02 1.82e7 PCB-134 33.50 1.50e7 33.98 153/168 4.51e7 36.38 PCB-146 PCB-142 PCB-133 1.70e7 1.86e7 1.53e7 35.83 35.28 34.64 PCB-141 1.69e7 36.52 163/138… 5.49e7 37.44 Abs. Int. 1.02e7 PCB-164 2.39e7PCB-160 37.15 2.18e7 37.58 5.12e6 0% 28.0 30.0 PCB-152 2.01e7 30.52 PCB-136 PCB-155 1.86e7 PCB-145 2.13e7 30.96 1.90e7 30.35 31.23 Rel. Int. 100% HxCB-4 26.97-38.16 361.8385 Fn4 Flags: PBM 4σ 1.02e3 32.0 PCB-148 1.44e7 32.50 34.0 36.0 147/149 139/140 151/135 2.88e7 2.93e7 2.78e7 33.80 34.32 33.02 PCB-154 PCB-143 1.62e7 PCB-132 1.28e7 33.23 1.27e7 34.06 34.87 38.0 153/168 3.57e7 36.38 PCB-165 1.70e7 35.62 163/138… 4.33e7 37.44 PCB-141 PCB-137 1.33e7 1.39e7 37.06 36.52 Abs. Int. 8.21e6 PCB-158 1.94e7 37.76 4.11e6 0% 28.0 30.0 32.0 34.0 ES-155 4.73e7 30.33 Rel. Int. 100% 36.0 ES-153 3.35e7 36.33 HxCB Std. 26.97-38.16 371.8817 Fn4 Flags: PBM 4σ 2.28e3 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.09e7 JS-138 3.20e7 37.40 5.47e6 0% 28.0 30.0 32.0 34.0 ES-155 3.62e7 30.33 Rel. Int. 100% 36.0 ES-153 2.58e7 36.33 HxCB Std. 26.97-38.16 373.8788 Fn4 Flags: PBM 4σ 1.59e3 38.0 0.00e0 RT Abs. Int. 8.55e6 JS-138 2.47e7 37.40 4.28e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.73e7 QC Check 26.97-38.16 330.9792 Fn4 Flags: - 8.63e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7966, 6834 scc: 756-952 34.0 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 13 of 21 615 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 3.54e7 38.49 HxCB-5 38.17-45.15 359.8415 Fn5 Flags: PBM 4σ 4.40e3 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 PCB-159 2.18e7 39.31 PCB-162 2.16e7 39.54 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 156/157 4.11e7 40.94 Abs. Int. 8.10e6 PCB-169 2.01e7 43.65 PCB-167 2.28e7 39.95 4.05e6 0% 39.0 Rel. Int. 100% HxCB-5 38.17-45.15 361.8385 Fn5 Flags: PBM 4σ 4.25e3 128/166 2.94e7 38.49 PCB-162 PCB-159 1.77e7 39.54 1.78e7 39.30 40.0 41.0 42.0 43.0 44.0 45.0 156/157 3.38e7 40.93 Abs. Int. 6.78e6 PCB-169 1.64e7 43.65 PCB-167 1.89e7 39.95 3.39e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 4.16e7 39.93 HxCB Std. 38.17-45.15 371.8817 Fn5 Flags: PBM 4σ 5.39e3 41.0 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 7.87e7 40.92 0.00e0 RT Abs. Int. 1.43e7 ES-169 3.72e7 43.63 7.17e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 3.25e7 39.93 HxCB Std. 38.17-45.15 373.8788 Fn5 Flags: PBM 4σ 3.98e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 6.19e7 40.92 0.00e0 RT Abs. Int. 1.10e7 ES-169 2.97e7 43.63 5.50e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.00e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.01e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0862, 8183 scc: 756-952 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 14 of 21 616 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Rel. Int. 100% PCB-188 1.75e7 35.23 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-179 1.70e7 PCB-184 1.57e7 35.51 35.97 HpCB-4 30.00-38.16 393.8025 Fn4 Flags: PBM 4σ 7.17e2 PCB-186 1.61e7 36.67 Abs. Int. 4.34e6 PCB-178 1.15e7 37.79 2.17e6 0% 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 PCB-188 1.65e7 35.23 36.0 PCB-179 1.59e7 35.51 PCB-176 1.63e7 36.27 HpCB-4 30.00-38.16 395.7995 Fn4 Flags: PBM 4σ 5.30e2 37.0 PCB-186 1.52e7 36.67 38.0 Abs. Int. 4.09e6 PCB-178 1.10e7 37.79 2.04e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.00e7 35.21 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.05e6 CS/SS-178 2.02e7 37.77 HpCB Std. 30.00-38.16 405.8428 Fn4 Flags: PBM 4σ 1.55e3 3.53e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.81e7 35.21 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.59e6 CS/SS-178 1.90e7 37.77 HpCB Std. 30.00-38.16 407.8398 Fn4 Flags: PBM 4σ 1.47e3 3.30e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.73e7 QC Check 30.00-38.16 330.9792 Fn4 Flags: - 8.63e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6450, 5672 scc: 756-952 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 15 of 21 617 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.17-45.15 393.8025 Fn5 Flags: PBM 4σ 4.75e3 PCB-183 1.57e7 39.09 PCB-182 PCB-185 1.61e7 1.53e7 38.74 39.17 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 180/193 3.38e7 42.06 PCB-192 1.71e7 41.79 PCB-172 1.33e7 41.54 171/173 2.59e7 PCB-181 40.19 PCB-177 1.46e7 1.30e7 40.01 39.66 PCB-191 1.86e7 42.39 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-170 1.27e7 43.16 Abs. Int. 5.99e6 PCB-190 1.80e7 43.62 2.99e6 0% 39.0 Rel. Int. 100% HpCB-5 38.17-45.15 395.7995 Fn5 Flags: PBM 4σ 3.86e3 PCB-182 1.54e7 38.74 PCB-183 PCB-187 1.52e7 1.51e7 39.09 38.57 40.0 41.0 42.0 180/193 3.22e7 42.06 171/173 2.46e7 PCB-181 40.19 PCB-177 1.40e7 1.23e7 40.01 39.66 PCB-172 1.26e7 41.54 43.0 PCB-191 1.76e7 42.39 PCB-170 1.20e7 43.16 44.0 45.0 Abs. Int. 5.62e6 PCB-190 1.73e7 43.62 2.81e6 0% 39.0 40.0 41.0 42.0 ES-180 2.68e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 405.8428 Fn5 Flags: PBM 4σ 2.19e3 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 6.51e6 ES-170 2.23e7 43.14 3.26e6 0% 39.0 40.0 41.0 42.0 ES-180 2.56e7 42.08 Rel. Int. 100% HpCB-5 Std. 38.17-45.15 407.8398 Fn5 Flags: PBM 4σ 2.73e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.30e6 ES-170 2.09e7 43.14 3.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.00e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.01e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6427, 2188 scc: 756-952 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 16 of 21 618 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-189 1.84e7 45.77 Abs. Int. 4.49e6 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PBM 4σ 2.45e3 2.25e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.72e7 45.77 Abs. Int. 4.26e6 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PBM 4σ 2.12e3 2.13e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 3.23e7 45.75 0.00e0 RT Abs. Int. 7.87e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 4.94e3 3.94e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 3.12e7 45.75 0.00e0 RT Abs. Int. 7.36e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 5.92e3 3.68e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.10e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.05e6 0% 46.0 47.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 0282, 4641 scc: 756-952 48.0 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 17 of 21 619 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 PCB-202 1.33e7 39.77 Rel. Int. 100% PCB-201 1.48e7 40.55 OcCB-5 38.17-45.15 427.7635 Fn5 Flags: PBM 4σ 6.01e2 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-197 1.54e7 PCB-204 41.32 PCB-200 1.40e7 1.32e7 41.13 41.41 198/199 1.89e7 43.73 Abs. Int. 3.63e6 PCB-196 9.69e6 44.30 PCB-203 1.01e7 44.47 1.81e6 0% 39.0 40.0 PCB-202 1.45e7 39.77 Rel. Int. 100% OcCB-5 38.17-45.15 429.7606 Fn5 Flags: PBM 4σ 9.59e2 41.0 PCB-201 1.64e7 40.55 42.0 43.0 PCB-197 1.72e7 PCB-204 41.32 PCB-200 1.53e7 1.45e7 41.13 41.41 44.0 45.0 198/199 2.08e7 43.73 Abs. Int. 3.94e6 PCB-196 1.07e7 44.30 PCB-203 1.09e7 44.47 1.97e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.65e7 39.74 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 6.30e6 OcCB Std. 38.17-45.15 439.8038 Fn5 Flags: PBM 4σ 1.51e3 3.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.90e7 39.74 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.03e6 OcCB Std. 38.17-45.15 441.8008 Fn5 Flags: PBM 4σ 1.53e3 3.52e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.00e7 QC Check 38.17-45.15 380.9760 Fn5 Flags: - 5.01e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6027, 7498 scc: 756-952 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 18 of 21 620 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PBM 4σ 2.30e3 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 PCB-194 9.24e6 47.54 PCB-195 8.49e6 45.59 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-205 1.13e7 47.94 Abs. Int. 2.65e6 1.32e6 0% 46.0 Rel. Int. 100% OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PBM 4σ 1.66e3 47.0 48.0 PCB-194 1.01e7 47.54 PCB-195 9.36e6 45.59 49.0 50.0 PCB-205 1.22e7 47.93 0.00e0 RT Abs. Int. 2.86e6 1.43e6 0% 46.0 47.0 48.0 JS-194 1.98e7 47.52 Rel. Int. 100% 49.0 50.0 ES-205 2.14e7 47.92 0.00e0 RT Abs. Int. 5.13e6 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 3.57e3 2.57e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.16e7 47.52 49.0 50.0 ES-205 2.39e7 47.92 0.00e0 RT Abs. Int. 5.86e6 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 3.93e3 2.93e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.10e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.05e6 0% 46.0 47.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 6244, 6339 scc: 756-952 48.0 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 19 of 21 621 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.17-50.16 461.7245 Fn6 Flags: PBM 4σ 1.64e3 PCB-208 1.21e7 45.39 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-207 1.27e7 46.18 Abs. Int. 3.11e6 PCB-206 7.51e6 49.40 1.55e6 0% 46.0 Rel. Int. 100% NoCB 45.17-50.16 463.7216 Fn6 Flags: PBM 4σ 2.40e3 PCB-208 1.55e7 45.39 47.0 48.0 49.0 50.0 PCB-207 1.62e7 46.18 Abs. Int. 3.85e6 PCB-206 9.62e6 49.40 1.92e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 5.35e6 ES-208 2.21e7 45.37 ES-206 1.38e7 49.38 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.05e3 2.68e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 2.76e7 45.37 50.0 Abs. Int. 6.54e6 ES-206 1.76e7 49.38 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 3.26e3 0.00e0 RT 3.27e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.10e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 1.05e6 0% 46.0 47.0 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 7268, 6126 scc: 756-952 48.0 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 20 of 21 622 of 622 SGS-AP ID: OPR1_11899_PCB Instr: AutoSpec-Premier MM7 Sample ID: 0_11899_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 47 Acq: 27-Mar-2014 11:32:47 User: LKB Datafile: 140327X02 PCB-209 1.14e7 50.83 Rel. Int. 100% Abs. Int. 2.47e6 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 5.73e2 1.23e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 9.81e6 50.83 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.11e6 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 7.74e2 1.06e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.16e7 50.81 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.57e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 8.98e2 2.28e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.81e7 50.81 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.83e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.31e2 1.91e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.93e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 9.67e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6506\A6506_11899 PCB\Resources\OPR1_11899_PCB.utp_res, saved 30-Mar-2014 13:53 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/US0007933 cc: 8520, 5771 scc: 756-952 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: 27-Mar-2014 14:04 Printed: 30-Mar-2014 14:43 Page 21 of 21 1 of 417 4 APRIL 2014 DELANEY PETERSON ANCHOR QEA 7200 Olive Way, Ste 300 Seattle WA 98101 t. 206-287-9130 e. DPeterson@anchorqea.com SUBJECT: CERTIFICATE OF RESULTS Dear Delaney; Attached to this narrative are the analytical results for sample(s) submitted for the determination of polychlorinated biphenyl congeners. The insert below summarizes information about the project. If applicable, QC annotations below highlight specific analytical observations and assessments made during the sample handling and data interpretation phases. Results reported relate only to the items tested. PROJECT INFORMATION SUMMARY (When applicable, see QC Annotations for details) Client Project Patrick Bayou Superfund Ste SGS Project # A6517 Analytical Protocol(s) Method 1668A No. Samples Submitted 1 Additional QC Sample(s) 0 No. Laboratory Method Blanks 1 No. OPRs / Batch CS3 1 Date Received 18-Mar-2014 Condition Received good Temperature upon Receipt (C) 1.9 Extraction within Holding Time yes Analysis within Holding Time yes SGS Environmental Services 5500 Business Drive Wilmington, NC 28405 +1 910 350 1903 +1 866 846 8290 www.sgs.com Member of the SGS Group (SGS SA) 2 of 417 + , " ! * ! " ( ( ! ! ( ( ! $ " - ! ( " - . ( " ! ! + ! , - + ! $ . " + 0 ! " # $ " % " / , ) ' ! $ & " " ! ' ( ) & ! & ' $ ( ! ! ! - ( ! ! + " $ ! $ ) ! $ - ) # $ ! ! " ! + ! " & + " ' ! ' ( ' . $ ! ( ! ( % $ " " " & 1 / & ! 1 ! ! - 2 3 ( 4 . 2 - 1 / ! " ' . ! ! ! ! $ " $ $ " - ) ) ( " " ! - ! 0 $ " 1 ) ! $ . + " ) / Digitally signed by Amy Boehm Date: 2014.04.04 11:13:13 -04'00' ( ) 5 6 ! ( + ! " " ! * 7 . " 3 of 417 APPENDIX A: GENERAL DATA QUALIFIERS / DATA ATTRIBUTES B The analyte was found in the method blank, at a concentration that was at least 10% of the concentration in the sample. C Two or more congeners co-elute. In EDDs, C denotes the lowest IUPAC congener in a co-elution group and additional co-eluters for the group are shown with the number of the lowest IUPAC co-eluter. E The reported concentration exceeds the calibration range (upper point of the calibration curve) and is an estimated value. EMPC Represents an Estimated Maximum Possible Concentration. EMPCs arise in cases where the signal/noise ratio is not sufficient for peak identification (the determined ion-abundance ratio is outside the allowed theoretical range), or where there is a co-eluting interference. H/h If the standard recovery is below the method or SOP specified value “H” is assigned. If the obtained value is less than half the specified value “h” is assigned.1 J Indicates that an analyte has a concentration below the reporting limit (lowest point of the calibration curve) and is an estimated value. ND Indicates a non-detect. NR Indicates a value that is not reportable. PR Due to interference, the associated congener is poorly resolved. QI Indicates the presence of a quantitative interference. SI Denotes “Single Ion Mode” and is utilized for PCBs where the secondary ion trace has a significantly elevated noise level due to background PFK. Responses for such peaks are calculated using an EMPC approach based solely on the primary ion area(s) and may be considered estimates.1 U The analyte was not detected. The estimated detection limit (EDL) may be reported for this analyte. V The labeled standard recovery was found to be outside of the method control limits. Page 3 of 5 4 of 417 APPENDIX B: DRBC/TMDL SPECIFIC DATA QUALIFIERS / DATA ATTRIBUTES J The reported result is an estimate. The value is less than the minimum calibration level but greater than the estimated detection limit (EDL). U The analyte was not detected in the sample at the estimated detection limit (EDL). E The reported concentration is an estimate. The value exceeds the upper calibration range (upper point of the calibration curve). D Dilution Data. Result was obtained from the analysis of a dilution. B Analyte found in the sample and associated method blank. C Co-eluting congener Cxx Co-elutes with the indicated congener, data is reported under the lowest IUPAC congener. ‘Xx’ denotes the IUPAC number with the lowest numerical designated congener. NR Analyte is not reportable because of problems in sample preparation or analysis. V Labeled standard recovery is not within method control limits. X Results from re-injection/repeat/second-column analysis. EMPC Estimated maximum possible concentration. Indicates that a peak is identified but did not meet the method specified ion-abundance ratio. APPENDIX C: LAB IDENTIFIERS AR Indicates use of the archived portion of the sample extract. CU Indicates a sample that required additional clean-up prior to MS injection/processing. D Indicates a dilution of the sample extract. The number that follows the “D” indicates the dilution factor. DE Indicates a dilution performed with the addition of ES (extraction standard) solution. DUP Designation for a duplicate sample. MS Designation for a matrix spike. MSD Designation for a matrix spike duplicate. RJ Indicates a reinjection of the sample extract. S Indicates a sample split. The number that follows the “S” indicates the split factor. Page 4 of 5 5 of 417 SGS CERTIFICATIONS California 07255CA Connecticut PH-0258 Florida (primary NELAP) E87634 ISO17025 2726.01 Kansas E-10330 Louisiana 04115 Maryland (DW only) 299 New Jersey NC100 New York 11685 North Carolina DENR 481 North Carolina DHHS (DW only) 37776 North Dakota R-197 Oregon NC200002 Pennsylvania 68-03675 South Carolina 99029 Texas T104704260-13-5 Utah NC009192013-3 Virginia (DW only) 00235 Virginia 460214 Washington State C913 West Virginia 293 Page 5 of 5 6 of 417 Sample ID: Method 1668A PB081_A-2SWMID-140315-N Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: 15-Mar-2014 pH Conc. pg/L PCB-77 33'44'-TeCB 46.2 PCB-81 344'5-TeCB 1.96 PCB-105 233'44'-PeCB 143 PCB-114 2344'5-PeCB 8.76 PCB-118 23'44'5-PeCB 258 PCB-123 23'44'5'-PeCB 7.08 PCB-126 33'44'5-PeCB EMPC PCB-156/157 233'44'5/233'44'5'-HxCB 15.8 PCB-167 23'44'55'-HxCB 4.97 PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB 0.937 Aqueous 1.18 L 6 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11903 Qualifier J 1.49 J J JC J 0.28 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.0184 0.0493 0 0802 0.0802 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 31.1 420 3,420 6,910 2,520 559 147 36.9 11 52.2 Total PCB (Mono-Deca) 14,100 Checkcode: 544-381-QBT SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6517 A6517_11903_PCB_001-RJ 0.167 0.172 0 176 0.176 2,520 564 152 38.9 14,100 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 18-Mar-2014 20-Mar-2014 28-Mar-2014 Recovery % 71.8 84.8 105 110 109 93.1 119 98 96.2 130 107 104 108 109 112 100 100 89.3 89.6 89.3 106 109 121 102 114 93.3 97.3 110 89.6 104 118 135 Report Created: 04-Apr-2014 09:46 Analyst: ds 7 of 417 Sample ID: PB081_A-2SWMID-140315-N Client Data Sample Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site 15-Mar-2014 Date Collected: Matrix: Weight/Volume: pH Conc. Qualifiers PCB-1 26.2 PCB-2 1.72 J PCB-3 3.18 JB Project No.: A6517 Date Received: 1.18 L Sample ID: A6517_11903_PCB_001-RJ Date Extracted: 20-Mar-2014 11903 Date Analyzed: 28-Mar-2014 544-381-QBT Time Analyzed: pg/L Tri Conc. PCB-19 104 PCB-30/18 686 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. Qualifiers Tetra 18-Mar-2014 20:40:49 Conc. Qualifiers J PCB-54 3.65 J PCB-72 4.39 PCB-50/53 214 C PCB-68 30.7 PCB-17 236 PCB-45 197 PCB-57 2.87 PCB-27 42.4 PCB-51 64.5 PCB-58 (0.649) Conc. 31.1 PCB-24 4.39 EMPC 31.1 PCB-16 233 Di Conc. Qualifiers Aqueous 6 Units Mono Method 1668A Laboratory Data PCB-32 227 PCB-34 3.32 PCB-23 (1.04) J J PCB-46 78.8 PCB-67 13.9 PCB-52 1,180 PCB-63 22.8 PCB-61/70/74/76 1,020 PCB-73 2.28 PCB-43 38.1 PCB-69/49 581 PCB-48 172 J 629 PCB-55 6.49 PCB-56 298 PCB-4 155 PCB-10 5.4 J PCB-26/29 122 PCB-9 7.72 J PCB-25 87.9 PCB-44/47/65 982 C PCB-60 130 PCB-7 3.19 J PCB-31 625 PCB-59/62/75 71.9 C PCB-80 (0.6) PCB-6 55.1 PCB-28/20 630 C PCB-42 245 PCB-79 4.53 PCB-5 2.16 J PCB-21/33 152 C PCB-41 57.6 PCB-78 (0.721) C PCB-8 101 PCB-22 165 PCB 14 PCB-14 (0 319) (0.319) PCB 36 PCB-36 (0 997) (0.997) PCB-11 20.4 B PCB-39 5.14 PCB-13/12 15.8 JC PCB-38 (1.08) PCB-15 53.8 PCB-35 8.23 PCB-37 87.2 PCB-71/40 438 PCB 64 PCB-64 368 C PCB-66 C PCB-81 1.96 PCB 77 PCB-77 46 2 46.2 J C J J J J J Conc. 420 Conc. 3,420 Conc. 6,910 EMPC 420 EMPC 3,420 EMPC 6,910 Totals Conc. EMPC Mono-Tri 3,870 3,870 Tel: +1 910 794-1613 Tetra-Hexa 9,980 9,990 www.us.sgs.com Hepta-Deca 247 254 Mono-Deca 14,100 14,100 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 8 of 417 Sample ID: Penta PCB-104 PB081_A-2SWMID-140315-N Conc. Qualifiers (0.163) PCB-96 10 PCB-103 3.22 J J PCB-94 4.5 PCB-95 294 PCB-100/93 7.39 JC Conc. Qualifiers PCB-108/119/86/97/125/87 283 C PCB-155 PCB-117 8.84 PCB-152 0.364 J PCB-146 17.8 PCB-116/85 104 C PCB-150 0.236 J PCB-161 (0.169) Hexa Conc. Qualifiers [0.294] J EMPC PCB-110 396 PCB-136 17.4 PCB-115 10.6 PCB-145 (0.15) PCB-148 (0.217) PCB-82 71.7 PCB-102 22 PCB-111 (0.354) PCB-98 (0.58) PCB-120 [0.517] PCB-88 4.51 PCB-107/124 11.8 PCB-91 71.8 PCB-109 21.8 J Method 1668A Penta 10.2 J EMPC PCB-154 [1.19] J EMPC PCB-164 8.81 JC PCB-144 5.74 J PCB-163/138/129 PCB-147/149 90.9 C PCB-160 PCB-158 14.1 PCB-128/166 22.7 C PCB-159 [0.933] J EMPC J 7.08 J PCB-134 7.84 J [1.11] J EMPC PCB-143 [0.667] J EMPC PCB-121 (0.357) PCB-118 258 2.84 JC J 21.2 PCB-139/140 PCB-122 6.12 PCB-131 2.46 PCB-114 8.76 J PCB-142 (0.262) PCB-105 143 PCB-132 46 PCB-133 [1.66] PCB-99 210 PCB-127 (0.393) PCB-112 (0.366) PCB-126 1.49 Hepta PCB-188 Conc. Qualifiers (0.19) J EMPC 138 PCB-162 0.525 4.97 J PCB-156/157 15.8 JC PCB-169 (0.28) J EMPC Conc. 2,520 Conc. 559 2,520 EMPC 564 Hepta Conc. Nona Conc. Qualifiers 18.9 Octa PCB-202 Conc. Qualifiers 1.97 J J EMPC PCB-208 3.06 Qualifiers J PCB-207 2.64 J PCB-206 5.28 J PCB-179 7.89 J PCB-177 11.7 PCB-201 [1.53] 0.395 J PCB-181 [0.459] J EMPC PCB-204 (0.252) PCB-176 2.41 J PCB-171/173 6.4 JC PCB-197 [0.458] PCB-172 3.43 J PCB-200 1.08 J Conc. 11 PCB-192 (0.33) PCB-198/199 10.9 JC EMPC 11 PCB-196 4.49 J Deca Conc. PCB-186 (0.225) [3.63] J EMPC PCB-175 0.72 J PCB-180/193 38.5 C J EMPC PCB-187 21 PCB-191 [0.781] PCB-182 (0.361) PCB-170 19.5 PCB-183 9.77 PCB-185 2.07 J C PCB-167 PCB-184 PCB-178 J (0.179) EMPC PCB-174 C 7.57 PCB-123 PCB-83 87.5 22.3 PCB-130 PCB-106 C PCB-153/168 PCB-141 PCB-137 140 62 Qualifiers C 14.1 322 Conc. (0.184) 35.5 PCB-84 PCB-113/90/101 PCB-165 PCB-151/135 PCB-89 PCB-92 Hexa J EMPC PCB-203 5.32 J PCB-195 3.89 J PCB-190 3.64 J PCB-194 9.27 PCB-189 0.937 J PCB-205 (0.363) Conc. 147 Conc. 36.9 EMPC 152 EMPC 38.9 209 Congener PCB Summary Page 2 of 2 PCB-209 52.2 Qualifiers 9 of 417 Sample ID: Method 1668A Method Blank A6517 Client Data Name: Project ID: Date Collected: Analyte Sample Data ANCHOR QEA Matrix: Patrick Bayou Superfund Site Weight/Volume: n/a pH Conc. pg/L PCB-77 33'44'-TeCB ND PCB-81 344'5-TeCB ND PCB-105 233'44'-PeCB ND PCB-114 2344'5-PeCB ND PCB-118 23'44'5-PeCB 2.91 PCB-123 23'44'5'-PeCB ND PCB-126 33'44'5-PeCB ND PCB-156/157 233'44'5/233'44'5'-HxCB ND PCB-167 23'44'55'-HxCB ND PCB-169 33'44'55'-HxCB ND PCB-189 233'44'55'-HpCB ND Aqueous 1.00 L n/a DL pg/L 1.64 1.81 1.05 0.995 Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 0.0000873 0.0847 0 169 0.169 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 2.77 8.82 2.06 12.8 12.4 8.51 ND ND ND ND Total PCB (Mono-Deca) 47.4 Checkcode: 680-324-FDZ C 0.0000873 0.0847 0 169 0.169 6.84 14.8 20.9 13.4 1.21 1.27 3.37 1.31 67.5 SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11903 Qualifier J 0.992 1.36 1.45 0.906 1.08 1.02 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6517 MB1_11903_PCB_TLX-RJ2 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 n/a 20-Mar-2014 28-Mar-2014 Recovery % 95.7 110 133 133 136 114 147 120 117 158 V 128 128 134 130 132 123 125 107 111 108 126 126 149 126 138 121 133 139 128 124 139 V 161 V Report Created: 04-Apr-2014 09:44 Analyst: ds 10 of 417 Sample ID: Method Blank A6517 Client Data ANCHOR QEA Name: Project ID: Patrick Bayou Superfund Site n/a Date Collected: Mono Method 1668A Sample Data Conc. Qualifiers J PCB-1 1.08 PCB-2 (1.22) PCB-3 1.69 J Laboratory Data Matrix: Weight/Volume: Aqueous Project No.: A6517 Date Received: n/a 1.00 L Sample ID: MB1_11903_PCB_TLX-RJ2 Date Extracted: 20-Mar-2014 11903 Date Analyzed: 28-Mar-2014 680-324-FDZ Time Analyzed: pH n/a QC Batch No.: Units pg/L Checkcode: Tri Conc. PCB-19 (2.56) PCB-30/18 (1.88) PCB-17 Qualifiers Tetra Conc. PCB-54 (0.971) PCB-50/53 (1.51) (2.21) PCB-45 C Qualifiers Tetra PCB-72 C 19:45:47 Conc. (1.6) PCB-68 (1.5) (1.66) PCB-57 (1.66) (1.58) PCB-27 (1.61) PCB-51 (1.55) PCB-58 Conc. 2.77 PCB-24 (1.69) PCB-46 (1.89) PCB-67 (1.52) EMPC 2.77 PCB-16 (2.97) PCB-52 5.34 PCB-63 (1.44) PCB-32 (1.52) PCB-73 (1.16) PCB-61/70/74/76 Di Conc. PCB-34 (1.64) PCB-43 (1.84) PCB-66 Qualifiers PCB-4 (2.05) PCB-23 (1.62) PCB-10 (1.31) PCB-26/29 (1.6) PCB-9 (2.03) PCB-25 (1.62) PCB-7 (1.78) PCB-31 [1.96] J EMPC PCB-6 (1.91) PCB-28/20 [2.82] J EMPC C PCB-42 PCB-5 (1.9) PCB-21/33 2.06 JC PCB-41 PCB-8 (1.89) PCB-22 (1.7) PCB-71/40 (1.52) PCB 14 PCB-14 (1 59) (1.59) PCB 36 PCB-36 (1 55) (1.55) PCB 64 PCB-64 (1 05) (1.05) PCB-11 8.82 J PCB-39 (1.51) PCB-13/12 (1.86) C PCB-15 (1.92) PCB-38 (1.68) PCB-35 (1.72) PCB-37 (1.9) PCB-69/49 C [2] PCB-48 J J EMPC C (1.54) 3.84 JC (1.71) PCB-55 (1.71) PCB-56 (1.73) PCB-44/47/65 3.67 JC PCB-60 (1.68) PCB-59/62/75 (1.11) C PCB-80 (1.47) (1.7) PCB-79 (1.47) (1.82) PCB-78 (1.76) PCB-81 (1.81) PCB 77 PCB-77 (1 64) (1.64) C Qualifiers Conc. 8.82 Conc. 2.06 Conc. 12.8 EMPC 8.82 EMPC 6.84 EMPC 14.8 Totals Conc. EMPC Mono-Tri 13.6 18.4 Tel: +1 910 794-1613 Tetra-Hexa 33.7 49.1 www.us.sgs.com Hepta-Deca 0 0 Mono-Deca 47.4 67.5 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 11 of 417 Sample ID: Penta Method Blank A6517 Conc. PCB-104 (0.755) Qualifiers Method 1668A Penta Conc. Qualifiers Hexa PCB-108/119/86/97/125/87 [2.67] J EMPC C PCB-155 Conc. Qualifiers (0.61) Hexa PCB-165 Conc. PCB-96 (0.915) PCB-117 (1.02) PCB-152 (0.675) PCB-146 (1.02) PCB-103 (1.29) PCB-116/85 (1.37) C PCB-150 (0.665) PCB-161 (0.796) PCB-94 (1.52) PCB-110 5.2 J PCB-136 (0.726) PCB-153/168 [2.85] PCB-95 4.27 J PCB-115 (1.04) PCB-145 (0.703) PCB-141 (1.13) PCB-100/93 (1.4) C PCB-82 (1.75) PCB-148 (1.02) PCB-102 (1.2) PCB-111 (0.996) PCB-151/135 PCB-98 (1.63) PCB-120 (0.982) PCB-88 (1.55) PCB-107/124 (1.09) PCB-91 (1.31) PCB-109 (0.97) C 2 JC PCB-130 (1.28) PCB-137 (1.05) (0.822) PCB-154 (0.913) PCB-164 PCB-144 (1.03) PCB-163/138/129 PCB-147/149 3.55 JC 2.96 PCB-160 (0.845) (0.765) PCB-84 (1.68) PCB-123 (0.992) PCB-134 (1.26) PCB-158 PCB-89 (1.58) PCB-106 (1.08) PCB-143 (1.15) PCB-128/166 (1.17) PCB-121 (1) PCB-118 2.91 PCB-139/140 (1.04) PCB-159 (0.956) PCB-92 (1.48) PCB-113/90/101 [4.17] PCB-83 (1.73) PCB-99 [1.67] PCB-112 (1.03) Hepta Conc. PCB-188 (0.882) J EMPC C J EMPC Qualifiers J C PCB-122 (1.16) PCB-131 (1.2) PCB-162 (0.954) PCB-114 (0.995) PCB-142 (1.24) PCB-167 (0.906) PCB-105 (1.05) PCB-132 [2.01] PCB-127 (1.05) PCB-133 (1.12) PCB-126 (1.36) J EMPC PCB-156/157 (1.45) PCB-169 (1.08) Conc. 12.4 Conc. 8.51 EMPC 20.9 EMPC 13.4 Hepta Conc. Nona Conc. PCB-174 (1.6) Qualifiers Octa PCB-202 Conc. Qualifiers (1.24) PCB-208 (2.71) PCB-179 (0.994) PCB-177 (1.63) PCB-201 (1.14) PCB-207 (2.59) PCB-184 (1.06) PCB-181 (1.4) PCB-204 (1.21) PCB-206 (4.03) PCB-176 (0.978) PCB-171/173 (1.6) PCB-197 (1.18) C PCB-186 (1.05) PCB-172 (1.54) PCB-200 (1.2) PCB-178 (1.45) PCB-192 (1.17) PCB-198/199 (1.75) PCB-175 (1.4) PCB-180/193 (1.21) PCB-196 (1.64) PCB-187 (1.31) PCB-191 (1.09) PCB-203 (1.56) PCB-182 (1.28) PCB-170 (1.52) PCB-195 (1.91) C PCB-183 (1.26) PCB-190 (1.08) PCB-194 (1.71) PCB-185 (1.36) PCB-189 (1.02) PCB-205 (1.3) Conc. 0 Conc. 0 EMPC 0 EMPC 0 209 Congener PCB Summary Page 2 of 2 C Conc. 0 EMPC 0 Deca Conc. PCB-209 Qualifiers (0.867) (1.31) J EMPC C JC C C Qualifiers Qualifiers 12 of 417 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140328X08 Analysis Date: Lab ID: OPR1_11903_PCB-RJ2 NATIVE ANALYTES PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-104 22'466'-PeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-155 22'44'66'-HxCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-188 22'34'566'-HpCB PCB-189 233'44'55'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-206 22'33'44'55'6-NoCB PCB-208 22'33'455'66'-NoCB PCB-209 DeCB Processed: 04 Apr 2014 09:49 28-MAR-2014 17:55:43 SPIKE CONC. RECOVERY RANGE (%) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 112 113 94.1 104 96.8 112 94 102 105 93.3 97.6 99.2 97.6 98.8 105 96.2 98.9 97.5 95.8 92.8 102 97.9 98.1 99.7 99.2 96.9 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 Contract-required recovery limits for OPR as specified in Table 6, Method 1668A. Analyst: ds FORM 8A OK - 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 13 of 417 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140328X08 Analysis Date: Lab ID: OPR1_11903_PCB-RJ2 LABELED STANDARDS ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 FORM 8B 28-MAR-2014 17:55:43 SPIKE CONC. RECOVERY RANGE (%) 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 86.7 89.1 110 107 108 96 119 100 98.9 129 109 106 109 106 117 98.4 97 90.4 90.6 97.7 100 102 119 102 111 99.2 107 111 102 15 15 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 - 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 100 100 100 98.8 112 129 40 40 40 - 125 125 125 Y Y N OK CLEANUP STANDARDS CS PCB-28 CS PCB-111 CS PCB-178 Processed: 04 Apr 2014 09:49 Analyst: ds 14 of 417 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: AP Smp ID PB081_A-2SWMID-140315-N A6517_001 Preservation Type: Notes/Comments: Amy Boehm 18-Mar-14 at 15:30 A6517 21 days 8-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com Ice - Good Condition Sample Condition & Notes Logged in by: Christina Newkirk Quantity WS Sample Seals: Samples received intact Not all samples had printed lables, see pictures for ID written on lids Received by: Christina Newkirk Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Size 2 Delaney Peterson ANCHOR QEA Patrick Bayou Superfund Site N/A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Sampling Date Sampling Time Received Temp Container # 15-Mar-14 10:15 1.9 1 Shipping # 805046133022 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. QC'ed by: AK SGS Analytical Perspectives 15 0141? CHAIN 0F CUSTODY CONVENTIONAL SHALE PROJECT SEND DOCUMENTATION I RESULTS TO: SPECIAL INSTRUCTIONS I COMMENTS: I PROJECT: oi.) 0 gbl_01. 8? COMPANY: QEA. LLC -RO. CONTACT. jg 14,154.4ng {Reason OUOTE ADDRESS: 4200 1? IL PHONE 5v 1&1 PHESEBVATIVE a ,0 CU TURN AROUNDTIME EMAIL: 306 ?903 ?3.346 pea-(Gan dancino ea cam REPORT LEVEL. (see reverse) .J Level I .1 Level II 86ml IV INVOICE lF SAME) I SPECIAL DELIVERABLES: State of Origin: COMPANY PNL ONTACT: 80 IO ANALYSIS 81 METHOD 3m? 71 Other: 12?" {2'15 pa? I 630 PHONE stI-vn? EMAIL: (a ~5avI-(r -. (UM 0C TYPE CONT. MS MSD DUP IC.G) MATRIX I1TY M15 \q Vl/ SAMPLE ID I DESCRIPTION DATE TIME REMARKS #00 TIME: Henge/Ex RECEIVED BY: #1 I DATE: HELINOUISHED BY (2): Page of 565 NORTH AMERICA INC, ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 910 350 1903 I 910 794 1613 1 Member Of the 868 Group (568 SA) 16 of 417 Project Initiation Form Project Number: A6517 Client Name: Analysis Method: ANCHOR QEA 1668A Initiation Date: Sample Matrix: TAT: Project Manager: 19-Mar-14 Aqueous 21 days Amy Special Instructions 1668A w/ OPR Reporting Instructions PM Initials: aboehm Date: 19-Mar-2014 = 17 of 417 Prep Sheet 3l Il r. ;-F=D:_etl~~v t-R:_ I 1668/\ I \ I'rojcct 1\6517 # 1\ I' Sample Clicnt If) 1\6517_11903_001 I'BOXI Mill Mcthod - 11903 OI'RI - 11903 Sample Batch ID -1\-2SWMID-140315-N Illank 0_11903_0I'ROOI # Volumc (mI.) 11903 Talex # Extract Inil/Dalc: # I 3 'D\)I.) \ I \Q~~ '). (Td) I I Wliter I I lA-1t- '3 l'2..ll {'i ~nitlDatc: , I Transfcr Init/Datcr.t0 .~ \7 U ll~ I .~;::~~,,~ Ohsl'rvlItions Initials 18 '3 vrB 113 3/'Zi 1;4 - "NL ye,\lcrw~ s \." , ~\L- TlI--~ - ~\~ -C(.....\...t...-", I~,-\\l~ ~ -t. IA7;O ~\. Cycle Time Slleciallnstruetions: 1668A wi OrR II'" RV SDS # 3 \\l'~ \1\'(. ') \L-t> ~~~\;~J. Start: Stop: \,~,~ '"-"""" 1:cr"> ~I!V' Tolucnc CII,CL, "\:>:r"-\. G6 01-?--/?(})'-( Acid Silicll »\\(7) Basc Silica Ilcxanc o ")1 '-{'Ull t.{ C vLo"2-6l '1 IlydroMatrix Sand Silica Stop: \\"1-0 SUlllJly II>s Florisil Start: G 1.. -Z.:i t..-O \ ~ (;),\.-f2..., I'CB CS/SS \oV{Z-O\113 n-IS~1 \1-H-t.. 50 ,pg./ II, 100 pg. hlL l oh..-"I 2( I'" \'2 ..\ let It 'I 20 ('CB.IS \07. C;"2 Ol"':l,{b 1-..- QlP-;:) 200 Ilg./~IL \1.. -'''-\LI 10 Fiual Volume Fiual Soln'ut 21 of 417 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: AP Smp ID PB081_A-2SWMID-140315-N A6517_001 Preservation Type: Notes/Comments: Amy Boehm 18-Mar-14 at 15:30 A6517 21 days 8-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com Ice - Good Condition Sample Condition & Notes Logged in by: Christina Newkirk Quantity WS Sample Seals: Samples received intact Not all samples had printed lables, see pictures for ID written on lids Received by: Christina Newkirk Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Size 2 Delaney Peterson ANCHOR QEA Patrick Bayou Superfund Site N/A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Sampling Date Sampling Time Received Temp Container # 15-Mar-14 10:15 1.9 1 Shipping # 805046133022 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. QC'ed by: AK SGS Analytical Perspectives 22 of 417 ~ lDS\\ I CONVENTIONAL CHAIN OF CUSTODY PROJECT INFO: SEND DOCUMENTATION PROJECT: COMPANY: 04 ()2 B(.,{-0 I. () 8 'PO. #: QUOTE #. SITE REF: Pc..-li--,'cJL ~ REPORT LEVEL: (see reverse) D: y'C Jafl~ Pt!ter..5C() -:}20 0 live WC4" INVOICE TO: COMPANY: ADDRESS: PHONE: EMAIL: (OCHECK PNL CONTACT: I I oLt'i 1-"1&..,/\ ~~j .sUi~eti:30 Ho~~h-" '9 SAMPIf 10 IDESCRIPTION 1ft'? ~'" 0-2.:SWN\ --1'1 TIME .1hS-h'" , lD} I)" ------- ------ ---- k ",Atl!i!Sa \0- ...•. .... iwih .t14tim&ii.? ..•.. 0 n ?02-"I DATE MS MSD . +V, ....sG-, TYPE DUP ~ PI n i ewS bc.hpe or !i'l ~C+"D-V (C,G) MATRIX ws {f l ~ •.. c.cl"l'"'\ (3 b IF SAME) ac • PRESERVATIVE d "c!.kr.sof"\C.c(/'\.c.hD~ec o Level II ~elIV o State of Origin: o Other: SPECIAL DELIVERABLES: r:l 0 Levell I COMMENTS: (,<..C . 5v ok.. tCfce> EMAIL: TURN AROUND TIME: j SPECIAL INSTRUCTIONS .5c"&. ij. t~ w A qf! 10 I ZOb-C-Jo3- 33C::;~ PHONE: (fl) I RESULTS TO: A"c.J"ll(' Q~A CONTACT: ADDRESS' & SHALE £ k: 0"" ~n "~ ~. co NT. ~ GTY :J .~ ANALYSIS & METHOD r \j Y'\ FJ ct. " / V REMARKS I V V V / / ---- -- -- I --- / ---- -- -- / ----.... / -----/ f-- ......... ~/" CO~R~~EDBVI" .-:-"'" RELINQUISHED BY (2): ~~ ;}0'1 TIME: DATE: TIME: /~cx.J RECj?;J£~ / (~~~ rS.oc ;;)C"'LC T::JABSENT.Jh'Y' ." • .. •..•.• C •• SAty1P..~..EBECEIPTTEMP: °c RECEIVED BY: \.C\ ""{.,; CARRIER\.:r\~ »INGlES: Page_of_ SGS NORTHAMERICA INC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington. .• *11 .": TRACKING .... 'iit 910350190319107941613 Member ill tii #:~05ZXIl;J;~ ~{J7rv ... NC 28405 ;",A;.Mi.k%;? .v1wWiil .k ~, www.sgs.com of the SGS Group ISGS SAl 23 of 417 SGS Analytical Perspectives — Run Log Project: A6517_11903_PCB Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Datafile Vial# Wt/Vol Client/Sample ID Analyst(s) Checkcode Acq Date 7 140328X07 Tray1:03 CS3_140328_PCB_XB 1.00 SIL 13-79-3 LKB, DES 740-668 28-Mar-2014 17:00:58 8 140328X08 Tray1:76 OPR1_11903_PCB-RJ2 1.00 0_11903_OPR001 LKB, DES 662-053 28-Mar-2014 17:55:43 9 140328X09 Tray1:02 SBS_140328_PCB_XC 1.00 SIL 13-42-1 LKB, DES 100-145 28-Mar-2014 18:50:44 10 140328X10 Tray1:77 MB1_11903_PCB_TLX-RJ2 1.00 Method Blank LKB, DES 680-324 28-Mar-2014 19:45:47 11 140328X11 Tray1:78 A6517_11903_PCB_001-RJ 1.18 PB081_A-2SWMID-140315-N LKB, DES 544-381 28-Mar-2014 20:40:49 Lab ID Project file: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB.utp_prj, saved 31-Mar-2014 07:44 AP UltraTrace-Pro V4.81 User/System: DE/US0008026 Acq Time Printed: 31-Mar-2014 08:03 24 of 417 Lab ID: MB1_11903_PCB_TLX-RJ2 ACQ: 28-Mar-2014 19:45:47 LKB Wt/Vol: 1.00 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB Client ID: Method Blank A6517 UTP: 31-Mar-2014 07:31 DES J-level: 10 pg/L Datafile: 140328X10 RPT: 04-Apr-2014 09:45 ds Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB NotFnd NotFnd NotFnd NotFnd 34.75 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.88 14.16 14.41 20.12 17.49 26.43 20.40 32.76 32.28 25.37 35.74 35.19 34.73 34.45 38.35 36.31 30.31 40.89 39.91 43.60 43.12 42.05 35.19 45.73 39.72 47.89 49.35 45.34 50.78 QC J C V Pred RRT Actual RRT 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 - 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7247 0.8641 0.8794 1.2274 1.0672 1.0791 0.8326 1.3372 1.3177 0.8322 1.1724 1.1547 1.1394 1.1302 1.2580 0.9716 0.8110 1.0941 1.0678 1.1667 0.9080 0.8855 0.7409 0.9629 0.8364 1.0084 1.0392 0.9548 1.0693 Diff Secs 0 +0.1 +0.1 -0.1 +0.4 -0.1 +0.6 -0.2 +1.6 +1.4 -0.5 +0.9 +0.8 +0.6 +0.6 +1.2 0 -0.7 +0.5 +0.2 +0.8 -0.3 -0.3 -0.8 0 -0.5 0 0 -0.3 -0.3 Page 1 of 5 Split: 1 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.74E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.02E+07 5.27E+07 3.05E+07 6.09E+07 3.02E+07 4.51E+07 3.02E+07 3.94E+07 3.80E+07 2.73E+07 3.30E+07 3.34E+07 3.32E+07 3.30E+07 2.90E+07 2.32E+07 3.33E+07 5.73E+07 3.09E+07 2.81E+07 1.84E+07 2.14E+07 2.34E+07 2.79E+07 2.23E+07 2.12E+07 1.54E+07 2.30E+07 1.99E+07 Checkcode: 680-324-FDZ Ra 0.65 3.22 3.28 1.60 1.58 1.07 1.09 0.77 0.81 0.79 1.60 1.61 1.60 1.57 1.58 1.55 1.32 1.28 1.25 1.29 1.28 1.06 1.08 1.06 1.02 0.93 0.88 0.81 0.80 1.20 Method 1668A RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ND ND ND ND 2.91 ND ND ND ND ND ND ND 3.68E+03 3.68E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 2.05E+03 1.66E+03 1.66E+03 1.66E+03 1.48E+03 1.25E+03 1.64 1.81 1.05 0.995 0.992 0.992 1.36 1.45 0.906 1.08 1.02 1.31 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 95.7 % 110 % 133 % 133 % 136 % 114 % 147 % 120 % 117 % 158 % 128 % 128 % 134 % 130 % 132 % 123 % 125 % 107 % 111 % 108 % 126 % 126 % 149 % 126 % 138 % 121 % 133 % 139 % 128 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Printed: 4/4/2014 9:51 AM 25 of 417 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.88 32.77 37.75 CS PCB-28 CS PCB-111 CS PCB-178 22.88 32.77 37.75 JS JS JS JS JS 16.39 24.50 30.48 37.37 47.49 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC V V Pred RRT Actual RRT Diff Secs Response Ra 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 5.46E+07 3.63E+07 1.57E+07 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.89 NotFnd 14.18 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 19.56 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd J J J C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.0013 1.0010 0.9722 - +0.1 0 +0.1 Page 2 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.07 1.59 1.13 1.11 1.03 0.62 109 % 107 % 108 % 30% 30% 30% 135% 135% 135% 5.46E+07 3.63E+07 1.57E+07 1.07 1.59 1.13 1.85 1.22 0.58 124 % 139 % 161 % 30% 30% 30% 135% 135% 135% 4.40E+07 2.38E+07 2.14E+07 1.67E+07 1.40E+07 1.57 0.81 1.58 1.32 0.92 3.84E+03 5.23E+03 3.84E+03 5.31E+03 5.31E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 5.40E+03 5.40E+03 5.40E+03 5.40E+03 5.40E+03 5.40E+03 1.05 1.22 1.03 2.05 1.31 2.03 1.78 1.91 1.9 1.89 1.59 1.85 1.86 1.92 2.56 1.88 2.21 1.61 1.69 2.97 EMPC 2.77 8.82 6.84 14.8 20.9 13.4 0 0 0 NON-EMPC 2.77 8.82 2.06 12.8 12.4 8.51 0 0 0 2.58E+04 0.00E+00 4.49E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.85E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SI SI 1.54 0.95 1.17 1.01 1.23 1.92 0.97 1.10 1.03 1.03 1.04 1.23 1.06 1.06 1.02 1.15 1.56 1.33 1.82 1.74 0.99 DL 1.04 1.99 2.23 1.5 1.02 1.01 1.21 1.27 3.37 1.08 ND 1.69 ND ND ND ND ND ND ND ND 8.82 ND ND ND ND ND ND ND ND Printed: 4/4/2014 9:51 AM 26 of 417 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB NotFnd NotFnd NotFnd NotFnd NotFnd 22.63 22.90 23.10 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 24.52 NotFnd NotFnd 24.96 NotFnd 25.41 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 28.73 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC C J EMPC J EMPC C J C C J J EMPC C J C C C J C Pred RRT Actual RRT 1.1758 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.8561 0.8662 0.8740 1.0008 1.0189 1.0373 0.8901 - Diff Secs -0.1 -1.1 +0.3 -0.1 +1.2 -1.7 -0.2 Page 3 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.93E+04 7.98E+04 5.94E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 9.12E+04 0.00E+00 0.00E+00 4.16E+04 0.00E+00 6.73E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 9.11E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 0.77 0.85 1.05 0.78 1.10 0.84 0.79 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.93 1.25 1.27 1.28 1.26 1.34 1.26 1.28 1.20 1.32 1.36 1.22 1.19 1.08 1.35 0.92 0.84 0.90 0.74 0.90 1.19 0.75 1.10 0.90 0.96 1.25 0.82 0.76 0.92 1.33 1.26 1.35 1.22 1.27 1.33 1.40 1.25 1.18 1.18 1.17 1.20 1.38 1.37 1.15 1.43 1.18 0.93 0.79 ND ND ND ND ND 1.96 2.82 2.06 ND ND ND ND ND ND ND ND ND ND ND 5.34 ND ND 2 ND 3.67 ND ND ND ND ND ND ND ND ND ND ND 3.84 ND ND ND ND ND ND ND ND ND ND ND 5.40E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 2.25E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 1.57E+03 1.57E+03 1.94E+03 1.94E+03 1.52 1.64 1.62 1.6 1.62 1.52 1.63 1.59 1.7 1.55 1.51 1.68 1.72 1.9 0.971 1.51 1.66 1.55 1.89 1.55 1.16 1.84 1.27 1.54 1.44 1.11 1.7 1.82 1.52 1.05 1.6 1.5 1.66 1.58 1.52 1.44 1.62 1.71 1.71 1.73 1.68 1.47 1.47 1.76 0.755 0.915 1.29 1.52 Printed: 4/4/2014 9:51 AM 27 of 417 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.96 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.50 NotFnd 31.00 NotFnd 31.47 NotFnd NotFnd 32.20 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 33.00 NotFnd NotFnd 33.78 NotFnd NotFnd NotFnd NotFnd NotFnd 34.84 NotFnd NotFnd NotFnd NotFnd 36.34 SGS Evironmental Services QC J C J EMPC C J EMPC J EMPC C C J C J C J C C J EMPC J EMPC C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9174 1.0007 1.0171 1.0325 1.0563 1.0887 1.1144 1.1495 0.9723 -0.3 +1.5 -0.4 +0.9 +0.4 +0.2 +0.6 +0.2 -1.1 Page 4 of 5 Response Ra RRF Conc. / Recv. 6.08E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.61E+04 0.00E+00 2.47E+04 0.00E+00 4.31E+04 0.00E+00 0.00E+00 9.40E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.54E+04 0.00E+00 0.00E+00 4.59E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.31E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.70E+04 0.65 0.86 0.86 1.00 0.74 0.78 0.92 0.71 0.76 1.20 0.81 0.96 0.70 0.90 1.17 0.98 1.18 0.88 1.10 1.16 0.69 1.21 1.22 1.11 1.24 1.11 1.03 1.12 1.26 1.14 1.15 1.06 1.09 1.15 1.09 1.29 1.14 1.11 0.93 1.02 1.13 0.98 0.95 0.99 1.05 1.35 1.15 1.47 1.42 4.27 ND ND ND ND ND ND ND ND ND 4.17 ND 1.67 ND 2.67 ND ND 5.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 ND ND 3.55 ND ND ND ND ND 2.01 ND ND ND ND 2.85 0.51 0.81 0.72 0.55 1.32 1.24 0.95 1.44 Noise / Recv. Low DL / Recv. High 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.39 1.4 1.2 1.63 1.55 1.31 1.68 1.58 1 1.48 1.25 1.73 1.34 1.03 1.23 1.02 1.37 1.1 1.04 1.75 0.996 0.982 1.09 0.97 1.08 1.16 1.05 0.61 0.675 0.665 0.726 0.703 1.02 1.07 0.913 1.03 1.05 1.26 1.15 1.04 1.2 1.24 1.19 1.12 0.867 1.02 0.796 0.829 Printed: 4/4/2014 9:51 AM 28 of 417 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB NotFnd NotFnd NotFnd NotFnd 37.40 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J C C C C C Pred RRT Actual RRT 0.9766 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 1.0007 - Diff Secs -0.9 Page 5 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.94E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.41 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.04 0.92 1.11 1.43 1.15 1.39 1.53 0.90 1.10 1.10 1.27 1.13 1.06 1.15 1.07 0.77 1.07 1.15 1.18 1.20 1.10 0.94 0.92 1.07 0.94 0.98 1.29 1.24 1.38 1.13 1.60 1.05 1.14 1.07 1.10 1.08 0.74 0.80 0.83 0.72 0.81 1.06 1.12 1.18 1.11 ND ND ND ND 2.96 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.66E+03 1.66E+03 1.66E+03 1.32E+03 1.32E+03 1.32E+03 1.32E+03 1.32E+03 1.32E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.44E+03 1.44E+03 1.44E+03 3.21E+03 3.21E+03 3.21E+03 1.13 1.28 1.05 0.822 1.02 0.845 0.765 1.17 0.956 0.954 0.882 0.994 1.06 0.978 1.05 1.45 1.4 1.31 1.28 1.26 1.36 1.6 1.63 1.4 1.6 1.54 1.17 1.21 1.09 1.52 1.08 1.24 1.14 1.21 1.18 1.2 1.75 1.64 1.56 1.91 1.71 1.3 2.71 2.59 4.03 Printed: 4/4/2014 9:51 AM 29 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.00e7 2.00e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 8.56e6 4.28e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 7.56e6 3.78e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.11 330.9792 Fn4 Flags: 0% Abs. Int. 1.37e7 6.85e6 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 Rel. Int. QC chk 100% 38.13-45.15 380.9760 Fn5 Flags: 0% Abs. Int. 8.27e6 4.14e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.51e6 7.54e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.42e6 7.09e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 scc: 680-324 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 04-Apr-2014 09:51 Page 1 of 21 30 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 PCB-3 3.41e4 SI 14.18 PCB-1 1.96e4 SI 11.89 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.91e3 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Abs. Int. 1.35e4 6.73e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.96e3 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 2.32e3 4.48e3 0% 11.0 12.0 13.0 ES-1 3.83e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 4.04e7 14.16 0.00e0 16.0 RT Abs. Int. 1.46e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 4.33e3 7.29e6 0% 11.0 12.0 13.0 ES-1 1.19e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 1.23e7 14.16 0.00e0 16.0 RT Abs. Int. 4.68e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.24e4 2.34e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.00e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.00e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0728, 9520 scc: 680-324 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 09:51 Page 2 of 21 31 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 6.86e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 3.24e3 3.43e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.05e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 9.14e3 1.02e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.88e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.48e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.58e3 3.24e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.17e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.04e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.94e3 2.02e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.00e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.00e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 6488, 6296 scc: 680-324 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:12 (DES) Printed: 04-Apr-2014 09:51 Page 3 of 21 32 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 PCB-11 1.73e5 19.56 Rel. Int. 100% Abs. Int. 5.45e4 DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.05e3 2.72e4 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 6.77e4 PCB-11 1.12e5 19.55 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 9.06e3 3.39e4 0% 17.0 Rel. Int. 100% DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 2.57e4 18.0 19.0 20.0 21.0 ES-15 3.73e7 20.12 JS-9 2.69e7 16.39 5.22e6 17.0 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.42e3 0.00e0 RT Abs. Int. 1.04e7 0% Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 21.0 ES-15 2.36e7 20.11 JS-9 1.71e7 16.39 0.00e0 RT Abs. Int. 6.61e6 3.30e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.56e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.28e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8456, 5195 scc: 680-324 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:15 (DES) Printed: 04-Apr-2014 09:51 Page 4 of 21 33 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 1.70e4 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: B 4σ 3.02e3 8.49e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e4 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PB 4σ 2.38e3 5.72e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 3.77e4 ES-19 1.56e7 17.49 6.09e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.46e7 17.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.46e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.36e4 2.23e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.56e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.28e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 4780, 6276 scc: 680-324 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:15 (DES) Printed: 04-Apr-2014 09:51 Page 5 of 21 34 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 PCB-31 3.03e4 22.63 TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 2.66e3 28/20 4.07e4 22.90 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Abs. Int. 1.34e4 21/33 3.04e4 23.10 6.70e3 0% 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 28/20 4.76e4 22.90 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.06e3 PCB-31 3.94e4 22.62 Abs. Int. 1.75e4 21/33 2.90e4 23.12 8.76e3 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 2.83e7 22.88 Rel. Int. 100% ES-37 2.35e7 26.43 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.61e4 Abs. Int. 7.82e6 3.91e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 2.64e7 22.88 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 2.16e7 26.43 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 1.99e4 Abs. Int. 7.24e6 3.62e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.56e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.78e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8901, 6703 scc: 680-324 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 09:51 Page 6 of 21 35 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 3.72e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 7.35e2 1.86e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.20e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 1.51e3 1.60e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.32e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.73e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 3.08e3 1.87e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.70e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.89e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 2.48e3 2.44e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.56e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.28e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 5195, 2420 scc: 680-324 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 10:45 (LKB) Printed: 04-Apr-2014 09:51 Page 7 of 21 36 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 PCB-52 3.99e4 24.52 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.07e3 69/49 2.56e4 24.96 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Abs. Int. 1.41e4 44/47… 3.07e4 25.41 7.04e3 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 Abs. Int. 1.61e4 PCB-52 5.13e4 24.52 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.46e3 69/49 2.34e4 24.96 44/47… 3.66e4 25.42 8.07e3 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 0.00e0 RT Abs. Int. 3.61e6 JS-52 1.07e7 24.50 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 8.35e3 0.00e0 RT 1.81e6 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 Abs. Int. 4.57e6 JS-52 1.31e7 24.50 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 5.11e3 0.00e0 RT 2.29e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.56e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.78e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0302, 3687 scc: 680-324 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 07:30 (DES) Printed: 04-Apr-2014 09:51 Page 8 of 21 37 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 61/70... 4.03e4 28.73 Rel. Int. 100% Abs. Int. 8.22e3 TeCB-4 26.97-38.11 289.9224 Fn4 Flags: PBM 4σ 1.40e3 4.11e3 0% 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 61/70... 5.08e4 28.73 Rel. Int. 100% Abs. Int. 1.08e4 TeCB-4 26.97-38.11 291.9194 Fn4 Flags: PBM 4σ 2.28e3 5.38e3 0.00e0 38.0 RT 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.68e7 32.28 TeCB Std. 26.97-38.11 301.9626 Fn4 Flags: PBM 4σ 9.96e3 34.0 ES-77 1.76e7 32.76 36.0 Abs. Int. 4.35e6 (1.76e7 + 2.18e7) * 2000 pg * 100 % (1.07e7 + 1.31e7) * 2000 pg * 1.38 DES 31-Mar-2014 07:40 Recv(ES-77) = 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 2.13e7 32.28 TeCB Std. 26.97-38.11 303.9597 Fn4 Flags: PBM 4σ 5.56e3 34.0 36.0 = 120 % 2.18e6 0.00e0 38.0 RT Abs. Int. 5.38e6 ES-77 2.18e7 32.76 2.69e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.37e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.85e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8235, 3393 scc: 680-324 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:17 (DES) Printed: 04-Apr-2014 09:51 Page 9 of 21 38 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 2.34e3 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PB 4σ 5.50e2 1.17e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.94e3 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PB 4σ 1.02e3 9.69e2 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.68e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.46e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.66e3 2.23e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.05e7 25.36 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.76e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.16e3 1.38e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.56e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.78e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8097, 5836 scc: 680-324 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:50 Printed: 04-Apr-2014 09:51 Page 10 of 21 39 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.97-38.11 323.8834 Fn4 Flags: PBM 4σ 8.11e2 PCB-95 2.39e4 27.96 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 113/90… 2.53e4 30.50 PCB-110 3.32e4 32.20 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Abs. Int. 1.07e4 PCB-118 2.27e4 34.75 PCB-99108/119... 1.23e4 1.93e4 31.00 31.47 < S/N 0% 28.0 Rel. Int. 100% PeCB-4 26.97-38.11 325.8804 Fn4 Flags: PBM 4σ 1.13e3 PCB-95 3.69e4 27.97 30.0 32.0 113/90… 5.01e4 30.50 34.0 36.0 30.0 PCB-118 3.47e4 34.75 108/119... PCB-99 2.66e4 1.52e4 31.47 31.01 8.77e3 32.0 34.0 CS/SS-111 2.23e7 32.77 Rel. Int. 100% JS-101 1.31e7 30.48 PeCB Std. 26.97-38.11 337.9207 Fn4 Flags: PBM 4σ 1.50e3 0.00e0 38.0 RT Abs. Int. 1.75e4 PCB-110 6.08e4 32.20 0% 28.0 5.33e3 ES-123 2.02e7 34.45 36.0 ES-118 ES-114 2.02e7 2.05e7 34.73 35.19 ES-105 2.03e7 35.74 0.00e0 38.0 RT Abs. Int. 5.52e6 2.76e6 0% 28.0 30.0 32.0 34.0 CS/SS-111 1.40e7 32.77 Rel. Int. 100% JS-101 8.32e6 30.48 PeCB Std. 26.97-38.11 339.9177 Fn4 Flags: PBM 4σ 2.81e3 ES-123 1.28e7 34.45 36.0 ES-118 ES-114 1.29e7 1.29e7 34.73 35.19 ES-105 1.27e7 35.74 0.00e0 38.0 RT Abs. Int. 3.44e6 1.72e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.37e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.85e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 2804, 0009 scc: 680-324 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:17 (DES) Printed: 04-Apr-2014 09:51 Page 11 of 21 40 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 9.31e3 PeCB-5 38.13-45.15 323.8834 Fn5 Flags: PB 4σ 9.16e2 4.65e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 2.03e4 PeCB-5 38.13-45.15 325.8804 Fn5 Flags: PB 4σ 1.13e3 1.02e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.14e6 ES-126 1.76e7 38.35 PeCB Std. 38.13-45.15 337.9207 Fn5 Flags: PBM 4σ 4.68e3 2.07e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.81e6 ES-126 1.14e7 38.35 PeCB Std. 38.13-45.15 339.9177 Fn5 Flags: PBM 4σ 3.40e3 1.40e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.27e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 7736, 4844 scc: 680-324 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:12 (DES) Printed: 04-Apr-2014 09:51 Page 12 of 21 41 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Rel. Int. 100% Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 153/168 3.00e4 36.34 147/149 2.55e4 33.78 HxCB-4 26.97-38.11 359.8415 Fn4 Flags: PBM 4σ 5.53e2 151/135 1.44e4 33.00 163/138… 2.31e4 37.40 PCB-132 1.29e4 34.84 3.74e3 0% 28.0 30.0 32.0 34.0 HxCB-4 26.97-38.11 361.8385 Fn4 Flags: PBM 4σ 8.06e2 153/168 2.09e4 36.33 PCB-132 1.36e4 34.84 151/135 1.10e4 32.99 0.00e0 38.0 RT 36.0 147/149 2.05e4 33.77 Rel. Int. 100% 163/138… 1.63e4 37.40 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 ES-155 1.87e7 30.31 Rel. Int. 100% ES-153 1.32e7 36.31 HxCB Std. 26.97-38.11 371.8817 Fn4 Flags: PBM 4σ 1.42e3 Abs. Int. 4.97e6 JS-138 9.54e6 37.37 0% 28.0 30.0 32.0 34.0 ES-153 1.00e7 36.31 HxCB Std. 26.97-38.11 373.8788 Fn4 Flags: PBM 4σ 1.70e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 2.48e6 0.00e0 38.0 RT 36.0 ES-155 1.46e7 30.31 Rel. Int. 100% Abs. Int. 6.10e3 3.05e3 0% 28.0 Abs. Int. 7.47e3 Abs. Int. 3.78e6 JS-138 7.21e6 37.37 1.89e6 0.00e0 38.0 RT Abs. Int. 1.37e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.85e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 6009, 0529 scc: 680-324 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:18 (DES) Printed: 04-Apr-2014 09:51 Page 13 of 21 42 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 2.47e3 HxCB-5 38.13-45.15 359.8415 Fn5 Flags: PB 4σ 8.20e2 1.23e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.35e3 HxCB-5 38.13-45.15 361.8385 Fn5 Flags: PB 4σ 8.35e2 2.18e3 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.74e7 39.91 HxCB Std. 38.13-45.15 371.8817 Fn5 Flags: PBM 4σ 2.85e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.19e7 40.89 0.00e0 RT Abs. Int. 5.79e6 ES-169 1.58e7 43.60 2.89e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.35e7 39.91 HxCB Std. 38.13-45.15 373.8788 Fn5 Flags: PBM 4σ 5.17e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 2.54e7 40.89 0.00e0 RT Abs. Int. 4.52e6 ES-169 1.24e7 43.61 2.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.27e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0486, 5817 scc: 680-324 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 09:51 Page 14 of 21 43 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 3.25e3 HpCB-4 30.00-38.11 393.8025 Fn4 Flags: PB 4σ 7.15e2 1.63e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.42e3 HpCB-4 30.00-38.11 395.7995 Fn4 Flags: PB 4σ 6.03e2 1.21e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.21e7 35.19 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.03e6 CS/SS-178 8.34e6 37.75 HpCB Std. 30.00-38.11 405.8428 Fn4 Flags: PBM 4σ 1.47e3 1.51e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.14e7 35.19 Rel. Int. 100% Abs. Int. 2.92e6 CS/SS-178 7.38e6 37.75 HpCB Std. 30.00-38.11 407.8398 Fn4 Flags: PBM 4σ 1.50e3 1.46e6 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e7 QC Check 30.00-38.11 330.9792 Fn4 Flags: - 6.85e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 9967, 5748 scc: 680-324 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:50 Printed: 04-Apr-2014 09:51 Page 15 of 21 44 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 3.78e3 HpCB-5 38.13-45.15 393.8025 Fn5 Flags: B 4σ 7.66e2 1.89e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e3 HpCB-5 38.13-45.15 395.7995 Fn5 Flags: B 4σ 7.96e2 1.29e3 0% 39.0 40.0 41.0 42.0 ES-180 1.11e7 42.05 Rel. Int. 100% 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.70e6 ES-170 9.49e6 43.12 HpCB-5 Std. 38.13-45.15 405.8428 Fn5 Flags: PBM 4σ 1.73e3 1.35e6 0% 39.0 40.0 41.0 42.0 ES-180 1.03e7 42.05 Rel. Int. 100% HpCB-5 Std. 38.13-45.15 407.8398 Fn5 Flags: PBM 4σ 3.53e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.58e6 ES-170 8.93e6 43.12 1.29e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.27e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3561, 9416 scc: 680-324 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 09:51 Page 16 of 21 45 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 1.88e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 7.47e2 9.38e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 2.19e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 7.34e2 1.10e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.41e7 45.73 0.00e0 RT Abs. Int. 3.40e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 3.24e3 1.70e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.38e7 45.73 0.00e0 RT Abs. Int. 3.17e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.58e3 1.58e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 7.54e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 9327, 3854 scc: 680-324 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:50 Printed: 04-Apr-2014 09:51 Page 17 of 21 46 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 2.37e3 OcCB-5 38.13-45.15 427.7635 Fn5 Flags: PB 4σ 7.31e2 1.19e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.67e3 OcCB-5 38.13-45.15 429.7606 Fn5 Flags: PB 4σ 7.33e2 1.34e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.08e7 39.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.71e6 OcCB Std. 38.13-45.15 439.8038 Fn5 Flags: PBM 4σ 1.59e3 1.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.16e7 39.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e6 OcCB Std. 38.13-45.15 441.8008 Fn5 Flags: PBM 4σ 1.43e3 1.43e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.27e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3916, 9274 scc: 680-324 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:50 Printed: 04-Apr-2014 09:51 Page 18 of 21 47 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 1.74e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PB 4σ 6.95e2 8.72e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.82e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PB 4σ 7.43e2 9.10e2 0% 46.0 47.0 48.0 49.0 50.0 ES-205 9.95e6 47.89 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.45e6 JS-194 6.70e6 47.49 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 1.82e3 1.22e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 1.12e7 47.89 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e6 JS-194 7.33e6 47.49 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.74e3 1.39e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 7.54e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 7110, 1117 scc: 680-324 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:14 (DES) Printed: 04-Apr-2014 09:51 Page 19 of 21 48 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 2.23e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 1.17e3 1.12e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 4.73e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 2.05e3 2.36e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 1.02e7 45.34 50.0 0.00e0 RT Abs. Int. 2.34e6 ES-206 6.91e6 49.35 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.10e3 1.17e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 1.28e7 45.34 50.0 Abs. Int. 3.00e6 ES-206 8.53e6 49.35 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.52e3 0.00e0 RT 1.50e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 7.54e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8295, 6602 scc: 680-324 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 09:51 Page 20 of 21 49 of 417 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 3.17e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: B 4σ 5.60e2 1.58e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.89e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: B 4σ 6.91e2 9.46e2 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.09e7 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.34e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 9.64e2 1.17e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 9.06e6 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.99e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.55e2 9.95e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.42e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 7.09e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 07:40 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 1312, 9304 scc: 680-324 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:14 (DES) Printed: 04-Apr-2014 09:52 Page 21 of 21 50 of 417 Lab ID: A6517_11903_PCB_001-RJ ACQ: 28-Mar-2014 20:40:49 LKB Wt/Vol: 1.18 L Client ID: PB081_A-2SWMID-140315-N UTP: 31-Mar-2014 07:34 DES J-level: 8.45 pg/L Datafile: 140328X11 RPT: 04-Apr-2014 09:46 ds Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.76 32.29 35.75 35.21 34.74 34.46 38.36 40.89 39.92 NotFnd 45.74 50.80 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.86 14.14 14.40 20.10 17.47 26.42 20.38 32.74 32.27 25.35 35.73 35.18 34.72 34.44 38.34 36.30 30.30 40.88 39.90 43.60 43.11 42.04 35.18 45.72 39.71 47.88 49.35 45.34 50.78 QC J J J EMPC J C J J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0006 1.0006 1.0006 1.0006 1.0007 1.0006 1.0002 1.0005 1.0004 1.0004 0 +0.2 0 -0.2 0 +0.2 +0.2 -0.7 -0.2 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7246 0.8640 0.8794 1.2277 1.0674 1.0790 0.8324 1.3373 1.3179 0.8321 1.1725 1.1548 1.1395 1.1303 1.2582 0.9716 0.8109 1.0941 1.0678 1.1668 0.9079 0.8854 0.7408 0.9629 0.8363 1.0084 1.0392 0.9548 1.0693 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB Split: 1 Checkcode: 544-381-QBT Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.81 0.85 0.63 0.61 0.61 0.62 0.75 1.25 1.15 0 0 4.66E+06 1.86E+05 1.19E+07 7.70E+05 2.22E+07 6.41E+05 1.10E+05 1.14E+06 3.99E+05 0.00E+00 5.99E+04 2.14E+06 1.01 1.14 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 46.2 1.96 143 8.76 258 7.08 1.49 15.8 4.97 ND 0.937 52.2 6.74E+03 6.74E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.86E+03 1.95E+03 1.95E+03 1.95E+03 1.77E+03 1.27E+03 0.686 0.739 0.394 0.37 0.385 0.353 0.534 0.376 0.244 0.28 0.295 0.354 +0.1 0 -0.1 +0.7 +0.1 +0.5 -0.5 +1.8 +1.7 -0.6 +1.1 +1.1 +0.8 +0.8 +1.6 0 -0.9 +0.5 +0.2 +1.0 -0.5 -0.5 -1.1 0 -0.7 0 0 -0.3 -0.3 1.71E+08 1.84E+08 1.10E+08 2.28E+08 1.11E+08 1.69E+08 1.12E+08 1.48E+08 1.43E+08 1.02E+08 1.26E+08 1.23E+08 1.22E+08 1.26E+08 1.13E+08 8.81E+07 1.25E+08 2.23E+08 1.17E+08 1.09E+08 6.88E+07 8.32E+07 8.85E+07 1.01E+08 8.62E+07 7.25E+07 5.04E+07 8.06E+07 6.21E+07 3.24 3.30 1.58 1.55 1.06 1.09 0.79 0.80 0.79 1.62 1.58 1.60 1.59 1.59 1.55 1.26 1.27 1.25 1.26 1.26 1.05 1.07 1.06 1.02 0.94 0.89 0.79 0.79 1.17 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 71.8 % 84.8 % 105 % 110 % 109 % 93.1 % 119 % 98 % 96.2 % 130 % 107 % 104 % 108 % 109 % 112 % 100 % 100 % 89.3 % 89.6 % 89.3 % 106 % 109 % 121 % 102 % 114 % 93.3 % 97.3 % 110 % 89.6 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Page 1 of 5 Printed: 4/4/2014 9:51 AM 51 of 417 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.87 32.76 37.74 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 2.09E+08 1.41E+08 6.14E+07 1.07 1.57 1.08 1.11 1.03 0.62 111 % 108 % 112 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.87 32.76 37.74 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 2.09E+08 1.41E+08 6.14E+07 1.07 1.57 1.08 1.85 1.22 0.58 104 % 118 % 135 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.37 24.48 30.47 37.37 47.48 2.00E+08 1.09E+08 9.79E+07 7.81E+07 6.25E+07 1.57 0.78 1.59 1.28 0.91 5.86E+03 5.86E+03 5.86E+03 6.56E+03 6.56E+03 5.64E+03 5.64E+03 5.64E+03 5.64E+03 5.64E+03 5.64E+03 5.64E+03 5.64E+03 5.64E+03 6.67E+03 6.67E+03 6.67E+03 6.67E+03 6.67E+03 6.67E+03 0.386 0.339 0.391 0.621 0.398 0.406 0.357 0.382 0.38 0.378 0.319 0.37 0.372 0.385 0.777 0.572 0.67 0.491 0.514 0.902 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.87 13.98 14.16 14.41 14.59 16.39 16.55 16.78 17.08 17.20 NotFnd 19.54 19.81 20.11 17.49 19.26 19.65 19.84 19.97 20.07 J J B J J J J B J C C J 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.0011 0.9881 1.0009 1.0011 1.0135 1.0010 1.0112 1.0250 1.0435 1.0508 0.9722 0.9855 1.0006 1.0010 1.1020 1.1246 1.1357 1.1430 1.1488 0 +0.1 -0.1 0 0 0 +0.1 +0.1 +0.2 +0.2 +0.1 -1.3 -0.2 0 +0.7 +0.4 +0.5 0 +0.5 Page 2 of 5 NON-EMPC 31.1 420 3,420 6,910 2,520 559 147 36.9 11 2.53E+06 2.18E+05 3.50E+05 1.25E+07 6.76E+05 1.01E+06 4.74E+05 7.65E+06 3.01E+05 1.42E+07 0.00E+00 2.93E+06 2.25E+06 7.41E+06 7.84E+06 7.00E+07 2.05E+07 5.04E+06 4.98E+05 1.51E+07 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 31.1 420 3,420 6,910 2,520 564 152 38.9 11 3.19 3.34 3.11 1.58 1.61 1.58 1.54 1.65 1.70 1.62 1.64 1.54 1.62 1.04 1.05 1.06 1.08 1.19 1.07 0.95 1.17 1.01 1.23 1.92 0.97 1.10 1.03 1.03 1.04 1.23 1.06 1.06 1.02 1.15 1.56 1.33 1.82 1.74 0.99 DL 0.389 0.503 0.998 0.474 0.366 0.257 0.329 0.31 0.881 26.2 1.72 3.18 155 5.4 7.72 3.19 55.1 2.16 101 ND 20.4 15.8 53.8 104 686 236 42.4 4.39 233 Printed: 4/4/2014 9:51 AM 52 of 417 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.55 21.70 NotFnd 22.11 22.33 22.61 22.89 23.10 23.45 NotFnd 25.20 NotFnd 26.08 26.44 20.40 22.36 22.98 23.05 23.26 24.51 24.63 24.73 24.95 25.21 25.40 25.69 25.87 26.19 26.29 26.49 27.21 27.47 27.84 NotFnd 28.20 28.43 28.72 29.00 29.14 29.58 29.77 NotFnd 31.43 NotFnd NotFnd 25.69 27.38 27.58 SGS Evironmental Services QC J C C C J J J C J C C C C J J C J J J J Pred RRT Actual RRT Diff Secs 1.1758 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1762 0.8214 0.8370 0.8454 0.8559 0.8663 0.8744 0.8877 0.9539 0.9870 1.0009 1.0009 0.9133 0.9385 0.9415 0.9498 1.0009 1.0059 1.0100 1.0189 1.0296 1.0374 1.0493 1.0565 1.0698 1.0739 1.0821 0.8432 0.8513 0.8628 0.8739 0.8809 0.8902 0.8986 0.9032 0.9167 0.9227 0.9741 1.0134 0.8987 0.9050 +0.5 -0.5 -1.7 -0.3 -0.4 -1.0 +0.8 -0.4 +2.6 -0.2 +0.3 -0.1 -1.6 +0.3 +0.3 -0.1 0 -0.4 -0.1 +1.2 +0.2 -1.5 -0.5 +0.3 0 +0.3 +0.3 -0.7 -0.3 -0.3 -0.3 -0.3 0 -0.5 -0.3 -0.4 -0.4 +0.8 0 -0.3 -0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 2.87E+07 4.14E+05 0.00E+00 1.56E+07 1.11E+07 8.39E+07 7.90E+07 1.95E+07 1.97E+07 0.00E+00 6.97E+05 0.00E+00 9.78E+05 9.40E+06 3.26E+05 1.68E+07 1.41E+07 4.91E+06 4.93E+06 9.01E+07 2.31E+05 2.44E+06 5.40E+07 1.32E+07 8.04E+07 7.64E+06 1.70E+07 3.73E+06 3.40E+07 4.14E+07 4.72E+05 3.52E+06 2.97E+05 0.00E+00 1.56E+06 2.70E+06 1.08E+08 6.29E+07 6.51E+05 2.95E+07 1.33E+07 0.00E+00 5.28E+05 0.00E+00 0.00E+00 7.16E+05 2.24E+05 2.65E+05 1.06 1.05 1.93 1.25 1.27 1.28 1.26 1.34 1.26 1.28 1.20 1.32 1.36 1.22 1.19 1.08 1.35 0.92 0.84 0.90 0.74 0.90 1.19 0.75 1.10 0.90 0.96 1.25 0.82 0.76 0.92 1.33 1.26 1.35 1.22 1.27 1.33 1.40 1.25 1.18 1.18 1.17 1.20 1.38 1.37 1.15 1.43 1.18 0.93 0.79 227 3.32 ND 122 87.9 625 630 152 165 ND 5.14 ND 8.23 87.2 3.65 214 197 64.5 78.8 1,180 2.28 38.1 581 172 982 71.9 245 57.6 438 368 4.39 30.7 2.87 ND 13.9 22.8 1,020 629 6.49 298 130 ND 4.53 ND ND 10 3.22 4.5 1.00 1.00 1.00 1.01 1.01 1.02 0.99 1.13 1.02 0.78 0.78 0.79 0.80 0.79 0.79 0.72 0.79 0.78 0.79 0.78 0.80 0.78 0.81 0.79 0.77 0.75 0.76 0.71 0.79 0.77 0.79 0.80 0.76 0.81 0.81 0.73 0.64 0.61 0.63 Noise / Recv. Low DL / Recv. High 6.67E+03 1.32E+04 1.32E+04 1.32E+04 1.32E+04 1.32E+04 1.32E+04 1.32E+04 1.32E+04 1.32E+04 1.32E+04 1.32E+04 1.32E+04 1.32E+04 2.32E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 2.60E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 6.74E+03 1.39E+03 1.39E+03 3.18E+03 3.18E+03 0.461 1.05 1.04 1.03 1.04 0.979 1.05 1.02 1.1 0.997 0.969 1.08 1.11 1.22 0.244 0.346 0.38 0.356 0.434 0.355 0.267 0.423 0.291 0.353 0.331 0.255 0.39 0.418 0.349 0.24 0.654 0.612 0.678 0.649 0.623 0.591 0.663 0.701 0.7 0.709 0.689 0.6 0.603 0.721 0.163 0.197 0.458 0.542 Printed: 4/4/2014 9:51 AM 53 of 417 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.95 28.16 28.28 NotFnd 28.65 28.71 28.90 29.32 NotFnd 29.98 30.49 30.89 31.00 NotFnd 31.47 31.97 32.06 32.19 32.28 32.47 NotFnd 33.18 34.15 34.36 34.55 35.04 NotFnd 30.32 30.48 30.63 30.93 NotFnd NotFnd 32.99 33.20 33.47 33.76 33.94 34.03 34.28 34.46 NotFnd 34.84 35.24 NotFnd 35.80 NotFnd 36.32 SGS Evironmental Services QC J C J C C C J EMPC J C J EMPC J J EMPC J J C J EMPC J C J J EMPC J C J J EMPC C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9174 0.9243 0.9280 0.9403 0.9424 0.9487 0.9624 0.9840 1.0007 1.0140 1.0173 1.0330 1.0493 1.0522 1.0564 1.0594 1.0657 1.0890 0.9916 0.9977 1.0033 1.0091 1.0007 1.0059 1.0110 1.0208 1.0887 1.0956 1.1045 1.1143 1.1203 1.1231 1.1315 1.1372 1.1499 1.1630 0.9580 0.9721 -0.3 -0.5 -0.3 0 0 0 0 -0.2 +1.5 -0.4 0 +1.9 -0.4 -0.6 +0.6 +0.8 +0.4 +0.6 0 +0.2 -1.0 0 0 -0.2 +0.6 +0.2 +0.2 +0.4 +0.8 +0.4 +0.8 +1.2 +0.6 +0.6 +1.0 +0.8 -0.4 -1.5 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.89E+07 4.73E+05 1.65E+06 0.00E+00 2.62E+05 4.93E+06 7.46E+06 7.98E+05 0.00E+00 3.75E+06 2.31E+07 1.10E+06 1.41E+07 0.00E+00 2.06E+07 7.76E+05 6.78E+06 3.24E+07 9.17E+05 3.68E+06 0.00E+00 4.73E+04 9.76E+05 2.02E+06 9.15E+04 4.63E+05 0.00E+00 2.73E+04 3.06E+04 2.01E+04 1.36E+06 0.00E+00 0.00E+00 2.02E+06 7.96E+04 3.41E+05 5.29E+06 3.82E+05 3.55E+04 1.68E+05 1.25E+05 0.00E+00 2.38E+06 9.06E+04 0.00E+00 1.07E+06 0.00E+00 6.46E+06 0.61 0.65 0.63 0.86 0.86 1.00 0.74 0.78 0.92 0.71 0.76 1.20 0.81 0.96 0.70 0.90 1.17 0.98 1.18 0.88 1.10 1.16 0.69 1.21 1.22 1.11 1.24 1.11 1.03 1.12 1.26 1.14 1.15 1.06 1.09 1.15 1.09 1.29 1.14 1.11 0.93 1.02 1.13 0.98 0.95 0.99 1.05 1.35 1.15 1.47 1.42 294 7.39 22 ND 4.51 71.8 140 14.1 ND 62 322 21.2 210 ND 283 8.84 104 396 10.6 71.7 ND 0.517 11.8 21.8 1.11 6.12 ND 0.294 0.364 0.236 17.4 ND ND 35.5 1.19 5.74 90.9 7.84 0.667 2.84 2.46 ND 46 1.66 ND 17.8 ND 87.5 0.59 0.64 0.61 0.62 0.62 0.63 0.63 0.62 0.61 0.62 0.62 0.62 0.59 0.59 0.47 0.63 0.62 0.46 0.61 0.92 1.08 1.31 1.25 1.25 1.01 1.31 1.28 1.08 1.49 1.28 1.34 1.28 1.49 1.31 1.23 Noise / Recv. Low DL / Recv. High 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 3.18E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 0.496 0.498 0.427 0.58 0.55 0.465 0.599 0.564 0.357 0.527 0.445 0.614 0.477 0.366 0.438 0.363 0.488 0.39 0.37 0.622 0.354 0.349 0.386 0.345 0.386 0.43 0.393 0.13 0.144 0.142 0.155 0.15 0.217 0.228 0.194 0.219 0.223 0.267 0.244 0.22 0.255 0.262 0.252 0.237 0.184 0.217 0.169 0.176 Printed: 4/4/2014 9:51 AM 54 of 417 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.49 36.84 37.03 37.12 37.39 NotFnd 37.72 38.47 39.26 39.51 NotFnd 35.48 35.93 36.24 NotFnd 37.76 38.31 38.53 NotFnd 39.06 39.14 39.25 39.63 39.97 40.17 41.51 NotFnd 42.06 42.36 43.13 43.58 39.73 40.52 NotFnd 41.28 41.37 43.72 44.27 44.44 45.56 47.51 NotFnd 45.36 46.15 49.37 SGS Evironmental Services QC J C C J EMPC J J J J J EMPC J J J EMPC J C J C J EMPC J J J EMPC J EMPC J J C J J J J J J Pred RRT Actual RRT Diff Secs 0.9766 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 0.9858 0.9911 0.9933 1.0007 1.0096 0.9642 0.9841 0.9903 1.0087 1.0214 1.0301 1.0735 1.0889 1.0954 1.1102 1.1127 1.1159 1.1265 1.1361 1.1418 0.9078 0.9199 0.9265 0.9433 0.9532 1.0006 1.0203 1.0394 1.0418 1.1008 1.1148 1.1191 0.9516 0.9921 1.0004 1.0179 1.0004 0 -0.2 0 0 -0.9 0 +0.2 -0.7 0 +0.2 -0.4 +0.2 +0.5 +0.5 +0.5 +0.2 +0.5 +0.7 +0.7 0 +1.2 -0.5 +1.3 -0.3 -0.3 -0.3 +0.2 0 -0.5 0 +1.8 +0.5 +0.8 0 0 -0.3 +0.3 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 1.21E+06 4.89E+05 4.40E+05 6.56E+05 8.22E+06 0.00E+00 1.13E+06 1.41E+06 7.09E+04 4.00E+04 0.00E+00 4.66E+05 2.18E+04 1.45E+05 0.00E+00 1.47E+05 3.81E+04 1.19E+06 0.00E+00 5.75E+05 1.13E+05 8.71E+05 5.30E+05 2.42E+04 2.96E+05 1.65E+05 0.00E+00 2.36E+06 5.32E+04 9.01E+05 2.37E+05 1.06E+05 8.96E+04 0.00E+00 2.58E+04 5.98E+04 4.12E+05 1.83E+05 2.27E+05 1.21E+05 3.21E+05 0.00E+00 1.64E+05 1.48E+05 1.76E+05 1.20 1.22 1.12 1.35 1.28 1.04 0.92 1.11 1.43 1.15 1.39 1.53 0.90 1.10 1.10 1.27 1.13 1.06 1.15 1.07 0.77 1.07 1.15 1.18 1.20 1.10 0.94 0.92 1.07 0.94 0.98 1.29 1.24 1.38 1.13 1.60 1.05 1.14 1.07 1.10 1.08 0.74 0.80 0.83 0.72 0.81 1.06 1.12 1.18 1.11 22.3 10.2 7.57 8.81 138 ND 14.1 22.7 0.933 0.525 ND 7.89 0.395 2.41 ND 3.63 0.72 21 ND 9.77 2.07 18.9 11.7 0.459 6.4 3.43 ND 38.5 0.781 19.5 3.64 1.97 1.53 ND 0.458 1.08 10.9 4.49 5.32 3.89 9.27 ND 3.06 2.64 5.28 1.24 1.22 1.49 1.33 1.04 1.19 1.13 0.87 1.04 1.07 1.13 1.04 1.03 0.99 0.87 1.07 1.12 1.08 0.79 1.06 0.97 0.87 0.69 1.08 1.00 0.97 0.92 1.00 1.01 0.93 0.83 0.77 0.75 Noise / Recv. Low DL / Recv. High 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.95E+03 1.95E+03 1.95E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.35E+03 1.58E+03 1.58E+03 1.58E+03 3.47E+03 3.47E+03 3.47E+03 0.24 0.271 0.224 0.175 0.217 0.179 0.162 0.314 0.258 0.257 0.19 0.214 0.228 0.21 0.225 0.311 0.396 0.37 0.361 0.356 0.385 0.454 0.461 0.397 0.454 0.435 0.33 0.342 0.308 0.47 0.334 0.257 0.236 0.252 0.246 0.25 0.364 0.34 0.325 0.533 0.478 0.363 0.666 0.637 1.1 Printed: 4/4/2014 9:51 AM 55 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 3.68e7 1.84e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 7.94e6 3.97e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 7.17e6 3.58e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.11 330.9792 Fn4 Flags: 0% Abs. Int. 1.30e7 6.48e6 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 Rel. Int. QC chk 100% 38.13-45.16 380.9760 Fn5 Flags: 0% Abs. Int. 7.95e6 3.98e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.18-50.15 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.37e6 6.87e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.34e6 6.68e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 scc: 544-381 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 04-Apr-2014 09:52 Page 1 of 21 56 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 PCB-1 1.92e6 11.87 Rel. Int. 100% Abs. Int. 7.79e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.60e3 3.89e5 PCB-3 2.65e5 14.16 PCB-2 1.68e5 13.98 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 6.03e5 11.87 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.42e5 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.26e3 1.21e5 PCB-3 8.51e4 14.16 PCB-2 5.02e4 13.97 0% 11.0 12.0 13.0 ES-1 1.31e8 11.86 Rel. Int. 100% 14.0 15.0 ES-3 1.41e8 14.14 0.00e0 16.0 RT Abs. Int. 5.15e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 6.56e3 2.57e7 0% 11.0 12.0 13.0 ES-1 4.03e7 11.86 Rel. Int. 100% 14.0 15.0 ES-3 4.28e7 14.14 0.00e0 16.0 RT Abs. Int. 1.61e7 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 5.24e4 8.06e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.68e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 1.84e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 4775, 8145 scc: 544-381 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 2 of 21 57 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 Rel. Int. 100% Abs. Int. 2.59e6 PCB-4 7.63e6 14.41 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 3.99e3 1.30e6 PCB-10 4.17e5 14.59 0% 11.0 12.0 13.0 14.0 Rel. Int. 100% 15.0 Abs. Int. 1.69e6 PCB-4 4.83e6 14.41 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 7.76e3 0.00e0 16.0 RT 8.43e5 PCB-10 2.59e5 14.59 0% 11.0 12.0 13.0 14.0 15.0 ES-4 6.74e7 14.40 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.22e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.17e3 1.11e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.26e7 14.40 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.40e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.50e3 7.01e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.68e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 1.84e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 1306, 9252 scc: 544-381 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 3 of 21 58 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 PCB-8 8.78e6 17.20 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 3.44e3 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 Abs. Int. 2.60e6 PCB-6 4.76e6 16.78 PCB-11 1.82e6 19.54 PCB-9 6.17e5 16.39 PCB-15 4.59e6 20.11 13/12 1.37e6 19.81 1.30e6 0% 17.0 19.0 20.0 21.0 PCB-8 5.42e6 17.20 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 8.32e3 18.0 Abs. Int. 1.61e6 PCB-6 2.89e6 16.78 PCB-11 1.11e6 19.54 PCB-9 3.91e5 16.39 PCB-15 2.83e6 20.11 13/12 8.86e5 19.81 8.05e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 ES-15 1.39e8 20.10 JS-9 1.22e8 16.37 0.00e0 RT Abs. Int. 3.70e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 2.89e4 1.85e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 21.0 ES-15 8.93e7 20.10 JS-9 7.79e7 16.37 0.00e0 RT Abs. Int. 2.41e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 6.80e3 1.21e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.94e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 3.97e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3704, 8740 scc: 544-381 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 4 of 21 59 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Rel. Int. 100% Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 Abs. Int. 9.70e6 30/18 3.58e7 19.26 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 4.05e3 PCB-17 1.05e7 19.65 PCB-19 4.01e6 17.49 PCB-27 2.62e6 19.84 PCB-16 7.81e6 20.07 PCB-32 1.48e7 20.55 4.85e6 0% 17.0 18.0 Rel. Int. 100% 19.0 20.0 21.0 Abs. Int. 9.31e6 30/18 3.42e7 19.26 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.62e3 PCB-17 9.99e6 19.65 PCB-19 3.84e6 17.49 PCB-27 2.42e6 19.84 PCB-16 7.29e6 20.07 PCB-32 1.39e7 20.55 4.66e6 0% 17.0 18.0 19.0 0.00e0 RT 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.03e7 ES-19 5.69e7 17.47 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.43e4 1.52e7 0% 17.0 18.0 19.0 20.0 21.0 ES-19 5.37e7 17.47 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.57e7 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.48e4 7.85e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.94e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 3.97e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 7408, 2870 scc: 544-381 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 5 of 21 60 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 PCB-31 4.20e7 28/20 22.61 3.97e7 22.89 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 6.26e3 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 26/29 7.78e6 22.11 Abs. Int. 1.08e7 21/33 9.79e6 23.10 PCB-25 5.55e6 22.33 5.38e6 PCB-22 9.96e6 23.45 PCB-37 4.75e6 26.44 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 4.19e7 28/20 22.61 3.93e7 22.89 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 6.96e3 24.0 26/29 7.80e6 22.11 PCB-25 5.53e6 22.33 Abs. Int. 1.06e7 21/33 9.72e6 23.10 5.29e6 PCB-22 9.78e6 23.45 PCB-37 4.65e6 26.44 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 1.08e8 22.87 Rel. Int. 100% ES-37 8.80e7 26.42 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.34e4 Abs. Int. 2.78e7 1.39e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 1.01e8 22.87 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 8.07e7 26.42 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 1.96e4 Abs. Int. 2.54e7 1.27e7 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.17e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.58e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3014, 4072 scc: 544-381 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 6 of 21 61 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 PCB-54 1.43e5 20.40 Rel. Int. 100% Abs. Int. 3.99e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 9.62e2 2.00e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.83e5 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.14e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.36e3 2.57e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.92e7 20.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.31e7 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 2.71e3 6.56e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 6.23e7 20.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e7 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 3.00e3 8.23e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.94e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 3.97e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 6662, 7806 scc: 544-381 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 7 of 21 62 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 PCB-52 3.98e7 24.51 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.42e3 50/53 7.38e6 22.36 PCB-51 2.19e6 23.05 PCB-45 6.19e6 22.98 69/49 2.37e7 24.95 44/47… 3.53e7 25.40 PCB-48 5.82e6 25.21 PCB-46 2.17e6 23.26 Abs. Int. 1.05e7 PCB-42 7.49e6 25.87 59/62… 3.39e6 25.69 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 5.03e7 24.51 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.18e3 50/53 9.41e6 22.36 PCB-51 2.72e6 23.05 PCB-45 7.87e6 22.98 PCB-48 7.36e6 25.21 PCB-46 2.76e6 23.25 Abs. Int. 1.31e7 PCB-42 9.55e6 25.87 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.79e7 24.48 Rel. Int. 100% 5.24e6 0.00e0 RT 26.0 44/47… 4.51e7 25.40 69/49 3.03e7 24.95 PCB-64 1.80e7 26.49 PCB-41 1.67e6 26.19 0% 22.0 71/40 1.50e7 26.29 71/40 1.91e7 26.29 PCB-64 2.34e7 26.49 6.55e6 0.00e0 RT Abs. Int. 1.26e7 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 7.59e3 6.31e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 6.11e7 24.48 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 4.01e3 8.09e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.17e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.58e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0156, 8946 scc: 544-381 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 8 of 21 63 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 Abs. Int. 8.39e6 61/70... PCB-66 4.79e7 2.79e7 28.72 29.00 TeCB-4 26.97-38.11 289.9224 Fn4 Flags: PBM 4σ 2.63e3 PCB-56 1.32e7 29.58 PCB-60 5.92e6 29.77 4.19e6 PCB-77 2.08e6 32.76 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 Abs. Int. 1.04e7 61/70... PCB-66 6.03e7 3.50e7 28.72 29.00 TeCB-4 26.97-38.11 291.9194 Fn4 Flags: PBM 4σ 4.11e3 PCB-56 1.63e7 29.58 PCB-60 7.34e6 29.77 5.20e6 PCB-77 2.57e6 32.76 0% 28.0 0.00e0 38.0 RT 30.0 Rel. Int. 100% 32.0 ES-81 6.34e7 32.27 TeCB Std. 26.97-38.11 301.9626 Fn4 Flags: PBM 4σ 1.47e4 34.0 36.0 0.00e0 38.0 RT Abs. Int. 1.60e7 ES-77 6.55e7 32.74 7.99e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 8.00e7 32.27 TeCB Std. 26.97-38.11 303.9597 Fn4 Flags: PBM 4σ 1.04e4 34.0 36.0 0.00e0 38.0 RT Abs. Int. 2.02e7 ES-77 8.22e7 32.75 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.30e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.48e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3279, 2329 scc: 544-381 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 9 of 21 64 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 PCB-96 2.80e5 25.69 Rel. Int. 100% Abs. Int. 7.21e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 6.87e2 3.61e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 4.36e5 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e5 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 7.07e2 5.16e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 6.32e7 25.35 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.56e7 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.66e3 7.81e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 3.89e7 25.35 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.98e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.34e3 4.99e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.17e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.58e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 9664, 5893 scc: 544-381 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 10 of 21 65 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Rel. Int. 100% PeCB-4 26.97-38.11 323.8834 Fn4 Flags: PBM 4σ 1.29e3 113/90… 8.92e6 30.49 PCB-95 7.19e6 27.95 PCB-91 1.93e6 28.71 PCB-84 2.82e6 28.90 PCB-92 1.44e6 29.98 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.11 325.8804 Fn4 Flags: PBM 4σ 1.89e3 0% PCB-95 1.17e7 27.95 PCB-91 3.00e6 28.71 PCB-84 4.64e6 PCB-102 28.90 1.01e6 28.28 28.0 PCB-92 2.31e6 29.98 30.0 Rel. Int. 100% PCB-110 1.24e7 32.19 PCB-99 5.38e6108/119... 31.00 7.83e6 116/85 31.47 2.60e6 PCB-115PCB-82 32.06 3.41e5 1.37e6 32.28 32.47 32.0 113/90… 1.42e7 30.49 Abs. Int. 2.98e6 PCB-118 8.46e6 34.74 PCB-109 7.69e5 34.36 34.0 PCB-105 4.59e6 35.75 36.0 PCB-110 2.00e7 32.19 PCB-99 8.68e6108/119... 31.00 1.28e7 116/85 31.47 4.19e6 PCB-115PCB-82 32.06 5.76e5 2.31e6 32.28 32.47 32.0 1.49e6 0.00e0 38.0 RT Abs. Int. 4.79e6 PCB-118 1.38e7 34.74 PCB-109 1.25e6 34.36 34.0 CS/SS-111 8.60e7 32.76 JS-101 6.01e7 30.47 PeCB Std. 26.97-38.11 337.9207 Fn4 Flags: PBM 4σ 1.77e3 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 PCB-105 7.30e6 35.75 36.0 ES-118 ES-114 ES-123 7.50e7 7.60e7 7.74e7 34.72 35.18 34.44 ES-105 7.72e7 35.73 2.39e6 0.00e0 38.0 RT Abs. Int. 2.12e7 1.06e7 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.47e7 32.76 JS-101 3.79e7 30.47 PeCB Std. 26.97-38.11 339.9177 Fn4 Flags: PBM 4σ 2.51e3 34.0 36.0 ES-118 ES-114 ES-123 4.71e7 4.75e7 4.88e7 34.72 35.18 34.44 ES-105 4.88e7 35.73 0.00e0 38.0 RT Abs. Int. 1.32e7 6.60e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.30e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.48e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 5520, 0869 scc: 544-381 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 11 of 21 66 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 Rel. Int. 100% Abs. Int. 9.39e5 PeCB-5 38.13-45.16 323.8834 Fn5 Flags: PBM 4σ 1.52e3 4.69e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 2.12e6 PeCB-5 38.13-45.16 325.8804 Fn5 Flags: PBM 4σ 2.35e3 1.06e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.68e7 ES-126 6.87e7 38.34 PeCB Std. 38.13-45.16 337.9207 Fn5 Flags: PBM 4σ 8.16e3 8.39e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.11e7 ES-126 4.44e7 38.34 PeCB Std. 38.13-45.16 339.9177 Fn5 Flags: PBM 4σ 7.78e3 5.53e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.95e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 3.98e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 2573, 3557 scc: 544-381 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 12 of 21 67 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Rel. Int. 100% Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 153/168 3.57e6 36.32 147/149 2.97e6 33.76 HxCB-4 26.97-38.11 359.8415 Fn4 Flags: PBM 4σ 7.08e2 PCB-136 7.54e5 30.93 PCB-132 1.33e6 34.84 151/135 1.12e6 32.99 163/138… 4.61e6 37.39 PCB-141 6.58e5 PCB-137 36.49 2.33e5 37.03 PCB-146 6.05e5 35.80 PCB-158 6.24e5 37.72 0% 28.0 30.0 32.0 34.0 5.17e5 0.00e0 38.0 RT 36.0 153/168 2.89e6 36.32 Rel. Int. 100% Abs. Int. 1.03e6 163/138… 3.61e6 37.39 Abs. Int. 8.20e5 147/149 2.32e6 33.76 HxCB-4 26.97-38.11 361.8385 Fn4 Flags: PBM 4σ 5.00e2 PCB-136 6.05e5 30.93 151/135 9.00e5 32.99 PCB-134 1.83e5 33.94 PCB-132 1.04e6 34.84 PCB-141 PCB-158 5.48e5 PCB-164 5.03e5 2.79e5 36.49 37.72 37.11 PCB-146 4.63e5 35.80 0.00e0 38.0 RT 0% 28.0 30.0 32.0 34.0 36.0 ES-155 6.98e7 30.30 Rel. Int. 100% ES-153 4.91e7 36.30 HxCB Std. 26.97-38.11 371.8817 Fn4 Flags: PBM 4σ 1.34e3 4.10e5 Abs. Int. 1.74e7 JS-138 4.38e7 37.37 8.71e6 0% 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 ES-155 5.49e7 30.30 Rel. Int. 100% ES-153 3.90e7 36.30 HxCB Std. 26.97-38.11 373.8788 Fn4 Flags: PBM 4σ 1.20e3 Abs. Int. 1.36e7 JS-138 3.43e7 37.37 6.80e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.30e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.48e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 2685, 5047 scc: 544-381 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 07:33 (DES) Printed: 04-Apr-2014 09:52 Page 13 of 21 68 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 128/166 7.76e5 38.47 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 Abs. Int. 1.79e5 156/157 6.36e5 40.89 HxCB-5 38.13-45.16 359.8415 Fn5 Flags: PBM 4σ 7.41e2 PCB-159 4.69e4 39.26 PCB-167 2.13e5 39.92 8.95e4 0% 39.0 Rel. Int. 100% 40.0 128/166 6.38e5 38.47 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.43e5 156/157 5.07e5 40.89 HxCB-5 38.13-45.16 361.8385 Fn5 Flags: PBM 4σ 1.21e3 PCB-159 3.15e4 39.26 PCB-167 1.86e5 39.92 7.17e4 0% 39.0 Rel. Int. 100% 40.0 ES-167 6.50e7 39.90 HxCB Std. 38.13-45.16 371.8817 Fn5 Flags: PBM 4σ 1.01e4 0.00e0 RT 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.24e8 40.88 0.00e0 RT Abs. Int. 2.22e7 ES-169 6.06e7 43.60 1.11e7 0% 39.0 Rel. Int. 100% 40.0 ES-167 5.17e7 39.90 HxCB Std. 38.13-45.16 373.8788 Fn5 Flags: PBM 4σ 8.39e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 9.90e7 40.88 0.00e0 RT Abs. Int. 1.74e7 ES-169 4.80e7 43.60 8.72e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.95e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 3.98e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 5928, 2111 scc: 544-381 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 14 of 21 69 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Rel. Int. 100% Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 Abs. Int. 6.21e4 PCB-179 2.38e5 35.48 HpCB-4 30.00-38.11 393.8025 Fn4 Flags: PBM 4σ 6.08e2 PCB-184 1.19e4 35.93 PCB-178 7.50e4 37.76 PCB-176 7.68e4 36.24 3.10e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 37.0 38.0 Abs. Int. 6.14e4 PCB-179 2.28e5 35.48 HpCB-4 30.00-38.11 395.7995 Fn4 Flags: PBM 4σ 6.02e2 PCB-184 9.95e3 35.94 PCB-178 8.64e4 37.76 PCB-176 6.78e4 36.24 3.07e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 4.55e7 35.18 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 1.09e7 CS/SS-178 3.19e7 37.74 HpCB Std. 30.00-38.11 405.8428 Fn4 Flags: PBM 4σ 1.57e3 5.46e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 4.30e7 35.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.00e7 CS/SS-178 2.95e7 37.74 HpCB Std. 30.00-38.11 407.8398 Fn4 Flags: PBM 4σ 1.17e3 5.00e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.30e7 QC Check 30.00-38.11 330.9792 Fn4 Flags: - 6.48e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 1999, 9220 scc: 544-381 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 15 of 21 70 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 180/193 1.22e6 42.06 Rel. Int. 100% HpCB-5 38.13-45.16 393.8025 Fn5 Flags: PBM 4σ 8.05e2 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 PCB-187 6.15e5 38.53 PCB-174 PCB-183 4.42e5 39.25 PCB-177 3.06e5 2.64e5 39.06 PCB-185 39.63 5.75e4 39.14 171/173 1.52e5 40.17 Abs. Int. 2.71e5 PCB-170 4.64e5 43.13 PCB-172 8.73e4 41.51 1.35e5 PCB-190 1.17e5 43.58 0% 39.0 40.0 41.0 42.0 44.0 45.0 180/193 1.14e6 42.06 Rel. Int. 100% HpCB-5 38.13-45.16 395.7995 Fn5 Flags: PBM 4σ 1.25e3 43.0 PCB-187 5.75e5 38.53 PCB-174 4.28e5 PCB-177 PCB-183 39.25 2.67e5 2.70e5PCB-185 39.63 39.05 5.51e4 39.14 171/173 1.43e5 40.16 Abs. Int. 2.64e5 PCB-170 4.36e5 43.13 PCB-172 7.80e4 41.51 1.32e5 PCB-190 1.20e5 43.58 0% 39.0 40.0 41.0 42.0 ES-180 4.30e7 42.04 Rel. Int. 100% HpCB-5 Std. 38.13-45.16 405.8428 Fn5 Flags: PBM 4σ 3.53e3 0.00e0 RT 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.05e7 ES-170 3.53e7 43.11 5.26e6 0% 39.0 40.0 41.0 42.0 ES-180 4.02e7 42.04 Rel. Int. 100% HpCB-5 Std. 38.13-45.16 407.8398 Fn5 Flags: PBM 4σ 4.30e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 9.80e6 ES-170 3.36e7 43.11 4.90e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.95e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 3.98e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3854, 9990 scc: 544-381 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 16 of 21 71 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 PCB-189 3.01e4 45.74 Abs. Int. 8.14e3 (3.01e4 + 2.98e4) * 2000 pg = 0.94 pg/L (5.08e7 + 4.98e7) * 1.07 * 1.184 L DES 31-Mar-2014 07:44 Conc(PCB-189) = HpCB-6 45.18-50.15 393.8025 Fn6 Flags: PBM 4σ 8.89e2 4.07e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.98e4 45.74 Abs. Int. 7.36e3 HpCB-6 45.18-50.15 395.7995 Fn6 Flags: PBM 4σ 8.76e2 3.68e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 5.08e7 45.72 0.00e0 RT Abs. Int. 1.19e7 HpCB Std. 45.18-50.15 405.8428 Fn6 Flags: PBM 4σ 4.67e3 5.94e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.98e7 45.72 0.00e0 RT Abs. Int. 1.18e7 HpCB Std. 45.18-50.15 407.8398 Fn6 Flags: PBM 4σ 4.25e3 5.92e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 6.87e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8477, 1479 scc: 544-381 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 17 of 21 72 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 198/199 2.03e5 43.72 Rel. Int. 100% OcCB-5 38.13-45.16 427.7635 Fn5 Flags: PBM 4σ 7.85e2 PCB-202 4.92e4 39.73 PCB-201 4.22e4 40.52 Abs. Int. 5.37e4 PCB-196 8.72e4 44.27 PCB-197 PCB-200 2.99e4 1.47e4 41.37 41.28 PCB-203 1.13e5 44.44 2.69e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 198/199 2.09e5 43.72 Rel. Int. 100% OcCB-5 38.13-45.16 429.7606 Fn5 Flags: PBM 4σ 5.60e2 PCB-202 5.66e4 39.73 PCB-201 6.11e4 40.52 Abs. Int. 4.32e4 PCB-196 9.53e4 44.27 PCB-197 1.36e4 41.28 PCB-203 1.14e5 44.44 2.16e4 PCB-200 2.99e4 41.38 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 4.17e7 39.71 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 1.01e7 OcCB Std. 38.13-45.16 439.8038 Fn5 Flags: PBM 4σ 1.17e3 5.07e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 4.45e7 39.71 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 OcCB Std. 38.13-45.16 441.8008 Fn5 Flags: PBM 4σ 1.65e3 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.95e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 3.98e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8714, 2773 scc: 544-381 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 18 of 21 73 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 PCB-194 1.54e5 47.51 Rel. Int. 100% OcCB-6 45.18-50.15 427.7635 Fn6 Flags: PBM 4σ 7.13e2 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 Abs. Int. 3.77e4 PCB-195 6.05e4 45.56 1.88e4 0% 46.0 47.0 49.0 50.0 PCB-194 1.66e5 47.50 Rel. Int. 100% OcCB-6 45.18-50.15 429.7606 Fn6 Flags: PBM 4σ 8.63e2 48.0 0.00e0 RT Abs. Int. 3.84e4 PCB-195 6.01e4 45.56 1.92e4 0% 46.0 47.0 48.0 JS-194 2.97e7 47.48 Rel. Int. 100% 49.0 50.0 ES-205 3.42e7 47.88 0.00e0 RT Abs. Int. 8.15e6 OcCB Std. 45.18-50.15 439.8038 Fn6 Flags: PBM 4σ 3.97e3 4.08e6 0% 46.0 47.0 48.0 JS-194 3.28e7 47.48 Rel. Int. 100% 49.0 50.0 ES-205 3.83e7 47.88 0.00e0 RT Abs. Int. 8.96e6 OcCB Std. 45.18-50.15 441.8008 Fn6 Flags: PBM 4σ 5.15e3 4.48e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 6.87e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 6275, 6103 scc: 544-381 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 19 of 21 74 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.18-50.15 461.7245 Fn6 Flags: PBM 4σ 9.59e2 PCB-208 7.41e4 45.36 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 PCB-207 6.45e4 46.15 PCB-206 7.52e4 49.37 Abs. Int. 2.05e4 1.02e4 0% 46.0 Rel. Int. 100% NoCB 45.18-50.15 463.7216 Fn6 Flags: PBM 4σ 2.51e3 PCB-208 8.97e4 45.36 47.0 48.0 49.0 50.0 PCB-206 1.00e5 49.36 PCB-207 8.33e4 46.14 Abs. Int. 2.34e4 1.17e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 8.65e6 ES-208 3.56e7 45.34 ES-206 2.23e7 49.35 NoCB Std. 45.18-50.15 473.7648 Fn6 Flags: PBM 4σ 3.29e3 4.33e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 1.10e7 ES-208 4.49e7 45.34 ES-206 2.81e7 49.35 NoCB Std. 45.18-50.15 475.7619 Fn6 Flags: PBM 4σ 3.70e3 5.48e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 6.87e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 9064, 9234 scc: 544-381 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 20 of 21 75 of 417 SGS ID: A6517_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB081_A-2SWMID-140315-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 78 Acq: 28-Mar-2014 20:40:49 User: LKB Datafile: 140328X11 PCB-209 1.14e6 50.80 Rel. Int. 100% Abs. Int. 2.48e5 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 7.10e2 1.24e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 9.98e5 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.18e5 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 5.59e2 1.09e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.35e7 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.33e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.16e3 3.66e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.86e7 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.25e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 8.88e2 3.13e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.34e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 6.68e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 07:44 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 1648, 6350 scc: 544-381 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:36 Printed: 04-Apr-2014 09:52 Page 21 of 21 76 of 417 SGS Analytical Perspectives — Run Log Project: A6517_11903_PCB Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Datafile Vial# Wt/Vol Client/Sample ID Analyst(s) Checkcode Acq Date 7 140328X07 Tray1:03 CS3_140328_PCB_XB 1.00 SIL 13-79-3 LKB, DES 740-668 28-Mar-2014 17:00:58 8 140328X08 Tray1:76 OPR1_11903_PCB-RJ2 1.00 0_11903_OPR001 LKB, DES 662-053 28-Mar-2014 17:55:43 9 140328X09 Tray1:02 SBS_140328_PCB_XC 1.00 SIL 13-42-1 LKB, DES 100-145 28-Mar-2014 18:50:44 10 140328X10 Tray1:77 MB1_11903_PCB_TLX-RJ2 1.00 Method Blank LKB, DES 680-324 28-Mar-2014 19:45:47 11 140328X11 Tray1:78 A6517_11903_PCB_001-RJ 1.18 PB081_A-2SWMID-140315-N LKB, DES 544-381 28-Mar-2014 20:40:49 Lab ID Project file: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\A6517_11903_PCB.utp_prj, saved 31-Mar-2014 07:44 AP UltraTrace-Pro V4.81 User/System: DE/US0008026 Acq Time Printed: 31-Mar-2014 08:03 77 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services CS3_140328_PCB_XB 28-MAR-2014 17:00 140328X07 Processed: 31-Mar-2014 07:25 ICAL: MM7_PCB_10292013_20DEC2013 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.78 32.30 35.76 35.22 34.75 34.47 38.37 40.91 39.93 43.62 45.75 50.81 7.66E+07 7.45E+07 6.19E+07 6.65E+07 6.38E+07 6.63E+07 5.91E+07 1.04E+08 5.82E+07 5.35E+07 5.42E+07 3.80E+07 0.80 Y 0.80 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.65 Y 1.23 Y 1.22 Y 1.25 Y 1.06 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.20 1.19 1.13 1.21 1.19 1.22 1.21 1.11 1.17 1.15 1.09 1.08 3.8% 6.0% 1.1% 0.2% 0.4% 0.9% 8.9% 0.8% 0.8% 1.9% 1.9% -3.4% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 11.87 14.16 14.41 20.11 17.49 26.43 20.40 32.76 32.28 25.37 35.74 35.20 34.73 34.45 38.35 36.32 30.32 40.89 39.91 43.61 43.12 42.05 35.19 45.73 39.72 47.89 49.35 45.35 50.78 2.09E+08 1.94E+08 1.09E+08 2.07E+08 1.01E+08 1.51E+08 1.00E+08 1.28E+08 1.26E+08 8.98E+07 1.10E+08 1.10E+08 1.07E+08 1.09E+08 9.80E+07 7.78E+07 1.09E+08 1.89E+08 9.94E+07 9.33E+07 6.28E+07 7.34E+07 7.87E+07 9.91E+07 7.62E+07 7.59E+07 5.41E+07 7.81E+07 7.06E+07 3.25 Y 3.26 Y 1.61 Y 1.57 Y 1.06 Y 1.10 Y 0.79 Y 0.80 Y 0.80 Y 1.58 Y 1.59 Y 1.58 Y 1.56 Y 1.59 Y 1.54 Y 1.26 Y 1.24 Y 1.27 Y 1.26 Y 1.26 Y 1.07 Y 1.07 Y 1.07 Y 1.03 Y 0.92 Y 0.89 Y 0.80 Y 0.80 Y 1.18 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.09 1.01 0.57 1.08 0.53 1.51 1.00 1.28 1.26 0.99 1.21 1.21 1.17 1.19 1.08 1.13 1.58 1.37 1.44 1.35 1.04 1.22 1.14 1.64 1.11 1.26 0.90 1.30 1.17 -8.9% -7.2% 8.7% 3.3% 3.8% -9.1% 16.4% -7.3% -8.0% 22.9% 0.6% -0.5% 1.4% 0.6% 4.8% 1.3% -0.4% -14.4% -13.6% -13.0% 10.0% 7.0% 21.6% 3.8% 14.0% 1.2% 8.3% 10.3% 5.6% Page 1 of 6 78 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services Processed: 31-Mar-2014 07:25 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB 28-MAR-2014 17:00 140328X07 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 22.88 32.77 37.75 1.65E+08 1.11E+08 4.80E+07 1.09 Y 1.56 Y 1.07 Y 1.11 1.03 0.62 1.10 1.02 0.61 -1.4% -0.4% -1.6% CS PCB-28 CS PCB-111 CS PCB-178 22.88 32.77 37.75 1.65E+08 1.11E+08 4.80E+07 1.09 Y 1.56 Y 1.07 Y 1.85 1.22 0.58 1.65 1.22 0.70 -10.4% 0.2% 19.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.39 24.50 30.48 37.38 47.49 1.92E+08 9.99E+07 9.09E+07 6.89E+07 6.03E+07 1.56 Y 0.78 Y 1.59 Y 1.27 Y 0.89 Y - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 11.89 14.17 14.43 20.13 17.51 26.45 20.42 25.39 30.34 35.21 39.75 47.91 45.37 49.37 1.13E+08 1.11E+08 6.43E+07 1.14E+08 5.69E+07 9.31E+07 6.47E+07 6.10E+07 6.76E+07 4.59E+07 3.84E+07 3.93E+07 4.33E+07 2.98E+07 3.21 Y 3.23 Y 1.59 Y 1.63 Y 1.05 Y 1.01 Y 0.80 Y 0.63 Y 1.25 Y 1.06 Y 0.91 Y 0.91 Y 0.78 Y 0.78 Y 1.08 1.15 1.18 1.10 1.13 1.23 1.29 1.36 1.24 1.17 1.01 1.03 1.11 1.10 13.4% 13.6% -4.6% 7.9% -1.7% 14.4% -4.4% -5.2% -1.7% -8.0% -4.3% -2.4% -1.3% -1.3% 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 - Page 2 of 6 - 79 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB Processed: 31-Mar-2014 07:25 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB 28-MAR-2014 17:00 140328X07 RT Response RA 11.89 13.99 14.17 14.43 14.61 16.40 16.57 16.80 17.10 17.22 18.77 19.55 19.84 20.13 17.51 19.27 19.67 19.86 19.99 20.09 20.57 21.72 21.87 22.15 22.35 22.63 22.91 23.09 23.47 24.85 25.17 25.70 26.09 26.45 20.42 22.40 22.99 23.06 23.27 24.52 24.65 1.13E+08 1.13E+08 1.11E+08 6.43E+07 1.05E+08 1.00E+08 1.14E+08 1.06E+08 1.07E+08 1.07E+08 1.27E+08 1.10E+08 2.18E+08 1.14E+08 5.69E+07 1.58E+08 6.72E+07 9.18E+07 8.77E+07 5.00E+07 9.76E+07 9.42E+07 9.55E+07 1.93E+08 9.53E+07 1.01E+08 1.89E+08 1.94E+08 9.05E+07 9.95E+07 1.02E+08 9.20E+07 8.97E+07 9.31E+07 6.47E+07 1.16E+08 5.28E+07 5.63E+07 4.62E+07 5.64E+07 7.51E+07 3.21 Y 3.21 Y 3.23 Y 1.59 Y 1.59 Y 1.64 Y 1.64 Y 1.63 Y 1.64 Y 1.64 Y 1.64 Y 1.64 Y 1.64 Y 1.63 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.02 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.02 Y 1.01 Y 1.02 Y 1.01 Y 1.01 Y 0.80 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 RRF 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 1.17 1.92 0.97 1.10 1.03 1.03 1.04 1.23 1.06 1.06 1.56 1.33 1.82 1.74 0.99 1.93 1.25 1.27 1.28 1.26 1.34 1.26 1.28 1.20 1.32 1.36 1.22 1.19 0.92 0.84 0.90 0.74 0.90 1.19 12.7% -2.9% 2.3% 5.0% 3.1% 3.0% 0.5% 4.2% 5.0% 6.7% 1.5% 1.9% 0.0% 0.7% -1.7% 0.7% 10.0% 9.5% 9.4% 9.1% 9.7% 10.9% 9.3% 11.2% 12.7% 12.0% 10.4% 14.4% 5.2% 9.5% 4.2% 5.3% 6.5% 7.4% 80 of 417 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeC PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB Processed: 31-Mar-2014 07:25 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB 28-MAR-2014 17:00 140328X07 RT Response RA 24.75 24.94 25.22 25.44 25.72 25.88 26.22 26.31 26.51 27.22 27.48 27.85 28.05 28.21 28.44 28.73 29.01 29.16 29.59 29.79 30.11 31.43 31.92 25.39 25.71 27.40 27.59 27.97 28.18 28.30 28.36 28.66 28.73 28.92 29.34 29.68 30.00 30.48 30.92 4.74E+07 1.38E+08 5.68E+07 1.82E+08 2.36E+08 5.15E+07 4.79E+07 1.15E+08 8.34E+07 7.94E+07 8.48E+07 7.66E+07 8.01E+07 8.33E+07 8.78E+07 3.14E+08 7.41E+07 7.43E+07 7.33E+07 7.55E+07 8.65E+07 8.62E+07 7.21E+07 6.10E+07 5.31E+07 5.06E+07 4.28E+07 4.68E+07 9.32E+07 5.44E+07 4.00E+07 4.22E+07 5.00E+07 3.87E+07 4.12E+07 6.49E+07 4.40E+07 1.56E+08 3.78E+07 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.77 Y 0.79 Y 0.79 Y 0.80 Y 0.79 Y 0.80 Y 0.81 Y 0.79 Y 0.80 Y 0.79 Y 0.80 Y 0.81 Y 0.80 Y 0.80 Y 0.80 Y 0.81 Y 0.80 Y 0.63 Y 0.63 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y Page 4 of 6 RRF 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.75 1.10 0.90 0.96 1.25 0.82 0.76 0.92 1.33 1.26 1.35 1.22 1.27 1.33 1.40 1.25 1.18 1.18 1.17 1.20 1.38 1.37 1.15 1.18 0.93 0.79 0.86 0.86 1.00 0.74 0.78 0.92 0.71 0.76 1.20 0.81 0.96 0.70 6.2% 7.1% 7.8% 6.7% 7.5% 7.4% 9.7% 6.6% 8.7% 4.5% 5.7% 4.8% 8.1% 5.3% 7.7% 4.1% 7.0% 5.5% 5.1% 5.8% 4.9% 5.0% 8.0% -3.7% 0.2% -1.4% -0.5% -0.6% 3.5% -2.8% -2.6% -2.5% -0.3% -0.6% -0.3% -1.1% -2.5% -2.6% 81 of 417 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Processed: 31-Mar-2014 07:25 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB 28-MAR-2014 17:00 140328X07 Name PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB RT Response RA 31.01 31.11 31.46 32.00 32.09 32.20 32.29 32.49 32.80 33.19 34.16 34.37 34.59 35.05 36.99 30.34 30.50 30.64 30.95 31.22 32.49 33.01 33.22 33.48 33.78 33.96 34.04 34.30 34.48 34.62 34.85 35.26 35.60 35.81 35.93 36.36 36.50 36.85 37.05 37.13 37.42 4.87E+07 6.34E+07 3.18E+08 6.39E+07 9.50E+07 5.95E+07 6.28E+07 3.73E+07 6.55E+07 6.64E+07 1.20E+08 6.72E+07 6.01E+07 5.70E+07 6.14E+07 6.76E+07 6.21E+07 6.30E+07 5.77E+07 5.97E+07 4.47E+07 8.49E+07 5.00E+07 4.43E+07 8.67E+07 3.63E+07 3.97E+07 8.80E+07 3.79E+07 3.69E+07 3.85E+07 4.08E+07 5.26E+07 4.47E+07 5.73E+07 1.10E+08 4.04E+07 3.58E+07 4.33E+07 5.55E+07 1.34E+08 0.63 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 1.25 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.26 Y 1.27 Y 1.26 Y 1.26 Y 1.25 Y 1.28 Y 1.27 Y 1.27 Y 1.26 Y 1.26 Y 1.26 Y 1.26 Y 1.27 Y 1.28 Y 1.26 Y 1.26 Y 1.27 Y 1.27 Y 1.26 Y 1.26 Y Page 5 of 6 RRF 0.92 1.17 0.98 1.14 0.94 1.12 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 0.90 1.17 0.98 1.18 0.88 1.10 1.16 0.69 1.21 1.22 1.11 1.24 1.11 1.03 1.12 1.14 1.15 1.06 1.09 1.15 1.09 1.29 1.14 1.11 0.93 1.02 1.13 0.98 0.95 0.99 1.05 1.35 1.15 1.47 1.42 1.04 0.92 1.11 1.43 1.15 -2.6% -0.1% -0.3% 3.4% -6.9% -2.0% -0.2% -1.3% -1.2% 1.0% 0.9% -1.2% 0.2% 4.0% 1.9% -3.0% -1.8% -0.7% -1.9% -2.9% -4.1% -4.2% -3.8% -5.2% 1.0% -9.5% -6.1% -4.9% -4.1% -4.0% -7.3% -3.9% -4.3% -3.1% -2.7% -4.6% -5.4% -4.1% -4.7% -3.7% 82 of 417 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB Processed: 31-Mar-2014 07:25 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB 28-MAR-2014 17:00 140328X07 RT Response RA 37.56 37.74 38.47 39.29 39.52 35.21 35.50 35.95 36.25 36.65 37.77 38.32 38.55 38.72 39.07 39.16 39.27 39.64 39.99 40.17 41.52 41.77 42.04 42.37 43.14 43.59 39.75 40.53 41.11 41.29 41.38 43.71 44.28 44.45 45.57 47.51 47.91 45.37 46.15 49.37 5.40E+07 5.96E+07 8.97E+07 5.47E+07 5.48E+07 4.59E+07 4.43E+07 4.15E+07 4.51E+07 4.21E+07 3.04E+07 3.94E+07 4.22E+07 4.32E+07 4.38E+07 4.05E+07 3.44E+07 3.39E+07 3.93E+07 6.88E+07 3.59E+07 4.72E+07 9.13E+07 5.07E+07 3.56E+07 5.01E+07 3.84E+07 4.36E+07 4.09E+07 4.20E+07 4.13E+07 5.67E+07 3.03E+07 3.18E+07 2.74E+07 3.06E+07 3.93E+07 4.33E+07 4.59E+07 2.98E+07 1.26 Y 1.25 Y 1.23 Y 1.23 Y 1.24 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.06 Y 1.07 Y 1.06 Y 1.05 Y 1.06 Y 1.05 Y 1.06 Y 1.05 Y 1.04 Y 1.04 Y 1.05 Y 1.06 Y 1.04 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 0.91 Y 0.92 Y 0.91 Y 0.91 Y 0.91 Y 0.91 Y 0.90 Y 0.91 Y 0.90 Y 0.91 Y 0.91 Y 0.78 Y 0.79 Y 0.78 Y Page 6 of 6 RRF 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 1.39 1.53 0.90 1.10 1.10 1.13 1.06 1.15 1.07 0.77 1.07 1.15 1.18 1.20 1.10 0.94 0.92 1.07 0.94 0.98 1.29 1.24 1.38 1.13 1.60 1.14 1.07 1.10 1.08 0.74 0.80 0.83 0.72 0.81 1.18 - -8.3% -7.7% 0.4% -1.3% 2.9% -3.0% -6.5% -7.1% -4.9% -8.3% 0.0% 1.1% 0.2% -0.8% 4.1% -5.3% -2.9% -1.6% -1.1% -1.1% 0.0% -1.3% -0.9% -0.1% -3.9% -6.3% -3.7% -7.5% -2.1% -8.1% -4.6% -4.6% -5.8% -4.5% -1.3% - 83 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.57e7 2.28e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 9.38e6 4.69e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 8.09e6 4.05e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.11 330.9792 Fn4 Flags: 0% Abs. Int. 1.51e7 7.55e6 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 Rel. Int. QC chk 100% 38.13-45.16 380.9760 Fn5 Flags: 0% Abs. Int. 9.30e6 4.65e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.18-50.15 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.69e6 8.46e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.62e6 8.09e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 scc: 740-668 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 07:44 Page 1 of 21 84 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-1 8.62e7 11.89 Rel. Int. 100% Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-2 8.61e7 13.99 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.64e3 Abs. Int. 3.43e7 PCB-3 8.49e7 14.17 1.71e7 0% 11.0 12.0 13.0 PCB-1 2.68e7 11.89 Rel. Int. 100% 14.0 PCB-2 2.69e7 13.99 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.36e3 15.0 0.00e0 16.0 RT Abs. Int. 1.07e7 PCB-3 2.63e7 14.17 5.35e6 0% 11.0 12.0 ES-1 1.60e8 11.87 Rel. Int. 100% MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 5.83e3 13.0 (1.60e8 + 4.92e7) * 2000 pg RRF = = 1.09 (1.17e8 + 7.51e7) * 2000 pg DES 31-Mar-2014 07:37 14.0 15.0 0.00e0 16.0 RT Abs. Int. 6.41e7 ES-3 1.48e8 14.16 3.20e7 0% 11.0 12.0 13.0 ES-1 4.92e7 11.87 Rel. Int. 100% 14.0 15.0 Abs. Int. 1.99e7 ES-3 4.55e7 14.16 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.96e4 0.00e0 16.0 RT 9.94e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.57e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.28e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 9017, 6608 scc: 740-668 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 12:56 (DES) Printed: 31-Mar-2014 07:44 Page 2 of 21 85 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 Rel. Int. 100% Abs. Int. 2.13e7 PCB-10 6.45e7 14.61 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 4.70e3 PCB-4 3.94e7 14.43 1.07e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 1.37e7 PCB-10 4.06e7 14.61 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 6.74e3 PCB-4 2.48e7 14.43 6.86e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 6.74e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 2.26e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 6.33e3 1.13e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.19e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.38e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.92e3 6.91e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.57e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.28e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 8907, 5218 scc: 740-668 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 12:53 (DES) Printed: 31-Mar-2014 07:44 Page 3 of 21 86 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 5.36e3 PCB-9 6.21e7 16.40 PCB-7 7.06e7 PCB-6 16.57 6.59e7 16.80 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-14 7.89e7 18.77 PCB-5 6.63e7 17.10 PCB-8 6.67e7 17.22 PCB-11 6.81e7 19.55 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 13/12 1.36e8 19.84 Abs. Int. 2.27e7 PCB-15 7.06e7 20.13 1.13e7 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.22e4 PCB-9 3.79e7 16.40 PCB-7 4.30e7 PCB-6 16.57 4.04e7 16.79 18.0 19.0 PCB-14 4.82e7 18.77 PCB-5 4.05e7 PCB-8 17.10 4.05e7 17.22 20.0 PCB-11 4.16e7 19.55 13/12 8.28e7 19.84 21.0 Abs. Int. 1.38e7 PCB-15 4.32e7 20.13 6.92e6 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 1.17e8 16.39 20.0 21.0 ES-15 1.26e8 20.11 0.00e0 RT Abs. Int. 3.65e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 2.54e4 1.82e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 7.51e7 16.39 20.0 21.0 ES-15 8.04e7 20.11 0.00e0 RT Abs. Int. 2.36e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 7.69e3 1.18e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.38e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.69e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 8602, 7773 scc: 740-668 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:00 Printed: 31-Mar-2014 07:44 Page 4 of 21 87 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 30/18 8.06e7 19.27 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.02e3 PCB-19 2.91e7 17.51 PCB-17 3.44e7 19.67 PCB-27 4.70e7 19.86 PCB-24 4.48e7 19.99 PCB-16 2.56e7 20.09 Abs. Int. 2.21e7 PCB-32 4.99e7 20.57 1.10e7 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 7.70e7 19.27 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.24e3 PCB-19 2.78e7 17.51 PCB-17 3.28e7 19.67 21.0 Abs. Int. 2.13e7 PCB-24 4.29e7 19.99 PCB-27 4.48e7 19.86 PCB-16 2.43e7 20.09 PCB-32 4.77e7 20.57 1.06e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 2.20e7 ES-19 5.21e7 17.49 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.38e4 0.00e0 RT 1.10e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.04e7 ES-19 4.89e7 17.49 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.93e4 0.00e0 RT 1.02e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.38e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.69e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 0800, 1630 scc: 740-668 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 12:56 (DES) Printed: 31-Mar-2014 07:44 Page 5 of 21 88 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 28/20 9.50e7 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 8.82e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-23 PCB-34 4.80e7 4.76e7 21.87 21.72 26/29 9.71e7 22.15 PCB-31 5.08e7 22.63 Abs. Int. 2.24e7 PCB-39 5.14e7 25.17 PCB-36 5.03e7 24.85 PCB-22 4.56e7 23.47 PCB-38 4.64e7 25.70 PCB-35 4.51e7 26.09 PCB-37 4.68e7 26.45 0% 22.0 24.0 25.0 0.00e0 RT 26.0 28/20 9.44e7 22.91 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 6.90e3 23.0 PCB-23 PCB-34 4.74e7 4.66e7 21.87 21.72 26/29 9.62e7 22.15 PCB-31 5.05e7 22.63 Abs. Int. 2.23e7 PCB-39 5.09e7 25.17 PCB-36 4.93e7 24.85 PCB-22 4.50e7 23.47 PCB-38 4.55e7 25.70 PCB-35 4.46e7 26.09 PCB-37 4.63e7 26.45 23.0 24.0 25.0 26.0 CS/SS-28 8.63e7 22.88 Rel. Int. 100% 1.11e7 0.00e0 RT 0% 22.0 1.12e7 ES-37 7.89e7 26.43 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 5.70e4 Abs. Int. 2.35e7 1.17e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 7.89e7 22.88 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 7.20e7 26.43 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.50e4 Abs. Int. 2.19e7 1.10e7 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.09e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.05e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 5649, 2933 scc: 740-668 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:00 Printed: 31-Mar-2014 07:44 Page 6 of 21 89 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-54 2.88e7 20.42 Rel. Int. 100% Abs. Int. 7.84e6 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 7.71e2 3.92e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 3.59e7 20.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.76e6 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.00e3 4.88e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.41e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.19e7 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 3.21e3 5.95e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 5.61e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.55e7 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 3.05e3 7.74e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.38e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.69e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 6998, 2569 scc: 740-668 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:34 Printed: 31-Mar-2014 07:44 Page 7 of 21 90 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.45e3 50/53 5.12e7 22.40 PCB-51 2.48e7 23.06 PCB-45 2.32e7 22.99 PCB-73 3.30e7 PCB-52 24.65 2.48e7 24.52 PCB-46 2.04e7 23.27 69/49 6.08e7 24.94 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 44/47… 8.02e7 25.44 PCB-48 2.51e7 25.22 59/62… 1.04e8 25.72 71/40 5.09e7 26.31 PCB-42 2.26e7 25.88 PCB-41 2.09e7 26.22 Abs. Int. 1.93e7 PCB-64 3.68e7 26.51 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.45e3 50/53 6.47e7 22.40 24.0 PCB-51 3.14e7 23.06 PCB-45 2.96e7 22.99 25.0 PCB-73 4.20e7 PCB-52 24.65 3.16e7 24.52 PCB-46 2.58e7 23.27 69/49 7.69e7 24.94 PCB-48 3.18e7 25.22 59/62… 1.32e8 25.72 71/40 6.41e7 26.31 PCB-42 2.88e7 25.88 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.37e7 24.50 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 1.02e8 25.44 9.64e6 PCB-41 2.70e7 26.22 Abs. Int. 2.47e7 PCB-64 4.67e7 26.51 1.24e7 0.00e0 RT Abs. Int. 1.21e7 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 1.16e4 6.03e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 5.62e7 24.50 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 4.46e3 7.59e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.09e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.05e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 9257, 9535 scc: 740-668 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 12:57 (DES) Printed: 31-Mar-2014 07:44 Page 8 of 21 91 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.97-38.11 289.9224 Fn4 Flags: PBM 4σ 5.38e3 PCB-58 3.58e7 28.05 PCB-68 PCB-67 3.75e7 3.69e7 27.48 28.21 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 61/70... 1.39e8 28.73 PCB-55 3.31e7 29.16 PCB-60 PCB-80 3.34e7 3.85e7 29.79 30.11 PCB-79 3.86e7 31.43 PCB-78 3.20e7 31.92 PCB-81 3.32e7 32.30 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 Abs. Int. 1.74e7 (3.40e7 + 4.26e7) * 2000 pg RRF = = 1.20 (5.71e7 + 7.11e7) * 1000 pg PCB-77 DES 31-Mar-2014 07:36 3.40e7 32.78 8.72e6 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.11 291.9194 Fn4 Flags: PBM 4σ 6.38e3 PCB-68 4.73e7 27.48 61/70... 1.75e8 PCB-67 28.73 4.65e7 28.21 PCB-63 4.89e7 PCB-66 4.12e7 28.44 29.01 30.0 32.0 PCB-60 4.20e7 29.79 PCB-56 4.08e7 29.59 PCB-80 4.80e7 30.11 PCB-79 4.77e7 31.43 PCB-78 4.01e7 31.92PCB-81 4.14e7 32.30 34.0 36.0 Abs. Int. 2.17e7 PCB-77 4.26e7 32.78 1.09e7 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 5.57e7 32.28 TeCB Std. 26.97-38.11 301.9626 Fn4 Flags: PBM 4σ 9.77e3 0.00e0 38.0 RT 34.0 36.0 0.00e0 38.0 RT Abs. Int. 1.55e7 ES-77 5.71e7 32.76 7.75e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 6.99e7 32.28 TeCB Std. 26.97-38.11 303.9597 Fn4 Flags: PBM 4σ 9.32e3 34.0 36.0 0.00e0 38.0 RT Abs. Int. 1.94e7 ES-77 7.11e7 32.76 9.70e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.51e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.55e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 1236, 5295 scc: 740-668 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:00 Printed: 31-Mar-2014 07:44 Page 9 of 21 92 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-104 2.37e7 25.39 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 9.96e2 PCB-96 2.06e7 25.71 Abs. Int. 6.06e6 3.03e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 3.73e7 25.39 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 6.60e2 PCB-96 3.25e7 25.71 0.00e0 RT Abs. Int. 9.62e6 4.81e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 5.50e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.42e7 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.10e3 7.09e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 3.48e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.75e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.47e3 4.38e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.09e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.05e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 6365, 4523 scc: 740-668 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:34 Printed: 31-Mar-2014 07:44 Page 10 of 21 93 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 108/119... 1.22e8 31.46 Rel. Int. 100% PeCB-4 26.97-38.11 323.8834 Fn4 Flags: PBM 4σ 1.62e3 PCB-103 1.93e7 27.40 PCB-91 1.92e7 100/93 28.73 3.54e7 28.18 PCB-88 1.62e7 28.66 PCB-121 2.47e7 29.68 113/90… 6.00e7 30.48 116/85 3.64e7 32.09 PCB-99 1.87e7 31.01 PCB-111 PCB-120 2.50e7 2.54e7 32.80 33.19 107/124 PCB-118 2.43e7 4.59e7 34.75 34.16 PCB-123 PCB-114 2.54e7 2.52e7 34.47 35.22 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 Abs. Int. 1.74e7 PCB-105 2.37e7 35.76 PCB-127 2.35e7 36.99 0% 28.0 30.0 32.0 108/119... 1.96e8 31.46 Rel. Int. 100% PeCB-4 26.97-38.11 325.8804 Fn4 Flags: PBM 4σ 2.53e3 34.0 PCB-94 2.65e7 27.59 100/93 5.78e7 28.18 PCB-91 3.08e7 28.73 PCB-89 2.54e7 29.34 113/90… 9.64e7 30.48 PCB-112 PCB-92 3.91e7 2.71e7 31.11 30.00 116/85 PCB-115 5.86e7 3.87e7 PCB-111 32.09 32.29 4.04e7 32.80 PCB-117 PCB-110 PCB-120 3.96e7 3.68e7 4.10e7 PCB-82 32.00 32.20 33.19 2.31e7 32.48 PCB-118 107/124 3.95e7 7.43e7 34.75 34.16 PCB-114 PCB-123 4.13e7 4.09e7 35.22 34.47 30.0 Rel. Int. 100% 32.0 CS/SS-111 6.78e7 32.77 JS-101 5.58e7 30.48 PeCB Std. 26.97-38.11 337.9207 Fn4 Flags: PBM 4σ 2.87e3 34.0 ES-118 ES-114 ES-123 6.51e7 6.75e7 6.67e7 34.73 35.20 34.45 0.00e0 38.0 RT 36.0 Abs. Int. 2.82e7 PCB-105 3.82e7 35.76 0% 28.0 8.72e6 36.0 ES-105 6.74e7 35.74 PCB-127 3.79e7 36.99 1.41e7 0.00e0 38.0 RT Abs. Int. 1.71e7 8.55e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.34e7 32.77 JS-101 3.51e7 30.48 PeCB Std. 26.97-38.11 339.9177 Fn4 Flags: PBM 4σ 2.75e3 34.0 ES-118 ES-114 4.27e7 ES-123 4.17e7 35.20 4.19e7 34.73 34.45 36.0 ES-105 4.25e7 35.74 0.00e0 38.0 RT Abs. Int. 1.11e7 5.53e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.51e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.55e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 2872, 0755 scc: 740-668 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 12:58 (DES) Printed: 31-Mar-2014 07:44 Page 11 of 21 94 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 Abs. Int. 5.70e6 PCB-126 2.32e7 38.37 PeCB-5 38.13-45.16 323.8834 Fn5 Flags: PBM 4σ 2.86e3 2.85e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 8.98e6 PCB-126 3.58e7 38.37 PeCB-5 38.13-45.16 325.8804 Fn5 Flags: PBM 4σ 3.80e3 4.49e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.41e7 ES-126 5.94e7 38.35 PeCB Std. 38.13-45.16 337.9207 Fn5 Flags: PBM 4σ 6.45e3 7.04e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 9.26e6 ES-126 3.85e7 38.35 PeCB Std. 38.13-45.16 339.9177 Fn5 Flags: PBM 4σ 5.59e3 4.63e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.30e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.65e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 6585, 0725 scc: 740-668 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:34 Printed: 31-Mar-2014 07:44 Page 12 of 21 95 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% PCB-150 PCB-155 3.52e7 3.76e7 30.64 30.34 HxCB-4 26.97-38.11 359.8415 Fn4 Flags: PBM 4σ 6.58e2 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 147/149 139/140 4.83e7 4.92e7 33.78 34.30 PCB-145 3.34e7 31.22 PCB-148 2.51e7 32.49 153/168 6.15e7 36.36 151/135 4.74e7 PCB-144 PCB-143 PCB-142 PCB-133 PCB-146 33.01 2.47e7 2.23e7 2.28e7 2.50e7 2.06e7 35.81 33.48 34.04 35.26 34.62 PCB-141 2.25e7 36.50 163/138… 7.46e7 37.42 PCB-164 PCB-160 3.09e7 3.01e7 37.13 37.56 0% 28.0 30.0 PCB-152 2.74e7 30.50 PCB-150 PCB-155 2.78e7 3.00e7 30.64 30.34 Rel. Int. 100% HxCB-4 26.97-38.11 361.8385 Fn4 Flags: PBM 4σ 7.39e2 32.0 PCB-145 2.62e7 31.22 PCB-148 1.96e7 32.49 34.0 30.0 163/138… 5.91e7 147/149 139/140 37.42 153/168 151/135 PCB-133 3.84e7 3.88e7 4.87e7 3.76e7 1.80e7 33.78 34.30 36.36 33.01 35.26 PCB-158 PCB-154 2.65e7 PCB-146 PCB-141 PCB-137 PCB-143 2.20e7 PCB-132 37.74 1.97e7 1.91e7 1.74e7 33.22 1.79e7 1.71e7 35.81 37.05 34.04 36.50 34.85 32.0 34.0 ES-155 6.03e7 30.32 Rel. Int. 100% 7.05e6 0.00e0 38.0 RT 36.0 36.0 ES-153 4.33e7 36.32 HxCB Std. 26.97-38.11 371.8817 Fn4 Flags: PBM 4σ 1.47e3 Abs. Int. 1.11e7 5.57e6 0.00e0 38.0 RT 0% 28.0 Abs. Int. 1.41e7 JS-138 3.85e7 37.38 Abs. Int. 1.46e7 7.32e6 0% 28.0 30.0 32.0 34.0 ES-155 4.88e7 30.32 Rel. Int. 100% ES-153 3.44e7 36.32 HxCB Std. 26.97-38.11 373.8788 Fn4 Flags: PBM 4σ 2.79e3 0.00e0 38.0 RT 36.0 Abs. Int. 1.21e7 JS-138 3.04e7 37.38 6.07e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.51e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.55e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 1851, 4601 scc: 740-668 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:00 Printed: 31-Mar-2014 07:44 Page 13 of 21 96 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.95e7 38.47 HxCB-5 38.13-45.16 359.8415 Fn5 Flags: PBM 4σ 5.26e3 PCB-162 PCB-159 3.03e7 39.52 3.01e7 39.29 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 156/157 5.75e7 40.91 Abs. Int. 1.13e7 PCB-169 2.97e7 43.62 PCB-167 3.20e7 39.93 5.67e6 0% 39.0 Rel. Int. 100% HxCB-5 38.13-45.16 361.8385 Fn5 Flags: PBM 4σ 5.57e3 128/166 4.03e7 38.47 PCB-162 PCB-159 2.45e7 39.52 2.46e7 39.28 40.0 41.0 42.0 43.0 44.0 45.0 156/157 4.69e7 40.91 Abs. Int. 9.12e6 PCB-169 2.38e7 43.62 PCB-167 2.62e7 39.93 4.56e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.06e8 40.89 Rel. Int. 100% ES-167 5.53e7 39.91 HxCB Std. 38.13-45.16 371.8817 Fn5 Flags: PBM 4σ 7.73e3 0.00e0 RT 0.00e0 RT Abs. Int. 1.95e7 ES-169 5.21e7 43.61 9.73e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 4.41e7 39.91 HxCB Std. 38.13-45.16 373.8788 Fn5 Flags: PBM 4σ 1.09e4 41.0 42.0 43.0 44.0 45.0 ES-156/157 8.31e7 40.89 0.00e0 RT Abs. Int. 1.50e7 ES-169 4.12e7 43.61 7.52e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.30e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.65e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 7125, 7718 scc: 740-668 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 12:59 (DES) Printed: 31-Mar-2014 07:44 Page 14 of 21 97 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% PCB-188 2.36e7 35.21 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-179 PCB-184 2.27e7 2.13e7 35.50 35.95 HpCB-4 30.00-38.11 393.8025 Fn4 Flags: PBM 4σ 7.85e2 PCB-186 2.17e7 36.65 Abs. Int. 5.84e6 PCB-178 1.57e7 37.77 2.92e6 0% 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 PCB-188 2.23e7 35.21 36.0 PCB-179 2.16e7 35.49 PCB-176 2.18e7 36.25 HpCB-4 30.00-38.11 395.7995 Fn4 Flags: PBM 4σ 5.58e2 37.0 PCB-186 2.04e7 36.65 38.0 0.00e0 RT Abs. Int. 5.47e6 PCB-178 1.47e7 37.77 2.74e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 4.07e7 35.19 Rel. Int. 100% Abs. Int. 1.00e7 HpCB Std. 30.00-38.11 405.8428 Fn4 Flags: PBM 4σ 1.24e3 CS/SS-178 2.48e7 37.75 5.02e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.80e7 35.19 Rel. Int. 100% CS/SS-178 2.32e7 37.75 4.57e6 0% 32.0 33.0 34.0 35.0 0.00e0 RT Abs. Int. 9.14e6 HpCB Std. 30.00-38.11 407.8398 Fn4 Flags: PBM 4σ 1.48e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e7 QC Check 30.00-38.11 330.9792 Fn4 Flags: - 7.55e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 1441, 4699 scc: 740-668 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:00 Printed: 31-Mar-2014 07:45 Page 15 of 21 98 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.13-45.16 393.8025 Fn5 Flags: PBM 4σ 4.91e3 PCB-183 2.25e7 39.07 PCB-182 PCB-185 PCB-175 2.22e7 2.08e7 2.03e7 38.72 39.16 38.32 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 180/193 4.68e7 42.04 171/173 3.52e7 PCB-181 40.17 PCB-177 2.00e7 1.72e7 39.99 39.64 PCB-172 1.84e7 41.52 PCB-191 2.59e7 42.37 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-170 1.83e7 43.14 Abs. Int. 8.05e6 PCB-190 2.57e7 43.59 4.03e6 0% 39.0 Rel. Int. 100% HpCB-5 38.13-45.16 395.7995 Fn5 Flags: PBM 4σ 4.77e3 PCB-182 2.10e7 38.72 PCB-183 PCB-187 2.14e7 2.06e7 39.07 38.55 40.0 41.0 42.0 180/193 4.45e7 42.04 171/173 3.35e7 PCB-181 40.17 PCB-177 1.93e7 1.66e7 39.99 39.64 PCB-172 1.74e7 41.52 43.0 PCB-191 2.48e7 42.37 PCB-170 1.74e7 43.14 44.0 45.0 Abs. Int. 7.60e6 PCB-190 2.44e7 43.59 3.80e6 0% 39.0 40.0 41.0 42.0 ES-180 3.79e7 42.05 Rel. Int. 100% 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 8.99e6 ES-170 3.25e7 43.12 HpCB-5 Std. 38.13-45.16 405.8428 Fn5 Flags: PBM 4σ 3.14e3 4.50e6 0% 39.0 40.0 41.0 42.0 ES-180 3.54e7 42.05 Rel. Int. 100% 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.52e6 ES-170 3.03e7 43.12 HpCB-5 Std. 38.13-45.16 407.8398 Fn5 Flags: PBM 4σ 4.90e3 4.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.30e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.65e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 2117, 3569 scc: 740-668 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 12:59 (DES) Printed: 31-Mar-2014 07:45 Page 16 of 21 99 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-189 2.79e7 45.75 Abs. Int. 6.70e6 HpCB-6 45.18-50.15 393.8025 Fn6 Flags: PBM 4σ 2.53e3 3.35e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.63e7 45.75 Abs. Int. 6.36e6 HpCB-6 45.18-50.15 395.7995 Fn6 Flags: PBM 4σ 1.86e3 3.18e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 5.03e7 45.73 0.00e0 RT Abs. Int. 1.21e7 HpCB Std. 45.18-50.15 405.8428 Fn6 Flags: PBM 4σ 5.55e3 6.06e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.88e7 45.73 0.00e0 RT Abs. Int. 1.17e7 HpCB Std. 45.18-50.15 407.8398 Fn6 Flags: PBM 4σ 3.82e3 5.85e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.69e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 8.46e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 5572, 2288 scc: 740-668 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:00 Printed: 31-Mar-2014 07:45 Page 17 of 21 100 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-201 2.09e7 40.53 PCB-202 1.83e7 39.75 OcCB-5 38.13-45.16 427.7635 Fn5 Flags: PBM 4σ 5.33e2 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-197 1.99e7 PCB-204 41.29 PCB-200 1.95e7 1.97e7 41.11 41.38 198/199 2.71e7 43.71 Abs. Int. 5.17e6 PCB-196 1.44e7 44.28 PCB-203 1.52e7 44.45 2.59e6 0% 39.0 40.0 PCB-201 2.27e7 40.53 PCB-202 2.01e7 39.75 Rel. Int. 100% 41.0 OcCB-5 38.13-45.16 429.7606 Fn5 Flags: PBM 4σ 8.44e2 42.0 43.0 PCB-197 2.20e7 PCB-204 41.29 PCB-200 2.14e7 2.16e7 41.11 41.38 44.0 45.0 198/199 2.96e7 43.71 0.00e0 RT Abs. Int. 5.50e6 PCB-196 1.59e7 44.28 PCB-203 1.66e7 44.45 2.75e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.65e7 39.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.79e6 OcCB Std. 38.13-45.16 439.8038 Fn5 Flags: PBM 4σ 1.29e3 4.40e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.97e7 39.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.47e6 OcCB Std. 38.13-45.16 441.8008 Fn5 Flags: PBM 4σ 1.19e3 4.74e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.30e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.65e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 7409, 2275 scc: 740-668 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:00 (DES) Printed: 31-Mar-2014 07:45 Page 18 of 21 101 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.18-50.15 427.7635 Fn6 Flags: PBM 4σ 2.57e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-194 1.46e7 47.51 PCB-195 1.30e7 45.57 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-205 1.87e7 47.91 Abs. Int. 4.42e6 2.21e6 0% 46.0 Rel. Int. 100% OcCB-6 45.18-50.15 429.7606 Fn6 Flags: PBM 4σ 2.37e3 47.0 48.0 PCB-194 1.60e7 47.51 PCB-195 1.44e7 45.57 49.0 50.0 PCB-205 2.06e7 47.91 0.00e0 RT Abs. Int. 4.87e6 2.43e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.83e7 47.49 OcCB Std. 45.18-50.15 439.8038 Fn6 Flags: PBM 4σ 2.90e3 49.0 50.0 ES-205 3.56e7 47.89 0.00e0 RT Abs. Int. 8.25e6 4.13e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 3.20e7 47.49 OcCB Std. 45.18-50.15 441.8008 Fn6 Flags: PBM 4σ 3.95e3 49.0 50.0 ES-205 4.03e7 47.89 0.00e0 RT Abs. Int. 9.26e6 4.63e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.69e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 8.46e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 3711, 4774 scc: 740-668 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:00 Printed: 31-Mar-2014 07:45 Page 19 of 21 102 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.18-50.15 461.7245 Fn6 Flags: PBM 4σ 1.52e3 PCB-208 1.89e7 45.37 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-207 2.02e7 46.15 Abs. Int. 4.88e6 PCB-206 1.31e7 49.37 2.44e6 0% 46.0 Rel. Int. 100% NoCB 45.18-50.15 463.7216 Fn6 Flags: PBM 4σ 3.10e3 PCB-208 2.44e7 45.37 47.0 48.0 49.0 50.0 PCB-207 2.57e7 46.15 Abs. Int. 6.08e6 PCB-206 1.67e7 49.37 3.04e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 3.47e7 45.35 50.0 0.00e0 RT Abs. Int. 8.37e6 ES-206 2.41e7 49.35 NoCB Std. 45.18-50.15 473.7648 Fn6 Flags: PBM 4σ 2.95e3 4.18e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 4.34e7 45.35 50.0 Abs. Int. 1.04e7 ES-206 3.00e7 49.35 NoCB Std. 45.18-50.15 475.7619 Fn6 Flags: PBM 4σ 2.86e3 0.00e0 RT 5.22e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.69e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 8.46e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 7482, 6139 scc: 740-668 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:00 Printed: 31-Mar-2014 07:45 Page 20 of 21 103 of 417 SGS-AP ID: CS3_140328_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 28-Mar-2014 17:00:58 User: LKB Datafile: 140328X07 PCB-209 2.06e7 50.81 Rel. Int. 100% Abs. Int. 4.41e6 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 6.57e2 2.21e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.74e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.73e6 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.36e2 1.87e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.82e7 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 8.13e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.06e3 4.06e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.24e7 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.95e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 8.67e2 3.47e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.62e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 8.09e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\CS3_140328_PCB_XB.utp_res, saved 31-Mar-2014 07:38 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 9325, 8553 scc: 740-668 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:00 (DES) Printed: 31-Mar-2014 07:45 Page 21 of 21 104 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.09e7 2.04e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 8.91e6 4.46e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 7.85e6 3.92e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.11 330.9792 Fn4 Flags: 0% Abs. Int. 1.43e7 7.15e6 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 Rel. Int. QC chk 100% 38.13-45.16 380.9760 Fn5 Flags: 0% Abs. Int. 8.84e6 4.42e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.18-50.15 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.58e6 7.92e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.49e6 7.44e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 scc: 100-145 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 31-Mar-2014 07:45 Page 1 of 21 105 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 7.28e3 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 2.53e3 3.64e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.86e3 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 3.09e3 2.93e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.98e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 6.07e3 9.90e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.66e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.49e4 8.29e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.09e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.04e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 8191, 3635 scc: 100-145 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 11:02 (LKB) Printed: 31-Mar-2014 07:45 Page 2 of 21 106 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 6.39e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 3.80e3 3.20e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.88e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 8.93e3 9.38e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.62e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 9.05e3 1.31e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.70e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.19e3 3.85e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.09e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.04e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 8745, 1583 scc: 100-145 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 11:02 (LKB) Printed: 31-Mar-2014 07:45 Page 3 of 21 107 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 8.44e3 DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PB 4σ 3.58e3 4.22e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e4 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PB 4σ 9.31e3 2.05e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e5 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PB 4σ 2.48e4 5.06e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e4 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PB 4σ 8.19e3 6.77e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.91e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.46e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 3957, 9782 scc: 100-145 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 11:02 (LKB) Printed: 31-Mar-2014 07:45 Page 4 of 21 108 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 6.12e3 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PB 4σ 3.11e3 3.06e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.88e3 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PB 4σ 2.36e3 2.44e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.81e6 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PB 4σ 4.63e4 1.40e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.21e5 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PB 4σ 1.96e4 1.60e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.91e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.46e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 1154, 2640 scc: 100-145 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 11:04 Printed: 31-Mar-2014 07:45 Page 5 of 21 109 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-36 7.36e5 24.84 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 3.43e3 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Abs. Int. 1.87e5 SBS spiked with PCBs 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 128, 184, 182, 204 9.36e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-36 7.40e5 24.84 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.74e5 TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 1.95e3 8.69e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e6 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PB 4σ 4.41e4 5.31e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e5 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PB 4σ 1.92e4 6.36e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.85e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.92e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 2585, 7799 scc: 100-145 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 11:04 Printed: 31-Mar-2014 07:45 Page 6 of 21 110 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 2.75e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 1.14e3 1.38e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.06e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 1.45e3 2.53e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.12e3 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PB 4σ 3.80e3 4.06e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.69e3 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PB 4σ 2.31e3 2.85e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.91e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.46e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 3502, 5001 scc: 100-145 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 11:02 (LKB) Printed: 31-Mar-2014 07:45 Page 7 of 21 111 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 3.90e3 TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PB 4σ 9.92e2 1.95e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PB 4σ 1.44e3 2.36e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e4 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PB 4σ 6.98e3 7.20e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e4 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PB 4σ 3.95e3 6.77e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.85e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.92e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 1821, 9939 scc: 100-145 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 11:04 Printed: 31-Mar-2014 07:45 Page 8 of 21 112 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 5.38e5 27.21 PCB-79 5.39e5 31.43 TeCB-4 26.97-38.11 289.9224 Fn4 Flags: PBM 4σ 1.74e3 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Abs. Int. 1.44e5 PCB-78 4.65e5 31.92 7.20e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 6.48e5 27.21 32.0 PCB-79 6.52e5 31.42 TeCB-4 26.97-38.11 291.9194 Fn4 Flags: PBM 4σ 2.28e3 34.0 36.0 0.00e0 38.0 RT Abs. Int. 1.74e5 PCB-78 6.10e5 31.92 8.69e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.94e4 TeCB Std. 26.97-38.11 301.9626 Fn4 Flags: PB 4σ 7.71e3 9.69e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.17e4 TeCB Std. 26.97-38.11 303.9597 Fn4 Flags: PB 4σ 5.59e3 5.85e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.43e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.15e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 3600, 8807 scc: 100-145 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:11 (DES) Printed: 31-Mar-2014 07:45 Page 9 of 21 113 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 PCB-96 3.18e5 25.70 Rel. Int. 100% Abs. Int. 7.92e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 7.62e2 3.96e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 4.83e5 25.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e5 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 8.86e2 5.87e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.67e3 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PB 4σ 1.39e3 2.34e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.03e3 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PB 4σ 1.27e3 2.52e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.85e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.92e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 8852, 5619 scc: 100-145 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:11 (DES) Printed: 31-Mar-2014 07:45 Page 10 of 21 114 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.97-38.11 323.8834 Fn4 Flags: PBM 4σ 8.91e2 PCB-98 2.45e5 28.35 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 3.31e5 34.15 PCB-89 2.58e5 29.33 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Abs. Int. 8.76e4 PCB-106 3.46e5 34.58 4.38e4 0% 28.0 Rel. Int. 100% PCB-98 4.30e5 28.35 PeCB-4 26.97-38.11 325.8804 Fn4 Flags: PBM 4σ 1.10e3 30.0 32.0 34.0 107/124 5.43e5 34.15 PCB-89 3.96e5 29.33 36.0 0.00e0 38.0 RT Abs. Int. 1.34e5 PCB-106 5.21e5 34.58 6.71e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 7.18e3 PeCB Std. 26.97-38.11 337.9207 Fn4 Flags: PB 4σ 1.59e3 3.59e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 7.66e3 PeCB Std. 26.97-38.11 339.9177 Fn4 Flags: PB 4σ 2.06e3 3.83e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.43e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.15e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 3511, 3984 scc: 100-145 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:11 Printed: 31-Mar-2014 07:45 Page 11 of 21 115 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 5.36e3 PeCB-5 38.13-45.16 323.8834 Fn5 Flags: PB 4σ 9.35e2 2.68e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.87e3 PeCB-5 38.13-45.16 325.8804 Fn5 Flags: PB 4σ 1.25e3 3.94e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.26e3 PeCB Std. 38.13-45.16 337.9207 Fn5 Flags: PB 4σ 1.39e3 2.63e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.32e3 PeCB Std. 38.13-45.16 339.9177 Fn5 Flags: PB 4σ 1.99e3 3.16e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.84e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.42e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 6564, 9216 scc: 100-145 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 11:04 Printed: 31-Mar-2014 07:45 Page 12 of 21 116 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 PCB-152 5.33e5 30.49 Rel. Int. 100% Abs. Int. 1.23e5 HxCB-4 26.97-38.11 359.8415 Fn4 Flags: PBM 4σ 8.34e2 6.17e4 0% 28.0 30.0 32.0 34.0 36.0 PCB-152 4.37e5 30.49 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.05e5 HxCB-4 26.97-38.11 361.8385 Fn4 Flags: PBM 4σ 8.51e2 5.26e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 6.73e3 HxCB Std. 26.97-38.11 371.8817 Fn4 Flags: PB 4σ 1.40e3 3.37e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 8.59e3 HxCB Std. 26.97-38.11 373.8788 Fn4 Flags: PB 4σ 1.91e3 4.29e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.43e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.15e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 1046, 3088 scc: 100-145 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 11:04 Printed: 31-Mar-2014 07:46 Page 13 of 21 117 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Abs. Int. 1.14e5 128/166 4.46e5 38.46 HxCB-5 38.13-45.16 359.8415 Fn5 Flags: PBM 4σ 9.51e2 5.72e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.92e4 128/166 3.67e5 38.46 HxCB-5 38.13-45.16 361.8385 Fn5 Flags: PBM 4σ 1.22e3 4.46e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.56e3 HxCB Std. 38.13-45.16 371.8817 Fn5 Flags: PB 4σ 1.87e3 4.78e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.53e3 HxCB Std. 38.13-45.16 373.8788 Fn5 Flags: PB 4σ 1.88e3 4.77e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.84e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.42e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 5129, 0375 scc: 100-145 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 11:04 Printed: 31-Mar-2014 07:46 Page 14 of 21 118 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 PCB-184 3.26e5 35.95 Rel. Int. 100% Abs. Int. 8.41e4 HpCB-4 30.00-38.11 393.8025 Fn4 Flags: PBM 4σ 7.60e2 4.21e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 3.10e5 35.95 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.61e4 HpCB-4 30.00-38.11 395.7995 Fn4 Flags: PBM 4σ 6.71e2 3.80e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.31e3 HpCB Std. 30.00-38.11 405.8428 Fn4 Flags: PB 4σ 1.60e3 2.15e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.47e3 HpCB Std. 30.00-38.11 407.8398 Fn4 Flags: PB 4σ 1.36e3 2.24e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e7 QC Check 30.00-38.11 330.9792 Fn4 Flags: - 7.15e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 3884, 4161 scc: 100-145 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 11:02 (LKB) Printed: 31-Mar-2014 07:46 Page 15 of 21 119 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 PCB-182 3.49e5 38.72 Abs. Int. 8.50e4 HpCB-5 38.13-45.16 393.8025 Fn5 Flags: PBM 4σ 1.02e3 4.25e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 3.25e5 38.72 0.00e0 RT Abs. Int. 7.91e4 HpCB-5 38.13-45.16 395.7995 Fn5 Flags: PBM 4σ 9.60e2 3.95e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.11e3 HpCB-5 Std. 38.13-45.16 405.8428 Fn5 Flags: PB 4σ 1.78e3 4.56e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.85e3 HpCB-5 Std. 38.13-45.16 407.8398 Fn5 Flags: PB 4σ 1.81e3 2.93e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.84e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.42e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 9976, 5886 scc: 100-145 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:11 (DES) Printed: 31-Mar-2014 07:46 Page 16 of 21 120 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 2.72e3 HpCB-6 45.18-50.15 393.8025 Fn6 Flags: PB 4σ 1.01e3 1.36e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.71e3 HpCB-6 45.18-50.15 395.7995 Fn6 Flags: PB 4σ 6.91e2 1.35e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.67e3 HpCB Std. 45.18-50.15 405.8428 Fn6 Flags: PB 4σ 1.55e3 4.34e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.01e3 HpCB Std. 45.18-50.15 407.8398 Fn6 Flags: PB 4σ 1.16e3 3.01e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 7.92e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 3943, 2319 scc: 100-145 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 11:04 Printed: 31-Mar-2014 07:46 Page 17 of 21 121 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 PCB-204 3.06e5 41.10 Rel. Int. 100% Abs. Int. 8.25e4 OcCB-5 38.13-45.16 427.7635 Fn5 Flags: PBM 4σ 9.33e2 4.13e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 3.35e5 41.10 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.95e4 OcCB-5 38.13-45.16 429.7606 Fn5 Flags: PBM 4σ 9.15e2 3.98e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.93e3 OcCB Std. 38.13-45.16 439.8038 Fn5 Flags: PB 4σ 1.55e3 3.97e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e3 OcCB Std. 38.13-45.16 441.8008 Fn5 Flags: PB 4σ 1.40e3 2.85e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.84e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.42e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 0735, 1992 scc: 100-145 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 11:02 (LKB) Printed: 31-Mar-2014 07:46 Page 18 of 21 122 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 2.23e3 OcCB-6 45.18-50.15 427.7635 Fn6 Flags: PB 4σ 5.55e2 1.11e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.72e3 OcCB-6 45.18-50.15 429.7606 Fn6 Flags: PB 4σ 9.08e2 8.61e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.80e3 OcCB Std. 45.18-50.15 439.8038 Fn6 Flags: PB 4σ 8.35e2 2.40e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.95e3 OcCB Std. 45.18-50.15 441.8008 Fn6 Flags: PB 4σ 1.07e3 1.98e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 7.92e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 8649, 1248 scc: 100-145 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 11:02 (LKB) Printed: 31-Mar-2014 07:46 Page 19 of 21 123 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 2.53e3 NoCB 45.18-50.15 461.7245 Fn6 Flags: PB 4σ 1.08e3 1.27e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.39e3 NoCB 45.18-50.15 463.7216 Fn6 Flags: PB 4σ 2.18e3 2.69e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.46e3 NoCB Std. 45.18-50.15 473.7648 Fn6 Flags: PB 4σ 1.04e3 1.73e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.92e3 NoCB Std. 45.18-50.15 475.7619 Fn6 Flags: PB 4σ 1.07e3 2.46e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 7.92e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 6158, 8602 scc: 100-145 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 11:04 Printed: 31-Mar-2014 07:46 Page 20 of 21 124 of 417 SGS-AP ID: SBS_140328_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 28-Mar-2014 18:50:44 User: LKB Datafile: 140328X09 Rel. Int. 100% Abs. Int. 2.51e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: PB 4σ 5.58e2 1.25e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.17e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: PB 4σ 7.66e2 1.09e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.38e3 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PB 4σ 8.59e2 1.69e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.45e3 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PB 4σ 8.74e2 3.22e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.49e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 7.44e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\SBS_140328_PCB_XC.utp_res, saved 30-Mar-2014 13:11 (DES) AP UltraTrace-Pro V4.81 User/System: DE/US0008026 cc: 7735, 4837 scc: 100-145 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 11:04 Printed: 31-Mar-2014 07:46 Page 21 of 21 Resolution Check Report Printed: 125 of 417 Page 1 of 5 MassLynx 4.1 SCN 881 Friday, March 28, 2014 17:00:55 Eastern Daylight Time M 180.9888 R 12019 M 204.9888 R 14278 180.9 M 218.9856 R 12284 204.9 1.00e0 x17 M 230.9856 R 12681 218.9 1.00e0 x17 230.9 1.00e0 x17 1.00e0 x17 0.450 0.026 0.475 0.700 0.425 0.450 0.024 0.650 0.400 0.425 0.022 0.600 0.500 0.018 0.450 0.016 0.400 0.375 0.400 0.020 0.550 0.375 0.350 0.350 0.325 0.325 0.300 0.300 0.275 0.275 0.250 0.014 0.250 0.350 0.225 0.225 0.012 0.300 0.200 0.200 0.175 0.010 0.175 0.250 0.150 0.150 0.008 0.125 0.200 0.125 0.006 0.150 0.100 0.100 0.100 0.075 0.075 0.004 0.050 0.050 0.002 0.050 0.025 0.025 -0.000 -0.000 180.89 180.90 180.91 -0.000 180.92 204.87 M 242.9856 R 13090 204.88 204.89 218.86 M 218.9856 R 12726 242.9 -0.000 204.90 218.87 x17 218.89 230.85 M 230.9856 R 12376 218.9 1.00e0 218.88 230.86 230.87 M 242.9856 R 12565 230.9 1.00e0 x17 230.88 242.9 1.00e0 x17 1.00e0 x17 0.500 0.425 0.100 0.100 0.475 0.400 0.450 0.090 0.090 0.375 0.425 0.400 0.350 0.375 0.325 0.350 0.300 0.080 0.080 0.070 0.325 0.070 0.275 0.300 0.060 0.060 0.250 0.275 0.225 0.250 0.050 0.050 0.200 0.225 0.040 0.200 0.175 0.175 0.150 0.150 0.030 0.040 0.030 0.125 0.125 0.100 0.100 0.020 0.020 0.075 0.075 0.050 0.050 0.010 -0.000 242.84 242.85 242.86 242.87 -0.000 242.88 218.88 M 254.9856 R 13968 0.010 0.025 0.025 -0.000 218.89 218.90 218.91 M 268.9824 R 12322 254.9 -0.000 218.92 230.87 230.88 230.89 x17 230.91 242.86 M 280.9824 R 11932 268.9 1.00e0 230.90 242.87 242.88 x17 242.90 M 292.9824 R 12588 280.9 1.00e0 242.89 292.8 1.00e0 x17 0.260 1.00e0 x17 0.075 0.160 0.040 0.240 0.150 0.140 0.035 0.070 0.065 0.220 0.060 0.130 0.200 0.120 0.030 0.055 0.180 0.110 0.025 0.050 0.100 0.160 0.090 0.140 0.045 0.040 0.080 0.020 0.120 0.035 0.070 0.030 0.100 0.060 0.015 0.025 0.080 0.050 0.020 0.040 0.010 0.060 0.015 0.030 0.040 0.005 0.010 0.020 0.020 0.010 -0.000 -0.000 254.85 254.86 254.87 254.88 254.89 0.005 -0.000 268.84 268.85 268.86 268.87 268.88 280.83 280.84 280.85 280.86 280.87 280.88 -0.000 292.82 292.83 292.84 292.85 292.86 292.87 Resolution Check Report Printed: 126 of 417 Page 2 of 5 MassLynx 4.1 SCN 881 Friday, March 28, 2014 17:00:55 Eastern Daylight Time M 304.9824 R 12792 M 242.9856 R 12477 304.8 M 254.9856 R 13497 242.9 1.00e0 x17 M 268.9824 R 12562 254.9 1.00e0 x17 268.9 1.00e0 x17 0.032 1.00e0 x17 0.170 0.045 0.110 0.030 0.160 0.028 0.100 0.150 0.040 0.140 0.026 0.090 0.024 0.130 0.035 0.120 0.080 0.022 0.030 0.020 0.110 0.070 0.100 0.018 0.025 0.060 0.090 0.016 0.080 0.014 0.050 0.020 0.070 0.012 0.040 0.060 0.015 0.010 0.050 0.030 0.008 0.040 0.010 0.006 0.020 0.030 0.004 0.005 0.020 -0.000 -0.000 0.010 0.002 0.010 -0.000 -0.000 304.82 304.83 304.84 304.85 304.86 304.87 242.88 M 280.9824 R 12954 242.89 242.90 242.91 242.92 254.87 M 292.9824 R 12501 280.9 254.88 254.89 x17 254.91 268.86 M 304.9824 R 12919 292.9 1.00e0 254.90 268.87 x17 268.89 268.90 M 316.9824 R 13838 304.9 1.00e0 268.88 316.8 1.00e0 x17 0.260 1.00e0 x17 0.018 0.090 0.045 0.017 0.240 0.085 0.016 0.080 0.220 0.040 0.015 0.075 0.014 0.200 0.070 0.035 0.013 0.065 0.180 0.012 0.060 0.030 0.160 0.011 0.055 0.140 0.050 0.010 0.025 0.009 0.045 0.120 0.040 0.100 0.008 0.020 0.007 0.035 0.030 0.080 0.006 0.015 0.005 0.025 0.060 0.020 0.004 0.010 0.003 0.015 0.040 0.010 0.002 0.005 0.020 0.001 0.005 -0.000 -0.000 280.85 280.86 280.87 280.88 -0.000 280.89 292.84 M 330.9792 R 12537 292.85 292.86 292.87 292.88 304.83 M 342.9792 R 12230 330.8 -0.000 292.89 304.84 304.85 x17 304.87 304.88 316.82 M 280.9824 R 12626 342.8 1.00e0 0.130 304.86 316.83 316.84 316.85 x17 0.050 316.88 292.9 1.00e0 x17 0.280 0.120 316.87 M 292.9824 R 12205 280.9 1.00e0 316.86 1.00e0 x17 0.085 0.080 0.260 0.045 0.110 0.075 0.240 0.070 0.040 0.220 0.100 0.065 0.090 0.200 0.035 0.060 0.180 0.080 0.055 0.030 0.050 0.160 0.070 0.045 0.025 0.140 0.060 0.040 0.120 0.035 0.020 0.050 0.040 0.015 0.100 0.030 0.080 0.025 0.030 0.020 0.060 0.010 0.015 0.020 0.040 0.010 0.005 0.010 0.020 -0.000 -0.000 330.81 330.82 330.83 330.84 330.85 330.86 330.87 0.005 -0.000 342.81 342.82 342.83 342.84 342.85 342.86 342.87 -0.000 280.86 280.87 280.88 280.89 280.90 280.91 292.85 292.86 292.87 292.88 292.89 292.90 Resolution Check Report Printed: 127 of 417 Page 3 of 5 MassLynx 4.1 SCN 881 Friday, March 28, 2014 17:00:55 Eastern Daylight Time M 304.9824 R 13580 M 316.9824 R 13240 304.9 M 330.9792 R 12594 316.9 1.00e0 x17 M 342.9792 R 12437 330.8 1.00e0 x17 342.8 1.00e0 x17 1.00e0 x17 0.060 0.040 0.017 0.150 0.016 0.140 0.015 0.035 0.055 0.130 0.050 0.014 0.120 0.045 0.013 0.030 0.110 0.012 0.040 0.100 0.011 0.025 0.035 0.090 0.010 0.009 0.080 0.008 0.070 0.030 0.020 0.025 0.007 0.060 0.015 0.006 0.050 0.020 0.040 0.015 0.005 0.010 0.004 0.030 0.003 0.005 0.010 0.020 0.002 0.005 0.010 0.001 -0.000 -0.000 304.84 304.85 304.86 304.87 304.88 304.89 -0.000 316.83 M 366.9792 R 13454 316.84 316.85 316.86 316.87 316.88 330.82 M 380.9760 R 12537 366.8 -0.000 316.89 330.83 330.84 330.85 x17 330.87 330.88 M 392.9760 R 12470 380.8 1.00e0 330.86 342.81 342.82 342.83 342.84 x17 342.87 404.8 1.00e0 x17 0.028 1.00e0 x17 0.020 0.016 0.075 0.019 0.026 0.015 342.86 M 404.9760 R 14323 392.8 1.00e0 342.85 0.070 0.018 0.024 0.014 0.017 0.065 0.013 0.016 0.022 0.060 0.015 0.012 0.020 0.055 0.014 0.011 0.050 0.018 0.045 0.016 0.013 0.010 0.012 0.009 0.011 0.040 0.014 0.008 0.010 0.035 0.009 0.012 0.007 0.008 0.030 0.006 0.010 0.007 0.025 0.005 0.006 0.008 0.020 0.004 0.005 0.006 0.003 0.015 0.002 0.010 0.004 0.003 0.004 0.002 0.001 0.005 0.002 -0.000 -0.000 380.78 -0.000 366.80 366.81 366.82 366.83 366.84 366.85 366.86 M 430.9728 R 12347 0.001 380.79 380.80 380.81 380.82 380.83 380.84 380.85 392.78 M 316.9824 R 13140 430.8 -0.000 392.79 392.80 392.81 x17 392.83 392.84 392.85 404.78 M 330.9792 R 12194 316.8 1.00e0 392.82 404.79 404.80 404.81 x17 404.83 404.84 404.85 M 342.9792 R 12954 330.8 1.00e0 404.82 342.8 1.00e0 x17 1.00e0 x17 0.160 0.065 0.032 0.150 0.020 0.060 0.030 0.140 0.028 0.018 0.055 0.130 0.026 0.050 0.120 0.016 0.024 0.110 0.022 0.045 0.014 0.100 0.040 0.020 0.090 0.012 0.018 0.035 0.080 0.016 0.010 0.030 0.070 0.014 0.060 0.008 0.012 0.025 0.050 0.010 0.020 0.006 0.040 0.008 0.015 0.030 0.004 0.006 0.010 0.020 0.004 0.002 0.005 0.010 0.002 -0.000 -0.000 430.78 430.79 430.80 430.81 430.82 430.83 430.84 430.85 -0.000 316.82 316.83 316.84 316.85 316.86 316.87 316.88 -0.000 330.81 330.82 330.83 330.84 330.85 330.86 342.80 342.81 342.82 342.83 342.84 342.85 342.86 Resolution Check Report Printed: 128 of 417 Page 4 of 5 MassLynx 4.1 SCN 881 Friday, March 28, 2014 17:00:55 Eastern Daylight Time M 366.9792 R 14037 M 380.9760 R 12693 366.8 M 392.9760 R 12788 380.8 1.00e0 x17 0.016 0.015 M 404.9760 R 13310 392.8 1.00e0 x17 404.8 1.00e0 0.090 0.036 0.085 0.034 0.080 0.032 0.014 0.075 0.030 0.013 0.070 0.028 0.012 0.065 0.026 0.011 0.060 0.024 0.055 0.022 0.050 0.020 0.045 0.018 0.040 0.016 0.035 0.014 0.030 0.012 0.025 0.010 0.020 0.008 0.015 0.006 0.010 0.004 0.005 0.002 x17 1.00e0 x17 0.024 0.022 0.020 0.018 0.016 0.010 0.009 0.014 0.008 0.012 0.007 0.010 0.006 0.008 0.005 0.004 0.003 0.002 0.006 0.004 0.002 0.001 -0.000 366.78 366.79 366.80 366.81 366.82 366.83 -0.000 380.76 366.84 M 430.9728 R 12233 -0.000 380.77 380.78 380.79 380.80 380.81 380.82 392.76 M 442.9728 R 13138 430.8 -0.000 380.83 392.77 392.78 392.79 x17 x17 404.75 404.76 404.77 404.78 404.79 404.80 404.81 404.82 M 392.9760 R 13123 392.8 1.00e0 x17 1.00e0 x17 0.100 0.040 0.019 0.040 392.82 380.8 1.00e0 0.020 0.045 392.81 M 380.9760 R 12502 442.8 1.00e0 0.050 392.80 0.095 0.018 0.090 0.017 0.085 0.016 0.080 0.015 0.075 0.014 0.070 0.013 0.065 0.012 0.060 0.011 0.055 0.010 0.050 0.009 0.045 0.008 0.040 0.007 0.035 0.006 0.030 0.005 0.025 0.004 0.020 0.003 0.015 0.035 0.030 0.035 0.030 0.025 0.020 0.015 0.010 0.025 0.020 0.015 0.010 0.005 0.005 0.002 0.001 0.005 -0.000 430.72 -0.000 -0.000 430.73 430.74 430.75 430.76 430.77 430.78 430.79 430.80 0.010 442.72 M 404.9760 R 15201 442.73 442.74 442.75 442.76 442.77 442.78 442.79 442.80 380.75 M 430.9728 R 12345 404.8 -0.000 380.76 380.77 380.78 x17 380.80 380.81 380.82 M 442.9728 R 13774 430.7 1.00e0 380.79 392.74 392.75 392.76 x17 392.78 392.79 392.80 392.81 M 454.9728 R 13447 442.7 1.00e0 392.77 454.7 1.00e0 x17 1.00e0 x17 0.026 0.017 0.045 0.022 0.024 0.020 0.040 0.016 0.015 0.022 0.014 0.018 0.020 0.035 0.013 0.016 0.018 0.012 0.030 0.011 0.016 0.014 0.010 0.014 0.025 0.012 0.009 0.012 0.010 0.008 0.020 0.007 0.010 0.008 0.006 0.015 0.008 0.005 0.006 0.006 0.010 0.004 0.004 0.003 0.004 0.002 0.005 0.002 0.002 -0.000 -0.000 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 0.001 -0.000 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 430.78 -0.000 442.69 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 454.68 454.69 454.70 454.71 454.72 454.73 454.74 454.75 454.76 Resolution Check Report Printed: 129 of 417 Page 5 of 5 MassLynx 4.1 SCN 881 Friday, March 28, 2014 17:00:55 Eastern Daylight Time M 466.9728 R 14208 M 480.9696 R 13335 466.7 M 430.9728 R 12771 480.7 1.00e0 x17 M 442.9728 R 13406 430.8 1.00e0 x17 442.8 1.00e0 x17 1.00e0 x17 0.036 0.060 0.034 0.010 0.024 0.032 0.055 0.022 0.009 0.030 0.050 0.020 0.028 0.008 0.045 0.026 0.018 0.024 0.007 0.040 0.016 0.022 0.006 0.035 0.020 0.014 0.018 0.030 0.005 0.012 0.016 0.025 0.014 0.004 0.012 0.003 0.010 0.020 0.008 0.015 0.006 0.010 0.004 0.010 0.008 0.002 0.006 0.004 0.001 0.005 0.002 0.002 -0.000 466.67 466.68 466.69 466.70 466.71 466.72 466.73 466.74 -0.000 480.65 466.75 M 454.9728 R 13157 -0.000 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 430.73 M 466.9728 R 15824 454.7 -0.000 480.74 430.74 430.75 430.76 x17 430.78 430.79 430.80 442.71 M 480.9696 R 12820 466.7 1.00e0 430.77 442.72 442.73 442.74 442.75 x17 442.77 442.78 442.79 M 492.9696 R 13700 480.7 1.00e0 0.012 442.76 492.7 1.00e0 x17 1.00e0 x17 0.020 0.034 0.018 0.019 0.032 0.011 0.017 0.018 0.030 0.016 0.017 0.010 0.028 0.015 0.009 0.014 0.013 0.016 0.026 0.015 0.024 0.014 0.008 0.012 0.013 0.022 0.011 0.012 0.007 0.020 0.011 0.010 0.018 0.006 0.010 0.009 0.016 0.008 0.005 0.009 0.014 0.008 0.012 0.007 0.010 0.006 0.007 0.004 0.006 0.005 0.003 0.005 0.008 0.004 0.004 0.006 0.002 0.003 0.003 0.004 0.002 0.002 0.001 0.001 -0.000 -0.000 454.70 454.71 454.72 454.73 454.74 454.75 454.76 454.77 454.78 466.69 M 504.9696 R 14063 466.70 466.71 466.72 466.73 466.74 466.75 466.76 466.77 466.78 M 516.9697 R 16349 504.7 516.7 1.00e0 x17 0.015 1.00e0 x17 0.009 0.014 0.008 0.013 0.012 0.007 0.011 0.010 0.006 0.009 0.005 0.008 0.007 0.004 0.006 0.005 0.003 0.004 0.002 0.003 0.002 0.001 0.001 -0.000 -0.000 504.66 504.67 504.68 504.69 504.70 504.71 504.72 504.73 504.74 504.75 516.65 516.66 516.67 516.68 516.69 516.70 516.71 516.72 516.73 516.74 0.002 0.001 -0.000 -0.000 480.68 480.69 480.70 480.71 480.72 480.73 480.74 480.75 480.76 492.67 492.68 492.69 492.70 492.71 492.72 492.73 492.74 492.75 Resolution Check Report Printed: 130 of 417 Page 1 of 5 MassLynx 4.1 SCN 881 Saturday, March 29, 2014 03:18:06 Eastern Daylight Time M 180.9888 R 11451 M 204.9888 R 14250 180.9 M 218.9856 R 12265 204.9 1.00e0 x17 M 230.9856 R 12112 218.9 1.00e0 x17 230.9 1.00e0 x17 0.014 0.425 0.400 1.00e0 x17 0.260 0.300 0.013 0.280 0.375 0.012 0.240 0.260 0.220 0.350 0.011 0.240 0.010 0.220 0.275 0.009 0.200 0.250 0.008 0.200 0.325 0.300 0.180 0.160 0.180 0.225 0.140 0.160 0.007 0.200 0.140 0.120 0.120 0.100 0.006 0.175 0.005 0.150 0.100 0.125 0.080 0.004 0.080 0.100 0.060 0.003 0.060 0.075 0.040 0.002 0.040 0.050 0.025 -0.000 180.89 180.90 0.001 0.020 -0.000 -0.000 180.91 204.87 M 242.9856 R 13631 204.88 204.89 204.90 M 218.9856 R 12537 242.9 0.020 218.85 218.86 218.87 x17 218.89 M 230.9856 R 12293 218.9 1.00e0 218.88 -0.000 230.84 230.85 230.86 x17 242.9 1.00e0 x17 1.00e0 0.260 0.065 0.240 0.060 0.220 0.055 0.200 0.050 0.180 0.045 0.180 0.160 0.040 0.160 0.140 0.035 0.120 0.030 0.100 0.025 0.080 0.020 0.060 0.015 0.060 230.88 M 242.9856 R 12997 230.9 1.00e0 0.300 230.87 x17 0.280 0.055 0.260 0.050 0.240 0.220 0.045 0.200 0.040 0.035 0.030 0.140 0.025 0.120 0.020 0.100 0.080 0.015 0.060 0.010 0.040 0.010 0.040 0.005 -0.000 242.84 242.85 242.86 0.020 0.020 0.005 -0.000 -0.000 -0.000 242.87 218.88 M 254.9856 R 13056 218.89 218.90 218.91 230.87 M 268.9824 R 12788 254.9 230.88 230.89 x17 242.86 M 280.9824 R 12746 268.9 1.00e0 230.90 242.87 242.88 x17 242.90 M 292.9824 R 12596 280.9 1.00e0 242.89 292.8 1.00e0 x17 1.00e0 x17 0.170 0.028 0.055 0.160 0.110 0.026 0.050 0.150 0.100 0.024 0.140 0.045 0.022 0.090 0.130 0.040 0.120 0.020 0.080 0.110 0.018 0.035 0.070 0.100 0.016 0.030 0.090 0.060 0.014 0.080 0.012 0.050 0.010 0.040 0.025 0.070 0.060 0.020 0.050 0.008 0.015 0.030 0.040 0.006 0.030 0.020 0.010 0.004 0.020 0.005 0.010 0.002 0.010 -0.000 -0.000 254.85 254.86 254.87 254.88 254.89 -0.000 268.84 268.85 268.86 268.87 268.88 -0.000 280.83 280.84 280.85 280.86 280.87 280.88 292.82 292.83 292.84 292.85 292.86 292.87 Resolution Check Report Printed: 131 of 417 Page 2 of 5 MassLynx 4.1 SCN 881 Saturday, March 29, 2014 03:18:06 Eastern Daylight Time M 304.9824 R 13778 M 242.9856 R 12740 304.8 M 254.9856 R 13175 242.9 1.00e0 x17 M 268.9824 R 12626 254.9 1.00e0 x17 268.9 1.00e0 x17 1.00e0 x17 0.110 0.022 0.028 0.065 0.100 0.020 0.026 0.060 0.024 0.055 0.018 0.090 0.022 0.050 0.016 0.080 0.020 0.045 0.070 0.014 0.018 0.040 0.016 0.012 0.060 0.035 0.014 0.010 0.050 0.030 0.012 0.025 0.008 0.040 0.010 0.020 0.008 0.006 0.015 0.030 0.006 0.020 0.004 0.010 0.004 0.005 0.002 0.010 0.002 -0.000 -0.000 304.82 304.83 304.84 304.85 304.86 -0.000 304.87 242.88 M 280.9824 R 13123 242.89 242.90 254.87 M 292.9824 R 12759 280.9 -0.000 242.91 254.88 254.89 x17 254.91 268.85 M 304.9824 R 13090 292.9 1.00e0 0.170 254.90 268.86 268.87 x17 268.89 268.90 M 316.9824 R 14926 304.9 1.00e0 268.88 316.8 1.00e0 x17 1.00e0 x17 0.055 0.013 0.160 0.024 0.050 0.150 0.012 0.022 0.140 0.011 0.045 0.020 0.130 0.010 0.040 0.120 0.018 0.009 0.110 0.035 0.016 0.008 0.100 0.014 0.030 0.090 0.007 0.080 0.012 0.025 0.006 0.070 0.010 0.005 0.020 0.060 0.008 0.050 0.004 0.015 0.040 0.006 0.003 0.010 0.030 0.004 0.002 0.020 0.005 0.002 0.001 -0.000 -0.000 -0.000 0.010 -0.000 280.84 280.85 280.86 280.87 280.88 280.89 292.84 M 330.9792 R 12953 292.85 292.86 292.87 292.88 304.83 M 342.9792 R 13026 330.8 304.84 304.85 x17 304.87 304.88 316.82 M 280.9824 R 13026 342.8 1.00e0 304.86 316.83 316.84 x17 316.86 316.87 M 292.9824 R 12540 280.9 1.00e0 316.85 292.9 1.00e0 x17 1.00e0 x17 0.170 0.034 0.085 0.160 0.050 0.032 0.080 0.150 0.030 0.075 0.045 0.140 0.028 0.070 0.130 0.026 0.040 0.065 0.120 0.024 0.060 0.035 0.110 0.022 0.055 0.100 0.020 0.030 0.050 0.090 0.018 0.045 0.016 0.080 0.014 0.070 0.012 0.060 0.010 0.050 0.020 0.008 0.040 0.015 0.006 0.030 0.010 0.004 0.020 0.005 0.002 0.010 0.040 0.035 0.025 0.020 0.030 0.025 0.015 0.010 0.005 -0.000 -0.000 330.81 330.82 330.83 330.84 330.85 330.86 -0.000 342.81 342.82 342.83 342.84 342.85 342.86 342.87 -0.000 280.86 280.87 280.88 280.89 280.90 280.91 292.85 292.86 292.87 292.88 292.89 292.90 Resolution Check Report Printed: 132 of 417 Page 3 of 5 MassLynx 4.1 SCN 881 Saturday, March 29, 2014 03:18:06 Eastern Daylight Time M 304.9824 R 14450 M 316.9824 R 15206 304.9 M 330.9792 R 12988 316.9 1.00e0 x17 M 342.9792 R 14388 330.8 1.00e0 x17 342.8 1.00e0 x17 1.00e0 x17 0.100 0.013 0.038 0.095 0.026 0.012 0.036 0.090 0.024 0.034 0.085 0.011 0.032 0.080 0.022 0.010 0.075 0.030 0.070 0.028 0.065 0.026 0.060 0.024 0.055 0.022 0.050 0.020 0.045 0.018 0.040 0.016 0.035 0.014 0.030 0.012 0.025 0.010 0.020 0.008 0.015 0.006 0.020 0.009 0.018 0.008 0.016 0.007 0.014 0.006 0.012 0.005 0.010 0.004 0.008 0.003 0.006 0.004 0.002 0.002 0.001 0.010 0.004 0.005 -0.000 -0.000 304.84 304.85 304.86 304.87 304.88 316.83 M 366.9792 R 16049 0.002 -0.000 304.89 316.84 316.85 316.86 316.87 330.82 M 380.9760 R 13311 366.8 -0.000 316.88 330.83 330.84 330.85 x17 330.87 342.81 M 392.9760 R 13780 380.8 1.00e0 330.86 342.82 342.83 342.84 x17 342.86 342.87 M 404.9760 R 15732 392.8 1.00e0 342.85 404.8 1.00e0 x17 1.00e0 x17 0.013 0.020 0.010 0.050 0.012 0.018 0.009 0.011 0.045 0.016 0.008 0.010 0.040 0.009 0.014 0.007 0.035 0.008 0.012 0.006 0.030 0.007 0.010 0.005 0.025 0.004 0.006 0.008 0.020 0.005 0.004 0.006 0.003 0.015 0.002 0.010 0.004 0.001 0.005 0.002 -0.000 -0.000 -0.000 0.003 0.002 366.79 366.80 366.81 366.82 366.83 366.84 366.85 366.86 M 430.9728 R 13476 0.001 380.78 380.79 380.80 380.81 380.82 380.83 380.84 380.85 392.78 M 316.9824 R 15004 430.8 -0.000 392.79 392.80 392.81 x17 0.024 392.83 392.84 392.85 x17 0.010 0.018 0.009 404.81 404.82 404.83 404.84 404.85 M 342.9792 R 12695 342.8 1.00e0 x17 0.085 0.011 404.80 1.00e0 x17 0.090 0.012 0.020 404.79 330.8 1.00e0 0.022 404.78 M 330.9792 R 12956 316.8 1.00e0 392.82 0.040 0.080 0.075 0.035 0.070 0.016 0.008 0.014 0.007 0.012 0.006 0.010 0.005 0.008 0.004 0.006 0.003 0.065 0.030 0.060 0.055 0.025 0.050 0.045 0.020 0.040 0.035 0.015 0.030 0.025 0.010 0.020 0.004 0.002 0.002 0.001 0.015 0.005 0.010 0.005 -0.000 430.77 -0.000 430.78 430.79 430.80 430.81 430.82 430.83 430.84 430.85 316.82 316.83 316.84 316.85 316.86 316.87 -0.000 330.80 330.81 330.82 330.83 330.84 330.85 330.86 -0.000 342.79 342.80 342.81 342.82 342.83 342.84 342.85 Resolution Check Report Printed: 133 of 417 Page 4 of 5 MassLynx 4.1 SCN 881 Saturday, March 29, 2014 03:18:06 Eastern Daylight Time M 366.9792 R 14768 M 380.9760 R 12595 366.8 M 392.9760 R 12988 380.8 1.00e0 x17 M 404.9760 R 13566 392.8 1.00e0 x17 404.8 1.00e0 x17 1.00e0 x17 0.024 0.011 0.015 0.055 0.022 0.010 0.014 0.050 0.020 0.013 0.009 0.045 0.018 0.040 0.016 0.035 0.014 0.030 0.012 0.025 0.010 0.020 0.008 0.015 0.006 0.010 0.004 0.001 0.005 0.002 -0.000 -0.000 -0.000 0.012 0.008 0.011 0.007 0.010 0.009 0.006 0.008 0.005 0.007 0.006 0.004 0.003 0.005 0.004 0.003 0.002 0.002 0.001 366.78 366.79 366.80 366.81 366.82 366.83 366.84 380.76 M 430.9728 R 13354 380.77 380.78 380.79 380.80 380.81 380.82 380.83 392.75 M 442.9728 R 14036 430.8 -0.000 392.76 392.77 392.78 x17 0.030 0.015 0.028 0.014 0.026 0.013 0.024 0.012 0.022 0.011 392.81 392.82 404.74 404.75 404.76 404.77 x17 404.78 404.79 404.80 404.81 M 392.9760 R 13737 380.8 1.00e0 0.016 392.80 M 380.9760 R 12756 442.8 1.00e0 0.032 392.79 392.8 1.00e0 x17 1.00e0 0.060 0.026 0.055 0.024 x17 0.022 0.050 0.020 0.045 0.018 0.040 0.020 0.010 0.018 0.009 0.016 0.008 0.014 0.007 0.016 0.035 0.014 0.030 0.012 0.025 0.012 0.010 0.006 0.020 0.010 0.005 0.008 0.004 0.006 0.003 0.008 0.015 0.006 0.010 0.004 0.004 0.002 0.002 0.001 -0.000 -0.000 430.72 430.73 430.74 430.75 430.76 430.77 430.78 430.79 430.80 442.72 M 404.9760 R 13890 442.73 442.74 442.75 442.76 442.77 442.78 442.79 0.002 -0.000 -0.000 442.80 380.75 M 430.9728 R 13827 404.8 0.005 380.76 380.77 380.78 x17 380.80 380.81 392.74 M 442.9728 R 16105 430.7 1.00e0 380.79 392.76 x17 392.77 392.78 392.79 392.80 M 454.9728 R 15475 442.7 1.00e0 454.7 1.00e0 x17 1.00e0 x17 0.014 0.034 0.016 392.75 0.018 0.032 0.015 0.013 0.017 0.030 0.016 0.014 0.028 0.012 0.015 0.013 0.011 0.026 0.014 0.024 0.013 0.022 0.012 0.020 0.011 0.012 0.010 0.011 0.009 0.010 0.008 0.009 0.010 0.018 0.008 0.007 0.009 0.016 0.008 0.007 0.006 0.014 0.007 0.006 0.005 0.012 0.006 0.005 0.010 0.004 0.005 0.004 0.008 0.004 0.003 0.006 0.002 0.004 0.002 0.001 0.002 0.001 -0.000 404.72 -0.000 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 0.003 0.003 0.002 0.001 -0.000 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 -0.000 442.69 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 454.68 454.69 454.70 454.71 454.72 454.73 454.74 454.75 454.76 Resolution Check Report Printed: 134 of 417 Page 5 of 5 MassLynx 4.1 SCN 881 Saturday, March 29, 2014 03:18:06 Eastern Daylight Time M 466.9728 R 17589 M 480.9696 R 13752 466.7 M 430.9728 R 13721 480.7 1.00e0 x17 M 442.9728 R 14097 430.8 1.00e0 x17 442.8 1.00e0 x17 1.00e0 x17 0.019 0.040 0.022 0.018 0.008 0.017 0.020 0.035 0.016 0.007 0.015 0.018 0.014 0.030 0.006 0.016 0.013 0.012 0.014 0.025 0.005 0.011 0.012 0.010 0.020 0.004 0.009 0.010 0.003 0.008 0.007 0.015 0.008 0.006 0.005 0.006 0.010 0.002 0.004 0.004 0.003 0.005 0.001 0.002 0.002 0.001 -0.000 -0.000 466.67 466.68 466.69 466.70 466.71 466.72 466.73 466.74 466.75 480.65 M 454.9728 R 15933 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 -0.000 430.72 480.74 M 466.9728 R 17198 454.7 -0.000 430.73 430.74 430.75 430.76 x17 430.78 430.79 430.80 442.71 M 480.9696 R 13549 466.7 1.00e0 442.72 442.73 442.74 x17 442.76 442.77 442.78 442.79 492.7 1.00e0 x17 0.022 0.012 442.75 M 492.9696 R 14213 480.7 1.00e0 0.009 0.013 430.77 1.00e0 x17 0.013 0.012 0.020 0.008 0.011 0.011 0.018 0.007 0.010 0.010 0.016 0.009 0.009 0.006 0.014 0.008 0.008 0.005 0.007 0.006 0.004 0.012 0.007 0.010 0.006 0.005 0.005 0.008 0.003 0.004 0.004 0.006 0.003 0.003 0.002 0.004 0.002 0.002 0.001 0.002 0.001 -0.000 -0.000 454.70 454.71 454.72 454.73 454.74 454.75 454.76 454.77 454.78 466.69 M 504.9696 R 15776 466.70 466.71 466.72 466.73 466.74 466.75 466.76 466.77 480.68 M 516.9697 R 16025 504.7 516.7 1.00e0 x17 1.00e0 x17 0.006 0.012 0.011 0.005 0.010 0.009 0.004 0.008 0.007 0.003 0.006 0.005 0.002 0.004 0.003 0.001 0.002 0.001 -0.000 504.65 -0.000 504.66 504.67 504.68 504.69 504.70 504.71 504.72 504.73 504.74 0.001 -0.000 516.65 516.66 516.67 516.68 516.69 516.70 516.71 516.72 516.73 516.74 480.69 480.70 480.71 480.72 480.73 480.74 480.75 480.76 -0.000 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 492.74 492.75 PCB ICAL PAGE RANGE: 135 TO 389 PCB ICAL Summary 135 of 417 Printed: 3 Jan 2014 16:53 SGS Analytical Perspectives ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 Date Processed: 3 Jan 2014 16:52 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB Mean 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 % RSD 4.1% 3.1% 5.1% 4.8% 4.2% 2.4% 5.8% 4.0% 4.0% 3.5% 5.0% 3.9% 131220X02 0.5 CS0 1.17 1.08 1.13 1.14 1.20 1.20 1.05 1.07 1.11 1.12 1.08 1.18 131220X03 1 CS1 1.11 1.13 1.02 1.16 1.13 1.20 1.07 1.07 1.13 1.07 1.00 1.10 131220X04 5 CS2 1.09 1.08 1.07 1.15 1.13 1.16 1.05 1.05 1.12 1.09 1.03 1.06 131220X05 50 CS3 1.14 1.12 1.13 1.23 1.22 1.23 1.12 1.12 1.20 1.16 1.07 1.09 131220X06 400 CS4 1.17 1.14 1.15 1.24 1.22 1.23 1.14 1.11 1.18 1.14 1.10 1.10 131220X08 2000 CS5 1.22 1.17 1.18 1.29 1.25 1.25 1.21 1.17 1.23 1.17 1.16 1.15 3.7% 2.3% 0.7% 1.1% 1.4% 1.8% 1.0% 1.8% 2.5% 1.7% 2.5% 2.3% 2.4% 1.2% 3.2% 1.4% 3.0% 2.0% 2.0% 2.3% 1.9% 3.6% 1.9% 1.1% 1.2% 0.9% 1.4% 1.25 1.12 0.52 1.04 0.50 1.69 0.86 1.38 1.37 0.82 1.22 1.24 1.19 1.19 1.07 1.14 1.66 1.60 1.68 1.54 0.92 1.11 0.97 1.61 0.96 1.24 0.83 1.22 1.09 0.52 1.04 0.50 1.64 0.86 1.37 1.35 0.80 1.21 1.22 1.17 1.20 1.02 1.11 1.60 1.57 1.65 1.53 0.93 1.10 0.93 1.57 0.96 1.23 0.82 1.21 1.10 0.53 1.05 0.51 1.68 0.88 1.42 1.36 0.82 1.25 1.26 1.19 1.20 1.07 1.13 1.63 1.63 1.71 1.58 0.96 1.13 0.96 1.60 0.99 1.26 0.85 1.18 1.06 0.52 1.02 0.50 1.61 0.85 1.34 1.32 0.80 1.18 1.19 1.13 1.16 0.99 1.10 1.56 1.56 1.62 1.51 0.95 1.11 0.92 1.57 0.97 1.24 0.83 1.17 1.08 0.52 1.05 0.51 1.66 0.86 1.38 1.38 0.79 1.18 1.21 1.14 1.19 1.01 1.11 1.56 1.64 1.70 1.60 0.95 1.16 0.93 1.57 0.97 1.25 0.83 1.13 1.06 0.53 1.05 0.52 1.69 0.85 1.40 1.42 0.78 1.17 1.19 1.14 1.18 1.01 1.10 1.52 1.61 1.65 1.58 0.97 1.21 0.93 1.58 0.97 1.25 0.82 PCB ICAL PAGE RANGE: 135 TO 389 PCB ICAL Summary 136 of 417 Printed: 3 Jan 2014 16:53 SGS Analytical Perspectives ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 131220X03 1 CS1 1.16 1.10 131220X04 5 CS2 1.20 1.14 131220X05 50 CS3 1.17 1.11 131220X06 400 CS4 1.18 1.11 131220X08 2000 CS5 1.19 1.08 Name ES PCB-208 ES PCB-209 Mean 1.17 1.11 % RSD 1.4% 1.9% 131220X02 0.5 CS0 1.16 1.12 SS PCB-28 SS PCB-111 SS PCB-178 1.11 1.03 0.62 1.2% 1.6% 2.7% 1.12 1.04 0.64 1.12 1.02 0.61 1.11 1.03 0.61 1.12 1.05 0.61 1.11 1.00 0.61 1.09 1.03 0.64 CS PCB-28 CS PCB-111 CS PCB-178 1.85 1.22 0.58 1.4% 1.4% 3.7% 1.89 1.24 0.62 1.84 1.22 0.57 1.86 1.23 0.58 1.81 1.22 0.56 1.84 1.19 0.57 1.83 1.21 0.60 PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-153/168 ...-HxCB PCB-155 22'44'66'-HxCB PCB-170 22'33'44'5-HpCB PCB-180/193 ...-HpCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.46 1.26 1.14 1.26 1.27 1.05 1.06 1.12 1.11 3.4% 2.9% 3.8% 3.8% 2.5% 4.7% 2.1% 1.5% 3.7% 2.3% 6.1% 2.7% 3.1% 3.2% 4.0% 3.8% 3.0% 0.99 1.00 1.17 1.01 1.13 1.02 1.40 1.44 1.38 1.23 1.09 1.26 1.23 1.05 1.07 1.09 1.09 0.94 0.98 1.20 0.98 1.12 1.05 1.34 1.41 1.42 1.25 1.06 1.22 1.32 1.05 1.03 1.11 1.11 0.92 0.98 1.20 0.98 1.12 1.05 1.31 1.40 1.43 1.23 1.09 1.23 1.22 1.00 1.01 1.07 1.08 0.97 1.04 1.27 1.03 1.17 1.10 1.36 1.45 1.48 1.27 1.15 1.27 1.26 1.06 1.06 1.13 1.11 0.98 1.05 1.27 1.04 1.16 1.10 1.35 1.45 1.50 1.29 1.19 1.27 1.28 1.06 1.07 1.14 1.12 0.91 1.00 1.29 1.08 1.19 1.16 1.36 1.46 1.53 1.29 1.24 1.31 1.31 1.10 1.13 1.19 1.18 137 of 417 PCB ICAL Summary - Ax2 Detail SGS Analytical Perspectives Printed: 3 Jan 2014 16:53 ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB Mean 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 % RSD 3.4% 3.8% 2.9% 3.8% 3.9% 2.8% 5.7% 4.5% 4.8% 3.2% 3.9% 4.5% 6.8% 3.8% 2.5% 3.5% 4.4% 3.6% 3.4% 4.3% 2.4% 3.0% 4.1% 3.0% 2.6% 3.3% 3.6% 3.3% 2.8% 4.4% 4.1% 3.7% 4.6% 4.7% 2.1% 2.7% 5.4% 5.9% 2.5% 1.7% 0.5 CS0 0.99 1.02 1.00 1.17 1.91 0.93 0.95 0.97 1.03 1.07 1.14 0.98 0.88 1.01 1.13 1.49 1.23 1.77 1.67 0.99 1.90 1.11 1.20 1.15 1.13 1.25 1.13 1.15 1.08 1.13 1.18 1.07 1.01 1.02 1.40 0.89 0.78 0.80 0.70 0.85 1 CS1 0.94 1.01 0.98 1.20 1.90 0.95 1.03 0.94 0.92 0.99 1.14 0.95 0.96 0.98 1.12 1.47 1.28 1.76 1.69 0.94 1.91 1.09 1.09 1.14 1.14 1.16 1.08 1.14 1.05 1.12 1.16 1.08 0.98 1.05 1.34 0.85 0.76 0.82 0.68 0.83 5 CS2 0.92 0.98 0.98 1.20 1.93 0.90 1.02 0.96 0.96 1.00 1.15 0.99 0.97 0.98 1.12 1.51 1.27 1.77 1.67 1.00 1.85 1.11 1.10 1.13 1.13 1.19 1.08 1.13 1.04 1.13 1.16 1.06 1.00 1.05 1.31 0.84 0.70 0.89 0.68 0.82 50 CS3 0.97 1.08 1.04 1.27 2.05 0.96 1.09 1.03 1.02 1.04 1.20 1.03 1.02 1.03 1.17 1.57 1.33 1.83 1.74 1.00 1.93 1.15 1.18 1.20 1.18 1.26 1.17 1.21 1.09 1.19 1.24 1.14 1.08 1.10 1.36 0.90 0.74 0.93 0.72 0.86 400 CS4 0.98 1.08 1.05 1.27 2.04 0.96 1.08 1.03 1.02 1.03 1.21 1.04 1.03 1.04 1.16 1.59 1.34 1.87 1.73 1.05 1.93 1.18 1.19 1.21 1.18 1.24 1.17 1.21 1.10 1.21 1.25 1.16 1.07 1.10 1.35 0.89 0.78 0.88 0.71 0.85 2000 CS5 0.91 1.02 1.00 1.29 2.06 0.97 1.11 1.05 1.05 1.07 1.25 1.07 1.07 1.08 1.19 1.60 1.38 1.92 1.83 1.06 1.99 1.16 1.17 1.21 1.18 1.25 1.17 1.21 1.12 1.24 1.27 1.11 1.10 1.16 1.36 0.89 0.83 0.84 0.71 0.85 138 of 417 PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB 1.11 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 1.16 4.0% 4.5% 3.4% 3.5% 3.3% 3.7% 2.8% 4.3% 3.9% 3.9% 2.1% 2.7% 2.6% 2.9% 1.9% 3.1% 2.4% 3.3% 2.3% 2.9% 1.8% 2.3% 2.5% 4.2% 1.5% 4.7% 2.7% 3.3% 3.9% 3.5% 6.3% 8.5% 11.9% 10.7% 4.5% 3.8% 3.2% 2.3% 2.4% 4.0% 6.0% 3.9% 3.2% 6.9% 6.2% 6.3% 4.4% 1.13 0.68 0.99 0.83 0.89 1.13 0.76 0.68 0.84 1.17 1.19 1.26 1.18 1.17 1.23 1.30 1.20 1.06 1.09 1.13 1.13 1.30 1.26 1.04 1.44 1.12 0.91 0.79 0.89 0.84 0.97 0.73 0.96 0.76 0.71 0.73 1.18 0.82 0.98 0.77 0.88 1.12 0.98 1.02 1.02 1.09 1.18 1.06 0.68 0.98 0.79 0.88 1.13 0.73 0.66 0.82 1.18 1.18 1.24 1.11 1.13 1.25 1.26 1.16 1.06 1.10 1.05 1.12 1.29 1.33 0.99 1.41 1.24 0.91 0.76 0.80 0.83 0.93 0.68 0.72 0.95 0.66 0.74 1.15 0.81 0.96 0.70 0.88 1.12 0.94 1.15 0.87 1.07 1.11 1.06 0.72 0.99 0.83 0.86 1.13 0.75 0.69 0.83 1.18 1.19 1.24 1.16 1.15 1.23 1.24 1.16 1.09 1.12 1.10 1.11 1.28 1.28 1.04 1.40 1.20 0.91 0.79 0.85 0.85 0.99 0.71 0.73 0.94 0.70 0.75 1.16 0.79 0.96 0.71 0.88 1.16 0.95 1.15 0.88 1.06 1.16 1.12 0.77 1.05 0.87 0.93 1.21 0.79 0.73 0.87 1.27 1.25 1.31 1.20 1.20 1.29 1.33 1.23 1.14 1.14 1.13 1.15 1.35 1.31 1.10 1.45 1.26 0.96 0.83 0.89 0.88 1.03 0.80 0.74 1.04 0.75 0.80 1.23 0.84 1.00 0.72 0.91 1.24 1.01 1.17 0.94 1.25 1.10 1.12 0.72 1.05 0.85 0.93 1.22 0.77 0.68 0.90 1.25 1.22 1.31 1.16 1.19 1.27 1.32 1.22 1.14 1.12 1.12 1.14 1.32 1.35 1.08 1.45 1.28 0.95 0.81 0.87 0.90 0.87 0.86 0.85 0.95 0.73 0.78 1.23 0.83 1.01 0.70 0.98 1.17 1.02 1.09 0.99 1.11 1.16 1.17 0.70 1.06 0.87 0.93 1.18 0.78 0.73 0.89 1.28 1.23 1.30 1.17 1.23 1.28 1.34 1.21 1.13 1.15 1.13 1.16 1.34 1.32 1.11 1.46 1.27 0.95 0.82 0.89 0.89 1.02 0.77 0.78 1.03 0.74 0.79 1.24 0.84 1.01 0.69 1.00 1.18 0.97 1.25 0.95 1.13 1.24 139 of 417 PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 3.4% 2.9% 4.3% 4.7% 8.6% 3.3% 4.1% 5.5% 2.3% 4.1% 3.7% 6.5% 3.0% 4.0% 2.4% 3.1% 3.1% 3.5% 4.3% 3.3% 3.3% 2.7% 4.9% 2.0% 2.8% 1.5% 3.4% 3.6% 3.7% 2.5% 1.8% 5.1% 5.4% 4.0% 2.3% 2.4% 5.7% 3.3% 5.3% 3.1% 1.6% 2.7% 1.7% 1.5% 3.8% 4.2% 4.0% 0.69 1.23 1.18 1.07 1.26 1.12 0.97 1.09 1.23 1.16 1.18 1.01 1.13 1.14 1.11 1.38 1.22 1.12 0.97 1.07 1.20 1.02 0.96 1.03 1.13 1.41 1.19 1.50 1.38 1.10 0.97 1.19 1.35 1.18 1.49 1.69 0.86 1.09 1.03 1.23 1.19 1.14 1.21 1.14 0.88 1.02 1.08 0.67 1.17 1.14 1.03 1.05 1.08 0.96 1.04 1.25 1.12 1.10 0.98 1.09 1.14 1.13 1.29 1.12 1.15 0.90 1.10 1.16 1.02 0.92 1.01 1.11 1.39 1.16 1.44 1.42 1.05 0.95 1.14 1.48 1.15 1.48 1.64 0.86 1.11 1.01 1.32 1.16 1.09 1.22 1.11 0.80 1.05 1.12 0.67 1.19 1.18 1.07 1.26 1.04 0.95 1.03 1.23 1.13 1.15 1.04 1.06 1.16 1.12 1.30 1.17 1.16 0.88 1.14 1.17 0.98 0.97 1.01 1.09 1.40 1.17 1.50 1.43 1.07 0.96 1.10 1.52 1.14 1.49 1.62 0.85 1.07 1.03 1.22 1.13 1.10 1.22 1.10 0.82 1.05 1.11 0.70 1.25 1.24 1.14 1.33 1.12 1.01 1.11 1.27 1.16 1.20 1.09 1.12 1.19 1.14 1.33 1.19 1.18 0.89 1.18 1.20 1.03 1.01 1.03 1.13 1.42 1.19 1.54 1.48 1.10 0.97 1.10 1.58 1.17 1.55 1.63 0.91 1.13 1.11 1.26 1.17 1.13 1.25 1.14 0.84 1.08 1.15 0.72 1.23 1.25 1.12 1.26 1.13 1.02 1.12 1.29 1.23 1.21 1.12 1.14 1.23 1.16 1.37 1.20 1.21 0.96 1.12 1.24 1.04 1.03 1.03 1.16 1.39 1.24 1.55 1.50 1.10 0.98 1.22 1.51 1.23 1.56 1.67 0.93 1.12 1.10 1.28 1.16 1.13 1.24 1.12 0.84 1.10 1.17 0.73 1.26 1.28 1.17 1.36 1.14 1.06 1.19 1.29 1.23 1.22 1.16 1.16 1.25 1.18 1.38 1.20 1.23 0.94 1.16 1.27 1.06 1.06 1.06 1.17 1.44 1.26 1.60 1.53 1.12 1.00 1.24 1.55 1.27 1.52 1.72 0.98 1.17 1.15 1.31 1.15 1.17 1.26 1.14 0.88 1.15 1.21 140 of 417 PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 4.7% 3.5% 9.3% 4.3% 2.6% 4.9% 5.3% 3.7% 5.1% 2.7% 2.6% 6.1% 5.4% 3.2% 3.2% 2.5% 5.1% 5.6% 3.2% 2.8% 2.5% 4.3% 3.5% 4.0% 3.8% 3.1% 3.0% 1.09 1.16 0.95 0.93 0.93 1.03 0.90 0.96 1.17 1.26 1.41 1.09 1.63 1.05 1.16 1.10 1.26 1.03 0.80 0.84 0.87 0.79 0.88 1.07 1.09 1.20 1.09 1.14 1.18 1.03 1.04 0.94 1.07 0.90 0.97 1.27 1.22 1.40 1.06 1.58 1.05 1.22 1.13 1.16 1.04 0.79 0.80 0.85 0.74 0.82 1.03 1.11 1.16 1.11 1.16 1.21 0.99 0.96 0.93 1.04 0.92 0.95 1.28 1.23 1.33 1.09 1.58 1.00 1.19 1.08 1.11 1.12 0.78 0.82 0.85 0.73 0.81 1.01 1.07 1.14 1.08 1.22 1.28 1.03 1.00 0.95 1.11 0.97 1.02 1.32 1.27 1.40 1.15 1.66 1.06 1.24 1.12 1.15 1.16 0.80 0.84 0.88 0.75 0.84 1.06 1.13 1.20 1.11 1.21 1.18 1.15 0.98 0.96 1.12 0.98 1.00 1.32 1.27 1.40 1.19 1.69 1.06 1.27 1.12 1.21 1.12 0.82 0.84 0.88 0.77 0.85 1.07 1.14 1.20 1.12 1.23 1.22 1.21 1.03 0.99 1.17 1.03 1.04 1.36 1.31 1.44 1.24 1.82 1.10 1.24 1.16 1.26 1.17 0.86 0.87 0.91 0.82 0.88 1.13 1.19 1.24 1.18 1668A/B ICALs Air Historica Data Ax RSD Mean sd 77 10.6 1.04 0.11 1.11 1.13 1.34 81 9.6 1.08 0.10 1.13 1.13 1.13 105 4.6 0.96 0.04 1.11 1.09 1.15 1.11 2.1 1.11 0.02 114 4.9 0.96 0.05 1.18 1.16 1.22 1.2 2.1 1.19 0.02 118 6.8 0.95 0.06 1.11 1.11 1.17 1.19 3.7 1.15 0.04 123 3.9 0.97 0.04 1.08 1.19 1.27 1.21 6.5 1.19 0.08 126 8.6 1.00 0.09 1.07 1.06 1.12 1.11 2.9 1.09 0.03 156/157 6.4 0.99 0.06 1.09 1.11 1.18 1.1 3.7 1.12 0.04 167 5.8 0.98 0.06 1.14 1.14 1.23 1.16 3.8 1.17 0.04 169 4.5 0.97 0.04 1.09 1.11 1.19 1.12 3.7 1.13 0.04 189 14.7 0.95 0.14 1.07 1.06 1.09 1.07 1.3 1.07 0.01 1 9.3 1.16 0.11 1.02 1.03 0.93 0.95 5.1 0.98 0.05 3 9.5 1.16 0.11 0.98 1.04 0.97 1.01 3.4 1.00 0.03 141 of 417 MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd 1.15 8.8 1.18 0.10 1.12 0.4 1.13 0.00 4 4.7 1.03 0.05 1.11 1.17 1.13 1.23 4.5 1.16 0.05 15 11.8 1.02 0.12 0.99 1.08 1.05 1.02 3.9 1.03 0.04 19 4.7 1.04 0.05 1.10 1.09 1.10 1.15 2.3 1.11 0.03 37 12.1 1.06 0.13 1.00 1.10 1.05 1.08 4.2 1.06 0.04 54 104 4.3 1.06 0.05 1.18 1.21 1.24 1.35 6.0 1.25 0.07 5.4 1.01 0.05 1.11 1.25 1.31 1.43 10.2 1.28 0.13 1.19 1.22 1.38 1.46 9.8 1.31 0.13 1.08 1.09 1.22 1.26 7.8 1.16 0.09 170 1.06 1.07 1.11 1.14 3.3 1.09 0.04 180 188 1.08 1.16 1.21 1.26 6.6 1.18 0.08 4.2 1.02 0.04 1.03 1.03 1.01 1.27 11.4 1.09 0.12 202 3.0 0.91 0.03 0.93 0.91 0.97 1.05 6.4 0.97 0.06 205 5.4 0.96 0.05 1.07 1.09 1.11 1.06 1.8 1.08 0.02 208 2.3 0.93 0.02 1.02 1.02 1.07 1.12 4.7 1.06 0.05 206 3.2 0.97 0.03 0.99 0.98 0.92 1.11 7.9 1.00 0.08 209 7.0 0.95 0.07 1.07 1.07 1.13 1.11 2.6 1.10 0.03 1 6.7 1.01 0.07 1.08 1.08 1.20 1.19 6.0 1.14 0.07 3 5.5 1.02 0.06 1.14 1.08 1.14 1.09 2.7 1.11 0.03 153 155 3.2 1.02 0.03 PD from Mean -4.3% 0.1% -1.9% -2.4% -3.4% 0.2% -2.6% -1.2% -2.8% -1.5% -1.4% 4.9% 4.4% 0.8% 4.5% -1.7% 4.3% -3.0% -1.7% -7.0% -6.2% -1.9% -1.6% -4.8% -5.3% 0.6% -3.8% -2.2% -2.1% ES 4 10.0 0.69 0.07 0.50 0.49 0.57 0.52 6.8 0.52 0.04 15 4.2 1.06 0.04 1.18 1.11 1.07 1.04 5.5 1.10 0.06 19 6.3 0.62 0.04 0.53 0.55 0.57 0.51 4.8 0.54 0.03 37 10.4 1.36 0.14 1.64 1.64 1.55 1.66 2.9 1.62 0.05 54 7.3 1.18 0.09 0.87 0.94 0.86 0.86 4.4 0.88 0.04 77 11.1 1.23 0.14 1.26 1.35 1.11 1.38 9.6 1.27 0.12 81 9.4 1.19 0.11 1.20 1.29 1.26 1.37 5.6 1.28 0.07 104 8.0 1.33 0.11 1.08 0.99 0.89 0.8 13.2 0.94 0.12 105 4.1 1.27 0.05 1.22 1.23 1.23 1.2 1.2 1.22 0.02 114 4.2 1.31 0.05 1.24 1.25 1.24 1.22 1.0 1.24 0.01 118 5.3 1.31 0.07 1.28 1.28 1.26 1.16 4.6 1.24 0.06 123 3.9 1.24 0.05 1.35 1.22 1.21 1.19 5.9 1.24 0.07 126 6.7 1.30 0.09 1.22 1.20 1.09 1.03 7.9 1.14 0.09 1.10 1.14 1.15 1.11 2.1 1.13 0.02 153 155 7.0 1.42 0.10 1.41 1.50 1.56 1.59 5.1 1.51 0.08 156/157 7.7 1.22 0.09 1.41 1.45 1.59 1.6 6.4 1.51 0.10 167 7.6 1.25 0.09 1.43 1.49 1.68 1.67 8.1 1.57 0.13 169 8.1 1.23 0.10 1.37 1.40 1.42 1.56 5.8 1.44 0.08 170 1.04 1.00 0.93 0.95 5.1 0.98 0.05 180 1.28 1.16 1.12 1.14 6.3 1.17 0.07 188 8.5 1.27 0.11 1.12 1.18 1.23 0.94 11.4 1.12 0.13 189 7.8 1.52 0.12 1.53 1.49 1.46 1.58 3.5 1.51 0.05 202 6.6 1.18 0.08 1.07 1.14 1.10 0.97 6.7 1.07 0.07 205 3.9 1.27 0.05 1.26 1.20 1.22 1.24 2.0 1.23 0.02 206 11.3 0.97 0.11 0.90 0.87 0.95 0.83 5.9 0.89 0.05 208 10.2 1.27 0.13 1.22 1.19 1.19 1.17 1.7 1.19 0.02 MM7 Comparing ICAL RRFs 20DEC2013.xlsx -5.0% -2.7% -6.0% 0.8% 2.3% 0.8% 6.5% 5.7% 0.7% 5.6% 1.1% 0.7% 3.0% -2.0% 5.6% 1.3% -1.2% -3.9% -4.6% -2.4% 2.1% -1.3% 5.3% -1.8% 6.4% -2.2% -2.1% -0.2% 1668A/B ICALs Air Historica Data Ax RSD Mean sd 209 8.3 1.20 0.10 142 of 417 MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 1.06 1.00 1.12 1.11 PD from Mean RSD Mean sd 5.1 1.07 0.06 -6.8% 0.8% 0.2% 3.1% SS 28 3.6 1.05 0.04 0.98 1.07 1.10 1.11 5.6 1.07 0.06 111 4.0 1.05 0.04 0.90 1.01 1.08 1.03 7.5 1.00 0.07 178 3.9 0.71 0.03 0.62 0.63 0.57 0.62 4.4 0.61 0.03 Additional Ax RSD Mean sd PCB-1 2-MoCB 1.02 1.03 0.93 0.95 5.1 0.98 0.05 PCB-2 3-MoCB 0.97 1.04 0.97 1.03 3.7 1.00 0.04 PCB-3 4-MoCB 0.98 1.04 0.97 1.01 3.4 1.00 0.03 PCB-4 22'-DiCB 1.11 1.17 1.13 1.23 4.5 1.16 0.05 PCB-10 26-DiCB 1.71 1.83 1.75 1.98 6.5 1.82 0.12 PCB-9 25-DiCB 0.83 0.89 0.90 0.95 5.7 0.89 0.05 PCB-7 24-DiCB 0.95 1.02 1.02 1.05 4.3 1.01 0.04 PCB-6 23'-DiCB 0.89 0.95 0.96 1.00 4.7 0.95 0.04 PCB-5 23-DiCB 0.89 0.97 0.97 1.00 4.7 0.96 0.05 PCB-8 24'-DiCB 0.93 0.98 1.00 1.03 4.3 0.99 0.04 PCB-14 35-DiCB 1.07 1.16 1.15 1.18 4.2 1.14 0.05 PCB-11 33'-DiCB 0.94 1.00 0.99 1.01 3.3 0.98 0.03 PCB-13/12 34'-/34-DiCB 0.95 1.02 0.99 0.99 2.8 0.99 0.03 PCB-15 44'-DiCB 0.99 1.08 1.05 1.02 3.9 1.03 0.04 0.03 PCB-19 22'6-TrCB 1.10 1.09 1.10 1.15 2.3 1.11 PCB-30/18 246-/22'5-TrCB 1.48 1.46 1.45 1.54 2.6 1.48 0.04 PCB-17 22'4-TrCB 1.28 1.25 1.26 1.31 2.0 1.28 0.03 PCB-27 23'6-TrCB 1.70 1.69 1.68 1.82 3.8 1.72 0.07 PCB-24 236-TrCB 1.63 1.63 1.60 1.72 3.1 1.65 0.05 PCB-16 22'3-TrCB 0.97 0.95 0.96 1.01 2.6 0.97 0.03 PCB-32 24'6-TrCB 1.81 1.79 1.84 1.92 3.1 1.84 0.06 PCB-34 2'35-TrCB 0.98 1.05 1.04 1.14 6.4 1.05 0.07 PCB-23 235-TrCB 0.98 1.06 1.07 1.16 6.9 1.07 0.07 PCB-26/29 23'5-/245-TrCB 1.00 1.09 1.07 1.17 6.3 1.08 0.07 PCB-25 23'4-TrCB 0.99 1.07 1.09 1.16 6.5 1.08 0.07 PCB-31 24'5-TrCB 1.03 1.11 1.13 1.23 7.2 1.13 0.08 PCB-28/20 244'-/233'-TrCB 0.98 1.07 1.06 1.13 5.6 1.06 0.06 PCB-21/33 234-/2'34-TrCB 1.01 1.09 1.08 1.17 6.0 1.09 0.06 PCB-22 234'-TrCB 0.93 1.02 1.00 1.08 6.0 1.01 0.06 PCB-36 33'5-TrCB 1.03 1.13 1.09 1.17 5.4 1.10 0.06 PCB-39 34'5-TrCB 1.10 1.17 1.13 1.21 4.1 1.15 0.05 PCB-38 345-TrCB 0.95 1.03 1.02 1.10 5.9 1.02 0.06 PCB-35 33'4-TrCB 0.96 1.04 1.00 1.04 4.0 1.01 0.04 PCB-37 344'-TrCB 1.00 1.10 1.05 1.08 4.2 1.06 0.04 PCB-54 22'66'-TeCB 1.18 1.21 1.24 1.35 6.0 1.25 0.07 PCB-50/53 22'46-/22'56'TeCB 0.85 0.86 0.88 0.88 2.0 0.87 0.02 PCB-45 22'36-TeCB 0.75 0.73 0.76 0.77 2.2 0.75 0.02 PCB-51 22'46'-TeCB 0.85 0.88 0.91 0.86 3.2 0.87 0.03 PCB-46 22'36'-TeCB 0.68 0.70 0.71 0.70 1.6 0.70 0.01 PCB-52 22'55'-TeCB 0.82 0.84 0.86 0.84 2.0 0.84 0.02 PCB-73 23'5'6TeCB 1.10 1.09 1.13 1.11 1.4 1.11 0.02 0.03 PCB-43 22'35-TeCB 0.66 0.72 0.72 0.71 4.5 0.70 PCB-69/49 23'46-/22'45'TeCB 1.00 1.01 1.05 1.02 2.1 1.02 0.02 PCB-48 22'45-TeCB 0.83 0.85 0.87 0.84 1.7 0.85 0.01 0.01 PCB-44/47/65 22'35'-/22'44'- 0.88 0.89 0.91 0.90 1.5 0.90 PCB-59/62/75 233'6-/2346-/24 1.12 1.14 1.18 1.17 2.4 1.15 0.03 PCB-42 22'34'-TeCB 0.77 0.76 2.9 0.78 0.02 0.77 0.81 MM7 Comparing ICAL RRFs 20DEC2013.xlsx PCB-41 22'34-TeCB 0.72 0.73 0.71 0.69 2.2 0.71 0.02 PCB-71/40 23'4'6/22'33'-TeCB 0.85 0.87 0.88 0.86 1.5 0.86 0.01 PCB-64 234'6-TeCB 1.21 1.24 1.26 1.22 1.7 1.23 0.02 PD from Historical Mean 4.9% 3.8% 4.4% 0.8% 0.7% 0.4% 1.4% -0.2% 1.4% -0.2% 1.5% 1.7% 3.2% 4.5% -1.7% -1.6% -1.9% -1.8% -0.7% -2.1% -2.8% -0.3% -0.8% 0.3% -0.3% -1.3% 0.7% 0.3% 0.8% 2.1% 1.2% 0.7% 3.2% 4.3% -3.0% -1.1% -2.8% 0.6% -0.3% 0.3% -1.5% 3.0% -0.8% 0.4% -0.8% -1.2% -0.8% 2.1% 0.2% 0.5% 1668A/B ICALs Air Historica Data Ax RSD 143 of 417 Mean sd MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd PCB-72 23'55'-TeCB 1.13 1.14 1.17 1.21 3.0 1.16 0.03 PCB-68 23'45'-TeCB 1.21 1.21 1.26 1.28 2.8 1.24 0.04 PCB-57 233'5-TeCB 1.10 1.11 1.12 1.16 2.3 1.12 0.03 PCB-58 233'5-TeCB 1.11 1.10 1.16 1.18 3.4 1.14 0.04 PCB-67 23'45-TeCB 1.15 1.16 1.20 1.26 4.2 1.19 0.05 PCB-63 234'5-TeCB 1.22 1.22 1.25 1.30 3.1 1.25 0.04 PCB-61/70/74/76 2345-/23'4'5 1.13 1.13 1.17 1.20 2.8 1.16 0.03 PCB-66 23'44'-TeCB 1.06 1.08 1.10 1.10 1.7 1.09 0.02 PCB-55 233'4-TeCB 1.09 1.10 1.11 1.12 1.3 1.10 0.01 PCB-56 233'4'-TeCB 1.05 1.06 1.07 1.11 2.4 1.07 0.03 PCB-60 2344'-TeCB 1.12 1.11 1.15 1.14 1.5 1.13 0.02 PCB-80 33'55'-TeCB 1.26 1.25 1.27 1.31 2.1 1.27 0.03 PCB-79 33'45'-TeCB 1.26 1.23 1.28 1.31 2.6 1.27 0.03 PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6-/22'356-P PCB-102 22'456'-PeCB PCB-98 22'3'46-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 233'5'6-/22'3 PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125/87 233 PCB-117 234'56-PeCB PCB-116/85 23456-/22'344'-Pe PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 233'4'5-/2'3455' PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 2'33'45-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'HxCB PCB-148 22'34'56'-HxCB PCB-151/135 22'355'6-/22'33' PCB-154 22'44'5'6-HxCB PCB-144 22'345'6-HxCB PCB-147/149 22'34'56-/22'34' PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 22'344'6-/22'344' PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB 1.09 1.08 1.05 1.06 1.6 1.07 0.02 1.11 1.25 1.31 1.43 10.2 1.28 0.13 0.98 1.08 1.12 1.23 9.5 1.10 0.10 0.80 0.90 0.95 0.93 7.2 0.90 0.06 0.70 0.78 0.81 0.80 6.6 0.77 0.05 0.75 0.83 0.88 0.87 7.5 0.83 0.06 0.76 0.84 0.90 0.86 6.9 0.84 0.06 0.82 0.90 0.98 0.97 8.1 0.92 0.07 0.69 0.77 0.80 0.76 5.9 0.76 0.04 0.67 0.79 0.77 0.80 7.8 0.76 0.06 0.84 0.88 1.00 0.94 7.5 0.91 0.07 0.65 0.71 0.72 0.72 5.2 0.70 0.04 0.68 0.76 0.78 0.76 6.0 0.75 0.04 1.02 1.14 1.20 1.20 7.4 1.14 0.08 0.73 0.80 0.84 0.82 6.0 0.80 0.05 0.85 0.93 0.99 0.99 7.0 0.94 0.07 0.63 0.71 0.72 0.71 5.7 0.69 0.04 0.82 0.87 0.95 0.92 6.5 0.89 0.06 1.01 1.13 1.17 1.17 6.7 1.12 0.07 0.87 0.95 1.01 0.98 6.4 0.95 0.06 0.96 1.04 1.05 1.14 7.2 1.05 0.08 0.87 0.97 1.03 0.94 7.0 0.95 0.07 0.95 1.02 1.11 1.12 7.7 1.05 0.08 1.02 1.16 1.21 1.16 6.9 1.14 0.08 0.63 0.69 0.72 0.70 5.5 0.68 0.04 1.05 1.15 1.22 1.22 7.0 1.16 0.08 1.05 1.16 1.22 1.21 6.5 1.16 0.08 0.99 1.07 1.11 1.10 5.3 1.07 0.06 1.05 1.14 1.18 1.25 7.1 1.16 0.08 0.98 1.07 1.11 1.11 5.6 1.07 0.06 1.01 1.00 1.01 0.99 1.0 1.00 0.01 1.12 1.10 1.08 1.10 1.5 1.10 0.02 1.08 1.09 1.22 1.26 7.8 1.16 0.09 1.00 1.01 1.14 1.17 8.0 1.08 0.09 1.03 1.00 1.15 1.18 7.9 1.09 0.09 0.95 0.95 1.07 1.07 6.8 1.01 0.07 0.98 0.96 1.09 1.11 7.4 1.03 0.08 0.96 0.97 1.12 1.18 10.5 1.06 0.11 0.94 0.96 1.11 1.14 9.8 1.04 0.10 1.05 1.09 1.26 1.34 11.7 1.19 0.14 0.96 0.98 1.13 1.18 10.1 1.06 0.11 0.96 0.99 1.14 1.18 10.3 1.07 0.11 0.78 0.80 0.90 0.92 8.1 0.85 0.07 0.92 0.95 1.09 1.13 10.0 1.02 0.10 0.99 1.00 1.14 1.21 10.1 1.09 0.11 0.84 0.85 0.98 1.03 10.4 0.93 0.10 0.99 7.4 0.93 0.07 0.86 MM7 Comparing ICAL RRFs 20DEC2013.xlsx 0.87 0.98 0.87 0.89 1.02 1.03 8.8 0.95 0.08 0.92 0.91 1.04 1.13 10.2 1.00 0.10 PD from Mean -1.8% -2.5% -1.4% -3.4% -2.8% -2.6% -2.3% -0.9% -0.6% -1.7% -1.5% -1.5% -2.9% 0.9% -1.7% -2.4% 0.6% 0.4% -0.7% 0.2% -1.9% 2.4% 4.7% -3.8% 1.4% 1.9% 0.2% 0.2% -0.9% 2.8% -2.1% 0.7% -0.1% -0.7% 2.2% -2.6% 1.8% 0.9% -0.5% -0.1% 0.6% -1.2% 0.1% -0.2% -0.1% -6.2% -6.4% -8.0% -5.7% -7.0% -8.2% -7.2% -8.1% -7.7% -7.8% -5.8% -6.8% -7.9% -8.2% -5.7% -6.7% -8.7% 1668A/B ICALs Air Historica Data Ax PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 22'44'55'-/23'44' PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 233'4'56-/22' PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 22'33'44'-/2344'5 PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'4'56-HpCB PCB-181 22'344'56-HpCB PCB-171/173 22'33'44'6-/22'3 PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 22'344'55'-/233' PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 22'33'455'6-/22' PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB RSD 144 of 417 Mean sd MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd 1.12 1.13 1.32 1.41 11.4 1.24 0.14 0.99 1.01 1.16 1.20 10.0 1.09 0.11 1.24 1.25 1.41 1.52 9.8 1.36 0.13 1.19 1.22 1.38 1.46 9.8 1.31 0.13 0.92 0.93 1.06 1.09 8.9 1.00 0.09 0.82 0.85 0.95 0.97 8.2 0.90 0.07 1.00 1.04 1.08 1.16 6.3 1.07 0.07 1.21 1.22 1.45 1.50 11.2 1.35 0.15 1.01 1.02 1.14 1.19 8.1 1.09 0.09 1.18 1.21 1.32 1.52 11.9 1.31 0.16 1.30 1.34 1.50 1.66 11.4 1.45 0.17 0.91 0.90 0.95 0.90 2.7 0.92 0.02 1.07 1.06 1.14 1.11 3.0 1.10 0.03 1.09 1.08 1.14 1.07 2.7 1.09 0.03 1.03 1.03 1.01 1.27 11.4 1.09 0.12 0.95 0.97 0.92 1.16 10.8 1.00 0.11 0.94 0.93 0.90 1.13 10.6 0.98 0.10 1.05 1.05 1.00 1.23 9.4 1.08 0.10 0.98 0.98 0.94 1.13 8.3 1.01 0.08 0.73 0.74 0.69 0.84 8.6 0.75 0.06 0.95 1.01 1.09 1.07 6.1 1.03 0.06 0.99 1.06 1.17 1.14 7.4 1.09 0.08 1.02 1.11 1.19 1.18 6.9 1.12 0.08 1.06 1.13 1.17 1.20 5.4 1.14 0.06 0.95 1.02 1.13 1.06 7.3 1.04 0.08 0.83 0.93 0.99 0.99 8.0 0.93 0.07 0.85 0.91 0.97 0.95 5.7 0.92 0.05 0.98 1.06 1.10 1.09 4.9 1.06 0.05 0.85 0.93 0.96 0.95 5.4 0.92 0.05 0.88 0.95 0.99 0.99 5.5 0.95 0.05 1.12 1.24 1.26 1.29 6.0 1.23 0.07 1.08 1.16 1.21 1.26 6.6 1.18 0.08 1.20 1.30 1.32 1.40 6.4 1.31 0.08 1.06 1.07 1.11 1.14 3.3 1.09 0.04 1.42 1.45 1.54 1.66 7.2 1.52 0.11 0.93 0.91 0.97 1.05 6.4 0.97 0.06 1.04 1.02 1.07 1.22 8.3 1.09 0.09 0.99 0.98 1.02 1.12 6.3 1.03 0.07 1.03 1.06 1.13 1.19 6.3 1.10 0.07 1.02 0.96 1.02 1.11 6.0 1.03 0.06 0.74 0.72 0.73 0.81 5.7 0.75 0.04 0.77 0.73 0.76 0.83 5.5 0.77 0.04 0.80 0.76 0.79 0.87 5.7 0.80 0.05 0.79 0.80 0.82 0.77 2.7 0.80 0.02 0.87 0.87 0.89 0.84 2.3 0.87 0.02 1.07 1.09 1.11 1.06 1.8 1.08 0.02 1.02 1.02 1.07 1.12 4.7 1.06 0.05 1.07 1.06 1.10 1.19 5.4 1.10 0.06 0.99 0.98 0.92 1.11 7.9 1.00 0.08 MM7 Comparing ICAL RRFs 20DEC2013.xlsx PD from Mean -9.0% -7.6% -7.6% -7.0% -7.3% -5.7% -2.7% -9.1% -6.2% -7.6% -7.7% -1.9% -3.0% -1.7% -4.8% -3.1% -4.6% -3.2% -2.6% -1.8% -2.0% -2.5% -1.2% -0.6% -2.0% -0.7% -1.3% 0.3% 0.6% 0.3% 1.0% -1.6% -0.3% -1.9% -4.3% -5.3% -6.2% -4.9% -3.6% -6.4% -4.2% -5.3% -5.1% 0.5% 0.7% 0.6% -3.8% -4.3% -2.0% 145 of 417 SGS Analytical Perspectives — Run Log Project: 131220 QC MM7 Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Datafile Vial# Wt/Vol Client/Sample ID Analyst(s) Checkcode Acq Date 2 131220X02 Tray1:37 CS0_131220_PCB_XA 1.00 SIL 13-79-6 LKB 067-110 20-Dec-2013 14:56:33 3 131220X03 Tray1:38 CS1_131220_PCB_XA 1.00 SIL 13-79-5 LKB 983-753 20-Dec-2013 16:14:56 Lab ID Acq Time 4 131220X04 Tray1:39 CS2_131220_PCB_XA 1.00 SIL 13-79-4 LKB 288-489 20-Dec-2013 17:09:38 5 131220X05 Tray1:40 CS3_131220_PCB_XA 1.00 SIL 13-79-3 LKB 297-225 20-Dec-2013 18:04:38 20-Dec-2013 18:59:38 6 131220X06 Tray1:41 CS4_131220_PCB_XA 1.00 SIL 13-79-2 LKB 186-257 7 131220X07 Tray1:02 SBS_131220_PCB_XB 1.00 SIL 9-42-1 LKB 307-094 20-Dec-2013 19:54:39 8 131220X08 Tray1:42 CS5_131220_PCB_XA 1.00 SIL 13-84-1 LKB 807-075 20-Dec-2013 20:49:35 9 131220X09 Tray1:02 SBS_131220_PCB_XC 1.00 SIL 9-42-1 LKB 023-880 20-Dec-2013 21:57:30 10 131220X10 Tray1:02 SBS_131220_PCB_XD 1.00 SIL 9-42-1 LKB 979-518 20-Dec-2013 22:52:16 Project file: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\131220 QC MM7.utp_prj, saved 03-Jan-2014 17:08 AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 Printed: 03-Jan-2014 17:17 146 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.12 32.64 36.11 35.57 35.10 34.82 38.73 41.28 40.30 44.00 46.13 51.25 6.82E+05 6.25E+05 5.30E+05 5.44E+05 5.47E+05 5.49E+05 4.31E+05 8.79E+05 4.81E+05 4.43E+05 4.42E+05 3.36E+05 0.76 Y 0.76 Y 0.63 Y 0.67 Y 0.67 Y 0.63 Y 0.61 Y 1.18 Y 1.11 Y 1.39 Y 1.03 Y 1.21 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.08 1.13 1.14 1.20 1.20 1.05 1.07 1.11 1.12 1.08 1.18 1.8% -3.1% 1.5% -5.0% 0.6% -0.6% -5.2% -2.5% -4.2% -0.5% 0.2% 6.0% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.05 14.37 14.63 20.39 17.75 26.75 20.68 33.10 32.62 25.69 36.09 35.55 35.08 34.80 38.71 36.67 30.66 41.26 40.28 43.98 43.50 42.43 35.54 46.11 40.09 48.28 49.75 45.73 51.23 2.32E+08 2.09E+08 9.70E+07 1.92E+08 9.22E+07 1.42E+08 7.28E+07 1.16E+08 1.15E+08 6.25E+07 9.38E+07 9.51E+07 9.14E+07 9.13E+07 8.22E+07 5.84E+07 8.51E+07 1.64E+08 8.65E+07 7.92E+07 4.71E+07 5.69E+07 4.97E+07 8.21E+07 4.94E+07 6.33E+07 4.24E+07 5.90E+07 5.69E+07 3.31 Y 3.36 Y 1.64 Y 1.56 Y 1.08 Y 1.09 Y 0.79 Y 0.80 Y 0.81 Y 1.64 Y 1.62 Y 1.64 Y 1.64 Y 1.59 Y 1.56 Y 1.32 Y 1.30 Y 1.31 Y 1.29 Y 1.29 Y 1.09 Y 1.07 Y 1.11 Y 1.04 Y 0.92 Y 0.90 Y 0.81 Y 0.81 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.25 1.12 0.52 1.04 0.50 1.69 0.86 1.38 1.37 0.82 1.22 1.24 1.19 1.19 1.07 1.14 1.66 1.60 1.68 1.54 0.92 1.11 0.97 1.61 0.96 1.24 0.83 1.16 1.12 5.1% 3.5% 0.1% -0.4% -1.7% 1.7% 0.4% -0.1% 0.2% 1.5% 1.8% 1.8% 2.9% 0.4% 4.3% 2.1% 4.3% 0.0% 0.9% -1.0% -2.5% -2.0% 2.9% 1.7% -0.9% -0.3% 0.3% -1.6% 0.5% Page 1 of 6 147 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.18 33.12 38.11 1.59E+08 9.52E+07 3.17E+07 1.09 Y 1.60 Y 1.06 Y 1.11 1.03 0.62 1.12 1.04 0.64 0.5% 1.3% 3.0% CS PCB-28 CS PCB-111 CS PCB-178 23.18 33.12 38.11 1.59E+08 9.52E+07 3.17E+07 1.09 Y 1.60 Y 1.06 Y 1.85 1.22 0.58 1.89 1.24 0.62 2.2% 1.7% 6.0% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.63 24.81 30.82 37.74 47.88 1.86E+08 8.42E+07 7.67E+07 5.14E+07 5.10E+07 1.57 Y 0.81 Y 1.63 Y 1.34 Y 0.93 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.06 14.39 14.64 20.41 17.77 26.77 20.70 25.71 30.68 35.56 40.11 48.30 45.75 49.77 1.15E+06 1.04E+06 5.70E+05 9.73E+05 5.22E+05 7.24E+05 5.08E+05 4.49E+05 5.21E+05 3.05E+05 2.58E+05 3.40E+05 3.21E+05 2.31E+05 3.25 Y 3.26 Y 0.00 S 0.00 S 1.03 Y 1.07 Y 0.86 Y 0.64 Y 1.33 Y 1.15 Y 0.94 Y 0.94 Y 0.83 Y 0.73 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.99 1.00 1.17 1.01 1.13 1.02 1.40 1.44 1.23 1.23 1.05 1.07 1.09 1.09 3.9% -0.9% -4.7% -0.7% -1.3% -5.6% 3.4% 0.3% -2.8% -3.2% -0.7% 1.3% -3.0% -2.5% Page 2 of 6 148 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 12.06 14.20 14.39 14.64 14.83 16.65 16.82 17.04 17.35 17.47 19.04 19.83 20.12 20.41 17.77 19.54 19.95 20.14 20.27 20.37 20.86 22.01 22.16 22.45 22.65 22.92 23.21 23.39 23.77 25.16 25.48 26.02 26.41 26.77 20.70 22.70 23.29 23.37 23.57 24.83 24.96 25.06 25.26 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.15E+06 1.07E+06 1.04E+06 5.70E+05 9.26E+05 8.91E+05 9.13E+05 9.28E+05 9.94E+05 1.02E+06 1.10E+06 9.44E+05 1.69E+06 9.73E+05 5.22E+05 1.37E+06 5.65E+05 8.14E+05 7.72E+05 4.55E+05 8.78E+05 7.89E+05 8.53E+05 1.63E+06 8.01E+05 8.89E+05 1.61E+06 1.63E+06 7.71E+05 8.01E+05 8.42E+05 7.61E+05 7.19E+05 7.24E+05 5.08E+05 1.02E+06 4.52E+05 4.59E+05 4.01E+05 4.90E+05 6.54E+05 3.93E+05 1.15E+06 RA 3.25 Y 3.22 Y 3.26 Y 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 1.03 Y 1.04 Y 1.04 Y 1.08 Y 1.06 Y 1.10 Y 1.08 Y 1.08 Y 0.94 Y 1.01 Y 0.97 Y 1.01 Y 1.02 Y 0.98 Y 1.00 Y 1.00 Y 1.02 Y 0.93 Y 1.01 Y 1.07 Y 0.86 Y 0.81 Y 0.79 Y 0.83 Y 0.83 Y 0.76 Y 0.81 Y 0.85 Y 0.76 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.99 1.02 1.00 1.17 1.91 0.93 0.95 0.97 1.03 1.07 1.14 0.98 0.88 1.01 1.13 1.49 1.23 1.77 1.67 0.99 1.90 1.11 1.20 1.15 1.13 1.25 1.13 1.15 1.08 1.13 1.18 1.07 1.01 1.02 1.40 0.89 0.78 0.80 0.70 0.85 1.13 0.68 0.99 Dev'n 3.9% -0.9% -0.9% -4.7% -3.6% -2.0% -9.2% -3.0% 3.2% 3.2% -3.4% -2.8% -11.2% -0.7% -1.3% -3.2% -6.1% -2.9% -2.9% -2.0% -0.8% -2.3% 3.8% -2.1% -2.7% 2.0% -0.1% -2.4% 0.4% -3.7% -2.3% -3.2% -2.8% -5.6% 3.4% 1.3% 2.2% -7.3% -0.4% 0.7% 2.0% -4.1% -2.8% 149 of 417 PCB QC Summary - Ax2 Detail Lab ID: CS0_131220_PCB_XA Acquired: 20-DEC-2013 14:56 Datafile: 131220X02 Name RT PCB-48 22'45-TeCB 25.54 PCB-44/47/65 ...-TeCB 25.76 PCB-59/62/75 ...-TeCB 26.03 PCB-42 22'34'-TeCB 26.20 PCB-41 22'34-TeCB 26.54 PCB-71/40 23'4'6/22'33'-TeCB 26.63 PCB-64 234'6-TeCB 26.83 PCB-72 23'55'-TeCB 27.55 PCB-68 23'45'-TeCB 27.80 PCB-57 233'5-TeCB 28.18 PCB-58 233'5'-TeCB 28.38 PCB-67 23'45-TeCB 28.54 PCB-63 234'5-TeCB 28.77 PCB-61/70/74/76 ...-TeCB 29.06 PCB-66 23'44'-TeCB 29.34 PCB-55 233'4-TeCB 29.49 PCB-56 233'4'-TeCB 29.93 PCB-60 2344'-TeCB 30.12 PCB-80 33'55'-TeCB 30.44 PCB-79 33'45'-TeCB 31.77 PCB-78 33'45-TeCB 32.26 PCB-104 22'466'-PeCB 25.71 PCB-96 22'366'-PeCB 26.03 PCB-103 22'45'6-PeCB 27.72 PCB-94 22'356'-PeCB 27.91 PCB-95 22'35'6-PeCB 28.29 PCB-100/93 22'44'6/22'356-PeCB 28.51 PCB-102 22'456'-PeCB 28.62 PCB-98 22'34'6'-PeCB 28.70 PCB-88 22'346-PeCB 29.00 PCB-91 22'34'6-PeCB 29.06 PCB-84 22'33'6-PeCB 29.25 PCB-89 22'346'-PeCB 29.67 PCB-121 23'45'6-PeCB 30.01 PCB-92 22'355'-PeCB 30.33 PCB-113/90/101 ...-PeCB 30.82 PCB-83 22'33'5-PeCB 31.26 PCB-99 22'44'5-PeCB 31.36 PCB-112 233'56-PeCB 31.46 PCB-108/119/86/97/125...-PeCB 31.80 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.43 PCB-110 233'4'6-PeCB 32.54 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 4.76E+05 1.54E+06 1.95E+06 4.38E+05 3.93E+05 9.69E+05 6.74E+05 6.87E+05 7.26E+05 6.81E+05 6.76E+05 7.09E+05 7.50E+05 2.77E+06 6.11E+05 6.26E+05 6.53E+05 6.55E+05 7.47E+05 7.25E+05 6.00E+05 4.49E+05 3.51E+05 4.14E+05 3.59E+05 4.07E+05 7.64E+05 4.42E+05 3.31E+05 4.40E+05 3.45E+05 3.22E+05 3.31E+05 5.39E+05 3.73E+05 1.35E+06 3.50E+05 4.00E+05 5.12E+05 2.69E+06 4.64E+05 9.28E+05 4.96E+05 RA 0.82 Y 0.78 Y 0.80 Y 0.81 Y 0.87 Y 0.82 Y 0.82 Y 0.78 Y 0.84 Y 0.73 Y 0.76 Y 0.78 Y 0.82 Y 0.77 Y 0.79 Y 0.78 Y 0.82 Y 0.79 Y 0.82 Y 0.81 Y 0.82 Y 0.64 Y 0.75 N 0.64 Y 0.70 Y 0.58 Y 0.61 Y 0.64 Y 0.63 Y 0.66 Y 0.56 Y 0.60 Y 0.70 Y 0.64 Y 0.62 Y 0.62 Y 0.64 Y 0.61 Y 0.65 Y 0.63 Y 0.55 Y 0.58 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.83 0.89 1.13 0.76 0.68 0.84 1.17 1.19 1.26 1.18 1.17 1.23 1.30 1.20 1.06 1.09 1.13 1.13 1.30 1.26 1.04 1.44 1.12 0.91 0.79 0.89 0.84 0.97 0.73 0.96 0.76 0.71 0.73 1.18 0.82 0.98 0.77 0.88 1.12 0.98 1.02 1.02 1.09 Dev'n -1.5% -1.8% -3.2% -0.5% -2.0% -2.2% -4.3% -1.5% -1.4% 1.5% -0.6% -2.3% 0.2% 0.2% -3.9% -3.1% 2.0% 0.0% -1.4% -3.8% -2.0% 0.3% -8.6% -2.6% -1.5% 3.0% -3.1% 0.0% -4.3% 20.8% -19.9% -1.3% -4.9% -1.7% -0.4% -0.3% 7.3% -4.7% -4.0% 0.2% -10.6% 8.1% -2.7% 150 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 32.63 32.83 33.14 33.54 34.51 34.72 34.94 35.40 37.35 30.68 30.84 30.98 31.29 31.56 32.83 33.35 33.56 33.83 34.13 34.30 34.39 34.65 34.82 34.97 35.21 35.61 35.95 36.16 36.28 36.72 36.86 37.20 37.41 37.49 37.78 37.92 38.10 38.84 39.65 39.89 35.56 35.84 36.31 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 5.39E+05 3.15E+05 5.61E+05 5.37E+05 9.78E+05 5.73E+05 5.10E+05 4.64E+05 5.10E+05 5.21E+05 4.93E+05 5.01E+05 4.28E+05 4.79E+05 3.33E+05 6.47E+05 4.03E+05 3.56E+05 6.56E+05 2.84E+05 3.14E+05 7.00E+05 2.97E+05 2.79E+05 3.02E+05 3.31E+05 4.11E+05 3.49E+05 4.37E+05 8.08E+05 3.22E+05 2.84E+05 3.47E+05 3.94E+05 1.03E+06 4.35E+05 4.94E+05 7.41E+05 4.73E+05 4.43E+05 3.05E+05 2.95E+05 2.83E+05 RA 0.59 Y 0.59 Y 0.65 Y 0.66 Y 0.64 Y 0.63 Y 0.69 Y 0.65 Y 0.62 Y 1.33 Y 1.27 Y 1.36 Y 1.35 Y 1.26 Y 1.20 Y 1.21 Y 1.25 Y 1.23 Y 1.34 Y 1.23 Y 1.30 Y 1.27 Y 1.27 Y 1.25 Y 1.27 Y 1.25 Y 1.27 Y 1.21 Y 1.25 Y 1.27 Y 1.27 Y 1.16 Y 1.24 Y 1.20 Y 1.26 Y 1.23 Y 1.30 Y 1.33 Y 1.12 Y 1.33 Y 1.15 Y 1.06 Y 0.94 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.18 0.69 1.23 1.18 1.07 1.26 1.12 0.97 1.09 1.23 1.16 1.18 1.01 1.13 1.14 1.11 1.38 1.22 1.12 0.97 1.07 1.20 1.02 0.96 1.03 1.13 1.41 1.19 1.50 1.38 1.10 0.97 1.19 1.35 1.18 1.49 1.69 0.86 1.09 1.03 1.23 1.19 1.14 Dev'n 1.8% -1.1% 0.6% -2.8% -2.4% 0.2% 1.0% -2.0% -0.8% -2.8% -1.3% 0.1% -5.7% 0.9% -3.7% -2.9% 2.8% 3.1% -4.6% 5.0% -4.7% -0.6% -0.8% -3.4% 0.2% 0.1% -0.2% -0.7% -1.6% -5.0% 1.3% 0.0% 2.0% -10.0% -1.1% -1.7% 1.8% -4.7% -1.9% -4.3% -3.2% 2.3% 1.1% 151 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 36.60 37.00 38.13 38.68 38.91 39.09 39.43 39.52 39.63 40.00 40.35 40.54 41.89 42.14 42.41 42.74 43.51 43.97 40.11 40.90 41.48 41.67 41.76 44.08 44.66 44.83 45.95 47.90 48.30 45.75 46.54 49.77 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 3.00E+05 2.82E+05 2.19E+05 2.90E+05 3.08E+05 3.10E+05 3.29E+05 2.70E+05 2.63E+05 2.64E+05 2.93E+05 5.11E+05 2.73E+05 3.33E+05 7.15E+05 3.99E+05 2.56E+05 3.84E+05 2.58E+05 2.87E+05 2.72E+05 3.10E+05 2.54E+05 3.97E+05 2.07E+05 2.16E+05 2.51E+05 2.77E+05 3.40E+05 3.21E+05 3.55E+05 2.31E+05 RA 1.06 Y 1.10 Y 1.14 Y 1.08 Y 1.11 Y 1.13 Y 1.06 Y 1.04 Y 1.16 Y 1.06 Y 1.17 Y 1.09 Y 1.07 Y 1.10 Y 1.02 Y 1.10 Y 1.10 Y 1.02 Y 0.94 Y 1.04 N 0.90 Y 0.94 Y 1.01 Y 1.02 Y 0.90 Y 0.86 Y 0.94 Y 0.96 Y 0.94 Y 0.83 Y 0.76 Y 0.73 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.21 1.14 0.88 1.02 1.08 1.09 1.16 0.95 0.93 0.93 1.03 0.90 0.96 1.17 1.26 1.41 1.09 1.63 1.05 1.16 1.10 1.26 1.03 0.80 0.84 0.87 0.79 0.88 1.07 1.09 1.20 1.09 Dev'n -1.8% 1.0% 4.6% -4.9% -4.8% -7.2% -4.0% -10.4% -6.3% -2.5% -5.4% -5.3% -3.0% -9.0% -0.4% 0.7% -4.3% -1.8% -0.7% -4.7% -1.4% 5.5% -7.2% -0.6% 0.6% 0.0% 3.5% 3.8% 1.3% -3.0% 1.1% -2.5% 152 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.34e7 2.67e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.66e7 1.33e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.89e7 9.45e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.92e7 9.60e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.07e7 5.34e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.41e6 2.71e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.18e6 2.59e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 067-110 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:09 Page 1 of 21 153 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-1 8.80e5 12.06 Rel. Int. 100% Abs. Int. 3.62e5 PCB-2 8.15e5 14.20 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.75e3 PCB-3 7.98e5 14.39 1.81e5 0% 11.0 12.0 13.0 14.0 PCB-1 2.71e5 12.06 Rel. Int. 100% PCB-2 2.53e5 14.20 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 4.15e3 15.0 0.00e0 16.0 RT Abs. Int. 1.13e5 PCB-3 2.45e5 14.38 5.63e4 0% 11.0 12.0 13.0 14.0 ES-1 1.79e8 12.05 Rel. Int. 100% 15.0 Abs. Int. 7.29e7 ES-3 1.61e8 14.37 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.78e3 0.00e0 16.0 RT 3.65e7 0% 11.0 12.0 13.0 14.0 ES-1 5.39e7 12.05 Rel. Int. 100% 15.0 Abs. Int. 2.20e7 ES-3 4.79e7 14.37 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.76e4 0.00e0 16.0 RT 1.10e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.34e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.67e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4953, 9453 scc: 067-110 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 2 of 21 154 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Rel. Int. 100% PCB-4 3.47e5 SI 14.64 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 8.63e3 PCB-10 5.64e5 SI 14.83 9.85e4 0% 11.0 12.0 13.0 14.0 Abs. Int. 1.97e5 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.66e5 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: B 4σ 2.45e4 8.28e4 PFK INTERFERENCE 0% 11.0 12.0 13.0 14.0 15.0 ES-4 6.03e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.00e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 9.69e3 1.00e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.67e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.22e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.99e3 6.10e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.34e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.67e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4218, 8363 scc: 067-110 Revised: 20-Dec-2013 16:07 (LKB) Printed: 03-Jan-2014 17:09 Page 3 of 21 155 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.03e4 PCB-9 5.43e5 SI 16.65 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-14 6.67e5 SI 19.04 PCB-6 5.66e5 SI PCB-5 17.04 6.06e5 SI 17.35 PCB-8 6.24e5 SI 17.47 PCB-11 5.75e5 SI 19.83 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 13/12 1.03e6 SI 20.12 Abs. Int. 2.00e5 PCB-15 5.93e5 SI 20.41 1.00e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% Abs. Int. 2.04e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: B 4σ 4.98e4 PFK INTERFERENCE 1.02e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.13e8 16.63 21.0 0.00e0 RT Abs. Int. 3.67e7 ES-15 1.17e8 20.39 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.06e4 1.83e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.22e7 16.63 21.0 ES-15 7.51e7 20.39 0.00e0 RT Abs. Int. 2.31e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.56e3 1.16e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7888, 3701 scc: 067-110 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 4 of 21 156 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 30/18 6.99e5 19.54 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 4.59e3 PCB-19 2.65e5 17.77 Abs. Int. 1.97e5 PCB-27 4.22e5 20.14 PCB-17 2.89e5 19.95 PCB-16 2.38e5 20.37 PCB-32 4.55e5 20.86 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.74e5 19.54 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 2.66e3 PCB-19 2.58e5 17.77 PCB-17 2.76e5 19.94 PCB-24 3.75e5 20.27 PCB-27 3.92e5 20.14 PCB-16 2.16e5 20.37 21.0 Rel. Int. 100% 18.0 19.0 20.0 PCB-32 4.23e5 20.85 21.0 9.50e4 0.00e0 RT Abs. Int. 1.93e7 ES-19 4.80e7 17.75 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 8.60e4 0.00e0 RT Abs. Int. 1.90e5 0% 17.0 9.86e4 9.63e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.74e7 ES-19 4.42e7 17.75 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 4.22e4 0.00e0 RT 8.69e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5150, 2161 scc: 067-110 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 5 of 21 157 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 28/20 8.12e5 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.52e3 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-23 PCB-34 4.13e5 4.09e5 22.16 22.01 26/29 8.20e5 22.45 PCB-31 4.46e5 22.92 21/33 8.09e5 23.39 Abs. Int. 2.07e5 PCB-22 3.85e5 23.77 PCB-36 4.01e5 25.16 PCB-39 4.25e5 25.48 PCB-38 3.67e5 26.02 PCB-35 3.62e5 26.41 PCB-37 3.75e5 26.77 0% 22.0 24.0 25.0 26.0 27.0 28/20 7.97e5 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 4.06e3 23.0 PCB-23 4.41e5 PCB-34 22.16 3.80e5 22.01 26/29 8.12e5 22.45 PCB-31 4.43e5 22.92 23.0 PCB-22 3.86e5 23.77 PCB-36 4.00e5 25.16 PCB-39 4.16e5 25.48 PCB-38 3.93e5 26.02 24.0 25.0 PCB-35 3.57e5 26.41 PCB-37 3.50e5 26.77 26.0 CS/SS-28 8.29e7 23.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e5 0% 22.0 1.03e5 27.0 0.00e0 RT Abs. Int. 2.37e7 ES-37 7.42e7 26.75 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 1.09e5 1.02e5 1.19e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 7.59e7 23.18 Rel. Int. 100% 27.0 Abs. Int. 2.19e7 ES-37 6.81e7 26.75 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 3.46e4 0.00e0 RT 1.09e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3489, 3011 scc: 067-110 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 6 of 21 158 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-54 2.35e5 20.70 Rel. Int. 100% Abs. Int. 6.46e4 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.55e3 3.23e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.74e5 20.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.82e4 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.17e3 3.91e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.22e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.63e6 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.64e4 4.31e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.06e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 7.86e3 5.58e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5717, 8453 scc: 067-110 Revised: 20-Dec-2013 16:06 (LKB) Printed: 03-Jan-2014 17:09 Page 7 of 21 159 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.01e3 50/53 4.58e5 22.70 PCB-51 2.08e5 23.37 PCB-45 1.99e5 23.29 PCB-73 2.92e5 PCB-52 24.96 2.11e5 24.83 PCB-46 1.82e5 23.57 69/49 4.95e5 25.26 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 44/47… 6.71e5 25.76 59/62… 8.68e5 26.03 PCB-48 2.15e5 25.54 PCB-42 1.96e5 26.20 71/40 4.36e5 26.63 PCB-41 1.83e5 26.54 Abs. Int. 1.53e5 PCB-64 3.04e5 26.83 7.63e4 27.0 0.00e0 RT 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.48e3 50/53 5.66e5 22.70 24.0 PCB-51 2.51e5 23.37 PCB-45 2.53e5 23.29 25.0 PCB-73 3.62e5 PCB-52 24.96 2.79e5 24.83 PCB-46 2.19e5 23.57 26.0 69/49 6.51e5 25.26 59/62… 44/47… 1.08e6 8.65e5 26.03 25.76 PCB-48 2.62e5 25.54 PCB-42 2.42e5 26.20 71/40 5.32e5 26.63 PCB-41 2.10e5 26.54 Abs. Int. 1.85e5 PCB-64 3.70e5 26.83 9.27e4 27.0 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.78e7 24.81 Rel. Int. 100% Abs. Int. 1.00e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 3.08e4 5.01e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 4.64e7 24.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.96e4 6.40e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6598, 8859 scc: 067-110 Revised: 03-Jan-2014 11:21 (LKB) Printed: 03-Jan-2014 17:09 Page 8 of 21 160 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 61/70... 1.21e6 29.06 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.26e3 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-68 3.31e5 27.80 PCB-67 3.10e5 28.54 (2.70e5 + 3.56e5) * 100 pg/uL PCB-78= 1.08 2.71e5 (5.16e7 + 6.38e7) * .5 pg/uL 32.26 PCB-79 03-Jan-2014 11:20 PCB-55LKBPCB-60 PCB-80 PCB-81 2.89e5 3.24e5 2.74e5 3.36e5 2.70e5 30.12 31.77 29.49 30.44 32.64 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 1.49e5 RRF(PCB-81) = PCB-77 2.95e5 33.12 7.45e4 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 2.42e3 PCB-57 3.94e5 28.18 PCB-68 3.96e5 27.80 30.0 61/70... 1.56e6 29.06 PCB-63 4.12e5 PCB-66 3.42e5 28.77 29.34 32.0 PCB-60 3.65e5 30.12 PCB-56 3.60e5 29.93 PCB-80 4.12e5 30.45 PCB-79 4.01e5 31.77 34.0 PCB-78 3.29e5 32.26PCB-81 3.56e5 32.64 36.0 38.0 Abs. Int. 1.90e5 PCB-77 3.88e5 33.12 9.52e4 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 5.16e7 32.62 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.10e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.47e7 ES-77 5.18e7 33.10 7.37e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.38e7 32.62 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 2.52e4 36.0 38.0 0.00e0 RT Abs. Int. 1.79e7 ES-77 6.46e7 33.10 8.96e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0219, 8038 scc: 067-110 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 9 of 21 161 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-104 1.75e5 25.71 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 8.14e2 Abs. Int. 4.89e4 PCB-96 1.63e5 26.03 2.44e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.74e5 25.71 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 9.29e2 27.0 0.00e0 RT Abs. Int. 7.44e4 PCB-96 2.17e5 26.02 3.72e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 3.88e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.91e6 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.55e3 4.96e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.37e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.05e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.87e3 3.03e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5253, 4725 scc: 067-110 Revised: 20-Dec-2013 16:06 (LKB) Printed: 03-Jan-2014 17:09 Page 10 of 21 162 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 108/119... 1.04e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 2.21e3 PCB-103 1.61e5 27.72 100/93 2.88e5 28.51 PCB-88 1.75e5 29.00 PCB-121 2.11e5 30.01 113/90… 5.12e5 30.82 116/85 3.42e5 32.43 PCB-99 1.52e5 31.36 PCB-111 2.21e5 PCB-120 2.13e5 33.14 33.54 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-118 107/124 2.20e5 3.81e5 35.10 34.51 PCB-114 PCB-123 2.18e5 2.12e5 35.57 34.82 Abs. Int. 1.54e5 PCB-105 2.05e5 36.11 PCB-127 1.96e5 37.35 7.68e4 0% 28.0 30.0 32.0 108/119... 1.64e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 4.66e3 34.0 PCB-94 2.12e5 27.91 100/93 4.76e5 28.51 PCB-91 2.21e5 29.06 PCB-121 3.28e5 30.01 113/90… 8.33e5 30.82 PCB-112 3.11e5 31.45 116/85 PCB-115 5.86e5 3.38e5 32.43 32.63 PCB-117 PCB-110 PCB-111 PCB-120 3.40e5 3.00e5 3.06e5 3.24e5 33.14 32.34 32.54 33.54 36.0 PCB-118 107/124 3.27e5 5.97e5 35.10 34.51 PCB-123 PCB-114 3.37e5 3.26e5 34.82 35.57 38.0 Abs. Int. 2.29e5 PCB-105 3.25e5 36.11 PCB-127 3.14e5 37.35 1.14e5 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.86e7 33.12 JS-101 4.75e7 30.82 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.00e3 34.0 36.0 ES-123 5.61e7 34.80 ES-118 ES-114 5.68e7 5.90e7 35.08 35.55 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.47e7 ES-105 5.80e7 36.09 7.34e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 3.66e7 33.12 JS-101 2.91e7 30.82 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.10e3 34.0 36.0 ES-118 ES-114 3.61e7 ES-123 3.46e7 35.55 3.52e7 35.08 34.80 38.0 0.00e0 RT Abs. Int. 9.50e6 ES-105 3.59e7 36.09 4.75e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7393, 8355 scc: 067-110 Revised: 03-Jan-2014 16:46 (LKB) Printed: 03-Jan-2014 17:09 Page 11 of 21 163 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 3.76e4 PCB-126 1.64e5 38.73 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.18e3 1.88e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.47e4 PCB-126 2.67e5 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.48e3 3.23e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.25e7 ES-126 5.01e7 38.71 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 5.64e3 6.27e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.77e6 ES-126 3.21e7 38.71 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 4.88e3 3.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4712, 3338 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 12 of 21 164 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PCB-155 PCB-150 2.97e5 2.89e5 30.98 30.68 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.52e2 PCB-145 2.67e5 31.56 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 163/138… 5.74e5 153/168 PCB-13737.78 4.52e5 1.92e5 36.72 37.41 PCB-160 151/135PCB-144 PCB-164 3.54e5 1.97e5 PCB-143 PCB-142 PCB-133 PCB-146 PCB-141 2.14e5 2.40e5 1.80e5 37.92 1.78e5 1.55e5 33.35 33.83 37.49 1.84e5 1.91e5 36.86 36.16 34.39 34.97 35.61 147/149 139/140 3.75e5 3.92e5 34.65 34.13 PCB-148 1.82e5 32.83 0% 28.0 30.0 32.0 PCB-152 2.17e5 30.84 PCB-136 PCB-155 1.82e5 PCB-145 2.24e5 31.28 2.11e5 30.68 31.56 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 8.44e2 34.0 PCB-148 1.51e5 32.83 139/140 147/149 3.08e5 151/135 2.80e5 34.65 2.92e5 34.13 33.35 PCB-154 PCB-143 PCB-131 1.79e5 1.37e5 1.31e5 33.56 34.39 34.82 36.0 PCB-133 1.47e5 PCB-165 35.61 1.81e5 35.95 38.0 153/168 3.56e5 36.72 163/138… 4.56e5 37.78 PCB-141 PCB-137 1.42e5 1.55e5 37.40 36.86 PCB-158 2.14e5 38.10 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.81e7 30.66 Rel. Int. 100% ES-153 3.32e7 36.67 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.51e3 Abs. Int. 1.11e5 5.57e4 0.00e0 RT Abs. Int. 8.34e4 4.17e4 0.00e0 RT Abs. Int. 1.25e7 JS-138 2.94e7 37.74 6.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.70e7 30.66 Rel. Int. 100% ES-153 2.52e7 36.67 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.03e3 0.00e0 RT Abs. Int. 9.38e6 JS-138 2.20e7 37.74 4.69e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6209, 6582 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 13 of 21 165 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.23e5 38.84 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.22e3 PCB-159 2.50e5 39.65 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-162 2.53e5 39.89 156/157 4.75e5 41.28 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 1.04e5 PCB-169 2.58e5 44.00 PCB-167 2.54e5 40.30 5.20e4 0% 39.0 Rel. Int. 100% 128/166 3.18e5 38.83 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.11e3 40.0 41.0 42.0 43.0 44.0 45.0 156/157 4.04e5 41.28 PCB-159 PCB-162 2.23e5 1.90e5 39.65 39.89 Abs. Int. 7.56e4 PCB-169 1.85e5 44.00 PCB-167 2.28e5 40.30 3.78e4 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 4.87e7 40.28 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 9.39e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 9.32e7 41.26 0.00e0 RT Abs. Int. 1.67e7 ES-169 4.45e7 43.98 8.34e6 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 3.78e7 40.28 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 6.54e3 42.0 43.0 44.0 45.0 ES-156/157 7.11e7 41.26 0.00e0 RT Abs. Int. 1.29e7 ES-169 3.46e7 43.98 6.47e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3213, 6781 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 14 of 21 166 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PCB-188 1.63e5 35.56 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-179 1.52e5 PCB-184 35.84 1.37e5 36.31 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.36e2 PCB-186 1.48e5 37.00 PCB-178 1.17e5 38.13 Abs. Int. 4.15e4 2.08e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.42e5 35.56 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.81e2 PCB-179 1.44e5 35.84 37.0 PCB-176 1.46e5 36.60 PCB-186 1.35e5 37.00 38.0 Abs. Int. 3.92e4 PCB-178 1.02e5 38.13 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.61e7 35.54 Rel. Int. 100% CS/SS-178 1.63e7 38.11 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.35e7 35.54 Rel. Int. 100% CS/SS-178 1.53e7 38.11 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.47e6 0.00e0 RT Abs. Int. 5.99e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.39e3 31.0 1.96e4 Abs. Int. 6.93e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.30e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 2.99e6 0.00e0 RT Abs. Int. 1.89e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.45e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6881, 0191 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 15 of 21 167 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.06e3 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-185 1.38e5 171/173 39.52 2.66e5 PCB-182 1.65e5 PCB-183 PCB-174 PCB-177 PCB-181 40.54 1.69e5 1.35e5 1.58e5 39.09 1.42e5 39.4339.63 40.00 40.35 180/193 3.61e5 42.41 PCB-172 1.41e5 41.89 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-191 2.09e5 42.74 PCB-170 1.34e5 43.51 Abs. Int. 5.93e4 PCB-190 1.94e5 43.97 2.96e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 9.28e2 40.0 PCB-182 1.45e5 39.09 PCB-183 1.60e5 PCB-187 39.43 1.46e5 38.91 41.0 42.0 43.0 180/193 3.54e5 42.41 171/173 PCB-177 PCB-181 2.44e5 1.28e5 1.35e5 40.54 40.00 40.35 PCB-191 1.90e5 42.74 PCB-172 1.32e5 41.89 44.0 45.0 PCB-190 1.90e5 43.97 Abs. Int. 5.34e4 PCB-170 1.22e5 43.52 2.67e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 ES-180 2.95e7 42.43 (2.46e7 + 2.25e7) 8 100 pg/uL RRF(ES-170) = = 0.924 (2.46e7 + 2.64e7) * 100 pg/uL LKB 03-Jan-2014 11:42 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.94e3 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 7.54e6 ES-170 2.46e7 43.50 3.77e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.74e7 42.43 Rel. Int. 100% 44.0 45.0 Abs. Int. 6.83e6 ES-170 2.25e7 43.50 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 1.82e3 0.00e0 RT 3.42e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3799, 6132 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 16 of 21 168 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-189 2.24e5 46.13 Abs. Int. 5.27e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.21e3 2.63e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.18e5 46.13 Abs. Int. 5.43e4 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 7.69e2 2.72e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.19e7 46.11 0.00e0 RT Abs. Int. 1.03e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 3.48e3 5.16e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.02e7 46.11 0.00e0 RT Abs. Int. 9.81e6 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 5.08e3 4.90e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2597, 5520 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 17 of 21 169 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-202 1.25e5 40.11 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 5.85e2 PCB-201 1.58e5 40.90 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 198/199 2.01e5 44.08 PCB-197 1.51e5 PCB-204 41.67 PCB-200 1.28e5 1.29e5 41.76 41.48 Abs. Int. 4.15e4 PCB-196 9.79e4 44.66 PCB-203 9.97e4 44.83 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.33e5 40.11 41.0 PCB-201 1.52e5 40.90 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 8.32e2 42.0 43.0 PCB-197 1.60e5 PCB-204 41.67 PCB-200 1.26e5 1.43e5 41.76 41.48 44.0 198/199 1.96e5 44.08 45.0 2.08e4 0.00e0 RT Abs. Int. 4.09e4 PCB-196 1.09e5 44.66 PCB-203 1.16e5 44.83 2.04e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.37e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.85e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.16e3 2.92e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.57e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.36e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 2.16e3 3.18e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3435, 2261 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 18 of 21 170 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 6.43e2 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-195 1.22e5 45.95 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-205 1.65e5 48.30 PCB-194 1.36e5 47.90 Abs. Int. 3.94e4 1.97e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 9.26e2 47.0 48.0 50.0 PCB-205 1.75e5 48.30 PCB-194 1.41e5 47.90 PCB-195 1.30e5 45.95 49.0 0.00e0 RT Abs. Int. 4.19e4 2.10e4 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.00e7 48.28 JS-194 2.46e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 4.05e3 49.0 0.00e0 RT Abs. Int. 7.11e6 3.56e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.33e7 48.28 Rel. Int. 100% Abs. Int. 7.81e6 JS-194 2.64e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.43e3 0.00e0 RT 3.91e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3437, 5090 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 19 of 21 171 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.06e3 PCB-208 1.46e5 45.75 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-207 1.53e5 46.54 Abs. Int. 3.84e4 PCB-206 9.77e4 49.77 1.92e4 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.83e3 PCB-208 1.75e5 45.74 47.0 48.0 49.0 PCB-207 2.02e5 46.54 50.0 Abs. Int. 4.66e4 PCB-206 1.33e5 49.77 2.33e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.64e7 45.73 50.0 0.00e0 RT Abs. Int. 6.27e6 ES-206 1.90e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.29e3 3.13e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.25e7 45.73 50.0 Abs. Int. 7.77e6 ES-206 2.34e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.08e3 0.00e0 RT 3.89e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6144, 7443 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 20 of 21 172 of 417 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-209 1.84e5 51.25 Rel. Int. 100% Abs. Int. 4.31e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 4.82e2 2.16e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.52e5 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.02e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.04e2 1.51e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.09e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.59e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 8.47e2 3.29e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.60e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.33e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.14e2 2.66e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.18e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.59e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4095, 3490 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 21 of 21 173 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.15e7 2.57e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.58e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.83e7 9.14e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.88e7 9.41e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.05e7 5.26e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.25e6 2.63e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.06e6 2.53e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 983-753 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:09 Page 1 of 21 174 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.12 32.64 36.12 35.58 35.11 34.82 38.73 41.29 40.30 44.01 46.14 51.26 1.44E+06 1.43E+06 1.07E+06 1.23E+06 1.13E+06 1.24E+06 9.39E+05 1.93E+06 1.07E+06 9.43E+05 8.81E+05 6.80E+05 0.79 Y 0.81 Y 0.63 Y 0.64 Y 0.62 Y 0.61 Y 0.63 Y 1.26 Y 1.25 Y 1.29 Y 1.07 Y 1.22 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.11 1.13 1.02 1.16 1.13 1.20 1.07 1.07 1.13 1.07 1.00 1.10 -3.6% 0.8% -7.9% -3.3% -5.3% -1.2% -3.3% -2.5% -2.8% -4.8% -6.6% -1.1% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.05 14.37 14.63 20.39 17.75 26.75 20.68 33.10 32.63 25.69 36.09 35.55 35.09 34.80 38.71 36.68 30.66 41.27 40.28 43.99 43.50 42.43 35.55 46.12 40.09 48.29 49.76 45.73 51.23 2.45E+08 2.19E+08 1.05E+08 2.08E+08 1.01E+08 1.55E+08 8.14E+07 1.30E+08 1.27E+08 6.93E+07 1.04E+08 1.06E+08 1.01E+08 1.03E+08 8.78E+07 6.38E+07 9.19E+07 1.81E+08 9.51E+07 8.81E+07 5.21E+07 6.14E+07 5.38E+07 8.78E+07 5.52E+07 6.89E+07 4.58E+07 6.49E+07 6.17E+07 3.30 Y 3.33 Y 1.62 Y 1.56 Y 1.09 Y 1.10 Y 0.81 Y 0.82 Y 0.82 Y 1.68 Y 1.61 Y 1.64 Y 1.61 Y 1.61 Y 1.58 Y 1.31 Y 1.28 Y 1.29 Y 1.28 Y 1.26 Y 1.09 Y 1.09 Y 1.11 Y 1.03 Y 0.93 Y 0.90 Y 0.81 Y 0.80 Y 1.20 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.22 1.09 0.52 1.04 0.50 1.64 0.86 1.37 1.35 0.80 1.21 1.22 1.17 1.20 1.02 1.11 1.60 1.57 1.65 1.53 0.93 1.10 0.93 1.57 0.96 1.23 0.82 1.16 1.10 2.1% 0.4% -0.1% -0.5% -0.8% -1.1% 0.2% -0.7% -1.5% 0.0% 0.7% 0.5% 0.8% 0.9% -0.9% -0.4% 0.6% -1.9% -1.0% -1.6% -1.8% -3.7% -0.5% -1.0% -1.1% -1.2% -1.4% -1.4% -0.7% Page 1 of 6 175 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.18 33.12 38.12 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.58 Y 1.10 Y 1.11 1.03 0.62 1.12 1.02 0.61 0.7% -0.8% -1.9% CS PCB-28 CS PCB-111 CS PCB-178 23.18 33.12 38.12 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.58 Y 1.10 Y 1.85 1.22 0.58 1.84 1.22 0.57 -0.4% 0.1% -2.4% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.63 24.81 30.82 37.74 47.89 2.01E+08 9.43E+07 8.62E+07 5.75E+07 5.60E+07 1.58 Y 0.81 Y 1.61 Y 1.31 Y 0.90 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.06 14.39 14.65 20.41 17.77 26.77 20.70 25.71 30.68 35.57 40.11 48.31 45.75 49.78 2.30E+06 2.16E+06 1.26E+06 2.04E+06 1.13E+06 1.62E+06 1.09E+06 9.78E+05 1.15E+06 7.09E+05 5.78E+05 7.06E+05 7.23E+05 5.11E+05 3.36 Y 3.09 Y 1.52 Y 1.55 Y 1.07 Y 1.01 Y 0.81 Y 0.64 Y 1.32 Y 1.05 Y 0.95 Y 0.90 Y 0.82 Y 0.79 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.94 0.98 1.20 0.98 1.12 1.05 1.34 1.41 1.25 1.32 1.05 1.03 1.11 1.11 -1.3% -2.5% -2.4% -4.0% -2.6% -3.0% -0.7% -1.5% -1.1% 3.9% -0.5% -3.2% -0.7% 0.0% Page 2 of 6 176 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 12.06 14.20 14.39 14.65 14.83 16.65 16.82 17.04 17.35 17.47 19.04 19.83 20.12 20.41 17.77 19.54 19.95 20.14 20.28 20.37 20.85 22.01 22.16 22.45 22.64 22.93 23.21 23.39 23.77 25.16 25.48 26.02 26.41 26.77 20.70 22.70 23.29 23.37 23.57 24.83 24.97 25.06 25.26 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 2.30E+06 2.22E+06 2.16E+06 1.26E+06 1.99E+06 1.98E+06 2.15E+06 1.96E+06 1.92E+06 2.06E+06 2.37E+06 1.97E+06 4.01E+06 2.04E+06 1.13E+06 2.96E+06 1.29E+06 1.77E+06 1.71E+06 9.51E+05 1.93E+06 1.70E+06 1.69E+06 3.54E+06 1.76E+06 1.79E+06 3.35E+06 3.53E+06 1.63E+06 1.74E+06 1.81E+06 1.68E+06 1.52E+06 1.62E+06 1.09E+06 2.16E+06 9.68E+05 1.04E+06 8.57E+05 1.06E+06 1.35E+06 8.63E+05 2.50E+06 RA 3.36 Y 3.19 Y 3.09 Y 1.52 Y 1.53 Y 1.52 Y 1.55 Y 1.59 Y 1.63 Y 1.64 Y 1.53 Y 1.60 Y 1.64 Y 1.55 Y 1.07 Y 1.02 Y 1.05 Y 1.07 Y 1.05 Y 1.08 Y 1.04 Y 1.01 Y 1.02 Y 1.00 Y 0.93 Y 1.00 Y 0.97 Y 1.00 Y 0.98 Y 0.96 Y 0.98 Y 1.02 Y 0.97 Y 1.01 Y 0.81 Y 0.78 Y 0.81 Y 0.82 Y 0.74 Y 0.77 Y 0.75 Y 0.75 Y 0.75 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.94 1.01 0.98 1.20 1.90 0.95 1.03 0.94 0.92 0.99 1.14 0.95 0.96 0.98 1.12 1.47 1.28 1.76 1.69 0.94 1.91 1.09 1.09 1.14 1.14 1.16 1.08 1.14 1.05 1.12 1.16 1.08 0.98 1.05 1.34 0.85 0.76 0.82 0.68 0.83 1.06 0.68 0.98 Dev'n -1.3% -2.1% -2.5% -2.4% -4.3% 0.8% -1.3% -5.2% -7.9% -4.3% -3.6% -6.2% -2.7% -4.0% -2.6% -4.3% -1.9% -3.4% -1.8% -6.2% -0.2% -3.6% -5.7% -2.6% -1.8% -5.5% -4.5% -3.0% -2.5% -4.1% -3.9% -1.9% -5.4% -3.0% -0.7% -2.9% -0.6% -4.6% -3.4% -1.4% -4.6% -4.4% -3.8% 177 of 417 PCB QC Summary - Ax2 Detail Lab ID: CS1_131220_PCB_XA Acquired: 20-DEC-2013 16:14 Datafile: 131220X03 Name RT PCB-48 22'45-TeCB 25.54 PCB-44/47/65 ...-TeCB 25.76 PCB-59/62/75 ...-TeCB 26.04 PCB-42 22'34'-TeCB 26.20 PCB-41 22'34-TeCB 26.54 PCB-71/40 23'4'6/22'33'-TeCB 26.63 PCB-64 234'6-TeCB 26.83 PCB-72 23'55'-TeCB 27.55 PCB-68 23'45'-TeCB 27.81 PCB-57 233'5-TeCB 28.18 PCB-58 233'5'-TeCB 28.38 PCB-67 23'45-TeCB 28.54 PCB-63 234'5-TeCB 28.77 PCB-61/70/74/76 ...-TeCB 29.06 PCB-66 23'44'-TeCB 29.34 PCB-55 233'4-TeCB 29.49 PCB-56 233'4'-TeCB 29.93 PCB-60 2344'-TeCB 30.12 PCB-80 33'55'-TeCB 30.45 PCB-79 33'45'-TeCB 31.78 PCB-78 33'45-TeCB 32.27 PCB-104 22'466'-PeCB 25.71 PCB-96 22'366'-PeCB 26.03 PCB-103 22'45'6-PeCB 27.72 PCB-94 22'356'-PeCB 27.91 PCB-95 22'35'6-PeCB 28.30 PCB-100/93 22'44'6/22'356-PeCB 28.51 PCB-102 22'456'-PeCB 28.63 PCB-98 22'34'6'-PeCB 28.69 PCB-88 22'346-PeCB 28.99 PCB-91 22'34'6-PeCB 29.06 PCB-84 22'33'6-PeCB 29.25 PCB-89 22'346'-PeCB 29.67 PCB-121 23'45'6-PeCB 30.02 PCB-92 22'355'-PeCB 30.33 PCB-113/90/101 ...-PeCB 30.82 PCB-83 22'33'5-PeCB 31.26 PCB-99 22'44'5-PeCB 31.36 PCB-112 233'56-PeCB 31.46 PCB-108/119/86/97/125...-PeCB 31.80 PCB-117 234'56-PeCB 32.34 PCB-116/85 23456/22'344'-PeCB 32.43 PCB-110 233'4'6-PeCB 32.54 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.01E+06 3.36E+06 4.29E+06 9.26E+05 8.37E+05 2.09E+06 1.50E+06 1.50E+06 1.57E+06 1.41E+06 1.44E+06 1.59E+06 1.60E+06 5.90E+06 1.35E+06 1.40E+06 1.33E+06 1.42E+06 1.64E+06 1.69E+06 1.26E+06 9.78E+05 8.58E+05 9.36E+05 7.83E+05 8.29E+05 1.71E+06 9.57E+05 7.04E+05 7.38E+05 9.82E+05 6.84E+05 7.66E+05 1.19E+06 8.33E+05 2.96E+06 7.27E+05 9.10E+05 1.16E+06 5.82E+06 1.19E+06 1.79E+06 1.10E+06 RA 0.77 Y 0.79 Y 0.80 Y 0.75 Y 0.80 Y 0.82 Y 0.75 Y 0.80 Y 0.77 Y 0.85 Y 0.79 Y 0.76 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.78 Y 0.78 Y 0.76 Y 0.80 Y 0.77 Y 0.64 Y 0.71 Y 0.64 Y 0.65 Y 0.59 Y 0.59 Y 0.62 Y 0.64 Y 0.59 Y 0.56 Y 0.58 Y 0.63 Y 0.67 Y 0.61 Y 0.62 Y 0.67 Y 0.63 Y 0.65 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.79 0.88 1.13 0.73 0.66 0.82 1.18 1.18 1.24 1.11 1.13 1.25 1.26 1.16 1.06 1.10 1.05 1.12 1.29 1.33 0.99 1.41 1.24 0.91 0.76 0.80 0.83 0.93 0.68 0.72 0.95 0.66 0.74 1.15 0.81 0.96 0.70 0.88 1.12 0.94 1.15 0.87 1.07 Dev'n -5.5% -2.5% -3.3% -4.4% -5.2% -4.1% -3.1% -2.1% -3.0% -4.3% -4.0% -0.7% -3.2% -3.0% -3.5% -1.8% -5.4% -1.4% -1.8% 1.6% -6.5% -1.5% 0.8% -2.5% -5.2% -7.3% -4.0% -4.2% -10.0% -10.4% 0.8% -7.4% -2.8% -3.9% -1.6% -2.9% -1.5% -4.2% -3.8% -4.0% 1.3% -7.6% -4.4% 178 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 32.63 32.83 33.15 33.54 34.51 34.72 34.94 35.40 37.35 30.68 30.84 30.98 31.29 31.56 32.83 33.36 33.57 33.83 34.13 34.31 34.39 34.66 34.83 34.98 35.21 35.61 35.95 36.17 36.29 36.72 36.86 37.21 37.41 37.49 37.78 37.92 38.10 38.84 39.65 39.89 35.57 35.85 36.32 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.15E+06 6.91E+05 1.20E+06 1.18E+06 2.12E+06 1.09E+06 1.12E+06 1.01E+06 1.08E+06 1.15E+06 1.03E+06 1.02E+06 8.99E+05 1.00E+06 7.25E+05 1.44E+06 8.24E+05 7.12E+05 1.47E+06 5.72E+05 7.05E+05 1.49E+06 6.51E+05 5.89E+05 6.45E+05 7.07E+05 8.89E+05 7.40E+05 9.19E+05 1.81E+06 6.67E+05 6.08E+05 7.27E+05 9.46E+05 2.21E+06 9.44E+05 1.05E+06 1.64E+06 1.05E+06 9.62E+05 7.09E+05 6.25E+05 5.87E+05 RA 0.66 Y 0.62 Y 0.64 Y 0.65 Y 0.63 Y 0.61 Y 0.63 Y 0.63 Y 0.63 Y 1.32 Y 1.37 Y 1.19 Y 1.33 Y 1.26 Y 1.41 Y 1.27 Y 1.31 Y 1.24 Y 1.29 Y 1.37 Y 1.29 Y 1.23 Y 1.25 Y 1.28 Y 1.26 Y 1.26 Y 1.25 Y 1.25 Y 1.24 Y 1.24 Y 1.26 Y 1.33 Y 1.30 Y 1.33 Y 1.21 Y 1.29 Y 1.33 Y 1.18 Y 1.27 Y 1.13 Y 1.05 Y 1.09 Y 1.02 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.11 0.67 1.17 1.14 1.03 1.05 1.08 0.96 1.04 1.25 1.12 1.10 0.98 1.09 1.14 1.13 1.29 1.12 1.15 0.90 1.10 1.16 1.02 0.92 1.01 1.11 1.39 1.16 1.44 1.42 1.05 0.95 1.14 1.48 1.15 1.48 1.64 0.86 1.11 1.01 1.32 1.16 1.09 Dev'n -4.2% -4.0% -4.5% -5.6% -6.4% -16.1% -2.0% -3.7% -5.5% -1.1% -4.2% -6.1% -8.3% -2.4% -3.9% -1.1% -3.8% -5.7% -2.3% -3.0% -2.2% -3.5% -0.6% -6.8% -2.0% -2.1% -1.1% -3.5% -5.3% -2.7% -4.0% -2.0% -2.1% -1.0% -3.2% -2.3% -1.2% -4.3% -0.8% -5.6% 3.9% 0.1% -3.2% 179 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 36.61 37.01 38.14 38.69 38.91 39.09 39.44 39.52 39.63 40.01 40.36 40.54 41.89 42.14 42.42 42.75 43.52 43.98 40.11 40.90 41.48 41.67 41.76 44.09 44.67 44.84 45.96 47.91 48.31 45.75 46.54 49.78 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 6.55E+05 5.96E+05 4.31E+05 6.43E+05 6.87E+05 6.98E+05 7.24E+05 6.34E+05 6.37E+05 5.78E+05 6.58E+05 1.11E+06 5.95E+05 7.80E+05 1.50E+06 8.57E+05 5.51E+05 8.22E+05 5.78E+05 6.75E+05 6.21E+05 6.41E+05 5.73E+05 8.75E+05 4.40E+05 4.68E+05 5.10E+05 5.61E+05 7.06E+05 7.23E+05 7.50E+05 5.11E+05 RA 1.14 Y 1.00 Y 1.08 Y 1.04 Y 1.08 Y 1.03 Y 1.15 Y 1.02 Y 1.07 Y 1.13 Y 1.09 Y 1.08 Y 1.09 Y 1.06 Y 0.95 Y 1.12 Y 0.98 Y 1.07 Y 0.95 Y 0.92 Y 0.94 Y 0.90 Y 0.90 Y 0.91 Y 0.99 Y 0.92 Y 0.94 Y 0.90 Y 0.90 Y 0.82 Y 0.80 Y 0.79 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.22 1.11 0.80 1.05 1.12 1.14 1.18 1.03 1.04 0.94 1.07 0.90 0.97 1.27 1.22 1.40 1.06 1.58 1.05 1.22 1.13 1.16 1.04 0.79 0.80 0.85 0.74 0.82 1.03 1.11 1.16 1.11 Dev'n -1.2% -1.5% -4.9% -2.3% -1.7% -3.2% -2.1% -2.6% 4.9% -1.0% -1.4% -4.7% -2.0% -1.3% -3.0% 0.1% -6.8% -5.0% -0.5% 0.1% 0.8% -2.4% -6.2% -2.0% -4.4% -3.0% -3.4% -3.3% -3.2% -0.7% -2.9% 0.0% 180 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-1 1.77e6 12.06 Rel. Int. 100% PCB-2 1.69e6 14.20 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.00e3 Abs. Int. 7.15e5 PCB-3 1.63e6 14.39 3.57e5 0% 11.0 12.0 13.0 PCB-1 5.28e5 12.06 Rel. Int. 100% 14.0 PCB-2 5.29e5 14.20 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.63e3 15.0 0.00e0 16.0 RT Abs. Int. 2.17e5 PCB-3 5.27e5 14.38 1.08e5 0% 11.0 12.0 13.0 14.0 ES-1 1.88e8 12.05 Rel. Int. 100% 15.0 Abs. Int. 7.30e7 ES-3 1.69e8 14.37 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.69e3 0.00e0 16.0 RT 3.65e7 0% 11.0 12.0 13.0 14.0 ES-1 5.69e7 12.05 Rel. Int. 100% 15.0 Abs. Int. 2.24e7 ES-3 5.06e7 14.37 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.35e4 0.00e0 16.0 RT 1.12e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2722, 6482 scc: 983-753 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 2 of 21 181 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Rel. Int. 100% PCB-4 7.61e5 14.65 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.83e3 PCB-10 1.20e6 14.83 2.01e5 0% 11.0 12.0 13.0 14.0 Rel. Int. 100% 15.0 PCB-4 5.00e5 14.64 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.52e4 PCB-10 7.85e5 14.83 0% 12.0 13.0 0.00e0 16.0 RT Abs. Int. 2.69e5 1.35e5 PFK INTERFERENCE 11.0 Abs. Int. 4.03e5 14.0 15.0 ES-4 6.48e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.20e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 1.02e4 1.10e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.00e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.35e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.10e3 6.77e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9174, 6214 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:09 Page 3 of 21 182 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 8.83e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-6 1.21e6 17.04 PCB-9 1.20e6 16.65 PCB-14 1.43e6 19.04 PCB-5 1.19e6 17.35 PCB-8 1.28e6 17.47 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-11 1.22e6 19.83 13/12 2.49e6 20.12 Abs. Int. 4.02e5 PCB-15 1.24e6 20.41 2.01e5 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.29e4 PCB-9 7.88e5 16.65 PCB-7 8.44e5 16.82 18.0 19.0 PCB-14 9.38e5 19.04 PCB-5 7.31e5 PCB-8 17.35 7.79e5 17.47 PFK INTERFERENCE 20.0 PCB-11 7.59e5 19.83 13/12 1.52e6 20.12 21.0 Abs. Int. 3.35e5 PCB-15 7.98e5 20.41 1.67e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.23e8 16.63 21.0 0.00e0 RT Abs. Int. 3.85e7 ES-15 1.27e8 20.39 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.10e4 1.93e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.80e7 16.63 21.0 ES-15 8.13e7 20.39 0.00e0 RT Abs. Int. 2.48e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.06e3 1.24e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9567, 5816 scc: 983-753 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 4 of 21 183 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 30/18 1.50e6 19.54 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.85e3 PCB-19 5.82e5 17.77 Abs. Int. 4.10e5 PCB-27 9.13e5 20.14 PCB-17 6.61e5 19.95 PCB-16 4.95e5 20.37 PCB-32 9.84e5 20.85 2.05e5 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 1.47e6 19.54 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 2.47e3 PCB-19 5.45e5 17.76 PCB-17 6.30e5 19.95 21.0 Abs. Int. 4.07e5 PCB-27 8.57e5 20.14 PCB-16 4.56e5 20.37 PCB-32 9.46e5 20.85 2.04e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 2.14e7 ES-19 5.26e7 17.75 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 7.23e4 0.00e0 RT 1.07e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.97e7 ES-19 4.83e7 17.75 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 4.38e4 0.00e0 RT 9.86e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7724, 7248 scc: 983-753 Revised: 27-Dec-2013 11:30 (LKB) Printed: 03-Jan-2014 17:09 Page 5 of 21 184 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 28/20 1.65e6 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.02e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-23 PCB-34 8.55e5 8.51e5 22.16 22.01 26/29 1.77e6 22.45 PCB-31 8.95e5 22.93 Abs. Int. 4.21e5 PCB-22 8.08e5 23.77 PCB-36 8.50e5 25.16 PCB-39 8.93e5 25.48 PCB-38 8.46e5 26.02 PCB-35 7.51e5 26.41 PCB-37 8.13e5 26.77 0% 22.0 24.0 25.0 26.0 27.0 28/20 1.70e6 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.84e3 23.0 PCB-23 PCB-34 8.35e5 8.46e5 22.16 22.01 26/29 1.77e6 22.45 PCB-31 9.00e5 22.92 23.0 PCB-22 8.24e5 23.77 PCB-36 8.89e5 25.16 PCB-39 9.12e5 25.48 PCB-38 8.33e5 26.02 24.0 25.0 PCB-35 7.74e5 26.41 PCB-37 8.08e5 26.77 26.0 CS/SS-28 9.06e7 23.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.28e5 0% 22.0 2.11e5 27.0 0.00e0 RT Abs. Int. 2.54e7 ES-37 8.13e7 26.75 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 1.13e5 2.14e5 1.27e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.29e7 23.18 Rel. Int. 100% 27.0 Abs. Int. 2.36e7 ES-37 7.38e7 26.75 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 3.74e4 0.00e0 RT 1.18e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2047, 2588 scc: 983-753 Revised: 27-Dec-2013 11:30 (LKB) Printed: 03-Jan-2014 17:09 Page 6 of 21 185 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-54 4.89e5 20.70 Rel. Int. 100% Abs. Int. 1.37e5 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.36e3 6.83e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 6.03e5 20.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e5 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.17e3 9.39e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.65e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 2.02e4 5.12e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.49e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 8.82e3 6.20e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7968, 7088 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:09 Page 7 of 21 186 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 1.58e3 50/53 9.50e5 22.70 PCB-51 4.70e5 23.37 PCB-45 4.32e5 23.29 PCB-73 PCB-52 5.78e5 4.59e5 24.97 24.83 PCB-46 3.64e5 23.57 69/49 1.07e6 25.26 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 44/47… 1.48e6 25.76 59/62… 1.91e6 26.04 PCB-48 4.38e5 25.54 PCB-42 3.97e5 26.20 71/40 9.42e5 26.63 PCB-41 3.71e5 26.54 Abs. Int. 3.53e5 PCB-64 6.46e5 26.83 1.77e5 27.0 0.00e0 RT 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.72e3 50/53 1.21e6 22.70 24.0 PCB-51 5.71e5 23.37 PCB-45 5.36e5 23.29 25.0 PCB-73 7.69e5 PCB-52 24.97 5.98e5 24.83 PCB-46 4.93e5 23.57 26.0 69/49 1.42e6 25.26 59/62… 44/47… 2.38e6 1.87e6 26.04 25.76 PCB-48 5.68e5 25.54 PCB-42 5.29e5 26.20 71/40 1.15e6 26.63 PCB-41 4.66e5 26.54 Abs. Int. 4.32e5 PCB-64 8.56e5 26.83 2.16e5 27.0 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.22e7 24.81 Rel. Int. 100% Abs. Int. 1.13e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.67e4 5.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.21e7 24.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.42e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 2.28e4 7.10e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4359, 5676 scc: 983-753 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 8 of 21 187 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 61/70... 2.59e6 29.06 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 3.33e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-57 6.50e5 28.18 PCB-63 7.04e5 28.77 PCB-55 6.16e5 29.49 Abs. Int. 3.24e5 PCB-60 6.21e5 PCB-80 7.09e5 30.12 30.45 PCB-81 6.42e5 32.64 PCB-79 7.50e5 31.78 PCB-77 6.36e5 33.12 1.62e5 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 2.68e3 PCB-68 8.90e5 27.81 30.0 61/70... 3.32e6 PCB-60 PCB-67 29.06 8.00e5 9.01e5 30.12 28.54 PCB-63 PCB-66 PCB-80 PCB-56 8.91e5 7.50e5 9.28e5 7.48e5 28.77 29.34 30.45 29.93 32.0 34.0 36.0 38.0 Abs. Int. 4.24e5 PCB-81 7.90e5 32.64 PCB-79 9.35e5 31.78 PCB-77 8.03e5 33.12 2.12e5 0% 28.0 30.0 0.00e0 RT 32.0 Rel. Int. 100% 34.0 ES-81 5.70e7 32.63 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.49e4 36.0 38.0 0.00e0 RT Abs. Int. 1.53e7 ES-77 5.83e7 33.10 7.63e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.00e7 32.63 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.91e4 36.0 38.0 0.00e0 RT Abs. Int. 1.88e7 ES-77 7.13e7 33.10 9.38e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8043, 1494 scc: 983-753 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:31 Printed: 03-Jan-2014 17:10 Page 9 of 21 188 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-104 3.83e5 25.71 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 9.09e2 Abs. Int. 9.50e4 PCB-96 3.57e5 26.03 4.75e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 5.96e5 25.71 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 8.81e2 27.0 0.00e0 RT Abs. Int. 1.52e5 PCB-96 5.01e5 26.03 7.58e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.34e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.97e3 5.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.59e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.60e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 1.70e3 3.30e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7311, 3592 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:10 Page 10 of 21 189 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 5.53e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 108/119... 2.22e6 31.80 (4.35e5 + 6.99e5) * 100 pg/uL RRF(PCB-118) = = 1.13 (6.20e7 + 3.86e7) * 1.0 pg/uL 113/90… 100/9311:45 LKB 03-Jan-2014 1.13e6 6.34e5 30.82 PCB-121 PCB-99 28.51 PCB-88 PCB-103 4.78e5 3.53e5 3.66e5 30.02 2.75e5 31.36 27.72 28.99 116/85 6.89e5 32.43 PCB-111 4.71e5 PCB-120 33.15 4.66e5 33.54 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-118 107/124 4.35e5 8.23e5 35.11 34.51 PCB-123 PCB-114 4.68e5 4.77e5 34.82 35.58 Abs. Int. 3.39e5 PCB-105 4.12e5 36.12 PCB-127 4.20e5 37.35 1.70e5 0% 28.0 30.0 32.0 108/119... 3.61e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 7.14e3 34.0 PCB-94 4.74e5 27.91 100/93 1.08e6 28.51 PCB-91 6.28e5 29.06 PCB-89 4.69e5 29.67 113/90… 1.83e6 30.82 PCB-112 PCB-92 7.02e5 5.18e5 31.46 30.33 116/85 PCB-115 1.10e6 6.93e5 32.43 32.63 PCB-110 PCB-111 PCB-117 7.33e5 PCB-120 6.81e5 7.35e5 7.14e5 33.14 32.54 32.34 33.54 36.0 PCB-118 107/124 6.99e5 1.30e6 35.11 34.51 PCB-123 PCB-114 7.67e5 7.51e5 34.82 35.58 38.0 Abs. Int. 5.56e5 PCB-105 6.57e5 36.12 PCB-127 6.61e5 37.35 2.78e5 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 6.46e7 33.12 JS-101 5.31e7 30.82 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.82e3 34.0 36.0 ES-123 6.36e7 34.80 ES-114 6.56e7 35.55 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.61e7 ES-105 6.43e7 36.09 8.07e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.08e7 33.12 JS-101 3.31e7 30.82 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.71e3 34.0 36.0 ES-118 ES-123 3.86e7 3.96e7 35.09 34.80 38.0 0.00e0 RT Abs. Int. 1.02e7 ES-105 4.00e7 36.09 5.09e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7344, 6760 scc: 983-753 Revised: 30-Dec-2013 13:07 (LKB) Printed: 03-Jan-2014 17:10 Page 11 of 21 190 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Abs. Int. 9.23e4 PCB-126 3.63e5 38.73 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.27e3 4.61e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.52e5 PCB-126 5.76e5 38.73 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.57e3 7.61e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.28e7 ES-126 5.38e7 38.71 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.43e3 6.40e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.29e6 ES-126 3.40e7 38.71 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 7.41e3 4.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0821, 7826 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 12 of 21 191 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-136 5.13e5 31.29 PCB-155 PCB-150 5.51e5 PCB-145 6.53e5 30.98 5.58e5 30.68 31.56 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.22e2 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 147/149 139/140 8.25e5 8.18e5 34.13 34.66 PCB-148 4.24e5 32.83 151/135 8.04e5 PCB-144 PCB-143 PCB-133 PCB-146 33.36 3.94e5 3.96e5 PCB-142 3.94e5 4.11e5 3.30e5 36.17 33.83 34.39 35.61 34.98 153/168 1.00e6 36.72 PCB-141 3.72e5 36.86 163/138… 1.21e6 37.78 PCB-164 PCB-160 5.40e5 5.32e5 37.49 37.92 1.11e5 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PCB-150 PCB-155 4.64e5 4.93e5 30.98 30.68 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 8.63e2 PCB-145 4.42e5 31.56 PCB-148 3.01e5 32.83 147/149 139/140 151/135 6.41e5 6.67e5 6.33e5 34.66 34.13 33.35 PCB-154 PCB-143 PCB-132 3.56e5 3.08e5 2.85e5 33.57 34.39 35.21 36.0 38.0 153/168 8.09e5 36.72 PCB-165 3.96e5 35.95 163/138… 1.00e6 37.78 PCB-137 PCB-141 3.17e5 2.95e5 37.41 36.86 30.0 32.0 34.0 36.0 ES-155 5.16e7 30.66 Rel. Int. 100% HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.53e3 Abs. Int. 1.88e5 9.41e4 38.0 ES-153 3.62e7 36.68 0.00e0 RT PCB-158 4.50e5 38.10 0% 28.0 Abs. Int. 2.21e5 JS-138 3.26e7 37.74 0.00e0 RT Abs. Int. 1.25e7 6.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.04e7 30.66 Rel. Int. 100% ES-153 2.76e7 36.68 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.37e3 0.00e0 RT Abs. Int. 9.99e6 JS-138 2.49e7 37.74 4.99e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4865, 1501 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 13 of 21 192 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 8.84e5 38.84 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.56e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-162 PCB-159 5.10e5 5.87e5 39.89 39.65 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 156/157 1.08e6 41.29 Abs. Int. 2.09e5 PCB-167 5.96e5 40.30 PCB-169 5.31e5 44.01 1.04e5 0% 39.0 Rel. Int. 100% 128/166 7.52e5 38.84 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.20e3 40.0 PCB-162 PCB-159 4.52e5 39.89 4.64e5 39.65 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.82e5 156/157 8.55e5 41.28 PCB-169 4.12e5 44.00 PCB-167 4.78e5 40.30 9.11e4 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.33e7 40.28 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 8.34e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.02e8 41.27 (1.02e8 + 7.90e7) * 100 pg/uL RRF(ES-156/157) = = 1.57 (3.26e7 + 2.49e7) * 200 pg/uL LKB 03-Jan-2014 11:48 0.00e0 RT Abs. Int. 1.85e7 ES-169 4.92e7 43.99 9.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 7.90e7 41.27 Rel. Int. 100% ES-167 4.18e7 40.28 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 9.96e3 0.00e0 RT Abs. Int. 1.47e7 ES-169 3.89e7 43.99 7.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2729, 9872 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 14 of 21 193 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% PCB-188 3.62e5 35.57 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.15e2 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-179 3.26e5 PCB-184 2.97e5 35.85 36.32 PCB-186 2.98e5 37.01 Abs. Int. 8.73e4 PCB-178 2.24e5 38.14 4.37e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 3.46e5 35.57 PCB-179 2.99e5 35.85 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.25e2 37.0 PCB-176 3.06e5 36.61 PCB-186 2.98e5 37.01 38.0 Abs. Int. 8.68e4 PCB-178 2.07e5 38.14 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.82e7 35.55 Rel. Int. 100% CS/SS-178 1.71e7 38.12 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.55e7 35.55 Rel. Int. 100% CS/SS-178 1.56e7 38.12 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.55e6 0.00e0 RT Abs. Int. 6.62e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.42e3 31.0 4.34e4 Abs. Int. 7.11e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.34e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 3.31e6 0.00e0 RT Abs. Int. 1.88e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6233, 0370 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 15 of 21 194 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.17e3 PCB-182 PCB-183 3.55e5 3.87e5 39.44 39.09 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-177 PCB-181 3.06e5 3.43e5 40.01 40.36 171/173 5.75e5 40.54 PCB-172 3.10e5 41.89 180/193 7.33e5 42.42 PCB-192 4.01e5 42.14 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Abs. Int. 1.52e5 PCB-191 4.53e5 42.75 PCB-170 2.72e5 43.52 PCB-190 4.24e5 43.98 7.59e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.47e3 40.0 41.0 PCB-182 PCB-185 3.14e5 3.43e5 171/173 39.52 39.09 5.34e5 PCB-187 PCB-181 40.54 PCB-183 3.31e5 PCB-174 PCB-177 3.15e5 3.37e5 38.91 3.08e5 40.36 2.71e5 39.4439.63 40.01 42.0 43.0 180/193 7.69e5 42.42 PCB-172 2.85e5 41.89 PCB-191 4.05e5 42.75 44.0 45.0 Abs. Int. 1.26e5 PCB-190 3.97e5 43.98 PCB-170 2.79e5 43.52 6.28e4 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.20e7 42.43 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 8.23e6 ES-170 2.71e7 43.50 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 2.53e3 0.00e0 RT 4.12e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.93e7 42.43 Rel. Int. 100% 44.0 45.0 Abs. Int. 7.29e6 ES-170 2.50e7 43.50 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.41e3 0.00e0 RT 3.64e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7891, 3827 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 16 of 21 195 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-189 4.54e5 46.14 Abs. Int. 1.16e5 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.02e3 5.81e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 4.26e5 46.14 Abs. Int. 1.09e5 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 8.26e2 5.43e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.46e7 46.12 0.00e0 RT Abs. Int. 1.06e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 6.63e3 5.31e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.32e7 46.12 0.00e0 RT Abs. Int. 1.01e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.18e3 5.03e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5887, 3655 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 17 of 21 196 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-202 2.82e5 40.11 Rel. Int. 100% PCB-201 3.23e5 40.90 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 7.19e2 PCB-197 3.04e5 PCB-204 41.67 PCB-200 3.00e5 2.72e5 41.48 41.76 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 198/199 4.18e5 44.09 Abs. Int. 8.33e4 PCB-196 2.19e5 44.67 PCB-203 2.24e5 44.84 0% 39.0 Rel. Int. 100% 40.0 PCB-202 2.96e5 40.11 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.84e2 41.0 PCB-201 3.52e5 40.90 42.0 43.0 44.0 45.0 198/199 4.57e5 44.09 PCB-197 3.38e5PCB-200 PCB-204 41.67 3.01e5 3.20e5 41.76 41.48 40.0 41.0 42.0 PCB-196 2.21e5 44.66 43.0 44.0 PCB-203 2.44e5 44.84 4.51e4 45.0 ES-202 2.66e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.01e4 0% 39.0 4.17e4 0.00e0 RT Abs. Int. 6.53e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.52e3 3.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.85e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.30e3 3.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3815, 7054 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 18 of 21 197 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 8.34e2 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-205 3.35e5 48.31 PCB-195 2.47e5 45.96 Abs. Int. 7.93e4 PCB-194 2.65e5 47.91 3.97e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 7.51e2 47.0 48.0 49.0 50.0 PCB-205 3.71e5 48.31 PCB-195 2.63e5 45.96 0.00e0 RT Abs. Int. 9.00e4 PCB-194 2.96e5 47.91 4.50e4 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.26e7 48.29 Rel. Int. 100% Abs. Int. 7.66e6 JS-194 2.66e7 47.89 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.09e3 0.00e0 RT 3.83e6 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.63e7 48.29 JS-194 2.94e7 47.89 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.82e3 49.0 0.00e0 RT Abs. Int. 8.37e6 4.19e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1382, 4116 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 19 of 21 198 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.01e3 PCB-208 3.26e5 45.75 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-207 3.34e5 46.54 Abs. Int. 8.61e4 PCB-206 2.25e5 49.78 4.30e4 0% 46.0 Rel. Int. 100% PCB-208 3.97e5 45.75 47.0 48.0 49.0 PCB-207 4.16e5 46.54 50.0 Abs. Int. 1.01e5 PCB-206 2.86e5 49.78 NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.89e3 5.06e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.87e7 45.73 50.0 0.00e0 RT Abs. Int. 6.89e6 ES-206 2.06e7 49.76 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.22e3 3.45e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.61e7 45.73 50.0 Abs. Int. 8.47e6 ES-206 2.53e7 49.76 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.67e3 0.00e0 RT 4.24e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0808, 5245 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 20 of 21 199 of 417 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-209 3.74e5 51.26 Rel. Int. 100% Abs. Int. 7.55e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.21e2 3.77e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 3.06e5 51.26 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.81e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.94e2 3.41e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.36e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.01e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 8.10e2 3.50e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.81e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.76e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.63e2 2.88e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.06e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.53e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6986, 0137 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 21 of 21 200 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.11 32.63 36.11 35.56 35.10 34.82 38.72 41.28 40.29 44.00 46.13 51.25 7.18E+06 6.81E+06 5.68E+06 6.19E+06 5.72E+06 5.95E+06 4.77E+06 9.62E+06 5.42E+06 4.85E+06 4.61E+06 3.38E+06 0.79 Y 0.77 Y 0.64 Y 0.62 Y 0.60 Y 0.63 Y 0.62 Y 1.25 Y 1.21 Y 1.23 Y 1.02 Y 1.17 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.09 1.08 1.07 1.15 1.13 1.16 1.05 1.05 1.12 1.09 1.03 1.06 -5.2% -3.8% -4.0% -4.1% -5.1% -3.9% -5.1% -4.7% -3.2% -3.1% -3.6% -4.8% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.04 14.36 14.61 20.38 17.73 26.74 20.66 33.09 32.61 25.67 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.26 40.27 43.98 43.49 42.42 35.54 46.11 40.08 48.28 49.75 45.73 51.23 2.39E+08 2.19E+08 1.04E+08 2.08E+08 1.01E+08 1.56E+08 8.13E+07 1.31E+08 1.27E+08 7.00E+07 1.06E+08 1.07E+08 1.01E+08 1.02E+08 9.09E+07 6.37E+07 9.19E+07 1.84E+08 9.64E+07 8.90E+07 5.32E+07 6.31E+07 5.40E+07 8.91E+07 5.60E+07 7.02E+07 4.73E+07 6.67E+07 6.37E+07 3.26 Y 3.37 Y 1.62 Y 1.56 Y 1.08 Y 1.09 Y 0.82 Y 0.80 Y 0.80 Y 1.67 Y 1.61 Y 1.65 Y 1.61 Y 1.58 Y 1.58 Y 1.31 Y 1.33 Y 1.30 Y 1.30 Y 1.30 Y 1.08 Y 1.09 Y 1.06 Y 1.03 Y 0.94 Y 0.89 Y 0.81 Y 0.80 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.21 1.10 0.53 1.05 0.51 1.68 0.88 1.42 1.36 0.82 1.25 1.26 1.19 1.20 1.07 1.13 1.63 1.63 1.71 1.58 0.96 1.13 0.96 1.60 0.99 1.26 0.85 1.20 1.14 1.3% 1.5% 0.5% 0.9% 0.4% 1.0% 1.7% 2.5% -0.2% 2.2% 3.7% 3.3% 2.4% 1.1% 3.7% 1.3% 2.5% 1.9% 2.3% 1.3% 1.0% -0.4% 1.8% 1.0% 2.3% 1.3% 2.3% 1.9% 3.2% Page 1 of 6 201 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.11 38.10 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.62 Y 1.12 Y 1.11 1.03 0.62 1.11 1.03 0.61 -0.2% 0.0% -2.3% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.11 38.10 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.62 Y 1.12 Y 1.85 1.22 0.58 1.86 1.23 0.58 0.9% 1.1% -0.5% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.81 37.73 47.88 1.98E+08 9.28E+07 8.53E+07 5.64E+07 5.57E+07 1.57 Y 0.79 Y 1.59 Y 1.31 Y 0.92 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.05 14.37 14.63 20.39 17.75 26.76 20.68 25.69 30.67 35.56 40.10 48.30 45.75 49.78 1.11E+07 1.07E+07 6.23E+06 1.02E+07 5.64E+06 8.15E+06 5.32E+06 4.90E+06 5.67E+06 3.30E+06 2.80E+06 3.53E+06 3.57E+06 2.55E+06 3.29 Y 3.19 Y 1.60 Y 1.65 Y 1.05 Y 0.98 Y 0.81 Y 0.65 Y 1.29 Y 1.10 Y 0.89 Y 0.93 Y 0.81 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.92 0.98 1.20 0.98 1.12 1.05 1.31 1.40 1.23 1.22 1.00 1.01 1.07 1.08 -2.9% -3.0% -2.9% -4.3% -2.5% -2.9% -3.2% -2.3% -2.2% -3.7% -5.1% -5.1% -4.7% -3.2% Page 2 of 6 202 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 12.05 14.18 14.37 14.63 14.81 16.63 16.80 17.03 17.33 17.45 19.02 19.81 20.11 20.39 17.75 19.52 19.93 20.12 20.26 20.35 20.84 21.99 22.14 22.43 22.63 22.91 23.19 23.38 23.75 25.14 25.46 26.00 26.39 26.76 20.68 22.68 23.27 23.34 23.55 24.82 24.94 25.04 25.24 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 1.11E+07 1.07E+07 1.07E+07 6.23E+06 1.01E+07 9.38E+06 1.06E+07 9.98E+06 1.00E+07 1.05E+07 1.19E+07 1.03E+07 2.02E+07 1.02E+07 5.64E+06 1.52E+07 6.40E+06 8.92E+06 8.42E+06 5.03E+06 9.31E+06 8.68E+06 8.57E+06 1.76E+07 8.79E+06 9.29E+06 1.69E+07 1.76E+07 8.06E+06 8.80E+06 9.00E+06 8.25E+06 7.78E+06 8.15E+06 5.32E+06 1.07E+07 4.46E+06 5.62E+06 4.33E+06 5.19E+06 6.70E+06 4.56E+06 1.26E+07 RA 3.29 Y 3.30 Y 3.19 Y 1.60 Y 1.59 Y 1.58 Y 1.65 Y 1.58 Y 1.62 Y 1.60 Y 1.61 Y 1.64 Y 1.61 Y 1.65 Y 1.05 Y 1.08 Y 1.08 Y 1.07 Y 1.05 Y 1.05 Y 1.07 Y 0.97 Y 1.00 Y 0.99 Y 0.95 Y 0.97 Y 1.00 Y 0.99 Y 1.00 Y 0.98 Y 0.97 Y 0.97 Y 1.00 Y 0.98 Y 0.81 Y 0.80 Y 0.79 Y 0.80 Y 0.78 Y 0.79 Y 0.79 Y 0.75 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.92 0.98 0.98 1.20 1.93 0.90 1.02 0.96 0.96 1.00 1.15 0.99 0.97 0.98 1.12 1.51 1.27 1.77 1.67 1.00 1.85 1.11 1.10 1.13 1.13 1.19 1.08 1.13 1.04 1.13 1.16 1.06 1.00 1.05 1.31 0.84 0.70 0.89 0.68 0.82 1.06 0.72 0.99 Dev'n -2.9% -5.2% -3.0% -2.9% -2.5% -4.6% -2.9% -3.7% -3.7% -2.7% -2.9% -1.9% -1.7% -4.3% -2.5% -1.8% -2.7% -2.6% -3.0% -0.7% -3.7% -1.9% -4.7% -3.4% -2.4% -2.7% -4.3% -3.7% -4.1% -3.4% -4.5% -4.0% -3.9% -2.9% -3.2% -3.9% -8.2% 3.3% -2.0% -2.8% -4.8% 1.4% -2.8% 203 of 417 PCB QC Summary - Ax2 Detail Lab ID: CS2_131220_PCB_XA Acquired: 20-DEC-2013 17:09 Datafile: 131220X04 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.02 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.52 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.79 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.37 PCB-67 23'45-TeCB 28.52 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.05 PCB-66 23'44'-TeCB 29.33 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.11 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.76 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.01 PCB-103 22'45'6-PeCB 27.71 PCB-94 22'356'-PeCB 27.90 PCB-95 22'35'6-PeCB 28.28 PCB-100/93 22'44'6/22'356-PeCB 28.50 PCB-102 22'456'-PeCB 28.61 PCB-98 22'34'6'-PeCB 28.68 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.24 PCB-89 22'346'-PeCB 29.66 PCB-121 23'45'6-PeCB 30.00 PCB-92 22'355'-PeCB 30.32 PCB-113/90/101 ...-PeCB 30.81 PCB-83 22'33'5-PeCB 31.25 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.79 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.42 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.24E+06 1.64E+07 2.14E+07 4.75E+06 4.38E+06 1.05E+07 7.49E+06 7.51E+06 7.85E+06 7.33E+06 7.30E+06 7.81E+06 7.85E+06 2.94E+07 6.87E+06 7.07E+06 6.96E+06 7.00E+06 8.09E+06 8.10E+06 6.61E+06 4.90E+06 4.21E+06 4.65E+06 4.04E+06 4.36E+06 8.64E+06 5.08E+06 3.64E+06 3.75E+06 4.80E+06 3.58E+06 3.81E+06 5.96E+06 4.05E+06 1.47E+07 3.64E+06 4.49E+06 5.95E+06 2.92E+07 5.88E+06 9.01E+06 5.43E+06 RA 0.81 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.81 Y 0.79 Y 0.80 Y 0.75 Y 0.77 Y 0.76 Y 0.77 Y 0.76 Y 0.79 Y 0.76 Y 0.79 Y 0.77 Y 0.78 Y 0.80 Y 0.78 Y 0.79 Y 0.65 Y 0.65 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.63 Y 0.64 Y 0.65 Y 0.63 Y 0.61 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.59 Y 0.64 Y 0.63 Y 0.62 Y 0.62 Y 0.64 Y 0.63 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.83 0.86 1.13 0.75 0.69 0.83 1.18 1.19 1.24 1.16 1.15 1.23 1.24 1.16 1.09 1.12 1.10 1.11 1.28 1.28 1.04 1.40 1.20 0.91 0.79 0.85 0.85 0.99 0.71 0.73 0.94 0.70 0.75 1.16 0.79 0.96 0.71 0.88 1.16 0.95 1.15 0.88 1.06 Dev'n -1.3% -4.4% -3.2% -1.7% -0.5% -3.8% -3.0% -1.9% -2.8% -0.5% -2.1% -2.0% -4.4% -3.0% -1.5% -0.3% -1.0% -2.5% -2.7% -2.0% -1.6% -2.3% -2.0% -2.2% -1.3% -1.5% -2.1% 2.6% -6.0% -8.2% -0.5% -2.1% -2.3% -2.9% -3.5% -2.5% -0.4% -4.7% -0.4% -2.9% 1.1% -6.3% -5.0% 204 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 32.62 32.82 33.13 33.53 34.50 34.71 34.93 35.39 37.34 30.67 30.82 30.97 31.27 31.55 32.82 33.34 33.55 33.82 34.12 34.29 34.38 34.64 34.82 34.96 35.20 35.60 35.94 36.16 36.28 36.71 36.85 37.20 37.40 37.48 37.77 37.91 38.09 38.83 39.64 39.88 35.56 35.84 36.30 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.94E+06 3.45E+06 6.10E+06 6.04E+06 1.09E+07 6.46E+06 5.32E+06 5.09E+06 5.46E+06 5.67E+06 5.18E+06 5.27E+06 4.80E+06 4.89E+06 3.69E+06 7.14E+06 4.14E+06 3.74E+06 7.38E+06 2.81E+06 3.63E+06 7.45E+06 3.13E+06 3.09E+06 3.22E+06 3.47E+06 4.45E+06 3.72E+06 4.78E+06 9.14E+06 3.40E+06 3.05E+06 3.51E+06 4.84E+06 1.09E+07 4.74E+06 5.15E+06 8.23E+06 5.14E+06 4.97E+06 3.30E+06 3.06E+06 2.96E+06 RA 0.60 Y 0.62 Y 0.63 Y 0.64 Y 0.62 Y 0.62 Y 0.64 Y 0.64 Y 0.62 Y 1.29 Y 1.28 Y 1.27 Y 1.26 Y 1.31 Y 1.28 Y 1.23 Y 1.24 Y 1.28 Y 1.29 Y 1.29 Y 1.26 Y 1.28 Y 1.29 Y 1.24 Y 1.28 Y 1.26 Y 1.24 Y 1.30 Y 1.30 Y 1.28 Y 1.30 Y 1.25 Y 1.28 Y 1.28 Y 1.27 Y 1.26 Y 1.28 Y 1.25 Y 1.24 Y 1.21 Y 1.10 Y 1.09 Y 1.03 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.16 0.67 1.19 1.18 1.07 1.26 1.04 0.95 1.03 1.23 1.13 1.15 1.04 1.06 1.16 1.12 1.30 1.17 1.16 0.88 1.14 1.17 0.98 0.97 1.01 1.09 1.40 1.17 1.50 1.43 1.07 0.96 1.10 1.52 1.14 1.49 1.62 0.85 1.07 1.03 1.22 1.13 1.10 Dev'n 0.3% -3.3% -2.3% -2.5% -2.9% 0.8% -5.8% -4.5% -6.2% -2.2% -3.8% -2.5% -2.1% -4.5% -2.2% -1.6% -3.2% -0.8% -1.6% -4.5% 0.8% -3.0% -4.2% -1.9% -2.1% -3.9% -0.9% -2.9% -1.4% -1.6% -2.0% -1.7% -5.3% 1.3% -3.9% -1.7% -2.7% -5.1% -4.4% -3.7% -3.7% -2.3% -2.6% 205 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 36.60 37.00 38.13 38.67 38.90 39.08 39.43 39.52 39.62 40.00 40.35 40.53 41.88 42.13 42.41 42.74 43.51 43.97 40.10 40.89 41.47 41.66 41.75 44.08 44.66 44.83 45.95 47.90 48.30 45.75 46.54 49.78 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 3.29E+06 2.98E+06 2.21E+06 3.31E+06 3.49E+06 3.67E+06 3.83E+06 3.13E+06 3.03E+06 2.93E+06 3.27E+06 5.79E+06 2.98E+06 4.03E+06 7.75E+06 4.20E+06 2.91E+06 4.21E+06 2.80E+06 3.33E+06 3.01E+06 3.09E+06 3.13E+06 4.38E+06 2.29E+06 2.39E+06 2.57E+06 2.84E+06 3.53E+06 3.57E+06 3.79E+06 2.55E+06 RA 1.07 Y 1.06 Y 1.08 Y 1.06 Y 0.96 Y 1.07 Y 1.05 Y 1.08 Y 1.07 Y 1.10 Y 1.08 Y 1.06 Y 1.07 Y 1.06 Y 1.08 Y 1.05 Y 1.04 Y 1.06 Y 0.89 Y 0.92 Y 0.94 Y 0.91 Y 0.89 Y 0.92 Y 0.94 Y 0.93 Y 0.90 Y 0.87 Y 0.93 Y 0.81 Y 0.76 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.22 1.10 0.82 1.05 1.11 1.16 1.21 0.99 0.96 0.93 1.04 0.92 0.95 1.28 1.23 1.33 1.09 1.58 1.00 1.19 1.08 1.11 1.12 0.78 0.82 0.85 0.73 0.81 1.01 1.07 1.14 1.08 Dev'n -1.2% -1.9% -2.7% -2.3% -2.9% -1.0% 0.7% -6.4% -2.8% -2.3% -4.9% -3.1% -4.3% -0.7% -2.6% -4.6% -3.7% -4.7% -5.1% -2.7% -3.6% -7.1% 1.0% -3.4% -1.8% -2.2% -4.5% -4.1% -5.1% -4.7% -4.4% -3.2% 206 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.95e7 2.47e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.50e7 1.25e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.78e7 8.90e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.83e7 9.17e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.06e7 5.32e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.51e6 2.75e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.31e6 2.65e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 288-489 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:10 Page 1 of 21 207 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-1 8.49e6 12.05 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-2 8.22e6 14.18 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.63e3 Abs. Int. 3.53e6 PCB-3 8.15e6 14.37 1.77e6 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.58e6 12.05 Rel. Int. 100% PCB-2 2.50e6 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.76e3 0.00e0 16.0 RT Abs. Int. 1.06e6 PCB-3 2.55e6 14.37 5.29e5 0% 11.0 12.0 13.0 14.0 ES-1 1.83e8 12.04 Rel. Int. 100% 15.0 Abs. Int. 7.14e7 ES-3 1.69e8 14.36 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.48e3 0.00e0 16.0 RT 3.57e7 0% 11.0 12.0 13.0 14.0 ES-1 5.63e7 12.04 Rel. Int. 100% 15.0 Abs. Int. 2.26e7 ES-3 5.01e7 14.36 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.97e4 0.00e0 16.0 RT 1.13e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.47e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5986, 8076 scc: 288-489 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 2 of 21 208 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. 100% PCB-4 3.84e6 14.63 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.13e3 PCB-10 6.17e6 14.81 1.01e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.89e6 14.81 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.22e4 PCB-4 2.39e6 14.63 12.0 13.0 14.0 15.0 ES-4 6.43e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.30e6 6.50e5 0% 11.0 Abs. Int. 2.02e6 0.00e0 16.0 RT Abs. Int. 2.12e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 1.16e4 1.06e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.98e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.35e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.62e3 6.76e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.47e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2760, 4750 scc: 288-489 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 3 of 21 209 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.04e4 PCB-9 5.75e6 16.63 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-7 6.57e6 PCB-6 16.80 6.12e6 17.03 PCB-14 7.35e6 19.02 PCB-5 6.20e6 PCB-8 17.33 6.43e6 17.45 PCB-11 6.41e6 19.81 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 13/12 1.25e7 20.11 Abs. Int. 2.17e6 PCB-15 6.32e6 20.39 1.09e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.28e4 PCB-9 3.64e6 16.63 PCB-7 3.99e6 16.80 18.0 19.0 PCB-14 4.57e6 19.02 PCB-5 3.84e6 PCB-8 17.33 4.02e6 17.45 20.0 PCB-11 3.91e6 19.81 13/12 7.75e6 20.10 21.0 Abs. Int. 1.40e6 PCB-15 3.83e6 20.39 7.00e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.21e8 16.61 21.0 0.00e0 RT Abs. Int. 3.98e7 ES-15 1.27e8 20.38 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.35e4 1.99e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.71e7 16.61 21.0 0.00e0 RT Abs. Int. 2.51e7 ES-15 8.13e7 20.38 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 1.09e4 1.26e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0673, 3078 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 4 of 21 210 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 30/18 7.88e6 19.52 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.57e3 PCB-19 2.89e6 17.75 PCB-17 3.33e6 19.93 PCB-27 4.61e6 20.12 PCB-24 4.30e6 20.26 PCB-16 2.58e6 20.35 Abs. Int. 2.14e6 PCB-32 4.81e6 20.84 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 7.32e6 19.52 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 4.49e3 PCB-19 2.75e6 17.75 PCB-17 3.07e6 19.93 21.0 Rel. Int. 100% 18.0 19.0 PCB-16 2.45e6 20.35 20.0 PCB-32 4.50e6 20.84 21.0 1.01e6 0.00e0 RT Abs. Int. 2.17e7 ES-19 5.22e7 17.73 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 7.41e4 0.00e0 RT Abs. Int. 2.01e6 PCB-24 4.11e6 20.26 PCB-27 4.31e6 20.12 0% 17.0 1.07e6 1.09e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.98e7 ES-19 4.85e7 17.73 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.71e4 0.00e0 RT 9.91e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9474, 8467 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 5 of 21 211 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.73e3 PCB-23 PCB-34 4.29e6 4.28e6 22.14 21.99 26/29 8.76e6 22.43 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 28/20 8.42e6 23.19 PCB-31 4.58e6 22.91 Abs. Int. 1.95e6 PCB-22 4.03e6 23.75 PCB-36 4.36e6 25.14 PCB-39 4.43e6 25.46 PCB-38 4.07e6 26.00 PCB-35 3.89e6 26.39 PCB-37 4.03e6 26.76 9.75e5 0% 22.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.67e3 PCB-34 PCB-23 4.40e6 4.28e6 22.14 21.99 23.0 26/29 8.87e6 22.43 24.0 25.0 26.0 27.0 28/20 8.46e6 23.19 PCB-31 4.70e6 22.91 Abs. Int. 2.01e6 PCB-22 4.03e6 23.75 PCB-36 4.44e6 25.14 PCB-39 4.58e6 25.46 PCB-38 4.19e6 26.00 PCB-35 3.89e6 26.39 PCB-37 4.12e6 26.76 1.00e6 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 9.02e7 23.16 Rel. Int. 100% 0.00e0 RT 27.0 0.00e0 RT Abs. Int. 2.37e7 ES-37 8.14e7 26.74 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.65e4 1.19e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.25e7 23.16 Rel. Int. 100% 27.0 0.00e0 RT Abs. Int. 2.20e7 ES-37 7.44e7 26.74 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.85e4 1.10e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1479, 2682 scc: 288-489 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 6 of 21 212 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-54 2.39e6 20.68 Rel. Int. 100% Abs. Int. 6.38e5 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.54e3 3.19e5 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.93e6 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.02e5 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.39e3 4.01e5 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.66e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.66e4 5.03e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.47e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 9.99e3 6.01e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6205, 6671 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 7 of 21 213 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.15e3 50/53 4.73e6 22.68 PCB-51 2.50e6 23.34 PCB-45 1.96e6 23.27 PCB-73 PCB-52 2.96e6 2.29e6 24.94 24.82 PCB-46 1.90e6 23.55 69/49 5.55e6 25.24 44/47… 7.19e6 25.74 PCB-48 2.34e6 25.52 59/62… 9.47e6 26.02 71/40 4.67e6 26.61 PCB-42 2.09e6 26.18 PCB-41 1.93e6 26.52 Abs. Int. 1.80e6 PCB-64 3.30e6 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.66e3 50/53 5.93e6 22.68 24.0 PCB-51 3.11e6 23.34 PCB-45 2.49e6 23.27 25.0 PCB-73 3.74e6 PCB-52 24.94 2.90e6 24.82 PCB-46 2.44e6 23.56 26.0 44/47… 9.21e6 25.74 69/49 7.04e6 25.24 PCB-48 2.89e6 25.52 59/62… 1.19e7 26.02 PCB-42 2.66e6 26.18 27.0 71/40 5.78e6 26.61 PCB-41 2.45e6 26.52 23.0 24.0 25.0 26.0 PCB-64 4.19e6 26.81 27.0 JS-52 4.09e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.14e6 0% 22.0 9.00e5 1.07e6 0.00e0 RT Abs. Int. 1.09e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.65e4 5.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.18e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.53e4 6.74e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7645, 3266 scc: 288-489 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 8 of 21 214 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 61/70... 1.30e7 29.05 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 1.09e4 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-57 3.19e6 28.16 PCB-63 3.39e6 28.75 PCB-55 3.12e6 29.47 PCB-60 PCB-80 3.07e6 3.59e6 30.43 30.11 PCB-79 3.56e6 31.76 PCB-78 2.91e6 32.25 PCB-81 2.96e6 32.63 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Abs. Int. 1.61e6 PCB-77 3.16e6 33.11 8.04e5 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 7.51e3 PCB-57 4.13e6 28.16 PCB-68 4.48e6 27.79 30.0 61/70... 1.64e7 29.04 32.0 PCB-60 3.93e6 30.11 PCB-63 4.46e6 PCB-66 PCB-56 3.90e6 3.93e6 28.75 29.33 29.91 PCB-80 4.50e6 30.43 PCB-79 4.54e6 31.76 34.0 PCB-78 3.70e6 32.25PCB-81 3.85e6 32.63 36.0 38.0 Abs. Int. 2.10e6 PCB-77 4.02e6 33.11 1.05e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 5.62e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.57e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.52e7 ES-77 5.84e7 33.09 7.62e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.04e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.96e4 36.0 38.0 0.00e0 RT Abs. Int. 1.93e7 ES-77 7.31e7 33.09 9.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6185, 5150 scc: 288-489 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 9 of 21 215 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-104 1.93e6 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.00e3 Abs. Int. 5.05e5 PCB-96 1.65e6 26.01 2.53e5 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.97e6 25.69 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.05e3 27.0 0.00e0 RT Abs. Int. 8.18e5 PCB-96 2.56e6 26.01 4.09e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.38e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 3.73e3 5.63e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.62e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.64e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 1.51e3 3.32e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5147, 8237 scc: 288-489 Revised: 30-Dec-2013 12:10 (LKB) Printed: 03-Jan-2014 17:10 Page 10 of 21 216 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 108/119... 1.11e7 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 4.67e4 PCB-103 1.79e6 27.71 100/93 3.34e6 28.50 PCB-88 1.48e6 28.98 PCB-121 2.30e6 30.00 113/90… 5.72e6 30.81 116/85 3.51e6 32.42 PCB-99 1.74e6 31.34 PCB-111 2.37e6 PCB-120 2.36e6 33.13 33.53 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 107/124 PCB-118 2.15e6 4.19e6 35.10 34.50 PCB-123 PCB-114 2.30e6 2.37e6 34.82 35.56 Abs. Int. 1.65e6 PCB-105 2.21e6 36.11 PCB-127 2.09e6 37.34 8.24e5 0% 28.0 30.0 32.0 108/119... 1.81e7 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 7.48e4 34.0 PCB-94 2.47e6 27.90 100/93 5.30e6 28.49 PCB-91 2.94e6 29.04 PCB-89 2.35e6 29.65 113/90… 9.02e6 30.80 PCB-112 PCB-92 3.65e6 2.50e6 31.44 30.32 116/85 PCB-115 5.50e6 3.71e6 32.42 32.62 PCB-111 PCB-117 PCB-110 3.73e6 PCB-120 3.63e6 3.34e6 3.68e6 33.13 32.33 32.53 33.53 36.0 PCB-118 107/124 3.56e6 6.71e6 35.10 34.50 PCB-123 PCB-114 3.66e6 3.82e6 34.82 35.56 38.0 Abs. Int. 2.65e6 PCB-105 3.47e6 36.11 PCB-127 3.36e6 37.34 1.33e6 0% 28.0 Rel. Int. 100% PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.45e3 30.0 32.0 34.0 CS/SS-111 6.50e7 33.11 JS-101 5.23e7 (6.56e7 + 4.07e7) * 100 pg/uL RRF(ES-105) = = 1.25 30.81 (5.23e7 + 3.30e7) * 100 pg/uL LKB 03-Jan-2014 11:50 36.0 ES-123 6.26e7 34.79 ES-114 ES-118 6.68e7 6.24e7 35.54 35.07 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.62e7 ES-105 6.56e7 36.08 8.09e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 4.02e7 33.11 JS-101 3.30e7 30.81 36.0 ES-123 3.97e7 34.79 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 1.58e3 ES-118 ES-114 3.88e7 4.05e7 35.07 35.54 38.0 0.00e0 RT Abs. Int. 9.82e6 ES-105 4.07e7 36.08 4.91e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6550, 0341 scc: 288-489 Revised: 03-Jan-2014 16:44 (LKB) Printed: 03-Jan-2014 17:10 Page 11 of 21 217 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-126 1.83e6 38.72 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.16e3 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Abs. Int. 4.48e5 (1.83e6 + 2.94e6) * 100 pg/uL RRF(PCB-126) = = 1.05 (5.56e7 + 3.53e7) * 5 pg/uL LKB 03-Jan-2014 11:49 2.24e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.89e5 PCB-126 2.94e6 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.88e3 3.44e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.35e7 ES-126 5.56e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.79e3 6.76e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.80e6 ES-126 3.53e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 5.68e3 4.40e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3455, 1978 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 12 of 21 218 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% PCB-155 PCB-150 3.19e6 2.94e6 30.97 30.67 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 8.82e2 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 147/149 139/140 4.16e6 4.18e6 34.12 34.64 PCB-145 2.77e6 31.55 PCB-148 2.07e6 32.82 153/168 5.13e6 36.71 151/135PCB-144 3.94e6 2.10e6 PCB-143 PCB-142 PCB-133 PCB-146 2.02e6 33.34 33.82 1.94e6 2.10e6 1.71e6 36.16 34.38 35.60 34.96 PCB-141 1.92e6 36.85 163/138… 6.11e6 37.77 PCB-164 PCB-160 2.71e6 2.64e6 37.48 37.91 0% 28.0 30.0 32.0 PCB-136 2.12e6 31.27 PCB-150 PCB-155 2.32e6 PCB-145 2.47e6 30.97 2.12e6 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 6.38e2 34.0 PCB-148 1.62e6 32.82 147/149 139/140 151/135 3.22e6 3.27e6 3.20e6 34.12 33.34 34.64 PCB-154 PCB-143 1.84e6 1.60e6PCB-131 33.55 34.38 1.37e6 34.81 36.0 PCB-165 1.99e6 35.94 38.0 153/168 4.00e6 36.71 163/138… 4.82e6 37.77 PCB-141 PCB-137 1.48e6 1.54e6 37.39 36.85 PCB-158 2.26e6 38.09 0% 28.0 30.0 32.0 34.0 36.0 ES-155 5.24e7 30.64 Rel. Int. 100% 38.0 ES-153 3.62e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.74e3 Abs. Int. 1.15e6 5.77e5 0.00e0 RT Abs. Int. 9.25e5 4.62e5 0.00e0 RT Abs. Int. 1.29e7 JS-138 3.20e7 37.73 6.47e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.95e7 30.64 Rel. Int. 100% ES-153 2.75e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 1.30e3 0.00e0 RT Abs. Int. 9.93e6 JS-138 2.44e7 37.73 4.96e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8742, 2751 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 13 of 21 219 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.57e6 38.83 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.74e3 PCB-159 2.84e6 39.64 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-162 2.72e6 39.88 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 156/157 5.34e6 41.28 Abs. Int. 1.12e6 PCB-169 2.67e6 44.00 PCB-167 2.97e6 40.29 5.58e5 0% 39.0 Rel. Int. 100% 40.0 128/166 3.66e6 38.83 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.62e3 PCB-159 2.30e6 39.64 PCB-162 2.25e6 39.88 41.0 42.0 43.0 44.0 45.0 Abs. Int. 8.94e5 156/157 4.28e6 41.28 PCB-169 2.18e6 44.00 PCB-167 2.45e6 40.29 4.47e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.04e8 41.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 ES-167 5.44e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 1.17e4 0.00e0 RT ES-169 5.02e7 43.98 9.59e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 8.00e7 41.26 Rel. Int. 100% Abs. Int. 1.48e7 ES-167 4.20e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 7.32e3 0.00e0 RT ES-169 3.88e7 43.98 7.39e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3801, 7947 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 14 of 21 220 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% PCB-188 1.73e6 35.56 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-179 PCB-184 1.60e6 1.50e6 35.84 36.30 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.31e2 PCB-186 1.53e6 37.00 Abs. Int. 4.22e5 PCB-178 1.15e6 38.13 2.11e5 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.57e6 35.56 PCB-179 1.47e6 35.84 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 5.34e2 37.0 PCB-176 1.59e6 36.59 PCB-186 1.45e6 37.00 38.0 0.00e0 RT Abs. Int. 3.84e5 PCB-178 1.06e6 38.12 1.92e5 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.78e7 35.54 Rel. Int. 100% Abs. Int. 6.94e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.23e3 CS/SS-178 1.72e7 38.10 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.62e7 35.54 Rel. Int. 100% CS/SS-178 1.54e7 38.10 0% 32.0 33.0 34.0 35.0 3.47e6 0.00e0 RT Abs. Int. 6.31e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.34e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 3.15e6 0.00e0 RT Abs. Int. 1.83e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2821, 9130 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 15 of 21 221 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.67e3 PCB-182 1.90e6 39.08 PCB-185 1.62e6 39.52 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 180/193 4.02e6 42.41 171/173 2.98e6 40.53 PCB-181 PCB-177 1.53e6 1.69e6 40.35 40.00 PCB-172 1.54e6 41.88 PCB-191 2.15e6 42.74 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-170 1.49e6 43.51 Abs. Int. 6.84e5 PCB-190 2.17e6 43.97 3.42e5 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.83e3 PCB-182 1.77e6 39.08 PCB-187 PCB-183 1.78e6 1.87e6 38.90 39.43 40.0 41.0 42.0 43.0 180/193 3.73e6 42.41 171/173 2.82e6 PCB-181 40.53 PCB-177 1.57e6 1.40e6 40.35 40.00 PCB-172 1.44e6 41.88 PCB-191 2.05e6 42.74 44.0 PCB-170 1.42e6 43.51 45.0 Abs. Int. 6.33e5 PCB-190 2.05e6 43.97 3.17e5 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.29e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 7.97e6 ES-170 2.76e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.75e3 0.00e0 RT 3.98e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.02e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 7.41e6 ES-170 2.56e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.23e3 0.00e0 RT 3.70e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6498, 0239 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 16 of 21 222 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-189 2.33e6 46.13 Abs. Int. 5.42e5 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.05e3 2.71e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.28e6 46.13 Abs. Int. 5.54e5 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 7.55e2 2.77e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.53e7 46.11 0.00e0 RT Abs. Int. 1.08e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 5.40e3 5.39e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.38e7 46.11 0.00e0 RT Abs. Int. 1.06e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 4.80e3 5.28e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0018, 8768 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 17 of 21 223 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-202 1.32e6 40.10 PCB-201 1.60e6 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.62e2 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 198/199 2.09e6 44.08 PCB-197 1.48e6 PCB-204 41.66 PCB-200 1.46e6 1.47e6 41.47 41.75 Abs. Int. 3.82e5 PCB-196 1.11e6 44.66 PCB-203 1.15e6 44.83 1.91e5 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.48e6 40.10 41.0 PCB-201 1.73e6 40.89 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.89e2 42.0 43.0 44.0 45.0 198/199 2.28e6 44.08 PCB-197 1.62e6 41.66 PCB-200 PCB-204 1.66e6 1.55e6 41.75 41.47 0.00e0 RT Abs. Int. 4.14e5 PCB-196 1.18e6 44.66 PCB-203 1.24e6 44.83 2.07e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.72e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.70e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.49e3 3.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.88e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.04e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.76e3 3.52e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9441, 6444 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 18 of 21 224 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.06e3 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-205 1.70e6 48.30 PCB-195 1.22e6 45.95 Abs. Int. 4.21e5 PCB-194 1.32e6 47.90 2.11e5 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.03e3 47.0 PCB-195 1.35e6 45.95 48.0 49.0 50.0 PCB-205 1.83e6 48.30 PCB-194 1.52e6 47.90 0.00e0 RT Abs. Int. 4.31e5 2.15e5 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.31e7 48.28 Rel. Int. 100% Abs. Int. 7.84e6 JS-194 2.67e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.61e3 0.00e0 RT 3.92e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.71e7 48.28 Rel. Int. 100% Abs. Int. 8.92e6 JS-194 2.90e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 4.69e3 0.00e0 RT 4.46e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1137, 3820 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 19 of 21 225 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 6.72e2 PCB-208 1.60e6 45.75 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-207 1.64e6 46.54 Abs. Int. 3.86e5 PCB-206 1.12e6 49.78 1.93e5 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 2.48e3 PCB-208 1.97e6 45.75 47.0 48.0 49.0 50.0 PCB-207 2.15e6 46.54 Abs. Int. 5.02e5 PCB-206 1.43e6 49.77 2.51e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.97e7 45.73 50.0 0.00e0 RT Abs. Int. 7.00e6 ES-206 2.11e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 1.84e3 3.50e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.69e7 45.73 50.0 Abs. Int. 8.58e6 ES-206 2.61e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.64e3 0.00e0 RT 4.29e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6056, 4422 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 20 of 21 226 of 417 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-209 1.82e6 51.25 Rel. Int. 100% Abs. Int. 3.69e5 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.61e2 1.84e5 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.56e6 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.28e5 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 4.70e2 1.64e5 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.46e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.08e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 9.58e2 3.54e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.92e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.03e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.69e2 3.01e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.31e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.65e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6862, 7261 scc: 288-489 Revised: 30-Dec-2013 12:10 (LKB) Printed: 03-Jan-2014 17:10 Page 21 of 21 227 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.10 32.62 36.09 35.55 35.08 34.80 38.71 41.26 40.28 43.98 46.12 51.23 6.72E+07 6.46E+07 5.36E+07 5.90E+07 5.55E+07 5.75E+07 4.48E+07 9.35E+07 5.18E+07 4.66E+07 4.39E+07 3.15E+07 0.78 Y 0.78 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 1.23 Y 1.21 Y 1.24 Y 1.04 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.14 1.12 1.13 1.23 1.22 1.23 1.12 1.12 1.20 1.16 1.07 1.09 -0.9% -0.2% 1.3% 2.2% 2.5% 1.5% 1.1% 2.3% 2.9% 2.8% -0.2% -2.1% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.02 14.34 14.60 20.36 17.72 26.72 20.65 33.08 32.60 25.66 36.07 35.53 35.06 34.78 38.69 36.65 30.63 41.24 40.26 43.96 43.48 42.41 35.52 46.10 40.07 48.27 49.74 45.71 51.21 2.19E+08 1.97E+08 9.59E+07 1.90E+08 9.32E+07 1.42E+08 7.49E+07 1.18E+08 1.16E+08 6.47E+07 9.52E+07 9.60E+07 9.11E+07 9.36E+07 8.01E+07 5.89E+07 8.37E+07 1.67E+08 8.66E+07 8.06E+07 4.93E+07 5.80E+07 4.92E+07 8.18E+07 5.16E+07 6.45E+07 4.32E+07 6.09E+07 5.77E+07 3.31 Y 3.36 Y 1.62 Y 1.57 Y 1.08 Y 1.09 Y 0.82 Y 0.79 Y 0.81 Y 1.68 Y 1.57 Y 1.64 Y 1.63 Y 1.59 Y 1.60 Y 1.29 Y 1.30 Y 1.28 Y 1.28 Y 1.28 Y 1.09 Y 1.09 Y 1.11 Y 1.01 Y 0.93 Y 0.89 Y 0.80 Y 0.80 Y 1.21 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.18 1.06 0.52 1.02 0.50 1.61 0.85 1.34 1.32 0.80 1.18 1.19 1.13 1.16 0.99 1.10 1.56 1.56 1.62 1.51 0.95 1.11 0.92 1.57 0.97 1.24 0.83 1.17 1.11 -1.3% -2.5% -1.2% -1.9% -0.9% -2.9% -0.9% -2.9% -3.5% 0.0% -1.7% -2.1% -2.4% -2.1% -3.2% -1.2% -1.6% -2.7% -3.0% -3.2% -0.1% -2.2% -2.1% -0.9% -0.5% -0.6% -0.1% -0.5% -0.3% Page 1 of 6 228 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.15 33.09 38.09 1.59E+08 9.83E+07 3.00E+07 1.09 Y 1.61 Y 1.10 Y 1.11 1.03 0.62 1.12 1.05 0.61 1.0% 2.1% -1.7% CS PCB-28 CS PCB-111 CS PCB-178 23.15 33.09 38.09 1.59E+08 9.83E+07 3.00E+07 1.09 Y 1.61 Y 1.10 Y 1.85 1.22 0.58 1.81 1.22 0.56 -1.8% 0.0% -3.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.60 24.78 30.80 37.72 47.87 1.86E+08 8.78E+07 8.05E+07 5.35E+07 5.22E+07 1.55 Y 0.82 Y 1.58 Y 1.28 Y 0.91 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.04 14.36 14.62 20.38 17.73 26.74 20.67 25.68 30.65 35.54 40.09 48.28 45.73 49.76 1.06E+08 1.02E+08 6.07E+07 9.79E+07 5.43E+07 7.81E+07 5.09E+07 4.68E+07 5.34E+07 3.10E+07 2.75E+07 3.40E+07 3.44E+07 2.40E+07 3.22 Y 3.25 Y 1.59 Y 1.64 Y 1.06 Y 0.99 Y 0.82 Y 0.64 Y 1.27 Y 1.06 Y 0.92 Y 0.92 Y 0.77 Y 0.79 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.97 1.04 1.27 1.03 1.17 1.10 1.36 1.45 1.27 1.26 1.06 1.06 1.13 1.11 1.7% 2.8% 2.7% 1.2% 1.5% 2.2% 0.6% 0.9% 1.2% -0.6% 1.0% -0.5% 0.6% -0.3% Page 2 of 6 229 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 12.04 14.17 14.36 14.62 14.80 16.62 16.78 17.01 17.32 17.44 19.01 19.80 20.09 20.38 17.73 19.51 19.91 20.11 20.24 20.34 20.82 21.98 22.13 22.42 22.61 22.89 23.18 23.36 23.74 25.13 25.45 25.99 26.38 26.74 20.67 22.67 23.26 23.33 23.54 24.80 24.93 25.03 25.23 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 1.06E+08 1.07E+08 1.02E+08 6.07E+07 9.81E+07 9.11E+07 1.03E+08 9.79E+07 9.70E+07 9.83E+07 1.14E+08 9.79E+07 1.94E+08 9.79E+07 5.43E+07 1.46E+08 6.21E+07 8.52E+07 8.13E+07 4.64E+07 8.97E+07 8.15E+07 8.33E+07 1.69E+08 8.39E+07 8.91E+07 1.65E+08 1.71E+08 7.72E+07 8.43E+07 8.82E+07 8.09E+07 7.62E+07 7.81E+07 5.09E+07 1.04E+08 4.29E+07 5.41E+07 4.19E+07 4.97E+07 6.50E+07 4.44E+07 1.22E+08 RA 3.22 Y 3.26 Y 3.25 Y 1.59 Y 1.61 Y 1.64 Y 1.63 Y 1.63 Y 1.62 Y 1.64 Y 1.62 Y 1.64 Y 1.63 Y 1.64 Y 1.06 Y 1.05 Y 1.05 Y 1.06 Y 1.04 Y 1.06 Y 1.06 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.99 Y 0.99 Y 0.97 Y 0.98 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.82 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.97 1.08 1.04 1.27 2.05 0.96 1.09 1.03 1.02 1.04 1.20 1.03 1.02 1.03 1.17 1.57 1.33 1.83 1.74 1.00 1.93 1.15 1.18 1.20 1.18 1.26 1.17 1.21 1.09 1.19 1.24 1.14 1.08 1.10 1.36 0.90 0.74 0.93 0.72 0.86 1.12 0.77 1.05 Dev'n 1.7% 4.8% 2.8% 2.7% 3.2% 1.6% 4.1% 3.6% 2.0% 0.3% 1.9% 2.0% 3.1% 1.2% 1.5% 1.9% 2.2% 0.7% 1.2% -1.0% 0.3% 1.4% 1.8% 2.1% 2.3% 2.6% 3.0% 2.8% 0.9% 1.6% 2.8% 3.4% 3.5% 2.2% 0.6% 2.6% -3.3% 8.7% 3.5% 1.6% 0.9% 7.9% 3.2% 230 of 417 PCB QC Summary - Ax2 Detail Lab ID: CS3_131220_PCB_XA Acquired: 20-DEC-2013 18:04 Datafile: 131220X05 Name RT PCB-48 22'45-TeCB 25.51 PCB-44/47/65 ...-TeCB 25.73 PCB-59/62/75 ...-TeCB 26.01 PCB-42 22'34'-TeCB 26.17 PCB-41 22'34-TeCB 26.51 PCB-71/40 23'4'6/22'33'-TeCB 26.60 PCB-64 234'6-TeCB 26.80 PCB-72 23'55'-TeCB 27.52 PCB-68 23'45'-TeCB 27.78 PCB-57 233'5-TeCB 28.15 PCB-58 233'5'-TeCB 28.35 PCB-67 23'45-TeCB 28.51 PCB-63 234'5-TeCB 28.74 PCB-61/70/74/76 ...-TeCB 29.03 PCB-66 23'44'-TeCB 29.32 PCB-55 233'4-TeCB 29.46 PCB-56 233'4'-TeCB 29.90 PCB-60 2344'-TeCB 30.09 PCB-80 33'55'-TeCB 30.42 PCB-79 33'45'-TeCB 31.75 PCB-78 33'45-TeCB 32.24 PCB-104 22'466'-PeCB 25.68 PCB-96 22'366'-PeCB 26.00 PCB-103 22'45'6-PeCB 27.69 PCB-94 22'356'-PeCB 27.89 PCB-95 22'35'6-PeCB 28.27 PCB-100/93 22'44'6/22'356-PeCB 28.48 PCB-102 22'456'-PeCB 28.59 PCB-98 22'34'6'-PeCB 28.66 PCB-88 22'346-PeCB 28.96 PCB-91 22'34'6-PeCB 29.03 PCB-84 22'33'6-PeCB 29.22 PCB-89 22'346'-PeCB 29.64 PCB-121 23'45'6-PeCB 29.99 PCB-92 22'355'-PeCB 30.31 PCB-113/90/101 ...-PeCB 30.79 PCB-83 22'33'5-PeCB 31.23 PCB-99 22'44'5-PeCB 31.33 PCB-112 233'56-PeCB 31.43 PCB-108/119/86/97/125...-PeCB 31.78 PCB-117 234'56-PeCB 32.31 PCB-116/85 23456/22'344'-PeCB 32.41 PCB-110 233'4'6-PeCB 32.52 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 5.03E+07 1.61E+08 2.11E+08 4.56E+07 4.24E+07 1.01E+08 7.33E+07 7.21E+07 7.57E+07 6.97E+07 6.93E+07 7.46E+07 7.70E+07 2.84E+08 6.58E+07 6.61E+07 6.57E+07 6.65E+07 7.84E+07 7.58E+07 6.37E+07 4.68E+07 4.07E+07 4.49E+07 3.89E+07 4.15E+07 8.23E+07 4.80E+07 3.74E+07 3.48E+07 4.85E+07 3.51E+07 3.72E+07 5.76E+07 3.91E+07 1.40E+08 3.39E+07 4.26E+07 5.82E+07 2.85E+08 5.48E+07 8.79E+07 5.86E+07 RA 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.77 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.64 Y 0.65 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.87 0.93 1.21 0.79 0.73 0.87 1.27 1.25 1.31 1.20 1.20 1.29 1.33 1.23 1.14 1.14 1.13 1.15 1.35 1.31 1.10 1.45 1.26 0.96 0.83 0.89 0.88 1.03 0.80 0.74 1.04 0.75 0.80 1.23 0.84 1.00 0.72 0.91 1.24 1.01 1.17 0.94 1.25 Dev'n 3.5% 2.8% 4.0% 3.2% 5.4% 1.7% 3.7% 3.0% 2.4% 3.4% 1.6% 2.3% 2.5% 2.3% 3.1% 1.9% 2.2% 1.2% 3.1% 0.3% 3.6% 0.9% 2.3% 3.1% 3.9% 2.5% 1.9% 6.0% 5.5% -6.9% 9.9% 4.8% 4.3% 2.6% 1.9% 1.0% 1.2% -1.2% 6.6% 3.6% 2.9% -0.1% 12.0% 231 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 32.61 32.80 33.12 33.52 34.49 34.69 34.91 35.38 37.33 30.65 30.81 30.96 31.26 31.53 32.81 33.33 33.54 33.80 34.11 34.28 34.36 34.63 34.80 34.95 35.18 35.59 35.93 36.14 36.26 36.69 36.84 37.18 37.38 37.46 37.76 37.89 38.08 38.81 39.63 39.87 35.54 35.82 36.29 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 5.15E+07 3.29E+07 5.86E+07 5.80E+07 1.06E+08 6.23E+07 5.24E+07 4.86E+07 5.29E+07 5.34E+07 4.87E+07 5.03E+07 4.58E+07 4.68E+07 3.50E+07 6.71E+07 3.92E+07 3.50E+07 6.95E+07 2.62E+07 3.47E+07 7.06E+07 3.02E+07 2.97E+07 3.05E+07 3.33E+07 4.19E+07 3.49E+07 4.54E+07 8.69E+07 3.24E+07 2.87E+07 3.23E+07 4.64E+07 1.04E+08 4.57E+07 4.80E+07 7.91E+07 4.91E+07 4.82E+07 3.10E+07 2.89E+07 2.78E+07 RA 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 1.27 Y 1.29 Y 1.27 Y 1.28 Y 1.28 Y 1.29 Y 1.28 Y 1.27 Y 1.28 Y 1.26 Y 1.29 Y 1.29 Y 1.29 Y 1.28 Y 1.27 Y 1.29 Y 1.27 Y 1.29 Y 1.26 Y 1.29 Y 1.27 Y 1.26 Y 1.26 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.29 Y 1.23 Y 1.23 Y 1.22 Y 1.06 Y 1.08 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.10 0.70 1.25 1.24 1.14 1.33 1.12 1.01 1.11 1.27 1.16 1.20 1.09 1.12 1.19 1.14 1.33 1.19 1.18 0.89 1.18 1.20 1.03 1.01 1.03 1.13 1.42 1.19 1.54 1.48 1.10 0.97 1.10 1.58 1.17 1.55 1.63 0.91 1.13 1.11 1.26 1.17 1.13 Dev'n -5.0% 0.8% 2.6% 2.4% 3.4% 6.3% 1.3% 1.9% 1.5% 1.2% -0.8% 2.2% 2.6% 0.3% 0.6% 0.1% -0.9% 0.5% 0.4% -3.9% 4.3% -0.5% 0.0% 1.8% 0.4% -0.2% 1.0% -1.3% 1.3% 1.3% 1.2% 0.2% -5.5% 5.2% -1.4% 2.4% -1.8% 1.5% 1.7% 3.8% -0.6% 0.9% 0.2% 232 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 36.58 36.98 38.11 38.66 38.89 39.07 39.42 39.50 39.61 39.98 40.33 40.52 41.87 42.12 42.39 42.73 43.50 43.95 40.09 40.88 41.46 41.65 41.73 44.06 44.64 44.81 45.94 47.89 48.28 45.73 46.52 49.76 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 3.08E+07 2.82E+07 2.06E+07 3.12E+07 3.32E+07 3.55E+07 3.70E+07 2.99E+07 2.90E+07 2.76E+07 3.21E+07 5.60E+07 2.94E+07 3.83E+07 7.38E+07 4.06E+07 2.83E+07 4.10E+07 2.75E+07 3.19E+07 2.88E+07 2.98E+07 3.01E+07 4.14E+07 2.18E+07 2.26E+07 2.41E+07 2.69E+07 3.40E+07 3.44E+07 3.65E+07 2.40E+07 RA 1.08 Y 1.09 Y 1.08 Y 1.07 Y 1.07 Y 1.06 Y 1.06 Y 1.07 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 1.05 Y 1.07 Y 1.06 Y 1.08 Y 1.08 Y 1.05 Y 0.92 Y 0.91 Y 0.93 Y 0.91 Y 0.93 Y 0.91 Y 0.91 Y 0.91 Y 0.93 Y 0.91 Y 0.92 Y 0.77 Y 0.78 Y 0.79 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.25 1.14 0.84 1.08 1.15 1.22 1.28 1.03 1.00 0.95 1.11 0.97 1.02 1.32 1.27 1.40 1.15 1.66 1.06 1.24 1.12 1.15 1.16 0.80 0.84 0.88 0.75 0.84 1.06 1.13 1.20 1.11 Dev'n 1.6% 1.7% -0.7% 0.3% 0.7% 4.2% 6.0% -2.8% 1.1% 0.0% 1.7% 1.8% 2.7% 2.5% 1.0% 0.4% 1.0% 0.2% 1.0% 1.2% 0.0% -3.2% 5.1% -0.8% 1.1% 0.2% -2.5% -0.9% -0.5% 0.6% 0.7% -0.3% 233 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.31e7 2.66e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.72e7 1.36e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.99e7 9.97e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.02e7 1.01e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.14e7 5.71e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.75e6 2.88e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.38e6 2.69e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 297-225 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:10 Page 1 of 21 234 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-1 8.10e7 12.04 Rel. Int. 100% PCB-2 8.16e7 14.17 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.95e3 Abs. Int. 3.37e7 PCB-3 7.81e7 14.36 1.68e7 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.51e7 12.04 Rel. Int. 100% PCB-2 2.50e7 14.17 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 4.61e3 0.00e0 16.0 RT Abs. Int. 1.02e7 PCB-3 2.40e7 14.36 5.12e6 0% 11.0 12.0 13.0 14.0 ES-1 1.68e8 12.02 Rel. Int. 100% 15.0 Abs. Int. 6.63e7 ES-3 1.52e8 14.34 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 8.09e3 0.00e0 16.0 RT 3.32e7 0% 11.0 12.0 13.0 14.0 ES-1 5.08e7 12.02 Rel. Int. 100% 15.0 Abs. Int. 2.10e7 ES-3 4.52e7 14.34 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.05e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.31e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1305, 6088 scc: 297-225 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:10 Page 2 of 21 235 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Rel. Int. 100% PCB-10 6.05e7 14.80 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.28e3 PCB-4 3.73e7 14.62 1.01e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.76e7 14.80 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.69e4 PCB-4 2.35e7 14.61 12.0 13.0 14.0 15.0 ES-4 5.93e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.25e7 6.24e6 0% 11.0 Abs. Int. 2.01e7 0.00e0 16.0 RT Abs. Int. 1.97e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.17e3 9.87e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.66e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.25e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.04e3 6.25e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.31e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0655, 5434 scc: 297-225 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 3 of 21 236 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.09e4 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-6 6.06e7 17.01 PCB-9 5.66e7 16.62 PCB-14 7.06e7 19.01 PCB-5 6.00e7 17.32 PCB-8 6.10e7 17.44 PCB-11 6.08e7 19.80 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 13/12 1.20e8 20.09 Abs. Int. 2.06e7 PCB-15 6.08e7 20.38 1.03e7 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.56e4 PCB-9 3.46e7 16.62 PCB-7 3.94e7 16.78 18.0 19.0 PCB-14 4.35e7 19.01 PCB-5 3.70e7 17.32 PCB-8 3.73e7 17.44 20.0 PCB-11 3.71e7 19.80 13/12 7.35e7 20.09 21.0 Abs. Int. 1.26e7 PCB-15 3.71e7 20.38 6.30e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.13e8 16.60 21.0 ES-15 1.16e8 20.36 0.00e0 RT Abs. Int. 3.59e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.60e4 1.79e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.28e7 16.60 21.0 0.00e0 RT Abs. Int. 2.31e7 ES-15 7.40e7 20.36 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 1.25e4 1.15e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4598, 0207 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 4 of 21 237 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 30/18 7.47e7 19.51 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.64e3 PCB-19 2.79e7 17.73 PCB-17 3.19e7 19.91 PCB-27 4.38e7 20.11 PCB-24 4.15e7 20.24 PCB-16 2.39e7 20.34 Abs. Int. 2.03e7 PCB-32 4.61e7 20.82 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 7.11e7 19.51 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 4.04e3 PCB-19 2.64e7 17.73 PCB-17 3.03e7 19.91 21.0 PCB-24 3.98e7 20.24 PCB-27 4.15e7 20.11 Rel. Int. 100% 18.0 19.0 PCB-16 2.25e7 20.34 20.0 PCB-32 4.36e7 20.82 21.0 9.59e6 0.00e0 RT Abs. Int. 1.95e7 ES-19 4.84e7 17.72 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 8.84e4 0.00e0 RT Abs. Int. 1.92e7 0% 17.0 1.01e7 9.76e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.80e7 ES-19 4.48e7 17.72 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.99e4 0.00e0 RT 9.01e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2677, 3721 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 5 of 21 238 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 28/20 8.20e7 23.18 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 7.46e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-23 PCB-34 4.15e7 4.05e7 22.13 21.98 26/29 8.42e7 22.42 PCB-31 4.44e7 22.89 Abs. Int. 1.93e7 PCB-22 3.82e7 23.74 PCB-36 4.19e7 25.13 PCB-39 4.39e7 25.45 PCB-38 4.03e7 25.99 PCB-35 3.79e7 26.38 PCB-37 3.89e7 26.74 9.66e6 0% 22.0 24.0 25.0 26.0 27.0 28/20 8.32e7 23.18 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 6.03e3 23.0 PCB-23 PCB-34 4.18e7 4.10e7 22.13 21.98 26/29 8.52e7 22.42 PCB-31 4.47e7 22.89 Abs. Int. 1.94e7 PCB-22 3.90e7 23.74 PCB-36 4.24e7 25.13 PCB-39 4.43e7 25.45 PCB-38 4.06e7 25.99 PCB-35 3.84e7 26.38 PCB-37 3.92e7 26.74 9.69e6 0% 22.0 23.0 CS/SS-28 8.29e7 23.15 Rel. Int. 100% TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.92e4 24.0 25.0 26.0 27.0 23.0 24.0 1.13e7 25.0 26.0 CS/SS-28 7.62e7 23.15 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.27e7 ES-37 7.38e7 26.72 (8.29e7 + 7.62e7) RRF(CS-28) = = 1.81 (3.96e7 + 4.82e7) LKB 03-Jan-2014 15:10 0% 22.0 0.00e0 RT 27.0 Abs. Int. 2.07e7 ES-37 6.79e7 26.72 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 4.37e4 0.00e0 RT 1.04e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2630, 0050 scc: 297-225 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 6 of 21 239 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-54 2.30e7 20.67 Rel. Int. 100% Abs. Int. 6.33e6 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.43e3 3.17e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.80e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.75e6 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.25e3 3.87e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.37e7 20.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.21e6 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.87e4 4.60e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.12e7 20.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.10e4 5.62e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5811, 4868 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 7 of 21 240 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.05e3 50/53 4.60e7 22.67 PCB-51 2.40e7 23.33 PCB-45 1.89e7 23.26 PCB-73 PCB-52 2.87e7 2.19e7 24.93 24.80 PCB-46 1.84e7 23.54 69/49 5.38e7 25.23 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 44/47… 7.13e7 25.73 PCB-48 2.21e7 25.51 59/62… 9.32e7 26.01 71/40 4.48e7 26.60 PCB-42 2.01e7 26.17 PCB-41 1.85e7 26.51 Abs. Int. 1.68e7 PCB-64 3.24e7 26.80 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 2.01e3 50/53 5.81e7 22.67 24.0 PCB-51 3.01e7 23.33 PCB-45 2.41e7 23.26 25.0 PCB-73 3.63e7 PCB-52 24.93 2.78e7 24.80 PCB-46 2.35e7 23.54 26.0 69/49 6.83e7 25.23 44/47… 9.00e7 25.73 PCB-48 2.81e7 25.51 27.0 59/62… 1.17e8 26.00 71/40 5.63e7 26.60 PCB-42 2.55e7 26.17 PCB-41 2.39e7 26.51 23.0 24.0 25.0 26.0 PCB-64 4.09e7 26.80 27.0 JS-52 3.96e7 24.78 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.12e7 0% 22.0 8.42e6 1.06e7 0.00e0 RT Abs. Int. 1.03e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 3.01e4 5.16e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 4.82e7 24.78 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.93e4 6.39e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6030, 5973 scc: 297-225 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 8 of 21 241 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 61/70... 1.24e8 29.03 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 8.75e4 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-68 3.33e7 27.78 PCB-67 3.27e7 28.51 PCB-55 2.90e7 29.46 PCB-60 PCB-80 2.92e7 3.46e7 30.42 30.09 PCB-79 3.33e7 31.75 PCB-78 2.80e7 32.24PCB-81 2.83e7 32.62 Abs. Int. 1.54e7 PCB-77 2.95e7 33.10 7.71e6 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 5.75e4 PCB-57 3.91e7 28.15 PCB-68 4.24e7 27.78 30.0 61/70... 1.59e8 29.03 32.0 PCB-60 3.73e7 30.09 PCB-63 PCB-66 4.34e7 3.69e7 PCB-56 3.69e7 28.74 29.31 29.90 PCB-80 4.38e7 30.42 PCB-79 4.25e7 31.74 34.0 PCB-78 3.56e7 32.24PCB-81 3.63e7 32.62 36.0 38.0 Abs. Int. 1.98e7 PCB-77 3.77e7 33.10 9.88e6 0% 28.0 Rel. Int. 100% TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.69e4 30.0 32.0 34.0 ES-81 5.16e7 32.60 (5.16e7 + 6.42e7) * 100 pg/uL = 1.32 (3.96e7 + 4.82e7) * 100 pg/uL LKB 03-Jan-2014 15:09 RRF(ES-81) = 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.42e7 ES-77 5.20e7 33.08 7.08e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.42e7 32.60 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 2.60e4 36.0 38.0 0.00e0 RT Abs. Int. 1.77e7 ES-77 6.59e7 33.08 8.85e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8755, 8946 scc: 297-225 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 9 of 21 242 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-104 1.83e7 25.68 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 8.52e2 Abs. Int. 4.64e6 PCB-96 1.60e7 26.00 2.32e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.84e7 25.68 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.03e3 27.0 0.00e0 RT Abs. Int. 7.28e6 PCB-96 2.46e7 25.99 3.64e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.06e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 1.98e3 5.07e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.41e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.06e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.06e3 3.03e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9856, 2300 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 10 of 21 243 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 108/119... 1.09e8 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 1.43e5 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-103 1.72e7 27.69 PCB-91 1.86e7 100/93 29.03 3.15e7 28.48 PCB-88 1.32e7 28.96 PCB-121 2.21e7 29.99 113/90… 5.36e7 30.79 116/85 3.39e7 32.41 PCB-99 1.63e7 31.33 PCB-111 2.24e7 PCB-120 2.22e7 33.12 33.52 107/124 PCB-118 2.13e7 4.05e7 35.08 34.49 PCB-114 PCB-123 2.27e7 2.21e7 35.55 34.80 Abs. Int. 1.58e7 PCB-105 2.05e7 36.09 PCB-127 2.01e7 37.33 7.92e6 0% 28.0 30.0 32.0 36.0 38.0 108/119... 1.76e8 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 1.25e5 34.0 PCB-94 2.39e7 27.88 100/93 5.08e7 28.48 PCB-91 2.99e7 29.03 PCB-89 2.31e7 29.64 113/90… 8.61e7 30.79 PCB-112 3.59e7 PCB-92 31.43 2.43e7 30.31 116/85 PCB-115 5.40e7 3.18e7 PCB-111 32.40 32.61 3.62e7 33.12 PCB-117 PCB-110 PCB-120 3.38e7 3.61e7 PCB-82 3.58e7 32.31 32.52 2.03e7 33.52 32.80 107/124 PCB-118 3.42e7 6.57e7 35.08 34.49 PCB-114 PCB-123 3.63e7 3.54e7 35.55 34.80 Abs. Int. 2.53e7 PCB-105 3.31e7 36.09 PCB-127 3.28e7 37.33 1.27e7 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 6.07e7 33.09 JS-101 4.93e7 30.80 36.0 ES-118 ES-114 5.96e7 35.53 ES-123 5.64e7 5.74e7 35.06 34.78 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.18e3 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.48e7 ES-105 5.82e7 36.07 7.42e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 3.77e7 33.10 JS-101 3.12e7 30.80 36.0 ES-118 ES-114 ES-123 3.47e7 3.63e7 3.62e7 35.06 35.53 34.78 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.13e3 38.0 0.00e0 RT Abs. Int. 9.26e6 ES-105 3.70e7 36.07 4.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4291, 2615 scc: 297-225 Revised: 03-Jan-2014 16:45 (LKB) Printed: 03-Jan-2014 17:11 Page 11 of 21 244 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Abs. Int. 3.89e6 PCB-126 1.72e7 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 2.70e3 1.94e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.44e6 PCB-126 2.76e7 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 3.20e3 3.22e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.21e7 ES-126 4.93e7 38.69 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.26e3 6.04e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.54e6 ES-126 3.09e7 38.69 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 8.80e3 3.77e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5774, 8779 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 12 of 21 245 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% PCB-150 PCB-155 2.82e7 2.99e7 30.96 30.65 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.06e2 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 147/149 139/140 3.88e7 3.97e7 34.11 34.63 PCB-145 2.62e7 31.53 PCB-148 1.97e7 32.81 153/168 4.86e7 36.69 151/135PCB-144 3.76e7 1.97e7 PCB-143 PCB-142 PCB-133 PCB-146 1.95e7 1.86e7 1.95e7 33.33 33.80 1.66e7 36.14 34.36 35.59 34.95 PCB-141 1.81e7 36.84 163/138… 5.81e7 37.76 PCB-160 PCB-164 2.60e7 2.56e7 37.46 37.89 0% 28.0 30.0 32.0 PCB-152 2.13e7 30.81 PCB-150 PCB-155 2.21e7 2.35e7 30.95 30.65 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.05e3 PCB-145 2.06e7 31.53 34.0 PCB-148 1.53e7 32.81 147/149 139/140 151/135 3.08e7 3.09e7 2.95e7 34.11 34.63 33.33 PCB-154 PCB-143 1.73e7 1.51e7PCB-131 33.54 34.36 1.32e7 34.80 36.0 38.0 153/168 3.83e7 36.69 PCB-165 1.83e7 35.93 163/138… 4.56e7 37.75 PCB-141 PCB-137 1.43e7 1.43e7 37.38 36.84 PCB-158 2.10e7 38.08 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.73e7 30.63 Rel. Int. 100% ES-153 3.32e7 36.65 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.52e3 Abs. Int. 1.10e7 5.51e6 0.00e0 RT Abs. Int. 8.70e6 4.35e6 0.00e0 RT Abs. Int. 1.17e7 JS-138 3.00e7 37.72 5.87e6 0% 28.0 30.0 32.0 34.0 36.0 ES-155 3.64e7 30.63 Rel. Int. 100% 38.0 ES-153 2.57e7 36.65 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 1.83e3 0.00e0 RT Abs. Int. 8.88e6 JS-138 2.35e7 37.72 4.44e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0360, 4999 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 13 of 21 246 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.35e7 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.95e3 PCB-159 2.71e7 39.63 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-162 2.65e7 39.87 156/157 5.15e7 41.26 Abs. Int. 1.02e7 (2.84e7 + 2.34e7) * 100 pg/uL = 1.20 (4.86e7 + 3.80e7) * 50 pg/uL LKB 03-Jan-2014 11:58 RRF(PCB-167) = PCB-167 2.84e7 40.28 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-169 2.58e7 43.98 5.09e6 0% 39.0 Rel. Int. 100% 128/166 3.55e7 38.81 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 3.14e3 40.0 PCB-162 PCB-159 2.17e7 2.20e7 39.87 39.63 41.0 42.0 43.0 44.0 45.0 156/157 4.20e7 41.26 Abs. Int. 8.23e6 PCB-169 2.08e7 43.98 PCB-167 2.34e7 40.28 4.11e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 9.34e7 41.24 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.68e7 ES-167 4.86e7 40.26 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 7.61e3 0.00e0 RT ES-169 4.52e7 43.96 8.40e6 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 3.80e7 40.26 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 8.72e3 42.0 43.0 44.0 45.0 ES-156/157 7.32e7 41.24 0.00e0 RT Abs. Int. 1.31e7 ES-169 3.54e7 43.96 6.56e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6303, 7049 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 14 of 21 247 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% PCB-188 1.60e7 35.54 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-179 PCB-184 1.50e7 1.45e7 35.82 36.29 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.15e2 PCB-186 1.47e7 36.98 Abs. Int. 3.96e6 PCB-178 1.07e7 38.11 1.98e6 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.50e7 35.54 PCB-179 1.39e7 35.82 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.04e2 37.0 PCB-176 1.48e7 36.58 PCB-186 1.35e7 36.98 38.0 Abs. Int. 3.73e6 PCB-178 9.89e6 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.59e7 35.52 Rel. Int. 100% CS/SS-178 1.57e7 38.09 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.33e7 35.52 Rel. Int. 100% CS/SS-178 1.42e7 38.09 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.20e6 0.00e0 RT Abs. Int. 5.64e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.22e3 31.0 1.86e6 Abs. Int. 6.41e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.23e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 2.82e6 0.00e0 RT Abs. Int. 2.02e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9174, 9814 scc: 297-225 PKD: 30-Dec-2013 12:20 Printed: 03-Jan-2014 17:11 Page 15 of 21 248 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 4.43e3 PCB-183 1.91e7 PCB-182 39.42 PCB-185 1.83e7 1.54e7 39.07 39.50 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 180/193 3.80e7 42.39 171/173 2.87e7 PCB-181 40.52 PCB-177 1.65e7 1.42e7 40.33 39.98 PCB-172 1.51e7 41.87 PCB-191 2.11e7 42.73 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-170 1.47e7 43.50 Abs. Int. 6.40e6 PCB-190 2.10e7 43.95 3.20e6 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 3.72e3 PCB-182 1.72e7 39.07 PCB-183 PCB-187 1.79e7 1.61e7 39.42 38.89 40.0 41.0 42.0 43.0 180/193 3.58e7 42.39 171/173 2.72e7 PCB-181 40.52 PCB-177 1.56e7 1.34e7 40.33 39.98 PCB-172 1.43e7 41.87 PCB-191 1.95e7 42.73 44.0 45.0 Abs. Int. 6.07e6 PCB-190 2.01e7 43.95 PCB-170 1.36e7 43.50 3.04e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.02e7 42.41 Rel. Int. 100% 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 7.37e6 ES-170 2.58e7 43.48 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.18e3 3.69e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.77e7 42.41 Rel. Int. 100% 44.0 45.0 Abs. Int. 6.77e6 ES-170 2.36e7 43.48 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.05e3 0.00e0 RT 3.39e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1388, 8460 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 16 of 21 249 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-189 2.24e7 46.12 Abs. Int. 5.28e6 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.74e3 2.64e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.15e7 46.12 Abs. Int. 5.00e6 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 2.13e3 2.50e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.12e7 46.10 0.00e0 RT Abs. Int. 1.01e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 3.83e3 5.04e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.06e7 46.10 0.00e0 RT Abs. Int. 9.92e6 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.31e3 4.96e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7725, 6868 scc: 297-225 PKD: 30-Dec-2013 12:20 Printed: 03-Jan-2014 17:11 Page 17 of 21 250 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-202 1.32e7 40.09 Rel. Int. 100% PCB-201 1.52e7 40.88 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.54e2 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 198/199 1.98e7 44.06 PCB-197 1.42e7 PCB-204 41.65 PCB-200 1.39e7 1.45e7 41.46 41.73 Abs. Int. 3.62e6 PCB-196 1.04e7 44.64 PCB-203 1.08e7 44.81 1.81e6 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.43e7 40.09 41.0 PCB-201 1.67e7 40.88 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.75e2 42.0 43.0 44.0 45.0 198/199 2.17e7 44.06 PCB-197 1.55e7 PCB-204 41.65 PCB-200 1.49e7 1.56e7 41.46 41.73 0.00e0 RT Abs. Int. 3.99e6 PCB-196 1.14e7 44.64 PCB-203 1.18e7 44.81 1.99e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.49e7 40.07 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.20e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.53e3 3.10e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.68e7 40.07 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.66e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.32e3 3.33e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2479, 9839 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 18 of 21 251 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.61e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-205 1.63e7 48.28 PCB-195 1.16e7 45.94 Abs. Int. 3.80e6 PCB-194 1.29e7 47.89 1.90e6 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 2.48e3 47.0 48.0 49.0 50.0 PCB-205 1.77e7 48.28 PCB-195 1.25e7 45.94 0.00e0 RT Abs. Int. 4.16e6 PCB-194 1.41e7 47.88 2.08e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.04e7 48.27 Rel. Int. 100% Abs. Int. 7.24e6 JS-194 2.49e7 47.87 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.67e3 0.00e0 RT 3.62e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.40e7 48.27 Rel. Int. 100% Abs. Int. 8.13e6 JS-194 2.73e7 47.87 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.23e3 0.00e0 RT 4.07e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9372, 9268 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 19 of 21 252 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.22e3 PCB-208 1.50e7 45.73 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-207 1.60e7 46.52 Abs. Int. 3.79e6 PCB-206 1.06e7 49.76 1.89e6 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.78e3 PCB-208 1.94e7 45.73 47.0 48.0 49.0 50.0 PCB-207 2.05e7 46.52 Abs. Int. 4.79e6 PCB-206 1.34e7 49.76 2.40e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.71e7 45.71 50.0 0.00e0 RT Abs. Int. 6.38e6 ES-206 1.92e7 49.74 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.45e3 3.19e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.39e7 45.71 50.0 Abs. Int. 8.08e6 ES-206 2.40e7 49.74 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 3.05e3 0.00e0 RT 4.04e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5390, 1741 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 20 of 21 253 of 417 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-209 1.71e7 51.23 Rel. Int. 100% Abs. Int. 3.49e6 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 6.63e2 1.74e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.44e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.92e6 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.15e2 1.46e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.16e7 51.21 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.46e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 7.77e2 3.23e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.62e7 51.21 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.44e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.95e2 2.72e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.38e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.69e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6160, 7361 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 21 of 21 254 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.10 32.62 36.10 35.56 35.09 34.81 38.71 41.27 40.29 43.99 46.13 51.25 6.61E+08 6.42E+08 5.26E+08 5.80E+08 5.38E+08 5.67E+08 4.45E+08 9.01E+08 4.96E+08 4.52E+08 4.15E+08 2.92E+08 0.78 Y 0.78 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.63 Y 1.22 Y 1.23 Y 1.24 Y 1.05 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.14 1.15 1.24 1.22 1.23 1.14 1.11 1.18 1.14 1.10 1.10 1.7% 1.9% 3.3% 3.3% 2.6% 1.3% 2.8% 1.1% 1.4% 1.2% 2.3% -1.4% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.03 14.35 14.61 20.37 17.72 26.73 20.66 33.08 32.61 25.66 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.25 40.27 43.97 43.49 42.42 35.53 46.11 40.08 48.28 49.75 45.72 51.22 2.53E+08 2.32E+08 1.12E+08 2.25E+08 1.10E+08 1.69E+08 8.74E+07 1.41E+08 1.41E+08 7.69E+07 1.14E+08 1.17E+08 1.10E+08 1.15E+08 9.79E+07 6.88E+07 9.70E+07 2.03E+08 1.05E+08 9.92E+07 5.71E+07 6.95E+07 5.77E+07 9.44E+07 6.04E+07 7.51E+07 5.00E+07 7.07E+07 6.66E+07 3.29 Y 3.37 Y 1.64 Y 1.54 Y 1.08 Y 1.08 Y 0.83 Y 0.79 Y 0.77 Y 1.65 Y 1.60 Y 1.63 Y 1.63 Y 1.60 Y 1.53 Y 1.31 Y 1.30 Y 1.29 Y 1.27 Y 1.27 Y 1.09 Y 1.09 Y 1.13 Y 1.04 Y 0.94 Y 0.90 Y 0.81 Y 0.80 Y 1.18 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.17 1.08 0.52 1.05 0.51 1.66 0.86 1.38 1.38 0.79 1.18 1.21 1.14 1.19 1.01 1.11 1.56 1.64 1.70 1.60 0.95 1.16 0.93 1.57 0.97 1.25 0.83 1.18 1.11 -1.5% -0.6% -0.1% 0.6% 0.9% -0.4% -0.5% 0.0% 1.1% -1.2% -1.7% -1.1% -1.8% 0.4% -1.7% -0.6% -1.7% 2.3% 1.7% 2.7% 0.6% 2.0% -1.0% -0.5% 0.4% 0.7% 0.6% 0.4% 0.1% Page 1 of 6 255 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.10 38.10 1.88E+08 1.16E+08 3.54E+07 1.09 Y 1.60 Y 1.11 Y 1.11 1.03 0.62 1.11 1.00 0.61 0.2% -2.6% -1.0% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.10 38.10 1.88E+08 1.16E+08 3.54E+07 1.09 Y 1.60 Y 1.11 Y 1.85 1.22 0.58 1.84 1.19 0.57 -0.1% -2.2% -2.0% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.80 37.72 47.88 2.15E+08 1.02E+08 9.69E+07 6.21E+07 6.00E+07 1.55 Y 0.80 Y 1.60 Y 1.30 Y 0.91 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.04 14.36 14.62 20.38 17.74 26.75 20.68 25.69 30.66 35.55 40.10 48.30 45.74 49.77 9.92E+08 9.76E+08 5.69E+08 9.40E+08 5.10E+08 7.43E+08 4.71E+08 4.46E+08 5.02E+08 2.95E+08 2.56E+08 3.22E+08 3.23E+08 2.24E+08 3.21 Y 3.28 Y 1.58 Y 1.62 Y 1.05 Y 0.98 Y 0.83 Y 0.64 Y 1.27 Y 1.08 Y 0.92 Y 0.91 Y 0.78 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.98 1.05 1.27 1.04 1.16 1.10 1.35 1.45 1.29 1.28 1.06 1.07 1.14 1.12 3.0% 4.2% 2.9% 2.4% 1.2% 2.0% -0.4% 1.0% 2.6% 0.6% 0.6% 1.2% 1.7% 0.5% Page 2 of 6 256 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 12.04 14.18 14.36 14.62 14.80 16.62 16.79 17.02 17.32 17.44 19.01 19.80 20.10 20.38 17.74 19.51 19.92 20.11 20.25 20.34 20.83 21.98 22.14 22.42 22.62 22.90 23.19 23.37 23.75 25.14 25.46 25.99 26.39 26.75 20.68 22.68 23.27 23.34 23.55 24.81 24.94 25.04 25.23 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 9.92E+08 1.00E+09 9.76E+08 5.69E+08 9.17E+08 8.62E+08 9.69E+08 9.24E+08 9.17E+08 9.28E+08 1.09E+09 9.34E+08 1.86E+09 9.40E+08 5.10E+08 1.39E+09 5.88E+08 8.20E+08 7.60E+08 4.62E+08 8.47E+08 7.98E+08 8.06E+08 1.63E+09 8.00E+08 8.40E+08 1.58E+09 1.64E+09 7.44E+08 8.17E+08 8.41E+08 7.83E+08 7.26E+08 7.43E+08 4.71E+08 1.00E+09 4.42E+08 4.96E+08 3.98E+08 4.82E+08 6.34E+08 4.03E+08 1.18E+09 RA 3.21 Y 3.28 Y 3.28 Y 1.58 Y 1.60 Y 1.63 Y 1.64 Y 1.65 Y 1.63 Y 1.63 Y 1.64 Y 1.64 Y 1.64 Y 1.62 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.06 Y 1.05 Y 0.99 Y 0.98 Y 0.98 Y 0.97 Y 0.97 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.99 Y 0.99 Y 0.98 Y 0.83 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.98 1.08 1.05 1.27 2.04 0.96 1.08 1.03 1.02 1.03 1.21 1.04 1.03 1.04 1.16 1.59 1.34 1.87 1.73 1.05 1.93 1.18 1.19 1.21 1.18 1.24 1.17 1.21 1.10 1.21 1.25 1.16 1.07 1.10 1.35 0.89 0.78 0.88 0.71 0.85 1.12 0.72 1.05 Dev'n 3.0% 4.2% 4.2% 2.9% 3.1% 1.3% 2.9% 3.0% 1.7% -0.2% 2.2% 2.7% 4.5% 2.4% 1.2% 3.3% 2.6% 2.8% 0.5% 4.7% 0.6% 4.1% 3.3% 2.9% 2.4% 1.5% 3.0% 3.3% 2.0% 3.4% 2.8% 4.9% 3.4% 2.0% -0.4% 1.4% 2.2% 2.5% 1.0% 1.3% 1.1% 0.7% 2.5% 257 of 417 PCB QC Summary - Ax2 Detail Lab ID: CS4_131220_PCB_XA Acquired: 20-DEC-2013 18:59 Datafile: 131220X06 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.01 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.51 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.78 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.36 PCB-67 23'45-TeCB 28.52 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.04 PCB-66 23'44'-TeCB 29.32 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.10 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.75 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.00 PCB-103 22'45'6-PeCB 27.70 PCB-94 22'356'-PeCB 27.89 PCB-95 22'35'6-PeCB 28.27 PCB-100/93 22'44'6/22'356-PeCB 28.49 PCB-102 22'456'-PeCB 28.60 PCB-98 22'34'6'-PeCB 28.67 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.23 PCB-89 22'346'-PeCB 29.65 PCB-121 23'45'6-PeCB 29.99 PCB-92 22'355'-PeCB 30.31 PCB-113/90/101 ...-PeCB 30.80 PCB-83 22'33'5-PeCB 31.24 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.78 PCB-117 234'56-PeCB 32.32 PCB-116/85 23456/22'344'-PeCB 32.41 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 4.79E+08 1.57E+09 2.05E+09 4.36E+08 3.81E+08 1.02E+09 7.02E+08 6.86E+08 7.41E+08 6.53E+08 6.72E+08 7.17E+08 7.44E+08 2.76E+09 6.42E+08 6.33E+08 6.29E+08 6.41E+08 7.47E+08 7.60E+08 6.10E+08 4.46E+08 3.93E+08 4.37E+08 3.75E+08 4.04E+08 8.29E+08 4.01E+08 3.96E+08 3.93E+08 4.40E+08 3.38E+08 3.62E+08 5.66E+08 3.81E+08 1.39E+09 3.22E+08 4.51E+08 5.42E+08 2.82E+09 5.03E+08 9.15E+08 5.11E+08 RA 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.64 Y 0.65 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.85 0.93 1.22 0.77 0.68 0.90 1.25 1.22 1.31 1.16 1.19 1.27 1.32 1.22 1.14 1.12 1.12 1.14 1.32 1.35 1.08 1.45 1.28 0.95 0.81 0.87 0.90 0.87 0.86 0.85 0.95 0.73 0.78 1.23 0.83 1.01 0.70 0.98 1.17 1.02 1.09 0.99 1.11 Dev'n 1.4% 3.0% 4.3% 1.5% -2.7% 4.9% 2.0% 0.7% 2.9% -0.5% 1.1% 1.1% 1.7% 2.2% 3.3% 0.3% 0.6% 0.2% 0.9% 3.2% 1.9% 1.0% 3.9% 1.6% 1.6% 0.9% 3.9% -10.2% 13.2% 6.8% 0.9% 2.3% 2.8% 2.2% 0.7% 2.0% -2.5% 6.1% 0.5% 3.8% -4.3% 5.3% -1.0% 258 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 32.62 32.81 33.12 33.52 34.49 34.70 34.92 35.38 37.34 30.66 30.82 30.96 31.27 31.54 32.82 33.34 33.55 33.81 34.11 34.29 34.37 34.64 34.81 34.96 35.19 35.59 35.94 36.15 36.27 36.70 36.85 37.19 37.39 37.47 37.76 37.90 38.09 38.82 39.64 39.88 35.55 35.83 36.30 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.34E+08 3.31E+08 5.66E+08 5.76E+08 1.03E+09 5.82E+08 5.22E+08 4.75E+08 5.12E+08 5.02E+08 4.78E+08 4.68E+08 4.35E+08 4.41E+08 3.38E+08 6.39E+08 3.76E+08 3.29E+08 6.68E+08 2.65E+08 3.08E+08 6.80E+08 2.87E+08 2.82E+08 2.84E+08 3.19E+08 3.83E+08 3.42E+08 4.26E+08 8.26E+08 3.01E+08 2.69E+08 3.35E+08 4.16E+08 1.01E+09 4.29E+08 4.60E+08 7.86E+08 4.70E+08 4.62E+08 2.95E+08 2.67E+08 2.61E+08 RA 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.63 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.28 Y 1.27 Y 1.26 Y 1.28 Y 1.27 Y 1.28 Y 1.29 Y 1.30 Y 1.28 Y 1.28 Y 1.27 Y 1.28 Y 1.27 Y 1.29 Y 1.27 Y 1.27 Y 1.29 Y 1.27 Y 1.27 Y 1.28 Y 1.23 Y 1.23 Y 1.22 Y 1.08 Y 1.10 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.16 0.72 1.23 1.25 1.12 1.26 1.13 1.02 1.12 1.29 1.23 1.21 1.12 1.14 1.23 1.16 1.37 1.20 1.21 0.96 1.12 1.24 1.04 1.03 1.03 1.16 1.39 1.24 1.55 1.50 1.10 0.98 1.22 1.51 1.23 1.56 1.67 0.93 1.12 1.10 1.28 1.16 1.13 Dev'n -0.2% 3.0% 0.5% 2.9% 2.0% 0.6% 2.4% 2.2% 2.2% 2.6% 5.1% 2.7% 5.1% 2.1% 3.8% 1.9% 1.9% 1.2% 3.2% 4.4% -1.0% 2.6% 1.8% 3.6% 0.3% 2.4% -1.3% 3.4% 1.8% 3.0% 0.7% 0.6% 4.6% 0.9% 3.3% 2.8% 0.5% 3.7% 0.1% 2.4% 0.6% -0.3% 0.2% 259 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 36.59 36.99 38.12 38.67 38.90 39.08 39.42 39.51 39.62 39.99 40.34 40.53 41.88 42.13 42.40 42.74 43.51 43.96 40.10 40.89 41.47 41.66 41.75 44.07 44.65 44.82 45.95 47.90 48.30 45.74 46.53 49.77 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 2.85E+08 2.59E+08 1.94E+08 3.05E+08 3.25E+08 3.35E+08 3.29E+08 3.20E+08 2.73E+08 2.68E+08 3.10E+08 5.43E+08 2.79E+08 3.67E+08 7.06E+08 3.88E+08 2.72E+08 3.86E+08 2.56E+08 3.08E+08 2.70E+08 2.93E+08 2.71E+08 3.95E+08 2.03E+08 2.13E+08 2.31E+08 2.54E+08 3.22E+08 3.23E+08 3.40E+08 2.24E+08 RA 1.09 Y 1.08 Y 1.08 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 0.92 Y 0.92 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.92 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.78 Y 0.79 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.24 1.12 0.84 1.10 1.17 1.21 1.18 1.15 0.98 0.96 1.12 0.98 1.00 1.32 1.27 1.40 1.19 1.69 1.06 1.27 1.12 1.21 1.12 0.82 0.84 0.88 0.77 0.85 1.07 1.14 1.20 1.12 Dev'n 0.3% -0.3% -0.6% 2.1% 2.6% 2.7% -1.8% 8.5% -0.9% 1.4% 2.5% 3.1% 1.6% 2.6% 0.7% 0.1% 4.9% 1.7% 0.6% 4.3% 0.3% 1.7% 1.3% 0.9% 0.6% 1.0% 0.4% 0.4% 1.2% 1.7% 1.2% 0.5% 260 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.95e7 2.48e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.59e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.85e7 9.24e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.88e7 9.40e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.07e7 5.35e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.31e6 2.66e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.17e6 2.58e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 186-257 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:11 Page 1 of 21 261 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-1 7.57e8 12.04 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-2 7.66e8 14.18 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.55e3 Abs. Int. 3.12e8 PCB-3 7.48e8 14.36 1.56e8 0% 11.0 12.0 13.0 14.0 PCB-1 2.36e8 12.04 Rel. Int. 100% PCB-2 2.34e8 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.14e3 15.0 0.00e0 16.0 RT Abs. Int. 9.75e7 PCB-3 2.28e8 14.36 4.88e7 0% 11.0 12.0 13.0 14.0 ES-1 1.94e8 12.03 Rel. Int. 100% 15.0 Abs. Int. 7.70e7 ES-3 1.79e8 14.35 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 8.48e3 0.00e0 16.0 RT 3.85e7 0% 11.0 12.0 13.0 14.0 ES-1 5.88e7 12.03 Rel. Int. 100% 15.0 Abs. Int. 2.33e7 ES-3 5.31e7 14.35 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.17e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.48e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2447, 4248 scc: 186-257 Revised: 30-Dec-2013 12:40 (LKB) Printed: 03-Jan-2014 17:11 Page 2 of 21 262 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Rel. Int. 100% PCB-10 5.64e8 14.80 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.96e3 PCB-4 3.49e8 14.62 9.54e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.53e8 14.80 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.22e4 PCB-4 2.20e8 14.62 12.0 13.0 14.0 15.0 ES-4 6.97e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.20e8 6.02e7 0% 11.0 Abs. Int. 1.91e8 0.00e0 16.0 RT Abs. Int. 2.32e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.94e3 1.16e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.25e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.42e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.42e3 7.11e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.48e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5797, 8154 scc: 186-257 Revised: 30-Dec-2013 12:40 (LKB) Printed: 03-Jan-2014 17:11 Page 3 of 21 263 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.19e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-6 5.75e8 17.02 PCB-9 5.35e8 16.62 PCB-14 6.74e8 19.01 PCB-5 5.69e8 PCB-8 17.32 5.76e8 17.44 PCB-11 5.80e8 19.80 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 13/12 1.16e9 20.10 Abs. Int. 1.91e8 PCB-15 5.81e8 20.38 9.54e7 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.01e4 PCB-9 3.28e8 16.62 PCB-7 3.67e8 16.79 18.0 19.0 PCB-14 4.11e8 19.01 PCB-5 3.48e8 17.32 PCB-8 3.52e8 17.44 20.0 PCB-11 3.54e8 19.80 13/12 7.06e8 20.10 21.0 Abs. Int. 1.16e8 PCB-15 3.59e8 20.38 5.81e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.31e8 16.61 21.0 ES-15 1.36e8 20.37 0.00e0 RT Abs. Int. 4.21e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.87e4 2.11e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 8.44e7 16.61 21.0 ES-15 8.87e7 20.37 0.00e0 RT Abs. Int. 2.68e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 9.39e3 1.34e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2386, 7567 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 4 of 21 264 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 30/18 7.14e8 19.51 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 4.23e3 PCB-19 2.62e8 17.74 PCB-17 3.01e8 19.92 PCB-27 4.20e8 20.11 PCB-24 3.89e8 20.25 PCB-16 2.37e8 20.34 Abs. Int. 1.99e8 PCB-32 4.34e8 20.83 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.80e8 19.51 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 5.06e3 PCB-19 2.48e8 17.74 PCB-17 2.86e8 19.92 21.0 PCB-24 3.71e8 20.25 PCB-27 4.00e8 20.11 Rel. Int. 100% 18.0 19.0 PCB-16 2.25e8 20.34 20.0 PCB-32 4.13e8 20.83 21.0 9.49e7 0.00e0 RT Abs. Int. 2.38e7 ES-19 5.69e7 17.72 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 9.15e4 0.00e0 RT Abs. Int. 1.90e8 0% 17.0 9.97e7 1.19e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.16e7 ES-19 5.28e7 17.72 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.57e4 0.00e0 RT 1.08e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0138, 7970 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 5 of 21 265 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 1.75e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 28/20 7.84e8 23.19 26/29 PCB-23 8.07e8 PCB-34 3.99e8 22.42 3.98e8 22.14 21.98 PCB-31 4.13e8 22.90 Abs. Int. 1.95e8 PCB-22 3.70e8 23.75 PCB-36 4.06e8 25.14 PCB-39 4.17e8 25.46 PCB-38 3.90e8 25.99 PCB-35 3.61e8 26.39 PCB-37 3.69e8 26.75 0% 22.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 1.49e4 23.0 24.0 25.0 26.0 27.0 28/20 7.92e8 23.19 26/29 PCB-23 8.21e8 PCB-34 4.07e8 22.42 4.00e8 22.14 21.98 PCB-31 4.27e8 22.90 23.0 PCB-22 3.73e8 23.75 PCB-36 4.11e8 25.14 PCB-39 4.24e8 25.46 PCB-38 3.93e8 25.99 24.0 25.0 PCB-35 3.65e8 26.39 PCB-37 3.74e8 26.75 26.0 CS/SS-28 9.79e7 23.16 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e8 0% 22.0 9.74e7 27.0 0.00e0 RT Abs. Int. 2.75e7 ES-37 8.75e7 26.73 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.98e4 9.79e7 1.38e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 9.01e7 23.16 Rel. Int. 100% 27.0 0.00e0 RT Abs. Int. 2.57e7 ES-37 8.13e7 26.73 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.64e4 1.28e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3897, 4503 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 6 of 21 266 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-54 2.13e8 20.68 Rel. Int. 100% Abs. Int. 5.71e7 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 2.07e3 2.86e7 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.58e8 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.61e7 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.18e3 3.30e7 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.96e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.83e4 5.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.78e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.07e4 6.63e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0111, 4665 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 7 of 21 267 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 3.31e3 50/53 4.42e8 22.68 PCB-51 2.20e8 23.34 PCB-45 1.94e8 23.27 PCB-73 2.79e8 PCB-52 24.94 2.12e8 24.81 PCB-46 1.76e8 23.55 69/49 5.22e8 25.23 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 44/47… 6.94e8 25.74 PCB-48 2.12e8 25.52 59/62… 9.08e8 26.01 71/40 4.50e8 26.61 PCB-42 1.93e8 26.18 PCB-41 1.67e8 26.51 Abs. Int. 1.64e8 PCB-64 3.10e8 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 2.77e3 50/53 5.60e8 22.67 24.0 PCB-51 2.76e8 23.34 PCB-45 2.48e8 23.27 25.0 PCB-73 3.55e8 PCB-52 24.94 2.70e8 24.81 PCB-46 2.22e8 23.55 26.0 69/49 6.59e8 25.23 44/47… 8.79e8 25.73 PCB-48 2.68e8 25.52 27.0 59/62… 1.15e9 26.01 71/40 5.65e8 26.61 PCB-42 2.44e8 26.18 PCB-41 2.14e8 26.51 23.0 24.0 25.0 26.0 PCB-64 3.92e8 26.81 27.0 JS-52 4.53e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.06e8 0% 22.0 8.18e7 1.03e8 0.00e0 RT Abs. Int. 1.25e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.94e4 6.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.67e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.88e4 8.02e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6634, 9311 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 8 of 21 268 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 7.08e5 PCB-58 2.95e8 PCB-68 28.36 PCB-67 3.24e8 3.15e8 27.78 28.52 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 61/70... 1.21e9 29.04 PCB-55 2.78e8 29.47 PCB-60 PCB-80 2.82e8 3.28e8 30.10 30.43 PCB-79 3.33e8 31.75 PCB-78 2.67e8 32.25PCB-81 2.81e8 32.62 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 1.50e8 PCB-77 2.90e8 33.10 7.49e7 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 4.30e5 PCB-57 3.67e8 28.16 PCB-68 4.16e8 27.78 30.0 61/70... 1.55e9 29.04 PCB-63 4.18e8 PCB-66 3.61e8 28.74 29.32 32.0 PCB-60 3.59e8 30.10 PCB-56 3.53e8 29.91 PCB-80 4.19e8 30.43 PCB-79 4.27e8 31.75 34.0 PCB-78 3.43e8 32.24PCB-81 3.61e8 32.62 36.0 38.0 Abs. Int. 1.90e8 PCB-77 3.71e8 33.10 9.49e7 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.15e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.32e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.63e7 ES-77 6.25e7 33.08 8.16e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.94e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.92e4 36.0 38.0 0.00e0 RT Abs. Int. 2.16e7 ES-77 7.87e7 33.08 1.08e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9214, 1956 scc: 186-257 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 9 of 21 269 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-104 1.74e8 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.22e3 Abs. Int. 4.45e7 PCB-96 1.55e8 26.00 2.22e7 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.71e8 25.68 27.0 0.00e0 RT Abs. Int. 6.94e7 PCB-96 2.38e8 26.00 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.22e3 3.47e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.79e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.06e3 6.19e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.90e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.31e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 3.99e3 3.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9179, 1685 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 10 of 21 270 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 108/119... 1.09e9 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 4.02e5 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-103 1.67e8 27.70 PCB-91 1.70e8 100/93 29.04 3.16e8 28.49 PCB-88 PCB-84 1.50e8 1.30e8 28.98 29.23 PCB-121 2.18e8 29.99 113/90… 5.34e8 30.80 116/85 3.49e8 32.41 PCB-99 1.73e8 31.34 PCB-111 PCB-120 2.17e8 2.20e8 33.12 33.52 PCB-118 107/124 2.07e8 3.96e8 35.09 34.49 PCB-114 PCB-123 2.24e8 2.17e8 35.56 34.81 Abs. Int. 1.63e8 PCB-105 2.01e8 36.10 PCB-127 1.97e8 37.34 8.15e7 0% 28.0 30.0 32.0 36.0 38.0 108/119... 1.73e9 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 3.81e5 34.0 PCB-94 2.32e8 27.89 100/93 5.12e8 28.49 PCB-91 2.69e8 29.04 PCB-89 2.23e8 29.65 113/90… 8.58e8 30.80 PCB-112 3.34e8 PCB-92 31.44 2.35e8 30.31 116/85 PCB-115 5.66e8 3.29e8 PCB-111 32.41 32.62 3.49e8 33.12 PCB-117 PCB-110 PCB-120 3.10e8 3.14e8 PCB-82 3.55e8 32.32 32.53 2.05e8 33.52 32.81 PCB-118 107/124 3.31e8 6.37e8 35.09 34.49 PCB-114 PCB-123 3.56e8 3.50e8 35.56 34.81 Abs. Int. 2.59e8 PCB-105 3.25e8 36.10 PCB-127 3.15e8 37.33 1.30e8 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 7.11e7 33.10 JS-101 5.96e7 30.80 36.0 ES-114 ES-118 7.24e7 ES-123 6.82e7 35.54 7.10e7 35.07 34.79 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 5.01e3 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.77e7 ES-105 7.03e7 36.08 8.86e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.46e7 33.10 JS-101 3.72e7 30.80 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.24e3 34.0 36.0 ES-118 ES-114 ES-123 4.20e7 4.43e7 4.45e7 35.07 35.54 34.79 38.0 0.00e0 RT Abs. Int. 1.12e7 ES-105 4.41e7 36.08 5.59e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5110, 9189 scc: 186-257 Revised: 03-Jan-2014 16:45 (LKB) Printed: 03-Jan-2014 17:11 Page 11 of 21 271 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 4.01e7 PCB-126 1.72e8 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 7.09e3 2.01e7 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.56e7 PCB-126 2.74e8 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.06e4 3.28e7 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.43e7 ES-126 5.92e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.98e3 7.15e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 9.49e6 ES-126 3.86e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 6.20e3 4.75e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6238, 0621 scc: 186-257 Revised: 30-Dec-2013 12:42 (LKB) Printed: 03-Jan-2014 17:11 Page 12 of 21 272 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-136 2.43e8 31.27 PCB-150 PCB-155 2.62e8 PCB-145 2.81e8 30.96 2.47e8 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.99e3 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 147/149 139/140 3.74e8 3.81e8 34.11 34.64 PCB-148 1.89e8 32.82 151/135 3.58e8 PCB-144PCB-134 33.34 1.85e8 1.48e8 33.81 34.29 153/168 4.62e8 36.70 PCB-146 PCB-142 PCB-133 1.79e8 1.91e8 1.59e8 36.15 35.59 34.96 PCB-141 1.70e8 36.85 163/138… 5.67e8 37.76 PCB-164 PCB-160 2.34e8 2.40e8 37.47 37.90 0% 28.0 30.0 32.0 PCB-152 PCB-136 2.10e8 1.91e8 30.82 31.26 PCB-155 PCB-150 PCB-145 2.21e8 2.06e8 30.96 1.95e8 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 2.00e3 34.0 PCB-148 1.49e8 32.81 36.0 38.0 163/138… 4.47e8 147/149 139/140 37.76 153/168 151/135 2.94e8 3.00e8 PCB-142 3.63e8 2.80e8 34.11 34.641.23e8 36.70 33.34 PCB-158 34.96 PCB-154 2.02e8 PCB-133 PCB-146 PCB-141 PCB-137 PCB-143 1.66e8 38.08 PCB-131 1.40e8 1.51e8 1.35e8 1.26e8 33.55 1.31e8 1.47e8 36.15 37.39 35.59 34.37 34.81 36.85 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 5.48e7 30.64 Rel. Int. 100% ES-153 3.90e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 2.47e3 JS-138 3.51e7 37.72 Abs. Int. 1.07e8 5.37e7 0.00e0 RT Abs. Int. 8.44e7 4.22e7 0.00e0 RT Abs. Int. 1.34e7 6.72e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.22e7 30.64 Rel. Int. 100% ES-153 2.98e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.62e3 0.00e0 RT Abs. Int. 1.05e7 JS-138 2.69e7 37.72 5.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1491, 6768 scc: 186-257 Revised: 30-Dec-2013 12:42 (LKB) Printed: 03-Jan-2014 17:11 Page 13 of 21 273 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.33e8 38.82 PCB-159 2.59e8 39.64 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.38e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-162 2.54e8 39.88 156/157 4.95e8 41.27 PCB-167 2.73e8 40.29 (2.50e8 + 2.02e8) * 100 pg/uL RRF(PCB-169) = = 1.14 (5.54e7 + 4.38e7) * 400 pg/uL LKB 03-Jan-2014 15:13 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 1.01e8 PCB-169 2.50e8 43.99 5.03e7 0% 39.0 Rel. Int. 100% 128/166 3.53e8 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.35e4 40.0 PCB-162 PCB-159 2.08e8 2.11e8 39.88 39.64 41.0 42.0 43.0 44.0 45.0 156/157 4.05e8 41.27 Abs. Int. 8.13e7 PCB-169 2.02e8 43.99 PCB-167 2.23e8 40.29 4.06e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.89e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 6.07e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.14e8 41.25 0.00e0 RT Abs. Int. 2.04e7 ES-169 5.54e7 43.97 1.02e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 4.65e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 1.15e4 42.0 43.0 44.0 45.0 ES-156/157 8.87e7 41.25 0.00e0 RT Abs. Int. 1.58e7 ES-169 4.38e7 43.97 7.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0329, 5135 scc: 186-257 PKD: 30-Dec-2013 12:43 Printed: 03-Jan-2014 17:11 Page 14 of 21 274 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-184 PCB-188 PCB-179 1.36e8 1.40e8 1.53e8 36.30 35.83 35.55 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.20e3 PCB-186 1.35e8 36.99 Abs. Int. 3.81e7 PCB-178 1.01e8 38.12 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 PCB-179 1.27e8 1.41e8 35.83 35.55 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 1.40e3 37.0 PCB-176 1.36e8 36.59 PCB-186 1.24e8 36.99 38.0 32.0 33.0 34.0 35.0 36.0 37.0 PCB-178 9.30e7 38.12 38.0 ES-188 3.06e7 35.53 Rel. Int. 100% CS/SS-178 1.86e7 38.10 RRF(CS/SS-178) = 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.72e7 35.53 Rel. Int. 100% CS/SS-178 1.68e7 38.10 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.93e6 0.00e0 RT Abs. Int. 6.93e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.88e3 31.0 1.81e7 Abs. Int. 7.87e6 (1.86e7 + 1.68e7) = 0.571 (3.51e7 + 2.69e7) LKB 03-Jan-2014 15:12 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.68e3 0.00e0 RT Abs. Int. 3.61e7 0% 31.0 1.91e7 36.0 37.0 38.0 Rel. Int. 100% 3.47e6 0.00e0 RT Abs. Int. 1.88e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5850, 9481 scc: 186-257 Revised: 30-Dec-2013 12:43 (LKB) Printed: 03-Jan-2014 17:11 Page 15 of 21 275 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.32e4 PCB-183 1.69e8 39.42 PCB-182 PCB-185 1.72e8 1.65e8 39.08 39.51 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 180/193 3.63e8 42.40 171/173 2.79e8 PCB-181 40.53 PCB-177 1.59e8 1.38e8 40.34 39.99 PCB-172 1.44e8 41.88 PCB-191 2.00e8 42.74 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-170 1.39e8 43.51 Abs. Int. 6.46e7 PCB-190 1.98e8 43.96 3.23e7 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.40e4 40.0 PCB-182 1.63e8 39.07 PCB-187 1.58e8 38.89 PCB-183 1.60e8 39.42 41.0 171/173 2.64e8 PCB-181 40.53 PCB-177 1.51e8 1.30e8 40.34 39.99 42.0 43.0 180/193 3.43e8 42.40 PCB-172 1.36e8 41.88 PCB-191 1.88e8 42.73 44.0 PCB-170 1.33e8 43.51 45.0 Abs. Int. 6.16e7 PCB-190 1.88e8 43.96 3.08e7 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.62e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 9.22e6 ES-170 2.97e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 4.39e3 0.00e0 RT 4.61e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.33e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 8.14e6 ES-170 2.73e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.64e3 0.00e0 RT 4.07e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3134, 7737 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 16 of 21 276 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-189 2.13e8 46.13 Abs. Int. 5.10e7 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 7.35e3 2.55e7 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.02e8 46.12 Abs. Int. 4.99e7 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 5.38e3 2.50e7 0% 46.0 Rel. Int. 100% ES-189 4.82e7 46.11 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 5.63e3 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 1.16e7 (4.82e7 + 4.62e7) * 100 pg/uL RRF(ES-189) = = 1.58 (2.85e7 + 3.14e7) * 100 pg/uL LKB 03-Jan-2014 15:12 5.79e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.62e7 46.11 0.00e0 RT Abs. Int. 1.12e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 5.14e3 5.60e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6642, 3679 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 17 of 21 277 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-202 1.23e8 40.10 PCB-201 1.47e8 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 2.30e3 PCB-197 1.40e8 41.66 PCB-200 PCB-204 1.30e8 1.29e8 41.75 41.47 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 198/199 1.88e8 44.07 Abs. Int. 3.66e7 PCB-196 9.72e7 44.65 PCB-203 1.02e8 44.82 1.83e7 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.34e8 40.10 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.91e3 41.0 PCB-201 1.61e8 40.89 42.0 43.0 PCB-197 1.53e8 PCB-204 41.66 PCB-200 1.41e8 1.41e8 41.75 41.47 44.0 45.0 198/199 2.07e8 44.07 Abs. Int. 4.04e7 PCB-196 1.06e8 44.65 PCB-203 1.11e8 44.82 2.02e7 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.93e7 40.08 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.00e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.98e3 3.50e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.12e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.46e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 2.00e3 3.73e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0058, 7129 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 18 of 21 278 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 4.72e3 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-205 1.54e8 48.30 PCB-195 1.10e8 45.95 Abs. Int. 3.56e7 PCB-194 1.22e8 47.90 1.78e7 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 6.42e3 47.0 48.0 49.0 50.0 PCB-205 1.68e8 48.30 PCB-195 1.21e8 45.95 0.00e0 RT Abs. Int. 3.85e7 PCB-194 1.32e8 47.89 1.93e7 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.55e7 48.28 JS-194 2.85e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 4.99e3 49.0 0.00e0 RT Abs. Int. 8.26e6 4.13e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.96e7 48.28 Rel. Int. 100% Abs. Int. 9.37e6 JS-194 3.14e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.69e3 0.00e0 RT 4.68e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0147, 9308 scc: 186-257 Revised: 30-Dec-2013 12:43 (LKB) Printed: 03-Jan-2014 17:12 Page 19 of 21 279 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 3.76e3 PCB-208 1.42e8 45.74 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-207 1.50e8 46.53 Abs. Int. 3.60e7 PCB-206 9.85e7 49.77 1.80e7 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 5.22e3 PCB-208 1.81e8 45.74 47.0 48.0 49.0 50.0 PCB-207 1.90e8 46.53 Abs. Int. 4.58e7 PCB-206 1.25e8 49.77 2.29e7 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 3.15e7 45.72 50.0 0.00e0 RT Abs. Int. 7.52e6 ES-206 2.24e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.53e3 3.76e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.92e7 45.72 50.0 Abs. Int. 9.31e6 ES-206 2.77e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.58e3 0.00e0 RT 4.65e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9272, 3360 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:12 Page 20 of 21 280 of 417 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-209 1.58e8 51.25 Rel. Int. 100% Abs. Int. 3.32e7 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 7.36e2 1.66e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.34e8 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.80e7 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 8.28e2 1.40e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.60e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.71e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 1.07e3 3.86e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.05e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.37e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.97e2 3.18e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.17e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.58e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0022, 9026 scc: 186-257 PKD: 30-Dec-2013 12:40 Printed: 03-Jan-2014 17:12 Page 21 of 21 281 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.11 32.63 36.10 35.56 35.09 34.82 38.72 41.27 40.29 43.99 46.12 51.24 3.92E+09 3.81E+09 3.11E+09 3.45E+09 3.20E+09 3.32E+09 2.76E+09 5.55E+09 3.01E+09 2.75E+09 2.52E+09 1.71E+09 0.79 Y 0.78 Y 0.62 Y 0.63 Y 0.63 Y 0.62 Y 0.63 Y 1.23 Y 1.22 Y 1.24 Y 1.05 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.22 1.17 1.18 1.29 1.25 1.25 1.21 1.17 1.23 1.17 1.16 1.15 6.1% 4.4% 5.9% 6.9% 4.7% 3.0% 9.8% 6.3% 5.8% 4.3% 7.9% 3.3% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.03 14.35 14.61 20.38 17.73 26.74 20.67 33.09 32.61 25.67 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.25 40.27 43.97 43.49 42.42 35.53 46.11 40.08 48.27 49.75 45.72 51.22 2.62E+08 2.47E+08 1.23E+08 2.45E+08 1.20E+08 1.94E+08 9.79E+07 1.61E+08 1.63E+08 8.86E+07 1.32E+08 1.34E+08 1.28E+08 1.33E+08 1.14E+08 8.16E+07 1.13E+08 2.38E+08 1.22E+08 1.17E+08 6.70E+07 8.32E+07 6.88E+07 1.09E+08 7.17E+07 8.57E+07 5.62E+07 8.18E+07 7.42E+07 3.21 Y 3.30 Y 1.63 Y 1.53 Y 1.07 Y 1.09 Y 0.83 Y 0.79 Y 0.79 Y 1.66 Y 1.58 Y 1.60 Y 1.60 Y 1.59 Y 1.54 Y 1.32 Y 1.29 Y 1.27 Y 1.26 Y 1.27 Y 1.09 Y 1.09 Y 1.10 Y 1.01 Y 0.94 Y 0.89 Y 0.81 Y 0.80 Y 1.20 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.13 1.06 0.53 1.05 0.52 1.69 0.85 1.40 1.42 0.78 1.17 1.19 1.14 1.18 1.01 1.10 1.52 1.61 1.65 1.58 0.97 1.21 0.93 1.58 0.97 1.25 0.82 1.19 1.08 -5.6% -2.3% 0.9% 1.3% 2.2% 1.6% -0.9% 1.2% 4.0% -2.5% -2.9% -2.5% -1.9% -0.8% -2.2% -1.2% -4.1% 0.4% -1.0% 1.8% 2.9% 6.3% -1.1% -0.3% -0.2% 0.1% -1.6% 1.2% -2.8% Page 1 of 6 282 of 417 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.10 38.10 2.10E+08 1.37E+08 4.42E+07 1.08 Y 1.60 Y 1.12 Y 1.11 1.03 0.62 1.09 1.03 0.64 -2.3% 0.0% 3.8% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.10 38.10 2.10E+08 1.37E+08 4.42E+07 1.08 Y 1.60 Y 1.12 Y 1.85 1.22 0.58 1.83 1.21 0.60 -0.7% -0.7% 2.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.81 37.73 47.87 2.33E+08 1.15E+08 1.13E+08 7.41E+07 6.88E+07 1.55 Y 0.81 Y 1.60 Y 1.32 Y 0.90 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.05 14.37 14.63 20.39 17.75 26.76 20.69 25.69 30.66 35.55 40.10 48.29 45.74 49.77 4.77E+09 4.95E+09 3.16E+09 5.27E+09 2.86E+09 4.48E+09 2.66E+09 2.58E+09 2.91E+09 1.80E+09 1.58E+09 1.93E+09 1.95E+09 1.32E+09 2.71 Y 2.98 Y 1.59 Y 1.63 Y 1.05 Y 0.99 Y 0.82 Y 0.65 Y 1.29 Y 1.08 Y 0.92 Y 0.93 Y 0.79 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.91 1.00 1.29 1.08 1.19 1.16 1.36 1.46 1.29 1.31 1.10 1.13 1.19 1.18 -4.4% -0.6% 4.4% 5.5% 3.6% 7.4% 0.3% 1.6% 2.3% 3.0% 4.7% 6.3% 6.1% 5.5% Page 2 of 6 283 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 12.05 14.18 14.37 14.63 14.81 16.63 16.80 17.02 17.33 17.45 19.02 19.81 20.10 20.39 17.75 19.52 19.93 20.12 20.26 20.35 20.84 21.99 22.14 22.43 22.63 22.91 23.20 23.38 23.75 25.14 25.46 26.00 26.39 26.76 20.69 22.68 23.28 23.35 23.56 24.82 24.95 25.05 25.24 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 4.77E+09 5.06E+09 4.95E+09 3.16E+09 5.06E+09 4.77E+09 5.47E+09 5.14E+09 5.14E+09 5.25E+09 6.12E+09 5.26E+09 1.05E+10 5.27E+09 2.86E+09 7.69E+09 3.33E+09 4.61E+09 4.39E+09 2.55E+09 4.79E+09 4.49E+09 4.54E+09 9.34E+09 4.59E+09 4.84E+09 9.02E+09 9.35E+09 4.32E+09 4.81E+09 4.93E+09 4.32E+09 4.24E+09 4.48E+09 2.66E+09 5.80E+09 2.69E+09 2.73E+09 2.31E+09 2.76E+09 3.82E+09 2.28E+09 6.91E+09 RA 2.71 Y 2.92 Y 2.98 Y 1.59 Y 1.58 Y 1.62 Y 1.65 Y 1.63 Y 1.64 Y 1.64 Y 1.60 Y 1.63 Y 1.63 Y 1.63 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.00 Y 0.98 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.97 Y 0.98 Y 0.99 Y 0.98 Y 1.00 Y 0.99 Y 0.99 Y 0.82 Y 0.79 Y 0.79 Y 0.80 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.91 1.02 1.00 1.29 2.06 0.97 1.11 1.05 1.05 1.07 1.25 1.07 1.07 1.08 1.19 1.60 1.38 1.92 1.83 1.06 1.99 1.16 1.17 1.21 1.18 1.25 1.17 1.21 1.12 1.24 1.27 1.11 1.10 1.16 1.36 0.89 0.83 0.84 0.71 0.85 1.17 0.70 1.06 Dev'n -4.4% -0.9% -0.6% 4.4% 4.1% 2.9% 6.5% 5.3% 4.7% 3.7% 5.8% 6.2% 8.0% 5.5% 3.6% 4.0% 6.0% 5.5% 5.9% 5.3% 3.8% 2.3% 1.5% 3.0% 2.4% 2.1% 2.9% 2.9% 3.4% 6.2% 5.1% 0.9% 5.3% 7.4% 0.3% 1.5% 7.6% -2.6% 1.2% 0.5% 5.5% -1.5% 3.6% 284 of 417 PCB QC Summary - Ax2 Detail Lab ID: CS5_131220_PCB_XA Acquired: 20-DEC-2013 20:49 Datafile: 131220X08 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.02 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.52 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.79 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.37 PCB-67 23'45-TeCB 28.53 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.05 PCB-66 23'44'-TeCB 29.33 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.10 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.76 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.01 PCB-103 22'45'6-PeCB 27.71 PCB-94 22'356'-PeCB 27.90 PCB-95 22'35'6-PeCB 28.28 PCB-100/93 22'44'6/22'356-PeCB 28.50 PCB-102 22'456'-PeCB 28.61 PCB-98 22'34'6'-PeCB 28.68 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.24 PCB-89 22'346'-PeCB 29.65 PCB-121 23'45'6-PeCB 30.00 PCB-92 22'355'-PeCB 30.32 PCB-113/90/101 ...-PeCB 30.80 PCB-83 22'33'5-PeCB 31.24 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.79 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.42 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 2.83E+09 9.10E+09 1.15E+10 2.53E+09 2.38E+09 5.79E+09 4.17E+09 4.01E+09 4.24E+09 3.81E+09 4.00E+09 4.17E+09 4.37E+09 1.58E+10 3.68E+09 3.76E+09 3.68E+09 3.79E+09 4.36E+09 4.29E+09 3.62E+09 2.58E+09 2.25E+09 2.54E+09 2.18E+09 2.36E+09 4.75E+09 2.73E+09 2.05E+09 2.08E+09 2.73E+09 1.98E+09 2.09E+09 3.31E+09 2.25E+09 8.09E+09 1.82E+09 2.67E+09 3.15E+09 1.55E+10 3.32E+09 5.04E+09 3.01E+09 RA 0.79 Y 0.79 Y 0.81 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.65 Y 0.65 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.64 Y 0.61 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.68 Y 0.62 Y 0.63 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.87 0.93 1.18 0.78 0.73 0.89 1.28 1.23 1.30 1.17 1.23 1.28 1.34 1.21 1.13 1.15 1.13 1.16 1.34 1.32 1.11 1.46 1.27 0.95 0.82 0.89 0.89 1.02 0.77 0.78 1.03 0.74 0.79 1.24 0.84 1.01 0.69 1.00 1.18 0.97 1.25 0.95 1.13 Dev'n 3.4% 3.0% 1.4% 1.9% 5.0% 3.5% 4.8% 1.8% 1.9% 0.4% 4.1% 1.6% 3.2% 1.4% 2.4% 3.0% 1.6% 2.6% 1.9% 0.8% 4.6% 1.6% 3.5% 2.6% 2.5% 2.4% 3.4% 5.8% 1.6% -2.2% 8.9% 3.7% 3.0% 3.7% 2.9% 2.8% -4.1% 8.8% 1.3% -0.7% 9.6% 0.6% 1.1% 285 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 32.62 32.81 33.13 33.53 34.50 34.71 34.93 35.39 37.34 30.66 30.82 30.97 31.27 31.54 32.82 33.34 33.55 33.81 34.12 34.29 34.37 34.64 34.81 34.96 35.19 35.60 35.94 36.15 36.27 36.70 36.85 37.19 37.39 37.47 37.77 37.90 38.09 38.82 39.64 39.88 35.55 35.83 36.30 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 3.31E+09 1.94E+09 3.35E+09 3.41E+09 6.21E+09 3.61E+09 3.03E+09 2.83E+09 3.14E+09 2.91E+09 2.78E+09 2.75E+09 2.61E+09 2.61E+09 2.03E+09 3.85E+09 2.26E+09 1.97E+09 4.02E+09 1.54E+09 1.89E+09 4.13E+09 1.73E+09 1.72E+09 1.74E+09 1.91E+09 2.36E+09 2.06E+09 2.61E+09 4.99E+09 1.83E+09 1.63E+09 2.02E+09 2.53E+09 6.19E+09 2.49E+09 2.80E+09 4.79E+09 2.87E+09 2.82E+09 1.80E+09 1.59E+09 1.62E+09 RA 0.63 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 1.29 Y 1.26 Y 1.26 Y 1.27 Y 1.28 Y 1.30 Y 1.28 Y 1.26 Y 1.28 Y 1.26 Y 1.26 Y 1.28 Y 1.28 Y 1.28 Y 1.26 Y 1.27 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.26 Y 1.27 Y 1.29 Y 1.26 Y 1.29 Y 1.28 Y 1.22 Y 1.23 Y 1.22 Y 1.08 Y 1.11 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.24 0.73 1.26 1.28 1.17 1.36 1.14 1.06 1.19 1.29 1.23 1.22 1.16 1.16 1.25 1.18 1.38 1.20 1.23 0.94 1.16 1.27 1.06 1.06 1.06 1.17 1.44 1.26 1.60 1.53 1.12 1.00 1.24 1.55 1.27 1.52 1.72 0.98 1.17 1.15 1.31 1.15 1.17 Dev'n 7.2% 4.5% 3.1% 5.7% 6.2% 8.2% 3.1% 6.1% 8.8% 2.3% 5.0% 3.6% 8.4% 3.7% 5.4% 3.6% 3.2% 1.8% 4.9% 2.0% 2.7% 5.1% 3.7% 6.7% 3.2% 3.7% 2.5% 5.0% 5.3% 5.0% 2.9% 3.0% 6.3% 3.5% 6.4% 0.6% 3.4% 8.8% 5.3% 7.5% 3.0% -0.7% 4.2% 286 of 417 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 36.59 36.99 38.12 38.67 38.90 39.08 39.42 39.51 39.62 39.99 40.34 40.53 41.88 42.13 42.40 42.73 43.51 43.96 40.10 40.89 41.47 41.66 41.75 44.07 44.65 44.82 45.95 47.89 48.29 45.74 46.53 49.77 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 1.74E+09 1.57E+09 1.21E+09 1.91E+09 2.01E+09 2.05E+09 2.03E+09 2.01E+09 1.71E+09 1.65E+09 1.95E+09 3.42E+09 1.73E+09 2.27E+09 4.38E+09 2.40E+09 1.66E+09 2.44E+09 1.58E+09 1.78E+09 1.66E+09 1.80E+09 1.68E+09 2.46E+09 1.24E+09 1.30E+09 1.40E+09 1.50E+09 1.93E+09 1.95E+09 2.03E+09 1.32E+09 RA 1.08 Y 1.09 Y 1.09 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 0.92 Y 0.92 Y 0.92 Y 0.92 Y 0.92 Y 0.91 Y 0.91 Y 0.92 Y 0.92 Y 0.93 Y 0.93 Y 0.79 Y 0.79 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.26 1.14 0.88 1.15 1.21 1.23 1.22 1.21 1.03 0.99 1.17 1.03 1.04 1.36 1.31 1.44 1.24 1.82 1.10 1.24 1.16 1.26 1.17 0.86 0.87 0.91 0.82 0.88 1.13 1.19 1.24 1.18 Dev'n 2.3% 1.1% 4.2% 7.1% 6.2% 4.6% 1.1% 13.9% 4.0% 4.3% 7.5% 8.3% 5.0% 5.9% 4.3% 3.3% 9.0% 9.7% 4.7% 1.8% 3.8% 5.5% 6.1% 5.9% 3.9% 4.0% 6.5% 4.1% 6.3% 6.1% 4.2% 5.5% 287 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.74e7 2.37e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.57e7 1.28e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.87e7 9.33e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.96e7 9.79e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.14e7 5.71e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.71e6 2.86e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.37e6 2.68e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 807-075 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:13 Page 1 of 21 288 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-1 3.48e9 12.05 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-2 3.77e9 14.18 Abs. Int. 1.07e9 PCB-3 3.71e9 14.37 MoCB 10.03-16.00 188.0393 Fn1 Flags: OPBM 4σ 4.15e3 5.37e8 0% 11.0 12.0 13.0 PCB-1 1.29e9 12.05 Rel. Int. 100% 14.0 PCB-2 1.29e9 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.52e3 15.0 0.00e0 16.0 RT Abs. Int. 5.17e8 PCB-3 1.25e9 14.37 2.58e8 0% 11.0 12.0 13.0 14.0 ES-1 2.00e8 12.03 Rel. Int. 100% 15.0 Abs. Int. 7.82e7 ES-3 1.89e8 14.35 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 7.14e3 0.00e0 16.0 RT 3.91e7 0% 11.0 12.0 13.0 14.0 ES-1 6.21e7 12.03 Rel. Int. 100% 15.0 Abs. Int. 2.45e7 ES-3 5.75e7 14.35 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.23e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.74e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.37e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7909, 8443 scc: 807-075 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 2 of 21 289 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Rel. Int. 100% PCB-4 1.94e9 14.63 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: OPBM 4σ 5.76e3 PCB-10 3.10e9 14.81 5.11e8 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 1.96e9 14.81 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.26e4 PCB-4 1.22e9 14.63 12.0 13.0 14.0 15.0 ES-4 7.59e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.47e8 3.23e8 0% 11.0 Abs. Int. 1.02e9 0.00e0 16.0 RT Abs. Int. 2.55e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.86e3 1.27e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.67e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.50e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.71e3 7.49e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.74e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.37e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9558, 1963 scc: 807-075 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 3 of 21 290 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: OPBM 4σ 1.34e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-6 3.19e9 17.02 PCB-9 2.95e9 16.63 PCB-14 3.77e9 19.02 PCB-5 3.19e9 17.33 PCB-8 3.26e9 17.45 PCB-11 3.26e9 19.81 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 13/12 6.49e9 20.10 Abs. Int. 1.07e9 PCB-15 3.27e9 20.39 5.36e8 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 3.90e4 PCB-9 1.82e9 16.63 18.0 PCB-14 2.35e9 19.02 PCB-5 1.95e9 PCB-8 17.33 1.99e9 17.45 PCB-7 2.06e9 16.80 19.0 20.0 PCB-11 2.00e9 19.81 13/12 3.99e9 20.10 21.0 Abs. Int. 6.86e8 PCB-15 2.01e9 20.39 3.43e8 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.42e8 16.61 21.0 ES-15 1.48e8 20.38 0.00e0 RT Abs. Int. 4.57e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.73e4 2.28e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 9.12e7 16.61 21.0 ES-15 9.71e7 20.38 0.00e0 RT Abs. Int. 2.93e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.93e3 1.46e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3253, 5347 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 4 of 21 291 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 30/18 3.92e9 19.52 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: OPBM 4σ 4.61e3 PCB-19 1.46e9 17.75 PCB-17 1.71e9 19.93 PCB-27 2.36e9 20.12 PCB-24 2.24e9 20.26 PCB-16 1.30e9 20.35 Abs. Int. 1.05e9 PCB-32 2.46e9 20.84 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 3.78e9 19.52 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: OPBM 4σ 3.65e3 PCB-19 1.40e9 17.75 PCB-17 1.62e9 19.93 PCB-24 2.15e9 20.26 PCB-27 2.25e9 20.12 PCB-16 1.24e9 20.35 21.0 Rel. Int. 100% 18.0 19.0 20.0 PCB-32 2.34e9 20.83 21.0 5.20e8 0.00e0 RT Abs. Int. 2.64e7 ES-19 6.21e7 17.73 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 9.95e4 0.00e0 RT Abs. Int. 1.04e9 0% 17.0 5.26e8 1.32e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.45e7 ES-19 5.82e7 17.73 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.48e4 0.00e0 RT 1.22e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8073, 3622 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 5 of 21 292 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 28/20 4.47e9 23.20 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: OPBM 4σ 4.92e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-23 PCB-34 2.25e9 2.24e9 22.14 21.99 26/29 4.64e9 22.43 PCB-31 2.40e9 22.91 Abs. Int. 1.07e9 PCB-22 2.14e9 23.75 PCB-36 2.39e9 25.14 PCB-39 2.44e9 25.46 PCB-38 2.15e9 26.00 PCB-35 2.11e9 26.39 PCB-37 2.23e9 26.76 0% 22.0 24.0 25.0 26.0 27.0 28/20 4.55e9 23.20 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: OPBM 4σ 5.05e4 23.0 PCB-23 PCB-34 2.29e9 2.25e9 22.14 21.99 26/29 4.70e9 22.43 PCB-31 2.44e9 22.91 23.0 PCB-22 2.18e9 23.75 PCB-36 2.42e9 25.14 PCB-39 2.49e9 25.46 PCB-38 2.16e9 26.00 24.0 25.0 PCB-35 2.13e9 26.39 PCB-37 2.25e9 26.75 26.0 CS/SS-28 1.09e8 23.16 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e9 5.32e8 0% 22.0 5.35e8 27.0 ES-37 1.01e8 26.74 0.00e0 RT Abs. Int. 2.96e7 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 8.57e4 1.48e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 1.01e8 23.16 Rel. Int. 100% 27.0 ES-37 9.28e7 26.74 0.00e0 RT Abs. Int. 2.82e7 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.96e4 1.41e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3047, 4081 scc: 807-075 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 6 of 21 293 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-54 1.20e9 20.69 Rel. Int. 100% Abs. Int. 3.45e8 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 2.02e3 1.72e8 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.46e9 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.14e8 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.44e3 2.07e8 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.43e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.72e4 6.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 5.36e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.53e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.34e4 7.63e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0340, 6239 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 7 of 21 294 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 5.68e3 50/53 2.56e9 22.68 PCB-51 1.21e9 23.35 PCB-45 1.19e9 23.28 PCB-73 1.69e9 PCB-52 24.95 1.22e9 24.82 PCB-46 1.02e9 23.56 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 59/62… 44/47… 5.18e9 4.02e9 26.02 25.74 69/49 3.05e9 25.24 PCB-48 1.25e9 25.52 PCB-42 1.12e9 26.18 71/40 2.56e9 26.61 PCB-41 1.04e9 26.52 Abs. Int. 9.33e8 PCB-64 1.85e9 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: OPBM 4σ 6.24e3 50/53 3.24e9 22.68 24.0 PCB-51 1.52e9 23.35 PCB-45 1.50e9 23.28 25.0 PCB-73 2.13e9 PCB-52 24.95 1.54e9 24.82 PCB-46 1.29e9 23.56 26.0 44/47… 59/62… 5.08e9 6.37e9 26.02 25.74 69/49 3.85e9 25.24 PCB-48 1.58e9 25.52 PCB-42 1.41e9 26.18 27.0 PCB-64 2.32e9 26.81 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.11e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e9 71/40 3.23e9 26.61 PCB-41 1.33e9 26.52 4.66e8 5.33e8 0.00e0 RT Abs. Int. 1.44e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.50e4 7.22e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 6.35e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.80e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 2.42e4 9.02e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7633, 4971 scc: 807-075 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 8 of 21 295 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 3.46e6 PCB-58 1.77e9 PCB-68 28.37 PCB-67 1.86e9 1.83e9 27.79 28.53 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 61/70... 7.00e9 29.05 PCB-55 1.66e9 29.47 PCB-60 PCB-80 1.67e9 1.92e9 30.10 30.43 PCB-79 1.89e9 31.76 PCB-78 1.60e9 32.25PCB-81 1.67e9 32.63 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Abs. Int. 8.48e8 PCB-77 1.73e9 33.11 4.24e8 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: OPBM 4σ 2.54e6 PCB-68 2.38e9 27.79 30.0 61/70... 8.84e9 PCB-60 PCB-67 29.05 2.13e9 2.34e9 30.10 28.53 PCB-63 PCB-80 2.44e9 PCB-66 PCB-56 2.06e9 2.05e9 2.44e9 28.75 29.91 29.33 30.43 32.0 PCB-79 2.40e9 31.76 34.0 PCB-78 2.02e9 32.25PCB-81 2.13e9 32.63 36.0 38.0 Abs. Int. 1.07e9 PCB-77 2.19e9 33.11 5.33e8 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.18e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.65e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 2.00e7 ES-77 7.10e7 33.09 9.98e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 9.11e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.84e4 36.0 38.0 0.00e0 RT Abs. Int. 2.45e7 ES-77 8.96e7 33.09 1.23e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3954, 5702 scc: 807-075 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 9 of 21 296 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-104 1.01e9 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.69e3 Abs. Int. 2.66e8 PCB-96 8.84e8 26.01 1.33e8 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 1.57e9 25.69 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.74e3 27.0 0.00e0 RT Abs. Int. 4.07e8 PCB-96 1.37e9 26.01 2.04e8 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 5.53e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.48e3 7.06e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 3.33e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.34e3 4.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6832, 9715 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 10 of 21 297 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 108/119... 6.27e9 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 6.54e6 PCB-103 9.76e8 27.71 100/93 1.82e9 28.50 PCB-88 7.91e8 28.98 PCB-121 1.27e9 30.00 113/90… 3.10e9 30.80 116/85 1.94e9 32.42 PCB-99 1.03e9 31.34 PCB-111 PCB-120 1.29e9 1.30e9 33.13 33.53 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-118 107/124 1.23e9 2.39e9 35.09 34.50 PCB-114 PCB-123 1.33e9 1.27e9 35.56 34.82 Abs. Int. 8.81e8 PCB-105 1.20e9 36.10 PCB-127 1.21e9 37.34 4.40e8 0% 28.0 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: OPBM 4σ 5.33e6 30.0 100/93 2.93e9 28.50 PCB-94 1.34e9 27.90 PCB-91 1.68e9 29.04 PCB-121 2.05e9 30.00 32.0 113/90… 4.99e9 30.80 34.0 108/119... 9.26e9 31.79 PCB-112 1.93e9 31.44 116/85 PCB-115 3.10e9 2.03e9 32.42 32.62 PCB-111 2.06e9 PCB-117 PCB-110 33.13 PCB-120 2.05e9 1.85e9 2.11e9 32.33 PCB-82 32.53 33.53 1.20e9 32.81 36.0 107/124 PCB-118 3.82e9 1.97e9 34.50 35.09 PCB-114 PCB-123 2.12e9 2.05e9 35.56 34.82 38.0 Abs. Int. 1.07e9 PCB-105 1.91e9 36.10 PCB-127 1.94e9 37.34 5.37e8 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 8.44e7 33.10 JS-101 6.96e7 30.81 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 9.28e3 34.0 36.0 ES-123 8.16e7 34.79 ES-114 8.27e7 35.54 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 2.13e7 ES-105 8.08e7 36.08 1.07e7 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.27e7 33.11 JS-101 4.34e7 30.81 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 6.82e3 34.0 36.0 ES-118 ES-123 4.95e7 5.15e7 35.07 34.79 38.0 0.00e0 RT Abs. Int. 1.32e7 ES-105 5.11e7 36.08 6.61e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0782, 2709 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 11 of 21 298 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Abs. Int. 2.63e8 PCB-126 1.07e9 38.72 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.64e4 1.32e8 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 4.19e8 PCB-126 1.69e9 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 2.44e4 2.09e8 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.65e7 ES-126 6.89e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.99e3 8.25e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.08e7 ES-126 4.48e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 8.23e3 5.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1246, 7147 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 12 of 21 299 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% PCB-150 PCB-155 1.54e9 1.64e9 30.97 30.66 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.19e4 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 147/149 139/140 2.24e9 2.32e9 34.64 34.12 PCB-145 1.46e9 31.54 PCB-148 1.15e9 32.82 153/168 2.80e9 36.70 151/135PCB-144 2.16e9 1.10e9 PCB-143 PCB-142 PCB-133 PCB-146 1.06e9 9.62e8 1.07e9 1.15e9 33.34 33.81 36.15 34.37 35.60 34.96 PCB-141 1.02e9 36.85 163/138… 3.46e9 37.77 PCB-164 PCB-160 1.42e9 1.40e9 37.47 37.90 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PCB-150 PCB-155 1.22e9 1.27e9 30.97 30.66 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.03e4 PCB-145 1.15e9 31.54 PCB-148 8.85e8 32.82 147/149 139/140 151/135 1.78e9 1.81e9 1.69e9 34.12 34.64 33.34 PCB-154 9.99e8 PCB-143 PCB-131 33.55 8.28e8 7.60e8 34.37 34.81 36.0 38.0 153/168 2.19e9 36.70 PCB-165 1.04e9 35.94 163/138… 2.74e9 37.77 PCB-137 PCB-141 8.87e8 8.04e8 37.39 36.85 30.0 32.0 34.0 36.0 38.0 ES-153 4.65e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.02e4 0.00e0 RT Abs. Int. 5.14e8 2.57e8 ES-155 6.35e7 30.64 Rel. Int. 100% 3.23e8 PCB-158 1.23e9 38.09 0% 28.0 Abs. Int. 6.47e8 0.00e0 RT Abs. Int. 1.67e7 JS-138 4.21e7 37.73 8.33e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.94e7 30.64 Rel. Int. 100% ES-153 3.51e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 9.67e3 0.00e0 RT Abs. Int. 1.26e7 JS-138 3.19e7 37.73 6.31e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2850, 7769 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 13 of 21 300 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 2.63e9 38.82 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.24e4 PCB-159 1.58e9 39.64 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-162 1.55e9 39.88 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 156/157 3.06e9 41.27 Abs. Int. 6.29e8 PCB-169 1.52e9 43.99 PCB-167 1.65e9 40.29 3.15e8 0% 39.0 Rel. Int. 100% 40.0 128/166 2.16e9 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 3.49e4 PCB-159 1.29e9 39.64 PCB-162 1.27e9 39.88 41.0 42.0 43.0 44.0 45.0 156/157 2.49e9 41.27 Abs. Int. 5.14e8 PCB-169 1.23e9 43.99 PCB-167 1.35e9 40.29 2.57e8 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 6.83e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 9.18e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.33e8 41.25 0.00e0 RT Abs. Int. 2.38e7 ES-169 6.57e7 43.97 1.19e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.40e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 1.04e4 42.0 43.0 44.0 45.0 ES-156/157 1.05e8 41.25 0.00e0 RT Abs. Int. 1.92e7 ES-169 5.16e7 43.97 9.61e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1763, 4652 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 14 of 21 301 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-184 PCB-188 PCB-179 8.43e8 8.35e8 9.36e8 36.30 35.83 35.55 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.64e3 PCB-186 8.18e8 36.99 Abs. Int. 2.32e8 PCB-178 6.30e8 38.12 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 PCB-179 7.54e8 8.64e8 35.83 35.55 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.12e3 37.0 PCB-176 8.33e8 36.59 PCB-186 7.49e8 36.99 38.0 1.16e8 0.00e0 RT Abs. Int. 2.17e8 PCB-178 5.80e8 38.12 1.09e8 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.60e7 35.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.14e6 CS/SS-178 2.33e7 38.10 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 7.77e3 4.57e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.28e7 35.53 Rel. Int. 100% Abs. Int. 8.50e6 CS/SS-178 2.09e7 38.10 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 8.62e3 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 4.25e6 0.00e0 RT Abs. Int. 1.96e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2899, 3493 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 15 of 21 302 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 3.40e4 PCB-183 1.04e9 39.42 PCB-182 PCB-185 1.05e9 1.03e9 39.08 39.51 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 171/173 1.76e9 PCB-181 40.53 PCB-177 1.00e9 8.47e8 40.34 39.99 180/193 2.25e9 42.40 PCB-172 8.89e8 41.88 PCB-191 1.23e9 42.73 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-170 8.50e8 43.51 Abs. Int. 4.06e8 PCB-190 1.25e9 43.96 2.03e8 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 3.24e4 PCB-182 9.93e8 39.08 PCB-187 9.76e8 38.90 40.0 41.0 PCB-185 9.75e8 171/173 39.51 1.66e9 PCB-183 PCB-181 40.53 9.87e8 PCB-174 PCB-177 9.47e8 39.428.30e8 40.34 8.03e8 39.62 39.99 42.0 43.0 180/193 2.13e9 42.40 PCB-172 8.40e8 41.88 PCB-191 1.16e9 42.73 44.0 PCB-170 8.08e8 43.51 45.0 Abs. Int. 3.84e8 PCB-190 1.19e9 43.96 1.92e8 0% 39.0 40.0 41.0 42.0 43.0 ES-180 4.34e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 1.07e7 ES-170 3.49e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 4.84e3 0.00e0 RT 5.36e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.98e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 9.63e6 ES-170 3.21e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 5.08e3 0.00e0 RT 4.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2041, 8697 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 16 of 21 303 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-189 1.29e9 46.12 Abs. Int. 3.12e8 (1.29e9 + 1.23e9) * 100 pg/uL RRF(PCB-189) = = 1.16 (5.47e7 + 5.39e7) * 2000 pg/uL LKB 03-Jan-2014 15:14 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.63e4 1.56e8 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.23e9 46.12 Abs. Int. 3.06e8 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 1.40e4 1.53e8 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 5.47e7 46.11 0.00e0 RT Abs. Int. 1.27e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 4.44e3 6.36e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 5.39e7 46.11 0.00e0 RT Abs. Int. 1.27e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.76e3 6.37e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2216, 7571 scc: 807-075 PKD: 30-Dec-2013 12:54 Printed: 03-Jan-2014 17:13 Page 17 of 21 304 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-202 7.56e8 40.10 Rel. Int. 100% PCB-201 8.55e8 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.48e4 PCB-197 8.62e8 PCB-204 41.66 PCB-200 8.05e8 7.97e8 41.75 41.47 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 198/199 1.17e9 44.07 Abs. Int. 2.15e8 PCB-196 5.92e8 44.65 PCB-203 6.25e8 44.82 1.08e8 0% 39.0 Rel. Int. 100% 40.0 PCB-202 8.24e8 40.10 41.0 PCB-201 9.27e8 40.89 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.08e4 42.0 43.0 44.0 45.0 198/199 1.28e9 44.07 PCB-197 9.38e8 PCB-204 41.66 PCB-200 8.78e8 8.63e8 41.75 41.47 0.00e0 RT Abs. Int. 2.36e8 PCB-196 6.50e8 44.65 PCB-203 6.78e8 44.82 1.18e8 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.48e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.29e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 3.12e3 4.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.68e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.97e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 3.99e3 4.48e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0215, 8218 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 18 of 21 305 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.20e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-205 9.28e8 48.29 PCB-195 6.71e8 45.95 Abs. Int. 2.26e8 PCB-194 7.24e8 47.89 1.13e8 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.62e4 47.0 48.0 49.0 50.0 PCB-205 1.00e9 48.29 PCB-195 7.29e8 45.94 0.00e0 RT Abs. Int. 2.44e8 PCB-194 7.81e8 47.89 1.22e8 0% 46.0 47.0 48.0 49.0 50.0 ES-205 4.04e7 48.27 Rel. Int. 100% Abs. Int. 9.47e6 JS-194 3.26e7 47.87 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.58e3 0.00e0 RT 4.73e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 4.53e7 48.27 Rel. Int. 100% Abs. Int. 1.07e7 JS-194 3.62e7 47.87 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.24e3 0.00e0 RT 5.36e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5003, 9428 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 19 of 21 306 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.01e4 PCB-208 8.58e8 45.74 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-207 8.96e8 46.53 Abs. Int. 2.14e8 PCB-206 5.80e8 49.77 1.07e8 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 9.96e3 PCB-208 1.09e9 45.74 47.0 48.0 49.0 50.0 PCB-207 1.14e9 46.53 Abs. Int. 2.72e8 PCB-206 7.39e8 49.77 1.36e8 0% 46.0 Rel. Int. 100% ES-208 3.65e7 45.72 47.0 48.0 49.0 (2.51e7 + 3.11e7) * 100 pg/uL RRF(ES-206) = = 0.817 (3.26e7 + 3.62e7) * 100 pg/uL LKB 03-Jan-2014 15:15 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.91e3 50.0 0.00e0 RT Abs. Int. 8.88e6 ES-206 2.51e7 49.75 4.44e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 4.54e7 45.72 50.0 Abs. Int. 1.10e7 ES-206 3.11e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 3.68e3 0.00e0 RT 5.50e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9164, 3773 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 20 of 21 307 of 417 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-209 9.25e8 51.24 Rel. Int. 100% Abs. Int. 1.91e8 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.67e2 9.53e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 7.84e8 51.24 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.62e8 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 7.64e2 8.12e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 4.05e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 8.58e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 9.63e2 4.29e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.38e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.95e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 9.42e2 3.48e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.37e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.68e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2549, 9998 scc: 807-075 PKD: 30-Dec-2013 12:54 Printed: 03-Jan-2014 17:13 Page 21 of 21 308 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.22e7 2.61e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.72e7 1.36e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 2.01e7 1.00e7 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.04e7 1.02e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.13e7 5.65e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.41e6 2.71e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.01e6 2.51e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 307-094 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:20 Page 1 of 21 309 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.16e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 3.94e3 1.58e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.54e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 4.69e3 7.70e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.27e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.36e3 6.37e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.24e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.44e4 1.62e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7343, 4554 scc: 307-094 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 2 of 21 310 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.28e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 5.78e3 6.40e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.33e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.40e4 2.67e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.06e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 1.15e4 1.53e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.13e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.54e3 4.07e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5268, 6714 scc: 307-094 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:20 Page 3 of 21 311 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 4.54e4 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PB 4σ 1.00e4 2.27e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PB 4σ 3.46e4 5.29e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PB 4σ 2.39e4 6.65e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.80e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 5.74e3 8.99e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7794, 8414 scc: 307-094 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 4 of 21 312 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.24e4 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PB 4σ 3.92e3 1.62e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.45e4 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PB 4σ 3.55e3 7.26e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e7 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PB 4σ 8.60e4 8.24e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e6 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 3.76e4 9.38e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9784, 2296 scc: 307-094 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 5 of 21 313 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-36 2.93e5 25.14 Abs. Int. 7.96e4 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.38e3 3.98e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-36 2.95e5 25.14 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.83e4 TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.71e3 4.42e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.09e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PB 4σ 1.03e5 3.54e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.88e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PB 4σ 2.46e4 4.44e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3148, 7222 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 6 of 21 314 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.93e3 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.09e3 1.96e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.96e3 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 2.52e3 2.48e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.40e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.94e4 1.70e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.28e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 1.07e4 1.14e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0991, 8988 scc: 307-094 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:20 Page 7 of 21 315 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.17e4 TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PB 4σ 2.25e3 5.84e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.15e4 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PB 4σ 2.67e3 5.76e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.91e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 2.82e4 2.96e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.07e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.92e4 1.53e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7948, 8617 scc: 307-094 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 8 of 21 316 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-79 2.26e5 31.75 PCB-72 2.07e5 27.52 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 6.17e4 PCB-78 1.97e5 32.24 TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.66e3 3.08e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 2.56e5 27.52 32.0 PCB-79 2.68e5 31.75 TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 3.32e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.90e4 PCB-78 2.72e5 32.24 3.95e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e5 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.37e4 5.49e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.25e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 2.33e4 2.12e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7736, 9764 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 9 of 21 317 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-96 1.05e5 26.00 Rel. Int. 100% Abs. Int. 3.40e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.14e3 1.70e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 1.64e5 26.00 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e4 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.87e3 2.36e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.13e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 1.83e3 4.07e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e4 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 3.05e3 6.03e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0353, 9971 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 10 of 21 318 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 1.10e5 28.67 PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 1.82e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 1.77e5 34.49 PCB-89 1.08e5 29.65 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 4.57e4 PCB-106 1.42e5 34.92 2.29e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 1.77e5 28.66 PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 2.25e3 32.0 34.0 107/124 2.62e5 34.49 PCB-89 1.65e5 29.65 36.0 38.0 0.00e0 RT Abs. Int. 6.64e4 PCB-106 2.46e5 34.92 3.32e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.39e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PB 4σ 2.97e3 4.19e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.10e4 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 3.35e3 1.05e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0422, 7587 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 11 of 21 319 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.14e4 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PB 4σ 1.38e3 5.68e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e4 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PB 4σ 2.07e3 5.82e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e4 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PB 4σ 3.86e3 5.35e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.79e3 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 3.22e3 4.40e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8143, 7330 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 12 of 21 320 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-152 1.98e5 30.81 Rel. Int. 100% Abs. Int. 5.01e4 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.45e3 2.51e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 1.63e5 30.82 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.90e4 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.20e3 2.45e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.02e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.13e3 3.51e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.52e3 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 1.46e3 4.26e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9006, 0485 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 13 of 21 321 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 4.57e4 128/166 1.94e5 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.70e3 2.29e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.57e4 128/166 1.54e5 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.45e3 1.78e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e4 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.35e3 5.83e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e4 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 2.67e3 6.86e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3751, 1283 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 14 of 21 322 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-184 1.12e5 36.29 Rel. Int. 100% Abs. Int. 2.62e4 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.47e2 1.31e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 9.31e4 36.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e4 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.58e2 1.29e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.56e3 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.34e3 3.28e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.66e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.42e3 2.83e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2030, 9921 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 15 of 21 323 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-182 1.14e5 39.07 Abs. Int. 3.24e4 HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.43e3 1.62e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 1.15e5 39.07 0.00e0 RT Abs. Int. 3.09e4 HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.38e3 1.55e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.25e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 2.06e3 3.63e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.88e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.65e3 4.44e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9648, 6911 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 16 of 21 324 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.01e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PB 4σ 1.19e3 5.03e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.51e3 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PB 4σ 1.11e3 4.26e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.79e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.59e3 3.90e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.31e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.83e3 3.16e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7686, 7875 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 17 of 21 325 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-204 9.83e4 41.46 Rel. Int. 100% Abs. Int. 2.26e4 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.80e2 1.13e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 1.07e5 41.46 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.65e4 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 9.64e2 1.33e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.22e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.43e3 2.61e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.84e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.17e3 2.42e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7434, 5203 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 18 of 21 326 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 5.92e3 OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PB 4σ 9.45e2 2.96e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.14e3 OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PB 4σ 1.03e3 3.57e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.89e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 9.26e2 1.95e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.29e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 1.20e3 2.14e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3968, 5793 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 19 of 21 327 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 6.43e3 NoCB 45.52-50.76 461.7245 Fn6 Flags: PB 4σ 8.92e2 3.21e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.70e3 NoCB 45.52-50.76 463.7216 Fn6 Flags: PB 4σ 1.80e3 4.35e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 7.83e2 1.70e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.03e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 9.21e2 1.52e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1314, 4053 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 20 of 21 328 of 417 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 9.53e3 DeCB 50.77-52.00 497.6826 Fn7 Flags: PB 4σ 6.42e2 4.77e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 8.19e3 DeCB 50.77-52.00 499.6797 Fn7 Flags: PB 4σ 5.71e2 4.09e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.38e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 8.45e2 3.69e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.06e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 9.91e2 2.03e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.01e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.51e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2056, 2173 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 21 of 21 329 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.22e7 2.61e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.70e7 1.35e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.95e7 9.77e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.02e7 1.01e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.16e7 5.82e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.65e6 2.82e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.37e6 2.69e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 023-880 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:21 Page 1 of 21 330 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% PCB-2 2.54e5 14.19 PCB-1 9.53e4 12.05 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 5.93e3 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 8.74e4 PCB-3 2.45e5 14.37 4.37e4 0% 11.0 12.0 13.0 Rel. Int. 100% PCB-2 7.20e4 14.19 PCB-1 3.41e4 12.05 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.60e3 14.0 15.0 0.00e0 16.0 RT Abs. Int. 3.18e4 PCB-3 8.20e4 14.37 1.59e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.47e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.84e3 7.33e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.77e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.83e4 1.39e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0471, 6660 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:21 Page 2 of 21 331 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. 100% Abs. Int. 2.84e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: B 4σ 9.07e3 1.42e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.71e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.21e4 2.35e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.27e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 9.85e3 1.63e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.15e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.73e3 4.07e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6955, 1198 scc: 023-880 Revised: 03-Jan-2014 10:42 (LKB) Printed: 03-Jan-2014 15:21 Page 3 of 21 332 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 13/12 7.84e5 20.10 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 7.95e3 Abs. Int. 1.62e5 PCB-15 5.54e5 20.40 8.10e4 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 13/12 4.79e5 20.11 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 3.56e4 21.0 0.00e0 RT Abs. Int. 1.68e5 PCB-15 2.92e5 20.40 8.40e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.47e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PB 4σ 2.95e4 7.34e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 8.05e3 8.91e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1004, 1945 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:21 Page 4 of 21 333 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 30/18 1.02e5 19.51 Rel. Int. 100% PCB-32 9.86e4 20.83 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 5.05e3 Abs. Int. 3.37e4 1.69e4 0% 17.0 18.0 19.0 20.0 30/18 8.90e4 19.51 Rel. Int. 100% 21.0 PCB-32 9.05e4 20.83 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 5.21e3 0.00e0 RT Abs. Int. 2.80e4 1.40e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.62e6 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PB 4σ 7.41e4 1.81e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e5 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 4.02e4 2.37e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7330, 0490 scc: 023-880 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 5 of 21 334 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 6.17e3 PCB-25 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 28/20 1.95e5 4.56e5 22.62 23.19 21/33 PCB-31 26/29 PCB-22 3.54e5 PCB-34 PCB-23 2.70e5 2.18e5 2.16e5 23.37 1.14e5 1.01e5 22.90 22.42 23.75 21.99 22.13 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 2.29e5 PCB-36 8.79e5 25.14 PCB-39 2.73e5 25.46 PCB-38 2.32e5 26.00 PCB-35 3.72e5 26.39 PCB-37 4.64e5 26.75 0% 22.0 23.0 24.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 5.69e3 25.0 26.0 27.0 PCB-34 PCB-23 1.21e5 8.99e4 21.99 22.14 PCB-31 2.22e5 22.90 28/20 4.74e5 23.19 PCB-39 2.84e5 25.46 PCB-22 2.14e5 23.75 PCB-38 2.31e5 25.99 PCB-35 3.67e5 26.39 PCB-37 4.75e5 26.75 0% 22.0 23.0 24.0 25.0 0.00e0 RT Abs. Int. 2.33e5 PCB-36 8.72e5 25.14 26/29 3.42e5 22.42 1.14e5 26.0 27.0 Rel. Int. 100% 1.16e5 0.00e0 RT Abs. Int. 1.82e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: B 4σ 1.01e5 9.12e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.65e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: B 4σ 2.14e4 2.33e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0081, 4527 scc: 023-880 Revised: 03-Jan-2014 10:43 (LKB) Printed: 03-Jan-2014 15:21 Page 6 of 21 335 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. 100% Abs. Int. 1.05e4 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.87e3 5.23e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e4 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 3.46e3 6.85e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.13e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.79e4 2.07e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 1.31e4 1.01e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1788, 2188 scc: 023-880 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 7 of 21 336 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 4.08e3 50/53 8.82e4 22.66 PCB-51 3.01e4 23.35 PCB-45 6.53e4 23.26 PCB-52 5.23e4 24.80 PCB-46 5.27e4 23.53 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 59/62… 2.93e5 44/47… 26.01 69/49 2.20e5 1.62e5 25.73 25.22 PCB-48 PCB-42 7.08e4 PCB-43 6.47e4 25.51 3.75e4 26.16 25.02 71/40 1.63e5 26.60 PCB-41 5.55e4 26.50 Abs. Int. 5.11e4 PCB-64 1.31e5 26.81 2.55e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 44/47… 2.62e5 25.73 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 3.91e3 50/53 1.15e5 22.66 PCB-45 9.74e4 PCB-51 23.26 3.49e4 23.34 PCB-73 PCB-52 8.10e4 8.34e4 24.93 24.81 PCB-46 5.48e4 23.53 69/49 1.69e5 25.23 PCB-48 8.01e4 25.51 59/62… 3.86e5 26.01 PCB-42 9.68e4 26.17 27.0 Abs. Int. 6.43e4 71/40 2.00e5 26.60 PCB-41 8.18e4 26.50 PCB-64 1.45e5 26.81 0% 22.0 23.0 24.0 25.0 26.0 0.00e0 RT 27.0 Rel. Int. 100% 3.22e4 0.00e0 RT Abs. Int. 5.61e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 3.21e4 2.80e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.20e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.50e4 2.10e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9260, 1022 scc: 023-880 Revised: 03-Jan-2014 10:45 (LKB) Printed: 03-Jan-2014 15:21 Page 8 of 21 337 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 4.14e3 PCB-79 6.64e5 31.75 PCB-68 1.40e5 27.78 61/70... 6.48e5 PCB-67 29.04 1.47e5 28.51 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-78 6.28e5 32.25 PCB-81 2.16e5 32.63 PCB-60 2.09e5 PCB-80 30.10 1.57e5 30.42 Abs. Int. 1.64e5 PCB-77 3.03e5 33.11 8.19e4 0% 28.0 30.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 5.02e3 PCB-68 1.72e5 27.78 61/70... 8.54e5 29.04 PCB-58 1.60e5 28.36 32.0 PCB-79 8.37e5 31.75 PCB-60 2.92e5 30.10 PCB-56 2.45e5 29.91 34.0 36.0 38.0 PCB-78 7.88e5 32.25 PCB-81 2.81e5 32.62 PCB-80 2.05e5 30.42 Abs. Int. 2.07e5 PCB-77 3.76e5 33.10 1.03e5 0% 28.0 30.0 32.0 0.00e0 RT 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.26e5 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.26e4 6.29e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 2.39e4 2.68e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9272, 0996 scc: 023-880 Revised: 03-Jan-2014 10:45 (LKB) Printed: 03-Jan-2014 15:21 Page 9 of 21 338 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-96 2.95e5 26.00 Rel. Int. 100% Abs. Int. 7.59e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 2.73e3 3.80e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 4.53e5 26.00 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e5 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 2.97e3 5.85e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.19e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 2.88e3 3.10e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e4 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 2.00e3 5.50e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9067, 8571 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 10 of 21 339 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 3.58e3 PCB-94 2.95e4 27.88 PCB-103 3.75e4 27.70 PCB-98 3.00e5 28.67 PCB-89 2.73e5 29.65 PCB-88 PCB-102 2.92e43.71e4 28.58 28.96 PCB-115PCB-111 116/85 108/119... 1.26e5 8.89e4 7.52e4 3.82e5 32.61 33.12 32.40 31.78 113/90… PCB-110 PCB-117 PCB-120 PCB-112 1.59e5 PCB-82 PCB-92 9.55e4 8.60e4 1.01e5 6.31e4 6.21e4 4.31e4 30.80 32.52 32.31 33.52 31.44 32.80 30.31 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 107/124 5.07e5 34.49 PCB-106 4.17e5 34.92 PCB-123 1.05e5 34.81 Abs. Int. 1.18e5 PCB-114 1.30e5 35.56 PCB-105 1.53e5 36.10 5.89e4 PCB-127 1.03e5 37.33 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 4.75e3 PCB-98 4.78e5 28.67 PCB-94 4.70e4 27.88 100/93 PCB-91 1.17e5 7.93e4 28.48 29.03 PCB-89 4.33e5 29.65 PCB-121 8.53e4 29.99 113/90… 2.82e5 30.80 108/119... 5.90e5 31.78 116/85 2.08e5 32.41 PCB-111 PCB-120 1.40e5 1.62e5 33.12 33.52 36.0 107/124 8.47e5PCB-106 34.49 6.54e5 34.92 PCB-118 2.21e5 35.09 PCB-114 PCB-123 2.15e5 1.84e5 35.56 34.80 38.0 Abs. Int. 2.03e5 PCB-105 2.46e5 36.10 1.01e5 PCB-127 1.72e5 37.33 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.74e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: B 4σ 3.01e3 4.87e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.22e3 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 2.81e3 4.11e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8550, 9289 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 11 of 21 340 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 3.44e4 PCB-126 1.41e5 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 3.09e3 1.72e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.47e4 PCB-126 2.22e5 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 3.11e3 2.73e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e4 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: B 4σ 2.86e3 6.96e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.66e4 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 4.68e3 8.28e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7286, 3128 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 12 of 21 341 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-152 5.29e5 30.82 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 2.53e3 Abs. Int. 1.36e5 PCB-136 7.72e4 31.26 PCB-155 PCB-150 5.62e4 6.03e4 30.95 30.65 147/149 1.25e5 34.10 PCB-145 7.39e4 31.54 PCB-148 4.67e4 32.81 151/135PCB-144 1.23e5 6.19e4 33.33 33.81 139/140 1.26e5 34.63 163/138… 153/168 2.49e5 1.85e5 PCB-130 37.76 36.69 7.31e4 37.18 PCB-133 6.22e4 35.59 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 4.18e5 30.82 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 2.89e3 PCB-155 5.10e4 30.65 30.0 0.00e0 RT Abs. Int. 9.83e4 PCB-136PCB-145 6.77e4 5.42e4 31.26 31.53 PCB-148 3.62e4 32.80 151/135 9.81e4 33.33 147/149 139/140 PCB-154 8.16e4 1.08e5 PCB-132 34.11 34.63 7.32e4 4.19e4 35.18 33.54 PCB-165 6.42e4 35.92 153/168 1.45e5 PCB-130 36.69 5.76e4 37.18 163/138… 2.19e5 37.76 0% 28.0 6.78e4 32.0 34.0 36.0 38.0 Rel. Int. 100% 4.91e4 0.00e0 RT Abs. Int. 7.03e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.12e3 3.52e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e4 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 2.03e3 5.60e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9259, 3315 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 13 of 21 342 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 1.39e5 128/166 6.14e5 38.82 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.34e3 PCB-159 PCB-162 1.16e5 1.26e5 39.87 39.63 156/157 3.32e5 41.27 PCB-167 1.57e5 40.28 PCB-169 2.14e5 43.99 6.96e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.22e5 128/166 4.95e5 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 2.96e3 PCB-159 PCB-162 8.70e4 9.27e4 39.87 39.64 156/157 2.77e5 41.26 PCB-167 1.32e5 40.28 PCB-169 1.69e5 43.99 6.08e4 0% 39.0 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.95e3 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.33e3 4.97e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.04e3 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 3.23e3 4.52e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8276, 7547 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 14 of 21 343 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-184 2.68e5 36.29 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.58e3 PCB-176 4.45e4 36.58 PCB-188 PCB-179 4.57e4 4.46e4 35.54 35.82 Abs. Int. 6.82e4 3.41e4 PCB-186 4.22e4 36.98 PCB-178 2.67e4 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.47e5 36.29 Rel. Int. 100% HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 1.40e3 PCB-188 3.07e4 35.54 PCB-179 4.09e4 35.82 PCB-176 3.65e4 36.58 Abs. Int. 6.26e4 3.13e4 PCB-186 3.84e4 36.98 PCB-178 3.29e4 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 0.00e0 RT 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.97e3 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.36e3 4.99e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.60e3 2.36e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4826, 4197 scc: 023-880 Revised: 03-Jan-2014 10:41 (LKB) Printed: 03-Jan-2014 15:21 Page 15 of 21 344 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 2.77e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Abs. Int. 8.38e4 PCB-182 3.66e5 39.07 PCB-187 6.01e4 38.89 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 180/193 1.45e5 42.40 PCB-181 6.17e4 40.33 PCB-172 PCB-192 7.81e4 6.05e4 42.12 41.88 171/173 9.70e4 40.52 PCB-191 1.03e5 42.73 PCB-170 7.09e4 43.50 PCB-190 1.20e5 43.96 4.19e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 2.37e3 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 9.23e4 PCB-182 3.30e5 39.07 PCB-187 4.62e4 38.89 PCB-181 5.19e4 40.34 171/173 1.09e5 40.52 180/193 1.66e5 42.40 PCB-172 6.22e4 41.87 PCB-191 8.30e4 42.74 PCB-170 7.42e4 43.50 PCB-190 1.10e5 43.96 4.62e4 0% 39.0 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.33e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 2.04e3 3.17e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.17e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.47e3 2.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4824, 0790 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 16 of 21 345 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-189 1.86e5 46.12 Abs. Int. 4.41e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 2.14e3 2.20e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.80e5 46.12 0.00e0 RT Abs. Int. 3.90e4 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 1.55e3 1.95e4 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.95e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.80e3 3.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.98e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.26e3 2.99e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9412, 0969 scc: 023-880 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:21 Page 17 of 21 346 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 7.23e4 PCB-204 2.75e5 41.47 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.73e3 PCB-202 3.27e4 40.09 198/199 8.41e4 44.07 PCB-197PCB-200 5.44e4 4.31e4 41.65 41.74 PCB-201 4.24e4 40.88 PCB-196 3.54e4 44.64 PCB-203 5.07e4 44.81 0% 39.0 40.0 41.0 Rel. Int. 100% 42.0 43.0 44.0 45.0 PCB-202 3.20e4 40.10 PCB-201 4.63e4 40.88 198/199 9.16e4 44.07 PCB-197 5.35e4PCB-200 41.65 3.24e4 41.74 PCB-196 5.46e4 44.65 4.03e4 PCB-203 5.63e4 44.82 0% 39.0 40.0 41.0 0.00e0 RT Abs. Int. 8.06e4 PCB-204 2.97e5 41.46 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.53e3 3.61e4 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.40e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.09e3 2.20e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.81e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.39e3 2.41e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3025, 8975 scc: 023-880 Revised: 03-Jan-2014 11:04 (LKB) Printed: 03-Jan-2014 15:21 Page 18 of 21 347 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.24e3 PCB-205 1.41e5 48.29 PCB-194 1.24e5 47.89 PCB-195 7.30e4 45.94 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 3.02e4 1.51e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.81e3 47.0 48.0 50.0 PCB-205 1.59e5 48.29 PCB-194 1.34e5 47.88 PCB-195 8.40e4 45.94 49.0 0.00e0 RT Abs. Int. 3.19e4 1.60e4 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.72e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 9.24e2 1.86e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.30e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 1.09e3 2.15e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4721, 5462 scc: 023-880 Revised: 03-Jan-2014 10:41 (LKB) Printed: 03-Jan-2014 15:22 Page 19 of 21 348 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.18e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-206 1.29e5 49.76 PCB-207 9.69e4 46.52 Abs. Int. 2.57e4 PCB-208 8.35e4 45.73 1.28e4 0% 46.0 48.0 49.0 50.0 PCB-206 1.73e5 49.76 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 2.42e3 47.0 PCB-208 9.91e4 45.73 Abs. Int. 4.00e4 PCB-207 1.16e5 46.52 2.00e4 0% 46.0 0.00e0 RT 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.41e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 9.48e2 1.20e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.76e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 8.46e2 1.38e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3085, 2852 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:22 Page 20 of 21 349 of 417 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-209 2.67e5 51.24 Rel. Int. 100% Abs. Int. 4.95e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 7.44e2 2.47e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.36e5 51.24 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.55e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.79e2 2.27e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.81e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 8.32e2 1.91e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.08e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 7.81e2 2.54e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.37e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.69e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6138, 0081 scc: 023-880 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 21 of 21 350 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.15e7 2.57e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.57e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.83e7 9.14e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.86e7 9.28e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.12e7 5.60e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.71e6 2.85e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.51e6 2.76e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 979-518 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:22 Page 1 of 21 351 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 3.05e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: B 4σ 4.17e3 1.52e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.64e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: B 4σ 4.11e3 8.18e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.16e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.27e3 5.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.96e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 4.32e4 1.48e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5489, 8194 scc: 979-518 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 2 of 21 352 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.27e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 7.90e3 6.34e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.88e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.37e4 2.44e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.49e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 9.74e3 1.74e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.63e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 4.20e3 3.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7629, 0428 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 3 of 21 353 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 5.56e4 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: B 4σ 8.46e3 2.78e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PB 4σ 3.25e4 5.50e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: B 4σ 2.86e4 6.38e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.63e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 8.50e3 8.13e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8027, 5868 scc: 979-518 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 4 of 21 354 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.85e4 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PB 4σ 4.38e3 9.27e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e4 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PB 4σ 5.38e3 8.02e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.40e6 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: B 4σ 8.60e4 4.70e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e6 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 3.91e4 5.47e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0214, 1156 scc: 979-518 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 5 of 21 355 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-36 7.19e5 25.13 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.14e3 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.86e5 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 9.28e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-36 7.38e5 25.13 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e5 TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.70e3 9.30e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.09e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PB 4σ 9.16e4 2.54e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.78e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PB 4σ 2.79e4 2.89e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5941, 5542 scc: 979-518 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 6 of 21 356 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 6.01e3 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.17e3 3.00e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.11e3 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 2.42e3 3.56e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.72e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.83e4 1.86e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 9.43e3 9.97e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0820, 5379 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 7 of 21 357 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.58e4 TeCB-3 21.52-27.30 289.9224 Fn3 Flags: B 4σ 3.16e3 7.90e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.18e4 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PB 4σ 2.98e3 1.09e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.82e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 2.93e4 2.41e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.23e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.52e4 1.62e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8350, 9425 scc: 979-518 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 8 of 21 358 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 5.47e5 27.52 PCB-79 5.36e5 31.74 TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.89e3 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.43e5 PCB-78 5.18e5 32.24 7.14e4 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 4.42e3 30.0 32.0 PCB-79 7.00e5 31.74 PCB-72 6.98e5 27.51 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.76e5 PCB-78 6.62e5 32.24 8.82e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.97e4 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.92e4 3.99e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.63e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 1.73e4 2.31e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2818, 5309 scc: 979-518 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 9 of 21 359 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-96 2.82e5 25.99 Rel. Int. 100% Abs. Int. 7.28e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 2.12e3 3.64e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 4.29e5 25.99 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e5 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.71e3 5.88e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.59e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 1.81e3 4.29e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.60e3 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 2.46e3 3.80e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8819, 8478 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 10 of 21 360 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 2.64e5 28.66 PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 2.65e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 3.94e5 34.48 PCB-89 2.48e5 29.64 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 8.72e4 PCB-106 3.37e5 34.91 4.36e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 4.27e5 28.66 PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 2.41e3 32.0 34.0 107/124 6.21e5 34.48 PCB-89 4.17e5 29.64 36.0 38.0 0.00e0 RT Abs. Int. 1.58e5 PCB-106 5.67e5 34.91 7.89e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.87e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PB 4σ 2.55e3 3.93e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e4 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 3.22e3 6.44e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9704, 3378 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 11 of 21 361 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.12e4 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PB 4σ 1.59e3 5.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e4 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PB 4σ 2.77e3 1.01e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.73e3 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PB 4σ 2.80e3 4.36e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e4 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 3.82e3 6.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2883, 5187 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 12 of 21 362 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-152 4.83e5 30.81 Rel. Int. 100% Abs. Int. 1.18e5 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.87e3 5.91e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 3.94e5 30.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.51e4 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.90e3 4.75e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.12e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.86e3 4.06e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e3 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 1.70e3 4.24e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0506, 2521 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 13 of 21 363 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.20e5 128/166 4.76e5 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 2.12e3 6.00e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.02e5 128/166 3.90e5 38.81 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 2.33e3 5.11e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.60e3 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.45e3 4.80e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.66e4 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 3.23e3 8.31e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2148, 6219 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 14 of 21 364 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-184 2.50e5 36.28 Rel. Int. 100% Abs. Int. 6.09e4 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.13e3 3.04e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.25e5 36.28 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.52e4 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.66e2 2.76e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e4 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.64e3 7.92e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.24e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.38e3 2.12e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4369, 5758 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 15 of 21 365 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-182 3.17e5 39.06 Abs. Int. 7.81e4 HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.82e3 3.90e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 2.99e5 39.06 0.00e0 RT Abs. Int. 7.31e4 HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.86e3 3.66e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.19e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 1.88e3 4.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.22e3 4.24e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1213, 4954 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 16 of 21 366 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 9.62e3 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PB 4σ 1.27e3 4.81e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.53e3 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PB 4σ 1.44e3 3.76e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.39e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.56e3 2.69e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.29e3 2.36e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7659, 9371 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 17 of 21 367 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-204 2.39e5 41.45 Rel. Int. 100% Abs. Int. 6.07e4 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.15e3 3.04e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 2.84e5 41.45 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.24e4 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.08e3 3.62e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.33e3 2.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.83e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.25e3 2.92e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8871, 8933 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 18 of 21 368 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 5.29e3 OcCB-6 45.52-50.76 427.7635 Fn6 Flags: B 4σ 1.16e3 2.65e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.96e3 OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PB 4σ 1.12e3 2.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.04e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 7.05e2 1.52e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 8.79e2 1.29e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4309, 5142 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 19 of 21 369 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 4.42e3 NoCB 45.52-50.76 461.7245 Fn6 Flags: PB 4σ 1.08e3 2.21e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.67e3 NoCB 45.52-50.76 463.7216 Fn6 Flags: PB 4σ 1.77e3 2.84e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.46e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 8.65e2 1.73e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.81e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 7.98e2 1.40e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8411, 8296 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 20 of 21 370 of 417 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 4.94e3 DeCB 50.77-52.00 497.6826 Fn7 Flags: PB 4σ 4.11e2 2.47e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.97e3 DeCB 50.77-52.00 499.6797 Fn7 Flags: PB 4σ 6.24e2 2.48e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.05e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 5.08e2 1.02e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.19e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 9.76e2 1.09e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.51e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.76e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9640, 2741 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 21 of 21 Experiment Calibration Report 371 of 417 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 1 @ 200 (ppm) Printed: Friday, December 20, 2013 14:51:56 Eastern Standard Time M 180.9888 R 11467 M 192.9888 R 9920 242.8 M 204.9888 R 12316 180.9 1.00e0 x16 1.200 M 218.9856 R 11902 192.9 1.00e0 x16 204.9 1.00e0 x16 x16 0.425 0.065 0.100 1.00e0 0.400 0.060 1.100 0.375 0.090 0.055 1.000 0.080 0.350 0.325 0.050 0.900 0.070 0.300 0.045 0.800 0.275 0.040 0.060 0.700 0.250 0.035 0.600 0.225 0.050 0.200 0.030 0.500 0.175 0.040 0.025 0.150 0.400 0.030 0.300 0.020 0.125 0.015 0.100 0.020 0.075 0.200 0.010 0.050 0.010 0.100 -0.000 0.005 -0.000 180.87 180.88 180.89 180.90 192.86 M 230.9856 R 11523 192.87 192.88 192.89 230.8 x16 1.00e0 x16 0.600 0.170 0.550 0.160 0.150 0.500 0.140 0.450 0.130 0.120 0.400 0.110 0.350 0.100 0.090 0.300 0.080 0.250 0.070 0.060 0.200 0.050 0.150 0.040 0.030 0.100 0.020 0.050 0.010 -0.000 -0.000 230.82 230.83 230.84 230.85 242.80 242.81 242.82 242.83 242.84 -0.000 204.85 M 242.9856 R 11311 218.8 1.00e0 0.025 -0.000 204.86 204.87 204.88 218.83 218.84 218.85 218.86 Experiment Calibration Report 372 of 417 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 2 @ 200 (ppm) Printed: Friday, December 20, 2013 14:52:25 Eastern Standard Time M 218.9856 R 11415 M 230.9856 R 11111 304.8 M 242.9856 R 10549 218.9 1.00e0 x16 0.400 M 254.9856 R 10639 230.9 1.00e0 x16 242.9 1.00e0 x16 0.600 1.00e0 x16 0.110 0.200 0.375 0.550 0.100 0.350 0.180 0.500 0.325 0.090 0.300 0.450 0.160 0.400 0.140 0.080 0.275 0.250 0.070 0.350 0.225 0.120 0.060 0.200 0.300 0.100 0.050 0.175 0.250 0.080 0.150 0.040 0.200 0.125 0.060 0.100 0.030 0.150 0.075 0.040 0.020 0.100 0.050 0.050 0.025 -0.000 -0.000 218.86 218.87 218.88 218.89 230.85 M 268.9824 R 10161 230.86 230.87 230.88 0.010 -0.000 -0.000 230.89 M 280.9824 R 10871 254.8 0.020 242.84 242.85 x16 242.87 242.88 M 292.9824 R 10203 268.8 1.00e0 242.86 254.83 254.84 254.85 x16 0.280 254.87 M 304.9824 R 10820 280.8 1.00e0 254.86 292.8 1.00e0 x16 1.00e0 x16 0.120 0.150 0.070 0.260 0.140 0.110 0.065 0.100 0.060 0.240 0.130 0.220 0.120 0.055 0.090 0.110 0.200 0.100 0.180 0.090 0.160 0.070 0.140 0.060 0.050 0.080 0.045 0.040 0.080 0.035 0.070 0.120 0.030 0.050 0.060 0.100 0.025 0.040 0.050 0.080 0.020 0.040 0.030 0.060 0.015 0.030 0.020 0.040 0.020 0.010 0.010 0.020 0.010 -0.000 -0.000 268.81 268.82 268.83 268.84 268.85 0.005 -0.000 280.80 280.81 280.82 280.83 280.84 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 304.78 304.79 304.80 304.81 304.82 304.83 Experiment Calibration Report 373 of 417 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 3 @ 200 (ppm) Printed: Friday, December 20, 2013 14:52:57 Eastern Standard Time M 242.9856 R 11208 M 254.9856 R 10868 342.8 M 268.9824 R 10822 242.9 1.00e0 x16 M 280.9824 R 10819 254.9 1.00e0 x16 268.8 1.00e0 x16 1.00e0 x16 0.110 0.200 0.100 0.180 0.090 0.160 0.080 0.160 0.320 0.150 0.300 0.140 0.280 0.130 0.260 0.120 0.240 0.110 0.220 0.100 0.200 0.090 0.180 0.080 0.160 0.070 0.140 0.060 0.120 0.050 0.100 0.040 0.080 0.030 0.060 0.020 0.040 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.010 0.010 -0.000 -0.000 242.85 242.86 242.87 242.88 242.89 254.84 M 292.9824 R 11364 254.85 254.86 254.87 M 304.9824 R 10328 280.8 0.020 -0.000 268.82 254.88 268.83 268.84 x16 0.160 268.86 -0.000 280.81 268.87 M 316.9824 R 10549 292.8 1.00e0 268.85 280.82 280.83 280.84 x16 280.86 M 330.9792 R 9803 304.8 1.00e0 280.85 316.8 1.00e0 x16 1.00e0 x16 0.110 0.100 0.045 0.150 0.100 0.090 0.040 0.140 0.090 0.130 0.080 0.035 0.120 0.080 0.070 0.110 0.030 0.070 0.100 0.060 0.090 0.060 0.025 0.080 0.050 0.070 0.050 0.020 0.040 0.060 0.040 0.015 0.050 0.030 0.030 0.040 0.010 0.020 0.030 0.020 0.020 0.005 0.010 0.010 0.010 -0.000 -0.000 292.80 292.81 292.82 292.83 292.84 292.85 304.79 M 342.9792 R 10375 330.8 1.00e0 x16 0.075 0.070 0.065 0.060 0.055 0.050 0.045 0.040 0.035 0.030 0.025 0.020 0.015 0.010 0.005 -0.000 342.76 342.77 342.78 342.79 342.80 342.81 -0.000 342.82 304.80 304.81 304.82 304.83 304.84 316.78 316.79 316.80 316.81 316.82 316.83 -0.000 330.76 330.77 330.78 330.79 330.80 330.81 330.82 Experiment Calibration Report 374 of 417 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 4 @ 200 (ppm) Printed: Friday, December 20, 2013 14:53:27 Eastern Standard Time M 280.9824 R 11901 M 292.9824 R 10771 416.8 M 304.9824 R 11159 280.8 1.00e0 x16 0.320 0.160 0.300 0.150 0.280 0.140 M 316.9824 R 10777 292.8 1.00e0 x16 304.8 1.00e0 x16 0.130 0.240 0.120 0.220 0.110 0.200 0.100 0.180 0.090 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 x16 0.045 0.110 0.040 0.100 0.260 1.00e0 0.120 0.090 0.035 0.080 0.030 0.070 0.025 0.060 0.020 0.050 0.040 0.015 0.030 0.010 0.020 0.005 0.010 0.020 0.010 -0.000 -0.000 280.83 280.84 280.85 280.86 -0.000 280.87 292.82 M 330.9792 R 11627 292.83 292.84 292.85 292.86 304.81 M 342.9792 R 10375 316.8 -0.000 304.82 304.83 x16 0.160 304.85 304.86 M 354.9792 R 10965 330.8 1.00e0 304.84 316.79 316.80 316.81 316.82 x16 x16 1.00e0 x16 0.034 0.032 0.060 0.150 316.85 354.8 1.00e0 0.065 0.120 316.84 M 366.9792 R 10868 342.8 1.00e0 316.83 0.110 0.030 0.140 0.055 0.028 0.100 0.130 0.050 0.120 0.026 0.090 0.024 0.045 0.110 0.080 0.022 0.040 0.100 0.020 0.070 0.090 0.080 0.035 0.018 0.030 0.016 0.060 0.070 0.014 0.050 0.025 0.060 0.012 0.040 0.050 0.040 0.020 0.030 0.030 0.010 0.008 0.015 0.006 0.020 0.010 0.010 0.005 -0.000 -0.000 0.020 0.004 0.010 -0.000 330.78 330.79 330.80 330.81 330.82 330.83 342.77 M 380.9760 R 10685 342.78 342.79 342.80 342.81 342.82 342.83 M 392.9760 R 10869 366.8 0.002 -0.000 354.76 354.77 354.78 x16 354.80 354.81 354.82 M 404.9760 R 10290 380.8 1.00e0 354.79 366.74 366.75 366.76 366.77 x16 366.79 366.80 366.81 M 416.9760 R 11464 392.8 1.00e0 366.78 404.8 1.00e0 x16 1.00e0 x16 0.028 0.065 0.015 0.045 0.026 0.014 0.060 0.024 0.040 0.013 0.055 0.022 0.012 0.035 0.050 0.045 0.030 0.040 0.020 0.011 0.018 0.010 0.016 0.009 0.025 0.035 0.008 0.014 0.030 0.007 0.012 0.020 0.006 0.025 0.010 0.005 0.015 0.020 0.008 0.015 0.006 0.004 0.010 0.003 0.010 0.004 0.002 0.005 0.005 0.002 -0.000 -0.000 380.73 380.74 380.75 380.76 380.77 380.78 380.79 0.001 -0.000 392.72 392.73 392.74 392.75 392.76 392.77 392.78 392.79 404.72 404.73 404.74 404.75 404.76 404.77 404.78 404.79 -0.000 416.71 416.72 416.73 416.74 416.75 416.76 416.77 416.78 416.79 Experiment Calibration Report 375 of 417 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 5 @ 200 (ppm) Printed: Friday, December 20, 2013 14:54:02 Eastern Standard Time M 316.9824 R 10870 M 330.9792 R 10775 442.7 M 342.9792 R 10285 316.8 1.00e0 x16 M 354.9792 R 10121 330.8 1.00e0 x16 342.8 1.00e0 x16 0.150 x16 0.065 0.130 0.045 1.00e0 0.140 0.060 0.120 0.130 0.040 0.055 0.110 0.120 0.035 0.100 0.050 0.100 0.090 0.045 0.090 0.080 0.040 0.080 0.070 0.035 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.110 0.030 0.025 0.070 0.020 0.060 0.050 0.015 0.040 0.010 0.030 0.020 0.005 -0.000 -0.000 316.78 316.79 316.80 316.81 316.82 -0.000 316.83 330.76 M 366.9792 R 10872 0.005 0.010 0.010 330.77 330.78 330.79 330.80 330.81 342.75 M 380.9760 R 10122 354.8 -0.000 330.82 342.76 342.77 342.78 x16 342.81 354.74 354.75 354.76 x16 354.77 354.78 354.79 354.80 M 404.9760 R 9840 380.7 1.00e0 0.100 0.040 342.80 M 392.9760 R 10775 366.8 1.00e0 342.79 392.7 1.00e0 x16 1.00e0 x16 0.070 0.045 0.065 0.090 0.035 0.060 0.080 0.040 0.055 0.030 0.035 0.050 0.070 0.045 0.025 0.030 0.060 0.040 0.025 0.050 0.020 0.035 0.030 0.020 0.040 0.015 0.025 0.015 0.030 0.020 0.010 0.015 0.020 0.010 0.010 0.005 0.005 0.010 0.005 -0.000 -0.000 366.73 366.74 366.75 366.76 366.77 366.78 -0.000 366.79 380.71 M 416.9760 R 10964 380.72 380.73 380.74 380.75 380.76 380.77 392.70 M 430.9728 R 10332 404.7 -0.000 392.71 392.72 392.73 x16 392.75 392.76 404.68 M 442.9728 R 10204 416.7 1.00e0 392.74 430.7 1.00e0 x16 0.040 1.00e0 x16 0.030 0.026 0.028 0.024 0.035 0.026 0.022 0.024 0.030 0.020 0.022 0.020 0.018 0.025 0.018 0.016 0.016 0.014 0.020 0.014 0.012 0.012 0.015 0.010 0.010 0.008 0.008 0.010 0.006 0.006 0.004 0.004 0.005 0.002 0.002 -0.000 416.67 416.68 416.69 416.70 416.71 416.72 416.73 416.74 -0.000 430.65 -0.000 430.66 430.67 430.68 430.69 430.70 430.71 430.72 430.73 442.65 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 404.69 404.70 404.71 404.72 404.73 404.74 404.75 Experiment Calibration Report 376 of 417 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 6 @ 200 (ppm) Printed: Friday, December 20, 2013 14:55:29 Eastern Standard Time M 380.9760 R 10121 M 392.9760 R 10333 480.6 M 404.9760 R 10730 380.7 1.00e0 x16 M 416.9760 R 10825 392.7 1.00e0 x16 404.7 1.00e0 x16 1.00e0 x16 0.080 0.090 0.075 0.050 0.035 0.070 0.080 0.045 0.065 0.030 0.060 0.070 0.040 0.055 0.025 0.035 0.060 0.050 0.045 0.030 0.050 0.020 0.040 0.025 0.035 0.040 0.030 0.030 0.015 0.020 0.025 0.015 0.010 0.020 0.020 0.015 0.010 0.005 0.010 0.010 0.005 0.005 -0.000 -0.000 380.69 380.70 380.71 380.72 380.73 380.74 380.75 -0.000 380.76 M 430.9728 R 9958 392.68 392.69 392.70 392.71 392.72 392.73 392.74 M 442.9728 R 10204 416.7 -0.000 404.66 404.67 404.68 404.69 404.70 x16 404.72 404.73 416.65 M 454.9728 R 10286 430.7 1.00e0 404.71 416.66 416.67 416.68 x16 416.70 416.71 416.72 M 466.9728 R 10246 442.7 1.00e0 416.69 454.6 1.00e0 x16 1.00e0 x16 0.026 0.050 0.045 0.024 0.050 0.045 0.022 0.040 0.045 0.040 0.020 0.040 0.035 0.018 0.035 0.035 0.030 0.016 0.030 0.030 0.014 0.025 0.025 0.025 0.012 0.020 0.020 0.010 0.020 0.015 0.015 0.015 0.010 0.010 0.008 0.006 0.010 0.004 0.005 0.005 0.005 0.002 -0.000 -0.000 430.63 430.64 430.65 430.66 430.67 430.68 430.69 430.70 430.71 M 480.9696 R 10165 466.6 1.00e0 x16 0.028 0.026 0.024 0.022 0.020 0.018 0.016 0.014 0.012 0.010 0.008 0.006 0.004 0.002 -0.000 480.57 480.58 480.59 480.60 480.61 480.62 480.63 480.64 480.65 480.66 -0.000 442.62 442.63 442.64 442.65 442.66 442.67 442.68 442.69 442.70 -0.000 454.61 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 466.59 466.60 466.61 466.62 466.63 466.64 466.65 466.66 466.67 466.68 Experiment Calibration Report 377 of 417 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 7 @ 200 (ppm) Printed: Friday, December 20, 2013 14:56:11 Eastern Standard Time M 430.9728 R 10591 M 442.9728 R 11468 516.6 M 454.9728 R 10774 430.7 1.00e0 x16 M 466.9728 R 11625 442.7 1.00e0 x16 454.7 1.00e0 x16 0.055 1.00e0 x16 0.032 0.050 0.045 0.030 0.050 0.045 0.028 0.040 0.045 0.026 0.040 0.024 0.035 0.040 0.022 0.035 0.035 0.030 0.020 0.030 0.018 0.030 0.025 0.016 0.025 0.025 0.014 0.020 0.020 0.012 0.020 0.015 0.010 0.015 0.015 0.008 0.010 0.010 0.010 0.006 0.004 0.005 0.005 0.005 0.002 -0.000 -0.000 430.66 430.67 430.68 430.69 430.70 430.71 430.72 430.73 -0.000 442.64 M 480.9696 R 9999 442.65 442.66 442.67 442.68 442.69 442.70 442.71 454.63 M 492.9696 R 11060 466.7 -0.000 442.72 454.64 454.65 454.66 x16 454.68 454.69 454.70 454.71 466.62 M 504.9696 R 10504 480.6 1.00e0 454.67 466.63 466.64 466.65 x16 466.67 466.68 466.69 504.6 1.00e0 x16 0.040 1.00e0 x16 0.020 0.034 0.032 0.032 0.018 0.030 0.035 0.030 0.028 0.028 0.026 0.016 0.030 0.026 0.024 0.014 0.024 0.022 0.022 0.025 0.012 0.020 0.020 0.018 0.018 0.016 0.020 0.010 0.016 0.014 0.008 0.014 0.015 0.012 0.012 0.010 0.010 0.008 0.008 0.006 0.006 0.004 0.004 0.006 0.010 0.004 0.002 0.002 -0.000 -0.000 480.60 480.61 480.62 480.63 480.64 480.65 480.66 480.67 480.68 0.005 0.002 -0.000 492.59 492.60 492.61 492.62 492.63 492.64 492.65 492.66 492.67 -0.000 504.57 504.58 504.59 504.60 504.61 504.62 466.70 M 516.9697 R 11012 492.6 1.00e0 0.034 466.66 504.63 504.64 504.65 504.66 516.56 516.57 516.58 516.59 516.60 516.61 516.62 516.63 516.64 Resolution Check Report Printed: 378 of 417 Page 1 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 180.9888 R 11709 M 192.9888 R 10531 180.9 M 204.9888 R 11823 192.9 1.00e0 x16 M 218.9856 R 12380 204.9 1.00e0 x16 218.9 1.00e0 x16 1.00e0 x16 0.130 0.075 1.300 0.450 0.120 0.070 1.200 0.110 0.065 0.100 0.060 0.400 1.100 0.350 1.000 0.055 0.090 0.900 0.050 0.300 0.080 0.800 0.045 0.070 0.700 0.250 0.040 0.060 0.035 0.050 0.030 0.600 0.200 0.500 0.025 0.040 0.400 0.150 0.020 0.030 0.300 0.100 0.015 0.200 0.020 0.100 0.010 0.010 0.050 -0.000 0.005 -0.000 180.87 180.88 180.89 -0.000 180.90 192.86 M 230.9856 R 11709 192.87 192.88 204.85 M 242.9856 R 11344 230.8 -0.000 192.89 204.86 204.87 x16 218.83 M 218.9856 R 11709 242.8 1.00e0 204.88 218.84 218.85 x16 218.87 M 230.9856 R 11709 218.9 1.00e0 218.86 230.9 1.00e0 x16 1.00e0 x16 0.650 0.200 0.450 0.650 0.600 0.425 0.180 0.550 0.400 0.600 0.375 0.550 0.160 0.500 0.350 0.500 0.450 0.325 0.140 0.450 0.300 0.400 0.275 0.120 0.400 0.250 0.350 0.350 0.100 0.225 0.300 0.300 0.200 0.080 0.250 0.175 0.250 0.150 0.200 0.060 0.200 0.125 0.150 0.150 0.100 0.040 0.075 0.100 0.020 0.050 -0.000 -0.000 0.100 0.050 0.050 0.025 -0.000 230.82 230.83 230.84 230.85 230.86 242.81 M 242.9856 R 11737 242.82 242.83 242.84 242.85 218.86 M 254.9856 R 11378 242.9 -0.000 218.87 218.88 x16 230.85 M 268.9824 R 11848 254.8 1.00e0 218.89 x16 0.110 0.100 230.89 280.8 x16 1.00e0 x16 0.320 0.160 0.200 230.88 M 280.9824 R 11210 1.00e0 0.170 0.220 230.87 268.8 1.00e0 0.120 0.240 230.86 0.300 0.150 0.280 0.140 0.260 0.130 0.180 0.090 0.160 0.080 0.140 0.070 0.240 0.120 0.220 0.110 0.200 0.100 0.180 0.090 0.120 0.060 0.100 0.050 0.080 0.040 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.060 0.030 0.040 0.020 0.040 0.080 0.030 0.060 0.040 0.020 0.010 0.020 -0.000 -0.000 242.84 242.85 242.86 242.87 242.88 254.83 254.84 254.85 254.86 254.87 0.010 0.020 -0.000 -0.000 268.81 268.82 268.83 268.84 268.85 268.86 280.80 280.81 280.82 280.83 280.84 280.85 Resolution Check Report Printed: 379 of 417 Page 2 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 292.9824 R 11577 M 304.9824 R 11389 292.8 M 242.9856 R 11827 304.8 1.00e0 x16 M 254.9856 R 11793 242.9 1.00e0 x16 254.9 1.00e0 x16 1.00e0 x16 0.090 0.240 0.120 0.085 0.140 0.220 0.080 0.130 0.110 0.075 0.200 0.120 0.100 0.070 0.110 0.180 0.065 0.100 0.060 0.090 0.055 0.090 0.160 0.080 0.140 0.050 0.070 0.080 0.045 0.120 0.070 0.060 0.040 0.060 0.035 0.050 0.030 0.040 0.025 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.030 0.015 0.020 0.010 0.020 0.010 0.010 0.005 -0.000 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 -0.000 304.78 M 268.9824 R 11467 304.79 304.80 304.81 304.82 304.83 M 280.9824 R 11683 268.8 -0.000 242.85 242.86 242.87 x16 242.89 254.84 M 292.9824 R 11337 280.8 1.00e0 242.88 254.85 254.86 x16 254.88 M 304.9824 R 11548 292.8 1.00e0 254.87 304.8 1.00e0 x16 1.00e0 x16 0.360 0.170 0.180 0.110 0.340 0.160 0.320 0.160 0.100 0.150 0.300 0.140 0.280 0.140 0.090 0.130 0.260 0.080 0.120 0.240 0.120 0.110 0.220 0.070 0.100 0.200 0.100 0.080 0.060 0.040 0.020 0.180 0.090 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.010 0.060 0.050 0.040 0.030 0.020 0.010 -0.000 -0.000 268.83 268.84 268.85 268.86 -0.000 268.87 280.82 M 316.9824 R 11605 280.83 280.84 280.85 292.81 M 330.9792 R 11186 316.8 -0.000 280.86 292.82 292.83 x16 292.85 x16 0.110 304.83 304.84 304.85 280.9 x16 1.00e0 x16 0.375 0.085 0.120 304.82 M 280.9824 R 11876 1.00e0 0.090 0.130 0.045 304.81 342.8 1.00e0 0.050 304.80 M 342.9792 R 11340 330.8 1.00e0 0.055 292.84 0.350 0.080 0.325 0.075 0.300 0.070 0.100 0.040 0.065 0.275 0.060 0.250 0.090 0.035 0.080 0.055 0.225 0.050 0.030 0.070 0.200 0.045 0.025 0.175 0.060 0.040 0.050 0.020 0.035 0.150 0.030 0.125 0.040 0.025 0.015 0.030 0.075 0.010 0.015 0.020 0.050 0.010 0.005 -0.000 316.78 0.100 0.020 0.010 -0.000 316.79 316.80 316.81 316.82 316.83 316.84 330.77 330.78 330.79 330.80 330.81 330.82 330.83 0.005 0.025 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 280.83 280.84 280.85 280.86 280.87 280.88 Resolution Check Report Printed: 380 of 417 Page 3 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 292.9824 R 12107 M 304.9824 R 11576 292.8 M 316.9824 R 11932 304.8 1.00e0 x16 M 330.9792 R 11547 316.8 1.00e0 x16 330.8 1.00e0 x16 1.00e0 x16 0.200 0.180 0.055 0.130 0.170 0.180 0.120 0.050 0.160 0.150 0.110 0.160 0.045 0.140 0.100 0.140 0.130 0.040 0.090 0.120 0.035 0.120 0.110 0.080 0.100 0.070 0.030 0.060 0.025 0.100 0.090 0.080 0.080 0.070 0.050 0.020 0.060 0.060 0.040 0.050 0.015 0.030 0.040 0.040 0.010 0.030 0.020 0.020 0.020 0.005 0.010 -0.000 0.010 -0.000 292.82 292.83 292.84 292.85 292.86 -0.000 292.87 304.81 M 342.9792 R 11458 304.82 304.83 304.84 304.85 316.80 M 354.9792 R 11569 342.8 -0.000 304.86 316.81 316.82 316.83 x16 316.85 330.78 M 366.9792 R 12588 354.8 1.00e0 316.84 330.79 330.80 330.81 x16 330.83 330.84 M 380.9760 R 11628 366.8 1.00e0 330.82 380.8 1.00e0 x16 1.00e0 x16 0.080 0.075 0.130 0.075 0.070 0.040 0.120 0.070 0.065 0.110 0.065 0.035 0.060 0.060 0.100 0.055 0.055 0.030 0.090 0.050 0.050 0.080 0.045 0.025 0.045 0.040 0.070 0.040 0.035 0.060 0.020 0.035 0.030 0.030 0.050 0.015 0.025 0.025 0.040 0.020 0.020 0.010 0.030 0.015 0.020 0.015 0.010 0.010 0.005 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 342.83 0.005 -0.000 354.76 M 392.9760 R 11554 0.010 0.005 354.77 354.78 354.79 354.80 354.81 354.82 366.75 M 404.9760 R 11821 392.8 -0.000 366.76 366.77 x16 366.79 366.80 366.81 380.74 M 416.9760 R 11574 404.8 1.00e0 0.065 366.78 380.75 380.76 x16 380.78 380.79 380.80 M 316.9824 R 11467 416.8 1.00e0 0.040 380.77 316.8 1.00e0 x16 1.00e0 x16 0.060 0.020 0.060 0.055 0.018 0.035 0.055 0.050 0.016 0.050 0.030 0.045 0.045 0.014 0.040 0.025 0.040 0.012 0.035 0.010 0.030 0.035 0.020 0.030 0.025 0.008 0.025 0.015 0.020 0.020 0.006 0.010 0.015 0.015 0.004 0.010 0.010 0.005 0.002 0.005 0.005 -0.000 -0.000 392.73 392.74 392.75 392.76 392.77 392.78 392.79 392.80 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 -0.000 416.72 -0.000 416.73 416.74 416.75 416.76 416.77 416.78 416.79 416.80 316.78 316.79 316.80 316.81 316.82 316.83 316.84 Resolution Check Report Printed: 381 of 417 Page 4 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 330.9792 R 12118 M 342.9792 R 11633 330.8 M 354.9792 R 11643 342.8 1.00e0 x16 M 366.9792 R 11396 354.8 1.00e0 x16 366.8 1.00e0 x16 1.00e0 x16 0.075 0.170 0.150 0.045 0.070 0.160 0.140 0.065 0.150 0.040 0.130 0.140 0.060 0.120 0.130 0.035 0.055 0.110 0.120 0.050 0.100 0.110 0.100 0.090 0.090 0.080 0.080 0.070 0.030 0.045 0.025 0.040 0.035 0.020 0.070 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.060 0.050 0.015 0.040 0.010 0.030 0.020 0.005 0.005 0.010 0.010 -0.000 -0.000 330.77 330.78 330.79 330.80 330.81 -0.000 330.82 342.76 M 380.9760 R 11086 342.77 342.78 342.79 342.80 342.81 M 392.9760 R 10917 380.7 -0.000 354.74 354.75 354.76 354.77 x16 354.79 354.80 366.73 M 404.9760 R 11685 392.7 1.00e0 354.78 x16 0.080 366.76 366.77 366.78 366.79 366.80 M 416.9760 R 11737 416.7 1.00e0 x16 1.00e0 x16 0.032 0.055 0.030 0.075 0.050 0.028 0.070 0.090 0.026 0.045 0.065 0.080 366.75 404.7 1.00e0 0.110 0.100 366.74 0.024 0.060 0.040 0.022 0.055 0.070 0.035 0.050 0.060 0.020 0.018 0.045 0.030 0.016 0.040 0.050 0.025 0.035 0.040 0.030 0.014 0.012 0.020 0.010 0.025 0.030 0.015 0.008 0.020 0.020 0.015 0.006 0.010 0.004 0.010 0.010 0.005 0.005 -0.000 380.72 380.73 380.74 380.75 380.76 380.77 0.002 -0.000 392.70 380.78 M 430.9728 R 11418 -0.000 392.71 392.72 392.73 392.74 392.75 392.76 392.77 404.69 M 442.9728 R 11628 430.7 -0.000 404.70 404.71 404.72 x16 404.74 404.75 404.76 416.68 M 380.9760 R 11522 442.7 1.00e0 404.73 416.69 416.70 416.71 x16 416.73 416.74 416.75 M 392.9760 R 11852 380.7 1.00e0 0.045 416.72 392.7 1.00e0 x16 1.00e0 x16 0.110 0.090 0.100 0.040 0.035 0.090 0.080 0.080 0.070 0.035 0.030 0.030 0.070 0.025 0.060 0.025 0.060 0.050 0.020 0.050 0.020 0.040 0.015 0.040 0.015 0.030 0.030 0.010 0.010 0.020 0.020 0.005 0.005 0.010 0.010 -0.000 430.66 -0.000 430.67 430.68 430.69 430.70 430.71 430.72 430.73 430.74 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 -0.000 380.70 380.71 380.72 380.73 380.74 380.75 380.76 380.77 392.69 392.70 392.71 392.72 392.73 392.74 392.75 392.76 Resolution Check Report Printed: 382 of 417 Page 5 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 404.9760 R 11798 M 416.9760 R 11962 404.7 M 430.9728 R 11403 416.7 1.00e0 x16 M 442.9728 R 12348 430.7 1.00e0 x16 0.065 442.7 1.00e0 x16 0.040 0.060 0.055 0.035 1.00e0 x16 0.055 0.060 0.055 0.050 0.050 0.045 0.045 0.040 0.050 0.030 0.045 0.040 0.035 0.040 0.035 0.025 0.030 0.035 0.030 0.030 0.020 0.025 0.025 0.025 0.020 0.015 0.020 0.020 0.015 0.015 0.015 0.010 0.010 0.010 0.010 0.005 0.005 0.005 0.005 -0.000 404.68 404.69 404.70 404.71 404.72 404.73 404.74 -0.000 416.66 404.75 M 454.9728 R 11665 -0.000 416.67 416.68 416.69 416.70 416.71 416.72 416.73 430.65 M 466.9728 R 11529 454.7 -0.000 416.74 430.66 430.67 430.68 x16 430.70 430.71 430.72 442.64 M 480.9696 R 11402 466.7 1.00e0 0.060 430.69 442.65 442.66 442.67 x16 442.69 442.70 442.71 M 430.9728 R 11904 480.6 1.00e0 442.68 430.7 1.00e0 x16 1.00e0 x16 0.036 0.032 0.070 0.034 0.030 0.055 0.032 0.065 0.030 0.060 0.028 0.050 0.026 0.028 0.045 0.024 0.040 0.055 0.026 0.050 0.022 0.024 0.020 0.022 0.045 0.018 0.020 0.040 0.016 0.018 0.035 0.030 0.025 0.035 0.016 0.014 0.030 0.014 0.012 0.025 0.012 0.020 0.010 0.010 0.015 0.020 0.008 0.008 0.006 0.010 0.015 0.006 0.010 0.004 0.004 0.005 -0.000 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 0.002 0.002 -0.000 -0.000 454.70 466.61 M 442.9728 R 12063 466.62 466.63 466.64 466.65 466.66 466.67 466.68 466.69 480.59 M 454.9728 R 11740 442.7 0.005 -0.000 480.60 480.61 480.62 480.63 x16 480.65 480.66 480.67 480.68 M 466.9728 R 11628 454.7 1.00e0 480.64 430.67 430.68 430.69 430.70 x16 430.72 430.73 430.74 430.75 M 480.9696 R 12053 466.7 1.00e0 430.71 480.7 1.00e0 x16 1.00e0 x16 0.060 0.055 0.055 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.050 0.050 0.045 0.045 0.040 0.040 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 -0.000 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 0.005 0.005 -0.000 -0.000 480.61 466.63 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 480.62 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 Resolution Check Report Printed: 383 of 417 Page 6 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 492.9696 R 11688 M 504.9696 R 11467 492.6 M 516.9697 R 12194 504.6 1.00e0 x16 516.6 1.00e0 x16 0.045 1.00e0 x16 0.024 0.040 0.022 0.040 0.020 0.035 0.035 0.018 0.030 0.030 0.016 0.014 0.025 0.025 0.012 0.020 0.020 0.010 0.015 0.015 0.010 0.010 0.005 0.005 0.008 0.006 0.004 0.002 -0.000 -0.000 492.60 492.61 492.62 492.63 492.64 492.65 492.66 492.67 492.68 492.69 -0.000 504.59 504.60 504.61 504.62 504.63 504.64 504.65 504.66 504.67 504.68 516.58 516.59 516.60 516.61 516.62 516.63 516.64 516.65 516.66 516.67 Resolution Check Report Printed: 384 of 417 Page 1 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 180.9888 R 11682 M 192.9888 R 9510 180.9 M 204.9888 R 12347 192.9 1.00e0 x16 M 218.9856 R 11961 204.9 1.00e0 x16 218.9 1.00e0 x16 1.300 1.200 0.110 1.100 0.100 1.000 0.090 1.00e0 x16 0.500 0.075 0.070 0.450 0.065 0.400 0.060 0.055 0.900 0.350 0.080 0.050 0.800 0.070 0.300 0.045 0.700 0.040 0.060 0.250 0.600 0.035 0.050 0.200 0.030 0.500 0.040 0.025 0.030 0.020 0.400 0.150 0.300 0.100 0.015 0.020 0.200 0.010 0.050 0.010 0.100 -0.000 0.005 -0.000 180.87 180.88 180.89 -0.000 180.90 192.86 M 230.9856 R 11520 192.87 192.88 204.85 M 242.9856 R 11312 230.8 -0.000 192.89 204.86 204.87 x16 218.83 M 218.9856 R 11315 242.8 1.00e0 204.88 218.84 218.85 x16 230.9 1.00e0 x16 0.450 0.650 218.87 M 230.9856 R 11522 218.9 1.00e0 218.86 1.00e0 x16 0.650 0.425 0.180 0.600 0.400 0.600 0.375 0.160 0.550 0.550 0.350 0.500 0.500 0.325 0.140 0.450 0.300 0.450 0.275 0.120 0.400 0.400 0.250 0.350 0.350 0.100 0.225 0.300 0.080 0.200 0.300 0.175 0.250 0.250 0.150 0.060 0.200 0.200 0.125 0.150 0.150 0.100 0.040 0.075 0.100 0.100 0.020 0.050 -0.000 -0.000 0.050 0.050 0.025 -0.000 230.82 230.83 230.84 230.85 230.86 242.81 M 242.9856 R 11628 242.82 242.83 242.84 242.85 218.86 M 254.9856 R 11961 242.9 -0.000 218.87 218.88 x16 230.85 M 268.9824 R 11118 254.8 1.00e0 218.89 230.86 230.87 M 280.9824 R 11012 268.8 1.00e0 x16 230.88 280.8 1.00e0 x16 0.140 1.00e0 x16 0.320 0.180 0.240 0.300 0.130 0.220 0.280 0.160 0.120 0.260 0.200 0.110 0.140 0.180 0.100 0.160 0.090 0.240 0.220 0.120 0.200 0.080 0.140 0.180 0.100 0.070 0.160 0.120 0.140 0.080 0.060 0.100 0.120 0.050 0.060 0.080 0.100 0.040 0.080 0.060 0.040 0.030 0.060 0.040 0.020 0.040 0.020 0.020 0.010 -0.000 -0.000 242.84 242.85 242.86 242.87 242.88 0.020 -0.000 254.83 254.84 254.85 254.86 254.87 -0.000 268.81 268.82 268.83 268.84 268.85 268.86 280.80 280.81 280.82 280.83 280.84 280.85 Resolution Check Report Printed: 385 of 417 Page 2 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 292.9824 R 11427 M 304.9824 R 11317 292.8 M 242.9856 R 11601 304.8 1.00e0 x16 M 254.9856 R 11717 242.9 1.00e0 x16 254.9 1.00e0 x16 1.00e0 x16 0.120 0.085 0.140 0.220 0.080 0.110 0.130 0.075 0.200 0.100 0.120 0.070 0.180 0.110 0.065 0.100 0.060 0.090 0.160 0.080 0.055 0.090 0.140 0.070 0.050 0.080 0.045 0.070 0.120 0.060 0.040 0.100 0.060 0.035 0.050 0.030 0.050 0.080 0.040 0.025 0.040 0.060 0.030 0.040 0.020 0.020 0.030 0.015 0.020 0.010 0.020 0.010 0.010 0.005 -0.000 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 -0.000 304.78 M 268.9824 R 11601 304.79 304.80 304.81 304.82 242.85 M 280.9824 R 11468 268.8 -0.000 304.83 242.86 242.87 x16 242.89 254.84 M 292.9824 R 11375 280.8 1.00e0 242.88 x16 0.375 0.160 0.150 x16 0.110 0.100 0.140 0.300 1.00e0 0.120 0.180 0.325 254.88 304.8 x16 0.170 0.350 254.87 M 304.9824 R 11295 1.00e0 0.180 0.160 254.86 292.8 1.00e0 0.400 0.200 254.85 0.090 0.130 0.140 0.275 0.080 0.120 0.250 0.110 0.120 0.070 0.225 0.100 0.100 0.200 0.090 0.175 0.080 0.150 0.070 0.060 0.050 0.080 0.040 0.060 0.125 0.060 0.050 0.100 0.030 0.040 0.040 0.075 0.020 0.030 0.050 0.020 0.020 0.010 0.025 -0.000 0.010 -0.000 268.82 268.83 268.84 268.85 268.86 268.87 -0.000 280.81 M 316.9824 R 11720 280.82 280.83 280.84 280.85 280.86 M 330.9792 R 11212 316.8 -0.000 292.80 292.81 292.82 x16 292.84 292.85 304.79 M 342.9792 R 10706 330.8 1.00e0 292.83 304.80 304.81 304.82 x16 0.050 304.84 M 280.9824 R 11548 342.8 1.00e0 0.130 304.83 280.9 1.00e0 x16 1.00e0 0.090 0.360 0.085 0.340 x16 0.120 0.080 0.045 0.110 0.100 0.040 0.090 0.035 0.080 0.030 0.320 0.075 0.300 0.070 0.280 0.065 0.260 0.060 0.240 0.055 0.220 0.050 0.200 0.045 0.180 0.040 0.160 0.035 0.140 0.030 0.120 0.025 0.100 0.020 0.080 0.015 0.060 0.070 0.025 0.060 0.050 0.020 0.040 0.015 0.030 0.010 0.020 0.010 0.005 0.040 0.010 0.005 -0.000 -0.000 316.78 316.79 316.80 316.81 316.82 316.83 0.020 -0.000 330.77 330.78 330.79 330.80 330.81 330.82 -0.000 342.76 342.77 342.78 342.79 342.80 342.81 342.82 280.83 280.84 280.85 280.86 280.87 280.88 Resolution Check Report Printed: 386 of 417 Page 3 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 292.9824 R 11417 M 304.9824 R 11746 292.8 M 316.9824 R 11860 304.8 1.00e0 x16 M 330.9792 R 11399 316.8 1.00e0 x16 330.8 1.00e0 x16 1.00e0 x16 0.140 0.055 0.180 0.130 0.180 0.120 0.050 0.110 0.045 0.160 0.160 0.140 0.100 0.140 0.040 0.090 0.120 0.120 0.035 0.080 0.100 0.030 0.070 0.100 0.025 0.060 0.080 0.080 0.050 0.020 0.060 0.060 0.040 0.015 0.030 0.040 0.040 0.010 0.020 0.020 -0.000 -0.000 292.82 292.83 292.84 292.85 292.86 -0.000 292.87 304.81 M 342.9792 R 11424 0.020 0.005 0.010 304.82 304.83 304.84 304.85 316.80 M 354.9792 R 11788 342.8 -0.000 304.86 316.81 316.82 316.83 x16 316.85 330.78 M 366.9792 R 11879 354.8 1.00e0 316.84 330.79 330.80 x16 330.82 330.83 330.84 M 380.9760 R 11573 366.8 1.00e0 330.81 380.8 1.00e0 x16 1.00e0 x16 0.075 0.140 0.080 0.040 0.070 0.075 0.130 0.065 0.120 0.060 0.110 0.055 0.070 0.035 0.065 0.060 0.030 0.100 0.050 0.090 0.045 0.080 0.040 0.070 0.035 0.060 0.030 0.055 0.050 0.025 0.045 0.040 0.020 0.035 0.030 0.015 0.050 0.025 0.040 0.020 0.025 0.020 0.010 0.030 0.015 0.020 0.010 0.010 0.005 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 342.83 0.015 0.010 -0.000 -0.000 0.005 354.76 M 392.9760 R 11520 0.005 354.77 354.78 354.79 354.80 354.81 354.82 366.75 M 404.9760 R 10823 392.8 366.76 366.77 366.78 x16 0.060 366.80 366.81 380.74 M 416.9760 R 11908 404.8 1.00e0 366.79 380.75 380.76 x16 0.032 0.017 380.79 380.80 316.8 1.00e0 0.018 380.78 M 316.9824 R 11415 416.8 1.00e0 0.034 380.77 x16 1.00e0 x16 0.050 0.016 0.030 0.055 0.015 0.028 0.050 0.040 0.013 0.024 0.045 0.045 0.014 0.026 0.012 0.022 0.035 0.040 0.011 0.020 0.010 0.035 0.030 0.018 0.009 0.030 0.016 0.025 0.008 0.014 0.025 0.007 0.020 0.012 0.006 0.020 0.010 0.015 0.005 0.008 0.015 0.004 0.006 0.003 0.004 0.002 0.002 0.001 0.010 0.010 0.005 0.005 -0.000 -0.000 392.73 392.74 392.75 392.76 392.77 392.78 392.79 392.80 -0.000 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 416.72 416.73 416.74 416.75 416.76 416.77 416.78 416.79 416.80 -0.000 316.78 316.79 316.80 316.81 316.82 316.83 316.84 Resolution Check Report Printed: 387 of 417 Page 4 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 330.9792 R 10964 M 342.9792 R 11765 330.8 M 354.9792 R 11187 342.8 1.00e0 x16 M 366.9792 R 11482 354.8 1.00e0 x16 366.8 1.00e0 x16 1.00e0 x16 0.075 0.150 0.170 0.050 0.160 0.070 0.140 0.150 0.130 0.065 0.120 0.060 0.110 0.055 0.100 0.050 0.090 0.045 0.090 0.080 0.040 0.080 0.070 0.035 0.070 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.140 0.045 0.040 0.130 0.120 0.035 0.110 0.100 0.060 0.030 0.025 0.020 0.050 0.015 0.040 0.010 0.030 0.020 0.005 0.010 0.010 -0.000 0.005 -0.000 330.77 330.78 330.79 330.80 330.81 330.82 342.76 M 380.9760 R 11186 342.77 342.78 342.79 342.80 -0.000 354.74 342.81 M 392.9760 R 11378 380.7 -0.000 354.75 354.76 354.77 x16 354.79 354.80 354.81 M 404.9760 R 11235 392.7 1.00e0 354.78 366.73 366.74 366.75 366.76 x16 366.78 366.79 366.80 M 416.9760 R 11174 404.7 1.00e0 366.77 416.7 1.00e0 x16 1.00e0 x16 0.085 0.110 0.028 0.050 0.080 0.026 0.100 0.075 0.045 0.024 0.070 0.090 0.065 0.022 0.040 0.080 0.060 0.020 0.035 0.055 0.070 0.018 0.050 0.060 0.030 0.016 0.045 0.014 0.025 0.040 0.050 0.012 0.035 0.020 0.040 0.030 0.010 0.025 0.015 0.030 0.008 0.020 0.006 0.020 0.010 0.015 0.004 0.010 0.005 0.010 0.002 0.005 -0.000 -0.000 380.72 380.73 380.74 380.75 380.76 380.77 -0.000 380.78 392.71 M 430.9728 R 11476 392.72 392.73 392.74 392.75 392.76 392.77 404.69 M 442.9728 R 11163 430.7 -0.000 404.70 404.71 404.72 x16 404.74 404.75 404.76 416.68 M 380.9760 R 11287 442.7 1.00e0 404.73 416.69 416.70 416.71 x16 416.73 416.74 416.75 M 392.9760 R 11340 380.7 1.00e0 416.72 392.7 1.00e0 x16 1.00e0 x16 0.036 0.050 0.085 0.034 0.100 0.080 0.032 0.045 0.075 0.090 0.030 0.070 0.040 0.028 0.080 0.065 0.026 0.035 0.060 0.024 0.070 0.055 0.022 0.030 0.050 0.060 0.020 0.045 0.018 0.025 0.050 0.040 0.016 0.020 0.035 0.014 0.040 0.030 0.012 0.015 0.010 0.025 0.030 0.020 0.008 0.010 0.020 0.006 0.015 0.010 0.004 0.005 0.010 0.005 0.002 -0.000 -0.000 430.67 430.68 430.69 430.70 430.71 430.72 430.73 430.74 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 -0.000 380.70 380.71 380.72 380.73 380.74 380.75 380.76 380.77 392.69 392.70 392.71 392.72 392.73 392.74 392.75 392.76 Resolution Check Report Printed: 388 of 417 Page 5 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 404.9760 R 11765 M 416.9760 R 11990 404.7 M 430.9728 R 11174 416.7 1.00e0 x16 M 442.9728 R 11086 430.7 1.00e0 x16 0.060 442.7 1.00e0 x16 1.00e0 x16 0.055 0.060 0.040 0.055 0.050 0.035 0.045 0.055 0.050 0.050 0.045 0.045 0.040 0.030 0.040 0.040 0.035 0.025 0.035 0.035 0.030 0.030 0.030 0.020 0.025 0.025 0.025 0.020 0.015 0.020 0.020 0.015 0.015 0.015 0.010 0.010 0.010 0.010 0.005 0.005 0.005 0.005 -0.000 -0.000 404.68 404.69 404.70 404.71 404.72 404.73 404.74 -0.000 404.75 416.67 M 454.9728 R 11171 416.68 416.69 416.70 416.71 416.72 416.73 416.74 430.65 M 466.9728 R 12194 454.7 430.66 430.67 430.68 x16 430.70 430.71 -0.000 442.63 430.72 M 480.9696 R 11753 466.7 1.00e0 430.69 442.64 442.65 442.66 442.67 x16 442.69 442.70 442.71 M 430.9728 R 11116 480.6 1.00e0 0.028 442.68 430.7 1.00e0 x16 1.00e0 x16 0.036 0.060 0.050 0.034 0.026 0.055 0.032 0.024 0.045 0.030 0.050 0.022 0.028 0.020 0.026 0.040 0.045 0.024 0.035 0.040 0.018 0.022 0.016 0.030 0.035 0.020 0.014 0.018 0.030 0.025 0.016 0.012 0.025 0.014 0.020 0.010 0.012 0.015 0.008 0.010 0.006 0.008 0.020 0.015 0.010 0.006 0.010 0.004 0.004 0.005 0.005 0.002 -0.000 0.002 -0.000 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 454.70 -0.000 466.61 M 442.9728 R 11717 466.62 466.63 466.64 466.65 466.66 466.67 466.68 466.69 M 454.9728 R 11627 442.7 -0.000 480.59 480.60 480.61 480.62 480.63 x16 480.65 480.66 480.67 480.68 M 466.9728 R 12498 454.7 1.00e0 480.64 x16 0.050 0.045 430.69 430.70 430.71 430.72 430.73 430.74 430.75 M 480.9696 R 11221 480.7 1.00e0 x16 0.036 0.050 430.68 466.7 1.00e0 0.055 430.67 1.00e0 x16 0.040 0.034 0.032 0.035 0.030 0.045 0.028 0.040 0.030 0.026 0.040 0.035 0.024 0.035 0.025 0.022 0.030 0.020 0.030 0.018 0.025 0.020 0.016 0.025 0.014 0.020 0.020 0.015 0.012 0.015 0.010 0.015 0.010 0.008 0.010 0.010 0.006 0.005 0.005 -0.000 -0.000 0.005 0.004 0.002 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 -0.000 466.63 -0.000 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 480.62 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 Resolution Check Report Printed: 389 of 417 Page 6 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 492.9696 R 10752 M 504.9696 R 11338 492.7 M 516.9697 R 11848 504.6 1.00e0 x16 516.6 1.00e0 x16 1.00e0 x16 0.040 0.022 0.035 0.020 0.035 0.018 0.030 0.030 0.016 0.025 0.025 0.014 0.012 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 0.010 0.008 0.006 0.004 0.002 -0.000 -0.000 492.61 492.62 492.63 492.64 492.65 492.66 492.67 492.68 492.69 -0.000 504.59 504.60 504.61 504.62 504.63 504.64 504.65 504.66 504.67 504.68 516.58 516.59 516.60 516.61 516.62 516.63 516.64 516.65 516.66 516.67 390 of 417 Lab ID: OPR1_11903_PCB-RJ2 ACQ: 28-Mar-2014 17:55:43 LKB Wt/Vol: 1.00 L Client ID: 0_11903_OPR001 UTP: 30-Mar-2014 13:41 DES J-level: 10 pg/uL Datafile: 140328X08 RPT: 04-Apr-2014 09:49 ds Stds (pg): JS: 100 ES: 100 CS/SS: 100 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.77 32.29 35.76 35.21 34.75 34.47 38.36 40.91 39.93 43.62 45.75 50.80 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES 11.87 14.15 14.40 20.11 17.48 26.43 20.39 32.75 32.28 25.36 35.73 35.19 34.73 34.45 38.34 36.31 30.31 40.89 39.91 43.60 43.12 42.05 35.18 45.73 39.72 47.89 49.35 45.34 50.78 PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services QC C ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB Split: 1 Checkcode: 662-053-GHH Method 1668A Pred RRT Actual RRT Diff Secs Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0005 1.0007 1.0007 1.0006 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 0 0 +0.2 0 0 +0.2 0 0 0 0 0 0 6.34E+07 6.21E+07 5.04E+07 5.47E+07 5.19E+07 5.33E+07 4.94E+07 8.78E+07 4.79E+07 4.58E+07 4.27E+07 2.95E+07 0.80 0.80 0.62 0.62 0.62 0.62 0.64 1.21 1.21 1.24 1.07 1.18 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 50.8 52.4 48.8 49.6 48.8 49.4 52.6 98.9 48.7 47.9 51.1 48.5 1.19E+04 1.19E+04 4.97E+03 4.97E+03 4.97E+03 4.97E+03 5.75E+03 8.30E+03 8.30E+03 8.30E+03 4.48E+03 1.44E+03 0.101 0.104 0.0499 0.0474 0.0489 0.0477 0.064 0.131 0.0876 0.0913 0.0562 0.0272 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7246 0.8640 0.8794 1.2276 1.0674 1.0790 0.8325 1.3373 1.3179 0.8321 1.1725 1.1547 1.1394 1.1302 1.2581 0.9716 0.8110 1.0941 1.0678 1.1667 0.9079 0.8855 0.7409 0.9629 0.8364 1.0084 1.0392 0.9548 1.0693 +0.1 0 -0.1 +0.6 +0.1 +0.5 -0.4 +1.8 +1.7 -0.6 +1.1 +0.8 +0.6 +0.6 +1.4 0 -0.7 +0.5 +0.2 +0.8 -0.5 -0.3 -0.8 0 -0.5 0 0 -0.3 -0.3 1.52E+08 1.42E+08 8.42E+07 1.64E+08 8.05E+07 1.25E+08 8.04E+07 1.08E+08 1.06E+08 7.32E+07 9.28E+07 9.16E+07 8.93E+07 8.90E+07 8.49E+07 6.21E+07 8.62E+07 1.62E+08 8.45E+07 8.51E+07 5.05E+07 6.00E+07 6.27E+07 7.78E+07 6.04E+07 5.95E+07 4.28E+07 6.29E+07 5.46E+07 3.26 3.26 1.60 1.55 1.06 1.09 0.78 0.79 0.79 1.56 1.59 1.59 1.59 1.57 1.56 1.29 1.27 1.25 1.26 1.27 1.07 1.07 1.08 1.02 0.92 0.88 0.80 0.79 1.17 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 86.7 % 89.1 % 110 % 107 % 108 % 96 % 119 % 100 % 98.9 % 129 % 109 % 106 % 109 % 106 % 117 % 98.4 % 97 % 90.4 % 90.6 % 97.7 % 100 % 102 % 119 % 102 % 111 % 99.2 % 107 % 111 % 102 % 15% 15% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% Page 1 of 5 Printed: 4/4/2014 9:50 AM 391 of 417 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.87 32.77 37.75 0.9339 1.0750 1.0100 0.9338 1.0752 1.0100 -0.1 +0.4 0 1.43E+08 9.69E+07 4.21E+07 1.07 1.57 1.08 1.11 1.03 0.62 103 % 106 % 108 % 40% 40% 40% 125% 125% 125% CS PCB-28 CS PCB-111 CS PCB-178 22.87 32.77 37.75 0.9339 1.0750 1.0100 0.9338 1.0752 1.0100 -0.1 +0.4 0 1.43E+08 9.69E+07 4.21E+07 1.07 1.57 1.08 1.85 1.22 0.58 98.8 % 112 % 129 % 40% 40% 40% 125% 125% 125% JS JS JS JS JS 16.38 24.49 30.48 37.37 47.49 1.47E+08 7.83E+07 7.09E+07 5.59E+07 4.82E+07 1.57 0.80 1.58 1.28 0.91 5.89E+03 5.89E+03 5.89E+03 5.73E+03 5.73E+03 6.59E+03 6.59E+03 6.59E+03 6.59E+03 6.59E+03 6.59E+03 6.59E+03 6.59E+03 6.59E+03 5.93E+03 5.93E+03 5.93E+03 5.93E+03 5.93E+03 5.93E+03 0.0252 0.0271 0.0312 0.0405 0.026 0.0377 0.0332 0.0355 0.0353 0.0352 0.0297 0.0344 0.0345 0.0358 0.0539 0.0397 0.0465 0.034 0.0356 0.0625 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC V Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.88 13.98 14.16 14.42 14.60 16.39 16.56 16.79 17.09 17.21 18.76 19.54 19.84 20.12 17.50 19.26 19.66 19.85 19.98 20.08 B C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.0011 0.9881 1.0010 1.0011 1.0135 1.0010 1.0112 1.0249 1.0434 1.0507 0.9332 0.9720 0.9866 1.0008 1.0010 1.1015 1.1245 1.1355 1.1432 1.1486 0 +0.1 0 0 0 0 +0.1 0 +0.1 +0.1 -0.2 -0.1 0 0 0 +0.1 +0.2 +0.2 +0.2 +0.2 Page 2 of 5 NON-EMPC 163 589 1,180 2,030 2,280 2,130 1,220 619 151 8.13E+07 8.39E+07 8.13E+07 4.88E+07 7.96E+07 7.65E+07 8.69E+07 8.18E+07 8.23E+07 8.34E+07 9.88E+07 8.66E+07 1.72E+08 8.69E+07 4.47E+07 1.24E+08 5.30E+07 7.25E+07 6.91E+07 4.00E+07 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 163 589 1,180 2,030 2,280 2,130 1,220 619 151 3.17 3.23 3.24 1.58 1.58 1.64 1.63 1.65 1.64 1.64 1.62 1.63 1.63 1.64 1.04 1.05 1.04 1.05 1.04 1.05 0.95 1.17 1.01 1.23 1.92 0.97 1.10 1.03 1.03 1.04 1.23 1.06 1.06 1.02 1.15 1.56 1.33 1.82 1.74 0.99 DL 0.0282 0.0381 0.0601 0.0578 0.0457 0.0824 0.0976 0.0489 0.091 56.1 50.6 56.6 47 49.1 48.3 48.3 48.6 48.7 49.1 49 49.8 99.4 52 48.4 99 49.5 49.5 49.4 50.3 Printed: 4/4/2014 9:50 AM 392 of 417 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.56 21.71 21.86 22.14 22.34 22.62 22.90 23.08 23.46 24.84 25.16 25.69 26.08 26.45 20.41 22.39 22.98 23.05 23.26 24.51 24.64 24.74 24.93 25.22 25.43 25.71 25.87 26.21 26.30 26.50 27.22 27.47 27.85 28.05 28.20 28.43 28.72 29.01 29.15 29.59 29.78 30.10 31.43 31.92 25.38 25.70 27.39 27.58 SGS Evironmental Services QC C C C C B C C C C C Pred RRT Actual RRT Diff Secs Response Ra 1.1758 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1761 0.8214 0.8271 0.8379 0.8453 0.8559 0.8666 0.8735 0.8877 0.9400 0.9521 0.9722 0.9871 1.0007 1.0010 0.9143 0.9383 0.9412 0.9498 1.0009 1.0061 1.0100 1.0181 1.0296 1.0385 1.0497 1.0565 1.0701 1.0740 1.0821 0.8432 0.8512 0.8627 0.8690 0.8739 0.8808 0.8899 0.8987 0.9032 0.9167 0.9227 0.9327 0.9737 0.9889 1.0009 1.0134 0.8987 0.9050 +0.4 -0.5 -0.5 -0.5 -0.4 -0.4 -0.5 -0.4 -0.4 -0.1 -0.2 -0.2 0 0 0 -0.3 0 -0.1 -0.1 0 -0.1 -0.1 0 +0.2 +0.2 +0.2 +0.3 +0.5 +0.5 +0.3 -0.7 -0.5 -0.5 -0.5 -0.3 -0.5 -0.5 -0.3 -0.3 -0.4 -0.4 -0.4 0 0 0 0 -0.3 -0.2 7.69E+07 7.50E+07 7.48E+07 1.55E+08 7.69E+07 8.04E+07 1.51E+08 1.56E+08 7.24E+07 7.96E+07 8.20E+07 7.58E+07 7.26E+07 7.56E+07 5.11E+07 9.32E+07 4.13E+07 4.69E+07 3.80E+07 4.59E+07 6.03E+07 4.01E+07 1.13E+08 4.63E+07 1.48E+08 1.91E+08 4.30E+07 3.77E+07 9.63E+07 6.81E+07 6.46E+07 6.79E+07 6.38E+07 6.37E+07 6.84E+07 6.96E+07 2.53E+08 6.16E+07 5.95E+07 5.97E+07 6.12E+07 7.05E+07 7.03E+07 5.82E+07 4.89E+07 4.31E+07 4.09E+07 3.52E+07 1.04 1.02 1.01 1.01 1.01 1.01 1.02 1.01 1.00 1.01 1.01 1.03 1.01 1.00 0.79 0.79 0.79 0.79 0.79 0.79 0.78 0.79 0.79 0.80 0.79 0.78 0.78 0.77 0.80 0.79 0.80 0.79 0.80 0.80 0.80 0.79 0.80 0.80 0.79 0.80 0.79 0.80 0.79 0.78 0.63 0.64 0.61 0.61 Page 3 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.93 1.25 1.27 1.28 1.26 1.34 1.26 1.28 1.20 1.32 1.36 1.22 1.19 1.08 1.35 0.92 0.84 0.90 0.74 0.90 1.19 0.75 1.10 0.90 0.96 1.25 0.82 0.76 0.92 1.33 1.26 1.35 1.22 1.27 1.33 1.40 1.25 1.18 1.18 1.17 1.20 1.38 1.37 1.15 1.43 1.18 0.93 0.79 49.4 48.1 47.4 96.6 48.8 47.9 96.5 97.4 48.3 48.3 48.4 49.8 48.9 56.1 47 95.4 46.4 49.5 48.8 48.2 47.7 50.2 97.1 48.4 145 144 49.6 46.7 99.3 48.4 48.2 47.5 49.4 47.2 48.7 47 191 49.3 47.5 48.3 48.1 48.4 48.4 47.9 46.6 49.7 49.2 50.1 5.93E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 8.82E+03 2.16E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 3.11E+03 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.19E+04 1.69E+03 1.69E+03 4.97E+03 4.97E+03 0.032 0.0573 0.0566 0.0559 0.0567 0.0533 0.057 0.0558 0.0596 0.0543 0.0527 0.0587 0.0602 0.0664 0.0175 0.0329 0.0361 0.0339 0.0412 0.0338 0.0254 0.0402 0.0277 0.0335 0.0314 0.0242 0.037 0.0398 0.0331 0.0228 0.0916 0.0858 0.0949 0.0908 0.0873 0.0828 0.0928 0.0982 0.098 0.0993 0.0964 0.0841 0.0844 0.101 0.0163 0.0198 0.0619 0.0732 Printed: 4/4/2014 9:50 AM 393 of 417 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.96 28.17 28.28 28.35 28.65 28.72 28.91 29.33 29.67 29.99 30.47 30.91 31.01 31.11 31.45 31.99 32.08 32.20 32.28 32.48 32.79 33.19 34.15 34.36 34.58 35.04 36.99 30.33 30.49 30.64 30.94 31.21 32.48 33.00 33.21 33.47 33.78 33.95 34.03 34.30 34.47 34.61 34.85 35.25 35.59 35.81 35.93 36.35 SGS Evironmental Services QC C C C C B C C C C C Pred RRT Actual RRT Diff Secs Response Ra 0.9176 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9175 0.9244 0.9280 0.9303 0.9401 0.9422 0.9487 0.9624 0.9736 0.9840 0.9999 1.0142 1.0174 1.0208 1.0321 1.0496 1.0527 1.0565 1.0593 1.0657 1.0759 1.0890 0.9915 0.9976 1.0040 1.0091 1.0351 1.0007 1.0061 1.0108 1.0208 1.0297 1.0717 1.0888 1.0957 1.1044 1.1144 1.1202 1.1228 1.1315 1.1373 1.1421 1.1498 1.1631 0.9524 0.9581 0.9613 0.9727 -0.2 -0.3 -0.3 -0.3 -0.3 -0.3 0 0 0 -0.2 0 0 +0.2 +0.4 +0.2 +0.2 +0.4 +0.8 +0.6 +0.4 +0.4 +0.6 -0.2 0 +0.4 0 +0.2 0 +0.2 +0.2 +0.2 +0.2 +0.6 +0.4 +0.6 +0.6 +0.6 +0.6 +0.6 +0.6 +0.8 +1.0 +0.8 +1.1 -0.2 -0.2 0 -0.2 3.75E+07 7.31E+07 4.27E+07 3.59E+07 2.98E+07 4.49E+07 3.18E+07 3.33E+07 5.34E+07 3.64E+07 1.28E+08 2.97E+07 4.30E+07 5.04E+07 2.56E+08 4.93E+07 8.38E+07 4.97E+07 4.92E+07 3.08E+07 5.32E+07 5.37E+07 9.69E+07 5.66E+07 4.72E+07 4.64E+07 5.02E+07 5.23E+07 4.97E+07 5.10E+07 4.68E+07 4.78E+07 3.59E+07 6.94E+07 4.05E+07 3.56E+07 7.19E+07 2.72E+07 3.48E+07 7.21E+07 3.11E+07 3.00E+07 3.18E+07 3.33E+07 4.37E+07 3.80E+07 4.56E+07 8.85E+07 0.62 0.61 0.63 0.62 0.61 0.62 0.62 0.61 0.63 0.61 0.62 0.63 0.62 0.62 0.62 0.62 0.62 0.62 0.63 0.61 0.62 0.62 0.62 0.61 0.61 0.62 0.61 1.27 1.26 1.27 1.28 1.26 1.26 1.25 1.26 1.27 1.28 1.25 1.27 1.26 1.25 1.26 1.28 1.26 1.26 1.26 1.27 1.27 Page 4 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.86 0.86 1.00 0.74 0.78 0.92 0.71 0.76 1.20 0.81 0.96 0.70 0.90 1.17 0.98 1.18 0.88 1.10 1.16 0.69 1.21 1.22 1.11 1.24 1.11 1.03 1.12 1.26 1.14 1.15 1.06 1.09 1.15 1.09 1.29 1.14 1.11 0.93 1.02 1.13 0.98 0.95 0.99 1.05 1.35 1.15 1.47 1.42 48.9 95.6 47.9 54.7 43.1 54.8 50 49.3 50.1 50.4 149 47.9 53.8 48.5 294 47 108 50.9 47.7 50.2 49.6 49.3 98.3 51.3 47.9 49 48.4 48.1 50.7 51.3 51.3 50.7 50.3 102 50.7 50.4 104 47 54.8 103 51.3 50.9 51.7 51.1 52 53.1 49.8 101 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 4.97E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 0.067 0.0673 0.0577 0.0783 0.0743 0.0627 0.081 0.0762 0.0483 0.0712 0.0601 0.0829 0.0644 0.0495 0.0591 0.0491 0.066 0.0527 0.0499 0.0839 0.0479 0.0472 0.0522 0.0466 0.0521 0.0552 0.0497 0.0193 0.0214 0.0211 0.023 0.0223 0.0298 0.0313 0.0266 0.03 0.0307 0.0367 0.0335 0.0302 0.0351 0.036 0.0345 0.0326 0.0253 0.0297 0.0232 0.0241 Printed: 4/4/2014 9:50 AM 394 of 417 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.50 36.84 37.04 37.13 37.42 37.55 37.73 38.47 39.28 39.52 35.21 35.49 35.95 36.24 36.64 37.77 38.31 38.54 38.72 39.07 39.15 39.26 39.64 39.98 40.17 41.51 41.76 42.04 42.37 43.14 43.59 39.74 40.53 41.10 41.29 41.38 43.70 44.28 44.45 45.57 47.51 47.91 45.36 46.15 49.37 SGS Evironmental Services QC C C C C C Pred RRT Actual RRT Diff Secs Response Ra 0.9766 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9765 0.9859 0.9912 0.9934 1.0011 1.0049 1.0096 0.9640 0.9843 0.9903 1.0006 1.0087 1.0217 1.0301 1.0415 1.0735 1.0889 1.0954 1.1005 1.1103 1.1127 1.1158 1.1265 1.1364 1.1416 0.9079 0.9133 0.9193 0.9265 0.9434 0.9532 1.0005 1.0203 1.0348 1.0395 1.0419 1.1003 1.1148 1.1190 0.9515 0.9921 1.0004 1.0005 1.0178 1.0004 -0.2 0 +0.2 +0.2 0 +0.2 0 -0.2 -0.2 0 0 +0.2 +0.2 +0.2 +0.4 +0.5 +0.5 +0.5 +0.7 +0.5 +0.5 +0.5 +0.7 +0.7 +0.7 -0.2 -0.3 -0.3 -0.3 0 -0.3 0 0 0 -0.2 +0.2 +0.5 +0.5 +0.5 -0.3 0 0 0 0 0 3.36E+07 2.96E+07 3.77E+07 4.42E+07 1.10E+08 4.25E+07 4.93E+07 7.46E+07 4.49E+07 4.50E+07 3.69E+07 3.77E+07 3.36E+07 3.78E+07 3.46E+07 2.48E+07 3.51E+07 3.50E+07 3.53E+07 3.73E+07 3.06E+07 2.97E+07 2.86E+07 3.19E+07 5.66E+07 2.95E+07 3.83E+07 7.57E+07 4.12E+07 2.96E+07 4.40E+07 3.12E+07 3.56E+07 3.35E+07 3.53E+07 3.30E+07 4.81E+07 2.51E+07 2.58E+07 2.23E+07 2.52E+07 3.10E+07 3.51E+07 3.79E+07 2.38E+07 1.26 1.28 1.29 1.29 1.28 1.27 1.26 1.23 1.23 1.21 1.07 1.06 1.05 1.06 1.07 1.06 1.05 1.05 1.05 1.06 1.04 1.06 1.06 1.04 1.05 1.04 1.05 1.04 1.06 1.04 1.04 0.90 0.90 0.91 0.91 0.90 0.90 0.91 0.91 0.92 0.91 0.91 0.78 0.78 0.78 Page 5 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.04 0.92 1.11 1.43 1.15 1.39 1.53 0.90 1.10 1.10 1.27 1.13 1.06 1.15 1.07 0.77 1.07 1.15 1.18 1.20 1.10 0.94 0.92 1.07 0.94 0.98 1.29 1.24 1.38 1.13 1.60 1.05 1.14 1.07 1.10 1.08 0.74 0.80 0.83 0.72 0.81 1.06 1.12 1.18 1.11 52.1 51.8 54.4 49.9 155 49.2 51.8 97.7 48.3 48.3 46.4 53.3 50.7 52.6 51.5 51.2 54.5 50.6 49.9 52.1 46.1 53 51.6 49.6 101 50.3 49.6 101 49.7 51.6 54.6 48.9 51.5 51.6 53 50.3 107 52.3 51.1 51.8 52.6 49 49.6 51.2 49.9 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 2.05E+03 8.30E+03 8.30E+03 8.30E+03 1.54E+03 1.54E+03 1.54E+03 1.54E+03 1.54E+03 1.54E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 8.99E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 1.76E+03 4.21E+03 4.21E+03 4.21E+03 4.97E+03 4.97E+03 4.97E+03 0.0329 0.0372 0.0307 0.024 0.0298 0.0246 0.0223 0.113 0.0926 0.0923 0.0202 0.0227 0.0243 0.0224 0.0239 0.0331 0.15 0.14 0.137 0.135 0.146 0.172 0.174 0.15 0.171 0.164 0.125 0.129 0.116 0.165 0.117 0.0286 0.0264 0.0281 0.0274 0.0278 0.0406 0.0379 0.0362 0.101 0.0909 0.0691 0.0735 0.0703 0.108 Printed: 4/4/2014 9:50 AM 395 of 417 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140328X08 Analysis Date: Lab ID: OPR1_11903_PCB-RJ2 NATIVE ANALYTES PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-104 22'466'-PeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-155 22'44'66'-HxCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-188 22'34'566'-HpCB PCB-189 233'44'55'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-206 22'33'44'55'6-NoCB PCB-208 22'33'455'66'-NoCB PCB-209 DeCB Processed: 04 Apr 2014 09:49 28-MAR-2014 17:55:43 SPIKE CONC. RECOVERY RANGE (%) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 112 113 94.1 104 96.8 112 94 102 105 93.3 97.6 99.2 97.6 98.8 105 96.2 98.9 97.5 95.8 92.8 102 97.9 98.1 99.7 99.2 96.9 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 Contract-required recovery limits for OPR as specified in Table 6, Method 1668A. Analyst: ds FORM 8A OK - 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 396 of 417 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140328X08 Analysis Date: Lab ID: OPR1_11903_PCB-RJ2 LABELED STANDARDS ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 FORM 8B 28-MAR-2014 17:55:43 SPIKE CONC. RECOVERY RANGE (%) 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 86.7 89.1 110 107 108 96 119 100 98.9 129 109 106 109 106 117 98.4 97 90.4 90.6 97.7 100 102 119 102 111 99.2 107 111 102 15 15 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 - 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 100 100 100 98.8 112 129 40 40 40 - 125 125 125 Y Y N OK CLEANUP STANDARDS CS PCB-28 CS PCB-111 CS PCB-178 Processed: 04 Apr 2014 09:49 Analyst: ds 397 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.25e7 2.12e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 9.34e6 4.67e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 8.31e6 4.15e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.11 330.9792 Fn4 Flags: 0% Abs. Int. 1.49e7 7.44e6 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 Rel. Int. QC chk 100% 38.13-45.16 380.9760 Fn5 Flags: 0% Abs. Int. 8.67e6 4.34e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.18-50.15 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.55e6 7.75e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.52e6 7.60e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 scc: 662-053 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 04-Apr-2014 09:51 Page 1 of 21 398 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 PCB-1 6.18e7 11.88 Rel. Int. 100% Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 PCB-2 6.40e7 13.98 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.56e3 Abs. Int. 2.46e7 PCB-3 6.21e7 14.16 1.23e7 0% 11.0 12.0 13.0 PCB-1 1.95e7 11.88 Rel. Int. 100% 14.0 PCB-2 1.98e7 13.98 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 2.33e3 15.0 0.00e0 16.0 RT Abs. Int. 7.66e6 PCB-3 1.92e7 14.16 3.83e6 0% 11.0 12.0 13.0 ES-1 1.16e8 11.87 Rel. Int. 100% 14.0 15.0 Abs. Int. 4.70e7 ES-3 1.09e8 14.15 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 6.39e3 0.00e0 16.0 RT 2.35e7 0% 11.0 12.0 13.0 ES-1 3.57e7 11.87 Rel. Int. 100% 14.0 15.0 Abs. Int. 1.43e7 ES-3 3.34e7 14.15 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.76e4 0.00e0 16.0 RT 7.16e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.25e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.12e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8820, 4342 scc: 662-053 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:05 (DES) Printed: 04-Apr-2014 09:51 Page 2 of 21 399 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 Rel. Int. 100% Abs. Int. 1.60e7 PCB-10 4.87e7 14.60 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 3.49e3 PCB-4 2.99e7 14.42 8.00e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 1.00e7 PCB-10 3.08e7 14.60 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 9.47e3 PCB-4 1.89e7 14.42 5.02e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 5.18e7 14.40 Rel. Int. 100% 0.00e0 16.0 RT 0.00e0 16.0 RT Abs. Int. 1.77e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 9.72e3 8.83e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.24e7 14.40 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.11e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.68e3 5.53e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.25e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.12e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 6795, 2042 scc: 662-053 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:02 (DES) Printed: 04-Apr-2014 09:51 Page 3 of 21 400 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.02e3 PCB-9 4.75e7 16.39 PCB-7 5.39e7 PCB-6 16.56 5.09e7 16.79 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 PCB-14 6.11e7 18.76 PCB-5 5.12e7 17.09 PCB-8 5.18e7 17.21 PCB-11 5.37e7 19.54 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 13/12 1.07e8 19.84 Abs. Int. 1.76e7 PCB-15 5.39e7 20.12 8.82e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.15e4 PCB-9 2.90e7 16.39 PCB-7 3.31e7 PCB-6 16.56 3.09e7 16.79 18.0 19.0 20.0 PCB-14 3.77e7 18.76 PCB-5 3.11e7 17.09 PCB-8 3.15e7 17.21 PCB-11 3.29e7 19.54 13/12 6.54e7 19.84 21.0 Abs. Int. 1.09e7 PCB-15 3.30e7 20.12 5.43e6 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 8.98e7 16.38 20.0 21.0 ES-15 9.97e7 20.11 0.00e0 RT Abs. Int. 2.80e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 2.86e4 1.40e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 5.73e7 16.38 20.0 21.0 ES-15 6.41e7 20.10 0.00e0 RT Abs. Int. 1.74e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 7.89e3 8.72e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.34e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.67e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 4510, 6570 scc: 662-053 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:10 Printed: 04-Apr-2014 09:51 Page 4 of 21 401 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Rel. Int. 100% Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 30/18 6.37e7 19.26 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 3.04e3 PCB-19 2.28e7 17.50 PCB-17 2.71e7 19.66 PCB-27 3.72e7 19.85 PCB-24 3.53e7 19.98 PCB-16 2.05e7 20.08 Abs. Int. 1.71e7 PCB-32 3.92e7 20.56 8.55e6 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.07e7 19.26 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.88e3 PCB-19 2.19e7 17.50 PCB-17 2.59e7 19.66 21.0 PCB-24 3.38e7 19.98 PCB-27 3.53e7 19.85 Abs. Int. 1.65e7 PCB-16 1.95e7 20.08 PCB-32 3.76e7 20.56 8.26e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 4.14e7 17.48 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 1.24e7 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.27e4 6.20e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 3.92e7 17.48 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.07e4 5.81e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.34e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.67e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0252, 9893 scc: 662-053 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:10 Printed: 04-Apr-2014 09:51 Page 5 of 21 402 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 28/20 7.62e7 22.90 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 4.80e3 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 PCB-23 PCB-34 3.77e7 3.78e7 21.86 21.71 26/29 7.78e7 22.14 PCB-31 4.04e7 22.62 Abs. Int. 1.75e7 PCB-36 3.99e7 24.84 PCB-22 3.62e7 23.46 PCB-39 4.11e7 25.16 PCB-38 3.84e7 25.69 PCB-35 3.65e7 26.08 PCB-37 3.79e7 26.45 0% 22.0 24.0 25.0 0.00e0 RT 26.0 28/20 7.50e7 22.90 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 4.02e3 23.0 PCB-23 PCB-34 3.71e7 3.72e7 21.86 21.71 26/29 7.68e7 22.14 PCB-31 4.00e7 22.62 Abs. Int. 1.73e7 PCB-36 3.96e7 24.84 PCB-22 3.61e7 23.46 PCB-39 4.08e7 25.16 PCB-38 3.74e7 25.69 PCB-35 3.61e7 26.08 PCB-37 3.78e7 26.45 23.0 24.0 25.0 26.0 CS/SS-28 7.38e7 22.87 Rel. Int. 100% 8.67e6 0.00e0 RT 0% 22.0 8.77e6 ES-37 6.51e7 26.43 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.87e4 Abs. Int. 1.91e7 9.57e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 6.90e7 22.87 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 5.98e7 26.43 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.24e4 Abs. Int. 1.79e7 8.97e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.31e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.15e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8344, 9934 scc: 662-053 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:10 Printed: 04-Apr-2014 09:51 Page 6 of 21 403 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 PCB-54 2.26e7 20.41 Rel. Int. 100% Abs. Int. 6.01e6 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 8.36e2 3.00e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.85e7 20.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.48e6 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.32e3 3.74e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.53e7 20.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.98e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 3.92e3 4.99e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.52e7 20.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.25e7 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 2.76e3 6.24e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.34e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.67e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 1329, 5348 scc: 662-053 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:06 (DES) Printed: 04-Apr-2014 09:51 Page 7 of 21 404 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.51e3 50/53 4.10e7 22.39 PCB-51 2.08e7 23.05 PCB-45 1.82e7 22.98 PCB-73 2.65e7 PCB-52 24.64 2.02e7 24.51 PCB-46 1.68e7 23.26 69/49 4.97e7 24.93 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 44/47… 6.53e7 25.43 PCB-48 2.05e7 25.22 59/62… 8.41e7 25.71 71/40 4.27e7 26.30 PCB-42 1.89e7 25.87 PCB-41 1.64e7 26.21 Abs. Int. 1.51e7 PCB-64 3.00e7 26.50 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.59e3 50/53 5.21e7 22.39 24.0 PCB-51 2.61e7 23.05 PCB-45 2.31e7 22.98 25.0 PCB-73 3.38e7 PCB-52 24.64 2.57e7 24.51 PCB-46 2.12e7 23.26 69/49 6.29e7 24.93 PCB-48 2.58e7 25.22 59/62… 1.07e8 25.71 71/40 5.36e7 26.30 PCB-42 2.41e7 25.87 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.49e7 24.49 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 8.25e7 25.43 7.53e6 PCB-41 2.13e7 26.21 Abs. Int. 1.93e7 PCB-64 3.81e7 26.50 9.63e6 0.00e0 RT Abs. Int. 9.37e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 6.74e3 4.69e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.34e7 24.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 6.37e3 5.92e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.31e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.15e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 7270, 7208 scc: 662-053 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:10 Printed: 04-Apr-2014 09:51 Page 8 of 21 405 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.97-38.11 289.9224 Fn4 Flags: PBM 4σ 5.12e3 PCB-58 2.83e7 28.05 PCB-68 PCB-67 3.00e7 3.03e7 27.47 28.20 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 61/70... 1.12e8 28.72 PCB-55 2.63e7 29.15 PCB-60 PCB-80 2.71e7 3.14e7 29.78 30.10 PCB-79 3.11e7 31.43 PCB-78 2.56e7 31.92 PCB-81 2.76e7 32.29 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 Abs. Int. 1.39e7 PCB-77 2.81e7 32.77 6.93e6 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.11 291.9194 Fn4 Flags: PBM 4σ 6.74e3 PCB-57 3.55e7 27.84 PCB-68 3.78e7 27.47 30.0 61/70... 1.41e8 28.72 PCB-63 PCB-66 3.89e7 3.42e7 28.43 29.00 32.0 PCB-60 3.42e7 29.78 PCB-56 3.31e7 29.59 PCB-80 3.92e7 30.10 PCB-79 3.92e7 31.43 PCB-78 3.26e7 31.92 PCB-81 3.44e7 32.29 34.0 36.0 Abs. Int. 1.68e7 PCB-77 3.53e7 32.77 8.40e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 4.66e7 32.28 TeCB Std. 26.97-38.11 301.9626 Fn4 Flags: PBM 4σ 1.06e4 0.00e0 38.0 RT 34.0 36.0 0.00e0 38.0 RT Abs. Int. 1.13e7 ES-77 4.78e7 32.75 5.64e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 5.93e7 32.28 TeCB Std. 26.97-38.11 303.9597 Fn4 Flags: PBM 4σ 9.34e3 34.0 36.0 0.00e0 38.0 RT Abs. Int. 1.44e7 ES-77 6.06e7 32.75 7.22e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.49e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.44e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 7990, 2112 scc: 662-053 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:07 (DES) Printed: 04-Apr-2014 09:51 Page 9 of 21 406 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Rel. Int. 100% Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 PCB-104 1.88e7 25.38 Abs. Int. 4.72e6 PCB-96 1.68e7 25.70 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 9.05e2 2.36e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 3.01e7 25.38 0.00e0 RT Abs. Int. 7.47e6 PCB-96 2.63e7 25.70 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 7.82e2 3.74e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 4.46e7 25.36 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e7 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.77e3 5.49e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.87e7 25.36 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.21e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.41e3 3.60e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.31e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 4.15e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 6762, 0942 scc: 662-053 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:10 Printed: 04-Apr-2014 09:51 Page 10 of 21 407 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 108/119... 9.80e7 31.45 Rel. Int. 100% PeCB-4 26.97-38.11 323.8834 Fn4 Flags: PBM 4σ 2.02e3 PCB-103 1.55e7 27.39 100/93 2.77e7 28.17 PCB-88 1.13e7 28.65 PCB-121 2.06e7 29.67 113/90… 4.87e7 30.47 116/85 3.19e7 32.08 PCB-99 1.64e7 31.01 PCB-111 2.04e7 PCB-120 2.06e7 32.79 33.19 107/124 PCB-118 1.98e7 3.72e7 34.75 34.15 PCB-123 PCB-114 2.04e7 2.09e7 34.47 35.21 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 Abs. Int. 1.42e7 PCB-105 1.93e7 35.76 PCB-127 1.91e7 36.99 0% 28.0 30.0 32.0 108/119... 1.58e8 31.45 Rel. Int. 100% PeCB-4 26.97-38.11 325.8804 Fn4 Flags: PBM 4σ 2.94e3 34.0 PCB-94 2.19e7 27.58 100/93 4.53e7 28.17 PCB-91 2.78e7 28.72 PCB-89 2.06e7 29.33 113/90… 7.89e7 30.47 PCB-112 PCB-92 3.11e7 2.26e7 31.11 29.99 116/85 PCB-115 5.19e7 3.02e7 32.08 32.28 PCB-110 PCB-111 PCB-120 PCB-117 3.28e7 3.07e7 3.05e7 3.31e7 32.79 32.20 31.99 33.19 PCB-118 107/124 3.20e7 5.98e7 34.75 34.15 PCB-123 PCB-114 3.29e7 3.38e7 34.47 35.21 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.92e7 32.77 JS-101 4.34e7 30.48 PeCB Std. 26.97-38.11 337.9207 Fn4 Flags: PBM 4σ 3.50e3 34.0 ES-118 ES-114 5.62e7 ES-123 5.49e7 35.19 5.44e7 34.73 34.45 0.00e0 38.0 RT 36.0 Abs. Int. 2.28e7 PCB-105 3.11e7 35.76 0% 28.0 7.10e6 36.0 ES-105 5.70e7 35.73 PCB-127 3.11e7 36.99 1.14e7 0.00e0 38.0 RT Abs. Int. 1.45e7 7.23e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 3.77e7 32.77 JS-101 2.74e7 30.48 PeCB Std. 26.97-38.11 339.9177 Fn4 Flags: PBM 4σ 2.12e3 34.0 ES-118 ES-123 3.44e7 3.46e7 34.73 34.45 36.0 ES-105 3.58e7 35.73 0.00e0 38.0 RT Abs. Int. 9.39e6 4.70e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.49e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.44e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0175, 2021 scc: 662-053 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:05 (DES) Printed: 04-Apr-2014 09:51 Page 11 of 21 408 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PeCB-5 38.13-45.16 323.8834 Fn5 Flags: PBM 4σ 2.58e3 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 PCB-126 1.93e7 (1.93e7 + 3.01e7) * 2000 pg * 100 % 38.36 Recv(PCB-126) = (5.17e7 + 3.32e7) * 2000 pg * 1.11 DES 31-Mar-2014 07:39 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 Abs. Int. 4.47e6 = 52.4 % 2.24e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 7.01e6 PCB-126 3.01e7 38.36 PeCB-5 38.13-45.16 325.8804 Fn5 Flags: PBM 4σ 3.17e3 3.51e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.24e7 ES-126 5.17e7 38.34 PeCB Std. 38.13-45.16 337.9207 Fn5 Flags: PBM 4σ 7.34e3 6.18e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.21e6 ES-126 3.32e7 38.34 PeCB Std. 38.13-45.16 339.9177 Fn5 Flags: PBM 4σ 5.40e3 4.10e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.67e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.34e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8625, 6991 scc: 662-053 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:41 Printed: 04-Apr-2014 09:51 Page 12 of 21 409 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 PCB-150 PCB-155 2.86e7 2.93e7 30.64 30.33 HxCB-4 26.97-38.11 359.8415 Fn4 Flags: PBM 4σ 9.99e2 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 147/149 139/140 4.03e7 4.03e7 33.78 34.30 PCB-145 2.66e7 31.21 PCB-148 2.00e7 32.48 153/168 4.95e7 36.35 151/135 PCB-146 3.86e7 PCB-144 PCB-143 PCB-142 PCB-133 2.12e7 33.00 2.00e7 1.95e7 1.68e7 1.86e7 35.81 33.47 34.03 35.25 34.61 PCB-141 1.88e7 36.50 163/138… 6.18e7 37.42 PCB-164 PCB-160 2.49e7 2.37e7 37.13 37.55 0% 28.0 30.0 PCB-152 2.20e7 30.49 PCB-136 PCB-155 2.05e7 PCB-145 2.30e7 30.94 2.11e7 30.33 31.21 Rel. Int. 100% HxCB-4 26.97-38.11 361.8385 Fn4 Flags: PBM 4σ 1.05e3 32.0 PCB-148 1.59e7 32.48 34.0 PCB-165 1.93e7 35.59 153/168 3.90e7 36.35 163/138… 4.85e7 37.42 PCB-141 PCB-137 1.48e7 1.65e7 37.04 36.50 30.0 32.0 34.0 ES-155 4.81e7 30.31 Rel. Int. 100% HxCB Std. 26.97-38.11 371.8817 Fn4 Flags: PBM 4σ 1.38e3 4.32e6 0.00e0 38.0 RT 36.0 ES-153 3.50e7 36.31 Abs. Int. 8.64e6 PCB-158 2.18e7 37.73 0% 28.0 5.59e6 0.00e0 38.0 RT 36.0 147/149 139/140 151/135 3.16e7 3.19e7 3.08e7 33.78 34.29 33.00 PCB-154 PCB-143 1.80e7 PCB-131 1.53e7 1.38e7 33.21 34.03 34.47 Abs. Int. 1.12e7 JS-138 3.14e7 37.37 Abs. Int. 1.17e7 5.86e6 0% 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 ES-155 3.80e7 30.31 Rel. Int. 100% ES-153 2.71e7 36.31 HxCB Std. 26.97-38.11 373.8788 Fn4 Flags: PBM 4σ 1.80e3 Abs. Int. 9.73e6 JS-138 2.45e7 37.37 4.87e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.49e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 7.44e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 2287, 4503 scc: 662-053 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:10 Printed: 04-Apr-2014 09:51 Page 13 of 21 410 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.11e7 38.47 HxCB-5 38.13-45.16 359.8415 Fn5 Flags: PBM 4σ 4.71e3 PCB-159 2.47e7 39.28 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 PCB-162 2.47e7 39.52 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 156/157 4.81e7 40.91 Abs. Int. 9.38e6 PCB-169 2.54e7 43.62 PCB-167 2.62e7 39.93 4.69e6 0% 39.0 Rel. Int. 100% HxCB-5 38.13-45.16 361.8385 Fn5 Flags: PBM 4σ 3.59e3 128/166 3.35e7 38.47 PCB-162 PCB-159 2.03e7 39.52 2.02e7 39.28 40.0 41.0 42.0 43.0 156/157 3.97e7 40.91 44.0 45.0 Abs. Int. 7.56e6 PCB-169 2.05e7 43.62 PCB-167 2.16e7 39.93 3.78e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 4.71e7 39.91 HxCB Std. 38.13-45.16 371.8817 Fn5 Flags: PBM 4σ 6.03e3 0.00e0 RT 41.0 42.0 43.0 ES-156/157 8.98e7 40.89 44.0 45.0 0.00e0 RT Abs. Int. 1.60e7 ES-169 4.76e7 43.60 8.00e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 3.74e7 39.91 HxCB Std. 38.13-45.16 373.8788 Fn5 Flags: PBM 4σ 3.94e3 41.0 42.0 43.0 ES-156/157 7.20e7 40.89 44.0 45.0 0.00e0 RT Abs. Int. 1.27e7 ES-169 3.75e7 43.60 6.37e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.67e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.34e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 1280, 8591 scc: 662-053 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:09 (DES) Printed: 04-Apr-2014 09:51 Page 14 of 21 411 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Rel. Int. 100% PCB-188 1.91e7 35.21 HpCB-4 30.00-38.11 393.8025 Fn4 Flags: PBM 4σ 8.64e2 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 PCB-179 1.94e7 PCB-184 1.72e7 35.49 35.95 PCB-186 1.79e7 36.64 Abs. Int. 4.72e6 PCB-178 1.28e7 37.77 2.36e6 0% 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 PCB-188 1.79e7 35.21 HpCB-4 30.00-38.11 395.7995 Fn4 Flags: PBM 4σ 6.76e2 36.0 PCB-179 1.83e7 35.49 PCB-176 1.83e7 36.24 37.0 PCB-186 1.67e7 36.64 38.0 0.00e0 RT Abs. Int. 4.42e6 PCB-178 1.21e7 37.77 2.21e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.26e7 35.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.82e6 CS/SS-178 2.18e7 37.75 HpCB Std. 30.00-38.11 405.8428 Fn4 Flags: PBM 4σ 1.63e3 3.91e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.01e7 35.18 Rel. Int. 100% Abs. Int. 7.40e6 CS/SS-178 2.02e7 37.75 HpCB Std. 30.00-38.11 407.8398 Fn4 Flags: PBM 4σ 1.34e3 3.70e6 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.47e7 QC Check 30.00-38.11 330.9792 Fn4 Flags: - 7.34e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0246, 7272 scc: 662-053 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:10 Printed: 04-Apr-2014 09:51 Page 15 of 21 412 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.13-45.16 393.8025 Fn5 Flags: PBM 4σ 4.05e3 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 PCB-183 PCB-174 171/173 1.92e7 1.53e7 2.90e7 PCB-182 39.0739.26 PCB-185 1.81e7 PCB-181 40.17 PCB-177 1.56e7 38.72 1.63e7 1.47e7 39.15 39.98 39.64 180/193 3.86e7 42.04 PCB-172 1.50e7 41.51 PCB-191 2.12e7 42.37 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 Abs. Int. 6.52e6 PCB-190 2.24e7 43.59 PCB-170 1.51e7 43.14 3.26e6 0% 39.0 Rel. Int. 100% HpCB-5 38.13-45.16 395.7995 Fn5 Flags: PBM 4σ 4.94e3 PCB-182 1.72e7 38.72 PCB-183 PCB-187 1.81e7 1.71e7 39.07 38.54 40.0 41.0 42.0 180/193 3.72e7 42.04 171/173 2.76e7 PCB-181 40.17 PCB-177 1.56e7 1.39e7 39.98 39.63 PCB-172 1.45e7 41.51 43.0 PCB-191 2.00e7 42.37 44.0 45.0 Abs. Int. 6.28e6 PCB-190 2.16e7 43.59 PCB-170 1.45e7 43.14 3.14e6 0% 39.0 40.0 41.0 42.0 ES-180 3.10e7 42.05 Rel. Int. 100% 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 7.22e6 ES-170 2.61e7 43.12 HpCB-5 Std. 38.13-45.16 405.8428 Fn5 Flags: PBM 4σ 4.16e3 3.61e6 0% 39.0 40.0 41.0 42.0 ES-180 2.90e7 42.05 Rel. Int. 100% 43.0 44.0 45.0 0.00e0 RT Abs. Int. 6.78e6 ES-170 2.44e7 43.12 HpCB-5 Std. 38.13-45.16 407.8398 Fn5 Flags: PBM 4σ 4.45e3 3.39e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.67e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.34e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8904, 2699 scc: 662-053 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:10 Printed: 04-Apr-2014 09:51 Page 16 of 21 413 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 PCB-189 2.21e7 45.75 Abs. Int. 5.38e6 HpCB-6 45.18-50.15 393.8025 Fn6 Flags: PBM 4σ 2.37e3 2.69e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.06e7 45.75 Abs. Int. 4.87e6 HpCB-6 45.18-50.15 395.7995 Fn6 Flags: PBM 4σ 2.11e3 2.43e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 3.93e7 45.73 0.00e0 RT Abs. Int. 9.36e6 HpCB Std. 45.18-50.15 405.8428 Fn6 Flags: PBM 4σ 4.74e3 4.68e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 3.86e7 45.73 0.00e0 RT Abs. Int. 9.22e6 HpCB Std. 45.18-50.15 407.8398 Fn6 Flags: PBM 4σ 4.15e3 4.61e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.55e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 7.75e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0992, 7664 scc: 662-053 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:03 (DES) Printed: 04-Apr-2014 09:51 Page 17 of 21 414 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 PCB-201 1.69e7 40.53 PCB-202 1.48e7 39.74 OcCB-5 38.13-45.16 427.7635 Fn5 Flags: PBM 4σ 9.32e2 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 PCB-197 1.67e7 PCB-204 41.29 PCB-200 1.57e7 1.59e7 41.38 41.10 198/199 2.28e7 43.70 Abs. Int. 4.10e6 PCB-196 1.20e7 44.28 PCB-203 1.23e7 44.45 2.05e6 0% 39.0 Rel. Int. 100% 40.0 41.0 PCB-201 1.87e7 40.52 PCB-202 1.64e7 39.74 OcCB-5 38.13-45.16 429.7606 Fn5 Flags: PBM 4σ 8.32e2 42.0 43.0 PCB-197 1.85e7 PCB-204 41.29 PCB-200 1.73e7 1.75e7 41.38 41.10 44.0 45.0 198/199 2.53e7 43.70 0.00e0 RT Abs. Int. 4.59e6 PCB-196 1.32e7 44.28 PCB-203 1.35e7 44.45 2.29e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.89e7 39.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.99e6 OcCB Std. 38.13-45.16 439.8038 Fn5 Flags: PBM 4σ 1.68e3 3.49e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.16e7 39.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.67e6 OcCB Std. 38.13-45.16 441.8008 Fn5 Flags: PBM 4σ 1.85e3 3.83e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.67e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 4.34e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3009, 0906 scc: 662-053 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:03 (DES) Printed: 04-Apr-2014 09:51 Page 18 of 21 415 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.18-50.15 427.7635 Fn6 Flags: PBM 4σ 2.08e3 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 PCB-194 1.20e7 47.51 PCB-195 1.06e7 45.57 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 PCB-205 1.47e7 47.91 Abs. Int. 3.51e6 1.75e6 0% 46.0 Rel. Int. 100% OcCB-6 45.18-50.15 429.7606 Fn6 Flags: PBM 4σ 2.13e3 47.0 48.0 PCB-194 1.32e7 47.51 PCB-195 1.16e7 45.57 49.0 50.0 PCB-205 1.62e7 47.91 0.00e0 RT Abs. Int. 3.94e6 1.97e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.30e7 47.49 OcCB Std. 45.18-50.15 439.8038 Fn6 Flags: PBM 4σ 3.99e3 49.0 50.0 ES-205 2.78e7 47.89 0.00e0 RT Abs. Int. 6.72e6 3.36e6 0% 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.53e7 47.49 OcCB Std. 45.18-50.15 441.8008 Fn6 Flags: PBM 4σ 3.25e3 49.0 50.0 ES-205 3.17e7 47.89 0.00e0 RT Abs. Int. 7.65e6 3.82e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.55e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 7.75e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 6619, 2740 scc: 662-053 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:03 (DES) Printed: 04-Apr-2014 09:51 Page 19 of 21 416 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.18-50.15 461.7245 Fn6 Flags: PBM 4σ 1.71e3 PCB-208 1.54e7 45.36 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 PCB-207 1.66e7 46.15 Abs. Int. 3.95e6 PCB-206 1.04e7 49.37 1.98e6 0% 46.0 Rel. Int. 100% NoCB 45.18-50.15 463.7216 Fn6 Flags: PBM 4σ 3.26e3 PCB-208 1.97e7 45.36 47.0 48.0 49.0 50.0 PCB-207 2.13e7 46.15 Abs. Int. 5.07e6 PCB-206 1.34e7 49.37 2.53e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.78e7 45.34 50.0 0.00e0 RT Abs. Int. 6.65e6 ES-206 1.90e7 49.35 NoCB Std. 45.18-50.15 473.7648 Fn6 Flags: PBM 4σ 2.83e3 3.32e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.51e7 45.34 50.0 Abs. Int. 8.30e6 ES-206 2.38e7 49.35 NoCB Std. 45.18-50.15 475.7619 Fn6 Flags: PBM 4σ 2.23e3 0.00e0 RT 4.15e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.55e6 QC Check 45.18-50.15 454.9728 Fn6 Flags: - 7.75e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 5741, 6955 scc: 662-053 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:10 Printed: 04-Apr-2014 09:51 Page 20 of 21 417 of 417 SGS ID: OPR1_11903_PCB-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11903_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 76 Acq: 28-Mar-2014 17:55:43 User: LKB Datafile: 140328X08 PCB-209 1.59e7 50.80 Rel. Int. 100% Abs. Int. 3.43e6 DeCB 50.17-52.00 497.6826 Fn7 Flags: PBM 4σ 7.59e2 1.71e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.35e7 50.80 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.86e6 DeCB 50.17-52.00 499.6797 Fn7 Flags: PBM 4σ 6.83e2 1.43e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.95e7 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.43e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 1.17e3 3.21e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.51e7 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.61e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.62e2 2.80e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.52e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 7.60e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6517\A6517_11903 PCB\Resources\OPR1_11903_PCB-RJ2.utp_res, saved 31-Mar-2014 07:39 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3324, 9877 scc: 662-053 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:10 (DES) Printed: 04-Apr-2014 09:51 Page 21 of 21 1 of 562 4 APRIL 2014 DELANEY PETERSON ANCHOR QEA 7200 Olive Way, Ste 300 Seattle WA 98101 t. 206-287-9130 e. DPeterson@anchorqea.com SUBJECT: CERTIFICATE OF RESULTS Dear Delaney; Attached to this narrative are the analytical results for sample(s) submitted for the determination of polychlorinated biphenyl congeners. The insert below summarizes information about the project. If applicable, QC annotations below highlight specific analytical observations and assessments made during the sample handling and data interpretation phases. Results reported relate only to the items tested. PROJECT INFORMATION SUMMARY (When applicable, see QC Annotations for details) Client Project Patrick Bayou Superfund Ste SGS Project # A6521 Analytical Protocol(s) Method 1668A No. Samples Submitted 6 Additional QC Sample(s) 0 No. Laboratory Method Blanks 1 No. OPRs / Batch CS3 1 Date Received 19-Mar-2014 Condition Received good Temperature upon Receipt (C) 2.2 - 2.4 Extraction within Holding Time yes Analysis within Holding Time yes SGS Environmental Services 5500 Business Drive Wilmington, NC 28405 +1 910 350 1903 +1 866 846 8290 www.sgs.com Member of the SGS Group (SGS SA) 2 of 562 + , " ! * ! " ( ( ! ! ( ( ! $ " - ! ( " - . ( " ! ! + ! , - + ! $ . " + 0 ! " # $ " % " / , ) ' ! $ & " " ! ' ( ) & ! & ' $ ( ! ! ! - ( ! ! + " $ ! $ ) ! $ - ) # $ ! ! " ! + ! " & + " ' ! ' ( ' . $ ! ( ! ( % $ " " " & 1 / & ! 1 ! ! - 2 3 ( 4 . 2 - 1 / ! " ' . ! ! ! ! $ " $ $ " - ) ) ( " " ! - ! 0 $ " 1 ) ! $ . + " ) / Digitally signed by Amy Boehm Date: 2014.04.04 11:19:40 -04'00' ( ) 5 6 ! ( + ! " " ! * 7 . " 3 of 562 APPENDIX A: GENERAL DATA QUALIFIERS / DATA ATTRIBUTES B The analyte was found in the method blank, at a concentration that was at least 10% of the concentration in the sample. C Two or more congeners co-elute. In EDDs, C denotes the lowest IUPAC congener in a co-elution group and additional co-eluters for the group are shown with the number of the lowest IUPAC co-eluter. E The reported concentration exceeds the calibration range (upper point of the calibration curve) and is an estimated value. EMPC Represents an Estimated Maximum Possible Concentration. EMPCs arise in cases where the signal/noise ratio is not sufficient for peak identification (the determined ion-abundance ratio is outside the allowed theoretical range), or where there is a co-eluting interference. H/h If the standard recovery is below the method or SOP specified value “H” is assigned. If the obtained value is less than half the specified value “h” is assigned.1 J Indicates that an analyte has a concentration below the reporting limit (lowest point of the calibration curve) and is an estimated value. ND Indicates a non-detect. NR Indicates a value that is not reportable. PR Due to interference, the associated congener is poorly resolved. QI Indicates the presence of a quantitative interference. SI Denotes “Single Ion Mode” and is utilized for PCBs where the secondary ion trace has a significantly elevated noise level due to background PFK. Responses for such peaks are calculated using an EMPC approach based solely on the primary ion area(s) and may be considered estimates.1 U The analyte was not detected. The estimated detection limit (EDL) may be reported for this analyte. V The labeled standard recovery was found to be outside of the method control limits. Page 3 of 5 4 of 562 APPENDIX B: DRBC/TMDL SPECIFIC DATA QUALIFIERS / DATA ATTRIBUTES J The reported result is an estimate. The value is less than the minimum calibration level but greater than the estimated detection limit (EDL). U The analyte was not detected in the sample at the estimated detection limit (EDL). E The reported concentration is an estimate. The value exceeds the upper calibration range (upper point of the calibration curve). D Dilution Data. Result was obtained from the analysis of a dilution. B Analyte found in the sample and associated method blank. C Co-eluting congener Cxx Co-elutes with the indicated congener, data is reported under the lowest IUPAC congener. ‘Xx’ denotes the IUPAC number with the lowest numerical designated congener. NR Analyte is not reportable because of problems in sample preparation or analysis. V Labeled standard recovery is not within method control limits. X Results from re-injection/repeat/second-column analysis. EMPC Estimated maximum possible concentration. Indicates that a peak is identified but did not meet the method specified ion-abundance ratio. APPENDIX C: LAB IDENTIFIERS AR Indicates use of the archived portion of the sample extract. CU Indicates a sample that required additional clean-up prior to MS injection/processing. D Indicates a dilution of the sample extract. The number that follows the “D” indicates the dilution factor. DE Indicates a dilution performed with the addition of ES (extraction standard) solution. DUP Designation for a duplicate sample. MS Designation for a matrix spike. MSD Designation for a matrix spike duplicate. RJ Indicates a reinjection of the sample extract. S Indicates a sample split. The number that follows the “S” indicates the split factor. Page 4 of 5 5 of 562 SGS CERTIFICATIONS California 07255CA Connecticut PH-0258 Florida (primary NELAP) E87634 ISO17025 2726.01 Kansas E-10330 Louisiana 04115 Maryland (DW only) 299 New Jersey NC100 New York 11685 North Carolina DENR 481 North Carolina DHHS (DW only) 37776 North Dakota R-197 Oregon NC200002 Pennsylvania 68-03675 South Carolina 99029 Texas T104704260-13-5 Utah NC009192013-3 Virginia (DW only) 00235 Virginia 460214 Washington State C913 West Virginia 293 Page 5 of 5 6 of 562 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB083-1SWMID-140318-N ANCHOR QEA Patrick Bayou 18-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 35.4 1.82 99.3 6.19 182 5.04 1.23 11.4 3.4 ND 0.645 Aqueous 1.19 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 11903 Qualifier J J J J JC J 0.434 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.137 0.143 0 15 0.15 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 30.8 406 2,570 4,970 1,820 435 110 27.9 6.4 42.6 Total PCB (Mono-Deca) 10,400 Checkcode: 761-512-TRG SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6521 A6521_11903_PCB_001-RJ 0.137 0.143 0 15 0.15 1,820 436 122 31 7.87 10,400 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 19-Mar-2014 20-Mar-2014 28-Mar-2014 Recovery % 64.3 73.1 89.9 94.2 94.3 83.7 106 87.6 85.6 107 96.5 91 96 93.2 98.2 87.5 83 7 83.7 80.2 78.5 79.9 96.8 97.7 100 95.1 96.8 88.4 92.6 99.4 84.6 91 101 119 Report Created: 04-Apr-2014 10:12 Analyst: ds 7 of 562 Sample ID: PB083-1SWMID-140318-N Client Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: 18-Mar-2014 Date Collected: Laboratory Data pH Conc. Qualifiers PCB-1 23 PCB-2 2.1 J PCB-3 5.7 JB Project No.: A6521 Date Received: 1.19 L Sample ID: A6521_11903_PCB_001-RJ Date Extracted: 20-Mar-2014 11903 Date Analyzed: 28-Mar-2014 761-512-TRG Time Analyzed: pg/L Tri Conc. PCB-19 79.7 PCB-30/18 510 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. Qualifiers Tetra 19-Mar-2014 21:35:52 Conc. Qualifiers J PCB-54 2.83 J PCB-72 3.15 PCB-50/53 154 C PCB-68 25.6 PCB-17 180 PCB-45 129 PCB-57 2.47 J PCB-27 31.1 PCB-51 70.9 PCB-58 0.923 J PCB-46 57.3 PCB-67 10.6 PCB-52 829 PCB-63 16.3 Conc. 30.8 PCB-24 3.43 EMPC 30.8 PCB-16 172 Di Conc. Qualifiers Aqueous 7 Units Mono Method 1668A Sample Data J PCB-32 170 PCB-34 2.42 PCB-23 (0.923) J PCB-73 1.59 PCB-43 28.3 PCB-69/49 408 PCB-48 125 J 726 PCB-66 453 PCB-55 4.43 PCB-56 225 PCB-4 151 PCB-10 4.44 J PCB-26/29 90.3 PCB-9 7.02 J PCB-25 62.9 PCB-44/47/65 702 C PCB-60 96.8 PCB-7 3.57 J PCB-31 463 PCB-59/62/75 49.3 C PCB-80 (0.67) PCB-28/20 461 C PCB-42 178 PCB-79 8.5 J PCB-21/33 130 C PCB-41 52.3 PCB-78 (0.805) PCB-6 47 PCB-5 2.02 C PCB-8 101 PCB-22 131 PCB 14 PCB-14 (0 421) (0.421) PCB 36 PCB-36 (0 885) (0.885) PCB-11 22.7 B PCB-39 3.81 PCB-13/12 15.2 JC PCB-38 (0.957) PCB-15 51.5 PCB-35 7.39 PCB-37 73.5 PCB-71/40 312 PCB 64 PCB-64 264 C PCB-61/70/74/76 C PCB-81 1.82 PCB 77 PCB-77 35 4 35.4 C J J J J Conc. 406 Conc. 2,570 Conc. 4,970 EMPC 406 EMPC 2,570 EMPC 4,970 Totals Conc. EMPC Mono-Tri 3,010 3,010 Tel: +1 910 794-1613 Tetra-Hexa 7,220 7,230 www.us.sgs.com Hepta-Deca 187 203 Mono-Deca 10,400 10,400 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 8 of 562 Sample ID: Penta PCB-104 PB083-1SWMID-140318-N Conc. Qualifiers (0.282) Conc. Qualifiers PCB-108/119/86/97/125/87 207 C PCB-155 PCB-152 (0.263) PCB-146 13.8 C PCB-150 (0.259) PCB-161 (0.277) PCB-136 14 J PCB-145 (0.273) PCB-148 (0.356) PCB-96 7.27 J PCB-117 8.96 PCB-103 2.67 J PCB-116/85 68.5 PCB-94 3.32 J PCB-95 217 PCB-100/93 5.16 PCB-102 15.2 PCB-98 0.974 PCB-88 (0.759) PCB-91 PCB-84 JC PCB-110 292 PCB-115 7.61 PCB-82 52.4 PCB-111 (0.489) PCB-120 Hexa PCB-151/135 Conc. Qualifiers [0.329] J EMPC 28.2 C Hexa PCB-165 Conc. Qualifiers (0.302) PCB-153/168 69.2 PCB-141 16.9 C PCB-130 7.57 J PCB-137 5.51 J [0.681] J EMPC PCB-154 1.1 J PCB-164 7.06 J PCB-107/124 8.58 JC PCB-144 4.2 J PCB-163/138/129 105 C 52.7 PCB-109 15.7 71 C PCB-160 103 PCB-123 5.04 J PCB-134 6.39 J PCB-158 10.1 PCB-89 10.6 PCB-106 1.18 J PCB-143 0.717 J PCB-128/166 16.5 JC PCB-121 (0.493) PCB-118 182 PCB-139/140 2.37 JC PCB-159 [0.749] J EMPC PCB-92 45.1 PCB-122 4.58 J PCB-131 1.84 J PCB-162 (0.411) PCB-113/90/101 230 PCB-114 6.19 J PCB-142 (0.431) PCB-83 15.1 PCB-105 99.3 PCB-132 37.2 PCB-127 (0.507) PCB-133 1.43 PCB-126 [1.23] PCB-99 146 PCB-112 1.07 Hepta PCB-188 Conc. J Method 1668A Penta C J Qualifiers (0.258) PCB-179 7.12 PCB-184 (0.31) PCB-176 1.95 PCB-186 (0.305) PCB-178 J (0.294) PCB-167 3.4 J PCB-156/157 11.4 JC PCB-169 (0.434) J Conc. 1,820 Conc. 435 EMPC 1,820 EMPC 436 Hepta Conc. Nona Conc. PCB-174 J PCB-147/149 Qualifiers 15.9 PCB-177 [7.61] PCB-181 (0.578) J EMPC J PCB-171/173 4.68 JC 3.24 J PCB-172 [2.63] J EMPC PCB-192 (0.481) PCB-175 [0.667] J EMPC 31.5 PCB-187 18.3 PCB-191 [0.677] PCB-182 (0.526) PCB-170 14.7 PCB-180/193 Octa PCB-202 Conc. Qualifiers 2.06 J J PCB-201 1.16 PCB-204 (0.349) PCB-197 [0.581] PCB-200 PCB-208 2.19 Qualifiers J PCB-207 [1.47] J EMPC PCB-206 4.21 J J EMPC 0.853 J Conc. 6.4 PCB-198/199 9.2 JC EMPC 7.87 C PCB-196 3.55 J J EMPC PCB-203 4.61 J Deca Conc. PCB-195 [2.5] J EMPC J PCB-183 7.79 J PCB-190 2.78 J PCB-194 6.46 PCB-185 1.48 J PCB-189 0.645 J PCB-205 (0.49) Conc. 110 Conc. 27.9 EMPC 122 EMPC 31 209 Congener PCB Summary Page 2 of 2 PCB-209 42.6 Qualifiers 9 of 562 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB083-1SWMID-140318-D ANCHOR QEA Patrick Bayou 18-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 37.7 EMPC 108 6.49 191 5.63 1.08 11.5 3.5 ND 0.73 Aqueous 1.18 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 1.68 11903 Qualifier J J J J JC J 0.259 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.122 0.126 0 13 0.13 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 27.8 395 2,650 5,230 1,910 431 116 24.9 9.25 45.2 Total PCB (Mono-Deca) 10,800 Checkcode: 203-283-HKH SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA A6521 A6521_11903_PCB_002-RJ 0.122 0.126 0 13 0.13 2,660 5,230 1,910 433 27.5 10,800 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 19-Mar-2014 20-Mar-2014 28-Mar-2014 Recovery % 72.7 78.9 100 103 104 88.9 116 94.1 92.3 124 105 101 106 102 107 97.2 96 2 96.2 86.7 85.8 85.6 101 106 117 100 112 91.4 95.5 107 87.4 96.9 110 127 Report Created: 04-Apr-2014 10:13 Analyst: ds 10 of 562 Sample ID: PB083-1SWMID-140318-D Client Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: 18-Mar-2014 Date Collected: Laboratory Data pH Conc. Qualifiers PCB-1 21.4 PCB-2 1.49 J PCB-3 4.96 JB Project No.: A6521 Date Received: 1.18 L Sample ID: A6521_11903_PCB_002-RJ Date Extracted: 20-Mar-2014 11903 Date Analyzed: 28-Mar-2014 203-283-HKH Time Analyzed: pg/L Tri Conc. PCB-19 79.7 PCB-30/18 522 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. Qualifiers Tetra 19-Mar-2014 22:30:56 Conc. Qualifiers J EMPC PCB-54 3.2 J PCB-72 [3.23] PCB-50/53 159 C PCB-68 27.1 PCB-17 184 PCB-45 144 PCB-57 2.38 J PCB-27 31.5 PCB-51 62 PCB-58 1.12 J PCB-46 62.5 PCB-67 11.3 PCB-52 875 PCB-63 17.2 Conc. 27.8 PCB-24 [2.8] EMPC 27.8 PCB-16 181 Di Conc. Qualifiers Aqueous 7 Units Mono Method 1668A Sample Data J EMPC PCB-32 170 PCB-34 2.48 PCB-23 (0.664) J PCB-73 1.71 PCB-43 28.2 PCB-69/49 425 PCB-48 131 J 774 PCB-66 482 PCB-55 5.47 PCB-56 237 PCB-4 145 PCB-10 4.61 J PCB-26/29 91.5 PCB-9 6.87 J PCB-25 63.6 PCB-44/47/65 737 C PCB-60 105 PCB-7 3.16 J PCB-31 483 PCB-59/62/75 52.3 C PCB-80 (0.635) PCB-6 45.8 PCB-28/20 482 C PCB-42 184 PCB-79 3.07 PCB-5 1.83 J PCB-21/33 137 C PCB-41 51.6 PCB-78 (0.762) PCB-81 [1.68] PCB 77 PCB-77 37 7 37.7 C PCB-8 101 PCB-22 135 PCB 14 PCB-14 (0 356) (0.356) PCB 36 PCB-36 (0 637) (0.637) PCB-11 21.2 B PCB-39 4.53 J PCB-13/12 13.8 JC PCB-38 [0.797] J EMPC PCB-15 52.4 PCB-35 7.21 J PCB-37 77.6 PCB-71/40 330 PCB 64 PCB-64 277 C PCB-61/70/74/76 C Conc. 395 Conc. 2,650 Conc. 5,230 EMPC 395 EMPC 2,660 EMPC 5,230 C J J J EMPC Totals Conc. EMPC Mono-Tri 3,080 3,080 Tel: +1 910 794-1613 Tetra-Hexa 7,560 7,570 www.us.sgs.com Hepta-Deca 195 198 Mono-Deca 10,800 10,800 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 11 of 562 Sample ID: Penta PCB-104 PB083-1SWMID-140318-D Conc. Qualifiers (0.208) Method 1668A Penta Conc. Qualifiers PCB-108/119/86/97/125/87 218 C Hexa Conc. Qualifiers PCB-155 [0.273] J EMPC Hexa PCB-165 Conc. PCB-96 7.49 J PCB-117 8.19 J PCB-152 [0.228] J EMPC PCB-146 13.9 PCB-103 2.85 J PCB-116/85 73.9 C PCB-150 0.275 J PCB-161 (0.186) PCB-94 3.65 J PCB-95 227 PCB-100/93 5.05 PCB-102 15.6 PCB-98 1.45 PCB-88 (0.733) JC J PCB-110 305 PCB-136 13.1 PCB-115 9.47 PCB-145 (0.184) PCB-148 (0.239) PCB-82 54.2 PCB-111 (0.472) PCB-120 0.555 9 PCB-107/124 PCB-153/168 PCB-141 PCB-151/135 28.4 C J PCB-154 [1.03] J EMPC JC PCB-144 4.67 J 68.6 PCB-130 7.57 J PCB-137 5.75 J PCB-164 6.63 J PCB-163/138/129 104 C PCB-91 55.9 PCB-109 16.1 PCB-147/149 70.2 C PCB-160 (0.197) 110 PCB-123 5.63 J PCB-134 5.51 J PCB-158 10.4 PCB-89 10.5 PCB-106 [0.823] J EMPC PCB-143 0.367 J PCB-128/166 PCB-121 (0.476) PCB-118 191 PCB-139/140 2.24 JC PCB-92 46.8 J PCB-113/90/101 241 PCB-83 18.8 PCB-99 149 PCB-112 [0.984] Hepta PCB-188 Conc. J EMPC Qualifiers (0.157) PCB-122 4.31 J PCB-131 2.1 PCB-114 6.49 J PCB-142 (0.289) PCB-105 108 PCB-132 36.5 PCB-127 (0.489) PCB-133 1.32 PCB-126 [1.08] J 17.1 C PCB-159 [0.677] J EMPC J PCB-162 0.473 PCB-167 3.5 J PCB-156/157 11.5 JC PCB-169 (0.259) J Conc. 1,910 Conc. 431 EMPC 1,910 EMPC 433 Hepta Conc. Nona Conc. PCB-174 Qualifiers 14 PCB-179 6.7 J PCB-177 8.43 0.498 J PCB-181 (0.318) PCB-176 1.91 J PCB-171/173 4.32 PCB-186 (0.186) PCB-172 2.48 PCB-178 3.27 J PCB-192 (0.264) PCB-175 0.662 J PCB-180/193 28.6 PCB-187 17.5 PCB-191 0.726 (0.289) PCB-170 14.5 Octa PCB-202 PCB-184 PCB-182 C 17 PCB-84 C Qualifiers (0.203) J Conc. Qualifiers 1.83 J J 2.33 PCB-207 2.22 J PCB-206 4.7 J PCB-201 1.09 PCB-204 (0.262) JC PCB-197 0.501 J PCB-200 1.08 J Conc. 9.25 PCB-198/199 7.82 JC EMPC 9.25 C PCB-196 [2.65] J EMPC J PCB-203 4.23 J Deca Conc. PCB-195 2.23 J J PCB-183 7.14 J PCB-190 2.73 J PCB-194 6.09 PCB-185 1.59 J PCB-189 0.73 J PCB-205 (0.346) Conc. 116 Conc. 24.9 EMPC 116 EMPC 27.5 209 Congener PCB Summary Page 2 of 2 Qualifiers J PCB-208 J PCB-209 45.2 Qualifiers 12 of 562 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB087-1SWMID-140318-N ANCHOR QEA Patrick Bayou 18-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 20.8 ND 55.6 3.48 105 2.82 ND 7.98 2.42 ND 0.628 Aqueous 0.93 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L J J 0.752 JC J 0.342 J 0.00743 0.0503 0 0931 0.0931 0.00743 0.0503 0 0931 0.0931 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 27 349 1,730 2,660 1,040 290 46.4 10.2 ND 11.5 1,730 2,660 1,050 297 72.1 17.3 Total PCB (Mono-Deca) 6,160 Checkcode: 039-448-GDN SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11903 Qualifier 1.02 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6521 A6521_11903_PCB_003-RJ 1.65 6,220 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 19-Mar-2014 20-Mar-2014 28-Mar-2014 Recovery % 36.9 48.9 58.6 83 67.9 86.4 86.5 91.1 89.4 112 102 99.6 104 102 108 97.5 94 4 94.4 87 85.8 89.4 101 103 115 99.3 112 93 97.9 107 92 93.8 105 125 Report Created: 04-Apr-2014 10:13 Analyst: ds 13 of 562 Sample ID: PB087-1SWMID-140318-N Client Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: 18-Mar-2014 Date Collected: Laboratory Data pH Conc. Qualifiers PCB-1 18.9 PCB-2 2.03 J PCB-3 6.04 JB Project No.: A6521 Date Received: 0.93 L Sample ID: A6521_11903_PCB_003-RJ Date Extracted: 20-Mar-2014 11903 Date Analyzed: 28-Mar-2014 039-448-GDN Time Analyzed: pg/L Tri Conc. PCB-19 81.2 PCB-30/18 368 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. Qualifiers Tetra 19-Mar-2014 23:25:58 Conc. Qualifiers J PCB-54 2.88 J PCB-72 1.81 PCB-50/53 88.6 C PCB-68 23.9 PCB-17 150 PCB-45 67.2 PCB-57 1.4 PCB-27 26.4 PCB-51 56.4 PCB-58 (0.898) Conc. 27 PCB-24 2.56 EMPC 27 PCB-16 126 Di Conc. Qualifiers Aqueous 7 Units Mono Method 1668A Sample Data PCB-32 157 PCB-34 2.09 PCB-23 (1.07) J PCB-46 33 PCB-67 5.56 J PCB-52 451 PCB-63 9.59 J PCB-61/70/74/76 350 C PCB-66 231 PCB-55 [2.83] PCB-56 119 PCB-73 1.13 J PCB-43 14.4 PCB-69/49 228 C PCB-48 55.7 J PCB-4 149 PCB-10 3.54 J PCB-26/29 PCB-9 4.33 J PCB-25 65.2 PCB-44/47/65 389 C PCB-60 49.4 PCB-7 (0.801) PCB-31 242 PCB-59/62/75 27.4 JC PCB-80 (0.831) 64 C PCB-6 47.3 PCB-28/20 267 C PCB-42 100 PCB-79 [1.85] PCB-5 (0.852) PCB-21/33 60.8 C PCB-41 18 PCB-78 (0.998) PCB-71/40 177 PCB-81 (1.02) PCB 64 PCB-64 137 PCB 77 PCB-77 20 8 20.8 PCB-8 65.6 PCB-22 75.8 PCB 14 PCB-14 (0 716) (0.716) PCB 36 PCB-36 (1 03) (1.03) PCB-11 26.3 B PCB-39 2.19 17 JC PCB-38 (1.12) PCB-35 [4.47] PCB-37 38.8 PCB-13/12 PCB-15 35.9 J C J EMPC J EMPC J J EMPC Conc. 349 Conc. 1,730 Conc. 2,660 EMPC 349 EMPC 1,730 EMPC 2,660 Totals Conc. EMPC Mono-Tri 2,110 2,110 Tel: +1 910 794-1613 Tetra-Hexa 3,990 4,010 www.us.sgs.com Hepta-Deca 68.2 101 Mono-Deca 6,160 6,220 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 14 of 562 Sample ID: Penta PCB-104 PB087-1SWMID-140318-N Conc. Qualifiers (0.344) Method 1668A Penta Conc. Qualifiers PCB-108/119/86/97/125/87 117 C PCB-155 PCB-152 (0.329) PCB-146 9.56 C PCB-150 (0.324) PCB-161 (0.329) PCB-96 [4.22] J EMPC PCB-117 PCB-103 [1.41] J EMPC PCB-116/85 PCB-94 1.7 J PCB-95 128 (0.681) 44.4 Hexa Conc. Qualifiers [0.321] J EMPC PCB-110 179 PCB-136 9.51 PCB-115 (0.693) PCB-145 (0.342) PCB-148 (0.423) PCB-100/93 2.89 JC PCB-82 28.5 PCB-102 8.36 J PCB-111 (0.664) (0.655) PCB-98 (1.09) PCB-120 PCB-88 (1.03) PCB-107/124 [4.79] PCB-151/135 J EMPC C 19 J Hexa PCB-165 PCB-153/168 PCB-141 JBC Conc. Qualifiers (0.359) 45 J C 11.6 PCB-130 5.05 J PCB-137 3.72 J PCB-154 0.709 J PCB-164 5.04 J PCB-144 2.87 J PCB-163/138/129 71.2 C PCB-91 29.8 PCB-109 9.23 J PCB-147/149 48.5 C PCB-160 PCB-84 59.6 PCB-123 2.82 J PCB-134 [3.94] J EMPC PCB-158 7.25 J PCB-89 5.43 PCB-106 [1.15] J EMPC PCB-143 (0.475) PCB-128/166 11.8 JC PCB-121 (0.67) PCB-118 105 J PCB-92 27.4 PCB-122 2.67 J PCB-114 3.48 J PCB-105 55.6 PCB-127 (0.693) PCB-133 [1.31] PCB-126 (0.752) PCB-113/90/101 136 PCB-83 11.9 PCB-99 78.8 PCB-112 0.986 Hepta PCB-188 Conc. J C J Qualifiers (0.307) 26.3 J EMPC PCB-167 2.42 J PCB-156/157 7.98 JC PCB-169 (0.342) Hepta Conc. Qualifiers Nona Conc. [8.03] J EMPC J EMPC PCB-177 [5.05] (0.469) J EMPC (0.468) (0.511) 290 PCB-181 PCB-175 PCB-142 PCB-132 297 PCB-174 J EMPC (0.328) Conc. J [1.66] 0.502 PCB-162 EMPC J PCB-178 PCB-159 J EMPC 1,040 4.3 [1.04] JC [1.33] 1,050 0.533 (0.364) 1.66 PCB-131 Conc. PCB-179 PCB-176 PCB-139/140 EMPC PCB-184 PCB-186 (0.349) Octa PCB-202 Conc. Qualifiers [1.28] J EMPC J EMPC PCB-201 [0.836] PCB-204 (0.418) PCB-208 PCB-207 (1.22) PCB-206 (2.03) PCB-171/173 3.05 JC PCB-197 (0.408) PCB-172 1.43 J PCB-200 0.649 J Conc. 0 PCB-192 (0.39) PCB-198/199 4.85 JC EMPC 0 JC PCB-196 1.98 J Deca Conc. PCB-180/193 18.7 PCB-187 11.5 PCB-191 0.503 J PCB-203 2.74 J PCB-182 (0.426) PCB-170 [8.47] J EMPC PCB-195 [1.08] J EMPC J EMPC PCB-183 4.33 J PCB-190 [1.44] J EMPC PCB-194 [3.87] PCB-185 1.41 J PCB-189 0.628 J PCB-205 (0.563) Conc. 46.4 Conc. 10.2 EMPC 72.1 EMPC 17.3 209 Congener PCB Summary Page 2 of 2 PCB-209 Qualifiers (1.27) 11.5 Qualifiers 15 of 562 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB091-1SWMID-140318-N ANCHOR QEA Patrick Bayou 18-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 32.2 1.34 76.9 4.42 148 3.35 ND 8.99 2.78 ND 0.617 Aqueous 0.96 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L A6521 A6521_11903_PCB_004-RJ 11903 Qualifier J J J 0.864 JC J 0.446 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.011 0.0609 0 111 0.111 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 23.8 390 2,060 3,570 1,420 337 90.4 16 4.09 5.81 Total PCB (Mono-Deca) 7,920 Checkcode: 863-237-FYN SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 0.011 0.0609 0 111 0.111 2,060 3,570 1,420 22.3 J 7,930 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 19-Mar-2014 20-Mar-2014 29-Mar-2014 Recovery % 39.5 52.2 61.3 85 69.3 87.9 88.9 95.2 92.3 113 102 97.9 104 102 106 92.2 90 8 90.8 85.4 86.1 84.6 102 105 117 98.8 111 89.3 94.2 106 86 93.7 106 125 Report Created: 04-Apr-2014 10:13 Analyst: ds 16 of 562 Sample ID: PB091-1SWMID-140318-N Client Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: 18-Mar-2014 Date Collected: Laboratory Data pH Conc. Qualifiers PCB-1 15.2 PCB-2 2.69 J PCB-3 5.96 JB Project No.: A6521 Date Received: 0.96 L Sample ID: A6521_11903_PCB_004-RJ Date Extracted: 20-Mar-2014 11903 Date Analyzed: 29-Mar-2014 863-237-FYN Time Analyzed: pg/L Tri Conc. PCB-19 91.1 PCB-30/18 383 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. Qualifiers Tetra 19-Mar-2014 00:21:02 Conc. Qualifiers J PCB-54 3.41 J PCB-72 3.5 PCB-50/53 113 C PCB-68 22.7 PCB-17 181 PCB-45 77.1 PCB-57 2.2 J PCB-27 30.8 PCB-51 63.1 PCB-58 [1.24] J EMPC PCB-46 41.9 PCB-67 8.75 J PCB-52 574 PCB-63 15.7 Conc. 23.8 PCB-24 [2.13] EMPC 23.8 PCB-16 119 Di Conc. Qualifiers Aqueous 7 Units Mono Method 1668A Sample Data PCB-32 192 PCB-34 3.18 PCB-23 (1.02) J EMPC J PCB-73 1.35 PCB-43 19.5 PCB-69/49 326 PCB-48 69 J 490 PCB-66 337 PCB-55 4.12 PCB-56 169 PCB-4 147 PCB-10 3.57 J PCB-26/29 89.2 PCB-9 3.77 J PCB-25 106 PCB-44/47/65 511 C PCB-60 63.4 PCB-7 2.59 J PCB-31 302 PCB-59/62/75 35.6 C PCB-80 (0.653) C C PCB-61/70/74/76 PCB-6 70.6 PCB-28/20 349 C PCB-42 138 PCB-79 3.42 PCB-5 (0.82) PCB-21/33 64.4 C PCB-41 18.6 PCB-78 (0.784) PCB-8 68.3 PCB-22 92.6 PCB 14 PCB-14 (0 689) (0.689) PCB 36 PCB-36 (0 975) (0.975) PCB-11 30.6 B PCB-39 2.99 PCB-13/12 25.1 C PCB-38 (1.05) PCB-15 38.4 PCB-35 7.08 PCB-37 48.4 PCB-71/40 240 PCB 64 PCB-64 187 C PCB-81 1.34 PCB 77 PCB-77 32 2 32.2 C J J J J J Conc. 390 Conc. 2,060 Conc. 3,570 EMPC 390 EMPC 2,060 EMPC 3,570 Totals Conc. EMPC Mono-Tri 2,470 2,480 Tel: +1 910 794-1613 Tetra-Hexa 5,330 5,330 www.us.sgs.com Hepta-Deca 116 123 Mono-Deca 7,920 7,930 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 17 of 562 Sample ID: Penta PCB-104 PB091-1SWMID-140318-N Conc. Qualifiers (0.302) Method 1668A Penta Conc. Qualifiers PCB-108/119/86/97/125/87 158 C Hexa Conc. Qualifiers PCB-155 0.698 J Hexa PCB-165 Conc. PCB-96 5.9 J PCB-117 7.02 J PCB-152 (0.235) PCB-146 11.3 PCB-103 2.09 J PCB-116/85 53.2 C PCB-150 (0.232) PCB-161 (0.251) PCB-94 3.15 J PCB-110 235 PCB-136 10.2 PCB-95 157 PCB-115 3.52 J PCB-145 (0.245) PCB-100/93 4.64 PCB-148 (0.322) PCB-102 JC 12 PCB-98 0.905 PCB-88 (0.834) J PCB-82 39.5 PCB-111 (0.537) PCB-120 (0.529) PCB-107/124 6.34 PCB-151/135 22 J PCB-153/168 PCB-141 Qualifiers (0.273) 54 C 12.8 PCB-130 5.86 J C PCB-137 4.05 J PCB-164 5.75 J PCB-163/138/129 82.8 C PCB-154 (0.288) JC PCB-144 3.22 J PCB-91 44.1 PCB-109 13.9 PCB-147/149 53.7 C PCB-160 (0.266) PCB-84 82.9 PCB-123 3.35 J PCB-134 5.19 J PCB-158 8.02 J PCB-89 8.3 PCB-106 [1.49] J EMPC PCB-143 (0.362) PCB-128/166 12.7 JC PCB-121 (0.541) PCB-118 148 J PCB-92 37.2 PCB-122 3.31 J PCB-114 4.42 J PCB-105 76.9 PCB-127 (0.583) PCB-133 1.28 PCB-126 (0.864) PCB-113/90/101 177 PCB-83 16.4 PCB-99 116 PCB-112 0.68 Hepta PCB-188 Conc. J C J Qualifiers (0.26) PCB-139/140 2 JC PCB-159 0.674 PCB-131 1.49 J PCB-162 (0.4) PCB-142 (0.39) PCB-132 27.6 J PCB-167 2.78 J PCB-156/157 8.99 JC PCB-169 (0.446) Conc. 1,420 Conc. 337 EMPC 1,420 EMPC 337 Hepta Conc. Nona Conc. PCB-174 Qualifiers 11.2 Octa Conc. Qualifiers [1.64] J EMPC PCB-201 [0.796] J EMPC PCB-204 (0.407) PCB-202 PCB-179 5.36 J PCB-177 6.16 PCB-184 1.14 J PCB-181 (0.535) J PCB-176 1.31 J PCB-171/173 PCB-186 (0.309) PCB-178 2.4 J PCB-175 0.576 J PCB-180/193 PCB-196 2.62 J PCB-187 14.5 PCB-191 (0.415) PCB-203 [2.83] J EMPC PCB-182 (0.487) PCB-170 10.4 PCB-195 1.82 J PCB-183 6.9 J PCB-190 1.99 J PCB-194 4.28 J PCB-185 0.912 J PCB-189 0.617 J PCB-205 (0.425) PCB-208 1.04 PCB-207 (0.872) PCB-206 3.05 Qualifiers J J 3.16 JC PCB-197 [0.405] J EMPC PCB-172 2.04 J PCB-200 [0.601] J EMPC Conc. 4.09 PCB-192 (0.445) 7.25 JC EMPC 4.09 Deca Conc. Qualifiers 5.81 J 21.8 PCB-198/199 C Conc. 90.4 Conc. 16 EMPC 90.4 EMPC 22.3 209 Congener PCB Summary Page 2 of 2 PCB-209 18 of 562 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB093_A-1SWMID-140318-N ANCHOR QEA Patrick Bayou 18-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 21.1 1.3 49.7 2.83 97 2.99 ND 6.03 EMPC ND ND Aqueous 1.22 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L A6521 A6521_11903_PCB_005-RJ 11903 Qualifier J J J 0.751 1.77 JC J 0.254 0.261 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL 0.00726 0.0486 0 09 0.09 0.00731 0.0487 0 0901 0.0901 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 21.3 320 1,540 2,550 953 223 61.6 10.4 3.03 4.56 Total PCB (Mono-Deca) 5,680 Checkcode: 596-561-ZBW SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 321 1,540 2,560 956 227 63.4 16 J 5,710 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 19-Mar-2014 20-Mar-2014 29-Mar-2014 Recovery % 47.1 58.9 71.3 93.5 82 91.4 102 96.4 93.5 123 106 102 107 104 111 100 99 5 99.5 89.3 88.9 85.2 105 110 120 101 116 92.3 94.8 112 87.5 100 114 136 V Report Created: 04-Apr-2014 10:13 Analyst: ds 19 of 562 Sample ID: PB093_A-1SWMID-140318-N Client Data Sample Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: 18-Mar-2014 Date Collected: pH Conc. Qualifiers PCB-1 13.8 PCB-2 2.51 J PCB-3 5.06 JB Project No.: A6521 Date Received: 1.22 L Sample ID: A6521_11903_PCB_005-RJ Date Extracted: 20-Mar-2014 11903 Date Analyzed: 29-Mar-2014 596-561-ZBW Time Analyzed: pg/L Tri Conc. PCB-19 71.3 PCB-30/18 277 QC Batch No.: Checkcode: Qualifiers Tetra Conc. PCB-54 C PCB-50/53 Qualifiers Tetra 19-Mar-2014 01:16:07 Conc. Qualifiers J EMPC 2.47 J PCB-72 [2.56] 86 C PCB-68 24.1 PCB-17 129 PCB-45 55.5 PCB-57 2.11 J PCB-27 22.2 PCB-51 55.5 PCB-58 0.891 J PCB-46 30.8 PCB-67 6.63 J PCB-52 429 PCB-63 11.4 PCB-73 [0.842] PCB-43 14.7 Conc. 21.3 PCB-24 [1.6] EMPC 21.3 PCB-16 79.6 Di Conc. Qualifiers Aqueous 7 Units Mono Method 1668A Laboratory Data J EMPC PCB-32 137 PCB-34 2.77 PCB-23 (0.867) J 3.21 PCB-56 113 J PCB-26/29 77.6 PCB-9 3.57 J PCB-25 91.4 PCB-44/47/65 378 C PCB-60 41.6 PCB-7 2.28 J PCB-31 240 PCB-59/62/75 26.8 C PCB-80 (0.66) 63.2 [0.926] J EMPC C PCB-55 116 3.22 PCB-5 45.5 331 218 PCB-10 PCB-6 245 PCB-48 PCB-61/70/74/76 PCB-66 PCB-4 C PCB-69/49 J EMPC PCB-28/20 262 C PCB-42 97.8 PCB-79 [1.67] PCB-21/33 43.6 C PCB-41 16.2 PCB-78 (0.793) PCB-8 52.1 PCB-22 68.6 PCB 14 PCB-14 (0 473) (0.473) PCB 36 PCB-36 (0 832) (0.832) (0.809) PCB-11 27.6 B PCB-39 PCB-13/12 20.6 C PCB-38 (0.9) PCB-15 30.8 PCB-35 [4.69] PCB-37 34.1 PCB-71/40 163 PCB 64 PCB-64 132 C PCB-81 1.3 PCB 77 PCB-77 21 1 21.1 C J J EMPC J J EMPC Conc. 320 Conc. 1,540 Conc. 2,550 EMPC 321 EMPC 1,540 EMPC 2,560 Totals Conc. EMPC Mono-Tri 1,880 1,880 Tel: +1 910 794-1613 Tetra-Hexa 3,730 3,740 www.us.sgs.com Hepta-Deca 79.6 87 Mono-Deca 5,680 5,710 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 20 of 562 Sample ID: Penta PB093_A-1SWMID-140318-N Conc. Qualifiers Conc. Qualifiers PCB-108/119/86/97/125/87 106 C 3.17 36 PCB-136 6.55 J PCB-145 (0.213) PCB-141 8.12 J PCB-148 (0.274) PCB-130 4.2 J PCB-104 (0.208) PCB-96 3.65 J PCB-117 PCB-103 1.5 J PCB-116/85 J PCB-94 2.07 PCB-95 106 PCB-100/93 3.24 JC J PCB-102 7.95 PCB-98 0.752 PCB-88 (0.713) PCB-91 29.3 PCB-84 55.8 PCB-89 5.2 J Method 1668A Penta PCB-110 158 PCB-115 4.31 PCB-82 25.5 Hexa Conc. Qualifiers PCB-155 [0.615] J EMPC J PCB-152 (0.205) PCB-146 7.46 C PCB-150 (0.201) PCB-161 (0.214) PCB-111 (0.459) PCB-151/135 PCB-120 (0.453) PCB-154 PCB-107/124 4.44 PCB-109 8.98 JC J Hexa PCB-165 PCB-153/168 Conc. Qualifiers (0.233) 37 J C 15 JBC PCB-137 3.4 J 0.61 J PCB-164 3.16 J 55.9 C PCB-144 2.22 J PCB-163/138/129 PCB-147/149 36.6 C PCB-160 (0.227) PCB-158 5.31 J PCB-128/166 9.43 JC J EMPC PCB-123 2.99 J PCB-134 2.8 J PCB-106 [1.56] J EMPC PCB-143 [0.444] J EMPC PCB-121 (0.463) PCB-118 97 PCB-139/140 [1.1] J EMPC C PCB-159 [0.351] PCB-92 26.1 PCB-122 [1.88] J EMPC PCB-131 0.87 J PCB-162 0.283 J PCB-113/90/101 122 PCB-114 2.83 J PCB-142 (0.332) PCB-167 [1.77] J EMPC PCB-83 11.4 PCB-105 49.7 PCB-132 17.1 B PCB-156/157 6.03 JC PCB-99 78.3 PCB-127 (0.475) PCB-133 0.95 J PCB-169 PCB-112 0.604 PCB-126 (0.751) Hepta PCB-188 Conc. C J Qualifiers (0.203) Conc. 953 Conc. 223 EMPC 956 EMPC 227 Hepta Conc. Qualifiers Nona Conc. 8.03 J PCB-202 J PCB-174 PCB-179 3.96 J PCB-177 4.52 PCB-184 [0.889] J EMPC PCB-181 (0.426) PCB-176 [0.977] J EMPC PCB-171/173 PCB-186 (0.24) PCB-178 1.74 PCB-175 (0.425) J (0.254) 2.42 JC PCB-172 1.43 J PCB-192 (0.354) PCB-180/193 16 Octa Conc. Qualifiers 1.47 J PCB-201 [0.799] J EMPC PCB-204 (0.246) PCB-197 (0.24) PCB-208 0.997 PCB-207 (0.632) PCB-206 2.04 Qualifiers J J PCB-200 0.592 J Conc. 3.03 PCB-198/199 4.58 JC EMPC 3.03 JC PCB-196 [1.5] J EMPC Deca Conc. Qualifiers 4.56 J PCB-187 9.88 PCB-191 (0.33) PCB-203 2.5 J PCB-182 (0.388) PCB-170 7.03 J PCB-195 1.3 J PCB-183 4.27 J PCB-190 1.32 J PCB-194 [3.25] J EMPC PCB-185 0.909 J PCB-189 (0.261) PCB-205 (0.357) Conc. 61.6 Conc. 10.4 EMPC 63.4 EMPC 16 209 Congener PCB Summary Page 2 of 2 PCB-209 21 of 562 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A PB095-1SWMID-140318-N ANCHOR QEA Patrick Bayou 18-Mar-2014 PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L 28.8 1.52 71.9 4.12 136 3.91 EMPC 8.07 2.73 ND EMPC Aqueous 1.22 L 7 DL pg/L Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L A6521 A6521_11903_PCB_006-RJ 11903 Qualifier J J 0.921 J J JC J 0.281 0.362 J TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 0.0102 0.0515 0 0929 0.0929 21.2 305 1,730 3,100 1,320 295 82.5 22.1 0.102 0.106 0 111 0.111 1,730 3,100 1,320 299 85.1 23.1 3.29 5.17 J Total PCB (Mono-Deca) 6,880 Checkcode: 161-330-MBY SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 6,890 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 19-Mar-2014 20-Mar-2014 29-Mar-2014 Recovery % 39.6 50.3 59.7 84.9 70.6 78.8 91.7 83.8 81.5 103 90.3 87.5 90.3 87.8 92.5 84.4 81 6 81.6 74.6 76 73.2 89.4 92.9 102 86.2 97.2 81.4 83.2 93.5 78.2 112 124 148 V Report Created: 04-Apr-2014 10:14 Analyst: ds 22 of 562 Sample ID: PB095-1SWMID-140318-N Client Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: 18-Mar-2014 Date Collected: Laboratory Data pH Conc. Qualifiers PCB-1 13 PCB-2 2.58 J PCB-3 5.66 JB Aqueous Project No.: A6521 Date Received: 1.22 L Sample ID: A6521_11903_PCB_006-RJ Date Extracted: 20-Mar-2014 11903 Date Analyzed: 29-Mar-2014 161-330-MBY Time Analyzed: 7 Units Mono Method 1668A Sample Data pg/L Tri Conc. PCB-19 77.1 PCB-30/18 296 QC Batch No.: Checkcode: Qualifiers C Tetra Conc. Qualifiers J 2.82 J PCB-72 3.46 103 C PCB-68 23.2 PCB-17 139 PCB-45 64.1 PCB-57 [2.5] J EMPC PCB-27 24.3 PCB-51 60.8 PCB-58 1.61 J PCB-46 35.5 PCB-67 8.59 PCB-63 14.6 PCB-24 1.98 EMPC 21.2 PCB-16 86.6 PCB-52 530 PCB-32 158 PCB-73 1.35 PCB-34 3.06 PCB-43 17.9 PCB-23 (0.833) PCB-69/49 303 PCB-48 58 Qualifiers 02:11:12 Conc. PCB-50/53 21.2 Conc. Tetra PCB-54 Conc. Di Qualifiers 19-Mar-2014 J J J 287 PCB-66 300 PCB-4 111 PCB-10 3.05 J PCB-26/29 84.4 PCB-9 3.48 J PCB-25 104 PCB-44/47/65 473 C PCB-60 60.6 PCB-7 2.06 J PCB-31 267 PCB-59/62/75 32.8 C PCB-80 (0.592) C C PCB-61/70/74/76 PCB-55 3.8 PCB-56 149 PCB-6 55.5 PCB-28/20 310 C PCB-42 127 PCB-79 2.71 PCB-5 (0.309) PCB-21/33 49 C PCB-41 20.6 PCB-78 (0.711) PCB-8 51.7 PCB-22 80.2 PCB-71/40 214 PCB 14 PCB-14 (0 26) (0.26) PCB 36 PCB-36 (0 8) (0.8) PCB 64 PCB-64 169 PCB-11 26.2 B PCB-39 [1.07] PCB-13/12 20.8 C PCB-38 (0.865) PCB-15 31.3 PCB-35 5.94 PCB-37 41.1 C PCB-81 1.52 PCB 77 PCB-77 28 8 28.8 C J J J J EMPC J Conc. 305 Conc. 1,730 Conc. 3,100 EMPC 305 EMPC 1,730 EMPC 3,100 Totals Conc. EMPC Mono-Tri 2,050 2,050 Tel: +1 910 794-1613 Tetra-Hexa 4,710 4,720 www.us.sgs.com Hepta-Deca 110 117 Mono-Deca 6,880 6,890 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 23 of 562 Sample ID: Penta PB095-1SWMID-140318-N Conc. Qualifiers Method 1668A Penta Conc. Qualifiers Hexa PCB-108/119/86/97/125/87 143 C PCB-155 Conc. Qualifiers 0.818 J PCB-165 J PCB-146 9.47 PCB-161 (0.166) PCB-104 (0.17) PCB-96 5.36 J PCB-117 5.91 J PCB-152 0.25 PCB-103 2.13 J PCB-116/85 50.1 C PCB-150 (0.15) PCB-94 2.77 J PCB-110 219 PCB-136 9.64 PCB-95 145 PCB-115 4.42 J PCB-145 (0.159) PCB-148 (0.213) PCB-100/93 3.61 PCB-102 11.1 PCB-98 1.28 PCB-88 (0.771) JC J Hexa Conc. Qualifiers (0.181) PCB-153/168 48.6 PCB-141 10.9 C PCB-82 37.6 PCB-111 (0.497) PCB-120 [0.49] EMPC PCB-154 1 J PCB-164 4.12 J PCB-107/124 6.06 JC PCB-144 2.77 J PCB-163/138/129 72.4 C PCB-151/135 19.1 BC PCB-130 5.76 J PCB-137 4.09 J PCB-91 40.2 PCB-109 12.6 PCB-147/149 47.5 C PCB-160 PCB-84 75.4 PCB-123 3.91 J PCB-134 [3.78] J EMPC PCB-158 6.96 J PCB-89 7.14 PCB-106 1.42 J PCB-143 0.483 J PCB-128/166 11.7 JC PCB-121 (0.501) PCB-118 136 PCB-139/140 1.59 JC PCB-159 [0.458] J EMPC PCB-92 35.5 PCB-122 3.07 J PCB-131 1.29 J PCB-162 (0.264) J PCB-113/90/101 167 PCB-83 14.8 PCB-99 108 PCB-112 0.943 Hepta PCB-188 Conc. J C J Qualifiers (0.166) PCB-114 4.12 PCB-105 71.9 PCB-127 (0.537) PCB-126 0.921 PCB-142 (0.257) PCB-132 24.7 PCB-133 1.06 J (0.176) PCB-167 2.73 J PCB-156/157 8.07 JC PCB-169 (0.281) J EMPC Conc. 1,320 Conc. 295 EMPC 1,320 EMPC 299 Hepta Conc. Nona Conc. PCB-174 Qualifiers 10.6 PCB-179 4.66 J PCB-177 5.74 PCB-184 1.58 J PCB-181 (0.369) PCB-176 1.55 J PCB-171/173 J PCB-186 (0.196) PCB-178 2.86 J J EMPC 2.95 JC PCB-172 [1.83] J EMPC PCB-192 (0.307) PCB-180/193 Octa PCB-202 Conc. Qualifiers 1.92 J J PCB-208 [1.05] PCB-207 (0.689) PCB-206 [2.24] Qualifiers J EMPC PCB-201 1.1 PCB-204 (0.219) PCB-197 [0.444] J EMPC PCB-200 [0.559] J EMPC Conc. 0 6.82 JC EMPC 3.29 Deca Conc. Qualifiers 5.17 J PCB-198/199 PCB-175 [0.408] 21 C PCB-196 2.43 J PCB-187 13.4 PCB-191 0.437 J PCB-203 3.69 J PCB-182 (0.336) PCB-170 9.54 PCB-195 1.75 J PCB-183 5.49 J PCB-190 1.75 J PCB-194 4.38 J PCB-185 0.957 J PCB-189 [0.362] J EMPC PCB-205 (0.334) Conc. 82.5 Conc. 22.1 EMPC 85.1 EMPC 23.1 209 Congener PCB Summary Page 2 of 2 PCB-209 J EMPC 24 of 562 Sample ID: Client Data Name: Project ID: Date Collected: Analyte Method 1668A Method Blank A6521 ANCHOR QEA Patrick Bayou n/a PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 233'44'5/233'44'5'-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB Sample Data Matrix: Weight/Volume: pH Conc. pg/L ND ND ND ND 2.91 ND ND ND ND ND ND Aqueous 1.00 L n/a DL pg/L 1.64 1.81 1.05 0.995 Laboratory Data Project No.: Sample ID: QC Batch No.: EMPC pg/L 0.0000873 0.0847 0 169 0.169 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs Deca-CB 2.77 8.82 2.06 12.8 12.4 8.51 ND ND ND ND Total PCB (Mono-Deca) 47.4 Checkcode: 680-324-FDZ C 0.0000873 0.0847 0 169 0.169 6.84 14.8 20.9 13.4 1.21 1.27 3.37 1.31 67.5 SGS Environmental Services - PCB 2014 Rev. 4.04 5500 Business Drive T: 910 794-1613 Wilmington www.us.sgs.com North Carolina 28405 USA 11903 Qualifier J 0.992 1.36 1.45 0.906 1.08 1.02 TEQs (WHO M/H) ND = 0 ND = 0.5 x DL ND = DL A6521 MB1_11903_PCB_TLX-RJ2 Date Received: Date Extracted: Date Analyzed: Standard ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB PCB-155 155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 CS PCB-28 CS PCB-111 CS PCB-178 n/a 20-Mar-2014 28-Mar-2014 Recovery % 95.7 110 133 133 136 114 147 120 117 158 V 128 128 134 130 132 123 125 107 111 108 126 126 149 126 138 121 133 139 128 124 139 V 161 V Report Created: 04-Apr-2014 10:11 Analyst: ds 25 of 562 Sample ID: Method Blank A6521 Client Data Name: ANCHOR QEA Matrix: Project ID: Patrick Bayou Weight/Volume: n/a Date Collected: Mono Method 1668A Sample Data Conc. Qualifiers J PCB-1 1.08 PCB-2 (1.22) PCB-3 1.69 J Laboratory Data Aqueous Project No.: A6521 Date Received: n/a 1.00 L Sample ID: MB1_11903_PCB_TLX-RJ2 Date Extracted: 20-Mar-2014 11903 Date Analyzed: 28-Mar-2014 680-324-FDZ Time Analyzed: pH n/a QC Batch No.: Units pg/L Checkcode: Tri Conc. PCB-19 (2.56) PCB-30/18 (1.88) PCB-17 Qualifiers Tetra Conc. PCB-54 (0.971) PCB-50/53 (1.51) (2.21) PCB-45 C Qualifiers Tetra PCB-72 C 19:45:47 Conc. (1.6) PCB-68 (1.5) (1.66) PCB-57 (1.66) (1.58) PCB-27 (1.61) PCB-51 (1.55) PCB-58 Conc. 2.77 PCB-24 (1.69) PCB-46 (1.89) PCB-67 (1.52) EMPC 2.77 PCB-16 (2.97) PCB-52 5.34 PCB-63 (1.44) PCB-32 (1.52) PCB-73 (1.16) PCB-61/70/74/76 Di Conc. PCB-34 (1.64) PCB-43 (1.84) PCB-66 Qualifiers PCB-4 (2.05) PCB-23 (1.62) PCB-10 (1.31) PCB-26/29 (1.6) PCB-9 (2.03) PCB-25 (1.62) PCB-7 (1.78) PCB-31 [1.96] J EMPC PCB-6 (1.91) PCB-28/20 [2.82] J EMPC C PCB-42 PCB-5 (1.9) PCB-21/33 2.06 JC PCB-41 PCB-8 (1.89) PCB-22 (1.7) PCB-71/40 (1.52) PCB 14 PCB-14 (1 59) (1.59) PCB 36 PCB-36 (1 55) (1.55) PCB 64 PCB-64 (1 05) (1.05) PCB-11 8.82 J PCB-39 (1.51) PCB-13/12 (1.86) C PCB-15 (1.92) PCB-38 (1.68) PCB-35 (1.72) PCB-37 (1.9) PCB-69/49 C [2] PCB-48 J J EMPC C (1.54) 3.84 JC (1.71) PCB-55 (1.71) PCB-56 (1.73) PCB-44/47/65 3.67 JC PCB-60 (1.68) PCB-59/62/75 (1.11) C PCB-80 (1.47) (1.7) PCB-79 (1.47) (1.82) PCB-78 (1.76) PCB-81 (1.81) PCB 77 PCB-77 (1 64) (1.64) C Qualifiers Conc. 8.82 Conc. 2.06 Conc. 12.8 EMPC 8.82 EMPC 6.84 EMPC 14.8 Totals Conc. EMPC Mono-Tri 13.6 18.4 Tel: +1 910 794-1613 Tetra-Hexa 33.7 49.1 www.us.sgs.com Hepta-Deca 0 0 Mono-Deca 47.4 67.5 5500 Business Drive Wilmington, NC 28405, USA 209 Congener PCB Summary Page 1 of 2 26 of 562 Sample ID: Penta Method Blank A6521 Conc. PCB-104 (0.755) Qualifiers Method 1668A Penta Conc. Qualifiers Hexa PCB-108/119/86/97/125/87 [2.67] J EMPC C PCB-155 Conc. Qualifiers (0.61) Hexa PCB-165 Conc. PCB-96 (0.915) PCB-117 (1.02) PCB-152 (0.675) PCB-146 (1.02) PCB-103 (1.29) PCB-116/85 (1.37) C PCB-150 (0.665) PCB-161 (0.796) PCB-94 (1.52) PCB-110 5.2 J PCB-136 (0.726) PCB-153/168 [2.85] PCB-95 4.27 J PCB-115 (1.04) PCB-145 (0.703) PCB-141 (1.13) PCB-100/93 (1.4) C PCB-82 (1.75) PCB-148 (1.02) PCB-102 (1.2) PCB-111 (0.996) PCB-151/135 PCB-98 (1.63) PCB-120 (0.982) PCB-88 (1.55) PCB-107/124 (1.09) PCB-91 (1.31) PCB-109 (0.97) C 2 JC PCB-130 (1.28) PCB-137 (1.05) (0.822) PCB-154 (0.913) PCB-164 PCB-144 (1.03) PCB-163/138/129 PCB-147/149 3.55 JC 2.96 PCB-160 (0.845) (0.765) PCB-84 (1.68) PCB-123 (0.992) PCB-134 (1.26) PCB-158 PCB-89 (1.58) PCB-106 (1.08) PCB-143 (1.15) PCB-128/166 (1.17) PCB-121 (1) PCB-118 2.91 PCB-139/140 (1.04) PCB-159 (0.956) PCB-92 (1.48) PCB-113/90/101 [4.17] PCB-83 (1.73) PCB-99 [1.67] PCB-112 (1.03) Hepta Conc. PCB-188 (0.882) J EMPC C J EMPC Qualifiers J C PCB-122 (1.16) PCB-131 (1.2) PCB-162 (0.954) PCB-114 (0.995) PCB-142 (1.24) PCB-167 (0.906) PCB-105 (1.05) PCB-132 [2.01] PCB-127 (1.05) PCB-133 (1.12) PCB-126 (1.36) J EMPC PCB-156/157 (1.45) PCB-169 (1.08) Conc. 12.4 Conc. 8.51 EMPC 20.9 EMPC 13.4 Hepta Conc. Nona Conc. PCB-174 (1.6) Qualifiers Octa PCB-202 Conc. Qualifiers (1.24) PCB-208 (2.71) PCB-179 (0.994) PCB-177 (1.63) PCB-201 (1.14) PCB-207 (2.59) PCB-184 (1.06) PCB-181 (1.4) PCB-204 (1.21) PCB-206 (4.03) PCB-176 (0.978) PCB-171/173 (1.6) PCB-197 (1.18) C PCB-186 (1.05) PCB-172 (1.54) PCB-200 (1.2) PCB-178 (1.45) PCB-192 (1.17) PCB-198/199 (1.75) PCB-175 (1.4) PCB-180/193 (1.21) PCB-196 (1.64) PCB-187 (1.31) PCB-191 (1.09) PCB-203 (1.56) PCB-182 (1.28) PCB-170 (1.52) PCB-195 (1.91) C PCB-183 (1.26) PCB-190 (1.08) PCB-194 (1.71) PCB-185 (1.36) PCB-189 (1.02) PCB-205 (1.3) Conc. 0 Conc. 0 EMPC 0 EMPC 0 209 Congener PCB Summary Page 2 of 2 C Conc. 0 EMPC 0 Deca Conc. PCB-209 Qualifiers (0.867) (1.31) J EMPC C JC C C Qualifiers Qualifiers 27 of 562 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140328X08 Analysis Date: Lab ID: OPR1_11903_PCB-RJ2 NATIVE ANALYTES PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-104 22'466'-PeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-155 22'44'66'-HxCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-188 22'34'566'-HpCB PCB-189 233'44'55'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-206 22'33'44'55'6-NoCB PCB-208 22'33'455'66'-NoCB PCB-209 DeCB Processed: 04 Apr 2014 09:49 28-MAR-2014 17:55:43 SPIKE CONC. RECOVERY RANGE (%) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 112 113 94.1 104 96.8 112 94 102 105 93.3 97.6 99.2 97.6 98.8 105 96.2 98.9 97.5 95.8 92.8 102 97.9 98.1 99.7 99.2 96.9 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 Contract-required recovery limits for OPR as specified in Table 6, Method 1668A. Analyst: ds FORM 8A OK - 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 28 of 562 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140328X08 Analysis Date: Lab ID: OPR1_11903_PCB-RJ2 LABELED STANDARDS ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 FORM 8B 28-MAR-2014 17:55:43 SPIKE CONC. RECOVERY RANGE (%) 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 86.7 89.1 110 107 108 96 119 100 98.9 129 109 106 109 106 117 98.4 97 90.4 90.6 97.7 100 102 119 102 111 99.2 107 111 102 15 15 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 - 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 100 100 100 98.8 112 129 40 40 40 - 125 125 125 Y Y N OK CLEANUP STANDARDS CS PCB-28 CS PCB-111 CS PCB-178 Processed: 04 Apr 2014 09:49 Analyst: ds 29 of 562 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: Amy Boehm 19-Mar-14 at 10:20 A6521 30 days 18-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com AP Smp ID Sample Condition & Notes PB083-1SWMID-140318-N A6521_001 WS PB083-1SWMID-140318-D PB087-1SWMID-140318-N PB091-1SWMID-140318-N PB093_A-1SWMID-140318-N A6521_002 A6521_003 A6521_004 A6521_005 A6521_006 WS WS WS WS WS Ice - Good Condition Sample Seals: PB095-1SWMID-140318-N Preservation Type: Notes/Comments: Quantity Size Sampling Date 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 Sampling Time 15:23 15:23 15:53 17:08 17:37 18:47 Delaney Peterson ANCHOR QEA Patrick Bayou N//A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Received Temp Container # 2.4 1, 2 798261053444 2.4 2.4 2.4 2.4 2.4 1, 2 1, 2 1, 2 1, 2 1, 2 798261053444 Shipping # 798261053444 798261053444 798261053444 798261053444 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. Samples received intact Received by: Christina Newkirk Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Logged in by: Christina Newkirk QC'ed by: AK 19 Mar 14 SGS Analytical Perspectives 30 Of 562 CHAIN OF CUSTODY I CONVENTIONAL 81 SHALE PROJECT INFO: SEND DOCUMENTATION I RESULTS TO: INSTRUCTIONS I COMMENTS: new; Bow/[00 CONTACT: LLC QUOTE ADDRESS: #20 01/7 54/11:] 43/ PRESERVATIVE TURN AHOUNDTIME aiw? #295 I30 EMAIL: . REPORT LE gL/ . :3 VEL: (see reverse) Level i LI Level II eveT IV INVOICE T0: (DCHECK IF SAME) SPECIA LIVERABLES: w} State of Origin: COMPANY: CONTACT: gob DD: 1 Other: I ADDRESS: 13495 PHONE: ?43 5",0434 EMAIL: bob mlbi??aur all?. Cw? OC TYPE CONT. MS MSD DUP (0.6) MATRIX OTY SITE REF: W14 ANALYSIS 8: METHOD SAMPLE ID I DESCRIPTION DATE TIME REMARKS ?at/55 1/ a/ (4/551/ 1/ i RECEIVED BY: RELINOUISHED BY (2): . Page of IBIP 5 (I) 8G3 NORTH AMERICA INC. ENVIRONMENTAL SERVICES 5500' Business Drive Wilmington, NC 28405 910 350 1903 910 794 1613 Member of the 868 Group (SGS SAY 31 of 562 Project Initiation Form Project Number: A6521 Client Name: ANCHOR QEA 1668A Analysis Method: Initiation Date: Sample Matrix: TAT: Project Manager: 19-Mar-14 Aqueous 30 days Amy Special Instructions 1668A w/ OPR Reporting Instructions 1668A w/ OPR Anchor Equis EDD PM Initials: akornega Date: 19-Mar-2014 32 of 562 Prep Sheet 1,S_~ __ rM4J:LIy ".~SGS-- I IIlIljM",.".,."",. 16MlA Batch # 1\6521 Project # 11903 Extract Init/Date: ","''- 3 1..A 1\"\ ~~,~ J AAF.€frlnitIDate: \ )T1-lf~t-( ~ \ Client Sample AI' Sample ID A6521 -IIlJ03 001 Volume ID (mL) I'llOX3.1 SWMID.1403IX.N Talcx # \\1\) U, 1\6521 - IllJ03_002 I'BOX3.1 SWMID-1403IX-D \ \1) 5 1\6521 - 11903_003 1'1l0X7-ISWMID.1403IX.N ~)\ ~ PB091.ISWMID.1403IX.N Q"5''i 1 \ 1../2.\ ~ 1\6521 - IIlJ03 004 1\6521 - 11903_005 I'B093 - A.I SWMID.1403IX.N I'B095-ISWMID-1403IX.N l1- 1-. V q MBI - 11903 Method \b~ \ OPRI - IIlJ03 0_lllJ03_0PROOI \(11) l> 1- 1\6521 -11903_006 Blank Sllccial 16681\ wi OPR RV SDS # - -- -- - - # ( \ 2:> ....,I 2J I r 3 tff5 vf'fJ 1$ - cj;J3 V(B - 1"8 113 fB - '"!J/z/ 12tJ1l./ Start: Stop: ~~ (}f\\[., ,~ Ou\ ~~\l-- ).U- () 0\ ~\L ~ ~ 11..'"'\ / I t..I 00\ SeJ- 60\ ~\""' ~ 06\ V\IL.-r-...~ ')( ~ -r.. ~\l.. -c",-\.Lx ~ l.-(:) 0'1.- '2--' 'Z.- \ 'J Tctradccanc - OLt L \ 'U5\ :3 N~7..1:t\l~1 C> ""2..---z...,'-t~",\ 0) '2.0 20'"\ l{ ~\.Jn)Urllie:ttc 33 of 562 1668A Project # A6521 Batch # 11903 Inter-Department Communication Sheet Special Instructions Aqueous 34 of 562 TSS % TSS Determination I~ WorkSheet iili~ Tare Ilalanee Procedures: Add hoal & 0.45 ~Ull tilter and weigh. Record "Iloat WI." Place IIIter in glass filling funnel Filler 10 mL of aqueous sample through tiller into a wasle jar Rinse tiller with 20 mL of DI water Dry in ovcn ovcrnight @ 107 C Return dish to lop loader and record" Dry WI." A6521 Project: 11903 Ilateh: AI' Sample 10 1\6521 - 11903_00\ lloatWT. \.'15 Prep Date: J)ry WT. 0 0.\ 0 .\ \.1l \.l~ 1\652\ - 1\903_003 \,1~ \.11 \,l~ 1\903_004 /.11 1\652\ - 1\903_005 1.17 \,1~ 1\652\ - \1903 006 \,"11 \.1.1 - 'Y., TSS \.1.S 1\652\ - 11903 002 1\652\ ~'t Chemist: ~ Init/l}ate tvW.~ \-Nt ~\\ C.i- -1 0 "1 a ( 0 0.1- ~ 1 0 c).\ ~ l 0 0 D ~_\ ..\. '\'1" l Comments 35 of 562 Spike Sheet PCB I EllIi I~ 1 'V •. ,> Batch # A6521 Projcct # SPIKE S(Jiker Initialsl\)ate: Clicnt Sample AP Sample ID ID 1m 3/'l.Lw PBOS3-1 SWMID-1403IS-N A6521 - 11903 002 PBOS3-1 SWMID-1403IS-D A6521 - 11903 003 PBOS7-1 SWMID-14031S-N \!\'\- 11903 004 PB091-1 SWMID-1403IS-N A6521 - 11903005 PB093 A6521 - 11903 006 PB095-1 SWMID-14031S-N M131 - 11903 Mcthod OPRI - 11903 o-11903 - OI'ROOI A-ISWMID-1403IS-N Blank Sniked Volume Solution Cone. ~~/?,J.-i I .... /'l.-t/ 1'1 II)- J lly 11'1 Observer Initials \\'i~'L A6521 - 11903 001 - Exp. Date Spike amount - \~ o.J - ~\L o.--J ~t- - ~~ ~ ~'l- - ~\L oJ \J\'L - ~\~ ~'L- ~\L ~~ ~\lft\l~ r~ '51'2,\ l/l( 31£,,1.1/1 d It{ 100 pghlL Vl_\ \". \ \'\ (~L) 10, 1 Observer Initials '~'L \')-1~-' Units Observer Initials pcn.ls Amount: \I\'L \01-'\ L,..C\ 1~ Concentration Amount: 1.1) ,l.o ~\~ Standard SIL # Il(:n CS -...- pcn ES Spike ID Split Factor OJ 0'0 3\W\ Std. Type I PCBs PROFILE PCB i\X '209 Amount: 'I..O.,l.. PCB ES Amount: 201l.Observer Initials A6521 'Vater 11903 Sniked Amounl Snike Comnounds Analvte I I 1('('8A 20' ~ Information AX 209 \0"1.. •••.'1-0\ 1 \'\-\'l'\ 50 pg/l,lL \~\).,'\\\'\ 20' pen CS/SS pcn.ls \.()~ ""U>\.l~ \0 ICQ.OI3Ib \3-qlo-3 \")-%-1100 [lg/HL \ "/..\\c~\ \'1. 20 200 pg/flL \'1.-'~-\L-l 10 Final Volume Final Solvent 36 of 562 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: Amy Boehm 19-Mar-14 at 10:20 A6521 30 days 18-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com AP Smp ID Sample Condition & Notes PB083-1SWMID-140318-N A6521_001 WS PB083-1SWMID-140318-D PB087-1SWMID-140318-N PB091-1SWMID-140318-N PB093_A-1SWMID-140318-N A6521_002 A6521_003 A6521_004 A6521_005 A6521_006 WS WS WS WS WS Ice - Good Condition Sample Seals: PB095-1SWMID-140318-N Preservation Type: Notes/Comments: Quantity Size Sampling Date 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 2 1.25L Amber 18-Mar-14 Sampling Time 15:23 15:23 15:53 17:08 17:37 18:47 Delaney Peterson ANCHOR QEA Patrick Bayou N//A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Received Temp Container # 2.4 1, 2 798261053444 2.4 2.4 2.4 2.4 2.4 1, 2 1, 2 1, 2 1, 2 1, 2 798261053444 Shipping # 798261053444 798261053444 798261053444 798261053444 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. Samples received intact Received by: Christina Newkirk Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Logged in by: Christina Newkirk QC'ed by: AK 19 Mar 14 SGS Analytical Perspectives 37 of 562 _8 PROJECT INFO: PROJECT: E~o R.tr,,-c1L U 'PO, #: SEND DOCUMENTATION / RESULTS TO: COMPANY:Vei~ ~+050n SITEREF ot-/~z~t/-{lIOblT;,k '1 REPORT LEVEL: (see reverse I PHONE 5~Afftr::.tvA- o State S~L1VERABLES: [] DD: I 0 Level II ~ IV q6A: 'I 29~.,.q/3D INVOICE TO: (0 CHECK of Origin: COMPANY: IF SAME) PN L CONTACT: Other: -ISWmlo f57 -/5tVmIO- t?IJA~/-/Y.AJ(¥7/JJ /~t>~/~-/V -I LiIJ:3JRJ-.A/ -:',~-~_4 -/'lhJfY1lrJ- /"I/)3/~-,At! rl~ _ -15/../JM/IJ-f TIME MS MSD DUP CON~ MATRIX aTY ~1rJ~ ~"\I' /V ' G rr r-...r--.... D 5 iNS 5 t/ J/ REMARKS "- ~ w5 ~~~ ( ~~~ 311 ",ft."1 1/1~:r Jf/;';/'J. ~ ~~ (j- 1/!52.~ ~ ~ 1/ 0 "4 I~t:;.~ 1/'' fIJi 1'1 I 'f(7)" "LJ . - ~--"v (C, G) --.. ANALYSIS & METHOD TYPE '" /Q3 .,j,fO) !'1 P80fd -1SU/fYlln-ll-fo3/fj-D ~ ~ ~ ~ 5 tl t/ '17 6- w.5 S V t/ v (;.- /AJf~ 5 t/ V V 6- wS 5 V V- 'L/' '?/J0) /(..//)'{/~-N h bohpe or()ieci-~.,II'<~,Jvr.CofV\ ac DATE 80 "- a/V'\ 1/ 1-q3 S- -()tf3'1 EMAIL: SAMPLE ID / DESCRIPTION PRESERVATIVE Pm it'u.;:;k,' ADDRESS: PHONE: / COMMENTS: I dp~;(/~e CVl6~"r1--l!'A. ~ EMAIL: 0 Level SPECIAL INSTRUCTIONS f}'U:,h~l"at:4, Lc-L 7-ZD 0 I;~ ~~ 5v/k- /9pO ZOG, . S'+~WO TURNAROUNDTIME: & SHALE ADDRESS' CONTACT: QUOTE #' [. I CONVENTIONAL CHAIN OF CUSTODY r--- r-~ '\ / V V t/ 1/ /' ..-i\.. --- -.... -- ....•..•.• .....•.....• _/ COLL~I~~ED BY (1): V'''- . ....... 7~<,/1~~ RELINQUISHED BY (2): ~7;bltf DATE: TIME: IQZq TIME: RECEIVED BY: " t:ti/~- 'il ". RECEIVED BY: 'k Page_of_ i~r L"L.\C\ 3CO SGS NORTH AMERICA INC. ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 91035019031910794 Member " 1613 ~".?' 3",,,,,,,,, www.sgs.com of the SGS Group (SGS SAl 38 of 562 SGS Analytical Perspectives — Run Log Project: A6521_11903_PCB Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Datafile Vial# Wt/Vol Client/Sample ID Analyst(s) Checkcode Acq Date 7 140328X07 Tray1:03 CS3_140328_PCB_XB 1.00 SIL 13-79-3 LKB, DES 740-668 28-Mar-2014 17:00:58 8 140328X08 Tray1:76 OPR1_11903_PCB-RJ2 1.00 0_11903_OPR001 LKB, DES 662-053 28-Mar-2014 17:55:43 9 140328X09 Tray1:02 SBS_140328_PCB_XC 1.00 SIL 13-42-1 LKB, DES 100-145 28-Mar-2014 18:50:44 10 140328X10 Tray1:77 MB1_11903_PCB_TLX-RJ2 1.00 Method Blank LKB, DES 680-324 28-Mar-2014 19:45:47 12 140328X12 Tray1:79 A6521_11903_PCB_001-RJ 1.19 PB083-1SWMID-140318-N LKB, DES 761-512 28-Mar-2014 21:35:52 13 140328X13 Tray1:80 A6521_11903_PCB_002-RJ 1.18 PB083-1SWMID-140318-D LKB, DES 203-283 28-Mar-2014 22:30:56 14 140328X14 Tray1:81 A6521_11903_PCB_003-RJ 0.93 PB087-1SWMID-140318-N LKB, DES 039-448 28-Mar-2014 23:25:58 15 140328X15 Tray1:82 A6521_11903_PCB_004-RJ 0.96 PB091-1SWMID-140318-N LKB, DES 863-237 29-Mar-2014 00:21:02 16 140328X16 Tray1:83 A6521_11903_PCB_005-RJ 1.22 PB093_A-1SWMID-140318-N LKB, DES 596-561 29-Mar-2014 01:16:07 17 140328X17 Tray1:84 A6521_11903_PCB_006-RJ 1.22 PB095-1SWMID-140318-N LKB, DES 161-330 29-Mar-2014 02:11:12 Lab ID Project file: not saved AP UltraTrace-Pro V4.81 User/System: DE/US0008026 Acq Time Printed: 31-Mar-2014 08:38 39 of 562 Lab ID: MB1_11903_PCB_TLX-RJ2 ACQ: 28-Mar-2014 19:45:47 LKB Wt/Vol: 1.00 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB Client ID: Method Blank A6521 UTP: 31-Mar-2014 08:14 DES J-level: 10 pg/L Datafile: 140328X10 RPT: 04-Apr-2014 10:11 ds Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB NotFnd NotFnd NotFnd NotFnd 34.75 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.88 14.16 14.41 20.12 17.49 26.43 20.40 32.76 32.28 25.37 35.74 35.19 34.73 34.45 38.35 36.31 30.31 40.89 39.91 43.60 43.12 42.05 35.19 45.73 39.72 47.89 49.35 45.34 50.78 QC J C V Pred RRT Actual RRT 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 - 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7247 0.8641 0.8794 1.2274 1.0672 1.0791 0.8326 1.3372 1.3177 0.8322 1.1724 1.1547 1.1394 1.1302 1.2580 0.9716 0.8110 1.0941 1.0678 1.1667 0.9080 0.8855 0.7409 0.9629 0.8364 1.0084 1.0392 0.9548 1.0693 Diff Secs 0 +0.1 +0.1 -0.1 +0.4 -0.1 +0.6 -0.2 +1.6 +1.4 -0.5 +0.9 +0.8 +0.6 +0.6 +1.2 0 -0.7 +0.5 +0.2 +0.8 -0.3 -0.3 -0.8 0 -0.5 0 0 -0.3 -0.3 Page 1 of 5 Split: 1 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.74E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.02E+07 5.27E+07 3.05E+07 6.09E+07 3.02E+07 4.51E+07 3.02E+07 3.94E+07 3.80E+07 2.73E+07 3.30E+07 3.34E+07 3.32E+07 3.30E+07 2.90E+07 2.32E+07 3.33E+07 5.73E+07 3.09E+07 2.81E+07 1.84E+07 2.14E+07 2.34E+07 2.79E+07 2.23E+07 2.12E+07 1.54E+07 2.30E+07 1.99E+07 Checkcode: 680-324-FDZ Ra 0.65 3.22 3.28 1.60 1.58 1.07 1.09 0.77 0.81 0.79 1.60 1.61 1.60 1.57 1.58 1.55 1.32 1.28 1.25 1.29 1.28 1.06 1.08 1.06 1.02 0.93 0.88 0.81 0.80 1.20 Method 1668A RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ND ND ND ND 2.91 ND ND ND ND ND ND ND 3.68E+03 3.68E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 2.05E+03 1.66E+03 1.66E+03 1.66E+03 1.48E+03 1.25E+03 1.64 1.81 1.05 0.995 0.992 0.992 1.36 1.45 0.906 1.08 1.02 1.31 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 95.7 % 110 % 133 % 133 % 136 % 114 % 147 % 120 % 117 % 158 % 128 % 128 % 134 % 130 % 132 % 123 % 125 % 107 % 111 % 108 % 126 % 126 % 149 % 126 % 138 % 121 % 133 % 139 % 128 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Printed: 4/4/2014 10:17 AM 40 of 562 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.88 32.77 37.75 CS PCB-28 CS PCB-111 CS PCB-178 22.88 32.77 37.75 JS JS JS JS JS 16.39 24.50 30.48 37.37 47.49 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC V V Pred RRT Actual RRT Diff Secs Response Ra 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 5.46E+07 3.63E+07 1.57E+07 0.9339 1.0750 1.0100 0.9339 1.0752 1.0100 0 +0.4 0 Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.89 NotFnd 14.18 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 19.56 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd J J J C C 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.0013 1.0010 0.9722 - +0.1 0 +0.1 Page 2 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.07 1.59 1.13 1.11 1.03 0.62 109 % 107 % 108 % 30% 30% 30% 135% 135% 135% 5.46E+07 3.63E+07 1.57E+07 1.07 1.59 1.13 1.85 1.22 0.58 124 % 139 % 161 % 30% 30% 30% 135% 135% 135% 4.40E+07 2.38E+07 2.14E+07 1.67E+07 1.40E+07 1.57 0.81 1.58 1.32 0.92 3.84E+03 5.23E+03 3.84E+03 5.31E+03 5.31E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 6.65E+03 5.40E+03 5.40E+03 5.40E+03 5.40E+03 5.40E+03 5.40E+03 1.05 1.22 1.03 2.05 1.31 2.03 1.78 1.91 1.9 1.89 1.59 1.85 1.86 1.92 2.56 1.88 2.21 1.61 1.69 2.97 EMPC 2.77 8.82 6.84 14.8 20.9 13.4 0 0 0 NON-EMPC 2.77 8.82 2.06 12.8 12.4 8.51 0 0 0 2.58E+04 0.00E+00 4.49E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.85E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SI SI 1.54 0.95 1.17 1.01 1.23 1.92 0.97 1.10 1.03 1.03 1.04 1.23 1.06 1.06 1.02 1.15 1.56 1.33 1.82 1.74 0.99 DL 1.04 1.99 2.23 1.5 1.02 1.01 1.21 1.27 3.37 1.08 ND 1.69 ND ND ND ND ND ND ND ND 8.82 ND ND ND ND ND ND ND ND Printed: 4/4/2014 10:17 AM 41 of 562 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB NotFnd NotFnd NotFnd NotFnd NotFnd 22.63 22.90 23.10 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 24.52 NotFnd NotFnd 24.96 NotFnd 25.41 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 28.73 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC C J EMPC J EMPC C J C C J J EMPC C J C C C J C Pred RRT Actual RRT 1.1758 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 0.8561 0.8662 0.8740 1.0008 1.0189 1.0373 0.8901 - Diff Secs -0.1 -1.1 +0.3 -0.1 +1.2 -1.7 -0.2 Page 3 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.93E+04 7.98E+04 5.94E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 9.12E+04 0.00E+00 0.00E+00 4.16E+04 0.00E+00 6.73E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 9.11E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 0.77 0.85 1.05 0.78 1.10 0.84 0.79 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.93 1.25 1.27 1.28 1.26 1.34 1.26 1.28 1.20 1.32 1.36 1.22 1.19 1.08 1.35 0.92 0.84 0.90 0.74 0.90 1.19 0.75 1.10 0.90 0.96 1.25 0.82 0.76 0.92 1.33 1.26 1.35 1.22 1.27 1.33 1.40 1.25 1.18 1.18 1.17 1.20 1.38 1.37 1.15 1.43 1.18 0.93 0.79 ND ND ND ND ND 1.96 2.82 2.06 ND ND ND ND ND ND ND ND ND ND ND 5.34 ND ND 2 ND 3.67 ND ND ND ND ND ND ND ND ND ND ND 3.84 ND ND ND ND ND ND ND ND ND ND ND 5.40E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 4.72E+03 2.25E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 2.53E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 3.68E+03 1.57E+03 1.57E+03 1.94E+03 1.94E+03 1.52 1.64 1.62 1.6 1.62 1.52 1.63 1.59 1.7 1.55 1.51 1.68 1.72 1.9 0.971 1.51 1.66 1.55 1.89 1.55 1.16 1.84 1.27 1.54 1.44 1.11 1.7 1.82 1.52 1.05 1.6 1.5 1.66 1.58 1.52 1.44 1.62 1.71 1.71 1.73 1.68 1.47 1.47 1.76 0.755 0.915 1.29 1.52 Printed: 4/4/2014 10:17 AM 42 of 562 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.96 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.50 NotFnd 31.00 NotFnd 31.47 NotFnd NotFnd 32.20 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 33.00 NotFnd NotFnd 33.78 NotFnd NotFnd NotFnd NotFnd NotFnd 34.84 NotFnd NotFnd NotFnd NotFnd 36.34 SGS Evironmental Services QC J C J EMPC C J EMPC J EMPC C C J C J C J C C J EMPC J EMPC C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9174 1.0007 1.0171 1.0325 1.0563 1.0887 1.1144 1.1495 0.9723 -0.3 +1.5 -0.4 +0.9 +0.4 +0.2 +0.6 +0.2 -1.1 Page 4 of 5 Response Ra RRF Conc. / Recv. 6.08E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.61E+04 0.00E+00 2.47E+04 0.00E+00 4.31E+04 0.00E+00 0.00E+00 9.40E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.54E+04 0.00E+00 0.00E+00 4.59E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.31E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.70E+04 0.65 0.86 0.86 1.00 0.74 0.78 0.92 0.71 0.76 1.20 0.81 0.96 0.70 0.90 1.17 0.98 1.18 0.88 1.10 1.16 0.69 1.21 1.22 1.11 1.24 1.11 1.03 1.12 1.26 1.14 1.15 1.06 1.09 1.15 1.09 1.29 1.14 1.11 0.93 1.02 1.13 0.98 0.95 0.99 1.05 1.35 1.15 1.47 1.42 4.27 ND ND ND ND ND ND ND ND ND 4.17 ND 1.67 ND 2.67 ND ND 5.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 ND ND 3.55 ND ND ND ND ND 2.01 ND ND ND ND 2.85 0.51 0.81 0.72 0.55 1.32 1.24 0.95 1.44 Noise / Recv. Low DL / Recv. High 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.94E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.39 1.4 1.2 1.63 1.55 1.31 1.68 1.58 1 1.48 1.25 1.73 1.34 1.03 1.23 1.02 1.37 1.1 1.04 1.75 0.996 0.982 1.09 0.97 1.08 1.16 1.05 0.61 0.675 0.665 0.726 0.703 1.02 1.07 0.913 1.03 1.05 1.26 1.15 1.04 1.2 1.24 1.19 1.12 0.867 1.02 0.796 0.829 Printed: 4/4/2014 10:17 AM 43 of 562 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB NotFnd NotFnd NotFnd NotFnd 37.40 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J C C C C C Pred RRT Actual RRT 0.9766 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 1.0007 - Diff Secs -0.9 Page 5 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.94E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.41 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.04 0.92 1.11 1.43 1.15 1.39 1.53 0.90 1.10 1.10 1.27 1.13 1.06 1.15 1.07 0.77 1.07 1.15 1.18 1.20 1.10 0.94 0.92 1.07 0.94 0.98 1.29 1.24 1.38 1.13 1.60 1.05 1.14 1.07 1.10 1.08 0.74 0.80 0.83 0.72 0.81 1.06 1.12 1.18 1.11 ND ND ND ND 2.96 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.36E+03 1.66E+03 1.66E+03 1.66E+03 1.32E+03 1.32E+03 1.32E+03 1.32E+03 1.32E+03 1.32E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.56E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.44E+03 1.44E+03 1.44E+03 3.21E+03 3.21E+03 3.21E+03 1.13 1.28 1.05 0.822 1.02 0.845 0.765 1.17 0.956 0.954 0.882 0.994 1.06 0.978 1.05 1.45 1.4 1.31 1.28 1.26 1.36 1.6 1.63 1.4 1.6 1.54 1.17 1.21 1.09 1.52 1.08 1.24 1.14 1.21 1.18 1.2 1.75 1.64 1.56 1.91 1.71 1.3 2.71 2.59 4.03 Printed: 4/4/2014 10:17 AM 44 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.00e7 2.00e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 8.56e6 4.28e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 7.56e6 3.78e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.11 330.9792 Fn4 Flags: 0% Abs. Int. 1.37e7 6.85e6 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 Rel. Int. QC chk 100% 38.13-45.15 380.9760 Fn5 Flags: 0% Abs. Int. 8.27e6 4.14e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.17-50.16 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.51e6 7.54e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.42e6 7.09e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 scc: 680-324 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 04-Apr-2014 10:18 Page 1 of 21 45 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 PCB-3 3.41e4 SI 14.18 PCB-1 1.96e4 SI 11.89 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.91e3 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Abs. Int. 1.35e4 6.73e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.96e3 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 2.32e3 4.48e3 0% 11.0 12.0 13.0 ES-1 3.83e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 4.04e7 14.16 0.00e0 16.0 RT Abs. Int. 1.46e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 4.33e3 7.29e6 0% 11.0 12.0 13.0 ES-1 1.19e7 11.88 Rel. Int. 100% 14.0 15.0 ES-3 1.23e7 14.16 0.00e0 16.0 RT Abs. Int. 4.68e6 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.24e4 2.34e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.00e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.00e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0728, 9520 scc: 680-324 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 10:18 Page 2 of 21 46 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 6.86e3 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 3.24e3 3.43e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.05e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 9.14e3 1.02e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.88e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.48e6 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.58e3 3.24e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.17e7 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.04e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.94e3 2.02e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.00e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.00e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 6488, 6296 scc: 680-324 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:12 (DES) Printed: 04-Apr-2014 10:18 Page 3 of 21 47 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 PCB-11 1.73e5 19.56 Rel. Int. 100% Abs. Int. 5.45e4 DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 4.05e3 2.72e4 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 21.0 Abs. Int. 6.77e4 PCB-11 1.12e5 19.55 DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 9.06e3 3.39e4 0% 17.0 Rel. Int. 100% DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 2.57e4 18.0 19.0 20.0 21.0 ES-15 3.73e7 20.12 JS-9 2.69e7 16.39 5.22e6 17.0 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 5.42e3 0.00e0 RT Abs. Int. 1.04e7 0% Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 21.0 ES-15 2.36e7 20.11 JS-9 1.71e7 16.39 0.00e0 RT Abs. Int. 6.61e6 3.30e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.56e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.28e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8456, 5195 scc: 680-324 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:15 (DES) Printed: 04-Apr-2014 10:18 Page 4 of 21 48 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 1.70e4 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: B 4σ 3.02e3 8.49e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e4 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PB 4σ 2.38e3 5.72e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 3.77e4 ES-19 1.56e7 17.49 6.09e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 1.46e7 17.49 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.46e6 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.36e4 2.23e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.56e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.28e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 4780, 6276 scc: 680-324 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:15 (DES) Printed: 04-Apr-2014 10:18 Page 5 of 21 49 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 PCB-31 3.03e4 22.63 TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 2.66e3 28/20 4.07e4 22.90 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Abs. Int. 1.34e4 21/33 3.04e4 23.10 6.70e3 0% 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 28/20 4.76e4 22.90 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 2.06e3 PCB-31 3.94e4 22.62 Abs. Int. 1.75e4 21/33 2.90e4 23.12 8.76e3 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 2.83e7 22.88 Rel. Int. 100% ES-37 2.35e7 26.43 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.61e4 Abs. Int. 7.82e6 3.91e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 2.64e7 22.88 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 2.16e7 26.43 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 1.99e4 Abs. Int. 7.24e6 3.62e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.56e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.78e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8901, 6703 scc: 680-324 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 10:18 Page 6 of 21 50 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 3.72e3 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PB 4σ 7.35e2 1.86e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.20e3 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PB 4σ 1.51e3 1.60e3 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.32e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.73e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 3.08e3 1.87e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 1.70e7 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.89e6 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 2.48e3 2.44e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.56e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 4.28e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 5195, 2420 scc: 680-324 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 10:45 (LKB) Printed: 04-Apr-2014 10:18 Page 7 of 21 51 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 PCB-52 3.99e4 24.52 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.07e3 69/49 2.56e4 24.96 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Abs. Int. 1.41e4 44/47… 3.07e4 25.41 7.04e3 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 Abs. Int. 1.61e4 PCB-52 5.13e4 24.52 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.46e3 69/49 2.34e4 24.96 44/47… 3.66e4 25.42 8.07e3 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 0.00e0 RT Abs. Int. 3.61e6 JS-52 1.07e7 24.50 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 8.35e3 0.00e0 RT 1.81e6 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 Abs. Int. 4.57e6 JS-52 1.31e7 24.50 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 5.11e3 0.00e0 RT 2.29e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.56e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.78e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0302, 3687 scc: 680-324 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 31-Mar-2014 08:10 (DES) Printed: 04-Apr-2014 10:18 Page 8 of 21 52 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 61/70... 4.03e4 28.73 Rel. Int. 100% Abs. Int. 8.22e3 TeCB-4 26.97-38.11 289.9224 Fn4 Flags: PBM 4σ 1.40e3 4.11e3 0% 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 61/70... 5.08e4 28.73 Rel. Int. 100% Abs. Int. 1.08e4 TeCB-4 26.97-38.11 291.9194 Fn4 Flags: PBM 4σ 2.28e3 5.38e3 0.00e0 38.0 RT 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.68e7 32.28 TeCB Std. 26.97-38.11 301.9626 Fn4 Flags: PBM 4σ 9.96e3 34.0 ES-77 1.76e7 32.76 36.0 Abs. Int. 4.35e6 (1.76e7 + 2.18e7) * 2000 pg * 100 % (1.07e7 + 1.31e7) * 2000 pg * 1.38 DES 31-Mar-2014 08:28 Recv(ES-77) = 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 2.13e7 32.28 TeCB Std. 26.97-38.11 303.9597 Fn4 Flags: PBM 4σ 5.56e3 34.0 36.0 = 120 % 2.18e6 0.00e0 38.0 RT Abs. Int. 5.38e6 ES-77 2.18e7 32.76 2.69e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.37e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.85e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8235, 3393 scc: 680-324 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:17 (DES) Printed: 04-Apr-2014 10:18 Page 9 of 21 53 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 2.34e3 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PB 4σ 5.50e2 1.17e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.94e3 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PB 4σ 1.02e3 9.69e2 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.68e7 25.37 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.46e6 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 1.66e3 2.23e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.05e7 25.36 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.76e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.16e3 1.38e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.56e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.78e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8097, 5836 scc: 680-324 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:50 Printed: 04-Apr-2014 10:18 Page 10 of 21 54 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.97-38.11 323.8834 Fn4 Flags: PBM 4σ 8.11e2 PCB-95 2.39e4 27.96 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 113/90… 2.53e4 30.50 PCB-110 3.32e4 32.20 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Abs. Int. 1.07e4 PCB-118 2.27e4 34.75 PCB-99108/119... 1.23e4 1.93e4 31.00 31.47 < S/N 0% 28.0 Rel. Int. 100% PeCB-4 26.97-38.11 325.8804 Fn4 Flags: PBM 4σ 1.13e3 PCB-95 3.69e4 27.97 30.0 32.0 113/90… 5.01e4 30.50 34.0 36.0 30.0 PCB-118 3.47e4 34.75 108/119... PCB-99 2.66e4 1.52e4 31.47 31.01 8.77e3 32.0 34.0 CS/SS-111 2.23e7 32.77 Rel. Int. 100% JS-101 1.31e7 30.48 PeCB Std. 26.97-38.11 337.9207 Fn4 Flags: PBM 4σ 1.50e3 0.00e0 38.0 RT Abs. Int. 1.75e4 PCB-110 6.08e4 32.20 0% 28.0 5.33e3 ES-123 2.02e7 34.45 36.0 ES-118 ES-114 2.02e7 2.05e7 34.73 35.19 ES-105 2.03e7 35.74 0.00e0 38.0 RT Abs. Int. 5.52e6 2.76e6 0% 28.0 30.0 32.0 34.0 CS/SS-111 1.40e7 32.77 Rel. Int. 100% JS-101 8.32e6 30.48 PeCB Std. 26.97-38.11 339.9177 Fn4 Flags: PBM 4σ 2.81e3 ES-123 1.28e7 34.45 36.0 ES-118 ES-114 1.29e7 1.29e7 34.73 35.19 ES-105 1.27e7 35.74 0.00e0 38.0 RT Abs. Int. 3.44e6 1.72e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.37e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.85e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 2804, 0009 scc: 680-324 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:17 (DES) Printed: 04-Apr-2014 10:18 Page 11 of 21 55 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 9.31e3 PeCB-5 38.13-45.15 323.8834 Fn5 Flags: PB 4σ 9.16e2 4.65e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 2.03e4 PeCB-5 38.13-45.15 325.8804 Fn5 Flags: PB 4σ 1.13e3 1.02e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 4.14e6 ES-126 1.76e7 38.35 PeCB Std. 38.13-45.15 337.9207 Fn5 Flags: PBM 4σ 4.68e3 2.07e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.81e6 ES-126 1.14e7 38.35 PeCB Std. 38.13-45.15 339.9177 Fn5 Flags: PBM 4σ 3.40e3 1.40e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.27e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 7736, 4844 scc: 680-324 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:12 (DES) Printed: 04-Apr-2014 10:18 Page 12 of 21 56 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Rel. Int. 100% Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 153/168 3.00e4 36.34 147/149 2.55e4 33.78 HxCB-4 26.97-38.11 359.8415 Fn4 Flags: PBM 4σ 5.53e2 151/135 1.44e4 33.00 163/138… 2.31e4 37.40 PCB-132 1.29e4 34.84 3.74e3 0% 28.0 30.0 32.0 34.0 HxCB-4 26.97-38.11 361.8385 Fn4 Flags: PBM 4σ 8.06e2 153/168 2.09e4 36.33 PCB-132 1.36e4 34.84 151/135 1.10e4 32.99 0.00e0 38.0 RT 36.0 147/149 2.05e4 33.77 Rel. Int. 100% 163/138… 1.63e4 37.40 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 ES-155 1.87e7 30.31 Rel. Int. 100% ES-153 1.32e7 36.31 HxCB Std. 26.97-38.11 371.8817 Fn4 Flags: PBM 4σ 1.42e3 Abs. Int. 4.97e6 JS-138 9.54e6 37.37 0% 28.0 30.0 32.0 34.0 ES-153 1.00e7 36.31 HxCB Std. 26.97-38.11 373.8788 Fn4 Flags: PBM 4σ 1.70e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 2.48e6 0.00e0 38.0 RT 36.0 ES-155 1.46e7 30.31 Rel. Int. 100% Abs. Int. 6.10e3 3.05e3 0% 28.0 Abs. Int. 7.47e3 Abs. Int. 3.78e6 JS-138 7.21e6 37.37 1.89e6 0.00e0 38.0 RT Abs. Int. 1.37e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.85e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 6009, 0529 scc: 680-324 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:18 (DES) Printed: 04-Apr-2014 10:18 Page 13 of 21 57 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 2.47e3 HxCB-5 38.13-45.15 359.8415 Fn5 Flags: PB 4σ 8.20e2 1.23e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.35e3 HxCB-5 38.13-45.15 361.8385 Fn5 Flags: PB 4σ 8.35e2 2.18e3 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.74e7 39.91 HxCB Std. 38.13-45.15 371.8817 Fn5 Flags: PBM 4σ 2.85e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 3.19e7 40.89 0.00e0 RT Abs. Int. 5.79e6 ES-169 1.58e7 43.60 2.89e6 0% 39.0 Rel. Int. 100% 40.0 ES-167 1.35e7 39.91 HxCB Std. 38.13-45.15 373.8788 Fn5 Flags: PBM 4σ 5.17e3 41.0 42.0 43.0 44.0 45.0 ES-156/157 2.54e7 40.89 0.00e0 RT Abs. Int. 4.52e6 ES-169 1.24e7 43.61 2.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.27e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0486, 5817 scc: 680-324 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 10:18 Page 14 of 21 58 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 3.25e3 HpCB-4 30.00-38.11 393.8025 Fn4 Flags: PB 4σ 7.15e2 1.63e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.42e3 HpCB-4 30.00-38.11 395.7995 Fn4 Flags: PB 4σ 6.03e2 1.21e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.21e7 35.19 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.03e6 CS/SS-178 8.34e6 37.75 HpCB Std. 30.00-38.11 405.8428 Fn4 Flags: PBM 4σ 1.47e3 1.51e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 1.14e7 35.19 Rel. Int. 100% Abs. Int. 2.92e6 CS/SS-178 7.38e6 37.75 HpCB Std. 30.00-38.11 407.8398 Fn4 Flags: PBM 4σ 1.50e3 1.46e6 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e7 QC Check 30.00-38.11 330.9792 Fn4 Flags: - 6.85e6 0% 31.0 32.0 33.0 34.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 9967, 5748 scc: 680-324 35.0 36.0 37.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:50 Printed: 04-Apr-2014 10:18 Page 15 of 21 59 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 3.78e3 HpCB-5 38.13-45.15 393.8025 Fn5 Flags: B 4σ 7.66e2 1.89e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e3 HpCB-5 38.13-45.15 395.7995 Fn5 Flags: B 4σ 7.96e2 1.29e3 0% 39.0 40.0 41.0 42.0 ES-180 1.11e7 42.05 Rel. Int. 100% 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.70e6 ES-170 9.49e6 43.12 HpCB-5 Std. 38.13-45.15 405.8428 Fn5 Flags: PBM 4σ 1.73e3 1.35e6 0% 39.0 40.0 41.0 42.0 ES-180 1.03e7 42.05 Rel. Int. 100% HpCB-5 Std. 38.13-45.15 407.8398 Fn5 Flags: PBM 4σ 3.53e3 43.0 44.0 45.0 0.00e0 RT Abs. Int. 2.58e6 ES-170 8.93e6 43.12 1.29e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.27e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3561, 9416 scc: 680-324 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 10:18 Page 16 of 21 60 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 1.88e3 HpCB-6 45.17-50.16 393.8025 Fn6 Flags: PB 4σ 7.47e2 9.38e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 2.19e3 HpCB-6 45.17-50.16 395.7995 Fn6 Flags: PB 4σ 7.34e2 1.10e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 1.41e7 45.73 0.00e0 RT Abs. Int. 3.40e6 HpCB Std. 45.17-50.16 405.8428 Fn6 Flags: PBM 4σ 3.24e3 1.70e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 1.38e7 45.73 0.00e0 RT Abs. Int. 3.17e6 HpCB Std. 45.17-50.16 407.8398 Fn6 Flags: PBM 4σ 2.58e3 1.58e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 7.54e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 9327, 3854 scc: 680-324 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:50 Printed: 04-Apr-2014 10:18 Page 17 of 21 61 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 2.37e3 OcCB-5 38.13-45.15 427.7635 Fn5 Flags: PB 4σ 7.31e2 1.19e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.67e3 OcCB-5 38.13-45.15 429.7606 Fn5 Flags: PB 4σ 7.33e2 1.34e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.08e7 39.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.71e6 OcCB Std. 38.13-45.15 439.8038 Fn5 Flags: PBM 4σ 1.59e3 1.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 1.16e7 39.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e6 OcCB Std. 38.13-45.15 441.8008 Fn5 Flags: PBM 4σ 1.43e3 1.43e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.27e6 QC Check 38.13-45.15 380.9760 Fn5 Flags: - 4.14e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 3916, 9274 scc: 680-324 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 10:50 Printed: 04-Apr-2014 10:18 Page 18 of 21 62 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 1.74e3 OcCB-6 45.17-50.16 427.7635 Fn6 Flags: PB 4σ 6.95e2 8.72e2 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.82e3 OcCB-6 45.17-50.16 429.7606 Fn6 Flags: PB 4σ 7.43e2 9.10e2 0% 46.0 47.0 48.0 49.0 50.0 ES-205 9.95e6 47.89 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.45e6 JS-194 6.70e6 47.49 OcCB Std. 45.17-50.16 439.8038 Fn6 Flags: PBM 4σ 1.82e3 1.22e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 1.12e7 47.89 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e6 JS-194 7.33e6 47.49 OcCB Std. 45.17-50.16 441.8008 Fn6 Flags: PBM 4σ 2.74e3 1.39e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 7.54e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 7110, 1117 scc: 680-324 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:14 (DES) Printed: 04-Apr-2014 10:18 Page 19 of 21 63 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 2.23e3 NoCB 45.17-50.16 461.7245 Fn6 Flags: PB 4σ 1.17e3 1.12e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% Abs. Int. 4.73e3 NoCB 45.17-50.16 463.7216 Fn6 Flags: PB 4σ 2.05e3 2.36e3 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 1.02e7 45.34 50.0 0.00e0 RT Abs. Int. 2.34e6 ES-206 6.91e6 49.35 NoCB Std. 45.17-50.16 473.7648 Fn6 Flags: PBM 4σ 2.10e3 1.17e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 1.28e7 45.34 50.0 Abs. Int. 3.00e6 ES-206 8.53e6 49.35 NoCB Std. 45.17-50.16 475.7619 Fn6 Flags: PBM 4σ 1.52e3 0.00e0 RT 1.50e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e6 QC Check 45.17-50.16 454.9728 Fn6 Flags: - 7.54e5 0% 46.0 47.0 48.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 8295, 6602 scc: 680-324 49.0 50.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 13:18 Printed: 04-Apr-2014 10:18 Page 20 of 21 64 of 562 SGS ID: MB1_11903_PCB_TLX-RJ2 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 77 Acq: 28-Mar-2014 19:45:47 User: LKB Datafile: 140328X10 Rel. Int. 100% Abs. Int. 3.17e3 DeCB 50.17-52.00 497.6826 Fn7 Flags: B 4σ 5.60e2 1.58e3 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.89e3 DeCB 50.17-52.00 499.6797 Fn7 Flags: B 4σ 6.91e2 9.46e2 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.09e7 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.34e6 DeCB Std. 50.17-52.00 509.7229 Fn7 Flags: PBM 4σ 9.64e2 1.17e6 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 9.06e6 50.78 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.99e6 DeCB Std. 50.17-52.00 511.7199 Fn7 Flags: PBM 4σ 9.55e2 9.95e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.42e6 QC Check 50.17-52.00 454.9728 Fn7 Flags: - 7.09e5 0% 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\MB1_11903_PCB_TLX-RJ2.utp_res, saved 31-Mar-2014 08:29 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 1312, 9304 scc: 680-324 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 13:14 (DES) Printed: 04-Apr-2014 10:18 Page 21 of 21 65 of 562 Lab ID: A6521_11903_PCB_001-RJ ACQ: 28-Mar-2014 21:35:52 LKB Wt/Vol: 1.19 L Client ID: PB083-1SWMID-140318-N UTP: 31-Mar-2014 08:14 DES J-level: 8.38 pg/L Datafile: 140328X12 RPT: 04-Apr-2014 10:12 ds Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.76 32.29 35.75 35.20 34.74 34.46 38.35 40.89 39.92 NotFnd 45.75 50.80 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.86 14.15 14.40 20.10 17.47 26.42 20.38 32.75 32.27 25.35 35.73 35.18 34.72 34.44 38.34 36.30 30.30 40.88 39.90 43.60 43.11 42.04 35.18 45.72 39.71 47.88 49.34 45.34 50.77 QC J J J J J C J J Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0006 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 1.0006 1.0007 1.0006 1.0005 1.0006 1.0007 1.0003 1.0002 1.0005 1.0005 1.0004 0 +0.4 0 -0.4 0 +0.2 -0.5 -0.7 -0.2 0.7245 0.8640 0.8795 1.2271 1.0673 1.0787 0.8328 1.3364 1.3170 0.8325 1.1720 1.1543 1.1391 1.1299 1.2575 0.9716 0.8114 1.0939 1.0677 1.1664 0.9081 0.8856 0.7413 0.9629 0.8366 1.0084 1.0392 0.9549 1.0694 0.7245 0.8640 0.8794 1.2277 1.0673 1.0791 0.8325 1.3374 1.3179 0.8321 1.1725 1.1548 1.1395 1.1303 1.2582 0.9716 0.8110 1.0942 1.0678 1.1668 0.9079 0.8855 0.7408 0.9629 0.8364 1.0084 1.0392 0.9548 1.0693 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140328_PCB_XB Split: 1 Checkcode: 761-512-TRG Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.81 0.75 0.61 0.69 0.62 0.69 0.65 1.15 1.33 +0.3 0 2.46E+06 1.19E+05 5.79E+06 3.73E+05 1.09E+07 3.05E+05 6.23E+04 5.66E+05 1.83E+05 0.00E+00 2.89E+04 1.23E+06 0.89 1.19 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 35.4 1.82 99.3 6.19 182 5.04 1.23 11.4 3.4 ND 0.645 42.6 5.32E+03 5.32E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 3.11E+03 2.07E+03 2.07E+03 2.07E+03 1.67E+03 1.25E+03 0.797 0.825 0.508 0.482 0.5 0.487 0.627 0.571 0.391 0.434 0.39 0.499 0 0 -0.1 +0.7 0 +0.6 -0.4 +2.0 +1.7 -0.6 +1.1 +1.1 +0.8 +0.8 +1.6 0 -0.7 +0.7 +0.2 +1.0 -0.5 -0.3 -1.1 0 -0.5 0 0 -0.3 -0.3 1.23E+08 1.28E+08 7.56E+07 1.58E+08 7.68E+07 1.16E+08 7.61E+07 1.01E+08 9.80E+07 6.51E+07 8.78E+07 8.39E+07 8.42E+07 8.37E+07 7.65E+07 5.84E+07 7.87E+07 1.52E+08 7.75E+07 7.36E+07 4.69E+07 5.53E+07 5.58E+07 6.99E+07 5.56E+07 5.11E+07 3.57E+07 5.43E+07 4.36E+07 3.25 3.28 1.62 1.56 1.05 1.09 0.78 0.80 0.79 1.61 1.59 1.61 1.60 1.57 1.54 1.26 1.27 1.27 1.22 1.24 1.09 1.04 1.06 1.03 0.91 0.89 0.80 0.80 1.18 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 64.3 % 73.1 % 89.9 % 94.2 % 94.3 % 83.7 % 106 % 87.6 % 85.6 % 107 % 96.5 % 91 % 96 % 93.2 % 98.2 % 87.5 % 83.7 % 80.2 % 78.5 % 79.9 % 96.8 % 97.7 % 100 % 95.1 % 96.8 % 88.4 % 92.6 % 99.4 % 84.6 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Page 1 of 5 Printed: 4/4/2014 10:17 AM 66 of 562 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.86 32.76 37.74 0.9339 1.0750 1.0100 0.9339 1.0752 1.0101 0 +0.4 +0.2 1.41E+08 9.38E+07 4.08E+07 1.08 1.57 1.04 1.11 1.03 0.62 109 % 109 % 118 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.86 32.76 37.74 0.9339 1.0750 1.0100 0.9339 1.0752 1.0101 0 +0.4 +0.2 1.41E+08 9.38E+07 4.08E+07 1.08 1.57 1.04 1.85 1.22 0.58 91 % 101 % 119 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.37 24.48 30.47 37.36 47.48 1.61E+08 8.37E+07 7.57E+07 5.92E+07 4.65E+07 1.56 0.79 1.62 1.25 0.89 5.65E+03 5.65E+03 5.65E+03 6.70E+03 6.70E+03 5.22E+03 5.22E+03 5.22E+03 5.22E+03 5.22E+03 5.22E+03 5.22E+03 5.22E+03 5.22E+03 4.76E+03 4.76E+03 4.76E+03 4.76E+03 4.76E+03 4.76E+03 0.513 0.471 0.544 0.907 0.581 0.535 0.471 0.504 0.501 0.499 0.421 0.488 0.49 0.508 0.777 0.571 0.67 0.49 0.513 0.901 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.88 13.98 14.16 14.41 14.59 16.39 16.56 16.78 17.08 17.20 NotFnd 19.54 19.81 20.11 17.49 19.26 19.65 19.84 19.97 20.07 J J B J J J J B J C C J 1.0011 0.9880 1.0010 1.0011 1.0135 1.0010 1.0111 1.0249 1.0433 1.0506 0.9334 0.9721 0.9866 1.0008 1.0010 1.1014 1.1243 1.1353 1.1430 1.1484 1.0011 0.9880 1.0009 1.0011 1.0136 1.0010 1.0112 1.0250 1.0435 1.0508 0.9721 0.9855 1.0007 1.0010 1.1020 1.1245 1.1356 1.1428 1.1487 0 0 -0.1 0 +0.1 0 +0.1 +0.1 +0.2 +0.2 0 -1.3 -0.1 0 +0.7 +0.2 +0.4 -0.2 +0.4 Page 2 of 5 NON-EMPC 30.8 406 2,570 4,970 1,820 435 110 27.9 6.4 1.61E+06 1.87E+05 4.38E+05 8.41E+06 3.85E+05 6.38E+05 3.69E+05 4.54E+06 1.96E+05 9.88E+06 0.00E+00 2.27E+06 1.51E+06 4.94E+06 4.19E+06 3.64E+07 1.10E+07 2.59E+06 2.72E+05 7.80E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 30.8 406 2,570 4,970 1,820 436 122 31 7.87 3.09 3.00 3.16 1.58 1.72 1.55 1.48 1.65 1.50 1.66 1.64 1.61 1.62 1.08 1.06 1.06 1.06 1.09 1.06 0.95 1.17 1.01 1.23 1.92 0.97 1.10 1.03 1.03 1.04 1.23 1.06 1.06 1.02 1.15 1.56 1.33 1.82 1.74 0.99 DL 0.528 0.708 0.929 0.58 0.481 0.408 0.465 0.423 1.22 23 2.1 5.7 151 4.44 7.02 3.57 47 2.02 101 ND 22.7 15.2 51.5 79.7 510 180 31.1 3.43 172 Printed: 4/4/2014 10:17 AM 67 of 562 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.55 21.70 NotFnd 22.11 22.33 22.61 22.89 23.10 23.45 NotFnd 25.20 NotFnd 26.08 26.44 20.40 22.36 22.97 23.05 23.25 24.51 24.63 24.73 24.95 25.21 25.40 25.69 25.87 26.20 26.30 26.50 27.21 27.47 27.84 28.05 28.20 28.43 28.73 29.00 29.15 29.58 29.77 NotFnd 31.48 NotFnd NotFnd 25.69 27.38 27.57 SGS Evironmental Services QC J C C C J J J C J C C C C J J J C J J J J Pred RRT Actual RRT Diff Secs 1.1758 0.8218 0.8275 0.8383 0.8456 0.8562 0.8670 0.8738 0.8880 0.9401 0.9522 0.9723 0.9871 1.0007 1.0010 0.9145 0.9383 0.9413 0.9499 1.0009 1.0062 1.0101 1.0181 1.0295 1.0384 1.0496 1.0563 1.0698 1.0737 1.0819 0.8436 0.8515 0.8630 0.8693 0.8741 0.8811 0.8902 0.8989 0.9034 0.9169 0.9229 0.9329 0.9737 0.9889 1.0009 1.0134 0.8989 0.9051 1.1762 0.8214 0.8370 0.8453 0.8559 0.8662 0.8743 0.8877 0.9539 0.9869 1.0009 1.0009 0.9133 0.9383 0.9413 0.9498 1.0009 1.0058 1.0101 1.0189 1.0296 1.0375 1.0493 1.0565 1.0701 1.0741 1.0821 0.8433 0.8512 0.8628 0.8692 0.8739 0.8809 0.8902 0.8986 0.9035 0.9167 0.9227 0.9754 1.0135 0.8986 0.9049 +0.5 -0.5 -1.7 -0.4 -0.4 -1.1 +0.7 -0.4 +2.6 -0.3 +0.3 -0.1 -1.6 0 0 -0.1 0 -0.6 0 +1.2 +0.2 -1.4 -0.5 +0.3 +0.5 +0.6 +0.3 -0.5 -0.5 -0.3 -0.2 -0.3 -0.3 0 -0.5 +0.2 -0.4 -0.4 +3.2 +0.2 -0.5 -0.3 Page 3 of 5 Response Ra RRF Conc. / Recv. 1.50E+07 2.10E+05 0.00E+00 8.03E+06 5.51E+06 4.32E+07 4.02E+07 1.16E+07 1.09E+07 0.00E+00 3.59E+05 0.00E+00 6.10E+05 5.50E+06 1.73E+05 8.28E+06 6.33E+06 3.71E+06 2.46E+06 4.35E+07 1.11E+05 1.25E+06 2.61E+07 6.62E+06 3.95E+07 3.60E+06 8.53E+06 2.33E+06 1.67E+07 2.05E+07 2.32E+05 2.02E+06 1.76E+05 6.88E+04 8.24E+05 1.33E+06 5.29E+07 3.12E+07 3.06E+05 1.54E+07 6.79E+06 0.00E+00 6.82E+05 0.00E+00 0.00E+00 3.34E+05 1.24E+05 1.31E+05 1.06 0.94 1.93 1.25 1.27 1.28 1.26 1.34 1.26 1.28 1.20 1.32 1.36 1.22 1.19 1.08 1.35 0.92 0.84 0.90 0.74 0.90 1.19 0.75 1.10 0.90 0.96 1.25 0.82 0.76 0.92 1.33 1.26 1.35 1.22 1.27 1.33 1.40 1.25 1.18 1.18 1.17 1.20 1.38 1.37 1.15 1.43 1.18 0.93 0.79 170 2.42 ND 90.3 62.9 463 461 130 131 ND 3.81 ND 7.39 73.5 2.83 154 129 70.9 57.3 829 1.59 28.3 408 125 702 49.3 178 52.3 312 264 3.15 25.6 2.47 0.923 10.6 16.3 726 453 4.43 225 96.8 ND 8.5 ND ND 7.27 2.67 3.32 1.00 1.04 1.02 1.02 1.01 1.00 1.01 1.10 1.02 0.83 0.79 0.78 0.79 0.78 0.78 0.77 0.76 0.79 0.79 0.79 0.78 0.79 0.77 0.78 0.78 0.85 0.78 0.77 0.87 0.82 0.81 0.80 0.79 0.81 0.79 0.80 0.81 0.63 0.66 0.57 Noise / Recv. Low DL / Recv. High 4.76E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 8.11E+03 2.05E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 2.56E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 5.32E+03 1.61E+03 1.61E+03 2.93E+03 2.93E+03 0.461 0.935 0.923 0.911 0.925 0.869 0.93 0.91 0.973 0.885 0.86 0.957 0.982 1.08 0.301 0.482 0.53 0.497 0.604 0.495 0.372 0.589 0.406 0.492 0.461 0.355 0.543 0.583 0.486 0.335 0.73 0.683 0.757 0.724 0.696 0.66 0.74 0.783 0.781 0.791 0.768 0.67 0.672 0.805 0.282 0.341 0.632 0.747 Printed: 4/4/2014 10:17 AM 68 of 562 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.95 28.17 28.27 28.35 NotFnd 28.71 28.91 29.32 NotFnd 29.98 30.49 30.89 31.00 31.11 31.47 31.98 32.06 32.19 32.28 32.47 NotFnd 33.17 34.15 34.36 34.55 35.03 NotFnd 30.32 NotFnd NotFnd 30.93 NotFnd NotFnd 32.99 33.20 33.47 33.76 33.94 34.03 34.28 34.46 NotFnd 34.84 35.25 NotFnd 35.80 NotFnd 36.32 SGS Evironmental Services QC J C J C J C C J J EMPC J C J J J EMPC C J J C J J J C J J C Pred RRT Actual RRT Diff Secs 0.9176 0.9246 0.9282 0.9305 0.9403 0.9424 0.9487 0.9624 0.9736 0.9841 0.9999 1.0142 1.0173 1.0206 1.0320 1.0495 1.0525 1.0561 1.0590 1.0655 1.0757 1.0887 0.9916 0.9976 1.0038 1.0091 1.0350 1.0007 1.0060 1.0107 1.0207 1.0296 1.0714 1.0886 1.0954 1.1041 1.1141 1.1199 1.1225 1.1312 1.1369 1.1416 1.1494 1.1626 0.9525 0.9582 0.9613 0.9728 0.9174 0.9244 0.9280 0.9305 0.9423 0.9487 0.9624 0.9840 1.0007 1.0139 1.0173 1.0211 1.0330 1.0497 1.0523 1.0564 1.0594 1.0657 1.0887 0.9917 0.9977 1.0033 1.0091 1.0006 1.0208 1.0887 1.0957 1.1044 1.1143 1.1202 1.1232 1.1314 1.1372 1.1499 1.1634 0.9580 0.9722 -0.3 -0.3 -0.3 0 -0.2 0 0 -0.2 +1.5 -0.6 0 +0.9 +1.9 +0.4 -0.4 +0.6 +0.8 +0.4 0 +0.2 +0.2 -1.0 0 -0.2 +0.2 +0.2 +0.6 +0.6 +0.4 +0.6 +1.4 +0.4 +0.6 +1.0 +1.7 -0.4 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 9.33E+06 2.21E+05 7.59E+05 3.59E+04 0.00E+00 2.42E+06 3.68E+06 4.01E+05 0.00E+00 1.83E+06 1.10E+07 5.24E+05 6.56E+06 6.24E+04 1.01E+07 5.26E+05 3.00E+06 1.60E+07 4.40E+05 1.80E+06 0.00E+00 4.16E+04 4.74E+05 9.71E+05 6.53E+04 2.37E+05 0.00E+00 1.95E+04 0.00E+00 0.00E+00 6.93E+05 0.00E+00 0.00E+00 1.07E+06 4.93E+04 1.67E+05 2.76E+06 2.08E+05 2.55E+04 9.33E+04 6.25E+04 0.00E+00 1.28E+06 5.22E+04 0.00E+00 5.52E+05 0.00E+00 3.42E+06 0.62 0.64 0.57 0.56 0.86 0.86 1.00 0.74 0.78 0.92 0.71 0.76 1.20 0.81 0.96 0.70 0.90 1.17 0.98 1.18 0.88 1.10 1.16 0.69 1.21 1.22 1.11 1.24 1.11 1.03 1.12 1.26 1.14 1.15 1.06 1.09 1.15 1.09 1.29 1.14 1.11 0.93 1.02 1.13 0.98 0.95 0.99 1.05 1.35 1.15 1.47 1.42 217 5.16 15.2 0.974 ND 52.7 103 10.6 ND 45.1 230 15.1 146 1.07 207 8.96 68.5 292 7.61 52.4 ND 0.681 8.58 15.7 1.18 4.58 ND 0.329 ND ND 14 ND ND 28.2 1.1 4.2 71 6.39 0.717 2.37 1.84 ND 37.2 1.43 ND 13.8 ND 69.2 0.62 0.64 0.55 0.61 0.62 0.63 0.61 0.63 0.61 0.66 0.62 0.61 0.63 0.60 0.78 0.64 0.62 0.54 0.65 0.84 1.26 1.26 1.41 1.24 1.28 1.17 1.27 1.22 1.12 1.25 1.36 1.19 1.23 Noise / Recv. Low DL / Recv. High 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 0.684 0.687 0.589 0.8 0.759 0.641 0.826 0.777 0.493 0.727 0.614 0.846 0.657 0.505 0.604 0.501 0.674 0.538 0.51 0.857 0.489 0.482 0.532 0.476 0.532 0.561 0.507 0.237 0.263 0.259 0.282 0.273 0.356 0.374 0.318 0.359 0.367 0.438 0.4 0.361 0.419 0.431 0.413 0.39 0.302 0.356 0.277 0.289 Printed: 4/4/2014 10:17 AM 69 of 562 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.49 36.84 37.03 37.12 37.39 NotFnd 37.73 38.47 39.26 NotFnd NotFnd 35.48 NotFnd 36.24 NotFnd 37.76 38.32 38.53 NotFnd 39.05 39.13 39.25 39.63 NotFnd 40.17 41.50 NotFnd 42.06 42.36 43.13 43.58 39.74 40.52 NotFnd 41.29 41.38 43.71 44.27 44.44 45.56 47.50 NotFnd 45.36 46.14 49.37 SGS Evironmental Services QC J J J C J C J EMPC J J J J EMPC J J J EMPC J C J EMPC C J EMPC J J J J EMPC J J C J J J EMPC J J J EMPC J Pred RRT Actual RRT Diff Secs 0.9766 0.9859 0.9911 0.9933 1.0011 1.0048 1.0096 0.9641 0.9844 0.9903 1.0006 1.0086 1.0216 1.0300 1.0413 1.0733 1.0887 1.0952 1.1002 1.1101 1.1125 1.1156 1.1262 1.1361 1.1413 0.9080 0.9134 0.9194 0.9266 0.9434 0.9533 1.0005 1.0203 1.0348 1.0396 1.0418 1.1001 1.1146 1.1188 0.9516 0.9921 1.0004 1.0005 1.0178 1.0004 0.9766 0.9859 0.9911 0.9933 1.0007 1.0096 0.9642 0.9840 1.0087 1.0301 1.0735 1.0893 1.0954 1.1102 1.1125 1.1159 1.1266 1.1418 0.9078 0.9200 0.9264 0.9434 0.9532 1.0006 1.0202 1.0396 1.0420 1.1007 1.1148 1.1191 0.9515 0.9921 1.0006 1.0178 1.0005 0 0 0 0 -0.9 0 +0.2 -0.9 +0.2 +0.2 +0.5 +1.4 +0.5 +0.2 0 +0.7 +1.0 +1.2 -0.5 +1.5 -0.5 0 -0.3 +0.2 -0.2 0 +0.5 +1.6 +0.5 +0.8 -0.3 0 +0.3 0 +0.3 Page 5 of 5 Response Ra RRF Conc. / Recv. 6.12E+05 2.43E+05 2.14E+05 3.51E+05 4.20E+06 0.00E+00 5.38E+05 6.88E+05 3.81E+04 0.00E+00 0.00E+00 2.67E+05 0.00E+00 7.44E+04 0.00E+00 8.35E+04 2.36E+04 6.95E+05 0.00E+00 3.07E+05 5.40E+04 4.91E+05 2.32E+05 0.00E+00 1.45E+05 8.48E+04 0.00E+00 1.29E+06 3.08E+04 4.68E+05 1.24E+05 7.18E+04 4.39E+04 0.00E+00 2.12E+04 3.07E+04 2.27E+05 9.35E+04 1.27E+05 5.50E+04 1.59E+05 0.00E+00 7.96E+04 5.60E+04 9.99E+04 1.21 1.25 1.33 1.20 1.24 1.04 0.92 1.11 1.43 1.15 1.39 1.53 0.90 1.10 1.10 1.27 1.13 1.06 1.15 1.07 0.77 1.07 1.15 1.18 1.20 1.10 0.94 0.92 1.07 0.94 0.98 1.29 1.24 1.38 1.13 1.60 1.05 1.14 1.07 1.10 1.08 0.74 0.80 0.83 0.72 0.81 1.06 1.12 1.18 1.11 16.9 7.57 5.51 7.06 105 ND 10.1 16.5 0.749 ND ND 7.12 ND 1.95 ND 3.24 0.667 18.3 ND 7.79 1.48 15.9 7.61 ND 4.68 2.63 ND 31.5 0.677 14.7 2.78 2.06 1.16 ND 0.581 0.853 9.2 3.55 4.61 2.5 6.46 ND 2.19 1.47 4.21 1.33 1.26 1.59 1.01 1.10 1.17 0.79 1.04 1.11 1.18 1.14 1.24 0.96 1.21 1.05 0.78 0.98 0.97 0.92 0.91 0.70 0.89 1.00 0.93 0.79 1.04 1.00 0.78 0.94 0.70 Noise / Recv. Low DL / Recv. High 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 1.38E+03 2.07E+03 2.07E+03 2.07E+03 1.06E+03 1.06E+03 1.06E+03 1.06E+03 1.06E+03 1.06E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.21E+03 1.53E+03 1.53E+03 1.53E+03 3.39E+03 3.39E+03 3.39E+03 0.394 0.444 0.367 0.287 0.357 0.294 0.267 0.503 0.413 0.411 0.258 0.29 0.31 0.285 0.305 0.423 0.577 0.538 0.526 0.518 0.561 0.661 0.671 0.578 0.661 0.633 0.481 0.498 0.448 0.66 0.469 0.356 0.327 0.349 0.34 0.345 0.503 0.471 0.449 0.719 0.644 0.49 0.95 0.908 1.49 Printed: 4/4/2014 10:17 AM 70 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 3.45e7 1.73e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.26 242.9856 Fn2 Flags: 0% Abs. Int. 7.54e6 3.77e6 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.27-26.95 292.9824 Fn3 Flags: 0% Abs. Int. 6.84e6 3.42e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.97-38.11 330.9792 Fn4 Flags: 0% Abs. Int. 1.24e7 6.20e6 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 Rel. Int. QC chk 100% 38.13-45.16 380.9760 Fn5 Flags: 0% Abs. Int. 7.42e6 3.71e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.18-50.15 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 1.30e6 6.51e5 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.17-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 1.28e6 6.38e5 50.2 50.4 50.6 50.8 51.0 51.2 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 scc: 761-512 51.4 51.6 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 04-Apr-2014 10:18 Page 1 of 21 71 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 PCB-1 1.22e6 11.88 Rel. Int. 100% Abs. Int. 4.94e5 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.92e3 2.47e5 PCB-3 3.33e5 14.16 PCB-2 1.40e5 13.98 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 3.95e5 11.87 Rel. Int. 100% Abs. Int. 1.67e5 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 2.73e3 8.36e4 PCB-3 1.05e5 14.16 PCB-2 4.67e4 13.98 0% 11.0 12.0 13.0 ES-1 9.44e7 11.86 Rel. Int. 100% 0.00e0 16.0 RT 14.0 15.0 ES-3 9.80e7 14.15 0.00e0 16.0 RT Abs. Int. 3.70e7 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 6.86e3 1.85e7 0% 11.0 12.0 13.0 ES-1 2.91e7 11.86 Rel. Int. 100% 14.0 15.0 ES-3 2.99e7 14.15 0.00e0 16.0 RT Abs. Int. 1.16e7 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.57e4 5.82e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.45e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 1.73e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 2387, 0017 scc: 761-512 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:18 Page 2 of 21 72 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 PCB-4 5.15e6 14.41 Rel. Int. 100% Abs. Int. 1.78e6 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 4.08e3 8.90e5 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 3.26e6 14.41 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.12e6 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 8.02e3 5.59e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.67e7 14.40 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.55e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 9.34e3 7.76e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.89e7 14.40 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 9.55e6 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.51e3 4.78e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.45e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 1.73e7 0% 11.0 12.0 13.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0378, 0587 scc: 761-512 14.0 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:18 Page 3 of 21 73 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 PCB-8 6.16e6 17.20 Rel. Int. 100% DiCB-2 16.02-21.26 222.0003 Fn2 Flags: PBM 4σ 3.18e3 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 Abs. Int. 1.79e6 PCB-6 2.83e6 16.78 PCB-11 1.41e6 19.54 PCB-9 3.88e5 16.39 PCB-15 3.06e6 20.11 13/12 9.33e5 19.81 8.96e5 0% 17.0 19.0 20.0 21.0 PCB-8 3.72e6 17.20 Rel. Int. 100% DiCB-2 16.02-21.26 223.9974 Fn2 Flags: PBM 4σ 1.03e4 18.0 Abs. Int. 1.07e6 PCB-6 1.71e6 16.78 PCB-11 8.59e5 19.54 PCB-9 2.50e5 16.39 PCB-15 1.88e6 20.11 13/12 5.79e5 19.81 5.35e5 0% 17.0 Rel. Int. 100% 18.0 19.0 JS-9 9.80e7 16.37 20.0 21.0 ES-15 9.61e7 20.10 0.00e0 RT Abs. Int. 2.89e7 DiCB Std. 16.02-21.26 234.0406 Fn2 Flags: PBM 4σ 2.97e4 1.44e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 JS-9 6.29e7 16.37 20.0 21.0 ES-15 6.15e7 20.10 0.00e0 RT Abs. Int. 1.84e7 DiCB Std. 16.02-21.26 236.0376 Fn2 Flags: PBM 4σ 7.71e3 9.20e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.54e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 3.77e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 9187, 7032 scc: 761-512 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:18 Page 4 of 21 74 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 Rel. Int. 100% Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 Abs. Int. 5.26e6 30/18 1.87e7 19.26 TrCB-2 16.02-21.26 255.9613 Fn2 Flags: PBM 4σ 2.66e3 PCB-17 5.65e6 19.65 PCB-19 2.18e6 17.49 PCB-27 1.33e6 19.84 PCB-16 4.02e6 20.07 PCB-32 7.73e6 20.55 2.63e6 0% 17.0 18.0 Rel. Int. 100% 19.0 20.0 21.0 Abs. Int. 5.06e6 30/18 1.77e7 19.26 TrCB-2 16.02-21.26 257.9584 Fn2 Flags: PBM 4σ 2.10e3 PCB-17 5.32e6 19.65 PCB-19 2.01e6 17.49 PCB-27 1.26e6 19.84 PCB-16 3.78e6 20.07 PCB-32 7.29e6 20.55 2.53e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 3.93e7 17.47 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 1.15e7 TrCB Std. 16.02-21.26 268.0016 Fn2 Flags: PBM 4σ 4.06e4 5.75e6 0% 17.0 18.0 19.0 20.0 21.0 ES-19 3.75e7 17.47 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e7 TrCB Std. 16.02-21.26 269.9986 Fn2 Flags: PBM 4σ 2.35e4 5.50e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.54e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 3.77e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 1442, 5154 scc: 761-512 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:18 Page 5 of 21 75 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 PCB-31 2.18e7 28/20 22.61 2.03e7 22.89 Rel. Int. 100% TrCB-3 21.27-26.95 255.9613 Fn3 Flags: PBM 4σ 4.76e3 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 26/29 4.01e6 22.11 Abs. Int. 5.65e6 21/33 5.83e6 23.10 PCB-25 2.81e6 22.33 2.83e6 PCB-22 5.46e6 23.45 PCB-37 2.78e6 26.44 0% 22.0 23.0 25.0 0.00e0 RT 26.0 PCB-31 2.14e7 28/20 22.61 1.99e7 22.89 Rel. Int. 100% TrCB-3 21.27-26.95 257.9584 Fn3 Flags: PBM 4σ 3.35e3 24.0 26/29 4.02e6 22.11 PCB-25 2.71e6 22.33 Abs. Int. 5.55e6 21/33 5.77e6 23.10 2.78e6 PCB-22 5.44e6 23.45 PCB-37 2.72e6 26.44 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 7.30e7 22.86 Rel. Int. 100% ES-37 6.08e7 26.42 TrCB Std. 21.27-26.95 268.0016 Fn3 Flags: PBM 4σ 4.37e4 Abs. Int. 1.92e7 9.61e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 6.76e7 22.86 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 5.56e7 26.42 TrCB Std. 21.27-26.95 269.9986 Fn3 Flags: PBM 4σ 2.39e4 Abs. Int. 1.77e7 8.86e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.84e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.42e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 9717, 1603 scc: 761-512 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:18 Page 6 of 21 76 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 PCB-54 7.84e4 20.40 Rel. Int. 100% Abs. Int. 2.40e4 TeCB-2 16.02-21.26 289.9224 Fn2 Flags: PBM 4σ 8.71e2 1.20e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 9.50e4 20.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.89e4 TeCB-2 16.02-21.26 291.9194 Fn2 Flags: PBM 4σ 1.18e3 1.45e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.33e7 20.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.24e6 TeCB Std. 16.02-21.26 301.9626 Fn2 Flags: PBM 4σ 2.39e3 4.62e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.27e7 20.38 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e7 TeCB Std. 16.02-21.26 303.9597 Fn2 Flags: PBM 4σ 2.42e3 5.86e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.54e6 QC Check 16.02-21.26 242.9856 Fn2 Flags: - 3.77e6 0% 17.0 18.0 19.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0273, 6437 scc: 761-512 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:18 Page 7 of 21 77 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 PCB-52 1.91e7 24.51 Rel. Int. 100% TeCB-3 21.27-26.95 289.9224 Fn3 Flags: PBM 4σ 1.17e3 50/53 3.64e6 22.36 PCB-51 1.63e6 23.05 PCB-45 2.78e6 22.97 69/49 1.15e7 24.95 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 44/47… 1.74e7 25.40 PCB-48 2.92e6 25.21 PCB-46 1.08e6 23.25 Abs. Int. 4.93e6 PCB-42 3.77e6 25.87 59/62… 1.58e6 25.69 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 PCB-52 2.44e7 24.51 TeCB-3 21.27-26.95 291.9194 Fn3 Flags: PBM 4σ 1.40e3 50/53 4.63e6 22.36 PCB-51 2.07e6 23.05 PCB-45 3.56e6 22.97 23.0 PCB-48 3.71e6 25.21 PCB-46 1.38e6 23.25 25.0 Abs. Int. 6.33e6 PCB-42 4.77e6 25.87 26.0 JS-52 3.70e7 24.48 Rel. Int. 100% 2.47e6 0.00e0 RT 44/47… 2.22e7 25.40 69/49 1.46e7 24.95 24.0 PCB-64 9.01e6 26.50 26.0 0% 22.0 71/40 7.33e6 26.30 PCB-41 1.01e6 26.20 71/40 9.37e6 26.30 PCB-41 1.32e6 26.20 PCB-64 1.15e7 26.49 3.17e6 0.00e0 RT Abs. Int. 9.48e6 TeCB Std. 21.27-26.95 301.9626 Fn3 Flags: PBM 4σ 6.58e3 4.74e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.67e7 24.48 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e7 TeCB Std. 21.27-26.95 303.9597 Fn3 Flags: PBM 4σ 4.19e3 5.92e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.84e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.42e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 0955, 5032 scc: 761-512 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:19 Page 8 of 21 78 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.97-38.11 289.9224 Fn4 Flags: PBM 4σ 2.07e3 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 Abs. Int. 4.11e6 61/70... PCB-66 2.35e7 1.38e7 28.73 29.00 PCB-56 6.80e6 29.58 PCB-60 3.02e6 29.77 PCB-68 8.88e5 27.47 2.05e6 PCB-77 1.10e6 32.76 0% 28.0 Rel. Int. 100% TeCB-4 26.97-38.11 291.9194 Fn4 Flags: PBM 4σ 3.25e3 30.0 32.0 34.0 36.0 Abs. Int. 4.97e6 61/70... PCB-66 2.94e7 1.74e7 28.72 29.00 PCB-68 1.13e6 27.47 PCB-56 8.57e6 29.58 PCB-60 3.78e6 29.77 2.49e6 PCB-77 1.36e6 32.76 0% 28.0 0.00e0 38.0 RT 30.0 Rel. Int. 100% 32.0 ES-81 4.32e7 32.27 TeCB Std. 26.97-38.11 301.9626 Fn4 Flags: PBM 4σ 1.21e4 34.0 36.0 0.00e0 38.0 RT Abs. Int. 1.08e7 ES-77 4.50e7 32.75 5.38e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 5.48e7 32.27 TeCB Std. 26.97-38.11 303.9597 Fn4 Flags: PBM 4σ 7.09e3 34.0 36.0 0.00e0 38.0 RT Abs. Int. 1.36e7 ES-77 5.65e7 32.75 6.78e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.24e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.20e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 4246, 8228 scc: 761-512 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:19 Page 9 of 21 79 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 PCB-96 1.30e5 25.69 Rel. Int. 100% Abs. Int. 3.42e4 PeCB-3 21.27-26.95 323.8834 Fn3 Flags: PBM 4σ 6.77e2 1.71e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 2.04e5 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.74e4 PeCB-3 21.27-26.95 325.8804 Fn3 Flags: PBM 4σ 9.36e2 2.87e4 0% 22.0 23.0 24.0 25.0 26.0 ES-104 4.01e7 25.35 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e7 PeCB Std. 21.27-26.95 337.9207 Fn3 Flags: PBM 4σ 2.52e3 5.16e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.49e7 25.35 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.39e6 PeCB Std. 21.27-26.95 339.9177 Fn3 Flags: PBM 4σ 1.43e3 3.20e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.84e6 QC Check 21.27-26.95 292.9824 Fn3 Flags: - 3.42e6 0% 22.0 23.0 24.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 5157, 7236 scc: 761-512 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:19 Page 10 of 21 80 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 PCB-110 6.07e6 32.19 Rel. Int. 100% PeCB-4 26.97-38.11 323.8834 Fn4 Flags: PBM 4σ 1.23e3 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 113/90… 4.23e6 30.49 PCB-95 3.58e6 27.95 PCB-91 9.25e5 28.71 PCB-84 1.44e6 28.91 PCB-92 6.89e5 29.98 PCB-99 2.49e6108/119... 31.00 3.82e6 116/85 31.47 1.15e6 PCB-115PCB-82 32.06 1.71e5 6.73e5 32.28 32.47 Abs. Int. 1.52e6 PCB-118 4.17e6 34.74 PCB-109 3.71e5 34.36 PCB-105 2.20e6 35.75 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.97-38.11 325.8804 Fn4 Flags: PBM 4σ 1.70e3 0% PCB-95 5.75e6 27.95 PCB-91 1.50e6 28.71 PCB-84 2.24e6 PCB-102 28.90 4.82e5 28.27 28.0 32.0 113/90… 6.79e6 30.49 PCB-92 1.14e6 29.98 30.0 Rel. Int. 100% 34.0 36.0 PCB-110 9.90e6 32.19 PCB-99 4.07e6108/119... 31.00 6.29e6 31.47 PCB-115PCB-82 PCB-117 2.69e5 1.13e6 3.17e5 31.9832.28 32.47 32.0 PeCB Std. 26.97-38.11 337.9207 Fn4 Flags: PBM 4σ 2.10e3 0.00e0 38.0 RT Abs. Int. 2.41e6 PCB-118 6.73e6 34.74 PCB-109 6.00e5 34.36 34.0 CS/SS-111 5.73e7 32.76 JS-101 4.68e7 30.47 7.58e5 ES-118 ES-114 5.17e7 ES-123 5.18e7 35.18 5.11e7 34.72 34.44 PCB-105 3.59e6 35.75 36.0 ES-105 5.40e7 35.73 1.21e6 0.00e0 38.0 RT Abs. Int. 1.43e7 7.16e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 3.65e7 32.76 JS-101 2.89e7 30.47 PeCB Std. 26.97-38.11 339.9177 Fn4 Flags: PBM 4σ 1.66e3 34.0 ES-118 ES-114 ES-123 3.24e7 3.22e7 3.26e7 34.72 35.18 34.44 36.0 ES-105 3.39e7 35.73 0.00e0 38.0 RT Abs. Int. 9.04e6 4.52e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 38.0 RT Abs. Int. 1.24e7 QC Check 26.97-38.11 330.9792 Fn4 Flags: - 6.20e6 0% 28.0 30.0 32.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 5103, 1673 scc: 761-512 34.0 36.0 0.00e0 38.0 RT Peak annotation: Areas, Centroids Revised: 30-Mar-2014 14:35 (DES) Printed: 04-Apr-2014 10:19 Page 11 of 21 81 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 Rel. Int. 100% Abs. Int. 9.49e5 PeCB-5 38.13-45.16 323.8834 Fn5 Flags: PBM 4σ 1.20e3 4.75e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% Abs. Int. 2.10e6 PeCB-5 38.13-45.16 325.8804 Fn5 Flags: PBM 4σ 1.91e3 1.05e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.14e7 ES-126 4.64e7 38.34 PeCB Std. 38.13-45.16 337.9207 Fn5 Flags: PBM 4σ 5.18e3 5.70e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.04e6 ES-126 3.01e7 38.34 PeCB Std. 38.13-45.16 339.9177 Fn5 Flags: PBM 4σ 6.44e3 3.52e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.42e6 QC Check 38.13-45.16 380.9760 Fn5 Flags: - 3.71e6 0% 39.0 40.0 41.0 42.0 Results: P:\A6500_A6599\A6521\A6521_11903 PCB\Resources\A6521_11903_PCB_001-RJ.utp_res, saved 31-Mar-2014 08:14 (DES) SGS UltraTrace-Pro V4.82 User/System: DES/US0008026 cc: 4733, 3229 scc: 761-512 43.0 44.0 45.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Mar-2014 14:04 Printed: 04-Apr-2014 10:19 Page 12 of 21 82 of 562 SGS ID: A6521_11903_PCB_001-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB083-1SWMID-140318-N VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 79 Rel. Int. 100% Acq: 28-Mar-2014 21:35:52 User: LKB Datafile: 140328X12 153/168 1.88e6 36.32 147/149 1.55e6 33.76 HxCB-4 26.97-38.11 359.8415 Fn4 Flags: PBM 4σ 6.88e2 PCB-136 3.86e5 30.93 PCB-132 7.13e5 34.84 151/135 5.98e5 32.99 163/138… 2.32e6 37.39 PCB-141 3.35e5 PCB-137 36.49 1.22e5 37.03 PCB-146 3.00e5 35.80 2.69e5 PCB-158 3.07e5 37.73 0% 28.0 30.0 32.0 34.0 0.00e0 38.0 RT 36.0 153/168 1.53e6 36.32 Rel. Int. 100% HxCB-4 26.97-38.11 361.8385 Fn4 Flags: PBM 4σ 6.88e2 147/149 1.21e6 33.77 v~~ I'-Jr -r,.J... ~./y \)'"L OL. L\ ~"'i- \-\,-0 l.-o\Y, 6'1...'2-\. ~0 t'1 \,..1.0 L() SUIJIJly J1)s \\: \6 ""--..... Tolucnc \\S'{ (- Sand Hexane Silica Stop: >1-z.s11~ 11"1,'("'" Florisil Start: fJ\,1L- \It\Lo~<'~ /LA- CH2CL, Stop: Translcr Init/Datc: Ohst'r\'ations Cvclc Time Succial Instroctious: 1668A wi OI'R Dissolvcd samplcs nccd to hc iiltcrcd hciilrC c,traction IN ~1,e?Ll-uP --- 113 bt I '-1 \.-113 3 '1B L{ /?; l-f 018 --3 !'vJ-:!/ A~lnit/l)ate: ('I'd) # I Water 1668/\ O'fYbO tJ J'"bfi - oj, ~2;»'f (J;rrI.1 \1.1'1 'ZIO 1'> Acid Silica Basc Silica IlydroMatri, Tctradccanc .j-J'I"'~ ~J.J'1~ ~ 011'{~H o hOlo/\.{ -- 01.21.flA N rJ1u(J Lel'/ 34 of 603 1M AN .••• '.rnCAI. Project # A6528 Batch # 1668A Ptr~~P"CTl\lI':~ 11906 Inter-Department Communication Sheet Special Instructiolls 1668A wi Dissolved OPR samples need to be filtered before extraction Aqueous 35 of 603 TSS % TSS Determination SGS.- WorkSheet .~i1l •..,,"",., en""""",, Tarc Balancc Procedures: Add boal & O.4:i ~1I11 !illcr and weigh. Rccord "Boat WI." Place !iltcr in glass !illing funnel Fillcr 10 1111. of aqucous sample through IiItcr inlo a waste jar Rinse filler wilh 20 ml, of DI walcr Dry in own ovcrnight@ IO? C Rclurn dish IOloploader and rccord "Dry WI." Project: A6528 Batch: 11906 APSllmlJle ID llo11tWT. \v\\L Chcmist: Prep Datc: Dry WT. %,TSS ~ Init/l)llte J)\\ CJ- 1\6528 - 11906 001 \,1.1 \.1~ o '\ 0M-- \ 0 1\6528 11906_002 \.""18 t,1~ () M'L I 0 1\6528 - 11906Jl03 \~"\~ \,lq 6 .\ ~\L l D A6528 - 11906 004 \.\.~ l 0 Ll~ CJ fv\~1 5\,?-'\11 Comments 36 of 603 Spike Sheet PCB I liiL'--!lbc:c,:::s"",~"""" A,•••.••~.,.~K ..•.' 1', '<''''''1',(-'-' :v"J; ~- Analvte SPIKE Slliked AlIIount Sllil,c COlllllounds . Spiker Initials/l)ate: AI' Sample ID Clicnt Sample ID A6528 - 11906 001 PB099-ISWMID-140319-N (TOTAL) A6528 - 11906 002 1'13099-1SWMID-140J 19-MD (TOTAL) 11906 003 I'BI01.I-ISWMID-140J 19-N (TOTAL) A6528 - {\4- > 1'l'1/''1 VIA :. Mil",? PCB Ax 209 Amount: ~ l"v Observer Initials "CBCS Amount: T? _\ Observer Initials Amount: iO.u ..f Observer Initials - o-J \V\~ - ck' \J\\[. - oJ ~~ ~,/II.A( PCB ES Amount:"Z.Il",LObserver Initials \NL ,~ tv\t.- PCB.IS ~~ Method Blank ~\~ - o-J \J\V- 0 - 11906 OI'ROOI \f\\L ~\'L ()J' \1\'i- OI'RI (DISSOLVED) )\'1.-~\I~~ \cu. h~ ') \7..-1. \ \'\ Standard PCB ES \0 1...-'\. -z..c \'7, \l, \)--"\~-\ 100 pg/ftL C-'L\ \..II. \1 "\ (ilL) ('1 oJ MBI - 11906 Std. Type Spike II) SIL # Concentration Units Exp. Date Spike amount Slllit Factor -- I'BIOI.I-ISWMID-140JI9-N 11906 ~/'UI Oi PROFILE PCBs Solution Conc. Snikcd Volullll' \~ A6528 - 11906 004 - ~ I Water I 11906 Batch # A6528 Project # I 1668A '20 Information PCB Ax 209 \ 01...9c -u> \1 \ ",-'1.~""1 50 pg/uL \\l\V\.l("I. 20 3Iu/lL{ PCB.IS PCB CS/SS IO"l.' 'to \> a IUL 6 lu .••• l'~-'b_ <. I~~C(0-"3 100 pg/ftL t.\..( I~ II" 20 200 pghtL 12..-Iq-I ~ 10 Final Volulllc Final Soh'cnt 37 of 603 Sample Receipt Notification 2714 Exchange Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8290 Fax: 910 794-3919 Client Smp ID Project Manager: Receipt Date & Time: AP Project name: Requested TAT: Projected due date: Matrix: Phone#: Email Address: AP Smp ID Amy Boehm 20-Mar-14 at 09:40 A6528 21 days 10-Apr-14 Aqueous 910-794-1613 Amy.Boehm@sgs.com Sample Condition & Notes PB099-1SWMID-140319-N (TOTAL) A6528_001 Grab PB099-1SWMID-140319-MD (TOTAL) A6528_002 A6528_003 A6528_004 Grab Grab Grab Ice - Good Condition Sample Seals: PB101.1-1SWMID-140319-N (TOTAL) PB101.1-1SWMID-140319-N (DISSOLVED) Preservation Type: Notes/Comments: Quantity Size Sampling Date 2 1.25L Amber 19-Mar-14 2 1L Amber 19-Mar-14 2 1L Amber 19-Mar-14 2 1.25L Amber 19-Mar-14 Sampling Time 17:13 16:45 17:45 17:45 Delaney Peterson ANCHOR QEA Patrick Bayou N/A N/A Method 1668A 206.903.3396 dpeterson@anchorqea.com Received Temp Container # 4 1 875887997089 4 4 4 1 1 1 875887997089 Shipping # 875887997089 875887997089 No Any un-extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. Samples received intact Received by: Christina Newkirk Company Contact: Company: Project Name & Site: Project PO#: QAAP/Contract #: Requested Analysis: Phone#: Email Address: Logged in by: Christina Newkirk QC'ed by: AK 20 Mar 14 SGS Analytical Perspectives 38 of 603 CHAIN OF CUSTODY I CONVENTIONAL & SHALE SPECIAL INSTRUCTIONS PROJECT INFO: PROJECT: / COMMENTS: 0 1.10 Z~4 -0 I. O~ P.O, #: QUOTE #' SITE REF; Jifl' (c-f ~~t)!, PRESERVATIVE ~dwc; TURN AROUND TIME: REPORT LEVEL: (see reverse I D Level S':.C~L1VERABLES: ~ State of Origin: d::fEDD: D Other. I D Level I~ /' /'/ ..•.. --><:;" --1---1-- --I---~ --~ --I"--- C .--------) -------- ~A~ COLL",~~ISHED ~t, RELINQUISHED Page_of_ TIME: BY(1): n ~~/C,~ BY (21: J~1() DATE: TIME: SGS NORTH AMERICA INC, R'{?:lft.y RECEIVED BY: -1- ENVIRONMENTAL SERVICES 5500 Business Drive Wilmington, NC 28405 91035019031910794 Member 1613 www.sgs.com of the SGS Group ISGS SA) 39 of 603 SGS Analytical Perspectives — Run Log Project: A6528_11906_PCB Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Wt/Vol Client/Sample ID Analyst(s) Checkcode Datafile Vial# Lab ID Acq Date Acq Time 1 140402X01 Tray1:03 CS3_140402_PCB_XA 1.00 SIL 13-79-3 LKB, CEM 090-369 01-Apr-2014 23:29:14 2 140402X02 Tray1:20 OPR1_11906_PCB 1.00 0_11906_OPR001 LKB, CEM 758-213 02-Apr-2014 00:23:43 3 140402X03 Tray1:02 SBS_140402_PCB_XA 1.00 SIL 13-42-1 LKB, CEM 542-620 02-Apr-2014 01:18:59 4 140402X04 Tray1:21 MB1_11906_PCB_TLX 1.00 Method Blank LKB, CEM 122-856 02-Apr-2014 02:14:08 5 140402X10 Tray1:27 A6528_11906_PCB_001 1.22 PB099-1SWMID-140319-N (TOTAL) LKB, CEM 065-928 02-Apr-2014 07:45:18 6 140402X11 Tray1:28 A6528_11906_PCB_002 0.97 PB099-1SWMID-140319-MD (TOTAL) LKB, CEM 334-515 02-Apr-2014 08:40:36 7 140403X04 Tray1:03 CS3_140403_PCB_XB 1.00 SIL 13-79-3 LKB, CEM 739-978 03-Apr-2014 15:20:55 8 140403X05 Tray1:02 SBS_140403_PCB_XC 1.00 SIL 13-42-1 LKB, CEM 701-763 03-Apr-2014 16:27:17 9 140403X06 Tray1:21 MB1_11906_PCB_TLX-RJ 1.00 Method Blank LKB, CEM 441-024 03-Apr-2014 17:21:41 10 140403X11 Tray1:03 CS3_140403_PCB_XC 1.00 SIL 13-79-3 LKB, CEM 980-763 03-Apr-2014 22:09:02 11 140403X18 Tray1:41 A6528_11906_PCB_003 0.96 PB101.1-1SWMID-140319-N (TOTAL) LKB, CEM 388-879 04-Apr-2014 04:34:05 12 140403X19 Tray1:42 A6528_11906_PCB_004 1.12 PB101.1-1SWMID-140319-N (DISSOLVED) LKB, CEM 118-899 04-Apr-2014 05:29:13 Project file: not saved SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 Printed: 06-Apr-2014 17:28 40 of 603 Lab ID: MB1_11906_PCB_TLX-RJ ACQ: 03-Apr-2014 17:21:41 LKB Wt/Vol: 1.00 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XB Client ID: Method Blank A6528 UTP: 05-Apr-2014 03:00 CEM J-level: 10 pg/L Datafile: 140403X06 RPT: 06-Apr-2014 16:15 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB NotFnd NotFnd 35.64 NotFnd 34.64 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 50.69 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.81 14.08 14.33 20.02 17.40 26.33 20.30 32.64 32.17 25.26 35.62 35.08 34.61 34.33 38.23 36.20 30.20 40.78 39.79 43.49 43.00 41.93 35.07 45.61 39.61 47.77 49.23 45.23 50.65 QC J J EMPC C J Pred RRT Actual RRT 1.0006 1.0005 1.0007 1.0006 1.0007 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0000 1.0006 1.0006 1.0007 0.7244 0.8640 0.8793 1.2279 1.0674 1.0793 0.8322 1.3381 1.3186 0.8317 1.1729 1.1551 1.1398 1.1306 1.2588 0.9715 0.8106 1.0943 1.0679 1.1671 0.9078 0.8852 0.7404 0.9628 0.8361 1.0084 1.0393 0.9547 1.0692 0.7244 0.8640 0.8792 1.2282 1.0673 1.0794 0.8321 1.3383 1.3188 0.8317 1.1730 1.1552 1.1399 1.1306 1.2590 0.9715 0.8105 1.0944 1.0680 1.1672 0.9077 0.8852 0.7403 0.9628 0.8360 1.0084 1.0393 0.9547 1.0692 Diff Secs Split: 1 Response +2.1 0.00E+00 0.00E+00 5.07E+04 0.00E+00 9.73E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.71E+04 0 0 -0.1 +0.4 -0.1 +0.2 -0.1 +0.4 +0.4 0 +0.2 +0.2 +0.2 0 +0.5 0 -0.2 +0.2 +0.2 +0.3 -0.3 0 -0.2 0 -0.2 0 0 0 0 6.75E+07 7.07E+07 4.25E+07 9.04E+07 4.23E+07 7.45E+07 4.61E+07 6.68E+07 6.39E+07 4.58E+07 5.74E+07 5.63E+07 5.52E+07 5.54E+07 4.92E+07 4.08E+07 5.86E+07 9.68E+07 5.05E+07 4.71E+07 3.01E+07 3.69E+07 4.16E+07 4.41E+07 3.84E+07 3.33E+07 2.43E+07 3.58E+07 3.05E+07 -0.2 -0.2 Page 1 of 5 Checkcode: 441-024-FNH Method 1668A RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.12 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ND ND 1.59 ND 2.96 ND ND ND ND ND ND 1.01 4.10E+03 4.10E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 2.27E+03 1.46E+03 1.46E+03 1.46E+03 1.67E+03 1.11E+03 1.05 1.15 0.642 0.604 0.59 0.568 0.871 0.782 0.521 0.566 0.731 0.766 3.28 3.35 1.61 1.58 1.07 1.09 0.80 0.79 0.81 1.61 1.59 1.59 1.63 1.57 1.60 1.32 1.25 1.28 1.28 1.25 1.08 1.09 1.08 1.03 0.94 0.91 0.80 0.79 1.19 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 65.4 % 75.3 % 93.9 % 100 % 96.6 % 87.3 % 104 % 94 % 90.9 % 122 % 102 % 99.1 % 102 % 100 % 103 % 95.6 % 95.5 % 78.4 % 78.4 % 78.5 % 97.4 % 101 % 115 % 98.7 % 103 % 95 % 104 % 108 % 97.4 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% Ra 0.54 0.79 Printed: 4/6/2014 5:19 PM 41 of 603 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.77 32.66 37.63 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 7.87E+07 5.69E+07 2.67E+07 1.10 1.55 1.07 1.11 1.03 0.62 95 % 99.7 % 104 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.77 32.66 37.63 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 7.87E+07 5.69E+07 2.67E+07 1.10 1.55 1.07 1.85 1.22 0.58 82.9 % 99.9 % 119 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.30 24.39 30.37 37.26 47.37 8.65E+07 5.14E+07 4.66E+07 3.86E+07 2.82E+07 1.57 0.81 1.59 1.31 0.90 4.27E+03 4.27E+03 4.27E+03 7.21E+03 7.21E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 8.73E+03 6.82E+03 6.82E+03 6.82E+03 6.82E+03 6.82E+03 6.82E+03 0.846 0.767 0.885 2.04 1.35 1.82 1.62 1.73 1.71 1.66 1.44 1.66 1.66 1.74 2.25 1.71 2.02 1.46 1.5 2.76 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 19.46 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd C C 1.0011 0.9880 1.0009 1.0011 1.0135 1.0010 1.0111 1.0250 1.0435 1.0507 0.9331 0.9720 0.9866 1.0008 1.0010 1.1017 1.1247 1.1357 1.1435 1.1489 0.9721 - +0.1 Page 2 of 5 Noise / Recv. Low DL / Recv. High EMPC 0 10.2 4.94 16.9 25.8 16 0 0 0 NON-EMPC 0 10.2 4.94 13.3 10.6 9.22 0 0 0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.92E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 RRF Conc. / Recv. SI 0.95 1.16 1.01 1.23 1.87 0.98 1.10 1.03 1.04 1.07 1.23 1.07 1.07 1.02 1.15 1.51 1.28 1.77 1.72 0.94 DL 0.865 1.89 2.07 1.07 0.615 0.564 0.792 0.758 1.74 ND ND ND ND ND ND ND ND ND ND ND 10.2 ND ND ND ND ND ND ND ND Printed: 4/6/2014 5:19 PM 42 of 603 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB NotFnd NotFnd NotFnd NotFnd NotFnd 22.52 22.80 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 24.41 NotFnd NotFnd 24.85 NotFnd 25.31 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 28.61 28.90 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC C J J C C C J J C J EMPC C C C J C J Pred RRT Actual RRT 1.1763 0.8211 0.8268 0.8375 0.8451 0.8556 0.8663 0.8732 0.8875 0.9397 0.9520 0.9721 0.9871 1.0008 1.0010 0.9141 0.9381 0.9410 0.9497 1.0009 1.0062 1.0102 1.0181 1.0296 1.0385 1.0498 1.0566 1.0702 1.0741 1.0823 0.8429 0.8509 0.8624 0.8687 0.8736 0.8806 0.8897 0.8984 0.9030 0.9165 0.9225 0.9326 0.9737 0.9888 1.0009 1.0135 0.8985 0.9048 0.8554 0.8660 1.0008 1.0188 1.0378 0.8896 0.8986 - Diff Secs -0.3 -0.4 -0.1 +1.0 -1.1 -0.2 +0.3 Page 3 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.02E+05 1.33E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.47E+05 0.00E+00 0.00E+00 7.07E+04 0.00E+00 1.06E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.51E+05 6.72E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.16 0.90 0.80 0.76 0.92 0.70 0.70 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.88 1.23 1.25 1.28 1.30 1.33 1.24 1.28 1.19 1.30 1.36 1.20 1.16 1.08 1.35 0.88 0.71 0.95 0.70 0.87 1.17 0.70 1.05 0.86 0.92 1.20 0.79 0.67 0.90 1.28 1.20 1.25 1.15 1.19 1.24 1.29 1.18 1.11 1.10 1.09 1.12 1.31 1.29 1.07 1.43 1.16 0.93 0.77 ND ND ND ND ND 2.06 2.88 ND ND ND ND ND ND ND ND ND ND ND ND 5.29 ND ND 2.11 ND 3.59 ND ND ND ND ND ND ND ND ND ND ND 4.02 1.89 ND ND ND ND ND ND ND ND ND ND 6.82E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 7.80E+03 3.10E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 4.10E+03 1.48E+03 1.48E+03 1.95E+03 1.95E+03 1.37 1.64 1.62 1.59 1.56 1.53 1.64 1.58 1.71 1.56 1.5 1.69 1.75 1.88 0.851 1.14 1.42 1.06 1.43 1.16 0.861 1.43 0.959 1.17 1.09 0.836 1.28 1.49 1.11 0.785 1.07 1.02 1.12 1.08 1.04 0.993 1.09 1.16 1.16 1.17 1.14 0.979 0.997 1.19 0.415 0.513 0.741 0.888 Printed: 4/6/2014 5:19 PM 43 of 603 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.86 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.39 NotFnd 30.89 NotFnd 31.38 NotFnd NotFnd 32.09 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.83 NotFnd NotFnd 32.89 NotFnd NotFnd 33.66 NotFnd NotFnd NotFnd NotFnd NotFnd 34.74 NotFnd NotFnd 35.68 NotFnd 36.22 SGS Evironmental Services QC J C J EMPC C J EMPC J C C J EMPC C J J EMPC C J EMPC C C J EMPC J J C Pred RRT Actual RRT Diff Secs 0.9173 0.9243 0.9278 0.9301 0.9402 0.9423 0.9486 0.9623 0.9735 0.9840 0.9999 1.0144 1.0175 1.0208 1.0321 1.0496 1.0527 1.0566 1.0594 1.0659 1.0761 1.0892 0.9915 0.9975 1.0039 1.0091 1.0351 1.0007 1.0062 1.0108 1.0210 1.0299 1.0719 1.0891 1.0960 1.1048 1.1148 1.1205 1.1231 1.1319 1.1377 1.1425 1.1502 1.1636 0.9523 0.9580 0.9612 0.9727 0.9174 1.0008 1.0174 1.0335 1.0566 1.0210 1.0890 1.1147 1.1505 0.9577 0.9721 +0.2 +1.6 -0.2 +2.6 0 0 -0.2 -0.2 +0.6 -0.6 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.13E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.17E+05 0.00E+00 4.76E+04 0.00E+00 1.12E+05 0.00E+00 0.00E+00 1.76E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.97E+04 0.00E+00 0.00E+00 3.48E+04 0.00E+00 0.00E+00 7.93E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.96E+04 0.00E+00 0.00E+00 2.50E+04 0.00E+00 9.76E+04 0.61 0.85 0.83 0.97 0.76 0.72 0.97 0.70 0.75 1.19 0.81 0.96 0.69 0.88 1.16 0.97 1.17 0.89 1.06 1.20 0.68 1.20 1.21 1.09 1.22 1.10 1.01 1.10 1.26 1.09 1.10 1.02 1.05 1.08 1.04 1.22 1.08 1.07 0.88 0.99 1.10 0.93 0.92 0.95 1.01 1.31 1.11 1.41 1.38 4.79 ND ND ND ND ND ND ND ND ND 4.4 ND 1.95 ND 4.19 ND ND 5.96 ND ND ND ND ND ND ND ND ND ND ND ND 0.662 ND ND 1.64 ND ND 3.63 ND ND ND ND ND 1.52 ND ND 1.1 ND 3.47 0.51 0.83 0.66 0.51 1.31 1.72 1.45 0.82 1.26 1.20 Noise / Recv. Low DL / Recv. High 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.95E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 0.809 0.829 0.71 0.902 0.952 0.711 0.978 0.914 0.577 0.851 0.716 1 0.782 0.591 0.713 0.586 0.773 0.647 0.574 1.01 0.573 0.567 0.629 0.566 0.628 0.718 0.648 0.387 0.446 0.445 0.481 0.467 0.675 0.704 0.599 0.678 0.683 0.832 0.738 0.664 0.788 0.797 0.768 0.725 0.558 0.655 0.518 0.53 Printed: 4/6/2014 5:19 PM 44 of 603 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB NotFnd NotFnd NotFnd NotFnd 37.28 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J C C C C C Pred RRT Actual RRT 0.9766 0.9859 0.9912 0.9934 1.0011 1.0049 1.0097 0.9639 0.9843 0.9903 1.0006 1.0087 1.0217 1.0302 1.0415 1.0736 1.0891 1.0956 1.1007 1.1105 1.1129 1.1160 1.1268 1.1366 1.1419 0.9077 0.9131 0.9191 0.9264 0.9433 0.9531 1.0005 1.0203 1.0348 1.0396 1.0419 1.1005 1.1150 1.1192 0.9515 0.9921 1.0004 1.0005 1.0179 1.0004 1.0007 - Diff Secs -0.9 Page 5 of 5 Response 0.00E+00 0.00E+00 0.00E+00 0.00E+00 9.04E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Ra 1.27 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.01 0.89 1.07 1.42 1.11 1.32 1.50 0.89 1.07 1.06 1.27 1.08 1.02 1.13 1.07 0.75 1.06 1.14 1.16 1.16 1.11 0.94 0.93 1.08 0.93 0.97 1.29 1.23 1.36 1.11 1.60 1.05 1.12 1.04 1.19 0.99 0.73 0.77 0.80 0.70 0.78 1.06 1.12 1.14 1.11 ND ND ND ND 3.99 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.47E+03 1.46E+03 1.46E+03 1.46E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.67E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.49E+03 1.49E+03 1.49E+03 2.67E+03 2.67E+03 2.67E+03 0.726 0.82 0.682 0.515 0.657 0.552 0.485 0.681 0.564 0.571 0.511 0.598 0.634 0.576 0.606 0.859 0.918 0.856 0.843 0.841 0.881 1.04 1.04 0.902 1.04 1.01 0.754 0.793 0.718 1.06 0.731 0.604 0.57 0.609 0.536 0.642 0.874 0.825 0.798 1.37 1.24 0.912 1.42 1.39 2.07 Printed: 4/6/2014 5:19 PM 45 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 7.12e7 3.56e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 3.13e7 1.57e7 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 2.77e7 1.39e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 2.82e7 1.41e7 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 1.62e7 8.11e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 7.71e6 3.86e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 7.35e6 3.68e6 50.0 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 441-024 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:25 Page 1 of 21 46 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 1.44e4 MoCB 10.03-15.71 188.0393 Fn1 Flags: B 4σ 2.32e3 7.18e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.35e3 MoCB 10.03-15.71 190.0363 Fn1 Flags: B 4σ 1.95e3 3.67e3 0% 11.0 12.0 13.0 ES-1 5.18e7 11.81 Rel. Int. 100% 14.0 15.0 ES-3 5.45e7 14.08 0.00e0 RT Abs. Int. 2.03e7 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PBM 4σ 5.30e3 1.02e7 0% 11.0 12.0 13.0 ES-1 1.58e7 11.81 Rel. Int. 100% 14.0 15.0 ES-3 1.63e7 14.08 0.00e0 RT Abs. Int. 6.25e6 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PBM 4σ 3.01e4 3.12e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.12e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 3.56e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0022, 7573 scc: 441-024 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:58 (CEM) Printed: 06-Apr-2014 17:25 Page 2 of 21 47 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 1.05e4 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PB 4σ 4.39e3 5.25e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.01e4 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PB 4σ 1.46e4 1.51e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.62e7 14.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.84e6 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PBM 4σ 7.06e3 4.42e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.62e7 14.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.54e6 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PBM 4σ 3.34e3 2.77e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.12e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 3.56e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7150, 2755 scc: 441-024 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:23 (CEM) Printed: 06-Apr-2014 17:25 Page 3 of 21 48 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 PCB-11 3.00e5 SI 19.46 Rel. Int. 100% Abs. Int. 8.31e4 DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PBM 4σ 5.32e3 4.16e4 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.24e4 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PB 4σ 1.79e4 3.62e4 0% 16.0 17.0 18.0 19.0 JS-9 5.29e7 16.30 Rel. Int. 100% 20.0 21.0 ES-15 5.54e7 20.02 0.00e0 RT Abs. Int. 1.65e7 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PBM 4σ 1.23e4 8.25e6 0% 16.0 17.0 18.0 19.0 JS-9 3.37e7 16.30 Rel. Int. 100% 20.0 21.0 ES-15 3.50e7 20.02 0.00e0 RT Abs. Int. 1.05e7 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PBM 4σ 5.52e3 5.26e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.13e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.57e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0940, 7163 scc: 441-024 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:58 (CEM) Printed: 06-Apr-2014 17:25 Page 4 of 21 49 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 1.81e4 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PB 4σ 3.48e3 9.05e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e4 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PB 4σ 3.33e3 5.88e3 0% 16.0 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 9.74e6 ES-19 2.18e7 17.40 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PBM 4σ 5.93e4 0.00e0 RT 4.87e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-19 2.05e7 17.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.32e6 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PBM 4σ 2.51e4 3.16e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.13e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.57e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7632, 9789 scc: 441-024 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:23 Printed: 06-Apr-2014 17:25 Page 5 of 21 50 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 PCB-31 5.50e4 22.52 TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 4.41e3 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Abs. Int. 1.81e4 28/20 6.29e4 22.80 9.03e3 0% 22.0 Rel. Int. 100% 23.0 PCB-31 4.73e4 22.53 TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 3.39e3 24.0 25.0 0.00e0 RT 26.0 Abs. Int. 2.15e4 28/20 7.03e4 22.79 1.07e4 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 4.12e7 22.77 Rel. Int. 100% ES-37 3.89e7 26.33 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PBM 4σ 6.25e4 Abs. Int. 1.11e7 5.56e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 3.75e7 22.77 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.56e7 26.33 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PBM 4σ 2.17e4 Abs. Int. 1.01e7 5.06e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.77e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.39e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2491, 6463 scc: 441-024 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:59 (CEM) Printed: 06-Apr-2014 17:25 Page 6 of 21 51 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 3.20e3 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PB 4σ 1.70e3 1.60e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.60e3 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PB 4σ 1.40e3 1.30e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 2.04e7 20.30 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.99e6 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PBM 4σ 1.46e4 2.99e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 2.57e7 20.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.35e6 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PBM 4σ 1.42e4 3.67e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.13e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.57e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1109, 2613 scc: 441-024 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:23 (CEM) Printed: 06-Apr-2014 17:25 Page 7 of 21 52 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 PCB-52 6.51e4 24.41 Rel. Int. 100% 69/49 3.04e4 24.85 TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 1.73e3 Abs. Int. 1.70e4 44/47… 5.45e4 25.31 8.52e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-52 8.15e4 24.41 Rel. Int. 100% Abs. Int. 2.11e4 69/49 4.03e4 24.85 TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 1.48e3 44/47… 5.94e4 25.32 1.05e4 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.30e7 24.39 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 6.20e6 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PBM 4σ 2.77e4 3.10e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.84e7 24.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.72e6 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PBM 4σ 2.40e4 3.86e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.77e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.39e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2284, 1601 scc: 441-024 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:59 (CEM) Printed: 06-Apr-2014 17:25 Page 8 of 21 53 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% 61/70... 6.25e4 28.61 TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 1.94e3 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Abs. Int. 1.56e4 PCB-66 2.78e4 28.90 7.79e3 0% 28.0 Rel. Int. 100% 30.0 32.0 34.0 36.0 Abs. Int. 1.88e4 61/70... 8.88e4 28.62 PCB-66 3.94e4 28.91 TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 2.16e3 9.42e3 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.85e7 32.17 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PBM 4σ 3.55e4 34.0 36.0 0.00e0 RT Abs. Int. 7.50e6 ES-77 2.94e7 32.64 3.75e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.54e7 32.17 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PBM 4σ 2.10e4 34.0 36.0 0.00e0 RT Abs. Int. 9.55e6 ES-77 3.74e7 32.64 4.78e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.82e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.41e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1816, 4666 scc: 441-024 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:59 (CEM) Printed: 06-Apr-2014 17:25 Page 9 of 21 54 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 2.73e3 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PB 4σ 6.41e2 1.36e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.06e3 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PB 4σ 8.42e2 1.03e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.83e7 25.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.69e6 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PBM 4σ 4.62e3 3.85e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.76e7 25.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.79e6 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PBM 4σ 1.24e3 2.40e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.77e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.39e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6495, 7293 scc: 441-024 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:23 (CEM) Printed: 06-Apr-2014 17:25 Page 10 of 21 55 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 9.82e2 PCB-95 4.29e4 27.86 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 113/90… 4.48e4 30.39 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Abs. Int. 2.05e4 PCB-110 6.72e4 32.09 PCB-118 4.72e4 34.64 108/119... PCB-99 4.45e4 2.44e4 31.38 30.89 PCB-105 1.77e4 35.64 0% 28.0 30.0 32.0 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 9.70e2 PCB-95 7.00e4 27.85 113/90… 8.80e4 30.39 34.0 36.0 30.0 PCB-118 6.01e4 34.64 108/119... PCB-99 6.75e4 2.94e4 31.37 30.90 Rel. Int. 100% 32.0 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PBM 4σ 4.29e3 34.0 CS/SS-111 3.46e7 32.66 JS-101 2.86e7 30.37 0.00e0 RT Abs. Int. 3.48e4 PCB-110 1.31e5 32.09 PCB-105 3.30e4 35.64 0% 28.0 1.02e4 ES-118 ES-114 3.46e7 ES-123 3.42e7 3.39e7 34.61 35.08 34.33 36.0 ES-105 3.52e7 35.62 1.74e4 0.00e0 RT Abs. Int. 9.07e6 4.54e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 2.23e7 32.66 JS-101 1.80e7 30.37 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PBM 4σ 3.30e3 ES-118 ES-114 ES-123 2.10e7 2.17e7 2.16e7 34.61 35.08 34.33 36.0 ES-105 2.22e7 35.62 0.00e0 RT Abs. Int. 5.73e6 2.86e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.82e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.41e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7250, 9315 scc: 441-024 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:59 (CEM) Printed: 06-Apr-2014 17:25 Page 11 of 21 56 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 1.82e4 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PB 4σ 1.07e3 9.08e3 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 4.07e4 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PB 4σ 1.20e3 2.03e4 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 3.62e6 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 2.20e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 4.39e6 ES-126 1.89e7 38.23 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PBM 4σ 4.81e3 0% 38.0 0.00e0 RT Abs. Int. 7.24e6 ES-126 3.03e7 38.23 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PBM 4σ 5.55e3 Rel. Int. 100% 0.00e0 RT 8.11e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2916, 9172 scc: 441-024 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:23 Printed: 06-Apr-2014 17:25 Page 12 of 21 57 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 147/149 5.10e4 33.66 Rel. Int. 100% HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 7.88e2 153/168 5.32e4 36.22 151/135 2.65e4 32.89 PCB-136 1.12e4 30.83 PCB-132 1.64e4 34.74 163/138… 5.06e4 37.28 PCB-146 1.40e4 35.68 8.11e3 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 6.84e2 PCB-136 8.52e3 30.82 0.00e0 RT 36.0 153/168 4.44e4 36.21 147/149 3.53e4 33.65 PCB-132 2.00e4 34.74 151/135 1.55e4 32.88 Abs. Int. 1.37e4 163/138… 3.98e4 37.29 6.87e3 PCB-146 1.11e4 35.69 0.00e0 RT 0% 28.0 30.0 32.0 34.0 36.0 ES-155 3.25e7 30.20 Rel. Int. 100% ES-153 2.32e7 36.20 HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PBM 4σ 1.39e3 Abs. Int. 1.62e4 JS-138 2.19e7 37.26 Abs. Int. 8.36e6 4.18e6 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 ES-155 2.61e7 30.20 Rel. Int. 100% ES-153 1.76e7 36.20 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PBM 4σ 1.25e3 Abs. Int. 6.60e6 JS-138 1.67e7 37.26 3.30e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.82e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.41e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3885, 6297 scc: 441-024 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:00 (CEM) Printed: 06-Apr-2014 17:25 Page 13 of 21 58 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 3.37e3 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PB 4σ 8.27e2 0% 38.0 1.69e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 3.86e3 HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PB 4σ 6.34e2 0% 38.0 1.93e3 39.0 Rel. Int. 100% 41.0 42.0 43.0 44.0 ES-156/157 5.44e7 40.78 39.0 40.0 ES-167 2.22e7 39.79 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PBM 4σ 3.89e3 Abs. Int. 9.56e6 ES-169 2.62e7 43.49 41.0 42.0 43.0 ES-156/157 4.24e7 40.78 44.0 0.00e0 RT Abs. Int. 7.45e6 ES-169 2.09e7 43.49 3.73e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT 4.78e6 Rel. Int. 100% 0% 38.0 40.0 ES-167 2.83e7 39.79 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PBM 4σ 2.46e3 0% 38.0 0.00e0 RT 8.11e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7022, 3727 scc: 441-024 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:23 Printed: 06-Apr-2014 17:25 Page 14 of 21 59 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 3.16e3 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PB 4σ 7.36e2 0% 30.0 1.58e3 31.0 32.0 33.0 34.0 35.0 36.0 0.00e0 RT 37.0 Rel. Int. 100% Abs. Int. 3.05e3 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PB 4σ 5.72e2 0% 30.0 1.52e3 31.0 32.0 33.0 34.0 35.0 36.0 ES-188 2.16e7 35.07 Rel. Int. 100% Abs. Int. 5.23e6 CS/SS-178 1.38e7 37.63 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PBM 4σ 1.14e3 0% 30.0 2.62e6 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 4.89e6 CS/SS-178 1.29e7 37.63 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PBM 4σ 1.95e3 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 2.45e6 0.00e0 RT Abs. Int. 2.82e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 0.00e0 RT 37.0 ES-188 2.00e7 35.07 Rel. Int. 100% 0% 30.0 0.00e0 RT 37.0 1.41e7 31.0 32.0 33.0 34.0 35.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8991, 1979 scc: 441-024 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:23 Printed: 06-Apr-2014 17:25 Page 15 of 21 60 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 4.74e3 HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PB 4σ 8.06e2 0% 38.0 2.37e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 4.41e3 HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PB 4σ 8.67e2 0% 38.0 2.21e3 39.0 40.0 41.0 42.0 ES-180 1.93e7 41.93 Rel. Int. 100% HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PBM 4σ 1.58e3 0% 38.0 43.0 44.0 Abs. Int. 4.48e6 ES-170 1.56e7 43.00 39.0 40.0 41.0 42.0 ES-180 1.77e7 41.93 43.0 44.0 0.00e0 RT Abs. Int. 4.27e6 ES-170 1.45e7 43.00 HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PBM 4σ 2.90e3 2.13e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT 2.24e6 Rel. Int. 100% 0% 38.0 0.00e0 RT 8.11e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9790, 9250 scc: 441-024 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:23 Printed: 06-Apr-2014 17:25 Page 16 of 21 61 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 3.10e3 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PB 4σ 1.02e3 1.55e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.47e3 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PB 4σ 6.46e2 1.23e3 0% 45.0 46.0 47.0 48.0 49.0 ES-189 2.24e7 45.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.40e6 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PBM 4σ 2.06e3 2.70e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 2.17e7 45.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.27e6 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PBM 4σ 2.69e3 2.64e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.71e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 3.86e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8304, 8829 scc: 441-024 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:23 Printed: 06-Apr-2014 17:25 Page 17 of 21 62 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 3.34e3 OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PB 4σ 7.27e2 0% 38.0 1.67e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 4.00e3 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PB 4σ 4.33e2 0% 38.0 2.00e3 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 1.86e7 39.61 Rel. Int. 100% 2.21e6 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 1.98e7 39.61 Rel. Int. 100% 2.37e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.62e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 4.74e6 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PBM 4σ 2.01e3 0% 38.0 0.00e0 RT Abs. Int. 4.41e6 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PBM 4σ 1.20e3 0% 38.0 0.00e0 RT 8.11e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5083, 8264 scc: 441-024 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:23 Printed: 06-Apr-2014 17:25 Page 18 of 21 63 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 1.37e3 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PB 4σ 8.99e2 6.83e2 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.79e3 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PB 4σ 5.87e2 1.40e3 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.34e7 47.37 49.0 ES-205 1.58e7 47.77 0.00e0 RT Abs. Int. 3.65e6 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PBM 4σ 1.70e3 1.83e6 0% 45.0 46.0 47.0 48.0 JS-194 1.48e7 47.37 Rel. Int. 100% 49.0 ES-205 1.75e7 47.77 0.00e0 RT Abs. Int. 4.07e6 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PBM 4σ 1.85e3 2.04e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.71e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 3.86e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0215, 3012 scc: 441-024 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:23 (CEM) Printed: 06-Apr-2014 17:25 Page 19 of 21 64 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 Rel. Int. 100% Abs. Int. 2.06e3 NoCB 44.77-49.81 461.7245 Fn6 Flags: PB 4σ 9.94e2 1.03e3 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. 100% Abs. Int. 3.59e3 NoCB 44.77-49.81 463.7216 Fn6 Flags: PB 4σ 1.67e3 1.80e3 0.00e0 RT 0% 45.0 46.0 47.0 48.0 49.0 ES-208 1.57e7 45.23 Rel. Int. 100% ES-206 1.08e7 49.23 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PBM 4σ 2.28e3 Abs. Int. 3.69e6 1.84e6 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 ES-208 2.00e7 45.23 Rel. Int. 100% ES-206 1.35e7 49.23 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PBM 4σ 2.71e3 Abs. Int. 4.83e6 2.41e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.71e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 3.86e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5287, 1399 scc: 441-024 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:23 Printed: 06-Apr-2014 17:25 Page 20 of 21 65 of 603 SGS ID: MB1_11906_PCB_TLX-RJ Instr: [ILM] AutoSpec-Premier MM7 Sample ID: Method Blank VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 21 Acq: 03-Apr-2014 17:21:41 User: LKB Datafile: 140403X06 PCB-209 9.08e3 50.69 Rel. Int. 100% Abs. Int. 2.70e3 DeCB 49.82-52.00 497.6826 Fn7 Flags: PBM 4σ 3.61e2 1.35e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 8.07e3 50.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.90e3 DeCB 49.82-52.00 499.6797 Fn7 Flags: PBM 4σ 7.49e2 1.45e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.66e7 50.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.54e6 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PBM 4σ 9.51e2 1.77e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.39e7 50.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.94e6 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PBM 4σ 7.86e2 1.47e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.35e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 3.68e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\MB1_11906_PCB_TLX-RJ.utp_res, saved 05-Apr-2014 03:00 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7620, 9861 scc: 441-024 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:23 (CEM) Printed: 06-Apr-2014 17:25 Page 21 of 21 66 of 603 Lab ID: A6528_11906_PCB_001 ACQ: 02-Apr-2014 07:45:18 LKB Wt/Vol: 1.22 L Client ID: PB099-1SWMID-140319-N (TOTAL) UTP: 05-Apr-2014 00:48 CEM J-level: 8.22 pg/L Datafile: 140402X10 RPT: 06-Apr-2014 16:18 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.68 NotFnd 35.66 NotFnd 34.65 NotFnd NotFnd 40.80 NotFnd NotFnd NotFnd 50.70 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.82 14.10 14.34 20.04 17.41 26.34 20.31 32.66 32.19 25.27 35.64 35.10 34.63 34.35 38.25 36.21 30.21 40.79 39.81 43.51 43.02 41.95 35.09 45.63 39.62 47.79 49.26 45.25 50.68 QC J EMPC C J B EMPC Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0007 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0000 1.0006 1.0006 1.0006 1.0001 1.0005 0 0.7244 0.8640 0.8793 1.2279 1.0674 1.0793 0.8322 1.3381 1.3186 0.8317 1.1729 1.1551 1.1398 1.1306 1.2588 0.9715 0.8106 1.0943 1.0679 1.1671 0.9078 0.8852 0.7404 0.9628 0.8361 1.0084 1.0393 0.9547 1.0692 0.7243 0.8642 0.8792 1.2283 1.0673 1.0795 0.8322 1.3384 1.3189 0.8317 1.1730 1.1551 1.1399 1.1306 1.2590 0.9715 0.8105 1.0944 1.0680 1.1673 0.9078 0.8852 0.7403 0.9628 0.8360 1.0084 1.0393 0.9547 1.0693 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140402_PCB_XA Split: 1 Checkcode: 065-928-ZGC Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.84 +1.5 2.17E+05 0.00E+00 3.94E+05 0.00E+00 8.88E+05 0.00E+00 0.00E+00 4.66E+04 0.00E+00 0.00E+00 0.00E+00 1.95E+04 0.79 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 12.9 ND 29 ND 63.5 ND ND 3.87 ND ND ND 2.41 3.96E+03 3.96E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 2.04E+03 1.55E+03 1.55E+03 1.55E+03 1.50E+03 1.23E+03 2.45 2.53 1.48 1.29 1.32 1.27 1.64 1.87 1.28 1.32 1.36 1.73 -0.1 +0.2 -0.1 +0.5 -0.1 +0.3 0 +0.6 +0.6 0 +0.2 0 +0.2 0 +0.5 0 -0.2 +0.2 +0.2 +0.5 0 0 -0.2 0 -0.2 0 0 0 +0.3 2.44E+07 2.45E+07 1.22E+07 3.28E+07 1.24E+07 2.67E+07 1.38E+07 2.40E+07 2.35E+07 1.42E+07 2.00E+07 1.95E+07 1.93E+07 1.97E+07 1.86E+07 1.41E+07 1.88E+07 3.60E+07 1.81E+07 1.85E+07 1.12E+07 1.33E+07 1.38E+07 1.78E+07 1.29E+07 1.34E+07 9.23E+06 1.37E+07 1.19E+07 3.26 3.38 1.65 1.60 1.10 1.11 0.79 0.80 0.83 1.74 1.65 1.61 1.63 1.61 1.52 1.31 1.29 1.31 1.23 1.31 1.11 1.12 1.07 1.06 0.94 0.88 0.79 0.78 1.17 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 57.4 % 63.2 % 65.7 % 88.4 % 68.8 % 91.2 % 91.3 % 98.5 % 97.8 % 109 % 103 % 99 % 103 % 102 % 112 % 93.6 % 87.2 % 82.7 % 80 % 87.6 % 89.5 % 89.2 % 108 % 97.7 % 97.7 % 93.4 % 96.6 % 101 % 93.3 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% -0.2 -0.2 -1.0 Page 1 of 5 0.53 0.61 0.99 Printed: 4/6/2014 5:19 PM 67 of 603 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.79 32.67 37.65 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 3.06E+07 2.01E+07 8.71E+06 1.12 1.58 1.04 1.11 1.03 0.62 103 % 99 % 102 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.79 32.67 37.65 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 3.06E+07 2.01E+07 8.71E+06 1.12 1.58 1.04 1.85 1.22 0.58 94.2 % 101 % 110 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.31 24.40 30.38 37.27 47.39 3.57E+07 1.76E+07 1.62E+07 1.36E+07 1.15E+07 1.60 0.79 1.64 1.33 0.90 4.55E+03 4.55E+03 4.55E+03 1.04E+04 1.04E+04 9.57E+03 9.57E+03 9.57E+03 9.57E+03 9.57E+03 9.57E+03 9.57E+03 9.57E+03 9.57E+03 5.88E+03 5.88E+03 5.88E+03 5.88E+03 5.88E+03 5.88E+03 2.07 1.96 2.29 8.42 5.41 4.4 3.84 4.12 4.09 4 3.46 4.02 4 4.19 5.41 4.02 4.76 3.45 3.51 6.51 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.83 13.93 14.11 14.36 NotFnd NotFnd NotFnd 16.72 NotFnd 17.14 NotFnd 19.48 19.75 20.05 17.43 19.19 19.58 19.77 NotFnd 20.00 J EMPC B C C EMPC 1.0011 0.9880 1.0009 1.0011 1.0135 1.0010 1.0111 1.0250 1.0435 1.0507 0.9331 0.9720 0.9866 1.0008 1.0010 1.1017 1.1247 1.1357 1.1435 1.1489 1.0010 0.9879 1.0009 1.0011 1.0250 1.0509 0.9722 0.9857 1.0006 1.0010 1.1022 1.1248 1.1357 1.1491 -0.1 -0.1 0 0 0 +0.2 +0.2 -1.1 -0.2 0 +0.6 +0.1 0 +0.2 Page 2 of 5 NON-EMPC 25.5 248 1,060 1,550 530 127 15.4 0 0 2.36E+05 6.51E+04 1.33E+05 8.47E+05 0.00E+00 0.00E+00 0.00E+00 1.10E+06 0.00E+00 8.30E+05 0.00E+00 4.86E+05 3.70E+05 4.79E+05 3.99E+05 2.35E+06 8.66E+05 1.76E+05 0.00E+00 5.08E+05 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 29.2 248 1,070 1,550 540 131 29.6 0 0 3.12 2.54 3.37 1.73 1.67 1.64 SI SI SI 1.13 1.05 1.05 1.34 1.11 0.95 1.18 1.01 1.23 1.92 0.97 1.11 1.04 1.04 1.07 1.24 1.06 1.07 1.02 1.15 1.55 1.30 1.80 1.77 0.95 DL 2.18 6.3 4.98 2.32 1.36 1.38 1.4 1.51 4.19 16.7 3.71 8.82 92.3 ND ND ND 53 ND 39 ND 23 17.4 23.5 46.1 201 87.9 13 ND 70.6 Printed: 4/6/2014 5:19 PM 68 of 603 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.48 NotFnd NotFnd 22.04 22.26 22.54 22.81 23.02 23.38 NotFnd NotFnd NotFnd NotFnd 26.37 NotFnd 22.29 22.89 22.96 23.18 24.43 NotFnd NotFnd 24.87 25.13 25.32 25.61 25.79 26.11 26.22 26.41 NotFnd 27.39 NotFnd NotFnd 28.12 28.34 28.65 28.91 NotFnd 29.50 29.69 NotFnd NotFnd NotFnd NotFnd 25.61 NotFnd NotFnd SGS Evironmental Services QC C C C C C C J C C J EMPC J C J EMPC Pred RRT Actual RRT Diff Secs 1.1763 0.8211 0.8268 0.8375 0.8451 0.8556 0.8663 0.8732 0.8875 0.9397 0.9520 0.9721 0.9871 1.0008 1.0010 0.9141 0.9381 0.9410 0.9497 1.0009 1.0062 1.0102 1.0181 1.0296 1.0385 1.0498 1.0566 1.0702 1.0741 1.0823 0.8429 0.8509 0.8624 0.8687 0.8736 0.8806 0.8897 0.8984 0.9030 0.9165 0.9225 0.9326 0.9737 0.9888 1.0009 1.0135 0.8985 0.9048 1.1764 0.8366 0.8449 0.8555 0.8659 0.8738 0.8874 1.0010 0.9132 0.9380 0.9409 0.9497 1.0010 1.0190 1.0297 1.0377 1.0494 1.0566 1.0701 1.0742 1.0823 0.8509 0.8736 0.8806 0.8900 0.8983 0.9165 0.9224 1.0136 - +0.1 -1.2 -0.3 -0.1 -0.5 +0.8 -0.1 +0.3 -1.2 -0.1 -0.1 0 +0.1 +1.3 +0.2 -1.2 -0.6 0 -0.2 +0.2 0 0 0 0 +0.5 -0.2 0 -0.2 +0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 1.32E+06 0.00E+00 0.00E+00 1.10E+06 1.32E+06 3.49E+06 3.62E+06 7.04E+05 9.37E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.15E+05 0.00E+00 6.40E+05 3.36E+05 5.28E+05 1.79E+05 3.06E+06 0.00E+00 0.00E+00 2.06E+06 3.66E+05 2.96E+06 2.79E+05 6.54E+05 9.72E+04 1.28E+06 1.45E+06 0.00E+00 5.01E+05 0.00E+00 0.00E+00 6.36E+04 1.32E+05 3.54E+06 2.18E+06 0.00E+00 1.14E+06 4.66E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.64E+04 0.00E+00 0.00E+00 1.07 1.93 1.24 1.25 1.27 1.31 1.32 1.23 1.29 1.19 1.34 1.34 1.21 1.16 1.08 1.35 0.85 0.70 0.90 0.68 0.83 1.16 0.68 1.03 0.85 0.90 1.18 0.76 0.67 0.87 1.24 1.25 1.32 1.19 1.21 1.29 1.34 1.22 1.16 1.15 1.15 1.16 1.35 1.40 1.12 1.43 1.19 0.96 0.80 90.7 ND ND 53.4 62.1 162 181 33.7 48.7 ND ND ND ND 23.7 ND 52.4 33.4 41.1 18.4 256 ND ND 139 30.2 229 16.6 59.7 10.1 102 81.6 ND 26.6 ND ND 3.45 6.86 203 131 ND 69.4 27.9 ND ND ND ND 2.57 ND ND 0.96 1.03 1.02 0.99 1.02 0.96 0.96 0.78 0.83 0.78 0.75 0.78 0.78 0.83 0.79 0.73 0.76 0.78 0.80 0.81 0.76 1.11 0.86 0.82 0.82 0.78 0.78 0.76 Noise / Recv. Low DL / Recv. High 5.88E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 8.03E+03 2.55E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 2.77E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 3.96E+03 1.55E+03 1.55E+03 1.87E+03 1.87E+03 3.22 3.98 3.93 3.87 3.76 3.71 4 3.82 4.15 3.67 3.67 4.08 4.24 4.56 1.93 2.32 2.81 2.2 2.91 2.37 1.71 2.91 1.92 2.34 2.19 1.68 2.59 2.95 2.27 1.59 2.27 2.15 2.37 2.33 2.2 2.11 2.32 2.44 2.45 2.47 2.43 2.09 2.02 2.52 1.16 1.4 1.6 1.91 Printed: 4/6/2014 5:19 PM 69 of 603 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.87 NotFnd 28.20 NotFnd NotFnd 28.63 28.82 NotFnd NotFnd 29.90 30.41 30.81 30.91 NotFnd 31.39 31.89 31.98 32.10 NotFnd 32.38 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.85 NotFnd NotFnd 32.90 NotFnd NotFnd 33.68 NotFnd NotFnd NotFnd NotFnd NotFnd 34.75 NotFnd NotFnd 35.71 NotFnd 36.23 SGS Evironmental Services QC C J C J EMPC C J EMPC C C J B J B C B C C B J B B C Pred RRT Actual RRT Diff Secs 0.9173 0.9243 0.9278 0.9301 0.9402 0.9423 0.9486 0.9623 0.9735 0.9840 0.9999 1.0144 1.0175 1.0208 1.0321 1.0496 1.0527 1.0566 1.0594 1.0659 1.0761 1.0892 0.9915 0.9975 1.0039 1.0091 1.0351 1.0007 1.0062 1.0108 1.0210 1.0299 1.0719 1.0891 1.0960 1.1048 1.1148 1.1205 1.1231 1.1319 1.1377 1.1425 1.1502 1.1636 0.9523 0.9580 0.9612 0.9727 0.9173 0.9280 0.9421 0.9486 0.9841 1.0007 1.0142 1.0173 1.0331 1.0497 1.0525 1.0566 1.0658 1.0210 1.0890 1.1146 1.1503 0.9579 0.9721 0 +0.3 -0.3 0 +0.2 +1.5 -0.4 -0.4 +1.9 +0.2 -0.4 0 -0.2 0 -0.2 -0.4 +0.2 -0.2 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 6.91E+05 0.00E+00 4.57E+04 0.00E+00 0.00E+00 1.89E+05 2.73E+05 0.00E+00 0.00E+00 1.54E+05 8.16E+05 3.66E+04 4.98E+05 0.00E+00 7.38E+05 3.18E+04 2.05E+05 1.25E+06 0.00E+00 1.24E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.80E+04 0.00E+00 0.00E+00 9.16E+04 0.00E+00 0.00E+00 2.09E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 8.84E+04 0.00E+00 0.00E+00 4.60E+04 0.00E+00 2.82E+05 0.59 0.87 0.87 0.86 0.89 0.81 0.91 0.72 0.77 1.22 0.83 0.97 0.73 0.91 1.17 0.99 1.08 0.99 1.13 1.18 0.69 1.23 1.23 1.11 1.28 1.11 1.01 1.11 1.26 1.08 1.11 1.02 1.04 1.10 1.05 1.24 1.09 1.09 0.79 1.08 1.11 0.93 0.92 0.96 1.02 1.32 1.14 1.41 1.40 66.4 ND 4.44 ND ND 17.3 31.5 ND ND 15.6 69.9 4.19 45.9 ND 62.3 2.46 17.3 92.3 ND 15 ND ND ND ND ND ND ND ND ND ND 4.98 ND ND 10.1 ND ND 22.5 ND ND ND ND ND 10.8 ND ND 4.71 ND 23.5 0.70 0.60 0.61 0.64 0.64 0.43 0.70 0.59 0.81 0.64 0.63 0.64 1.35 1.17 1.20 1.17 1.15 1.42 Noise / Recv. Low DL / Recv. High 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.87E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.77 1.76 1.79 1.73 1.9 1.68 2.12 1.99 1.25 1.86 1.58 2.1 1.69 1.31 1.55 1.42 1.55 1.36 1.3 2.21 1.25 1.24 1.38 1.2 1.38 1.54 1.48 1.04 1.21 1.17 1.29 1.25 1.59 1.65 1.4 1.6 1.6 2.22 1.61 1.57 1.87 1.9 1.82 1.7 1.32 1.53 1.24 1.25 Printed: 4/6/2014 5:19 PM 70 of 603 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.41 NotFnd NotFnd NotFnd 37.30 NotFnd 37.63 38.38 NotFnd NotFnd NotFnd 35.40 NotFnd NotFnd NotFnd NotFnd NotFnd 38.45 NotFnd 38.96 NotFnd 39.15 NotFnd NotFnd NotFnd NotFnd NotFnd 41.97 NotFnd 43.04 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J B C J J C J J EMPC J J EMPC C J C J EMPC C Pred RRT Actual RRT Diff Secs 0.9766 0.9859 0.9912 0.9934 1.0011 1.0049 1.0097 0.9639 0.9843 0.9903 1.0006 1.0087 1.0217 1.0302 1.0415 1.0736 1.0891 1.0956 1.1007 1.1105 1.1129 1.1160 1.1268 1.1366 1.1419 0.9077 0.9131 0.9191 0.9264 0.9433 0.9531 1.0005 1.0203 1.0348 1.0396 1.0419 1.1005 1.1150 1.1192 0.9515 0.9921 1.0004 1.0005 1.0179 1.0004 0.9767 1.0006 1.0095 0.9642 1.0089 1.0959 1.1105 1.1159 0.9197 0.9431 - +0.2 -1.1 -0.5 +0.7 +0.4 +0.7 0 -0.2 +1.5 -0.5 Page 5 of 5 Response Ra RRF Conc. / Recv. 4.48E+04 0.00E+00 0.00E+00 0.00E+00 3.50E+05 0.00E+00 4.89E+04 5.35E+04 0.00E+00 0.00E+00 0.00E+00 2.27E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.17E+04 0.00E+00 2.73E+04 0.00E+00 3.11E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.03E+05 0.00E+00 2.90E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.18 1.02 0.90 1.14 1.38 1.13 1.29 1.52 0.88 1.07 1.09 1.27 1.07 1.03 1.14 1.05 0.75 1.08 1.16 1.20 1.24 1.04 1.00 0.93 1.08 0.95 0.98 1.30 1.24 1.39 1.12 1.57 1.05 1.12 1.05 1.12 1.06 0.72 0.75 0.77 0.73 0.81 1.06 1.12 1.15 1.11 5.15 ND ND ND 36.2 ND 3.77 5.47 ND ND ND 2.54 ND ND ND ND ND 6.57 ND 2.72 ND 3.84 ND ND ND ND ND 10.2 ND 3.79 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1.31 1.10 1.33 1.13 1.22 1.11 1.33 0.98 1.65 Noise / Recv. Low DL / Recv. High 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.53E+03 1.55E+03 1.55E+03 1.55E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.22E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.33E+03 1.18E+03 1.18E+03 1.18E+03 3.04E+03 3.04E+03 3.04E+03 1.72 1.94 1.53 1.26 1.54 1.35 1.15 1.68 1.39 1.37 1.11 1.32 1.37 1.24 1.33 1.87 1.49 1.39 1.33 1.3 1.54 1.61 1.72 1.49 1.69 1.64 1.24 1.3 1.15 1.53 1.09 1.6 1.51 1.6 1.5 1.58 2.35 2.23 2.18 2.06 1.85 1.42 3.32 3.26 5.05 Printed: 4/6/2014 5:19 PM 71 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 3.12e7 1.56e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 2.42e7 1.21e7 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 1.60e7 7.98e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 1.14e7 5.69e6 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 6.36e6 3.18e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.21e6 2.60e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 5.18e6 2.59e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 065-928 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:22 Page 1 of 21 72 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 PCB-1 1.79e5 11.83 Rel. Int. 100% Abs. Int. 7.72e4 MoCB 10.03-15.71 188.0393 Fn1 Flags: PBM 4σ 2.66e3 PCB-3 1.02e5 14.11 PCB-2 4.93e4 13.93 3.86e4 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 5.73e4 11.82 Rel. Int. 100% Abs. Int. 2.54e4 MoCB 10.03-15.71 190.0363 Fn1 Flags: PBM 4σ 1.89e3 PCB-3 3.04e4 14.11 PCB-2 1.94e4 13.93 1.27e4 0% 11.0 12.0 13.0 ES-1 1.87e7 11.82 Rel. Int. 100% 0.00e0 RT 14.0 15.0 0.00e0 RT Abs. Int. 7.25e6 ES-3 1.89e7 14.10 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PBM 4σ 4.92e3 3.62e6 0% 11.0 12.0 13.0 ES-1 5.73e6 11.81 Rel. Int. 100% 14.0 15.0 0.00e0 RT Abs. Int. 2.31e6 ES-3 5.59e6 14.10 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PBM 4σ 3.34e4 1.15e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.12e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.56e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4064, 4755 scc: 065-928 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:47 (CEM) Printed: 06-Apr-2014 17:22 Page 2 of 21 73 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 PCB-4 5.37e5 14.36 Rel. Int. 100% Abs. Int. 1.85e5 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PBM 4σ 6.35e3 9.24e4 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 3.10e5 14.36 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.32e5 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PBM 4σ 1.38e4 6.58e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 7.62e6 14.34 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e6 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PBM 4σ 7.35e3 1.29e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.61e6 14.34 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.57e6 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PBM 4σ 3.87e3 7.87e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.12e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.56e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9589, 1448 scc: 065-928 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:48 (CEM) Printed: 06-Apr-2014 17:22 Page 3 of 21 74 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PCB-6 6.86e5 16.72 DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PBM 4σ 5.83e3 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Abs. Int. 2.19e5 PCB-8 5.15e5 17.14 PCB-11 2.96e5 SI 19.48 13/12 2.26e5 SI 19.75 PCB-15 2.92e5 SI 20.05 1.09e5 0% 16.0 17.0 Rel. Int. 100% PCB-6 4.10e5 16.72 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PBM 4σ 2.54e4 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 1.70e5 PCB-8 3.15e5 17.14 8.50e4 0% 16.0 17.0 18.0 19.0 20.0 JS-9 2.20e7 16.31 Rel. Int. 100% 21.0 Abs. Int. 6.79e6 ES-15 2.02e7 20.04 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PBM 4σ 1.93e4 (2.02e7 + 1.26e7) * 2000 pg * 100 = 88.3% (2.20e7 + 1.37e7) * 2000 pg * 1.04 CEM 06-Apr-2014 16:31 3.40e6 Recv(ES-15) = 0% 16.0 17.0 18.0 19.0 JS-9 1.37e7 16.31 Rel. Int. 100% 20.0 21.0 0.00e0 RT Abs. Int. 4.20e6 ES-15 1.26e7 20.04 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PBM 4σ 4.93e3 0.00e0 RT 2.10e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.42e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.21e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7960, 4791 scc: 065-928 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:32 (CEM) Printed: 06-Apr-2014 17:22 Page 4 of 21 75 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Rel. Int. 100% Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Abs. Int. 3.60e5 30/18 1.20e6 19.19 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PBM 4σ 3.17e3 PCB-17 4.44e5 19.58 PCB-19 2.12e5 17.43 PCB-27 1.16e5 19.77 PCB-16 2.67e5 20.00 PCB-32 6.84e5 20.48 1.80e5 0% 16.0 17.0 18.0 Rel. Int. 100% 19.0 20.0 21.0 Abs. Int. 3.50e5 30/18 1.14e6 19.19 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PBM 4σ 2.71e3 PCB-17 4.22e5 19.58 PCB-19 1.87e5 17.43 PCB-27 8.63e4 19.78 PCB-16 2.41e5 20.00 PCB-32 6.38e5 20.48 1.75e5 0% 16.0 17.0 18.0 19.0 0.00e0 RT 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.50e6 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PBM 4σ 7.04e4 ES-19 6.49e6 17.41 3.75e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-19 5.91e6 17.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.90e6 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PBM 4σ 2.46e4 9.49e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.42e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.21e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3791, 3570 scc: 065-928 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:33 (CEM) Printed: 06-Apr-2014 17:22 Page 5 of 21 76 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 PCB-31 1.76e6 22.54 Rel. Int. 100% TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 4.76e3 26/29 5.38e5 22.04 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 28/20 1.80e6 22.81 PCB-25 6.67e5 22.26 Abs. Int. 4.78e5 21/33 3.56e5 23.02 2.39e5 PCB-22 4.58e5 23.38 PCB-37 2.03e5 26.37 0% 22.0 23.0 PCB-31 1.72e6 22.54 Rel. Int. 100% TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 3.26e3 26/29 5.63e5 22.04 PCB-25 6.50e5 22.26 24.0 25.0 0.00e0 RT 26.0 28/20 1.82e6 22.81 Abs. Int. 4.74e5 21/33 3.48e5 23.02 2.37e5 PCB-22 4.79e5 23.38 PCB-37 2.12e5 26.37 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 1.62e7 22.79 Rel. Int. 100% ES-37 1.40e7 26.34 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PBM 4σ 7.47e4 Abs. Int. 4.44e6 2.22e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 1.45e7 22.79 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 1.26e7 26.35 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PBM 4σ 2.05e4 Abs. Int. 4.03e6 2.02e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 7.98e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4154, 2446 scc: 065-928 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:33 (CEM) Printed: 06-Apr-2014 17:22 Page 6 of 21 77 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Rel. Int. 100% Abs. Int. 2.80e3 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PB 4σ 1.11e3 1.40e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.99e3 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PB 4σ 1.44e3 2.00e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 6.09e6 20.31 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.77e6 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PBM 4σ 1.05e4 8.87e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 7.75e6 20.31 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.34e6 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PBM 4σ 6.71e3 1.17e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.42e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.21e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2352, 1264 scc: 065-928 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:27 Printed: 06-Apr-2014 17:23 Page 7 of 21 78 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 PCB-52 1.34e6 24.43 Rel. Int. 100% TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 1.46e3 50/53 2.81e5 22.29 69/49 9.01e5 24.87 PCB-51 2.32e5 22.96 PCB-45 1.53e5 22.89 PCB-48 1.67e5 25.13 PCB-46 7.69e4 23.18 Abs. Int. 3.64e5 44/47… 1.31e6 25.32 59/62… 1.18e5 25.61 PCB-42 2.83e5 25.79 71/40 5.66e5 26.22 PCB-64 6.52e5 26.41 0% 22.0 23.0 24.0 25.0 PCB-52 1.72e6 24.43 Rel. Int. 100% TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 1.30e3 50/53 3.59e5 22.28 PCB-45 1.83e5 22.89 PCB-48 1.99e5 25.13 PCB-46 1.02e5 23.18 Abs. Int. 4.54e5 59/62… 1.61e5 25.61 PCB-42 3.71e5 25.79 0% 22.0 23.0 24.0 25.0 26.0 JS-52 7.79e6 24.40 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 1.65e6 25.32 69/49 1.15e6 24.87 PCB-51 2.97e5 22.96 1.82e5 71/40 7.11e5 26.22 PCB-64 8.01e5 26.41 2.27e5 0.00e0 RT Abs. Int. 2.13e6 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PBM 4σ 2.43e4 1.06e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 9.81e6 24.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.62e6 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PBM 4σ 1.89e4 1.31e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 7.98e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5370, 9948 scc: 065-928 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:27 Printed: 06-Apr-2014 17:23 Page 8 of 21 79 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 1.66e3 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Abs. Int. 2.74e5 PCB-66 9.83e5 28.91 PCB-68 2.16e5 27.39 PCB-56 4.97e5 29.50 PCB-63 6.09e4 28.34 PCB-60 2.05e5 29.69 PCB-77 9.91e4 32.68 0% 28.0 30.0 (9.91e4 + 1.18e5) * 2000 pg/ul = 12.9 pg/L (1.07e7 + 1.33e7) * 1.15 * 1.217L CEM 06-Apr-2014 16:30 PCB-68 2.85e5 27.39 32.0 34.0 36.0 1.63e5 PCB-60 2.61e5 29.69 PCB-77 1.18e5 32.68 0% 28.0 0.00e0 RT Abs. Int. 3.26e5 PCB-56 6.41e5 29.50 PCB-63 7.10e4 28.34 1.37e5 Conc(PCB-77) = 61/70... 1.94e6 28.65 Rel. Int. 100% TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 2.30e3 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 30.0 Rel. Int. 100% 32.0 ES-81 1.07e7 32.19 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PBM 4σ 2.75e4 34.0 36.0 0.00e0 RT Abs. Int. 2.63e6 ES-77 1.07e7 32.66 1.31e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 1.29e7 32.19 34.0 36.0 0.00e0 RT Abs. Int. 3.24e6 ES-77 1.33e7 32.66 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PBM 4σ 1.58e4 1.62e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 5.69e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6896, 4196 scc: 065-928 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:34 (CEM) Printed: 06-Apr-2014 17:23 Page 9 of 21 80 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 PCB-96 1.24e4 25.61 Rel. Int. 100% Abs. Int. 4.70e3 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 7.81e2 2.35e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 1.63e4 25.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e3 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 7.72e2 2.63e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 8.99e6 25.27 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.43e6 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PBM 4σ 2.46e3 1.21e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 5.18e6 25.27 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e6 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PBM 4σ 1.60e3 7.03e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 7.98e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9120, 0882 scc: 065-928 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:35 (CEM) Printed: 06-Apr-2014 17:23 Page 10 of 21 81 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 PCB-110 4.83e5 32.10 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 8.57e2 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 PCB-95 2.55e5 27.87 PCB-91 PCB-84 7.10e4 1.03e5 28.63 28.82 113/90… 3.17e5 30.41 PCB-99 2.05e5108/119... 30.91 2.73e5 116/85 PCB-92 31.39 8.02e4 6.04e4 31.98 29.90 Abs. Int. 1.30e5 PCB-118 3.37e5 34.65 PCB-105 1.37e5 35.66 PCB-82 4.88e4 32.38 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 1.01e3 32.0 113/90… 4.98e5 30.41 PCB-95 4.36e5 27.87 PCB-91 1.18e5 28.63 PCB-84 1.70e5 28.82 PCB-92 9.39e4 29.90 34.0 PCB-110 7.63e5 32.10 PCB-99108/119... 2.93e5 4.65e5 30.91 31.39 116/85 1.25e5 PCB-83 31.97 3.29e4 30.81 36.0 PCB-105 2.57e5 35.66 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 1.23e7 32.67 JS-101 1.01e7 30.38 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PBM 4σ 2.27e3 34.0 ES-118 ES-114 1.21e7 ES-123 1.20e7 1.21e7 34.63 35.10 34.35 0.00e0 RT Abs. Int. 1.79e5 PCB-118 5.51e5 34.65 PCB-82 7.57e4 32.39 6.50e4 36.0 ES-105 1.25e7 35.64 8.97e4 0.00e0 RT Abs. Int. 3.09e6 1.54e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 7.77e6 32.67 JS-101 6.13e6 30.38 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PBM 4σ 3.09e3 ES-118 ES-114 7.49e6 ES-123 7.33e6 7.54e6 34.63 35.10 34.35 36.0 ES-105 7.56e6 35.64 0.00e0 RT Abs. Int. 1.97e6 9.85e5 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 5.69e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8878, 5126 scc: 065-928 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:35 (CEM) Printed: 06-Apr-2014 17:23 Page 11 of 21 82 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Rel. Int. 100% Abs. Int. 4.66e5 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PB 4σ 9.55e2 2.33e5 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 1.08e6 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PB 4σ 1.08e3 5.38e5 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 1.39e6 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 9.02e5 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.36e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 1.80e6 ES-126 7.37e6 38.25 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PBM 4σ 3.58e3 0% 38.0 0.00e0 RT Abs. Int. 2.78e6 ES-126 1.12e7 38.25 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PBM 4σ 4.74e3 Rel. Int. 100% 0.00e0 RT 3.18e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4279, 0289 scc: 065-928 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:29 (CEM) Printed: 06-Apr-2014 17:23 Page 12 of 21 83 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 153/168 1.65e5 36.23 Rel. Int. 100% 163/138… 1.99e5 37.30 147/149 1.14e5 33.68 HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 6.58e2 PCB-136 3.33e4 30.85 PCB-132 4.77e4 34.75 151/135 4.94e4 32.90 PCB-146 2.46e4 35.71 PCB-141 2.42e4 36.41 PCB-158 2.56e4 37.63 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 8.67e2 PCB-136 2.46e4 30.85 153/168 1.16e5 36.24 PCB-132 4.07e4 34.76 151/135 4.22e4 32.90 PCB-141 2.06e4 36.40 PCB-146 2.14e4 35.71 163/138… 1.51e5 37.30 PCB-158 2.33e4 37.63 30.0 32.0 34.0 ES-155 1.06e7 30.21 Rel. Int. 100% 36.0 ES-153 7.97e6 36.21 HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PBM 4σ 1.61e3 Abs. Int. 3.83e4 1.91e4 0.00e0 RT 0% 28.0 2.24e4 0.00e0 RT 36.0 147/149 9.54e4 33.68 Abs. Int. 4.48e4 JS-138 7.77e6 37.27 Abs. Int. 2.70e6 1.35e6 0% 28.0 30.0 32.0 34.0 ES-155 8.23e6 30.21 Rel. Int. 100% ES-153 6.10e6 36.21 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PBM 4σ 1.39e3 0.00e0 RT 36.0 JS-138 5.83e6 37.28 Abs. Int. 2.03e6 1.02e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 5.69e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8280, 0739 scc: 065-928 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:37 (CEM) Printed: 06-Apr-2014 17:23 Page 13 of 21 84 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 128/166 3.05e4 38.38 3.87e3 0% 38.0 39.0 40.0 128/166 2.30e4 38.38 39.0 43.0 44.0 40.0 41.0 42.0 43.0 44.0 0.00e0 RT Abs. Int. 3.53e6 ES-169 1.05e7 43.51 ES-167 1.00e7 39.81 1.77e6 39.0 Rel. Int. 100% 40.0 ES-167 8.13e6 39.81 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PBM 4σ 3.36e3 41.0 42.0 43.0 ES-156/157 1.56e7 40.80 44.0 0.00e0 RT Abs. Int. 2.74e6 ES-169 8.02e6 43.51 1.37e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.36e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 8.23e3 ES-156/157 2.04e7 40.79 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PBM 4σ 4.14e3 0% 38.0 42.0 4.12e3 Rel. Int. 100% 0% 38.0 41.0 156/157 2.62e4 40.81 HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 6.15e2 0% 38.0 Abs. Int. 7.75e3 156/157 2.59e4 40.80 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 9.38e2 Rel. Int. 100% Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 3.18e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7697, 0097 scc: 065-928 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:30 (CEM) Printed: 06-Apr-2014 17:23 Page 14 of 21 85 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 PCB-179 1.20e4 35.40 Rel. Int. 100% Abs. Int. 3.86e3 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 6.77e2 0% 30.0 1.93e3 31.0 32.0 33.0 34.0 35.0 36.0 0.00e0 RT 37.0 PCB-179 1.07e4 35.39 Rel. Int. 100% Abs. Int. 4.73e3 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 5.40e2 0% 30.0 2.37e3 31.0 32.0 33.0 34.0 35.0 36.0 ES-188 7.12e6 35.09 Rel. Int. 100% Abs. Int. 1.84e6 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PBM 4σ 1.35e3 0% 30.0 CS/SS-178 4.45e6 37.65 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 1.60e6 CS/SS-178 4.26e6 37.65 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PBM 4σ 1.62e3 7.99e5 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 9.21e5 0.00e0 RT 37.0 ES-188 6.63e6 35.09 Rel. Int. 100% 0% 30.0 0.00e0 RT 37.0 5.69e6 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2013, 8342 scc: 065-928 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:37 (CEM) Printed: 06-Apr-2014 17:23 Page 15 of 21 86 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 6.01e2 HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 6.16e2 0% 38.0 180/193 5.07e4 41.97 PCB-187 3.68e4 38.45 PCB-183 1.44e4 38.96 0% 38.0 Rel. Int. 100% Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Abs. Int. 1.21e4 PCB-170 2.34e4 43.04 PCB-174 2.03e4 39.15 39.0 6.04e3 40.0 41.0 42.0 43.0 44.0 180/193 5.18e4 41.97 PCB-187 3.02e4 38.44 PCB-183 1.29e4 38.97 39.0 Abs. Int. 1.23e4 PCB-170 1.42e4 43.04 PCB-174 1.53e4 39.16 40.0 41.0 42.0 ES-180 7.06e6 41.95 Rel. Int. 100% 43.0 6.13e3 44.0 ES-170 5.92e6 43.02 8.23e5 39.0 40.0 41.0 42.0 ES-180 6.29e6 41.95 Rel. Int. 100% 43.0 44.0 ES-170 5.32e6 43.02 7.66e5 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.36e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 1.53e6 HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PBM 4σ 1.70e3 0% 38.0 0.00e0 RT Abs. Int. 1.65e6 HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PBM 4σ 3.18e3 0% 38.0 0.00e0 RT 3.18e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9060, 0648 scc: 065-928 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:31 (CEM) Printed: 06-Apr-2014 17:23 Page 16 of 21 87 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Rel. Int. 100% Abs. Int. 2.10e3 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PB 4σ 8.13e2 1.05e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.30e3 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PB 4σ 6.87e2 1.15e3 0% 45.0 46.0 47.0 48.0 49.0 ES-189 9.17e6 45.63 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e6 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PBM 4σ 2.33e3 1.09e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 8.65e6 45.63 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.07e6 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PBM 4σ 1.98e3 1.04e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.21e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.60e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6196, 4505 scc: 065-928 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:27 Printed: 06-Apr-2014 17:23 Page 17 of 21 88 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Rel. Int. 100% Abs. Int. 3.08e3 OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PB 4σ 6.37e2 0% 38.0 1.54e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 4.15e3 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PB 4σ 6.90e2 0% 38.0 2.07e3 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 6.24e6 39.62 Rel. Int. 100% 7.85e5 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 6.64e6 39.62 Rel. Int. 100% 8.03e5 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.36e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 1.61e6 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PBM 4σ 1.64e3 0% 38.0 0.00e0 RT Abs. Int. 1.57e6 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PBM 4σ 1.26e3 0% 38.0 0.00e0 RT 3.18e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3424, 6542 scc: 065-928 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:27 Printed: 06-Apr-2014 17:23 Page 18 of 21 89 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Rel. Int. 100% Abs. Int. 2.28e3 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PB 4σ 5.00e2 1.14e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e3 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PB 4σ 6.81e2 9.14e2 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 5.46e6 47.39 49.0 ES-205 6.28e6 47.79 0.00e0 RT Abs. Int. 1.52e6 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PBM 4σ 8.24e2 7.58e5 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 6.07e6 47.39 49.0 ES-205 7.11e6 47.79 0.00e0 RT Abs. Int. 1.67e6 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PBM 4σ 1.60e3 8.35e5 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.21e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.60e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8691, 0131 scc: 065-928 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:27 Printed: 06-Apr-2014 17:23 Page 19 of 21 90 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 Rel. Int. 100% Abs. Int. 2.20e3 NoCB 44.77-49.81 461.7245 Fn6 Flags: PB 4σ 9.37e2 1.10e3 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. 100% Abs. Int. 4.88e3 NoCB 44.77-49.81 463.7216 Fn6 Flags: PB 4σ 2.10e3 2.44e3 0.00e0 RT 0% 45.0 46.0 47.0 48.0 49.0 ES-208 6.04e6 45.25 Rel. Int. 100% ES-206 4.09e6 49.26 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PBM 4σ 9.21e2 Abs. Int. 1.47e6 7.35e5 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 ES-208 7.69e6 45.25 Rel. Int. 100% ES-206 5.15e6 49.26 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PBM 4σ 1.01e3 Abs. Int. 1.85e6 9.23e5 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.21e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.60e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2901, 9390 scc: 065-928 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:27 Printed: 06-Apr-2014 17:23 Page 20 of 21 91 of 603 SGS ID: A6528_11906_PCB_001 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 27 Acq: 02-Apr-2014 07:45:18 User: LKB Datafile: 140402X10 PCB-209 1.05e4 50.70 Rel. Int. 100% Abs. Int. 3.24e3 DeCB 49.82-52.00 497.6826 Fn7 Flags: PBM 4σ 6.96e2 1.62e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.34e4 50.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.58e3 DeCB 49.82-52.00 499.6797 Fn7 Flags: PBM 4σ 5.31e2 1.79e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 6.42e6 50.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e6 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PBM 4σ 9.00e2 7.05e5 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 5.51e6 50.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e6 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PBM 4σ 8.03e2 5.98e5 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.18e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 2.59e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_001.utp_res, saved 06-Apr-2014 16:32 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9818, 4226 scc: 065-928 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:32 (CEM) Printed: 06-Apr-2014 17:23 Page 21 of 21 92 of 603 Lab ID: A6528_11906_PCB_002 ACQ: 02-Apr-2014 08:40:36 LKB Wt/Vol: 0.97 L Client ID: PB099-1SWMID-140319-MD (TOTAL) UTP: 05-Apr-2014 02:04 CEM J-level: 10.3 pg/L Datafile: 140402X11 RPT: 06-Apr-2014 16:18 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.68 NotFnd 35.66 35.11 34.65 34.37 NotFnd 40.80 39.83 NotFnd NotFnd 50.70 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.81 14.09 14.33 20.02 17.40 26.34 20.30 32.66 32.18 25.26 35.64 35.09 34.63 34.35 38.25 36.21 30.21 40.79 39.81 43.51 43.02 41.95 35.08 45.63 39.62 47.79 49.25 45.24 50.68 QC J EMPC J J EMPC C J J B Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0007 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0000 1.0005 1.0007 1.0005 1.0006 1.0006 1.0002 1.0005 1.0004 -0.2 0.7244 0.8640 0.8793 1.2279 1.0674 1.0793 0.8322 1.3381 1.3186 0.8317 1.1729 1.1551 1.1398 1.1306 1.2588 0.9715 0.8106 1.0943 1.0679 1.1671 0.9078 0.8852 0.7404 0.9628 0.8361 1.0084 1.0393 0.9547 1.0692 0.7244 0.8641 0.8792 1.2283 1.0674 1.0794 0.8321 1.3385 1.3190 0.8316 1.1730 1.1552 1.1399 1.1307 1.2590 0.9715 0.8105 1.0944 1.0680 1.1672 0.9077 0.8852 0.7403 0.9628 0.8360 1.0084 1.0393 0.9547 1.0693 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140402_PCB_XA Split: 1 Checkcode: 334-515-WYK Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.78 +1.2 5.53E+05 0.00E+00 1.01E+06 6.65E+04 2.15E+06 6.38E+04 0.00E+00 9.29E+04 4.53E+04 0.00E+00 0.00E+00 4.75E+04 1.06 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 14 ND 32 2 65.1 1.94 ND 3.37 1.5 ND ND 2.95 4.44E+03 4.44E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 2.36E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.13E+03 1.15 1.25 0.541 0.519 0.523 0.518 0.872 0.754 0.479 0.524 0.6 0.828 0 +0.1 -0.1 +0.5 0 +0.2 -0.1 +0.8 +0.8 -0.2 +0.2 +0.2 +0.2 +0.2 +0.5 0 -0.2 +0.2 +0.2 +0.3 -0.3 0 -0.2 0 -0.2 0 0 0 +0.3 5.46E+07 6.06E+07 3.27E+07 9.78E+07 3.48E+07 8.07E+07 4.25E+07 7.07E+07 6.76E+07 4.16E+07 5.84E+07 5.69E+07 5.71E+07 5.60E+07 5.37E+07 4.06E+07 5.13E+07 1.04E+08 5.37E+07 5.15E+07 3.05E+07 3.61E+07 3.94E+07 4.84E+07 3.70E+07 3.44E+07 2.33E+07 3.65E+07 2.98E+07 3.30 3.39 1.62 1.58 1.09 1.12 0.77 0.81 0.79 1.59 1.59 1.63 1.60 1.57 1.57 1.32 1.29 1.28 1.30 1.26 1.07 1.08 1.10 1.04 0.91 0.89 0.81 0.80 1.18 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 45.1 % 55 % 61.7 % 92.6 % 67.8 % 92.6 % 94.2 % 97.5 % 94.3 % 122 % 115 % 110 % 116 % 111 % 123 % 99.9 % 87.9 % 88.1 % 87.6 % 90.1 % 98 % 97.4 % 114 % 107 % 104 % 96.7 % 98.3 % 109 % 94.1 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 0 -0.2 -0.2 -0.2 -0.7 -0.2 Page 1 of 5 0.61 0.85 0.62 0.54 0.95 1.37 Printed: 4/6/2014 5:19 PM 93 of 603 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.78 32.67 37.65 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 9.95E+07 5.94E+07 2.62E+07 1.12 1.60 1.05 1.11 1.03 0.62 111 % 103 % 108 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.78 32.67 37.65 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 9.95E+07 5.94E+07 2.62E+07 1.12 1.60 1.05 1.85 1.22 0.58 103 % 115 % 123 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.30 24.40 30.38 37.27 47.39 1.02E+08 5.24E+07 4.24E+07 3.67E+07 2.86E+07 1.59 0.83 1.60 1.29 0.92 4.93E+03 4.93E+03 4.93E+03 6.75E+03 6.75E+03 7.90E+03 7.90E+03 7.90E+03 7.90E+03 7.90E+03 7.90E+03 7.90E+03 7.90E+03 7.90E+03 6.56E+03 6.56E+03 6.56E+03 6.56E+03 6.56E+03 6.56E+03 1.2 1.08 1.26 2.5 1.61 1.61 1.4 1.51 1.5 1.46 1.26 1.47 1.46 1.53 2.95 2.19 2.59 1.88 1.91 3.55 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.82 13.91 14.10 14.35 14.53 16.32 16.48 16.71 NotFnd 17.13 NotFnd 19.47 19.73 20.04 17.42 19.18 19.57 19.77 NotFnd 20.00 J J EMPC J J J B J C C 1.0011 0.9880 1.0009 1.0011 1.0135 1.0010 1.0111 1.0250 1.0435 1.0507 0.9331 0.9720 0.9866 1.0008 1.0010 1.1017 1.1247 1.1357 1.1435 1.1489 1.0011 0.9877 1.0008 1.0011 1.0135 1.0011 1.0111 1.0250 1.0510 0.9722 0.9855 1.0006 1.0012 1.1023 1.1248 1.1360 1.1491 0 -0.3 -0.1 0 0 +0.1 0 0 +0.3 +0.2 -1.3 -0.2 +0.2 +0.7 +0.1 +0.4 +0.2 Page 2 of 5 NON-EMPC 15.3 231 1,090 1,770 592 135 25 5.72 0 3.29E+05 7.82E+04 1.50E+05 1.67E+06 8.64E+04 1.24E+05 1.03E+05 2.19E+06 0.00E+00 1.66E+06 0.00E+00 1.18E+06 7.78E+05 1.05E+06 8.71E+05 5.31E+06 2.10E+06 4.81E+05 0.00E+00 1.10E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 20.4 231 1,090 1,770 598 148 45.1 13.9 0 2.90 3.40 2.53 1.51 SI SI SI 1.61 1.57 1.70 1.51 1.53 1.09 1.01 1.04 1.08 1.05 0.95 1.18 1.01 1.23 1.92 0.97 1.11 1.04 1.04 1.07 1.24 1.06 1.07 1.02 1.15 1.55 1.30 1.80 1.77 0.95 DL 1.23 2.02 2.41 1.1 0.59 0.54 0.76 0.754 2.09 13.1 2.26 5.06 85.4 2.84 2.69 1.96 44.7 ND 32.8 ND 23.5 15.4 21.7 45 203 95.3 15.8 ND 68.3 Printed: 4/6/2014 5:19 PM 94 of 603 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.47 NotFnd NotFnd 22.03 22.25 22.53 22.80 23.01 23.37 NotFnd NotFnd NotFnd NotFnd 26.36 20.33 22.28 22.88 22.95 23.17 24.42 NotFnd 24.63 24.86 25.12 25.32 25.61 25.78 26.11 26.21 26.41 27.12 27.38 27.74 NotFnd 28.11 28.34 28.64 28.91 NotFnd 29.49 29.69 NotFnd NotFnd NotFnd NotFnd 25.61 NotFnd NotFnd SGS Evironmental Services QC C C C J EMPC C C C J C C J J J J C J EMPC Pred RRT Actual RRT Diff Secs 1.1763 0.8211 0.8268 0.8375 0.8451 0.8556 0.8663 0.8732 0.8875 0.9397 0.9520 0.9721 0.9871 1.0008 1.0010 0.9141 0.9381 0.9410 0.9497 1.0009 1.0062 1.0102 1.0181 1.0296 1.0385 1.0498 1.0566 1.0702 1.0741 1.0823 0.8429 0.8509 0.8624 0.8687 0.8736 0.8806 0.8897 0.8984 0.9030 0.9165 0.9225 0.9326 0.9737 0.9888 1.0009 1.0135 0.8985 0.9048 1.1766 0.8365 0.8449 0.8555 0.8659 0.8739 0.8874 1.0009 1.0012 0.9131 0.9379 0.9408 0.9496 1.0009 1.0096 1.0190 1.0296 1.0377 1.0495 1.0566 1.0702 1.0742 1.0824 0.8426 0.8508 0.8620 0.8735 0.8806 0.8900 0.8984 0.9165 0.9225 1.0136 - +0.4 -1.3 -0.3 -0.1 -0.5 +1.0 -0.1 +0.2 +0.2 -1.3 -0.3 -0.3 -0.1 0 -0.9 +1.3 0 -1.2 -0.5 0 0 +0.2 +0.2 -0.5 -0.2 -0.7 -0.2 0 +0.5 0 0 0 +0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 3.08E+06 0.00E+00 0.00E+00 2.57E+06 3.19E+06 8.36E+06 8.76E+06 1.68E+06 2.31E+06 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.06E+06 4.65E+04 1.61E+06 8.44E+05 1.58E+06 4.73E+05 8.08E+06 0.00E+00 2.55E+05 5.29E+06 9.67E+05 7.80E+06 7.11E+05 1.70E+06 2.73E+05 3.24E+06 3.68E+06 6.83E+04 1.36E+06 4.93E+04 0.00E+00 1.91E+05 3.36E+05 9.15E+06 5.58E+06 0.00E+00 2.76E+06 1.06E+06 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.83E+04 0.00E+00 0.00E+00 1.04 1.93 1.24 1.25 1.27 1.31 1.32 1.23 1.29 1.19 1.34 1.34 1.21 1.16 1.08 1.35 0.85 0.70 0.90 0.68 0.83 1.16 0.68 1.03 0.85 0.90 1.18 0.76 0.67 0.87 1.24 1.25 1.32 1.19 1.21 1.29 1.34 1.22 1.16 1.15 1.15 1.16 1.35 1.40 1.12 1.43 1.19 0.96 0.80 94.6 ND ND 51.7 62.3 161 182 33.3 49.8 ND ND ND ND 25.1 1.67 57.7 36.6 53.6 21.2 295 ND 11.5 156 34.9 264 18.4 67.7 12.4 114 90.2 1.67 31.6 1.26 ND 4.53 7.63 229 147 ND 73.6 27.8 ND ND ND ND 2.85 ND ND 0.98 1.01 1.00 1.02 1.02 0.99 1.06 0.96 0.81 0.78 0.81 0.75 0.78 0.85 0.79 0.78 0.78 0.77 0.80 0.73 0.80 0.82 0.82 0.79 0.76 0.80 0.86 0.83 0.83 0.81 0.80 0.51 Noise / Recv. Low DL / Recv. High 6.56E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 7.76E+03 2.61E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 3.08E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 4.44E+03 1.68E+03 1.68E+03 1.65E+03 1.65E+03 1.75 1.64 1.62 1.6 1.55 1.53 1.65 1.57 1.71 1.51 1.51 1.68 1.74 1.88 0.811 1.13 1.38 1.08 1.42 1.16 0.835 1.42 0.937 1.14 1.07 0.822 1.26 1.44 1.11 0.778 1.12 1.06 1.17 1.15 1.08 1.04 1.14 1.21 1.21 1.22 1.2 1.03 0.998 1.24 0.564 0.681 0.655 0.781 Printed: 4/6/2014 5:19 PM 95 of 603 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.87 28.07 28.19 NotFnd NotFnd 28.62 28.82 NotFnd NotFnd 29.89 30.40 30.80 30.91 NotFnd 31.38 NotFnd 31.96 32.10 NotFnd 32.38 NotFnd NotFnd NotFnd 34.27 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.84 NotFnd NotFnd 32.90 NotFnd NotFnd 33.67 33.86 NotFnd 34.19 NotFnd NotFnd 34.75 NotFnd NotFnd 35.70 NotFnd 36.23 SGS Evironmental Services QC J EMPC C J C J C C C J J B EMPC J B C B C J J EMPC C B J B B C Pred RRT Actual RRT Diff Secs 0.9173 0.9243 0.9278 0.9301 0.9402 0.9423 0.9486 0.9623 0.9735 0.9840 0.9999 1.0144 1.0175 1.0208 1.0321 1.0496 1.0527 1.0566 1.0594 1.0659 1.0761 1.0892 0.9915 0.9975 1.0039 1.0091 1.0351 1.0007 1.0062 1.0108 1.0210 1.0299 1.0719 1.0891 1.0960 1.1048 1.1148 1.1205 1.1231 1.1319 1.1377 1.1425 1.1502 1.1636 0.9523 0.9580 0.9612 0.9727 0.9173 0.9239 0.9280 0.9422 0.9486 0.9840 1.0007 1.0140 1.0175 1.0331 1.0520 1.0567 1.0659 0.9977 1.0209 1.0891 1.1146 1.1208 1.1318 1.1503 0.9579 0.9721 0 -0.7 +0.3 -0.2 0 0 +1.5 -0.7 0 +1.9 -1.3 +0.2 0 +0.4 -0.2 0 -0.4 +0.6 -0.2 +0.2 -0.2 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.68E+06 3.77E+04 1.59E+05 0.00E+00 0.00E+00 4.71E+05 7.22E+05 0.00E+00 0.00E+00 3.45E+05 2.02E+06 1.16E+05 1.21E+06 0.00E+00 1.74E+06 0.00E+00 5.88E+05 3.13E+06 0.00E+00 3.28E+05 0.00E+00 0.00E+00 0.00E+00 2.10E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.19E+05 0.00E+00 0.00E+00 2.13E+05 0.00E+00 0.00E+00 5.21E+05 3.86E+04 0.00E+00 2.05E+04 0.00E+00 0.00E+00 2.33E+05 0.00E+00 0.00E+00 1.07E+05 0.00E+00 7.08E+05 0.63 0.76 0.64 0.87 0.87 0.86 0.89 0.81 0.91 0.72 0.77 1.22 0.83 0.97 0.73 0.91 1.17 0.99 1.08 0.99 1.13 1.18 0.69 1.23 1.23 1.11 1.28 1.11 1.01 1.11 1.26 1.08 1.11 1.02 1.04 1.10 1.05 1.24 1.09 1.09 0.79 1.08 1.11 0.93 0.92 0.96 1.02 1.32 1.14 1.41 1.40 71.2 1.59 6.81 ND ND 19 36.7 ND ND 15.4 76.4 5.83 49.3 ND 64.6 ND 21.8 102 ND 17.4 ND ND ND 6.04 ND ND ND ND ND ND 4.72 ND ND 10.2 ND ND 24.3 2.49 ND 0.938 ND ND 12.4 ND ND 4.76 ND 25.7 0.66 0.64 0.57 0.62 0.55 0.62 0.61 0.64 0.64 0.63 0.63 1.54 1.08 1.28 1.38 1.48 1.29 1.18 1.29 Noise / Recv. Low DL / Recv. High 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.65E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 0.721 0.718 0.73 0.709 0.776 0.688 0.867 0.813 0.512 0.76 0.644 0.86 0.692 0.534 0.633 0.581 0.632 0.556 0.531 0.903 0.512 0.508 0.564 0.491 0.565 0.618 0.543 0.401 0.469 0.454 0.498 0.485 0.619 0.645 0.547 0.626 0.624 0.865 0.628 0.613 0.728 0.742 0.711 0.665 0.516 0.596 0.482 0.486 Printed: 4/6/2014 5:19 PM 96 of 603 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.40 36.74 36.95 37.04 37.30 NotFnd 37.63 38.38 NotFnd NotFnd NotFnd 35.39 35.85 NotFnd NotFnd 37.67 NotFnd 38.44 NotFnd 38.96 NotFnd 39.16 39.54 NotFnd 40.07 41.41 NotFnd 41.97 NotFnd 43.04 43.49 39.64 NotFnd NotFnd NotFnd NotFnd 43.62 44.18 44.35 45.47 47.41 NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J J J J B C J J EMPC C J J EMPC J J J J J J EMPC C J J EMPC C J EMPC J EMPC J J EMPC C J EMPC J EMPC J J Pred RRT Actual RRT Diff Secs 0.9766 0.9859 0.9912 0.9934 1.0011 1.0049 1.0097 0.9639 0.9843 0.9903 1.0006 1.0087 1.0217 1.0302 1.0415 1.0736 1.0891 1.0956 1.1007 1.1105 1.1129 1.1160 1.1268 1.1366 1.1419 0.9077 0.9131 0.9191 0.9264 0.9433 0.9531 1.0005 1.0203 1.0348 1.0396 1.0419 1.1005 1.1150 1.1192 0.9515 0.9921 1.0004 1.0005 1.0179 1.0004 0.9766 0.9857 0.9913 0.9937 1.0007 1.0097 0.9641 1.0087 1.0219 1.0738 1.0957 1.1106 1.1162 1.1269 1.1423 0.9076 0.9197 0.9432 0.9532 1.0005 1.1009 1.1152 1.1195 0.9514 0.9921 - 0 -0.4 +0.2 +0.7 -0.9 0 +0.5 0 +0.4 +0.5 +0.2 +0.2 +0.5 +0.2 +1.0 -0.2 +1.5 -0.3 +0.3 0 +1.0 +0.5 +0.8 -0.3 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 1.13E+05 4.56E+04 6.14E+04 5.80E+04 8.05E+05 0.00E+00 1.15E+05 1.12E+05 0.00E+00 0.00E+00 0.00E+00 5.71E+04 1.93E+04 0.00E+00 0.00E+00 1.64E+04 0.00E+00 1.57E+05 0.00E+00 7.28E+04 0.00E+00 9.19E+04 5.94E+04 0.00E+00 3.53E+04 1.92E+04 0.00E+00 2.51E+05 0.00E+00 6.64E+04 3.30E+04 2.85E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.43E+04 2.15E+04 3.34E+04 1.83E+04 3.64E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.41 1.41 1.17 1.14 1.27 1.02 0.90 1.14 1.38 1.13 1.29 1.52 0.88 1.07 1.09 1.27 1.07 1.03 1.14 1.05 0.75 1.08 1.16 1.20 1.24 1.04 1.00 0.93 1.08 0.95 0.98 1.30 1.24 1.39 1.12 1.57 1.05 1.12 1.05 1.12 1.06 0.72 0.75 0.77 0.73 0.81 1.06 1.12 1.15 1.11 5.66 2.57 2.74 2.13 36.2 ND 3.85 4.86 ND ND ND 2.8 0.981 ND ND 1.14 ND 7.73 ND 3.36 ND 5.25 3.63 ND 2.12 1.12 ND 11.6 ND 4.01 1.42 1.51 ND ND ND ND 4.23 1.59 2.41 1.51 2.69 ND ND ND ND 1.42 1.48 1.05 1.44 1.15 0.99 1.07 0.96 0.97 0.80 1.04 0.86 1.60 1.27 0.97 1.12 1.05 1.10 0.77 0.92 Noise / Recv. Low DL / Recv. High 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.27E+03 1.43E+03 1.43E+03 1.43E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.16E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.69E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.40E+03 1.29E+03 1.29E+03 1.29E+03 3.09E+03 3.09E+03 3.09E+03 0.669 0.756 0.598 0.492 0.602 0.525 0.448 0.629 0.519 0.513 0.487 0.578 0.601 0.544 0.586 0.821 0.928 0.869 0.834 0.812 0.965 1.01 1.08 0.928 1.06 1.02 0.772 0.81 0.722 1.07 0.762 0.759 0.717 0.762 0.714 0.753 1.12 1.06 1.03 1.09 0.977 0.748 1.6 1.57 2.59 Printed: 4/6/2014 5:19 PM 97 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 3.44e7 1.72e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 2.86e7 1.43e7 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 1.97e7 9.84e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 1.24e7 6.22e6 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 6.76e6 3.38e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.35e6 2.67e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 5.36e6 2.68e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 334-515 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:23 Page 1 of 21 98 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 PCB-1 2.45e5 11.82 Rel. Int. 100% Abs. Int. 9.39e4 MoCB 10.03-15.71 188.0393 Fn1 Flags: PBM 4σ 2.50e3 PCB-3 1.14e5 14.10 PCB-2 6.05e4 13.91 4.70e4 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 8.44e4 11.82 Rel. Int. 100% Abs. Int. 3.28e4 MoCB 10.03-15.71 190.0363 Fn1 Flags: PBM 4σ 2.43e3 PCB-3 4.49e4 14.10 PCB-2 1.78e4 13.91 1.64e4 0% 11.0 12.0 13.0 ES-1 4.19e7 11.81 Rel. Int. 100% 0.00e0 RT 14.0 15.0 ES-3 4.68e7 14.09 0.00e0 RT Abs. Int. 1.71e7 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PBM 4σ 8.18e3 8.53e6 0% 11.0 12.0 13.0 ES-1 1.27e7 11.81 Rel. Int. 100% 14.0 15.0 ES-3 1.38e7 14.09 0.00e0 RT Abs. Int. 5.38e6 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PBM 4σ 3.10e4 2.69e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.44e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.72e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9378, 9978 scc: 334-515 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 01:01 (CEM) Printed: 06-Apr-2014 17:23 Page 2 of 21 99 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 Rel. Int. 100% Abs. Int. 3.39e5 PCB-4 1.00e6 14.35 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PBM 4σ 4.11e3 1.69e5 PCB-10 5.27e4 SI 14.53 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 6.67e5 14.35 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e5 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PBM 4σ 1.61e4 1.25e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.02e7 14.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.00e6 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PBM 4σ 6.74e3 3.50e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.25e7 14.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.29e6 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PBM 4σ 4.80e3 2.14e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.44e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.72e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2035, 8264 scc: 334-515 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:03 (CEM) Printed: 06-Apr-2014 17:23 Page 3 of 21 100 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 PCB-6 1.35e6 16.71 Rel. Int. 100% DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PBM 4σ 4.81e3 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Abs. Int. 4.20e5 PCB-8 1.02e6 17.13 PCB-11 7.44e5 19.47 PCB-9 PCB-7 7.55e4 SI 6.30e4 SI 16.32 16.48 13/12 4.68e5 19.73 PCB-15 6.35e5 20.04 2.10e5 0% 16.0 17.0 Rel. Int. 100% PCB-6 8.41e5 16.71 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PBM 4σ 2.23e4 18.0 19.0 20.0 21.0 Abs. Int. 3.18e5 PCB-8 6.45e5 17.13 PCB-11 4.38e5 19.47 13/12 3.10e5 19.73 PCB-15 4.15e5 20.04 1.59e5 0% 16.0 17.0 18.0 19.0 JS-9 6.23e7 16.30 Rel. Int. 100% 0.00e0 RT 20.0 21.0 Abs. Int. 1.94e7 ES-15 5.98e7 20.02 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PBM 4σ 2.18e4 0.00e0 RT 9.68e6 0% 16.0 17.0 18.0 19.0 JS-9 3.92e7 16.30 Rel. Int. 100% 20.0 21.0 Abs. Int. 1.21e7 ES-15 3.80e7 20.02 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PBM 4σ 4.77e3 0.00e0 RT 6.05e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.43e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9666, 9069 scc: 334-515 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:03 (CEM) Printed: 06-Apr-2014 17:23 Page 4 of 21 101 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Rel. Int. 100% Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 Abs. Int. 7.34e5 30/18 2.67e6 19.18 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PBM 4σ 3.34e3 PCB-17 1.07e6 19.57 PCB-19 4.55e5 17.42 PCB-32 1.57e6 20.47 PCB-27 2.50e5 19.77 3.67e5 PCB-16 5.63e5 20.00 0% 16.0 17.0 18.0 Rel. Int. 100% 19.0 20.0 21.0 Abs. Int. 7.74e5 30/18 2.64e6 19.18 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PBM 4σ 3.22e3 PCB-17 1.03e6 19.57 PCB-19 4.16e5 17.42 PCB-27 2.31e5 19.76 PCB-16 5.37e5 19.99 PCB-32 1.51e6 20.47 3.87e5 0% 16.0 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 7.25e6 ES-19 1.82e7 17.40 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PBM 4σ 7.22e4 0.00e0 RT 3.62e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-19 1.66e7 17.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.78e6 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PBM 4σ 2.74e4 2.39e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.43e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3393, 2768 scc: 334-515 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 01:03 (CEM) Printed: 06-Apr-2014 17:23 Page 5 of 21 102 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 PCB-31 4.19e6 22.53 Rel. Int. 100% TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 3.38e3 26/29 1.27e6 22.03 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 28/20 4.42e6 22.80 PCB-25 1.60e6 22.25 Abs. Int. 1.10e6 21/33 8.44e5 23.01 5.52e5 PCB-22 1.15e6 23.37 PCB-37 5.44e5 26.36 0% 22.0 23.0 PCB-31 4.17e6 22.53 Rel. Int. 100% TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 4.38e3 26/29 1.30e6 22.03 24.0 25.0 0.00e0 RT 26.0 28/20 4.34e6 22.80 PCB-25 1.58e6 22.25 Abs. Int. 1.07e6 21/33 8.31e5 23.02 5.35e5 PCB-22 1.16e6 23.37 PCB-37 5.15e5 26.36 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 5.26e7 22.78 Rel. Int. 100% ES-37 4.26e7 26.34 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PBM 4σ 1.03e5 Abs. Int. 1.40e7 7.02e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 4.69e7 22.78 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 3.81e7 26.34 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PBM 4σ 2.65e4 Abs. Int. 1.23e7 6.15e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.97e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 9.84e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4643, 1142 scc: 334-515 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 01:03 (CEM) Printed: 06-Apr-2014 17:23 Page 6 of 21 103 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 PCB-54 2.51e4 20.33 Rel. Int. 100% Abs. Int. 7.57e3 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PBM 4σ 1.53e3 3.78e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 PCB-54 2.61e4 20.31 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.73e3 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PBM 4σ 1.07e3 3.87e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 1.85e7 20.30 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.33e6 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PBM 4σ 1.16e4 2.67e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 2.40e7 20.30 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.84e6 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PBM 4σ 7.44e3 3.42e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.86e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.43e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7921, 9488 scc: 334-515 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:01 (CEM) Printed: 06-Apr-2014 17:23 Page 7 of 21 104 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 PCB-52 3.55e6 24.42 Rel. Int. 100% TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 1.33e3 50/53 7.21e5 22.28 69/49 2.34e6 24.86 PCB-51 7.08e5 22.95 PCB-45 3.71e5 22.88 PCB-48 4.25e5 25.12 PCB-46 2.02e5 23.17 Abs. Int. 9.41e5 44/47… 3.43e6 25.32 71/40 1.44e6 26.21 PCB-42 7.53e5 25.78 PCB-64 1.65e6 26.41 0% 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 PCB-52 4.53e6 24.42 Rel. Int. 100% TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 1.75e3 50/53 8.91e5 22.28 PCB-45 4.73e5 22.88 PCB-48 5.42e5 25.12 PCB-46 2.70e5 23.17 Abs. Int. 1.16e6 44/47… 4.37e6 25.32 69/49 2.95e6 24.86 PCB-51 8.70e5 22.95 71/40 1.80e6 26.21 PCB-42 9.44e5 25.78 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.37e7 24.40 Rel. Int. 100% 4.70e5 PCB-64 2.02e6 26.41 5.79e5 0.00e0 RT Abs. Int. 6.31e6 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PBM 4σ 2.42e4 3.16e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.87e7 24.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.51e6 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PBM 4σ 1.89e4 3.76e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.97e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 9.84e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0726, 8065 scc: 334-515 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 01:03 (CEM) Printed: 06-Apr-2014 17:23 Page 8 of 21 105 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 1.48e3 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 Abs. Int. 6.85e5 PCB-66 2.52e6 28.91 PCB-68 6.03e5 27.38 PCB-56 1.23e6 29.49 PCB-60 4.72e5 29.69 PCB-63 1.55e5 28.34 3.43e5 PCB-77 2.43e5 32.68 0% 28.0 32.0 34.0 36.0 61/70... 5.00e6 28.64 Rel. Int. 100% TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 2.96e3 30.0 PCB-68 7.59e5 27.38 PCB-63 1.81e5 28.34 Abs. Int. 8.33e5 PCB-56 1.53e6 29.49 PCB-60 5.90e5 29.69 4.17e5 PCB-77 3.10e5 32.67 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.99e7 32.18 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PBM 4σ 2.07e4 34.0 36.0 0.00e0 RT Abs. Int. 7.75e6 ES-77 3.17e7 32.66 3.87e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.77e7 32.18 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PBM 4σ 2.36e4 34.0 36.0 0.00e0 RT Abs. Int. 9.46e6 ES-77 3.90e7 32.66 4.73e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 6.22e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0929, 2757 scc: 334-515 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 01:04 (CEM) Printed: 06-Apr-2014 17:23 Page 9 of 21 106 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 PCB-96 2.61e4 25.61 Rel. Int. 100% Abs. Int. 8.94e3 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 6.87e2 4.47e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 5.08e4 25.60 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e4 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 9.88e2 6.95e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.55e7 25.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.55e6 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PBM 4σ 2.48e3 3.28e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.61e7 25.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.06e6 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PBM 4σ 2.29e3 2.03e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.97e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 9.84e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7132, 8827 scc: 334-515 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 01:04 (CEM) Printed: 06-Apr-2014 17:23 Page 10 of 21 107 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 PCB-110 1.22e6 32.10 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 9.48e2 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 Abs. Int. 3.04e5 113/90… 7.74e5 30.40 PCB-95 6.50e5 27.87 PCB-91 1.87e5 28.62 PCB-84 2.82e5 28.82 PCB-118 8.18e5 34.65 PCB-99 4.64e5108/119... 30.91 6.61e5 116/85 31.38 2.29e5 31.96 PCB-92 1.25e5 29.89 PCB-82 1.27e5 32.38 PCB-109 8.08e4 34.27 PCB-105 3.82e5 35.66 0% 28.0 30.0 34.0 36.0 PCB-110 1.91e6 32.10 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 7.06e2 32.0 PCB-91 2.84e5 28.62 PCB-84 4.40e5 28.82 PCB-92 2.20e5 29.89 PCB-99 7.49e5108/119... 30.91 1.08e6 116/85 31.38 3.59e5 PCB-83 31.96 7.47e4 30.81 PCB-118 1.33e6 34.65 PCB-82 2.02e5 32.38 PCB-105 6.26e5 35.66 PCB-109 1.29e5 34.27 0% 28.0 30.0 Rel. Int. 100% 32.0 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PBM 4σ 2.92e3 34.0 CS/SS-111 3.66e7 32.67 JS-101 2.61e7 30.38 0.00e0 RT Abs. Int. 4.51e5 113/90… 1.25e6 30.40 PCB-95 1.03e6 27.86 1.52e5 ES-123 3.42e7 34.35 36.0 ES-118 ES-114 3.52e7 3.52e7 34.63 35.09 ES-105 3.59e7 35.64 2.26e5 0.00e0 RT Abs. Int. 9.17e6 4.58e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 2.28e7 32.67 JS-101 1.63e7 30.38 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PBM 4σ 2.27e3 34.0 ES-118 ES-114 ES-123 2.20e7 2.17e7 2.18e7 34.63 35.09 34.35 36.0 ES-105 2.25e7 35.64 0.00e0 RT Abs. Int. 5.91e6 2.95e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 6.22e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0891, 5235 scc: 334-515 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 01:06 (CEM) Printed: 06-Apr-2014 17:23 Page 11 of 21 108 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 Rel. Int. 100% Abs. Int. 1.02e6 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PB 4σ 1.05e3 5.08e5 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 2.25e6 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PB 4σ 1.31e3 1.12e6 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 3.85e6 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 2.42e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 4.83e6 ES-126 2.09e7 38.25 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PBM 4σ 5.31e3 0% 38.0 0.00e0 RT Abs. Int. 7.70e6 ES-126 3.28e7 38.25 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PBM 4σ 4.58e3 Rel. Int. 100% 0.00e0 RT 3.38e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8043, 7454 scc: 334-515 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:48 Printed: 06-Apr-2014 17:23 Page 12 of 21 109 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 153/168 3.98e5 36.23 Rel. Int. 100% 163/138… 4.50e5 37.30 Abs. Int. 1.07e5 147/149 2.92e5 33.67 HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 6.81e2 PCB-136 8.14e4 30.84 151/135 1.11e5 32.90 PCB-134 2.24e4 33.86 PCB-132 1.31e5 34.75 PCB-146 5.79e4 35.70 PCB-141 6.61e4 PCB-137 36.40 3.31e4 36.95 PCB-158 6.74e4 37.63 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% 147/149 2.29e5 33.67 HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 5.86e2 PCB-136 5.29e4 30.84 PCB-132 1.02e5 34.75 151/135 1.02e5 32.90 0.00e0 RT 36.0 153/168 3.10e5 36.23 PCB-146 4.91e4 35.70 163/138… 3.55e5 37.30 PCB-141 PCB-164 PCB-158 4.75e4 4.71e4 2.71e4 37.63 36.40 37.04 30.0 32.0 34.0 ES-155 2.89e7 30.21 Rel. Int. 100% 36.0 ES-153 2.31e7 36.21 HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PBM 4σ 1.30e3 Abs. Int. 7.52e4 3.76e4 0.00e0 RT 0% 28.0 5.33e4 JS-138 2.07e7 37.27 Abs. Int. 7.30e6 3.65e6 0% 28.0 30.0 32.0 34.0 ES-155 2.24e7 30.21 Rel. Int. 100% ES-153 1.75e7 36.21 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PBM 4σ 2.06e3 0.00e0 RT 36.0 JS-138 1.61e7 37.27 Abs. Int. 5.47e6 2.73e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 6.22e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7073, 4727 scc: 334-515 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:02 (CEM) Printed: 06-Apr-2014 17:23 Page 13 of 21 110 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% 128/166 7.39e4 38.38 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 7.64e2 PCB-167 2.61e4 39.83 0% 38.0 Rel. Int. 100% 39.0 Abs. Int. 1.55e4 156/157 5.16e4 40.80 7.75e3 41.0 42.0 43.0 44.0 39.0 40.0 ES-167 3.04e7 39.81 6.02e3 41.0 42.0 43.0 ES-156/157 5.82e7 40.79 44.0 0.00e0 RT Abs. Int. 9.99e6 ES-169 2.88e7 43.51 5.00e6 39.0 40.0 41.0 42.0 43.0 44.0 ES-156/157 4.53e7 40.79 Rel. Int. 100% ES-167 2.33e7 39.81 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PBM 4σ 5.96e3 0.00e0 RT Abs. Int. 8.12e6 ES-169 2.28e7 43.51 4.06e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 1.20e4 PCB-167 1.91e4 39.83 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PBM 4σ 4.41e3 0% 38.0 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 156/157 5.40e4 40.80 Rel. Int. 100% 0% 38.0 40.0 128/166 4.98e4 38.38 HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 6.63e2 0% 38.0 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 3.38e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1707, 7801 scc: 334-515 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 01:07 (CEM) Printed: 06-Apr-2014 17:23 Page 14 of 21 111 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Rel. Int. 100% PCB-184 1.36e4 35.85 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 36.0 PCB-178 8.79e3 37.67 Abs. Int. 8.82e3 PCB-184 9.44e3 35.85 31.0 32.0 33.0 34.0 35.0 36.0 PCB-178 7.63e3 37.68 Abs. Int. 5.04e6 CS/SS-178 1.34e7 37.65 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PBM 4σ 1.40e3 0% 30.0 2.52e6 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 4.68e6 CS/SS-178 1.28e7 37.65 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PBM 4σ 1.32e3 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 2.34e6 0.00e0 RT Abs. Int. 1.24e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 0.00e0 RT 37.0 ES-188 1.87e7 35.08 Rel. Int. 100% 0% 30.0 4.41e3 0.00e0 RT 37.0 ES-188 2.06e7 35.08 Rel. Int. 100% 3.71e3 0.00e0 RT 37.0 PCB-179 2.78e4 35.39 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 5.33e2 0% 30.0 Abs. Int. 7.42e3 PCB-179 2.93e4 35.39 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 6.22e2 0% 30.0 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 6.22e6 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8585, 8838 scc: 334-515 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:02 (CEM) Printed: 06-Apr-2014 17:23 Page 15 of 21 112 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 9.24e2 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 180/193 1.28e5 41.97 PCB-187 7.79e4 38.44 0% 38.0 PCB-174 PCB-183 4.51e4 3.77e4 39.16 38.96 PCB-177 2.92e4 39.54 39.0 171/173 1.80e4 40.07 40.0 41.0 0% 38.0 Abs. Int. 2.93e4 PCB-170 5.22e4 43.04 PCB-172 9.79e3 41.41 42.0 PCB-190 2.05e4 43.49 43.0 1.46e4 44.0 180/193 1.48e5 41.97 Rel. Int. 100% HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 7.66e2 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 PCB-187 7.87e4 38.44 PCB-174 PCB-183 4.68e4 3.51e4 39.16 38.96 39.0 PCB-177 3.02e4 39.53 171/173 2.26e4 40.07 40.0 41.0 42.0 ES-180 1.87e7 41.95 Rel. Int. 100% Abs. Int. 2.91e4 PCB-170 3.26e4 43.04 PCB-172 9.45e3 41.41 43.0 1.46e4 PCB-190 1.62e4 43.49 44.0 2.25e6 39.0 40.0 41.0 42.0 ES-180 1.74e7 41.95 Rel. Int. 100% 43.0 44.0 2.10e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 4.19e6 ES-170 1.47e7 43.02 HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PBM 4σ 2.46e3 0% 38.0 0.00e0 RT Abs. Int. 4.50e6 ES-170 1.58e7 43.02 HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PBM 4σ 2.71e3 0% 38.0 0.00e0 RT 3.38e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4905, 3094 scc: 334-515 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 01:59 (CEM) Printed: 06-Apr-2014 17:23 Page 16 of 21 113 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 Rel. Int. 100% Abs. Int. 2.49e3 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PB 4σ 6.91e2 1.25e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e3 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PB 4σ 7.38e2 1.28e3 0% 45.0 46.0 47.0 48.0 49.0 ES-189 2.46e7 45.63 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.82e6 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PBM 4σ 2.51e3 2.91e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 2.37e7 45.63 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.57e6 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PBM 4σ 2.53e3 2.78e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.35e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.67e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4505, 2615 scc: 334-515 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:48 Printed: 06-Apr-2014 17:23 Page 17 of 21 114 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 198/199 3.21e4 43.62 Rel. Int. 100% PCB-202 1.41e4 39.64 OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PBM 4σ 6.72e2 0% 38.0 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 39.0 PCB-196 1.20e4 44.18 40.0 41.0 42.0 43.0 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PBM 4σ 7.28e2 PCB-202 1.45e4 39.63 39.0 PCB-196 1.14e4 44.18 40.0 41.0 42.0 43.0 44.0 PCB-203 1.77e4 44.35 3.77e3 0.00e0 RT Abs. Int. 4.29e6 2.15e6 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 1.94e7 39.62 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.79e6 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PBM 4σ 1.86e3 2.40e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 7.53e3 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PBM 4σ 1.43e3 0% 38.0 4.28e3 44.0 ES-202 1.76e7 39.62 Rel. Int. 100% 0% 38.0 PCB-203 1.95e4 44.35 198/199 2.87e4 43.62 Rel. Int. 100% 0% 38.0 Abs. Int. 8.55e3 3.38e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5488, 1416 scc: 334-515 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:00 (CEM) Printed: 06-Apr-2014 17:23 Page 18 of 21 115 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 PCB-194 1.75e4 47.41 Rel. Int. 100% Abs. Int. 5.11e3 PCB-195 7.96e3 45.47 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PBM 4σ 6.22e2 2.55e3 0% 45.0 46.0 47.0 48.0 49.0 PCB-194 1.90e4 47.41 Rel. Int. 100% OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PBM 4σ 6.63e2 Abs. Int. 5.56e3 PCB-195 1.04e4 45.47 2.78e3 0% 45.0 0.00e0 RT 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.37e7 47.39 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PBM 4σ 1.62e3 49.0 ES-205 1.62e7 47.79 0.00e0 RT Abs. Int. 3.94e6 1.97e6 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.49e7 47.39 49.0 ES-205 1.82e7 47.79 0.00e0 RT Abs. Int. 4.28e6 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PBM 4σ 1.15e3 2.14e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.35e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.67e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8772, 3450 scc: 334-515 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:00 (CEM) Printed: 06-Apr-2014 17:23 Page 19 of 21 116 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 Rel. Int. 100% Abs. Int. 3.73e3 NoCB 44.77-49.81 461.7245 Fn6 Flags: PB 4σ 9.59e2 1.87e3 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. 100% Abs. Int. 5.04e3 NoCB 44.77-49.81 463.7216 Fn6 Flags: PB 4σ 2.13e3 2.52e3 0.00e0 RT 0% 45.0 46.0 47.0 48.0 49.0 ES-208 1.62e7 45.24 Rel. Int. 100% Abs. Int. 3.91e6 ES-206 1.04e7 49.25 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PBM 4σ 1.80e3 1.96e6 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 ES-208 2.03e7 45.24 Rel. Int. 100% Abs. Int. 4.86e6 ES-206 1.29e7 49.25 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PBM 4σ 1.97e3 2.43e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.35e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.67e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8636, 4472 scc: 334-515 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:48 Printed: 06-Apr-2014 17:23 Page 20 of 21 117 of 603 SGS ID: A6528_11906_PCB_002 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB099-1SWMID-140319-MD (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 28 Acq: 02-Apr-2014 08:40:36 User: LKB Datafile: 140402X11 PCB-209 2.45e4 50.70 Rel. Int. 100% Abs. Int. 5.63e3 DeCB 49.82-52.00 497.6826 Fn7 Flags: PBM 4σ 5.01e2 2.81e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.31e4 50.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.61e3 DeCB 49.82-52.00 499.6797 Fn7 Flags: PBM 4σ 6.24e2 3.30e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.62e7 50.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e6 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PBM 4σ 9.41e2 1.70e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.37e7 50.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.90e6 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PBM 4σ 7.50e2 1.45e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 2.68e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_002.utp_res, saved 05-Apr-2014 02:04 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1855, 4092 scc: 334-515 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:00 (CEM) Printed: 06-Apr-2014 17:23 Page 21 of 21 118 of 603 Lab ID: A6528_11906_PCB_003 ACQ: 04-Apr-2014 04:34:05 LKB Wt/Vol: 0.96 L ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XC Client ID: PB101.1-1SWMID-140319-N (TOTAL) UTP: 06-Apr-2014 16:55 CEM J-level: 10.4 pg/L Datafile: 140403X18 RPT: 10-Apr-2014 11:16 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.66 NotFnd 35.64 35.10 34.64 34.36 NotFnd 40.79 39.81 NotFnd NotFnd 50.68 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.81 14.09 14.33 20.02 17.40 26.33 20.30 32.65 32.17 25.26 35.62 35.08 34.62 34.34 38.23 36.20 30.20 40.78 39.79 43.49 43.00 41.94 35.07 45.61 39.61 47.77 49.24 45.23 50.65 QC J EMPC J J C J EMPC J B Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0007 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0000 1.0004 1.0006 1.0005 1.0007 1.0008 1.0003 1.0004 1.0006 -0.4 0.7244 0.8640 0.8793 1.2279 1.0674 1.0793 0.8322 1.3381 1.3186 0.8317 1.1729 1.1551 1.1398 1.1306 1.2588 0.9715 0.8106 1.0943 1.0679 1.1671 0.9078 0.8852 0.7404 0.9628 0.8361 1.0084 1.0393 0.9547 1.0692 0.7245 0.8641 0.8793 1.2282 1.0674 1.0794 0.8321 1.3383 1.3188 0.8317 1.1730 1.1552 1.1399 1.1306 1.2590 0.9715 0.8105 1.0944 1.0680 1.1672 0.9077 0.8852 0.7403 0.9628 0.8360 1.0084 1.0393 0.9547 1.0692 Split: 1 Checkcode: 388-879-CFL Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.75 +1.8 4.25E+05 0.00E+00 8.73E+05 5.74E+04 1.75E+06 4.48E+04 0.00E+00 8.92E+04 3.18E+04 0.00E+00 0.00E+00 4.48E+04 1.06 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 13.4 ND 32.6 2.02 63.3 1.6 ND 3.93 1.29 ND ND 3.08 4.56E+03 4.56E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.55E+03 1.61E+03 1.61E+03 1.61E+03 1.65E+03 1.21E+03 1.48 1.56 1.03 0.95 0.952 0.94 1.17 1.02 0.688 0.735 0.822 0.967 +0.1 +0.1 0 +0.4 0 +0.2 -0.1 +0.4 +0.4 0 +0.2 +0.2 +0.2 0 +0.5 0 -0.2 +0.2 +0.2 +0.3 -0.3 0 -0.2 0 -0.2 0 0 0 0 3.30E+07 3.90E+07 2.29E+07 6.90E+07 2.60E+07 6.29E+07 3.55E+07 5.76E+07 5.54E+07 3.77E+07 5.02E+07 4.95E+07 4.84E+07 4.82E+07 4.30E+07 3.68E+07 4.96E+07 8.64E+07 4.43E+07 4.19E+07 2.70E+07 3.25E+07 3.75E+07 3.94E+07 3.53E+07 2.98E+07 2.17E+07 3.22E+07 2.73E+07 3.27 3.43 1.61 1.57 1.06 1.10 0.79 0.80 0.79 1.59 1.59 1.60 1.59 1.58 1.54 1.31 1.27 1.30 1.26 1.27 1.08 1.08 1.06 1.04 0.90 0.90 0.80 0.80 1.17 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 37.7 % 48.9 % 59.8 % 90.4 % 70 % 85.2 % 92.7 % 93.7 % 91.2 % 115 % 103 % 99.8 % 103 % 99.8 % 103 % 100 % 91.9 % 79.5 % 78.2 % 79.2 % 94 % 95.5 % 118 % 97.3 % 107 % 93.8 % 102 % 107 % 96.2 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% -0.2 -0.2 0 +0.2 -0.5 -0.5 Page 1 of 5 0.64 0.74 0.63 0.55 1.39 1.50 Printed: 4/10/2014 11:23 AM 119 of 603 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.78 32.66 37.64 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 7.27E+07 5.29E+07 2.54E+07 1.09 1.56 1.06 1.11 1.03 0.62 104 % 107 % 109 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.78 32.66 37.64 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 7.27E+07 5.29E+07 2.54E+07 1.09 1.56 1.06 1.85 1.22 0.58 88.6 % 106 % 128 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.30 24.39 30.37 37.26 47.37 7.34E+07 4.45E+07 4.07E+07 3.40E+07 2.56E+07 1.58 0.80 1.61 1.25 0.90 4.55E+03 4.55E+03 4.55E+03 5.58E+03 5.58E+03 6.03E+03 6.03E+03 6.03E+03 6.03E+03 6.03E+03 6.03E+03 6.03E+03 6.03E+03 6.03E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 5.74E+03 1.86 1.53 1.75 2.96 1.94 1.65 1.45 1.55 1.56 1.52 1.3 1.52 1.52 1.58 3.35 2.55 3.02 2.16 2.23 4.1 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.82 13.92 14.10 14.35 NotFnd NotFnd NotFnd 16.71 NotFnd 17.13 NotFnd 19.46 19.73 20.03 17.42 19.18 19.57 19.76 NotFnd 19.99 J J B J EMPC C C 1.0011 0.9880 1.0009 1.0011 1.0135 1.0010 1.0111 1.0250 1.0435 1.0507 0.9331 0.9720 0.9866 1.0008 1.0010 1.1017 1.1247 1.1357 1.1435 1.1489 1.0011 0.9879 1.0011 1.0010 1.0251 1.0509 0.9720 0.9854 1.0007 1.0011 1.1022 1.1248 1.1357 1.1491 0 -0.1 +0.2 -0.1 +0.1 +0.2 0 -1.4 -0.1 +0.1 +0.6 +0.1 0 +0.2 Page 2 of 5 NON-EMPC 25.9 176 877 1,610 619 146 42 7.56 0 2.27E+05 8.03E+04 1.34E+05 1.01E+06 0.00E+00 0.00E+00 0.00E+00 1.02E+06 0.00E+00 8.79E+05 0.00E+00 9.41E+05 3.02E+05 6.54E+05 5.24E+05 3.05E+06 1.24E+06 3.08E+05 0.00E+00 6.98E+05 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 25.9 184 877 1,610 640 158 51.8 16.2 0 2.90 3.21 3.02 1.54 1.76 1.63 1.63 2.03 1.62 1.15 1.05 1.00 0.97 1.08 0.95 1.15 1.01 1.23 1.88 0.97 1.11 1.04 1.03 1.06 1.23 1.06 1.06 1.02 1.15 1.51 1.27 1.77 1.72 0.94 DL 1.8 2.27 2.62 1.29 0.925 0.725 0.888 0.855 2.19 15.1 3.73 7.12 74.4 ND ND ND 29.8 ND 25.1 ND 26.9 8.63 19.4 36.7 163 78.8 14 ND 59.8 Printed: 4/10/2014 11:23 AM 120 of 603 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.47 NotFnd NotFnd 22.03 22.25 22.53 22.80 23.01 23.37 NotFnd NotFnd NotFnd NotFnd 26.35 20.32 22.27 22.88 22.96 23.16 24.42 NotFnd 24.64 24.86 25.11 25.31 25.60 25.77 26.10 26.20 26.40 NotFnd 27.37 NotFnd NotFnd 28.10 28.33 28.63 28.90 NotFnd 29.48 29.68 NotFnd 31.37 NotFnd NotFnd 25.60 NotFnd NotFnd SGS Evironmental Services QC C C C J EMPC C J C C J C C J J C J J Pred RRT Actual RRT Diff Secs 1.1763 0.8211 0.8268 0.8375 0.8451 0.8556 0.8663 0.8732 0.8875 0.9397 0.9520 0.9721 0.9871 1.0008 1.0010 0.9141 0.9381 0.9410 0.9497 1.0009 1.0062 1.0102 1.0181 1.0296 1.0385 1.0498 1.0566 1.0702 1.0741 1.0823 0.8429 0.8509 0.8624 0.8687 0.8736 0.8806 0.8897 0.8984 0.9030 0.9165 0.9225 0.9326 0.9737 0.9888 1.0009 1.0135 0.8985 0.9048 1.1765 0.8366 0.8449 0.8556 0.8659 0.8739 0.8875 1.0009 1.0011 0.9130 0.9381 0.9412 0.9496 1.0009 1.0101 1.0189 1.0295 1.0376 1.0495 1.0566 1.0701 1.0742 1.0823 0.8509 0.8736 0.8806 0.8900 0.8984 0.9164 0.9225 0.9751 1.0136 - +0.2 -1.2 -0.3 0 -0.5 +1.0 0 +0.2 +0.1 -1.5 0 +0.3 -0.1 0 -0.1 +1.2 -0.2 -1.4 -0.5 0 -0.2 +0.2 0 0 0 0 +0.5 0 -0.2 0 +2.6 +0.2 Page 3 of 5 Response Ra RRF Conc. / Recv. 1.86E+06 0.00E+00 0.00E+00 1.51E+06 1.84E+06 4.91E+06 5.60E+06 9.96E+05 1.39E+06 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.61E+05 2.26E+04 1.11E+06 7.93E+05 8.76E+05 3.50E+05 6.05E+06 0.00E+00 1.82E+05 4.09E+06 7.79E+05 6.17E+06 5.78E+05 1.35E+06 2.75E+05 2.59E+06 2.93E+06 0.00E+00 8.39E+05 0.00E+00 0.00E+00 1.47E+05 2.52E+05 6.91E+06 4.22E+06 0.00E+00 2.18E+06 9.02E+05 0.00E+00 1.16E+05 0.00E+00 0.00E+00 6.28E+04 0.00E+00 0.00E+00 1.07 1.88 1.24 1.26 1.28 1.30 1.34 1.24 1.29 1.19 1.34 1.35 1.21 1.17 1.08 1.35 0.91 0.75 0.95 0.73 0.89 1.15 0.72 1.09 0.89 0.96 1.25 0.82 0.72 0.92 1.33 1.23 1.32 1.17 1.23 1.27 1.33 1.21 1.18 1.15 1.14 1.16 1.36 1.37 1.11 1.43 1.15 0.92 0.78 79.7 ND ND 39.3 46.8 122 150 25.6 38.8 ND ND ND ND 23.4 0.983 46.2 39.8 34.6 18.1 255 ND 9.59 142 33 243 17.4 62.6 14.4 106 83 ND 24 ND ND 4.37 7.16 215 134 ND 72 29.4 ND 3.2 ND ND 3.02 ND ND 1.03 0.99 1.01 0.99 1.02 1.01 1.05 1.10 0.77 0.79 0.87 0.81 0.79 0.82 0.79 0.79 0.78 0.76 0.79 0.71 0.81 0.76 0.81 0.77 0.74 0.82 0.78 0.80 0.79 0.74 0.68 Noise / Recv. Low DL / Recv. High 5.74E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 6.24E+03 2.37E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 2.93E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 4.56E+03 1.46E+03 1.46E+03 2.65E+03 2.65E+03 2.05 1.64 1.62 1.6 1.57 1.52 1.64 1.58 1.71 1.52 1.51 1.68 1.74 1.89 0.934 1.23 1.49 1.17 1.53 1.25 0.971 1.56 1.03 1.26 1.17 0.895 1.37 1.55 1.21 0.84 1.41 1.32 1.49 1.42 1.37 1.31 1.44 1.47 1.52 1.53 1.51 1.28 1.28 1.57 0.505 0.628 1.23 1.47 Printed: 4/10/2014 11:23 AM 121 of 603 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.86 NotFnd 28.18 NotFnd NotFnd 28.61 28.81 29.22 NotFnd 29.88 30.39 30.80 30.90 NotFnd 31.37 31.87 31.96 32.09 NotFnd 32.37 NotFnd NotFnd 34.05 34.25 34.43 NotFnd NotFnd NotFnd NotFnd NotFnd 30.83 NotFnd NotFnd 32.88 NotFnd NotFnd 33.66 NotFnd NotFnd NotFnd NotFnd NotFnd 34.74 NotFnd NotFnd 35.69 NotFnd 36.22 SGS Evironmental Services QC C J J EMPC C J C J C J EMPC C J J EMPC J B EMPC J B C B C C B J B B C Pred RRT Actual RRT Diff Secs 0.9173 0.9243 0.9278 0.9301 0.9402 0.9423 0.9486 0.9623 0.9735 0.9840 0.9999 1.0144 1.0175 1.0208 1.0321 1.0496 1.0527 1.0566 1.0594 1.0659 1.0761 1.0892 0.9915 0.9975 1.0039 1.0091 1.0351 1.0007 1.0062 1.0108 1.0210 1.0299 1.0719 1.0891 1.0960 1.1048 1.1148 1.1205 1.1231 1.1319 1.1377 1.1425 1.1502 1.1636 0.9523 0.9580 0.9612 0.9727 0.9173 0.9281 0.9422 0.9486 0.9622 0.9840 1.0007 1.0143 1.0174 1.0330 1.0494 1.0523 1.0567 1.0659 0.9917 0.9976 1.0028 1.0210 1.0890 1.1147 1.1503 0.9580 0.9721 0 +0.5 -0.2 0 -0.2 0 +1.5 -0.2 -0.2 +1.7 -0.4 -0.8 +0.2 0 +0.4 +0.2 -2.3 0 -0.2 -0.2 +0.2 0 -1.3 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.52E+06 0.00E+00 1.30E+05 0.00E+00 0.00E+00 4.34E+05 6.13E+05 8.78E+04 0.00E+00 2.82E+05 1.86E+06 1.30E+05 1.03E+06 0.00E+00 1.68E+06 6.93E+04 4.93E+05 2.64E+06 0.00E+00 2.99E+05 0.00E+00 0.00E+00 6.97E+04 1.56E+05 3.70E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.08E+05 0.00E+00 0.00E+00 2.10E+05 0.00E+00 0.00E+00 5.43E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.20E+05 0.00E+00 0.00E+00 1.06E+05 0.00E+00 6.56E+05 0.62 0.84 0.85 0.84 0.85 0.81 0.88 0.70 0.75 1.19 0.80 0.96 0.65 0.95 1.12 0.97 1.09 0.96 1.10 1.12 0.69 1.21 1.20 1.09 1.19 1.15 1.00 1.09 1.26 1.08 1.10 1.00 1.04 1.08 1.04 1.22 1.09 1.08 0.82 1.06 1.11 0.92 0.92 0.96 1.02 1.33 1.12 1.50 1.38 78 ND 6.72 ND ND 21.5 37.8 5.09 ND 15.2 84.4 8.7 46.8 ND 75.3 2.75 22.3 104 ND 18.8 ND ND 2.78 5.72 1.4 ND ND ND ND ND 4.52 ND ND 11.5 ND ND 28.6 ND ND ND ND ND 13 ND ND 5.37 ND 27 0.65 0.56 0.66 0.64 0.52 0.61 0.65 0.63 0.58 0.67 0.64 0.64 0.68 0.51 0.60 0.42 1.59 1.14 1.26 1.16 1.07 1.39 Noise / Recv. Low DL / Recv. High 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 2.65E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.35 1.35 1.36 1.34 1.4 1.3 1.62 1.52 0.961 1.42 1.19 1.76 1.2 1.01 1.18 1.04 1.19 1.04 1.02 1.65 0.946 0.949 1.05 0.961 0.994 1.15 1.05 0.457 0.536 0.523 0.575 0.556 0.769 0.792 0.678 0.758 0.767 1.01 0.783 0.746 0.899 0.897 0.861 0.813 0.622 0.735 0.552 0.599 Printed: 4/10/2014 11:23 AM 122 of 603 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.39 36.73 36.92 37.01 37.28 NotFnd 37.62 38.37 NotFnd NotFnd NotFnd 35.38 35.83 36.14 NotFnd 37.66 NotFnd 38.43 NotFnd 38.95 NotFnd 39.15 39.52 NotFnd NotFnd NotFnd NotFnd 41.95 NotFnd 43.03 NotFnd 39.63 NotFnd NotFnd NotFnd NotFnd 43.61 44.17 44.33 NotFnd 47.39 NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J J J J EMPC B C J EMPC J C J J J EMPC J J EMPC J EMPC J C J C J J J EMPC C J J EMPC J Pred RRT Actual RRT Diff Secs 0.9766 0.9859 0.9912 0.9934 1.0011 1.0049 1.0097 0.9639 0.9843 0.9903 1.0006 1.0087 1.0217 1.0302 1.0415 1.0736 1.0891 1.0956 1.1007 1.1105 1.1129 1.1160 1.1268 1.1366 1.1419 0.9077 0.9131 0.9191 0.9264 0.9433 0.9531 1.0005 1.0203 1.0348 1.0396 1.0419 1.1005 1.1150 1.1192 0.9515 0.9921 1.0004 1.0005 1.0179 1.0004 0.9766 0.9858 0.9909 0.9934 1.0007 1.0097 0.9643 1.0088 1.0216 1.0304 1.0738 1.0956 1.1105 1.1163 1.1269 0.9198 0.9434 1.0006 1.1011 1.1152 1.1192 0.9920 - 0 -0.2 -0.7 0 -0.9 0 +0.9 +0.2 -0.2 +0.4 +0.5 0 0 +0.7 +0.2 +1.8 +0.3 +0.2 +1.6 +0.5 0 -0.3 Page 5 of 5 Response Ra RRF Conc. / Recv. 1.18E+05 5.40E+04 4.40E+04 5.81E+04 7.49E+05 0.00E+00 8.90E+04 1.19E+05 0.00E+00 0.00E+00 0.00E+00 7.98E+04 4.19E+04 1.86E+04 0.00E+00 2.06E+04 0.00E+00 1.96E+05 0.00E+00 6.31E+04 0.00E+00 8.28E+04 6.20E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.51E+05 0.00E+00 7.83E+04 0.00E+00 3.12E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.95E+04 3.25E+04 4.02E+04 0.00E+00 3.73E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.25 1.40 1.13 0.95 1.22 1.05 0.92 1.20 1.36 1.11 1.39 1.53 0.87 1.06 1.06 1.27 1.07 1.05 1.15 1.08 0.76 1.06 1.12 1.16 1.24 1.00 0.96 0.92 1.08 0.94 0.97 1.28 1.23 1.37 1.11 1.58 1.05 1.12 1.06 1.16 1.03 0.73 0.78 0.80 0.72 0.79 1.06 1.12 1.13 1.11 6.39 3.34 2.09 2.43 38.3 ND 3.31 6.44 ND ND ND 4.15 2.21 0.903 ND 1.5 ND 11.2 ND 3.28 ND 5.57 4.34 ND ND ND ND 13.1 ND 5.47 ND 1.76 ND ND ND ND 5.61 2.48 2.99 ND 3.33 ND ND ND ND 1.06 1.12 1.02 0.89 1.35 1.17 1.09 1.25 0.83 1.00 0.96 1.14 0.91 1.07 1.00 1.11 0.98 Noise / Recv. Low DL / Recv. High 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.39E+03 1.61E+03 1.61E+03 1.61E+03 1.30E+03 1.30E+03 1.30E+03 1.30E+03 1.30E+03 1.30E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.31E+03 1.35E+03 1.35E+03 1.35E+03 3.01E+03 3.01E+03 3.01E+03 0.79 0.901 0.689 0.609 0.743 0.594 0.54 0.917 0.755 0.754 0.574 0.68 0.691 0.634 0.672 0.953 1.03 0.974 0.946 0.884 1.09 1.15 1.19 1.02 1.17 1.13 0.853 0.89 0.796 1.18 0.824 0.771 0.727 0.765 0.698 0.791 1.11 1.04 1.02 1.38 1.27 0.94 1.71 1.7 2.67 Printed: 4/10/2014 11:23 AM 123 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 5.31e7 2.66e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 1.95e7 9.73e6 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 1.65e7 8.23e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 2.04e7 1.02e7 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 1.21e7 6.07e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 4.11e6 2.05e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 3.86e6 1.93e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 388-879 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:26 Page 1 of 21 124 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-1 1.69e5 11.82 Rel. Int. 100% Abs. Int. 6.85e4 MoCB 10.03-15.71 188.0393 Fn1 Flags: PBM 4σ 2.28e3 PCB-3 1.01e5 14.10 PCB-2 6.13e4 13.92 3.42e4 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 5.83e4 11.82 Rel. Int. 100% Abs. Int. 2.64e4 MoCB 10.03-15.71 190.0363 Fn1 Flags: PBM 4σ 2.27e3 PCB-3 3.33e4 14.10 PCB-2 1.91e4 13.91 1.32e4 0% 11.0 12.0 13.0 14.0 15.0 ES-3 3.02e7 14.09 ES-1 2.53e7 11.81 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 1.04e7 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PBM 4σ 4.14e3 5.21e6 0% 11.0 12.0 13.0 ES-1 7.74e6 11.81 Rel. Int. 100% 14.0 15.0 ES-3 8.80e6 14.08 0.00e0 RT Abs. Int. 3.17e6 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PBM 4σ 3.22e4 1.58e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0070, 2765 scc: 388-879 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:38 Printed: 06-Apr-2014 17:26 Page 2 of 21 125 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-4 6.10e5 14.35 Rel. Int. 100% Abs. Int. 2.14e5 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PBM 4σ 3.40e3 1.07e5 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 3.97e5 14.35 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.52e5 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PBM 4σ 1.02e4 7.59e4 0% 11.0 12.0 13.0 14.0 15.0 ES-4 1.42e7 14.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.94e6 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PBM 4σ 5.76e3 2.47e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 8.77e6 14.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.04e6 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PBM 4σ 3.33e3 1.52e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8294, 2493 scc: 388-879 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:38 (CEM) Printed: 06-Apr-2014 17:26 Page 3 of 21 126 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PCB-6 6.52e5 16.71 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-8 5.45e5 17.13 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 Abs. Int. 2.09e5 PCB-11 5.83e5 19.46 DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PBM 4σ 3.67e3 13/12 2.39e5 19.73 PCB-15 4.04e5 20.03 1.05e5 0% 16.0 17.0 Rel. Int. 100% PCB-6 3.70e5 16.71 18.0 19.0 PCB-8 3.34e5 17.13 20.0 13/12 1.18e5 19.73 PCB-15 2.49e5 20.03 7.27e4 0% 16.0 17.0 18.0 19.0 JS-9 4.50e7 16.30 Rel. Int. 100% 20.0 21.0 (4.22e7 + 2.68e7) * 2000 pg * 100 = 90.4% (4.50e7 + 2.84e7) * 2000 pg * 1.04 CEM 06-Apr-2014 16:43 7.07e6 Recv(ES-156/157) = 0% 16.0 17.0 18.0 19.0 JS-9 2.84e7 16.30 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 ES-15 4.22e7 20.02 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PBM 4σ 1.89e4 0.00e0 RT Abs. Int. 1.45e5 PCB-11 3.58e5 19.46 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PBM 4σ 1.25e4 21.0 20.0 21.0 0.00e0 RT Abs. Int. 9.06e6 ES-15 2.68e7 20.02 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PBM 4σ 4.97e3 4.53e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 9.73e6 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3985, 1218 scc: 388-879 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:38 Printed: 06-Apr-2014 17:26 Page 4 of 21 127 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 Abs. Int. 4.53e5 30/18 1.56e6 19.18 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PBM 4σ 3.10e3 PCB-17 6.22e5 19.57 PCB-19 2.80e5 17.42 PCB-27 1.52e5 19.76 PCB-16 3.62e5 19.99 PCB-32 9.62e5 20.47 2.27e5 0% 16.0 17.0 18.0 Rel. Int. 100% 19.0 20.0 21.0 Abs. Int. 4.49e5 30/18 1.49e6 19.18 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PBM 4σ 2.64e3 PCB-17 6.23e5 19.57 PCB-19 2.44e5 17.42 PCB-27 1.56e5 19.76 PCB-16 3.36e5 19.99 PCB-32 8.98e5 20.47 2.25e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-19 1.34e7 17.40 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 4.23e6 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PBM 4σ 4.82e4 2.12e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-19 1.26e7 17.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.85e6 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PBM 4σ 1.63e4 1.93e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 9.73e6 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4788, 8711 scc: 388-879 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:38 Printed: 06-Apr-2014 17:26 Page 5 of 21 128 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-31 2.47e6 22.53 Rel. Int. 100% TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 3.28e3 26/29 7.68e5 22.03 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 28/20 2.79e6 22.80 PCB-25 9.15e5 22.25 Abs. Int. 7.06e5 21/33 5.03e5 23.01 PCB-22 6.98e5 23.37 PCB-37 3.90e5 26.35 0% 22.0 23.0 PCB-31 2.44e6 22.53 Rel. Int. 100% TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 2.96e3 26/29 7.44e5 22.03 24.0 25.0 0.00e0 RT 26.0 28/20 2.81e6 22.80 PCB-25 9.20e5 22.25 Abs. Int. 7.00e5 21/33 4.93e5 23.01 3.50e5 PCB-22 6.93e5 23.37 PCB-37 3.71e5 26.35 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 3.80e7 22.78 Rel. Int. 100% 3.53e5 ES-37 3.30e7 26.33 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PBM 4σ 3.87e4 Abs. Int. 1.06e7 5.31e6 0% 22.0 23.0 24.0 25.0 CS/SS-28 3.47e7 22.78 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 2.99e7 26.33 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PBM 4σ 2.07e4 Abs. Int. 9.66e6 4.83e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 8.23e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4348, 0363 scc: 388-879 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:38 Printed: 06-Apr-2014 17:26 Page 6 of 21 129 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-54 1.39e4 20.32 Rel. Int. 100% Abs. Int. 5.87e3 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PBM 4σ 1.08e3 2.93e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 PCB-54 1.27e4 20.32 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.38e3 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PBM 4σ 1.29e3 2.19e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 1.56e7 20.30 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.32e6 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PBM 4σ 9.92e3 2.16e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 1.99e7 20.30 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.60e6 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PBM 4σ 6.63e3 2.80e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 9.73e6 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4955, 3450 scc: 388-879 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:38 (CEM) Printed: 06-Apr-2014 17:26 Page 7 of 21 130 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-52 2.67e6 24.42 Rel. Int. 100% TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 1.34e3 69/49 1.81e6 24.86 PCB-51 4.06e5 22.96 50/53 4.83e5 22.27 PCB-45 3.51e5 22.88 PCB-48 3.43e5 25.11 PCB-46 1.57e5 23.16 Abs. Int. 7.42e5 44/47… 2.69e6 25.31 59/62… 2.50e5 25.60 PCB-42 5.96e5 25.77 71/40 1.16e6 26.20 PCB-64 1.26e6 26.40 0% 22.0 23.0 24.0 25.0 PCB-52 3.38e6 24.42 Rel. Int. 100% TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 1.59e3 50/53 6.26e5 22.27 PCB-45 4.42e5 22.89 PCB-48 4.36e5 25.11 PCB-46 1.93e5 23.16 Abs. Int. 9.00e5 59/62… 3.28e5 25.60 PCB-42 7.57e5 25.77 0% 22.0 23.0 24.0 25.0 26.0 JS-52 1.98e7 24.39 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 3.47e6 25.31 69/49 2.28e6 24.85 PCB-51 4.69e5 22.96 3.71e5 71/40 1.43e6 26.20 PCB-64 1.67e6 26.40 4.50e5 0.00e0 RT Abs. Int. 5.24e6 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PBM 4σ 2.32e4 2.62e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 2.46e7 24.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.35e6 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PBM 4σ 1.25e4 3.18e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 8.23e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5298, 0389 scc: 388-879 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:42 (CEM) Printed: 06-Apr-2014 17:26 Page 8 of 21 131 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-66 1.85e6 28.90 Rel. Int. 100% TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 1.80e3 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-68 3.76e5 27.37 Abs. Int. 5.12e5 PCB-56 9.69e5 29.48 PCB-60 3.98e5 29.68 PCB-63 1.07e5 28.33 2.56e5 PCB-77 1.82e5 32.66 0% 28.0 32.0 34.0 36.0 61/70... 3.80e6 28.63 Rel. Int. 100% TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 2.77e3 30.0 PCB-68 4.64e5 27.37 PCB-63 1.45e5 28.33 Abs. Int. 6.22e5 PCB-56 1.21e6 29.48 PCB-60 5.03e5 29.68 3.11e5 PCB-77 2.43e5 32.66 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 2.44e7 32.17 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PBM 4σ 1.73e4 34.0 36.0 0.00e0 RT Abs. Int. 6.25e6 ES-77 2.56e7 32.65 3.12e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 3.10e7 32.17 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PBM 4σ 1.23e4 34.0 36.0 0.00e0 RT Abs. Int. 7.66e6 ES-77 3.20e7 32.65 3.83e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9656, 5432 scc: 388-879 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:43 (CEM) Printed: 06-Apr-2014 17:26 Page 9 of 21 132 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-96 2.55e4 25.60 Rel. Int. 100% Abs. Int. 8.17e3 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 7.09e2 4.09e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 3.73e4 25.60 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.41e3 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 7.53e2 4.70e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 2.31e7 25.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.48e6 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PBM 4σ 2.09e3 3.24e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 1.46e7 25.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.02e6 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PBM 4σ 1.97e3 2.01e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 8.23e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4969, 1973 scc: 388-879 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:38 (CEM) Printed: 06-Apr-2014 17:26 Page 10 of 21 133 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-110 1.03e6 32.09 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 1.43e3 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 Abs. Int. 2.55e5 113/90… 7.05e5 30.39 PCB-95 5.82e5 27.86 PCB-91 1.56e5 28.61 PCB-84 2.45e5 28.81 PCB-118 6.77e5 34.64 PCB-99 3.96e5108/119... 116/85 30.90 6.14e5 31.37 1.93e5 31.96 PCB-92 1.08e5 29.88 PCB-82 1.21e5 32.37 PCB-109 5.84e4 34.25 PCB-105 3.42e5 35.64 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 1.22e3 0% PCB-95 9.36e5 27.86 32.0 113/90… 1.15e6 30.39 PCB-91 2.77e5 28.61 PCB-84 3.69e5 PCB-102 28.81 7.85e4 28.18 28.0 30.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.87e5 PCB-118 1.07e6 34.64 PCB-82 1.78e5 32.37 32.0 PCB-105 5.31e5 35.64 PCB-109 9.78e4 34.26 34.0 CS/SS-111 3.22e7 32.66 JS-101 2.51e7 30.37 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PBM 4σ 2.52e3 36.0 PCB-110 1.61e6 32.09 PCB-99108/119... 6.30e5 1.06e6 30.90 31.37 116/85 3.00e5 PCB-83 31.96 7.89e4 30.80 PCB-92 2.09e5 29.88 34.0 1.27e5 ES-123 2.95e7 34.34 36.0 ES-118 ES-114 2.97e7 3.05e7 34.62 35.08 ES-105 3.08e7 35.62 1.94e5 0.00e0 RT Abs. Int. 8.01e6 4.01e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 2.06e7 32.66 JS-101 1.56e7 30.37 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PBM 4σ 2.43e3 34.0 ES-114 ES-118 1.90e7 ES-123 1.87e7 35.08 1.87e7 34.62 34.34 36.0 ES-105 1.94e7 35.62 0.00e0 RT Abs. Int. 5.19e6 2.60e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7615, 7893 scc: 388-879 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:44 (CEM) Printed: 06-Apr-2014 17:26 Page 11 of 21 134 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 Rel. Int. 100% Abs. Int. 1.38e6 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PB 4σ 1.25e3 6.89e5 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 3.16e6 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PB 4σ 1.31e3 1.58e6 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 3.12e6 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 2.03e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 4.05e6 ES-126 1.69e7 38.23 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PBM 4σ 4.55e3 0% 38.0 0.00e0 RT Abs. Int. 6.24e6 ES-126 2.61e7 38.23 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PBM 4σ 5.43e3 Rel. Int. 100% 0.00e0 RT 6.07e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1688, 2258 scc: 388-879 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:38 Printed: 06-Apr-2014 17:26 Page 12 of 21 135 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 153/168 3.82e5 36.22 147/149 3.03e5 33.66 HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 6.21e2 PCB-136 7.63e4 30.83 PCB-132 1.18e5 34.74 151/135 1.12e5 32.88 PCB-146 5.50e4 35.69 163/138… 4.11e5 37.28 PCB-141 6.54e4 PCB-137 36.39 2.33e4 36.92 5.11e4 PCB-158 4.95e4 37.62 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 7.66e2 PCB-136 4.78e4 30.84 153/168 2.74e5 36.22 PCB-132 1.02e5 34.73 151/135 9.81e4 32.88 0.00e0 RT 36.0 147/149 2.40e5 33.66 PCB-146 5.12e4 35.69 163/138… 3.38e5 37.29 PCB-141 PCB-164 PCB-158 4.67e4 5.22e4 3.40e4 37.61 36.39 37.01 30.0 32.0 34.0 ES-155 2.77e7 30.20 Rel. Int. 100% 36.0 ES-153 2.08e7 36.20 HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PBM 4σ 1.68e3 Abs. Int. 7.88e4 3.94e4 0.00e0 RT 0% 28.0 Abs. Int. 1.02e5 JS-138 1.89e7 37.26 Abs. Int. 7.03e6 3.51e6 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 ES-155 2.19e7 30.20 Rel. Int. 100% ES-153 1.59e7 36.20 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PBM 4σ 1.66e3 JS-138 1.51e7 37.26 Abs. Int. 5.57e6 2.79e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0529, 1179 scc: 388-879 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:44 (CEM) Printed: 06-Apr-2014 17:26 Page 13 of 21 136 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% 128/166 6.28e4 38.37 PCB-167 2.12e4 39.81 0% 38.0 39.0 (5.18e4 + 3.74e4) * 4000 pg = 3.92 pg/L (4.88e7 + 3.76e7) * 1.10 * 0.957 L CEM 06-Apr-2014 16:42 Conc(156/157) = 41.0 42.0 43.0 6.64e3 44.0 39.0 40.0 5.62e3 41.0 42.0 43.0 44.0 ES-156/157 4.88e7 40.78 ES-167 2.47e7 39.79 0.00e0 RT Abs. Int. 8.48e6 ES-169 2.34e7 43.49 4.24e6 39.0 Rel. Int. 100% 40.0 ES-167 1.96e7 39.79 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PBM 4σ 4.28e3 41.0 42.0 43.0 44.0 ES-156/157 3.76e7 40.78 0.00e0 RT Abs. Int. 6.64e6 ES-169 1.84e7 43.49 3.32e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 1.12e4 PCB-167 1.41e4 39.81 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PBM 4σ 4.48e3 0% 38.0 Abs. Int. 1.33e4 156/157 3.74e4 40.79 Rel. Int. 100% 0% 38.0 40.0 128/166 5.62e4 38.38 HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 8.24e2 0% 38.0 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 156/157 5.18e4 40.79 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 7.82e2 Rel. Int. 100% Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 6.07e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7130, 3885 scc: 388-879 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 16:42 (CEM) Printed: 06-Apr-2014 17:26 Page 14 of 21 137 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% PCB-184 1.97e4 35.83 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 PCB-179 3.95e4 35.38 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 6.74e2 0% 30.0 Abs. Int. 1.13e4 PCB-179 4.04e4 35.38 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 6.26e2 0% 30.0 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-178 1.11e4 37.66 PCB-176 1.23e4 36.14 36.0 32.0 33.0 34.0 35.0 Abs. Int. 8.59e3 PCB-184 2.21e4 35.83 PCB-178 9.51e3 37.67 36.0 Abs. Int. 4.81e6 CS/SS-178 1.31e7 37.64 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PBM 4σ 1.39e3 2.40e6 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 4.38e6 CS/SS-178 1.23e7 37.64 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PBM 4σ 1.45e3 2.19e6 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 0.00e0 RT 37.0 ES-188 1.82e7 35.07 Rel. Int. 100% 0% 30.0 4.29e3 0.00e0 RT 37.0 ES-188 1.93e7 35.07 Rel. Int. 100% 0% 30.0 0.00e0 RT 37.0 PCB-176 9.14e3 36.13 31.0 5.63e3 1.02e7 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0058, 0534 scc: 388-879 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 16:55 (CEM) Printed: 06-Apr-2014 17:26 Page 15 of 21 138 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 9.47e2 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 180/193 1.23e5 41.95 PCB-187 1.02e5 38.43 0% 38.0 PCB-183 PCB-174 3.86e4 4.22e4 39.15 38.95 39.0 0% 38.0 Abs. Int. 3.08e4 PCB-170 4.17e4 43.03 PCB-177 3.10e4 39.52 40.0 41.0 42.0 43.0 1.54e4 44.0 180/193 1.28e5 41.95 Rel. Int. 100% HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 6.78e2 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-187 9.37e4 38.43 PCB-174 PCB-183 5.08e4 39.14 3.09e4 38.95 39.0 Abs. Int. 3.14e4 PCB-170 3.65e4 43.03 PCB-177 3.11e4 39.52 40.0 41.0 42.0 ES-180 1.69e7 41.94 Rel. Int. 100% 43.0 1.57e4 44.0 2.02e6 39.0 40.0 41.0 42.0 ES-180 1.56e7 41.94 Rel. Int. 100% HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PBM 4σ 2.87e3 0% 38.0 43.0 44.0 0.00e0 RT Abs. Int. 3.70e6 ES-170 1.30e7 43.00 1.85e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 4.03e6 ES-170 1.40e7 43.00 HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PBM 4σ 2.34e3 0% 38.0 0.00e0 RT 6.07e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1800, 4183 scc: 388-879 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:40 (CEM) Printed: 06-Apr-2014 17:26 Page 16 of 21 139 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 Rel. Int. 100% Abs. Int. 1.83e3 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PB 4σ 8.27e2 9.13e2 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e3 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PB 4σ 8.23e2 9.93e2 0% 45.0 46.0 47.0 48.0 49.0 ES-189 2.01e7 45.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.97e6 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PBM 4σ 2.49e3 2.49e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 1.94e7 45.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.76e6 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PBM 4σ 3.00e3 2.38e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.05e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0112, 0220 scc: 388-879 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:40 (CEM) Printed: 06-Apr-2014 17:26 Page 17 of 21 140 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 198/199 3.95e4 43.61 Rel. Int. 100% PCB-202 1.49e4 39.63 OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PBM 4σ 6.61e2 0% 38.0 39.0 PCB-196 1.62e4 44.17 40.0 41.0 42.0 43.0 PCB-202 1.63e4 39.62 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PBM 4σ 6.48e2 39.0 Abs. Int. 8.38e3 41.0 42.0 43.0 44.0 ES-202 1.67e7 39.61 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 1.85e7 39.61 0.00e0 RT 0.00e0 RT Abs. Int. 4.38e6 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PBM 4σ 1.54e3 2.19e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 4.19e3 2.00e6 Rel. Int. 100% 0% 38.0 PCB-203 2.13e4 44.33 Abs. Int. 4.00e6 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PBM 4σ 1.75e3 0% 38.0 0.00e0 RT 44.0 PCB-196 1.63e4 44.16 40.0 Abs. Int. 8.23e3 4.11e3 198/199 3.67e4 43.60 Rel. Int. 100% 0% 38.0 PCB-203 2.37e4 44.33 6.07e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6738, 0133 scc: 388-879 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:41 (CEM) Printed: 06-Apr-2014 17:26 Page 18 of 21 141 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-194 1.84e4 47.39 Rel. Int. 100% Abs. Int. 5.74e3 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PBM 4σ 8.23e2 2.87e3 0% 45.0 46.0 47.0 48.0 49.0 PCB-194 1.89e4 47.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.79e3 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PBM 4σ 5.26e2 2.89e3 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.21e7 47.37 49.0 ES-205 1.41e7 47.77 0.00e0 RT Abs. Int. 3.34e6 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PBM 4σ 2.39e3 1.67e6 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 1.35e7 47.38 49.0 ES-205 1.57e7 47.77 0.00e0 RT Abs. Int. 3.79e6 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PBM 4σ 1.86e3 1.90e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.05e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7903, 5678 scc: 388-879 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:41 (CEM) Printed: 06-Apr-2014 17:26 Page 19 of 21 142 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 Rel. Int. 100% Abs. Int. 4.59e3 NoCB 44.77-49.81 461.7245 Fn6 Flags: PB 4σ 8.82e2 2.30e3 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. 100% Abs. Int. 5.04e3 NoCB 44.77-49.81 463.7216 Fn6 Flags: PB 4σ 2.12e3 2.52e3 0.00e0 RT 0% 45.0 46.0 47.0 48.0 49.0 ES-208 1.43e7 45.23 Rel. Int. 100% ES-206 9.65e6 49.24 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PBM 4σ 1.14e3 Abs. Int. 3.62e6 1.81e6 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 ES-208 1.80e7 45.23 Rel. Int. 100% ES-206 1.20e7 49.24 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PBM 4σ 1.82e3 Abs. Int. 4.40e6 2.20e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.11e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.05e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9999, 5604 scc: 388-879 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:38 Printed: 06-Apr-2014 17:26 Page 20 of 21 143 of 603 SGS ID: A6528_11906_PCB_003 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (TOTAL) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 04-Apr-2014 04:34:05 User: LKB Datafile: 140403X18 PCB-209 2.30e4 50.68 Rel. Int. 100% Abs. Int. 6.43e3 DeCB 49.82-52.00 497.6826 Fn7 Flags: PBM 4σ 6.20e2 3.22e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.17e4 50.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.39e3 DeCB 49.82-52.00 499.6797 Fn7 Flags: PBM 4σ 5.93e2 3.69e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.47e7 50.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.18e6 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PBM 4σ 1.05e3 1.59e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 1.26e7 50.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.67e6 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PBM 4σ 9.66e2 1.34e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.86e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 1.93e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_003.utp_res, saved 06-Apr-2014 16:55 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3688, 4171 scc: 388-879 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:41 (CEM) Printed: 06-Apr-2014 17:26 Page 21 of 21 144 of 603 Lab ID: A6528_11906_PCB_004 ACQ: 04-Apr-2014 05:29:13 LKB Wt/Vol: 1.12 L Client ID: PB101.1-1SWMID-140319-N (DISSOLVED) UTP: 06-Apr-2014 00:37 CEM J-level: 8.97 pg/L Datafile: 140403X19 RPT: 06-Apr-2014 16:20 CM Stds (pg): JS: 2000 ES: 2000 CS/SS: 2000 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.66 NotFnd 35.63 35.08 34.63 NotFnd NotFnd 40.77 NotFnd NotFnd NotFnd 50.67 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services 11.80 14.08 14.33 20.01 17.39 26.32 20.29 32.64 32.16 25.25 35.61 35.07 34.61 34.33 38.22 36.19 30.19 40.77 39.79 43.48 43.00 41.93 35.06 45.60 39.60 47.77 49.23 45.22 50.65 QC J J B J EMPC B J C J B Pred RRT Actual RRT Diff Secs 1.0006 1.0005 1.0007 1.0006 1.0007 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0000 1.0006 1.0005 1.0001 1.0007 1.0000 1.0005 0 0.7244 0.8640 0.8793 1.2279 1.0674 1.0793 0.8322 1.3381 1.3186 0.8317 1.1729 1.1551 1.1398 1.1306 1.2588 0.9715 0.8106 1.0943 1.0679 1.1671 0.9078 0.8852 0.7404 0.9628 0.8361 1.0084 1.0393 0.9547 1.0692 0.7244 0.8640 0.8793 1.2282 1.0674 1.0793 0.8321 1.3384 1.3189 0.8317 1.1730 1.1552 1.1399 1.1306 1.2590 0.9715 0.8105 1.0944 1.0680 1.1673 0.9077 0.8852 0.7403 0.9628 0.8360 1.0084 1.0393 0.9547 1.0692 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XC Split: 1 Checkcode: 118-899-GHZ Method 1668A Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.81 +1.5 2.39E+05 0.00E+00 3.42E+05 3.51E+04 7.92E+05 0.00E+00 0.00E+00 4.48E+04 0.00E+00 0.00E+00 0.00E+00 4.77E+04 1.18 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 2.65 ND 4.55 0.442 10.2 ND ND 0.706 ND ND ND 1.18 3.99E+03 3.99E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 2.33E+03 1.45E+03 1.45E+03 1.45E+03 1.63E+03 1.06E+03 0.455 0.483 0.263 0.247 0.256 0.25 0.367 0.329 0.216 0.238 0.31 0.306 0 0 0 +0.4 0 0 -0.1 +0.6 +0.6 0 +0.2 +0.2 +0.2 0 +0.5 0 -0.2 +0.2 +0.2 +0.5 -0.3 0 -0.2 0 -0.2 0 0 0 0 9.83E+07 1.17E+08 6.71E+07 1.78E+08 7.03E+07 1.55E+08 9.05E+07 1.40E+08 1.35E+08 9.41E+07 1.21E+08 1.18E+08 1.17E+08 1.16E+08 1.06E+08 8.57E+07 1.19E+08 2.07E+08 1.08E+08 1.03E+08 6.57E+07 7.83E+07 9.08E+07 9.42E+07 8.37E+07 7.17E+07 5.10E+07 7.76E+07 6.53E+07 3.29 3.35 1.59 1.58 1.06 1.10 0.79 0.80 0.81 1.60 1.61 1.60 1.61 1.56 1.58 1.31 1.28 1.28 1.26 1.25 1.08 1.06 1.07 1.05 0.93 0.89 0.80 0.80 1.18 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 48.1 % 62.7 % 74.9 % 99.9 % 81.1 % 89.4 % 100 % 96.9 % 94.3 % 123 % 106 % 102 % 106 % 103 % 109 % 99.6 % 94.3 % 81.5 % 81.2 % 83 % 100 % 101 % 121 % 102 % 109 % 98.6 % 105 % 113 % 101 % 15% 15% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 25% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% 150% -0.4 -1.1 0 -1.2 Page 1 of 5 0.63 0.76 0.64 1.26 Printed: 4/6/2014 5:18 PM 145 of 603 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.77 32.65 37.63 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 1.76E+08 1.27E+08 5.90E+07 1.10 1.58 1.07 1.11 1.03 0.62 102 % 107 % 105 % 30% 30% 30% 135% 135% 135% CS PCB-28 CS PCB-111 CS PCB-178 22.77 32.65 37.63 0.9337 1.0754 1.0101 0.9337 1.0754 1.0101 0 0 0 1.76E+08 1.27E+08 5.90E+07 1.10 1.58 1.07 1.85 1.22 0.58 91 % 109 % 127 % 30% 30% 30% 135% 135% 135% JS JS JS JS JS 16.29 24.39 30.36 37.25 47.37 1.71E+08 1.05E+08 9.50E+07 7.95E+07 5.85E+07 1.58 0.81 1.57 1.29 0.90 4.68E+03 4.68E+03 4.68E+03 5.67E+03 5.67E+03 5.79E+03 5.79E+03 5.79E+03 5.79E+03 5.79E+03 5.79E+03 5.79E+03 5.79E+03 5.79E+03 5.88E+03 5.88E+03 5.88E+03 5.88E+03 5.88E+03 5.88E+03 0.576 0.453 0.518 0.897 0.589 0.535 0.47 0.5 0.504 0.49 0.422 0.491 0.491 0.51 1.11 0.843 1 0.717 0.739 1.36 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.82 13.91 14.09 14.34 14.52 16.31 16.48 16.70 NotFnd 17.12 NotFnd 19.45 19.73 20.02 17.41 19.17 19.56 19.75 19.88 19.98 J J J J J B J C C J J 1.0011 0.9880 1.0009 1.0011 1.0135 1.0010 1.0111 1.0250 1.0435 1.0507 0.9331 0.9720 0.9866 1.0008 1.0010 1.1017 1.1247 1.1357 1.1435 1.1489 1.0011 0.9882 1.0010 1.0011 1.0135 1.0008 1.0113 1.0250 1.0509 0.9721 0.9857 1.0006 1.0010 1.1022 1.1248 1.1358 1.1429 1.1490 0 +0.2 +0.1 0 0 -0.2 +0.2 0 +0.2 +0.1 -1.1 -0.2 0 +0.6 +0.1 +0.1 -0.7 +0.1 Page 2 of 5 NON-EMPC 20.5 141 462 529 124 29 9.02 0.857 0 5.91E+05 1.87E+05 4.40E+05 2.44E+06 1.39E+05 1.98E+05 1.51E+05 2.18E+06 0.00E+00 2.10E+06 0.00E+00 2.32E+06 8.24E+05 1.23E+06 1.08E+06 5.61E+06 2.16E+06 5.92E+05 7.85E+04 1.41E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 20.5 141 462 530 127 32.9 10.9 1.96 0 3.34 2.89 2.94 1.57 SI SI SI 1.60 1.66 1.62 1.35 1.50 1.07 1.03 1.01 1.12 1.16 1.09 0.95 1.15 1.01 1.23 1.88 0.97 1.11 1.04 1.03 1.06 1.23 1.06 1.06 1.02 1.15 1.51 1.27 1.77 1.72 0.94 DL 0.547 0.704 0.955 0.437 0.264 0.243 0.344 0.287 0.718 11.3 2.49 6.69 52.8 1.97 2.05 1.37 21.1 ND 19.9 ND 22 7.84 12.2 24 95 43.4 8.51 1.16 38.4 Printed: 4/6/2014 5:18 PM 146 of 603 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.46 NotFnd NotFnd 22.02 22.24 22.52 22.79 23.00 23.36 NotFnd NotFnd NotFnd NotFnd 26.35 20.31 22.27 22.88 22.95 23.16 24.41 NotFnd 24.64 24.85 25.11 25.30 25.59 25.77 26.10 26.20 26.39 NotFnd 27.36 NotFnd NotFnd 28.09 28.32 28.62 28.89 NotFnd 29.47 29.67 NotFnd NotFnd NotFnd NotFnd 25.59 NotFnd NotFnd SGS Evironmental Services QC C C J C J EMPC C J J C C J C J C J J C J J Pred RRT Actual RRT Diff Secs 1.1763 0.8211 0.8268 0.8375 0.8451 0.8556 0.8663 0.8732 0.8875 0.9397 0.9520 0.9721 0.9871 1.0008 1.0010 0.9141 0.9381 0.9410 0.9497 1.0009 1.0062 1.0102 1.0181 1.0296 1.0385 1.0498 1.0566 1.0702 1.0741 1.0823 0.8429 0.8509 0.8624 0.8687 0.8736 0.8806 0.8897 0.8984 0.9030 0.9165 0.9225 0.9326 0.9737 0.9888 1.0009 1.0135 0.8985 0.9048 1.1766 0.8366 0.8449 0.8556 0.8660 0.8739 0.8874 1.0011 1.0008 0.9131 0.9381 0.9411 0.9497 1.0009 1.0103 1.0190 1.0296 1.0376 1.0494 1.0566 1.0701 1.0743 1.0823 0.8509 0.8735 0.8806 0.8900 0.8984 0.9165 0.9225 1.0135 - +0.4 -1.2 -0.3 0 -0.4 +1.0 -0.1 +0.5 -0.2 -1.3 0 +0.1 0 0 +0.1 +1.3 0 -1.4 -0.6 0 -0.2 +0.3 0 0 -0.2 0 +0.5 0 0 0 0 Page 3 of 5 Response Ra RRF Conc. / Recv. 3.14E+06 0.00E+00 0.00E+00 2.10E+06 2.73E+06 6.61E+06 7.14E+06 1.49E+06 1.97E+06 0.00E+00 0.00E+00 0.00E+00 0.00E+00 8.90E+05 3.71E+04 1.36E+06 9.88E+05 1.83E+06 4.31E+05 6.09E+06 0.00E+00 1.70E+05 3.58E+06 7.16E+05 5.95E+06 5.54E+05 1.21E+06 2.49E+05 2.48E+06 2.72E+06 0.00E+00 2.41E+06 0.00E+00 0.00E+00 1.11E+05 1.60E+05 4.62E+06 2.62E+06 0.00E+00 1.49E+06 5.97E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.23E+04 0.00E+00 0.00E+00 1.03 1.88 1.24 1.26 1.28 1.30 1.34 1.24 1.29 1.19 1.34 1.35 1.21 1.17 1.08 1.35 0.91 0.75 0.95 0.73 0.89 1.15 0.72 1.09 0.89 0.96 1.25 0.82 0.72 0.92 1.33 1.23 1.32 1.17 1.23 1.27 1.33 1.21 1.18 1.15 1.14 1.16 1.36 1.37 1.11 1.43 1.15 0.92 0.78 42.7 ND ND 19 24.2 56.9 66.4 13.3 19.1 ND ND ND ND 9.52 0.544 20 17.5 25.4 7.87 90.6 ND 3.16 43.8 10.7 82.7 5.89 19.8 4.58 35.7 27.2 ND 24.3 ND ND 1.16 1.6 50.8 29.5 ND 17.4 6.86 ND ND ND ND 0.7 ND ND 0.97 0.99 0.99 1.01 1.00 1.04 1.10 1.02 0.79 0.76 0.78 0.83 0.77 0.75 0.78 0.81 0.81 0.79 0.79 0.76 0.76 0.77 0.80 0.71 0.86 0.80 0.80 0.75 0.77 0.69 Noise / Recv. Low DL / Recv. High 5.88E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 7.42E+03 2.19E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.21E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 3.99E+03 1.53E+03 1.53E+03 1.92E+03 1.92E+03 0.677 0.696 0.687 0.678 0.665 0.646 0.698 0.671 0.727 0.644 0.641 0.713 0.738 0.802 0.282 0.48 0.578 0.456 0.597 0.486 0.378 0.607 0.401 0.488 0.456 0.348 0.534 0.602 0.472 0.327 0.438 0.411 0.461 0.441 0.426 0.407 0.447 0.457 0.47 0.475 0.468 0.398 0.396 0.487 0.2 0.248 0.328 0.39 Printed: 4/6/2014 5:18 PM 147 of 603 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.85 NotFnd 28.17 NotFnd NotFnd 28.61 28.80 29.21 NotFnd 29.88 30.38 30.78 30.89 31.03 31.37 NotFnd 31.94 32.08 NotFnd 32.36 NotFnd NotFnd 34.05 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 30.82 NotFnd NotFnd 32.88 NotFnd NotFnd 33.65 NotFnd NotFnd NotFnd NotFnd NotFnd 34.73 NotFnd NotFnd 35.69 NotFnd 36.21 SGS Evironmental Services QC B C J J J J J B C J EMPC J B EMPC J B C J C B J J EMPC C J B EMPC J B C J B C C J B EMPC J B J B C Pred RRT Actual RRT Diff Secs 0.9173 0.9243 0.9278 0.9301 0.9402 0.9423 0.9486 0.9623 0.9735 0.9840 0.9999 1.0144 1.0175 1.0208 1.0321 1.0496 1.0527 1.0566 1.0594 1.0659 1.0761 1.0892 0.9915 0.9975 1.0039 1.0091 1.0351 1.0007 1.0062 1.0108 1.0210 1.0299 1.0719 1.0891 1.0960 1.1048 1.1148 1.1205 1.1231 1.1319 1.1377 1.1425 1.1502 1.1636 0.9523 0.9580 0.9612 0.9727 0.9173 0.9278 0.9422 0.9486 0.9622 0.9841 1.0007 1.0139 1.0174 1.0219 1.0331 1.0520 1.0567 1.0660 0.9918 1.0210 1.0889 1.1147 1.1503 0.9580 0.9720 0 0 -0.2 0 -0.2 +0.2 +1.5 -0.9 -0.2 +2.0 +1.9 -1.3 +0.2 +0.2 +0.6 0 -0.4 -0.2 +0.2 0 -1.5 Page 4 of 5 Response Ra RRF Conc. / Recv. 1.06E+06 0.00E+00 8.96E+04 0.00E+00 0.00E+00 2.42E+05 4.25E+05 4.16E+04 0.00E+00 1.92E+05 1.06E+06 6.16E+04 5.27E+05 7.97E+03 9.01E+05 0.00E+00 2.67E+05 1.52E+06 0.00E+00 1.38E+05 0.00E+00 0.00E+00 3.82E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 9.70E+04 0.00E+00 0.00E+00 1.58E+05 0.00E+00 0.00E+00 3.25E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.13E+05 0.00E+00 0.00E+00 6.03E+04 0.00E+00 3.65E+05 0.62 0.84 0.85 0.84 0.85 0.81 0.88 0.70 0.75 1.19 0.80 0.96 0.65 0.95 1.12 0.97 1.09 0.96 1.10 1.12 0.69 1.21 1.20 1.09 1.19 1.15 1.00 1.09 1.26 1.08 1.10 1.00 1.04 1.08 1.04 1.22 1.09 1.08 0.82 1.06 1.11 0.92 0.92 0.96 1.02 1.33 1.12 1.50 1.38 19.5 ND 1.66 ND ND 4.28 9.36 0.863 ND 3.71 17.2 1.47 8.58 0.11 14.5 ND 4.33 21.5 ND 3.11 ND ND 0.545 ND ND ND ND ND ND ND 1.45 ND ND 3.17 ND ND 6.31 ND ND ND ND ND 2.47 ND ND 1.12 ND 5.53 0.62 0.65 0.61 0.62 0.59 0.62 0.50 0.59 0.98 0.60 0.64 0.61 0.55 0.80 1.47 1.29 1.35 1.05 1.12 1.12 Noise / Recv. Low DL / Recv. High 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.92E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 0.36 0.359 0.363 0.356 0.373 0.347 0.431 0.406 0.256 0.377 0.317 0.468 0.318 0.27 0.314 0.278 0.317 0.276 0.272 0.44 0.252 0.253 0.279 0.256 0.264 0.298 0.268 0.189 0.221 0.216 0.237 0.23 0.321 0.331 0.283 0.317 0.32 0.421 0.327 0.312 0.375 0.375 0.36 0.34 0.26 0.307 0.23 0.25 Printed: 4/6/2014 5:18 PM 148 of 603 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.38 NotFnd 36.93 37.01 37.28 NotFnd 37.61 38.36 NotFnd NotFnd NotFnd 35.37 NotFnd NotFnd NotFnd NotFnd NotFnd 38.42 NotFnd 38.94 NotFnd 39.14 39.51 NotFnd NotFnd NotFnd NotFnd 41.95 NotFnd 43.02 NotFnd NotFnd NotFnd NotFnd NotFnd NotFnd 43.60 NotFnd NotFnd NotFnd 47.39 NotFnd NotFnd NotFnd NotFnd SGS Evironmental Services QC J J J J B C J J C J J EMPC J J J C J C J J EMPC C J Pred RRT Actual RRT Diff Secs 0.9766 0.9859 0.9912 0.9934 1.0011 1.0049 1.0097 0.9639 0.9843 0.9903 1.0006 1.0087 1.0217 1.0302 1.0415 1.0736 1.0891 1.0956 1.1007 1.1105 1.1129 1.1160 1.1268 1.1366 1.1419 0.9077 0.9131 0.9191 0.9264 0.9433 0.9531 1.0005 1.0203 1.0348 1.0396 1.0419 1.1005 1.1150 1.1192 0.9515 0.9921 1.0004 1.0005 1.0179 1.0004 0.9767 0.9914 0.9934 1.0007 1.0097 0.9642 1.0087 1.0957 1.1106 1.1163 1.1268 0.9198 0.9433 1.1010 0.9921 - +0.2 +0.4 0 -0.9 0 +0.7 0 +0.2 +0.2 +0.7 0 +1.8 0 +1.3 0 Page 5 of 5 Response Ra RRF Conc. / Recv. 7.11E+04 0.00E+00 2.81E+04 3.49E+04 4.22E+05 0.00E+00 5.62E+04 5.42E+04 0.00E+00 0.00E+00 0.00E+00 4.05E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 8.97E+04 0.00E+00 4.93E+04 0.00E+00 5.93E+04 3.59E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.76E+05 0.00E+00 7.17E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.77E+04 0.00E+00 0.00E+00 0.00E+00 2.69E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.18 1.05 0.92 1.20 1.36 1.11 1.39 1.53 0.87 1.06 1.06 1.27 1.07 1.05 1.15 1.08 0.76 1.06 1.12 1.16 1.24 1.00 0.96 0.92 1.08 0.94 0.97 1.28 1.23 1.37 1.11 1.58 1.05 1.12 1.06 1.16 1.03 0.73 0.78 0.80 0.72 0.79 1.06 1.12 1.13 1.11 1.42 ND 0.49 0.537 7.93 ND 0.768 1.03 ND ND ND 0.748 ND ND ND ND ND 1.83 ND 0.913 ND 1.42 0.895 ND ND ND ND 3.27 ND 1.77 ND ND ND ND ND ND 1.1 ND ND ND 0.857 ND ND ND ND 1.34 1.18 1.24 1.23 1.19 1.02 0.88 1.14 1.03 1.15 1.13 1.15 1.32 1.01 Noise / Recv. Low DL / Recv. High 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.63E+03 1.45E+03 1.45E+03 1.45E+03 1.37E+03 1.37E+03 1.37E+03 1.37E+03 1.37E+03 1.37E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.91E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.20E+03 1.31E+03 1.31E+03 1.31E+03 2.60E+03 2.60E+03 2.60E+03 0.33 0.376 0.288 0.254 0.31 0.248 0.226 0.287 0.237 0.236 0.212 0.251 0.255 0.234 0.248 0.351 0.408 0.386 0.375 0.351 0.433 0.454 0.472 0.403 0.462 0.447 0.338 0.353 0.316 0.498 0.349 0.249 0.235 0.247 0.225 0.256 0.357 0.337 0.328 0.477 0.437 0.324 0.564 0.558 0.872 Printed: 4/6/2014 5:18 PM 149 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 5.15e7 2.57e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 1.81e7 9.07e6 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 1.61e7 8.07e6 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 2.07e7 1.04e7 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 1.20e7 5.99e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 3.90e6 1.95e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 3.66e6 1.83e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 118-899 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:26 Page 1 of 21 150 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 PCB-1 4.55e5 11.82 Rel. Int. 100% Abs. Int. 2.00e5 MoCB 10.03-15.71 188.0393 Fn1 Flags: PBM 4σ 2.38e3 PCB-3 3.28e5 14.09 PCB-2 1.39e5 13.91 1.00e5 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 1.36e5 11.81 Rel. Int. 100% Abs. Int. 6.14e4 MoCB 10.03-15.71 190.0363 Fn1 Flags: PBM 4σ 2.30e3 PCB-3 1.12e5 14.09 PCB-2 4.82e4 13.91 3.07e4 0% 11.0 12.0 13.0 14.0 15.0 ES-3 8.99e7 14.08 ES-1 7.54e7 11.80 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 3.09e7 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PBM 4σ 6.81e3 1.54e7 0% 11.0 12.0 13.0 15.0 ES-3 2.69e7 14.08 ES-1 2.29e7 11.80 Rel. Int. 100% 14.0 0.00e0 RT Abs. Int. 9.25e6 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PBM 4σ 3.13e4 4.62e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.15e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9053, 8146 scc: 118-899 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:04 (CEM) Printed: 06-Apr-2014 17:26 Page 2 of 21 151 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 Rel. Int. 100% Abs. Int. 5.18e5 PCB-4 1.49e6 14.34 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PBM 4σ 3.45e3 2.59e5 PCB-10 8.44e4 SI 14.52 0% 11.0 12.0 13.0 14.0 15.0 PCB-4 9.48e5 14.34 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.19e5 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PBM 4σ 9.81e3 1.60e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.12e7 14.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PBM 4σ 6.60e3 7.05e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 2.59e7 14.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.98e6 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PBM 4σ 2.57e3 4.49e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.15e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2995, 7851 scc: 118-899 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:05 (CEM) Printed: 06-Apr-2014 17:26 Page 3 of 21 152 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 PCB-6 1.34e6 16.70 Rel. Int. 100% DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PBM 4σ 3.53e3 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-8 1.31e6 17.12 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 Abs. Int. 4.15e5 PCB-11 1.43e6 19.45 13/12 4.73e5 19.73 PCB-9 PCB-7 1.21e5 SI 9.19e4 SI 16.31 16.48 PCB-15 7.40e5 20.02 2.08e5 0% 16.0 17.0 Rel. Int. 100% PCB-6 8.38e5 16.70 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PBM 4σ 1.14e4 18.0 19.0 PCB-8 7.88e5 17.12 20.0 21.0 Abs. Int. 2.80e5 PCB-11 8.84e5 19.45 13/12 3.51e5 19.72 PCB-15 4.95e5 20.02 1.40e5 0% 16.0 17.0 18.0 19.0 JS-9 1.05e8 16.29 Rel. Int. 100% 0.00e0 RT 20.0 21.0 ES-15 1.09e8 20.01 0.00e0 RT Abs. Int. 3.33e7 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PBM 4σ 2.15e4 1.66e7 0% 16.0 17.0 18.0 19.0 JS-9 6.65e7 16.29 Rel. Int. 100% 20.0 21.0 ES-15 6.90e7 20.01 0.00e0 RT Abs. Int. 2.10e7 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PBM 4σ 5.63e3 1.05e7 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.81e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 9.07e6 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3317, 4437 scc: 118-899 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:04 (CEM) Printed: 06-Apr-2014 17:26 Page 4 of 21 153 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 Abs. Int. 8.49e5 30/18 2.85e6 19.17 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PBM 4σ 2.84e3 PCB-17 1.08e6 19.56 PCB-19 5.57e5 17.41 PCB-27 3.13e5 19.75 PCB-16 7.36e5 19.98 PCB-32 1.60e6 20.46 4.24e5 0% 16.0 17.0 18.0 Rel. Int. 100% 19.0 20.0 21.0 Abs. Int. 8.05e5 30/18 2.77e6 19.17 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PBM 4σ 3.04e3 PCB-17 1.07e6 19.56 PCB-19 5.22e5 17.41 PCB-27 2.79e5 19.75 PCB-16 6.75e5 19.98 PCB-32 1.55e6 20.46 4.03e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-19 3.62e7 17.39 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 1.08e7 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PBM 4σ 4.15e4 5.38e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-19 3.41e7 17.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e7 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PBM 4σ 2.17e4 5.09e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.81e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 9.07e6 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1476, 1213 scc: 118-899 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:12 (CEM) Printed: 06-Apr-2014 17:26 Page 5 of 21 154 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-31 3.28e6 22.52 Rel. Int. 100% TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 4.59e3 26/29 1.04e6 22.02 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 28/20 3.59e6 22.79 PCB-25 1.36e6 22.24 Abs. Int. 9.26e5 21/33 7.45e5 23.00 4.63e5 PCB-22 1.01e6 23.36 PCB-37 4.65e5 26.35 0% 22.0 23.0 PCB-31 3.32e6 22.52 Rel. Int. 100% TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 2.82e3 26/29 1.07e6 22.02 24.0 25.0 0.00e0 RT 26.0 28/20 3.55e6 22.79 PCB-25 1.37e6 22.24 Abs. Int. 9.04e5 21/33 7.45e5 23.00 4.52e5 PCB-22 9.66e5 23.36 PCB-37 4.24e5 26.34 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 9.20e7 22.77 Rel. Int. 100% ES-37 8.15e7 26.32 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PBM 4σ 4.01e4 Abs. Int. 2.47e7 1.24e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 8.38e7 22.77 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 7.40e7 26.32 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PBM 4σ 2.05e4 Abs. Int. 2.21e7 1.11e7 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.61e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 8.07e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8214, 5691 scc: 118-899 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:36 (CEM) Printed: 06-Apr-2014 17:26 Page 6 of 21 155 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 PCB-54 2.13e4 20.31 Rel. Int. 100% Abs. Int. 7.72e3 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PBM 4σ 1.01e3 3.86e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 PCB-54 2.09e4 20.31 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.18e3 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PBM 4σ 1.17e3 3.09e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 3.99e7 20.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PBM 4σ 9.57e3 5.67e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 5.06e7 20.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e7 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PBM 4σ 7.69e3 7.21e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.81e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 9.07e6 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8803, 9973 scc: 118-899 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:12 (CEM) Printed: 06-Apr-2014 17:26 Page 7 of 21 156 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 PCB-52 2.66e6 24.41 Rel. Int. 100% TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 1.75e3 PCB-51 7.97e5 22.95 50/53 6.03e5 22.27 PCB-45 4.28e5 22.88 69/49 1.56e6 24.85 PCB-48 3.21e5 25.11 PCB-46 1.96e5 23.16 Abs. Int. 6.87e5 44/47… 2.66e6 25.30 71/40 1.07e6 26.20 PCB-42 5.35e5 25.77 PCB-64 1.19e6 26.39 0% 22.0 23.0 24.0 25.0 PCB-52 3.44e6 24.41 Rel. Int. 100% TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 1.46e3 50/53 7.59e5 22.27 PCB-51 1.03e6 22.95 PCB-45 5.60e5 22.88 PCB-48 3.96e5 25.11 PCB-46 2.35e5 23.16 Abs. Int. 8.87e5 71/40 1.41e6 26.19 23.0 24.0 25.0 26.0 JS-52 4.67e7 24.39 Rel. Int. 100% PCB-64 1.53e6 26.39 4.44e5 59/62… 3.10e5 25.59 0% 22.0 0.00e0 RT 26.0 44/47… 3.29e6 25.30 69/49 2.02e6 24.85 3.44e5 0.00e0 RT Abs. Int. 1.27e7 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PBM 4σ 1.75e4 6.36e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 5.79e7 24.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.57e7 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PBM 4σ 1.50e4 7.83e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.61e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 8.07e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9483, 6206 scc: 118-899 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:36 (CEM) Printed: 06-Apr-2014 17:26 Page 8 of 21 157 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 1.50e3 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 Abs. Int. 3.48e5 PCB-66 1.16e6 28.89 PCB-68 1.07e6 27.36 PCB-63 7.37e4 28.32 PCB-56 6.38e5 29.47 PCB-60 2.59e5 29.67 1.74e5 PCB-77 1.07e5 32.66 0% 28.0 Rel. Int. 100% TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 2.49e3 30.0 32.0 34.0 36.0 Abs. Int. 4.23e5 61/70... PCB-66 2.57e6 1.46e6 28.62 28.89 PCB-68 1.34e6 27.36 PCB-56 8.54e5 29.47 PCB-60 3.38e5 29.67 2.12e5 PCB-77 1.32e5 32.66 0% 28.0 0.00e0 RT 30.0 Rel. Int. 100% 32.0 ES-81 6.03e7 32.16 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PBM 4σ 2.33e4 34.0 36.0 0.00e0 RT Abs. Int. 1.52e7 ES-77 6.24e7 32.64 7.61e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 7.46e7 32.16 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PBM 4σ 1.38e4 34.0 36.0 0.00e0 RT Abs. Int. 1.92e7 ES-77 7.79e7 32.64 9.59e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.07e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.04e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1463, 2208 scc: 118-899 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:15 (CEM) Printed: 06-Apr-2014 17:26 Page 9 of 21 158 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 PCB-96 1.72e4 25.59 Rel. Int. 100% Abs. Int. 4.28e3 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 6.46e2 2.14e3 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 2.51e4 25.60 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.43e3 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 8.81e2 4.22e3 0% 22.0 23.0 24.0 25.0 26.0 ES-104 5.78e7 25.25 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.47e7 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PBM 4σ 2.92e3 7.35e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 3.62e7 25.25 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.32e6 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PBM 4σ 1.88e3 4.66e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.61e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 8.07e6 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4138, 3079 scc: 118-899 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:15 (CEM) Printed: 06-Apr-2014 17:27 Page 10 of 21 159 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 8.72e2 113/90… 4.05e5 30.38 PCB-95 4.06e5 27.85 PCB-84 PCB-91 1.61e5 9.55e4 28.80 28.61 0% 28.0 30.0 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 1.04e3 PCB-102 5.54e4 28.17 PCB-84 2.64e5 28.80 Abs. Int. 1.39e5 PCB-118 3.09e5 34.63 PCB-105 1.32e5 35.63 PCB-82 4.93e4 32.36 32.0 113/90… 6.53e5 30.38 PCB-95 6.53e5 27.85 PCB-110 5.74e5 32.08 PCB-99108/119... 1.95e5 3.37e5 30.89 31.37 116/85 1.04e5 PCB-83 31.94 2.36e4 30.78 PCB-92 7.16e4 29.88 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 34.0 36.0 PCB-110 9.46e5 32.08 PCB-92 1.20e5 29.88 PCB-99108/119... 3.32e5 5.64e5 30.89 31.37 116/85 1.63e5 31.94 30.0 32.0 Rel. Int. 100% PCB-118 4.83e5 34.63 PCB-82 8.90e4 32.36 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PBM 4σ 3.14e3 34.0 CS/SS-111 7.76e7 32.65 JS-101 5.80e7 30.36 0.00e0 RT Abs. Int. 2.22e5 PCB-105 2.10e5 35.63 0% 28.0 6.94e4 36.0 ES-118 ES-114 7.28e7 ES-123 7.21e7 35.07 7.05e7 34.61 34.33 ES-105 7.45e7 35.61 1.11e5 0.00e0 RT Abs. Int. 2.00e7 1.00e7 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.92e7 32.65 JS-101 3.70e7 30.36 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PBM 4σ 2.94e3 34.0 ES-123 4.52e7 34.33 36.0 ES-118 ES-114 4.49e7 4.55e7 34.61 35.07 ES-105 4.64e7 35.61 0.00e0 RT Abs. Int. 1.23e7 6.16e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.07e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.04e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0456, 7708 scc: 118-899 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:16 (CEM) Printed: 06-Apr-2014 17:27 Page 11 of 21 160 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 Rel. Int. 100% Abs. Int. 6.91e5 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PB 4σ 9.85e2 3.46e5 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 1.53e6 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PB 4σ 1.34e3 7.64e5 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 7.86e6 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 4.90e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 9.79e6 ES-126 4.12e7 38.22 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PBM 4σ 5.27e3 0% 38.0 0.00e0 RT Abs. Int. 1.57e7 ES-126 6.51e7 38.22 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PBM 4σ 7.61e3 Rel. Int. 100% 0.00e0 RT 5.99e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1043, 4983 scc: 118-899 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:45 Printed: 06-Apr-2014 17:27 Page 12 of 21 161 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 153/168 1.93e5 36.21 147/149 1.87e5 33.65 HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 1.06e3 PCB-136 6.35e4 30.82 PCB-132 6.30e4 34.73 151/135 8.89e4 32.88 PCB-146 3.18e4 35.69 163/138… 2.33e5 37.28 PCB-141 3.86e4 PCB-164 PCB-158 3.10e4 36.38 1.89e4 37.61 37.01 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% 153/168 1.72e5 36.21 HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 5.67e2 PCB-136 4.31e4 30.82 PCB-132 5.99e4 34.73 151/135 6.91e4 32.88 PCB-146 2.85e4 35.68 163/138… 1.89e5 37.28 PCB-141 3.26e4 PCB-137 36.38 1.20e4 36.93 PCB-158 2.52e4 37.61 30.0 32.0 34.0 36.0 ES-155 6.70e7 30.19 Rel. Int. 100% ES-153 4.86e7 36.19 HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PBM 4σ 1.57e3 Abs. Int. 4.07e4 2.04e4 0.00e0 RT 0% 28.0 2.65e4 0.00e0 RT 36.0 147/149 1.39e5 33.65 Abs. Int. 5.30e4 Abs. Int. 1.73e7 JS-138 4.49e7 37.25 8.63e6 0% 28.0 30.0 32.0 34.0 ES-155 5.22e7 30.19 Rel. Int. 100% ES-153 3.71e7 36.19 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PBM 4σ 1.42e3 0.00e0 RT 36.0 JS-138 3.47e7 37.25 Abs. Int. 1.32e7 6.58e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.07e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.04e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4491, 9252 scc: 118-899 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:19 (CEM) Printed: 06-Apr-2014 17:27 Page 13 of 21 162 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 128/166 2.94e4 38.36 Abs. Int. 8.77e3 156/157 2.49e4 40.77 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 6.65e2 4.38e3 0% 38.0 Rel. Int. 100% Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 39.0 40.0 128/166 2.48e4 38.36 41.0 42.0 43.0 44.0 Abs. Int. 7.01e3 156/157 1.99e4 40.77 HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 7.81e2 0% 38.0 3.51e3 39.0 Rel. Int. 100% 41.0 42.0 43.0 44.0 ES-156/157 1.16e8 40.77 39.0 Abs. Int. 2.01e7 ES-169 5.71e7 43.48 40.0 41.0 42.0 43.0 44.0 ES-156/157 9.11e7 40.77 ES-167 4.77e7 39.79 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PBM 4σ 6.78e3 0.00e0 RT Abs. Int. 1.58e7 ES-169 4.57e7 43.48 7.91e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT 1.01e7 Rel. Int. 100% 0% 38.0 40.0 ES-167 6.01e7 39.79 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PBM 4σ 7.25e3 0% 38.0 0.00e0 RT 5.99e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8064, 3939 scc: 118-899 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:45 (CEM) Printed: 06-Apr-2014 17:27 Page 14 of 21 163 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 PCB-179 2.04e4 35.37 Rel. Int. 100% Abs. Int. 4.66e3 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 6.24e2 0% 30.0 2.33e3 31.0 32.0 33.0 34.0 35.0 36.0 0.00e0 RT 37.0 PCB-179 2.01e4 35.37 Rel. Int. 100% Abs. Int. 6.85e3 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 7.49e2 0% 30.0 3.43e3 31.0 32.0 33.0 34.0 35.0 36.0 ES-188 4.70e7 35.06 Rel. Int. 100% Abs. Int. 1.19e7 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PBM 4σ 1.40e3 0% 30.0 CS/SS-178 3.05e7 37.63 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 1.10e7 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PBM 4σ 1.45e3 CS/SS-178 2.85e7 37.63 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 5.50e6 0.00e0 RT Abs. Int. 2.07e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 5.93e6 0.00e0 RT 37.0 ES-188 4.38e7 35.06 Rel. Int. 100% 0% 30.0 0.00e0 RT 37.0 1.04e7 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7605, 9199 scc: 118-899 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:37 (CEM) Printed: 06-Apr-2014 17:27 Page 15 of 21 164 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 180/193 9.34e4 41.95 Rel. Int. 100% HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 1.11e3 PCB-187 4.57e4 38.42 0% 38.0 PCB-174 PCB-183 3.01e4 39.14 2.62e4 38.94 39.0 0% 38.0 40.0 41.0 42.0 PCB-187 5.22e4 38.42 PCB-183 2.31e4 38.94 PCB-174 2.92e4 39.14 44.0 39.0 40.0 41.0 42.0 ES-180 4.04e7 41.93 43.0 1.09e4 44.0 0.00e0 RT Abs. Int. 1.02e7 ES-170 3.41e7 43.00 5.08e6 39.0 40.0 41.0 42.0 ES-180 3.80e7 41.93 Rel. Int. 100% HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PBM 4σ 3.63e3 43.0 44.0 0.00e0 RT Abs. Int. 9.20e6 ES-170 3.16e7 43.00 4.60e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 2.18e4 PCB-170 3.34e4 43.01 PCB-177 1.67e4 39.51 HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PBM 4σ 4.56e3 0% 38.0 43.0 1.14e4 180/193 8.24e4 41.94 Rel. Int. 100% 0% 38.0 Abs. Int. 2.27e4 PCB-170 3.83e4 43.02 PCB-177 1.92e4 39.51 Rel. Int. 100% HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 7.97e2 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 5.99e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8369, 1524 scc: 118-899 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:37 (CEM) Printed: 06-Apr-2014 17:27 Page 16 of 21 165 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 Rel. Int. 100% Abs. Int. 2.98e3 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PB 4σ 8.23e2 1.49e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.36e3 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PB 4σ 8.05e2 1.18e3 0% 45.0 46.0 47.0 48.0 49.0 ES-189 4.83e7 45.60 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PBM 4σ 3.96e3 5.62e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 4.60e7 45.60 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PBM 4σ 3.63e3 5.35e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.90e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 1.95e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5463, 1220 scc: 118-899 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:45 Printed: 06-Apr-2014 17:27 Page 17 of 21 166 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 198/199 2.62e4 43.60 Rel. Int. 100% Abs. Int. 5.79e3 OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PBM 4σ 6.17e2 0% 38.0 2.90e3 39.0 40.0 41.0 42.0 43.0 44.0 198/199 1.99e4 43.59 Rel. Int. 100% Abs. Int. 4.85e3 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PBM 4σ 5.81e2 0% 38.0 2.43e3 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 4.03e7 39.60 Rel. Int. 100% 4.93e6 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 4.34e7 39.60 Rel. Int. 100% 5.41e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 1.08e7 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PBM 4σ 1.69e3 0% 38.0 0.00e0 RT Abs. Int. 9.86e6 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PBM 4σ 1.60e3 0% 38.0 0.00e0 RT 5.99e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0213, 0261 scc: 118-899 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:36 (CEM) Printed: 06-Apr-2014 17:27 Page 18 of 21 167 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 PCB-194 1.35e4 47.39 Rel. Int. 100% Abs. Int. 3.46e3 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PBM 4σ 5.68e2 1.73e3 0% 45.0 46.0 47.0 48.0 49.0 PCB-194 1.34e4 47.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.49e3 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PBM 4σ 7.38e2 2.24e3 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.77e7 47.37 49.0 ES-205 3.39e7 47.77 0.00e0 RT Abs. Int. 8.05e6 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PBM 4σ 1.91e3 4.03e6 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 3.07e7 47.37 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PBM 4σ 2.35e3 49.0 ES-205 3.78e7 47.77 0.00e0 RT Abs. Int. 8.95e6 4.47e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.90e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 1.95e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0810, 2496 scc: 118-899 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:36 (CEM) Printed: 06-Apr-2014 17:27 Page 19 of 21 168 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 Rel. Int. 100% Abs. Int. 2.19e3 NoCB 44.77-49.81 461.7245 Fn6 Flags: PB 4σ 7.02e2 1.10e3 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. 100% Abs. Int. 4.86e3 NoCB 44.77-49.81 463.7216 Fn6 Flags: PB 4σ 1.89e3 2.43e3 0.00e0 RT 0% 45.0 46.0 47.0 48.0 49.0 ES-208 3.45e7 45.22 Rel. Int. 100% ES-206 2.27e7 49.23 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PBM 4σ 2.81e3 Abs. Int. 8.16e6 4.08e6 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 ES-208 4.31e7 45.22 Rel. Int. 100% ES-206 2.83e7 49.23 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PBM 4σ 2.22e3 Abs. Int. 1.05e7 5.24e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.90e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 1.95e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5002, 8423 scc: 118-899 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:45 Printed: 06-Apr-2014 17:27 Page 20 of 21 169 of 603 SGS ID: A6528_11906_PCB_004 Instr: [ILM] AutoSpec-Premier MM7 Sample ID: PB101.1-1SWMID-140319-N (DISSOLVED) VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 04-Apr-2014 05:29:13 User: LKB Datafile: 140403X19 PCB-209 2.58e4 50.67 Rel. Int. 100% Abs. Int. 6.21e3 DeCB 49.82-52.00 497.6826 Fn7 Flags: PBM 4σ 6.01e2 3.11e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.18e4 50.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.17e3 DeCB 49.82-52.00 499.6797 Fn7 Flags: PBM 4σ 4.61e2 3.09e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.53e7 50.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.55e6 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PBM 4σ 7.52e2 3.77e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.00e7 50.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.48e6 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PBM 4σ 8.01e2 3.24e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.66e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 1.83e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\A6528_11906_PCB_004.utp_res, saved 06-Apr-2014 00:37 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0979, 6416 scc: 118-899 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 00:36 (CEM) Printed: 06-Apr-2014 17:27 Page 21 of 21 170 of 603 SGS Analytical Perspectives — Run Log Project: A6528_11906_PCB Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Wt/Vol Client/Sample ID Analyst(s) Checkcode Datafile Vial# Lab ID Acq Date Acq Time 1 140402X01 Tray1:03 CS3_140402_PCB_XA 1.00 SIL 13-79-3 LKB, CEM 090-369 01-Apr-2014 23:29:14 2 140402X02 Tray1:20 OPR1_11906_PCB 1.00 0_11906_OPR001 LKB, CEM 758-213 02-Apr-2014 00:23:43 3 140402X03 Tray1:02 SBS_140402_PCB_XA 1.00 SIL 13-42-1 LKB, CEM 542-620 02-Apr-2014 01:18:59 4 140402X04 Tray1:21 MB1_11906_PCB_TLX 1.00 Method Blank LKB, CEM 122-856 02-Apr-2014 02:14:08 5 140402X10 Tray1:27 A6528_11906_PCB_001 1.22 PB099-1SWMID-140319-N (TOTAL) LKB, CEM 065-928 02-Apr-2014 07:45:18 6 140402X11 Tray1:28 A6528_11906_PCB_002 0.97 PB099-1SWMID-140319-MD (TOTAL) LKB, CEM 334-515 02-Apr-2014 08:40:36 7 140403X04 Tray1:03 CS3_140403_PCB_XB 1.00 SIL 13-79-3 LKB, CEM 739-978 03-Apr-2014 15:20:55 8 140403X05 Tray1:02 SBS_140403_PCB_XC 1.00 SIL 13-42-1 LKB, CEM 701-763 03-Apr-2014 16:27:17 9 140403X06 Tray1:21 MB1_11906_PCB_TLX-RJ 1.00 Method Blank LKB, CEM 441-024 03-Apr-2014 17:21:41 10 140403X11 Tray1:03 CS3_140403_PCB_XC 1.00 SIL 13-79-3 LKB, CEM 980-763 03-Apr-2014 22:09:02 11 140403X18 Tray1:41 A6528_11906_PCB_003 0.96 PB101.1-1SWMID-140319-N (TOTAL) LKB, CEM 388-879 04-Apr-2014 04:34:05 12 140403X19 Tray1:42 A6528_11906_PCB_004 1.12 PB101.1-1SWMID-140319-N (DISSOLVED) LKB, CEM 118-899 04-Apr-2014 05:29:13 Project file: not saved SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 Printed: 06-Apr-2014 17:28 171 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services CS3_140402_PCB_XA 01-APR-2014 23:29 140402X01 Processed: 6-Apr-2014 16:09 ICAL: MM7_PCB_10292013_20DEC2013 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.69 32.21 35.67 35.13 34.67 34.39 38.28 40.82 39.84 43.54 45.66 50.71 8.22E+07 7.99E+07 6.06E+07 6.70E+07 6.46E+07 6.52E+07 5.94E+07 1.02E+08 5.72E+07 5.06E+07 5.03E+07 3.26E+07 0.80 Y 0.80 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 1.22 Y 1.24 Y 1.23 Y 1.07 Y 1.17 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.19 1.18 1.11 1.20 1.19 1.21 1.20 1.09 1.16 1.11 1.10 1.08 3.7% 5.1% -0.4% -0.1% -0.3% -0.2% 8.6% -0.7% -0.6% -1.3% 2.5% -3.4% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 11.82 14.10 14.35 20.04 17.42 26.35 20.32 32.67 32.20 25.28 35.65 35.11 34.64 34.36 38.26 36.22 30.22 40.80 39.82 43.52 43.03 41.96 35.10 45.64 39.63 47.80 49.26 45.26 50.68 2.35E+08 2.20E+08 1.17E+08 2.20E+08 1.02E+08 1.61E+08 9.82E+07 1.38E+08 1.36E+08 8.82E+07 1.09E+08 1.11E+08 1.09E+08 1.08E+08 9.88E+07 7.92E+07 1.13E+08 1.88E+08 9.90E+07 9.12E+07 5.86E+07 6.98E+07 7.92E+07 9.13E+07 7.26E+07 6.67E+07 4.58E+07 6.93E+07 6.06E+07 3.34 Y 3.38 Y 1.60 Y 1.58 Y 1.07 Y 1.12 Y 0.80 Y 0.83 Y 0.79 Y 1.66 Y 1.62 Y 1.61 Y 1.61 Y 1.61 Y 1.57 Y 1.33 Y 1.30 Y 1.27 Y 1.27 Y 1.29 Y 1.09 Y 1.10 Y 1.09 Y 1.06 Y 0.93 Y 0.90 Y 0.80 Y 0.80 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.14 1.07 0.57 1.07 0.50 1.56 0.95 1.34 1.32 0.95 1.18 1.20 1.18 1.16 1.07 1.11 1.57 1.31 1.38 1.27 1.09 1.30 1.11 1.70 1.01 1.24 0.85 1.29 1.13 -4.2% -1.6% 8.8% 2.9% -2.0% -5.9% 10.9% -3.2% -3.2% 18.4% -1.8% -1.3% 1.4% -1.9% 3.7% -0.8% -0.9% -18.0% -17.2% -18.2% 15.1% 14.2% 17.7% 7.3% 4.5% -0.2% 2.8% 9.7% 1.6% Page 1 of 6 172 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services Processed: 6-Apr-2014 16:09 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140402_PCB_XA 01-APR-2014 23:29 140402X01 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 22.80 32.68 37.66 1.74E+08 1.14E+08 4.69E+07 1.12 Y 1.59 Y 1.10 Y 1.11 1.03 0.62 1.08 1.06 0.59 -2.5% 2.5% -4.4% CS PCB-28 CS PCB-111 CS PCB-178 22.80 32.68 37.66 1.74E+08 1.14E+08 4.69E+07 1.12 Y 1.59 Y 1.10 Y 1.85 1.22 0.58 1.69 1.23 0.65 -8.3% 0.6% 12.5% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.32 24.42 30.39 37.29 47.40 2.06E+08 1.03E+08 9.27E+07 7.16E+07 5.38E+07 1.58 Y 0.81 Y 1.62 Y 1.33 Y 0.91 Y - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 11.83 14.11 14.36 20.05 17.44 26.37 20.34 25.30 30.25 35.12 39.65 47.82 45.28 49.28 1.29E+08 1.29E+08 6.88E+07 1.22E+08 5.71E+07 9.80E+07 6.41E+07 6.07E+07 6.69E+07 4.57E+07 3.62E+07 3.43E+07 3.84E+07 2.52E+07 3.27 Y 3.26 Y 1.57 Y 1.64 Y 1.05 Y 1.01 Y 0.81 Y 0.64 Y 1.27 Y 1.07 Y 0.92 Y 0.90 Y 0.78 Y 0.78 Y 1.09 1.17 1.18 1.11 1.12 1.22 1.31 1.38 1.19 1.15 1.00 1.03 1.11 1.10 14.6% 16.0% -4.6% 8.7% -2.5% 13.1% -3.3% -3.9% -5.9% -9.1% -5.2% -3.0% -1.2% -1.2% 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 - Page 2 of 6 - 173 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB Processed: 6-Apr-2014 16:09 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140402_PCB_XA 01-APR-2014 23:29 140402X01 RT Response RA 11.83 13.93 14.11 14.36 14.54 16.33 16.50 16.73 17.03 17.15 18.70 19.48 19.77 20.05 17.44 19.19 19.59 19.78 19.92 20.01 20.49 21.64 21.79 22.07 22.27 22.55 22.83 23.01 23.39 24.76 25.09 25.62 26.01 26.37 20.34 22.32 22.90 22.97 23.19 24.44 24.57 1.29E+08 1.30E+08 1.29E+08 6.88E+07 1.12E+08 1.07E+08 1.23E+08 1.14E+08 1.15E+08 1.18E+08 1.36E+08 1.17E+08 2.35E+08 1.22E+08 5.71E+07 1.58E+08 6.66E+07 9.18E+07 9.04E+07 4.87E+07 9.86E+07 9.93E+07 1.01E+08 2.04E+08 1.05E+08 1.06E+08 1.98E+08 2.07E+08 9.53E+07 1.08E+08 1.08E+08 9.69E+07 9.33E+07 9.80E+07 6.41E+07 1.16E+08 4.78E+07 6.11E+07 4.63E+07 5.68E+07 7.87E+07 3.27 Y 3.25 Y 3.26 Y 1.57 Y 1.58 Y 1.64 Y 1.63 Y 1.64 Y 1.65 Y 1.65 Y 1.65 Y 1.66 Y 1.64 Y 1.64 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.07 Y 1.05 Y 1.01 Y 1.00 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.02 Y 1.01 Y 1.01 Y 0.81 Y 0.79 Y 0.78 Y 0.79 Y 0.80 Y 0.77 Y 0.80 Y Page 3 of 6 RRF 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 1.18 1.92 0.97 1.11 1.04 1.04 1.07 1.24 1.06 1.07 1.55 1.30 1.80 1.77 0.95 1.93 1.24 1.25 1.27 1.31 1.32 1.23 1.29 1.19 1.34 1.34 1.21 1.16 0.85 0.70 0.90 0.68 0.83 1.16 13.9% -3.3% 2.7% 6.4% 4.0% 4.2% 3.3% 4.7% 4.9% 7.8% 0.6% -0.1% -1.1% 2.7% -5.3% 0.6% 8.9% 8.4% 8.4% 12.9% 8.1% 8.7% 9.5% 9.9% 14.5% 10.7% 9.2% 11.6% -2.7% -8.3% 4.5% -2.7% -1.1% 4.1% 174 of 603 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeC PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB Processed: 6-Apr-2014 16:09 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140402_PCB_XA 01-APR-2014 23:29 140402X01 RT Response RA 24.66 24.86 25.14 25.36 25.63 25.80 26.13 26.22 26.42 27.14 27.39 27.77 27.97 28.13 28.35 28.64 28.93 29.07 29.51 29.70 30.02 31.35 31.84 25.30 25.62 27.31 27.50 27.88 28.09 28.20 28.27 28.58 28.64 28.83 29.25 29.59 29.91 30.39 30.83 4.62E+07 1.40E+08 5.76E+07 1.84E+08 2.40E+08 5.20E+07 4.57E+07 1.18E+08 8.46E+07 8.47E+07 8.96E+07 8.11E+07 8.26E+07 8.76E+07 9.14E+07 3.32E+08 7.87E+07 7.84E+07 7.79E+07 7.92E+07 9.19E+07 9.52E+07 7.65E+07 6.07E+07 5.24E+07 5.16E+07 4.33E+07 4.69E+07 9.42E+07 4.63E+07 4.77E+07 4.36E+07 4.92E+07 3.90E+07 4.16E+07 6.60E+07 4.45E+07 1.58E+08 3.93E+07 0.80 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.80 Y 0.80 Y 0.80 Y 0.80 Y 0.79 Y 0.80 Y 0.80 Y 0.80 Y 0.80 Y 0.80 Y 0.80 Y 0.81 Y 0.80 Y 0.80 Y 0.64 Y 0.64 Y 0.61 Y 0.61 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.63 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y Page 4 of 6 RRF 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.68 1.03 0.85 0.90 1.18 0.76 0.67 0.87 1.24 1.25 1.32 1.19 1.21 1.29 1.34 1.22 1.16 1.15 1.15 1.16 1.35 1.40 1.12 1.19 0.96 0.80 0.87 0.87 0.86 0.89 0.81 0.91 0.72 0.77 1.22 0.83 0.97 0.73 -4.4% 1.0% 0.9% -0.2% 1.0% 0.3% -3.4% 1.4% 1.8% 3.0% 3.1% 2.4% 3.0% 2.3% 3.5% 1.8% 5.0% 2.9% 3.1% 2.5% 2.9% 7.1% 5.9% -3.3% 2.9% 0.4% 0.4% 1.1% -11.3% 16.8% 1.3% -3.4% 1.2% 1.1% 2.0% 0.6% -1.2% 2.0% 175 of 603 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Processed: 6-Apr-2014 16:09 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140402_PCB_XA 01-APR-2014 23:29 140402X01 Name PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB RT Response RA 30.93 31.03 31.37 31.90 32.00 32.11 32.20 32.40 32.71 33.10 34.07 34.28 34.50 34.96 36.90 30.25 30.41 30.55 30.86 31.13 32.40 32.92 33.12 33.39 33.69 33.87 33.95 34.21 34.39 34.53 34.76 35.17 35.51 35.72 35.84 36.27 36.41 36.76 36.96 37.04 37.33 4.89E+07 6.33E+07 3.20E+08 5.82E+07 1.07E+08 6.08E+07 6.37E+07 3.75E+07 6.61E+07 6.66E+07 1.20E+08 6.89E+07 5.99E+07 5.62E+07 6.07E+07 6.69E+07 6.08E+07 6.28E+07 5.73E+07 5.88E+07 4.35E+07 8.35E+07 4.93E+07 4.30E+07 8.63E+07 3.11E+07 4.29E+07 8.78E+07 3.70E+07 3.63E+07 3.79E+07 4.05E+07 5.22E+07 4.52E+07 5.59E+07 1.11E+08 4.02E+07 3.56E+07 4.50E+07 5.47E+07 1.34E+08 0.62 Y 0.63 Y 0.62 Y 0.61 Y 0.61 Y 0.61 Y 0.62 Y 0.61 Y 0.63 Y 0.61 Y 0.61 Y 0.61 Y 0.61 Y 0.62 Y 0.63 Y 1.27 Y 1.26 Y 1.27 Y 1.28 Y 1.26 Y 1.27 Y 1.27 Y 1.26 Y 1.27 Y 1.26 Y 1.26 Y 1.27 Y 1.26 Y 1.27 Y 1.26 Y 1.26 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.29 Y 1.21 Y 1.27 Y 1.27 Y 1.28 Y 1.26 Y Page 5 of 6 RRF 0.92 1.17 0.98 1.14 0.94 1.12 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 0.91 1.17 0.99 1.08 0.99 1.13 1.18 0.69 1.23 1.23 1.11 1.28 1.11 1.01 1.11 1.08 1.11 1.02 1.04 1.10 1.05 1.24 1.09 1.09 0.79 1.08 1.11 0.93 0.92 0.96 1.02 1.32 1.14 1.41 1.40 1.02 0.90 1.14 1.38 1.13 -1.5% 0.5% 1.1% -5.1% 5.6% 0.9% 2.0% -0.3% 0.5% 1.9% 1.3% 2.0% 0.5% 1.5% 1.3% -8.1% -5.3% -4.8% -6.5% -7.0% -7.4% -7.3% -8.2% -7.3% -14.9% -4.1% -8.0% -8.9% -7.5% -7.2% -9.6% -6.5% -5.0% -7.3% -4.0% -6.7% -7.5% -2.3% -7.8% -5.0% 176 of 603 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB Processed: 6-Apr-2014 16:09 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140402_PCB_XA 01-APR-2014 23:29 140402X01 RT Response RA 37.47 37.65 38.38 39.19 39.43 35.12 35.40 35.86 36.16 36.56 37.68 38.23 38.45 38.63 38.98 39.06 39.17 39.55 39.89 40.08 41.43 41.67 41.95 42.28 43.05 43.50 39.65 40.44 41.01 41.20 41.29 43.62 44.19 44.36 45.48 47.42 47.82 45.28 46.06 49.28 5.13E+07 6.01E+07 8.76E+07 5.31E+07 5.37E+07 4.57E+07 4.23E+07 4.07E+07 4.50E+07 4.18E+07 2.98E+07 3.78E+07 4.04E+07 4.20E+07 4.32E+07 3.63E+07 3.49E+07 3.26E+07 3.78E+07 6.63E+07 3.42E+07 4.54E+07 8.66E+07 4.86E+07 3.28E+07 4.59E+07 3.62E+07 4.05E+07 3.81E+07 4.07E+07 3.86E+07 5.19E+07 2.74E+07 2.81E+07 2.43E+07 2.71E+07 3.43E+07 3.84E+07 3.97E+07 2.52E+07 1.27 Y 1.27 Y 1.20 Y 1.22 Y 1.22 Y 1.07 Y 1.07 Y 1.06 Y 1.07 Y 1.07 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.05 Y 1.06 Y 1.05 Y 1.05 Y 1.06 Y 1.05 Y 1.06 Y 1.05 Y 1.06 Y 1.05 Y 0.92 Y 0.92 Y 0.91 Y 0.90 Y 0.92 Y 0.91 Y 0.90 Y 0.92 Y 0.89 Y 0.90 Y 0.90 Y 0.78 Y 0.78 Y 0.78 Y Page 6 of 6 RRF 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 1.29 1.52 0.88 1.07 1.09 1.07 1.03 1.14 1.05 0.75 1.08 1.16 1.20 1.24 1.04 1.00 0.93 1.08 0.95 0.98 1.30 1.24 1.39 1.12 1.57 1.12 1.05 1.12 1.06 0.72 0.75 0.77 0.73 0.81 1.15 - -14.6% -8.7% -1.6% -3.8% 1.2% -8.0% -8.8% -7.8% -6.3% -10.7% 0.9% 1.6% 2.5% 2.7% -1.9% 1.0% -1.7% -0.6% 0.1% -0.9% 1.1% -1.6% -0.2% -1.4% -5.5% -8.7% -5.9% -5.9% -4.0% -11.6% -9.6% -11.5% -5.1% -3.8% -3.7% - 177 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 3.84e7 1.92e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 3.35e7 1.67e7 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 2.32e7 1.16e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 1.44e7 7.21e6 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 7.54e6 3.77e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.93e6 2.96e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 5.92e6 2.96e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 090-369 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:20 Page 1 of 21 178 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-1 9.85e7 11.83 Rel. Int. 100% Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-2 9.91e7 13.93 MoCB 10.03-15.71 188.0393 Fn1 Flags: PBM 4σ 3.11e3 Abs. Int. 3.94e7 PCB-3 9.86e7 14.11 1.97e7 0% 11.0 12.0 13.0 PCB-1 3.01e7 11.83 Rel. Int. 100% 14.0 PCB-2 3.05e7 13.93 MoCB 10.03-15.71 190.0363 Fn1 Flags: PBM 4σ 2.41e3 15.0 0.00e0 RT Abs. Int. 1.19e7 PCB-3 3.03e7 14.11 5.97e6 0% 11.0 12.0 13.0 ES-1 1.81e8 11.82 Rel. Int. 100% 14.0 15.0 Abs. Int. 7.22e7 ES-3 1.70e8 14.10 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PBM 4σ 7.43e3 0.00e0 RT 3.61e7 0% 11.0 12.0 13.0 ES-1 5.42e7 11.82 Rel. Int. 100% 14.0 15.0 Abs. Int. 2.16e7 ES-3 5.03e7 14.10 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PBM 4σ 3.16e4 0.00e0 RT 1.08e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.84e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.92e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2412, 7381 scc: 090-369 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 20:06 (CEM) Printed: 06-Apr-2014 17:20 Page 2 of 21 179 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 Rel. Int. 100% Abs. Int. 2.31e7 PCB-10 6.87e7 14.54 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PBM 4σ 5.17e3 PCB-4 4.20e7 14.36 1.15e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 1.46e7 PCB-10 4.35e7 14.54 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PBM 4σ 1.95e4 PCB-4 2.68e7 14.36 7.28e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 7.21e7 14.35 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 2.43e7 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PBM 4σ 7.89e3 1.21e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.50e7 14.35 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.50e7 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PBM 4σ 3.31e3 7.52e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.84e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.92e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5134, 8141 scc: 090-369 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 19:01 (CEM) Printed: 06-Apr-2014 17:20 Page 3 of 21 180 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PCB-6 7.09e7 16.73 PCB-9 6.65e7 16.33 DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PBM 4σ 8.61e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-14 8.48e7 18.70 PCB-5 7.16e7 PCB-8 17.03 7.32e7 17.15 PCB-11 7.30e7 19.48 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 13/12 1.46e8 19.77 Abs. Int. 2.33e7 PCB-15 7.59e7 20.05 1.17e7 0% 16.0 Rel. Int. 100% 17.0 PCB-9 4.05e7 16.33 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PBM 4σ 4.73e4 PCB-7 4.67e7 16.50 18.0 19.0 PCB-14 5.14e7 18.70 PCB-5 4.35e7 17.03 PCB-8 4.43e7 17.15 20.0 PCB-11 4.39e7 19.48 13/12 8.90e7 19.77 21.0 0.00e0 RT Abs. Int. 1.42e7 PCB-15 4.63e7 20.05 7.10e6 0% 16.0 17.0 18.0 19.0 20.0 JS-9 1.26e8 16.32 Rel. Int. 100% 21.0 ES-15 1.35e8 20.04 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PBM 4σ 2.28e4 Abs. Int. 3.86e7 (1.35e8 + 8.54e7) * 100 pg/ul = 1.07 (1.26e8 + 7.97e7) * 100 pg/ul CEM 06-Apr-2014 16:22 RRF (ES-15) = 1.93e7 0% 16.0 17.0 18.0 19.0 JS-9 7.97e7 16.32 Rel. Int. 100% 0.00e0 RT 20.0 21.0 ES-15 8.54e7 20.04 0.00e0 RT Abs. Int. 2.46e7 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PBM 4σ 5.26e3 1.23e7 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.35e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.67e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1588, 8697 scc: 090-369 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 20:06 (CEM) Printed: 06-Apr-2014 17:20 Page 4 of 21 181 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 30/18 8.09e7 19.19 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PBM 4σ 3.72e3 PCB-19 2.92e7 17.44 PCB-17 3.41e7 19.59 PCB-24 4.62e7 19.92 PCB-27 4.70e7 19.78 Abs. Int. 2.19e7 PCB-16 2.51e7 20.01 PCB-32 5.05e7 20.49 1.10e7 0% 16.0 17.0 18.0 Rel. Int. 100% 19.0 20.0 30/18 7.70e7 19.19 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PBM 4σ 3.28e3 PCB-19 2.79e7 17.44 PCB-17 3.25e7 19.59 PCB-24 4.42e7 19.92 PCB-27 4.48e7 19.78 21.0 Abs. Int. 2.08e7 PCB-16 2.36e7 20.01 PCB-32 4.81e7 20.49 1.04e7 0% 16.0 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 2.29e7 ES-19 5.28e7 17.42 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PBM 4σ 1.21e5 0.00e0 RT 1.15e7 0% 16.0 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.10e7 ES-19 4.94e7 17.42 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PBM 4σ 2.25e4 0.00e0 RT 1.05e7 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.35e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.67e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7833, 1090 scc: 090-369 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 19:01 Printed: 06-Apr-2014 17:20 Page 5 of 21 182 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 9.09e3 PCB-23 PCB-34 5.04e7 4.99e7 21.79 21.64 26/29 1.03e8 22.07 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 28/20 9.93e7 22.83 Abs. Int. 2.30e7 PCB-31 5.35e7 22.55 PCB-36 5.42e7 24.76 PCB-22 4.79e7 23.39 PCB-39 5.41e7 25.09 PCB-38 4.90e7 25.62 PCB-35 4.70e7 26.01 PCB-37 4.92e7 26.37 0% 22.0 Rel. Int. 100% TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 8.78e3 PCB-34 4.94e7 21.64 PCB-23 5.03e7 21.79 26/29 1.01e8 22.07 23.0 24.0 25.0 0.00e0 RT 26.0 28/20 9.84e7 22.83 Abs. Int. 2.27e7 PCB-31 5.29e7 22.54 PCB-36 5.35e7 24.76 PCB-22 4.74e7 23.39 PCB-39 5.37e7 25.09 PCB-38 4.80e7 25.62 PCB-35 4.63e7 26.01 PCB-37 4.88e7 26.37 23.0 24.0 25.0 26.0 CS/SS-28 9.20e7 22.80 Rel. Int. 100% 1.14e7 0.00e0 RT 0% 22.0 1.15e7 ES-37 8.50e7 26.35 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PBM 4σ 1.36e5 Abs. Int. 2.50e7 1.25e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 8.21e7 22.80 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 7.57e7 26.35 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PBM 4σ 2.57e4 Abs. Int. 2.24e7 1.12e7 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.32e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.16e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5173, 9697 scc: 090-369 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 23:54 (CEM) Printed: 06-Apr-2014 17:20 Page 6 of 21 183 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-54 2.86e7 20.34 Rel. Int. 100% Abs. Int. 7.71e6 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PBM 4σ 1.50e3 3.85e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 PCB-54 3.55e7 20.34 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.67e6 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PBM 4σ 1.40e3 4.83e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 4.35e7 20.32 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PBM 4σ 1.73e4 6.10e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 5.47e7 20.32 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.50e7 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PBM 4σ 7.68e3 7.51e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.35e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.67e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1527, 2065 scc: 090-369 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 19:01 (CEM) Printed: 06-Apr-2014 17:20 Page 7 of 21 184 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 1.78e3 50/53 5.11e7 22.32 PCB-51 2.70e7 22.97 PCB-45 2.10e7 22.90 PCB-73 3.50e7 PCB-52 24.57 2.47e7 24.44 PCB-46 2.05e7 23.19 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 69/49 6.18e7 24.86 44/47… 8.12e7 25.36 PCB-48 2.54e7 25.14 59/62… 1.06e8 25.63 71/40 5.24e7 26.22 PCB-42 2.30e7 25.80 PCB-41 2.00e7 26.13 Abs. Int. 1.92e7 PCB-64 3.71e7 26.42 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 2.24e3 50/53 6.50e7 22.32 24.0 PCB-51 3.41e7 22.97 PCB-45 2.69e7 22.90 25.0 PCB-73 4.37e7 PCB-52 24.57 3.21e7 24.44 PCB-46 2.58e7 23.19 69/49 7.86e7 24.86 PCB-48 3.22e7 25.14 59/62… 1.34e8 25.63 71/40 6.61e7 26.22 PCB-42 2.91e7 25.80 PCB-41 2.56e7 26.13 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.59e7 24.42 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 1.03e8 25.36 9.58e6 Abs. Int. 2.45e7 PCB-64 4.75e7 26.42 1.22e7 0.00e0 RT Abs. Int. 1.22e7 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PBM 4σ 3.14e4 6.11e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 5.69e7 24.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.49e7 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PBM 4σ 2.45e4 7.47e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.32e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.16e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5484, 2500 scc: 090-369 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 23:47 (CEM) Printed: 06-Apr-2014 17:20 Page 8 of 21 185 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 5.04e4 61/70... 1.48e8 28.64 PCB-68 3.98e7 27.39 PCB-72 3.77e7 27.14 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-67 3.87e7 28.13 PCB-55 3.48e7 29.07 PCB-60 PCB-80 3.51e7 4.12e7 30.02 29.70 PCB-79 4.23e7 31.35 PCB-78 3.39e7 31.84 PCB-81 3.56e7 32.21 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 Abs. Int. 1.79e7 PCB-77 3.65e7 32.69 8.93e6 0% 28.0 Rel. Int. 100% TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 3.48e4 61/70... 1.85e8 PCB-57 28.64 4.49e7 27.77 PCB-68 PCB-63 4.97e7 5.07e7 PCB-66 4.37e7 27.39 28.35 28.92 30.0 32.0 PCB-60 4.41e7 29.70 PCB-56 4.33e7 29.51 PCB-80 5.08e7 30.02 PCB-79 5.29e7 31.35 PCB-78 4.26e7 31.84 PCB-81 4.43e7 32.21 34.0 36.0 Abs. Int. 2.25e7 PCB-77 4.56e7 32.69 1.13e7 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 5.99e7 32.20 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PBM 4σ 3.34e4 0.00e0 RT 34.0 36.0 0.00e0 RT Abs. Int. 1.59e7 ES-77 6.26e7 32.67 7.97e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 7.61e7 32.20 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PBM 4σ 1.96e4 34.0 36.0 0.00e0 RT Abs. Int. 2.00e7 ES-77 7.51e7 32.67 1.00e7 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 7.21e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3161, 9361 scc: 090-369 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 23:55 (CEM) Printed: 06-Apr-2014 17:20 Page 9 of 21 186 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-104 2.38e7 25.30 Abs. Int. 5.99e6 PCB-96 2.04e7 25.62 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 6.12e2 3.00e6 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 PCB-104 3.70e7 25.30 0.00e0 RT Abs. Int. 9.37e6 PCB-96 3.19e7 25.62 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 6.80e2 4.68e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 5.51e7 25.28 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.40e7 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PBM 4σ 2.22e3 6.98e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 3.32e7 25.28 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.60e6 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PBM 4σ 2.00e3 4.30e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.32e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.16e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8272, 7313 scc: 090-369 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 19:01 Printed: 06-Apr-2014 17:20 Page 10 of 21 187 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 108/119... 1.22e8 31.37 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 8.19e4 PCB-103 1.96e7 27.31 100/93 3.60e7 28.09 PCB-88 1.64e7 28.58 PCB-121 2.52e7 29.59 113/90… 6.04e7 30.39 116/85 4.07e7 32.00 PCB-99 1.87e7 30.93 PCB-111 PCB-120 2.55e7 2.53e7 32.71 33.10 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-118 107/124 2.48e7 4.56e7 34.67 34.07 PCB-114 PCB-123 2.56e7 2.49e7 35.13 34.39 Abs. Int. 1.80e7 PCB-105 2.31e7 35.67 PCB-127 2.33e7 36.90 0% 28.0 30.0 32.0 0.00e0 RT 36.0 108/119... 1.98e8 31.37 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 1.52e5 34.0 PCB-94 2.68e7 27.50 100/93 5.82e7 28.09 PCB-91 3.02e7 28.64 PCB-89 2.58e7 29.25 113/90… 9.72e7 30.39 PCB-112 PCB-92 3.88e7 2.76e7 31.03 29.91 116/85 PCB-115 6.64e7 3.93e7 PCB-111 31.99 32.20 4.06e7 32.71 PCB-117 PCB-110 PCB-120 3.61e7 3.77e7 4.13e7 PCB-82 31.90 32.11 33.10 2.32e7 32.40 107/124 PCB-118 3.98e7 7.42e7 34.66 34.07 PCB-123 PCB-114 4.03e7 4.13e7 34.39 35.13 Abs. Int. 2.92e7 PCB-105 3.75e7 35.67 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 6.99e7 32.68 JS-101 5.73e7 30.39 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PBM 4σ 3.15e3 34.0 36.0 ES-118 ES-114 6.88e7 ES-123 6.72e7 6.65e7 34.64 35.11 34.36 9.02e6 ES-105 6.76e7 35.65 PCB-127 3.73e7 36.90 1.46e7 0.00e0 RT Abs. Int. 1.80e7 9.01e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.39e7 32.68 JS-101 3.54e7 30.39 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PBM 4σ 3.62e3 34.0 ES-123 4.14e7 34.36 36.0 ES-118 ES-114 4.17e7 4.26e7 34.64 35.11 ES-105 4.18e7 35.65 0.00e0 RT Abs. Int. 1.10e7 5.52e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 7.21e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1498, 2554 scc: 090-369 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 23:51 (CEM) Printed: 06-Apr-2014 17:20 Page 11 of 21 188 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 Abs. Int. 5.49e6 PCB-126 2.29e7 38.28 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PBM 4σ 2.73e3 (2.29e7 + 3.65e7) * 100 pg/ul = 1.2 (6.04e7 + 3.84e7) * 50 pg/ul CEM 06-Apr-2014 16:23 RRF (PCB-126) = 0% 38.0 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 39.0 40.0 2.75e6 41.0 42.0 43.0 44.0 Abs. Int. 8.82e6 PCB-126 3.65e7 38.28 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PBM 4σ 2.74e3 4.41e6 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 7.20e6 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 4.51e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.54e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 9.03e6 ES-126 3.84e7 38.26 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PBM 4σ 7.27e3 0% 38.0 0.00e0 RT Abs. Int. 1.44e7 ES-126 6.04e7 38.26 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PBM 4σ 6.41e3 Rel. Int. 100% 0.00e0 RT 3.77e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5732, 8771 scc: 090-369 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 19:01 Printed: 06-Apr-2014 17:20 Page 12 of 21 189 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-150 PCB-155 3.51e7 3.75e7 30.55 30.25 HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 6.16e2 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 147/149 139/140 4.82e7 4.89e7 33.69 34.21 PCB-145 3.28e7 31.13 PCB-148 2.44e7 32.40 153/168 6.23e7 36.27 151/135 4.68e7 PCB-144 PCB-143 PCB-142 PCB-133 PCB-146 2.26e7 2.53e7 32.92 2.41e7 2.40e7 2.02e7 35.72 33.39 33.95 35.17 34.53 PCB-141 2.21e7 36.41 163/138… 7.48e7 37.33 PCB-164 PCB-160 3.07e7 2.87e7 37.04 37.47 0% 28.0 30.0 PCB-152 2.69e7 30.41 PCB-150 PCB-155 2.77e7 2.94e7 30.55 30.24 Rel. Int. 100% HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 5.75e2 32.0 PCB-145 2.60e7 31.13 PCB-148 1.92e7 32.40 34.0 147/149 139/140 151/135 3.81e7 3.89e7 3.67e7 33.69 34.21 32.92 PCB-154 PCB-143 2.18e7 PCB-132 1.89e7 33.12 1.68e7 33.94 34.76 153/168 4.85e7 36.27 163/138… 5.95e7 37.33 PCB-141 PCB-137 1.82e7 1.99e7 36.96 36.41 30.0 32.0 34.0 ES-153 4.52e7 36.22 HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PBM 4σ 1.73e3 5.37e6 0.00e0 RT 36.0 ES-155 6.38e7 30.22 Rel. Int. 100% Abs. Int. 1.07e7 PCB-158 2.64e7 37.65 0% 28.0 6.83e6 0.00e0 RT 36.0 PCB-165 2.30e7 35.51 Abs. Int. 1.37e7 Abs. Int. 1.63e7 JS-138 4.09e7 37.29 8.14e6 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 ES-155 4.91e7 30.22 Rel. Int. 100% ES-153 3.41e7 36.22 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PBM 4σ 1.54e3 Abs. Int. 1.27e7 JS-138 3.08e7 37.29 6.33e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 7.21e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6388, 0557 scc: 090-369 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 23:53 (CEM) Printed: 06-Apr-2014 17:20 Page 13 of 21 190 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.78e7 38.38 PCB-162 PCB-159 2.95e7 39.43 2.92e7 39.19 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 4.00e3 0% 38.0 Rel. Int. 100% HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 4.01e3 0% 38.0 39.0 PCB-162 PCB-159 2.42e7 39.43 2.39e7 39.19 39.0 PCB-169 2.80e7 43.54 5.35e6 40.0 41.0 42.0 43.0 44.0 156/157 4.62e7 40.82 39.0 Abs. Int. 8.90e6 PCB-169 2.26e7 43.53 PCB-167 2.56e7 39.84 4.45e6 40.0 41.0 42.0 43.0 44.0 ES-156/157 1.05e8 40.80 0.00e0 RT Abs. Int. 1.88e7 ES-169 5.13e7 43.52 40.0 41.0 42.0 43.0 44.0 ES-156/157 8.27e7 40.80 ES-167 4.36e7 39.82 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PBM 4σ 6.41e3 0.00e0 RT Abs. Int. 1.45e7 ES-169 3.99e7 43.52 7.27e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.54e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT 9.41e6 Rel. Int. 100% 0% 38.0 Abs. Int. 1.07e7 PCB-167 3.16e7 39.84 ES-167 5.54e7 39.82 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PBM 4σ 6.98e3 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 156/157 5.62e7 40.82 128/166 3.98e7 38.38 Rel. Int. 100% 0% 38.0 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 3.77e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6973, 3032 scc: 090-369 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 19:01 Printed: 06-Apr-2014 17:20 Page 14 of 21 191 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% PCB-188 2.36e7 35.12 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 7.60e2 0% 30.0 31.0 32.0 33.0 34.0 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-179 PCB-184 2.19e7 2.09e7 35.40 35.86 35.0 PCB-188 PCB-179 2.04e7 2.21e7 35.40 35.12 Rel. Int. 100% 36.0 PCB-176 2.17e7 36.16 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 7.21e2 0% 30.0 PCB-186 2.16e7 36.56 PCB-186 2.01e7 36.56 31.0 32.0 33.0 34.0 Abs. Int. 5.47e6 PCB-178 1.45e7 37.68 35.0 36.0 0.00e0 RT 37.0 ES-188 4.13e7 35.10 Abs. Int. 1.02e7 CS/SS-178 2.45e7 37.66 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 9.57e6 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PBM 4σ 1.53e3 CS/SS-178 2.23e7 37.66 31.0 32.0 33.0 34.0 35.0 5.10e6 0.00e0 RT 37.0 ES-188 3.79e7 35.10 Rel. Int. 100% 36.0 37.0 Rel. Int. 100% 4.78e6 0.00e0 RT Abs. Int. 1.44e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 2.91e6 0.00e0 RT 37.0 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PBM 4σ 1.47e3 0% 30.0 PCB-178 1.53e7 37.68 2.74e6 Rel. Int. 100% 0% 30.0 Abs. Int. 5.82e6 7.21e6 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4089, 4891 scc: 090-369 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 23:54 (CEM) Printed: 06-Apr-2014 17:20 Page 15 of 21 192 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 4.27e3 PCB-175 1.93e7 38.23 0% 38.0 Rel. Int. 100% HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 4.72e3 0% 38.0 PCB-182 PCB-183 2.17e7 2.21e7 38.63 38.98 39.0 PCB-182 2.04e7 38.63 PCB-183 PCB-187 2.10e7 1.96e7 38.98 38.45 39.0 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-181 PCB-177 1.94e7 1.68e7 39.89 39.55 PCB-172 1.76e7 41.43 40.0 PCB-181 PCB-177 1.84e7 1.58e7 39.89 39.55 180/193 4.45e7 41.95 171/173 3.40e7 40.08 41.0 42.0 180/193 4.21e7 41.95 171/173 3.23e7 40.08 40.0 PCB-172 1.66e7 41.43 41.0 42.0 ES-180 3.65e7 41.96 Rel. Int. 100% PCB-191 2.49e7 42.28 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-170 1.69e7 43.05 3.97e6 43.0 PCB-191 2.37e7 42.28 PCB-170 1.59e7 43.05 43.0 Abs. Int. 7.95e6 PCB-190 2.35e7 43.50 44.0 Abs. Int. 7.42e6 PCB-190 2.24e7 43.50 3.71e6 44.0 4.40e6 39.0 40.0 41.0 42.0 ES-180 3.33e7 41.96 Rel. Int. 100% HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PBM 4σ 4.71e3 0% 38.0 43.0 44.0 0.00e0 RT Abs. Int. 8.30e6 ES-170 2.80e7 43.03 4.15e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.54e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 8.80e6 ES-170 3.05e7 43.03 HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PBM 4σ 2.54e3 0% 38.0 0.00e0 RT 3.77e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8254, 3297 scc: 090-369 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 23:56 (CEM) Printed: 06-Apr-2014 17:20 Page 16 of 21 193 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-189 2.60e7 45.66 Rel. Int. 100% Abs. Int. 6.15e6 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PBM 4σ 1.70e3 3.07e6 0% 45.0 46.0 47.0 48.0 49.0 PCB-189 2.43e7 45.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.78e6 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PBM 4σ 1.71e3 2.89e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 4.69e7 45.64 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PBM 4σ 3.99e3 5.58e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 4.44e7 45.64 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PBM 4σ 2.58e3 5.29e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.93e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.96e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5029, 8323 scc: 090-369 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 19:01 Printed: 06-Apr-2014 17:20 Page 17 of 21 194 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-201 1.94e7 40.44 PCB-202 1.74e7 39.65 OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PBM 4σ 6.64e2 0% 38.0 39.0 Rel. Int. 100% 40.0 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PBM 4σ 7.19e2 0% 38.0 39.0 40.0 PCB-197 1.93e7 41.20 PCB-200 PCB-204 1.85e7 1.81e7 41.29 41.01 41.0 PCB-201 2.11e7 40.44 PCB-202 1.89e7 39.65 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 198/199 2.48e7 43.62 PCB-196 1.30e7 44.19 42.0 43.0 PCB-197 2.14e7 41.20 PCB-200 PCB-204 2.01e7 2.00e7 41.29 41.01 41.0 Abs. Int. 4.91e6 Abs. Int. 5.40e6 198/199 2.71e7 43.62 PCB-196 1.44e7 44.19 42.0 43.0 44.0 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 3.76e7 39.63 0.00e0 RT 0.00e0 RT Abs. Int. 8.77e6 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PBM 4σ 1.46e3 4.39e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.54e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 2.70e6 4.06e6 Rel. Int. 100% 0% 38.0 PCB-203 1.46e7 44.36 Abs. Int. 8.12e6 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PBM 4σ 1.55e3 0% 38.0 2.46e6 0.00e0 RT 44.0 ES-202 3.50e7 39.63 Rel. Int. 100% PCB-203 1.34e7 44.36 3.77e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8988, 7738 scc: 090-369 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 19:01 Printed: 06-Apr-2014 17:20 Page 18 of 21 195 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-194 1.29e7 47.42 PCB-195 1.15e7 45.48 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PBM 4σ 1.50e3 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-205 1.63e7 47.82 Abs. Int. 3.85e6 1.92e6 0% 45.0 Rel. Int. 100% 46.0 47.0 PCB-194 1.42e7 47.42 PCB-195 1.28e7 45.48 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PBM 4σ 1.49e3 48.0 49.0 PCB-205 1.80e7 47.82 0.00e0 RT Abs. Int. 4.25e6 2.13e6 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.56e7 47.40 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PBM 4σ 1.77e3 49.0 ES-205 3.16e7 47.80 0.00e0 RT Abs. Int. 7.35e6 3.68e6 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.82e7 47.40 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PBM 4σ 1.64e3 49.0 ES-205 3.51e7 47.80 0.00e0 RT Abs. Int. 8.41e6 4.21e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.93e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.96e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0198, 3920 scc: 090-369 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 19:01 Printed: 06-Apr-2014 17:20 Page 19 of 21 196 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 PCB-208 1.68e7 45.28 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-207 1.74e7 46.06 Abs. Int. 4.16e6 PCB-206 1.11e7 49.28 NoCB 44.77-49.81 461.7245 Fn6 Flags: PBM 4σ 1.08e3 2.08e6 0% 45.0 46.0 PCB-208 2.16e7 45.28 Rel. Int. 100% 47.0 48.0 0.00e0 RT 49.0 PCB-207 2.23e7 46.06 Abs. Int. 5.25e6 PCB-206 1.41e7 49.28 NoCB 44.77-49.81 463.7216 Fn6 Flags: PBM 4σ 1.80e3 2.62e6 0.00e0 RT 0% 45.0 46.0 47.0 48.0 49.0 ES-208 3.08e7 45.26 Rel. Int. 100% ES-206 2.04e7 49.26 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PBM 4σ 2.10e3 Abs. Int. 7.40e6 3.70e6 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 ES-208 3.84e7 45.26 Rel. Int. 100% ES-206 2.54e7 49.26 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PBM 4σ 2.16e3 Abs. Int. 9.21e6 4.60e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.93e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.96e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1381, 0065 scc: 090-369 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 19:01 Printed: 06-Apr-2014 17:20 Page 20 of 21 197 of 603 SGS ID: CS3_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 01-Apr-2014 23:29:14 User: LKB Datafile: 140402X01 PCB-209 1.76e7 50.71 Rel. Int. 100% Abs. Int. 3.67e6 DeCB 49.82-52.00 497.6826 Fn7 Flags: PBM 4σ 6.61e2 1.83e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.50e7 50.71 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.13e6 DeCB 49.82-52.00 499.6797 Fn7 Flags: PBM 4σ 5.96e2 1.57e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.29e7 50.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.94e6 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PBM 4σ 8.82e2 3.47e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.77e7 50.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.99e6 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PBM 4σ 1.04e3 2.99e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.92e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 2.96e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140402_PCB_XA.utp_res, saved 06-Apr-2014 16:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1721, 5704 scc: 090-369 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 23:54 (CEM) Printed: 06-Apr-2014 17:20 Page 21 of 21 198 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services CS3_140403_PCB_XB 03-APR-2014 15:20 140403X04 Processed: 6-Apr-2014 16:14 ICAL: MM7_PCB_10292013_20DEC2013 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.66 32.18 35.65 35.10 34.64 34.36 38.25 40.80 39.82 43.51 45.63 50.68 8.00E+07 7.74E+07 6.34E+07 6.88E+07 6.61E+07 6.80E+07 5.91E+07 1.06E+08 5.89E+07 5.28E+07 5.22E+07 3.81E+07 0.81 Y 0.80 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.64 Y 1.22 Y 1.21 Y 1.23 Y 1.06 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.16 1.14 1.11 1.19 1.19 1.21 1.18 1.08 1.15 1.11 1.10 1.07 0.6% 1.9% -0.1% -0.8% -0.1% -0.3% 6.9% -1.2% -1.4% -1.6% 2.2% -4.3% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 11.81 14.08 14.33 20.01 17.40 26.32 20.30 32.64 32.17 25.26 35.62 35.08 34.62 34.34 38.23 36.20 30.20 40.78 39.79 43.49 43.01 41.94 35.07 45.61 39.61 47.78 49.24 45.23 50.66 2.25E+08 2.12E+08 1.23E+08 2.15E+08 1.06E+08 1.56E+08 1.07E+08 1.38E+08 1.36E+08 9.74E+07 1.14E+08 1.15E+08 1.11E+08 1.13E+08 9.99E+07 8.67E+07 1.20E+08 1.96E+08 1.03E+08 9.55E+07 6.44E+07 7.66E+07 8.95E+07 9.52E+07 8.12E+07 7.48E+07 5.45E+07 7.75E+07 7.16E+07 3.29 Y 3.36 Y 1.59 Y 1.59 Y 1.07 Y 1.10 Y 0.79 Y 0.81 Y 0.81 Y 1.64 Y 1.59 Y 1.61 Y 1.59 Y 1.57 Y 1.55 Y 1.30 Y 1.29 Y 1.28 Y 1.29 Y 1.25 Y 1.08 Y 1.07 Y 1.07 Y 1.05 Y 0.92 Y 0.90 Y 0.82 Y 0.80 Y 1.18 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.12 1.05 0.61 1.07 0.53 1.46 1.00 1.29 1.27 1.02 1.19 1.20 1.16 1.17 1.04 1.11 1.53 1.25 1.31 1.22 1.09 1.30 1.14 1.62 1.04 1.27 0.93 1.32 1.22 -5.9% -3.0% 16.7% 2.8% 4.7% -12.3% 16.2% -6.7% -7.2% 26.5% -1.0% -1.2% 0.2% -1.0% 1.4% -0.7% -3.6% -21.7% -21.4% -21.7% 15.6% 14.5% 21.6% 2.3% 6.8% 2.2% 11.8% 12.1% 9.6% Page 1 of 6 199 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services Processed: 6-Apr-2014 16:14 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XB 03-APR-2014 15:20 140403X04 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 22.77 32.66 37.64 1.69E+08 1.17E+08 5.41E+07 1.10 Y 1.60 Y 1.07 Y 1.11 1.03 0.62 1.08 1.04 0.60 -2.5% 1.4% -2.3% CS PCB-28 CS PCB-111 CS PCB-178 22.77 32.66 37.64 1.69E+08 1.17E+08 5.41E+07 1.10 Y 1.60 Y 1.07 Y 1.85 1.22 0.58 1.58 1.23 0.69 -14.4% 0.4% 18.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.30 24.39 30.37 37.26 47.38 2.01E+08 1.07E+08 9.58E+07 7.84E+07 5.88E+07 1.58 Y 0.80 Y 1.61 Y 1.28 Y 0.90 Y - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 11.82 14.09 14.35 20.03 17.41 26.34 20.31 25.28 30.22 35.10 39.63 47.80 45.25 49.26 1.23E+08 1.23E+08 7.08E+07 1.20E+08 5.84E+07 9.59E+07 6.86E+07 6.60E+07 7.18E+07 5.06E+07 4.06E+07 3.77E+07 4.25E+07 2.93E+07 3.19 Y 3.24 Y 1.57 Y 1.64 Y 1.05 Y 1.00 Y 0.80 Y 0.64 Y 1.27 Y 1.06 Y 0.91 Y 0.89 Y 0.78 Y 0.77 Y 1.09 1.16 1.16 1.12 1.10 1.23 1.28 1.36 1.20 1.13 1.00 1.01 1.10 1.08 14.4% 15.2% -6.2% 9.5% -4.3% 13.9% -5.3% -5.4% -5.1% -10.9% -5.1% -4.9% -2.3% -3.4% 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 - Page 2 of 6 - 200 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB Processed: 6-Apr-2014 16:14 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XB 03-APR-2014 15:20 140403X04 RT Response RA 11.82 13.91 14.09 14.35 14.52 16.31 16.48 16.70 17.01 17.12 18.67 19.45 19.74 20.03 17.41 19.17 19.57 19.76 19.89 19.99 20.47 21.61 21.76 22.05 22.24 22.52 22.80 22.98 23.36 24.74 25.06 25.59 25.98 26.34 20.31 22.29 22.88 22.95 23.16 24.41 24.54 1.23E+08 1.23E+08 1.23E+08 7.08E+07 1.15E+08 1.05E+08 1.18E+08 1.11E+08 1.12E+08 1.15E+08 1.33E+08 1.15E+08 2.30E+08 1.20E+08 5.84E+07 1.61E+08 6.81E+07 9.41E+07 9.16E+07 4.99E+07 1.00E+08 9.64E+07 9.76E+07 1.99E+08 1.02E+08 1.04E+08 1.94E+08 2.00E+08 9.25E+07 1.02E+08 1.06E+08 9.38E+07 9.05E+07 9.59E+07 6.86E+07 1.19E+08 4.80E+07 6.46E+07 4.77E+07 5.90E+07 7.93E+07 3.19 Y 3.22 Y 3.24 Y 1.57 Y 1.58 Y 1.62 Y 1.63 Y 1.63 Y 1.65 Y 1.62 Y 1.63 Y 1.63 Y 1.64 Y 1.64 Y 1.05 Y 1.05 Y 1.04 Y 1.04 Y 1.05 Y 1.04 Y 1.05 Y 1.01 Y 1.01 Y 1.01 Y 1.00 Y 1.01 Y 1.01 Y 1.01 Y 1.00 Y 1.02 Y 1.01 Y 1.02 Y 1.01 Y 1.00 Y 0.80 Y 0.78 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y Page 3 of 6 RRF 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 1.16 1.87 0.98 1.10 1.03 1.04 1.07 1.23 1.07 1.07 1.51 1.28 1.77 1.72 0.94 1.88 1.23 1.25 1.28 1.30 1.33 1.24 1.28 1.19 1.30 1.36 1.20 1.16 0.88 0.71 0.95 0.70 0.87 1.17 12.6% -5.6% 3.3% 5.1% 3.3% 3.6% 3.8% 4.7% 5.8% 8.1% -1.5% -2.0% -2.7% -0.1% -6.7% -1.8% 8.8% 8.2% 8.9% 12.4% 8.6% 9.6% 9.3% 9.8% 11.3% 11.9% 8.8% 11.5% 0.2% -8.0% 10.6% 0.6% 2.8% 4.9% 201 of 603 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeC PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB Processed: 6-Apr-2014 16:14 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XB 03-APR-2014 15:20 140403X04 RT Response RA 24.64 24.83 25.11 25.33 25.61 25.77 26.10 26.20 26.40 27.11 27.37 27.74 27.94 28.10 28.32 28.62 28.90 29.05 29.48 29.67 30.00 31.32 31.81 25.28 25.60 27.28 27.48 27.86 28.07 28.18 28.25 28.55 28.61 28.81 29.22 29.56 29.88 30.37 30.80 4.78E+07 1.42E+08 5.84E+07 1.88E+08 2.45E+08 5.35E+07 4.57E+07 1.23E+08 8.69E+07 8.12E+07 8.52E+07 7.79E+07 8.07E+07 8.39E+07 8.78E+07 3.21E+08 7.54E+07 7.49E+07 7.43E+07 7.62E+07 8.90E+07 8.75E+07 7.30E+07 6.60E+07 5.65E+07 5.23E+07 4.36E+07 4.79E+07 9.34E+07 5.45E+07 4.29E+07 4.07E+07 5.44E+07 3.96E+07 4.24E+07 6.71E+07 4.55E+07 1.62E+08 3.86E+07 0.78 Y 0.78 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.77 Y 0.79 Y 0.79 Y 0.80 Y 0.79 Y 0.80 Y 0.81 Y 0.79 Y 0.80 Y 0.80 Y 0.80 Y 0.80 Y 0.80 Y 0.79 Y 0.81 Y 0.80 Y 0.80 Y 0.64 Y 0.64 Y 0.62 Y 0.61 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.61 Y Page 4 of 6 RRF 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.70 1.05 0.86 0.92 1.20 0.79 0.67 0.90 1.28 1.20 1.25 1.15 1.19 1.24 1.29 1.18 1.11 1.10 1.09 1.12 1.31 1.29 1.07 1.16 0.93 0.77 0.85 0.83 0.97 0.76 0.72 0.97 0.70 0.75 1.19 0.81 0.96 0.69 -0.9% 2.5% 2.5% 2.1% 3.2% 3.3% -3.1% 5.2% 4.8% -1.2% -1.8% -1.5% 0.7% -1.9% -0.4% -1.5% 0.8% -1.6% -1.4% -1.2% -0.2% -1.4% 1.2% -5.6% -0.2% -3.1% -1.8% -3.9% 0.1% 0.6% -9.4% 2.5% -1.7% -1.4% -0.6% -1.5% -2.5% -4.1% 202 of 603 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Processed: 6-Apr-2014 16:14 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XB 03-APR-2014 15:20 140403X04 Name PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB RT Response RA 30.90 31.00 31.35 31.88 31.97 32.08 32.17 32.37 32.68 33.08 34.05 34.25 34.47 34.93 36.88 30.22 30.39 30.53 30.83 31.10 32.37 32.89 33.10 33.36 33.67 33.84 33.92 34.18 34.36 34.50 34.74 35.14 35.48 35.70 35.81 36.24 36.39 36.73 36.93 37.01 37.30 4.95E+07 6.56E+07 3.26E+08 6.61E+07 1.00E+08 5.99E+07 6.75E+07 3.84E+07 6.76E+07 6.83E+07 1.23E+08 6.84E+07 6.17E+07 5.83E+07 6.29E+07 7.18E+07 6.57E+07 6.58E+07 6.10E+07 6.28E+07 4.69E+07 8.99E+07 5.29E+07 4.67E+07 9.27E+07 3.80E+07 4.29E+07 9.53E+07 4.01E+07 3.97E+07 4.12E+07 4.36E+07 5.67E+07 4.83E+07 6.12E+07 1.19E+08 4.36E+07 3.86E+07 4.64E+07 6.15E+07 1.44E+08 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 1.27 Y 1.25 Y 1.27 Y 1.28 Y 1.25 Y 1.26 Y 1.26 Y 1.26 Y 1.26 Y 1.26 Y 1.26 Y 1.28 Y 1.26 Y 1.27 Y 1.25 Y 1.28 Y 1.27 Y 1.27 Y 1.25 Y 1.27 Y 1.26 Y 1.27 Y 1.28 Y 1.24 Y 1.27 Y 1.27 Y Page 5 of 6 RRF 0.92 1.17 0.98 1.14 0.94 1.12 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 0.88 1.16 0.97 1.17 0.89 1.06 1.20 0.68 1.20 1.21 1.09 1.22 1.10 1.01 1.10 1.09 1.10 1.02 1.05 1.08 1.04 1.22 1.08 1.07 0.88 0.99 1.10 0.93 0.92 0.95 1.01 1.31 1.11 1.41 1.38 1.01 0.89 1.07 1.42 1.11 -4.5% -0.3% -1.4% 3.1% -5.4% -4.9% 3.5% -2.2% -1.6% 0.1% -0.4% -3.0% -0.9% 1.7% 0.7% -6.7% -6.8% -4.7% -6.2% -8.5% -9.0% -9.1% -8.9% -9.0% -5.1% -12.3% -8.8% -9.7% -7.5% -7.8% -11.1% -7.2% -7.3% -7.3% -5.4% -7.6% -8.5% -8.0% -5.3% -6.6% 203 of 603 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB Processed: 6-Apr-2014 16:14 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XB 03-APR-2014 15:20 140403X04 RT Response RA 37.44 37.62 38.36 39.17 39.41 35.10 35.38 35.83 36.13 36.53 37.66 38.20 38.43 38.61 38.95 39.04 39.15 39.52 39.87 40.05 41.40 41.65 41.92 42.25 43.03 43.48 39.63 40.41 40.99 41.18 41.27 43.59 44.16 44.33 45.46 47.40 47.80 45.25 46.04 49.26 5.74E+07 6.52E+07 9.14E+07 5.51E+07 5.45E+07 5.06E+07 4.85E+07 4.58E+07 5.04E+07 4.79E+07 3.38E+07 4.07E+07 4.37E+07 4.43E+07 4.44E+07 4.24E+07 3.61E+07 3.58E+07 4.14E+07 7.16E+07 3.71E+07 4.95E+07 9.42E+07 5.21E+07 3.57E+07 5.15E+07 4.06E+07 4.53E+07 4.24E+07 4.82E+07 4.02E+07 5.91E+07 3.13E+07 3.24E+07 2.63E+07 2.92E+07 3.77E+07 4.25E+07 4.43E+07 2.93E+07 1.27 Y 1.26 Y 1.22 Y 1.22 Y 1.22 Y 1.06 Y 1.06 Y 1.06 Y 1.07 Y 1.07 Y 1.08 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.04 Y 1.05 Y 1.05 Y 1.06 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 0.91 Y 0.91 Y 0.91 Y 0.90 Y 0.91 Y 0.90 Y 0.89 Y 0.90 Y 0.90 Y 0.89 Y 0.89 Y 0.78 Y 0.78 Y 0.77 Y Page 6 of 6 RRF 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 1.32 1.50 0.89 1.07 1.06 1.08 1.02 1.13 1.07 0.75 1.06 1.14 1.16 1.16 1.11 0.94 0.93 1.08 0.93 0.97 1.29 1.23 1.36 1.11 1.60 1.12 1.04 1.19 0.99 0.73 0.77 0.80 0.70 0.78 1.14 - -12.7% -9.5% -1.2% -3.9% -1.2% -6.7% -9.3% -8.6% -4.9% -10.5% -1.0% 0.1% -1.6% -3.7% 4.4% -4.8% -1.7% -0.6% -1.4% -2.0% 0.5% -2.5% -2.6% -2.3% -3.6% -8.6% -6.4% -0.3% -10.6% -10.1% -7.6% -8.8% -8.2% -7.3% -3.8% - 204 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 7.80e7 3.90e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 3.58e7 1.79e7 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 3.02e7 1.51e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 3.06e7 1.53e7 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 1.73e7 8.65e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 8.41e6 4.20e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 7.75e6 3.87e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 739-978 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:23 Page 1 of 21 205 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-1 9.35e7 11.82 Rel. Int. 100% Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 PCB-2 9.41e7 13.91 MoCB 10.03-15.71 188.0393 Fn1 Flags: PBM 4σ 2.57e3 Abs. Int. 3.68e7 PCB-3 9.40e7 14.09 1.84e7 0% 11.0 12.0 13.0 PCB-1 2.93e7 11.82 Rel. Int. 100% 14.0 PCB-2 2.92e7 13.91 MoCB 10.03-15.71 190.0363 Fn1 Flags: PBM 4σ 2.50e3 15.0 0.00e0 RT Abs. Int. 1.17e7 PCB-3 2.90e7 14.09 5.85e6 0% 11.0 12.0 13.0 ES-1 1.73e8 11.81 Rel. Int. 100% 14.0 15.0 Abs. Int. 6.94e7 ES-3 1.63e8 14.08 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PBM 4σ 5.21e3 0.00e0 RT 3.47e7 0% 11.0 12.0 13.0 ES-1 5.26e7 11.81 Rel. Int. 100% 14.0 15.0 Abs. Int. 2.13e7 ES-3 4.86e7 14.08 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PBM 4σ 2.58e4 0.00e0 RT 1.06e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.80e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 3.90e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9411, 2454 scc: 739-978 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:10 Printed: 06-Apr-2014 17:24 Page 2 of 21 206 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 Rel. Int. 100% Abs. Int. 2.39e7 PCB-10 7.03e7 14.52 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PBM 4σ 6.00e3 PCB-4 4.33e7 14.35 1.19e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 1.50e7 PCB-10 4.44e7 14.52 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PBM 4σ 1.76e4 PCB-4 2.76e7 14.35 7.48e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 7.52e7 14.33 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 2.56e7 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PBM 4σ 6.63e3 1.28e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.73e7 14.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.61e7 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PBM 4σ 3.05e3 8.03e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.80e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 3.90e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4113, 7652 scc: 739-978 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:10 (CEM) Printed: 06-Apr-2014 17:24 Page 3 of 21 207 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PCB-6 6.86e7 16.70 PCB-9 6.50e7 16.31 DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PBM 4σ 6.88e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-14 8.23e7 18.67 PCB-5 6.95e7 PCB-8 17.01 7.13e7 17.12 PCB-11 7.13e7 19.45 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 13/12 1.43e8 19.74 Abs. Int. 2.30e7 PCB-15 7.45e7 20.03 1.15e7 0% 16.0 Rel. Int. 100% 17.0 PCB-9 4.00e7 16.31 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PBM 4σ 2.21e4 PCB-7 4.49e7 16.48 18.0 19.0 PCB-14 5.05e7 18.67 PCB-5 4.22e7 PCB-8 17.01 4.39e7 17.12 20.0 PCB-11 4.37e7 19.45 13/12 8.71e7 19.74 21.0 0.00e0 RT Abs. Int. 1.43e7 PCB-15 4.56e7 20.03 7.16e6 0% 16.0 17.0 18.0 19.0 JS-9 1.23e8 16.30 Rel. Int. 100% 20.0 21.0 ES-15 1.32e8 20.01 0.00e0 RT Abs. Int. 3.89e7 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PBM 4σ 1.77e4 1.95e7 0% 16.0 17.0 18.0 19.0 JS-9 7.81e7 16.30 Rel. Int. 100% 20.0 21.0 ES-15 8.30e7 20.01 0.00e0 RT Abs. Int. 2.47e7 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PBM 4σ 5.95e3 1.24e7 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.58e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.79e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9410, 4603 scc: 739-978 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:17 (CEM) Printed: 06-Apr-2014 17:24 Page 4 of 21 208 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 30/18 8.24e7 19.17 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PBM 4σ 4.34e3 PCB-19 3.00e7 17.41 PCB-17 3.48e7 19.57 PCB-24 4.69e7 19.89 PCB-27 4.80e7 19.76 PCB-16 2.54e7 19.99 Abs. Int. 2.25e7 PCB-32 5.14e7 20.47 1.13e7 0% 16.0 17.0 18.0 Rel. Int. 100% 19.0 20.0 30/18 7.88e7 19.16 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PBM 4σ 2.88e3 PCB-19 2.84e7 17.41 PCB-17 3.33e7 19.56 PCB-24 4.47e7 19.89 PCB-27 4.62e7 19.76 21.0 Abs. Int. 2.17e7 PCB-16 2.45e7 19.99 PCB-32 4.89e7 20.46 1.08e7 0% 16.0 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 2.36e7 ES-19 5.50e7 17.40 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PBM 4σ 7.98e4 0.00e0 RT 1.18e7 0% 16.0 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.19e7 ES-19 5.15e7 17.40 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PBM 4σ 3.13e4 0.00e0 RT 1.10e7 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.58e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.79e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8938, 7188 scc: 739-978 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:10 Printed: 06-Apr-2014 17:24 Page 5 of 21 209 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 28/20 9.73e7 22.80 Rel. Int. 100% TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 7.63e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-23 PCB-34 4.91e7 4.85e7 21.76 21.61 26/29 1.00e8 22.05 Abs. Int. 2.30e7 PCB-31 5.22e7 22.52 PCB-36 5.12e7 24.74 PCB-22 4.64e7 23.36 PCB-39 5.33e7 25.06 PCB-38 4.74e7 25.59 PCB-35 4.55e7 25.98 PCB-37 4.80e7 26.34 0% 22.0 24.0 25.0 0.00e0 RT 26.0 28/20 9.64e7 22.80 Rel. Int. 100% TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 7.21e3 23.0 PCB-23 PCB-34 4.85e7 4.79e7 21.76 21.61 26/29 9.88e7 22.04 Abs. Int. 2.28e7 PCB-31 5.17e7 22.52 PCB-36 5.04e7 24.74 PCB-22 4.61e7 23.36 PCB-39 5.25e7 25.06 PCB-38 4.64e7 25.59 PCB-35 4.50e7 25.98 PCB-37 4.79e7 26.34 23.0 24.0 25.0 26.0 CS/SS-28 8.86e7 22.77 Rel. Int. 100% ES-37 8.18e7 26.32 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PBM 4σ 7.68e4 1.14e7 0.00e0 RT 0% 22.0 1.15e7 Abs. Int. 2.49e7 1.24e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 8.06e7 22.77 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 7.43e7 26.32 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PBM 4σ 2.32e4 Abs. Int. 2.26e7 1.13e7 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.02e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.51e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0590, 6859 scc: 739-978 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:17 (CEM) Printed: 06-Apr-2014 17:24 Page 6 of 21 210 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 PCB-54 3.06e7 20.31 Rel. Int. 100% Abs. Int. 8.82e6 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PBM 4σ 1.89e3 4.41e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 PCB-54 3.80e7 20.31 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.08e7 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PBM 4σ 1.60e3 5.39e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 4.73e7 20.30 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.30e7 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PBM 4σ 2.14e4 6.48e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 5.99e7 20.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.67e7 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PBM 4σ 1.36e4 8.33e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.58e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.79e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8519, 5792 scc: 739-978 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:10 (CEM) Printed: 06-Apr-2014 17:24 Page 7 of 21 211 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 2.69e3 50/53 5.24e7 22.29 PCB-51 2.86e7 22.95 PCB-45 2.10e7 22.88 PCB-73 3.47e7 PCB-52 24.54 2.60e7 24.41 PCB-46 2.09e7 23.16 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 69/49 6.24e7 24.83 44/47… 8.27e7 25.33 PCB-48 2.57e7 25.11 59/62… 1.08e8 25.61 71/40 5.41e7 26.20 PCB-42 2.35e7 25.77 PCB-41 2.00e7 26.10 Abs. Int. 2.04e7 PCB-64 3.84e7 26.40 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 2.27e3 50/53 6.69e7 22.29 24.0 PCB-51 3.60e7 22.95 PCB-45 2.69e7 22.88 25.0 PCB-73 4.46e7 PCB-52 24.54 3.30e7 24.41 PCB-46 2.68e7 23.16 69/49 7.99e7 24.83 PCB-48 3.27e7 25.11 59/62… 1.38e8 25.61 71/40 6.87e7 26.20 PCB-42 3.01e7 25.77 PCB-41 2.58e7 26.10 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.75e7 24.39 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 1.05e8 25.33 1.02e7 Abs. Int. 2.60e7 PCB-64 4.85e7 26.40 1.30e7 0.00e0 RT Abs. Int. 1.29e7 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PBM 4σ 3.66e4 6.45e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 5.96e7 24.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PBM 4σ 2.46e4 7.99e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.02e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.51e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2457, 7715 scc: 739-978 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:18 (CEM) Printed: 06-Apr-2014 17:24 Page 8 of 21 212 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 61/70... 1.42e8 28.62 Rel. Int. 100% TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 5.50e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-72 3.61e7 27.11 PCB-57 3.46e7 27.74 PCB-63 3.91e7 28.32 PCB-55 3.32e7 29.05 PCB-60 PCB-80 3.37e7 3.98e7 30.00 29.67 PCB-79 3.88e7 31.32 PCB-78 3.25e7 31.81PCB-81 3.44e7 32.18 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 Abs. Int. 1.75e7 PCB-77 3.57e7 32.66 (3.57e7 + 4.42e7) * 100 pg/ul = 1.16 (6.19e7 + 7.63e7) * 50 pg/ul CEM 06-Apr-2014 16:24 RRF (PCB-77) = 0% 28.0 Rel. Int. 100% TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 6.90e3 PCB-57 4.33e7 27.74 PCB-68 4.75e7 27.37 30.0 32.0 61/70... 1.79e8 28.62 PCB-60 4.25e7 29.67 PCB-63 PCB-80 4.87e7 PCB-66 PCB-56 4.19e7 4.13e7 4.93e7 28.32 29.48 28.90 30.00 PCB-79 4.86e7 31.32 PCB-78 4.05e7 31.81PCB-81 4.31e7 32.18 34.0 36.0 30.0 Rel. Int. 100% PCB-77 4.42e7 32.66 32.0 ES-81 6.10e7 32.17 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PBM 4σ 3.87e4 0.00e0 RT Abs. Int. 2.20e7 1.10e7 0% 28.0 8.77e6 34.0 36.0 0.00e0 RT Abs. Int. 1.58e7 ES-77 6.19e7 32.64 7.92e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 7.49e7 32.17 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PBM 4σ 2.80e4 34.0 36.0 0.00e0 RT Abs. Int. 1.98e7 ES-77 7.63e7 32.64 9.88e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.06e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.53e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2130, 5580 scc: 739-978 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 16:12 (CEM) Printed: 06-Apr-2014 17:24 Page 9 of 21 213 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 PCB-104 2.58e7 25.28 Abs. Int. 6.70e6 PCB-96 2.20e7 25.60 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 9.72e2 3.35e6 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 PCB-104 4.02e7 25.28 PCB-96 3.44e7 25.60 0.00e0 RT Abs. Int. 1.02e7 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 8.53e2 5.10e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 6.06e7 25.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PBM 4σ 2.69e3 8.00e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 3.68e7 25.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.51e6 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PBM 4σ 2.79e3 4.76e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.02e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.51e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9222, 3112 scc: 739-978 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:10 Printed: 06-Apr-2014 17:24 Page 10 of 21 214 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 108/119... 1.24e8 31.35 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 1.37e3 PCB-103 2.01e7 27.28 100/93 3.57e7 28.07 PCB-88 1.55e7 28.55 PCB-121 2.56e7 29.56 113/90… 6.17e7 30.37 116/85 3.83e7 31.97 PCB-99 1.89e7 30.90 PCB-111 2.58e7 PCB-120 2.59e7 32.68 33.08 PCB-118 107/124 2.53e7 4.69e7 34.64 34.05 PCB-114 PCB-123 2.63e7 2.59e7 35.10 34.36 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 Abs. Int. 1.80e7 PCB-105 2.43e7 35.65 PCB-127 2.40e7 36.88 0% 28.0 30.0 32.0 108/119... 2.02e8 31.35 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 1.13e3 34.0 PCB-94 2.70e7 27.47 100/93 5.77e7 28.07 PCB-91 3.34e7 28.61 PCB-89 2.62e7 29.22 113/90… 1.00e8 30.37 PCB-112 PCB-92 4.05e7 2.81e7 31.00 29.88 116/85 PCB-115 6.19e7 4.15e7 PCB-111 31.97 32.17 4.18e7 32.68 PCB-117 PCB-110 PCB-120 4.10e7 3.70e7 4.23e7 PCB-82 31.88 32.082.38e7 33.08 32.37 PCB-118 107/124 4.08e7 7.62e7 34.64 34.04 PCB-114 PCB-123 4.26e7 4.21e7 35.10 34.36 30.0 Rel. Int. 100% 32.0 CS/SS-111 7.24e7 32.66 JS-101 5.91e7 30.37 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PBM 4σ 3.69e3 34.0 ES-118 ES-114 7.11e7 ES-123 6.83e7 35.08 6.88e7 34.62 34.34 0.00e0 RT 36.0 Abs. Int. 2.93e7 PCB-105 3.92e7 35.65 0% 28.0 8.98e6 36.0 ES-105 7.01e7 35.62 PCB-127 3.89e7 36.87 1.46e7 0.00e0 RT Abs. Int. 1.80e7 9.01e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.51e7 32.66 JS-101 3.67e7 30.37 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PBM 4σ 3.79e3 34.0 ES-114 ES-118 4.42e7 ES-123 4.30e7 35.08 4.38e7 34.62 34.34 36.0 ES-105 4.40e7 35.62 0.00e0 RT Abs. Int. 1.14e7 5.68e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.06e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.53e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7316, 2481 scc: 739-978 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 06-Apr-2014 16:13 (CEM) Printed: 06-Apr-2014 17:24 Page 11 of 21 215 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 Abs. Int. 5.51e6 PCB-126 2.30e7 38.25 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PBM 4σ 2.76e3 2.75e6 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 Abs. Int. 8.68e6 PCB-126 3.61e7 38.25 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PBM 4σ 3.51e3 4.34e6 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 7.41e6 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 4.78e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.73e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 9.56e6 ES-126 3.92e7 38.23 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PBM 4σ 4.47e3 0% 38.0 0.00e0 RT Abs. Int. 1.48e7 ES-126 6.06e7 38.23 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PBM 4σ 5.75e3 Rel. Int. 100% 0.00e0 RT 8.65e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9078, 5216 scc: 739-978 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:10 Printed: 06-Apr-2014 17:24 Page 12 of 21 216 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-136 3.43e7 30.83 PCB-150 PCB-155 3.68e7 PCB-145 4.02e7 30.53 3.49e7 30.22 31.10 Rel. Int. 100% HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 8.14e2 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 147/149 139/140 5.17e7 5.32e7 33.67 34.18 PCB-148 2.61e7 32.37 151/135 5.01e7 PCB-144PCB-134 32.89 2.60e7 2.12e7 33.36 33.84 153/168 6.66e7 36.24 PCB-146 PCB-142 PCB-133 2.68e7 2.45e7 35.70 2.20e7 35.14 34.50 PCB-141 2.44e7 36.39 163/138… 8.07e7 37.30 PCB-164 3.43e7PCB-160 37.01 3.21e7 37.44 0% 28.0 30.0 PCB-152 PCB-136 2.92e7 2.67e7 30.39 30.83 PCB-150 PCB-155 2.91e7 PCB-145 3.16e7 30.53 2.79e7 30.22 31.10 Rel. Int. 100% HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 9.98e2 32.0 PCB-148 2.08e7 32.37 34.0 147/149 139/140 151/135 4.11e7 4.21e7 3.98e7 33.67 34.18 32.89 PCB-154 PCB-143 PCB-132 2.34e7 1.88e7 1.81e7 33.10 33.92 34.74 PCB-146 2.15e7 35.69 163/138… 6.38e7 37.30 PCB-141 PCB-137 1.92e7 2.07e7 36.93 36.39 30.0 32.0 34.0 ES-155 6.78e7 30.20 Rel. Int. 100% HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PBM 4σ 1.64e3 6.03e6 0.00e0 RT 36.0 ES-153 4.90e7 36.20 Abs. Int. 1.21e7 PCB-158 2.88e7 37.62 0% 28.0 7.69e6 0.00e0 RT 36.0 153/168 5.29e7 36.24 Abs. Int. 1.54e7 JS-138 4.40e7 37.26 Abs. Int. 1.72e7 8.58e6 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 ES-155 5.23e7 30.20 Rel. Int. 100% ES-153 3.77e7 36.20 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PBM 4σ 1.42e3 JS-138 3.44e7 37.26 Abs. Int. 1.33e7 6.64e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.06e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.53e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5392, 9453 scc: 739-978 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:20 (CEM) Printed: 06-Apr-2014 17:24 Page 13 of 21 217 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% 128/166 5.03e7 38.36 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 3.29e3 PCB-159 3.02e7 39.17 0% 38.0 Rel. Int. 100% HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 3.19e3 0% 38.0 PCB-162 PCB-159 2.46e7 39.41 2.49e7 39.17 39.0 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 156/157 5.84e7 40.80 Abs. Int. 1.16e7 PCB-169 2.91e7 43.51 PCB-167 3.22e7 39.82 40.0 128/166 4.11e7 38.36 5.80e6 41.0 42.0 43.0 44.0 156/157 4.80e7 40.80 40.0 PCB-169 2.37e7 43.51 4.72e6 41.0 42.0 43.0 44.0 ES-156/157 1.10e8 40.78 0.00e0 RT Abs. Int. 1.97e7 ES-169 5.31e7 43.49 9.84e6 39.0 Rel. Int. 100% 40.0 ES-167 4.50e7 39.79 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PBM 4σ 7.83e3 41.0 42.0 43.0 44.0 ES-156/157 8.60e7 40.78 0.00e0 RT Abs. Int. 1.54e7 ES-169 4.24e7 43.49 7.69e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.73e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 9.45e6 PCB-167 2.67e7 39.82 ES-167 5.79e7 39.79 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PBM 4σ 6.53e3 0% 38.0 PCB-162 2.99e7 39.41 39.0 Rel. Int. 100% 0% 38.0 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 8.65e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2019, 8835 scc: 739-978 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:20 (CEM) Printed: 06-Apr-2014 17:24 Page 14 of 21 218 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% PCB-188 2.60e7 35.10 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 PCB-179 2.50e7 PCB-184 2.35e7 35.38 35.83 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 9.08e2 0% 30.0 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 PCB-188 2.46e7 35.09 36.0 PCB-179 2.35e7 35.38 PCB-176 2.44e7 36.13 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 5.61e2 0% 30.0 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 6.53e6 PCB-186 2.48e7 36.53 PCB-178 1.75e7 37.66 Abs. Int. 6.10e6 PCB-186 2.32e7 36.53 PCB-178 1.63e7 37.66 Abs. Int. 1.11e7 CS/SS-178 2.80e7 37.64 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 1.06e7 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PBM 4σ 1.27e3 0% 30.0 CS/SS-178 2.61e7 37.64 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 5.29e6 0.00e0 RT Abs. Int. 3.06e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 5.53e6 0.00e0 RT 37.0 ES-188 4.32e7 35.07 Rel. Int. 100% 3.05e6 0.00e0 RT 37.0 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PBM 4σ 1.45e3 0% 30.0 0.00e0 RT 37.0 ES-188 4.63e7 35.07 Rel. Int. 100% 3.27e6 1.53e7 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6419, 4504 scc: 739-978 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:20 (CEM) Printed: 06-Apr-2014 17:24 Page 15 of 21 219 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 5.54e3 PCB-175 2.10e7 38.20 0% 38.0 Rel. Int. 100% HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 4.02e3 0% 38.0 PCB-183 2.28e7 38.95 PCB-182 PCB-185 2.27e7 2.18e7 38.61 39.04 39.0 PCB-182 2.16e7 38.61 PCB-183 PCB-187 2.16e7 2.12e7 38.95 38.43 39.0 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 171/173 3.67e7 PCB-181 40.05 PCB-177 2.11e7 1.84e7 39.87 39.52 40.0 PCB-172 1.90e7 41.40 41.0 171/173 3.49e7 PCB-181 40.05 PCB-177 2.03e7 1.74e7 39.87 39.52 40.0 180/193 PCB-192 4.60e7 2.41e7 41.92 41.65 42.0 ES-180 3.96e7 41.94 Rel. Int. 100% PCB-191 2.67e7 42.25 42.0 PCB-172 1.81e7 41.40 41.0 180/193 4.82e7 41.92 PCB-192 2.55e7 41.65 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 PCB-170 1.83e7 43.03 4.34e6 43.0 PCB-191 2.53e7 42.25 Abs. Int. 8.68e6 PCB-190 2.63e7 43.48 44.0 Abs. Int. 8.02e6 PCB-190 2.52e7 43.48 PCB-170 1.75e7 43.02 43.0 4.01e6 44.0 4.81e6 39.0 40.0 41.0 42.0 ES-180 3.69e7 41.94 Rel. Int. 100% 43.0 44.0 4.57e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.73e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 9.14e6 ES-170 3.09e7 43.01 HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PBM 4σ 4.22e3 0% 38.0 0.00e0 RT Abs. Int. 9.61e6 ES-170 3.35e7 43.01 HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PBM 4σ 4.02e3 0% 38.0 0.00e0 RT 8.65e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1836, 3305 scc: 739-978 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:21 (CEM) Printed: 06-Apr-2014 17:24 Page 16 of 21 220 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 PCB-189 2.69e7 45.63 Rel. Int. 100% Abs. Int. 6.63e6 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PBM 4σ 1.83e3 3.32e6 0% 45.0 46.0 47.0 48.0 49.0 PCB-189 2.54e7 45.63 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.25e6 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PBM 4σ 1.81e3 3.12e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 4.87e7 45.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PBM 4σ 3.36e3 5.80e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 4.65e7 45.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e7 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PBM 4σ 3.62e3 5.43e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.41e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 4.20e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9631, 9808 scc: 739-978 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:21 (CEM) Printed: 06-Apr-2014 17:24 Page 17 of 21 221 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-201 2.15e7 40.41 PCB-202 1.93e7 39.63 Rel. Int. 100% OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PBM 4σ 8.49e2 0% 38.0 PCB-197 2.29e7 PCB-204 41.18 PCB-200 1.92e7 2.02e7 41.27 40.99 198/199 2.81e7 43.59 Abs. Int. 5.32e6 PCB-196 1.48e7 44.16 39.0 40.0 41.0 PCB-201 2.38e7 40.41 PCB-202 2.12e7 39.63 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PBM 4σ 6.72e2 PCB-204 2.22e7 40.99 42.0 43.0 PCB-197 2.53e7 41.18 PCB-200 2.10e7 41.27 198/199 3.11e7 43.59 Abs. Int. 5.87e6 PCB-196 1.65e7 44.16 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 3.90e7 39.61 0.00e0 RT 4.81e6 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 4.22e7 39.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.03e7 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PBM 4σ 1.57e3 5.13e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.73e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 PCB-203 1.70e7 44.33 Abs. Int. 9.63e6 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PBM 4σ 1.36e3 0% 38.0 0.00e0 RT 44.0 2.93e6 Rel. Int. 100% 0% 38.0 PCB-203 1.53e7 44.33 2.66e6 Rel. Int. 100% 0% 38.0 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 8.65e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9932, 5222 scc: 739-978 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:10 Printed: 06-Apr-2014 17:24 Page 18 of 21 222 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-194 1.38e7 47.40 PCB-195 1.25e7 45.46 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PBM 4σ 1.86e3 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 PCB-205 1.78e7 47.80 Abs. Int. 4.25e6 2.13e6 0% 45.0 Rel. Int. 100% 46.0 47.0 PCB-194 1.55e7 47.40 PCB-195 1.38e7 45.45 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PBM 4σ 1.92e3 48.0 49.0 PCB-205 1.99e7 47.79 0.00e0 RT Abs. Int. 4.70e6 2.35e6 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.78e7 47.38 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PBM 4σ 3.17e3 49.0 ES-205 3.54e7 47.78 Abs. Int. 8.40e6 (3.54e7 + 3.94e7) * 100 pg/ul = 1.27 (2.78e7 + 3.10e7) * 100 pg/ul CEM 06-Apr-2014 16:25 4.20e6 RRF (ES-205) = 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 3.10e7 47.38 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PBM 4σ 2.87e3 0.00e0 RT 49.0 ES-205 3.94e7 47.78 0.00e0 RT Abs. Int. 9.55e6 4.77e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.41e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 4.20e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6069, 5121 scc: 739-978 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:21 (CEM) Printed: 06-Apr-2014 17:24 Page 19 of 21 223 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 PCB-208 1.87e7 45.25 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 PCB-207 1.94e7 46.04 PCB-206 1.28e7 49.26 NoCB 44.77-49.81 461.7245 Fn6 Flags: PBM 4σ 1.34e3 Abs. Int. 4.68e6 2.34e6 0% 45.0 46.0 PCB-208 2.38e7 45.25 Rel. Int. 100% 47.0 48.0 0.00e0 RT 49.0 PCB-207 2.49e7 46.04 PCB-206 1.65e7 49.26 NoCB 44.77-49.81 463.7216 Fn6 Flags: PBM 4σ 2.41e3 Abs. Int. 6.00e6 3.00e6 0.00e0 RT 0% 45.0 46.0 47.0 48.0 49.0 ES-208 3.44e7 45.23 Rel. Int. 100% ES-206 2.45e7 49.24 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PBM 4σ 2.51e3 Abs. Int. 8.16e6 4.08e6 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 ES-208 4.31e7 45.23 Rel. Int. 100% ES-206 3.00e7 49.24 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PBM 4σ 3.03e3 Abs. Int. 1.03e7 5.15e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.41e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 4.20e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7023, 1807 scc: 739-978 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:21 (CEM) Printed: 06-Apr-2014 17:24 Page 20 of 21 224 of 603 SGS ID: CS3_140403_PCB_XB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 15:20:55 User: LKB Datafile: 140403X04 PCB-209 2.06e7 50.68 Rel. Int. 100% Abs. Int. 4.45e6 DeCB 49.82-52.00 497.6826 Fn7 Flags: PBM 4σ 6.95e2 2.22e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.75e7 50.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.81e6 DeCB 49.82-52.00 499.6797 Fn7 Flags: PBM 4σ 5.88e2 1.90e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.87e7 50.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.35e6 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PBM 4σ 9.27e2 4.18e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.29e7 50.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.16e6 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PBM 4σ 8.65e2 3.58e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.75e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 3.87e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XB.utp_res, saved 06-Apr-2014 16:25 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7259, 0503 scc: 739-978 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:24 Page 21 of 21 225 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services CS3_140403_PCB_XC 03-APR-2014 22:09 140403X11 Processed: 6-Apr-2014 16:19 ICAL: MM7_PCB_10292013_20DEC2013 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.67 32.19 35.65 35.11 34.65 34.36 38.26 40.80 39.82 43.51 45.64 50.68 8.07E+07 7.73E+07 6.47E+07 7.05E+07 6.63E+07 6.95E+07 6.12E+07 1.13E+08 6.15E+07 5.41E+07 5.43E+07 3.94E+07 0.80 Y 0.79 Y 0.62 Y 0.61 Y 0.62 Y 0.63 Y 0.64 Y 1.22 Y 1.20 Y 1.23 Y 1.07 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.16 1.09 1.18 1.17 1.22 1.20 1.09 1.14 1.11 1.10 1.07 1.6% 3.7% -2.0% -1.6% -1.3% 0.5% 8.9% -0.6% -2.1% -1.6% 2.1% -4.3% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 11.81 14.09 14.34 20.03 17.41 26.33 20.31 32.65 32.18 25.27 35.63 35.09 34.62 34.34 38.24 36.20 30.21 40.78 39.80 43.50 43.01 41.94 35.08 45.62 39.61 47.78 49.24 45.23 50.66 2.26E+08 2.13E+08 1.24E+08 2.16E+08 1.08E+08 1.56E+08 1.10E+08 1.38E+08 1.33E+08 1.00E+08 1.19E+08 1.19E+08 1.13E+08 1.14E+08 1.02E+08 8.81E+07 1.23E+08 2.07E+08 1.08E+08 9.78E+07 6.81E+07 8.07E+07 9.19E+07 9.91E+07 8.57E+07 7.70E+07 5.53E+07 8.15E+07 7.39E+07 3.28 Y 3.34 Y 1.60 Y 1.58 Y 1.07 Y 1.10 Y 0.80 Y 0.80 Y 0.80 Y 1.64 Y 1.60 Y 1.62 Y 1.60 Y 1.59 Y 1.54 Y 1.30 Y 1.28 Y 1.28 Y 1.28 Y 1.26 Y 1.10 Y 1.07 Y 1.08 Y 1.03 Y 0.91 Y 0.89 Y 0.80 Y 0.79 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.13 1.06 0.62 1.08 0.54 1.45 1.02 1.28 1.24 1.04 1.24 1.24 1.18 1.19 1.06 1.08 1.51 1.27 1.33 1.20 1.12 1.33 1.13 1.63 1.05 1.27 0.91 1.34 1.22 -5.2% -2.1% 18.6% 3.6% 6.4% -12.9% 18.9% -7.5% -9.5% 30.0% 2.8% 1.8% 1.4% 0.2% 3.0% -2.9% -4.9% -20.6% -20.4% -22.9% 18.7% 17.0% 20.1% 3.3% 8.5% 2.1% 9.9% 14.4% 9.8% Page 1 of 6 226 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Environmental Services Processed: 6-Apr-2014 16:19 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XC 03-APR-2014 22:09 140403X11 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 22.78 32.67 37.64 1.70E+08 1.19E+08 5.66E+07 1.09 Y 1.59 Y 1.07 Y 1.11 1.03 0.62 1.09 1.05 0.62 -2.1% 1.6% -0.6% CS PCB-28 CS PCB-111 CS PCB-178 22.78 32.67 37.64 1.70E+08 1.19E+08 5.66E+07 1.09 Y 1.59 Y 1.07 Y 1.85 1.22 0.58 1.58 1.24 0.69 -14.7% 1.8% 19.4% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.31 24.40 30.38 37.27 47.38 2.00E+08 1.08E+08 9.60E+07 8.15E+07 6.06E+07 1.57 Y 0.80 Y 1.58 Y 1.29 Y 0.90 Y - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 11.83 14.10 14.36 20.04 17.43 26.35 20.33 25.29 30.23 35.10 39.63 47.80 45.26 49.26 1.23E+08 1.22E+08 7.12E+07 1.20E+08 5.91E+07 9.63E+07 6.99E+07 6.67E+07 7.23E+07 5.24E+07 4.28E+07 3.92E+07 4.43E+07 3.03E+07 3.19 Y 3.21 Y 1.58 Y 1.64 Y 1.05 Y 1.01 Y 0.81 Y 0.64 Y 1.25 Y 1.06 Y 0.90 Y 0.90 Y 0.78 Y 0.78 Y 1.09 1.15 1.15 1.11 1.10 1.23 1.27 1.33 1.17 1.14 1.00 1.02 1.09 1.10 14.1% 13.6% -7.0% 9.1% -4.4% 14.4% -6.3% -7.2% -6.8% -10.2% -5.2% -3.9% -3.1% -1.7% 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 - Page 2 of 6 - 227 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB Processed: 6-Apr-2014 16:19 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XC 03-APR-2014 22:09 140403X11 RT Response RA 11.83 13.92 14.10 14.36 14.53 16.32 16.49 16.72 17.02 17.14 18.69 19.46 19.76 20.04 17.43 19.18 19.58 19.77 19.90 20.00 20.48 21.62 21.77 22.06 22.25 22.53 22.81 23.00 23.37 24.75 25.07 25.60 25.99 26.35 20.33 22.31 22.89 22.96 23.17 24.42 24.55 1.23E+08 1.23E+08 1.22E+08 7.12E+07 1.17E+08 1.05E+08 1.19E+08 1.12E+08 1.11E+08 1.14E+08 1.33E+08 1.14E+08 2.28E+08 1.20E+08 5.91E+07 1.63E+08 6.84E+07 9.56E+07 9.28E+07 5.05E+07 1.01E+08 9.70E+07 9.83E+07 1.99E+08 1.02E+08 1.05E+08 1.94E+08 2.01E+08 9.29E+07 1.05E+08 1.05E+08 9.47E+07 9.15E+07 9.63E+07 6.99E+07 1.21E+08 5.02E+07 6.36E+07 4.86E+07 5.96E+07 7.68E+07 3.19 Y 3.21 Y 3.21 Y 1.58 Y 1.57 Y 1.63 Y 1.64 Y 1.65 Y 1.64 Y 1.62 Y 1.63 Y 1.65 Y 1.64 Y 1.64 Y 1.05 Y 1.04 Y 1.04 Y 1.05 Y 1.04 Y 1.05 Y 1.04 Y 1.02 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.01 Y 1.02 Y 1.02 Y 1.01 Y 0.81 Y 0.78 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y Page 3 of 6 RRF 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 1.15 1.88 0.97 1.11 1.04 1.03 1.06 1.23 1.06 1.06 1.51 1.27 1.77 1.72 0.94 1.88 1.24 1.26 1.28 1.30 1.34 1.24 1.29 1.19 1.34 1.35 1.21 1.17 0.91 0.75 0.95 0.73 0.89 1.15 11.7% -5.2% 2.8% 5.7% 4.3% 3.0% 2.7% 4.5% 4.8% 6.9% -1.9% -2.7% -2.4% -0.1% -6.8% -2.2% 9.5% 9.0% 9.0% 12.5% 9.3% 9.5% 9.9% 10.2% 14.9% 11.4% 9.8% 12.7% 3.4% -1.9% 11.0% 4.3% 6.0% 3.5% 228 of 603 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeC PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB Processed: 6-Apr-2014 16:19 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XC 03-APR-2014 22:09 140403X11 RT Response RA 24.65 24.84 25.12 25.34 25.62 25.78 26.11 26.21 26.41 27.12 27.38 27.75 27.95 28.11 28.33 28.63 28.90 29.05 29.49 29.68 30.00 31.33 31.82 25.29 25.61 27.29 27.48 27.87 28.08 28.18 28.25 28.56 28.62 28.82 29.23 29.57 29.89 30.38 30.81 4.78E+07 1.45E+08 5.94E+07 1.91E+08 2.50E+08 5.43E+07 4.82E+07 1.23E+08 8.88E+07 8.22E+07 8.78E+07 7.81E+07 8.18E+07 8.46E+07 8.85E+07 3.23E+08 7.89E+07 7.67E+07 7.60E+07 7.71E+07 9.06E+07 9.11E+07 7.40E+07 6.67E+07 5.78E+07 5.27E+07 4.44E+07 4.82E+07 9.66E+07 4.78E+07 4.86E+07 4.65E+07 5.00E+07 4.02E+07 4.27E+07 6.77E+07 4.59E+07 1.64E+08 3.70E+07 0.79 Y 0.78 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.80 Y 0.81 Y 0.79 Y 0.80 Y 0.80 Y 0.79 Y 0.80 Y 0.79 Y 0.80 Y 0.79 Y 0.80 Y 0.79 Y 0.80 Y 0.80 Y 0.64 Y 0.64 Y 0.62 Y 0.61 Y 0.61 Y 0.61 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y Page 4 of 6 RRF 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.72 1.09 0.89 0.96 1.25 0.82 0.72 0.92 1.33 1.23 1.32 1.17 1.23 1.27 1.33 1.21 1.18 1.15 1.14 1.16 1.36 1.37 1.11 1.15 0.92 0.78 0.84 0.85 0.84 0.85 0.81 0.88 0.70 0.75 1.19 0.80 0.96 0.65 0.9% 6.2% 6.2% 5.7% 7.2% 6.8% 4.0% 7.5% 9.0% 2.0% 3.1% 0.7% 4.1% 0.8% 2.2% 1.0% 7.4% 2.7% 2.6% 1.8% 3.5% 4.5% 4.6% -6.1% -0.7% -2.8% -2.6% -2.1% -13.6% 12.4% 2.0% -7.3% -1.7% -2.0% -1.2% -2.0% -3.1% -9.3% 229 of 603 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Processed: 6-Apr-2014 16:19 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XC 03-APR-2014 22:09 140403X11 Name PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB RT Response RA 30.90 31.01 31.35 31.89 31.98 32.10 32.18 32.38 32.69 33.09 34.05 34.26 34.48 34.94 36.88 30.23 30.39 30.53 30.84 31.11 32.38 32.90 33.11 33.37 33.67 33.85 33.93 34.19 34.37 34.51 34.75 35.15 35.49 35.70 35.82 36.25 36.39 36.74 36.94 37.02 37.31 5.44E+07 6.42E+07 3.31E+08 6.24E+07 1.09E+08 6.27E+07 6.37E+07 3.94E+07 6.88E+07 6.86E+07 1.24E+08 6.77E+07 6.55E+07 5.93E+07 6.48E+07 7.23E+07 6.63E+07 6.79E+07 6.18E+07 6.38E+07 4.74E+07 9.20E+07 5.37E+07 4.81E+07 9.50E+07 3.61E+07 4.65E+07 9.77E+07 4.05E+07 4.06E+07 4.23E+07 4.48E+07 5.86E+07 4.95E+07 6.61E+07 1.22E+08 4.61E+07 4.04E+07 5.29E+07 5.98E+07 1.47E+08 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.63 Y 0.61 Y 0.62 Y 0.61 Y 0.61 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 1.25 Y 1.27 Y 1.27 Y 1.27 Y 1.26 Y 1.26 Y 1.26 Y 1.26 Y 1.26 Y 1.27 Y 1.26 Y 1.26 Y 1.26 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.26 Y 1.27 Y 1.26 Y 1.27 Y 1.26 Y 1.27 Y 1.26 Y 1.25 Y Page 5 of 6 RRF 0.92 1.17 0.98 1.14 0.94 1.12 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 0.95 1.12 0.97 1.09 0.96 1.10 1.12 0.69 1.21 1.20 1.09 1.19 1.15 1.00 1.09 1.08 1.10 1.00 1.04 1.08 1.04 1.22 1.09 1.08 0.82 1.06 1.11 0.92 0.92 0.96 1.02 1.33 1.12 1.50 1.38 1.05 0.92 1.20 1.36 1.11 3.4% -3.7% -1.4% -4.0% 1.8% -1.8% -3.7% -1.0% -1.3% -0.9% -1.1% -5.4% 3.7% 0.1% -0.3% -8.2% -6.2% -5.9% -7.0% -9.0% -8.4% -9.2% -7.8% -8.3% -11.3% -6.4% -8.1% -10.3% -6.9% -6.9% -10.1% -5.6% -6.4% -1.5% -5.2% -3.9% -5.6% 3.2% -9.3% -6.4% 230 of 603 Lab ID: - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB Processed: 6-Apr-2014 16:19 ICAL: MM7_PCB_10292013_20DEC2013 CS3_140403_PCB_XC 03-APR-2014 22:09 140403X11 RT Response RA 37.44 37.63 38.36 39.17 39.41 35.10 35.39 35.84 36.14 36.54 37.66 38.21 38.43 38.61 38.96 39.05 39.15 39.53 39.87 40.06 41.41 41.65 41.93 42.26 43.03 43.48 39.63 40.42 40.99 41.18 41.28 43.59 44.17 44.34 45.46 47.40 47.80 45.26 46.04 49.26 6.13E+07 6.75E+07 9.43E+07 5.73E+07 5.73E+07 5.24E+07 4.92E+07 4.84E+07 5.28E+07 4.98E+07 3.51E+07 4.28E+07 4.53E+07 4.67E+07 4.99E+07 4.04E+07 3.85E+07 3.70E+07 4.34E+07 7.57E+07 3.91E+07 5.17E+07 9.91E+07 5.54E+07 3.77E+07 5.38E+07 4.28E+07 4.78E+07 4.55E+07 4.98E+07 4.40E+07 6.29E+07 3.33E+07 3.42E+07 2.77E+07 3.03E+07 3.92E+07 4.43E+07 4.62E+07 3.03E+07 1.25 Y 1.26 Y 1.22 Y 1.21 Y 1.22 Y 1.06 Y 1.07 Y 1.06 Y 1.08 Y 1.06 Y 1.07 Y 1.06 Y 1.04 Y 1.06 Y 1.05 Y 1.05 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.05 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.04 Y 0.90 Y 0.91 Y 0.92 Y 0.91 Y 0.92 Y 0.92 Y 0.90 Y 0.90 Y 0.90 Y 0.90 Y 0.90 Y 0.78 Y 0.78 Y 0.78 Y Page 6 of 6 RRF 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 1.39 1.53 0.87 1.06 1.06 1.07 1.05 1.15 1.08 0.76 1.06 1.12 1.16 1.24 1.00 0.96 0.92 1.08 0.94 0.97 1.28 1.23 1.37 1.11 1.58 1.12 1.06 1.16 1.03 0.73 0.78 0.80 0.72 0.79 1.13 - -8.1% -7.8% -3.0% -5.0% -1.1% -7.8% -6.5% -6.8% -3.7% -9.3% -1.0% -1.4% -1.5% 2.7% -5.5% -3.4% -3.4% -1.2% -1.0% -1.8% -0.4% -2.5% -1.5% -2.6% -4.9% -8.7% -4.9% -2.3% -7.3% -9.3% -6.8% -8.6% -6.0% -6.8% -4.7% - 231 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 6.25e7 3.12e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 2.46e7 1.23e7 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 2.18e7 1.09e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 2.50e7 1.25e7 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 1.43e7 7.16e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.65e6 2.82e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 5.48e6 2.74e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 980-763 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:25 Page 1 of 21 232 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-1 9.38e7 11.83 Rel. Int. 100% Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 PCB-2 9.38e7 13.92 MoCB 10.03-15.71 188.0393 Fn1 Flags: PBM 4σ 2.10e3 Abs. Int. 3.68e7 PCB-3 9.32e7 14.10 1.84e7 0% 11.0 12.0 13.0 PCB-1 2.94e7 11.83 Rel. Int. 100% 14.0 PCB-2 2.92e7 13.92 MoCB 10.03-15.71 190.0363 Fn1 Flags: PBM 4σ 2.57e3 15.0 0.00e0 RT Abs. Int. 1.17e7 PCB-3 2.90e7 14.10 5.85e6 0% 11.0 12.0 13.0 ES-1 1.74e8 11.81 Rel. Int. 100% 14.0 15.0 Abs. Int. 6.94e7 ES-3 1.64e8 14.09 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PBM 4σ 8.99e3 0.00e0 RT 3.47e7 0% 11.0 12.0 13.0 ES-1 5.29e7 11.81 Rel. Int. 100% 14.0 15.0 Abs. Int. 2.12e7 ES-3 4.91e7 14.09 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PBM 4σ 2.25e4 0.00e0 RT 1.06e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.25e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 3.12e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4526, 2632 scc: 980-763 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:00 Printed: 06-Apr-2014 17:25 Page 2 of 21 233 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 Rel. Int. 100% Abs. Int. 2.43e7 PCB-10 7.13e7 14.53 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PBM 4σ 2.67e3 PCB-4 4.36e7 14.36 1.21e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 1.55e7 PCB-10 4.53e7 14.53 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PBM 4σ 1.29e4 PCB-4 2.75e7 14.36 7.76e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 7.63e7 14.34 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 2.61e7 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PBM 4σ 7.36e3 1.31e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.77e7 14.34 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.64e7 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PBM 4σ 2.37e3 8.19e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.25e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 3.12e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1187, 0744 scc: 980-763 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:00 (CEM) Printed: 06-Apr-2014 17:25 Page 3 of 21 234 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PCB-6 6.99e7 16.72 PCB-9 6.51e7 16.32 DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PBM 4σ 4.50e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-14 8.25e7 18.69 PCB-5 6.92e7 PCB-8 17.02 7.08e7 17.14 PCB-11 7.12e7 19.46 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 13/12 1.42e8 19.76 Abs. Int. 2.32e7 PCB-15 7.47e7 20.04 1.16e7 0% 16.0 Rel. Int. 100% 17.0 PCB-9 3.99e7 16.32 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PBM 4σ 1.74e4 PCB-7 4.52e7 16.49 18.0 19.0 PCB-14 5.05e7 18.69 PCB-5 4.23e7 PCB-8 17.02 4.36e7 17.13 20.0 PCB-11 4.32e7 19.46 13/12 8.67e7 19.76 21.0 0.00e0 RT Abs. Int. 1.42e7 PCB-15 4.55e7 20.04 7.08e6 0% 16.0 17.0 18.0 19.0 JS-9 1.22e8 16.31 Rel. Int. 100% 20.0 21.0 ES-15 1.32e8 20.03 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PBM 4σ 1.73e4 Abs. Int. 3.98e7 (1.32e8 + 8.36e7) * 100 pg/ul = 1.08 (1.22e8 + 7.79e7) * 100 pg/ul CEM 06-Apr-2014 16:29 1.99e7 RRF (ES-15) = 0% 16.0 17.0 18.0 19.0 JS-9 7.79e7 16.31 Rel. Int. 100% 0.00e0 RT 20.0 21.0 ES-15 8.36e7 20.02 0.00e0 RT Abs. Int. 2.51e7 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PBM 4σ 5.58e3 1.25e7 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.46e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.23e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5016, 9425 scc: 980-763 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:01 (CEM) Printed: 06-Apr-2014 17:25 Page 4 of 21 235 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 30/18 8.27e7 19.18 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PBM 4σ 3.91e3 PCB-19 3.02e7 17.43 PCB-17 3.49e7 19.58 PCB-27 4.89e7 19.77 PCB-24 4.73e7 19.90 PCB-16 2.59e7 20.00 Abs. Int. 2.30e7 PCB-32 5.16e7 20.48 1.15e7 0% 16.0 17.0 18.0 Rel. Int. 100% 19.0 20.0 30/18 7.98e7 19.18 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PBM 4σ 2.62e3 PCB-19 2.89e7 17.42 PCB-17 3.35e7 19.58 PCB-24 4.55e7 19.90 PCB-27 4.67e7 19.77 21.0 Abs. Int. 2.23e7 PCB-16 2.46e7 20.00 PCB-32 4.96e7 20.48 1.11e7 0% 16.0 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 2.38e7 ES-19 5.58e7 17.41 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PBM 4σ 6.17e4 0.00e0 RT 1.19e7 0% 16.0 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.23e7 ES-19 5.20e7 17.41 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PBM 4σ 2.43e4 0.00e0 RT 1.12e7 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.46e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.23e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2028, 6839 scc: 980-763 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:00 Printed: 06-Apr-2014 17:25 Page 5 of 21 236 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 28/20 9.74e7 22.81 Rel. Int. 100% TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 8.40e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-34 4.89e7 21.62 PCB-23 4.94e7 21.77 26/29 1.00e8 22.06 Abs. Int. 2.35e7 PCB-31 5.25e7 22.53 PCB-36 5.27e7 24.75 PCB-22 4.67e7 23.37 PCB-39 5.30e7 25.07 PCB-38 4.77e7 25.60 PCB-35 4.61e7 25.99 PCB-37 4.83e7 26.35 0% 22.0 24.0 25.0 0.00e0 RT 26.0 28/20 9.62e7 22.81 Rel. Int. 100% TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 5.84e3 23.0 PCB-34 4.81e7 21.62 PCB-23 4.89e7 21.77 26/29 9.90e7 22.06 Abs. Int. 2.33e7 PCB-31 5.20e7 22.53 PCB-36 5.22e7 24.75 PCB-22 4.62e7 23.37 PCB-39 5.24e7 25.07 PCB-38 4.69e7 25.60 PCB-35 4.54e7 25.99 PCB-37 4.80e7 26.35 23.0 24.0 25.0 26.0 CS/SS-28 8.87e7 22.78 Rel. Int. 100% 1.16e7 0.00e0 RT 0% 22.0 1.17e7 ES-37 8.17e7 26.33 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PBM 4σ 5.59e4 Abs. Int. 2.47e7 1.23e7 0% 22.0 23.0 24.0 25.0 CS/SS-28 8.12e7 22.78 Rel. Int. 100% 0.00e0 RT 26.0 ES-37 7.44e7 26.33 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PBM 4σ 1.59e4 Abs. Int. 2.24e7 1.12e7 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.18e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.09e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7408, 2546 scc: 980-763 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:01 (CEM) Printed: 06-Apr-2014 17:25 Page 6 of 21 237 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 PCB-54 3.13e7 20.33 Rel. Int. 100% Abs. Int. 8.79e6 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PBM 4σ 1.54e3 4.39e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 PCB-54 3.87e7 20.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e7 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PBM 4σ 1.55e3 5.44e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 4.91e7 20.31 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PBM 4σ 1.31e4 7.05e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 6.13e7 20.31 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.75e7 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PBM 4σ 9.65e3 8.73e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.46e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.23e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4700, 9903 scc: 980-763 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:00 Printed: 06-Apr-2014 17:25 Page 7 of 21 238 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 2.40e3 50/53 5.29e7 22.31 PCB-51 2.81e7 22.96 PCB-45 2.20e7 22.89 PCB-73 PCB-52 3.36e7 2.62e7 24.55 24.42 PCB-46 2.15e7 23.17 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 69/49 6.36e7 24.84 44/47… 8.41e7 25.34 PCB-48 2.61e7 25.12 59/62… 1.10e8 25.62 71/40 5.40e7 26.21 PCB-42 2.39e7 25.78 PCB-41 2.12e7 26.11 Abs. Int. 2.05e7 PCB-64 3.89e7 26.41 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 1.58e3 50/53 6.79e7 22.30 24.0 PCB-51 3.55e7 22.96 PCB-45 2.82e7 22.89 25.0 PCB-73 4.31e7 PCB-52 24.55 3.34e7 24.42 PCB-46 2.71e7 23.17 69/49 8.12e7 24.84 PCB-48 3.33e7 25.12 59/62… 1.40e8 25.62 71/40 6.90e7 26.21 PCB-42 3.04e7 25.78 PCB-41 2.71e7 26.11 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.79e7 24.40 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 1.07e8 25.34 1.02e7 Abs. Int. 2.65e7 PCB-64 4.99e7 26.41 1.32e7 0.00e0 RT Abs. Int. 1.32e7 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PBM 4σ 2.85e4 6.62e6 0% 22.0 23.0 24.0 25.0 26.0 JS-52 5.99e7 24.40 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e7 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PBM 4σ 1.80e4 8.23e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.18e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.09e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7621, 1640 scc: 980-763 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:00 Printed: 06-Apr-2014 17:25 Page 8 of 21 239 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 7.06e3 61/70... 1.43e8 28.63 PCB-68 3.92e7 27.38 PCB-72 3.65e7 27.12 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-67 3.75e7 28.11 PCB-55 3.40e7 29.05 PCB-60 PCB-80 3.42e7 4.01e7 29.68 30.00 PCB-79 4.04e7 31.33 PCB-78 3.28e7 31.82 PCB-81 3.42e7 32.19 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 Abs. Int. 1.67e7 PCB-77 3.60e7 32.67 8.36e6 0% 28.0 Rel. Int. 100% TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 6.97e3 61/70... 1.80e8 PCB-57 28.62 4.35e7 27.75 PCB-63 PCB-68 4.93e7 PCB-66 4.86e7 4.42e7 28.33 27.38 28.90 30.0 32.0 PCB-60 4.29e7 29.68 PCB-56 4.24e7 29.49 PCB-80 5.05e7 30.00 PCB-79 5.07e7 31.33 PCB-78 4.12e7 31.82 PCB-81 4.31e7 32.19 34.0 36.0 Abs. Int. 2.13e7 PCB-77 4.47e7 32.67 1.07e7 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 5.95e7 32.18 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PBM 4σ 3.12e4 0.00e0 RT 34.0 36.0 0.00e0 RT Abs. Int. 1.58e7 ES-77 6.14e7 32.65 7.90e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 7.39e7 32.18 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PBM 4σ 1.98e4 34.0 36.0 0.00e0 RT Abs. Int. 1.93e7 ES-77 7.66e7 32.65 9.67e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.25e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7827, 8061 scc: 980-763 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:38 (CEM) Printed: 06-Apr-2014 17:25 Page 9 of 21 240 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 PCB-104 2.59e7 25.29 Abs. Int. 6.78e6 PCB-96 2.26e7 25.61 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 7.55e2 3.39e6 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 PCB-104 4.08e7 25.29 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 8.58e2 0.00e0 RT Abs. Int. 1.08e7 PCB-96 3.52e7 25.61 5.40e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 6.24e7 25.27 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.63e7 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PBM 4σ 1.94e3 8.16e6 0% 22.0 23.0 24.0 25.0 26.0 ES-104 3.79e7 25.27 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.83e6 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PBM 4σ 3.39e3 4.91e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.18e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.09e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5239, 1141 scc: 980-763 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:00 (CEM) Printed: 06-Apr-2014 17:25 Page 10 of 21 241 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 108/119... 1.26e8 31.35 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 1.46e3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 PCB-103 2.02e7 27.29 100/93 3.67e7 28.08 PCB-88 1.77e7 28.56 PCB-121 2.59e7 29.57 113/90… 6.25e7 30.38 116/85 4.18e7 31.98 PCB-99 2.05e7 30.90 PCB-111 2.62e7 PCB-120 2.60e7 32.69 33.09 107/124 PCB-118 2.53e7 4.72e7 34.65 34.05 PCB-123 PCB-114 2.68e7 2.68e7 34.36 35.11 Abs. Int. 1.84e7 PCB-105 2.47e7 35.65 PCB-127 2.47e7 36.88 0% 28.0 30.0 32.0 108/119... 2.04e8 31.35 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 1.98e3 34.0 PCB-94 2.75e7 27.48 100/93 5.99e7 28.08 PCB-91 3.09e7 28.62 PCB-89 2.64e7 29.23 113/90… 1.01e8 30.37 PCB-112 PCB-92 3.97e7 2.84e7 31.01 29.89 116/85 PCB-115 6.75e7 3.92e7 31.98 32.18 PCB-117 PCB-110 PCB-111 PCB-120 4.26e7 3.88e7 3.87e7 4.26e7 32.69 31.89 32.10 33.08 107/124 PCB-118 4.11e7 7.68e7 34.64 34.05 PCB-123 PCB-114 4.27e7 4.37e7 34.36 35.11 30.0 Rel. Int. 100% 32.0 CS/SS-111 7.34e7 32.67 JS-101 5.88e7 30.38 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PBM 4σ 4.84e3 34.0 ES-118 ES-114 7.36e7 35.09 ES-123 6.94e7 7.01e7 34.62 34.34 0.00e0 RT 36.0 Abs. Int. 3.00e7 PCB-105 4.00e7 35.65 0% 28.0 9.22e6 36.0 ES-105 7.30e7 35.63 PCB-127 4.01e7 36.88 1.50e7 0.00e0 RT Abs. Int. 1.85e7 9.27e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.60e7 32.67 JS-101 3.73e7 30.38 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PBM 4σ 3.67e3 34.0 ES-118 ES-114 4.55e7 ES-123 4.35e7 35.09 4.41e7 34.62 34.34 36.0 ES-105 4.57e7 35.63 0.00e0 RT Abs. Int. 1.15e7 5.75e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.25e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5209, 8874 scc: 980-763 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:38 (CEM) Printed: 06-Apr-2014 17:25 Page 11 of 21 242 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 Abs. Int. 5.66e6 PCB-126 2.40e7 38.26 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PBM 4σ 3.52e3 2.83e6 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 Abs. Int. 9.01e6 PCB-126 3.73e7 38.26 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PBM 4σ 3.55e3 4.51e6 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 7.45e6 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 4.87e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 9.75e6 ES-126 4.00e7 38.24 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PBM 4σ 5.60e3 0% 38.0 0.00e0 RT Abs. Int. 1.49e7 ES-126 6.16e7 38.24 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PBM 4σ 6.50e3 Rel. Int. 100% 0.00e0 RT 7.16e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3440, 1215 scc: 980-763 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:35 (CEM) Printed: 06-Apr-2014 17:25 Page 12 of 21 243 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Rel. Int. 100% PCB-155 PCB-150 4.02e7 3.80e7 30.53 30.23 HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 6.04e2 PCB-145 3.56e7 31.11 PCB-148 2.64e7 32.38 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 163/138… 8.18e7 147/149 139/140 37.31 153/168 5.32e7 5.45e7 6.79e7 33.67 34.19 36.25 PCB-164 PCB-160 151/135PCB-144 PCB-146 PCB-141 3.34e7 3.41e7 5.12e7 2.68e7 PCB-143 PCB-142 PCB-133 2.76e7 37.02 37.44 2.58e7 2.60e7 2.27e7 2.51e7 32.90 33.37 35.70 36.39 33.93 35.15 34.51 0% 28.0 30.0 PCB-152 2.93e7 30.39 PCB-155 PCB-150 3.22e7 2.99e7 30.53 30.23 Rel. Int. 100% HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 6.02e2 32.0 PCB-145 2.82e7 31.11 PCB-148 2.10e7 32.38 34.0 147/149 139/140 151/135 4.18e7 4.32e7 4.07e7 33.67 34.19 32.90 PCB-154 PCB-143 2.38e7 PCB-132 2.06e7 33.10 1.87e7 33.93 34.75 PCB-165 2.58e7 35.49 163/138… 6.53e7 37.31 PCB-141 PCB-137 2.03e7 2.33e7 36.94 36.39 30.0 32.0 34.0 ES-155 6.90e7 30.21 Rel. Int. 100% HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PBM 4σ 1.64e3 6.17e6 0.00e0 RT 36.0 ES-153 4.98e7 36.20 Abs. Int. 1.23e7 PCB-158 2.99e7 37.63 0% 28.0 7.82e6 0.00e0 RT 36.0 153/168 5.38e7 36.25 Abs. Int. 1.56e7 JS-138 4.59e7 37.27 Abs. Int. 1.73e7 8.63e6 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 ES-155 5.41e7 30.21 Rel. Int. 100% ES-153 3.83e7 36.20 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PBM 4σ 1.73e3 Abs. Int. 1.36e7 JS-138 3.56e7 37.27 6.82e6 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.25e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6239, 4488 scc: 980-763 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:36 (CEM) Printed: 06-Apr-2014 17:25 Page 13 of 21 244 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% 128/166 5.18e7 38.36 PCB-159 3.14e7 39.17 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 4.02e3 0% 38.0 Rel. Int. 100% HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 4.17e3 0% 38.0 PCB-162 PCB-159 2.59e7 2.59e7 39.41 39.17 39.0 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 156/157 6.21e7 40.80 Abs. Int. 1.19e7 PCB-169 2.99e7 43.51 PCB-167 3.36e7 39.82 40.0 128/166 4.25e7 38.36 5.95e6 41.0 42.0 43.0 44.0 156/157 5.08e7 40.80 40.0 PCB-169 2.42e7 43.51 4.91e6 41.0 42.0 43.0 44.0 ES-156/157 1.16e8 40.78 0.00e0 RT Abs. Int. 2.08e7 ES-169 5.46e7 43.50 1.04e7 39.0 Rel. Int. 100% 40.0 ES-167 4.74e7 39.80 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PBM 4σ 5.86e3 41.0 42.0 43.0 44.0 ES-156/157 9.07e7 40.78 0.00e0 RT Abs. Int. 1.60e7 ES-169 4.32e7 43.50 8.01e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 9.82e6 PCB-167 2.79e7 39.82 ES-167 6.08e7 39.80 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PBM 4σ 7.35e3 0% 38.0 PCB-162 3.15e7 39.41 39.0 Rel. Int. 100% 0% 38.0 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 7.16e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6766, 9221 scc: 980-763 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:36 (CEM) Printed: 06-Apr-2014 17:26 Page 14 of 21 245 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 PCB-188 PCB-179 2.54e7 2.70e7 35.39 35.10 Rel. Int. 100% PCB-184 2.49e7 35.84 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 6.97e2 0% 30.0 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 PCB-188 2.54e7 35.10 36.0 PCB-179 2.38e7 35.39 PCB-176 2.54e7 36.14 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 5.50e2 0% 30.0 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 6.86e6 PCB-186 2.57e7 36.54 PCB-178 1.82e7 37.66 Abs. Int. 6.36e6 PCB-186 2.41e7 36.54 PCB-178 1.69e7 37.66 Abs. Int. 1.21e7 CS/SS-178 2.93e7 37.64 31.0 32.0 33.0 34.0 35.0 36.0 Abs. Int. 1.13e7 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PBM 4σ 1.69e3 0% 30.0 CS/SS-178 2.73e7 37.64 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 5.63e6 0.00e0 RT Abs. Int. 2.50e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 6.07e6 0.00e0 RT 37.0 ES-188 4.42e7 35.08 Rel. Int. 100% 3.18e6 0.00e0 RT 37.0 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PBM 4σ 1.79e3 0% 30.0 0.00e0 RT 37.0 ES-188 4.77e7 35.08 Rel. Int. 100% 3.43e6 1.25e7 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1222, 4325 scc: 980-763 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:00 Printed: 06-Apr-2014 17:26 Page 15 of 21 246 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 5.17e3 PCB-175 2.21e7 38.21 0% 38.0 Rel. Int. 100% HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 4.59e3 0% 38.0 PCB-183 2.55e7 38.96 PCB-182 PCB-185 2.40e7 2.07e7 38.61 39.05 39.0 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 180/193 5.07e7 41.93 171/173 3.88e7 PCB-181 40.06 PCB-177 2.22e7 39.87 1.89e7 39.53 40.0 PCB-172 2.01e7 41.41 41.0 PCB-182 PCB-185 1.97e7 2.27e7 171/173 39.05 38.61 3.69e7 PCB-183 PCB-187 PCB-181 40.06 2.44e7 2.21e7 PCB-174 PCB-177 2.11e7 38.961.88e7 38.43 1.81e7 39.87 39.15 39.53 39.0 40.0 42.0 180/193 4.84e7 41.93 PCB-172 1.91e7 41.41 41.0 42.0 ES-180 4.17e7 41.94 Rel. Int. 100% HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PBM 4σ 3.26e3 0% 38.0 PCB-170 1.94e7 43.03 4.40e6 43.0 PCB-191 2.69e7 42.26 PCB-170 1.83e7 43.03 43.0 Abs. Int. 8.80e6 PCB-190 2.75e7 43.48 44.0 39.0 40.0 41.0 42.0 ES-180 3.89e7 41.94 HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PBM 4σ 5.12e3 Abs. Int. 8.34e6 PCB-190 2.63e7 43.48 4.17e6 44.0 0.00e0 RT Abs. Int. 1.02e7 ES-170 3.56e7 43.01 43.0 44.0 0.00e0 RT Abs. Int. 9.69e6 ES-170 3.25e7 43.01 4.85e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT 5.12e6 Rel. Int. 100% 0% 38.0 PCB-191 2.85e7 42.26 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 7.16e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9102, 6439 scc: 980-763 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:37 (CEM) Printed: 06-Apr-2014 17:26 Page 16 of 21 247 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 PCB-189 2.81e7 45.64 Rel. Int. 100% Abs. Int. 6.74e6 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PBM 4σ 2.48e3 3.37e6 0% 45.0 46.0 47.0 48.0 49.0 PCB-189 2.63e7 45.64 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.34e6 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PBM 4σ 1.96e3 3.17e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 5.04e7 45.62 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.22e7 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PBM 4σ 3.32e3 6.12e6 0% 45.0 46.0 47.0 48.0 49.0 ES-189 4.88e7 45.62 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PBM 4σ 3.36e3 6.02e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.82e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5081, 7131 scc: 980-763 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 03:37 (CEM) Printed: 06-Apr-2014 17:26 Page 17 of 21 248 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-201 2.27e7 40.42 PCB-202 2.03e7 39.63 OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PBM 4σ 8.56e2 0% 38.0 PCB-197 2.38e7 41.18 PCB-200 2.10e7 41.28 198/199 3.01e7 43.59 Abs. Int. 5.69e6 PCB-196 1.58e7 44.17 39.0 40.0 41.0 PCB-201 2.51e7 40.42 PCB-202 2.25e7 39.63 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PBM 4σ 7.89e2 PCB-204 2.37e7 40.99 42.0 43.0 PCB-197 2.60e7 41.18 PCB-200 2.29e7 41.28 198/199 3.27e7 43.59 Abs. Int. 6.05e6 PCB-196 1.75e7 44.17 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 4.09e7 39.61 0.00e0 RT 5.08e6 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 4.48e7 39.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PBM 4σ 1.78e3 5.59e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.43e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 PCB-203 1.80e7 44.34 Abs. Int. 1.02e7 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PBM 4σ 1.94e3 0% 38.0 0.00e0 RT 44.0 3.02e6 Rel. Int. 100% 0% 38.0 PCB-203 1.62e7 44.34 2.85e6 Rel. Int. 100% 0% 38.0 PCB-204 2.17e7 40.99 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 7.16e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7969, 4755 scc: 980-763 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:00 Printed: 06-Apr-2014 17:26 Page 18 of 21 249 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 PCB-194 1.43e7 47.40 PCB-195 1.31e7 45.46 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PBM 4σ 1.78e3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 PCB-205 1.86e7 47.80 Abs. Int. 4.48e6 2.24e6 0% 45.0 Rel. Int. 100% 46.0 47.0 PCB-194 1.59e7 47.40 PCB-195 1.46e7 45.46 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PBM 4σ 1.77e3 48.0 49.0 PCB-205 2.06e7 47.80 0.00e0 RT Abs. Int. 4.94e6 2.47e6 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 2.87e7 47.38 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PBM 4σ 1.88e3 49.0 ES-205 3.62e7 47.78 0.00e0 RT Abs. Int. 8.54e6 4.27e6 0% 45.0 46.0 47.0 Rel. Int. 100% 48.0 JS-194 3.19e7 47.38 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PBM 4σ 2.84e3 49.0 ES-205 4.08e7 47.78 0.00e0 RT Abs. Int. 9.75e6 4.87e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.82e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0780, 6723 scc: 980-763 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:00 Printed: 06-Apr-2014 17:26 Page 19 of 21 250 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 PCB-208 1.94e7 45.26 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 PCB-207 2.03e7 46.04 PCB-206 1.32e7 49.26 NoCB 44.77-49.81 461.7245 Fn6 Flags: PBM 4σ 1.51e3 Abs. Int. 4.94e6 2.47e6 0% 45.0 46.0 PCB-208 2.49e7 45.25 Rel. Int. 100% 47.0 48.0 0.00e0 RT 49.0 PCB-207 2.60e7 46.04 PCB-206 1.70e7 49.26 NoCB 44.77-49.81 463.7216 Fn6 Flags: PBM 4σ 2.11e3 Abs. Int. 6.31e6 3.16e6 0.00e0 RT 0% 45.0 46.0 47.0 48.0 49.0 ES-208 3.61e7 45.23 Rel. Int. 100% ES-206 2.46e7 49.24 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PBM 4σ 1.99e3 Abs. Int. 8.62e6 4.31e6 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 ES-208 4.54e7 45.23 Rel. Int. 100% ES-206 3.07e7 49.24 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PBM 4σ 2.46e3 Abs. Int. 1.07e7 5.37e6 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.82e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1217, 9979 scc: 980-763 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:00 Printed: 06-Apr-2014 17:26 Page 20 of 21 251 of 603 SGS ID: CS3_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 3 Acq: 03-Apr-2014 22:09:02 User: LKB Datafile: 140403X11 PCB-209 2.13e7 50.68 Rel. Int. 100% Abs. Int. 4.69e6 DeCB 49.82-52.00 497.6826 Fn7 Flags: PBM 4σ 6.86e2 (2.13e7 + 1.81e7) * 100 pg/ul = 1.07 (4.02e7 + 3.37e7) * 50 pg/ul CEM 06-Apr-2014 16:25 RRF (PCB-209) = 2.35e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.81e7 50.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.00e6 DeCB 49.82-52.00 499.6797 Fn7 Flags: PBM 4σ 6.09e2 2.00e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 4.02e7 50.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.82e6 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PBM 4σ 1.05e3 4.41e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.37e7 50.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.44e6 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PBM 4σ 9.50e2 3.72e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.48e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 2.74e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\CS3_140403_PCB_XC.utp_res, saved 06-Apr-2014 16:29 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0096, 4750 scc: 980-763 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 03:00 Printed: 06-Apr-2014 17:26 Page 21 of 21 252 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 3.77e7 1.88e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 3.51e7 1.75e7 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 2.48e7 1.24e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 1.51e7 7.55e6 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 7.57e6 3.79e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.92e6 2.96e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 5.84e6 2.92e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 542-620 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:21 Page 1 of 21 253 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 5.97e3 MoCB 10.03-15.71 188.0393 Fn1 Flags: PB 4σ 2.35e3 2.99e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.32e3 MoCB 10.03-15.71 190.0363 Fn1 Flags: PB 4σ 2.09e3 2.66e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.18e3 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PB 4σ 3.99e3 3.09e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e5 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PB 4σ 2.73e4 9.46e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.77e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.88e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1953, 7778 scc: 542-620 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:26 (CEM) Printed: 06-Apr-2014 17:21 Page 2 of 21 254 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 8.64e3 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PB 4σ 5.72e3 4.32e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.21e4 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PB 4σ 1.52e4 2.11e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.35e4 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PB 4σ 7.73e3 1.18e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.98e3 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PB 4σ 4.12e3 3.99e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.77e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.88e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4036, 1586 scc: 542-620 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:26 (CEM) Printed: 06-Apr-2014 17:21 Page 3 of 21 255 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 9.71e3 DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PB 4σ 7.54e3 4.85e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.11e5 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PB 4σ 2.66e4 5.56e4 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.19e5 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PB 4σ 1.78e4 5.94e4 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e4 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PB 4σ 4.96e3 6.97e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.51e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.75e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7512, 5965 scc: 542-620 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:21 Page 4 of 21 256 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 1.05e4 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PB 4σ 3.95e3 5.24e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.37e3 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PB 4σ 3.26e3 3.19e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e6 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PB 4σ 1.03e5 9.43e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.42e5 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PB 4σ 2.72e4 1.21e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.51e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.75e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6625, 5297 scc: 542-620 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:21 Page 5 of 21 257 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 PCB-36 7.41e5 24.77 Rel. Int. 100% Abs. Int. 1.98e5 TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 4.05e3 9.89e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-36 7.25e5 24.77 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.64e5 TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 2.85e3 8.19e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e6 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PB 4σ 1.28e5 8.01e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.42e5 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PB 4σ 2.22e4 2.71e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.48e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.24e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0310, 3441 scc: 542-620 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:21 Page 6 of 21 258 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 3.47e3 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PB 4σ 1.47e3 1.73e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.71e3 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PB 4σ 1.34e3 1.86e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.97e4 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PB 4σ 1.43e4 1.48e4 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.91e4 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PB 4σ 1.06e4 9.53e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.51e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.75e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0434, 5014 scc: 542-620 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:26 (CEM) Printed: 06-Apr-2014 17:21 Page 7 of 21 259 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 4.81e3 TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PB 4σ 1.69e3 2.40e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.47e3 TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PB 4σ 1.57e3 3.23e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.68e4 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PB 4σ 2.20e4 3.34e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.81e4 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PB 4σ 2.17e4 1.90e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.48e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.24e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1573, 3073 scc: 542-620 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:21 Page 8 of 21 260 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 5.39e5 27.14 PCB-79 4.87e5 31.35 TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 1.94e3 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Abs. Int. 1.36e5 PCB-78 4.73e5 31.84 6.79e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 6.60e5 27.14 32.0 PCB-79 6.52e5 31.35 TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 2.64e3 34.0 36.0 0.00e0 RT Abs. Int. 1.75e5 PCB-78 6.03e5 31.84 8.77e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.30e4 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PB 4σ 3.31e4 4.15e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.98e4 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PB 4σ 1.81e4 1.99e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 7.55e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3088, 3488 scc: 542-620 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:21 Page 9 of 21 261 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 PCB-96 2.89e5 25.62 Rel. Int. 100% Abs. Int. 7.33e4 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 9.65e2 3.67e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 4.52e5 25.62 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e5 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 7.12e2 5.71e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.55e3 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PB 4σ 2.91e3 4.27e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.93e3 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PB 4σ 1.58e3 4.97e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.48e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.24e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6854, 5018 scc: 542-620 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:26 (CEM) Printed: 06-Apr-2014 17:21 Page 10 of 21 262 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 1.01e3 PCB-98 2.39e5 28.27 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 3.36e5 34.07 PCB-89 1.97e5 29.25 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Abs. Int. 8.36e4 PCB-106 3.16e5 34.50 4.18e4 0% 28.0 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 1.01e3 PCB-98 3.77e5 28.27 30.0 32.0 34.0 107/124 5.28e5 34.07 PCB-89 3.60e5 29.25 36.0 0.00e0 RT Abs. Int. 1.38e5 PCB-106 5.09e5 34.50 6.89e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.93e3 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PB 4σ 3.00e3 4.97e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.49e3 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PB 4σ 1.91e3 4.25e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 7.55e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0155, 9721 scc: 542-620 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:21 Page 11 of 21 263 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 4.55e3 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PB 4σ 1.00e3 0% 38.0 2.27e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 5.62e3 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PB 4σ 7.85e2 0% 38.0 2.81e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 4.18e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 3.63e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.57e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 7.26e3 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PB 4σ 3.87e3 0% 38.0 0.00e0 RT Abs. Int. 8.35e3 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PB 4σ 2.44e3 0% 38.0 0.00e0 RT 3.79e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1244, 8322 scc: 542-620 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:21 Page 12 of 21 264 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 PCB-152 4.86e5 30.41 Rel. Int. 100% Abs. Int. 1.19e5 HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 7.56e2 5.94e4 0% 28.0 30.0 32.0 34.0 36.0 PCB-152 3.88e5 30.41 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.08e5 HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 7.58e2 5.40e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e4 HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PB 4σ 1.30e3 5.92e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.06e3 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PB 4σ 1.55e3 3.53e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 7.55e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9887, 8454 scc: 542-620 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:21 Page 13 of 21 265 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 128/166 3.86e5 38.38 Abs. Int. 8.94e4 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 7.58e2 4.47e4 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 128/166 3.21e5 38.38 Abs. Int. 7.98e4 HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 7.62e2 0% 38.0 3.99e4 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 6.02e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 3.01e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.57e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 6.02e3 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PB 4σ 1.80e3 0% 38.0 0.00e0 RT Abs. Int. 1.20e4 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PB 4σ 1.65e3 0% 38.0 0.00e0 RT 3.79e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8463, 5456 scc: 542-620 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:21 Page 14 of 21 266 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 PCB-184 2.97e5 35.86 Rel. Int. 100% Abs. Int. 7.42e4 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 6.09e2 0% 30.0 3.71e4 31.0 32.0 33.0 34.0 35.0 36.0 37.0 PCB-184 2.68e5 35.86 Rel. Int. 100% Abs. Int. 6.50e4 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 6.56e2 0% 30.0 3.25e4 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 3.83e3 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 3.05e3 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.51e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 0.00e0 RT Abs. Int. 6.09e3 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PB 4σ 1.47e3 0% 30.0 0.00e0 RT Abs. Int. 7.66e3 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PB 4σ 1.23e3 0% 30.0 0.00e0 RT 7.54e6 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1228, 3596 scc: 542-620 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:26 (CEM) Printed: 06-Apr-2014 17:22 Page 15 of 21 267 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 PCB-182 3.05e5 38.63 Abs. Int. 8.54e4 HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 1.06e3 4.27e4 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 PCB-182 2.97e5 38.63 Abs. Int. 7.22e4 HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 8.95e2 0% 38.0 3.61e4 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 2.83e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 2.11e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.57e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 4.22e3 HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PB 4σ 2.05e3 0% 38.0 0.00e0 RT Abs. Int. 5.65e3 HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PB 4σ 1.24e3 0% 38.0 0.00e0 RT 3.79e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4395, 6318 scc: 542-620 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:22 Page 16 of 21 268 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 2.34e3 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PB 4σ 9.11e2 1.17e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e3 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PB 4σ 7.62e2 7.90e2 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.09e3 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PB 4σ 1.95e3 2.55e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.78e3 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PB 4σ 1.30e3 1.89e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.92e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.96e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2420, 3415 scc: 542-620 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:26 (CEM) Printed: 06-Apr-2014 17:22 Page 17 of 21 269 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 PCB-204 2.59e5 41.01 Rel. Int. 100% Abs. Int. 6.35e4 OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PBM 4σ 5.61e2 0% 38.0 3.18e4 39.0 40.0 41.0 42.0 43.0 44.0 PCB-204 2.81e5 41.02 Rel. Int. 100% Abs. Int. 7.37e4 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PBM 4σ 6.25e2 0% 38.0 3.68e4 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 1.94e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 1.59e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.57e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 3.18e3 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PB 4σ 1.45e3 0% 38.0 0.00e0 RT Abs. Int. 3.89e3 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PB 4σ 1.34e3 0% 38.0 0.00e0 RT 3.79e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5938, 4195 scc: 542-620 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:26 (CEM) Printed: 06-Apr-2014 17:22 Page 18 of 21 270 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 1.70e3 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PB 4σ 6.88e2 8.51e2 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.34e3 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PB 4σ 5.73e2 1.17e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.33e3 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PB 4σ 8.84e2 2.16e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.21e3 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PB 4σ 1.03e3 2.11e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.92e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.96e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5367, 0313 scc: 542-620 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 00:26 Printed: 06-Apr-2014 17:22 Page 19 of 21 271 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 2.08e3 NoCB 44.77-49.81 461.7245 Fn6 Flags: PB 4σ 1.00e3 1.04e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.71e3 NoCB 44.77-49.81 463.7216 Fn6 Flags: PB 4σ 1.88e3 2.35e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.27e3 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PB 4σ 1.23e3 1.63e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.39e3 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PB 4σ 8.79e2 2.70e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.92e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.96e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4787, 7846 scc: 542-620 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:26 (CEM) Printed: 06-Apr-2014 17:22 Page 20 of 21 272 of 603 SGS ID: SBS_140402_PCB_XA Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 02-Apr-2014 01:18:59 User: LKB Datafile: 140402X03 Rel. Int. 100% Abs. Int. 1.54e3 DeCB 49.82-52.00 497.6826 Fn7 Flags: PB 4σ 5.85e2 7.69e2 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.49e3 DeCB 49.82-52.00 499.6797 Fn7 Flags: PB 4σ 5.87e2 7.45e2 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.36e3 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PB 4σ 9.03e2 1.18e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.15e3 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PB 4σ 7.84e2 1.57e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.84e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 2.92e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140402_PCB_XA.utp_res, saved 05-Apr-2014 00:26 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0363, 7096 scc: 542-620 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:26 (CEM) Printed: 06-Apr-2014 17:22 Page 21 of 21 273 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 7.32e7 3.66e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 3.42e7 1.71e7 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 2.92e7 1.46e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 2.94e7 1.47e7 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 1.70e7 8.48e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 8.05e6 4.02e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 7.41e6 3.71e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 701-763 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:24 Page 1 of 21 274 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 1.11e4 MoCB 10.03-15.71 188.0393 Fn1 Flags: PB 4σ 2.27e3 5.54e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.42e3 MoCB 10.03-15.71 190.0363 Fn1 Flags: PB 4σ 2.34e3 3.71e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.10e4 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PB 4σ 5.26e3 1.05e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.38e4 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PB 4σ 2.43e4 2.69e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.32e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 3.66e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9281, 6727 scc: 701-763 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:24 Page 2 of 21 275 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 1.23e4 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PB 4σ 3.45e3 6.16e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.59e4 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PB 4σ 1.66e4 1.79e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.17e4 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PB 4σ 6.23e3 1.09e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.15e3 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PB 4σ 3.43e3 3.08e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.32e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 3.66e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0317, 0085 scc: 701-763 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:24 Page 3 of 21 276 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 1.50e4 DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PB 4σ 6.83e3 7.48e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.03e4 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PB 4σ 2.14e4 3.02e4 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.65e4 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PB 4σ 1.55e4 3.83e4 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.94e4 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PB 4σ 5.35e3 9.69e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.42e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.71e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4865, 1486 scc: 701-763 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:24 Page 4 of 21 277 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 9.28e3 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PB 4σ 3.47e3 4.64e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.07e3 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PB 4σ 3.61e3 3.53e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.49e6 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PB 4σ 6.13e4 2.24e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e5 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PB 4σ 2.49e4 2.62e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.42e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.71e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1459, 0911 scc: 701-763 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:24 Page 5 of 21 278 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 PCB-36 8.38e5 24.75 Rel. Int. 100% Abs. Int. 2.27e5 TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 3.46e3 1.14e5 0% 22.0 23.0 24.0 25.0 26.0 PCB-36 8.01e5 24.75 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e5 TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 3.28e3 9.76e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.12e6 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PB 4σ 6.50e4 1.06e6 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e5 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PB 4σ 2.72e4 1.29e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.92e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.46e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5025, 2081 scc: 701-763 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:24 Page 6 of 21 279 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 4.52e3 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PB 4σ 1.90e3 2.26e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.46e3 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PB 4σ 1.76e3 2.23e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.49e4 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PB 4σ 1.64e4 1.75e4 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e4 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PB 4σ 1.24e4 9.95e3 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.42e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.71e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1620, 0532 scc: 701-763 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:24 Page 7 of 21 280 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 59/62… 1.89e4 25.61 Rel. Int. 100% Abs. Int. 6.25e3 TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 2.09e3 3.12e3 0% 22.0 23.0 24.0 25.0 26.0 59/62… 2.74e4 25.62 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e4 TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 1.51e3 5.11e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.48e4 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PB 4σ 3.94e4 3.24e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.82e4 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PB 4σ 2.01e4 1.91e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.92e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.46e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7045, 1714 scc: 701-763 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:24 Page 8 of 21 281 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 5.69e5 27.12 PCB-79 5.81e5 31.33 TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 1.99e3 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Abs. Int. 1.52e5 PCB-78 5.18e5 31.82 7.58e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 7.37e5 27.12 32.0 PCB-79 7.20e5 31.33 TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 2.20e3 34.0 36.0 0.00e0 RT Abs. Int. 2.07e5 PCB-78 6.85e5 31.82 1.04e5 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e5 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PB 4σ 3.66e4 9.23e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.85e4 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PB 4σ 2.06e4 2.43e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.94e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.47e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7481, 2348 scc: 701-763 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:24 Page 9 of 21 282 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 PCB-96 3.57e5 25.61 Rel. Int. 100% Abs. Int. 9.10e4 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 1.10e3 4.55e4 0% 22.0 23.0 24.0 25.0 26.0 PCB-96 5.82e5 25.61 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e5 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 7.77e2 7.91e4 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.65e3 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PB 4σ 3.74e3 4.83e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.42e3 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PB 4σ 3.08e3 4.71e3 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.92e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.46e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6115, 5178 scc: 701-763 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:24 Page 10 of 21 283 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 1.08e3 PCB-98 2.90e5 28.26 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 3.92e5 34.05 PCB-89 2.76e5 29.23 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Abs. Int. 9.44e4 PCB-106 3.68e5 34.48 4.72e4 0% 28.0 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 9.30e2 PCB-98 4.83e5 28.26 30.0 32.0 34.0 107/124 6.48e5 34.05 PCB-89 4.36e5 29.23 36.0 0.00e0 RT Abs. Int. 1.68e5 PCB-106 6.02e5 34.48 8.40e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.76e4 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PB 4σ 4.34e3 8.81e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e4 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PB 4σ 3.37e3 5.36e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.94e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.47e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 5161, 1092 scc: 701-763 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:24 Page 11 of 21 284 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 4.63e3 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PB 4σ 8.85e2 0% 38.0 2.32e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% Abs. Int. 6.99e3 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PB 4σ 1.17e3 0% 38.0 3.50e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 8.10e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 1.24e4 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.70e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 2.47e4 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PB 4σ 4.07e3 0% 38.0 0.00e0 RT Abs. Int. 1.62e4 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PB 4σ 3.72e3 0% 38.0 0.00e0 RT 8.48e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2076, 7446 scc: 701-763 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:24 Page 12 of 21 285 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 PCB-152 6.24e5 30.39 Rel. Int. 100% Abs. Int. 1.59e5 HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 7.85e2 7.93e4 0% 28.0 30.0 32.0 34.0 36.0 PCB-152 4.78e5 30.39 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e5 HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 8.85e2 6.34e4 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e4 HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PB 4σ 1.24e3 5.90e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.71e3 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PB 4σ 1.63e3 3.85e3 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.94e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 1.47e7 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4157, 1473 scc: 701-763 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:24 Page 13 of 21 286 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 128/166 4.79e5 38.36 Abs. Int. 1.21e5 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 1.04e3 6.05e4 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 128/166 3.93e5 38.36 Abs. Int. 9.70e4 HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 8.89e2 0% 38.0 4.85e4 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 7.85e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 5.24e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.70e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 1.05e4 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: B 4σ 1.75e3 0% 38.0 0.00e0 RT Abs. Int. 1.57e4 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: B 4σ 1.26e3 0% 38.0 0.00e0 RT 8.48e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0290, 0997 scc: 701-763 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:24 Page 14 of 21 287 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 PCB-184 3.67e5 35.84 Rel. Int. 100% Abs. Int. 8.87e4 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 6.23e2 0% 30.0 4.44e4 31.0 32.0 33.0 34.0 35.0 36.0 37.0 PCB-184 3.56e5 35.84 Rel. Int. 100% Abs. Int. 8.84e4 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 6.40e2 0% 30.0 4.42e4 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 4.06e3 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 3.50e3 31.0 32.0 33.0 34.0 35.0 36.0 37.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.94e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 0.00e0 RT Abs. Int. 7.01e3 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PB 4σ 1.44e3 0% 30.0 0.00e0 RT Abs. Int. 8.12e3 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PB 4σ 1.21e3 0% 30.0 0.00e0 RT 1.47e7 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7037, 8436 scc: 701-763 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:24 Page 15 of 21 288 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 PCB-182 3.59e5 38.61 Abs. Int. 7.85e4 HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 1.28e3 3.92e4 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 PCB-182 3.62e5 38.61 Abs. Int. 8.55e4 HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 8.38e2 0% 38.0 4.28e4 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 7.33e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 6.59e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.70e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 1.32e4 HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PB 4σ 1.42e3 0% 38.0 0.00e0 RT Abs. Int. 1.47e4 HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PB 4σ 1.54e3 0% 38.0 0.00e0 RT 8.48e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7857, 6138 scc: 701-763 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:24 Page 16 of 21 289 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 4.94e3 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PB 4σ 7.70e2 2.47e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.77e3 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PB 4σ 8.81e2 1.88e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e4 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: B 4σ 1.41e3 5.11e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e4 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: B 4σ 1.27e3 5.03e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.05e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 4.02e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9738, 8298 scc: 701-763 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:24 Page 17 of 21 290 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 PCB-204 3.25e5 40.99 Rel. Int. 100% Abs. Int. 8.90e4 OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PBM 4σ 8.70e2 0% 38.0 4.45e4 39.0 40.0 41.0 42.0 43.0 44.0 PCB-204 3.56e5 40.99 Rel. Int. 100% Abs. Int. 8.79e4 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PBM 4σ 6.64e2 0% 38.0 4.39e4 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 2.60e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 3.28e3 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.70e7 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 6.56e3 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PB 4σ 1.07e3 0% 38.0 0.00e0 RT Abs. Int. 5.20e3 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PB 4σ 1.65e3 0% 38.0 0.00e0 RT 8.48e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2055, 0608 scc: 701-763 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:24 Page 18 of 21 291 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 3.00e3 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: B 4σ 6.88e2 1.50e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.05e3 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: B 4σ 7.33e2 2.02e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e4 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: B 4σ 9.22e2 5.70e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.22e3 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: B 4σ 8.08e2 2.61e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.05e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 4.02e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1822, 9873 scc: 701-763 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 02:22 (CEM) Printed: 06-Apr-2014 17:25 Page 19 of 21 292 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 2.69e3 NoCB 44.77-49.81 461.7245 Fn6 Flags: PB 4σ 9.59e2 1.34e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.76e3 NoCB 44.77-49.81 463.7216 Fn6 Flags: PB 4σ 1.71e3 2.38e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.92e3 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PB 4σ 8.83e2 1.96e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.05e3 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PB 4σ 9.35e2 3.03e3 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.05e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 4.02e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3042, 9438 scc: 701-763 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:25 Page 20 of 21 293 of 603 SGS ID: SBS_140403_PCB_XC Instr: [ILM] AutoSpec-Premier MM7 Sample ID: SIL 13-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 03-Apr-2014 16:27:17 User: LKB Datafile: 140403X05 Rel. Int. 100% Abs. Int. 5.45e3 DeCB 49.82-52.00 497.6826 Fn7 Flags: PB 4σ 5.83e2 2.72e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.92e3 DeCB 49.82-52.00 499.6797 Fn7 Flags: PB 4σ 6.00e2 1.96e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.40e3 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PB 4σ 1.02e3 3.20e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.74e3 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PB 4σ 8.45e2 3.37e3 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.41e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 3.71e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\SBS_140403_PCB_XC.utp_res, saved 05-Apr-2014 02:23 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3250, 4083 scc: 701-763 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: 05-Apr-2014 02:22 Printed: 06-Apr-2014 17:25 Page 21 of 21 Resolution Check Report Printed: 294 of 603 Page 1 of 5 MassLynx 4.1 SCN 881 Tuesday, April 01, 2014 23:29:09 Eastern Daylight Time M 180.9888 R 12570 M 204.9888 R 12628 180.9 M 218.9856 R 12376 204.9 1.00e0 x10 M 230.9856 R 12107 218.9 1.00e0 x10 230.9 1.00e0 x10 1.00e0 x10 1.500 0.130 0.320 1.400 0.500 0.300 0.120 1.300 0.280 0.110 0.450 1.200 0.260 0.100 1.100 0.400 0.240 1.000 0.090 0.220 0.900 0.080 0.200 0.800 0.070 0.350 0.300 0.180 0.160 0.700 0.250 0.060 0.140 0.600 0.050 0.200 0.120 0.500 0.100 0.040 0.150 0.400 0.080 0.030 0.300 0.100 0.060 0.020 0.200 0.040 0.050 0.010 0.100 -0.000 0.020 -0.000 180.88 180.89 180.90 180.91 204.86 M 242.9856 R 11709 204.87 204.88 -0.000 218.84 204.89 M 218.9856 R 11550 242.8 -0.000 218.85 218.86 x10 218.88 230.83 M 230.9856 R 11743 218.9 1.00e0 218.87 230.84 230.85 x10 230.87 M 242.9856 R 11796 230.9 1.00e0 230.86 242.9 1.00e0 x10 1.00e0 x10 0.280 0.260 0.320 0.260 0.500 0.240 0.300 0.240 0.280 0.220 0.450 0.220 0.260 0.200 0.400 0.200 0.240 0.180 0.220 0.160 0.350 0.180 0.200 0.160 0.300 0.180 0.140 0.140 0.160 0.250 0.120 0.120 0.140 0.100 0.200 0.120 0.080 0.100 0.100 0.080 0.150 0.080 0.060 0.060 0.100 0.060 0.040 0.040 0.040 0.050 0.020 0.020 0.020 -0.000 242.82 -0.000 242.83 242.84 242.85 -0.000 242.86 218.87 M 254.9856 R 11574 218.88 218.89 218.90 230.86 M 268.9824 R 10894 254.9 -0.000 230.87 x10 230.89 230.90 242.85 M 280.9824 R 11186 268.8 1.00e0 230.88 242.86 x10 242.88 242.89 M 292.9824 R 11312 280.8 1.00e0 242.87 292.8 1.00e0 x10 1.00e0 x10 0.100 0.190 0.160 0.095 0.180 0.220 0.150 0.090 0.170 0.140 0.200 0.085 0.160 0.080 0.130 0.150 0.180 0.075 0.120 0.140 0.070 0.160 0.130 0.110 0.065 0.120 0.060 0.100 0.140 0.110 0.090 0.055 0.100 0.120 0.050 0.090 0.080 0.045 0.070 0.100 0.080 0.040 0.070 0.060 0.035 0.060 0.030 0.050 0.025 0.040 0.020 0.080 0.050 0.060 0.040 0.030 0.040 0.030 0.015 0.020 0.010 0.010 0.005 0.020 -0.000 0.020 0.010 -0.000 254.84 254.85 254.86 254.87 254.88 -0.000 268.83 268.84 268.85 268.86 268.87 -0.000 280.82 280.83 280.84 280.85 280.86 292.81 292.82 292.83 292.84 292.85 292.86 Resolution Check Report Printed: 295 of 603 Page 2 of 5 MassLynx 4.1 SCN 881 Tuesday, April 01, 2014 23:29:09 Eastern Daylight Time M 304.9824 R 10845 M 242.9856 R 11662 304.8 M 254.9856 R 12051 242.9 1.00e0 x10 M 268.9824 R 11723 254.9 1.00e0 x10 268.9 1.00e0 x10 1.00e0 x10 0.100 0.300 0.200 0.095 0.110 0.280 0.090 0.180 0.100 0.085 0.260 0.080 0.240 0.090 0.160 0.075 0.220 0.070 0.080 0.140 0.065 0.200 0.070 0.060 0.180 0.120 0.055 0.160 0.060 0.050 0.100 0.140 0.045 0.050 0.120 0.040 0.080 0.035 0.040 0.100 0.030 0.060 0.080 0.030 0.025 0.060 0.020 0.040 0.020 0.015 0.040 0.010 0.020 0.010 -0.000 -0.000 0.020 -0.000 0.005 -0.000 304.80 304.81 304.82 304.83 304.84 304.85 242.87 M 280.9824 R 11415 242.88 242.89 242.90 254.86 M 292.9824 R 11526 280.9 254.87 x10 254.89 254.90 268.84 M 304.9824 R 11764 292.8 1.00e0 254.88 268.85 268.86 x10 268.88 268.89 M 316.9824 R 11694 304.8 1.00e0 268.87 316.8 1.00e0 x10 0.180 1.00e0 x10 0.075 0.240 0.140 0.170 0.070 0.220 0.160 0.130 0.150 0.120 0.065 0.200 0.060 0.140 0.180 0.110 0.055 0.130 0.100 0.120 0.160 0.140 0.050 0.110 0.090 0.100 0.080 0.045 0.040 0.090 0.120 0.070 0.035 0.080 0.060 0.100 0.030 0.070 0.050 0.060 0.080 0.050 0.025 0.040 0.020 0.060 0.040 0.030 0.015 0.030 0.040 0.020 0.010 0.020 0.020 0.010 -0.000 -0.000 280.83 280.84 280.85 280.86 280.87 280.88 292.82 M 330.9792 R 10846 292.83 292.84 292.85 292.86 0.005 -0.000 292.87 304.81 M 342.9792 R 10869 330.8 0.010 -0.000 304.82 304.83 x10 304.85 304.86 x10 0.090 0.085 0.080 0.080 0.075 0.075 0.070 0.070 316.82 316.83 316.84 316.85 292.9 x10 1.00e0 x10 0.190 0.180 0.260 0.170 0.240 0.160 0.065 0.065 0.060 0.060 0.055 0.055 0.050 0.050 0.045 0.045 0.040 0.040 0.035 0.035 0.030 0.030 0.220 0.150 0.140 0.200 0.130 0.180 0.120 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 -0.000 0.160 330.80 330.81 330.82 330.83 330.84 330.85 0.110 0.100 0.140 0.090 0.120 0.080 0.070 0.100 0.060 0.080 0.050 0.060 0.040 0.030 0.040 0.020 0.020 0.010 -0.000 330.79 -0.000 342.79 342.80 342.81 342.82 342.83 342.84 342.85 -0.000 280.85 280.86 280.87 316.86 M 292.9824 R 12255 1.00e0 0.280 0.085 316.81 280.9 1.00e0 0.090 316.80 M 280.9824 R 11848 342.8 1.00e0 304.84 280.88 280.89 292.84 292.85 292.86 292.87 292.88 Resolution Check Report Printed: 296 of 603 Page 3 of 5 MassLynx 4.1 SCN 881 Tuesday, April 01, 2014 23:29:09 Eastern Daylight Time M 304.9824 R 12019 M 316.9824 R 12241 304.9 M 330.9792 R 11849 316.8 1.00e0 x10 0.160 0.070 0.150 0.065 M 342.9792 R 11365 330.8 1.00e0 x10 342.8 1.00e0 x10 x10 0.110 0.100 0.140 1.00e0 0.120 0.110 0.060 0.100 0.090 0.130 0.055 0.090 0.120 0.080 0.050 0.110 0.080 0.045 0.070 0.100 0.070 0.040 0.090 0.060 0.060 0.035 0.080 0.050 0.070 0.030 0.060 0.050 0.040 0.025 0.040 0.050 0.020 0.030 0.030 0.040 0.015 0.030 0.020 0.020 0.010 0.020 0.010 0.005 0.010 -0.000 -0.000 304.83 304.84 304.85 304.86 304.87 304.88 316.82 M 366.9792 R 12073 316.83 316.84 316.85 316.86 M 380.9760 R 11552 366.8 0.010 -0.000 330.80 316.87 330.81 330.82 330.83 x10 330.85 -0.000 342.79 330.86 M 392.9760 R 11312 380.8 1.00e0 330.84 342.80 342.81 342.82 x10 342.84 342.85 M 404.9760 R 11286 392.8 1.00e0 342.83 404.8 1.00e0 x10 0.055 1.00e0 x10 0.045 0.050 0.050 0.045 0.045 0.040 0.040 0.035 0.035 0.035 0.030 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.010 0.005 0.005 0.005 0.050 0.040 0.045 0.040 0.035 0.025 0.030 0.025 0.020 0.020 0.015 0.015 0.010 -0.000 366.77 -0.000 366.78 366.79 366.80 366.81 366.82 366.83 366.84 M 430.9728 R 11069 0.005 -0.000 380.76 380.77 380.78 380.79 380.80 380.81 380.82 392.76 M 316.9824 R 11443 430.8 -0.000 380.83 392.77 392.78 x10 392.80 392.81 392.82 392.83 M 330.9792 R 11062 316.8 1.00e0 392.79 404.76 404.77 404.78 x10 404.80 404.81 404.82 404.83 M 342.9792 R 11415 330.8 1.00e0 404.79 342.8 1.00e0 x10 1.00e0 0.110 0.130 0.100 0.120 x10 0.085 0.020 0.080 0.075 0.018 0.110 0.090 0.070 0.100 0.016 0.065 0.080 0.090 0.060 0.014 0.070 0.055 0.080 0.050 0.012 0.060 0.070 0.045 0.010 0.040 0.060 0.050 0.035 0.050 0.008 0.040 0.030 0.040 0.025 0.006 0.030 0.030 0.020 0.004 0.020 0.015 0.020 0.010 0.002 0.010 0.010 0.005 -0.000 -0.000 430.75 430.76 430.77 430.78 430.79 430.80 430.81 430.82 -0.000 316.81 316.82 316.83 316.84 316.85 316.86 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 330.85 342.78 342.79 342.80 342.81 342.82 342.83 342.84 Resolution Check Report Printed: 297 of 603 Page 4 of 5 MassLynx 4.1 SCN 881 Tuesday, April 01, 2014 23:29:09 Eastern Daylight Time M 366.9792 R 11062 M 380.9760 R 11261 366.8 M 392.9760 R 10940 380.8 1.00e0 x10 M 404.9760 R 11135 392.8 1.00e0 x10 404.8 1.00e0 x10 1.00e0 x10 0.060 0.065 0.055 0.055 0.050 0.050 0.045 0.045 0.055 0.060 0.050 0.055 0.040 0.040 0.035 0.035 0.030 0.030 0.050 0.045 0.045 0.040 0.040 0.035 0.035 0.030 0.030 0.025 0.025 0.025 0.025 0.020 0.020 0.020 0.020 0.015 0.015 0.015 0.015 0.010 0.010 0.010 0.010 0.005 0.005 -0.000 366.76 366.77 366.78 366.79 366.80 366.81 -0.000 380.74 366.82 M 430.9728 R 11451 0.005 0.005 380.75 380.76 380.77 380.78 380.79 380.80 -0.000 392.73 380.81 M 442.9728 R 11338 430.7 -0.000 392.74 392.75 392.76 x10 392.78 392.79 392.80 404.72 M 380.9760 R 11358 442.7 1.00e0 392.77 x10 0.030 0.024 0.028 404.76 404.77 404.78 404.79 392.8 x10 1.00e0 x10 0.070 0.060 0.065 0.055 0.060 0.050 0.055 0.026 0.022 404.75 M 392.9760 R 11261 1.00e0 0.032 0.026 404.74 380.8 1.00e0 0.065 0.028 404.73 0.024 0.020 0.050 0.045 0.022 0.045 0.018 0.016 0.014 0.020 0.040 0.018 0.035 0.040 0.035 0.016 0.030 0.014 0.012 0.030 0.025 0.012 0.010 0.025 0.020 0.010 0.020 0.008 0.008 0.015 0.015 0.006 0.006 0.010 0.004 0.010 0.004 0.002 0.002 -0.000 -0.000 442.69 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 430.78 M 404.9760 R 11261 442.70 442.71 442.72 442.73 442.74 442.75 442.76 0.005 -0.000 -0.000 442.77 380.73 M 430.9728 R 11396 404.7 0.005 380.74 380.75 380.76 x10 380.78 380.79 380.80 392.72 M 442.9728 R 12026 430.7 1.00e0 380.77 392.73 392.74 392.75 x10 392.77 392.78 392.79 M 454.9728 R 11682 442.7 1.00e0 392.76 454.7 1.00e0 x10 1.00e0 x10 0.075 0.028 0.036 0.026 0.034 0.070 0.065 0.045 0.032 0.040 0.024 0.030 0.060 0.022 0.028 0.035 0.055 0.026 0.020 0.050 0.024 0.018 0.045 0.030 0.022 0.016 0.020 0.040 0.014 0.025 0.018 0.035 0.016 0.012 0.020 0.030 0.014 0.010 0.025 0.012 0.008 0.010 0.015 0.006 0.008 0.010 0.004 0.020 0.015 0.010 0.006 0.004 0.002 0.005 -0.000 404.72 404.73 404.74 404.75 404.76 404.77 404.78 0.005 0.002 -0.000 404.71 -0.000 430.68 430.69 430.70 430.71 430.72 430.73 430.74 430.75 430.76 -0.000 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 442.75 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 454.74 Resolution Check Report Printed: 298 of 603 Page 5 of 5 MassLynx 4.1 SCN 881 Tuesday, April 01, 2014 23:29:09 Eastern Daylight Time M 466.9728 R 11764 M 480.9696 R 11737 466.7 M 430.9728 R 11293 480.7 1.00e0 x10 M 442.9728 R 11796 430.7 1.00e0 x10 442.7 1.00e0 0.018 0.038 0.017 0.036 x10 0.026 0.024 0.016 0.022 0.015 1.00e0 x10 0.045 0.034 0.040 0.032 0.030 0.014 0.020 0.035 0.028 0.013 0.026 0.018 0.012 0.030 0.024 0.011 0.016 0.022 0.010 0.025 0.020 0.014 0.009 0.018 0.012 0.008 0.020 0.016 0.007 0.010 0.014 0.006 0.015 0.012 0.008 0.005 0.006 0.010 0.004 0.004 0.002 0.003 0.006 0.002 0.004 0.001 -0.000 466.66 466.67 466.68 466.69 466.70 466.71 466.72 466.73 -0.000 480.63 M 454.9728 R 11805 0.005 0.002 -0.000 466.65 0.010 0.008 480.64 480.65 480.66 480.67 480.68 480.69 480.70 480.71 M 466.9728 R 11907 454.7 -0.000 480.72 430.71 430.72 430.73 430.74 x10 430.76 430.77 430.78 442.69 M 480.9696 R 11975 466.7 1.00e0 0.050 430.75 442.70 442.71 442.72 442.73 x10 442.75 442.76 442.77 M 492.9696 R 12168 480.7 1.00e0 442.74 492.7 1.00e0 x10 1.00e0 x10 0.019 0.028 0.022 0.018 0.026 0.045 0.017 0.020 0.024 0.016 0.040 0.015 0.022 0.018 0.014 0.020 0.035 0.016 0.013 0.018 0.012 0.014 0.030 0.011 0.016 0.010 0.025 0.012 0.014 0.009 0.012 0.010 0.008 0.020 0.007 0.010 0.008 0.006 0.015 0.008 0.005 0.006 0.010 0.006 0.004 0.004 0.003 0.004 0.002 0.005 0.002 -0.000 -0.000 454.68 454.69 454.70 454.71 454.72 454.73 454.74 454.75 454.76 466.67 M 504.9696 R 11439 466.68 466.69 466.70 466.71 466.72 466.73 466.74 516.7 x10 1.00e0 x10 0.017 0.028 0.016 0.026 0.015 0.024 0.014 0.022 0.013 0.020 0.012 0.011 0.018 0.010 0.016 0.009 0.014 0.008 0.012 0.007 0.010 0.006 0.005 0.008 0.004 0.006 0.003 0.004 0.002 0.002 0.001 -0.000 -0.000 504.63 504.64 504.65 504.66 504.67 504.68 -0.000 480.65 466.75 M 516.9697 R 13426 504.7 1.00e0 504.69 504.70 504.71 504.72 0.002 0.001 516.62 516.63 516.64 516.65 516.66 516.67 516.68 516.69 516.70 -0.000 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 480.74 492.64 492.65 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 Resolution Check Report Printed: 299 of 603 Page 1 of 5 MassLynx 4.1 SCN 881 Wednesday, April 02, 2014 09:47:36 Eastern Daylight Time M 180.9888 R 12794 M 204.9888 R 13163 180.9 M 218.9856 R 12469 204.9 1.00e0 x10 M 230.9856 R 12376 218.9 1.00e0 x10 230.9 1.00e0 x10 1.00e0 x10 0.100 1.300 0.475 0.300 0.095 0.450 1.200 0.090 0.280 0.425 0.085 1.100 0.260 0.400 0.080 1.000 0.240 0.075 0.900 0.800 0.070 0.220 0.065 0.200 0.375 0.350 0.325 0.300 0.060 0.180 0.275 0.055 0.700 0.160 0.050 0.600 0.045 0.250 0.225 0.140 0.200 0.040 0.120 0.500 0.175 0.035 0.100 0.400 0.150 0.030 0.025 0.080 0.020 0.060 0.125 0.300 0.200 0.100 0.075 0.015 0.040 0.050 0.010 0.100 0.020 0.005 -0.000 -0.000 180.88 180.89 180.90 204.86 M 242.9856 R 12481 0.025 -0.000 180.91 204.87 204.88 204.89 M 218.9856 R 12224 242.8 -0.000 218.84 218.85 218.86 x10 218.88 230.83 M 230.9856 R 12142 218.9 1.00e0 218.87 230.84 230.85 x10 230.87 M 242.9856 R 11684 230.9 1.00e0 0.300 230.86 242.9 1.00e0 x10 1.00e0 x10 0.475 0.220 0.220 0.450 0.280 0.425 0.200 0.200 0.260 0.400 0.240 0.180 0.180 0.375 0.350 0.220 0.160 0.160 0.325 0.200 0.300 0.140 0.140 0.180 0.275 0.120 0.160 0.250 0.140 0.225 0.120 0.100 0.100 0.200 0.120 0.175 0.080 0.080 0.100 0.150 0.080 0.060 0.125 0.060 0.100 0.060 0.040 0.040 0.075 0.040 0.050 0.020 0.020 -0.000 -0.000 242.82 242.83 242.84 242.85 -0.000 242.86 218.87 M 254.9856 R 12383 0.020 0.025 218.88 218.89 230.86 M 268.9824 R 12037 254.9 -0.000 218.90 230.87 x10 0.140 0.085 230.90 242.85 242.86 x10 242.87 242.88 242.89 M 292.9824 R 11767 280.8 1.00e0 0.090 230.89 M 280.9824 R 11467 268.8 1.00e0 0.150 230.88 292.8 1.00e0 x10 1.00e0 x10 0.130 0.200 0.120 0.080 0.130 0.180 0.075 0.110 0.120 0.070 0.160 0.110 0.100 0.065 0.100 0.060 0.090 0.055 0.090 0.140 0.080 0.120 0.050 0.080 0.070 0.045 0.100 0.070 0.060 0.040 0.060 0.035 0.050 0.030 0.040 0.025 0.080 0.050 0.040 0.060 0.030 0.020 0.030 0.040 0.015 0.020 0.020 0.010 0.020 0.010 0.010 0.005 -0.000 -0.000 254.84 254.85 254.86 254.87 254.88 268.83 268.84 268.85 268.86 268.87 -0.000 280.81 -0.000 280.82 280.83 280.84 280.85 280.86 292.81 292.82 292.83 292.84 292.85 292.86 Resolution Check Report Printed: 300 of 603 Page 2 of 5 MassLynx 4.1 SCN 881 Wednesday, April 02, 2014 09:47:36 Eastern Daylight Time M 304.9824 R 11852 M 242.9856 R 11991 304.8 M 254.9856 R 11995 242.9 1.00e0 x10 M 268.9824 R 11798 254.9 1.00e0 x10 268.9 1.00e0 x10 1.00e0 x10 0.095 0.150 0.090 0.090 0.240 0.140 0.085 0.085 0.080 0.075 0.220 0.130 0.200 0.120 0.080 0.075 0.070 0.070 0.110 0.180 0.065 0.065 0.100 0.060 0.060 0.160 0.090 0.055 0.055 0.140 0.050 0.080 0.045 0.120 0.070 0.100 0.060 0.050 0.045 0.040 0.040 0.035 0.035 0.030 0.050 0.080 0.025 0.030 0.040 0.025 0.060 0.020 0.020 0.030 0.015 0.040 0.015 0.020 0.010 0.010 0.020 0.010 0.005 -0.000 -0.000 304.80 304.81 304.82 304.83 304.84 304.85 M 280.9824 R 11849 0.005 -0.000 242.86 242.87 242.88 242.89 242.90 M 292.9824 R 11765 280.9 -0.000 254.85 254.86 254.87 x10 254.89 268.84 M 304.9824 R 11682 292.8 1.00e0 254.88 268.85 268.86 x10 268.88 M 316.9824 R 11879 304.8 1.00e0 268.87 316.8 1.00e0 x10 1.00e0 x10 0.065 0.220 0.120 0.150 0.060 0.200 0.110 0.140 0.055 0.130 0.100 0.180 0.050 0.120 0.090 0.160 0.110 0.045 0.080 0.100 0.140 0.040 0.090 0.070 0.120 0.035 0.080 0.060 0.100 0.030 0.070 0.050 0.025 0.060 0.080 0.040 0.050 0.060 0.020 0.040 0.030 0.015 0.030 0.040 0.020 0.010 0.020 0.020 0.010 0.005 -0.000 -0.000 0.010 -0.000 -0.000 280.83 280.84 280.85 280.86 280.87 280.88 292.82 M 330.9792 R 11821 292.83 292.84 292.85 292.86 292.87 304.81 M 342.9792 R 11825 330.8 304.82 304.83 x10 304.85 304.86 316.80 M 280.9824 R 12195 342.8 1.00e0 304.84 316.81 316.82 x10 316.84 316.85 292.9 1.00e0 x10 1.00e0 x10 0.085 0.240 0.075 0.160 0.080 0.070 0.150 0.220 0.075 0.065 0.070 0.140 0.200 0.130 0.060 0.065 0.180 0.060 0.055 0.055 0.050 0.050 0.045 0.120 0.110 0.160 0.100 0.140 0.090 0.045 0.040 0.120 0.040 0.080 0.035 0.035 0.070 0.100 0.030 0.060 0.030 0.080 0.025 0.050 0.025 0.020 0.060 0.020 0.040 0.015 0.015 0.030 0.040 0.010 0.010 0.020 0.020 0.005 0.005 -0.000 0.010 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 -0.000 342.79 342.80 342.81 342.82 342.83 342.84 -0.000 280.85 280.86 280.87 316.86 M 292.9824 R 12257 280.9 1.00e0 316.83 280.88 280.89 292.84 292.85 292.86 292.87 292.88 Resolution Check Report Printed: 301 of 603 Page 3 of 5 MassLynx 4.1 SCN 881 Wednesday, April 02, 2014 09:47:36 Eastern Daylight Time M 304.9824 R 12322 M 316.9824 R 12412 304.9 M 330.9792 R 11655 316.8 1.00e0 x10 M 342.9792 R 11655 330.8 1.00e0 x10 342.8 1.00e0 x10 1.00e0 x10 0.110 0.100 0.140 0.055 0.100 0.130 0.090 0.050 0.090 0.120 0.045 0.080 0.110 0.080 0.040 0.100 0.070 0.070 0.090 0.035 0.060 0.060 0.080 0.030 0.050 0.070 0.050 0.025 0.060 0.040 0.040 0.020 0.050 0.040 0.030 0.030 0.015 0.030 0.020 0.020 0.010 0.020 0.010 0.010 0.005 0.010 -0.000 -0.000 304.83 304.84 304.85 304.86 304.87 -0.000 304.88 316.82 M 366.9792 R 12378 316.83 316.84 316.85 316.86 316.87 M 380.9760 R 11968 366.8 -0.000 330.80 330.81 330.82 330.83 x10 330.85 330.86 342.79 M 392.9760 R 11825 380.8 1.00e0 330.84 342.80 342.81 342.82 x10 342.84 342.85 M 404.9760 R 11493 392.8 1.00e0 342.83 404.8 1.00e0 x10 1.00e0 x10 0.050 0.040 0.045 0.045 0.040 0.040 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.020 0.015 0.015 0.015 0.010 0.010 0.010 0.045 0.035 0.040 0.030 0.035 0.030 0.025 0.025 0.020 0.015 0.010 0.005 0.005 0.005 0.005 -0.000 366.77 -0.000 -0.000 366.78 366.79 366.80 366.81 366.82 366.83 366.84 380.76 M 430.9728 R 10972 380.77 380.78 380.79 380.80 380.81 380.82 380.83 M 316.9824 R 12406 430.8 -0.000 392.76 392.77 392.78 x10 392.80 392.81 392.82 392.83 M 330.9792 R 11421 316.8 1.00e0 392.79 404.76 404.77 404.78 x10 404.80 404.81 404.82 404.83 M 342.9792 R 11659 330.8 1.00e0 404.79 342.8 1.00e0 x10 1.00e0 x10 0.110 0.075 0.019 0.110 0.070 0.100 0.018 0.017 0.065 0.016 0.060 0.100 0.090 0.090 0.015 0.055 0.080 0.014 0.080 0.050 0.013 0.070 0.012 0.070 0.045 0.011 0.060 0.040 0.060 0.010 0.035 0.009 0.050 0.050 0.008 0.030 0.040 0.007 0.040 0.025 0.006 0.030 0.020 0.005 0.004 0.030 0.015 0.020 0.003 0.020 0.010 0.002 0.010 0.010 0.005 0.001 -0.000 -0.000 430.74 430.75 430.76 430.77 430.78 430.79 430.80 430.81 430.82 -0.000 316.80 316.81 316.82 316.83 316.84 316.85 316.86 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 330.85 342.78 342.79 342.80 342.81 342.82 342.83 342.84 Resolution Check Report Printed: 302 of 603 Page 4 of 5 MassLynx 4.1 SCN 881 Wednesday, April 02, 2014 09:47:36 Eastern Daylight Time M 366.9792 R 11363 M 380.9760 R 11683 366.8 M 392.9760 R 11746 380.8 1.00e0 x10 M 404.9760 R 11723 392.8 1.00e0 x10 404.8 1.00e0 x10 1.00e0 x10 0.050 0.045 0.050 0.050 0.040 0.045 0.045 0.035 0.040 0.040 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 0.045 0.040 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.005 -0.000 -0.000 366.76 366.77 366.78 366.79 366.80 366.81 366.82 0.005 -0.000 380.74 M 430.9728 R 11709 0.010 380.75 380.76 380.77 380.78 380.79 380.80 380.81 M 442.9728 R 11365 430.7 -0.000 392.73 392.74 392.75 392.76 392.77 x10 392.79 392.80 404.72 M 380.9760 R 12056 442.7 1.00e0 392.78 404.73 404.74 404.75 404.76 x10 404.78 404.79 M 392.9760 R 11907 380.8 1.00e0 404.77 392.8 1.00e0 x10 0.028 1.00e0 0.060 0.060 0.055 0.055 0.050 0.050 0.045 0.045 0.018 0.040 0.040 0.016 0.035 0.035 0.014 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 x10 0.022 0.026 0.020 0.024 0.018 0.022 0.020 0.016 0.014 0.012 0.010 0.012 0.010 0.008 0.008 0.006 0.006 0.004 0.004 0.002 -0.000 -0.000 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 -0.000 442.69 M 404.9760 R 12078 0.005 0.005 0.002 442.70 442.71 442.72 442.73 442.74 442.75 442.76 380.73 M 430.9728 R 11940 404.7 -0.000 442.77 380.74 380.75 380.76 x10 380.78 380.79 380.80 M 442.9728 R 12132 430.7 1.00e0 380.77 392.72 392.73 392.74 392.75 x10 0.026 392.77 392.78 392.79 M 454.9728 R 11709 442.7 1.00e0 392.76 454.7 1.00e0 x10 0.034 1.00e0 x10 0.040 0.065 0.032 0.024 0.060 0.030 0.035 0.022 0.028 0.055 0.020 0.026 0.018 0.024 0.050 0.030 0.045 0.022 0.016 0.025 0.040 0.020 0.014 0.018 0.035 0.020 0.016 0.012 0.030 0.014 0.010 0.025 0.015 0.012 0.008 0.020 0.015 0.006 0.010 0.004 0.005 0.002 0.010 0.010 0.008 0.006 0.005 0.004 -0.000 0.002 -0.000 404.71 404.72 404.73 404.74 404.75 404.76 404.77 404.78 -0.000 430.68 430.69 430.70 430.71 430.72 430.73 430.74 430.75 430.76 -0.000 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 442.75 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 454.74 Resolution Check Report Printed: 303 of 603 Page 5 of 5 MassLynx 4.1 SCN 881 Wednesday, April 02, 2014 09:47:36 Eastern Daylight Time M 466.9728 R 11821 M 480.9696 R 11961 466.7 M 430.9728 R 11683 480.7 1.00e0 x10 M 442.9728 R 12345 430.7 1.00e0 x10 442.7 1.00e0 x10 0.022 0.034 x10 0.036 0.016 0.032 0.034 0.030 0.032 0.028 0.030 0.026 0.028 0.024 0.026 0.015 0.020 1.00e0 0.038 0.017 0.014 0.018 0.013 0.012 0.016 0.011 0.024 0.022 0.014 0.010 0.022 0.020 0.009 0.012 0.020 0.018 0.018 0.008 0.016 0.010 0.016 0.007 0.014 0.014 0.006 0.008 0.012 0.012 0.005 0.010 0.006 0.010 0.004 0.004 0.008 0.003 0.006 0.002 0.004 0.001 0.002 0.008 0.006 0.004 0.002 -0.000 466.64 -0.000 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 480.63 M 454.9728 R 11908 0.002 -0.000 466.73 480.64 480.65 480.66 480.67 480.68 480.69 480.70 480.71 M 466.9728 R 12053 454.7 -0.000 430.70 430.71 430.72 430.73 430.74 x10 430.76 430.77 430.78 442.69 M 480.9696 R 12406 466.7 1.00e0 430.75 442.70 442.71 442.72 442.73 x10 442.75 442.76 442.77 M 492.9696 R 12859 480.7 1.00e0 492.7 1.00e0 x10 1.00e0 x10 0.022 0.016 0.028 442.74 0.045 0.015 0.026 0.020 0.014 0.040 0.024 0.018 0.013 0.022 0.035 0.012 0.016 0.020 0.011 0.030 0.018 0.014 0.010 0.016 0.009 0.014 0.008 0.012 0.025 0.010 0.020 0.007 0.012 0.006 0.008 0.010 0.015 0.005 0.008 0.006 0.004 0.010 0.006 0.003 0.004 0.004 0.002 0.005 0.002 0.002 -0.000 0.001 -0.000 454.68 454.69 454.70 454.71 454.72 454.73 454.74 454.75 -0.000 454.76 466.67 M 504.9696 R 12073 466.68 466.69 466.70 466.71 466.72 466.73 466.74 516.7 x10 1.00e0 x10 0.013 0.024 0.012 0.022 0.011 0.020 0.010 0.018 0.009 0.016 0.008 0.014 0.007 0.012 0.006 0.010 0.005 0.008 0.004 0.006 0.003 0.004 0.002 0.002 0.001 -0.000 -0.000 504.64 504.65 504.66 504.67 504.68 504.69 504.70 504.71 504.72 516.62 516.63 516.64 516.65 516.66 516.67 516.68 516.69 516.70 -0.000 480.65 M 516.9697 R 13192 504.7 1.00e0 504.63 466.75 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 480.74 492.64 492.65 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 Experiment Calibration Report 304 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 1 @ 200 (ppm) Printed: Thursday, April 03, 2014 12:54:24 Eastern Daylight Time M 180.9888 R 12820 M 204.9888 R 13808 242.8 M 218.9856 R 13019 180.9 1.00e0 x8 M 230.9856 R 12754 204.9 1.00e0 x8 218.9 1.00e0 x8 0.080 2.000 1.800 0.700 0.070 0.800 0.600 0.060 1.400 0.550 0.055 0.700 0.500 0.050 1.200 0.040 0.400 0.035 0.350 0.030 0.300 0.025 0.250 0.020 0.200 0.015 0.150 0.010 0.100 0.005 0.050 0.800 0.600 0.400 0.600 0.450 0.045 1.000 x8 0.900 0.650 0.065 1.600 1.00e0 1.000 0.750 0.075 0.500 0.400 0.300 0.200 0.200 0.100 -0.000 180.88 180.89 180.90 180.91 M 242.9856 R 12953 230.9 1.00e0 x8 0.300 0.280 0.260 0.240 0.220 0.200 0.180 0.160 0.140 0.120 0.100 0.080 0.060 0.040 0.020 -0.000 242.83 242.84 242.85 242.86 -0.000 204.86 204.87 204.88 204.89 -0.000 218.85 218.86 218.87 218.88 230.84 230.85 230.86 230.87 Experiment Calibration Report 305 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 2 @ 200 (ppm) Printed: Thursday, April 03, 2014 12:55:21 Eastern Daylight Time M 218.9856 R 12690 M 230.9856 R 12078 304.8 M 242.9856 R 12133 218.9 1.00e0 x8 M 254.9856 R 12137 230.9 1.00e0 x8 242.9 1.00e0 x8 1.00e0 x8 0.650 1.500 0.350 2.000 0.600 1.400 0.325 1.300 0.550 1.800 0.300 1.200 0.500 0.275 1.600 1.100 0.450 0.250 0.400 0.225 0.350 0.200 1.400 1.000 0.900 1.200 0.800 1.000 0.700 0.175 0.300 0.150 0.600 0.250 0.800 0.125 0.500 0.200 0.600 0.400 0.100 0.150 0.300 0.075 0.400 0.100 0.050 0.200 0.200 0.050 0.100 0.025 -0.000 218.87 218.88 218.89 218.90 218.91 M 268.9824 R 11792 230.86 230.87 230.88 230.89 230.90 242.85 M 280.9824 R 12132 254.9 242.86 242.87 x8 242.89 254.84 M 292.9824 R 11062 268.9 1.00e0 242.88 254.85 254.86 x8 254.88 M 304.9824 R 11159 280.8 1.00e0 254.87 292.8 1.00e0 x8 1.00e0 x8 0.340 0.650 0.550 0.320 1.100 0.600 0.300 0.500 1.000 0.550 0.280 0.450 0.260 0.900 0.500 0.240 0.400 0.450 0.800 0.400 0.700 0.220 0.350 0.350 0.200 0.180 0.300 0.600 0.160 0.300 0.250 0.500 0.140 0.250 0.120 0.200 0.400 0.200 0.100 0.300 0.150 0.200 0.100 0.100 0.050 0.080 0.150 0.100 0.060 0.040 0.050 0.020 -0.000 -0.000 268.83 268.84 268.85 268.86 268.87 -0.000 280.82 280.83 280.84 280.85 280.86 292.81 292.82 292.83 292.84 292.85 292.86 304.80 304.81 304.82 304.83 304.84 304.85 Experiment Calibration Report 306 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 3 @ 200 (ppm) Printed: Thursday, April 03, 2014 12:55:45 Eastern Daylight Time M 242.9856 R 12313 M 254.9856 R 12819 342.8 M 268.9824 R 11792 242.9 1.00e0 x8 M 280.9824 R 12199 254.9 1.00e0 x8 268.9 1.00e0 x8 1.00e0 x8 0.375 0.750 1.200 0.600 0.350 0.700 1.100 0.325 0.650 0.550 1.000 0.300 0.600 0.500 0.900 0.275 0.550 0.450 0.250 0.500 0.800 0.400 0.225 0.450 0.700 0.350 0.200 0.400 0.350 0.175 0.300 0.300 0.150 0.250 0.250 0.125 0.200 0.100 0.150 0.075 0.100 0.050 0.050 0.025 -0.000 242.88 242.89 242.90 0.400 0.150 0.300 0.100 0.200 0.100 0.050 -0.000 242.91 254.86 M 292.9824 R 11629 0.500 0.200 -0.000 242.87 0.600 254.87 254.88 254.89 254.90 268.85 M 304.9824 R 11903 280.9 268.86 268.87 x8 0.600 268.89 280.84 M 316.9824 R 11570 292.9 1.00e0 0.650 268.88 280.85 280.86 x8 316.8 1.00e0 0.170 0.400 0.160 0.375 0.150 0.350 0.140 0.325 0.130 0.300 0.120 0.275 0.110 0.250 0.100 0.225 0.090 0.200 0.080 0.175 0.070 0.150 0.060 0.125 0.050 0.100 0.040 0.075 0.030 0.050 0.020 0.025 0.010 280.88 M 330.9792 R 11737 304.8 1.00e0 0.425 280.87 x8 1.00e0 x8 0.550 0.500 0.550 0.500 0.450 0.450 0.400 0.350 0.400 0.350 0.300 0.300 0.250 0.250 0.200 0.200 0.150 0.150 0.100 0.100 0.050 0.050 -0.000 -0.000 292.83 292.84 292.85 292.86 292.87 292.88 M 342.9792 R 11310 330.8 1.00e0 x8 0.400 0.375 0.350 0.325 0.300 0.275 0.250 0.225 0.200 0.175 0.150 0.125 0.100 0.075 0.050 0.025 -0.000 342.79 342.80 342.81 342.82 342.83 342.84 342.85 304.82 304.83 304.84 304.85 304.86 304.87 -0.000 316.81 316.82 316.83 316.84 316.85 316.86 330.79 330.80 330.81 330.82 330.83 330.84 330.85 Experiment Calibration Report 307 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 4 @ 200 (ppm) Printed: Thursday, April 03, 2014 12:56:12 Eastern Daylight Time M 280.9824 R 13225 M 292.9824 R 12558 430.8 M 304.9824 R 12625 280.9 1.00e0 x8 M 316.9824 R 12629 292.9 1.00e0 x8 304.9 1.00e0 x8 0.450 1.300 1.00e0 x8 0.160 0.600 0.150 1.200 0.400 0.550 0.140 1.100 0.130 0.500 0.350 1.000 0.120 0.450 0.900 0.110 0.300 0.400 0.100 0.800 0.090 0.250 0.350 0.700 0.080 0.300 0.600 0.200 0.070 0.250 0.500 0.060 0.400 0.200 0.300 0.150 0.200 0.100 0.100 0.050 0.150 0.050 0.040 0.100 0.030 0.020 0.050 0.010 -0.000 280.85 280.86 280.87 280.88 -0.000 280.89 292.84 M 330.9792 R 12195 292.85 292.86 292.87 292.88 292.89 304.83 M 342.9792 R 12313 316.8 304.84 304.85 x8 304.87 304.88 316.82 M 366.9792 R 11904 330.8 1.00e0 304.86 316.83 316.84 x8 316.86 316.87 M 380.9760 R 11523 342.8 1.00e0 316.85 366.8 1.00e0 x8 1.00e0 x8 0.550 0.650 0.500 0.600 0.150 0.350 0.140 0.325 0.130 0.550 0.300 0.450 0.120 0.500 0.400 0.275 0.110 0.450 0.250 0.100 0.350 0.225 0.400 0.090 0.200 0.300 0.350 0.080 0.175 0.070 0.250 0.300 0.150 0.060 0.250 0.200 0.125 0.050 0.200 0.150 0.100 0.040 0.150 0.075 0.030 0.100 0.100 0.050 0.020 0.050 0.050 0.025 0.010 -0.000 -0.000 330.81 330.82 330.83 330.84 330.85 -0.000 330.86 342.80 M 392.9760 R 11517 342.81 342.82 342.83 342.84 342.85 M 404.9760 R 11311 380.8 -0.000 342.86 366.78 366.79 366.80 366.81 x8 366.83 366.84 404.8 1.00e0 x8 1.00e0 x8 0.160 0.280 0.170 0.150 0.160 0.260 0.140 0.150 0.240 0.130 0.140 0.220 0.120 0.130 0.200 0.120 0.110 0.180 0.110 0.100 0.100 0.090 0.090 0.080 0.160 0.140 0.080 0.120 0.070 0.070 0.100 0.060 0.080 0.050 0.060 0.050 0.040 0.040 0.060 0.030 0.030 0.040 0.020 0.020 0.020 0.010 0.010 -0.000 -0.000 392.76 392.77 392.78 392.79 392.80 392.81 392.82 392.83 -0.000 404.76 404.77 404.78 404.79 380.76 M 430.9728 R 10549 392.8 1.00e0 366.82 404.80 404.81 404.82 404.83 430.75 430.76 430.77 430.78 430.79 430.80 430.81 430.82 380.77 380.78 380.79 380.80 380.81 380.82 380.83 Experiment Calibration Report 308 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 5 @ 200 (ppm) Printed: Thursday, April 03, 2014 12:56:42 Eastern Daylight Time M 316.9824 R 12311 M 330.9792 R 11905 442.7 M 342.9792 R 11795 316.8 1.00e0 x8 M 366.9792 R 11960 330.8 1.00e0 x8 0.180 342.8 1.00e0 x8 0.550 0.170 0.130 0.500 0.150 0.450 0.140 x8 0.140 0.500 0.160 1.00e0 0.150 0.550 0.120 0.450 0.130 0.110 0.400 0.400 0.120 0.100 0.350 0.110 0.090 0.350 0.100 0.300 0.080 0.300 0.090 0.070 0.250 0.080 0.250 0.060 0.070 0.200 0.200 0.060 0.050 0.050 0.150 0.150 0.040 0.040 0.030 0.100 0.100 0.030 0.020 0.020 0.050 0.050 0.010 0.010 -0.000 -0.000 316.81 316.82 316.83 316.84 316.85 -0.000 316.86 330.79 M 380.9760 R 11212 330.80 330.81 330.82 330.83 330.84 342.78 M 392.9760 R 12136 366.8 -0.000 330.85 342.79 342.80 x8 342.82 342.83 342.84 366.76 M 404.9760 R 11259 380.8 1.00e0 342.81 366.77 366.78 366.79 x8 366.81 366.82 M 430.9728 R 10683 392.8 1.00e0 366.80 404.8 1.00e0 x8 1.00e0 x8 0.340 0.375 0.200 0.320 0.200 0.350 0.300 0.325 0.180 0.180 0.280 0.300 0.260 0.275 0.240 0.250 0.220 0.225 0.200 0.200 0.180 0.160 0.160 0.140 0.140 0.120 0.120 0.160 0.175 0.100 0.100 0.140 0.150 0.080 0.080 0.060 0.060 0.040 0.040 0.120 0.125 0.100 0.100 0.080 0.075 0.060 0.050 0.040 0.020 0.020 0.025 0.020 -0.000 -0.000 380.75 380.76 380.77 380.78 380.79 380.80 380.81 392.74 M 442.9728 R 10824 430.7 1.00e0 x8 0.170 0.160 0.150 0.140 0.130 0.120 0.110 0.100 0.090 0.080 0.070 0.060 0.050 0.040 0.030 0.020 0.010 -0.000 442.69 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 392.75 392.76 392.77 392.78 392.79 392.80 -0.000 404.72 -0.000 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 430.78 Experiment Calibration Report 309 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 6 @ 200 (ppm) Printed: Thursday, April 03, 2014 12:57:03 Eastern Daylight Time M 380.9760 R 11575 M 392.9760 R 11792 480.7 M 404.9760 R 12017 380.8 1.00e0 x8 0.340 0.375 0.320 M 430.9728 R 11362 392.8 1.00e0 0.400 x8 404.7 1.00e0 x8 1.00e0 x8 0.220 0.200 0.200 0.350 0.300 0.325 0.280 0.300 0.260 0.180 0.180 0.160 0.160 0.240 0.275 0.140 0.220 0.250 0.140 0.200 0.120 0.225 0.120 0.180 0.200 0.100 0.160 0.100 0.175 0.140 0.080 0.150 0.080 0.120 0.125 0.100 0.100 0.060 0.060 0.080 0.075 0.050 0.040 0.025 0.020 0.040 0.040 0.060 0.020 0.020 -0.000 -0.000 380.73 380.74 380.75 380.76 380.77 380.78 380.79 -0.000 380.80 392.72 M 442.9728 R 12078 392.73 392.74 392.75 392.76 392.77 392.78 404.71 M 454.9728 R 11367 430.7 -0.000 392.79 404.72 404.73 404.74 x8 404.76 404.77 404.78 430.68 M 466.9728 R 11684 442.7 1.00e0 404.75 430.69 430.70 430.71 430.72 x8 430.74 430.75 430.76 M 480.9696 R 10680 454.7 1.00e0 430.73 466.7 1.00e0 x8 1.00e0 x8 0.130 0.110 0.200 0.200 0.180 0.180 0.160 0.160 0.140 0.140 0.120 0.100 0.110 0.090 0.100 0.080 0.090 0.070 0.080 0.120 0.120 0.070 0.060 0.100 0.100 0.060 0.050 0.050 0.080 0.080 0.040 0.040 0.060 0.060 0.040 0.040 0.020 0.020 0.030 0.030 -0.000 0.020 -0.000 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 442.75 0.020 0.010 0.010 -0.000 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 454.74 -0.000 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 466.73 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 480.71 480.72 Experiment Calibration Report 310 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk4.ref Function: 7 @ 200 (ppm) Printed: Thursday, April 03, 2014 12:57:24 Eastern Daylight Time M 430.9728 R 11904 M 442.9728 R 12017 516.7 M 454.9728 R 11737 430.7 1.00e0 x8 M 466.9728 R 11903 442.7 1.00e0 x8 454.7 1.00e0 x8 1.00e0 x8 0.240 0.110 0.200 0.200 0.220 0.100 0.180 0.180 0.200 0.090 0.160 0.160 0.180 0.080 0.160 0.140 0.140 0.120 0.140 0.070 0.120 0.060 0.120 0.100 0.100 0.050 0.100 0.080 0.080 0.060 0.060 0.040 0.040 0.020 0.020 0.040 0.080 0.030 0.060 0.020 0.040 0.020 -0.000 -0.000 430.71 430.72 430.73 430.74 430.75 430.76 430.77 430.78 442.70 M 480.9696 R 11208 442.71 442.72 442.73 442.74 442.75 442.76 M 492.9696 R 11467 466.7 0.010 -0.000 454.68 442.77 -0.000 454.69 454.70 454.71 454.72 x8 454.74 454.75 454.76 454.77 M 504.9696 R 11683 480.7 1.00e0 454.73 x8 466.69 466.70 466.71 0.120 0.130 0.100 0.120 0.080 466.75 1.00e0 0.070 0.065 0.060 0.055 0.050 0.100 0.080 0.060 0.090 0.045 0.080 0.040 0.060 0.070 0.035 0.050 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.070 0.050 0.040 0.040 0.030 0.030 0.020 0.020 0.010 0.020 0.010 0.010 -0.000 480.67 480.68 480.69 480.70 480.71 480.72 480.73 480.74 0.005 0.010 -0.000 480.66 -0.000 492.65 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 492.74 504.64 504.65 504.66 504.67 504.68 466.76 x8 0.075 0.110 0.090 0.070 466.74 0.080 0.140 0.110 466.73 504.7 x8 0.150 0.090 466.72 M 516.9697 R 11848 1.00e0 0.130 0.100 466.68 492.7 1.00e0 0.160 0.110 466.67 504.69 504.70 504.71 504.72 504.73 -0.000 516.62 516.63 516.64 516.65 516.66 516.67 516.68 516.69 516.70 516.71 Resolution Check Report Printed: 311 of 603 Page 1 of 5 MassLynx 4.1 SCN 881 Thursday, April 03, 2014 22:08:59 Eastern Daylight Time M 180.9888 R 13233 M 204.9888 R 13739 180.9 M 218.9856 R 13549 204.9 1.00e0 x10 M 230.9856 R 13091 218.9 1.00e0 x10 230.9 1.00e0 x10 1.600 1.00e0 x10 0.800 0.060 0.550 1.500 1.400 0.055 1.300 0.050 0.750 0.700 0.500 0.650 0.450 1.200 0.600 0.045 0.400 1.100 0.550 0.040 1.000 0.500 0.350 0.900 0.035 0.450 0.300 0.800 0.400 0.030 0.700 0.350 0.250 0.025 0.600 0.300 0.200 0.500 0.020 0.400 0.015 0.250 0.150 0.300 0.010 0.100 0.005 0.050 -0.000 -0.000 0.200 0.150 0.200 0.100 0.100 -0.000 180.88 180.89 180.90 0.050 180.91 204.86 M 242.9856 R 12987 204.87 204.88 204.89 218.85 M 218.9856 R 13021 242.8 -0.000 218.86 218.87 x10 230.84 M 230.9856 R 12531 218.9 1.00e0 218.88 230.85 230.86 M 242.9856 R 13021 230.9 1.00e0 x10 0.220 230.87 242.9 1.00e0 x10 1.00e0 x10 0.750 0.200 0.700 0.500 0.200 0.180 0.650 0.180 0.450 0.160 0.400 0.140 0.350 0.120 0.300 0.100 0.250 0.080 0.200 0.060 0.150 0.040 0.100 0.020 0.050 0.600 0.160 0.550 0.140 0.500 0.450 0.120 0.400 0.100 0.350 0.300 0.080 0.250 0.060 0.200 0.150 0.040 0.100 0.020 0.050 -0.000 -0.000 242.83 242.84 242.85 242.86 -0.000 242.87 M 254.9856 R 12642 218.87 218.88 218.89 218.90 M 268.9824 R 12136 254.9 -0.000 218.91 230.86 230.87 230.88 x10 230.90 242.85 M 280.9824 R 11904 268.9 1.00e0 230.89 x10 x10 0.150 0.350 0.180 0.140 0.325 0.130 0.300 0.120 0.275 0.110 0.250 0.070 1.00e0 0.160 0.100 0.140 242.89 292.8 x10 0.375 0.080 242.88 M 292.9824 R 12019 1.00e0 0.200 0.110 0.160 242.87 280.8 1.00e0 0.090 242.86 0.120 0.060 0.100 0.050 0.080 0.100 0.225 0.090 0.200 0.080 0.175 0.070 0.150 0.060 0.125 0.050 0.100 0.040 0.075 0.030 0.040 0.060 0.030 0.040 0.020 0.050 0.020 0.020 0.010 -0.000 -0.000 254.84 254.85 254.86 254.87 254.88 268.83 268.84 268.85 268.86 268.87 0.025 0.010 -0.000 -0.000 280.82 280.83 280.84 280.85 280.86 280.87 292.81 292.82 292.83 292.84 292.85 292.86 Resolution Check Report Printed: 312 of 603 Page 2 of 5 MassLynx 4.1 SCN 881 Thursday, April 03, 2014 22:08:59 Eastern Daylight Time M 304.9824 R 11792 M 242.9856 R 12958 304.8 M 254.9856 R 13061 242.9 1.00e0 x10 M 268.9824 R 12859 254.9 1.00e0 x10 268.9 1.00e0 x10 1.00e0 x10 0.110 0.180 0.220 0.090 0.100 0.200 0.160 0.080 0.090 0.180 0.140 0.080 0.070 0.160 0.120 0.070 0.060 0.140 0.060 0.100 0.120 0.050 0.050 0.100 0.040 0.080 0.040 0.080 0.060 0.030 0.030 0.060 0.040 0.020 0.010 -0.000 0.040 0.020 0.020 0.010 -0.000 304.80 304.81 304.82 304.83 304.84 242.87 M 280.9824 R 12652 0.020 -0.000 304.85 242.88 242.89 242.90 M 292.9824 R 12594 280.9 -0.000 242.91 254.86 254.87 x10 254.89 254.90 268.84 M 304.9824 R 12628 292.8 1.00e0 254.88 268.85 268.86 268.87 x10 268.89 M 316.9824 R 13123 304.8 1.00e0 268.88 316.8 1.00e0 x10 1.00e0 x10 0.400 0.110 0.375 0.050 0.180 0.100 0.350 0.045 0.160 0.325 0.090 0.300 0.040 0.140 0.080 0.275 0.035 0.250 0.070 0.120 0.225 0.030 0.060 0.100 0.200 0.025 0.050 0.175 0.080 0.150 0.020 0.040 0.125 0.060 0.015 0.030 0.100 0.040 0.075 0.010 0.020 0.050 0.020 0.005 0.010 0.025 -0.000 280.83 280.84 280.85 280.86 280.87 -0.000 292.82 280.88 M 330.9792 R 12438 -0.000 292.83 292.84 292.85 292.86 304.82 M 342.9792 R 12378 330.8 -0.000 292.87 304.83 x10 304.85 304.86 304.87 M 280.9824 R 12788 342.8 1.00e0 304.84 316.81 316.82 316.83 x10 316.85 316.86 M 292.9824 R 12438 280.9 1.00e0 316.84 292.9 1.00e0 x10 1.00e0 x10 0.180 0.180 0.170 0.110 0.160 0.100 0.150 0.140 0.090 0.130 0.400 0.170 0.375 0.160 0.350 0.150 0.325 0.140 0.300 0.130 0.080 0.120 0.120 0.275 0.110 0.110 0.250 0.070 0.100 0.100 0.225 0.060 0.090 0.090 0.200 0.080 0.080 0.050 0.175 0.070 0.070 0.150 0.040 0.060 0.060 0.125 0.050 0.030 0.040 0.040 0.075 0.020 0.030 0.050 0.100 0.030 0.050 0.020 0.020 0.010 0.025 0.010 -0.000 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 330.85 0.010 -0.000 342.79 342.80 342.81 342.82 342.83 342.84 342.85 -0.000 280.85 280.86 280.87 280.88 280.89 292.84 292.85 292.86 292.87 292.88 292.89 Resolution Check Report Printed: 313 of 603 Page 3 of 5 MassLynx 4.1 SCN 881 Thursday, April 03, 2014 22:08:59 Eastern Daylight Time M 304.9824 R 12788 M 316.9824 R 13058 304.9 M 330.9792 R 12345 316.8 1.00e0 x10 M 342.9792 R 12820 330.8 1.00e0 x10 342.8 1.00e0 x10 1.00e0 x10 0.200 0.130 0.110 0.040 0.180 0.035 0.160 0.120 0.100 0.110 0.090 0.100 0.140 0.030 0.080 0.090 0.120 0.070 0.080 0.025 0.060 0.070 0.100 0.020 0.060 0.050 0.080 0.050 0.015 0.040 0.060 0.040 0.030 0.010 0.030 0.040 0.020 0.020 0.005 0.020 0.010 0.010 -0.000 -0.000 304.83 304.84 304.85 304.86 304.87 -0.000 304.88 316.82 M 366.9792 R 13123 316.83 316.84 316.85 316.86 316.87 330.81 M 380.9760 R 12499 366.8 -0.000 330.82 330.83 x10 330.85 330.86 342.80 M 392.9760 R 11737 380.8 1.00e0 330.84 342.81 342.82 x10 342.84 342.85 M 404.9760 R 12457 392.8 1.00e0 342.83 404.8 1.00e0 x10 1.00e0 x10 0.075 0.040 0.100 0.040 0.070 0.065 0.090 0.035 0.035 0.060 0.080 0.030 0.055 0.030 0.070 0.050 0.025 0.045 0.025 0.060 0.040 0.020 0.050 0.020 0.035 0.030 0.040 0.015 0.015 0.025 0.030 0.020 0.010 0.010 0.015 0.020 0.010 0.005 0.005 0.010 0.005 -0.000 366.78 366.79 366.80 366.81 366.82 366.83 -0.000 380.76 366.84 M 430.9728 R 11494 -0.000 380.77 380.78 380.79 380.80 380.81 380.82 380.83 392.76 M 316.9824 R 12997 430.8 -0.000 392.77 392.78 x10 392.80 392.81 392.82 392.83 404.76 M 330.9792 R 12167 316.8 1.00e0 392.79 404.77 404.78 x10 404.80 404.81 404.82 404.83 M 342.9792 R 12407 330.8 1.00e0 404.79 342.8 1.00e0 x10 1.00e0 x10 0.055 0.180 0.140 0.045 0.050 0.130 0.160 0.040 0.120 0.045 0.110 0.140 0.040 0.035 0.100 0.030 0.035 0.120 0.030 0.100 0.090 0.025 0.080 0.070 0.025 0.080 0.020 0.060 0.020 0.050 0.060 0.015 0.040 0.015 0.040 0.010 0.030 0.010 0.020 0.005 0.020 0.005 0.010 -0.000 -0.000 430.75 430.76 430.77 430.78 430.79 430.80 430.81 430.82 -0.000 316.81 316.82 316.83 316.84 316.85 316.86 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 330.85 342.78 342.79 342.80 342.81 342.82 342.83 342.84 Resolution Check Report Printed: 314 of 603 Page 4 of 5 MassLynx 4.1 SCN 881 Thursday, April 03, 2014 22:08:59 Eastern Daylight Time M 366.9792 R 13519 M 380.9760 R 12196 366.8 M 392.9760 R 12383 380.8 1.00e0 x10 M 404.9760 R 12658 392.8 1.00e0 x10 404.8 1.00e0 x10 0.120 1.00e0 x10 0.055 0.080 0.040 0.110 0.035 0.075 0.050 0.070 0.100 0.045 0.065 0.090 0.060 0.030 0.080 0.040 0.055 0.035 0.050 0.025 0.070 0.045 0.060 0.020 0.030 0.040 0.025 0.035 0.050 0.030 0.015 0.020 0.040 0.025 0.015 0.030 0.010 0.020 0.015 0.020 0.010 0.010 0.005 0.005 0.010 0.005 -0.000 -0.000 366.76 366.77 366.78 366.79 366.80 366.81 -0.000 366.82 380.75 M 430.9728 R 11272 380.76 380.77 380.78 380.79 380.80 392.74 M 442.9728 R 12297 430.7 -0.000 380.81 392.75 392.76 392.77 x10 392.80 404.73 404.74 404.75 404.76 x10 404.77 404.78 404.79 404.80 M 392.9760 R 12165 380.8 1.00e0 0.045 0.060 392.79 M 380.9760 R 12452 442.7 1.00e0 392.78 392.8 1.00e0 x10 1.00e0 x10 0.080 0.110 0.075 0.055 0.100 0.040 0.050 0.070 0.065 0.090 0.035 0.060 0.045 0.080 0.055 0.030 0.040 0.070 0.050 0.035 0.045 0.025 0.060 0.040 0.030 0.050 0.020 0.035 0.025 0.030 0.040 0.015 0.020 0.025 0.030 0.015 0.020 0.010 0.015 0.020 0.010 0.010 0.005 0.010 0.005 0.005 -0.000 -0.000 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 -0.000 430.78 M 404.9760 R 12953 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 380.73 M 430.9728 R 12052 404.7 -0.000 380.74 380.75 380.76 x10 380.78 380.79 380.80 x10 0.045 0.050 392.74 392.75 392.76 392.77 392.78 392.79 M 454.9728 R 12440 454.7 1.00e0 x10 0.055 0.055 392.73 442.7 1.00e0 0.050 392.72 M 442.9728 R 12317 430.7 1.00e0 380.77 1.00e0 x10 0.050 0.050 0.045 0.045 0.040 0.045 0.040 0.040 0.040 0.035 0.035 0.035 0.035 0.030 0.030 0.030 0.030 0.025 0.025 0.025 0.025 0.020 0.020 0.020 0.020 0.015 0.010 0.005 -0.000 0.010 0.010 0.005 0.005 -0.000 404.71 404.72 404.73 404.74 404.75 404.76 404.77 404.78 0.015 0.015 0.015 0.010 0.005 -0.000 430.68 430.69 430.70 430.71 430.72 430.73 430.74 430.75 430.76 -0.000 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 442.75 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 454.74 Resolution Check Report Printed: 315 of 603 Page 5 of 5 MassLynx 4.1 SCN 881 Thursday, April 03, 2014 22:08:59 Eastern Daylight Time M 466.9728 R 12898 M 480.9696 R 12301 466.7 M 430.9728 R 12469 480.7 1.00e0 x10 M 442.9728 R 13138 430.7 1.00e0 x10 442.7 1.00e0 x10 0.065 0.024 1.00e0 x10 0.050 0.040 0.060 0.022 0.045 0.055 0.035 0.020 0.040 0.050 0.018 0.030 0.035 0.045 0.016 0.040 0.025 0.030 0.014 0.035 0.012 0.025 0.020 0.030 0.010 0.025 0.020 0.020 0.015 0.015 0.008 0.006 0.010 0.015 0.010 0.004 0.010 0.005 0.002 0.005 0.005 -0.000 -0.000 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 466.73 -0.000 480.63 M 454.9728 R 12690 480.64 480.65 480.66 480.67 480.68 480.69 480.70 480.71 M 466.9728 R 13021 454.7 -0.000 480.72 430.71 430.72 430.73 430.74 x10 430.76 430.77 430.78 442.70 M 480.9696 R 12048 466.7 1.00e0 430.75 442.71 442.72 442.73 x10 442.75 442.76 442.77 M 492.9696 R 13001 480.7 1.00e0 442.74 492.7 1.00e0 x10 1.00e0 x10 0.032 0.034 0.030 0.024 0.032 0.045 0.022 0.040 0.028 0.030 0.026 0.028 0.024 0.026 0.022 0.024 0.020 0.022 0.020 0.035 0.018 0.016 0.030 0.020 0.018 0.014 0.025 0.018 0.016 0.012 0.016 0.014 0.020 0.014 0.010 0.012 0.012 0.010 0.008 0.015 0.010 0.008 0.006 0.010 0.008 0.006 0.006 0.004 0.004 0.004 0.005 0.002 -0.000 -0.000 454.69 454.70 454.71 454.72 454.73 454.74 454.75 454.76 454.77 M 504.9696 R 12378 466.67 466.68 466.69 466.70 466.71 466.72 466.73 466.74 466.75 M 516.9697 R 13520 504.7 516.7 1.00e0 x10 1.00e0 x10 0.020 0.040 0.018 0.035 0.016 0.030 0.014 0.025 0.012 0.020 0.010 0.008 0.015 0.006 0.010 0.004 0.005 0.002 -0.000 -0.000 504.64 504.65 504.66 504.67 504.68 466.76 504.69 504.70 504.71 504.72 504.73 516.62 516.63 516.64 516.65 516.66 516.67 516.68 516.69 516.70 516.71 0.002 0.002 -0.000 -0.000 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 480.74 492.65 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 Resolution Check Report Printed: 316 of 603 Page 1 of 5 MassLynx 4.1 SCN 881 Friday, April 04, 2014 06:36:11 Eastern Daylight Time M 180.9888 R 14055 M 204.9888 R 14048 180.9 M 218.9856 R 13441 204.9 1.00e0 x10 x10 0.040 1.100 M 230.9856 R 13703 218.9 1.00e0 230.9 1.00e0 x10 1.00e0 x10 0.600 0.450 0.550 1.000 0.400 0.035 0.500 0.900 0.350 0.450 0.030 0.800 0.400 0.300 0.700 0.025 0.350 0.250 0.600 0.300 0.020 0.500 0.200 0.250 0.015 0.400 0.200 0.150 0.300 0.150 0.010 0.100 0.200 0.100 0.005 0.050 0.100 0.050 -0.000 -0.000 180.88 180.89 180.90 180.91 204.86 M 242.9856 R 13440 204.87 204.88 -0.000 218.84 204.89 M 218.9856 R 12755 242.8 218.85 218.86 x10 230.84 230.85 x10 230.86 230.87 M 242.9856 R 12988 230.9 1.00e0 0.425 0.150 -0.000 230.83 218.88 M 230.9856 R 12690 218.9 1.00e0 218.87 242.9 1.00e0 x10 1.00e0 x10 0.150 0.550 0.400 0.140 0.140 0.500 0.375 0.130 0.130 0.350 0.450 0.120 0.120 0.325 0.110 0.100 0.275 0.090 0.250 0.080 0.225 0.070 0.200 0.110 0.400 0.300 0.100 0.350 0.090 0.300 0.080 0.070 0.250 0.175 0.060 0.060 0.200 0.150 0.050 0.050 0.125 0.150 0.040 0.040 0.100 0.030 0.030 0.100 0.075 0.020 0.020 0.050 0.050 0.010 0.010 0.025 -0.000 242.82 -0.000 242.83 242.84 242.85 -0.000 242.86 218.87 M 254.9856 R 13069 218.88 218.89 218.90 230.86 M 268.9824 R 12406 254.9 -0.000 230.87 x10 230.89 230.90 M 280.9824 R 13029 268.8 1.00e0 230.88 242.85 x10 242.88 242.89 292.8 1.00e0 x10 1.00e0 0.320 0.120 0.150 0.300 0.110 0.140 0.280 0.130 0.260 0.120 0.240 0.110 0.220 0.100 0.200 0.040 0.090 0.180 0.035 0.080 0.160 0.030 0.070 0.140 0.060 0.120 0.050 0.100 0.040 0.080 0.030 0.060 0.020 0.040 0.010 0.020 0.065 242.87 M 292.9824 R 12695 280.8 1.00e0 0.160 0.070 242.86 0.060 x10 0.100 0.055 0.050 0.045 0.090 0.080 0.070 0.025 0.060 0.050 0.040 0.020 0.030 0.015 0.010 0.005 -0.000 -0.000 254.84 254.85 254.86 254.87 254.88 0.020 0.010 -0.000 268.83 268.84 268.85 268.86 268.87 -0.000 280.82 280.83 280.84 280.85 280.86 292.81 292.82 292.83 292.84 292.85 292.86 Resolution Check Report Printed: 317 of 603 Page 2 of 5 MassLynx 4.1 SCN 881 Friday, April 04, 2014 06:36:11 Eastern Daylight Time M 304.9824 R 12693 M 242.9856 R 13158 304.8 M 254.9856 R 13513 242.9 1.00e0 x10 x10 268.9 1.00e0 x10 1.00e0 x10 0.075 0.150 0.160 0.060 M 268.9824 R 12855 254.9 1.00e0 0.170 0.070 0.140 0.150 0.065 0.055 0.130 0.140 0.060 0.050 0.120 0.130 0.055 0.120 0.045 0.110 0.050 0.110 0.100 0.040 0.035 0.030 0.100 0.045 0.090 0.040 0.080 0.035 0.070 0.090 0.080 0.070 0.030 0.025 0.060 0.060 0.020 0.025 0.050 0.020 0.040 0.015 0.030 0.050 0.040 0.015 0.030 0.010 0.010 0.020 0.005 -0.000 304.80 304.81 304.82 304.83 304.84 0.005 0.010 -0.000 -0.000 304.85 242.87 M 280.9824 R 13230 0.020 0.010 -0.000 242.88 242.89 242.90 254.86 M 292.9824 R 12406 280.9 254.87 x10 254.89 254.90 M 304.9824 R 12693 292.8 1.00e0 254.88 268.84 268.85 268.86 x10 268.88 M 316.9824 R 13245 304.8 1.00e0 268.87 316.8 1.00e0 x10 1.00e0 x10 0.130 0.320 0.034 0.300 0.070 0.120 0.032 0.280 0.065 0.030 0.110 0.260 0.060 0.028 0.055 0.026 0.100 0.240 0.220 0.090 0.200 0.080 0.024 0.050 0.022 0.045 0.020 0.180 0.070 0.040 0.060 0.035 0.018 0.160 0.016 0.140 0.050 0.120 0.100 0.030 0.014 0.025 0.012 0.040 0.010 0.020 0.080 0.030 0.008 0.015 0.060 0.006 0.020 0.010 0.040 0.020 -0.000 280.83 280.84 280.85 280.86 280.87 0.005 0.002 -0.000 -0.000 -0.000 280.88 292.82 M 330.9792 R 12820 0.004 0.010 292.83 292.84 292.85 292.86 292.87 304.81 M 342.9792 R 11820 330.8 304.82 304.83 x10 304.86 316.80 316.81 316.82 x10 316.83 316.84 316.85 292.9 1.00e0 x10 1.00e0 x10 0.320 0.120 0.075 0.300 0.070 0.280 0.065 0.260 0.060 0.240 0.055 0.220 0.090 0.050 0.200 0.080 0.045 0.180 0.070 0.040 0.160 0.035 0.140 0.030 0.120 0.025 0.100 0.040 0.020 0.080 0.030 0.015 0.060 0.010 0.040 0.130 0.120 0.110 0.100 0.110 0.100 0.060 0.090 0.080 0.070 0.060 0.050 0.050 0.040 0.030 0.020 0.020 0.010 0.005 0.020 -0.000 -0.000 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 330.85 342.79 342.80 342.81 342.82 342.83 342.84 342.85 0.010 -0.000 280.85 280.86 280.87 316.86 M 292.9824 R 13404 280.9 1.00e0 0.080 0.140 304.85 M 280.9824 R 13515 342.8 1.00e0 304.84 280.88 280.89 292.84 292.85 292.86 292.87 292.88 Resolution Check Report Printed: 318 of 603 Page 3 of 5 MassLynx 4.1 SCN 881 Friday, April 04, 2014 06:36:11 Eastern Daylight Time M 304.9824 R 13420 M 316.9824 R 13257 304.9 M 330.9792 R 13382 316.8 1.00e0 x10 M 342.9792 R 12919 330.8 1.00e0 x10 342.8 1.00e0 x10 1.00e0 x10 0.160 0.080 0.028 0.150 0.075 0.090 0.026 0.140 0.070 0.024 0.130 0.065 0.022 0.070 0.020 0.110 0.050 0.018 0.100 0.045 0.016 0.090 0.040 0.014 0.055 0.080 0.120 0.060 0.060 0.050 0.080 0.070 0.035 0.012 0.040 0.060 0.030 0.010 0.050 0.025 0.030 0.008 0.040 0.020 0.006 0.004 0.010 0.020 0.030 0.015 0.020 0.010 0.002 0.005 -0.000 0.010 -0.000 304.83 304.84 304.85 304.86 304.87 -0.000 304.88 316.82 M 366.9792 R 13667 316.83 316.84 316.85 316.86 316.87 M 380.9760 R 12502 366.8 -0.000 330.80 330.81 330.82 330.83 x10 0.026 330.85 330.86 342.79 M 392.9760 R 12691 380.8 1.00e0 330.84 342.80 342.81 342.82 x10 342.85 404.8 1.00e0 x10 1.00e0 x10 0.030 0.045 0.085 342.84 M 404.9760 R 13158 392.8 1.00e0 342.83 0.028 0.080 0.024 0.040 0.026 0.075 0.022 0.024 0.070 0.035 0.020 0.065 0.018 0.060 0.022 0.020 0.030 0.055 0.018 0.016 0.050 0.014 0.025 0.016 0.045 0.014 0.040 0.012 0.020 0.012 0.035 0.010 0.030 0.008 0.010 0.015 0.025 0.008 0.020 0.006 0.010 0.006 0.015 0.004 0.004 0.010 0.002 0.005 0.002 0.005 -0.000 -0.000 366.77 366.78 366.79 366.80 366.81 366.82 366.83 -0.000 366.84 M 430.9728 R 11655 380.76 380.77 380.78 380.79 380.80 380.81 380.82 380.83 M 316.9824 R 14093 430.8 -0.000 392.76 392.77 392.78 x10 392.80 392.81 392.82 392.83 M 330.9792 R 12763 316.8 1.00e0 392.79 404.76 404.77 404.78 x10 404.80 404.81 404.82 404.83 M 342.9792 R 12596 330.8 1.00e0 404.79 342.8 1.00e0 x10 1.00e0 x10 0.150 0.032 0.030 0.140 0.028 0.130 0.026 0.120 0.024 0.110 0.022 0.100 0.100 0.035 0.090 0.030 0.080 0.070 0.025 0.020 0.090 0.060 0.018 0.020 0.080 0.016 0.050 0.070 0.014 0.060 0.015 0.040 0.012 0.050 0.010 0.010 0.030 0.006 0.005 0.030 0.040 0.008 0.004 0.020 0.002 0.010 0.020 0.010 -0.000 430.74 430.75 430.76 430.77 430.78 430.79 430.80 430.81 430.82 -0.000 316.80 -0.000 316.81 316.82 316.83 316.84 316.85 316.86 -0.000 330.79 330.80 330.81 330.82 330.83 330.84 330.85 342.78 342.79 342.80 342.81 342.82 342.83 342.84 Resolution Check Report Printed: 319 of 603 Page 4 of 5 MassLynx 4.1 SCN 881 Friday, April 04, 2014 06:36:11 Eastern Daylight Time M 366.9792 R 13444 M 380.9760 R 12658 366.8 M 392.9760 R 12667 380.8 1.00e0 x10 M 404.9760 R 13006 392.8 1.00e0 x10 0.090 0.055 0.080 0.050 0.026 404.8 1.00e0 x10 1.00e0 x10 0.032 0.030 0.024 0.028 0.022 0.045 0.026 0.070 0.020 0.024 0.040 0.018 0.022 0.060 0.035 0.020 0.016 0.050 0.018 0.030 0.014 0.016 0.012 0.025 0.040 0.010 0.014 0.012 0.020 0.030 0.010 0.008 0.015 0.008 0.006 0.020 0.006 0.010 0.004 0.004 0.010 0.005 0.002 0.002 -0.000 -0.000 366.76 366.77 366.78 366.79 366.80 366.81 366.82 -0.000 380.74 M 430.9728 R 12261 380.75 380.76 380.77 380.78 380.79 380.80 380.81 392.73 M 442.9728 R 12197 430.7 -0.000 392.74 392.75 392.76 x10 392.78 392.79 392.80 404.72 M 380.9760 R 12565 442.7 1.00e0 392.77 404.74 404.75 404.76 x10 404.77 404.78 404.79 M 392.9760 R 12690 380.8 1.00e0 392.8 1.00e0 x10 0.034 1.00e0 x10 0.055 0.032 0.045 404.73 0.090 0.050 0.030 0.028 0.040 0.080 0.045 0.070 0.040 0.026 0.035 0.024 0.022 0.030 0.035 0.060 0.020 0.030 0.018 0.025 0.050 0.016 0.020 0.025 0.014 0.040 0.020 0.012 0.015 0.030 0.010 0.015 0.008 0.010 0.020 0.010 0.006 0.004 0.005 0.010 0.005 0.002 -0.000 -0.000 430.70 430.71 430.72 430.73 430.74 430.75 430.76 430.77 -0.000 442.69 M 404.9760 R 13455 442.70 442.71 442.72 442.73 442.74 442.75 442.76 442.77 M 430.9728 R 12926 404.7 -0.000 380.73 380.74 380.75 380.76 x10 380.78 380.79 380.80 M 442.9728 R 13420 430.7 1.00e0 380.77 392.72 392.73 392.74 392.75 x10 392.77 392.78 392.79 M 454.9728 R 13194 442.7 1.00e0 392.76 454.7 1.00e0 x10 1.00e0 x10 0.045 0.036 0.032 0.034 0.032 0.040 0.035 0.035 0.030 0.030 0.028 0.030 0.028 0.026 0.024 0.026 0.022 0.030 0.024 0.025 0.020 0.022 0.025 0.020 0.018 0.020 0.018 0.016 0.020 0.016 0.014 0.014 0.015 0.012 0.015 0.012 0.010 0.010 0.010 0.008 0.010 0.008 0.006 0.006 0.005 0.004 0.005 0.004 -0.000 -0.000 0.002 0.002 -0.000 -0.000 404.71 404.72 404.73 404.74 404.75 404.76 404.77 404.78 430.68 430.69 430.70 430.71 430.72 430.73 430.74 430.75 430.76 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 442.75 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 454.74 Resolution Check Report Printed: 320 of 603 Page 5 of 5 MassLynx 4.1 SCN 881 Friday, April 04, 2014 06:36:11 Eastern Daylight Time M 466.9728 R 13930 M 480.9696 R 13021 466.7 M 430.9728 R 12722 480.7 1.00e0 x10 M 442.9728 R 13091 430.7 1.00e0 x10 442.7 1.00e0 x10 1.00e0 x10 0.016 0.035 0.032 0.055 0.015 0.030 0.014 0.050 0.028 0.030 0.013 0.026 0.045 0.012 0.024 0.025 0.040 0.011 0.022 0.010 0.035 0.020 0.009 0.020 0.018 0.030 0.008 0.016 0.007 0.025 0.014 0.006 0.012 0.005 0.010 0.004 0.008 0.003 0.006 0.002 0.015 0.020 0.010 0.015 0.010 0.005 0.004 0.005 0.001 0.002 -0.000 466.64 -0.000 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 -0.000 466.73 480.63 M 454.9728 R 13850 480.64 480.65 480.66 480.67 480.68 480.69 480.70 480.71 430.71 M 466.9728 R 13668 454.7 -0.000 430.72 430.73 430.74 x10 430.76 430.77 430.78 442.69 M 480.9696 R 12502 466.7 1.00e0 430.75 442.70 442.71 442.72 442.73 x10 442.75 442.76 442.77 M 492.9696 R 12965 480.7 1.00e0 442.74 492.7 1.00e0 x10 1.00e0 x10 0.020 0.030 0.018 0.035 0.026 0.028 0.024 0.026 0.016 0.022 0.024 0.030 0.020 0.022 0.014 0.025 0.020 0.018 0.018 0.016 0.016 0.014 0.012 0.020 0.010 0.014 0.008 0.012 0.012 0.015 0.010 0.010 0.006 0.008 0.008 0.010 0.006 0.004 0.006 0.004 0.004 0.005 0.002 -0.000 -0.000 454.68 454.69 454.70 454.71 454.72 454.73 454.74 454.75 454.76 466.67 M 504.9696 R 13552 466.68 466.69 466.70 466.71 466.72 466.73 466.74 516.7 x10 1.00e0 0.026 0.013 0.024 0.012 0.022 0.011 0.020 0.010 0.018 0.009 0.016 0.008 0.014 0.007 0.012 0.006 0.010 0.005 0.008 0.004 0.006 0.003 0.004 x10 0.002 0.002 0.001 -0.000 -0.000 504.64 504.65 504.66 504.67 504.68 504.69 504.70 504.71 504.72 516.62 516.63 516.64 516.65 516.66 516.67 516.68 516.69 516.70 0.002 -0.000 480.65 M 516.9697 R 13945 504.7 1.00e0 504.63 466.75 0.002 -0.000 480.66 480.67 480.68 480.69 480.70 480.71 480.72 480.73 480.74 492.64 492.65 492.66 492.67 492.68 492.69 492.70 492.71 492.72 492.73 PCB ICAL PAGE RANGE: 321 TO 575 PCB ICAL Summary 321 of 603 Printed: 3 Jan 2014 16:53 SGS Analytical Perspectives ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 Date Processed: 3 Jan 2014 16:52 Name PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB Mean 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 % RSD 4.1% 3.1% 5.1% 4.8% 4.2% 2.4% 5.8% 4.0% 4.0% 3.5% 5.0% 3.9% 131220X02 0.5 CS0 1.17 1.08 1.13 1.14 1.20 1.20 1.05 1.07 1.11 1.12 1.08 1.18 131220X03 1 CS1 1.11 1.13 1.02 1.16 1.13 1.20 1.07 1.07 1.13 1.07 1.00 1.10 131220X04 5 CS2 1.09 1.08 1.07 1.15 1.13 1.16 1.05 1.05 1.12 1.09 1.03 1.06 131220X05 50 CS3 1.14 1.12 1.13 1.23 1.22 1.23 1.12 1.12 1.20 1.16 1.07 1.09 131220X06 400 CS4 1.17 1.14 1.15 1.24 1.22 1.23 1.14 1.11 1.18 1.14 1.10 1.10 131220X08 2000 CS5 1.22 1.17 1.18 1.29 1.25 1.25 1.21 1.17 1.23 1.17 1.16 1.15 3.7% 2.3% 0.7% 1.1% 1.4% 1.8% 1.0% 1.8% 2.5% 1.7% 2.5% 2.3% 2.4% 1.2% 3.2% 1.4% 3.0% 2.0% 2.0% 2.3% 1.9% 3.6% 1.9% 1.1% 1.2% 0.9% 1.4% 1.25 1.12 0.52 1.04 0.50 1.69 0.86 1.38 1.37 0.82 1.22 1.24 1.19 1.19 1.07 1.14 1.66 1.60 1.68 1.54 0.92 1.11 0.97 1.61 0.96 1.24 0.83 1.22 1.09 0.52 1.04 0.50 1.64 0.86 1.37 1.35 0.80 1.21 1.22 1.17 1.20 1.02 1.11 1.60 1.57 1.65 1.53 0.93 1.10 0.93 1.57 0.96 1.23 0.82 1.21 1.10 0.53 1.05 0.51 1.68 0.88 1.42 1.36 0.82 1.25 1.26 1.19 1.20 1.07 1.13 1.63 1.63 1.71 1.58 0.96 1.13 0.96 1.60 0.99 1.26 0.85 1.18 1.06 0.52 1.02 0.50 1.61 0.85 1.34 1.32 0.80 1.18 1.19 1.13 1.16 0.99 1.10 1.56 1.56 1.62 1.51 0.95 1.11 0.92 1.57 0.97 1.24 0.83 1.17 1.08 0.52 1.05 0.51 1.66 0.86 1.38 1.38 0.79 1.18 1.21 1.14 1.19 1.01 1.11 1.56 1.64 1.70 1.60 0.95 1.16 0.93 1.57 0.97 1.25 0.83 1.13 1.06 0.53 1.05 0.52 1.69 0.85 1.40 1.42 0.78 1.17 1.19 1.14 1.18 1.01 1.10 1.52 1.61 1.65 1.58 0.97 1.21 0.93 1.58 0.97 1.25 0.82 PCB ICAL PAGE RANGE: 321 TO 575 PCB ICAL Summary 322 of 603 Printed: 3 Jan 2014 16:53 SGS Analytical Perspectives ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 131220X03 1 CS1 1.16 1.10 131220X04 5 CS2 1.20 1.14 131220X05 50 CS3 1.17 1.11 131220X06 400 CS4 1.18 1.11 131220X08 2000 CS5 1.19 1.08 Name ES PCB-208 ES PCB-209 Mean 1.17 1.11 % RSD 1.4% 1.9% 131220X02 0.5 CS0 1.16 1.12 SS PCB-28 SS PCB-111 SS PCB-178 1.11 1.03 0.62 1.2% 1.6% 2.7% 1.12 1.04 0.64 1.12 1.02 0.61 1.11 1.03 0.61 1.12 1.05 0.61 1.11 1.00 0.61 1.09 1.03 0.64 CS PCB-28 CS PCB-111 CS PCB-178 1.85 1.22 0.58 1.4% 1.4% 3.7% 1.89 1.24 0.62 1.84 1.22 0.57 1.86 1.23 0.58 1.81 1.22 0.56 1.84 1.19 0.57 1.83 1.21 0.60 PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-153/168 ...-HxCB PCB-155 22'44'66'-HxCB PCB-170 22'33'44'5-HpCB PCB-180/193 ...-HpCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.46 1.26 1.14 1.26 1.27 1.05 1.06 1.12 1.11 3.4% 2.9% 3.8% 3.8% 2.5% 4.7% 2.1% 1.5% 3.7% 2.3% 6.1% 2.7% 3.1% 3.2% 4.0% 3.8% 3.0% 0.99 1.00 1.17 1.01 1.13 1.02 1.40 1.44 1.38 1.23 1.09 1.26 1.23 1.05 1.07 1.09 1.09 0.94 0.98 1.20 0.98 1.12 1.05 1.34 1.41 1.42 1.25 1.06 1.22 1.32 1.05 1.03 1.11 1.11 0.92 0.98 1.20 0.98 1.12 1.05 1.31 1.40 1.43 1.23 1.09 1.23 1.22 1.00 1.01 1.07 1.08 0.97 1.04 1.27 1.03 1.17 1.10 1.36 1.45 1.48 1.27 1.15 1.27 1.26 1.06 1.06 1.13 1.11 0.98 1.05 1.27 1.04 1.16 1.10 1.35 1.45 1.50 1.29 1.19 1.27 1.28 1.06 1.07 1.14 1.12 0.91 1.00 1.29 1.08 1.19 1.16 1.36 1.46 1.53 1.29 1.24 1.31 1.31 1.10 1.13 1.19 1.18 323 of 603 PCB ICAL Summary - Ax2 Detail SGS Analytical Perspectives Printed: 3 Jan 2014 16:53 ICAL: 131220 QC MM7 Acquired: 20 Dec 2013 Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB Mean 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 % RSD 3.4% 3.8% 2.9% 3.8% 3.9% 2.8% 5.7% 4.5% 4.8% 3.2% 3.9% 4.5% 6.8% 3.8% 2.5% 3.5% 4.4% 3.6% 3.4% 4.3% 2.4% 3.0% 4.1% 3.0% 2.6% 3.3% 3.6% 3.3% 2.8% 4.4% 4.1% 3.7% 4.6% 4.7% 2.1% 2.7% 5.4% 5.9% 2.5% 1.7% 0.5 CS0 0.99 1.02 1.00 1.17 1.91 0.93 0.95 0.97 1.03 1.07 1.14 0.98 0.88 1.01 1.13 1.49 1.23 1.77 1.67 0.99 1.90 1.11 1.20 1.15 1.13 1.25 1.13 1.15 1.08 1.13 1.18 1.07 1.01 1.02 1.40 0.89 0.78 0.80 0.70 0.85 1 CS1 0.94 1.01 0.98 1.20 1.90 0.95 1.03 0.94 0.92 0.99 1.14 0.95 0.96 0.98 1.12 1.47 1.28 1.76 1.69 0.94 1.91 1.09 1.09 1.14 1.14 1.16 1.08 1.14 1.05 1.12 1.16 1.08 0.98 1.05 1.34 0.85 0.76 0.82 0.68 0.83 5 CS2 0.92 0.98 0.98 1.20 1.93 0.90 1.02 0.96 0.96 1.00 1.15 0.99 0.97 0.98 1.12 1.51 1.27 1.77 1.67 1.00 1.85 1.11 1.10 1.13 1.13 1.19 1.08 1.13 1.04 1.13 1.16 1.06 1.00 1.05 1.31 0.84 0.70 0.89 0.68 0.82 50 CS3 0.97 1.08 1.04 1.27 2.05 0.96 1.09 1.03 1.02 1.04 1.20 1.03 1.02 1.03 1.17 1.57 1.33 1.83 1.74 1.00 1.93 1.15 1.18 1.20 1.18 1.26 1.17 1.21 1.09 1.19 1.24 1.14 1.08 1.10 1.36 0.90 0.74 0.93 0.72 0.86 400 CS4 0.98 1.08 1.05 1.27 2.04 0.96 1.08 1.03 1.02 1.03 1.21 1.04 1.03 1.04 1.16 1.59 1.34 1.87 1.73 1.05 1.93 1.18 1.19 1.21 1.18 1.24 1.17 1.21 1.10 1.21 1.25 1.16 1.07 1.10 1.35 0.89 0.78 0.88 0.71 0.85 2000 CS5 0.91 1.02 1.00 1.29 2.06 0.97 1.11 1.05 1.05 1.07 1.25 1.07 1.07 1.08 1.19 1.60 1.38 1.92 1.83 1.06 1.99 1.16 1.17 1.21 1.18 1.25 1.17 1.21 1.12 1.24 1.27 1.11 1.10 1.16 1.36 0.89 0.83 0.84 0.71 0.85 324 of 603 PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB 1.11 0.71 1.02 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 1.16 4.0% 4.5% 3.4% 3.5% 3.3% 3.7% 2.8% 4.3% 3.9% 3.9% 2.1% 2.7% 2.6% 2.9% 1.9% 3.1% 2.4% 3.3% 2.3% 2.9% 1.8% 2.3% 2.5% 4.2% 1.5% 4.7% 2.7% 3.3% 3.9% 3.5% 6.3% 8.5% 11.9% 10.7% 4.5% 3.8% 3.2% 2.3% 2.4% 4.0% 6.0% 3.9% 3.2% 6.9% 6.2% 6.3% 4.4% 1.13 0.68 0.99 0.83 0.89 1.13 0.76 0.68 0.84 1.17 1.19 1.26 1.18 1.17 1.23 1.30 1.20 1.06 1.09 1.13 1.13 1.30 1.26 1.04 1.44 1.12 0.91 0.79 0.89 0.84 0.97 0.73 0.96 0.76 0.71 0.73 1.18 0.82 0.98 0.77 0.88 1.12 0.98 1.02 1.02 1.09 1.18 1.06 0.68 0.98 0.79 0.88 1.13 0.73 0.66 0.82 1.18 1.18 1.24 1.11 1.13 1.25 1.26 1.16 1.06 1.10 1.05 1.12 1.29 1.33 0.99 1.41 1.24 0.91 0.76 0.80 0.83 0.93 0.68 0.72 0.95 0.66 0.74 1.15 0.81 0.96 0.70 0.88 1.12 0.94 1.15 0.87 1.07 1.11 1.06 0.72 0.99 0.83 0.86 1.13 0.75 0.69 0.83 1.18 1.19 1.24 1.16 1.15 1.23 1.24 1.16 1.09 1.12 1.10 1.11 1.28 1.28 1.04 1.40 1.20 0.91 0.79 0.85 0.85 0.99 0.71 0.73 0.94 0.70 0.75 1.16 0.79 0.96 0.71 0.88 1.16 0.95 1.15 0.88 1.06 1.16 1.12 0.77 1.05 0.87 0.93 1.21 0.79 0.73 0.87 1.27 1.25 1.31 1.20 1.20 1.29 1.33 1.23 1.14 1.14 1.13 1.15 1.35 1.31 1.10 1.45 1.26 0.96 0.83 0.89 0.88 1.03 0.80 0.74 1.04 0.75 0.80 1.23 0.84 1.00 0.72 0.91 1.24 1.01 1.17 0.94 1.25 1.10 1.12 0.72 1.05 0.85 0.93 1.22 0.77 0.68 0.90 1.25 1.22 1.31 1.16 1.19 1.27 1.32 1.22 1.14 1.12 1.12 1.14 1.32 1.35 1.08 1.45 1.28 0.95 0.81 0.87 0.90 0.87 0.86 0.85 0.95 0.73 0.78 1.23 0.83 1.01 0.70 0.98 1.17 1.02 1.09 0.99 1.11 1.16 1.17 0.70 1.06 0.87 0.93 1.18 0.78 0.73 0.89 1.28 1.23 1.30 1.17 1.23 1.28 1.34 1.21 1.13 1.15 1.13 1.16 1.34 1.32 1.11 1.46 1.27 0.95 0.82 0.89 0.89 1.02 0.77 0.78 1.03 0.74 0.79 1.24 0.84 1.01 0.69 1.00 1.18 0.97 1.25 0.95 1.13 1.24 325 of 603 PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 1.23 1.13 0.84 1.07 1.14 3.4% 2.9% 4.3% 4.7% 8.6% 3.3% 4.1% 5.5% 2.3% 4.1% 3.7% 6.5% 3.0% 4.0% 2.4% 3.1% 3.1% 3.5% 4.3% 3.3% 3.3% 2.7% 4.9% 2.0% 2.8% 1.5% 3.4% 3.6% 3.7% 2.5% 1.8% 5.1% 5.4% 4.0% 2.3% 2.4% 5.7% 3.3% 5.3% 3.1% 1.6% 2.7% 1.7% 1.5% 3.8% 4.2% 4.0% 0.69 1.23 1.18 1.07 1.26 1.12 0.97 1.09 1.23 1.16 1.18 1.01 1.13 1.14 1.11 1.38 1.22 1.12 0.97 1.07 1.20 1.02 0.96 1.03 1.13 1.41 1.19 1.50 1.38 1.10 0.97 1.19 1.35 1.18 1.49 1.69 0.86 1.09 1.03 1.23 1.19 1.14 1.21 1.14 0.88 1.02 1.08 0.67 1.17 1.14 1.03 1.05 1.08 0.96 1.04 1.25 1.12 1.10 0.98 1.09 1.14 1.13 1.29 1.12 1.15 0.90 1.10 1.16 1.02 0.92 1.01 1.11 1.39 1.16 1.44 1.42 1.05 0.95 1.14 1.48 1.15 1.48 1.64 0.86 1.11 1.01 1.32 1.16 1.09 1.22 1.11 0.80 1.05 1.12 0.67 1.19 1.18 1.07 1.26 1.04 0.95 1.03 1.23 1.13 1.15 1.04 1.06 1.16 1.12 1.30 1.17 1.16 0.88 1.14 1.17 0.98 0.97 1.01 1.09 1.40 1.17 1.50 1.43 1.07 0.96 1.10 1.52 1.14 1.49 1.62 0.85 1.07 1.03 1.22 1.13 1.10 1.22 1.10 0.82 1.05 1.11 0.70 1.25 1.24 1.14 1.33 1.12 1.01 1.11 1.27 1.16 1.20 1.09 1.12 1.19 1.14 1.33 1.19 1.18 0.89 1.18 1.20 1.03 1.01 1.03 1.13 1.42 1.19 1.54 1.48 1.10 0.97 1.10 1.58 1.17 1.55 1.63 0.91 1.13 1.11 1.26 1.17 1.13 1.25 1.14 0.84 1.08 1.15 0.72 1.23 1.25 1.12 1.26 1.13 1.02 1.12 1.29 1.23 1.21 1.12 1.14 1.23 1.16 1.37 1.20 1.21 0.96 1.12 1.24 1.04 1.03 1.03 1.16 1.39 1.24 1.55 1.50 1.10 0.98 1.22 1.51 1.23 1.56 1.67 0.93 1.12 1.10 1.28 1.16 1.13 1.24 1.12 0.84 1.10 1.17 0.73 1.26 1.28 1.17 1.36 1.14 1.06 1.19 1.29 1.23 1.22 1.16 1.16 1.25 1.18 1.38 1.20 1.23 0.94 1.16 1.27 1.06 1.06 1.06 1.17 1.44 1.26 1.60 1.53 1.12 1.00 1.24 1.55 1.27 1.52 1.72 0.98 1.17 1.15 1.31 1.15 1.17 1.26 1.14 0.88 1.15 1.21 326 of 603 PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 4.7% 3.5% 9.3% 4.3% 2.6% 4.9% 5.3% 3.7% 5.1% 2.7% 2.6% 6.1% 5.4% 3.2% 3.2% 2.5% 5.1% 5.6% 3.2% 2.8% 2.5% 4.3% 3.5% 4.0% 3.8% 3.1% 3.0% 1.09 1.16 0.95 0.93 0.93 1.03 0.90 0.96 1.17 1.26 1.41 1.09 1.63 1.05 1.16 1.10 1.26 1.03 0.80 0.84 0.87 0.79 0.88 1.07 1.09 1.20 1.09 1.14 1.18 1.03 1.04 0.94 1.07 0.90 0.97 1.27 1.22 1.40 1.06 1.58 1.05 1.22 1.13 1.16 1.04 0.79 0.80 0.85 0.74 0.82 1.03 1.11 1.16 1.11 1.16 1.21 0.99 0.96 0.93 1.04 0.92 0.95 1.28 1.23 1.33 1.09 1.58 1.00 1.19 1.08 1.11 1.12 0.78 0.82 0.85 0.73 0.81 1.01 1.07 1.14 1.08 1.22 1.28 1.03 1.00 0.95 1.11 0.97 1.02 1.32 1.27 1.40 1.15 1.66 1.06 1.24 1.12 1.15 1.16 0.80 0.84 0.88 0.75 0.84 1.06 1.13 1.20 1.11 1.21 1.18 1.15 0.98 0.96 1.12 0.98 1.00 1.32 1.27 1.40 1.19 1.69 1.06 1.27 1.12 1.21 1.12 0.82 0.84 0.88 0.77 0.85 1.07 1.14 1.20 1.12 1.23 1.22 1.21 1.03 0.99 1.17 1.03 1.04 1.36 1.31 1.44 1.24 1.82 1.10 1.24 1.16 1.26 1.17 0.86 0.87 0.91 0.82 0.88 1.13 1.19 1.24 1.18 1668A/B ICALs Air Historica Data Ax RSD Mean sd 77 10.6 1.04 0.11 1.11 1.13 1.34 81 9.6 1.08 0.10 1.13 1.13 1.13 105 4.6 0.96 0.04 1.11 1.09 1.15 1.11 2.1 1.11 0.02 114 4.9 0.96 0.05 1.18 1.16 1.22 1.2 2.1 1.19 0.02 118 6.8 0.95 0.06 1.11 1.11 1.17 1.19 3.7 1.15 0.04 123 3.9 0.97 0.04 1.08 1.19 1.27 1.21 6.5 1.19 0.08 126 8.6 1.00 0.09 1.07 1.06 1.12 1.11 2.9 1.09 0.03 156/157 6.4 0.99 0.06 1.09 1.11 1.18 1.1 3.7 1.12 0.04 167 5.8 0.98 0.06 1.14 1.14 1.23 1.16 3.8 1.17 0.04 169 4.5 0.97 0.04 1.09 1.11 1.19 1.12 3.7 1.13 0.04 189 14.7 0.95 0.14 1.07 1.06 1.09 1.07 1.3 1.07 0.01 1 9.3 1.16 0.11 1.02 1.03 0.93 0.95 5.1 0.98 0.05 3 9.5 1.16 0.11 0.98 1.04 0.97 1.01 3.4 1.00 0.03 327 of 603 MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd 1.15 8.8 1.18 0.10 1.12 0.4 1.13 0.00 4 4.7 1.03 0.05 1.11 1.17 1.13 1.23 4.5 1.16 0.05 15 11.8 1.02 0.12 0.99 1.08 1.05 1.02 3.9 1.03 0.04 19 4.7 1.04 0.05 1.10 1.09 1.10 1.15 2.3 1.11 0.03 37 12.1 1.06 0.13 1.00 1.10 1.05 1.08 4.2 1.06 0.04 54 104 4.3 1.06 0.05 1.18 1.21 1.24 1.35 6.0 1.25 0.07 5.4 1.01 0.05 1.11 1.25 1.31 1.43 10.2 1.28 0.13 1.19 1.22 1.38 1.46 9.8 1.31 0.13 1.08 1.09 1.22 1.26 7.8 1.16 0.09 170 1.06 1.07 1.11 1.14 3.3 1.09 0.04 180 188 1.08 1.16 1.21 1.26 6.6 1.18 0.08 4.2 1.02 0.04 1.03 1.03 1.01 1.27 11.4 1.09 0.12 202 3.0 0.91 0.03 0.93 0.91 0.97 1.05 6.4 0.97 0.06 205 5.4 0.96 0.05 1.07 1.09 1.11 1.06 1.8 1.08 0.02 208 2.3 0.93 0.02 1.02 1.02 1.07 1.12 4.7 1.06 0.05 206 3.2 0.97 0.03 0.99 0.98 0.92 1.11 7.9 1.00 0.08 209 7.0 0.95 0.07 1.07 1.07 1.13 1.11 2.6 1.10 0.03 1 6.7 1.01 0.07 1.08 1.08 1.20 1.19 6.0 1.14 0.07 3 5.5 1.02 0.06 1.14 1.08 1.14 1.09 2.7 1.11 0.03 153 155 3.2 1.02 0.03 PD from Mean -4.3% 0.1% -1.9% -2.4% -3.4% 0.2% -2.6% -1.2% -2.8% -1.5% -1.4% 4.9% 4.4% 0.8% 4.5% -1.7% 4.3% -3.0% -1.7% -7.0% -6.2% -1.9% -1.6% -4.8% -5.3% 0.6% -3.8% -2.2% -2.1% ES 4 10.0 0.69 0.07 0.50 0.49 0.57 0.52 6.8 0.52 0.04 15 4.2 1.06 0.04 1.18 1.11 1.07 1.04 5.5 1.10 0.06 19 6.3 0.62 0.04 0.53 0.55 0.57 0.51 4.8 0.54 0.03 37 10.4 1.36 0.14 1.64 1.64 1.55 1.66 2.9 1.62 0.05 54 7.3 1.18 0.09 0.87 0.94 0.86 0.86 4.4 0.88 0.04 77 11.1 1.23 0.14 1.26 1.35 1.11 1.38 9.6 1.27 0.12 81 9.4 1.19 0.11 1.20 1.29 1.26 1.37 5.6 1.28 0.07 104 8.0 1.33 0.11 1.08 0.99 0.89 0.8 13.2 0.94 0.12 105 4.1 1.27 0.05 1.22 1.23 1.23 1.2 1.2 1.22 0.02 114 4.2 1.31 0.05 1.24 1.25 1.24 1.22 1.0 1.24 0.01 118 5.3 1.31 0.07 1.28 1.28 1.26 1.16 4.6 1.24 0.06 123 3.9 1.24 0.05 1.35 1.22 1.21 1.19 5.9 1.24 0.07 126 6.7 1.30 0.09 1.22 1.20 1.09 1.03 7.9 1.14 0.09 1.10 1.14 1.15 1.11 2.1 1.13 0.02 153 155 7.0 1.42 0.10 1.41 1.50 1.56 1.59 5.1 1.51 0.08 156/157 7.7 1.22 0.09 1.41 1.45 1.59 1.6 6.4 1.51 0.10 167 7.6 1.25 0.09 1.43 1.49 1.68 1.67 8.1 1.57 0.13 169 8.1 1.23 0.10 1.37 1.40 1.42 1.56 5.8 1.44 0.08 170 1.04 1.00 0.93 0.95 5.1 0.98 0.05 180 1.28 1.16 1.12 1.14 6.3 1.17 0.07 188 8.5 1.27 0.11 1.12 1.18 1.23 0.94 11.4 1.12 0.13 189 7.8 1.52 0.12 1.53 1.49 1.46 1.58 3.5 1.51 0.05 202 6.6 1.18 0.08 1.07 1.14 1.10 0.97 6.7 1.07 0.07 205 3.9 1.27 0.05 1.26 1.20 1.22 1.24 2.0 1.23 0.02 206 11.3 0.97 0.11 0.90 0.87 0.95 0.83 5.9 0.89 0.05 208 10.2 1.27 0.13 1.22 1.19 1.19 1.17 1.7 1.19 0.02 MM7 Comparing ICAL RRFs 20DEC2013.xlsx -5.0% -2.7% -6.0% 0.8% 2.3% 0.8% 6.5% 5.7% 0.7% 5.6% 1.1% 0.7% 3.0% -2.0% 5.6% 1.3% -1.2% -3.9% -4.6% -2.4% 2.1% -1.3% 5.3% -1.8% 6.4% -2.2% -2.1% -0.2% 1668A/B ICALs Air Historica Data Ax RSD Mean sd 209 8.3 1.20 0.10 328 of 603 MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 1.06 1.00 1.12 1.11 PD from Mean RSD Mean sd 5.1 1.07 0.06 -6.8% 0.8% 0.2% 3.1% SS 28 3.6 1.05 0.04 0.98 1.07 1.10 1.11 5.6 1.07 0.06 111 4.0 1.05 0.04 0.90 1.01 1.08 1.03 7.5 1.00 0.07 178 3.9 0.71 0.03 0.62 0.63 0.57 0.62 4.4 0.61 0.03 Additional Ax RSD Mean sd PCB-1 2-MoCB 1.02 1.03 0.93 0.95 5.1 0.98 0.05 PCB-2 3-MoCB 0.97 1.04 0.97 1.03 3.7 1.00 0.04 PCB-3 4-MoCB 0.98 1.04 0.97 1.01 3.4 1.00 0.03 PCB-4 22'-DiCB 1.11 1.17 1.13 1.23 4.5 1.16 0.05 PCB-10 26-DiCB 1.71 1.83 1.75 1.98 6.5 1.82 0.12 PCB-9 25-DiCB 0.83 0.89 0.90 0.95 5.7 0.89 0.05 PCB-7 24-DiCB 0.95 1.02 1.02 1.05 4.3 1.01 0.04 PCB-6 23'-DiCB 0.89 0.95 0.96 1.00 4.7 0.95 0.04 PCB-5 23-DiCB 0.89 0.97 0.97 1.00 4.7 0.96 0.05 PCB-8 24'-DiCB 0.93 0.98 1.00 1.03 4.3 0.99 0.04 PCB-14 35-DiCB 1.07 1.16 1.15 1.18 4.2 1.14 0.05 PCB-11 33'-DiCB 0.94 1.00 0.99 1.01 3.3 0.98 0.03 PCB-13/12 34'-/34-DiCB 0.95 1.02 0.99 0.99 2.8 0.99 0.03 PCB-15 44'-DiCB 0.99 1.08 1.05 1.02 3.9 1.03 0.04 0.03 PCB-19 22'6-TrCB 1.10 1.09 1.10 1.15 2.3 1.11 PCB-30/18 246-/22'5-TrCB 1.48 1.46 1.45 1.54 2.6 1.48 0.04 PCB-17 22'4-TrCB 1.28 1.25 1.26 1.31 2.0 1.28 0.03 PCB-27 23'6-TrCB 1.70 1.69 1.68 1.82 3.8 1.72 0.07 PCB-24 236-TrCB 1.63 1.63 1.60 1.72 3.1 1.65 0.05 PCB-16 22'3-TrCB 0.97 0.95 0.96 1.01 2.6 0.97 0.03 PCB-32 24'6-TrCB 1.81 1.79 1.84 1.92 3.1 1.84 0.06 PCB-34 2'35-TrCB 0.98 1.05 1.04 1.14 6.4 1.05 0.07 PCB-23 235-TrCB 0.98 1.06 1.07 1.16 6.9 1.07 0.07 PCB-26/29 23'5-/245-TrCB 1.00 1.09 1.07 1.17 6.3 1.08 0.07 PCB-25 23'4-TrCB 0.99 1.07 1.09 1.16 6.5 1.08 0.07 PCB-31 24'5-TrCB 1.03 1.11 1.13 1.23 7.2 1.13 0.08 PCB-28/20 244'-/233'-TrCB 0.98 1.07 1.06 1.13 5.6 1.06 0.06 PCB-21/33 234-/2'34-TrCB 1.01 1.09 1.08 1.17 6.0 1.09 0.06 PCB-22 234'-TrCB 0.93 1.02 1.00 1.08 6.0 1.01 0.06 PCB-36 33'5-TrCB 1.03 1.13 1.09 1.17 5.4 1.10 0.06 PCB-39 34'5-TrCB 1.10 1.17 1.13 1.21 4.1 1.15 0.05 PCB-38 345-TrCB 0.95 1.03 1.02 1.10 5.9 1.02 0.06 PCB-35 33'4-TrCB 0.96 1.04 1.00 1.04 4.0 1.01 0.04 PCB-37 344'-TrCB 1.00 1.10 1.05 1.08 4.2 1.06 0.04 PCB-54 22'66'-TeCB 1.18 1.21 1.24 1.35 6.0 1.25 0.07 PCB-50/53 22'46-/22'56'TeCB 0.85 0.86 0.88 0.88 2.0 0.87 0.02 PCB-45 22'36-TeCB 0.75 0.73 0.76 0.77 2.2 0.75 0.02 PCB-51 22'46'-TeCB 0.85 0.88 0.91 0.86 3.2 0.87 0.03 PCB-46 22'36'-TeCB 0.68 0.70 0.71 0.70 1.6 0.70 0.01 PCB-52 22'55'-TeCB 0.82 0.84 0.86 0.84 2.0 0.84 0.02 PCB-73 23'5'6TeCB 1.10 1.09 1.13 1.11 1.4 1.11 0.02 0.03 PCB-43 22'35-TeCB 0.66 0.72 0.72 0.71 4.5 0.70 PCB-69/49 23'46-/22'45'TeCB 1.00 1.01 1.05 1.02 2.1 1.02 0.02 PCB-48 22'45-TeCB 0.83 0.85 0.87 0.84 1.7 0.85 0.01 0.01 PCB-44/47/65 22'35'-/22'44'- 0.88 0.89 0.91 0.90 1.5 0.90 PCB-59/62/75 233'6-/2346-/24 1.12 1.14 1.18 1.17 2.4 1.15 0.03 PCB-42 22'34'-TeCB 0.77 0.76 2.9 0.78 0.02 0.77 0.81 MM7 Comparing ICAL RRFs 20DEC2013.xlsx PCB-41 22'34-TeCB 0.72 0.73 0.71 0.69 2.2 0.71 0.02 PCB-71/40 23'4'6/22'33'-TeCB 0.85 0.87 0.88 0.86 1.5 0.86 0.01 PCB-64 234'6-TeCB 1.21 1.24 1.26 1.22 1.7 1.23 0.02 PD from Historical Mean 4.9% 3.8% 4.4% 0.8% 0.7% 0.4% 1.4% -0.2% 1.4% -0.2% 1.5% 1.7% 3.2% 4.5% -1.7% -1.6% -1.9% -1.8% -0.7% -2.1% -2.8% -0.3% -0.8% 0.3% -0.3% -1.3% 0.7% 0.3% 0.8% 2.1% 1.2% 0.7% 3.2% 4.3% -3.0% -1.1% -2.8% 0.6% -0.3% 0.3% -1.5% 3.0% -0.8% 0.4% -0.8% -1.2% -0.8% 2.1% 0.2% 0.5% 1668A/B ICALs Air Historica Data Ax RSD 329 of 603 Mean sd MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd PCB-72 23'55'-TeCB 1.13 1.14 1.17 1.21 3.0 1.16 0.03 PCB-68 23'45'-TeCB 1.21 1.21 1.26 1.28 2.8 1.24 0.04 PCB-57 233'5-TeCB 1.10 1.11 1.12 1.16 2.3 1.12 0.03 PCB-58 233'5-TeCB 1.11 1.10 1.16 1.18 3.4 1.14 0.04 PCB-67 23'45-TeCB 1.15 1.16 1.20 1.26 4.2 1.19 0.05 PCB-63 234'5-TeCB 1.22 1.22 1.25 1.30 3.1 1.25 0.04 PCB-61/70/74/76 2345-/23'4'5 1.13 1.13 1.17 1.20 2.8 1.16 0.03 PCB-66 23'44'-TeCB 1.06 1.08 1.10 1.10 1.7 1.09 0.02 PCB-55 233'4-TeCB 1.09 1.10 1.11 1.12 1.3 1.10 0.01 PCB-56 233'4'-TeCB 1.05 1.06 1.07 1.11 2.4 1.07 0.03 PCB-60 2344'-TeCB 1.12 1.11 1.15 1.14 1.5 1.13 0.02 PCB-80 33'55'-TeCB 1.26 1.25 1.27 1.31 2.1 1.27 0.03 PCB-79 33'45'-TeCB 1.26 1.23 1.28 1.31 2.6 1.27 0.03 PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB PCB-95 22'35'6-PeCB PCB-100/93 22'44'6-/22'356-P PCB-102 22'456'-PeCB PCB-98 22'3'46-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 233'5'6-/22'3 PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125/87 233 PCB-117 234'56-PeCB PCB-116/85 23456-/22'344'-Pe PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 233'4'5-/2'3455' PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 2'33'45-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'HxCB PCB-148 22'34'56'-HxCB PCB-151/135 22'355'6-/22'33' PCB-154 22'44'5'6-HxCB PCB-144 22'345'6-HxCB PCB-147/149 22'34'56-/22'34' PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 22'344'6-/22'344' PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB 1.09 1.08 1.05 1.06 1.6 1.07 0.02 1.11 1.25 1.31 1.43 10.2 1.28 0.13 0.98 1.08 1.12 1.23 9.5 1.10 0.10 0.80 0.90 0.95 0.93 7.2 0.90 0.06 0.70 0.78 0.81 0.80 6.6 0.77 0.05 0.75 0.83 0.88 0.87 7.5 0.83 0.06 0.76 0.84 0.90 0.86 6.9 0.84 0.06 0.82 0.90 0.98 0.97 8.1 0.92 0.07 0.69 0.77 0.80 0.76 5.9 0.76 0.04 0.67 0.79 0.77 0.80 7.8 0.76 0.06 0.84 0.88 1.00 0.94 7.5 0.91 0.07 0.65 0.71 0.72 0.72 5.2 0.70 0.04 0.68 0.76 0.78 0.76 6.0 0.75 0.04 1.02 1.14 1.20 1.20 7.4 1.14 0.08 0.73 0.80 0.84 0.82 6.0 0.80 0.05 0.85 0.93 0.99 0.99 7.0 0.94 0.07 0.63 0.71 0.72 0.71 5.7 0.69 0.04 0.82 0.87 0.95 0.92 6.5 0.89 0.06 1.01 1.13 1.17 1.17 6.7 1.12 0.07 0.87 0.95 1.01 0.98 6.4 0.95 0.06 0.96 1.04 1.05 1.14 7.2 1.05 0.08 0.87 0.97 1.03 0.94 7.0 0.95 0.07 0.95 1.02 1.11 1.12 7.7 1.05 0.08 1.02 1.16 1.21 1.16 6.9 1.14 0.08 0.63 0.69 0.72 0.70 5.5 0.68 0.04 1.05 1.15 1.22 1.22 7.0 1.16 0.08 1.05 1.16 1.22 1.21 6.5 1.16 0.08 0.99 1.07 1.11 1.10 5.3 1.07 0.06 1.05 1.14 1.18 1.25 7.1 1.16 0.08 0.98 1.07 1.11 1.11 5.6 1.07 0.06 1.01 1.00 1.01 0.99 1.0 1.00 0.01 1.12 1.10 1.08 1.10 1.5 1.10 0.02 1.08 1.09 1.22 1.26 7.8 1.16 0.09 1.00 1.01 1.14 1.17 8.0 1.08 0.09 1.03 1.00 1.15 1.18 7.9 1.09 0.09 0.95 0.95 1.07 1.07 6.8 1.01 0.07 0.98 0.96 1.09 1.11 7.4 1.03 0.08 0.96 0.97 1.12 1.18 10.5 1.06 0.11 0.94 0.96 1.11 1.14 9.8 1.04 0.10 1.05 1.09 1.26 1.34 11.7 1.19 0.14 0.96 0.98 1.13 1.18 10.1 1.06 0.11 0.96 0.99 1.14 1.18 10.3 1.07 0.11 0.78 0.80 0.90 0.92 8.1 0.85 0.07 0.92 0.95 1.09 1.13 10.0 1.02 0.10 0.99 1.00 1.14 1.21 10.1 1.09 0.11 0.84 0.85 0.98 1.03 10.4 0.93 0.10 0.99 7.4 0.93 0.07 0.86 MM7 Comparing ICAL RRFs 20DEC2013.xlsx 0.87 0.98 0.87 0.89 1.02 1.03 8.8 0.95 0.08 0.92 0.91 1.04 1.13 10.2 1.00 0.10 PD from Mean -1.8% -2.5% -1.4% -3.4% -2.8% -2.6% -2.3% -0.9% -0.6% -1.7% -1.5% -1.5% -2.9% 0.9% -1.7% -2.4% 0.6% 0.4% -0.7% 0.2% -1.9% 2.4% 4.7% -3.8% 1.4% 1.9% 0.2% 0.2% -0.9% 2.8% -2.1% 0.7% -0.1% -0.7% 2.2% -2.6% 1.8% 0.9% -0.5% -0.1% 0.6% -1.2% 0.1% -0.2% -0.1% -6.2% -6.4% -8.0% -5.7% -7.0% -8.2% -7.2% -8.1% -7.7% -7.8% -5.8% -6.8% -7.9% -8.2% -5.7% -6.7% -8.7% 1668A/B ICALs Air Historica Data Ax PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 22'44'55'-/23'44' PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 233'4'56-/22' PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 22'33'44'-/2344'5 PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'4'56-HpCB PCB-181 22'344'56-HpCB PCB-171/173 22'33'44'6-/22'3 PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 22'344'55'-/233' PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 22'33'455'6-/22' PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB RSD 330 of 603 Mean sd MM7_PCB_01102012_25 MM7_PCB_07132012_25 MM7_PCB_07122013_1 MM7_PCB_10292013_2 Analytical Perspectives JUL12 JUL12 9JUL2013 0DEC2013 RSD Mean sd 1.12 1.13 1.32 1.41 11.4 1.24 0.14 0.99 1.01 1.16 1.20 10.0 1.09 0.11 1.24 1.25 1.41 1.52 9.8 1.36 0.13 1.19 1.22 1.38 1.46 9.8 1.31 0.13 0.92 0.93 1.06 1.09 8.9 1.00 0.09 0.82 0.85 0.95 0.97 8.2 0.90 0.07 1.00 1.04 1.08 1.16 6.3 1.07 0.07 1.21 1.22 1.45 1.50 11.2 1.35 0.15 1.01 1.02 1.14 1.19 8.1 1.09 0.09 1.18 1.21 1.32 1.52 11.9 1.31 0.16 1.30 1.34 1.50 1.66 11.4 1.45 0.17 0.91 0.90 0.95 0.90 2.7 0.92 0.02 1.07 1.06 1.14 1.11 3.0 1.10 0.03 1.09 1.08 1.14 1.07 2.7 1.09 0.03 1.03 1.03 1.01 1.27 11.4 1.09 0.12 0.95 0.97 0.92 1.16 10.8 1.00 0.11 0.94 0.93 0.90 1.13 10.6 0.98 0.10 1.05 1.05 1.00 1.23 9.4 1.08 0.10 0.98 0.98 0.94 1.13 8.3 1.01 0.08 0.73 0.74 0.69 0.84 8.6 0.75 0.06 0.95 1.01 1.09 1.07 6.1 1.03 0.06 0.99 1.06 1.17 1.14 7.4 1.09 0.08 1.02 1.11 1.19 1.18 6.9 1.12 0.08 1.06 1.13 1.17 1.20 5.4 1.14 0.06 0.95 1.02 1.13 1.06 7.3 1.04 0.08 0.83 0.93 0.99 0.99 8.0 0.93 0.07 0.85 0.91 0.97 0.95 5.7 0.92 0.05 0.98 1.06 1.10 1.09 4.9 1.06 0.05 0.85 0.93 0.96 0.95 5.4 0.92 0.05 0.88 0.95 0.99 0.99 5.5 0.95 0.05 1.12 1.24 1.26 1.29 6.0 1.23 0.07 1.08 1.16 1.21 1.26 6.6 1.18 0.08 1.20 1.30 1.32 1.40 6.4 1.31 0.08 1.06 1.07 1.11 1.14 3.3 1.09 0.04 1.42 1.45 1.54 1.66 7.2 1.52 0.11 0.93 0.91 0.97 1.05 6.4 0.97 0.06 1.04 1.02 1.07 1.22 8.3 1.09 0.09 0.99 0.98 1.02 1.12 6.3 1.03 0.07 1.03 1.06 1.13 1.19 6.3 1.10 0.07 1.02 0.96 1.02 1.11 6.0 1.03 0.06 0.74 0.72 0.73 0.81 5.7 0.75 0.04 0.77 0.73 0.76 0.83 5.5 0.77 0.04 0.80 0.76 0.79 0.87 5.7 0.80 0.05 0.79 0.80 0.82 0.77 2.7 0.80 0.02 0.87 0.87 0.89 0.84 2.3 0.87 0.02 1.07 1.09 1.11 1.06 1.8 1.08 0.02 1.02 1.02 1.07 1.12 4.7 1.06 0.05 1.07 1.06 1.10 1.19 5.4 1.10 0.06 0.99 0.98 0.92 1.11 7.9 1.00 0.08 MM7 Comparing ICAL RRFs 20DEC2013.xlsx PD from Mean -9.0% -7.6% -7.6% -7.0% -7.3% -5.7% -2.7% -9.1% -6.2% -7.6% -7.7% -1.9% -3.0% -1.7% -4.8% -3.1% -4.6% -3.2% -2.6% -1.8% -2.0% -2.5% -1.2% -0.6% -2.0% -0.7% -1.3% 0.3% 0.6% 0.3% 1.0% -1.6% -0.3% -1.9% -4.3% -5.3% -6.2% -4.9% -3.6% -6.4% -4.2% -5.3% -5.1% 0.5% 0.7% 0.6% -3.8% -4.3% -2.0% 331 of 603 SGS Analytical Perspectives — Run Log Project: 131220 QC MM7 Instrument: MM7 (AutoSpec-Premier) MS Experiment: pcb-2012-01 GC Program: pcb90_a # Datafile Vial# Wt/Vol Client/Sample ID Analyst(s) Checkcode Acq Date 2 131220X02 Tray1:37 CS0_131220_PCB_XA 1.00 SIL 13-79-6 LKB 067-110 20-Dec-2013 14:56:33 3 131220X03 Tray1:38 CS1_131220_PCB_XA 1.00 SIL 13-79-5 LKB 983-753 20-Dec-2013 16:14:56 Lab ID Acq Time 4 131220X04 Tray1:39 CS2_131220_PCB_XA 1.00 SIL 13-79-4 LKB 288-489 20-Dec-2013 17:09:38 5 131220X05 Tray1:40 CS3_131220_PCB_XA 1.00 SIL 13-79-3 LKB 297-225 20-Dec-2013 18:04:38 20-Dec-2013 18:59:38 6 131220X06 Tray1:41 CS4_131220_PCB_XA 1.00 SIL 13-79-2 LKB 186-257 7 131220X07 Tray1:02 SBS_131220_PCB_XB 1.00 SIL 9-42-1 LKB 307-094 20-Dec-2013 19:54:39 8 131220X08 Tray1:42 CS5_131220_PCB_XA 1.00 SIL 13-84-1 LKB 807-075 20-Dec-2013 20:49:35 9 131220X09 Tray1:02 SBS_131220_PCB_XC 1.00 SIL 9-42-1 LKB 023-880 20-Dec-2013 21:57:30 10 131220X10 Tray1:02 SBS_131220_PCB_XD 1.00 SIL 9-42-1 LKB 979-518 20-Dec-2013 22:52:16 Project file: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\131220 QC MM7.utp_prj, saved 03-Jan-2014 17:08 AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 Printed: 03-Jan-2014 17:17 332 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.12 32.64 36.11 35.57 35.10 34.82 38.73 41.28 40.30 44.00 46.13 51.25 6.82E+05 6.25E+05 5.30E+05 5.44E+05 5.47E+05 5.49E+05 4.31E+05 8.79E+05 4.81E+05 4.43E+05 4.42E+05 3.36E+05 0.76 Y 0.76 Y 0.63 Y 0.67 Y 0.67 Y 0.63 Y 0.61 Y 1.18 Y 1.11 Y 1.39 Y 1.03 Y 1.21 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.08 1.13 1.14 1.20 1.20 1.05 1.07 1.11 1.12 1.08 1.18 1.8% -3.1% 1.5% -5.0% 0.6% -0.6% -5.2% -2.5% -4.2% -0.5% 0.2% 6.0% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.05 14.37 14.63 20.39 17.75 26.75 20.68 33.10 32.62 25.69 36.09 35.55 35.08 34.80 38.71 36.67 30.66 41.26 40.28 43.98 43.50 42.43 35.54 46.11 40.09 48.28 49.75 45.73 51.23 2.32E+08 2.09E+08 9.70E+07 1.92E+08 9.22E+07 1.42E+08 7.28E+07 1.16E+08 1.15E+08 6.25E+07 9.38E+07 9.51E+07 9.14E+07 9.13E+07 8.22E+07 5.84E+07 8.51E+07 1.64E+08 8.65E+07 7.92E+07 4.71E+07 5.69E+07 4.97E+07 8.21E+07 4.94E+07 6.33E+07 4.24E+07 5.90E+07 5.69E+07 3.31 Y 3.36 Y 1.64 Y 1.56 Y 1.08 Y 1.09 Y 0.79 Y 0.80 Y 0.81 Y 1.64 Y 1.62 Y 1.64 Y 1.64 Y 1.59 Y 1.56 Y 1.32 Y 1.30 Y 1.31 Y 1.29 Y 1.29 Y 1.09 Y 1.07 Y 1.11 Y 1.04 Y 0.92 Y 0.90 Y 0.81 Y 0.81 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.25 1.12 0.52 1.04 0.50 1.69 0.86 1.38 1.37 0.82 1.22 1.24 1.19 1.19 1.07 1.14 1.66 1.60 1.68 1.54 0.92 1.11 0.97 1.61 0.96 1.24 0.83 1.16 1.12 5.1% 3.5% 0.1% -0.4% -1.7% 1.7% 0.4% -0.1% 0.2% 1.5% 1.8% 1.8% 2.9% 0.4% 4.3% 2.1% 4.3% 0.0% 0.9% -1.0% -2.5% -2.0% 2.9% 1.7% -0.9% -0.3% 0.3% -1.6% 0.5% Page 1 of 6 333 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.18 33.12 38.11 1.59E+08 9.52E+07 3.17E+07 1.09 Y 1.60 Y 1.06 Y 1.11 1.03 0.62 1.12 1.04 0.64 0.5% 1.3% 3.0% CS PCB-28 CS PCB-111 CS PCB-178 23.18 33.12 38.11 1.59E+08 9.52E+07 3.17E+07 1.09 Y 1.60 Y 1.06 Y 1.85 1.22 0.58 1.89 1.24 0.62 2.2% 1.7% 6.0% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.63 24.81 30.82 37.74 47.88 1.86E+08 8.42E+07 7.67E+07 5.14E+07 5.10E+07 1.57 Y 0.81 Y 1.63 Y 1.34 Y 0.93 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.06 14.39 14.64 20.41 17.77 26.77 20.70 25.71 30.68 35.56 40.11 48.30 45.75 49.77 1.15E+06 1.04E+06 5.70E+05 9.73E+05 5.22E+05 7.24E+05 5.08E+05 4.49E+05 5.21E+05 3.05E+05 2.58E+05 3.40E+05 3.21E+05 2.31E+05 3.25 Y 3.26 Y 0.00 S 0.00 S 1.03 Y 1.07 Y 0.86 Y 0.64 Y 1.33 Y 1.15 Y 0.94 Y 0.94 Y 0.83 Y 0.73 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.99 1.00 1.17 1.01 1.13 1.02 1.40 1.44 1.23 1.23 1.05 1.07 1.09 1.09 3.9% -0.9% -4.7% -0.7% -1.3% -5.6% 3.4% 0.3% -2.8% -3.2% -0.7% 1.3% -3.0% -2.5% Page 2 of 6 334 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 12.06 14.20 14.39 14.64 14.83 16.65 16.82 17.04 17.35 17.47 19.04 19.83 20.12 20.41 17.77 19.54 19.95 20.14 20.27 20.37 20.86 22.01 22.16 22.45 22.65 22.92 23.21 23.39 23.77 25.16 25.48 26.02 26.41 26.77 20.70 22.70 23.29 23.37 23.57 24.83 24.96 25.06 25.26 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.15E+06 1.07E+06 1.04E+06 5.70E+05 9.26E+05 8.91E+05 9.13E+05 9.28E+05 9.94E+05 1.02E+06 1.10E+06 9.44E+05 1.69E+06 9.73E+05 5.22E+05 1.37E+06 5.65E+05 8.14E+05 7.72E+05 4.55E+05 8.78E+05 7.89E+05 8.53E+05 1.63E+06 8.01E+05 8.89E+05 1.61E+06 1.63E+06 7.71E+05 8.01E+05 8.42E+05 7.61E+05 7.19E+05 7.24E+05 5.08E+05 1.02E+06 4.52E+05 4.59E+05 4.01E+05 4.90E+05 6.54E+05 3.93E+05 1.15E+06 RA 3.25 Y 3.22 Y 3.26 Y 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 0.00 S 1.03 Y 1.04 Y 1.04 Y 1.08 Y 1.06 Y 1.10 Y 1.08 Y 1.08 Y 0.94 Y 1.01 Y 0.97 Y 1.01 Y 1.02 Y 0.98 Y 1.00 Y 1.00 Y 1.02 Y 0.93 Y 1.01 Y 1.07 Y 0.86 Y 0.81 Y 0.79 Y 0.83 Y 0.83 Y 0.76 Y 0.81 Y 0.85 Y 0.76 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.99 1.02 1.00 1.17 1.91 0.93 0.95 0.97 1.03 1.07 1.14 0.98 0.88 1.01 1.13 1.49 1.23 1.77 1.67 0.99 1.90 1.11 1.20 1.15 1.13 1.25 1.13 1.15 1.08 1.13 1.18 1.07 1.01 1.02 1.40 0.89 0.78 0.80 0.70 0.85 1.13 0.68 0.99 Dev'n 3.9% -0.9% -0.9% -4.7% -3.6% -2.0% -9.2% -3.0% 3.2% 3.2% -3.4% -2.8% -11.2% -0.7% -1.3% -3.2% -6.1% -2.9% -2.9% -2.0% -0.8% -2.3% 3.8% -2.1% -2.7% 2.0% -0.1% -2.4% 0.4% -3.7% -2.3% -3.2% -2.8% -5.6% 3.4% 1.3% 2.2% -7.3% -0.4% 0.7% 2.0% -4.1% -2.8% 335 of 603 PCB QC Summary - Ax2 Detail Lab ID: CS0_131220_PCB_XA Acquired: 20-DEC-2013 14:56 Datafile: 131220X02 Name RT PCB-48 22'45-TeCB 25.54 PCB-44/47/65 ...-TeCB 25.76 PCB-59/62/75 ...-TeCB 26.03 PCB-42 22'34'-TeCB 26.20 PCB-41 22'34-TeCB 26.54 PCB-71/40 23'4'6/22'33'-TeCB 26.63 PCB-64 234'6-TeCB 26.83 PCB-72 23'55'-TeCB 27.55 PCB-68 23'45'-TeCB 27.80 PCB-57 233'5-TeCB 28.18 PCB-58 233'5'-TeCB 28.38 PCB-67 23'45-TeCB 28.54 PCB-63 234'5-TeCB 28.77 PCB-61/70/74/76 ...-TeCB 29.06 PCB-66 23'44'-TeCB 29.34 PCB-55 233'4-TeCB 29.49 PCB-56 233'4'-TeCB 29.93 PCB-60 2344'-TeCB 30.12 PCB-80 33'55'-TeCB 30.44 PCB-79 33'45'-TeCB 31.77 PCB-78 33'45-TeCB 32.26 PCB-104 22'466'-PeCB 25.71 PCB-96 22'366'-PeCB 26.03 PCB-103 22'45'6-PeCB 27.72 PCB-94 22'356'-PeCB 27.91 PCB-95 22'35'6-PeCB 28.29 PCB-100/93 22'44'6/22'356-PeCB 28.51 PCB-102 22'456'-PeCB 28.62 PCB-98 22'34'6'-PeCB 28.70 PCB-88 22'346-PeCB 29.00 PCB-91 22'34'6-PeCB 29.06 PCB-84 22'33'6-PeCB 29.25 PCB-89 22'346'-PeCB 29.67 PCB-121 23'45'6-PeCB 30.01 PCB-92 22'355'-PeCB 30.33 PCB-113/90/101 ...-PeCB 30.82 PCB-83 22'33'5-PeCB 31.26 PCB-99 22'44'5-PeCB 31.36 PCB-112 233'56-PeCB 31.46 PCB-108/119/86/97/125...-PeCB 31.80 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.43 PCB-110 233'4'6-PeCB 32.54 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 4.76E+05 1.54E+06 1.95E+06 4.38E+05 3.93E+05 9.69E+05 6.74E+05 6.87E+05 7.26E+05 6.81E+05 6.76E+05 7.09E+05 7.50E+05 2.77E+06 6.11E+05 6.26E+05 6.53E+05 6.55E+05 7.47E+05 7.25E+05 6.00E+05 4.49E+05 3.51E+05 4.14E+05 3.59E+05 4.07E+05 7.64E+05 4.42E+05 3.31E+05 4.40E+05 3.45E+05 3.22E+05 3.31E+05 5.39E+05 3.73E+05 1.35E+06 3.50E+05 4.00E+05 5.12E+05 2.69E+06 4.64E+05 9.28E+05 4.96E+05 RA 0.82 Y 0.78 Y 0.80 Y 0.81 Y 0.87 Y 0.82 Y 0.82 Y 0.78 Y 0.84 Y 0.73 Y 0.76 Y 0.78 Y 0.82 Y 0.77 Y 0.79 Y 0.78 Y 0.82 Y 0.79 Y 0.82 Y 0.81 Y 0.82 Y 0.64 Y 0.75 N 0.64 Y 0.70 Y 0.58 Y 0.61 Y 0.64 Y 0.63 Y 0.66 Y 0.56 Y 0.60 Y 0.70 Y 0.64 Y 0.62 Y 0.62 Y 0.64 Y 0.61 Y 0.65 Y 0.63 Y 0.55 Y 0.58 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.83 0.89 1.13 0.76 0.68 0.84 1.17 1.19 1.26 1.18 1.17 1.23 1.30 1.20 1.06 1.09 1.13 1.13 1.30 1.26 1.04 1.44 1.12 0.91 0.79 0.89 0.84 0.97 0.73 0.96 0.76 0.71 0.73 1.18 0.82 0.98 0.77 0.88 1.12 0.98 1.02 1.02 1.09 Dev'n -1.5% -1.8% -3.2% -0.5% -2.0% -2.2% -4.3% -1.5% -1.4% 1.5% -0.6% -2.3% 0.2% 0.2% -3.9% -3.1% 2.0% 0.0% -1.4% -3.8% -2.0% 0.3% -8.6% -2.6% -1.5% 3.0% -3.1% 0.0% -4.3% 20.8% -19.9% -1.3% -4.9% -1.7% -0.4% -0.3% 7.3% -4.7% -4.0% 0.2% -10.6% 8.1% -2.7% 336 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 32.63 32.83 33.14 33.54 34.51 34.72 34.94 35.40 37.35 30.68 30.84 30.98 31.29 31.56 32.83 33.35 33.56 33.83 34.13 34.30 34.39 34.65 34.82 34.97 35.21 35.61 35.95 36.16 36.28 36.72 36.86 37.20 37.41 37.49 37.78 37.92 38.10 38.84 39.65 39.89 35.56 35.84 36.31 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 5.39E+05 3.15E+05 5.61E+05 5.37E+05 9.78E+05 5.73E+05 5.10E+05 4.64E+05 5.10E+05 5.21E+05 4.93E+05 5.01E+05 4.28E+05 4.79E+05 3.33E+05 6.47E+05 4.03E+05 3.56E+05 6.56E+05 2.84E+05 3.14E+05 7.00E+05 2.97E+05 2.79E+05 3.02E+05 3.31E+05 4.11E+05 3.49E+05 4.37E+05 8.08E+05 3.22E+05 2.84E+05 3.47E+05 3.94E+05 1.03E+06 4.35E+05 4.94E+05 7.41E+05 4.73E+05 4.43E+05 3.05E+05 2.95E+05 2.83E+05 RA 0.59 Y 0.59 Y 0.65 Y 0.66 Y 0.64 Y 0.63 Y 0.69 Y 0.65 Y 0.62 Y 1.33 Y 1.27 Y 1.36 Y 1.35 Y 1.26 Y 1.20 Y 1.21 Y 1.25 Y 1.23 Y 1.34 Y 1.23 Y 1.30 Y 1.27 Y 1.27 Y 1.25 Y 1.27 Y 1.25 Y 1.27 Y 1.21 Y 1.25 Y 1.27 Y 1.27 Y 1.16 Y 1.24 Y 1.20 Y 1.26 Y 1.23 Y 1.30 Y 1.33 Y 1.12 Y 1.33 Y 1.15 Y 1.06 Y 0.94 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.18 0.69 1.23 1.18 1.07 1.26 1.12 0.97 1.09 1.23 1.16 1.18 1.01 1.13 1.14 1.11 1.38 1.22 1.12 0.97 1.07 1.20 1.02 0.96 1.03 1.13 1.41 1.19 1.50 1.38 1.10 0.97 1.19 1.35 1.18 1.49 1.69 0.86 1.09 1.03 1.23 1.19 1.14 Dev'n 1.8% -1.1% 0.6% -2.8% -2.4% 0.2% 1.0% -2.0% -0.8% -2.8% -1.3% 0.1% -5.7% 0.9% -3.7% -2.9% 2.8% 3.1% -4.6% 5.0% -4.7% -0.6% -0.8% -3.4% 0.2% 0.1% -0.2% -0.7% -1.6% -5.0% 1.3% 0.0% 2.0% -10.0% -1.1% -1.7% 1.8% -4.7% -1.9% -4.3% -3.2% 2.3% 1.1% 337 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS0_131220_PCB_XA 20-DEC-2013 14:56 131220X02 RT 36.60 37.00 38.13 38.68 38.91 39.09 39.43 39.52 39.63 40.00 40.35 40.54 41.89 42.14 42.41 42.74 43.51 43.97 40.11 40.90 41.48 41.67 41.76 44.08 44.66 44.83 45.95 47.90 48.30 45.75 46.54 49.77 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 3.00E+05 2.82E+05 2.19E+05 2.90E+05 3.08E+05 3.10E+05 3.29E+05 2.70E+05 2.63E+05 2.64E+05 2.93E+05 5.11E+05 2.73E+05 3.33E+05 7.15E+05 3.99E+05 2.56E+05 3.84E+05 2.58E+05 2.87E+05 2.72E+05 3.10E+05 2.54E+05 3.97E+05 2.07E+05 2.16E+05 2.51E+05 2.77E+05 3.40E+05 3.21E+05 3.55E+05 2.31E+05 RA 1.06 Y 1.10 Y 1.14 Y 1.08 Y 1.11 Y 1.13 Y 1.06 Y 1.04 Y 1.16 Y 1.06 Y 1.17 Y 1.09 Y 1.07 Y 1.10 Y 1.02 Y 1.10 Y 1.10 Y 1.02 Y 0.94 Y 1.04 N 0.90 Y 0.94 Y 1.01 Y 1.02 Y 0.90 Y 0.86 Y 0.94 Y 0.96 Y 0.94 Y 0.83 Y 0.76 Y 0.73 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.21 1.14 0.88 1.02 1.08 1.09 1.16 0.95 0.93 0.93 1.03 0.90 0.96 1.17 1.26 1.41 1.09 1.63 1.05 1.16 1.10 1.26 1.03 0.80 0.84 0.87 0.79 0.88 1.07 1.09 1.20 1.09 Dev'n -1.8% 1.0% 4.6% -4.9% -4.8% -7.2% -4.0% -10.4% -6.3% -2.5% -5.4% -5.3% -3.0% -9.0% -0.4% 0.7% -4.3% -1.8% -0.7% -4.7% -1.4% 5.5% -7.2% -0.6% 0.6% 0.0% 3.5% 3.8% 1.3% -3.0% 1.1% -2.5% 338 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.34e7 2.67e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.66e7 1.33e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.89e7 9.45e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.92e7 9.60e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.07e7 5.34e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.41e6 2.71e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.18e6 2.59e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 067-110 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:09 Page 1 of 21 339 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-1 8.80e5 12.06 Rel. Int. 100% Abs. Int. 3.62e5 PCB-2 8.15e5 14.20 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.75e3 PCB-3 7.98e5 14.39 1.81e5 0% 11.0 12.0 13.0 14.0 PCB-1 2.71e5 12.06 Rel. Int. 100% PCB-2 2.53e5 14.20 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 4.15e3 15.0 0.00e0 16.0 RT Abs. Int. 1.13e5 PCB-3 2.45e5 14.38 5.63e4 0% 11.0 12.0 13.0 14.0 ES-1 1.79e8 12.05 Rel. Int. 100% 15.0 Abs. Int. 7.29e7 ES-3 1.61e8 14.37 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.78e3 0.00e0 16.0 RT 3.65e7 0% 11.0 12.0 13.0 14.0 ES-1 5.39e7 12.05 Rel. Int. 100% 15.0 Abs. Int. 2.20e7 ES-3 4.79e7 14.37 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.76e4 0.00e0 16.0 RT 1.10e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.34e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.67e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4953, 9453 scc: 067-110 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 2 of 21 340 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Rel. Int. 100% PCB-4 3.47e5 SI 14.64 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 8.63e3 PCB-10 5.64e5 SI 14.83 9.85e4 0% 11.0 12.0 13.0 14.0 Abs. Int. 1.97e5 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.66e5 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: B 4σ 2.45e4 8.28e4 PFK INTERFERENCE 0% 11.0 12.0 13.0 14.0 15.0 ES-4 6.03e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.00e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 9.69e3 1.00e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.67e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.22e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.99e3 6.10e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.34e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.67e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4218, 8363 scc: 067-110 Revised: 20-Dec-2013 16:07 (LKB) Printed: 03-Jan-2014 17:09 Page 3 of 21 341 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.03e4 PCB-9 5.43e5 SI 16.65 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-14 6.67e5 SI 19.04 PCB-6 5.66e5 SI PCB-5 17.04 6.06e5 SI 17.35 PCB-8 6.24e5 SI 17.47 PCB-11 5.75e5 SI 19.83 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 13/12 1.03e6 SI 20.12 Abs. Int. 2.00e5 PCB-15 5.93e5 SI 20.41 1.00e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% Abs. Int. 2.04e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: B 4σ 4.98e4 PFK INTERFERENCE 1.02e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.13e8 16.63 21.0 0.00e0 RT Abs. Int. 3.67e7 ES-15 1.17e8 20.39 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.06e4 1.83e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.22e7 16.63 21.0 ES-15 7.51e7 20.39 0.00e0 RT Abs. Int. 2.31e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.56e3 1.16e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7888, 3701 scc: 067-110 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 4 of 21 342 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 30/18 6.99e5 19.54 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 4.59e3 PCB-19 2.65e5 17.77 Abs. Int. 1.97e5 PCB-27 4.22e5 20.14 PCB-17 2.89e5 19.95 PCB-16 2.38e5 20.37 PCB-32 4.55e5 20.86 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.74e5 19.54 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 2.66e3 PCB-19 2.58e5 17.77 PCB-17 2.76e5 19.94 PCB-24 3.75e5 20.27 PCB-27 3.92e5 20.14 PCB-16 2.16e5 20.37 21.0 Rel. Int. 100% 18.0 19.0 20.0 PCB-32 4.23e5 20.85 21.0 9.50e4 0.00e0 RT Abs. Int. 1.93e7 ES-19 4.80e7 17.75 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 8.60e4 0.00e0 RT Abs. Int. 1.90e5 0% 17.0 9.86e4 9.63e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.74e7 ES-19 4.42e7 17.75 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 4.22e4 0.00e0 RT 8.69e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5150, 2161 scc: 067-110 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 5 of 21 343 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 28/20 8.12e5 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.52e3 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-23 PCB-34 4.13e5 4.09e5 22.16 22.01 26/29 8.20e5 22.45 PCB-31 4.46e5 22.92 21/33 8.09e5 23.39 Abs. Int. 2.07e5 PCB-22 3.85e5 23.77 PCB-36 4.01e5 25.16 PCB-39 4.25e5 25.48 PCB-38 3.67e5 26.02 PCB-35 3.62e5 26.41 PCB-37 3.75e5 26.77 0% 22.0 24.0 25.0 26.0 27.0 28/20 7.97e5 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 4.06e3 23.0 PCB-23 4.41e5 PCB-34 22.16 3.80e5 22.01 26/29 8.12e5 22.45 PCB-31 4.43e5 22.92 23.0 PCB-22 3.86e5 23.77 PCB-36 4.00e5 25.16 PCB-39 4.16e5 25.48 PCB-38 3.93e5 26.02 24.0 25.0 PCB-35 3.57e5 26.41 PCB-37 3.50e5 26.77 26.0 CS/SS-28 8.29e7 23.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e5 0% 22.0 1.03e5 27.0 0.00e0 RT Abs. Int. 2.37e7 ES-37 7.42e7 26.75 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 1.09e5 1.02e5 1.19e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 7.59e7 23.18 Rel. Int. 100% 27.0 Abs. Int. 2.19e7 ES-37 6.81e7 26.75 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 3.46e4 0.00e0 RT 1.09e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3489, 3011 scc: 067-110 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 6 of 21 344 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-54 2.35e5 20.70 Rel. Int. 100% Abs. Int. 6.46e4 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.55e3 3.23e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.74e5 20.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.82e4 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.17e3 3.91e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.22e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.63e6 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.64e4 4.31e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.06e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 7.86e3 5.58e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.66e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.33e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5717, 8453 scc: 067-110 Revised: 20-Dec-2013 16:06 (LKB) Printed: 03-Jan-2014 17:09 Page 7 of 21 345 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.01e3 50/53 4.58e5 22.70 PCB-51 2.08e5 23.37 PCB-45 1.99e5 23.29 PCB-73 2.92e5 PCB-52 24.96 2.11e5 24.83 PCB-46 1.82e5 23.57 69/49 4.95e5 25.26 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 44/47… 6.71e5 25.76 59/62… 8.68e5 26.03 PCB-48 2.15e5 25.54 PCB-42 1.96e5 26.20 71/40 4.36e5 26.63 PCB-41 1.83e5 26.54 Abs. Int. 1.53e5 PCB-64 3.04e5 26.83 7.63e4 27.0 0.00e0 RT 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.48e3 50/53 5.66e5 22.70 24.0 PCB-51 2.51e5 23.37 PCB-45 2.53e5 23.29 25.0 PCB-73 3.62e5 PCB-52 24.96 2.79e5 24.83 PCB-46 2.19e5 23.57 26.0 69/49 6.51e5 25.26 59/62… 44/47… 1.08e6 8.65e5 26.03 25.76 PCB-48 2.62e5 25.54 PCB-42 2.42e5 26.20 71/40 5.32e5 26.63 PCB-41 2.10e5 26.54 Abs. Int. 1.85e5 PCB-64 3.70e5 26.83 9.27e4 27.0 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 JS-52 3.78e7 24.81 Rel. Int. 100% Abs. Int. 1.00e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 3.08e4 5.01e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 4.64e7 24.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.96e4 6.40e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6598, 8859 scc: 067-110 Revised: 03-Jan-2014 11:21 (LKB) Printed: 03-Jan-2014 17:09 Page 8 of 21 346 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 61/70... 1.21e6 29.06 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.26e3 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-68 3.31e5 27.80 PCB-67 3.10e5 28.54 (2.70e5 + 3.56e5) * 100 pg/uL PCB-78= 1.08 2.71e5 (5.16e7 + 6.38e7) * .5 pg/uL 32.26 PCB-79 03-Jan-2014 11:20 PCB-55LKBPCB-60 PCB-80 PCB-81 2.89e5 3.24e5 2.74e5 3.36e5 2.70e5 30.12 31.77 29.49 30.44 32.64 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 1.49e5 RRF(PCB-81) = PCB-77 2.95e5 33.12 7.45e4 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 2.42e3 PCB-57 3.94e5 28.18 PCB-68 3.96e5 27.80 30.0 61/70... 1.56e6 29.06 PCB-63 4.12e5 PCB-66 3.42e5 28.77 29.34 32.0 PCB-60 3.65e5 30.12 PCB-56 3.60e5 29.93 PCB-80 4.12e5 30.45 PCB-79 4.01e5 31.77 34.0 PCB-78 3.29e5 32.26PCB-81 3.56e5 32.64 36.0 38.0 Abs. Int. 1.90e5 PCB-77 3.88e5 33.12 9.52e4 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 5.16e7 32.62 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.10e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.47e7 ES-77 5.18e7 33.10 7.37e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.38e7 32.62 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 2.52e4 36.0 38.0 0.00e0 RT Abs. Int. 1.79e7 ES-77 6.46e7 33.10 8.96e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0219, 8038 scc: 067-110 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 9 of 21 347 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-104 1.75e5 25.71 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 8.14e2 Abs. Int. 4.89e4 PCB-96 1.63e5 26.03 2.44e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.74e5 25.71 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 9.29e2 27.0 0.00e0 RT Abs. Int. 7.44e4 PCB-96 2.17e5 26.02 3.72e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 3.88e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.91e6 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.55e3 4.96e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.37e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.05e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.87e3 3.03e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.89e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5253, 4725 scc: 067-110 Revised: 20-Dec-2013 16:06 (LKB) Printed: 03-Jan-2014 17:09 Page 10 of 21 348 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 108/119... 1.04e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 2.21e3 PCB-103 1.61e5 27.72 100/93 2.88e5 28.51 PCB-88 1.75e5 29.00 PCB-121 2.11e5 30.01 113/90… 5.12e5 30.82 116/85 3.42e5 32.43 PCB-99 1.52e5 31.36 PCB-111 2.21e5 PCB-120 2.13e5 33.14 33.54 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-118 107/124 2.20e5 3.81e5 35.10 34.51 PCB-114 PCB-123 2.18e5 2.12e5 35.57 34.82 Abs. Int. 1.54e5 PCB-105 2.05e5 36.11 PCB-127 1.96e5 37.35 7.68e4 0% 28.0 30.0 32.0 108/119... 1.64e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 4.66e3 34.0 PCB-94 2.12e5 27.91 100/93 4.76e5 28.51 PCB-91 2.21e5 29.06 PCB-121 3.28e5 30.01 113/90… 8.33e5 30.82 PCB-112 3.11e5 31.45 116/85 PCB-115 5.86e5 3.38e5 32.43 32.63 PCB-117 PCB-110 PCB-111 PCB-120 3.40e5 3.00e5 3.06e5 3.24e5 33.14 32.34 32.54 33.54 36.0 PCB-118 107/124 3.27e5 5.97e5 35.10 34.51 PCB-123 PCB-114 3.37e5 3.26e5 34.82 35.57 38.0 Abs. Int. 2.29e5 PCB-105 3.25e5 36.11 PCB-127 3.14e5 37.35 1.14e5 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.86e7 33.12 JS-101 4.75e7 30.82 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.00e3 34.0 36.0 ES-123 5.61e7 34.80 ES-118 ES-114 5.68e7 5.90e7 35.08 35.55 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.47e7 ES-105 5.80e7 36.09 7.34e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 3.66e7 33.12 JS-101 2.91e7 30.82 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.10e3 34.0 36.0 ES-118 ES-114 3.61e7 ES-123 3.46e7 35.55 3.52e7 35.08 34.80 38.0 0.00e0 RT Abs. Int. 9.50e6 ES-105 3.59e7 36.09 4.75e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7393, 8355 scc: 067-110 Revised: 03-Jan-2014 16:46 (LKB) Printed: 03-Jan-2014 17:09 Page 11 of 21 349 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 3.76e4 PCB-126 1.64e5 38.73 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.18e3 1.88e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.47e4 PCB-126 2.67e5 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.48e3 3.23e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.25e7 ES-126 5.01e7 38.71 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 5.64e3 6.27e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.77e6 ES-126 3.21e7 38.71 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 4.88e3 3.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4712, 3338 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 12 of 21 350 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PCB-155 PCB-150 2.97e5 2.89e5 30.98 30.68 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.52e2 PCB-145 2.67e5 31.56 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 163/138… 5.74e5 153/168 PCB-13737.78 4.52e5 1.92e5 36.72 37.41 PCB-160 151/135PCB-144 PCB-164 3.54e5 1.97e5 PCB-143 PCB-142 PCB-133 PCB-146 PCB-141 2.14e5 2.40e5 1.80e5 37.92 1.78e5 1.55e5 33.35 33.83 37.49 1.84e5 1.91e5 36.86 36.16 34.39 34.97 35.61 147/149 139/140 3.75e5 3.92e5 34.65 34.13 PCB-148 1.82e5 32.83 0% 28.0 30.0 32.0 PCB-152 2.17e5 30.84 PCB-136 PCB-155 1.82e5 PCB-145 2.24e5 31.28 2.11e5 30.68 31.56 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 8.44e2 34.0 PCB-148 1.51e5 32.83 139/140 147/149 3.08e5 151/135 2.80e5 34.65 2.92e5 34.13 33.35 PCB-154 PCB-143 PCB-131 1.79e5 1.37e5 1.31e5 33.56 34.39 34.82 36.0 PCB-133 1.47e5 PCB-165 35.61 1.81e5 35.95 38.0 153/168 3.56e5 36.72 163/138… 4.56e5 37.78 PCB-141 PCB-137 1.42e5 1.55e5 37.40 36.86 PCB-158 2.14e5 38.10 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.81e7 30.66 Rel. Int. 100% ES-153 3.32e7 36.67 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.51e3 Abs. Int. 1.11e5 5.57e4 0.00e0 RT Abs. Int. 8.34e4 4.17e4 0.00e0 RT Abs. Int. 1.25e7 JS-138 2.94e7 37.74 6.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.70e7 30.66 Rel. Int. 100% ES-153 2.52e7 36.67 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.03e3 0.00e0 RT Abs. Int. 9.38e6 JS-138 2.20e7 37.74 4.69e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.60e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6209, 6582 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 13 of 21 351 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.23e5 38.84 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.22e3 PCB-159 2.50e5 39.65 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-162 2.53e5 39.89 156/157 4.75e5 41.28 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 Abs. Int. 1.04e5 PCB-169 2.58e5 44.00 PCB-167 2.54e5 40.30 5.20e4 0% 39.0 Rel. Int. 100% 128/166 3.18e5 38.83 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.11e3 40.0 41.0 42.0 43.0 44.0 45.0 156/157 4.04e5 41.28 PCB-159 PCB-162 2.23e5 1.90e5 39.65 39.89 Abs. Int. 7.56e4 PCB-169 1.85e5 44.00 PCB-167 2.28e5 40.30 3.78e4 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 4.87e7 40.28 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 9.39e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 9.32e7 41.26 0.00e0 RT Abs. Int. 1.67e7 ES-169 4.45e7 43.98 8.34e6 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 3.78e7 40.28 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 6.54e3 42.0 43.0 44.0 45.0 ES-156/157 7.11e7 41.26 0.00e0 RT Abs. Int. 1.29e7 ES-169 3.46e7 43.98 6.47e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3213, 6781 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 14 of 21 352 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Rel. Int. 100% PCB-188 1.63e5 35.56 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-179 1.52e5 PCB-184 35.84 1.37e5 36.31 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.36e2 PCB-186 1.48e5 37.00 PCB-178 1.17e5 38.13 Abs. Int. 4.15e4 2.08e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.42e5 35.56 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.81e2 PCB-179 1.44e5 35.84 37.0 PCB-176 1.46e5 36.60 PCB-186 1.35e5 37.00 38.0 Abs. Int. 3.92e4 PCB-178 1.02e5 38.13 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.61e7 35.54 Rel. Int. 100% CS/SS-178 1.63e7 38.11 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.35e7 35.54 Rel. Int. 100% CS/SS-178 1.53e7 38.11 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.47e6 0.00e0 RT Abs. Int. 5.99e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.39e3 31.0 1.96e4 Abs. Int. 6.93e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.30e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 2.99e6 0.00e0 RT Abs. Int. 1.89e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.45e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6881, 0191 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 15 of 21 353 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.06e3 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-185 1.38e5 171/173 39.52 2.66e5 PCB-182 1.65e5 PCB-183 PCB-174 PCB-177 PCB-181 40.54 1.69e5 1.35e5 1.58e5 39.09 1.42e5 39.4339.63 40.00 40.35 180/193 3.61e5 42.41 PCB-172 1.41e5 41.89 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-191 2.09e5 42.74 PCB-170 1.34e5 43.51 Abs. Int. 5.93e4 PCB-190 1.94e5 43.97 2.96e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 9.28e2 40.0 PCB-182 1.45e5 39.09 PCB-183 1.60e5 PCB-187 39.43 1.46e5 38.91 41.0 42.0 43.0 180/193 3.54e5 42.41 171/173 PCB-177 PCB-181 2.44e5 1.28e5 1.35e5 40.54 40.00 40.35 PCB-191 1.90e5 42.74 PCB-172 1.32e5 41.89 44.0 45.0 PCB-190 1.90e5 43.97 Abs. Int. 5.34e4 PCB-170 1.22e5 43.52 2.67e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 ES-180 2.95e7 42.43 (2.46e7 + 2.25e7) 8 100 pg/uL RRF(ES-170) = = 0.924 (2.46e7 + 2.64e7) * 100 pg/uL LKB 03-Jan-2014 11:42 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.94e3 43.0 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 7.54e6 ES-170 2.46e7 43.50 3.77e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.74e7 42.43 Rel. Int. 100% 44.0 45.0 Abs. Int. 6.83e6 ES-170 2.25e7 43.50 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 1.82e3 0.00e0 RT 3.42e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3799, 6132 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 16 of 21 354 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-189 2.24e5 46.13 Abs. Int. 5.27e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.21e3 2.63e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.18e5 46.13 Abs. Int. 5.43e4 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 7.69e2 2.72e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.19e7 46.11 0.00e0 RT Abs. Int. 1.03e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 3.48e3 5.16e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.02e7 46.11 0.00e0 RT Abs. Int. 9.81e6 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 5.08e3 4.90e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2597, 5520 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 17 of 21 355 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-202 1.25e5 40.11 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 5.85e2 PCB-201 1.58e5 40.90 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 198/199 2.01e5 44.08 PCB-197 1.51e5 PCB-204 41.67 PCB-200 1.28e5 1.29e5 41.76 41.48 Abs. Int. 4.15e4 PCB-196 9.79e4 44.66 PCB-203 9.97e4 44.83 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.33e5 40.11 41.0 PCB-201 1.52e5 40.90 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 8.32e2 42.0 43.0 PCB-197 1.60e5 PCB-204 41.67 PCB-200 1.26e5 1.43e5 41.76 41.48 44.0 198/199 1.96e5 44.08 45.0 2.08e4 0.00e0 RT Abs. Int. 4.09e4 PCB-196 1.09e5 44.66 PCB-203 1.16e5 44.83 2.04e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.37e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.85e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.16e3 2.92e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.57e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.36e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 2.16e3 3.18e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3435, 2261 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 18 of 21 356 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 6.43e2 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 PCB-195 1.22e5 45.95 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-205 1.65e5 48.30 PCB-194 1.36e5 47.90 Abs. Int. 3.94e4 1.97e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 9.26e2 47.0 48.0 50.0 PCB-205 1.75e5 48.30 PCB-194 1.41e5 47.90 PCB-195 1.30e5 45.95 49.0 0.00e0 RT Abs. Int. 4.19e4 2.10e4 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.00e7 48.28 JS-194 2.46e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 4.05e3 49.0 0.00e0 RT Abs. Int. 7.11e6 3.56e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.33e7 48.28 Rel. Int. 100% Abs. Int. 7.81e6 JS-194 2.64e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.43e3 0.00e0 RT 3.91e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3437, 5090 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 19 of 21 357 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.06e3 PCB-208 1.46e5 45.75 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-207 1.53e5 46.54 Abs. Int. 3.84e4 PCB-206 9.77e4 49.77 1.92e4 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.83e3 PCB-208 1.75e5 45.74 47.0 48.0 49.0 PCB-207 2.02e5 46.54 50.0 Abs. Int. 4.66e4 PCB-206 1.33e5 49.77 2.33e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.64e7 45.73 50.0 0.00e0 RT Abs. Int. 6.27e6 ES-206 1.90e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.29e3 3.13e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.25e7 45.73 50.0 Abs. Int. 7.77e6 ES-206 2.34e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.08e3 0.00e0 RT 3.89e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6144, 7443 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 20 of 21 358 of 603 SGS-AP ID: CS0_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-6 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 37 Acq: 20-Dec-2013 14:56:33 User: LKB Datafile: 131220X02 PCB-209 1.84e5 51.25 Rel. Int. 100% Abs. Int. 4.31e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 4.82e2 2.16e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.52e5 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.02e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.04e2 1.51e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.09e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.59e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 8.47e2 3.29e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.60e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.33e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.14e2 2.66e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.18e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.59e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS0_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4095, 3490 scc: 067-110 PKD: 20-Dec-2013 16:13 Printed: 03-Jan-2014 17:09 Page 21 of 21 359 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.15e7 2.57e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.58e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.83e7 9.14e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.88e7 9.41e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.05e7 5.26e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.25e6 2.63e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.06e6 2.53e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 983-753 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:09 Page 1 of 21 360 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.12 32.64 36.12 35.58 35.11 34.82 38.73 41.29 40.30 44.01 46.14 51.26 1.44E+06 1.43E+06 1.07E+06 1.23E+06 1.13E+06 1.24E+06 9.39E+05 1.93E+06 1.07E+06 9.43E+05 8.81E+05 6.80E+05 0.79 Y 0.81 Y 0.63 Y 0.64 Y 0.62 Y 0.61 Y 0.63 Y 1.26 Y 1.25 Y 1.29 Y 1.07 Y 1.22 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.11 1.13 1.02 1.16 1.13 1.20 1.07 1.07 1.13 1.07 1.00 1.10 -3.6% 0.8% -7.9% -3.3% -5.3% -1.2% -3.3% -2.5% -2.8% -4.8% -6.6% -1.1% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.05 14.37 14.63 20.39 17.75 26.75 20.68 33.10 32.63 25.69 36.09 35.55 35.09 34.80 38.71 36.68 30.66 41.27 40.28 43.99 43.50 42.43 35.55 46.12 40.09 48.29 49.76 45.73 51.23 2.45E+08 2.19E+08 1.05E+08 2.08E+08 1.01E+08 1.55E+08 8.14E+07 1.30E+08 1.27E+08 6.93E+07 1.04E+08 1.06E+08 1.01E+08 1.03E+08 8.78E+07 6.38E+07 9.19E+07 1.81E+08 9.51E+07 8.81E+07 5.21E+07 6.14E+07 5.38E+07 8.78E+07 5.52E+07 6.89E+07 4.58E+07 6.49E+07 6.17E+07 3.30 Y 3.33 Y 1.62 Y 1.56 Y 1.09 Y 1.10 Y 0.81 Y 0.82 Y 0.82 Y 1.68 Y 1.61 Y 1.64 Y 1.61 Y 1.61 Y 1.58 Y 1.31 Y 1.28 Y 1.29 Y 1.28 Y 1.26 Y 1.09 Y 1.09 Y 1.11 Y 1.03 Y 0.93 Y 0.90 Y 0.81 Y 0.80 Y 1.20 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.22 1.09 0.52 1.04 0.50 1.64 0.86 1.37 1.35 0.80 1.21 1.22 1.17 1.20 1.02 1.11 1.60 1.57 1.65 1.53 0.93 1.10 0.93 1.57 0.96 1.23 0.82 1.16 1.10 2.1% 0.4% -0.1% -0.5% -0.8% -1.1% 0.2% -0.7% -1.5% 0.0% 0.7% 0.5% 0.8% 0.9% -0.9% -0.4% 0.6% -1.9% -1.0% -1.6% -1.8% -3.7% -0.5% -1.0% -1.1% -1.2% -1.4% -1.4% -0.7% Page 1 of 6 361 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.18 33.12 38.12 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.58 Y 1.10 Y 1.11 1.03 0.62 1.12 1.02 0.61 0.7% -0.8% -1.9% CS PCB-28 CS PCB-111 CS PCB-178 23.18 33.12 38.12 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.58 Y 1.10 Y 1.85 1.22 0.58 1.84 1.22 0.57 -0.4% 0.1% -2.4% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.63 24.81 30.82 37.74 47.89 2.01E+08 9.43E+07 8.62E+07 5.75E+07 5.60E+07 1.58 Y 0.81 Y 1.61 Y 1.31 Y 0.90 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.06 14.39 14.65 20.41 17.77 26.77 20.70 25.71 30.68 35.57 40.11 48.31 45.75 49.78 2.30E+06 2.16E+06 1.26E+06 2.04E+06 1.13E+06 1.62E+06 1.09E+06 9.78E+05 1.15E+06 7.09E+05 5.78E+05 7.06E+05 7.23E+05 5.11E+05 3.36 Y 3.09 Y 1.52 Y 1.55 Y 1.07 Y 1.01 Y 0.81 Y 0.64 Y 1.32 Y 1.05 Y 0.95 Y 0.90 Y 0.82 Y 0.79 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.94 0.98 1.20 0.98 1.12 1.05 1.34 1.41 1.25 1.32 1.05 1.03 1.11 1.11 -1.3% -2.5% -2.4% -4.0% -2.6% -3.0% -0.7% -1.5% -1.1% 3.9% -0.5% -3.2% -0.7% 0.0% Page 2 of 6 362 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 12.06 14.20 14.39 14.65 14.83 16.65 16.82 17.04 17.35 17.47 19.04 19.83 20.12 20.41 17.77 19.54 19.95 20.14 20.28 20.37 20.85 22.01 22.16 22.45 22.64 22.93 23.21 23.39 23.77 25.16 25.48 26.02 26.41 26.77 20.70 22.70 23.29 23.37 23.57 24.83 24.97 25.06 25.26 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 2.30E+06 2.22E+06 2.16E+06 1.26E+06 1.99E+06 1.98E+06 2.15E+06 1.96E+06 1.92E+06 2.06E+06 2.37E+06 1.97E+06 4.01E+06 2.04E+06 1.13E+06 2.96E+06 1.29E+06 1.77E+06 1.71E+06 9.51E+05 1.93E+06 1.70E+06 1.69E+06 3.54E+06 1.76E+06 1.79E+06 3.35E+06 3.53E+06 1.63E+06 1.74E+06 1.81E+06 1.68E+06 1.52E+06 1.62E+06 1.09E+06 2.16E+06 9.68E+05 1.04E+06 8.57E+05 1.06E+06 1.35E+06 8.63E+05 2.50E+06 RA 3.36 Y 3.19 Y 3.09 Y 1.52 Y 1.53 Y 1.52 Y 1.55 Y 1.59 Y 1.63 Y 1.64 Y 1.53 Y 1.60 Y 1.64 Y 1.55 Y 1.07 Y 1.02 Y 1.05 Y 1.07 Y 1.05 Y 1.08 Y 1.04 Y 1.01 Y 1.02 Y 1.00 Y 0.93 Y 1.00 Y 0.97 Y 1.00 Y 0.98 Y 0.96 Y 0.98 Y 1.02 Y 0.97 Y 1.01 Y 0.81 Y 0.78 Y 0.81 Y 0.82 Y 0.74 Y 0.77 Y 0.75 Y 0.75 Y 0.75 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.94 1.01 0.98 1.20 1.90 0.95 1.03 0.94 0.92 0.99 1.14 0.95 0.96 0.98 1.12 1.47 1.28 1.76 1.69 0.94 1.91 1.09 1.09 1.14 1.14 1.16 1.08 1.14 1.05 1.12 1.16 1.08 0.98 1.05 1.34 0.85 0.76 0.82 0.68 0.83 1.06 0.68 0.98 Dev'n -1.3% -2.1% -2.5% -2.4% -4.3% 0.8% -1.3% -5.2% -7.9% -4.3% -3.6% -6.2% -2.7% -4.0% -2.6% -4.3% -1.9% -3.4% -1.8% -6.2% -0.2% -3.6% -5.7% -2.6% -1.8% -5.5% -4.5% -3.0% -2.5% -4.1% -3.9% -1.9% -5.4% -3.0% -0.7% -2.9% -0.6% -4.6% -3.4% -1.4% -4.6% -4.4% -3.8% 363 of 603 PCB QC Summary - Ax2 Detail Lab ID: CS1_131220_PCB_XA Acquired: 20-DEC-2013 16:14 Datafile: 131220X03 Name RT PCB-48 22'45-TeCB 25.54 PCB-44/47/65 ...-TeCB 25.76 PCB-59/62/75 ...-TeCB 26.04 PCB-42 22'34'-TeCB 26.20 PCB-41 22'34-TeCB 26.54 PCB-71/40 23'4'6/22'33'-TeCB 26.63 PCB-64 234'6-TeCB 26.83 PCB-72 23'55'-TeCB 27.55 PCB-68 23'45'-TeCB 27.81 PCB-57 233'5-TeCB 28.18 PCB-58 233'5'-TeCB 28.38 PCB-67 23'45-TeCB 28.54 PCB-63 234'5-TeCB 28.77 PCB-61/70/74/76 ...-TeCB 29.06 PCB-66 23'44'-TeCB 29.34 PCB-55 233'4-TeCB 29.49 PCB-56 233'4'-TeCB 29.93 PCB-60 2344'-TeCB 30.12 PCB-80 33'55'-TeCB 30.45 PCB-79 33'45'-TeCB 31.78 PCB-78 33'45-TeCB 32.27 PCB-104 22'466'-PeCB 25.71 PCB-96 22'366'-PeCB 26.03 PCB-103 22'45'6-PeCB 27.72 PCB-94 22'356'-PeCB 27.91 PCB-95 22'35'6-PeCB 28.30 PCB-100/93 22'44'6/22'356-PeCB 28.51 PCB-102 22'456'-PeCB 28.63 PCB-98 22'34'6'-PeCB 28.69 PCB-88 22'346-PeCB 28.99 PCB-91 22'34'6-PeCB 29.06 PCB-84 22'33'6-PeCB 29.25 PCB-89 22'346'-PeCB 29.67 PCB-121 23'45'6-PeCB 30.02 PCB-92 22'355'-PeCB 30.33 PCB-113/90/101 ...-PeCB 30.82 PCB-83 22'33'5-PeCB 31.26 PCB-99 22'44'5-PeCB 31.36 PCB-112 233'56-PeCB 31.46 PCB-108/119/86/97/125...-PeCB 31.80 PCB-117 234'56-PeCB 32.34 PCB-116/85 23456/22'344'-PeCB 32.43 PCB-110 233'4'6-PeCB 32.54 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.01E+06 3.36E+06 4.29E+06 9.26E+05 8.37E+05 2.09E+06 1.50E+06 1.50E+06 1.57E+06 1.41E+06 1.44E+06 1.59E+06 1.60E+06 5.90E+06 1.35E+06 1.40E+06 1.33E+06 1.42E+06 1.64E+06 1.69E+06 1.26E+06 9.78E+05 8.58E+05 9.36E+05 7.83E+05 8.29E+05 1.71E+06 9.57E+05 7.04E+05 7.38E+05 9.82E+05 6.84E+05 7.66E+05 1.19E+06 8.33E+05 2.96E+06 7.27E+05 9.10E+05 1.16E+06 5.82E+06 1.19E+06 1.79E+06 1.10E+06 RA 0.77 Y 0.79 Y 0.80 Y 0.75 Y 0.80 Y 0.82 Y 0.75 Y 0.80 Y 0.77 Y 0.85 Y 0.79 Y 0.76 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.78 Y 0.78 Y 0.76 Y 0.80 Y 0.77 Y 0.64 Y 0.71 Y 0.64 Y 0.65 Y 0.59 Y 0.59 Y 0.62 Y 0.64 Y 0.59 Y 0.56 Y 0.58 Y 0.63 Y 0.67 Y 0.61 Y 0.62 Y 0.67 Y 0.63 Y 0.65 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.79 0.88 1.13 0.73 0.66 0.82 1.18 1.18 1.24 1.11 1.13 1.25 1.26 1.16 1.06 1.10 1.05 1.12 1.29 1.33 0.99 1.41 1.24 0.91 0.76 0.80 0.83 0.93 0.68 0.72 0.95 0.66 0.74 1.15 0.81 0.96 0.70 0.88 1.12 0.94 1.15 0.87 1.07 Dev'n -5.5% -2.5% -3.3% -4.4% -5.2% -4.1% -3.1% -2.1% -3.0% -4.3% -4.0% -0.7% -3.2% -3.0% -3.5% -1.8% -5.4% -1.4% -1.8% 1.6% -6.5% -1.5% 0.8% -2.5% -5.2% -7.3% -4.0% -4.2% -10.0% -10.4% 0.8% -7.4% -2.8% -3.9% -1.6% -2.9% -1.5% -4.2% -3.8% -4.0% 1.3% -7.6% -4.4% 364 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 32.63 32.83 33.15 33.54 34.51 34.72 34.94 35.40 37.35 30.68 30.84 30.98 31.29 31.56 32.83 33.36 33.57 33.83 34.13 34.31 34.39 34.66 34.83 34.98 35.21 35.61 35.95 36.17 36.29 36.72 36.86 37.21 37.41 37.49 37.78 37.92 38.10 38.84 39.65 39.89 35.57 35.85 36.32 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 1.15E+06 6.91E+05 1.20E+06 1.18E+06 2.12E+06 1.09E+06 1.12E+06 1.01E+06 1.08E+06 1.15E+06 1.03E+06 1.02E+06 8.99E+05 1.00E+06 7.25E+05 1.44E+06 8.24E+05 7.12E+05 1.47E+06 5.72E+05 7.05E+05 1.49E+06 6.51E+05 5.89E+05 6.45E+05 7.07E+05 8.89E+05 7.40E+05 9.19E+05 1.81E+06 6.67E+05 6.08E+05 7.27E+05 9.46E+05 2.21E+06 9.44E+05 1.05E+06 1.64E+06 1.05E+06 9.62E+05 7.09E+05 6.25E+05 5.87E+05 RA 0.66 Y 0.62 Y 0.64 Y 0.65 Y 0.63 Y 0.61 Y 0.63 Y 0.63 Y 0.63 Y 1.32 Y 1.37 Y 1.19 Y 1.33 Y 1.26 Y 1.41 Y 1.27 Y 1.31 Y 1.24 Y 1.29 Y 1.37 Y 1.29 Y 1.23 Y 1.25 Y 1.28 Y 1.26 Y 1.26 Y 1.25 Y 1.25 Y 1.24 Y 1.24 Y 1.26 Y 1.33 Y 1.30 Y 1.33 Y 1.21 Y 1.29 Y 1.33 Y 1.18 Y 1.27 Y 1.13 Y 1.05 Y 1.09 Y 1.02 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.11 0.67 1.17 1.14 1.03 1.05 1.08 0.96 1.04 1.25 1.12 1.10 0.98 1.09 1.14 1.13 1.29 1.12 1.15 0.90 1.10 1.16 1.02 0.92 1.01 1.11 1.39 1.16 1.44 1.42 1.05 0.95 1.14 1.48 1.15 1.48 1.64 0.86 1.11 1.01 1.32 1.16 1.09 Dev'n -4.2% -4.0% -4.5% -5.6% -6.4% -16.1% -2.0% -3.7% -5.5% -1.1% -4.2% -6.1% -8.3% -2.4% -3.9% -1.1% -3.8% -5.7% -2.3% -3.0% -2.2% -3.5% -0.6% -6.8% -2.0% -2.1% -1.1% -3.5% -5.3% -2.7% -4.0% -2.0% -2.1% -1.0% -3.2% -2.3% -1.2% -4.3% -0.8% -5.6% 3.9% 0.1% -3.2% 365 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS1_131220_PCB_XA 20-DEC-2013 16:14 131220X03 RT 36.61 37.01 38.14 38.69 38.91 39.09 39.44 39.52 39.63 40.01 40.36 40.54 41.89 42.14 42.42 42.75 43.52 43.98 40.11 40.90 41.48 41.67 41.76 44.09 44.67 44.84 45.96 47.91 48.31 45.75 46.54 49.78 Printed: 3-Jan-2014 16:54 ICAL: 131220 QC MM7 Response 6.55E+05 5.96E+05 4.31E+05 6.43E+05 6.87E+05 6.98E+05 7.24E+05 6.34E+05 6.37E+05 5.78E+05 6.58E+05 1.11E+06 5.95E+05 7.80E+05 1.50E+06 8.57E+05 5.51E+05 8.22E+05 5.78E+05 6.75E+05 6.21E+05 6.41E+05 5.73E+05 8.75E+05 4.40E+05 4.68E+05 5.10E+05 5.61E+05 7.06E+05 7.23E+05 7.50E+05 5.11E+05 RA 1.14 Y 1.00 Y 1.08 Y 1.04 Y 1.08 Y 1.03 Y 1.15 Y 1.02 Y 1.07 Y 1.13 Y 1.09 Y 1.08 Y 1.09 Y 1.06 Y 0.95 Y 1.12 Y 0.98 Y 1.07 Y 0.95 Y 0.92 Y 0.94 Y 0.90 Y 0.90 Y 0.91 Y 0.99 Y 0.92 Y 0.94 Y 0.90 Y 0.90 Y 0.82 Y 0.80 Y 0.79 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.22 1.11 0.80 1.05 1.12 1.14 1.18 1.03 1.04 0.94 1.07 0.90 0.97 1.27 1.22 1.40 1.06 1.58 1.05 1.22 1.13 1.16 1.04 0.79 0.80 0.85 0.74 0.82 1.03 1.11 1.16 1.11 Dev'n -1.2% -1.5% -4.9% -2.3% -1.7% -3.2% -2.1% -2.6% 4.9% -1.0% -1.4% -4.7% -2.0% -1.3% -3.0% 0.1% -6.8% -5.0% -0.5% 0.1% 0.8% -2.4% -6.2% -2.0% -4.4% -3.0% -3.4% -3.3% -3.2% -0.7% -2.9% 0.0% 366 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-1 1.77e6 12.06 Rel. Int. 100% PCB-2 1.69e6 14.20 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.00e3 Abs. Int. 7.15e5 PCB-3 1.63e6 14.39 3.57e5 0% 11.0 12.0 13.0 PCB-1 5.28e5 12.06 Rel. Int. 100% 14.0 PCB-2 5.29e5 14.20 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.63e3 15.0 0.00e0 16.0 RT Abs. Int. 2.17e5 PCB-3 5.27e5 14.38 1.08e5 0% 11.0 12.0 13.0 14.0 ES-1 1.88e8 12.05 Rel. Int. 100% 15.0 Abs. Int. 7.30e7 ES-3 1.69e8 14.37 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.69e3 0.00e0 16.0 RT 3.65e7 0% 11.0 12.0 13.0 14.0 ES-1 5.69e7 12.05 Rel. Int. 100% 15.0 Abs. Int. 2.24e7 ES-3 5.06e7 14.37 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.35e4 0.00e0 16.0 RT 1.12e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2722, 6482 scc: 983-753 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 2 of 21 367 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Rel. Int. 100% PCB-4 7.61e5 14.65 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 5.83e3 PCB-10 1.20e6 14.83 2.01e5 0% 11.0 12.0 13.0 14.0 Rel. Int. 100% 15.0 PCB-4 5.00e5 14.64 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.52e4 PCB-10 7.85e5 14.83 0% 12.0 13.0 0.00e0 16.0 RT Abs. Int. 2.69e5 1.35e5 PFK INTERFERENCE 11.0 Abs. Int. 4.03e5 14.0 15.0 ES-4 6.48e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.20e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 1.02e4 1.10e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.00e7 14.63 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.35e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.10e3 6.77e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9174, 6214 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:09 Page 3 of 21 368 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 8.83e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-6 1.21e6 17.04 PCB-9 1.20e6 16.65 PCB-14 1.43e6 19.04 PCB-5 1.19e6 17.35 PCB-8 1.28e6 17.47 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-11 1.22e6 19.83 13/12 2.49e6 20.12 Abs. Int. 4.02e5 PCB-15 1.24e6 20.41 2.01e5 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.29e4 PCB-9 7.88e5 16.65 PCB-7 8.44e5 16.82 18.0 19.0 PCB-14 9.38e5 19.04 PCB-5 7.31e5 PCB-8 17.35 7.79e5 17.47 PFK INTERFERENCE 20.0 PCB-11 7.59e5 19.83 13/12 1.52e6 20.12 21.0 Abs. Int. 3.35e5 PCB-15 7.98e5 20.41 1.67e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.23e8 16.63 21.0 0.00e0 RT Abs. Int. 3.85e7 ES-15 1.27e8 20.39 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.10e4 1.93e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.80e7 16.63 21.0 ES-15 8.13e7 20.39 0.00e0 RT Abs. Int. 2.48e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.06e3 1.24e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9567, 5816 scc: 983-753 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 4 of 21 369 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 30/18 1.50e6 19.54 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.85e3 PCB-19 5.82e5 17.77 Abs. Int. 4.10e5 PCB-27 9.13e5 20.14 PCB-17 6.61e5 19.95 PCB-16 4.95e5 20.37 PCB-32 9.84e5 20.85 2.05e5 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 1.47e6 19.54 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 2.47e3 PCB-19 5.45e5 17.76 PCB-17 6.30e5 19.95 21.0 Abs. Int. 4.07e5 PCB-27 8.57e5 20.14 PCB-16 4.56e5 20.37 PCB-32 9.46e5 20.85 2.04e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 0.00e0 RT Abs. Int. 2.14e7 ES-19 5.26e7 17.75 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 7.23e4 0.00e0 RT 1.07e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.97e7 ES-19 4.83e7 17.75 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 4.38e4 0.00e0 RT 9.86e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7724, 7248 scc: 983-753 Revised: 27-Dec-2013 11:30 (LKB) Printed: 03-Jan-2014 17:09 Page 5 of 21 370 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 28/20 1.65e6 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.02e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-23 PCB-34 8.55e5 8.51e5 22.16 22.01 26/29 1.77e6 22.45 PCB-31 8.95e5 22.93 Abs. Int. 4.21e5 PCB-22 8.08e5 23.77 PCB-36 8.50e5 25.16 PCB-39 8.93e5 25.48 PCB-38 8.46e5 26.02 PCB-35 7.51e5 26.41 PCB-37 8.13e5 26.77 0% 22.0 24.0 25.0 26.0 27.0 28/20 1.70e6 23.21 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.84e3 23.0 PCB-23 PCB-34 8.35e5 8.46e5 22.16 22.01 26/29 1.77e6 22.45 PCB-31 9.00e5 22.92 23.0 PCB-22 8.24e5 23.77 PCB-36 8.89e5 25.16 PCB-39 9.12e5 25.48 PCB-38 8.33e5 26.02 24.0 25.0 PCB-35 7.74e5 26.41 PCB-37 8.08e5 26.77 26.0 CS/SS-28 9.06e7 23.18 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.28e5 0% 22.0 2.11e5 27.0 0.00e0 RT Abs. Int. 2.54e7 ES-37 8.13e7 26.75 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 1.13e5 2.14e5 1.27e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.29e7 23.18 Rel. Int. 100% 27.0 Abs. Int. 2.36e7 ES-37 7.38e7 26.75 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 3.74e4 0.00e0 RT 1.18e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2047, 2588 scc: 983-753 Revised: 27-Dec-2013 11:30 (LKB) Printed: 03-Jan-2014 17:09 Page 6 of 21 371 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-54 4.89e5 20.70 Rel. Int. 100% Abs. Int. 1.37e5 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.36e3 6.83e4 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 6.03e5 20.70 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e5 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.17e3 9.39e4 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.65e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 2.02e4 5.12e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.49e7 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 8.82e3 6.20e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7968, 7088 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:09 Page 7 of 21 372 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 1.58e3 50/53 9.50e5 22.70 PCB-51 4.70e5 23.37 PCB-45 4.32e5 23.29 PCB-73 PCB-52 5.78e5 4.59e5 24.97 24.83 PCB-46 3.64e5 23.57 69/49 1.07e6 25.26 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 44/47… 1.48e6 25.76 59/62… 1.91e6 26.04 PCB-48 4.38e5 25.54 PCB-42 3.97e5 26.20 71/40 9.42e5 26.63 PCB-41 3.71e5 26.54 Abs. Int. 3.53e5 PCB-64 6.46e5 26.83 1.77e5 27.0 0.00e0 RT 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.72e3 50/53 1.21e6 22.70 24.0 PCB-51 5.71e5 23.37 PCB-45 5.36e5 23.29 25.0 PCB-73 7.69e5 PCB-52 24.97 5.98e5 24.83 PCB-46 4.93e5 23.57 26.0 69/49 1.42e6 25.26 59/62… 44/47… 2.38e6 1.87e6 26.04 25.76 PCB-48 5.68e5 25.54 PCB-42 5.29e5 26.20 71/40 1.15e6 26.63 PCB-41 4.66e5 26.54 Abs. Int. 4.32e5 PCB-64 8.56e5 26.83 2.16e5 27.0 0.00e0 RT 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.22e7 24.81 Rel. Int. 100% Abs. Int. 1.13e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.67e4 5.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.21e7 24.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.42e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 2.28e4 7.10e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4359, 5676 scc: 983-753 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:09 Page 8 of 21 373 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 61/70... 2.59e6 29.06 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 3.33e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-57 6.50e5 28.18 PCB-63 7.04e5 28.77 PCB-55 6.16e5 29.49 Abs. Int. 3.24e5 PCB-60 6.21e5 PCB-80 7.09e5 30.12 30.45 PCB-81 6.42e5 32.64 PCB-79 7.50e5 31.78 PCB-77 6.36e5 33.12 1.62e5 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 2.68e3 PCB-68 8.90e5 27.81 30.0 61/70... 3.32e6 PCB-60 PCB-67 29.06 8.00e5 9.01e5 30.12 28.54 PCB-63 PCB-66 PCB-80 PCB-56 8.91e5 7.50e5 9.28e5 7.48e5 28.77 29.34 30.45 29.93 32.0 34.0 36.0 38.0 Abs. Int. 4.24e5 PCB-81 7.90e5 32.64 PCB-79 9.35e5 31.78 PCB-77 8.03e5 33.12 2.12e5 0% 28.0 30.0 0.00e0 RT 32.0 Rel. Int. 100% 34.0 ES-81 5.70e7 32.63 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.49e4 36.0 38.0 0.00e0 RT Abs. Int. 1.53e7 ES-77 5.83e7 33.10 7.63e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.00e7 32.63 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.91e4 36.0 38.0 0.00e0 RT Abs. Int. 1.88e7 ES-77 7.13e7 33.10 9.38e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8043, 1494 scc: 983-753 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 27-Dec-2013 11:31 Printed: 03-Jan-2014 17:10 Page 9 of 21 374 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-104 3.83e5 25.71 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 9.09e2 Abs. Int. 9.50e4 PCB-96 3.57e5 26.03 4.75e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 5.96e5 25.71 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 8.81e2 27.0 0.00e0 RT Abs. Int. 1.52e5 PCB-96 5.01e5 26.03 7.58e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.34e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.97e3 5.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.59e7 25.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.60e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 1.70e3 3.30e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7311, 3592 scc: 983-753 Revised: 27-Dec-2013 11:24 (LKB) Printed: 03-Jan-2014 17:10 Page 10 of 21 375 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 5.53e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 108/119... 2.22e6 31.80 (4.35e5 + 6.99e5) * 100 pg/uL RRF(PCB-118) = = 1.13 (6.20e7 + 3.86e7) * 1.0 pg/uL 113/90… 100/9311:45 LKB 03-Jan-2014 1.13e6 6.34e5 30.82 PCB-121 PCB-99 28.51 PCB-88 PCB-103 4.78e5 3.53e5 3.66e5 30.02 2.75e5 31.36 27.72 28.99 116/85 6.89e5 32.43 PCB-111 4.71e5 PCB-120 33.15 4.66e5 33.54 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-118 107/124 4.35e5 8.23e5 35.11 34.51 PCB-123 PCB-114 4.68e5 4.77e5 34.82 35.58 Abs. Int. 3.39e5 PCB-105 4.12e5 36.12 PCB-127 4.20e5 37.35 1.70e5 0% 28.0 30.0 32.0 108/119... 3.61e6 31.80 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 7.14e3 34.0 PCB-94 4.74e5 27.91 100/93 1.08e6 28.51 PCB-91 6.28e5 29.06 PCB-89 4.69e5 29.67 113/90… 1.83e6 30.82 PCB-112 PCB-92 7.02e5 5.18e5 31.46 30.33 116/85 PCB-115 1.10e6 6.93e5 32.43 32.63 PCB-110 PCB-111 PCB-117 7.33e5 PCB-120 6.81e5 7.35e5 7.14e5 33.14 32.54 32.34 33.54 36.0 PCB-118 107/124 6.99e5 1.30e6 35.11 34.51 PCB-123 PCB-114 7.67e5 7.51e5 34.82 35.58 38.0 Abs. Int. 5.56e5 PCB-105 6.57e5 36.12 PCB-127 6.61e5 37.35 2.78e5 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 6.46e7 33.12 JS-101 5.31e7 30.82 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.82e3 34.0 36.0 ES-123 6.36e7 34.80 ES-114 6.56e7 35.55 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.61e7 ES-105 6.43e7 36.09 8.07e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.08e7 33.12 JS-101 3.31e7 30.82 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.71e3 34.0 36.0 ES-118 ES-123 3.86e7 3.96e7 35.09 34.80 38.0 0.00e0 RT Abs. Int. 1.02e7 ES-105 4.00e7 36.09 5.09e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7344, 6760 scc: 983-753 Revised: 30-Dec-2013 13:07 (LKB) Printed: 03-Jan-2014 17:10 Page 11 of 21 376 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Abs. Int. 9.23e4 PCB-126 3.63e5 38.73 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.27e3 4.61e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.52e5 PCB-126 5.76e5 38.73 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.57e3 7.61e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.28e7 ES-126 5.38e7 38.71 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.43e3 6.40e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.29e6 ES-126 3.40e7 38.71 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 7.41e3 4.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0821, 7826 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 12 of 21 377 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-136 5.13e5 31.29 PCB-155 PCB-150 5.51e5 PCB-145 6.53e5 30.98 5.58e5 30.68 31.56 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.22e2 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 147/149 139/140 8.25e5 8.18e5 34.13 34.66 PCB-148 4.24e5 32.83 151/135 8.04e5 PCB-144 PCB-143 PCB-133 PCB-146 33.36 3.94e5 3.96e5 PCB-142 3.94e5 4.11e5 3.30e5 36.17 33.83 34.39 35.61 34.98 153/168 1.00e6 36.72 PCB-141 3.72e5 36.86 163/138… 1.21e6 37.78 PCB-164 PCB-160 5.40e5 5.32e5 37.49 37.92 1.11e5 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PCB-150 PCB-155 4.64e5 4.93e5 30.98 30.68 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 8.63e2 PCB-145 4.42e5 31.56 PCB-148 3.01e5 32.83 147/149 139/140 151/135 6.41e5 6.67e5 6.33e5 34.66 34.13 33.35 PCB-154 PCB-143 PCB-132 3.56e5 3.08e5 2.85e5 33.57 34.39 35.21 36.0 38.0 153/168 8.09e5 36.72 PCB-165 3.96e5 35.95 163/138… 1.00e6 37.78 PCB-137 PCB-141 3.17e5 2.95e5 37.41 36.86 30.0 32.0 34.0 36.0 ES-155 5.16e7 30.66 Rel. Int. 100% HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.53e3 Abs. Int. 1.88e5 9.41e4 38.0 ES-153 3.62e7 36.68 0.00e0 RT PCB-158 4.50e5 38.10 0% 28.0 Abs. Int. 2.21e5 JS-138 3.26e7 37.74 0.00e0 RT Abs. Int. 1.25e7 6.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.04e7 30.66 Rel. Int. 100% ES-153 2.76e7 36.68 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.37e3 0.00e0 RT Abs. Int. 9.99e6 JS-138 2.49e7 37.74 4.99e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4865, 1501 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 13 of 21 378 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 8.84e5 38.84 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.56e3 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-162 PCB-159 5.10e5 5.87e5 39.89 39.65 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 156/157 1.08e6 41.29 Abs. Int. 2.09e5 PCB-167 5.96e5 40.30 PCB-169 5.31e5 44.01 1.04e5 0% 39.0 Rel. Int. 100% 128/166 7.52e5 38.84 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.20e3 40.0 PCB-162 PCB-159 4.52e5 39.89 4.64e5 39.65 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.82e5 156/157 8.55e5 41.28 PCB-169 4.12e5 44.00 PCB-167 4.78e5 40.30 9.11e4 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.33e7 40.28 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 8.34e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.02e8 41.27 (1.02e8 + 7.90e7) * 100 pg/uL RRF(ES-156/157) = = 1.57 (3.26e7 + 2.49e7) * 200 pg/uL LKB 03-Jan-2014 11:48 0.00e0 RT Abs. Int. 1.85e7 ES-169 4.92e7 43.99 9.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 7.90e7 41.27 Rel. Int. 100% ES-167 4.18e7 40.28 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 9.96e3 0.00e0 RT Abs. Int. 1.47e7 ES-169 3.89e7 43.99 7.34e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2729, 9872 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 14 of 21 379 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Rel. Int. 100% PCB-188 3.62e5 35.57 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.15e2 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-179 3.26e5 PCB-184 2.97e5 35.85 36.32 PCB-186 2.98e5 37.01 Abs. Int. 8.73e4 PCB-178 2.24e5 38.14 4.37e4 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 3.46e5 35.57 PCB-179 2.99e5 35.85 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.25e2 37.0 PCB-176 3.06e5 36.61 PCB-186 2.98e5 37.01 38.0 Abs. Int. 8.68e4 PCB-178 2.07e5 38.14 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.82e7 35.55 Rel. Int. 100% CS/SS-178 1.71e7 38.12 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.55e7 35.55 Rel. Int. 100% CS/SS-178 1.56e7 38.12 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.55e6 0.00e0 RT Abs. Int. 6.62e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.42e3 31.0 4.34e4 Abs. Int. 7.11e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.34e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 3.31e6 0.00e0 RT Abs. Int. 1.88e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.41e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6233, 0370 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 15 of 21 380 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.17e3 PCB-182 PCB-183 3.55e5 3.87e5 39.44 39.09 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-177 PCB-181 3.06e5 3.43e5 40.01 40.36 171/173 5.75e5 40.54 PCB-172 3.10e5 41.89 180/193 7.33e5 42.42 PCB-192 4.01e5 42.14 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 Abs. Int. 1.52e5 PCB-191 4.53e5 42.75 PCB-170 2.72e5 43.52 PCB-190 4.24e5 43.98 7.59e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.47e3 40.0 41.0 PCB-182 PCB-185 3.14e5 3.43e5 171/173 39.52 39.09 5.34e5 PCB-187 PCB-181 40.54 PCB-183 3.31e5 PCB-174 PCB-177 3.15e5 3.37e5 38.91 3.08e5 40.36 2.71e5 39.4439.63 40.01 42.0 43.0 180/193 7.69e5 42.42 PCB-172 2.85e5 41.89 PCB-191 4.05e5 42.75 44.0 45.0 Abs. Int. 1.26e5 PCB-190 3.97e5 43.98 PCB-170 2.79e5 43.52 6.28e4 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.20e7 42.43 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 8.23e6 ES-170 2.71e7 43.50 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 2.53e3 0.00e0 RT 4.12e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.93e7 42.43 Rel. Int. 100% 44.0 45.0 Abs. Int. 7.29e6 ES-170 2.50e7 43.50 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.41e3 0.00e0 RT 3.64e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7891, 3827 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 16 of 21 381 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-189 4.54e5 46.14 Abs. Int. 1.16e5 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.02e3 5.81e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 4.26e5 46.14 Abs. Int. 1.09e5 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 8.26e2 5.43e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.46e7 46.12 0.00e0 RT Abs. Int. 1.06e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 6.63e3 5.31e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.32e7 46.12 0.00e0 RT Abs. Int. 1.01e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.18e3 5.03e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5887, 3655 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 17 of 21 382 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 PCB-202 2.82e5 40.11 Rel. Int. 100% PCB-201 3.23e5 40.90 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 7.19e2 PCB-197 3.04e5 PCB-204 41.67 PCB-200 3.00e5 2.72e5 41.48 41.76 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 198/199 4.18e5 44.09 Abs. Int. 8.33e4 PCB-196 2.19e5 44.67 PCB-203 2.24e5 44.84 0% 39.0 Rel. Int. 100% 40.0 PCB-202 2.96e5 40.11 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.84e2 41.0 PCB-201 3.52e5 40.90 42.0 43.0 44.0 45.0 198/199 4.57e5 44.09 PCB-197 3.38e5PCB-200 PCB-204 41.67 3.01e5 3.20e5 41.76 41.48 40.0 41.0 42.0 PCB-196 2.21e5 44.66 43.0 44.0 PCB-203 2.44e5 44.84 4.51e4 45.0 ES-202 2.66e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.01e4 0% 39.0 4.17e4 0.00e0 RT Abs. Int. 6.53e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.52e3 3.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.85e7 40.09 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.76e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.30e3 3.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.05e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.26e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3815, 7054 scc: 983-753 Revised: 27-Dec-2013 11:31 (LKB) Printed: 03-Jan-2014 17:10 Page 18 of 21 383 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 8.34e2 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-205 3.35e5 48.31 PCB-195 2.47e5 45.96 Abs. Int. 7.93e4 PCB-194 2.65e5 47.91 3.97e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 7.51e2 47.0 48.0 49.0 50.0 PCB-205 3.71e5 48.31 PCB-195 2.63e5 45.96 0.00e0 RT Abs. Int. 9.00e4 PCB-194 2.96e5 47.91 4.50e4 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.26e7 48.29 Rel. Int. 100% Abs. Int. 7.66e6 JS-194 2.66e7 47.89 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.09e3 0.00e0 RT 3.83e6 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.63e7 48.29 JS-194 2.94e7 47.89 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.82e3 49.0 0.00e0 RT Abs. Int. 8.37e6 4.19e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1382, 4116 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 19 of 21 384 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.01e3 PCB-208 3.26e5 45.75 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-207 3.34e5 46.54 Abs. Int. 8.61e4 PCB-206 2.25e5 49.78 4.30e4 0% 46.0 Rel. Int. 100% PCB-208 3.97e5 45.75 47.0 48.0 49.0 PCB-207 4.16e5 46.54 50.0 Abs. Int. 1.01e5 PCB-206 2.86e5 49.78 NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.89e3 5.06e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.87e7 45.73 50.0 0.00e0 RT Abs. Int. 6.89e6 ES-206 2.06e7 49.76 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.22e3 3.45e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.61e7 45.73 50.0 Abs. Int. 8.47e6 ES-206 2.53e7 49.76 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.67e3 0.00e0 RT 4.24e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.25e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.63e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0808, 5245 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 20 of 21 385 of 603 SGS-AP ID: CS1_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-5 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 38 Acq: 20-Dec-2013 16:14:56 User: LKB Datafile: 131220X03 PCB-209 3.74e5 51.26 Rel. Int. 100% Abs. Int. 7.55e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.21e2 3.77e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 3.06e5 51.26 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.81e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.94e2 3.41e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.36e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.01e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 8.10e2 3.50e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.81e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.76e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.63e2 2.88e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.06e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.53e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS1_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6986, 0137 scc: 983-753 PKD: 27-Dec-2013 11:29 Printed: 03-Jan-2014 17:10 Page 21 of 21 386 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.11 32.63 36.11 35.56 35.10 34.82 38.72 41.28 40.29 44.00 46.13 51.25 7.18E+06 6.81E+06 5.68E+06 6.19E+06 5.72E+06 5.95E+06 4.77E+06 9.62E+06 5.42E+06 4.85E+06 4.61E+06 3.38E+06 0.79 Y 0.77 Y 0.64 Y 0.62 Y 0.60 Y 0.63 Y 0.62 Y 1.25 Y 1.21 Y 1.23 Y 1.02 Y 1.17 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.09 1.08 1.07 1.15 1.13 1.16 1.05 1.05 1.12 1.09 1.03 1.06 -5.2% -3.8% -4.0% -4.1% -5.1% -3.9% -5.1% -4.7% -3.2% -3.1% -3.6% -4.8% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.04 14.36 14.61 20.38 17.73 26.74 20.66 33.09 32.61 25.67 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.26 40.27 43.98 43.49 42.42 35.54 46.11 40.08 48.28 49.75 45.73 51.23 2.39E+08 2.19E+08 1.04E+08 2.08E+08 1.01E+08 1.56E+08 8.13E+07 1.31E+08 1.27E+08 7.00E+07 1.06E+08 1.07E+08 1.01E+08 1.02E+08 9.09E+07 6.37E+07 9.19E+07 1.84E+08 9.64E+07 8.90E+07 5.32E+07 6.31E+07 5.40E+07 8.91E+07 5.60E+07 7.02E+07 4.73E+07 6.67E+07 6.37E+07 3.26 Y 3.37 Y 1.62 Y 1.56 Y 1.08 Y 1.09 Y 0.82 Y 0.80 Y 0.80 Y 1.67 Y 1.61 Y 1.65 Y 1.61 Y 1.58 Y 1.58 Y 1.31 Y 1.33 Y 1.30 Y 1.30 Y 1.30 Y 1.08 Y 1.09 Y 1.06 Y 1.03 Y 0.94 Y 0.89 Y 0.81 Y 0.80 Y 1.19 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.21 1.10 0.53 1.05 0.51 1.68 0.88 1.42 1.36 0.82 1.25 1.26 1.19 1.20 1.07 1.13 1.63 1.63 1.71 1.58 0.96 1.13 0.96 1.60 0.99 1.26 0.85 1.20 1.14 1.3% 1.5% 0.5% 0.9% 0.4% 1.0% 1.7% 2.5% -0.2% 2.2% 3.7% 3.3% 2.4% 1.1% 3.7% 1.3% 2.5% 1.9% 2.3% 1.3% 1.0% -0.4% 1.8% 1.0% 2.3% 1.3% 2.3% 1.9% 3.2% Page 1 of 6 387 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.11 38.10 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.62 Y 1.12 Y 1.11 1.03 0.62 1.11 1.03 0.61 -0.2% 0.0% -2.3% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.11 38.10 1.73E+08 1.05E+08 3.27E+07 1.09 Y 1.62 Y 1.12 Y 1.85 1.22 0.58 1.86 1.23 0.58 0.9% 1.1% -0.5% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.81 37.73 47.88 1.98E+08 9.28E+07 8.53E+07 5.64E+07 5.57E+07 1.57 Y 0.79 Y 1.59 Y 1.31 Y 0.92 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.05 14.37 14.63 20.39 17.75 26.76 20.68 25.69 30.67 35.56 40.10 48.30 45.75 49.78 1.11E+07 1.07E+07 6.23E+06 1.02E+07 5.64E+06 8.15E+06 5.32E+06 4.90E+06 5.67E+06 3.30E+06 2.80E+06 3.53E+06 3.57E+06 2.55E+06 3.29 Y 3.19 Y 1.60 Y 1.65 Y 1.05 Y 0.98 Y 0.81 Y 0.65 Y 1.29 Y 1.10 Y 0.89 Y 0.93 Y 0.81 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.92 0.98 1.20 0.98 1.12 1.05 1.31 1.40 1.23 1.22 1.00 1.01 1.07 1.08 -2.9% -3.0% -2.9% -4.3% -2.5% -2.9% -3.2% -2.3% -2.2% -3.7% -5.1% -5.1% -4.7% -3.2% Page 2 of 6 388 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 12.05 14.18 14.37 14.63 14.81 16.63 16.80 17.03 17.33 17.45 19.02 19.81 20.11 20.39 17.75 19.52 19.93 20.12 20.26 20.35 20.84 21.99 22.14 22.43 22.63 22.91 23.19 23.38 23.75 25.14 25.46 26.00 26.39 26.76 20.68 22.68 23.27 23.34 23.55 24.82 24.94 25.04 25.24 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 1.11E+07 1.07E+07 1.07E+07 6.23E+06 1.01E+07 9.38E+06 1.06E+07 9.98E+06 1.00E+07 1.05E+07 1.19E+07 1.03E+07 2.02E+07 1.02E+07 5.64E+06 1.52E+07 6.40E+06 8.92E+06 8.42E+06 5.03E+06 9.31E+06 8.68E+06 8.57E+06 1.76E+07 8.79E+06 9.29E+06 1.69E+07 1.76E+07 8.06E+06 8.80E+06 9.00E+06 8.25E+06 7.78E+06 8.15E+06 5.32E+06 1.07E+07 4.46E+06 5.62E+06 4.33E+06 5.19E+06 6.70E+06 4.56E+06 1.26E+07 RA 3.29 Y 3.30 Y 3.19 Y 1.60 Y 1.59 Y 1.58 Y 1.65 Y 1.58 Y 1.62 Y 1.60 Y 1.61 Y 1.64 Y 1.61 Y 1.65 Y 1.05 Y 1.08 Y 1.08 Y 1.07 Y 1.05 Y 1.05 Y 1.07 Y 0.97 Y 1.00 Y 0.99 Y 0.95 Y 0.97 Y 1.00 Y 0.99 Y 1.00 Y 0.98 Y 0.97 Y 0.97 Y 1.00 Y 0.98 Y 0.81 Y 0.80 Y 0.79 Y 0.80 Y 0.78 Y 0.79 Y 0.79 Y 0.75 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.92 0.98 0.98 1.20 1.93 0.90 1.02 0.96 0.96 1.00 1.15 0.99 0.97 0.98 1.12 1.51 1.27 1.77 1.67 1.00 1.85 1.11 1.10 1.13 1.13 1.19 1.08 1.13 1.04 1.13 1.16 1.06 1.00 1.05 1.31 0.84 0.70 0.89 0.68 0.82 1.06 0.72 0.99 Dev'n -2.9% -5.2% -3.0% -2.9% -2.5% -4.6% -2.9% -3.7% -3.7% -2.7% -2.9% -1.9% -1.7% -4.3% -2.5% -1.8% -2.7% -2.6% -3.0% -0.7% -3.7% -1.9% -4.7% -3.4% -2.4% -2.7% -4.3% -3.7% -4.1% -3.4% -4.5% -4.0% -3.9% -2.9% -3.2% -3.9% -8.2% 3.3% -2.0% -2.8% -4.8% 1.4% -2.8% 389 of 603 PCB QC Summary - Ax2 Detail Lab ID: CS2_131220_PCB_XA Acquired: 20-DEC-2013 17:09 Datafile: 131220X04 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.02 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.52 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.79 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.37 PCB-67 23'45-TeCB 28.52 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.05 PCB-66 23'44'-TeCB 29.33 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.11 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.76 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.01 PCB-103 22'45'6-PeCB 27.71 PCB-94 22'356'-PeCB 27.90 PCB-95 22'35'6-PeCB 28.28 PCB-100/93 22'44'6/22'356-PeCB 28.50 PCB-102 22'456'-PeCB 28.61 PCB-98 22'34'6'-PeCB 28.68 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.24 PCB-89 22'346'-PeCB 29.66 PCB-121 23'45'6-PeCB 30.00 PCB-92 22'355'-PeCB 30.32 PCB-113/90/101 ...-PeCB 30.81 PCB-83 22'33'5-PeCB 31.25 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.79 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.42 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.24E+06 1.64E+07 2.14E+07 4.75E+06 4.38E+06 1.05E+07 7.49E+06 7.51E+06 7.85E+06 7.33E+06 7.30E+06 7.81E+06 7.85E+06 2.94E+07 6.87E+06 7.07E+06 6.96E+06 7.00E+06 8.09E+06 8.10E+06 6.61E+06 4.90E+06 4.21E+06 4.65E+06 4.04E+06 4.36E+06 8.64E+06 5.08E+06 3.64E+06 3.75E+06 4.80E+06 3.58E+06 3.81E+06 5.96E+06 4.05E+06 1.47E+07 3.64E+06 4.49E+06 5.95E+06 2.92E+07 5.88E+06 9.01E+06 5.43E+06 RA 0.81 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.81 Y 0.79 Y 0.80 Y 0.75 Y 0.77 Y 0.76 Y 0.77 Y 0.76 Y 0.79 Y 0.76 Y 0.79 Y 0.77 Y 0.78 Y 0.80 Y 0.78 Y 0.79 Y 0.65 Y 0.65 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.63 Y 0.64 Y 0.65 Y 0.63 Y 0.61 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.59 Y 0.64 Y 0.63 Y 0.62 Y 0.62 Y 0.64 Y 0.63 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.83 0.86 1.13 0.75 0.69 0.83 1.18 1.19 1.24 1.16 1.15 1.23 1.24 1.16 1.09 1.12 1.10 1.11 1.28 1.28 1.04 1.40 1.20 0.91 0.79 0.85 0.85 0.99 0.71 0.73 0.94 0.70 0.75 1.16 0.79 0.96 0.71 0.88 1.16 0.95 1.15 0.88 1.06 Dev'n -1.3% -4.4% -3.2% -1.7% -0.5% -3.8% -3.0% -1.9% -2.8% -0.5% -2.1% -2.0% -4.4% -3.0% -1.5% -0.3% -1.0% -2.5% -2.7% -2.0% -1.6% -2.3% -2.0% -2.2% -1.3% -1.5% -2.1% 2.6% -6.0% -8.2% -0.5% -2.1% -2.3% -2.9% -3.5% -2.5% -0.4% -4.7% -0.4% -2.9% 1.1% -6.3% -5.0% 390 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 32.62 32.82 33.13 33.53 34.50 34.71 34.93 35.39 37.34 30.67 30.82 30.97 31.27 31.55 32.82 33.34 33.55 33.82 34.12 34.29 34.38 34.64 34.82 34.96 35.20 35.60 35.94 36.16 36.28 36.71 36.85 37.20 37.40 37.48 37.77 37.91 38.09 38.83 39.64 39.88 35.56 35.84 36.30 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.94E+06 3.45E+06 6.10E+06 6.04E+06 1.09E+07 6.46E+06 5.32E+06 5.09E+06 5.46E+06 5.67E+06 5.18E+06 5.27E+06 4.80E+06 4.89E+06 3.69E+06 7.14E+06 4.14E+06 3.74E+06 7.38E+06 2.81E+06 3.63E+06 7.45E+06 3.13E+06 3.09E+06 3.22E+06 3.47E+06 4.45E+06 3.72E+06 4.78E+06 9.14E+06 3.40E+06 3.05E+06 3.51E+06 4.84E+06 1.09E+07 4.74E+06 5.15E+06 8.23E+06 5.14E+06 4.97E+06 3.30E+06 3.06E+06 2.96E+06 RA 0.60 Y 0.62 Y 0.63 Y 0.64 Y 0.62 Y 0.62 Y 0.64 Y 0.64 Y 0.62 Y 1.29 Y 1.28 Y 1.27 Y 1.26 Y 1.31 Y 1.28 Y 1.23 Y 1.24 Y 1.28 Y 1.29 Y 1.29 Y 1.26 Y 1.28 Y 1.29 Y 1.24 Y 1.28 Y 1.26 Y 1.24 Y 1.30 Y 1.30 Y 1.28 Y 1.30 Y 1.25 Y 1.28 Y 1.28 Y 1.27 Y 1.26 Y 1.28 Y 1.25 Y 1.24 Y 1.21 Y 1.10 Y 1.09 Y 1.03 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.16 0.67 1.19 1.18 1.07 1.26 1.04 0.95 1.03 1.23 1.13 1.15 1.04 1.06 1.16 1.12 1.30 1.17 1.16 0.88 1.14 1.17 0.98 0.97 1.01 1.09 1.40 1.17 1.50 1.43 1.07 0.96 1.10 1.52 1.14 1.49 1.62 0.85 1.07 1.03 1.22 1.13 1.10 Dev'n 0.3% -3.3% -2.3% -2.5% -2.9% 0.8% -5.8% -4.5% -6.2% -2.2% -3.8% -2.5% -2.1% -4.5% -2.2% -1.6% -3.2% -0.8% -1.6% -4.5% 0.8% -3.0% -4.2% -1.9% -2.1% -3.9% -0.9% -2.9% -1.4% -1.6% -2.0% -1.7% -5.3% 1.3% -3.9% -1.7% -2.7% -5.1% -4.4% -3.7% -3.7% -2.3% -2.6% 391 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS2_131220_PCB_XA 20-DEC-2013 17:09 131220X04 RT 36.60 37.00 38.13 38.67 38.90 39.08 39.43 39.52 39.62 40.00 40.35 40.53 41.88 42.13 42.41 42.74 43.51 43.97 40.10 40.89 41.47 41.66 41.75 44.08 44.66 44.83 45.95 47.90 48.30 45.75 46.54 49.78 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 3.29E+06 2.98E+06 2.21E+06 3.31E+06 3.49E+06 3.67E+06 3.83E+06 3.13E+06 3.03E+06 2.93E+06 3.27E+06 5.79E+06 2.98E+06 4.03E+06 7.75E+06 4.20E+06 2.91E+06 4.21E+06 2.80E+06 3.33E+06 3.01E+06 3.09E+06 3.13E+06 4.38E+06 2.29E+06 2.39E+06 2.57E+06 2.84E+06 3.53E+06 3.57E+06 3.79E+06 2.55E+06 RA 1.07 Y 1.06 Y 1.08 Y 1.06 Y 0.96 Y 1.07 Y 1.05 Y 1.08 Y 1.07 Y 1.10 Y 1.08 Y 1.06 Y 1.07 Y 1.06 Y 1.08 Y 1.05 Y 1.04 Y 1.06 Y 0.89 Y 0.92 Y 0.94 Y 0.91 Y 0.89 Y 0.92 Y 0.94 Y 0.93 Y 0.90 Y 0.87 Y 0.93 Y 0.81 Y 0.76 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.22 1.10 0.82 1.05 1.11 1.16 1.21 0.99 0.96 0.93 1.04 0.92 0.95 1.28 1.23 1.33 1.09 1.58 1.00 1.19 1.08 1.11 1.12 0.78 0.82 0.85 0.73 0.81 1.01 1.07 1.14 1.08 Dev'n -1.2% -1.9% -2.7% -2.3% -2.9% -1.0% 0.7% -6.4% -2.8% -2.3% -4.9% -3.1% -4.3% -0.7% -2.6% -4.6% -3.7% -4.7% -5.1% -2.7% -3.6% -7.1% 1.0% -3.4% -1.8% -2.2% -4.5% -4.1% -5.1% -4.7% -4.4% -3.2% 392 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.95e7 2.47e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.50e7 1.25e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.78e7 8.90e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.83e7 9.17e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.06e7 5.32e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.51e6 2.75e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.31e6 2.65e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 288-489 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:10 Page 1 of 21 393 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-1 8.49e6 12.05 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-2 8.22e6 14.18 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.63e3 Abs. Int. 3.53e6 PCB-3 8.15e6 14.37 1.77e6 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.58e6 12.05 Rel. Int. 100% PCB-2 2.50e6 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.76e3 0.00e0 16.0 RT Abs. Int. 1.06e6 PCB-3 2.55e6 14.37 5.29e5 0% 11.0 12.0 13.0 14.0 ES-1 1.83e8 12.04 Rel. Int. 100% 15.0 Abs. Int. 7.14e7 ES-3 1.69e8 14.36 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 9.48e3 0.00e0 16.0 RT 3.57e7 0% 11.0 12.0 13.0 14.0 ES-1 5.63e7 12.04 Rel. Int. 100% 15.0 Abs. Int. 2.26e7 ES-3 5.01e7 14.36 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 3.97e4 0.00e0 16.0 RT 1.13e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.47e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5986, 8076 scc: 288-489 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 2 of 21 394 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. 100% PCB-4 3.84e6 14.63 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.13e3 PCB-10 6.17e6 14.81 1.01e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.89e6 14.81 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.22e4 PCB-4 2.39e6 14.63 12.0 13.0 14.0 15.0 ES-4 6.43e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.30e6 6.50e5 0% 11.0 Abs. Int. 2.02e6 0.00e0 16.0 RT Abs. Int. 2.12e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 1.16e4 1.06e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.98e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.35e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.62e3 6.76e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.47e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2760, 4750 scc: 288-489 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 3 of 21 395 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.04e4 PCB-9 5.75e6 16.63 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-7 6.57e6 PCB-6 16.80 6.12e6 17.03 PCB-14 7.35e6 19.02 PCB-5 6.20e6 PCB-8 17.33 6.43e6 17.45 PCB-11 6.41e6 19.81 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 13/12 1.25e7 20.11 Abs. Int. 2.17e6 PCB-15 6.32e6 20.39 1.09e6 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.28e4 PCB-9 3.64e6 16.63 PCB-7 3.99e6 16.80 18.0 19.0 PCB-14 4.57e6 19.02 PCB-5 3.84e6 PCB-8 17.33 4.02e6 17.45 20.0 PCB-11 3.91e6 19.81 13/12 7.75e6 20.10 21.0 Abs. Int. 1.40e6 PCB-15 3.83e6 20.39 7.00e5 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.21e8 16.61 21.0 0.00e0 RT Abs. Int. 3.98e7 ES-15 1.27e8 20.38 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.35e4 1.99e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.71e7 16.61 21.0 0.00e0 RT Abs. Int. 2.51e7 ES-15 8.13e7 20.38 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 1.09e4 1.26e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0673, 3078 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 4 of 21 396 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 30/18 7.88e6 19.52 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.57e3 PCB-19 2.89e6 17.75 PCB-17 3.33e6 19.93 PCB-27 4.61e6 20.12 PCB-24 4.30e6 20.26 PCB-16 2.58e6 20.35 Abs. Int. 2.14e6 PCB-32 4.81e6 20.84 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 7.32e6 19.52 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 4.49e3 PCB-19 2.75e6 17.75 PCB-17 3.07e6 19.93 21.0 Rel. Int. 100% 18.0 19.0 PCB-16 2.45e6 20.35 20.0 PCB-32 4.50e6 20.84 21.0 1.01e6 0.00e0 RT Abs. Int. 2.17e7 ES-19 5.22e7 17.73 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 7.41e4 0.00e0 RT Abs. Int. 2.01e6 PCB-24 4.11e6 20.26 PCB-27 4.31e6 20.12 0% 17.0 1.07e6 1.09e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.98e7 ES-19 4.85e7 17.73 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.71e4 0.00e0 RT 9.91e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9474, 8467 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 5 of 21 397 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.73e3 PCB-23 PCB-34 4.29e6 4.28e6 22.14 21.99 26/29 8.76e6 22.43 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 28/20 8.42e6 23.19 PCB-31 4.58e6 22.91 Abs. Int. 1.95e6 PCB-22 4.03e6 23.75 PCB-36 4.36e6 25.14 PCB-39 4.43e6 25.46 PCB-38 4.07e6 26.00 PCB-35 3.89e6 26.39 PCB-37 4.03e6 26.76 9.75e5 0% 22.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.67e3 PCB-34 PCB-23 4.40e6 4.28e6 22.14 21.99 23.0 26/29 8.87e6 22.43 24.0 25.0 26.0 27.0 28/20 8.46e6 23.19 PCB-31 4.70e6 22.91 Abs. Int. 2.01e6 PCB-22 4.03e6 23.75 PCB-36 4.44e6 25.14 PCB-39 4.58e6 25.46 PCB-38 4.19e6 26.00 PCB-35 3.89e6 26.39 PCB-37 4.12e6 26.76 1.00e6 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 9.02e7 23.16 Rel. Int. 100% 0.00e0 RT 27.0 0.00e0 RT Abs. Int. 2.37e7 ES-37 8.14e7 26.74 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.65e4 1.19e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 8.25e7 23.16 Rel. Int. 100% 27.0 0.00e0 RT Abs. Int. 2.20e7 ES-37 7.44e7 26.74 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.85e4 1.10e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1479, 2682 scc: 288-489 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 6 of 21 398 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-54 2.39e6 20.68 Rel. Int. 100% Abs. Int. 6.38e5 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.54e3 3.19e5 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.93e6 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.02e5 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.39e3 4.01e5 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.66e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.66e4 5.03e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.47e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.20e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 9.99e3 6.01e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.50e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.25e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6205, 6671 scc: 288-489 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 7 of 21 399 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.15e3 50/53 4.73e6 22.68 PCB-51 2.50e6 23.34 PCB-45 1.96e6 23.27 PCB-73 PCB-52 2.96e6 2.29e6 24.94 24.82 PCB-46 1.90e6 23.55 69/49 5.55e6 25.24 44/47… 7.19e6 25.74 PCB-48 2.34e6 25.52 59/62… 9.47e6 26.02 71/40 4.67e6 26.61 PCB-42 2.09e6 26.18 PCB-41 1.93e6 26.52 Abs. Int. 1.80e6 PCB-64 3.30e6 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 1.66e3 50/53 5.93e6 22.68 24.0 PCB-51 3.11e6 23.34 PCB-45 2.49e6 23.27 25.0 PCB-73 3.74e6 PCB-52 24.94 2.90e6 24.82 PCB-46 2.44e6 23.56 26.0 44/47… 9.21e6 25.74 69/49 7.04e6 25.24 PCB-48 2.89e6 25.52 59/62… 1.19e7 26.02 PCB-42 2.66e6 26.18 27.0 71/40 5.78e6 26.61 PCB-41 2.45e6 26.52 23.0 24.0 25.0 26.0 PCB-64 4.19e6 26.81 27.0 JS-52 4.09e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.14e6 0% 22.0 9.00e5 1.07e6 0.00e0 RT Abs. Int. 1.09e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.65e4 5.45e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.18e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.53e4 6.74e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7645, 3266 scc: 288-489 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 8 of 21 400 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 61/70... 1.30e7 29.05 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 1.09e4 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-57 3.19e6 28.16 PCB-63 3.39e6 28.75 PCB-55 3.12e6 29.47 PCB-60 PCB-80 3.07e6 3.59e6 30.43 30.11 PCB-79 3.56e6 31.76 PCB-78 2.91e6 32.25 PCB-81 2.96e6 32.63 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Abs. Int. 1.61e6 PCB-77 3.16e6 33.11 8.04e5 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 7.51e3 PCB-57 4.13e6 28.16 PCB-68 4.48e6 27.79 30.0 61/70... 1.64e7 29.04 32.0 PCB-60 3.93e6 30.11 PCB-63 4.46e6 PCB-66 PCB-56 3.90e6 3.93e6 28.75 29.33 29.91 PCB-80 4.50e6 30.43 PCB-79 4.54e6 31.76 34.0 PCB-78 3.70e6 32.25PCB-81 3.85e6 32.63 36.0 38.0 Abs. Int. 2.10e6 PCB-77 4.02e6 33.11 1.05e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 5.62e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.57e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.52e7 ES-77 5.84e7 33.09 7.62e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.04e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.96e4 36.0 38.0 0.00e0 RT Abs. Int. 1.93e7 ES-77 7.31e7 33.09 9.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6185, 5150 scc: 288-489 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 9 of 21 401 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-104 1.93e6 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.00e3 Abs. Int. 5.05e5 PCB-96 1.65e6 26.01 2.53e5 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.97e6 25.69 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.05e3 27.0 0.00e0 RT Abs. Int. 8.18e5 PCB-96 2.56e6 26.01 4.09e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.38e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 3.73e3 5.63e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.62e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.64e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 1.51e3 3.32e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 8.90e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5147, 8237 scc: 288-489 Revised: 30-Dec-2013 12:10 (LKB) Printed: 03-Jan-2014 17:10 Page 10 of 21 402 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 108/119... 1.11e7 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 4.67e4 PCB-103 1.79e6 27.71 100/93 3.34e6 28.50 PCB-88 1.48e6 28.98 PCB-121 2.30e6 30.00 113/90… 5.72e6 30.81 116/85 3.51e6 32.42 PCB-99 1.74e6 31.34 PCB-111 2.37e6 PCB-120 2.36e6 33.13 33.53 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 107/124 PCB-118 2.15e6 4.19e6 35.10 34.50 PCB-123 PCB-114 2.30e6 2.37e6 34.82 35.56 Abs. Int. 1.65e6 PCB-105 2.21e6 36.11 PCB-127 2.09e6 37.34 8.24e5 0% 28.0 30.0 32.0 108/119... 1.81e7 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 7.48e4 34.0 PCB-94 2.47e6 27.90 100/93 5.30e6 28.49 PCB-91 2.94e6 29.04 PCB-89 2.35e6 29.65 113/90… 9.02e6 30.80 PCB-112 PCB-92 3.65e6 2.50e6 31.44 30.32 116/85 PCB-115 5.50e6 3.71e6 32.42 32.62 PCB-111 PCB-117 PCB-110 3.73e6 PCB-120 3.63e6 3.34e6 3.68e6 33.13 32.33 32.53 33.53 36.0 PCB-118 107/124 3.56e6 6.71e6 35.10 34.50 PCB-123 PCB-114 3.66e6 3.82e6 34.82 35.56 38.0 Abs. Int. 2.65e6 PCB-105 3.47e6 36.11 PCB-127 3.36e6 37.34 1.33e6 0% 28.0 Rel. Int. 100% PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.45e3 30.0 32.0 34.0 CS/SS-111 6.50e7 33.11 JS-101 5.23e7 (6.56e7 + 4.07e7) * 100 pg/uL RRF(ES-105) = = 1.25 30.81 (5.23e7 + 3.30e7) * 100 pg/uL LKB 03-Jan-2014 11:50 36.0 ES-123 6.26e7 34.79 ES-114 ES-118 6.68e7 6.24e7 35.54 35.07 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.62e7 ES-105 6.56e7 36.08 8.09e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 4.02e7 33.11 JS-101 3.30e7 30.81 36.0 ES-123 3.97e7 34.79 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 1.58e3 ES-118 ES-114 3.88e7 4.05e7 35.07 35.54 38.0 0.00e0 RT Abs. Int. 9.82e6 ES-105 4.07e7 36.08 4.91e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6550, 0341 scc: 288-489 Revised: 03-Jan-2014 16:44 (LKB) Printed: 03-Jan-2014 17:10 Page 11 of 21 403 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-126 1.83e6 38.72 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.16e3 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 Abs. Int. 4.48e5 (1.83e6 + 2.94e6) * 100 pg/uL RRF(PCB-126) = = 1.05 (5.56e7 + 3.53e7) * 5 pg/uL LKB 03-Jan-2014 11:49 2.24e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.89e5 PCB-126 2.94e6 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.88e3 3.44e5 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.35e7 ES-126 5.56e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.79e3 6.76e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 8.80e6 ES-126 3.53e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 5.68e3 4.40e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3455, 1978 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 12 of 21 404 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% PCB-155 PCB-150 3.19e6 2.94e6 30.97 30.67 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 8.82e2 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 147/149 139/140 4.16e6 4.18e6 34.12 34.64 PCB-145 2.77e6 31.55 PCB-148 2.07e6 32.82 153/168 5.13e6 36.71 151/135PCB-144 3.94e6 2.10e6 PCB-143 PCB-142 PCB-133 PCB-146 2.02e6 33.34 33.82 1.94e6 2.10e6 1.71e6 36.16 34.38 35.60 34.96 PCB-141 1.92e6 36.85 163/138… 6.11e6 37.77 PCB-164 PCB-160 2.71e6 2.64e6 37.48 37.91 0% 28.0 30.0 32.0 PCB-136 2.12e6 31.27 PCB-150 PCB-155 2.32e6 PCB-145 2.47e6 30.97 2.12e6 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 6.38e2 34.0 PCB-148 1.62e6 32.82 147/149 139/140 151/135 3.22e6 3.27e6 3.20e6 34.12 33.34 34.64 PCB-154 PCB-143 1.84e6 1.60e6PCB-131 33.55 34.38 1.37e6 34.81 36.0 PCB-165 1.99e6 35.94 38.0 153/168 4.00e6 36.71 163/138… 4.82e6 37.77 PCB-141 PCB-137 1.48e6 1.54e6 37.39 36.85 PCB-158 2.26e6 38.09 0% 28.0 30.0 32.0 34.0 36.0 ES-155 5.24e7 30.64 Rel. Int. 100% 38.0 ES-153 3.62e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.74e3 Abs. Int. 1.15e6 5.77e5 0.00e0 RT Abs. Int. 9.25e5 4.62e5 0.00e0 RT Abs. Int. 1.29e7 JS-138 3.20e7 37.73 6.47e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 3.95e7 30.64 Rel. Int. 100% ES-153 2.75e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 1.30e3 0.00e0 RT Abs. Int. 9.93e6 JS-138 2.44e7 37.73 4.96e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8742, 2751 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 13 of 21 405 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.57e6 38.83 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.74e3 PCB-159 2.84e6 39.64 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-162 2.72e6 39.88 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 156/157 5.34e6 41.28 Abs. Int. 1.12e6 PCB-169 2.67e6 44.00 PCB-167 2.97e6 40.29 5.58e5 0% 39.0 Rel. Int. 100% 40.0 128/166 3.66e6 38.83 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.62e3 PCB-159 2.30e6 39.64 PCB-162 2.25e6 39.88 41.0 42.0 43.0 44.0 45.0 Abs. Int. 8.94e5 156/157 4.28e6 41.28 PCB-169 2.18e6 44.00 PCB-167 2.45e6 40.29 4.47e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 1.04e8 41.26 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.92e7 ES-167 5.44e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 1.17e4 0.00e0 RT ES-169 5.02e7 43.98 9.59e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 8.00e7 41.26 Rel. Int. 100% Abs. Int. 1.48e7 ES-167 4.20e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 7.32e3 0.00e0 RT ES-169 3.88e7 43.98 7.39e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3801, 7947 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 14 of 21 406 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Rel. Int. 100% PCB-188 1.73e6 35.56 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-179 PCB-184 1.60e6 1.50e6 35.84 36.30 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 6.31e2 PCB-186 1.53e6 37.00 Abs. Int. 4.22e5 PCB-178 1.15e6 38.13 2.11e5 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.57e6 35.56 PCB-179 1.47e6 35.84 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 5.34e2 37.0 PCB-176 1.59e6 36.59 PCB-186 1.45e6 37.00 38.0 0.00e0 RT Abs. Int. 3.84e5 PCB-178 1.06e6 38.12 1.92e5 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.78e7 35.54 Rel. Int. 100% Abs. Int. 6.94e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.23e3 CS/SS-178 1.72e7 38.10 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.62e7 35.54 Rel. Int. 100% CS/SS-178 1.54e7 38.10 0% 32.0 33.0 34.0 35.0 3.47e6 0.00e0 RT Abs. Int. 6.31e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.34e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 3.15e6 0.00e0 RT Abs. Int. 1.83e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.17e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2821, 9130 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 15 of 21 407 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.67e3 PCB-182 1.90e6 39.08 PCB-185 1.62e6 39.52 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 180/193 4.02e6 42.41 171/173 2.98e6 40.53 PCB-181 PCB-177 1.53e6 1.69e6 40.35 40.00 PCB-172 1.54e6 41.88 PCB-191 2.15e6 42.74 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-170 1.49e6 43.51 Abs. Int. 6.84e5 PCB-190 2.17e6 43.97 3.42e5 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.83e3 PCB-182 1.77e6 39.08 PCB-187 PCB-183 1.78e6 1.87e6 38.90 39.43 40.0 41.0 42.0 43.0 180/193 3.73e6 42.41 171/173 2.82e6 PCB-181 40.53 PCB-177 1.57e6 1.40e6 40.35 40.00 PCB-172 1.44e6 41.88 PCB-191 2.05e6 42.74 44.0 PCB-170 1.42e6 43.51 45.0 Abs. Int. 6.33e5 PCB-190 2.05e6 43.97 3.17e5 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.29e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 7.97e6 ES-170 2.76e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.75e3 0.00e0 RT 3.98e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.02e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 7.41e6 ES-170 2.56e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.23e3 0.00e0 RT 3.70e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6498, 0239 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 16 of 21 408 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-189 2.33e6 46.13 Abs. Int. 5.42e5 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.05e3 2.71e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.28e6 46.13 Abs. Int. 5.54e5 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 7.55e2 2.77e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.53e7 46.11 0.00e0 RT Abs. Int. 1.08e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 5.40e3 5.39e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.38e7 46.11 0.00e0 RT Abs. Int. 1.06e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 4.80e3 5.28e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0018, 8768 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 17 of 21 409 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 PCB-202 1.32e6 40.10 PCB-201 1.60e6 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.62e2 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 198/199 2.09e6 44.08 PCB-197 1.48e6 PCB-204 41.66 PCB-200 1.46e6 1.47e6 41.47 41.75 Abs. Int. 3.82e5 PCB-196 1.11e6 44.66 PCB-203 1.15e6 44.83 1.91e5 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.48e6 40.10 41.0 PCB-201 1.73e6 40.89 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.89e2 42.0 43.0 44.0 45.0 198/199 2.28e6 44.08 PCB-197 1.62e6 41.66 PCB-200 PCB-204 1.66e6 1.55e6 41.75 41.47 0.00e0 RT Abs. Int. 4.14e5 PCB-196 1.18e6 44.66 PCB-203 1.24e6 44.83 2.07e5 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.72e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.70e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.49e3 3.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.88e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.04e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.76e3 3.52e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.32e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9441, 6444 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 18 of 21 410 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.06e3 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-205 1.70e6 48.30 PCB-195 1.22e6 45.95 Abs. Int. 4.21e5 PCB-194 1.32e6 47.90 2.11e5 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.03e3 47.0 PCB-195 1.35e6 45.95 48.0 49.0 50.0 PCB-205 1.83e6 48.30 PCB-194 1.52e6 47.90 0.00e0 RT Abs. Int. 4.31e5 2.15e5 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.31e7 48.28 Rel. Int. 100% Abs. Int. 7.84e6 JS-194 2.67e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.61e3 0.00e0 RT 3.92e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.71e7 48.28 Rel. Int. 100% Abs. Int. 8.92e6 JS-194 2.90e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 4.69e3 0.00e0 RT 4.46e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1137, 3820 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 19 of 21 411 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 6.72e2 PCB-208 1.60e6 45.75 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-207 1.64e6 46.54 Abs. Int. 3.86e5 PCB-206 1.12e6 49.78 1.93e5 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 2.48e3 PCB-208 1.97e6 45.75 47.0 48.0 49.0 50.0 PCB-207 2.15e6 46.54 Abs. Int. 5.02e5 PCB-206 1.43e6 49.77 2.51e5 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.97e7 45.73 50.0 0.00e0 RT Abs. Int. 7.00e6 ES-206 2.11e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 1.84e3 3.50e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.69e7 45.73 50.0 Abs. Int. 8.58e6 ES-206 2.61e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.64e3 0.00e0 RT 4.29e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.51e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.75e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6056, 4422 scc: 288-489 PKD: 30-Dec-2013 12:14 Printed: 03-Jan-2014 17:10 Page 20 of 21 412 of 603 SGS-AP ID: CS2_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-4 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 39 Acq: 20-Dec-2013 17:09:38 User: LKB Datafile: 131220X04 PCB-209 1.82e6 51.25 Rel. Int. 100% Abs. Int. 3.69e5 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.61e2 1.84e5 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.56e6 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.28e5 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 4.70e2 1.64e5 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.46e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.08e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 9.58e2 3.54e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.92e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.03e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.69e2 3.01e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.31e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.65e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS2_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6862, 7261 scc: 288-489 Revised: 30-Dec-2013 12:10 (LKB) Printed: 03-Jan-2014 17:10 Page 21 of 21 413 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.10 32.62 36.09 35.55 35.08 34.80 38.71 41.26 40.28 43.98 46.12 51.23 6.72E+07 6.46E+07 5.36E+07 5.90E+07 5.55E+07 5.75E+07 4.48E+07 9.35E+07 5.18E+07 4.66E+07 4.39E+07 3.15E+07 0.78 Y 0.78 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 1.23 Y 1.21 Y 1.24 Y 1.04 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.14 1.12 1.13 1.23 1.22 1.23 1.12 1.12 1.20 1.16 1.07 1.09 -0.9% -0.2% 1.3% 2.2% 2.5% 1.5% 1.1% 2.3% 2.9% 2.8% -0.2% -2.1% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.02 14.34 14.60 20.36 17.72 26.72 20.65 33.08 32.60 25.66 36.07 35.53 35.06 34.78 38.69 36.65 30.63 41.24 40.26 43.96 43.48 42.41 35.52 46.10 40.07 48.27 49.74 45.71 51.21 2.19E+08 1.97E+08 9.59E+07 1.90E+08 9.32E+07 1.42E+08 7.49E+07 1.18E+08 1.16E+08 6.47E+07 9.52E+07 9.60E+07 9.11E+07 9.36E+07 8.01E+07 5.89E+07 8.37E+07 1.67E+08 8.66E+07 8.06E+07 4.93E+07 5.80E+07 4.92E+07 8.18E+07 5.16E+07 6.45E+07 4.32E+07 6.09E+07 5.77E+07 3.31 Y 3.36 Y 1.62 Y 1.57 Y 1.08 Y 1.09 Y 0.82 Y 0.79 Y 0.81 Y 1.68 Y 1.57 Y 1.64 Y 1.63 Y 1.59 Y 1.60 Y 1.29 Y 1.30 Y 1.28 Y 1.28 Y 1.28 Y 1.09 Y 1.09 Y 1.11 Y 1.01 Y 0.93 Y 0.89 Y 0.80 Y 0.80 Y 1.21 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.18 1.06 0.52 1.02 0.50 1.61 0.85 1.34 1.32 0.80 1.18 1.19 1.13 1.16 0.99 1.10 1.56 1.56 1.62 1.51 0.95 1.11 0.92 1.57 0.97 1.24 0.83 1.17 1.11 -1.3% -2.5% -1.2% -1.9% -0.9% -2.9% -0.9% -2.9% -3.5% 0.0% -1.7% -2.1% -2.4% -2.1% -3.2% -1.2% -1.6% -2.7% -3.0% -3.2% -0.1% -2.2% -2.1% -0.9% -0.5% -0.6% -0.1% -0.5% -0.3% Page 1 of 6 414 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.15 33.09 38.09 1.59E+08 9.83E+07 3.00E+07 1.09 Y 1.61 Y 1.10 Y 1.11 1.03 0.62 1.12 1.05 0.61 1.0% 2.1% -1.7% CS PCB-28 CS PCB-111 CS PCB-178 23.15 33.09 38.09 1.59E+08 9.83E+07 3.00E+07 1.09 Y 1.61 Y 1.10 Y 1.85 1.22 0.58 1.81 1.22 0.56 -1.8% 0.0% -3.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.60 24.78 30.80 37.72 47.87 1.86E+08 8.78E+07 8.05E+07 5.35E+07 5.22E+07 1.55 Y 0.82 Y 1.58 Y 1.28 Y 0.91 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.04 14.36 14.62 20.38 17.73 26.74 20.67 25.68 30.65 35.54 40.09 48.28 45.73 49.76 1.06E+08 1.02E+08 6.07E+07 9.79E+07 5.43E+07 7.81E+07 5.09E+07 4.68E+07 5.34E+07 3.10E+07 2.75E+07 3.40E+07 3.44E+07 2.40E+07 3.22 Y 3.25 Y 1.59 Y 1.64 Y 1.06 Y 0.99 Y 0.82 Y 0.64 Y 1.27 Y 1.06 Y 0.92 Y 0.92 Y 0.77 Y 0.79 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.97 1.04 1.27 1.03 1.17 1.10 1.36 1.45 1.27 1.26 1.06 1.06 1.13 1.11 1.7% 2.8% 2.7% 1.2% 1.5% 2.2% 0.6% 0.9% 1.2% -0.6% 1.0% -0.5% 0.6% -0.3% Page 2 of 6 415 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 12.04 14.17 14.36 14.62 14.80 16.62 16.78 17.01 17.32 17.44 19.01 19.80 20.09 20.38 17.73 19.51 19.91 20.11 20.24 20.34 20.82 21.98 22.13 22.42 22.61 22.89 23.18 23.36 23.74 25.13 25.45 25.99 26.38 26.74 20.67 22.67 23.26 23.33 23.54 24.80 24.93 25.03 25.23 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 1.06E+08 1.07E+08 1.02E+08 6.07E+07 9.81E+07 9.11E+07 1.03E+08 9.79E+07 9.70E+07 9.83E+07 1.14E+08 9.79E+07 1.94E+08 9.79E+07 5.43E+07 1.46E+08 6.21E+07 8.52E+07 8.13E+07 4.64E+07 8.97E+07 8.15E+07 8.33E+07 1.69E+08 8.39E+07 8.91E+07 1.65E+08 1.71E+08 7.72E+07 8.43E+07 8.82E+07 8.09E+07 7.62E+07 7.81E+07 5.09E+07 1.04E+08 4.29E+07 5.41E+07 4.19E+07 4.97E+07 6.50E+07 4.44E+07 1.22E+08 RA 3.22 Y 3.26 Y 3.25 Y 1.59 Y 1.61 Y 1.64 Y 1.63 Y 1.63 Y 1.62 Y 1.64 Y 1.62 Y 1.64 Y 1.63 Y 1.64 Y 1.06 Y 1.05 Y 1.05 Y 1.06 Y 1.04 Y 1.06 Y 1.06 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.99 Y 0.99 Y 0.97 Y 0.98 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.82 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.97 1.08 1.04 1.27 2.05 0.96 1.09 1.03 1.02 1.04 1.20 1.03 1.02 1.03 1.17 1.57 1.33 1.83 1.74 1.00 1.93 1.15 1.18 1.20 1.18 1.26 1.17 1.21 1.09 1.19 1.24 1.14 1.08 1.10 1.36 0.90 0.74 0.93 0.72 0.86 1.12 0.77 1.05 Dev'n 1.7% 4.8% 2.8% 2.7% 3.2% 1.6% 4.1% 3.6% 2.0% 0.3% 1.9% 2.0% 3.1% 1.2% 1.5% 1.9% 2.2% 0.7% 1.2% -1.0% 0.3% 1.4% 1.8% 2.1% 2.3% 2.6% 3.0% 2.8% 0.9% 1.6% 2.8% 3.4% 3.5% 2.2% 0.6% 2.6% -3.3% 8.7% 3.5% 1.6% 0.9% 7.9% 3.2% 416 of 603 PCB QC Summary - Ax2 Detail Lab ID: CS3_131220_PCB_XA Acquired: 20-DEC-2013 18:04 Datafile: 131220X05 Name RT PCB-48 22'45-TeCB 25.51 PCB-44/47/65 ...-TeCB 25.73 PCB-59/62/75 ...-TeCB 26.01 PCB-42 22'34'-TeCB 26.17 PCB-41 22'34-TeCB 26.51 PCB-71/40 23'4'6/22'33'-TeCB 26.60 PCB-64 234'6-TeCB 26.80 PCB-72 23'55'-TeCB 27.52 PCB-68 23'45'-TeCB 27.78 PCB-57 233'5-TeCB 28.15 PCB-58 233'5'-TeCB 28.35 PCB-67 23'45-TeCB 28.51 PCB-63 234'5-TeCB 28.74 PCB-61/70/74/76 ...-TeCB 29.03 PCB-66 23'44'-TeCB 29.32 PCB-55 233'4-TeCB 29.46 PCB-56 233'4'-TeCB 29.90 PCB-60 2344'-TeCB 30.09 PCB-80 33'55'-TeCB 30.42 PCB-79 33'45'-TeCB 31.75 PCB-78 33'45-TeCB 32.24 PCB-104 22'466'-PeCB 25.68 PCB-96 22'366'-PeCB 26.00 PCB-103 22'45'6-PeCB 27.69 PCB-94 22'356'-PeCB 27.89 PCB-95 22'35'6-PeCB 28.27 PCB-100/93 22'44'6/22'356-PeCB 28.48 PCB-102 22'456'-PeCB 28.59 PCB-98 22'34'6'-PeCB 28.66 PCB-88 22'346-PeCB 28.96 PCB-91 22'34'6-PeCB 29.03 PCB-84 22'33'6-PeCB 29.22 PCB-89 22'346'-PeCB 29.64 PCB-121 23'45'6-PeCB 29.99 PCB-92 22'355'-PeCB 30.31 PCB-113/90/101 ...-PeCB 30.79 PCB-83 22'33'5-PeCB 31.23 PCB-99 22'44'5-PeCB 31.33 PCB-112 233'56-PeCB 31.43 PCB-108/119/86/97/125...-PeCB 31.78 PCB-117 234'56-PeCB 32.31 PCB-116/85 23456/22'344'-PeCB 32.41 PCB-110 233'4'6-PeCB 32.52 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 5.03E+07 1.61E+08 2.11E+08 4.56E+07 4.24E+07 1.01E+08 7.33E+07 7.21E+07 7.57E+07 6.97E+07 6.93E+07 7.46E+07 7.70E+07 2.84E+08 6.58E+07 6.61E+07 6.57E+07 6.65E+07 7.84E+07 7.58E+07 6.37E+07 4.68E+07 4.07E+07 4.49E+07 3.89E+07 4.15E+07 8.23E+07 4.80E+07 3.74E+07 3.48E+07 4.85E+07 3.51E+07 3.72E+07 5.76E+07 3.91E+07 1.40E+08 3.39E+07 4.26E+07 5.82E+07 2.85E+08 5.48E+07 8.79E+07 5.86E+07 RA 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.77 Y 0.79 Y 0.78 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.79 Y 0.78 Y 0.79 Y 0.64 Y 0.65 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.61 Y 0.62 Y 0.61 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.87 0.93 1.21 0.79 0.73 0.87 1.27 1.25 1.31 1.20 1.20 1.29 1.33 1.23 1.14 1.14 1.13 1.15 1.35 1.31 1.10 1.45 1.26 0.96 0.83 0.89 0.88 1.03 0.80 0.74 1.04 0.75 0.80 1.23 0.84 1.00 0.72 0.91 1.24 1.01 1.17 0.94 1.25 Dev'n 3.5% 2.8% 4.0% 3.2% 5.4% 1.7% 3.7% 3.0% 2.4% 3.4% 1.6% 2.3% 2.5% 2.3% 3.1% 1.9% 2.2% 1.2% 3.1% 0.3% 3.6% 0.9% 2.3% 3.1% 3.9% 2.5% 1.9% 6.0% 5.5% -6.9% 9.9% 4.8% 4.3% 2.6% 1.9% 1.0% 1.2% -1.2% 6.6% 3.6% 2.9% -0.1% 12.0% 417 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 32.61 32.80 33.12 33.52 34.49 34.69 34.91 35.38 37.33 30.65 30.81 30.96 31.26 31.53 32.81 33.33 33.54 33.80 34.11 34.28 34.36 34.63 34.80 34.95 35.18 35.59 35.93 36.14 36.26 36.69 36.84 37.18 37.38 37.46 37.76 37.89 38.08 38.81 39.63 39.87 35.54 35.82 36.29 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 5.15E+07 3.29E+07 5.86E+07 5.80E+07 1.06E+08 6.23E+07 5.24E+07 4.86E+07 5.29E+07 5.34E+07 4.87E+07 5.03E+07 4.58E+07 4.68E+07 3.50E+07 6.71E+07 3.92E+07 3.50E+07 6.95E+07 2.62E+07 3.47E+07 7.06E+07 3.02E+07 2.97E+07 3.05E+07 3.33E+07 4.19E+07 3.49E+07 4.54E+07 8.69E+07 3.24E+07 2.87E+07 3.23E+07 4.64E+07 1.04E+08 4.57E+07 4.80E+07 7.91E+07 4.91E+07 4.82E+07 3.10E+07 2.89E+07 2.78E+07 RA 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 1.27 Y 1.29 Y 1.27 Y 1.28 Y 1.28 Y 1.29 Y 1.28 Y 1.27 Y 1.28 Y 1.26 Y 1.29 Y 1.29 Y 1.29 Y 1.28 Y 1.27 Y 1.29 Y 1.27 Y 1.29 Y 1.26 Y 1.29 Y 1.27 Y 1.26 Y 1.26 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.29 Y 1.23 Y 1.23 Y 1.22 Y 1.06 Y 1.08 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.10 0.70 1.25 1.24 1.14 1.33 1.12 1.01 1.11 1.27 1.16 1.20 1.09 1.12 1.19 1.14 1.33 1.19 1.18 0.89 1.18 1.20 1.03 1.01 1.03 1.13 1.42 1.19 1.54 1.48 1.10 0.97 1.10 1.58 1.17 1.55 1.63 0.91 1.13 1.11 1.26 1.17 1.13 Dev'n -5.0% 0.8% 2.6% 2.4% 3.4% 6.3% 1.3% 1.9% 1.5% 1.2% -0.8% 2.2% 2.6% 0.3% 0.6% 0.1% -0.9% 0.5% 0.4% -3.9% 4.3% -0.5% 0.0% 1.8% 0.4% -0.2% 1.0% -1.3% 1.3% 1.3% 1.2% 0.2% -5.5% 5.2% -1.4% 2.4% -1.8% 1.5% 1.7% 3.8% -0.6% 0.9% 0.2% 418 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS3_131220_PCB_XA 20-DEC-2013 18:04 131220X05 RT 36.58 36.98 38.11 38.66 38.89 39.07 39.42 39.50 39.61 39.98 40.33 40.52 41.87 42.12 42.39 42.73 43.50 43.95 40.09 40.88 41.46 41.65 41.73 44.06 44.64 44.81 45.94 47.89 48.28 45.73 46.52 49.76 Printed: 3-Jan-2014 16:57 ICAL: 131220 QC MM7 Response 3.08E+07 2.82E+07 2.06E+07 3.12E+07 3.32E+07 3.55E+07 3.70E+07 2.99E+07 2.90E+07 2.76E+07 3.21E+07 5.60E+07 2.94E+07 3.83E+07 7.38E+07 4.06E+07 2.83E+07 4.10E+07 2.75E+07 3.19E+07 2.88E+07 2.98E+07 3.01E+07 4.14E+07 2.18E+07 2.26E+07 2.41E+07 2.69E+07 3.40E+07 3.44E+07 3.65E+07 2.40E+07 RA 1.08 Y 1.09 Y 1.08 Y 1.07 Y 1.07 Y 1.06 Y 1.06 Y 1.07 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 1.05 Y 1.07 Y 1.06 Y 1.08 Y 1.08 Y 1.05 Y 0.92 Y 0.91 Y 0.93 Y 0.91 Y 0.93 Y 0.91 Y 0.91 Y 0.91 Y 0.93 Y 0.91 Y 0.92 Y 0.77 Y 0.78 Y 0.79 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.25 1.14 0.84 1.08 1.15 1.22 1.28 1.03 1.00 0.95 1.11 0.97 1.02 1.32 1.27 1.40 1.15 1.66 1.06 1.24 1.12 1.15 1.16 0.80 0.84 0.88 0.75 0.84 1.06 1.13 1.20 1.11 Dev'n 1.6% 1.7% -0.7% 0.3% 0.7% 4.2% 6.0% -2.8% 1.1% 0.0% 1.7% 1.8% 2.7% 2.5% 1.0% 0.4% 1.0% 0.2% 1.0% 1.2% 0.0% -3.2% 5.1% -0.8% 1.1% 0.2% -2.5% -0.9% -0.5% 0.6% 0.7% -0.3% 419 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.31e7 2.66e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.72e7 1.36e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.99e7 9.97e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.02e7 1.01e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.14e7 5.71e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.75e6 2.88e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.38e6 2.69e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 297-225 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:10 Page 1 of 21 420 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-1 8.10e7 12.04 Rel. Int. 100% PCB-2 8.16e7 14.17 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 2.95e3 Abs. Int. 3.37e7 PCB-3 7.81e7 14.36 1.68e7 0% 11.0 12.0 13.0 14.0 15.0 PCB-1 2.51e7 12.04 Rel. Int. 100% PCB-2 2.50e7 14.17 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 4.61e3 0.00e0 16.0 RT Abs. Int. 1.02e7 PCB-3 2.40e7 14.36 5.12e6 0% 11.0 12.0 13.0 14.0 ES-1 1.68e8 12.02 Rel. Int. 100% 15.0 Abs. Int. 6.63e7 ES-3 1.52e8 14.34 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 8.09e3 0.00e0 16.0 RT 3.32e7 0% 11.0 12.0 13.0 14.0 ES-1 5.08e7 12.02 Rel. Int. 100% 15.0 Abs. Int. 2.10e7 ES-3 4.52e7 14.34 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.05e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.31e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1305, 6088 scc: 297-225 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:10 Page 2 of 21 421 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Rel. Int. 100% PCB-10 6.05e7 14.80 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.28e3 PCB-4 3.73e7 14.62 1.01e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.76e7 14.80 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.69e4 PCB-4 2.35e7 14.61 12.0 13.0 14.0 15.0 ES-4 5.93e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.25e7 6.24e6 0% 11.0 Abs. Int. 2.01e7 0.00e0 16.0 RT Abs. Int. 1.97e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 7.17e3 9.87e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.66e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.25e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.04e3 6.25e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.31e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.66e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0655, 5434 scc: 297-225 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 3 of 21 422 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.09e4 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-6 6.06e7 17.01 PCB-9 5.66e7 16.62 PCB-14 7.06e7 19.01 PCB-5 6.00e7 17.32 PCB-8 6.10e7 17.44 PCB-11 6.08e7 19.80 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 13/12 1.20e8 20.09 Abs. Int. 2.06e7 PCB-15 6.08e7 20.38 1.03e7 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.56e4 PCB-9 3.46e7 16.62 PCB-7 3.94e7 16.78 18.0 19.0 PCB-14 4.35e7 19.01 PCB-5 3.70e7 17.32 PCB-8 3.73e7 17.44 20.0 PCB-11 3.71e7 19.80 13/12 7.35e7 20.09 21.0 Abs. Int. 1.26e7 PCB-15 3.71e7 20.38 6.30e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.13e8 16.60 21.0 ES-15 1.16e8 20.36 0.00e0 RT Abs. Int. 3.59e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.60e4 1.79e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 7.28e7 16.60 21.0 0.00e0 RT Abs. Int. 2.31e7 ES-15 7.40e7 20.36 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 1.25e4 1.15e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4598, 0207 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 4 of 21 423 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 30/18 7.47e7 19.51 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 3.64e3 PCB-19 2.79e7 17.73 PCB-17 3.19e7 19.91 PCB-27 4.38e7 20.11 PCB-24 4.15e7 20.24 PCB-16 2.39e7 20.34 Abs. Int. 2.03e7 PCB-32 4.61e7 20.82 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 7.11e7 19.51 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 4.04e3 PCB-19 2.64e7 17.73 PCB-17 3.03e7 19.91 21.0 PCB-24 3.98e7 20.24 PCB-27 4.15e7 20.11 Rel. Int. 100% 18.0 19.0 PCB-16 2.25e7 20.34 20.0 PCB-32 4.36e7 20.82 21.0 9.59e6 0.00e0 RT Abs. Int. 1.95e7 ES-19 4.84e7 17.72 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 8.84e4 0.00e0 RT Abs. Int. 1.92e7 0% 17.0 1.01e7 9.76e6 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 1.80e7 ES-19 4.48e7 17.72 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.99e4 0.00e0 RT 9.01e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2677, 3721 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 5 of 21 424 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 28/20 8.20e7 23.18 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 7.46e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-23 PCB-34 4.15e7 4.05e7 22.13 21.98 26/29 8.42e7 22.42 PCB-31 4.44e7 22.89 Abs. Int. 1.93e7 PCB-22 3.82e7 23.74 PCB-36 4.19e7 25.13 PCB-39 4.39e7 25.45 PCB-38 4.03e7 25.99 PCB-35 3.79e7 26.38 PCB-37 3.89e7 26.74 9.66e6 0% 22.0 24.0 25.0 26.0 27.0 28/20 8.32e7 23.18 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 6.03e3 23.0 PCB-23 PCB-34 4.18e7 4.10e7 22.13 21.98 26/29 8.52e7 22.42 PCB-31 4.47e7 22.89 Abs. Int. 1.94e7 PCB-22 3.90e7 23.74 PCB-36 4.24e7 25.13 PCB-39 4.43e7 25.45 PCB-38 4.06e7 25.99 PCB-35 3.84e7 26.38 PCB-37 3.92e7 26.74 9.69e6 0% 22.0 23.0 CS/SS-28 8.29e7 23.15 Rel. Int. 100% TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.92e4 24.0 25.0 26.0 27.0 23.0 24.0 1.13e7 25.0 26.0 CS/SS-28 7.62e7 23.15 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.27e7 ES-37 7.38e7 26.72 (8.29e7 + 7.62e7) RRF(CS-28) = = 1.81 (3.96e7 + 4.82e7) LKB 03-Jan-2014 15:10 0% 22.0 0.00e0 RT 27.0 Abs. Int. 2.07e7 ES-37 6.79e7 26.72 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 4.37e4 0.00e0 RT 1.04e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2630, 0050 scc: 297-225 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 6 of 21 425 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-54 2.30e7 20.67 Rel. Int. 100% Abs. Int. 6.33e6 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 1.43e3 3.17e6 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.80e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.75e6 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.25e3 3.87e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.37e7 20.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.21e6 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.87e4 4.60e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.12e7 20.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.10e4 5.62e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5811, 4868 scc: 297-225 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 7 of 21 426 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 2.05e3 50/53 4.60e7 22.67 PCB-51 2.40e7 23.33 PCB-45 1.89e7 23.26 PCB-73 PCB-52 2.87e7 2.19e7 24.93 24.80 PCB-46 1.84e7 23.54 69/49 5.38e7 25.23 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 44/47… 7.13e7 25.73 PCB-48 2.21e7 25.51 59/62… 9.32e7 26.01 71/40 4.48e7 26.60 PCB-42 2.01e7 26.17 PCB-41 1.85e7 26.51 Abs. Int. 1.68e7 PCB-64 3.24e7 26.80 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 2.01e3 50/53 5.81e7 22.67 24.0 PCB-51 3.01e7 23.33 PCB-45 2.41e7 23.26 25.0 PCB-73 3.63e7 PCB-52 24.93 2.78e7 24.80 PCB-46 2.35e7 23.54 26.0 69/49 6.83e7 25.23 44/47… 9.00e7 25.73 PCB-48 2.81e7 25.51 27.0 59/62… 1.17e8 26.00 71/40 5.63e7 26.60 PCB-42 2.55e7 26.17 PCB-41 2.39e7 26.51 23.0 24.0 25.0 26.0 PCB-64 4.09e7 26.80 27.0 JS-52 3.96e7 24.78 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.12e7 0% 22.0 8.42e6 1.06e7 0.00e0 RT Abs. Int. 1.03e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 3.01e4 5.16e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 4.82e7 24.78 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.93e4 6.39e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6030, 5973 scc: 297-225 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 8 of 21 427 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 61/70... 1.24e8 29.03 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 8.75e4 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-68 3.33e7 27.78 PCB-67 3.27e7 28.51 PCB-55 2.90e7 29.46 PCB-60 PCB-80 2.92e7 3.46e7 30.42 30.09 PCB-79 3.33e7 31.75 PCB-78 2.80e7 32.24PCB-81 2.83e7 32.62 Abs. Int. 1.54e7 PCB-77 2.95e7 33.10 7.71e6 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 5.75e4 PCB-57 3.91e7 28.15 PCB-68 4.24e7 27.78 30.0 61/70... 1.59e8 29.03 32.0 PCB-60 3.73e7 30.09 PCB-63 PCB-66 4.34e7 3.69e7 PCB-56 3.69e7 28.74 29.31 29.90 PCB-80 4.38e7 30.42 PCB-79 4.25e7 31.74 34.0 PCB-78 3.56e7 32.24PCB-81 3.63e7 32.62 36.0 38.0 Abs. Int. 1.98e7 PCB-77 3.77e7 33.10 9.88e6 0% 28.0 Rel. Int. 100% TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.69e4 30.0 32.0 34.0 ES-81 5.16e7 32.60 (5.16e7 + 6.42e7) * 100 pg/uL = 1.32 (3.96e7 + 4.82e7) * 100 pg/uL LKB 03-Jan-2014 15:09 RRF(ES-81) = 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.42e7 ES-77 5.20e7 33.08 7.08e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.42e7 32.60 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 2.60e4 36.0 38.0 0.00e0 RT Abs. Int. 1.77e7 ES-77 6.59e7 33.08 8.85e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8755, 8946 scc: 297-225 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 9 of 21 428 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-104 1.83e7 25.68 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 8.52e2 Abs. Int. 4.64e6 PCB-96 1.60e7 26.00 2.32e6 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.84e7 25.68 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.03e3 27.0 0.00e0 RT Abs. Int. 7.28e6 PCB-96 2.46e7 25.99 3.64e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.06e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.01e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 1.98e3 5.07e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.41e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.06e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.06e3 3.03e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.97e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9856, 2300 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 10 of 21 429 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 108/119... 1.09e8 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 1.43e5 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-103 1.72e7 27.69 PCB-91 1.86e7 100/93 29.03 3.15e7 28.48 PCB-88 1.32e7 28.96 PCB-121 2.21e7 29.99 113/90… 5.36e7 30.79 116/85 3.39e7 32.41 PCB-99 1.63e7 31.33 PCB-111 2.24e7 PCB-120 2.22e7 33.12 33.52 107/124 PCB-118 2.13e7 4.05e7 35.08 34.49 PCB-114 PCB-123 2.27e7 2.21e7 35.55 34.80 Abs. Int. 1.58e7 PCB-105 2.05e7 36.09 PCB-127 2.01e7 37.33 7.92e6 0% 28.0 30.0 32.0 36.0 38.0 108/119... 1.76e8 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 1.25e5 34.0 PCB-94 2.39e7 27.88 100/93 5.08e7 28.48 PCB-91 2.99e7 29.03 PCB-89 2.31e7 29.64 113/90… 8.61e7 30.79 PCB-112 3.59e7 PCB-92 31.43 2.43e7 30.31 116/85 PCB-115 5.40e7 3.18e7 PCB-111 32.40 32.61 3.62e7 33.12 PCB-117 PCB-110 PCB-120 3.38e7 3.61e7 PCB-82 3.58e7 32.31 32.52 2.03e7 33.52 32.80 107/124 PCB-118 3.42e7 6.57e7 35.08 34.49 PCB-114 PCB-123 3.63e7 3.54e7 35.55 34.80 Abs. Int. 2.53e7 PCB-105 3.31e7 36.09 PCB-127 3.28e7 37.33 1.27e7 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 6.07e7 33.09 JS-101 4.93e7 30.80 36.0 ES-118 ES-114 5.96e7 35.53 ES-123 5.64e7 5.74e7 35.06 34.78 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 4.18e3 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.48e7 ES-105 5.82e7 36.07 7.42e6 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 3.77e7 33.10 JS-101 3.12e7 30.80 36.0 ES-118 ES-114 ES-123 3.47e7 3.63e7 3.62e7 35.06 35.53 34.78 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.13e3 38.0 0.00e0 RT Abs. Int. 9.26e6 ES-105 3.70e7 36.07 4.63e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4291, 2615 scc: 297-225 Revised: 03-Jan-2014 16:45 (LKB) Printed: 03-Jan-2014 17:11 Page 11 of 21 430 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 Abs. Int. 3.89e6 PCB-126 1.72e7 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 2.70e3 1.94e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.44e6 PCB-126 2.76e7 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 3.20e3 3.22e6 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.21e7 ES-126 4.93e7 38.69 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.26e3 6.04e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 7.54e6 ES-126 3.09e7 38.69 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 8.80e3 3.77e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5774, 8779 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 12 of 21 431 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% PCB-150 PCB-155 2.82e7 2.99e7 30.96 30.65 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 9.06e2 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 147/149 139/140 3.88e7 3.97e7 34.11 34.63 PCB-145 2.62e7 31.53 PCB-148 1.97e7 32.81 153/168 4.86e7 36.69 151/135PCB-144 3.76e7 1.97e7 PCB-143 PCB-142 PCB-133 PCB-146 1.95e7 1.86e7 1.95e7 33.33 33.80 1.66e7 36.14 34.36 35.59 34.95 PCB-141 1.81e7 36.84 163/138… 5.81e7 37.76 PCB-160 PCB-164 2.60e7 2.56e7 37.46 37.89 0% 28.0 30.0 32.0 PCB-152 2.13e7 30.81 PCB-150 PCB-155 2.21e7 2.35e7 30.95 30.65 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.05e3 PCB-145 2.06e7 31.53 34.0 PCB-148 1.53e7 32.81 147/149 139/140 151/135 3.08e7 3.09e7 2.95e7 34.11 34.63 33.33 PCB-154 PCB-143 1.73e7 1.51e7PCB-131 33.54 34.36 1.32e7 34.80 36.0 38.0 153/168 3.83e7 36.69 PCB-165 1.83e7 35.93 163/138… 4.56e7 37.75 PCB-141 PCB-137 1.43e7 1.43e7 37.38 36.84 PCB-158 2.10e7 38.08 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.73e7 30.63 Rel. Int. 100% ES-153 3.32e7 36.65 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.52e3 Abs. Int. 1.10e7 5.51e6 0.00e0 RT Abs. Int. 8.70e6 4.35e6 0.00e0 RT Abs. Int. 1.17e7 JS-138 3.00e7 37.72 5.87e6 0% 28.0 30.0 32.0 34.0 36.0 ES-155 3.64e7 30.63 Rel. Int. 100% 38.0 ES-153 2.57e7 36.65 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 1.83e3 0.00e0 RT Abs. Int. 8.88e6 JS-138 2.35e7 37.72 4.44e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0360, 4999 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 13 of 21 432 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.35e7 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.95e3 PCB-159 2.71e7 39.63 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-162 2.65e7 39.87 156/157 5.15e7 41.26 Abs. Int. 1.02e7 (2.84e7 + 2.34e7) * 100 pg/uL = 1.20 (4.86e7 + 3.80e7) * 50 pg/uL LKB 03-Jan-2014 11:58 RRF(PCB-167) = PCB-167 2.84e7 40.28 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-169 2.58e7 43.98 5.09e6 0% 39.0 Rel. Int. 100% 128/166 3.55e7 38.81 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 3.14e3 40.0 PCB-162 PCB-159 2.17e7 2.20e7 39.87 39.63 41.0 42.0 43.0 44.0 45.0 156/157 4.20e7 41.26 Abs. Int. 8.23e6 PCB-169 2.08e7 43.98 PCB-167 2.34e7 40.28 4.11e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-156/157 9.34e7 41.24 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.68e7 ES-167 4.86e7 40.26 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 7.61e3 0.00e0 RT ES-169 4.52e7 43.96 8.40e6 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 3.80e7 40.26 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 8.72e3 42.0 43.0 44.0 45.0 ES-156/157 7.32e7 41.24 0.00e0 RT Abs. Int. 1.31e7 ES-169 3.54e7 43.96 6.56e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6303, 7049 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 14 of 21 433 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Rel. Int. 100% PCB-188 1.60e7 35.54 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-179 PCB-184 1.50e7 1.45e7 35.82 36.29 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.15e2 PCB-186 1.47e7 36.98 Abs. Int. 3.96e6 PCB-178 1.07e7 38.11 1.98e6 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 1.50e7 35.54 PCB-179 1.39e7 35.82 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 6.04e2 37.0 PCB-176 1.48e7 36.58 PCB-186 1.35e7 36.98 38.0 Abs. Int. 3.73e6 PCB-178 9.89e6 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.59e7 35.52 Rel. Int. 100% CS/SS-178 1.57e7 38.09 0% 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.33e7 35.52 Rel. Int. 100% CS/SS-178 1.42e7 38.09 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.20e6 0.00e0 RT Abs. Int. 5.64e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.22e3 31.0 1.86e6 Abs. Int. 6.41e6 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.23e3 31.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 2.82e6 0.00e0 RT Abs. Int. 2.02e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9174, 9814 scc: 297-225 PKD: 30-Dec-2013 12:20 Printed: 03-Jan-2014 17:11 Page 15 of 21 434 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 4.43e3 PCB-183 1.91e7 PCB-182 39.42 PCB-185 1.83e7 1.54e7 39.07 39.50 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 180/193 3.80e7 42.39 171/173 2.87e7 PCB-181 40.52 PCB-177 1.65e7 1.42e7 40.33 39.98 PCB-172 1.51e7 41.87 PCB-191 2.11e7 42.73 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-170 1.47e7 43.50 Abs. Int. 6.40e6 PCB-190 2.10e7 43.95 3.20e6 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 3.72e3 PCB-182 1.72e7 39.07 PCB-183 PCB-187 1.79e7 1.61e7 39.42 38.89 40.0 41.0 42.0 43.0 180/193 3.58e7 42.39 171/173 2.72e7 PCB-181 40.52 PCB-177 1.56e7 1.34e7 40.33 39.98 PCB-172 1.43e7 41.87 PCB-191 1.95e7 42.73 44.0 45.0 Abs. Int. 6.07e6 PCB-190 2.01e7 43.95 PCB-170 1.36e7 43.50 3.04e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.02e7 42.41 Rel. Int. 100% 0.00e0 RT 44.0 45.0 0.00e0 RT Abs. Int. 7.37e6 ES-170 2.58e7 43.48 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 3.18e3 3.69e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 2.77e7 42.41 Rel. Int. 100% 44.0 45.0 Abs. Int. 6.77e6 ES-170 2.36e7 43.48 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.05e3 0.00e0 RT 3.39e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1388, 8460 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 16 of 21 435 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-189 2.24e7 46.12 Abs. Int. 5.28e6 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.74e3 2.64e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.15e7 46.12 Abs. Int. 5.00e6 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 2.13e3 2.50e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 4.12e7 46.10 0.00e0 RT Abs. Int. 1.01e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 3.83e3 5.04e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.06e7 46.10 0.00e0 RT Abs. Int. 9.92e6 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.31e3 4.96e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7725, 6868 scc: 297-225 PKD: 30-Dec-2013 12:20 Printed: 03-Jan-2014 17:11 Page 17 of 21 436 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 PCB-202 1.32e7 40.09 Rel. Int. 100% PCB-201 1.52e7 40.88 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.54e2 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 198/199 1.98e7 44.06 PCB-197 1.42e7 PCB-204 41.65 PCB-200 1.39e7 1.45e7 41.46 41.73 Abs. Int. 3.62e6 PCB-196 1.04e7 44.64 PCB-203 1.08e7 44.81 1.81e6 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.43e7 40.09 41.0 PCB-201 1.67e7 40.88 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 7.75e2 42.0 43.0 44.0 45.0 198/199 2.17e7 44.06 PCB-197 1.55e7 PCB-204 41.65 PCB-200 1.49e7 1.56e7 41.46 41.73 0.00e0 RT Abs. Int. 3.99e6 PCB-196 1.14e7 44.64 PCB-203 1.18e7 44.81 1.99e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.49e7 40.07 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.20e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.53e3 3.10e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.68e7 40.07 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.66e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 1.32e3 3.33e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2479, 9839 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 18 of 21 437 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.61e3 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-205 1.63e7 48.28 PCB-195 1.16e7 45.94 Abs. Int. 3.80e6 PCB-194 1.29e7 47.89 1.90e6 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 2.48e3 47.0 48.0 49.0 50.0 PCB-205 1.77e7 48.28 PCB-195 1.25e7 45.94 0.00e0 RT Abs. Int. 4.16e6 PCB-194 1.41e7 47.88 2.08e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.04e7 48.27 Rel. Int. 100% Abs. Int. 7.24e6 JS-194 2.49e7 47.87 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.67e3 0.00e0 RT 3.62e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.40e7 48.27 Rel. Int. 100% Abs. Int. 8.13e6 JS-194 2.73e7 47.87 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.23e3 0.00e0 RT 4.07e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9372, 9268 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 19 of 21 438 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.22e3 PCB-208 1.50e7 45.73 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-207 1.60e7 46.52 Abs. Int. 3.79e6 PCB-206 1.06e7 49.76 1.89e6 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 1.78e3 PCB-208 1.94e7 45.73 47.0 48.0 49.0 50.0 PCB-207 2.05e7 46.52 Abs. Int. 4.79e6 PCB-206 1.34e7 49.76 2.40e6 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 2.71e7 45.71 50.0 0.00e0 RT Abs. Int. 6.38e6 ES-206 1.92e7 49.74 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.45e3 3.19e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.39e7 45.71 50.0 Abs. Int. 8.08e6 ES-206 2.40e7 49.74 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 3.05e3 0.00e0 RT 4.04e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.75e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.88e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5390, 1741 scc: 297-225 Revised: 30-Dec-2013 12:20 (LKB) Printed: 03-Jan-2014 17:11 Page 20 of 21 439 of 603 SGS-AP ID: CS3_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-3 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 40 Acq: 20-Dec-2013 18:04:38 User: LKB Datafile: 131220X05 PCB-209 1.71e7 51.23 Rel. Int. 100% Abs. Int. 3.49e6 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 6.63e2 1.74e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.44e7 51.23 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.92e6 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.15e2 1.46e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.16e7 51.21 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.46e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 7.77e2 3.23e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.62e7 51.21 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.44e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.95e2 2.72e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.38e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.69e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS3_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6160, 7361 scc: 297-225 PKD: 30-Dec-2013 12:19 Printed: 03-Jan-2014 17:11 Page 21 of 21 440 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.10 32.62 36.10 35.56 35.09 34.81 38.71 41.27 40.29 43.99 46.13 51.25 6.61E+08 6.42E+08 5.26E+08 5.80E+08 5.38E+08 5.67E+08 4.45E+08 9.01E+08 4.96E+08 4.52E+08 4.15E+08 2.92E+08 0.78 Y 0.78 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.63 Y 1.22 Y 1.23 Y 1.24 Y 1.05 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.17 1.14 1.15 1.24 1.22 1.23 1.14 1.11 1.18 1.14 1.10 1.10 1.7% 1.9% 3.3% 3.3% 2.6% 1.3% 2.8% 1.1% 1.4% 1.2% 2.3% -1.4% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.03 14.35 14.61 20.37 17.72 26.73 20.66 33.08 32.61 25.66 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.25 40.27 43.97 43.49 42.42 35.53 46.11 40.08 48.28 49.75 45.72 51.22 2.53E+08 2.32E+08 1.12E+08 2.25E+08 1.10E+08 1.69E+08 8.74E+07 1.41E+08 1.41E+08 7.69E+07 1.14E+08 1.17E+08 1.10E+08 1.15E+08 9.79E+07 6.88E+07 9.70E+07 2.03E+08 1.05E+08 9.92E+07 5.71E+07 6.95E+07 5.77E+07 9.44E+07 6.04E+07 7.51E+07 5.00E+07 7.07E+07 6.66E+07 3.29 Y 3.37 Y 1.64 Y 1.54 Y 1.08 Y 1.08 Y 0.83 Y 0.79 Y 0.77 Y 1.65 Y 1.60 Y 1.63 Y 1.63 Y 1.60 Y 1.53 Y 1.31 Y 1.30 Y 1.29 Y 1.27 Y 1.27 Y 1.09 Y 1.09 Y 1.13 Y 1.04 Y 0.94 Y 0.90 Y 0.81 Y 0.80 Y 1.18 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.17 1.08 0.52 1.05 0.51 1.66 0.86 1.38 1.38 0.79 1.18 1.21 1.14 1.19 1.01 1.11 1.56 1.64 1.70 1.60 0.95 1.16 0.93 1.57 0.97 1.25 0.83 1.18 1.11 -1.5% -0.6% -0.1% 0.6% 0.9% -0.4% -0.5% 0.0% 1.1% -1.2% -1.7% -1.1% -1.8% 0.4% -1.7% -0.6% -1.7% 2.3% 1.7% 2.7% 0.6% 2.0% -1.0% -0.5% 0.4% 0.7% 0.6% 0.4% 0.1% Page 1 of 6 441 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.10 38.10 1.88E+08 1.16E+08 3.54E+07 1.09 Y 1.60 Y 1.11 Y 1.11 1.03 0.62 1.11 1.00 0.61 0.2% -2.6% -1.0% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.10 38.10 1.88E+08 1.16E+08 3.54E+07 1.09 Y 1.60 Y 1.11 Y 1.85 1.22 0.58 1.84 1.19 0.57 -0.1% -2.2% -2.0% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.80 37.72 47.88 2.15E+08 1.02E+08 9.69E+07 6.21E+07 6.00E+07 1.55 Y 0.80 Y 1.60 Y 1.30 Y 0.91 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.04 14.36 14.62 20.38 17.74 26.75 20.68 25.69 30.66 35.55 40.10 48.30 45.74 49.77 9.92E+08 9.76E+08 5.69E+08 9.40E+08 5.10E+08 7.43E+08 4.71E+08 4.46E+08 5.02E+08 2.95E+08 2.56E+08 3.22E+08 3.23E+08 2.24E+08 3.21 Y 3.28 Y 1.58 Y 1.62 Y 1.05 Y 0.98 Y 0.83 Y 0.64 Y 1.27 Y 1.08 Y 0.92 Y 0.91 Y 0.78 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.98 1.05 1.27 1.04 1.16 1.10 1.35 1.45 1.29 1.28 1.06 1.07 1.14 1.12 3.0% 4.2% 2.9% 2.4% 1.2% 2.0% -0.4% 1.0% 2.6% 0.6% 0.6% 1.2% 1.7% 0.5% Page 2 of 6 442 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 12.04 14.18 14.36 14.62 14.80 16.62 16.79 17.02 17.32 17.44 19.01 19.80 20.10 20.38 17.74 19.51 19.92 20.11 20.25 20.34 20.83 21.98 22.14 22.42 22.62 22.90 23.19 23.37 23.75 25.14 25.46 25.99 26.39 26.75 20.68 22.68 23.27 23.34 23.55 24.81 24.94 25.04 25.23 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 9.92E+08 1.00E+09 9.76E+08 5.69E+08 9.17E+08 8.62E+08 9.69E+08 9.24E+08 9.17E+08 9.28E+08 1.09E+09 9.34E+08 1.86E+09 9.40E+08 5.10E+08 1.39E+09 5.88E+08 8.20E+08 7.60E+08 4.62E+08 8.47E+08 7.98E+08 8.06E+08 1.63E+09 8.00E+08 8.40E+08 1.58E+09 1.64E+09 7.44E+08 8.17E+08 8.41E+08 7.83E+08 7.26E+08 7.43E+08 4.71E+08 1.00E+09 4.42E+08 4.96E+08 3.98E+08 4.82E+08 6.34E+08 4.03E+08 1.18E+09 RA 3.21 Y 3.28 Y 3.28 Y 1.58 Y 1.60 Y 1.63 Y 1.64 Y 1.65 Y 1.63 Y 1.63 Y 1.64 Y 1.64 Y 1.64 Y 1.62 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.05 Y 1.06 Y 1.05 Y 0.99 Y 0.98 Y 0.98 Y 0.97 Y 0.97 Y 0.99 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.99 Y 0.99 Y 0.98 Y 0.83 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.98 1.08 1.05 1.27 2.04 0.96 1.08 1.03 1.02 1.03 1.21 1.04 1.03 1.04 1.16 1.59 1.34 1.87 1.73 1.05 1.93 1.18 1.19 1.21 1.18 1.24 1.17 1.21 1.10 1.21 1.25 1.16 1.07 1.10 1.35 0.89 0.78 0.88 0.71 0.85 1.12 0.72 1.05 Dev'n 3.0% 4.2% 4.2% 2.9% 3.1% 1.3% 2.9% 3.0% 1.7% -0.2% 2.2% 2.7% 4.5% 2.4% 1.2% 3.3% 2.6% 2.8% 0.5% 4.7% 0.6% 4.1% 3.3% 2.9% 2.4% 1.5% 3.0% 3.3% 2.0% 3.4% 2.8% 4.9% 3.4% 2.0% -0.4% 1.4% 2.2% 2.5% 1.0% 1.3% 1.1% 0.7% 2.5% 443 of 603 PCB QC Summary - Ax2 Detail Lab ID: CS4_131220_PCB_XA Acquired: 20-DEC-2013 18:59 Datafile: 131220X06 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.01 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.51 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.78 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.36 PCB-67 23'45-TeCB 28.52 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.04 PCB-66 23'44'-TeCB 29.32 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.10 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.75 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.00 PCB-103 22'45'6-PeCB 27.70 PCB-94 22'356'-PeCB 27.89 PCB-95 22'35'6-PeCB 28.27 PCB-100/93 22'44'6/22'356-PeCB 28.49 PCB-102 22'456'-PeCB 28.60 PCB-98 22'34'6'-PeCB 28.67 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.23 PCB-89 22'346'-PeCB 29.65 PCB-121 23'45'6-PeCB 29.99 PCB-92 22'355'-PeCB 30.31 PCB-113/90/101 ...-PeCB 30.80 PCB-83 22'33'5-PeCB 31.24 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.78 PCB-117 234'56-PeCB 32.32 PCB-116/85 23456/22'344'-PeCB 32.41 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 4.79E+08 1.57E+09 2.05E+09 4.36E+08 3.81E+08 1.02E+09 7.02E+08 6.86E+08 7.41E+08 6.53E+08 6.72E+08 7.17E+08 7.44E+08 2.76E+09 6.42E+08 6.33E+08 6.29E+08 6.41E+08 7.47E+08 7.60E+08 6.10E+08 4.46E+08 3.93E+08 4.37E+08 3.75E+08 4.04E+08 8.29E+08 4.01E+08 3.96E+08 3.93E+08 4.40E+08 3.38E+08 3.62E+08 5.66E+08 3.81E+08 1.39E+09 3.22E+08 4.51E+08 5.42E+08 2.82E+09 5.03E+08 9.15E+08 5.11E+08 RA 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.80 Y 0.79 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.78 Y 0.64 Y 0.65 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.85 0.93 1.22 0.77 0.68 0.90 1.25 1.22 1.31 1.16 1.19 1.27 1.32 1.22 1.14 1.12 1.12 1.14 1.32 1.35 1.08 1.45 1.28 0.95 0.81 0.87 0.90 0.87 0.86 0.85 0.95 0.73 0.78 1.23 0.83 1.01 0.70 0.98 1.17 1.02 1.09 0.99 1.11 Dev'n 1.4% 3.0% 4.3% 1.5% -2.7% 4.9% 2.0% 0.7% 2.9% -0.5% 1.1% 1.1% 1.7% 2.2% 3.3% 0.3% 0.6% 0.2% 0.9% 3.2% 1.9% 1.0% 3.9% 1.6% 1.6% 0.9% 3.9% -10.2% 13.2% 6.8% 0.9% 2.3% 2.8% 2.2% 0.7% 2.0% -2.5% 6.1% 0.5% 3.8% -4.3% 5.3% -1.0% 444 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 32.62 32.81 33.12 33.52 34.49 34.70 34.92 35.38 37.34 30.66 30.82 30.96 31.27 31.54 32.82 33.34 33.55 33.81 34.11 34.29 34.37 34.64 34.81 34.96 35.19 35.59 35.94 36.15 36.27 36.70 36.85 37.19 37.39 37.47 37.76 37.90 38.09 38.82 39.64 39.88 35.55 35.83 36.30 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 5.34E+08 3.31E+08 5.66E+08 5.76E+08 1.03E+09 5.82E+08 5.22E+08 4.75E+08 5.12E+08 5.02E+08 4.78E+08 4.68E+08 4.35E+08 4.41E+08 3.38E+08 6.39E+08 3.76E+08 3.29E+08 6.68E+08 2.65E+08 3.08E+08 6.80E+08 2.87E+08 2.82E+08 2.84E+08 3.19E+08 3.83E+08 3.42E+08 4.26E+08 8.26E+08 3.01E+08 2.69E+08 3.35E+08 4.16E+08 1.01E+09 4.29E+08 4.60E+08 7.86E+08 4.70E+08 4.62E+08 2.95E+08 2.67E+08 2.61E+08 RA 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.63 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.28 Y 1.27 Y 1.26 Y 1.28 Y 1.27 Y 1.28 Y 1.29 Y 1.30 Y 1.28 Y 1.28 Y 1.27 Y 1.28 Y 1.27 Y 1.29 Y 1.27 Y 1.27 Y 1.29 Y 1.27 Y 1.27 Y 1.28 Y 1.23 Y 1.23 Y 1.22 Y 1.08 Y 1.10 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.16 0.72 1.23 1.25 1.12 1.26 1.13 1.02 1.12 1.29 1.23 1.21 1.12 1.14 1.23 1.16 1.37 1.20 1.21 0.96 1.12 1.24 1.04 1.03 1.03 1.16 1.39 1.24 1.55 1.50 1.10 0.98 1.22 1.51 1.23 1.56 1.67 0.93 1.12 1.10 1.28 1.16 1.13 Dev'n -0.2% 3.0% 0.5% 2.9% 2.0% 0.6% 2.4% 2.2% 2.2% 2.6% 5.1% 2.7% 5.1% 2.1% 3.8% 1.9% 1.9% 1.2% 3.2% 4.4% -1.0% 2.6% 1.8% 3.6% 0.3% 2.4% -1.3% 3.4% 1.8% 3.0% 0.7% 0.6% 4.6% 0.9% 3.3% 2.8% 0.5% 3.7% 0.1% 2.4% 0.6% -0.3% 0.2% 445 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS4_131220_PCB_XA 20-DEC-2013 18:59 131220X06 RT 36.59 36.99 38.12 38.67 38.90 39.08 39.42 39.51 39.62 39.99 40.34 40.53 41.88 42.13 42.40 42.74 43.51 43.96 40.10 40.89 41.47 41.66 41.75 44.07 44.65 44.82 45.95 47.90 48.30 45.74 46.53 49.77 Printed: 3-Jan-2014 16:55 ICAL: 131220 QC MM7 Response 2.85E+08 2.59E+08 1.94E+08 3.05E+08 3.25E+08 3.35E+08 3.29E+08 3.20E+08 2.73E+08 2.68E+08 3.10E+08 5.43E+08 2.79E+08 3.67E+08 7.06E+08 3.88E+08 2.72E+08 3.86E+08 2.56E+08 3.08E+08 2.70E+08 2.93E+08 2.71E+08 3.95E+08 2.03E+08 2.13E+08 2.31E+08 2.54E+08 3.22E+08 3.23E+08 3.40E+08 2.24E+08 RA 1.09 Y 1.08 Y 1.08 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 0.92 Y 0.92 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.92 Y 0.92 Y 0.91 Y 0.92 Y 0.91 Y 0.78 Y 0.79 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.24 1.12 0.84 1.10 1.17 1.21 1.18 1.15 0.98 0.96 1.12 0.98 1.00 1.32 1.27 1.40 1.19 1.69 1.06 1.27 1.12 1.21 1.12 0.82 0.84 0.88 0.77 0.85 1.07 1.14 1.20 1.12 Dev'n 0.3% -0.3% -0.6% 2.1% 2.6% 2.7% -1.8% 8.5% -0.9% 1.4% 2.5% 3.1% 1.6% 2.6% 0.7% 0.1% 4.9% 1.7% 0.6% 4.3% 0.3% 1.7% 1.3% 0.9% 0.6% 1.0% 0.4% 0.4% 1.2% 1.7% 1.2% 0.5% 446 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.95e7 2.48e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.59e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.85e7 9.24e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.88e7 9.40e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.07e7 5.35e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.31e6 2.66e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.17e6 2.58e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 186-257 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:11 Page 1 of 21 447 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-1 7.57e8 12.04 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-2 7.66e8 14.18 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 3.55e3 Abs. Int. 3.12e8 PCB-3 7.48e8 14.36 1.56e8 0% 11.0 12.0 13.0 14.0 PCB-1 2.36e8 12.04 Rel. Int. 100% PCB-2 2.34e8 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.14e3 15.0 0.00e0 16.0 RT Abs. Int. 9.75e7 PCB-3 2.28e8 14.36 4.88e7 0% 11.0 12.0 13.0 14.0 ES-1 1.94e8 12.03 Rel. Int. 100% 15.0 Abs. Int. 7.70e7 ES-3 1.79e8 14.35 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 8.48e3 0.00e0 16.0 RT 3.85e7 0% 11.0 12.0 13.0 14.0 ES-1 5.88e7 12.03 Rel. Int. 100% 15.0 Abs. Int. 2.33e7 ES-3 5.31e7 14.35 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.17e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.48e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2447, 4248 scc: 186-257 Revised: 30-Dec-2013 12:40 (LKB) Printed: 03-Jan-2014 17:11 Page 2 of 21 448 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Rel. Int. 100% PCB-10 5.64e8 14.80 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PBM 4σ 6.96e3 PCB-4 3.49e8 14.62 9.54e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 3.53e8 14.80 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.22e4 PCB-4 2.20e8 14.62 12.0 13.0 14.0 15.0 ES-4 6.97e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.20e8 6.02e7 0% 11.0 Abs. Int. 1.91e8 0.00e0 16.0 RT Abs. Int. 2.32e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.94e3 1.16e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.25e7 14.60 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.42e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 4.42e3 7.11e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.95e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.48e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5797, 8154 scc: 186-257 Revised: 30-Dec-2013 12:40 (LKB) Printed: 03-Jan-2014 17:11 Page 3 of 21 449 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 1.19e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-6 5.75e8 17.02 PCB-9 5.35e8 16.62 PCB-14 6.74e8 19.01 PCB-5 5.69e8 PCB-8 17.32 5.76e8 17.44 PCB-11 5.80e8 19.80 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 13/12 1.16e9 20.10 Abs. Int. 1.91e8 PCB-15 5.81e8 20.38 9.54e7 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 4.01e4 PCB-9 3.28e8 16.62 PCB-7 3.67e8 16.79 18.0 19.0 PCB-14 4.11e8 19.01 PCB-5 3.48e8 17.32 PCB-8 3.52e8 17.44 20.0 PCB-11 3.54e8 19.80 13/12 7.06e8 20.10 21.0 Abs. Int. 1.16e8 PCB-15 3.59e8 20.38 5.81e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.31e8 16.61 21.0 ES-15 1.36e8 20.37 0.00e0 RT Abs. Int. 4.21e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.87e4 2.11e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 8.44e7 16.61 21.0 ES-15 8.87e7 20.37 0.00e0 RT Abs. Int. 2.68e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 9.39e3 1.34e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2386, 7567 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 4 of 21 450 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 30/18 7.14e8 19.51 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 4.23e3 PCB-19 2.62e8 17.74 PCB-17 3.01e8 19.92 PCB-27 4.20e8 20.11 PCB-24 3.89e8 20.25 PCB-16 2.37e8 20.34 Abs. Int. 1.99e8 PCB-32 4.34e8 20.83 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.80e8 19.51 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 5.06e3 PCB-19 2.48e8 17.74 PCB-17 2.86e8 19.92 21.0 PCB-24 3.71e8 20.25 PCB-27 4.00e8 20.11 Rel. Int. 100% 18.0 19.0 PCB-16 2.25e8 20.34 20.0 PCB-32 4.13e8 20.83 21.0 9.49e7 0.00e0 RT Abs. Int. 2.38e7 ES-19 5.69e7 17.72 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 9.15e4 0.00e0 RT Abs. Int. 1.90e8 0% 17.0 9.97e7 1.19e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.16e7 ES-19 5.28e7 17.72 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.57e4 0.00e0 RT 1.08e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0138, 7970 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 5 of 21 451 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 1.75e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 28/20 7.84e8 23.19 26/29 PCB-23 8.07e8 PCB-34 3.99e8 22.42 3.98e8 22.14 21.98 PCB-31 4.13e8 22.90 Abs. Int. 1.95e8 PCB-22 3.70e8 23.75 PCB-36 4.06e8 25.14 PCB-39 4.17e8 25.46 PCB-38 3.90e8 25.99 PCB-35 3.61e8 26.39 PCB-37 3.69e8 26.75 0% 22.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 1.49e4 23.0 24.0 25.0 26.0 27.0 28/20 7.92e8 23.19 26/29 PCB-23 8.21e8 PCB-34 4.07e8 22.42 4.00e8 22.14 21.98 PCB-31 4.27e8 22.90 23.0 PCB-22 3.73e8 23.75 PCB-36 4.11e8 25.14 PCB-39 4.24e8 25.46 PCB-38 3.93e8 25.99 24.0 25.0 PCB-35 3.65e8 26.39 PCB-37 3.74e8 26.75 26.0 CS/SS-28 9.79e7 23.16 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e8 0% 22.0 9.74e7 27.0 0.00e0 RT Abs. Int. 2.75e7 ES-37 8.75e7 26.73 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 9.98e4 9.79e7 1.38e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 9.01e7 23.16 Rel. Int. 100% 27.0 0.00e0 RT Abs. Int. 2.57e7 ES-37 8.13e7 26.73 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.64e4 1.28e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3897, 4503 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 6 of 21 452 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-54 2.13e8 20.68 Rel. Int. 100% Abs. Int. 5.71e7 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 2.07e3 2.86e7 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 2.58e8 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.61e7 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.18e3 3.30e7 0% 17.0 18.0 19.0 20.0 21.0 ES-54 3.96e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.83e4 5.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.78e7 20.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.07e4 6.63e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.59e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0111, 4665 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 7 of 21 453 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 3.31e3 50/53 4.42e8 22.68 PCB-51 2.20e8 23.34 PCB-45 1.94e8 23.27 PCB-73 2.79e8 PCB-52 24.94 2.12e8 24.81 PCB-46 1.76e8 23.55 69/49 5.22e8 25.23 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 44/47… 6.94e8 25.74 PCB-48 2.12e8 25.52 59/62… 9.08e8 26.01 71/40 4.50e8 26.61 PCB-42 1.93e8 26.18 PCB-41 1.67e8 26.51 Abs. Int. 1.64e8 PCB-64 3.10e8 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 2.77e3 50/53 5.60e8 22.67 24.0 PCB-51 2.76e8 23.34 PCB-45 2.48e8 23.27 25.0 PCB-73 3.55e8 PCB-52 24.94 2.70e8 24.81 PCB-46 2.22e8 23.55 26.0 69/49 6.59e8 25.23 44/47… 8.79e8 25.73 PCB-48 2.68e8 25.52 27.0 59/62… 1.15e9 26.01 71/40 5.65e8 26.61 PCB-42 2.44e8 26.18 PCB-41 2.14e8 26.51 23.0 24.0 25.0 26.0 PCB-64 3.92e8 26.81 27.0 JS-52 4.53e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.06e8 0% 22.0 8.18e7 1.03e8 0.00e0 RT Abs. Int. 1.25e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.94e4 6.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.67e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 1.88e4 8.02e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6634, 9311 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 8 of 21 454 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 7.08e5 PCB-58 2.95e8 PCB-68 28.36 PCB-67 3.24e8 3.15e8 27.78 28.52 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 61/70... 1.21e9 29.04 PCB-55 2.78e8 29.47 PCB-60 PCB-80 2.82e8 3.28e8 30.10 30.43 PCB-79 3.33e8 31.75 PCB-78 2.67e8 32.25PCB-81 2.81e8 32.62 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 1.50e8 PCB-77 2.90e8 33.10 7.49e7 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 4.30e5 PCB-57 3.67e8 28.16 PCB-68 4.16e8 27.78 30.0 61/70... 1.55e9 29.04 PCB-63 4.18e8 PCB-66 3.61e8 28.74 29.32 32.0 PCB-60 3.59e8 30.10 PCB-56 3.53e8 29.91 PCB-80 4.19e8 30.43 PCB-79 4.27e8 31.75 34.0 PCB-78 3.43e8 32.24PCB-81 3.61e8 32.62 36.0 38.0 Abs. Int. 1.90e8 PCB-77 3.71e8 33.10 9.49e7 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 6.15e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.32e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 1.63e7 ES-77 6.25e7 33.08 8.16e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.94e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.92e4 36.0 38.0 0.00e0 RT Abs. Int. 2.16e7 ES-77 7.87e7 33.08 1.08e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9214, 1956 scc: 186-257 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 9 of 21 455 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Rel. Int. 100% Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-104 1.74e8 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.22e3 Abs. Int. 4.45e7 PCB-96 1.55e8 26.00 2.22e7 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 2.71e8 25.68 27.0 0.00e0 RT Abs. Int. 6.94e7 PCB-96 2.38e8 26.00 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.22e3 3.47e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 4.79e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.24e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.06e3 6.19e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 2.90e7 25.66 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.31e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 3.99e3 3.66e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.85e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9179, 1685 scc: 186-257 Revised: 30-Dec-2013 12:41 (LKB) Printed: 03-Jan-2014 17:11 Page 10 of 21 456 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 108/119... 1.09e9 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 4.02e5 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-103 1.67e8 27.70 PCB-91 1.70e8 100/93 29.04 3.16e8 28.49 PCB-88 PCB-84 1.50e8 1.30e8 28.98 29.23 PCB-121 2.18e8 29.99 113/90… 5.34e8 30.80 116/85 3.49e8 32.41 PCB-99 1.73e8 31.34 PCB-111 PCB-120 2.17e8 2.20e8 33.12 33.52 PCB-118 107/124 2.07e8 3.96e8 35.09 34.49 PCB-114 PCB-123 2.24e8 2.17e8 35.56 34.81 Abs. Int. 1.63e8 PCB-105 2.01e8 36.10 PCB-127 1.97e8 37.34 8.15e7 0% 28.0 30.0 32.0 36.0 38.0 108/119... 1.73e9 31.78 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 3.81e5 34.0 PCB-94 2.32e8 27.89 100/93 5.12e8 28.49 PCB-91 2.69e8 29.04 PCB-89 2.23e8 29.65 113/90… 8.58e8 30.80 PCB-112 3.34e8 PCB-92 31.44 2.35e8 30.31 116/85 PCB-115 5.66e8 3.29e8 PCB-111 32.41 32.62 3.49e8 33.12 PCB-117 PCB-110 PCB-120 3.10e8 3.14e8 PCB-82 3.55e8 32.32 32.53 2.05e8 33.52 32.81 PCB-118 107/124 3.31e8 6.37e8 35.09 34.49 PCB-114 PCB-123 3.56e8 3.50e8 35.56 34.81 Abs. Int. 2.59e8 PCB-105 3.25e8 36.10 PCB-127 3.15e8 37.33 1.30e8 0% 28.0 30.0 Rel. Int. 100% 32.0 34.0 CS/SS-111 7.11e7 33.10 JS-101 5.96e7 30.80 36.0 ES-114 ES-118 7.24e7 ES-123 6.82e7 35.54 7.10e7 35.07 34.79 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 5.01e3 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 1.77e7 ES-105 7.03e7 36.08 8.86e6 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.46e7 33.10 JS-101 3.72e7 30.80 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 3.24e3 34.0 36.0 ES-118 ES-114 ES-123 4.20e7 4.43e7 4.45e7 35.07 35.54 34.79 38.0 0.00e0 RT Abs. Int. 1.12e7 ES-105 4.41e7 36.08 5.59e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5110, 9189 scc: 186-257 Revised: 03-Jan-2014 16:45 (LKB) Printed: 03-Jan-2014 17:11 Page 11 of 21 457 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 4.01e7 PCB-126 1.72e8 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 7.09e3 2.01e7 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 6.56e7 PCB-126 2.74e8 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 1.06e4 3.28e7 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.43e7 ES-126 5.92e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.98e3 7.15e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 9.49e6 ES-126 3.86e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 6.20e3 4.75e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6238, 0621 scc: 186-257 Revised: 30-Dec-2013 12:42 (LKB) Printed: 03-Jan-2014 17:11 Page 12 of 21 458 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-136 2.43e8 31.27 PCB-150 PCB-155 2.62e8 PCB-145 2.81e8 30.96 2.47e8 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.99e3 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 147/149 139/140 3.74e8 3.81e8 34.11 34.64 PCB-148 1.89e8 32.82 151/135 3.58e8 PCB-144PCB-134 33.34 1.85e8 1.48e8 33.81 34.29 153/168 4.62e8 36.70 PCB-146 PCB-142 PCB-133 1.79e8 1.91e8 1.59e8 36.15 35.59 34.96 PCB-141 1.70e8 36.85 163/138… 5.67e8 37.76 PCB-164 PCB-160 2.34e8 2.40e8 37.47 37.90 0% 28.0 30.0 32.0 PCB-152 PCB-136 2.10e8 1.91e8 30.82 31.26 PCB-155 PCB-150 PCB-145 2.21e8 2.06e8 30.96 1.95e8 30.66 31.54 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 2.00e3 34.0 PCB-148 1.49e8 32.81 36.0 38.0 163/138… 4.47e8 147/149 139/140 37.76 153/168 151/135 2.94e8 3.00e8 PCB-142 3.63e8 2.80e8 34.11 34.641.23e8 36.70 33.34 PCB-158 34.96 PCB-154 2.02e8 PCB-133 PCB-146 PCB-141 PCB-137 PCB-143 1.66e8 38.08 PCB-131 1.40e8 1.51e8 1.35e8 1.26e8 33.55 1.31e8 1.47e8 36.15 37.39 35.59 34.37 34.81 36.85 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 5.48e7 30.64 Rel. Int. 100% ES-153 3.90e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 2.47e3 JS-138 3.51e7 37.72 Abs. Int. 1.07e8 5.37e7 0.00e0 RT Abs. Int. 8.44e7 4.22e7 0.00e0 RT Abs. Int. 1.34e7 6.72e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.22e7 30.64 Rel. Int. 100% ES-153 2.98e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 2.62e3 0.00e0 RT Abs. Int. 1.05e7 JS-138 2.69e7 37.72 5.27e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1491, 6768 scc: 186-257 Revised: 30-Dec-2013 12:42 (LKB) Printed: 03-Jan-2014 17:11 Page 13 of 21 459 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.33e8 38.82 PCB-159 2.59e8 39.64 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.38e4 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-162 2.54e8 39.88 156/157 4.95e8 41.27 PCB-167 2.73e8 40.29 (2.50e8 + 2.02e8) * 100 pg/uL RRF(PCB-169) = = 1.14 (5.54e7 + 4.38e7) * 400 pg/uL LKB 03-Jan-2014 15:13 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 Abs. Int. 1.01e8 PCB-169 2.50e8 43.99 5.03e7 0% 39.0 Rel. Int. 100% 128/166 3.53e8 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.35e4 40.0 PCB-162 PCB-159 2.08e8 2.11e8 39.88 39.64 41.0 42.0 43.0 44.0 45.0 156/157 4.05e8 41.27 Abs. Int. 8.13e7 PCB-169 2.02e8 43.99 PCB-167 2.23e8 40.29 4.06e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.89e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 6.07e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.14e8 41.25 0.00e0 RT Abs. Int. 2.04e7 ES-169 5.54e7 43.97 1.02e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 4.65e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 1.15e4 42.0 43.0 44.0 45.0 ES-156/157 8.87e7 41.25 0.00e0 RT Abs. Int. 1.58e7 ES-169 4.38e7 43.97 7.89e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0329, 5135 scc: 186-257 PKD: 30-Dec-2013 12:43 Printed: 03-Jan-2014 17:11 Page 14 of 21 460 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-184 PCB-188 PCB-179 1.36e8 1.40e8 1.53e8 36.30 35.83 35.55 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.20e3 PCB-186 1.35e8 36.99 Abs. Int. 3.81e7 PCB-178 1.01e8 38.12 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 PCB-179 1.27e8 1.41e8 35.83 35.55 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 1.40e3 37.0 PCB-176 1.36e8 36.59 PCB-186 1.24e8 36.99 38.0 32.0 33.0 34.0 35.0 36.0 37.0 PCB-178 9.30e7 38.12 38.0 ES-188 3.06e7 35.53 Rel. Int. 100% CS/SS-178 1.86e7 38.10 RRF(CS/SS-178) = 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 2.72e7 35.53 Rel. Int. 100% CS/SS-178 1.68e7 38.10 0% 32.0 33.0 34.0 35.0 0.00e0 RT 3.93e6 0.00e0 RT Abs. Int. 6.93e6 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 1.88e3 31.0 1.81e7 Abs. Int. 7.87e6 (1.86e7 + 1.68e7) = 0.571 (3.51e7 + 2.69e7) LKB 03-Jan-2014 15:12 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 1.68e3 0.00e0 RT Abs. Int. 3.61e7 0% 31.0 1.91e7 36.0 37.0 38.0 Rel. Int. 100% 3.47e6 0.00e0 RT Abs. Int. 1.88e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.40e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5850, 9481 scc: 186-257 Revised: 30-Dec-2013 12:43 (LKB) Printed: 03-Jan-2014 17:11 Page 15 of 21 461 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.32e4 PCB-183 1.69e8 39.42 PCB-182 PCB-185 1.72e8 1.65e8 39.08 39.51 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 180/193 3.63e8 42.40 171/173 2.79e8 PCB-181 40.53 PCB-177 1.59e8 1.38e8 40.34 39.99 PCB-172 1.44e8 41.88 PCB-191 2.00e8 42.74 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-170 1.39e8 43.51 Abs. Int. 6.46e7 PCB-190 1.98e8 43.96 3.23e7 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.40e4 40.0 PCB-182 1.63e8 39.07 PCB-187 1.58e8 38.89 PCB-183 1.60e8 39.42 41.0 171/173 2.64e8 PCB-181 40.53 PCB-177 1.51e8 1.30e8 40.34 39.99 42.0 43.0 180/193 3.43e8 42.40 PCB-172 1.36e8 41.88 PCB-191 1.88e8 42.73 44.0 PCB-170 1.33e8 43.51 45.0 Abs. Int. 6.16e7 PCB-190 1.88e8 43.96 3.08e7 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.62e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 9.22e6 ES-170 2.97e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 4.39e3 0.00e0 RT 4.61e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.33e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 8.14e6 ES-170 2.73e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 3.64e3 0.00e0 RT 4.07e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3134, 7737 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 16 of 21 462 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-189 2.13e8 46.13 Abs. Int. 5.10e7 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 7.35e3 2.55e7 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 2.02e8 46.12 Abs. Int. 4.99e7 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 5.38e3 2.50e7 0% 46.0 Rel. Int. 100% ES-189 4.82e7 46.11 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 5.63e3 47.0 48.0 49.0 50.0 0.00e0 RT Abs. Int. 1.16e7 (4.82e7 + 4.62e7) * 100 pg/uL RRF(ES-189) = = 1.58 (2.85e7 + 3.14e7) * 100 pg/uL LKB 03-Jan-2014 15:12 5.79e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 4.62e7 46.11 0.00e0 RT Abs. Int. 1.12e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 5.14e3 5.60e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6642, 3679 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 17 of 21 463 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 PCB-202 1.23e8 40.10 PCB-201 1.47e8 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 2.30e3 PCB-197 1.40e8 41.66 PCB-200 PCB-204 1.30e8 1.29e8 41.75 41.47 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 198/199 1.88e8 44.07 Abs. Int. 3.66e7 PCB-196 9.72e7 44.65 PCB-203 1.02e8 44.82 1.83e7 0% 39.0 Rel. Int. 100% 40.0 PCB-202 1.34e8 40.10 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.91e3 41.0 PCB-201 1.61e8 40.89 42.0 43.0 PCB-197 1.53e8 PCB-204 41.66 PCB-200 1.41e8 1.41e8 41.75 41.47 44.0 45.0 198/199 2.07e8 44.07 Abs. Int. 4.04e7 PCB-196 1.06e8 44.65 PCB-203 1.11e8 44.82 2.02e7 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 2.93e7 40.08 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 7.00e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 1.98e3 3.50e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.12e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.46e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 2.00e3 3.73e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.35e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0058, 7129 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:11 Page 18 of 21 464 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 4.72e3 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-205 1.54e8 48.30 PCB-195 1.10e8 45.95 Abs. Int. 3.56e7 PCB-194 1.22e8 47.90 1.78e7 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 6.42e3 47.0 48.0 49.0 50.0 PCB-205 1.68e8 48.30 PCB-195 1.21e8 45.95 0.00e0 RT Abs. Int. 3.85e7 PCB-194 1.32e8 47.89 1.93e7 0% 46.0 47.0 Rel. Int. 100% 48.0 50.0 ES-205 3.55e7 48.28 JS-194 2.85e7 47.88 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 4.99e3 49.0 0.00e0 RT Abs. Int. 8.26e6 4.13e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 3.96e7 48.28 Rel. Int. 100% Abs. Int. 9.37e6 JS-194 3.14e7 47.88 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.69e3 0.00e0 RT 4.68e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0147, 9308 scc: 186-257 Revised: 30-Dec-2013 12:43 (LKB) Printed: 03-Jan-2014 17:12 Page 19 of 21 465 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 3.76e3 PCB-208 1.42e8 45.74 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-207 1.50e8 46.53 Abs. Int. 3.60e7 PCB-206 9.85e7 49.77 1.80e7 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 5.22e3 PCB-208 1.81e8 45.74 47.0 48.0 49.0 50.0 PCB-207 1.90e8 46.53 Abs. Int. 4.58e7 PCB-206 1.25e8 49.77 2.29e7 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 ES-208 3.15e7 45.72 50.0 0.00e0 RT Abs. Int. 7.52e6 ES-206 2.24e7 49.75 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.53e3 3.76e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 3.92e7 45.72 50.0 Abs. Int. 9.31e6 ES-206 2.77e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 2.58e3 0.00e0 RT 4.65e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.31e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.66e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9272, 3360 scc: 186-257 PKD: 30-Dec-2013 12:37 Printed: 03-Jan-2014 17:12 Page 20 of 21 466 of 603 SGS-AP ID: CS4_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-79-2 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 41 Acq: 20-Dec-2013 18:59:38 User: LKB Datafile: 131220X06 PCB-209 1.58e8 51.25 Rel. Int. 100% Abs. Int. 3.32e7 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 7.36e2 1.66e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.34e8 51.25 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.80e7 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 8.28e2 1.40e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.60e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.71e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 1.07e3 3.86e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.05e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.37e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 8.97e2 3.18e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.17e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.58e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS4_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0022, 9026 scc: 186-257 PKD: 30-Dec-2013 12:40 Printed: 03-Jan-2014 17:12 Page 21 of 21 467 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 RT Response RA ICAL RRF Dev'n PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 33.11 32.63 36.10 35.56 35.09 34.82 38.72 41.27 40.29 43.99 46.12 51.24 3.92E+09 3.81E+09 3.11E+09 3.45E+09 3.20E+09 3.32E+09 2.76E+09 5.55E+09 3.01E+09 2.75E+09 2.52E+09 1.71E+09 0.79 Y 0.78 Y 0.62 Y 0.63 Y 0.63 Y 0.62 Y 0.63 Y 1.23 Y 1.22 Y 1.24 Y 1.05 Y 1.18 Y 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 1.22 1.17 1.18 1.29 1.25 1.25 1.21 1.17 1.23 1.17 1.16 1.15 6.1% 4.4% 5.9% 6.9% 4.7% 3.0% 9.8% 6.3% 5.8% 4.3% 7.9% 3.3% ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 12.03 14.35 14.61 20.38 17.73 26.74 20.67 33.09 32.61 25.67 36.08 35.54 35.07 34.79 38.70 36.66 30.64 41.25 40.27 43.97 43.49 42.42 35.53 46.11 40.08 48.27 49.75 45.72 51.22 2.62E+08 2.47E+08 1.23E+08 2.45E+08 1.20E+08 1.94E+08 9.79E+07 1.61E+08 1.63E+08 8.86E+07 1.32E+08 1.34E+08 1.28E+08 1.33E+08 1.14E+08 8.16E+07 1.13E+08 2.38E+08 1.22E+08 1.17E+08 6.70E+07 8.32E+07 6.88E+07 1.09E+08 7.17E+07 8.57E+07 5.62E+07 8.18E+07 7.42E+07 3.21 Y 3.30 Y 1.63 Y 1.53 Y 1.07 Y 1.09 Y 0.83 Y 0.79 Y 0.79 Y 1.66 Y 1.58 Y 1.60 Y 1.60 Y 1.59 Y 1.54 Y 1.32 Y 1.29 Y 1.27 Y 1.26 Y 1.27 Y 1.09 Y 1.09 Y 1.10 Y 1.01 Y 0.94 Y 0.89 Y 0.81 Y 0.80 Y 1.20 Y 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 1.13 1.06 0.53 1.05 0.52 1.69 0.85 1.40 1.42 0.78 1.17 1.19 1.14 1.18 1.01 1.10 1.52 1.61 1.65 1.58 0.97 1.21 0.93 1.58 0.97 1.25 0.82 1.19 1.08 -5.6% -2.3% 0.9% 1.3% 2.2% 1.6% -0.9% 1.2% 4.0% -2.5% -2.9% -2.5% -1.9% -0.8% -2.2% -1.2% -4.1% 0.4% -1.0% 1.8% 2.9% 6.3% -1.1% -0.3% -0.2% 0.1% -1.6% 1.2% -2.8% Page 1 of 6 468 of 603 PCB QC Summary Lab ID: Acquired: Datafile: Name SGS Analytical Perspectives Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT Response RA ICAL RRF Dev'n SS PCB-28 SS PCB-111 SS PCB-178 23.16 33.10 38.10 2.10E+08 1.37E+08 4.42E+07 1.08 Y 1.60 Y 1.12 Y 1.11 1.03 0.62 1.09 1.03 0.64 -2.3% 0.0% 3.8% CS PCB-28 CS PCB-111 CS PCB-178 23.16 33.10 38.10 2.10E+08 1.37E+08 4.42E+07 1.08 Y 1.60 Y 1.12 Y 1.85 1.22 0.58 1.83 1.21 0.60 -0.7% -0.7% 2.7% JS PCB-9 JS PCB-52 JS PCB-101 JS PCB-138 JS PCB-194 16.61 24.79 30.81 37.73 47.87 2.33E+08 1.15E+08 1.13E+08 7.41E+07 6.88E+07 1.55 Y 0.81 Y 1.60 Y 1.32 Y 0.90 Y - - - PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-104 22'466'-PeCB PCB-155 22'44'66'-HxCB PCB-188 22'34'566'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-206 22'33'44'55'6-NoCB 12.05 14.37 14.63 20.39 17.75 26.76 20.69 25.69 30.66 35.55 40.10 48.29 45.74 49.77 4.77E+09 4.95E+09 3.16E+09 5.27E+09 2.86E+09 4.48E+09 2.66E+09 2.58E+09 2.91E+09 1.80E+09 1.58E+09 1.93E+09 1.95E+09 1.32E+09 2.71 Y 2.98 Y 1.59 Y 1.63 Y 1.05 Y 0.99 Y 0.82 Y 0.65 Y 1.29 Y 1.08 Y 0.92 Y 0.93 Y 0.79 Y 0.78 Y 0.95 1.01 1.23 1.02 1.15 1.08 1.35 1.43 1.26 1.27 1.05 1.06 1.12 1.11 0.91 1.00 1.29 1.08 1.19 1.16 1.36 1.46 1.29 1.31 1.10 1.13 1.19 1.18 -4.4% -0.6% 4.4% 5.5% 3.6% 7.4% 0.3% 1.6% 2.3% 3.0% 4.7% 6.3% 6.1% 5.5% Page 2 of 6 469 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 12.05 14.18 14.37 14.63 14.81 16.63 16.80 17.02 17.33 17.45 19.02 19.81 20.10 20.39 17.75 19.52 19.93 20.12 20.26 20.35 20.84 21.99 22.14 22.43 22.63 22.91 23.20 23.38 23.75 25.14 25.46 26.00 26.39 26.76 20.69 22.68 23.28 23.35 23.56 24.82 24.95 25.05 25.24 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 4.77E+09 5.06E+09 4.95E+09 3.16E+09 5.06E+09 4.77E+09 5.47E+09 5.14E+09 5.14E+09 5.25E+09 6.12E+09 5.26E+09 1.05E+10 5.27E+09 2.86E+09 7.69E+09 3.33E+09 4.61E+09 4.39E+09 2.55E+09 4.79E+09 4.49E+09 4.54E+09 9.34E+09 4.59E+09 4.84E+09 9.02E+09 9.35E+09 4.32E+09 4.81E+09 4.93E+09 4.32E+09 4.24E+09 4.48E+09 2.66E+09 5.80E+09 2.69E+09 2.73E+09 2.31E+09 2.76E+09 3.82E+09 2.28E+09 6.91E+09 RA 2.71 Y 2.92 Y 2.98 Y 1.59 Y 1.58 Y 1.62 Y 1.65 Y 1.63 Y 1.64 Y 1.64 Y 1.60 Y 1.63 Y 1.63 Y 1.63 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.04 Y 1.05 Y 1.05 Y 1.00 Y 0.98 Y 0.99 Y 0.99 Y 0.99 Y 0.98 Y 0.97 Y 0.98 Y 0.99 Y 0.98 Y 1.00 Y 0.99 Y 0.99 Y 0.82 Y 0.79 Y 0.79 Y 0.80 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y Page 3 of 6 ICAL 0.95 1.03 1.01 1.23 1.98 0.95 1.05 1.00 1.00 1.03 1.18 1.01 0.99 1.02 1.15 1.54 1.31 1.82 1.72 1.01 1.92 1.14 1.16 1.17 1.16 1.23 1.13 1.17 1.08 1.17 1.21 1.10 1.04 1.08 1.35 0.88 0.77 0.86 0.70 0.84 1.11 0.71 1.02 RRF 0.91 1.02 1.00 1.29 2.06 0.97 1.11 1.05 1.05 1.07 1.25 1.07 1.07 1.08 1.19 1.60 1.38 1.92 1.83 1.06 1.99 1.16 1.17 1.21 1.18 1.25 1.17 1.21 1.12 1.24 1.27 1.11 1.10 1.16 1.36 0.89 0.83 0.84 0.71 0.85 1.17 0.70 1.06 Dev'n -4.4% -0.9% -0.6% 4.4% 4.1% 2.9% 6.5% 5.3% 4.7% 3.7% 5.8% 6.2% 8.0% 5.5% 3.6% 4.0% 6.0% 5.5% 5.9% 5.3% 3.8% 2.3% 1.5% 3.0% 2.4% 2.1% 2.9% 2.9% 3.4% 6.2% 5.1% 0.9% 5.3% 7.4% 0.3% 1.5% 7.6% -2.6% 1.2% 0.5% 5.5% -1.5% 3.6% 470 of 603 PCB QC Summary - Ax2 Detail Lab ID: CS5_131220_PCB_XA Acquired: 20-DEC-2013 20:49 Datafile: 131220X08 Name RT PCB-48 22'45-TeCB 25.52 PCB-44/47/65 ...-TeCB 25.74 PCB-59/62/75 ...-TeCB 26.02 PCB-42 22'34'-TeCB 26.18 PCB-41 22'34-TeCB 26.52 PCB-71/40 23'4'6/22'33'-TeCB 26.61 PCB-64 234'6-TeCB 26.81 PCB-72 23'55'-TeCB 27.53 PCB-68 23'45'-TeCB 27.79 PCB-57 233'5-TeCB 28.16 PCB-58 233'5'-TeCB 28.37 PCB-67 23'45-TeCB 28.53 PCB-63 234'5-TeCB 28.75 PCB-61/70/74/76 ...-TeCB 29.05 PCB-66 23'44'-TeCB 29.33 PCB-55 233'4-TeCB 29.47 PCB-56 233'4'-TeCB 29.91 PCB-60 2344'-TeCB 30.10 PCB-80 33'55'-TeCB 30.43 PCB-79 33'45'-TeCB 31.76 PCB-78 33'45-TeCB 32.25 PCB-104 22'466'-PeCB 25.69 PCB-96 22'366'-PeCB 26.01 PCB-103 22'45'6-PeCB 27.71 PCB-94 22'356'-PeCB 27.90 PCB-95 22'35'6-PeCB 28.28 PCB-100/93 22'44'6/22'356-PeCB 28.50 PCB-102 22'456'-PeCB 28.61 PCB-98 22'34'6'-PeCB 28.68 PCB-88 22'346-PeCB 28.98 PCB-91 22'34'6-PeCB 29.04 PCB-84 22'33'6-PeCB 29.24 PCB-89 22'346'-PeCB 29.65 PCB-121 23'45'6-PeCB 30.00 PCB-92 22'355'-PeCB 30.32 PCB-113/90/101 ...-PeCB 30.80 PCB-83 22'33'5-PeCB 31.24 PCB-99 22'44'5-PeCB 31.34 PCB-112 233'56-PeCB 31.44 PCB-108/119/86/97/125...-PeCB 31.79 PCB-117 234'56-PeCB 32.33 PCB-116/85 23456/22'344'-PeCB 32.42 PCB-110 233'4'6-PeCB 32.53 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 2.83E+09 9.10E+09 1.15E+10 2.53E+09 2.38E+09 5.79E+09 4.17E+09 4.01E+09 4.24E+09 3.81E+09 4.00E+09 4.17E+09 4.37E+09 1.58E+10 3.68E+09 3.76E+09 3.68E+09 3.79E+09 4.36E+09 4.29E+09 3.62E+09 2.58E+09 2.25E+09 2.54E+09 2.18E+09 2.36E+09 4.75E+09 2.73E+09 2.05E+09 2.08E+09 2.73E+09 1.98E+09 2.09E+09 3.31E+09 2.25E+09 8.09E+09 1.82E+09 2.67E+09 3.15E+09 1.55E+10 3.32E+09 5.04E+09 3.01E+09 RA 0.79 Y 0.79 Y 0.81 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.78 Y 0.79 Y 0.79 Y 0.79 Y 0.65 Y 0.65 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.64 Y 0.61 Y 0.63 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.62 Y 0.63 Y 0.68 Y 0.62 Y 0.63 Y 0.62 Y Page 4 of 6 ICAL 0.84 0.90 1.17 0.76 0.69 0.86 1.22 1.21 1.28 1.16 1.18 1.26 1.30 1.20 1.10 1.12 1.11 1.14 1.31 1.31 1.06 1.43 1.23 0.93 0.80 0.87 0.86 0.97 0.76 0.80 0.94 0.72 0.76 1.20 0.82 0.99 0.71 0.92 1.17 0.98 1.14 0.94 1.12 RRF 0.87 0.93 1.18 0.78 0.73 0.89 1.28 1.23 1.30 1.17 1.23 1.28 1.34 1.21 1.13 1.15 1.13 1.16 1.34 1.32 1.11 1.46 1.27 0.95 0.82 0.89 0.89 1.02 0.77 0.78 1.03 0.74 0.79 1.24 0.84 1.01 0.69 1.00 1.18 0.97 1.25 0.95 1.13 Dev'n 3.4% 3.0% 1.4% 1.9% 5.0% 3.5% 4.8% 1.8% 1.9% 0.4% 4.1% 1.6% 3.2% 1.4% 2.4% 3.0% 1.6% 2.6% 1.9% 0.8% 4.6% 1.6% 3.5% 2.6% 2.5% 2.4% 3.4% 5.8% 1.6% -2.2% 8.9% 3.7% 3.0% 3.7% 2.9% 2.8% -4.1% 8.8% 1.3% -0.7% 9.6% 0.6% 1.1% 471 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 32.62 32.81 33.13 33.53 34.50 34.71 34.93 35.39 37.34 30.66 30.82 30.97 31.27 31.54 32.82 33.34 33.55 33.81 34.12 34.29 34.37 34.64 34.81 34.96 35.19 35.60 35.94 36.15 36.27 36.70 36.85 37.19 37.39 37.47 37.77 37.90 38.09 38.82 39.64 39.88 35.55 35.83 36.30 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 3.31E+09 1.94E+09 3.35E+09 3.41E+09 6.21E+09 3.61E+09 3.03E+09 2.83E+09 3.14E+09 2.91E+09 2.78E+09 2.75E+09 2.61E+09 2.61E+09 2.03E+09 3.85E+09 2.26E+09 1.97E+09 4.02E+09 1.54E+09 1.89E+09 4.13E+09 1.73E+09 1.72E+09 1.74E+09 1.91E+09 2.36E+09 2.06E+09 2.61E+09 4.99E+09 1.83E+09 1.63E+09 2.02E+09 2.53E+09 6.19E+09 2.49E+09 2.80E+09 4.79E+09 2.87E+09 2.82E+09 1.80E+09 1.59E+09 1.62E+09 RA 0.63 Y 0.62 Y 0.63 Y 0.62 Y 0.63 Y 0.62 Y 0.62 Y 0.63 Y 0.62 Y 1.29 Y 1.26 Y 1.26 Y 1.27 Y 1.28 Y 1.30 Y 1.28 Y 1.26 Y 1.28 Y 1.26 Y 1.26 Y 1.28 Y 1.28 Y 1.28 Y 1.26 Y 1.27 Y 1.26 Y 1.27 Y 1.27 Y 1.27 Y 1.28 Y 1.27 Y 1.26 Y 1.27 Y 1.29 Y 1.26 Y 1.29 Y 1.28 Y 1.22 Y 1.23 Y 1.22 Y 1.08 Y 1.11 Y 1.09 Y Page 5 of 6 ICAL 1.16 0.70 1.22 1.21 1.10 1.25 1.11 0.99 1.10 1.26 1.17 1.18 1.07 1.11 1.18 1.14 1.34 1.18 1.18 0.92 1.13 1.21 1.03 0.99 1.03 1.13 1.41 1.20 1.52 1.46 1.09 0.97 1.16 1.50 1.19 1.52 1.66 0.90 1.11 1.07 1.27 1.16 1.13 RRF 1.24 0.73 1.26 1.28 1.17 1.36 1.14 1.06 1.19 1.29 1.23 1.22 1.16 1.16 1.25 1.18 1.38 1.20 1.23 0.94 1.16 1.27 1.06 1.06 1.06 1.17 1.44 1.26 1.60 1.53 1.12 1.00 1.24 1.55 1.27 1.52 1.72 0.98 1.17 1.15 1.31 1.15 1.17 Dev'n 7.2% 4.5% 3.1% 5.7% 6.2% 8.2% 3.1% 6.1% 8.8% 2.3% 5.0% 3.6% 8.4% 3.7% 5.4% 3.6% 3.2% 1.8% 4.9% 2.0% 2.7% 5.1% 3.7% 6.7% 3.2% 3.7% 2.5% 5.0% 5.3% 5.0% 2.9% 3.0% 6.3% 3.5% 6.4% 0.6% 3.4% 8.8% 5.3% 7.5% 3.0% -0.7% 4.2% 472 of 603 PCB QC Summary - Ax2 Detail Lab ID: Acquired: Datafile: Name PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB CS5_131220_PCB_XA 20-DEC-2013 20:49 131220X08 RT 36.59 36.99 38.12 38.67 38.90 39.08 39.42 39.51 39.62 39.99 40.34 40.53 41.88 42.13 42.40 42.73 43.51 43.96 40.10 40.89 41.47 41.66 41.75 44.07 44.65 44.82 45.95 47.89 48.29 45.74 46.53 49.77 Printed: 3-Jan-2014 16:56 ICAL: 131220 QC MM7 Response 1.74E+09 1.57E+09 1.21E+09 1.91E+09 2.01E+09 2.05E+09 2.03E+09 2.01E+09 1.71E+09 1.65E+09 1.95E+09 3.42E+09 1.73E+09 2.27E+09 4.38E+09 2.40E+09 1.66E+09 2.44E+09 1.58E+09 1.78E+09 1.66E+09 1.80E+09 1.68E+09 2.46E+09 1.24E+09 1.30E+09 1.40E+09 1.50E+09 1.93E+09 1.95E+09 2.03E+09 1.32E+09 RA 1.08 Y 1.09 Y 1.09 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.06 Y 1.05 Y 1.05 Y 0.92 Y 0.92 Y 0.92 Y 0.92 Y 0.92 Y 0.91 Y 0.91 Y 0.92 Y 0.92 Y 0.93 Y 0.93 Y 0.79 Y 0.79 Y 0.78 Y Page 6 of 6 ICAL 1.23 1.13 0.84 1.07 1.14 1.18 1.20 1.06 0.99 0.95 1.09 0.95 0.99 1.29 1.26 1.40 1.14 1.66 1.05 1.22 1.12 1.19 1.11 0.81 0.83 0.87 0.77 0.84 1.06 1.12 1.19 1.11 RRF 1.26 1.14 0.88 1.15 1.21 1.23 1.22 1.21 1.03 0.99 1.17 1.03 1.04 1.36 1.31 1.44 1.24 1.82 1.10 1.24 1.16 1.26 1.17 0.86 0.87 0.91 0.82 0.88 1.13 1.19 1.24 1.18 Dev'n 2.3% 1.1% 4.2% 7.1% 6.2% 4.6% 1.1% 13.9% 4.0% 4.3% 7.5% 8.3% 5.0% 5.9% 4.3% 3.3% 9.0% 9.7% 4.7% 1.8% 3.8% 5.5% 6.1% 5.9% 3.9% 4.0% 6.5% 4.1% 6.3% 6.1% 4.2% 5.5% 473 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 4.74e7 2.37e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.57e7 1.28e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.87e7 9.33e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.96e7 9.79e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.14e7 5.71e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.71e6 2.86e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.37e6 2.68e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 807-075 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 17:13 Page 1 of 21 474 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-1 3.48e9 12.05 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-2 3.77e9 14.18 Abs. Int. 1.07e9 PCB-3 3.71e9 14.37 MoCB 10.03-16.00 188.0393 Fn1 Flags: OPBM 4σ 4.15e3 5.37e8 0% 11.0 12.0 13.0 PCB-1 1.29e9 12.05 Rel. Int. 100% 14.0 PCB-2 1.29e9 14.18 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.52e3 15.0 0.00e0 16.0 RT Abs. Int. 5.17e8 PCB-3 1.25e9 14.37 2.58e8 0% 11.0 12.0 13.0 14.0 ES-1 2.00e8 12.03 Rel. Int. 100% 15.0 Abs. Int. 7.82e7 ES-3 1.89e8 14.35 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PBM 4σ 7.14e3 0.00e0 16.0 RT 3.91e7 0% 11.0 12.0 13.0 14.0 ES-1 6.21e7 12.03 Rel. Int. 100% 15.0 Abs. Int. 2.45e7 ES-3 5.75e7 14.35 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PBM 4σ 4.09e4 0.00e0 16.0 RT 1.23e7 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.74e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.37e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7909, 8443 scc: 807-075 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 2 of 21 475 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Rel. Int. 100% PCB-4 1.94e9 14.63 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: OPBM 4σ 5.76e3 PCB-10 3.10e9 14.81 5.11e8 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% PCB-10 1.96e9 14.81 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PBM 4σ 2.26e4 PCB-4 1.22e9 14.63 12.0 13.0 14.0 15.0 ES-4 7.59e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 6.47e8 3.23e8 0% 11.0 Abs. Int. 1.02e9 0.00e0 16.0 RT Abs. Int. 2.55e7 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PBM 4σ 8.86e3 1.27e7 0% 11.0 12.0 13.0 14.0 15.0 ES-4 4.67e7 14.61 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.50e7 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PBM 4σ 3.71e3 7.49e6 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.74e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.37e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9558, 1963 scc: 807-075 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 3 of 21 476 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% DiCB-2 16.02-21.51 222.0003 Fn2 Flags: OPBM 4σ 1.34e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-6 3.19e9 17.02 PCB-9 2.95e9 16.63 PCB-14 3.77e9 19.02 PCB-5 3.19e9 17.33 PCB-8 3.26e9 17.45 PCB-11 3.26e9 19.81 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 13/12 6.49e9 20.10 Abs. Int. 1.07e9 PCB-15 3.27e9 20.39 5.36e8 0% 17.0 Rel. Int. 100% DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 3.90e4 PCB-9 1.82e9 16.63 18.0 PCB-14 2.35e9 19.02 PCB-5 1.95e9 PCB-8 17.33 1.99e9 17.45 PCB-7 2.06e9 16.80 19.0 20.0 PCB-11 2.00e9 19.81 13/12 3.99e9 20.10 21.0 Abs. Int. 6.86e8 PCB-15 2.01e9 20.39 3.43e8 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 JS-9 1.42e8 16.61 21.0 ES-15 1.48e8 20.38 0.00e0 RT Abs. Int. 4.57e7 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PBM 4σ 2.73e4 2.28e7 0% 17.0 Rel. Int. 100% 0.00e0 RT 18.0 19.0 20.0 JS-9 9.12e7 16.61 21.0 ES-15 9.71e7 20.38 0.00e0 RT Abs. Int. 2.93e7 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PBM 4σ 6.93e3 1.46e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3253, 5347 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 4 of 21 477 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 30/18 3.92e9 19.52 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: OPBM 4σ 4.61e3 PCB-19 1.46e9 17.75 PCB-17 1.71e9 19.93 PCB-27 2.36e9 20.12 PCB-24 2.24e9 20.26 PCB-16 1.30e9 20.35 Abs. Int. 1.05e9 PCB-32 2.46e9 20.84 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 3.78e9 19.52 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: OPBM 4σ 3.65e3 PCB-19 1.40e9 17.75 PCB-17 1.62e9 19.93 PCB-24 2.15e9 20.26 PCB-27 2.25e9 20.12 PCB-16 1.24e9 20.35 21.0 Rel. Int. 100% 18.0 19.0 20.0 PCB-32 2.34e9 20.83 21.0 5.20e8 0.00e0 RT Abs. Int. 2.64e7 ES-19 6.21e7 17.73 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PBM 4σ 9.95e4 0.00e0 RT Abs. Int. 1.04e9 0% 17.0 5.26e8 1.32e7 0% 17.0 Rel. Int. 100% 18.0 19.0 20.0 21.0 Abs. Int. 2.45e7 ES-19 5.82e7 17.73 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PBM 4σ 3.48e4 0.00e0 RT 1.22e7 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8073, 3622 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 5 of 21 478 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 28/20 4.47e9 23.20 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: OPBM 4σ 4.92e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-23 PCB-34 2.25e9 2.24e9 22.14 21.99 26/29 4.64e9 22.43 PCB-31 2.40e9 22.91 Abs. Int. 1.07e9 PCB-22 2.14e9 23.75 PCB-36 2.39e9 25.14 PCB-39 2.44e9 25.46 PCB-38 2.15e9 26.00 PCB-35 2.11e9 26.39 PCB-37 2.23e9 26.76 0% 22.0 24.0 25.0 26.0 27.0 28/20 4.55e9 23.20 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: OPBM 4σ 5.05e4 23.0 PCB-23 PCB-34 2.29e9 2.25e9 22.14 21.99 26/29 4.70e9 22.43 PCB-31 2.44e9 22.91 23.0 PCB-22 2.18e9 23.75 PCB-36 2.42e9 25.14 PCB-39 2.49e9 25.46 PCB-38 2.16e9 26.00 24.0 25.0 PCB-35 2.13e9 26.39 PCB-37 2.25e9 26.75 26.0 CS/SS-28 1.09e8 23.16 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e9 5.32e8 0% 22.0 5.35e8 27.0 ES-37 1.01e8 26.74 0.00e0 RT Abs. Int. 2.96e7 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PBM 4σ 8.57e4 1.48e7 0% 22.0 23.0 24.0 25.0 26.0 CS/SS-28 1.01e8 23.16 Rel. Int. 100% 27.0 ES-37 9.28e7 26.74 0.00e0 RT Abs. Int. 2.82e7 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PBM 4σ 2.96e4 1.41e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3047, 4081 scc: 807-075 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 6 of 21 479 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-54 1.20e9 20.69 Rel. Int. 100% Abs. Int. 3.45e8 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PBM 4σ 2.02e3 1.72e8 0% 17.0 18.0 19.0 20.0 21.0 PCB-54 1.46e9 20.68 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.14e8 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PBM 4σ 1.44e3 2.07e8 0% 17.0 18.0 19.0 20.0 21.0 ES-54 4.43e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e7 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PBM 4σ 1.72e4 6.37e6 0% 17.0 18.0 19.0 20.0 21.0 ES-54 5.36e7 20.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.53e7 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PBM 4σ 1.34e4 7.63e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.28e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0340, 6239 scc: 807-075 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 7 of 21 480 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 5.68e3 50/53 2.56e9 22.68 PCB-51 1.21e9 23.35 PCB-45 1.19e9 23.28 PCB-73 1.69e9 PCB-52 24.95 1.22e9 24.82 PCB-46 1.02e9 23.56 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 59/62… 44/47… 5.18e9 4.02e9 26.02 25.74 69/49 3.05e9 25.24 PCB-48 1.25e9 25.52 PCB-42 1.12e9 26.18 71/40 2.56e9 26.61 PCB-41 1.04e9 26.52 Abs. Int. 9.33e8 PCB-64 1.85e9 26.81 0% 22.0 23.0 Rel. Int. 100% TeCB-3 21.52-27.30 291.9194 Fn3 Flags: OPBM 4σ 6.24e3 50/53 3.24e9 22.68 24.0 PCB-51 1.52e9 23.35 PCB-45 1.50e9 23.28 25.0 PCB-73 2.13e9 PCB-52 24.95 1.54e9 24.82 PCB-46 1.29e9 23.56 26.0 44/47… 59/62… 5.08e9 6.37e9 26.02 25.74 69/49 3.85e9 25.24 PCB-48 1.58e9 25.52 PCB-42 1.41e9 26.18 27.0 PCB-64 2.32e9 26.81 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 5.11e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e9 71/40 3.23e9 26.61 PCB-41 1.33e9 26.52 4.66e8 5.33e8 0.00e0 RT Abs. Int. 1.44e7 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PBM 4σ 2.50e4 7.22e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 JS-52 6.35e7 24.79 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.80e7 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PBM 4σ 2.42e4 9.02e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7633, 4971 scc: 807-075 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 8 of 21 481 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 3.46e6 PCB-58 1.77e9 PCB-68 28.37 PCB-67 1.86e9 1.83e9 27.79 28.53 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 61/70... 7.00e9 29.05 PCB-55 1.66e9 29.47 PCB-60 PCB-80 1.67e9 1.92e9 30.10 30.43 PCB-79 1.89e9 31.76 PCB-78 1.60e9 32.25PCB-81 1.67e9 32.63 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Abs. Int. 8.48e8 PCB-77 1.73e9 33.11 4.24e8 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: OPBM 4σ 2.54e6 PCB-68 2.38e9 27.79 30.0 61/70... 8.84e9 PCB-60 PCB-67 29.05 2.13e9 2.34e9 30.10 28.53 PCB-63 PCB-80 2.44e9 PCB-66 PCB-56 2.06e9 2.05e9 2.44e9 28.75 29.91 29.33 30.43 32.0 PCB-79 2.40e9 31.76 34.0 PCB-78 2.02e9 32.25PCB-81 2.13e9 32.63 36.0 38.0 Abs. Int. 1.07e9 PCB-77 2.19e9 33.11 5.33e8 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 7.18e7 32.61 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PBM 4σ 3.65e4 0.00e0 RT 36.0 38.0 0.00e0 RT Abs. Int. 2.00e7 ES-77 7.10e7 33.09 9.98e6 0% 28.0 30.0 32.0 Rel. Int. 100% 34.0 ES-81 9.11e7 32.61 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PBM 4σ 1.84e4 36.0 38.0 0.00e0 RT Abs. Int. 2.45e7 ES-77 8.96e7 33.09 1.23e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3954, 5702 scc: 807-075 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 9 of 21 482 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-104 1.01e9 25.69 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.69e3 Abs. Int. 2.66e8 PCB-96 8.84e8 26.01 1.33e8 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 PCB-104 1.57e9 25.69 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.74e3 27.0 0.00e0 RT Abs. Int. 4.07e8 PCB-96 1.37e9 26.01 2.04e8 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 5.53e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.41e7 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PBM 4σ 2.48e3 7.06e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 ES-104 3.33e7 25.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e6 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PBM 4σ 2.34e3 4.24e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.87e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.33e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6832, 9715 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 10 of 21 483 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 108/119... 6.27e9 31.79 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 6.54e6 PCB-103 9.76e8 27.71 100/93 1.82e9 28.50 PCB-88 7.91e8 28.98 PCB-121 1.27e9 30.00 113/90… 3.10e9 30.80 116/85 1.94e9 32.42 PCB-99 1.03e9 31.34 PCB-111 PCB-120 1.29e9 1.30e9 33.13 33.53 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-118 107/124 1.23e9 2.39e9 35.09 34.50 PCB-114 PCB-123 1.33e9 1.27e9 35.56 34.82 Abs. Int. 8.81e8 PCB-105 1.20e9 36.10 PCB-127 1.21e9 37.34 4.40e8 0% 28.0 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: OPBM 4σ 5.33e6 30.0 100/93 2.93e9 28.50 PCB-94 1.34e9 27.90 PCB-91 1.68e9 29.04 PCB-121 2.05e9 30.00 32.0 113/90… 4.99e9 30.80 34.0 108/119... 9.26e9 31.79 PCB-112 1.93e9 31.44 116/85 PCB-115 3.10e9 2.03e9 32.42 32.62 PCB-111 2.06e9 PCB-117 PCB-110 33.13 PCB-120 2.05e9 1.85e9 2.11e9 32.33 PCB-82 32.53 33.53 1.20e9 32.81 36.0 107/124 PCB-118 3.82e9 1.97e9 34.50 35.09 PCB-114 PCB-123 2.12e9 2.05e9 35.56 34.82 38.0 Abs. Int. 1.07e9 PCB-105 1.91e9 36.10 PCB-127 1.94e9 37.34 5.37e8 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 8.44e7 33.10 JS-101 6.96e7 30.81 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PBM 4σ 9.28e3 34.0 36.0 ES-123 8.16e7 34.79 ES-114 8.27e7 35.54 0.00e0 RT 38.0 0.00e0 RT Abs. Int. 2.13e7 ES-105 8.08e7 36.08 1.07e7 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 5.27e7 33.11 JS-101 4.34e7 30.81 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PBM 4σ 6.82e3 34.0 36.0 ES-118 ES-123 4.95e7 5.15e7 35.07 34.79 38.0 0.00e0 RT Abs. Int. 1.32e7 ES-105 5.11e7 36.08 6.61e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0782, 2709 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 11 of 21 484 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 Abs. Int. 2.63e8 PCB-126 1.07e9 38.72 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 1.64e4 1.32e8 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 4.19e8 PCB-126 1.69e9 38.72 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 2.44e4 2.09e8 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.65e7 ES-126 6.89e7 38.70 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PBM 4σ 6.99e3 8.25e6 0% 39.0 Rel. Int. 100% 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.08e7 ES-126 4.48e7 38.70 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PBM 4σ 8.23e3 5.38e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1246, 7147 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 12 of 21 485 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Rel. Int. 100% PCB-150 PCB-155 1.54e9 1.64e9 30.97 30.66 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.19e4 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 147/149 139/140 2.24e9 2.32e9 34.64 34.12 PCB-145 1.46e9 31.54 PCB-148 1.15e9 32.82 153/168 2.80e9 36.70 151/135PCB-144 2.16e9 1.10e9 PCB-143 PCB-142 PCB-133 PCB-146 1.06e9 9.62e8 1.07e9 1.15e9 33.34 33.81 36.15 34.37 35.60 34.96 PCB-141 1.02e9 36.85 163/138… 3.46e9 37.77 PCB-164 PCB-160 1.42e9 1.40e9 37.47 37.90 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PCB-150 PCB-155 1.22e9 1.27e9 30.97 30.66 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.03e4 PCB-145 1.15e9 31.54 PCB-148 8.85e8 32.82 147/149 139/140 151/135 1.78e9 1.81e9 1.69e9 34.12 34.64 33.34 PCB-154 9.99e8 PCB-143 PCB-131 33.55 8.28e8 7.60e8 34.37 34.81 36.0 38.0 153/168 2.19e9 36.70 PCB-165 1.04e9 35.94 163/138… 2.74e9 37.77 PCB-137 PCB-141 8.87e8 8.04e8 37.39 36.85 30.0 32.0 34.0 36.0 38.0 ES-153 4.65e7 36.66 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PBM 4σ 1.02e4 0.00e0 RT Abs. Int. 5.14e8 2.57e8 ES-155 6.35e7 30.64 Rel. Int. 100% 3.23e8 PCB-158 1.23e9 38.09 0% 28.0 Abs. Int. 6.47e8 0.00e0 RT Abs. Int. 1.67e7 JS-138 4.21e7 37.73 8.33e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 ES-155 4.94e7 30.64 Rel. Int. 100% ES-153 3.51e7 36.66 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PBM 4σ 9.67e3 0.00e0 RT Abs. Int. 1.26e7 JS-138 3.19e7 37.73 6.31e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.96e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2850, 7769 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 13 of 21 486 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% 128/166 2.63e9 38.82 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.24e4 PCB-159 1.58e9 39.64 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-162 1.55e9 39.88 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 156/157 3.06e9 41.27 Abs. Int. 6.29e8 PCB-169 1.52e9 43.99 PCB-167 1.65e9 40.29 3.15e8 0% 39.0 Rel. Int. 100% 40.0 128/166 2.16e9 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 3.49e4 PCB-159 1.29e9 39.64 PCB-162 1.27e9 39.88 41.0 42.0 43.0 44.0 45.0 156/157 2.49e9 41.27 Abs. Int. 5.14e8 PCB-169 1.23e9 43.99 PCB-167 1.35e9 40.29 2.57e8 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 6.83e7 40.27 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PBM 4σ 9.18e3 0.00e0 RT 42.0 43.0 44.0 45.0 ES-156/157 1.33e8 41.25 0.00e0 RT Abs. Int. 2.38e7 ES-169 6.57e7 43.97 1.19e7 0% 39.0 40.0 Rel. Int. 100% 41.0 ES-167 5.40e7 40.27 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PBM 4σ 1.04e4 42.0 43.0 44.0 45.0 ES-156/157 1.05e8 41.25 0.00e0 RT Abs. Int. 1.92e7 ES-169 5.16e7 43.97 9.61e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1763, 4652 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 14 of 21 487 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-184 PCB-188 PCB-179 8.43e8 8.35e8 9.36e8 36.30 35.83 35.55 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.64e3 PCB-186 8.18e8 36.99 Abs. Int. 2.32e8 PCB-178 6.30e8 38.12 0% 31.0 32.0 33.0 34.0 35.0 Rel. Int. 100% 36.0 PCB-188 PCB-179 7.54e8 8.64e8 35.83 35.55 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.12e3 37.0 PCB-176 8.33e8 36.59 PCB-186 7.49e8 36.99 38.0 1.16e8 0.00e0 RT Abs. Int. 2.17e8 PCB-178 5.80e8 38.12 1.09e8 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.60e7 35.53 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.14e6 CS/SS-178 2.33e7 38.10 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PBM 4σ 7.77e3 4.57e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 ES-188 3.28e7 35.53 Rel. Int. 100% Abs. Int. 8.50e6 CS/SS-178 2.09e7 38.10 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PBM 4σ 8.62e3 0% 31.0 32.0 33.0 34.0 35.0 0.00e0 RT 36.0 37.0 38.0 Rel. Int. 100% 4.25e6 0.00e0 RT Abs. Int. 1.96e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.79e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2899, 3493 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 15 of 21 488 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 3.40e4 PCB-183 1.04e9 39.42 PCB-182 PCB-185 1.05e9 1.03e9 39.08 39.51 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 171/173 1.76e9 PCB-181 40.53 PCB-177 1.00e9 8.47e8 40.34 39.99 180/193 2.25e9 42.40 PCB-172 8.89e8 41.88 PCB-191 1.23e9 42.73 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-170 8.50e8 43.51 Abs. Int. 4.06e8 PCB-190 1.25e9 43.96 2.03e8 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 3.24e4 PCB-182 9.93e8 39.08 PCB-187 9.76e8 38.90 40.0 41.0 PCB-185 9.75e8 171/173 39.51 1.66e9 PCB-183 PCB-181 40.53 9.87e8 PCB-174 PCB-177 9.47e8 39.428.30e8 40.34 8.03e8 39.62 39.99 42.0 43.0 180/193 2.13e9 42.40 PCB-172 8.40e8 41.88 PCB-191 1.16e9 42.73 44.0 PCB-170 8.08e8 43.51 45.0 Abs. Int. 3.84e8 PCB-190 1.19e9 43.96 1.92e8 0% 39.0 40.0 41.0 42.0 43.0 ES-180 4.34e7 42.42 Rel. Int. 100% 44.0 45.0 0.00e0 RT Abs. Int. 1.07e7 ES-170 3.49e7 43.49 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PBM 4σ 4.84e3 0.00e0 RT 5.36e6 0% 39.0 40.0 41.0 42.0 43.0 ES-180 3.98e7 42.42 Rel. Int. 100% 44.0 45.0 Abs. Int. 9.63e6 ES-170 3.21e7 43.49 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PBM 4σ 5.08e3 0.00e0 RT 4.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2041, 8697 scc: 807-075 PKD: 30-Dec-2013 12:53 Printed: 03-Jan-2014 17:13 Page 16 of 21 489 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-189 1.29e9 46.12 Abs. Int. 3.12e8 (1.29e9 + 1.23e9) * 100 pg/uL RRF(PCB-189) = = 1.16 (5.47e7 + 5.39e7) * 2000 pg/uL LKB 03-Jan-2014 15:14 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 1.63e4 1.56e8 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.23e9 46.12 Abs. Int. 3.06e8 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 1.40e4 1.53e8 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 ES-189 5.47e7 46.11 0.00e0 RT Abs. Int. 1.27e7 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PBM 4σ 4.44e3 6.36e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 50.0 ES-189 5.39e7 46.11 0.00e0 RT Abs. Int. 1.27e7 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PBM 4σ 3.76e3 6.37e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2216, 7571 scc: 807-075 PKD: 30-Dec-2013 12:54 Printed: 03-Jan-2014 17:13 Page 17 of 21 490 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 PCB-202 7.56e8 40.10 Rel. Int. 100% PCB-201 8.55e8 40.89 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.48e4 PCB-197 8.62e8 PCB-204 41.66 PCB-200 8.05e8 7.97e8 41.75 41.47 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 198/199 1.17e9 44.07 Abs. Int. 2.15e8 PCB-196 5.92e8 44.65 PCB-203 6.25e8 44.82 1.08e8 0% 39.0 Rel. Int. 100% 40.0 PCB-202 8.24e8 40.10 41.0 PCB-201 9.27e8 40.89 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.08e4 42.0 43.0 44.0 45.0 198/199 1.28e9 44.07 PCB-197 9.38e8 PCB-204 41.66 PCB-200 8.78e8 8.63e8 41.75 41.47 0.00e0 RT Abs. Int. 2.36e8 PCB-196 6.50e8 44.65 PCB-203 6.78e8 44.82 1.18e8 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.48e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.29e6 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PBM 4σ 3.12e3 4.15e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 ES-202 3.68e7 40.08 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.97e6 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PBM 4σ 3.99e3 4.48e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.14e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.71e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0215, 8218 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 18 of 21 491 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.20e4 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-205 9.28e8 48.29 PCB-195 6.71e8 45.95 Abs. Int. 2.26e8 PCB-194 7.24e8 47.89 1.13e8 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.62e4 47.0 48.0 49.0 50.0 PCB-205 1.00e9 48.29 PCB-195 7.29e8 45.94 0.00e0 RT Abs. Int. 2.44e8 PCB-194 7.81e8 47.89 1.22e8 0% 46.0 47.0 48.0 49.0 50.0 ES-205 4.04e7 48.27 Rel. Int. 100% Abs. Int. 9.47e6 JS-194 3.26e7 47.87 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PBM 4σ 3.58e3 0.00e0 RT 4.73e6 0% 46.0 47.0 48.0 49.0 50.0 ES-205 4.53e7 48.27 Rel. Int. 100% Abs. Int. 1.07e7 JS-194 3.62e7 47.87 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PBM 4σ 3.24e3 0.00e0 RT 5.36e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5003, 9428 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 19 of 21 492 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.01e4 PCB-208 8.58e8 45.74 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-207 8.96e8 46.53 Abs. Int. 2.14e8 PCB-206 5.80e8 49.77 1.07e8 0% 46.0 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 9.96e3 PCB-208 1.09e9 45.74 47.0 48.0 49.0 50.0 PCB-207 1.14e9 46.53 Abs. Int. 2.72e8 PCB-206 7.39e8 49.77 1.36e8 0% 46.0 Rel. Int. 100% ES-208 3.65e7 45.72 47.0 48.0 49.0 (2.51e7 + 3.11e7) * 100 pg/uL RRF(ES-206) = = 0.817 (3.26e7 + 3.62e7) * 100 pg/uL LKB 03-Jan-2014 15:15 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PBM 4σ 2.91e3 50.0 0.00e0 RT Abs. Int. 8.88e6 ES-206 2.51e7 49.75 4.44e6 0% 46.0 Rel. Int. 100% 0.00e0 RT 47.0 48.0 49.0 ES-208 4.54e7 45.72 50.0 Abs. Int. 1.10e7 ES-206 3.11e7 49.75 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PBM 4σ 3.68e3 0.00e0 RT 5.50e6 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.86e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9164, 3773 scc: 807-075 Revised: 30-Dec-2013 12:54 (LKB) Printed: 03-Jan-2014 17:13 Page 20 of 21 493 of 603 SGS-AP ID: CS5_131220_PCB_XA Instr: AutoSpec-Premier MM7 Sample ID: SIL 13-84-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 42 Acq: 20-Dec-2013 20:49:35 User: LKB Datafile: 131220X08 PCB-209 9.25e8 51.24 Rel. Int. 100% Abs. Int. 1.91e8 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 5.67e2 9.53e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 7.84e8 51.24 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 1.62e8 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 7.64e2 8.12e7 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 4.05e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 8.58e6 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PBM 4σ 9.63e2 4.29e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 3.38e7 51.22 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 6.95e6 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PBM 4σ 9.42e2 3.48e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.37e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.68e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\CS5_131220_PCB_XA.utp_res, saved 03-Jan-2014 16:52 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2549, 9998 scc: 807-075 PKD: 30-Dec-2013 12:54 Printed: 03-Jan-2014 17:13 Page 21 of 21 494 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.22e7 2.61e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.72e7 1.36e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 2.01e7 1.00e7 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.04e7 1.02e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.13e7 5.65e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.41e6 2.71e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.01e6 2.51e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 307-094 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:20 Page 1 of 21 495 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.16e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: PB 4σ 3.94e3 1.58e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.54e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: PB 4σ 4.69e3 7.70e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.27e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.36e3 6.37e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.24e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.44e4 1.62e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7343, 4554 scc: 307-094 15.0 0.00e0 16.0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 2 of 21 496 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.28e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 5.78e3 6.40e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.33e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.40e4 2.67e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.06e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 1.15e4 1.53e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.13e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.54e3 4.07e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5268, 6714 scc: 307-094 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:20 Page 3 of 21 497 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 4.54e4 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PB 4σ 1.00e4 2.27e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.06e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PB 4σ 3.46e4 5.29e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.33e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PB 4σ 2.39e4 6.65e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.80e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 5.74e3 8.99e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7794, 8414 scc: 307-094 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 4 of 21 498 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.24e4 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PB 4σ 3.92e3 1.62e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.45e4 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PB 4σ 3.55e3 7.26e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.65e7 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PB 4σ 8.60e4 8.24e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.88e6 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 3.76e4 9.38e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9784, 2296 scc: 307-094 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 5 of 21 499 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-36 2.93e5 25.14 Abs. Int. 7.96e4 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.38e3 3.98e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-36 2.95e5 25.14 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.83e4 TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.71e3 4.42e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.09e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PB 4σ 1.03e5 3.54e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.88e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PB 4σ 2.46e4 4.44e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3148, 7222 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 6 of 21 500 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 3.93e3 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.09e3 1.96e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.96e3 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 2.52e3 2.48e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.40e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.94e4 1.70e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.28e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 1.07e4 1.14e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.72e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.36e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0991, 8988 scc: 307-094 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:20 Page 7 of 21 501 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.17e4 TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PB 4σ 2.25e3 5.84e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.15e4 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PB 4σ 2.67e3 5.76e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.91e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 2.82e4 2.96e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.07e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.92e4 1.53e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7948, 8617 scc: 307-094 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 8 of 21 502 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-79 2.26e5 31.75 PCB-72 2.07e5 27.52 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 6.17e4 PCB-78 1.97e5 32.24 TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.66e3 3.08e4 0% 28.0 Rel. Int. 100% 30.0 PCB-72 2.56e5 27.52 32.0 PCB-79 2.68e5 31.75 TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 3.32e3 34.0 36.0 38.0 0.00e0 RT Abs. Int. 7.90e4 PCB-78 2.72e5 32.24 3.95e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e5 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.37e4 5.49e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.25e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 2.33e4 2.12e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7736, 9764 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 9 of 21 503 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-96 1.05e5 26.00 Rel. Int. 100% Abs. Int. 3.40e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 1.14e3 1.70e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 1.64e5 26.00 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e4 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.87e3 2.36e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.13e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 1.83e3 4.07e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.21e4 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 3.05e3 6.03e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 1.00e7 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0353, 9971 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 10 of 21 504 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 1.10e5 28.67 PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 1.82e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 1.77e5 34.49 PCB-89 1.08e5 29.65 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 4.57e4 PCB-106 1.42e5 34.92 2.29e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 1.77e5 28.66 PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 2.25e3 32.0 34.0 107/124 2.62e5 34.49 PCB-89 1.65e5 29.65 36.0 38.0 0.00e0 RT Abs. Int. 6.64e4 PCB-106 2.46e5 34.92 3.32e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.39e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PB 4σ 2.97e3 4.19e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.10e4 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 3.35e3 1.05e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0422, 7587 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 11 of 21 505 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.14e4 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PB 4σ 1.38e3 5.68e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e4 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PB 4σ 2.07e3 5.82e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.07e4 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PB 4σ 3.86e3 5.35e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.79e3 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 3.22e3 4.40e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8143, 7330 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 12 of 21 506 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-152 1.98e5 30.81 Rel. Int. 100% Abs. Int. 5.01e4 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.45e3 2.51e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 1.63e5 30.82 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.90e4 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.20e3 2.45e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.02e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.13e3 3.51e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.52e3 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 1.46e3 4.26e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.04e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9006, 0485 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 13 of 21 507 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Abs. Int. 4.57e4 128/166 1.94e5 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 1.70e3 2.29e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 3.57e4 128/166 1.54e5 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 1.45e3 1.78e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e4 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.35e3 5.83e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e4 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 2.67e3 6.86e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3751, 1283 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 14 of 21 508 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-184 1.12e5 36.29 Rel. Int. 100% Abs. Int. 2.62e4 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 8.47e2 1.31e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 9.31e4 36.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e4 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.58e2 1.29e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.56e3 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.34e3 3.28e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.66e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.42e3 2.83e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.03e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.02e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2030, 9921 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 15 of 21 509 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-182 1.14e5 39.07 Abs. Int. 3.24e4 HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.43e3 1.62e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 1.15e5 39.07 0.00e0 RT Abs. Int. 3.09e4 HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.38e3 1.55e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.25e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 2.06e3 3.63e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.88e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.65e3 4.44e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9648, 6911 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 16 of 21 510 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 1.01e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PB 4σ 1.19e3 5.03e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.51e3 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PB 4σ 1.11e3 4.26e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.79e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.59e3 3.90e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.31e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.83e3 3.16e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7686, 7875 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 17 of 21 511 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 PCB-204 9.83e4 41.46 Rel. Int. 100% Abs. Int. 2.26e4 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 6.80e2 1.13e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 1.07e5 41.46 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.65e4 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 9.64e2 1.33e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.22e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.43e3 2.61e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.84e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.17e3 2.42e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.13e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.65e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7434, 5203 scc: 307-094 Revised: 03-Jan-2014 11:25 (LKB) Printed: 03-Jan-2014 15:20 Page 18 of 21 512 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 5.92e3 OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PB 4σ 9.45e2 2.96e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.14e3 OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PB 4σ 1.03e3 3.57e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.89e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 9.26e2 1.95e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.29e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 1.20e3 2.14e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3968, 5793 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 19 of 21 513 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 6.43e3 NoCB 45.52-50.76 461.7245 Fn6 Flags: PB 4σ 8.92e2 3.21e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.70e3 NoCB 45.52-50.76 463.7216 Fn6 Flags: PB 4σ 1.80e3 4.35e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.41e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 7.83e2 1.70e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.03e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 9.21e2 1.52e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.41e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.71e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1314, 4053 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 20 of 21 514 of 603 SGS-AP ID: SBS_131220_PCB_XB Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 19:54:39 User: LKB Datafile: 131220X07 Rel. Int. 100% Abs. Int. 9.53e3 DeCB 50.77-52.00 497.6826 Fn7 Flags: PB 4σ 6.42e2 4.77e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 8.19e3 DeCB 50.77-52.00 499.6797 Fn7 Flags: PB 4σ 5.71e2 4.09e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 7.38e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 8.45e2 3.69e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.06e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 9.91e2 2.03e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.01e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.51e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XB.utp_res, saved 03-Jan-2014 11:26 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2056, 2173 scc: 307-094 PKD: 03-Jan-2014 11:23 Printed: 03-Jan-2014 15:20 Page 21 of 21 515 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.22e7 2.61e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.70e7 1.35e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.95e7 9.77e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 2.02e7 1.01e7 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.16e7 5.82e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.65e6 2.82e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.37e6 2.69e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 023-880 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:21 Page 1 of 21 516 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% PCB-2 2.54e5 14.19 PCB-1 9.53e4 12.05 MoCB 10.03-16.00 188.0393 Fn1 Flags: PBM 4σ 5.93e3 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 8.74e4 PCB-3 2.45e5 14.37 4.37e4 0% 11.0 12.0 13.0 Rel. Int. 100% PCB-2 7.20e4 14.19 PCB-1 3.41e4 12.05 MoCB 10.03-16.00 190.0363 Fn1 Flags: PBM 4σ 3.60e3 14.0 15.0 0.00e0 16.0 RT Abs. Int. 3.18e4 PCB-3 8.20e4 14.37 1.59e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.47e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.84e3 7.33e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.77e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 3.83e4 1.39e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0471, 6660 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:21 Page 2 of 21 517 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. 100% Abs. Int. 2.84e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: B 4σ 9.07e3 1.42e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.71e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.21e4 2.35e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.27e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 9.85e3 1.63e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 8.15e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 3.73e3 4.07e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.22e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.61e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6955, 1198 scc: 023-880 Revised: 03-Jan-2014 10:42 (LKB) Printed: 03-Jan-2014 15:21 Page 3 of 21 518 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 13/12 7.84e5 20.10 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: PBM 4σ 7.95e3 Abs. Int. 1.62e5 PCB-15 5.54e5 20.40 8.10e4 0% 17.0 18.0 19.0 Rel. Int. 100% 20.0 13/12 4.79e5 20.11 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PBM 4σ 3.56e4 21.0 0.00e0 RT Abs. Int. 1.68e5 PCB-15 2.92e5 20.40 8.40e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.47e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: PB 4σ 2.95e4 7.34e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.78e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 8.05e3 8.91e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1004, 1945 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:21 Page 4 of 21 519 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 30/18 1.02e5 19.51 Rel. Int. 100% PCB-32 9.86e4 20.83 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PBM 4σ 5.05e3 Abs. Int. 3.37e4 1.69e4 0% 17.0 18.0 19.0 20.0 30/18 8.90e4 19.51 Rel. Int. 100% 21.0 PCB-32 9.05e4 20.83 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PBM 4σ 5.21e3 0.00e0 RT Abs. Int. 2.80e4 1.40e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.62e6 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: PB 4σ 7.41e4 1.81e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e5 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 4.02e4 2.37e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7330, 0490 scc: 023-880 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 5 of 21 520 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 6.17e3 PCB-25 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 28/20 1.95e5 4.56e5 22.62 23.19 21/33 PCB-31 26/29 PCB-22 3.54e5 PCB-34 PCB-23 2.70e5 2.18e5 2.16e5 23.37 1.14e5 1.01e5 22.90 22.42 23.75 21.99 22.13 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 2.29e5 PCB-36 8.79e5 25.14 PCB-39 2.73e5 25.46 PCB-38 2.32e5 26.00 PCB-35 3.72e5 26.39 PCB-37 4.64e5 26.75 0% 22.0 23.0 24.0 Rel. Int. 100% TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 5.69e3 25.0 26.0 27.0 PCB-34 PCB-23 1.21e5 8.99e4 21.99 22.14 PCB-31 2.22e5 22.90 28/20 4.74e5 23.19 PCB-39 2.84e5 25.46 PCB-22 2.14e5 23.75 PCB-38 2.31e5 25.99 PCB-35 3.67e5 26.39 PCB-37 4.75e5 26.75 0% 22.0 23.0 24.0 25.0 0.00e0 RT Abs. Int. 2.33e5 PCB-36 8.72e5 25.14 26/29 3.42e5 22.42 1.14e5 26.0 27.0 Rel. Int. 100% 1.16e5 0.00e0 RT Abs. Int. 1.82e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: B 4σ 1.01e5 9.12e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.65e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: B 4σ 2.14e4 2.33e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0081, 4527 scc: 023-880 Revised: 03-Jan-2014 10:43 (LKB) Printed: 03-Jan-2014 15:21 Page 6 of 21 521 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Rel. Int. 100% Abs. Int. 1.05e4 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.87e3 5.23e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.37e4 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 3.46e3 6.85e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.13e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.79e4 2.07e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 1.31e4 1.01e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.70e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.35e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1788, 2188 scc: 023-880 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 7 of 21 522 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TeCB-3 21.52-27.30 289.9224 Fn3 Flags: PBM 4σ 4.08e3 50/53 8.82e4 22.66 PCB-51 3.01e4 23.35 PCB-45 6.53e4 23.26 PCB-52 5.23e4 24.80 PCB-46 5.27e4 23.53 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 59/62… 2.93e5 44/47… 26.01 69/49 2.20e5 1.62e5 25.73 25.22 PCB-48 PCB-42 7.08e4 PCB-43 6.47e4 25.51 3.75e4 26.16 25.02 71/40 1.63e5 26.60 PCB-41 5.55e4 26.50 Abs. Int. 5.11e4 PCB-64 1.31e5 26.81 2.55e4 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% 26.0 44/47… 2.62e5 25.73 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PBM 4σ 3.91e3 50/53 1.15e5 22.66 PCB-45 9.74e4 PCB-51 23.26 3.49e4 23.34 PCB-73 PCB-52 8.10e4 8.34e4 24.93 24.81 PCB-46 5.48e4 23.53 69/49 1.69e5 25.23 PCB-48 8.01e4 25.51 59/62… 3.86e5 26.01 PCB-42 9.68e4 26.17 27.0 Abs. Int. 6.43e4 71/40 2.00e5 26.60 PCB-41 8.18e4 26.50 PCB-64 1.45e5 26.81 0% 22.0 23.0 24.0 25.0 26.0 0.00e0 RT 27.0 Rel. Int. 100% 3.22e4 0.00e0 RT Abs. Int. 5.61e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 3.21e4 2.80e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.20e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.50e4 2.10e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9260, 1022 scc: 023-880 Revised: 03-Jan-2014 10:45 (LKB) Printed: 03-Jan-2014 15:21 Page 8 of 21 523 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 4.14e3 PCB-79 6.64e5 31.75 PCB-68 1.40e5 27.78 61/70... 6.48e5 PCB-67 29.04 1.47e5 28.51 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-78 6.28e5 32.25 PCB-81 2.16e5 32.63 PCB-60 2.09e5 PCB-80 30.10 1.57e5 30.42 Abs. Int. 1.64e5 PCB-77 3.03e5 33.11 8.19e4 0% 28.0 30.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 5.02e3 PCB-68 1.72e5 27.78 61/70... 8.54e5 29.04 PCB-58 1.60e5 28.36 32.0 PCB-79 8.37e5 31.75 PCB-60 2.92e5 30.10 PCB-56 2.45e5 29.91 34.0 36.0 38.0 PCB-78 7.88e5 32.25 PCB-81 2.81e5 32.62 PCB-80 2.05e5 30.42 Abs. Int. 2.07e5 PCB-77 3.76e5 33.10 1.03e5 0% 28.0 30.0 32.0 0.00e0 RT 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.26e5 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.26e4 6.29e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.36e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 2.39e4 2.68e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9272, 0996 scc: 023-880 Revised: 03-Jan-2014 10:45 (LKB) Printed: 03-Jan-2014 15:21 Page 9 of 21 524 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-96 2.95e5 26.00 Rel. Int. 100% Abs. Int. 7.59e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 2.73e3 3.80e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 4.53e5 26.00 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.17e5 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 2.97e3 5.85e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.19e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 2.88e3 3.10e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e4 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 2.00e3 5.50e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.95e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.77e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9067, 8571 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 10 of 21 525 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 3.58e3 PCB-94 2.95e4 27.88 PCB-103 3.75e4 27.70 PCB-98 3.00e5 28.67 PCB-89 2.73e5 29.65 PCB-88 PCB-102 2.92e43.71e4 28.58 28.96 PCB-115PCB-111 116/85 108/119... 1.26e5 8.89e4 7.52e4 3.82e5 32.61 33.12 32.40 31.78 113/90… PCB-110 PCB-117 PCB-120 PCB-112 1.59e5 PCB-82 PCB-92 9.55e4 8.60e4 1.01e5 6.31e4 6.21e4 4.31e4 30.80 32.52 32.31 33.52 31.44 32.80 30.31 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 107/124 5.07e5 34.49 PCB-106 4.17e5 34.92 PCB-123 1.05e5 34.81 Abs. Int. 1.18e5 PCB-114 1.30e5 35.56 PCB-105 1.53e5 36.10 5.89e4 PCB-127 1.03e5 37.33 0% 28.0 30.0 32.0 34.0 Rel. Int. 100% PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 4.75e3 PCB-98 4.78e5 28.67 PCB-94 4.70e4 27.88 100/93 PCB-91 1.17e5 7.93e4 28.48 29.03 PCB-89 4.33e5 29.65 PCB-121 8.53e4 29.99 113/90… 2.82e5 30.80 108/119... 5.90e5 31.78 116/85 2.08e5 32.41 PCB-111 PCB-120 1.40e5 1.62e5 33.12 33.52 36.0 107/124 8.47e5PCB-106 34.49 6.54e5 34.92 PCB-118 2.21e5 35.09 PCB-114 PCB-123 2.15e5 1.84e5 35.56 34.80 38.0 Abs. Int. 2.03e5 PCB-105 2.46e5 36.10 1.01e5 PCB-127 1.72e5 37.33 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.74e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: B 4σ 3.01e3 4.87e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.22e3 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 2.81e3 4.11e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8550, 9289 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 11 of 21 526 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 3.44e4 PCB-126 1.41e5 38.71 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PBM 4σ 3.09e3 1.72e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 5.47e4 PCB-126 2.22e5 38.71 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PBM 4σ 3.11e3 2.73e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.39e4 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: B 4σ 2.86e3 6.96e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.66e4 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 4.68e3 8.28e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7286, 3128 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 12 of 21 527 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-152 5.29e5 30.82 Rel. Int. 100% HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 2.53e3 Abs. Int. 1.36e5 PCB-136 7.72e4 31.26 PCB-155 PCB-150 5.62e4 6.03e4 30.95 30.65 147/149 1.25e5 34.10 PCB-145 7.39e4 31.54 PCB-148 4.67e4 32.81 151/135PCB-144 1.23e5 6.19e4 33.33 33.81 139/140 1.26e5 34.63 163/138… 153/168 2.49e5 1.85e5 PCB-130 37.76 36.69 7.31e4 37.18 PCB-133 6.22e4 35.59 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 4.18e5 30.82 Rel. Int. 100% HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 2.89e3 PCB-155 5.10e4 30.65 30.0 0.00e0 RT Abs. Int. 9.83e4 PCB-136PCB-145 6.77e4 5.42e4 31.26 31.53 PCB-148 3.62e4 32.80 151/135 9.81e4 33.33 147/149 139/140 PCB-154 8.16e4 1.08e5 PCB-132 34.11 34.63 7.32e4 4.19e4 35.18 33.54 PCB-165 6.42e4 35.92 153/168 1.45e5 PCB-130 36.69 5.76e4 37.18 163/138… 2.19e5 37.76 0% 28.0 6.78e4 32.0 34.0 36.0 38.0 Rel. Int. 100% 4.91e4 0.00e0 RT Abs. Int. 7.03e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.12e3 3.52e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e4 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 2.03e3 5.60e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9259, 3315 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 13 of 21 528 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 1.39e5 128/166 6.14e5 38.82 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 3.34e3 PCB-159 PCB-162 1.16e5 1.26e5 39.87 39.63 156/157 3.32e5 41.27 PCB-167 1.57e5 40.28 PCB-169 2.14e5 43.99 6.96e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 1.22e5 128/166 4.95e5 38.82 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 2.96e3 PCB-159 PCB-162 8.70e4 9.27e4 39.87 39.64 156/157 2.77e5 41.26 PCB-167 1.32e5 40.28 PCB-169 1.69e5 43.99 6.08e4 0% 39.0 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.95e3 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.33e3 4.97e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.04e3 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 3.23e3 4.52e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8276, 7547 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 14 of 21 529 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-184 2.68e5 36.29 Rel. Int. 100% HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.58e3 PCB-176 4.45e4 36.58 PCB-188 PCB-179 4.57e4 4.46e4 35.54 35.82 Abs. Int. 6.82e4 3.41e4 PCB-186 4.22e4 36.98 PCB-178 2.67e4 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.47e5 36.29 Rel. Int. 100% HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 1.40e3 PCB-188 3.07e4 35.54 PCB-179 4.09e4 35.82 PCB-176 3.65e4 36.58 Abs. Int. 6.26e4 3.13e4 PCB-186 3.84e4 36.98 PCB-178 3.29e4 38.11 0% 31.0 32.0 33.0 34.0 35.0 36.0 0.00e0 RT 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.97e3 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.36e3 4.99e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.60e3 2.36e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.02e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 1.01e7 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4826, 4197 scc: 023-880 Revised: 03-Jan-2014 10:41 (LKB) Printed: 03-Jan-2014 15:21 Page 15 of 21 530 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 2.77e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Abs. Int. 8.38e4 PCB-182 3.66e5 39.07 PCB-187 6.01e4 38.89 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 180/193 1.45e5 42.40 PCB-181 6.17e4 40.33 PCB-172 PCB-192 7.81e4 6.05e4 42.12 41.88 171/173 9.70e4 40.52 PCB-191 1.03e5 42.73 PCB-170 7.09e4 43.50 PCB-190 1.20e5 43.96 4.19e4 0% 39.0 Rel. Int. 100% HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 2.37e3 40.0 41.0 42.0 43.0 44.0 45.0 Abs. Int. 9.23e4 PCB-182 3.30e5 39.07 PCB-187 4.62e4 38.89 PCB-181 5.19e4 40.34 171/173 1.09e5 40.52 180/193 1.66e5 42.40 PCB-172 6.22e4 41.87 PCB-191 8.30e4 42.74 PCB-170 7.42e4 43.50 PCB-190 1.10e5 43.96 4.62e4 0% 39.0 0.00e0 RT 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.33e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 2.04e3 3.17e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.17e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.47e3 2.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4824, 0790 scc: 023-880 PKD: 03-Jan-2014 11:05 Printed: 03-Jan-2014 15:21 Page 16 of 21 531 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-189 1.86e5 46.12 Abs. Int. 4.41e4 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PBM 4σ 2.14e3 2.20e4 0% 46.0 Rel. Int. 100% 47.0 48.0 49.0 50.0 PCB-189 1.80e5 46.12 0.00e0 RT Abs. Int. 3.90e4 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PBM 4σ 1.55e3 1.95e4 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.95e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.80e3 3.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.98e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.26e3 2.99e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9412, 0969 scc: 023-880 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:21 Page 17 of 21 532 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 7.23e4 PCB-204 2.75e5 41.47 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.73e3 PCB-202 3.27e4 40.09 198/199 8.41e4 44.07 PCB-197PCB-200 5.44e4 4.31e4 41.65 41.74 PCB-201 4.24e4 40.88 PCB-196 3.54e4 44.64 PCB-203 5.07e4 44.81 0% 39.0 40.0 41.0 Rel. Int. 100% 42.0 43.0 44.0 45.0 PCB-202 3.20e4 40.10 PCB-201 4.63e4 40.88 198/199 9.16e4 44.07 PCB-197 5.35e4PCB-200 41.65 3.24e4 41.74 PCB-196 5.46e4 44.65 4.03e4 PCB-203 5.63e4 44.82 0% 39.0 40.0 41.0 0.00e0 RT Abs. Int. 8.06e4 PCB-204 2.97e5 41.46 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.53e3 3.61e4 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.40e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.09e3 2.20e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.81e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.39e3 2.41e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.16e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.82e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3025, 8975 scc: 023-880 Revised: 03-Jan-2014 11:04 (LKB) Printed: 03-Jan-2014 15:21 Page 18 of 21 533 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Rel. Int. 100% OcCB-6 45.52-50.76 427.7635 Fn6 Flags: PBM 4σ 1.24e3 PCB-205 1.41e5 48.29 PCB-194 1.24e5 47.89 PCB-195 7.30e4 45.94 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 Abs. Int. 3.02e4 1.51e4 0% 46.0 Rel. Int. 100% OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PBM 4σ 1.81e3 47.0 48.0 50.0 PCB-205 1.59e5 48.29 PCB-194 1.34e5 47.88 PCB-195 8.40e4 45.94 49.0 0.00e0 RT Abs. Int. 3.19e4 1.60e4 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.72e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 9.24e2 1.86e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.30e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 1.09e3 2.15e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4721, 5462 scc: 023-880 Revised: 03-Jan-2014 10:41 (LKB) Printed: 03-Jan-2014 15:22 Page 19 of 21 534 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Rel. Int. 100% NoCB 45.52-50.76 461.7245 Fn6 Flags: PBM 4σ 1.18e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-206 1.29e5 49.76 PCB-207 9.69e4 46.52 Abs. Int. 2.57e4 PCB-208 8.35e4 45.73 1.28e4 0% 46.0 48.0 49.0 50.0 PCB-206 1.73e5 49.76 Rel. Int. 100% NoCB 45.52-50.76 463.7216 Fn6 Flags: PBM 4σ 2.42e3 47.0 PCB-208 9.91e4 45.73 Abs. Int. 4.00e4 PCB-207 1.16e5 46.52 2.00e4 0% 46.0 0.00e0 RT 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.41e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 9.48e2 1.20e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.76e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 8.46e2 1.38e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.65e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.82e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 3085, 2852 scc: 023-880 Revised: 03-Jan-2014 11:05 (LKB) Printed: 03-Jan-2014 15:22 Page 20 of 21 535 of 603 SGS-AP ID: SBS_131220_PCB_XC Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 21:57:30 User: LKB Datafile: 131220X09 PCB-209 2.67e5 51.24 Rel. Int. 100% Abs. Int. 4.95e4 DeCB 50.77-52.00 497.6826 Fn7 Flags: PBM 4σ 7.44e2 2.47e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 2.36e5 51.24 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.55e4 DeCB 50.77-52.00 499.6797 Fn7 Flags: PBM 4σ 6.79e2 2.27e4 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 3.81e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 8.32e2 1.91e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.08e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 7.81e2 2.54e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.37e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.69e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XC.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 6138, 0081 scc: 023-880 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 21 of 21 536 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. QC chk 100% 10.03-16.00 218.9856 Fn1 Flags: 0% Abs. Int. 5.15e7 2.57e7 11.0 12.0 13.0 14.0 0.00e0 16.0 RT 15.0 Rel. Int. QC chk 100% 16.02-21.51 242.9856 Fn2 Flags: 0% Abs. Int. 2.57e7 1.29e7 17.0 18.0 19.0 20.0 0.00e0 RT 21.0 Rel. Int. QC chk 100% 21.52-27.30 292.9824 Fn3 Flags: 0% Abs. Int. 1.83e7 9.14e6 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. QC chk 100% 27.33-38.50 330.9792 Fn4 Flags: 0% 0.00e0 RT Abs. Int. 1.86e7 9.28e6 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. QC chk 100% 38.52-45.50 380.9760 Fn5 Flags: 0% 0.00e0 RT Abs. Int. 1.12e7 5.60e6 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. QC chk 100% 45.52-50.76 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.71e6 2.85e6 46.0 47.0 48.0 49.0 50.0 Rel. Int. QC chk 100% 50.77-52.00 454.9728 Fn7 Flags: 0% 0.00e0 RT Abs. Int. 5.51e6 2.76e6 50.8 51.0 51.2 51.4 51.6 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 scc: 979-518 51.8 0.00e0 52.0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 03-Jan-2014 15:22 Page 1 of 21 537 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 3.05e4 MoCB 10.03-16.00 188.0393 Fn1 Flags: B 4σ 4.17e3 1.52e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.64e4 MoCB 10.03-16.00 190.0363 Fn1 Flags: B 4σ 4.11e3 8.18e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 1.16e4 MoCB Std. 10.03-16.00 200.0795 Fn1 Flags: PB 4σ 7.27e3 5.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 2.96e5 MoCB Std. 10.03-16.00 202.0766 Fn1 Flags: PB 4σ 4.32e4 1.48e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5489, 8194 scc: 979-518 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 2 of 21 538 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.27e4 DiCB-1 10.03-16.00 222.0003 Fn1 Flags: PB 4σ 7.90e3 6.34e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 4.88e4 DiCB-1 10.03-16.00 223.9974 Fn1 Flags: PB 4σ 2.37e4 2.44e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 3.49e4 DiCB Std. 10.03-16.00 234.0406 Fn1 Flags: PB 4σ 9.74e3 1.74e4 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 7.63e3 DiCB Std. 10.03-16.00 236.0376 Fn1 Flags: PB 4σ 4.20e3 3.82e3 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 16.0 RT Abs. Int. 5.15e7 QC Check 10.03-16.00 218.9856 Fn1 Flags: - 2.57e7 0% 11.0 12.0 13.0 14.0 15.0 0.00e0 16.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7629, 0428 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 3 of 21 539 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 5.56e4 DiCB-2 16.02-21.51 222.0003 Fn2 Flags: B 4σ 8.46e3 2.78e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.10e5 DiCB-2 16.02-21.51 223.9974 Fn2 Flags: PB 4σ 3.25e4 5.50e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.28e5 DiCB Std. 16.02-21.51 234.0406 Fn2 Flags: B 4σ 2.86e4 6.38e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.63e4 DiCB Std. 16.02-21.51 236.0376 Fn2 Flags: PB 4σ 8.50e3 8.13e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8027, 5868 scc: 979-518 Revised: 03-Jan-2014 11:06 (LKB) Printed: 03-Jan-2014 15:22 Page 4 of 21 540 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.85e4 TrCB-2 16.02-21.51 255.9613 Fn2 Flags: PB 4σ 4.38e3 9.27e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.60e4 TrCB-2 16.02-21.51 257.9584 Fn2 Flags: PB 4σ 5.38e3 8.02e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.40e6 TrCB Std. 16.02-21.51 268.0016 Fn2 Flags: B 4σ 8.60e4 4.70e6 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.09e6 TrCB Std. 16.02-21.51 269.9986 Fn2 Flags: PB 4σ 3.91e4 5.47e5 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0214, 1156 scc: 979-518 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 5 of 21 541 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-36 7.19e5 25.13 Rel. Int. 100% TrCB-3 21.52-27.30 255.9613 Fn3 Flags: PBM 4σ 4.14e3 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.86e5 SBS spiked with these native compounds: 36, 72, 79, 78, 96, 98, 89, 107, 106, 152, 166, 184, 182, 204 9.28e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-36 7.38e5 25.13 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e5 TrCB-3 21.52-27.30 257.9584 Fn3 Flags: PBM 4σ 3.70e3 9.30e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.09e6 TrCB Std. 21.52-27.30 268.0016 Fn3 Flags: PB 4σ 9.16e4 2.54e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.78e5 TrCB Std. 21.52-27.30 269.9986 Fn3 Flags: PB 4σ 2.79e4 2.89e5 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 5941, 5542 scc: 979-518 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 6 of 21 542 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 6.01e3 TeCB-2 16.02-21.51 289.9224 Fn2 Flags: PB 4σ 2.17e3 3.00e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.11e3 TeCB-2 16.02-21.51 291.9194 Fn2 Flags: PB 4σ 2.42e3 3.56e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.72e4 TeCB Std. 16.02-21.51 301.9626 Fn2 Flags: PB 4σ 1.83e4 1.86e4 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.99e4 TeCB Std. 16.02-21.51 303.9597 Fn2 Flags: PB 4σ 9.43e3 9.97e3 0% 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.57e7 QC Check 16.02-21.51 242.9856 Fn2 Flags: - 1.29e7 0% 17.0 18.0 19.0 20.0 21.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0820, 5379 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 7 of 21 543 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.58e4 TeCB-3 21.52-27.30 289.9224 Fn3 Flags: B 4σ 3.16e3 7.90e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.18e4 TeCB-3 21.52-27.30 291.9194 Fn3 Flags: PB 4σ 2.98e3 1.09e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.82e4 TeCB Std. 21.52-27.30 301.9626 Fn3 Flags: PB 4σ 2.93e4 2.41e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.23e4 TeCB Std. 21.52-27.30 303.9597 Fn3 Flags: PB 4σ 1.52e4 1.62e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8350, 9425 scc: 979-518 26.0 27.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 8 of 21 544 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 PCB-72 5.47e5 27.52 PCB-79 5.36e5 31.74 TeCB-4 27.33-38.50 289.9224 Fn4 Flags: PBM 4σ 2.89e3 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.43e5 PCB-78 5.18e5 32.24 7.14e4 0% 28.0 Rel. Int. 100% TeCB-4 27.33-38.50 291.9194 Fn4 Flags: PBM 4σ 4.42e3 30.0 32.0 PCB-79 7.00e5 31.74 PCB-72 6.98e5 27.51 34.0 36.0 38.0 0.00e0 RT Abs. Int. 1.76e5 PCB-78 6.62e5 32.24 8.82e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.97e4 TeCB Std. 27.33-38.50 301.9626 Fn4 Flags: PB 4σ 2.92e4 3.99e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.63e4 TeCB Std. 27.33-38.50 303.9597 Fn4 Flags: PB 4σ 1.73e4 2.31e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2818, 5309 scc: 979-518 36.0 38.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 9 of 21 545 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-96 2.82e5 25.99 Rel. Int. 100% Abs. Int. 7.28e4 PeCB-3 21.52-27.30 323.8834 Fn3 Flags: PBM 4σ 2.12e3 3.64e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 PCB-96 4.29e5 25.99 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.18e5 PeCB-3 21.52-27.30 325.8804 Fn3 Flags: PBM 4σ 1.71e3 5.88e4 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.59e3 PeCB Std. 21.52-27.30 337.9207 Fn3 Flags: PB 4σ 1.81e3 4.29e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.60e3 PeCB Std. 21.52-27.30 339.9177 Fn3 Flags: PB 4σ 2.46e3 3.80e3 0% 22.0 23.0 24.0 25.0 26.0 27.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.83e7 QC Check 21.52-27.30 292.9824 Fn3 Flags: - 9.14e6 0% 22.0 23.0 24.0 25.0 26.0 27.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8819, 8478 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 10 of 21 546 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% PCB-98 2.64e5 28.66 PeCB-4 27.33-38.50 323.8834 Fn4 Flags: PBM 4σ 2.65e3 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 107/124 3.94e5 34.48 PCB-89 2.48e5 29.64 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 8.72e4 PCB-106 3.37e5 34.91 4.36e4 0% 28.0 Rel. Int. 100% 30.0 PCB-98 4.27e5 28.66 PeCB-4 27.33-38.50 325.8804 Fn4 Flags: PBM 4σ 2.41e3 32.0 34.0 107/124 6.21e5 34.48 PCB-89 4.17e5 29.64 36.0 38.0 0.00e0 RT Abs. Int. 1.58e5 PCB-106 5.67e5 34.91 7.89e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.87e3 PeCB Std. 27.33-38.50 337.9207 Fn4 Flags: PB 4σ 2.55e3 3.93e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.29e4 PeCB Std. 27.33-38.50 339.9177 Fn4 Flags: PB 4σ 3.22e3 6.44e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9704, 3378 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 11 of 21 547 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 1.12e4 PeCB-5 38.52-45.50 323.8834 Fn5 Flags: PB 4σ 1.59e3 5.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.01e4 PeCB-5 38.52-45.50 325.8804 Fn5 Flags: PB 4σ 2.77e3 1.01e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.73e3 PeCB Std. 38.52-45.50 337.9207 Fn5 Flags: PB 4σ 2.80e3 4.36e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.27e4 PeCB Std. 38.52-45.50 339.9177 Fn5 Flags: PB 4σ 3.82e3 6.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2883, 5187 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 12 of 21 548 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-152 4.83e5 30.81 Rel. Int. 100% Abs. Int. 1.18e5 HxCB-4 27.33-38.50 359.8415 Fn4 Flags: PBM 4σ 1.87e3 5.91e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 PCB-152 3.94e5 30.81 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.51e4 HxCB-4 27.33-38.50 361.8385 Fn4 Flags: PBM 4σ 1.90e3 4.75e4 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.12e3 HxCB Std. 27.33-38.50 371.8817 Fn4 Flags: PB 4σ 1.86e3 4.06e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e3 HxCB Std. 27.33-38.50 373.8788 Fn4 Flags: PB 4σ 1.70e3 4.24e3 0% 28.0 30.0 32.0 34.0 36.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 27.33-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 28.0 30.0 32.0 34.0 36.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 0506, 2521 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 13 of 21 549 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Abs. Int. 1.20e5 128/166 4.76e5 38.81 HxCB-5 38.52-45.50 359.8415 Fn5 Flags: PBM 4σ 2.12e3 6.00e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Abs. Int. 1.02e5 128/166 3.90e5 38.81 HxCB-5 38.52-45.50 361.8385 Fn5 Flags: PBM 4σ 2.33e3 5.11e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.60e3 HxCB Std. 38.52-45.50 371.8817 Fn5 Flags: PB 4σ 2.45e3 4.80e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.66e4 HxCB Std. 38.52-45.50 373.8788 Fn5 Flags: PB 4σ 3.23e3 8.31e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 2148, 6219 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 14 of 21 550 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-184 2.50e5 36.28 Rel. Int. 100% Abs. Int. 6.09e4 HpCB-4 30.00-38.50 393.8025 Fn4 Flags: PBM 4σ 1.13e3 3.04e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 PCB-184 2.25e5 36.28 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.52e4 HpCB-4 30.00-38.50 395.7995 Fn4 Flags: PBM 4σ 8.66e2 2.76e4 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.58e4 HpCB Std. 30.00-38.50 405.8428 Fn4 Flags: PB 4σ 1.64e3 7.92e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.24e3 HpCB Std. 30.00-38.50 407.8398 Fn4 Flags: PB 4σ 1.38e3 2.12e3 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.86e7 QC Check 30.00-38.50 330.9792 Fn4 Flags: - 9.28e6 0% 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4369, 5758 scc: 979-518 Revised: 03-Jan-2014 11:07 (LKB) Printed: 03-Jan-2014 15:22 Page 15 of 21 551 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-182 3.17e5 39.06 Abs. Int. 7.81e4 HpCB-5 38.52-45.50 393.8025 Fn5 Flags: PBM 4σ 1.82e3 3.90e4 0% 39.0 Rel. Int. 100% 40.0 41.0 42.0 43.0 44.0 45.0 PCB-182 2.99e5 39.06 0.00e0 RT Abs. Int. 7.31e4 HpCB-5 38.52-45.50 395.7995 Fn5 Flags: PBM 4σ 1.86e3 3.66e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.19e3 HpCB-5 Std. 38.52-45.50 405.8428 Fn5 Flags: PB 4σ 1.88e3 4.59e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.48e3 HpCB-5 Std. 38.52-45.50 407.8398 Fn5 Flags: PB 4σ 1.22e3 4.24e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 1213, 4954 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 16 of 21 552 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 9.62e3 HpCB-6 45.52-50.76 393.8025 Fn6 Flags: PB 4σ 1.27e3 4.81e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.53e3 HpCB-6 45.52-50.76 395.7995 Fn6 Flags: PB 4σ 1.44e3 3.76e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.39e3 HpCB Std. 45.52-50.76 405.8428 Fn6 Flags: PB 4σ 2.56e3 2.69e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.72e3 HpCB Std. 45.52-50.76 407.8398 Fn6 Flags: PB 4σ 1.29e3 2.36e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 7659, 9371 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 17 of 21 553 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 PCB-204 2.39e5 41.45 Rel. Int. 100% Abs. Int. 6.07e4 OcCB-5 38.52-45.50 427.7635 Fn5 Flags: PBM 4σ 1.15e3 3.04e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 PCB-204 2.84e5 41.45 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.24e4 OcCB-5 38.52-45.50 429.7606 Fn5 Flags: PBM 4σ 1.08e3 3.62e4 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e3 OcCB Std. 38.52-45.50 439.8038 Fn5 Flags: PB 4σ 1.33e3 2.37e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.83e3 OcCB Std. 38.52-45.50 441.8008 Fn5 Flags: PB 4σ 1.25e3 2.92e3 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.12e7 QC Check 38.52-45.50 380.9760 Fn5 Flags: - 5.60e6 0% 39.0 40.0 41.0 42.0 43.0 44.0 45.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8871, 8933 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 18 of 21 554 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 5.29e3 OcCB-6 45.52-50.76 427.7635 Fn6 Flags: B 4σ 1.16e3 2.65e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.96e3 OcCB-6 45.52-50.76 429.7606 Fn6 Flags: PB 4σ 1.12e3 2.48e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.04e3 OcCB Std. 45.52-50.76 439.8038 Fn6 Flags: PB 4σ 7.05e2 1.52e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.58e3 OcCB Std. 45.52-50.76 441.8008 Fn6 Flags: PB 4σ 8.79e2 1.29e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 4309, 5142 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 19 of 21 555 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 4.42e3 NoCB 45.52-50.76 461.7245 Fn6 Flags: PB 4σ 1.08e3 2.21e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.67e3 NoCB 45.52-50.76 463.7216 Fn6 Flags: PB 4σ 1.77e3 2.84e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.46e3 NoCB Std. 45.52-50.76 473.7648 Fn6 Flags: PB 4σ 8.65e2 1.73e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.81e3 NoCB Std. 45.52-50.76 475.7619 Fn6 Flags: PB 4σ 7.98e2 1.40e3 0% 46.0 47.0 48.0 49.0 50.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.71e6 QC Check 45.52-50.76 454.9728 Fn6 Flags: - 2.85e6 0% 46.0 47.0 48.0 49.0 50.0 0.00e0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 8411, 8296 scc: 979-518 Revised: 27-Dec-2013 12:14 (LKB) Printed: 03-Jan-2014 15:22 Page 20 of 21 556 of 603 SGS-AP ID: SBS_131220_PCB_XD Instr: AutoSpec-Premier MM7 Sample ID: SIL 9-42-1 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 2 Acq: 20-Dec-2013 22:52:16 User: LKB Datafile: 131220X10 Rel. Int. 100% Abs. Int. 4.94e3 DeCB 50.77-52.00 497.6826 Fn7 Flags: PB 4σ 4.11e2 2.47e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 4.97e3 DeCB 50.77-52.00 499.6797 Fn7 Flags: PB 4σ 6.24e2 2.48e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.05e3 DeCB Std. 50.77-52.00 509.7229 Fn7 Flags: PB 4σ 5.08e2 1.02e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 2.19e3 DeCB Std. 50.77-52.00 511.7199 Fn7 Flags: PB 4σ 9.76e2 1.09e3 0% 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 52.0 RT Abs. Int. 5.51e6 QC Check 50.77-52.00 454.9728 Fn7 Flags: - 2.76e6 0% 50.8 51.0 51.2 51.4 51.6 51.8 0.00e0 52.0 RT Results: T:\UltraTracePro\ICAL results\MM7_PCB_10292013_20DEC2013\Resources\SBS_131220_PCB_XD.utp_res, saved 03-Jan-2014 11:08 (LKB) Peak annotation: Areas, Centroids AP UltraTrace-Pro V4.81 User/System: LKB/LBI7-065 cc: 9640, 2741 scc: 979-518 PKD: 03-Jan-2014 11:08 Printed: 03-Jan-2014 15:22 Page 21 of 21 Experiment Calibration Report 557 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 1 @ 200 (ppm) Printed: Friday, December 20, 2013 14:51:56 Eastern Standard Time M 180.9888 R 11467 M 192.9888 R 9920 242.8 M 204.9888 R 12316 180.9 1.00e0 x16 1.200 M 218.9856 R 11902 192.9 1.00e0 x16 204.9 1.00e0 x16 x16 0.425 0.065 0.100 1.00e0 0.400 0.060 1.100 0.375 0.090 0.055 1.000 0.080 0.350 0.325 0.050 0.900 0.070 0.300 0.045 0.800 0.275 0.040 0.060 0.700 0.250 0.035 0.600 0.225 0.050 0.200 0.030 0.500 0.175 0.040 0.025 0.150 0.400 0.030 0.300 0.020 0.125 0.015 0.100 0.020 0.075 0.200 0.010 0.050 0.010 0.100 -0.000 0.005 -0.000 180.87 180.88 180.89 180.90 192.86 M 230.9856 R 11523 192.87 192.88 192.89 230.8 x16 1.00e0 x16 0.600 0.170 0.550 0.160 0.150 0.500 0.140 0.450 0.130 0.120 0.400 0.110 0.350 0.100 0.090 0.300 0.080 0.250 0.070 0.060 0.200 0.050 0.150 0.040 0.030 0.100 0.020 0.050 0.010 -0.000 -0.000 230.82 230.83 230.84 230.85 242.80 242.81 242.82 242.83 242.84 -0.000 204.85 M 242.9856 R 11311 218.8 1.00e0 0.025 -0.000 204.86 204.87 204.88 218.83 218.84 218.85 218.86 Experiment Calibration Report 558 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 2 @ 200 (ppm) Printed: Friday, December 20, 2013 14:52:25 Eastern Standard Time M 218.9856 R 11415 M 230.9856 R 11111 304.8 M 242.9856 R 10549 218.9 1.00e0 x16 0.400 M 254.9856 R 10639 230.9 1.00e0 x16 242.9 1.00e0 x16 0.600 1.00e0 x16 0.110 0.200 0.375 0.550 0.100 0.350 0.180 0.500 0.325 0.090 0.300 0.450 0.160 0.400 0.140 0.080 0.275 0.250 0.070 0.350 0.225 0.120 0.060 0.200 0.300 0.100 0.050 0.175 0.250 0.080 0.150 0.040 0.200 0.125 0.060 0.100 0.030 0.150 0.075 0.040 0.020 0.100 0.050 0.050 0.025 -0.000 -0.000 218.86 218.87 218.88 218.89 230.85 M 268.9824 R 10161 230.86 230.87 230.88 0.010 -0.000 -0.000 230.89 M 280.9824 R 10871 254.8 0.020 242.84 242.85 x16 242.87 242.88 M 292.9824 R 10203 268.8 1.00e0 242.86 254.83 254.84 254.85 x16 0.280 254.87 M 304.9824 R 10820 280.8 1.00e0 254.86 292.8 1.00e0 x16 1.00e0 x16 0.120 0.150 0.070 0.260 0.140 0.110 0.065 0.100 0.060 0.240 0.130 0.220 0.120 0.055 0.090 0.110 0.200 0.100 0.180 0.090 0.160 0.070 0.140 0.060 0.050 0.080 0.045 0.040 0.080 0.035 0.070 0.120 0.030 0.050 0.060 0.100 0.025 0.040 0.050 0.080 0.020 0.040 0.030 0.060 0.015 0.030 0.020 0.040 0.020 0.010 0.010 0.020 0.010 -0.000 -0.000 268.81 268.82 268.83 268.84 268.85 0.005 -0.000 280.80 280.81 280.82 280.83 280.84 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 304.78 304.79 304.80 304.81 304.82 304.83 Experiment Calibration Report 559 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 3 @ 200 (ppm) Printed: Friday, December 20, 2013 14:52:57 Eastern Standard Time M 242.9856 R 11208 M 254.9856 R 10868 342.8 M 268.9824 R 10822 242.9 1.00e0 x16 M 280.9824 R 10819 254.9 1.00e0 x16 268.8 1.00e0 x16 1.00e0 x16 0.110 0.200 0.100 0.180 0.090 0.160 0.080 0.160 0.320 0.150 0.300 0.140 0.280 0.130 0.260 0.120 0.240 0.110 0.220 0.100 0.200 0.090 0.180 0.080 0.160 0.070 0.140 0.060 0.120 0.050 0.100 0.040 0.080 0.030 0.060 0.020 0.040 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.010 0.010 -0.000 -0.000 242.85 242.86 242.87 242.88 242.89 254.84 M 292.9824 R 11364 254.85 254.86 254.87 M 304.9824 R 10328 280.8 0.020 -0.000 268.82 254.88 268.83 268.84 x16 0.160 268.86 -0.000 280.81 268.87 M 316.9824 R 10549 292.8 1.00e0 268.85 280.82 280.83 280.84 x16 280.86 M 330.9792 R 9803 304.8 1.00e0 280.85 316.8 1.00e0 x16 1.00e0 x16 0.110 0.100 0.045 0.150 0.100 0.090 0.040 0.140 0.090 0.130 0.080 0.035 0.120 0.080 0.070 0.110 0.030 0.070 0.100 0.060 0.090 0.060 0.025 0.080 0.050 0.070 0.050 0.020 0.040 0.060 0.040 0.015 0.050 0.030 0.030 0.040 0.010 0.020 0.030 0.020 0.020 0.005 0.010 0.010 0.010 -0.000 -0.000 292.80 292.81 292.82 292.83 292.84 292.85 304.79 M 342.9792 R 10375 330.8 1.00e0 x16 0.075 0.070 0.065 0.060 0.055 0.050 0.045 0.040 0.035 0.030 0.025 0.020 0.015 0.010 0.005 -0.000 342.76 342.77 342.78 342.79 342.80 342.81 -0.000 342.82 304.80 304.81 304.82 304.83 304.84 316.78 316.79 316.80 316.81 316.82 316.83 -0.000 330.76 330.77 330.78 330.79 330.80 330.81 330.82 Experiment Calibration Report 560 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 4 @ 200 (ppm) Printed: Friday, December 20, 2013 14:53:27 Eastern Standard Time M 280.9824 R 11901 M 292.9824 R 10771 416.8 M 304.9824 R 11159 280.8 1.00e0 x16 0.320 0.160 0.300 0.150 0.280 0.140 M 316.9824 R 10777 292.8 1.00e0 x16 304.8 1.00e0 x16 0.130 0.240 0.120 0.220 0.110 0.200 0.100 0.180 0.090 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 x16 0.045 0.110 0.040 0.100 0.260 1.00e0 0.120 0.090 0.035 0.080 0.030 0.070 0.025 0.060 0.020 0.050 0.040 0.015 0.030 0.010 0.020 0.005 0.010 0.020 0.010 -0.000 -0.000 280.83 280.84 280.85 280.86 -0.000 280.87 292.82 M 330.9792 R 11627 292.83 292.84 292.85 292.86 304.81 M 342.9792 R 10375 316.8 -0.000 304.82 304.83 x16 0.160 304.85 304.86 M 354.9792 R 10965 330.8 1.00e0 304.84 316.79 316.80 316.81 316.82 x16 x16 1.00e0 x16 0.034 0.032 0.060 0.150 316.85 354.8 1.00e0 0.065 0.120 316.84 M 366.9792 R 10868 342.8 1.00e0 316.83 0.110 0.030 0.140 0.055 0.028 0.100 0.130 0.050 0.120 0.026 0.090 0.024 0.045 0.110 0.080 0.022 0.040 0.100 0.020 0.070 0.090 0.080 0.035 0.018 0.030 0.016 0.060 0.070 0.014 0.050 0.025 0.060 0.012 0.040 0.050 0.040 0.020 0.030 0.030 0.010 0.008 0.015 0.006 0.020 0.010 0.010 0.005 -0.000 -0.000 0.020 0.004 0.010 -0.000 330.78 330.79 330.80 330.81 330.82 330.83 342.77 M 380.9760 R 10685 342.78 342.79 342.80 342.81 342.82 342.83 M 392.9760 R 10869 366.8 0.002 -0.000 354.76 354.77 354.78 x16 354.80 354.81 354.82 M 404.9760 R 10290 380.8 1.00e0 354.79 366.74 366.75 366.76 366.77 x16 366.79 366.80 366.81 M 416.9760 R 11464 392.8 1.00e0 366.78 404.8 1.00e0 x16 1.00e0 x16 0.028 0.065 0.015 0.045 0.026 0.014 0.060 0.024 0.040 0.013 0.055 0.022 0.012 0.035 0.050 0.045 0.030 0.040 0.020 0.011 0.018 0.010 0.016 0.009 0.025 0.035 0.008 0.014 0.030 0.007 0.012 0.020 0.006 0.025 0.010 0.005 0.015 0.020 0.008 0.015 0.006 0.004 0.010 0.003 0.010 0.004 0.002 0.005 0.005 0.002 -0.000 -0.000 380.73 380.74 380.75 380.76 380.77 380.78 380.79 0.001 -0.000 392.72 392.73 392.74 392.75 392.76 392.77 392.78 392.79 404.72 404.73 404.74 404.75 404.76 404.77 404.78 404.79 -0.000 416.71 416.72 416.73 416.74 416.75 416.76 416.77 416.78 416.79 Experiment Calibration Report 561 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 5 @ 200 (ppm) Printed: Friday, December 20, 2013 14:54:02 Eastern Standard Time M 316.9824 R 10870 M 330.9792 R 10775 442.7 M 342.9792 R 10285 316.8 1.00e0 x16 M 354.9792 R 10121 330.8 1.00e0 x16 342.8 1.00e0 x16 0.150 x16 0.065 0.130 0.045 1.00e0 0.140 0.060 0.120 0.130 0.040 0.055 0.110 0.120 0.035 0.100 0.050 0.100 0.090 0.045 0.090 0.080 0.040 0.080 0.070 0.035 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.110 0.030 0.025 0.070 0.020 0.060 0.050 0.015 0.040 0.010 0.030 0.020 0.005 -0.000 -0.000 316.78 316.79 316.80 316.81 316.82 -0.000 316.83 330.76 M 366.9792 R 10872 0.005 0.010 0.010 330.77 330.78 330.79 330.80 330.81 342.75 M 380.9760 R 10122 354.8 -0.000 330.82 342.76 342.77 342.78 x16 342.81 354.74 354.75 354.76 x16 354.77 354.78 354.79 354.80 M 404.9760 R 9840 380.7 1.00e0 0.100 0.040 342.80 M 392.9760 R 10775 366.8 1.00e0 342.79 392.7 1.00e0 x16 1.00e0 x16 0.070 0.045 0.065 0.090 0.035 0.060 0.080 0.040 0.055 0.030 0.035 0.050 0.070 0.045 0.025 0.030 0.060 0.040 0.025 0.050 0.020 0.035 0.030 0.020 0.040 0.015 0.025 0.015 0.030 0.020 0.010 0.015 0.020 0.010 0.010 0.005 0.005 0.010 0.005 -0.000 -0.000 366.73 366.74 366.75 366.76 366.77 366.78 -0.000 366.79 380.71 M 416.9760 R 10964 380.72 380.73 380.74 380.75 380.76 380.77 392.70 M 430.9728 R 10332 404.7 -0.000 392.71 392.72 392.73 x16 392.75 392.76 404.68 M 442.9728 R 10204 416.7 1.00e0 392.74 430.7 1.00e0 x16 0.040 1.00e0 x16 0.030 0.026 0.028 0.024 0.035 0.026 0.022 0.024 0.030 0.020 0.022 0.020 0.018 0.025 0.018 0.016 0.016 0.014 0.020 0.014 0.012 0.012 0.015 0.010 0.010 0.008 0.008 0.010 0.006 0.006 0.004 0.004 0.005 0.002 0.002 -0.000 416.67 416.68 416.69 416.70 416.71 416.72 416.73 416.74 -0.000 430.65 -0.000 430.66 430.67 430.68 430.69 430.70 430.71 430.72 430.73 442.65 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 404.69 404.70 404.71 404.72 404.73 404.74 404.75 Experiment Calibration Report 562 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 6 @ 200 (ppm) Printed: Friday, December 20, 2013 14:55:29 Eastern Standard Time M 380.9760 R 10121 M 392.9760 R 10333 480.6 M 404.9760 R 10730 380.7 1.00e0 x16 M 416.9760 R 10825 392.7 1.00e0 x16 404.7 1.00e0 x16 1.00e0 x16 0.080 0.090 0.075 0.050 0.035 0.070 0.080 0.045 0.065 0.030 0.060 0.070 0.040 0.055 0.025 0.035 0.060 0.050 0.045 0.030 0.050 0.020 0.040 0.025 0.035 0.040 0.030 0.030 0.015 0.020 0.025 0.015 0.010 0.020 0.020 0.015 0.010 0.005 0.010 0.010 0.005 0.005 -0.000 -0.000 380.69 380.70 380.71 380.72 380.73 380.74 380.75 -0.000 380.76 M 430.9728 R 9958 392.68 392.69 392.70 392.71 392.72 392.73 392.74 M 442.9728 R 10204 416.7 -0.000 404.66 404.67 404.68 404.69 404.70 x16 404.72 404.73 416.65 M 454.9728 R 10286 430.7 1.00e0 404.71 416.66 416.67 416.68 x16 416.70 416.71 416.72 M 466.9728 R 10246 442.7 1.00e0 416.69 454.6 1.00e0 x16 1.00e0 x16 0.026 0.050 0.045 0.024 0.050 0.045 0.022 0.040 0.045 0.040 0.020 0.040 0.035 0.018 0.035 0.035 0.030 0.016 0.030 0.030 0.014 0.025 0.025 0.025 0.012 0.020 0.020 0.010 0.020 0.015 0.015 0.015 0.010 0.010 0.008 0.006 0.010 0.004 0.005 0.005 0.005 0.002 -0.000 -0.000 430.63 430.64 430.65 430.66 430.67 430.68 430.69 430.70 430.71 M 480.9696 R 10165 466.6 1.00e0 x16 0.028 0.026 0.024 0.022 0.020 0.018 0.016 0.014 0.012 0.010 0.008 0.006 0.004 0.002 -0.000 480.57 480.58 480.59 480.60 480.61 480.62 480.63 480.64 480.65 480.66 -0.000 442.62 442.63 442.64 442.65 442.66 442.67 442.68 442.69 442.70 -0.000 454.61 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 466.59 466.60 466.61 466.62 466.63 466.64 466.65 466.66 466.67 466.68 Experiment Calibration Report 563 of 603 Page 1 of 1 MassLynx 4.1 SCN 881 File: Experiment: pcb-2012-01.exp Reference: Pfk3.ref Function: 7 @ 200 (ppm) Printed: Friday, December 20, 2013 14:56:11 Eastern Standard Time M 430.9728 R 10591 M 442.9728 R 11468 516.6 M 454.9728 R 10774 430.7 1.00e0 x16 M 466.9728 R 11625 442.7 1.00e0 x16 454.7 1.00e0 x16 0.055 1.00e0 x16 0.032 0.050 0.045 0.030 0.050 0.045 0.028 0.040 0.045 0.026 0.040 0.024 0.035 0.040 0.022 0.035 0.035 0.030 0.020 0.030 0.018 0.030 0.025 0.016 0.025 0.025 0.014 0.020 0.020 0.012 0.020 0.015 0.010 0.015 0.015 0.008 0.010 0.010 0.010 0.006 0.004 0.005 0.005 0.005 0.002 -0.000 -0.000 430.66 430.67 430.68 430.69 430.70 430.71 430.72 430.73 -0.000 442.64 M 480.9696 R 9999 442.65 442.66 442.67 442.68 442.69 442.70 442.71 454.63 M 492.9696 R 11060 466.7 -0.000 442.72 454.64 454.65 454.66 x16 454.68 454.69 454.70 454.71 466.62 M 504.9696 R 10504 480.6 1.00e0 454.67 466.63 466.64 466.65 x16 466.67 466.68 466.69 504.6 1.00e0 x16 0.040 1.00e0 x16 0.020 0.034 0.032 0.032 0.018 0.030 0.035 0.030 0.028 0.028 0.026 0.016 0.030 0.026 0.024 0.014 0.024 0.022 0.022 0.025 0.012 0.020 0.020 0.018 0.018 0.016 0.020 0.010 0.016 0.014 0.008 0.014 0.015 0.012 0.012 0.010 0.010 0.008 0.008 0.006 0.006 0.004 0.004 0.006 0.010 0.004 0.002 0.002 -0.000 -0.000 480.60 480.61 480.62 480.63 480.64 480.65 480.66 480.67 480.68 0.005 0.002 -0.000 492.59 492.60 492.61 492.62 492.63 492.64 492.65 492.66 492.67 -0.000 504.57 504.58 504.59 504.60 504.61 504.62 466.70 M 516.9697 R 11012 492.6 1.00e0 0.034 466.66 504.63 504.64 504.65 504.66 516.56 516.57 516.58 516.59 516.60 516.61 516.62 516.63 516.64 Resolution Check Report Printed: 564 of 603 Page 1 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 180.9888 R 11709 M 192.9888 R 10531 180.9 M 204.9888 R 11823 192.9 1.00e0 x16 M 218.9856 R 12380 204.9 1.00e0 x16 218.9 1.00e0 x16 1.00e0 x16 0.130 0.075 1.300 0.450 0.120 0.070 1.200 0.110 0.065 0.100 0.060 0.400 1.100 0.350 1.000 0.055 0.090 0.900 0.050 0.300 0.080 0.800 0.045 0.070 0.700 0.250 0.040 0.060 0.035 0.050 0.030 0.600 0.200 0.500 0.025 0.040 0.400 0.150 0.020 0.030 0.300 0.100 0.015 0.200 0.020 0.100 0.010 0.010 0.050 -0.000 0.005 -0.000 180.87 180.88 180.89 -0.000 180.90 192.86 M 230.9856 R 11709 192.87 192.88 204.85 M 242.9856 R 11344 230.8 -0.000 192.89 204.86 204.87 x16 218.83 M 218.9856 R 11709 242.8 1.00e0 204.88 218.84 218.85 x16 218.87 M 230.9856 R 11709 218.9 1.00e0 218.86 230.9 1.00e0 x16 1.00e0 x16 0.650 0.200 0.450 0.650 0.600 0.425 0.180 0.550 0.400 0.600 0.375 0.550 0.160 0.500 0.350 0.500 0.450 0.325 0.140 0.450 0.300 0.400 0.275 0.120 0.400 0.250 0.350 0.350 0.100 0.225 0.300 0.300 0.200 0.080 0.250 0.175 0.250 0.150 0.200 0.060 0.200 0.125 0.150 0.150 0.100 0.040 0.075 0.100 0.020 0.050 -0.000 -0.000 0.100 0.050 0.050 0.025 -0.000 230.82 230.83 230.84 230.85 230.86 242.81 M 242.9856 R 11737 242.82 242.83 242.84 242.85 218.86 M 254.9856 R 11378 242.9 -0.000 218.87 218.88 x16 230.85 M 268.9824 R 11848 254.8 1.00e0 218.89 x16 0.110 0.100 230.89 280.8 x16 1.00e0 x16 0.320 0.160 0.200 230.88 M 280.9824 R 11210 1.00e0 0.170 0.220 230.87 268.8 1.00e0 0.120 0.240 230.86 0.300 0.150 0.280 0.140 0.260 0.130 0.180 0.090 0.160 0.080 0.140 0.070 0.240 0.120 0.220 0.110 0.200 0.100 0.180 0.090 0.120 0.060 0.100 0.050 0.080 0.040 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.060 0.030 0.040 0.020 0.040 0.080 0.030 0.060 0.040 0.020 0.010 0.020 -0.000 -0.000 242.84 242.85 242.86 242.87 242.88 254.83 254.84 254.85 254.86 254.87 0.010 0.020 -0.000 -0.000 268.81 268.82 268.83 268.84 268.85 268.86 280.80 280.81 280.82 280.83 280.84 280.85 Resolution Check Report Printed: 565 of 603 Page 2 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 292.9824 R 11577 M 304.9824 R 11389 292.8 M 242.9856 R 11827 304.8 1.00e0 x16 M 254.9856 R 11793 242.9 1.00e0 x16 254.9 1.00e0 x16 1.00e0 x16 0.090 0.240 0.120 0.085 0.140 0.220 0.080 0.130 0.110 0.075 0.200 0.120 0.100 0.070 0.110 0.180 0.065 0.100 0.060 0.090 0.055 0.090 0.160 0.080 0.140 0.050 0.070 0.080 0.045 0.120 0.070 0.060 0.040 0.060 0.035 0.050 0.030 0.040 0.025 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.030 0.015 0.020 0.010 0.020 0.010 0.010 0.005 -0.000 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 -0.000 304.78 M 268.9824 R 11467 304.79 304.80 304.81 304.82 304.83 M 280.9824 R 11683 268.8 -0.000 242.85 242.86 242.87 x16 242.89 254.84 M 292.9824 R 11337 280.8 1.00e0 242.88 254.85 254.86 x16 254.88 M 304.9824 R 11548 292.8 1.00e0 254.87 304.8 1.00e0 x16 1.00e0 x16 0.360 0.170 0.180 0.110 0.340 0.160 0.320 0.160 0.100 0.150 0.300 0.140 0.280 0.140 0.090 0.130 0.260 0.080 0.120 0.240 0.120 0.110 0.220 0.070 0.100 0.200 0.100 0.080 0.060 0.040 0.020 0.180 0.090 0.160 0.080 0.140 0.070 0.120 0.060 0.100 0.050 0.080 0.040 0.060 0.030 0.040 0.020 0.020 0.010 0.060 0.050 0.040 0.030 0.020 0.010 -0.000 -0.000 268.83 268.84 268.85 268.86 -0.000 268.87 280.82 M 316.9824 R 11605 280.83 280.84 280.85 292.81 M 330.9792 R 11186 316.8 -0.000 280.86 292.82 292.83 x16 292.85 x16 0.110 304.83 304.84 304.85 280.9 x16 1.00e0 x16 0.375 0.085 0.120 304.82 M 280.9824 R 11876 1.00e0 0.090 0.130 0.045 304.81 342.8 1.00e0 0.050 304.80 M 342.9792 R 11340 330.8 1.00e0 0.055 292.84 0.350 0.080 0.325 0.075 0.300 0.070 0.100 0.040 0.065 0.275 0.060 0.250 0.090 0.035 0.080 0.055 0.225 0.050 0.030 0.070 0.200 0.045 0.025 0.175 0.060 0.040 0.050 0.020 0.035 0.150 0.030 0.125 0.040 0.025 0.015 0.030 0.075 0.010 0.015 0.020 0.050 0.010 0.005 -0.000 316.78 0.100 0.020 0.010 -0.000 316.79 316.80 316.81 316.82 316.83 316.84 330.77 330.78 330.79 330.80 330.81 330.82 330.83 0.005 0.025 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 280.83 280.84 280.85 280.86 280.87 280.88 Resolution Check Report Printed: 566 of 603 Page 3 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 292.9824 R 12107 M 304.9824 R 11576 292.8 M 316.9824 R 11932 304.8 1.00e0 x16 M 330.9792 R 11547 316.8 1.00e0 x16 330.8 1.00e0 x16 1.00e0 x16 0.200 0.180 0.055 0.130 0.170 0.180 0.120 0.050 0.160 0.150 0.110 0.160 0.045 0.140 0.100 0.140 0.130 0.040 0.090 0.120 0.035 0.120 0.110 0.080 0.100 0.070 0.030 0.060 0.025 0.100 0.090 0.080 0.080 0.070 0.050 0.020 0.060 0.060 0.040 0.050 0.015 0.030 0.040 0.040 0.010 0.030 0.020 0.020 0.020 0.005 0.010 -0.000 0.010 -0.000 292.82 292.83 292.84 292.85 292.86 -0.000 292.87 304.81 M 342.9792 R 11458 304.82 304.83 304.84 304.85 316.80 M 354.9792 R 11569 342.8 -0.000 304.86 316.81 316.82 316.83 x16 316.85 330.78 M 366.9792 R 12588 354.8 1.00e0 316.84 330.79 330.80 330.81 x16 330.83 330.84 M 380.9760 R 11628 366.8 1.00e0 330.82 380.8 1.00e0 x16 1.00e0 x16 0.080 0.075 0.130 0.075 0.070 0.040 0.120 0.070 0.065 0.110 0.065 0.035 0.060 0.060 0.100 0.055 0.055 0.030 0.090 0.050 0.050 0.080 0.045 0.025 0.045 0.040 0.070 0.040 0.035 0.060 0.020 0.035 0.030 0.030 0.050 0.015 0.025 0.025 0.040 0.020 0.020 0.010 0.030 0.015 0.020 0.015 0.010 0.010 0.005 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 342.83 0.005 -0.000 354.76 M 392.9760 R 11554 0.010 0.005 354.77 354.78 354.79 354.80 354.81 354.82 366.75 M 404.9760 R 11821 392.8 -0.000 366.76 366.77 x16 366.79 366.80 366.81 380.74 M 416.9760 R 11574 404.8 1.00e0 0.065 366.78 380.75 380.76 x16 380.78 380.79 380.80 M 316.9824 R 11467 416.8 1.00e0 0.040 380.77 316.8 1.00e0 x16 1.00e0 x16 0.060 0.020 0.060 0.055 0.018 0.035 0.055 0.050 0.016 0.050 0.030 0.045 0.045 0.014 0.040 0.025 0.040 0.012 0.035 0.010 0.030 0.035 0.020 0.030 0.025 0.008 0.025 0.015 0.020 0.020 0.006 0.010 0.015 0.015 0.004 0.010 0.010 0.005 0.002 0.005 0.005 -0.000 -0.000 392.73 392.74 392.75 392.76 392.77 392.78 392.79 392.80 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 -0.000 416.72 -0.000 416.73 416.74 416.75 416.76 416.77 416.78 416.79 416.80 316.78 316.79 316.80 316.81 316.82 316.83 316.84 Resolution Check Report Printed: 567 of 603 Page 4 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 330.9792 R 12118 M 342.9792 R 11633 330.8 M 354.9792 R 11643 342.8 1.00e0 x16 M 366.9792 R 11396 354.8 1.00e0 x16 366.8 1.00e0 x16 1.00e0 x16 0.075 0.170 0.150 0.045 0.070 0.160 0.140 0.065 0.150 0.040 0.130 0.140 0.060 0.120 0.130 0.035 0.055 0.110 0.120 0.050 0.100 0.110 0.100 0.090 0.090 0.080 0.080 0.070 0.030 0.045 0.025 0.040 0.035 0.020 0.070 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.060 0.050 0.015 0.040 0.010 0.030 0.020 0.005 0.005 0.010 0.010 -0.000 -0.000 330.77 330.78 330.79 330.80 330.81 -0.000 330.82 342.76 M 380.9760 R 11086 342.77 342.78 342.79 342.80 342.81 M 392.9760 R 10917 380.7 -0.000 354.74 354.75 354.76 354.77 x16 354.79 354.80 366.73 M 404.9760 R 11685 392.7 1.00e0 354.78 x16 0.080 366.76 366.77 366.78 366.79 366.80 M 416.9760 R 11737 416.7 1.00e0 x16 1.00e0 x16 0.032 0.055 0.030 0.075 0.050 0.028 0.070 0.090 0.026 0.045 0.065 0.080 366.75 404.7 1.00e0 0.110 0.100 366.74 0.024 0.060 0.040 0.022 0.055 0.070 0.035 0.050 0.060 0.020 0.018 0.045 0.030 0.016 0.040 0.050 0.025 0.035 0.040 0.030 0.014 0.012 0.020 0.010 0.025 0.030 0.015 0.008 0.020 0.020 0.015 0.006 0.010 0.004 0.010 0.010 0.005 0.005 -0.000 380.72 380.73 380.74 380.75 380.76 380.77 0.002 -0.000 392.70 380.78 M 430.9728 R 11418 -0.000 392.71 392.72 392.73 392.74 392.75 392.76 392.77 404.69 M 442.9728 R 11628 430.7 -0.000 404.70 404.71 404.72 x16 404.74 404.75 404.76 416.68 M 380.9760 R 11522 442.7 1.00e0 404.73 416.69 416.70 416.71 x16 416.73 416.74 416.75 M 392.9760 R 11852 380.7 1.00e0 0.045 416.72 392.7 1.00e0 x16 1.00e0 x16 0.110 0.090 0.100 0.040 0.035 0.090 0.080 0.080 0.070 0.035 0.030 0.030 0.070 0.025 0.060 0.025 0.060 0.050 0.020 0.050 0.020 0.040 0.015 0.040 0.015 0.030 0.030 0.010 0.010 0.020 0.020 0.005 0.005 0.010 0.010 -0.000 430.66 -0.000 430.67 430.68 430.69 430.70 430.71 430.72 430.73 430.74 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 -0.000 380.70 380.71 380.72 380.73 380.74 380.75 380.76 380.77 392.69 392.70 392.71 392.72 392.73 392.74 392.75 392.76 Resolution Check Report Printed: 568 of 603 Page 5 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 404.9760 R 11798 M 416.9760 R 11962 404.7 M 430.9728 R 11403 416.7 1.00e0 x16 M 442.9728 R 12348 430.7 1.00e0 x16 0.065 442.7 1.00e0 x16 0.040 0.060 0.055 0.035 1.00e0 x16 0.055 0.060 0.055 0.050 0.050 0.045 0.045 0.040 0.050 0.030 0.045 0.040 0.035 0.040 0.035 0.025 0.030 0.035 0.030 0.030 0.020 0.025 0.025 0.025 0.020 0.015 0.020 0.020 0.015 0.015 0.015 0.010 0.010 0.010 0.010 0.005 0.005 0.005 0.005 -0.000 404.68 404.69 404.70 404.71 404.72 404.73 404.74 -0.000 416.66 404.75 M 454.9728 R 11665 -0.000 416.67 416.68 416.69 416.70 416.71 416.72 416.73 430.65 M 466.9728 R 11529 454.7 -0.000 416.74 430.66 430.67 430.68 x16 430.70 430.71 430.72 442.64 M 480.9696 R 11402 466.7 1.00e0 0.060 430.69 442.65 442.66 442.67 x16 442.69 442.70 442.71 M 430.9728 R 11904 480.6 1.00e0 442.68 430.7 1.00e0 x16 1.00e0 x16 0.036 0.032 0.070 0.034 0.030 0.055 0.032 0.065 0.030 0.060 0.028 0.050 0.026 0.028 0.045 0.024 0.040 0.055 0.026 0.050 0.022 0.024 0.020 0.022 0.045 0.018 0.020 0.040 0.016 0.018 0.035 0.030 0.025 0.035 0.016 0.014 0.030 0.014 0.012 0.025 0.012 0.020 0.010 0.010 0.015 0.020 0.008 0.008 0.006 0.010 0.015 0.006 0.010 0.004 0.004 0.005 -0.000 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 0.002 0.002 -0.000 -0.000 454.70 466.61 M 442.9728 R 12063 466.62 466.63 466.64 466.65 466.66 466.67 466.68 466.69 480.59 M 454.9728 R 11740 442.7 0.005 -0.000 480.60 480.61 480.62 480.63 x16 480.65 480.66 480.67 480.68 M 466.9728 R 11628 454.7 1.00e0 480.64 430.67 430.68 430.69 430.70 x16 430.72 430.73 430.74 430.75 M 480.9696 R 12053 466.7 1.00e0 430.71 480.7 1.00e0 x16 1.00e0 x16 0.060 0.055 0.055 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.050 0.050 0.045 0.045 0.040 0.040 0.035 0.035 0.030 0.030 0.025 0.025 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 -0.000 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 0.005 0.005 -0.000 -0.000 480.61 466.63 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 480.62 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 Resolution Check Report Printed: 569 of 603 Page 6 of 6 MassLynx 4.1 SCN 881 Friday, December 20, 2013 21:57:28 Eastern Standard Time M 492.9696 R 11688 M 504.9696 R 11467 492.6 M 516.9697 R 12194 504.6 1.00e0 x16 516.6 1.00e0 x16 0.045 1.00e0 x16 0.024 0.040 0.022 0.040 0.020 0.035 0.035 0.018 0.030 0.030 0.016 0.014 0.025 0.025 0.012 0.020 0.020 0.010 0.015 0.015 0.010 0.010 0.005 0.005 0.008 0.006 0.004 0.002 -0.000 -0.000 492.60 492.61 492.62 492.63 492.64 492.65 492.66 492.67 492.68 492.69 -0.000 504.59 504.60 504.61 504.62 504.63 504.64 504.65 504.66 504.67 504.68 516.58 516.59 516.60 516.61 516.62 516.63 516.64 516.65 516.66 516.67 Resolution Check Report Printed: 570 of 603 Page 1 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 180.9888 R 11682 M 192.9888 R 9510 180.9 M 204.9888 R 12347 192.9 1.00e0 x16 M 218.9856 R 11961 204.9 1.00e0 x16 218.9 1.00e0 x16 1.300 1.200 0.110 1.100 0.100 1.000 0.090 1.00e0 x16 0.500 0.075 0.070 0.450 0.065 0.400 0.060 0.055 0.900 0.350 0.080 0.050 0.800 0.070 0.300 0.045 0.700 0.040 0.060 0.250 0.600 0.035 0.050 0.200 0.030 0.500 0.040 0.025 0.030 0.020 0.400 0.150 0.300 0.100 0.015 0.020 0.200 0.010 0.050 0.010 0.100 -0.000 0.005 -0.000 180.87 180.88 180.89 -0.000 180.90 192.86 M 230.9856 R 11520 192.87 192.88 204.85 M 242.9856 R 11312 230.8 -0.000 192.89 204.86 204.87 x16 218.83 M 218.9856 R 11315 242.8 1.00e0 204.88 218.84 218.85 x16 230.9 1.00e0 x16 0.450 0.650 218.87 M 230.9856 R 11522 218.9 1.00e0 218.86 1.00e0 x16 0.650 0.425 0.180 0.600 0.400 0.600 0.375 0.160 0.550 0.550 0.350 0.500 0.500 0.325 0.140 0.450 0.300 0.450 0.275 0.120 0.400 0.400 0.250 0.350 0.350 0.100 0.225 0.300 0.080 0.200 0.300 0.175 0.250 0.250 0.150 0.060 0.200 0.200 0.125 0.150 0.150 0.100 0.040 0.075 0.100 0.100 0.020 0.050 -0.000 -0.000 0.050 0.050 0.025 -0.000 230.82 230.83 230.84 230.85 230.86 242.81 M 242.9856 R 11628 242.82 242.83 242.84 242.85 218.86 M 254.9856 R 11961 242.9 -0.000 218.87 218.88 x16 230.85 M 268.9824 R 11118 254.8 1.00e0 218.89 230.86 230.87 M 280.9824 R 11012 268.8 1.00e0 x16 230.88 280.8 1.00e0 x16 0.140 1.00e0 x16 0.320 0.180 0.240 0.300 0.130 0.220 0.280 0.160 0.120 0.260 0.200 0.110 0.140 0.180 0.100 0.160 0.090 0.240 0.220 0.120 0.200 0.080 0.140 0.180 0.100 0.070 0.160 0.120 0.140 0.080 0.060 0.100 0.120 0.050 0.060 0.080 0.100 0.040 0.080 0.060 0.040 0.030 0.060 0.040 0.020 0.040 0.020 0.020 0.010 -0.000 -0.000 242.84 242.85 242.86 242.87 242.88 0.020 -0.000 254.83 254.84 254.85 254.86 254.87 -0.000 268.81 268.82 268.83 268.84 268.85 268.86 280.80 280.81 280.82 280.83 280.84 280.85 Resolution Check Report Printed: 571 of 603 Page 2 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 292.9824 R 11427 M 304.9824 R 11317 292.8 M 242.9856 R 11601 304.8 1.00e0 x16 M 254.9856 R 11717 242.9 1.00e0 x16 254.9 1.00e0 x16 1.00e0 x16 0.120 0.085 0.140 0.220 0.080 0.110 0.130 0.075 0.200 0.100 0.120 0.070 0.180 0.110 0.065 0.100 0.060 0.090 0.160 0.080 0.055 0.090 0.140 0.070 0.050 0.080 0.045 0.070 0.120 0.060 0.040 0.100 0.060 0.035 0.050 0.030 0.050 0.080 0.040 0.025 0.040 0.060 0.030 0.040 0.020 0.020 0.030 0.015 0.020 0.010 0.020 0.010 0.010 0.005 -0.000 -0.000 292.79 292.80 292.81 292.82 292.83 292.84 -0.000 304.78 M 268.9824 R 11601 304.79 304.80 304.81 304.82 242.85 M 280.9824 R 11468 268.8 -0.000 304.83 242.86 242.87 x16 242.89 254.84 M 292.9824 R 11375 280.8 1.00e0 242.88 x16 0.375 0.160 0.150 x16 0.110 0.100 0.140 0.300 1.00e0 0.120 0.180 0.325 254.88 304.8 x16 0.170 0.350 254.87 M 304.9824 R 11295 1.00e0 0.180 0.160 254.86 292.8 1.00e0 0.400 0.200 254.85 0.090 0.130 0.140 0.275 0.080 0.120 0.250 0.110 0.120 0.070 0.225 0.100 0.100 0.200 0.090 0.175 0.080 0.150 0.070 0.060 0.050 0.080 0.040 0.060 0.125 0.060 0.050 0.100 0.030 0.040 0.040 0.075 0.020 0.030 0.050 0.020 0.020 0.010 0.025 -0.000 0.010 -0.000 268.82 268.83 268.84 268.85 268.86 268.87 -0.000 280.81 M 316.9824 R 11720 280.82 280.83 280.84 280.85 280.86 M 330.9792 R 11212 316.8 -0.000 292.80 292.81 292.82 x16 292.84 292.85 304.79 M 342.9792 R 10706 330.8 1.00e0 292.83 304.80 304.81 304.82 x16 0.050 304.84 M 280.9824 R 11548 342.8 1.00e0 0.130 304.83 280.9 1.00e0 x16 1.00e0 0.090 0.360 0.085 0.340 x16 0.120 0.080 0.045 0.110 0.100 0.040 0.090 0.035 0.080 0.030 0.320 0.075 0.300 0.070 0.280 0.065 0.260 0.060 0.240 0.055 0.220 0.050 0.200 0.045 0.180 0.040 0.160 0.035 0.140 0.030 0.120 0.025 0.100 0.020 0.080 0.015 0.060 0.070 0.025 0.060 0.050 0.020 0.040 0.015 0.030 0.010 0.020 0.010 0.005 0.040 0.010 0.005 -0.000 -0.000 316.78 316.79 316.80 316.81 316.82 316.83 0.020 -0.000 330.77 330.78 330.79 330.80 330.81 330.82 -0.000 342.76 342.77 342.78 342.79 342.80 342.81 342.82 280.83 280.84 280.85 280.86 280.87 280.88 Resolution Check Report Printed: 572 of 603 Page 3 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 292.9824 R 11417 M 304.9824 R 11746 292.8 M 316.9824 R 11860 304.8 1.00e0 x16 M 330.9792 R 11399 316.8 1.00e0 x16 330.8 1.00e0 x16 1.00e0 x16 0.140 0.055 0.180 0.130 0.180 0.120 0.050 0.110 0.045 0.160 0.160 0.140 0.100 0.140 0.040 0.090 0.120 0.120 0.035 0.080 0.100 0.030 0.070 0.100 0.025 0.060 0.080 0.080 0.050 0.020 0.060 0.060 0.040 0.015 0.030 0.040 0.040 0.010 0.020 0.020 -0.000 -0.000 292.82 292.83 292.84 292.85 292.86 -0.000 292.87 304.81 M 342.9792 R 11424 0.020 0.005 0.010 304.82 304.83 304.84 304.85 316.80 M 354.9792 R 11788 342.8 -0.000 304.86 316.81 316.82 316.83 x16 316.85 330.78 M 366.9792 R 11879 354.8 1.00e0 316.84 330.79 330.80 x16 330.82 330.83 330.84 M 380.9760 R 11573 366.8 1.00e0 330.81 380.8 1.00e0 x16 1.00e0 x16 0.075 0.140 0.080 0.040 0.070 0.075 0.130 0.065 0.120 0.060 0.110 0.055 0.070 0.035 0.065 0.060 0.030 0.100 0.050 0.090 0.045 0.080 0.040 0.070 0.035 0.060 0.030 0.055 0.050 0.025 0.045 0.040 0.020 0.035 0.030 0.015 0.050 0.025 0.040 0.020 0.025 0.020 0.010 0.030 0.015 0.020 0.010 0.010 0.005 -0.000 -0.000 342.77 342.78 342.79 342.80 342.81 342.82 342.83 0.015 0.010 -0.000 -0.000 0.005 354.76 M 392.9760 R 11520 0.005 354.77 354.78 354.79 354.80 354.81 354.82 366.75 M 404.9760 R 10823 392.8 366.76 366.77 366.78 x16 0.060 366.80 366.81 380.74 M 416.9760 R 11908 404.8 1.00e0 366.79 380.75 380.76 x16 0.032 0.017 380.79 380.80 316.8 1.00e0 0.018 380.78 M 316.9824 R 11415 416.8 1.00e0 0.034 380.77 x16 1.00e0 x16 0.050 0.016 0.030 0.055 0.015 0.028 0.050 0.040 0.013 0.024 0.045 0.045 0.014 0.026 0.012 0.022 0.035 0.040 0.011 0.020 0.010 0.035 0.030 0.018 0.009 0.030 0.016 0.025 0.008 0.014 0.025 0.007 0.020 0.012 0.006 0.020 0.010 0.015 0.005 0.008 0.015 0.004 0.006 0.003 0.004 0.002 0.002 0.001 0.010 0.010 0.005 0.005 -0.000 -0.000 392.73 392.74 392.75 392.76 392.77 392.78 392.79 392.80 -0.000 404.73 404.74 404.75 404.76 404.77 404.78 404.79 404.80 416.72 416.73 416.74 416.75 416.76 416.77 416.78 416.79 416.80 -0.000 316.78 316.79 316.80 316.81 316.82 316.83 316.84 Resolution Check Report Printed: 573 of 603 Page 4 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 330.9792 R 10964 M 342.9792 R 11765 330.8 M 354.9792 R 11187 342.8 1.00e0 x16 M 366.9792 R 11482 354.8 1.00e0 x16 366.8 1.00e0 x16 1.00e0 x16 0.075 0.150 0.170 0.050 0.160 0.070 0.140 0.150 0.130 0.065 0.120 0.060 0.110 0.055 0.100 0.050 0.090 0.045 0.090 0.080 0.040 0.080 0.070 0.035 0.070 0.060 0.030 0.050 0.025 0.040 0.020 0.030 0.015 0.020 0.010 0.140 0.045 0.040 0.130 0.120 0.035 0.110 0.100 0.060 0.030 0.025 0.020 0.050 0.015 0.040 0.010 0.030 0.020 0.005 0.010 0.010 -0.000 0.005 -0.000 330.77 330.78 330.79 330.80 330.81 330.82 342.76 M 380.9760 R 11186 342.77 342.78 342.79 342.80 -0.000 354.74 342.81 M 392.9760 R 11378 380.7 -0.000 354.75 354.76 354.77 x16 354.79 354.80 354.81 M 404.9760 R 11235 392.7 1.00e0 354.78 366.73 366.74 366.75 366.76 x16 366.78 366.79 366.80 M 416.9760 R 11174 404.7 1.00e0 366.77 416.7 1.00e0 x16 1.00e0 x16 0.085 0.110 0.028 0.050 0.080 0.026 0.100 0.075 0.045 0.024 0.070 0.090 0.065 0.022 0.040 0.080 0.060 0.020 0.035 0.055 0.070 0.018 0.050 0.060 0.030 0.016 0.045 0.014 0.025 0.040 0.050 0.012 0.035 0.020 0.040 0.030 0.010 0.025 0.015 0.030 0.008 0.020 0.006 0.020 0.010 0.015 0.004 0.010 0.005 0.010 0.002 0.005 -0.000 -0.000 380.72 380.73 380.74 380.75 380.76 380.77 -0.000 380.78 392.71 M 430.9728 R 11476 392.72 392.73 392.74 392.75 392.76 392.77 404.69 M 442.9728 R 11163 430.7 -0.000 404.70 404.71 404.72 x16 404.74 404.75 404.76 416.68 M 380.9760 R 11287 442.7 1.00e0 404.73 416.69 416.70 416.71 x16 416.73 416.74 416.75 M 392.9760 R 11340 380.7 1.00e0 416.72 392.7 1.00e0 x16 1.00e0 x16 0.036 0.050 0.085 0.034 0.100 0.080 0.032 0.045 0.075 0.090 0.030 0.070 0.040 0.028 0.080 0.065 0.026 0.035 0.060 0.024 0.070 0.055 0.022 0.030 0.050 0.060 0.020 0.045 0.018 0.025 0.050 0.040 0.016 0.020 0.035 0.014 0.040 0.030 0.012 0.015 0.010 0.025 0.030 0.020 0.008 0.010 0.020 0.006 0.015 0.010 0.004 0.005 0.010 0.005 0.002 -0.000 -0.000 430.67 430.68 430.69 430.70 430.71 430.72 430.73 430.74 -0.000 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 -0.000 380.70 380.71 380.72 380.73 380.74 380.75 380.76 380.77 392.69 392.70 392.71 392.72 392.73 392.74 392.75 392.76 Resolution Check Report Printed: 574 of 603 Page 5 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 404.9760 R 11765 M 416.9760 R 11990 404.7 M 430.9728 R 11174 416.7 1.00e0 x16 M 442.9728 R 11086 430.7 1.00e0 x16 0.060 442.7 1.00e0 x16 1.00e0 x16 0.055 0.060 0.040 0.055 0.050 0.035 0.045 0.055 0.050 0.050 0.045 0.045 0.040 0.030 0.040 0.040 0.035 0.025 0.035 0.035 0.030 0.030 0.030 0.020 0.025 0.025 0.025 0.020 0.015 0.020 0.020 0.015 0.015 0.015 0.010 0.010 0.010 0.010 0.005 0.005 0.005 0.005 -0.000 -0.000 404.68 404.69 404.70 404.71 404.72 404.73 404.74 -0.000 404.75 416.67 M 454.9728 R 11171 416.68 416.69 416.70 416.71 416.72 416.73 416.74 430.65 M 466.9728 R 12194 454.7 430.66 430.67 430.68 x16 430.70 430.71 -0.000 442.63 430.72 M 480.9696 R 11753 466.7 1.00e0 430.69 442.64 442.65 442.66 442.67 x16 442.69 442.70 442.71 M 430.9728 R 11116 480.6 1.00e0 0.028 442.68 430.7 1.00e0 x16 1.00e0 x16 0.036 0.060 0.050 0.034 0.026 0.055 0.032 0.024 0.045 0.030 0.050 0.022 0.028 0.020 0.026 0.040 0.045 0.024 0.035 0.040 0.018 0.022 0.016 0.030 0.035 0.020 0.014 0.018 0.030 0.025 0.016 0.012 0.025 0.014 0.020 0.010 0.012 0.015 0.008 0.010 0.006 0.008 0.020 0.015 0.010 0.006 0.010 0.004 0.004 0.005 0.005 0.002 -0.000 0.002 -0.000 454.62 454.63 454.64 454.65 454.66 454.67 454.68 454.69 454.70 -0.000 466.61 M 442.9728 R 11717 466.62 466.63 466.64 466.65 466.66 466.67 466.68 466.69 M 454.9728 R 11627 442.7 -0.000 480.59 480.60 480.61 480.62 480.63 x16 480.65 480.66 480.67 480.68 M 466.9728 R 12498 454.7 1.00e0 480.64 x16 0.050 0.045 430.69 430.70 430.71 430.72 430.73 430.74 430.75 M 480.9696 R 11221 480.7 1.00e0 x16 0.036 0.050 430.68 466.7 1.00e0 0.055 430.67 1.00e0 x16 0.040 0.034 0.032 0.035 0.030 0.045 0.028 0.040 0.030 0.026 0.040 0.035 0.024 0.035 0.025 0.022 0.030 0.020 0.030 0.018 0.025 0.020 0.016 0.025 0.014 0.020 0.020 0.015 0.012 0.015 0.010 0.015 0.010 0.008 0.010 0.010 0.006 0.005 0.005 -0.000 -0.000 0.005 0.004 0.002 442.66 442.67 442.68 442.69 442.70 442.71 442.72 442.73 442.74 454.65 454.66 454.67 454.68 454.69 454.70 454.71 454.72 454.73 -0.000 466.63 -0.000 466.64 466.65 466.66 466.67 466.68 466.69 466.70 466.71 466.72 480.62 480.63 480.64 480.65 480.66 480.67 480.68 480.69 480.70 Resolution Check Report Printed: 575 of 603 Page 6 of 6 MassLynx 4.1 SCN 881 Saturday, December 21, 2013 05:30:04 Eastern Standard Time M 492.9696 R 10752 M 504.9696 R 11338 492.7 M 516.9697 R 11848 504.6 1.00e0 x16 516.6 1.00e0 x16 1.00e0 x16 0.040 0.022 0.035 0.020 0.035 0.018 0.030 0.030 0.016 0.025 0.025 0.014 0.012 0.020 0.020 0.015 0.015 0.010 0.010 0.005 0.005 0.010 0.008 0.006 0.004 0.002 -0.000 -0.000 492.61 492.62 492.63 492.64 492.65 492.66 492.67 492.68 492.69 -0.000 504.59 504.60 504.61 504.62 504.63 504.64 504.65 504.66 504.67 504.68 516.58 516.59 516.60 516.61 516.62 516.63 516.64 516.65 516.66 516.67 576 of 603 Lab ID: OPR1_11906_PCB ACQ: 02-Apr-2014 00:23:43 LKB Wt/Vol: 1 µL Client ID: 0_11906_OPR001 UTP: 05-Apr-2014 00:19 CEM J-level: 10 pg/uL Datafile: 140402X02 RPT: 06-Apr-2014 16:10 CM Stds (pg): JS: 100 ES: 100 CS/SS: 100 Name Actual RT PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-189 233'44'55'-HpCB PCB-209 DeCB 32.70 32.23 35.68 35.14 34.67 34.39 38.29 40.83 39.85 43.55 45.67 50.72 ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES ES 11.84 14.12 14.36 20.06 17.43 26.37 20.33 32.68 32.21 25.29 35.66 35.12 34.65 34.37 38.27 36.23 30.23 40.81 39.83 43.53 43.04 41.97 35.11 45.65 39.64 47.81 49.27 45.27 50.69 PCB-1 PCB-3 PCB-4 PCB-15 PCB-19 PCB-37 PCB-54 PCB-77 PCB-81 PCB-104 PCB-105 PCB-114 PCB-118 PCB-123 PCB-126 PCB-153 PCB-155 PCB-156/157 PCB-167 PCB-169 PCB-170 PCB-180 PCB-188 PCB-189 PCB-202 PCB-205 PCB-206 PCB-208 PCB-209 SGS Evironmental Services QC C ICAL: MM7_PCB_10292013_20DEC2013 CS3_140402_PCB_XA Split: 1 Checkcode: 758-213-CJP Method 1668A Pred RRT Actual RRT Diff Secs Response Ra RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.0006 1.0005 1.0007 1.0006 1.0007 1.0007 1.0005 1.0005 1.0006 1.0004 1.0004 1.0000 1.0006 1.0006 1.0007 1.0007 1.0006 1.0006 1.0005 1.0005 1.0006 1.0004 1.0004 1.0004 0 +0.2 0 +0.2 -0.2 -0.2 0 0 0 0 0 +1.2 7.41E+06 7.33E+06 5.87E+06 6.32E+06 6.11E+06 6.29E+06 5.42E+06 9.39E+06 5.30E+06 4.29E+06 4.32E+06 2.72E+06 0.79 0.78 0.60 0.62 0.61 0.61 0.62 1.21 1.21 1.28 1.08 1.19 1.15 1.12 1.11 1.20 1.19 1.21 1.11 1.10 1.16 1.12 1.07 1.11 47.5 50 47.4 47.3 46.3 46.4 51.4 94.1 46.6 45.8 49.6 47.2 9.80E+03 9.80E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 2.84E+03 3.27E+03 3.27E+03 3.27E+03 2.40E+03 1.24E+03 0.622 0.652 0.536 0.481 0.489 0.467 0.296 0.464 0.306 0.354 0.296 0.237 0.7244 0.8640 0.8793 1.2279 1.0674 1.0793 0.8322 1.3381 1.3186 0.8317 1.1729 1.1551 1.1398 1.1306 1.2588 0.9715 0.8106 1.0943 1.0679 1.1671 0.9078 0.8852 0.7404 0.9628 0.8361 1.0084 1.0393 0.9547 1.0692 0.7247 0.8643 0.8793 1.2281 1.0672 1.0795 0.8323 1.3382 1.3186 0.8318 1.1728 1.1550 1.1397 1.1305 1.2588 0.9715 0.8106 1.0944 1.0679 1.1672 0.9078 0.8853 0.7405 0.9628 0.8361 1.0085 1.0393 0.9547 1.0693 +0.2 +0.3 0 +0.2 -0.2 +0.3 +0.1 +0.2 0 +0.2 -0.2 -0.2 -0.2 -0.2 0 0 0 +0.2 0 +0.3 0 +0.3 +0.2 0 0 +0.3 0 0 +0.3 2.01E+07 1.80E+07 1.01E+07 1.96E+07 8.92E+06 1.57E+07 8.98E+06 1.36E+07 1.31E+07 8.68E+06 1.11E+07 1.11E+07 1.11E+07 1.12E+07 9.54E+06 7.97E+06 1.11E+07 1.82E+07 9.79E+06 8.33E+06 5.37E+06 6.79E+06 7.72E+06 8.11E+06 7.04E+06 5.75E+06 4.06E+06 6.46E+06 5.18E+06 3.40 3.49 1.65 1.59 1.07 1.19 0.77 0.79 0.82 1.59 1.61 1.57 1.61 1.56 1.63 1.29 1.27 1.26 1.29 1.25 1.13 1.07 1.10 1.01 0.92 0.85 0.84 0.80 1.17 1.19 1.09 0.52 1.04 0.51 1.66 0.86 1.38 1.37 0.80 1.20 1.22 1.16 1.19 1.03 1.11 1.59 1.60 1.67 1.56 0.95 1.14 0.94 1.58 0.97 1.24 0.83 1.17 1.11 91.6 % 89.9 % 105 % 103 % 95.8 % 93 % 103 % 96.5 % 94.3 % 117 % 100 % 98.6 % 104 % 102 % 100 % 98.4 % 95.3 % 77.6 % 80.1 % 73.1 % 95.9 % 102 % 112 % 99.8 % 99.1 % 90.1 % 95.4 % 107 % 90.8 % 15% 15% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% 140% Page 1 of 5 Printed: 4/6/2014 5:19 PM 577 of 603 Name Actual RT SS PCB-28 SS PCB-111 SS PCB-178 22.81 32.69 37.67 0.9337 1.0754 1.0101 0.9338 1.0753 1.0100 +0.1 -0.2 -0.2 1.61E+07 1.14E+07 4.74E+06 1.15 1.57 1.13 1.11 1.03 0.62 92.1 % 98.5 % 99.1 % 40% 40% 40% 125% 125% 125% CS PCB-28 CS PCB-111 CS PCB-178 22.81 32.69 37.67 0.9337 1.0754 1.0101 0.9338 1.0753 1.0100 +0.1 -0.2 -0.2 1.61E+07 1.14E+07 4.74E+06 1.15 1.57 1.13 1.85 1.22 0.58 85.7 % 101 % 111 % 40% 40% 40% 125% 125% 125% JS JS JS JS JS 16.33 24.43 30.40 37.29 47.41 1.84E+07 1.02E+07 9.24E+06 7.33E+06 5.14E+06 1.57 0.82 1.59 1.33 0.89 4.79E+03 4.79E+03 4.79E+03 1.13E+04 1.13E+04 1.05E+04 1.05E+04 1.05E+04 1.05E+04 1.05E+04 1.05E+04 1.05E+04 1.05E+04 1.05E+04 7.30E+03 7.30E+03 7.30E+03 7.30E+03 7.30E+03 7.30E+03 0.168 0.179 0.209 0.657 0.423 0.506 0.441 0.474 0.47 0.46 0.398 0.463 0.46 0.482 0.574 0.426 0.505 0.366 0.372 0.691 PCB-9 PCB-52 PCB-101 PCB-138 PCB-194 QC Pred RRT Actual RRT Diff Secs Response Ra Totals Mono-CBs Di-CBs Tri-CBs Tetra-CBs Penta-CBs Hexa-CBs Hepta-CBs Octa-CBs Nona-CBs PCB-1 2-MoCB PCB-2 3-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-10 26-DiCB PCB-9 25-DiCB PCB-7 24-DiCB PCB-6 23'-DiCB PCB-5 23-DiCB PCB-8 24'-DiCB PCB-14 35-DiCB PCB-11 33'-DiCB PCB-13/12 34'/34-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-30/18 246/22'5-TrCB PCB-17 22'4-TrCB PCB-27 23'6-TrCB PCB-24 236-TrCB PCB-16 22'3-TrCB SGS Evironmental Services 11.85 13.95 14.13 14.38 14.56 16.35 16.51 16.74 17.04 17.16 18.71 19.49 19.79 20.07 17.45 19.20 19.60 19.79 19.93 20.03 C C 1.0011 0.9880 1.0009 1.0011 1.0135 1.0010 1.0111 1.0250 1.0435 1.0507 0.9331 0.9720 0.9866 1.0008 1.0010 1.1017 1.1247 1.1357 1.1435 1.1489 1.0011 0.9881 1.0010 1.0011 1.0136 1.0010 1.0111 1.0250 1.0434 1.0507 0.9330 0.9720 0.9866 1.0007 1.0010 1.1015 1.1245 1.1356 1.1433 1.1489 0 +0.1 +0.1 0 +0.1 0 0 0 -0.1 0 -0.1 0 0 -0.1 0 -0.2 -0.2 -0.1 -0.2 0 Page 2 of 5 NON-EMPC 160 560 1,130 2,010 2,110 1,990 1,150 572 143 1.06E+07 1.04E+07 1.02E+07 5.67E+06 9.43E+06 8.70E+06 9.95E+06 9.38E+06 9.42E+06 9.63E+06 1.13E+07 9.62E+06 1.95E+07 1.03E+07 4.81E+06 1.35E+07 5.82E+06 8.08E+06 7.79E+06 4.33E+06 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High EMPC 160 560 1,130 2,010 2,110 1,990 1,150 572 143 3.28 3.26 3.30 1.56 1.56 1.60 1.60 1.64 1.61 1.59 1.62 1.63 1.65 1.62 1.05 1.05 1.03 1.07 1.06 1.05 0.95 1.18 1.01 1.23 1.92 0.97 1.11 1.04 1.04 1.07 1.24 1.06 1.07 1.02 1.15 1.55 1.30 1.80 1.77 0.95 DL 0.189 0.57 0.609 0.413 0.403 0.306 0.402 0.272 0.504 55.2 49.2 56.1 45.6 48.8 45.6 45.5 46.1 45.9 45.9 46.5 46.1 93.1 51.4 47 98.1 50.1 50.4 49.4 51 Printed: 4/6/2014 5:19 PM 578 of 603 Name Actual RT PCB-32 24'6-TrCB PCB-34 23'5'-TrCB PCB-23 235-TrCB PCB-26/29 23'5/245-TrCB PCB-25 23'4-TrCB PCB-31 24'5-TrCB PCB-28/20 244'/233'-TrCB PCB-21/33 234/23'4'-TrCB PCB-22 234'-TrCB PCB-36 33'5-TrCB PCB-39 34'5-TrCB PCB-38 345-TrCB PCB-35 33'4-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-50/53 22'46/22'56'-TeCB PCB-45 22'36-TeCB PCB-51 22'46'-TeCB PCB-46 22'36'-TeCB PCB-52 22'55'-TeCB PCB-73 23'5'6-TeCB PCB-43 22'35-TeCB PCB-69/49 23'46/22'45'-TeCB PCB-48 22'45-TeCB PCB-44/47/65 ...-TeCB PCB-59/62/75 ...-TeCB PCB-42 22'34'-TeCB PCB-41 22'34-TeCB PCB-71/40 23'4'6/22'33'-TeCB PCB-64 234'6-TeCB PCB-72 23'55'-TeCB PCB-68 23'45'-TeCB PCB-57 233'5-TeCB PCB-58 233'5'-TeCB PCB-67 23'45-TeCB PCB-63 234'5-TeCB PCB-61/70/74/76 ...-TeCB PCB-66 23'44'-TeCB PCB-55 233'4-TeCB PCB-56 233'4'-TeCB PCB-60 2344'-TeCB PCB-80 33'55'-TeCB PCB-79 33'45'-TeCB PCB-78 33'45-TeCB PCB-104 22'466'-PeCB PCB-96 22'366'-PeCB PCB-103 22'45'6-PeCB PCB-94 22'356'-PeCB 20.50 21.65 21.80 22.08 22.28 22.56 22.84 23.02 23.40 24.78 25.10 25.63 26.03 26.39 20.35 22.33 22.91 22.99 23.20 24.45 24.57 24.67 24.87 25.15 25.37 25.64 25.81 26.14 26.23 26.43 27.15 27.40 27.78 27.98 28.14 28.36 28.65 28.94 29.08 29.52 29.71 30.03 31.36 31.85 25.31 25.63 27.32 27.51 SGS Evironmental Services QC C C C C C C C C C Pred RRT Actual RRT Diff Secs Response Ra 1.1763 0.8211 0.8268 0.8375 0.8451 0.8556 0.8663 0.8732 0.8875 0.9397 0.9520 0.9721 0.9871 1.0008 1.0010 0.9141 0.9381 0.9410 0.9497 1.0009 1.0062 1.0102 1.0181 1.0296 1.0385 1.0498 1.0566 1.0702 1.0741 1.0823 0.8429 0.8509 0.8624 0.8687 0.8736 0.8806 0.8897 0.8984 0.9030 0.9165 0.9225 0.9326 0.9737 0.9888 1.0009 1.0135 0.8985 0.9048 1.1762 0.8210 0.8267 0.8375 0.8450 0.8556 0.8663 0.8731 0.8874 0.9397 0.9520 0.9720 0.9870 1.0008 1.0010 0.9141 0.9381 0.9411 0.9497 1.0009 1.0061 1.0100 1.0181 1.0296 1.0385 1.0498 1.0565 1.0702 1.0741 1.0822 0.8429 0.8508 0.8624 0.8688 0.8736 0.8805 0.8896 0.8984 0.9030 0.9165 0.9225 0.9325 0.9737 0.9888 1.0009 1.0135 0.8985 0.9048 -0.1 -0.1 -0.1 0 -0.1 0 0 -0.1 -0.1 0 0 -0.2 -0.2 0 0 0 0 +0.1 0 0 -0.1 -0.3 0 0 0 0 -0.2 0 0 -0.2 0 -0.2 0 +0.2 0 -0.2 -0.2 0 0 0 0 -0.2 0 0 0 0 0 0 8.56E+06 8.65E+06 8.91E+06 1.81E+07 9.46E+06 9.37E+06 1.75E+07 1.86E+07 8.67E+06 9.43E+06 9.71E+06 8.79E+06 8.42E+06 8.91E+06 5.60E+06 1.04E+07 4.44E+06 5.36E+06 4.20E+06 5.08E+06 6.87E+06 4.52E+06 1.28E+07 5.24E+06 1.69E+07 2.19E+07 4.89E+06 4.38E+06 1.10E+07 7.87E+06 7.67E+06 8.29E+06 7.50E+06 7.69E+06 7.99E+06 8.31E+06 3.06E+07 7.40E+06 7.41E+06 7.35E+06 7.37E+06 8.61E+06 8.62E+06 7.06E+06 5.55E+06 4.91E+06 4.81E+06 4.12E+06 1.03 1.03 1.02 1.01 0.99 0.99 0.99 1.00 1.00 1.00 1.04 1.02 1.01 1.01 0.80 0.78 0.78 0.78 0.83 0.78 0.77 0.81 0.79 0.79 0.80 0.79 0.80 0.77 0.78 0.78 0.80 0.81 0.81 0.81 0.80 0.79 0.80 0.78 0.79 0.81 0.80 0.81 0.80 0.79 0.64 0.64 0.62 0.62 Page 3 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.93 1.24 1.25 1.27 1.31 1.32 1.23 1.29 1.19 1.34 1.34 1.21 1.16 1.08 1.35 0.85 0.70 0.90 0.68 0.83 1.16 0.68 1.03 0.85 0.90 1.18 0.76 0.67 0.87 1.24 1.25 1.32 1.19 1.21 1.29 1.34 1.22 1.16 1.15 1.15 1.16 1.35 1.40 1.12 1.43 1.19 0.96 0.80 49.7 44.6 45.2 90.6 46.1 45 90.5 92 46.5 44.8 46.1 46.4 46.1 52.6 46.1 92.9 48.2 45.5 47.1 46.5 45.3 50.7 94.6 47.2 143 142 48.7 49.7 96.1 48.3 47 48.1 48.1 48.3 47.4 47.2 191 48.8 49 49 48.3 48.6 47 48 44.6 47.6 44.9 45.9 7.30E+03 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 1.08E+04 2.91E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 3.29E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 9.80E+03 1.97E+03 1.97E+03 6.14E+03 6.14E+03 0.341 0.562 0.554 0.547 0.532 0.524 0.564 0.54 0.585 0.518 0.518 0.576 0.598 0.644 0.213 0.287 0.348 0.272 0.36 0.293 0.211 0.36 0.237 0.289 0.271 0.208 0.32 0.364 0.281 0.197 0.585 0.554 0.612 0.601 0.566 0.543 0.598 0.63 0.632 0.637 0.626 0.54 0.521 0.649 0.149 0.179 0.591 0.705 Printed: 4/6/2014 5:19 PM 579 of 603 Name Actual RT PCB-95 22'35'6-PeCB PCB-100/93 22'44'6/22'356-PeCB PCB-102 22'456'-PeCB PCB-98 22'34'6'-PeCB PCB-88 22'346-PeCB PCB-91 22'34'6-PeCB PCB-84 22'33'6-PeCB PCB-89 22'346'-PeCB PCB-121 23'45'6-PeCB PCB-92 22'355'-PeCB PCB-113/90/101 ...-PeCB PCB-83 22'33'5-PeCB PCB-99 22'44'5-PeCB PCB-112 233'56-PeCB PCB-108/119/86/97/125...-PeCB PCB-117 234'56-PeCB PCB-116/85 23456/22'344'-PeCB PCB-110 233'4'6-PeCB PCB-115 2344'6-PeCB PCB-82 22'33'4-PeCB PCB-111 233'55'-PeCB PCB-120 23'455'-PeCB PCB-107/124 ...-PeCB PCB-109 233'46-PeCB PCB-106 233'45-PeCB PCB-122 233'4'5'-PeCB PCB-127 33'455'-PeCB PCB-155 22'44'66'-HxCB PCB-152 22'3566'-HxCB PCB-150 22'34'66'-HxCB PCB-136 22'33'66'-HxCB PCB-145 22'3466'-HxCB PCB-148 22'34'56'-HxCB PCB-151/135 ...-HxCB PCB-154 22'44'56'-HxCB PCB-144 22'345'6-HxCB PCB-147/149 ...-HxCB PCB-134 22'33'56-HxCB PCB-143 22'3456'-HxCB PCB-139/140 ...-HxCB PCB-131 22'33'46-HxCB PCB-142 22'3456-HxCB PCB-132 22'33'46'-HxCB PCB-133 22'33'55'-HxCB PCB-165 233'55'6-HxCB PCB-146 22'34'55'-HxCB PCB-161 233'45'6-HxCB PCB-153/168 ...-HxCB 27.89 28.10 28.21 28.28 28.58 28.64 28.84 29.26 29.60 29.92 30.40 30.84 30.93 31.03 31.38 31.91 32.00 32.12 32.20 32.40 32.71 33.11 34.08 34.28 34.50 34.97 36.91 30.25 30.42 30.56 30.87 31.13 32.40 32.93 33.13 33.40 33.70 33.88 33.96 34.22 34.39 34.54 34.77 35.17 35.52 35.73 35.85 36.27 SGS Evironmental Services QC C C C C C C C C C Pred RRT Actual RRT Diff Secs Response Ra 0.9173 0.9243 0.9278 0.9301 0.9402 0.9423 0.9486 0.9623 0.9735 0.9840 0.9999 1.0144 1.0175 1.0208 1.0321 1.0496 1.0527 1.0566 1.0594 1.0659 1.0761 1.0892 0.9915 0.9975 1.0039 1.0091 1.0351 1.0007 1.0062 1.0108 1.0210 1.0299 1.0719 1.0891 1.0960 1.1048 1.1148 1.1205 1.1231 1.1319 1.1377 1.1425 1.1502 1.1636 0.9523 0.9580 0.9612 0.9727 0.9173 0.9242 0.9279 0.9302 0.9400 0.9421 0.9486 0.9623 0.9735 0.9840 0.9999 1.0143 1.0173 1.0207 1.0321 1.0497 1.0527 1.0564 1.0592 1.0658 1.0760 1.0891 0.9915 0.9974 1.0039 1.0091 1.0352 1.0007 1.0062 1.0109 1.0210 1.0299 1.0719 1.0891 1.0960 1.1047 1.1147 1.1206 1.1232 1.1319 1.1376 1.1424 1.1502 1.1635 0.9523 0.9580 0.9612 0.9727 0 -0.2 +0.2 +0.2 -0.3 -0.3 0 0 0 0 0 -0.2 -0.4 -0.2 0 +0.2 0 -0.4 -0.4 -0.2 -0.2 -0.2 0 -0.2 0 0 +0.2 0 0 +0.2 0 0 0 0 0 -0.2 -0.2 +0.2 +0.2 0 -0.2 -0.2 0 -0.2 0 0 0 0 4.43E+06 8.61E+06 5.13E+06 4.11E+06 3.64E+06 5.07E+06 3.71E+06 4.01E+06 6.25E+06 4.28E+06 1.49E+07 3.66E+06 4.62E+06 6.21E+06 3.00E+07 5.94E+06 9.48E+06 5.68E+06 6.36E+06 3.56E+06 6.41E+06 6.33E+06 1.14E+07 6.33E+06 5.88E+06 5.28E+06 5.80E+06 6.14E+06 5.87E+06 5.88E+06 5.50E+06 5.59E+06 4.16E+06 8.02E+06 4.61E+06 4.21E+06 8.22E+06 3.34E+06 3.90E+06 8.31E+06 3.62E+06 3.55E+06 3.62E+06 3.90E+06 5.03E+06 4.28E+06 5.39E+06 1.04E+07 0.62 0.61 0.62 0.64 0.62 0.61 0.63 0.63 0.60 0.61 0.61 0.62 0.62 0.62 0.61 0.61 0.63 0.61 0.62 0.61 0.63 0.61 0.62 0.61 0.63 0.62 0.63 1.28 1.29 1.26 1.27 1.27 1.26 1.28 1.25 1.26 1.25 1.29 1.27 1.29 1.27 1.30 1.27 1.26 1.29 1.21 1.29 1.25 Page 4 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 0.87 0.87 0.86 0.89 0.81 0.91 0.72 0.77 1.22 0.83 0.97 0.73 0.91 1.17 0.99 1.08 0.99 1.13 1.18 0.69 1.23 1.23 1.11 1.28 1.11 1.01 1.11 1.26 1.08 1.11 1.02 1.04 1.10 1.05 1.24 1.09 1.09 0.79 1.08 1.11 0.93 0.92 0.96 1.02 1.32 1.14 1.41 1.40 45.5 88.1 53.4 41.4 40.3 49.6 45.7 46.4 45.6 46.3 136 44.8 45.5 47.2 270 49.1 85.2 44.9 48 45.7 46.7 45.8 91.7 44.2 47.3 47.1 47 43.9 49.1 47.6 48.8 48.4 47.5 95.5 46.5 48.6 94.6 53.4 45.2 94 48.6 48.6 47.5 47.8 47.9 47.1 48 93.7 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 6.14E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 0.651 0.648 0.659 0.639 0.7 0.62 0.782 0.733 0.462 0.686 0.581 0.776 0.624 0.482 0.571 0.524 0.57 0.502 0.479 0.814 0.461 0.458 0.509 0.443 0.509 0.573 0.537 0.0983 0.115 0.111 0.122 0.119 0.176 0.184 0.156 0.179 0.178 0.247 0.179 0.175 0.208 0.212 0.203 0.19 0.147 0.17 0.137 0.139 Printed: 4/6/2014 5:19 PM 580 of 603 Name Actual RT PCB-141 22'3455'-HxCB PCB-130 22'33'45'-HxCB PCB-137 22'344'5-HxCB PCB-164 233'4'5'6-HxCB PCB-163/138/129 ...-HxCB PCB-160 233'456-HxCB PCB-158 233'44'6-HxCB PCB-128/166 ...-HxCB PCB-159 233'455'-HxCB PCB-162 233'4'55'-HxCB PCB-188 22'34'566'-HpCB PCB-179 22'33'566'-HpCB PCB-184 22'344'66'-HpCB PCB-176 22'33'466'-HpCB PCB-186 22'34566'-HpCB PCB-178 22'33'55'6-HpCB PCB-175 22'33'45'6-HpCB PCB-187 22'34'55'6-HpCB PCB-182 22'344'56'-HpCB PCB-183 22'344'5'6-HpCB PCB-185 22'3455'6-HpCB PCB-174 22'33'456'-HpCB PCB-177 22'33'45'6'-HpCB PCB-181 22'344'56-HpCB PCB-171/173 ...-HpCB PCB-172 22'33'455'-HpCB PCB-192 233'455'6-HpCB PCB-180/193 ...-HpCB PCB-191 233'44'5'6-HpCB PCB-170 22'33'44'5-HpCB PCB-190 233'44'56-HpCB PCB-202 22'33'55'66'-OcCB PCB-201 22'33'45'66'-OcCB PCB-204 22'344'566'-OcCB PCB-197 22'33'44'66'-OcCB PCB-200 22'33'4566'-OcCB PCB-198/199 ...-OcCB PCB-196 22'33'44'56'-OcCB PCB-203 22'344'55'6-OcCB PCB-195 22'33'44'56-OcCB PCB-194 22'33'44'55'-OcCB PCB-205 233'44'55'6-OcCB PCB-208 22'33'455'66'-NoCB PCB-207 22'33'44'566'-NoCB PCB-206 22'33'44'55'6-NoCB 36.42 36.77 36.96 37.05 37.34 37.47 37.66 38.39 39.20 39.44 35.13 35.41 35.87 36.16 36.56 37.69 38.23 38.46 38.64 38.98 39.07 39.18 39.56 39.90 40.09 41.44 41.68 41.96 42.29 43.06 43.51 39.66 40.44 41.02 41.21 41.31 43.62 44.20 44.37 45.49 47.43 47.83 45.29 46.07 49.29 SGS Evironmental Services QC C C C C C Pred RRT Actual RRT Diff Secs Response Ra 0.9766 0.9859 0.9912 0.9934 1.0011 1.0049 1.0097 0.9639 0.9843 0.9903 1.0006 1.0087 1.0217 1.0302 1.0415 1.0736 1.0891 1.0956 1.1007 1.1105 1.1129 1.1160 1.1268 1.1366 1.1419 0.9077 0.9131 0.9191 0.9264 0.9433 0.9531 1.0005 1.0203 1.0348 1.0396 1.0419 1.1005 1.1150 1.1192 0.9515 0.9921 1.0004 1.0005 1.0179 1.0004 0.9765 0.9859 0.9911 0.9933 1.0011 1.0048 1.0097 0.9640 0.9843 0.9903 1.0006 1.0087 1.0217 1.0301 1.0415 1.0736 1.0891 1.0956 1.1006 1.1104 1.1129 1.1161 1.1267 1.1366 1.1419 0.9077 0.9131 0.9192 0.9264 0.9433 0.9532 1.0006 1.0203 1.0349 1.0397 1.0420 1.1005 1.1150 1.1193 0.9514 0.9921 1.0004 1.0005 1.0178 1.0004 -0.2 0 -0.2 -0.2 0 -0.2 0 +0.2 0 0 0 0 0 -0.2 0 0 0 0 -0.2 -0.2 0 +0.2 -0.2 0 0 0 0 +0.3 0 0 +0.3 +0.2 0 +0.2 +0.2 +0.2 0 0 +0.3 -0.3 0 0 0 -0.3 0 3.89E+06 3.43E+06 4.02E+06 5.52E+06 1.26E+07 5.01E+06 5.74E+06 8.02E+06 4.91E+06 5.07E+06 4.31E+06 4.13E+06 3.91E+06 4.33E+06 4.00E+06 2.82E+06 3.64E+06 3.75E+06 3.91E+06 3.77E+06 3.69E+06 3.18E+06 3.01E+06 3.55E+06 6.19E+06 3.19E+06 4.21E+06 7.95E+06 4.32E+06 2.91E+06 4.12E+06 3.41E+06 3.73E+06 3.55E+06 4.00E+06 3.42E+06 4.69E+06 2.50E+06 2.55E+06 2.13E+06 2.34E+06 2.84E+06 3.44E+06 3.59E+06 2.15E+06 1.27 1.22 1.27 1.29 1.27 1.28 1.30 1.21 1.20 1.21 1.05 1.10 1.06 1.03 1.06 1.08 1.08 1.04 1.04 1.03 1.03 1.01 1.08 1.02 1.07 1.02 1.01 1.07 1.02 1.05 1.03 0.91 0.87 0.90 0.95 0.92 0.92 0.94 0.90 0.90 0.91 0.89 0.79 0.79 0.76 Page 5 of 5 RRF Conc. / Recv. Noise / Recv. Low DL / Recv. High 1.02 0.90 1.14 1.38 1.13 1.29 1.52 0.88 1.07 1.09 1.27 1.07 1.03 1.14 1.05 0.75 1.08 1.16 1.20 1.24 1.04 1.00 0.93 1.08 0.95 0.98 1.30 1.24 1.39 1.12 1.57 1.05 1.12 1.05 1.12 1.06 0.72 0.75 0.77 0.73 0.81 1.06 1.12 1.15 1.11 48 47.9 44.4 50.1 140 48.6 47.5 92.6 46.7 47.8 43.9 50.1 49.2 49.4 49.1 48.5 49.6 47.8 47.8 44.9 52.3 46.9 47.5 48.3 96 48 47.7 94.3 45.7 48.4 48.9 46 47.5 48.1 50.7 45.7 93 47 46.7 50.8 50.1 46.6 47.4 48.5 47.5 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 1.46E+03 3.27E+03 3.27E+03 3.27E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 1.34E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 3.93E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.43E+03 1.90E+03 1.90E+03 1.90E+03 2.81E+03 2.81E+03 2.81E+03 0.191 0.216 0.171 0.14 0.172 0.15 0.128 0.402 0.332 0.328 0.14 0.167 0.173 0.157 0.169 0.237 0.556 0.521 0.5 0.487 0.578 0.603 0.644 0.556 0.634 0.614 0.463 0.485 0.432 0.671 0.479 0.201 0.189 0.201 0.188 0.199 0.295 0.28 0.273 0.5 0.448 0.343 0.39 0.382 0.617 Printed: 4/6/2014 5:19 PM 581 of 603 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140402X02 Analysis Date: Lab ID: OPR1_11906_PCB NATIVE ANALYTES PCB-1 2-MoCB PCB-3 4-MoCB PCB-4 22'-DiCB PCB-15 44'-DiCB PCB-19 22'6-TrCB PCB-37 344'-TrCB PCB-54 22'66'-TeCB PCB-77 33'44'-TeCB PCB-81 344'5-TeCB PCB-104 22'466'-PeCB PCB-105 233'44'-PeCB PCB-114 2344'5-PeCB PCB-118 23'44'5-PeCB PCB-123 23'44'5'-PeCB PCB-126 33'44'5-PeCB PCB-155 22'44'66'-HxCB PCB-156/157 ...-HxCB PCB-167 23'44'55'-HxCB PCB-169 33'44'55'-HxCB PCB-188 22'34'566'-HpCB PCB-189 233'44'55'-HpCB PCB-202 22'33'55'66'-OcCB PCB-205 233'44'55'6-OcCB PCB-206 22'33'44'55'6-NoCB PCB-208 22'33'455'66'-NoCB PCB-209 DeCB Processed: 06 Apr 2014 16:10 02-APR-2014 00:23:43 SPIKE CONC. RECOVERY RANGE (%) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 110 112 91.2 103 94.1 105 92.2 94.9 100 89.2 94.7 94.7 92.5 92.8 103 87.8 94.1 93.1 91.6 87.9 99.3 91.9 93.2 95 94.8 94.5 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 Contract-required recovery limits for OPR as specified in Table 6, Method 1668A. Analyst: CM FORM 8A OK - 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 582 of 603 METHOD 1668A PCB ONGOING PRECISION AND RECOVERY (OPR) Lab Name: SGS Environmental Services Initial Calibration: ICAL: MM7_PCB_10292013_20DEC2013 Instrument ID: MM7 GC Column ID: VER Data Filename: 140402X02 Analysis Date: Lab ID: OPR1_11906_PCB LABELED STANDARDS ES PCB-1 ES PCB-3 ES PCB-4 ES PCB-15 ES PCB-19 ES PCB-37 ES PCB-54 ES PCB-77 ES PCB-81 ES PCB-104 ES PCB-105 ES PCB-114 ES PCB-118 ES PCB-123 ES PCB-126 ES PCB-153 ES PCB-155 ES PCB-156/157 ES PCB-167 ES PCB-169 ES PCB-170 ES PCB-180 ES PCB-188 ES PCB-189 ES PCB-202 ES PCB-205 ES PCB-206 ES PCB-208 ES PCB-209 FORM 8B 02-APR-2014 00:23:43 SPIKE CONC. RECOVERY RANGE (%) 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 200 100 100 100 100 100 100 100 100 100 100 100 91.6 89.9 105 103 95.8 93 103 96.5 94.3 117 100 98.6 104 102 100 98.4 95.3 77.6 80.1 73.1 95.9 102 112 99.8 99.1 90.1 95.4 107 90.8 15 15 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 - 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y 100 100 100 85.7 101 111 40 40 40 - 125 125 125 Y Y Y OK CLEANUP STANDARDS CS PCB-28 CS PCB-111 CS PCB-178 Processed: 06 Apr 2014 16:10 Analyst: CM 583 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 Rel. Int. QC chk 100% 10.03-15.71 218.9856 Fn1 Flags: 0% Abs. Int. 3.79e7 1.89e7 11.0 12.0 13.0 14.0 0.00e0 RT 15.0 Rel. Int. QC chk 100% 15.72-21.25 242.9856 Fn2 Flags: 0% Abs. Int. 3.37e7 1.68e7 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. QC chk 100% 21.27-26.76 292.9824 Fn3 Flags: 0% 0.00e0 RT Abs. Int. 2.32e7 1.16e7 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 Rel. Int. QC chk 100% 26.79-37.96 330.9792 Fn4 Flags: 0% Abs. Int. 1.44e7 7.21e6 28.0 Rel. Int. QC chk 100% 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 30.0 32.0 34.0 0.00e0 RT 36.0 Abs. Int. 7.46e6 3.73e6 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. QC chk 100% 44.77-49.81 454.9728 Fn6 Flags: 0% 0.00e0 RT Abs. Int. 5.72e6 2.86e6 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 Rel. Int. QC chk 100% 49.82-52.00 454.9728 Fn7 Flags: 0% Abs. Int. 5.74e6 2.87e6 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 scc: 758-213 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids PKD: n/a Printed: 06-Apr-2014 17:21 Page 1 of 21 584 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 PCB-1 8.10e6 11.85 Rel. Int. 100% Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-2 7.97e6 13.95 MoCB 10.03-15.71 188.0393 Fn1 Flags: PBM 4σ 2.60e3 Abs. Int. 3.00e6 PCB-3 7.80e6 14.13 1.50e6 0% 11.0 12.0 13.0 PCB-1 2.47e6 11.85 Rel. Int. 100% 14.0 PCB-2 2.44e6 13.95 MoCB 10.03-15.71 190.0363 Fn1 Flags: PBM 4σ 2.19e3 15.0 0.00e0 RT Abs. Int. 9.06e5 PCB-3 2.36e6 14.13 4.53e5 0% 11.0 12.0 13.0 ES-1 1.55e7 11.84 Rel. Int. 100% 14.0 15.0 Abs. Int. 5.78e6 ES-3 1.40e7 14.12 MoCB Std. 10.03-15.71 200.0795 Fn1 Flags: PBM 4σ 2.92e3 0.00e0 RT 2.89e6 0% 11.0 12.0 13.0 ES-1 4.56e6 11.84 Rel. Int. 100% 14.0 15.0 Abs. Int. 1.86e6 ES-3 4.00e6 14.12 MoCB Std. 10.03-15.71 202.0766 Fn1 Flags: PBM 4σ 2.92e4 0.00e0 RT 9.28e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.79e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.89e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4753, 0228 scc: 758-213 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 23:57 Printed: 06-Apr-2014 17:21 Page 2 of 21 585 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 Rel. Int. 100% Abs. Int. 1.95e6 PCB-10 5.74e6 14.56 DiCB-1 10.03-15.71 222.0003 Fn1 Flags: PBM 4σ 6.86e3 PCB-4 3.46e6 14.38 9.76e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% Abs. Int. 1.25e6 PCB-10 3.69e6 14.56 DiCB-1 10.03-15.71 223.9974 Fn1 Flags: PBM 4σ 1.50e4 PCB-4 2.21e6 14.38 6.23e5 0% 11.0 12.0 13.0 14.0 15.0 ES-4 6.28e6 14.36 Rel. Int. 100% 0.00e0 RT 0.00e0 RT Abs. Int. 2.16e6 DiCB Std. 10.03-15.71 234.0406 Fn1 Flags: PBM 4σ 8.69e3 1.08e6 0% 11.0 12.0 13.0 14.0 15.0 ES-4 3.81e6 14.36 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.23e6 DiCB Std. 10.03-15.71 236.0376 Fn1 Flags: PBM 4σ 3.07e3 6.16e5 0% 11.0 12.0 13.0 14.0 15.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.79e7 QC Check 10.03-15.71 218.9856 Fn1 Flags: - 1.89e7 0% 11.0 12.0 13.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7243, 9289 scc: 758-213 14.0 15.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 04-Apr-2014 23:57 (CEM) Printed: 06-Apr-2014 17:21 Page 3 of 21 586 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% PCB-6 5.83e6 16.74 PCB-9 5.36e6 16.35 DiCB-2 15.72-21.25 222.0003 Fn2 Flags: PBM 4σ 6.42e3 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 PCB-14 6.98e6 18.71 PCB-5 5.82e6 PCB-8 17.04 5.91e6 17.16 PCB-11 5.96e6 19.49 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 13/12 1.21e7 19.79 Abs. Int. 1.99e6 PCB-15 6.36e6 20.07 9.93e5 0% 16.0 Rel. Int. 100% 17.0 PCB-9 3.34e6 16.35 DiCB-2 15.72-21.25 223.9974 Fn2 Flags: PBM 4σ 3.01e4 PCB-7 3.82e6 16.51 18.0 19.0 20.0 PCB-14 4.31e6 18.71 PCB-5 3.61e6 PCB-8 17.04 3.72e6 17.16 PCB-11 3.65e6 19.50 13/12 7.37e6 19.79 21.0 0.00e0 RT Abs. Int. 1.29e6 PCB-15 3.93e6 20.07 6.46e5 0% 16.0 17.0 18.0 19.0 JS-9 1.12e7 16.33 Rel. Int. 100% 20.0 21.0 ES-15 1.21e7 20.06 0.00e0 RT Abs. Int. 3.43e6 DiCB Std. 15.72-21.25 234.0406 Fn2 Flags: PBM 4σ 1.79e4 1.71e6 0% 16.0 17.0 18.0 19.0 JS-9 7.16e6 16.33 Rel. Int. 100% 20.0 21.0 ES-15 7.58e6 20.06 0.00e0 RT Abs. Int. 2.23e6 DiCB Std. 15.72-21.25 236.0376 Fn2 Flags: PBM 4σ 6.13e3 1.11e6 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.37e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.68e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 6266, 5761 scc: 758-213 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:13 (CEM) Printed: 06-Apr-2014 17:21 Page 4 of 21 587 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Rel. Int. 100% Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 30/18 6.93e6 19.20 TrCB-2 15.72-21.25 255.9613 Fn2 Flags: PBM 4σ 4.30e3 PCB-19 2.47e6 17.45 PCB-17 2.96e6 19.60 PCB-24 4.01e6 19.93 PCB-27 4.17e6 19.79 Abs. Int. 1.96e6 PCB-16 2.22e6 20.03 PCB-32 4.34e6 20.50 9.80e5 0% 16.0 17.0 18.0 19.0 Rel. Int. 100% 20.0 30/18 6.59e6 19.20 TrCB-2 15.72-21.25 257.9584 Fn2 Flags: PBM 4σ 3.00e3 PCB-19 2.35e6 17.45 PCB-17 2.87e6 19.60 PCB-24 3.78e6 19.93 PCB-27 3.91e6 19.79 21.0 Abs. Int. 1.89e6 PCB-16 2.11e6 20.02 PCB-32 4.22e6 20.50 9.44e5 0% 16.0 17.0 18.0 19.0 0.00e0 RT 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.77e6 TrCB Std. 15.72-21.25 268.0016 Fn2 Flags: PBM 4σ 1.02e5 3.88e6 ES-19 4.60e6 17.43 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-19 4.32e6 17.43 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.35e6 TrCB Std. 15.72-21.25 269.9986 Fn2 Flags: PBM 4σ 2.26e4 6.75e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.37e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.68e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7453, 6900 scc: 758-213 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:13 (CEM) Printed: 06-Apr-2014 17:21 Page 5 of 21 588 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TrCB-3 21.27-26.76 255.9613 Fn3 Flags: PBM 4σ 6.58e3 PCB-34 4.40e6 21.65 PCB-23 4.50e6 21.80 26/29 9.07e6 22.08 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 28/20 8.68e6 22.84 PCB-31 4.65e6 22.56 Abs. Int. 2.03e6 PCB-36 4.72e6 24.78 PCB-22 4.33e6 23.40 PCB-39 4.94e6 25.10 PCB-38 4.44e6 25.63 PCB-35 4.22e6 26.03 PCB-37 4.47e6 26.39 0% 22.0 24.0 25.0 0.00e0 RT 26.0 28/20 8.81e6 22.84 Rel. Int. 100% TrCB-3 21.27-26.76 257.9584 Fn3 Flags: PBM 4σ 4.25e3 23.0 PCB-34 4.25e6 21.65 PCB-23 4.41e6 21.80 26/29 9.00e6 22.08 PCB-31 4.72e6 22.56 Abs. Int. 2.08e6 PCB-36 4.71e6 24.78 PCB-22 4.34e6 23.40 PCB-39 4.77e6 25.10 PCB-38 4.35e6 25.63 PCB-35 4.19e6 26.02 PCB-37 4.43e6 26.39 23.0 24.0 25.0 1.04e6 0.00e0 RT 0% 22.0 1.02e6 26.0 Rel. Int. 100% Abs. Int. 4.35e6 CS/SS-28 8.59e6 22.81 TrCB Std. 21.27-26.76 268.0016 Fn3 Flags: PBM 4σ 1.14e5 ES-37 8.55e6 26.37 0% 22.0 23.0 24.0 25.0 0.00e0 RT 26.0 CS/SS-28 7.49e6 22.81 Rel. Int. 100% ES-37 7.16e6 26.37 TrCB Std. 21.27-26.76 269.9986 Fn3 Flags: PBM 4σ 2.42e4 2.18e6 Abs. Int. 1.98e6 9.89e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.32e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.16e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 3480, 3391 scc: 758-213 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:14 (CEM) Printed: 06-Apr-2014 17:21 Page 6 of 21 589 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-54 2.49e6 20.35 Rel. Int. 100% Abs. Int. 7.23e5 TeCB-2 15.72-21.25 289.9224 Fn2 Flags: PBM 4σ 1.42e3 3.62e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 PCB-54 3.11e6 20.35 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.96e5 TeCB-2 15.72-21.25 291.9194 Fn2 Flags: PBM 4σ 1.49e3 4.48e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 3.91e6 20.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.11e6 TeCB Std. 15.72-21.25 301.9626 Fn2 Flags: PBM 4σ 1.40e4 5.55e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 ES-54 5.07e6 20.33 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.46e6 TeCB Std. 15.72-21.25 303.9597 Fn2 Flags: PBM 4σ 9.65e3 7.32e5 0% 16.0 17.0 18.0 19.0 20.0 21.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 3.37e7 QC Check 15.72-21.25 242.9856 Fn2 Flags: - 1.68e7 0% 16.0 17.0 18.0 19.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2241, 4499 scc: 758-213 20.0 21.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:14 (CEM) Printed: 06-Apr-2014 17:21 Page 7 of 21 590 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 Rel. Int. 100% TeCB-3 21.27-26.76 289.9224 Fn3 Flags: PBM 4σ 2.05e3 50/53 4.56e6 22.33 PCB-51 2.35e6 22.99 PCB-45 1.95e6 22.91 PCB-73 PCB-52 2.99e6 2.23e6 24.57 24.45 PCB-46 1.90e6 23.20 69/49 5.63e6 24.87 44/47… 7.49e6 25.37 PCB-48 2.32e6 25.15 59/62… 9.65e6 25.64 71/40 4.81e6 26.23 PCB-42 2.17e6 25.81 PCB-41 1.90e6 26.14 Abs. Int. 1.87e6 PCB-64 3.44e6 26.43 0% 22.0 23.0 24.0 25.0 Rel. Int. 100% TeCB-3 21.27-26.76 291.9194 Fn3 Flags: PBM 4σ 1.23e3 50/53 5.82e6 22.33 PCB-51 3.01e6 22.99 PCB-45 2.49e6 22.91 PCB-73 PCB-52 3.88e6 2.85e6 24.57 24.45 PCB-46 2.29e6 23.20 69/49 7.16e6 24.87 PCB-48 2.92e6 25.15 59/62… 1.22e7 25.64 PCB-42 2.72e6 25.81 71/40 6.15e6 26.23 PCB-41 2.47e6 26.14 0% 22.0 23.0 24.0 25.0 26.0 JS-52 4.58e6 24.43 Rel. Int. 100% 0.00e0 RT 26.0 44/47… 9.40e6 25.37 9.34e5 Abs. Int. 2.30e6 PCB-64 4.43e6 26.43 1.15e6 0.00e0 RT Abs. Int. 1.25e6 TeCB Std. 21.27-26.76 301.9626 Fn3 Flags: PBM 4σ 2.66e4 6.26e5 0% 22.0 23.0 24.0 25.0 26.0 JS-52 5.59e6 24.42 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.48e6 TeCB Std. 21.27-26.76 303.9597 Fn3 Flags: PBM 4σ 1.83e4 7.38e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.32e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.16e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 7533, 8079 scc: 758-213 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:17 (CEM) Printed: 06-Apr-2014 17:21 Page 8 of 21 591 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% TeCB-4 26.79-37.96 289.9224 Fn4 Flags: PBM 4σ 4.91e3 61/70... 1.36e7 28.65 PCB-68 3.71e6 27.40 PCB-72 3.41e6 27.15 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 PCB-67 3.56e6 28.14 PCB-55 3.28e6 29.08 PCB-60 PCB-80 3.28e6 3.84e6 30.03 29.71 PCB-79 3.84e6 31.36 PCB-78 3.12e6 31.85 PCB-81 3.22e6 32.23 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 Abs. Int. 1.67e6 PCB-77 3.26e6 32.70 8.36e5 0% 28.0 61/70... 1.70e7 28.65 Rel. Int. 100% TeCB-4 26.79-37.96 291.9194 Fn4 Flags: PBM 4σ 4.89e3 30.0 PCB-68 4.58e6 27.40 32.0 PCB-60 4.09e6 29.71 PCB-63 4.65e6 PCB-66 PCB-56 4.15e6 4.07e6 28.36 28.93 29.52 PCB-80 4.76e6 30.03 PCB-79 4.78e6 31.36 PCB-78 3.95e6 31.85 PCB-81 4.11e6 32.22 34.0 36.0 Abs. Int. 2.08e6 PCB-77 4.15e6 32.70 1.04e6 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 5.90e6 32.21 0.00e0 RT 34.0 36.0 0.00e0 RT Abs. Int. 1.54e6 ES-77 5.99e6 32.68 TeCB Std. 26.79-37.96 301.9626 Fn4 Flags: PBM 4σ 2.74e4 7.71e5 0% 28.0 30.0 Rel. Int. 100% 32.0 ES-81 7.20e6 32.21 TeCB Std. 26.79-37.96 303.9597 Fn4 Flags: PBM 4σ 2.09e4 34.0 36.0 0.00e0 RT Abs. Int. 1.89e6 ES-77 7.57e6 32.68 9.43e5 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 7.21e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0407, 4992 scc: 758-213 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:17 (CEM) Printed: 06-Apr-2014 17:21 Page 9 of 21 592 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Rel. Int. 100% Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-104 2.17e6 25.31 PCB-96 1.92e6 25.63 Abs. Int. 5.63e5 PeCB-3 21.27-26.76 323.8834 Fn3 Flags: PBM 4σ 9.14e2 2.82e5 0% 22.0 23.0 24.0 Rel. Int. 100% 25.0 26.0 PCB-104 3.37e6 25.31 0.00e0 RT Abs. Int. 9.30e5 PCB-96 2.99e6 25.63 PeCB-3 21.27-26.76 325.8804 Fn3 Flags: PBM 4σ 1.05e3 4.65e5 0% 22.0 23.0 24.0 25.0 26.0 ES-104 5.33e6 25.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.42e6 PeCB Std. 21.27-26.76 337.9207 Fn3 Flags: PBM 4σ 2.92e3 7.08e5 0% 22.0 23.0 24.0 25.0 26.0 ES-104 3.36e6 25.29 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.24e5 PeCB Std. 21.27-26.76 339.9177 Fn3 Flags: PBM 4σ 2.05e3 4.62e5 0% 22.0 23.0 24.0 25.0 26.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.32e7 QC Check 21.27-26.76 292.9824 Fn3 Flags: - 1.16e7 0% 22.0 23.0 24.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8834, 1574 scc: 758-213 25.0 26.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:17 (CEM) Printed: 06-Apr-2014 17:21 Page 10 of 21 593 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 108/119... 1.14e7 31.38 Rel. Int. 100% PeCB-4 26.79-37.96 323.8834 Fn4 Flags: PBM 4σ 2.71e3 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-103 1.84e6 27.32 100/93 3.25e6 28.10 PCB-88 1.40e6 28.58 PCB-121 2.34e6 29.60 113/90… 5.64e6 30.40 116/85 3.64e6 32.00 PCB-99 1.77e6 30.93 PCB-111 2.48e6 PCB-120 2.39e6 32.71 33.11 107/124 PCB-118 4.39e6 2.31e6 34.08 34.67 PCB-123 PCB-114 2.38e6 2.41e6 34.39 35.14 Abs. Int. 1.65e6 PCB-105 2.21e6 35.68 PCB-127 2.23e6 36.91 0% 28.0 30.0 32.0 108/119... 1.86e7 31.38 Rel. Int. 100% PeCB-4 26.79-37.96 325.8804 Fn4 Flags: PBM 4σ 3.42e3 PCB-94 2.54e6 27.51 100/93 5.36e6 28.10 PCB-91 3.16e6 28.64 PCB-89 2.46e6 29.26 113/90… 9.22e6 30.40 PCB-112 3.83e6 PCB-92 31.03 2.66e6 29.92 34.0 116/85 PCB-115 5.83e6 3.92e6 32.00 32.20 PCB-117 PCB-110 PCB-111 PCB-120 3.69e6 3.92e6 3.53e6 3.94e6 31.91 32.71 32.12 33.11 107/124 PCB-118 3.80e6 7.03e6 34.67 34.08 PCB-123 PCB-114 3.91e6 3.91e6 34.39 35.14 30.0 Rel. Int. 100% 32.0 CS/SS-111 6.93e6 32.69 JS-101 5.67e6 30.40 PeCB Std. 26.79-37.96 337.9207 Fn4 Flags: PBM 4σ 2.61e3 34.0 ES-118 ES-114 6.77e6 ES-123 6.84e6 6.82e6 34.65 35.12 34.37 0.00e0 RT 36.0 Abs. Int. 2.71e6 PCB-105 3.66e6 35.68 0% 28.0 8.27e5 36.0 ES-105 6.87e6 35.66 PCB-127 3.57e6 36.91 1.36e6 0.00e0 RT Abs. Int. 1.71e6 8.56e5 0% 28.0 30.0 Rel. Int. 100% 32.0 CS/SS-111 4.42e6 32.69 JS-101 3.57e6 30.40 PeCB Std. 26.79-37.96 339.9177 Fn4 Flags: PBM 4σ 2.39e3 34.0 ES-118 ES-123 4.25e6 ES-114 4.37e6 34.65 4.32e6 35.12 34.37 36.0 ES-105 4.26e6 35.66 0.00e0 RT Abs. Int. 1.13e6 5.63e5 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 7.21e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1728, 4373 scc: 758-213 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:18 (CEM) Printed: 06-Apr-2014 17:21 Page 11 of 21 594 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 Abs. Int. 4.87e5 PCB-126 2.07e6 38.29 PeCB-5 37.98-44.76 323.8834 Fn5 Flags: PBM 4σ 1.46e3 2.44e5 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 Abs. Int. 7.64e5 PCB-126 3.35e6 38.29 PeCB-5 37.98-44.76 325.8804 Fn5 Flags: PBM 4σ 1.38e3 3.82e5 0% 38.0 Rel. Int. 100% 39.0 40.0 41.0 42.0 43.0 44.0 6.75e5 0% 38.0 39.0 40.0 41.0 42.0 43.0 44.0 4.34e5 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.46e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT Abs. Int. 8.67e5 ES-126 3.62e6 38.27 PeCB Std. 37.98-44.76 339.9177 Fn5 Flags: PBM 4σ 2.86e3 0% 38.0 0.00e0 RT Abs. Int. 1.35e6 ES-126 5.92e6 38.27 PeCB Std. 37.98-44.76 337.9207 Fn5 Flags: PBM 4σ 4.76e3 Rel. Int. 100% 0.00e0 RT 3.73e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 2616, 3284 scc: 758-213 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 23:57 Printed: 06-Apr-2014 17:21 Page 12 of 21 595 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 PCB-136 3.07e6 30.87 PCB-150 PCB-155 3.28e6 PCB-145 3.45e6 30.56 3.13e6 30.25 31.13 Rel. Int. 100% HxCB-4 26.79-37.96 359.8415 Fn4 Flags: PBM 4σ 6.85e2 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 147/149 139/140 4.57e6 4.68e6 33.70 34.22 PCB-148 2.32e6 32.40 151/135 4.50e6 PCB-144 PCB-143 PCB-142 PCB-133 PCB-146 2.17e6 2.34e6 32.93 2.35e6 2.18e6 2.00e6 35.73 33.40 35.17 33.96 34.54 153/168 5.80e6 36.27 PCB-141 2.18e6 36.42 163/138… 7.03e6 37.34 PCB-164 3.11e6PCB-160 37.05 2.82e6 37.47 0% 28.0 30.0 PCB-152 2.56e6 30.42 PCB-136 PCB-155 2.42e6 PCB-145 2.69e6 30.86 2.46e6 30.25 31.13 Rel. Int. 100% HxCB-4 26.79-37.96 361.8385 Fn4 Flags: PBM 4σ 7.72e2 32.0 PCB-148 1.84e6 32.40 34.0 147/149 139/140 151/135 3.64e6 3.63e6 3.53e6 33.70 34.22 32.92 PCB-154 PCB-143 2.05e6 PCB-132 1.72e6 33.13 1.59e6 33.95 34.77 153/168 4.64e6 36.27 163/138… 5.54e6 37.34 PCB-141 PCB-137 1.71e6 1.77e6 36.96 36.42 30.0 32.0 34.0 ES-153 4.49e6 36.23 HxCB Std. 26.79-37.96 371.8817 Fn4 Flags: PBM 4σ 1.47e3 5.01e5 0.00e0 RT 36.0 ES-155 6.21e6 30.23 Rel. Int. 100% Abs. Int. 1.00e6 PCB-158 2.50e6 37.65 0% 28.0 6.73e5 0.00e0 RT 36.0 PCB-165 2.19e6 35.51 Abs. Int. 1.35e6 Abs. Int. 1.65e6 JS-138 4.19e6 37.29 8.23e5 0% 28.0 30.0 32.0 34.0 0.00e0 RT 36.0 ES-155 4.89e6 30.23 Rel. Int. 100% Abs. Int. 1.29e6 ES-153 3.48e6 36.23 HxCB Std. 26.79-37.96 373.8788 Fn4 Flags: PBM 4σ 1.62e3 JS-138 3.14e6 37.29 6.47e5 0% 28.0 30.0 32.0 34.0 36.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.44e7 QC Check 26.79-37.96 330.9792 Fn4 Flags: - 7.21e6 0% 28.0 30.0 32.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8599, 1286 scc: 758-213 34.0 36.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:18 (CEM) Printed: 06-Apr-2014 17:21 Page 13 of 21 596 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% 128/166 4.39e6 38.39 PCB-162 PCB-159 2.78e6 39.44 2.68e6 39.20 HxCB-5 37.98-44.76 359.8415 Fn5 Flags: PBM 4σ 1.46e3 0% 38.0 Rel. Int. 100% HxCB-5 37.98-44.76 361.8385 Fn5 Flags: PBM 4σ 1.81e3 0% 38.0 39.0 PCB-162 PCB-159 2.29e6 39.44 2.23e6 39.20 39.0 40.0 PCB-169 2.41e6 43.55 41.0 42.0 43.0 4.92e5 44.0 156/157 4.25e6 40.83 Abs. Int. 8.31e5 PCB-167 2.39e6 39.85 40.0 PCB-169 1.88e6 43.55 41.0 39.0 40.0 ES-167 4.28e6 39.83 HxCB Std. 37.98-44.76 373.8788 Fn5 Flags: PBM 4σ 1.94e3 42.0 43.0 4.16e5 44.0 ES-156/157 1.02e7 40.81 0.00e0 RT Abs. Int. 1.79e6 ES-169 4.64e6 43.53 41.0 42.0 43.0 44.0 ES-156/157 8.03e6 40.81 0.00e0 RT Abs. Int. 1.39e6 ES-169 3.70e6 43.53 6.94e5 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.46e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT 8.97e5 Rel. Int. 100% 0% 38.0 Abs. Int. 9.85e5 PCB-167 2.91e6 39.85 ES-167 5.51e6 39.83 HxCB Std. 37.98-44.76 371.8817 Fn5 Flags: PBM 4σ 2.71e3 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 156/157 5.14e6 40.83 128/166 3.63e6 38.39 Rel. Int. 100% 0% 38.0 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 3.73e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1810, 3808 scc: 758-213 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:18 (CEM) Printed: 06-Apr-2014 17:21 Page 14 of 21 597 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Rel. Int. 100% PCB-188 2.20e6 35.13 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-179 2.16e6 PCB-184 35.41 2.01e6 35.87 HpCB-4 29.99-37.96 393.8025 Fn4 Flags: PBM 4σ 7.23e2 0% 30.0 31.0 32.0 33.0 34.0 Rel. Int. 100% 35.0 PCB-188 2.10e6 35.13 36.0 PCB-179 1.97e6 35.41 PCB-176 2.13e6 36.16 HpCB-4 29.99-37.96 395.7995 Fn4 Flags: PBM 4σ 6.20e2 0% 30.0 31.0 32.0 33.0 34.0 35.0 36.0 PCB-186 2.06e6 36.56 PCB-186 1.94e6 36.56 32.0 33.0 34.0 PCB-178 1.36e6 37.69 35.0 Abs. Int. 9.90e5 36.0 Abs. Int. 9.07e5 CS/SS-178 2.22e6 37.67 32.0 33.0 34.0 35.0 4.95e5 0.00e0 RT 37.0 HpCB Std. 29.99-37.96 407.8398 Fn4 Flags: PBM 4σ 1.16e3 31.0 2.60e5 0.00e0 RT 37.0 ES-188 3.67e6 35.11 Rel. Int. 100% 36.0 37.0 Rel. Int. 100% 4.53e5 0.00e0 RT Abs. Int. 1.44e7 QC Check 29.99-37.96 330.9792 Fn4 Flags: 0% 30.0 Abs. Int. 5.21e5 CS/SS-178 2.52e6 37.67 31.0 2.75e5 0.00e0 RT 37.0 HpCB Std. 29.99-37.96 405.8428 Fn4 Flags: PBM 4σ 1.93e3 0% 30.0 PCB-178 1.46e6 37.69 ES-188 4.05e6 35.11 Rel. Int. 100% 0% 30.0 Abs. Int. 5.50e5 7.21e6 31.0 32.0 33.0 34.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 4680, 3198 scc: 758-213 35.0 36.0 37.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:19 (CEM) Printed: 06-Apr-2014 17:21 Page 15 of 21 598 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% HpCB-5 37.98-44.76 393.8025 Fn5 Flags: PBM 4σ 2.03e3 PCB-175 1.89e6 38.23 0% 38.0 Rel. Int. 100% HpCB-5 37.98-44.76 395.7995 Fn5 Flags: PBM 4σ 1.90e3 0% 38.0 PCB-183 1.92e6 PCB-182 38.98 PCB-185 1.99e6 1.87e6 38.64 39.07 39.0 PCB-182 1.92e6 38.64 PCB-183 PCB-187 1.86e6 1.84e6 38.98 38.46 39.0 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 180/193 4.10e6 41.96 171/173 3.20e6 PCB-181 40.09 PCB-177 1.79e6 1.56e6 39.90 39.56 40.0 PCB-172 1.62e6 41.44 41.0 171/173 2.99e6 PCB-181 40.09 PCB-177 1.76e6 39.90 1.45e6 39.56 40.0 42.0 180/193 3.85e6 41.96 PCB-172 1.58e6 41.43 41.0 42.0 ES-180 3.51e6 41.97 Rel. Int. 100% HpCB-5 Std. 37.98-44.76 405.8428 Fn5 Flags: PBM 4σ 1.83e3 0% 38.0 PCB-170 1.49e6 43.06 3.68e5 43.0 PCB-191 2.14e6 42.29 PCB-170 1.42e6 43.06 43.0 Abs. Int. 7.35e5 PCB-190 2.09e6 43.51 44.0 39.0 40.0 41.0 42.0 ES-180 3.28e6 41.97 HpCB-5 Std. 37.98-44.76 407.8398 Fn5 Flags: PBM 4σ 1.45e3 Abs. Int. 7.00e5 PCB-190 2.03e6 43.51 3.50e5 44.0 0.00e0 RT Abs. Int. 8.43e5 ES-170 2.85e6 43.04 43.0 44.0 0.00e0 RT Abs. Int. 7.88e5 ES-170 2.52e6 43.04 3.94e5 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.46e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT 4.22e5 Rel. Int. 100% 0% 38.0 PCB-191 2.18e6 42.29 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 3.73e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0128, 3393 scc: 758-213 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 23:57 Printed: 06-Apr-2014 17:21 Page 16 of 21 599 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-189 2.25e6 45.67 Rel. Int. 100% Abs. Int. 5.19e5 HpCB-6 44.77-49.81 393.8025 Fn6 Flags: PBM 4σ 1.52e3 2.59e5 0% 45.0 46.0 47.0 48.0 49.0 PCB-189 2.08e6 45.67 Rel. Int. 100% 0.00e0 RT Abs. Int. 4.75e5 HpCB-6 44.77-49.81 395.7995 Fn6 Flags: PBM 4σ 8.80e2 2.38e5 0% 45.0 46.0 47.0 48.0 49.0 ES-189 4.08e6 45.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 9.50e5 HpCB Std. 44.77-49.81 405.8428 Fn6 Flags: PBM 4σ 2.23e3 4.75e5 0% 45.0 46.0 47.0 48.0 49.0 ES-189 4.04e6 45.65 Rel. Int. 100% 0.00e0 RT Abs. Int. 1.02e6 HpCB Std. 44.77-49.81 407.8398 Fn6 Flags: PBM 4σ 1.94e3 5.09e5 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.72e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.86e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 9593, 4040 scc: 758-213 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 23:57 Printed: 06-Apr-2014 17:21 Page 17 of 21 600 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 PCB-201 1.74e6 40.44 PCB-202 1.62e6 39.66 Rel. Int. 100% OcCB-5 37.98-44.76 427.7635 Fn5 Flags: PBM 4σ 8.98e2 0% 38.0 39.0 Rel. Int. 100% 40.0 OcCB-5 37.98-44.76 429.7606 Fn5 Flags: PBM 4σ 5.29e2 0% 38.0 PCB-197 1.96e6 PCB-204 41.21 PCB-200 1.68e6 1.64e6 41.02 41.31 41.0 PCB-201 1.99e6 40.44 PCB-202 1.79e6 39.66 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-204 1.87e6 41.02 198/199 2.24e6 43.62 Abs. Int. 4.54e5 PCB-196 1.21e6 44.20 42.0 43.0 PCB-197 2.05e6 41.21 PCB-200 1.79e6 41.31 39.0 198/199 2.44e6 43.62 Abs. Int. 4.84e5 PCB-196 1.29e6 44.20 40.0 41.0 42.0 43.0 44.0 ES-202 3.38e6 39.64 PCB-203 1.34e6 44.37 0.00e0 RT Abs. Int. 8.13e5 4.06e5 39.0 40.0 41.0 42.0 43.0 44.0 ES-202 3.66e6 39.64 Rel. Int. 100% 0.00e0 RT Abs. Int. 8.78e5 OcCB Std. 37.98-44.76 441.8008 Fn5 Flags: PBM 4σ 1.67e3 4.39e5 39.0 40.0 41.0 42.0 43.0 44.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 7.46e6 QC Check 37.98-44.76 380.9760 Fn5 Flags: 0% 38.0 0.00e0 RT 44.0 OcCB Std. 37.98-44.76 439.8038 Fn5 Flags: PBM 4σ 1.36e3 0% 38.0 2.27e5 2.42e5 Rel. Int. 100% 0% 38.0 PCB-203 1.21e6 44.37 3.73e6 39.0 40.0 41.0 42.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 0279, 8645 scc: 758-213 43.0 44.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 23:57 Printed: 06-Apr-2014 17:21 Page 18 of 21 601 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Rel. Int. 100% Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 PCB-194 1.11e6 47.43 PCB-195 1.01e6 45.49 OcCB-6 44.77-49.81 427.7635 Fn6 Flags: PBM 4σ 7.57e2 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-205 1.34e6 47.83 Abs. Int. 2.99e5 1.50e5 0% 45.0 Rel. Int. 100% 46.0 47.0 PCB-194 1.23e6 47.43 PCB-195 1.12e6 45.49 OcCB-6 44.77-49.81 429.7606 Fn6 Flags: PBM 4σ 1.14e3 48.0 49.0 PCB-205 1.50e6 47.83 0.00e0 RT Abs. Int. 3.47e5 1.73e5 0% 45.0 46.0 47.0 48.0 JS-194 2.42e6 47.41 Rel. Int. 100% 49.0 ES-205 2.65e6 47.81 0.00e0 RT Abs. Int. 6.00e5 OcCB Std. 44.77-49.81 439.8038 Fn6 Flags: PBM 4σ 1.07e3 3.00e5 0% 45.0 46.0 47.0 48.0 JS-194 2.71e6 47.41 Rel. Int. 100% 49.0 ES-205 3.11e6 47.81 0.00e0 RT Abs. Int. 7.25e5 OcCB Std. 44.77-49.81 441.8008 Fn6 Flags: PBM 4σ 8.75e2 3.62e5 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.72e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.86e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8719, 4358 scc: 758-213 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids PKD: 04-Apr-2014 23:57 Printed: 06-Apr-2014 17:21 Page 19 of 21 602 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 PCB-208 1.51e6 45.29 Rel. Int. 100% Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-207 1.59e6 46.07 Abs. Int. 3.66e5 PCB-206 9.30e5 49.29 NoCB 44.77-49.81 461.7245 Fn6 Flags: PBM 4σ 9.50e2 1.83e5 0% 45.0 46.0 PCB-208 1.93e6 45.28 Rel. Int. 100% 47.0 48.0 0.00e0 RT 49.0 PCB-207 2.00e6 46.07 Abs. Int. 4.64e5 PCB-206 1.22e6 49.29 NoCB 44.77-49.81 463.7216 Fn6 Flags: PBM 4σ 1.86e3 2.32e5 0.00e0 RT 0% 45.0 46.0 47.0 48.0 49.0 ES-208 2.87e6 45.27 Rel. Int. 100% ES-206 1.86e6 49.27 NoCB Std. 44.77-49.81 473.7648 Fn6 Flags: PBM 4σ 9.50e2 Abs. Int. 7.12e5 3.56e5 0% 45.0 46.0 47.0 48.0 0.00e0 RT 49.0 ES-208 3.59e6 45.26 Rel. Int. 100% Abs. Int. 9.21e5 ES-206 2.20e6 49.27 NoCB Std. 44.77-49.81 475.7619 Fn6 Flags: PBM 4σ 1.26e3 4.60e5 0% 45.0 46.0 47.0 48.0 49.0 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.72e6 QC Check 44.77-49.81 454.9728 Fn6 Flags: - 2.86e6 0% 45.0 46.0 47.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 1747, 0581 scc: 758-213 48.0 49.0 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:19 (CEM) Printed: 06-Apr-2014 17:21 Page 20 of 21 603 of 603 SGS ID: OPR1_11906_PCB Instr: [ILM] AutoSpec-Premier MM7 Sample ID: 0_11906_OPR001 VSIR EI+ Expt: pcb-2012-01 GC: pcb90_a Vial: 20 Acq: 02-Apr-2014 00:23:43 User: LKB Datafile: 140402X02 PCB-209 1.48e6 50.72 Rel. Int. 100% Abs. Int. 3.07e5 DeCB 49.82-52.00 497.6826 Fn7 Flags: PBM 4σ 6.20e2 1.53e5 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 PCB-209 1.24e6 50.72 Rel. Int. 100% 0.00e0 RT Abs. Int. 2.61e5 DeCB 49.82-52.00 499.6797 Fn7 Flags: PBM 4σ 6.22e2 1.31e5 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.80e6 50.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 6.36e5 DeCB Std. 49.82-52.00 509.7229 Fn7 Flags: PBM 4σ 7.58e2 3.18e5 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 ES-209 2.38e6 50.69 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.33e5 DeCB Std. 49.82-52.00 511.7199 Fn7 Flags: PBM 4σ 1.19e3 2.67e5 0% 50.0 50.2 50.4 50.6 50.8 51.0 51.2 51.4 51.6 51.8 Rel. Int. 100% 0.00e0 RT Abs. Int. 5.74e6 QC Check 49.82-52.00 454.9728 Fn7 Flags: - 2.87e6 0% 50.0 50.2 50.4 50.6 50.8 51.0 Results: C:\UltraTracePro\results\CEM\A6528_11906 PCB\Resources\OPR1_11906_PCB.utp_res, saved 05-Apr-2014 00:20 (CEM) SGS UltraTrace-Pro V4.82 User/System: CEM/US0007762 cc: 8418, 2525 scc: 758-213 51.2 51.4 51.6 51.8 0.00e0 RT Peak annotation: Areas, Centroids Revised: 05-Apr-2014 00:19 (CEM) Printed: 06-Apr-2014 17:21 Page 21 of 21 LABORATORY DATA CONSULTANTS, INC. 2701 Loker Ave. West, Suite 220, Carlsbad, CA 92010 Bus: 760-827-1100 Fax: 760-827-1099 May 20,2014 Anchor QEA, LLC 720 Olive Way, Suite 900 Seattle, WA 98101 ATTN: Ms. Cindy Fields SUBJECT: Patrick Bayou, Data Validation Dear Ms. Fields, Enclosed are the final validation reports for the fractions listed below. These SDGs were received on April 21 ,2014. Attachment 1 is a summary of the samples that were reviewed for each analysis. LDe Project #31690: SDG# Fraction 31400373,31400389 31400395,31400411 31400420,31400427 A6492,A6504,A6506 A6517,A6521,A6528 Polychlorinated Biphenyls as Congeners, Wet Chemistry The data validation was performed under EPA Stage 2B guidelines. The analyses were validated using the following documents, as applicable to each method: • USEPA Contract Laboratory Program National Functional Guidelines for Chlorinated Dibenzo-p-Dioxins and Chlorinated Dibenzofurans Data Review, September 2011 • USEPA Contract Laboratory National Functional Guidelines for Inorganic Superfund Data Review, January 2010 • EPA SW 846, Third Edition, Test Methods for Evaluating Solid Waste, update 1, July 1992; update IIA, August 1993; update II, September 1994; update liB, January 1995; update III, December 1996; update lilA, April 1998; IIIB, November 2004; Update IV, February 2007 Please feel free to contact us if you have any questions. Christina Rink Project Manager/Chemist L:\Anchor\Patrick\31690COV. wpd UL-SF 791 n. Attachment 1 C'~ ~~ _ws ~DC SDG# DATE REC'D (3) DATE DUE PCB Cong (1668B) A _314003n 04/21/14 05/12/14 B 31400389 04/21/14 05/12/14 C 31400395 04/21/14 05/12/14 D 31400411 04/21/14 05/12/14 E 31400420 04/21/14 05/12/14 F 31400427 04/21/14 05/12/14 - - - - - - - G A6492 04/21/14 05/12/14 5 0 H A6504 04/21/14 05/12/14 9 0 I A6506 04/21/14 05/12/14 8 0 J A6517 04/21/14 05/12/14 1 0 K A6521 04/21/14 05/12/14 6 0 L A6528 04/21/14 05/12/14 4 0 rotal NCR 33 0 TOC (9060) DOC (9060) W S W 3 0 2 6 0 1 7 0 1 1 0 6 3 S .W S 0 3 0 0 6 0 0 7 0 1 0 0 - - - 6 0 0 1 3 0 0 - - - - - - - - - - - - - - - - 26 TSS (25400) 0 5 0 W S W S W S W S W 0 0 0 0 0 0 0 0 0 S .W S 0 0 -- W S W S W S W S W S W S 0 0 0 0 0 0 0 ~ 0 0 0 0 90 - - - - - - - - - 26 0 Shaded cells indicate Stage 4validation (all other cells are Stage 2Bvalidation). These sample counts do not include MS, MSD, or DUP's. ~- ~ ~ 0 0 31690ST.wpd LDC Report# 31690A6 Laboratory Data Consultants, Inc. Data Validation Report Project/Site Name: Patrick Bayou Collection Date: March 11, 2014 LDC Report Date: April 24, 2014 Matrix: Water Parameters: Wet Chemistry Validation Level: Stage 2B Laboratory: SGS Analytical Perspective Sample Delivery Group (SDG): 31400373 Sample Identification PB006.2-1SWMIO-140311-0 PB006.2-1SWMIO-140311-N HSC14.1-1SWMIO-140311-N PB006.2-1SWMIO-140311-0DUP PB006.2-1 SWMIO-140311-0MS PB006.2-1 SWMIO-140311-0MSO PB006.2-1 SWMIO-140311-NMS PB006.2-1SWMIO-140311-NMSO V:\LOGIN\ANCHOR\PATRICK\31690A6_AN3.DOC 1 Introduction This data review covers 8 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA SW 846 Method 9060A for Total Organic Carbon and Dissolved Organic Carbon and Standard Method 2540D for Total Suspended Solids. The review follows a modified outline ofthe USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review (January 2010). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, therefore qualification was not required. V:\LOGINIANCHOR\PATRICK\31690A6_AN3.DOC 2 I. Technical Holding Times All technical holding time requirements were met with the following exceptions: Sample Compound Finding PBOO6.2-1SWMID-140311-D PBOO6.2-1SWMID-140311-N Dissolved organic carbon Samples were filtered and preserved 5 days after receipt. Criteria Sample should be filtered and preserved immediately upon receipt. Flag AorP J (all detects) UJ (all non-detects) P The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. Initial Calibration All criteria for the initial calibration of each method were met. III. Calibration Verification Calibration verification frequency and analysis criteria were met for each method when applicable. IV. Blanks Method blanks were reviewed for each matrix as applicable. No contaminant concentrations were found in the initial, continuing and preparation blanks. V. Matrix Spike/Matrix Spike Duplicates Matrix spike (MS) and matrix spike duplicate (MSD) samples were reviewed for each matrix as applicable. Percent recoveries (%R) and relative percent differences (RPD) were within QC limits. VI. Duplicates Duplicate (DUP) sample analyses were reviewed for each matrix as applicable. Results were within QC limits. VII. Laboratory Control Samples Laboratory control samples were reviewed for each matrix as applicable. Percent recoveries (%R) were within QC limits. VIII. Sample Result Verification The results for the dissolved organic carbon analysis were greater than the total organic compound analysis as follows: V:ILOGINIANCHORIPATRICKI31690A6_AN3.DOC 3 Concentration (mg/L) Dissolved organic carbon Total organic carbon PB006.2-1SWMID-140311-D 9.80 6.75 PB006.2-1SWMID-140311-N 9.40 5.47 Sample Raw data were not reviewed for this SDG. IX. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. Due to technical holding time problems, data were qualified as estimated in two samples. The quality control criteria reviewed, other than those discussed above, were met and are considered acceptable. Sample results that were found to be estimated (J) are usable for limited purposes only. Based upon the Stage 2B data validation all other results are considered valid and usable for all purposes. Data flags are summarized at the end of this report if data has been qualified. X. Field Duplicates Samples PB006.2-1SWMID-140311-D and PB006.2-1SWMID-140311-N were identified as field duplicates. No contaminant concentrations were detected in any of the samples with the following exceptions: Concentration (mg/L) Analyte PBOOS.2-1SWMID-140311-D PBOOS.2-1SWMID-140311-N RPD Total organic carbon 6.75 5.47 21 Dissolved organic carbon 9.80 9.40 4 11 17 43 Total suspended solids XI. Field Blanks No field blanks were identified in this SDG. V:ILOGINIANCHORIPATRICKI31690A6_AN3.DOC 4 Patrick Bayou Wet Chemistry - Data Qualification Summary - SDG 31400373 I SOG 31400373 I Sam~le PB006.2-1SWMIO-140311-D PB006.2-1SWMID-140311-N I Anal}1e Dissolved organic carbon I Flag I J (all detects) UJ (all non-detects) AorP P I Reason Technical holding time Patrick Bayou Wet Chemistry - Laboratory Blank Data Qualification Summary - SDG 31400373 No Sample Data Qualified in this SDG V:ILOGINIANCHORIPATRICKI31690A6_AN3.DOC 5 I LDC #: 31690A6 VALIDATION COMPLETENESS WORKSHEET SDG #: 31400373 Stage 28 Laboratory: SGS Analytical Perspective Date: 4/ '0fJ/1 f Page:~ofL Reviewer: 1,..,.......2nd Reviewer: CYL- METHOD: (Analyte ),_--!..T~ot~a~1.:::::O~r:2!:a::!.n!!!ic::....C=ar~b~o.!..!.n'--'D=is~so~l..!..:ve~d~O~r:2!:a::!.n!!!ic::....C=ar~b~o.!..!.n...l.!:.E!....PA!...!....!S~W~84...!.:6::...!.:M.:..::e:..>:th.!.>o<.::d'-'9"-'0"""6=.LJ--'-"=-=..:=='-'-= Solids (SM2540D) The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I ~alidatiaD I Area 5vJ I. Technical holding times II Initial calibration III. Calibration verification IV Blanks V Matrix Spike/Matrix Spike Duplicates k VI. Duplicates />r- VII. Laboratory control samples VIII. Sample result verification Overall assessment of data X. Field duplicates XI l=i",lrl hl"nk<:> = = CammeDts Sampling dates: 3/" /1'-1 f fc, 'A ~ IX. Note: I Ix ~ / ~t,J Pr 5vJ t/,?--) #.../ = = A Acceptable N Not provided/applicable SW See worksheet ND No compounds detected R = Rinsate FB Field blank = = = = D Duplicate TB Trip blank EB Equipment blank Validated Samples: JYl.1 PB006.2-1SWMID-140311-D 11 2 PB006.2-1SWMID-140311-N ~ys 21 31 12 22 32 3 HSC14.1-1SWMID-140311-N 13 23 33 4 .~ 14 24 34 15 25 35 16 26 36 17 27 37 18 28 38 9 19 29 39 10 20 30 40 5 6 7 8 \ .\\1' 1 ~IY~ \Al, \tt' ~ '() t;"y 1~7 l/ \.rlS)9 Notes: ____________________________________________________________________________ 31690A6w'wpd I VALIDATION FINDINGS WORKSHEET Sample Specific Analysis Reference page:-f-ofL Reviewer: v---:--2nd reviewer: r72c----: All circled methods are applicable to each sample. Sample 10 ( , 2.-- i Parameter Matrix A'Lj; pH TDS CI F N0 3 N02 S04 P04 ALK CN- NH3 TKN ~ol CR 6 pH TDS CI F toc ..tR 6 NO~ NO, SO" PO" ALK CN- NH3 TKN '"-- CI0 4 + CIOtru pH TDS CI F NO~ NO, SO PO" ALK CN- NH~ TKN TOC CR6+ CIO r:N t fTOC Dissolved> Total I I 2 2 9.40 5.47 ..v , T~ -Y Comments: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ____ 31690A6_SV.wpd VALIDATION FINDINGS WORKSHEET LDC# 31960A6 Field Duplicates Page:_(_Of ) c:::::::; Reviewer: 2nd Reviewer: Ok-- Inorganics: Method See Cover I Concentration (mg/L} Analyte I I 1 I 6.75 2 I RPD I I I I 21 5.47 TOC DOC '155 I 9.80 \I V:\FIELD DUPLICATES\FD_inorganic\31960A6.wpd I 9.40 If I 4 LDC Report# 31690B6 Laboratory Data Consultants, Inc. Data Validation Report Project/Site Name: Patrick Bayou Collection Date: March 13,2014 LDC Report Date: April 24, 2014 Matrix: Water Parameters: Wet Chemistry Validation Level: Stage 2B Laboratory: SGS Analytical Perspective Sample Delivery Group (SDG): 31400389 Sample Identification PB020-1 SWMIO-140313-N PB031.1-1SWMIO-140313-N PB047.3-1 SWMIO-140313-N PB056_C-1 SWMIO-140313-N EF006.1-1SWMIO-140313-N PB119 B-1SWMIO-140313-N V:\LOGIN\ANCHOR\PATRICK\31690B6_AN3.DOC 1 Introduction This data review covers 6 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA SW 846 Method 9060A for Total Organic Carbon and Dissolved Organic Carbon and Standard Method 2540D for Total Suspended Solids. The review follows a modified outline of the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review (January 2010). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, therefore qualification was not required. V:ILOGINIANCHORIPATRICK\31690B6_AN3.DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. Initial Calibration All criteria for the initial calibration of each method were met. III. Calibration Verification Calibration verification frequency and analysis criteria were met for each method when applicable. IV. Blanks Method blanks were reviewed for each matrix as applicable. No contaminant concentrations were found in the initial, continuing and preparation blanks. V. Matrix Spike/Matrix Spike Duplicates Matrix spike (MS) and matrix spike duplicate (MSD) samples were reviewed for each matrix as applicable. Percent recoveries (%R) and relative percent differences (RPD) were within QC limits. VI. Duplicates Duplicate (DUP) sample analyses were reviewed for each matrix as applicable. Results were within QC limits. VII. Laboratory Control Samples Laboratory control samples were reviewed for each matrix as applicable. Percent recoveries (%R) were within QC limits. VIII. Sample Result Verification The results for the dissolved organic carbon analysis were greater than the total organic compound analysis as follows: Concentration (mg/L) Sample PB056_C-1SWMID-140313-N V:\LOGINIANCHOR\PATRICK\31690B6_AN3.DOC Dissolved organic carbon Total organic carbon 12.9 9.34 3 Raw data were not reviewed for this SDG. IX. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. The quality control criteria reviewed were met and are considered acceptable. Based upon the Stage 2B data validation all results are considered valid and usable for all purposes. X. Field Duplicates No field duplicates were identified in this SDG. XI. Field Blanks No field blanks were identified in this SDG. V:\LOGIN\ANCHOR\PATRICK\31690B6_AN3.DOC 4 Patrick Bayou Wet Chemistry - Data Qualification Summary - SDG 31400389 No Sample Data Qualified in this SDG Patrick Bayou Wet Chemistry - Laboratory Blank Data Qualification Summary - SDG 31400389 No Sample Data Qualified in this SDG V:ILOGINIANCHORIPATRICKI31690B6_AN3.DOC 5 Date: I~ Page:..iof_)_ Reviewer: v2nd Reviewer: 0\--- i I"rf/ VALIDATION COMPLETENESS WORKSHEET LDC #: 3169086 SDG #: 31400389 Stage 28 Laboratory: SGS Analytical Perspective Pr METHOD: (Analyte ),_---!..T~ot~a~1.: : O.!. .lr~a::.!.n!!.::ic::....C=ar~b:!:::o.!.!.n,,--,D=is~so~l..!.:ve::.!d~O.!...lr~a::.!.n!!.::ic::....C=ar~b:!:::o.!.!.n....l..:E,--PA'-....!....!S"-,Wc..:...:::.84-,-,6,,-,-,,M.!.!:e'-'!th..:..::o::..:=d:....:9,,-,0<-=6=.u--=-::=--=..:==e.:...:.nd:::.;e=d Solids (SM2540D) The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. Validation Arp-a Comments Pr I. Technical holding times II Initial calibration liI. Calibration verification IV Blanks fy V Matrix Spike/Matrix Spike Duplicates k VI. Duplicates fr VII. Laboratory control samples VIII. Sample result verification IX W Overall assessment of data A x. Field duplicates IJ )(1 i=i .. lrl hl TOe Dissolved> Total, Text Comments: ___________________________________________________________________________________________________________ LDC Report# 31690C6 Laboratory Data Consultants, Inc. Data Validation Report Project/Site Name: Patrick Bayou Collection Date: March 14,2014 LDC Report Date: April 24, 2014 Matrix: Water Parameters: Wet Chemistry Validation Level: Stage 2B Laboratory: SGS Analytical Perspective Sample Delivery Group (SDG): 31400395 Sample Identification PB070 B-2SWMIO-140314-N PB070 B-1SWMIO-140314-N PB079-1 SWMIO-140314-N PB081 A-1SWMIO-140314-N PB089-1 SWMIO-140314-N PB085-1 SWMIO-140314-N PB097A-1 SWM I0-140314-N PB070 B-2SWMIO-140314-NOUP V:ILOGINIANCHORIPATRICK\31690C6_AN3. DOC 1 Introduction This data review covers 8 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA SW 846 Method 9060A for Total Organic Carbon and Dissolved Organic Carbon and Standard Method 2540D for Total Suspended Solids. The review follows a modified outline of the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review (January 2010). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, ,therefore qualification was not required. V:ILOGINIANCHORIPATRICKI31690C6_AN3,DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. Initial Calibration All criteria for the initial calibration of each method were met. III. Calibration Verification Calibration verification frequency and analysis criteria were met for each method when applicable. IV. Blanks Method blanks were reviewed for. each matrix as applicable. No contaminant concentrations were found in the initial, continuing and preparation blanks. V. Matrix Spike/Matrix Spike Duplicates Matrix spike (MS) and matrix spike duplicate (MSD) samples were reviewed for each matrix as applicable. Percent recoveries (%R) and relative percent differences (RPD) were within QC limits. VI. Duplicates Duplicate (DUP) sample analyses were reviewed for each matrix as applicable. Results were within QC limits. VII. Laboratory Control Samples Laboratory control samples were reviewed for each matrix as applicable. Percent recoveries (%R) were within QC limits.· VIII. Sample Result Verification The results for the dissolved organic carbon analysis were greater than the total organic compound analysis as follows: Concentration (mg/L) Sample PB081_A-1 SWM I0-140314-N V:ILOGINIANCHORIPATRICKI31690C6_AN3.DOC Dissolved organic carbon Total organic carbon 26.3 16.2 3 Raw data were not reviewed for this SDG. IX. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. The quality control criteria reviewed were met and are considered acceptable. Based upon the Stage 2B data validation all results are considered valid and usable for all purposes. X. Field Duplicates No field duplicates were identified in this SDG. XI. Field Blanks No field blanks were identified in this SDG. V:ILOGINIANCHORIPATRICKI31690C6_AN3. DOC 4 Patrick Bayou Wet Chemistry - Data Qualification Summary - SDG 31400395 No Sample Data Qualified in this SDG Patrick Bayou Wet Chemistry - Laboratory Blank Data Qualification Summary - SDG 31400395 No Sample Data Qualified in this SDG V:ILOGINIANCHORIPATRICKl31690C6_AN3. DOC 5 4-!-rlh ~ LDC #: 31690C6 VALIDATION COMPLETENESS WORKSHEET SDG #: 31400395 Stage 28 Laboratory: SGS Analytical Perspective Date: Page:-LofL Reviewer: v-2nd Reviewer: ~ ~ METHOD: (Analyte)__T.!..:o~t:=!a!-1O~r:1!::a!..!..1n~ic~C~a::!.!r~b~o~nL....!D~i~ss~o~lv.!!e~d:!....O~r:1!::a!..!..1n~ic~C~a::!.!r~b~o~n..l.!:::.!.....!...!~~~~=~='.:!!..L1--!...:::=-=~~= Solids (SM2540D) The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I I llalidation A[ea I {), I. Technical holding times II Initial calibration Ill. Calibration verification Pr~ IV Blanks f>r V Matrix Spike/Matrix Spike Duplicates ~ VI. />r Duplicates VII. Laboratory control samples VIII. Sample result verification IX. Overall assessment of data X. Field duplicates VI I=;olrl hl<>nlr., Note: br ~VJ Samplinq dates: , /1'111,-/ \rodsl ~\? b- Sl1tq ~ I ~ o¢3 ~~ 1 J vU) / Pr IJ, JJ = = A =Acceptable N Not provided/applicable SW = See worksheet ND No compounds detected R Rinsate FB = Field blank = Validated Samples: Comments = = = D Duplicate TB Trip blank EB Equipment blank ~ 1 PB070 B-2SWMID-140314-N 11 2 PB070 B-1SWMID-140314-N 12 3 PB079~WMID-140314-N \V\~ 21 31 22 32 13 23 33 4 PB081 A-1SWMID-140314-N 14 24 34 5 PB089-1SWMID-140314-N 15 25 35 6 PB085-1SWMID-140314-N 16 26 36 7 PBO}!fA-1SWMID-140314-N 17 27 37 18 28 38 19 29 39 20 30 40 8 9 10 ql "' \ (}v->f v/ Notes: _________________________________________________________________________________ 31690C6W.wpd I LDC #: 3'\ bl/v Vb VALIDATION FINDINGS WORKSHEET Page:-+--ot.,L:- Sample Specific Analysis Reference Reviewer: 2nd reviewer: ~ C!J All circled methods are applicable to each sample. Sample 10 (- '1 4- Parameter Matrix ~ 1- pH TDS CI F N0 3 N02 S04 P0 4 ALK CN- NH3 TKN GO~ CR6+ CI0 4 pH TDS CI F NO~ NO, SO P04 ALK CN- NH~ TKN TOC CR -..-' 6 + CI0 4 pH TDS CI F NO~ NO, SO PO ALK CN- NH~ TKN TOC CR6+ CIO ~ q I fil-/ (T0) ~ cfOV) ~ pH TDS CI F N03 NO, S04 P04 ALK CN- NHs TKN TOC CR6+ CIO _~ pH TDS CI F NO~ NO, SO PO.d ALK CN- NH~ TKN TOC CR6+ CIO '-----""./ pH TDS CI F N0 3 NO, S04 P04 ALK CN- NHs TKN TOC CR6+ CIO pH TDS CI F NOs NO, SO.d PO.d ALK CN- NH~ TKN TOC CR6+ CIO pH TDS CI F N03 NO, S04 P04 ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F NOs NO, SO PO ALK CN- NHs TKN TOC CR6+ CIO.d pH TDS CI F NOs NO, SO PO ALK CN- NH3 TKN TOC CR6+ CIO.d pH TDS CI F NOs NO, SO.d PO.d ALK CN- NH" TKN TOC CR6+ CIO pH TDS CI F N03 N02 SO PO ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F NO" NO, SO.d POd ALK CN- NH~ TKN TOC CR6+ CIO Jl.H TDS CI F NO...3. NO, S04 P04 ALK CN- NHs TKN TOC CR6+ ClOd pH TDS CI F NOs NO, SO.d PO ALK CN- NH~ TKN TOC CR6+ CIO pH TDS CI F NO~ NO, SO PO ALK CN- NH3 TKN TOC CR6+ CI0 4 pH TDS CI F NOs NO, SO POd ALK CN- NHs TKN TOC CR6+ CIO.d pH TDS CI F NOs NO? SO PO ALK CN- NH3 TKN TOC CR6+ CIO.d pH TDS CI F N03 NO, SO.d POd ALK CN- NH~ TKN TOC CR6+ CIO pH TDS CI F NOs NO? SO.d POd ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F N0 3 NO, SOd P0 4 ALK CN- NH" TKN TOC CR6+ CIO pH TDS CI F NOs NO, SO PO ALK CN- NH3 TKN TOC CR6+ CI0 4 pH TDS CI F NO" NO, S04 P04 ALK CN- NH" TKN TOC CR6+ CIO.d pH TDS CI F NO" NO, SO PO ALK CN- NH3 TKN TOC CR6+ CIO.d nHiDS GI F NO. NO. SO PO AI K r.N- NH_ TKNIOC GR 6+ GIO Comments: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ METHODS. 6 VALIDATION FINDINGS WORKSHEET Sample Result Verification LDC #: 31690C6 page:..lol_ Reviewer: c..-,./ 2nd Reviewer o-z... METHOD: Inorganics, Method ---"'S:..:::e""'e....::C'-'=o:..:..ve""'_ r _ _ __ # Sample 10 TOC (mg/L) DOC (mg/L) Finding Qualifications 1 4 16.2 26.3 DOC > TOe Dissolved> Total, Text Comments: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ LDC Report# 31690D6 Laboratory Data Consultants, Inc. Data Validation Report Project/Site Name: Patrick Bayou Collection Date: March 15,2014 LDC Report Date: April 24, 2014 Matrix: Water Parameters: Wet Chemistry Validation Level: Stage 2B Laboratory: SGS' Analytical Perspective Sample Delivery Group (SDG): 31400411 Sample Identification PB081 A-2SWMID-140315-N PB081 A-2SWMID-140315-NMS PB081 A-2SWMID-140315-NMSD V:ILOGINIANCHORIPATRICK\31690D6_AN3. DOC 1 Introduction This data review covers 3 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA SW 846 Method 9060A for Total Organic Carbon and Standard Method 25400 for Total Suspended Solids. The review follows a modified outline of the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review (January 2010). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SOG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, therefore qualification was not required. V:ILOGINIANCHORIPATRICKl31690D6_AN3. DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. Initial Calibration All criteria for the initial calibration of each method were met. III. Calibration Verification Calibration verification frequency and analysis criteria were met for each method when applicable. IV. Blanks Method blanks were reviewed for each matrix as applicable. No contaminant concentrations were found in the initial, continuing and preparation blanks. V. Matrix Spike/Matrix Spike Duplicates Matrix spike (MS) and matrix spike duplicate (MSD) samples were reviewed for each matrix as applicable. Percent recoveries (%R) and relative percent differences (RPD) were within QC limits. VI. Duplicates Duplicate (DUP) sample analyses were reviewed for each matrix as applicable. Results were within QC limits. VII. Laboratory Control Samples Laboratory control samples were reviewed for each matrix as applicable. Percent recoveries (%R) were within QC limits. VIII. Sample Result Verification Raw data were not reviewed for this SDG. IX. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. The quality control criteria reviewed were met and are considered acceptable. Based upon the Stage 2B data validation all results are considered valid and usable for all purposes. V:ILOGINIANCHORIPATRICKI31690D6_AN3. DOC 3 X. Field Duplicates No field duplicates were identified in this SDG. XI. Field Blanks No field blanks were identified in this SDG. V:ILOGINIANCHORIPATRICKI31690D6_AN3.DOC 4 Patrick Bayou Wet Chemistry - Data Qualification Summary - SDG 31400411 No Sample Data Qualified in this SDG Patrick Bayou Wet Chemistry - Laboratory Blank Data Qualification Summary - SDG 31400411 No Sample Data Qualified in this SDG V:ILOGINIANCHORIPATRICKI31690D6_AN3.DOC 5 LOC #: 3169006 VALIDATION SOG #: 31400411 Laboratory: SGS Analytical Perspective METHOD: (Analyte) Date1!~I'f ot. L COMPLETENESS WORKSHEET Stage 28 Page: Reviewer: 2nd Reviewer: 7 ""'- OJ<: Total Or anic Carbon EPA SW846 Method 906 The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I ~alidatiaD I A[ea I A A I. Technical holding times II Initial calibration III. Calibration verification A IV Blanks iY V Matrix Spike/Matrix Spike Duplicates Dr VI. Duplicates PI- VII. Laboratory control samples VIII. Sample result verification IX. Overall assessment of data X. Field duplicates YI !=;",In hl<>nl.-" Note: ~ ~ / I ~/ I Y I 'VV'I{J ~ ~.. ~ 3/~D07~ S , \~ I ~ f.I ~ = = = ND No compounds detected R = Rinsate FB Field blank = 1 Sampling dates: N A Acceptable N = Not provided/applicable SW See worksheet I ated S ampes: V aI'd CammeDts = = D Duplicate TB Trip blank EB = Equipment blank ~ PB081 A-2SWMID-140315-N 11 \tv'\'$ 21 31 ~\ ""-7 12 22 32 l/ \'1S'J 13 23 33 4 14 24 34 5 15 25 35 6 16 26 36 7 17 27 37 8 18 28 38 9 19 29 39 10 20 30 40 2 3 Notes: _________________________________________________________________________________ 31690D6W.wpd I VALIDATION FINDINGS WORKSHEET Sample Specific Analysis Reference Page:-+--of~ Reviewer: 2nd reviewer: v---:--- d1--- All circled methods are applicable to each sample. Sam~le I 10 /YL pH TOS CI F N03 N02 S04 P0 4 ALK CN- NH3 TKN Go~ CR6+ CI0 4 \Ts:j) . I (tv),3 Parameter Matrix pH TOS CI F NO~ NO, SO" PO" ALK CN- NH~ TKN TOC CR In-- pH TOS CI F NO~ 6 + -./ ~ CI0 4 N0 2 SO PO" ALK CN- NH .. TKN (-foC)CR6+ CIO ~ pH TOS CI F NO~ NO, SO" PO" ALK CN- NH~ TKN TOC CR6+ CIO pH TOS CI F NO~ N02 SO PO ALK CN- NH~ TKN TOC CR6+ CIO" pH TOS CI F NO~ NO, SO PO ALK CN- NH~ TKN TOC CR6+ CIO pH TOS CI F NO~ N02 SO PO ALK CN- NH .. TKN TOC CR6+ CIO" pH TOS CI F NO~ NO, SO PO" ALK CN- NH~ TKN TOC CR6+ CI0 4 pH TOS CI F NO.. NO, SO PO ALK CN- NH .. TKN TOC CR6+ CIO" pH TOS CI F N0 3 NO, SO" P04 ALK CN- NH~ TKN TOC CR6+ CIO pH TOS CI F NO" NO, SO" PO" ALK CN- NH" TKN TOC CR6+ CIO" pH TOS CI F N0 3 NO, SO" PO" ALK CN- NH~ TKN TOC CR6+ CIO pH TOS CI F NO~ NO, SO" PO" ALK CN- NH .. TKN TOC CR6+ CIO pH TOS CI F NO~ NO, SO PO ALK CN- NH~ TKN TOC CR6 + CIO" pH TOS CI F NO.. NO, SO PO ALK CN- NH3 TKN TOC CR6+ CIO pH TOS CI F N03 NO, SO P0 4 ALK CN- NH" TKN TOC CR6+ CIO" pH TOS CI F NO~ NO, SO PO ALK CN- NH~ TKN TOC CR6+ CIO" pH TOS CI F NO~ NO z S04 POA ALK CN- NH3 TKN TOC CR6+ CIO" pH TOS CI F NO" NO, SO" PO" ALK CN- NH" TKN TOC CR6+ CIO pH TOS CI F NO~ N02 S04 P04 ALK CN- NH3 TKN TOC CR6 + CI04 pH TOS CI F NO~ NO, SO PO ALK CN- NH~ TKN TOC CR6+ CIO pH TOS CI F NO~ NO, SO PO ALK CN- NH~ TKN TOC CR6+ CIO" pH TOS CI F NO:! NO, SO PO ALK CN- NH" TKN TOC CR6+ CIO pH TOS CI F NO" NO, SO PO ALK CN- NH~ TKN TOC CR6+ CIO" nH TOS r.1 F NO. N(). S() P() AI I( r.N- NH TKN TOe r.R 6+ r.1() Comments: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ METHODS.6 LDC Report# 31690E6 Laboratory Data Consultants, Inc. Data Validation Report Project/Site Name: Patrick Bayou Collection Date: March 18,2014 LDC Report Date: April 24, 2014 Matrix: Water Parameters: Wet Chemistry Validation Level: Stage 2B Laboratory: SGS Analytical Perspective Sample Delivery Group (SDG): 31400420 Sample Identification PB083-1 SWM ID-140318-N PB083-1 SWMID-140318-D PB087-1 SWMID-140318-N PB091-1 SWMID-140318-N PB093-1 SWMID-140318-N PB095-1 SWM ID-140318-N PB095-1 SWMID-140318-NDUP V:\LOGIN\ANCHOR\PATRICK\31690E6_AN3.DOC 1 Introduction This data review covers 7 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA SW 846 Method 9060A for Total Organic Carbon and Standard Method 25400 for Total Suspended Solids. The review follows a modified outline of the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review (January 2010). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (pro~ocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, therefore qualification was not required. V:ILOGINIANCHORIPATRICKI31690E6_AN3.DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. Initial Calibration All criteria for the initial calibration of each method were met. III. Calibration Verification Calibration verification frequency and analysis criteria were met for each method when applicable. IV. Blanks Method blanks were reviewed for each matrix as applicable. No contaminant concentrations were found in the initial, continuing and preparation blanks. V. Matrix Spike/Matrix Spike Duplicates Matrix spike (MS) and matrix spike duplicate (MSD) samples were reviewed for each matrix as applicable. Percent recoveries (%R) and relative percent differences (RPD) were within QC limits. VI. Duplicates Duplicate (DUP) sample analyses were reviewed for each matrix as applicable. Results were within QC limits. VII. Laboratory Control Samples Laboratory control samples were reviewed for each matrix as applicable: Percent recoveries (%R) were within QC limits. VIII. Sample Result Verification Raw data were not reviewed for this SDG. IX. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. The quality control criteria reviewed were met and are considered acceptable. Based upon the Stage 2B data validation all results are considered valid and usable for all purposes. V:ILOGIN\ANCHORIPATRICKI31690E6_AN3.DOC 3 X. Field Duplicates Samples PB083-1SWMID-140318-N and PB083-1SWMID-140318-D were identified as field duplicates. No contaminant concentrations were detected in any of the samples with the following exceptions: Concentration (mg/L) Analyte PB083-1SWMID-140318-N PB083-1SWMID-140318-D RPD Total organic carbon 10.3 10.2 1 Total suspended solids 5.0 3.6U 200 XI. Field Blanks No field blanks were identified in this SDG. V:ILOGINIANCHORIPATRICKI31690E6_AN3.DOC 4 Patrick Bayou Wet Chemistry - Data Qualification Summary - SDG 31400420 No Sample Data Qualified in this SDG Patrick Bayou Wet Chemistry - Laboratory Blank Data Qualification Summary - SDG 31400420 No Sample Data Qualified in this SDG V:\LOGIN\ANCHOR\PATRICK\31690E6_AN3.DOC 5 LDC #: 31690E6 VALIDATION SDG #: 31400420 Laboratory: SGS Analytical Perspective rlt" '1-( COMPLETENESS WORKSHEET Stage 2B Date Page:-!-of '--" Reviewer: 2nd Reviewer: / c:rz.- ,b METHOD: (Analyte) Total Organic Carbon(EPA SW846 Method 9060), Total Suspended Solids (SM2540D) The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I ~alidaticD I. Technical holding times II Initial calibration I A[ea I I.i..- IV Blanks ty V Matrix Spike/Matrix Spike Duplicates P, PrJJ' VI. Duplicates VII. Laboratory control samples I} VIII. Sample result verification N IX. Overall assessment of data f>r X. Field duplicates ~V-I )(1 l=i",lrI hl"nk", / IV< ~ //Vl c., In ~ ~ YJ"er, ~ I f Dll +t ~ \I'--"" = tIl -:Y') D = Duplicate TB Trip blank EB Equipment blank = = k&- PB083-1SWMID-140318-N 11 2 PB083-1SWMID-140318-D 3 \A.") 21 31 12 22 32 PB087-1SWMID-140318-N 13 23 33 4 PB091-1SWMID-140318-N 14 24 34 5 PB093-1 SWMID-140318-N 15 25 35 6 PB095-1SWMID-140318-N 16 26 36 17 27 37 8 18 28 38 9 19 29 39 10 20 30 40 ~~ ~V\D / L-v/ ND = No compounds detected R = Rinsate FB = Field blank 1 7 1-+ tV ~t, \? Notes: _________________________________________________________________________________ 31690F6W.wpd I LDC #: 3'\ 11 j ;0.1 1.... k> VALIDATION FINDINGS WURKSHt:1:: I page:--f.-0t~ Sample Specific Analysis Reference Reviewer: 2nd reviewer: v--:.-~ All circled methods are applicable to each sample, Sample 10 \-~ ~ Parameter Matrix pH TDS CI F N0 3 N02 S04 P0 4 ALK CN- NH3 TKN V pH TDS CI F N0 3 NO? S04 PO" ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F N0 3 NO? SO 4' ~ k\~ Y ~v G.O~ ~fl-- pH TDS CI F N0 3 NO? SO CR6+ CI0 4 PO ALK CN- NH3 TKN TOC CR6+ CIO PO ALK CN- NH3 TKN TOC CR pH TDS CI F N0 3 NO? S04 P0 4 ALK CN- NH3 TKN fc;C) CR '-.:0- 6 6 + CIO + CI0 4 iTS;) JLov ~-/ ~UL) ---- £J ../ '- . p_H TDS CI F N0 3 N02 SO PO ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F N03 NO? S04 P0 4 ALK CN- NH3 TKN TOC CR6+ CI0 4 pH TDS CI F N03 NO? SOd PO ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F N0 3 NO? SO PO ALK CN- NH3 TKN TOC CR6+ CI0 4 pH TDS CI F N03 NO? SO PO ALK CN- NH3 TKN TOC CR6+ CI0 4 pH TDS CI F N03 NO? S04 P0 4 ALK CN- NH3 TKN TOC CR6+ CI0 4 pH TDS CI F N03 NO? SO PO ALK CN- NH3 TKN TOC CR6+ CI0 4 pH TDS CI F N03 NO? SO P0 4 ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F N03 NO? SO PO ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F N03 NO? S04 P0 4 ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F N0 3 NO? S04 P04 ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F N03 NO? SO PO ALK CN- NH3 TKN TOC CR 6+ CI0 4 pH TDS CI F N03 NO? SO PO ALK CN- NH3 TKN TOC CR6+ ClOd pH TDS CI F N0 3 NO? S04 PO" ALK CN- NH3 TKN TOC CR6+ CI0 4 pH TDS CI F NO:,! NO? S04 P04 ALK CN- NH3 TKN TOC CR6 + ClOd pH TDS CI F N03 NO? SO PO ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F N03 NO? S04 P0 4 ALK CN- NH3 TKN TOC CR6+ CIO pH TDS CI F NO:,! NO? SO PO ALK CN- NH:l TKN TOC CR6 + CIO pH TDS CI F N0 3 NO? S04 P0 4 ALK CN- NH3 TKN TOC CR6+ CI0 4 nH Tns r.1 r: Nn Nn Comments: SO PO AI K r.N- NH TKN Tnr.CR 6+ r.ln ------------------------------------------------------------------------ METHODS.6 VALIDATION FINDINGS WORKSHEET LDC# 31960F6 Field Duplicates Page:_t_of / Reviewer: c...-2nd Reviewer: (;t1/ Inorganics: Method See Cover I I TOe Analyte I I Concentration (mg/L) 1 12.1 9.0 V:\FIELD DUPLICATES\FD_inorganic\31960F6.wpd I I 2 11.9 I RPD I I I 2 I I LDC Report# 31690G31 Laboratory Data Consultants, Inc. Data Validation Report Project/Site Name: Patrick Bayou Superfund Site Collection Date: March 11, 2014 LDC Report Date: May 5,2014 Matrix: Water Parameters: Polychlorinated Biphenyls as Congeners Validation Level: Stage 2B Laboratory: SGS North America, Inc. Sample Delivery Group (SDG): A6492 Sample Identification PB006.2-1 SWMID-140311-D (Total) PB006.2-1 SWMID-140311-D (Dissolved) PB006.2-1 SWMID-140311-N (Total) PB006.2-1 SWMID-140311-N (Dissolved) HSC14.1-1SWMID-140311-N (Total) V:\LOGINIANCHOR\PATRICK\31690G31_AN3. DOC 1 Introduction This data review covers 5 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA Method 1668A for Polychlorinated Biphenyls as Congeners. This review follows USEPA Contract Laboratory Program (CLP) National Functional Guidelines for Chlorinated Dibenzo-p-Dioxins (COOs) and Chlorinated Dibenzofurans (CDFs) Data Review (September 2011). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of the presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, .therefore qualification was not required. V:ILOGINIANCHORIPATRICKI31690G31_AN3.DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. HRGC/HRMS Instrument Performance Check Instrument performance was checked at the required daily frequency. Retention time windows were established for all congeners. The chromatographic resolution between the congeners PCB-23 and PCB-34 and congeners PCB-182 and PCB187 was resolved with a valley of less than or equal to 40%. III. Initial Calibration A five pOint initial calibration was performed as required by the method. Percent relative standard deviations (%RSD) were less than or equal to 20.0% for all compounds. The ion abundance ratios for all PCBs were within method criteria with the following exceptions: Date Standard ID Compound Ion Abundance Ratio (Limits) .Associated Samples 2/5/14 140205S03 PC8-4 to PC8-15 0.00 (1.33-1.79) All samples in SDGA6492 Affected Compounds PC8-4 PC8-5 PC8-6 PC8-7 PC8-8 PC8-9 PC8-10 PC8-11 PC8-12 PC8-13 PC8-14 PC8-15 Flag AorP J (all detects) UJ (all non-detects) P The minimum SIN ratio was greater than or equal to 10 for each unlabeled compound and labeled compound. IV. Routine Calibration (Continuing) Routine calibration was performed at the required frequencies. All of the routine calibration percent differences (%D) between the initial calibration RRF and the routine calibration RRF were less than or equal to 30.0% for unlabeled compounds and less than or equal to 50.0% for labeled compounds. V:\LOGINIANCHOR\PATRICK\31690G31_AN3.DOC 3 The ion abundance ratios for all PCBs were within method criteria. V. Blanks Method blanks were reviewed for each matrix as applicable. No polychlorinated biphenyls as congeners contaminants were found in the method blanks with the following exceptions: Method Blank 10 MB1_11883 Extraction Date 3/14/14 Compound Concentration PCB-11 6.09 pg/L Associated Samples All samples in SDG A6492 Sample concentrations were compared to concentrations detected in the method blanks. The sample concentrations were either not detected or were significantly greater (>5X blank contaminants) than the concentrations found in the associated method blanks with the following exceptions: Sample Compound Reported Concentration Modified Final Concentration PB006.2-1SWMID-140311-D (Total) PCB-11 29.8 pg/L 29.8U pg/L PB006.2-1 SWM ID-140311-D (Dissolved) PCB-11 30 pg/L 30U pg/L HSC14.1-1SWMID-140311-N (Total) PCB-11 23.3 pg/L 23.3U pg/L VI. Matrix Spike/Matrix Spike Duplicates The laboratory has indicated that there were no matrix spike (MS) and matrix spike duplicate (MSO) analyses specified for the samples in this SOG, and therefore matrix spike and matrix spike duplicate analyses were not performed for this SOG. VII. Ongoing Precision & Recovery Samples (OPR) Ongoing precision and recovery (OPR).control samples were reviewed for each matrix as applicable. The percent recoveries (%R) were within the QC limits. VIII. Regional Quality Assurance and Quality Control Not applicable. IX. Internal Standards All internal standard recoveries (%R) were within QC limits. V:\LOGINIANCHOR\PATRICK\31690G31_AN3. DOC 4 X. Target Compound Identifications Raw data were not reviewed for this SDG. XI. Compound Quantitation All compound quantitations were within validation criteria with the following exceptions: Sample All samples in SDG A6492 Compound Flag AorP All compounds reported by the laboratory as estimated maximum possible concentration (EMPC) J (all detects) A Raw data were not reviewed for this SDG. XII. System Performance Raw data were not reviewed for this SDG. XIII. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. Due to initial calibration ion abundance ratio and compound quantitation problems, data were qualified as estimated in five samples. Due to method blank contamination problems, data were qualified as nondetected in three samples. The quality control criteria reviewed, other than those discussed above, were met and are considered acceptable. Sample results that were found to be estimated (J) are usable for limited purposes only. Based upon the Stage 2B data validation all other results are considered valid and usable for all purposes. Data flags are summarized at the end of this report if data has been qualified. XIV. Field Duplicates No field duplicates were identified in this SDG. XV. Field Blanks No field blanks were identified in this SDG. V:\LOGIN\ANCHOR\PATRICK\31690G31_AN3. DOC 5 Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Data Qualification Summary - SDG A6492 SDG Sample A6492 PB006.2-1SWMID-140311-D (Total) PB006.2-1 SWM ID-140311-D (Dissolved) PB006.2-1SWMID-140311-N (Total) PB006.2-1SWMID-140311-N (Dissolved) HSC14.1-1SWMID-140311-N (Total) PCB-4 PCB-5 PCB-6 PCB-7 PCB-8 PCB-9 PCB-10 PCB-11 PCB-12 PCB-13 PCB-14 PCB-15 A6492 PB006.2-1SWMID-140311-D (Total) PB006.2-1SWMID-140311-D (Dissolved) PB006.2-1SWMID-140311-N (Total) PB006.2-1 SWM ID-140311-N (Dissolved) HSC14.1-1SWMID-140311-N (Total) All compounds reported by the laboratory as estimated maximum possible concentration (EM PC) Compound FI~ AorP J (all detects) UJ (all non-detects) P Initial calibration (ion abundance ratio) J (all detects) A Com·pound quantitation Reason Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Laboratory Blank Data Qualification Summary - SDG A6492 SDG Sample Compound Modified Final Concentration AorP A6492 PB006.2-1SWMID-140311-D (Total) PCB-11 29.8U pg/L A A6492 PB006.2-1 SWMID-140311-D (Dissolved) PCB-11 30U pg/L A A6492 HSC14.1-1SWMID-140311-N (Total) PCB-11 23.3U pg/L A V:\LOGINIANCHOR\PATRICK\31690G31_AN3. DOC 6 LDC #: 31690G31 VALIDATION COMPLETENESS WORKSHEET SDG#: A6492 Stage 28 Laboratory: ~3 Allalytical PkRtCLive (;S N()v-/;'h e n'c. CL.METHOD: HRGC/HRMS Polychlorinated Biphenyl Congeners (EPA Method 1668A) Date: 5--;).-ILf Page:--Lof~ Reviewer: ~ 2nd Reviewer: m == The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I I llaJidatioD A[ea I. Technical holding times II. GC/MS Instrument performance check liI. Initial calibration IV. Continuing calibration/fe'Ir V. Blanks VI. A ASvJ I Sampling dates: 3/" f,y. ~ ;;)0 A '?30/sO Matrix spike/Matrix spike duplicates I\J (·S· VII. Laboratory control samples A VIII. Regional quality assurance and quality control N IX. Internal standards A x. Target compound identifications N XI. Compound quantitation/RUL.QQ/I.OOs XII. System performance N XIII. Overall assessment of data A XIV. Field duplicates AI XV. Field blanks td Note: I Com meets 5vJ = = A Acceptable N Not provided/applicable SW = See worksheet O"f>e ~~ ND = No compounds detected R Rinsate FB Field blank = = = = D Duplicate TB Trip blank EB = Equipment blank I Val'dated Sam PIes: ~ ~ 1 PB006.2-1SWMID-140311-D (Total) 11 21 31 2 PB006.2-1SWMID-140311-D (Dissolved) 12 22 32 3 PB006.2-1SWMID-140311-N (Total) 13 23 33 4 PB006.2-1SWMID-140311-N (Dissolved) 14 24 34 5 HSC14.1-1SWMID-140311-N (Total) 15 25 35 6 16 26 36 7 17 27 37 8 18 28 38 9 19 29 39 10 20 30 40 31690G31W.wpd t--\b\_ \I ~<6 ~ LDC #: 3! t9<'lOG3) VALIDATION FINDINGS WORKSHEET Initial Calibration page:-LocJ_ Reviewer:~ 2nd Reviewer: __ ~-=~ METHOD: HRGC/HRMS Polychlorinated Biphenyls (EPA Method 1668A) Please see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". roN N/A Was the initial calibration performed at 5 concentration levels? IDN N/A Were all percent relative standard deviations (%RSD) .:=: 20% for unlabeled standards and labeled standards? yeN N/A Did all calibration standards meet the Ion Abundance Ratio criteria? y N (JIN Was the signal to noise ratio for each target compound> 2.5 and for each recovery and internal standard> 10? '-' # Date 02/05/14 D Standard ID Compound 140205S03 PCB-4 to PCB-15 Halogen Selected ions (m/z) Finding Ion Abundace Ratio Finding %RSD 0.00 Ion Abundace Ratio D (1.33-1.79) Halogen J/UJ/P (PCB-4 to PCB-15,'fotal All Selected ions (m/z) 1 CI M/M+2 7CI M/M+2 2CI M/M+2 7CI M+2/M+4 3CI M/M+2 BCI M+2/M+4 4CI M/M+2 9CI M/M+2 5CI M+2/M+4 9Cl M/M-2 6CI M/M+2 10 Cl M/M+2 6CI M+2/M+4 1668-INICAL_SGS.wpd Qualifications Associated Samples Bi-eBS~ Ion Abundace Ratio VALIDATION FINDINGS WORKSHEET Blanks LDC #: 31690G31 page:_lofL Reviewer: 2nd Reviewer: METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) ~ase see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". Qt N N/~ Were all samples associated with a method blank? Y N Nt Was a method blank performed for each matrix and whenever a sample extraction was performed? ~N N/A Was the method blank contaminated? ank extraction date: 03/14/14 Blank analysis date: Conc. units:JLq/L I~t Associated samples: 03/24/14 Sian 10 Sample Identification MB1 11883 5x 1 2 5 PCB-11 6.09 30.5 29.8 30* 23.3 .,.. ,.. 'V,g, ..... ,..,.., rc9 - v.v" ,Ju.;)· All contaminants within five times the method blank concentration were qualified as not detected. V:\Validation-Blanks\31690G31.wpd All Qy."a..Q lA.. c:::rh::! c:z.-. LOC #: 31 ~qo~?:J VALIDATION FINDINGS WORKSHEET Compound Quantitation and Reported CRQLs Page: _1_of_1_ Reviewer:~ 2nd Reviewer: Qz. METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) Please see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". ~ ~ # I I Were the correct internal standard (IS), quantitation ions and relative response factors (RRF) used to quantitate the compound? Compound quantitation and CRQLs were adjusted to reflect all sample dilutions and dry weight factors (if necessary). Date Compound I I Finding Associated Samples Qualifications EMPC results All Jdets/A I I I Comments: __________________________________________________________________________________________________________ P:lAnchor_PO\1668-COMQUA.wpd LDC Report# Laboratory Data Consultants, Inc. Data Va.lidation Report Project/Site Name: Patrick Bayou Superfund Site Collection Date: March 13, 2014 LDC Report Date: May 5,2014 Matrix: Water Parameters: Polychlorinated Biphenyls as Congeners Validation Level: Stage 2B Laboratory: SGS North America, Inc. Sample Delivery Group (SDG): A6504 Sample Identification PB020-1 SWMID-140313-N (TOTAL) PB031.1-1SWMID-140313-N (TOTAL) PB047.3-1SWMID-140313-N (TOTAL) PB056_C-1SWMID-140313-N (TOTAL) PB056_C-1SWMID-140313-N (DISSOLVED) EF006.1-1 SWMID-140313-N (TOTAL) PB119_B-1SWMID-140313-N (TOTAL) EB1-01 (TOTAL) EB1-01 (DISSOLVED) V:ILOGINIANCHORIPATRICKI31690H31_AN3.DOC 1 ~1690H31 Introduction This data review covers 5 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA Method 1668A for Polychlorinated Biphenyls as Congeners. This review follows USEPA Contract Laboratory Program (CLP) National Functional Guidelines for Chlorinated Dibenzo-p-Dioxins (COOs) and Chlorinated Dibenzofurans (CDFs) Data Review (September 2011). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of the presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, therefore qualification was not required. V:ILOGINIANCHORIPATRICKI31690H31_AN3.DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. HRGC/HRMS Instrument Performance Check Instrument performance was checked at the required daily frequency. Retention time windows were established for all congeners. The chromatographic resolution between the congeners PCB-23 and PCB-34 and congeners PCB-182 and PCB187 was resolved with a valley of less than or equal to 40%. III. Initial Calibration A five pOint initial calibration was performed as required by the method. Percent relative standard deviations (%RSD) were less than or equal to 20.0% for all compounds. The ion abundance ratios for all PCBs were within method criteria. The minimum SIN ratio was greater than or equal to 10 for each unlabeled compound and labeled compound. . IV. Routine Calibration (Continuing) Routine calibration was performed at the required frequencies. All of the routine calibration percent differences (%D) between the initial calibration RRF and the routine calibration RRF were less than or equal to 30.0% for unlabeled compounds and less than or equal to 50.0% for laheled compounds. The ion abundance ratios for all PCBs were within method criteria. V. Blanks Method blanks were reviewed for each matrix as applicable. No polychlorinated biphenyls as congeners contaminants were found in the method blanks with the following exceptions: V:\LOGINIANCHOR\PATRICK\31690H31_AN3. DOC 3 Method Blank ID MB1_11892 Extraction Date 3/18/14 Compound PCB-118 PCB-11 PCB-31 PCB-28/20 PCB-52 PCB-69/49 Concentration 2.52 pg/L 8.96 pg/L 2.28 pg/L 2.49 pg/L 4.39 pg/L 2 pg/L 3.07 pg/L 2.85 pg/L 3.83 pg/L 4.13 pg/L 2.77 pg/L 2.56 pg/L 2.84 pg/L 2.82 pg/L PCB-44/47/65 PCB-61 170174176 PCB-95 PCB-113/90/101 PCB-110 PCB-147/149 PCB-153/168 PCB-163/138/129 Associated Samples All samples in SDG A6504 Sample concentrations were compared to concentrations detected in the method blanks. The sample concentrations were either not detected or were significantly greater (>5X blank contaminants) than the concentrations found in the associated method blanks with the following exceptions: Sample Compound Reported Concentration Modified Final Concentration PB020-1SWMID-140313-N (TOTAL) PCB-11 30.7 pg/L 30.7U pg/L PB031.1-1SWMID-140313-N (TOTAL) PCB-11 23.5 pg/L 23.5U pg/L PB047.3-1SWMID-140313-N (TOTAL) PCB-11 18.8 pg/L 18.8U pg/L PB056_C-1SWMID-140313-N (TOTAL) PCB-11 30.9 pg/L 30.9U pg/L PB056_C-1 SWMID-140313-N (DISSOLVED) PCB-11 24.3 pg/L 24.3U pg/L EF006.1-1SWMID-140313-N (TOTAL) PCB-11 23.1 pg/L 23.1U pg/L PB119_B-1SWMID-140313-N (TOTAL) PCB-11 PCB-69/49 PCB-95 15 pg/L 9.2 pg/L 16 pg/L 19.3 pg/L 15U pg/L 9.2U pg/L 16U pg/L 19.3U pg/L 2.66 pg/L 13 pg/L 3.3 pg/L 4.85 pg/L 4.45 pg/L 2.85 pg/L 4.66 pg/L 4.16 pg/L 4.57 pg/L 4.57 pg/L 2.32 pg/L 4.18 pg/L 2.66U pg/L 13U pg/L 3.3U pg/L 4.85U pg/L 4.45U pg/L 2.85U pg/L 4.66U pg/L 4.16U pg/L 4.57U pg/L 4.57U pg/L 2.32U pg/L 4.18U pg/L PCB-113/90/101 EB1-01 (TOTAL) PCB-118 PCB-11 PCB-31 PCB-28/20 PCB-52 PCB-69/49 PCB-95 PCB-113/90/101 PCB-110 PCB-147/149 PCB-153/168 PCB-163/138/129 V:\LOGINIANCHOR\PATRICK\31690H31_AN3.DOC 4 Sample . Compound EB1-01 (DISSOLVED) Reported Concentration Modified Final Concentration 1.73 pg/L 11.6 pg/L 3.09 pg/L 4.76 pg/L 4.05 pg/L 2.45 pg/L 4.48 pg/L 3.45 pg/L 3.32 pg/L 3.51 pg/L 2.57 pg/L 2.29 pg/L 1.73U pg/L 11.6U pg/L 3.09U pg/L 4.76U pg/L 4.05U pg/L 2.45U pg/L 4.48U pg/L 3.45U pg/L 3.32U pg/L 3.51U pg/L 2.57U pg/L 2.29U pg/L PCB-118 PCB-11 PCB-31 PCB-28/20 PCB-52 PCB-69/49 PCB-61 170174176 PCB-95 PCB-113/90/101 PCB-110 PCB-147/149 PCB-153/168 VI. Matrix Spike/Matrix Spike Duplicates The laboratory has indicated that there were no matrix spike (MS) and matrix spike duplicate (MSD) analyses specified for the samples in this SDG, and therefore matrix spike and matrix spike duplicate analyses were not performed for this SDG. VII. Ongoing Precision & Recovery Samples (OPR) Ongoing precision and recovery (OPR) control samples were reviewed for each matrix as applicable. The percent recoveries (%R) and relative percent differences (RPD) were within the QC limits. VIII. Regional Quality Assurance and Quality Control Not applicable. IX. Internal Standards All internal standard recoveries (%R) were within QC limits. X. Target Compound Identifications Raw data were not reviewed for this SDG. XI. Compound Quantitation All compound quantitations were within validation criteria with the following exceptions: I Sample All samples in SDG A6504 I Compound All compounds reported by the laboratory as estimated maximum possible concentration (EMPC) Raw data were not reviewed for this SDG. V:ILOGINIANCHORIPATRICKI31690H31_AN3.DOC 5 I Flag J (all detects) I AorP A I XII. System Performance Raw data were not reviewed for this SDG. XIII. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. Due to compound quantitation problems, data were qualified as estimated in nine samples. Due to method blank contamination problems, data were qualified as nondetected in nine samples. The quality control criteria reviewed, other than those discussed above, were met and are considered acceptable. Sample results .that were found to be estimated (J) are usable for limited purposes only. Based upon the Stage 2B data validation all other results are considered valid and usable for all purposes. Data flags are summarized at the end of this report if data has been qualified. XIV. Field Duplicates No field duplicates were identified in this SDG. XV. Field Blanks Samples EB-1-01 (TOTAL) and EB1-01 (DISSOVLED) were identified as equipment blanks. No polychlorinated biphenyls as congeners contaminants were found with the following exceptions: Blank 10 EB-1-01 (TOTAL) Compound PCB-118 PCB-8 PCB-11 PCB-17 PCB-31 PCB-28/20 PCB-21/33 PCB-51 PCB-52 PCB-69/49 PCB-44/47/65 PCB-68 PCB-95 PCB-113/90/101 PCB-110 PCB-147/149 PCB-153/168 PCB-163/138/129 PCB-187 PCB-180/193 V:ILOGINIANCHORIPATRICKI31690H31_AN3.DOC Concentration (pg/L) 2.66 3.13 13 8.35 3.3 4.85 4.52 81.8 4.45 2.85 29.3 37.1 4.66 4.16 4.57 4.57 2.32 4.18 1.86 2.84 6 Blank 10 EB1-01 (DISSOVlED) Compound 1.73 11.6 5.99 2.98 3.09 4.76 4.35 1.95 52.5 4.05 2.45 22.2 33.1 4.48 2.47 3.45 3.32 3.51 2.57 2.29 PCB-118 PCB-11 PCB-17 PCB-25 PCB-31 PCB-28/20 PCB-21 133 PCB-22 PCB-51 PCB-52 PCB-69/49 PCB-44/47/65 PCB-68 PCB-61170174176 PCB-66 PCB-95 PCB-113/90/101 PCB-110 PCB-147/149 PCB-153/168 V:ILOGINIANCHORIPATRICKI31690H31_AN3. DOC Concentration (pall) 7 Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Data Qualification Summary - SDG A6504 I SOG A6504 I I Sample PB020-1SWMID-140313-N (TOTAL) PB031.1-1SWMID-140313-N (TOTAL) PB047.3-1SWMID-140313-N (TOTAL) PB056_C-1SWMID-140313-N (TOTAL) PB056_C-1SWMID-140313-N (DISSOLVED) EF006.1-1SWMID-140313-N (TOTAL) PB119_B-1SWMID-140313-N (TOTAL) EB1-01 (TOTAL) EB1-01 (DISSOLVED) Compound I All compounds reported by the laboratory as estimated maximum possible concentration (EMPC) Fla~ I AorP J (all detects) A I Reason Compound quantitation Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Laboratory Blank Data QuaUfication Summary - SDG A6504 SOG Sample Compound Modified Final Concentration AorP A6504 PB020-1SWMID-140313-N (TOTAL) PCB-11 30.7U pg/L A A6504 PB031.1-1SWMID-140313-N (TOTAL) PCB-11 23.5U pg/L A A6504 PB047.3-1SWMID-140313-N (TOTAL) PCB-11 18.8U pg/L A A6504 PB056_C-1SWMID-140313-N (TOTAL) PCB-11 30.9U pg/L A A6504 PB056_C-1SWMID-140313-N (DISSOLVED) PCB-11 24.3U pg/L A A6504 EF006.1-1SWMID-140313-N (TOTAL) PCB-11 23.1U pg/L A A6504 PB119_B-1SWMID-140313-N (TOTAL) PCB-11 PCB-69/49 PCB-95 PCB-113/90/101 15U pg/L 9.2U pg/L 16U pg/L 19.3U pg/L A A6504 EB1-01 (TOTAL) PCB-118 PCB-11 PCB-31 PCB-28/20 PCB-52 PCB-69/49 PCB-95 PCB-113/90/101 PCB-110 PCB-147/149 PCB-153/168 PCB-163/138/129 2.66U pg/L 13U pg/L 3.3U pg/L 4.85U pg/L 4.45U pg/L 2.85U pg/L 4.66U pg/L 4.16U pg/L 4.57U pg/L 4.57U pg/L 2.32U pg/L 4.18U pg/L A V:\LOGINIANCHOR\PATRICK\31690H31_AN3. DOC 8 I SDG A6504 Sample EB1-01 (DISSOLVED) Compound PCB-118 PCB-11 PCB-31 PCB-28/20 PCB-52 PCB-69/49 PCB-61170174176 PCB-95 PCB-113/90/101 PCB-11 0 PCB-147/149 PCB-153/168 V:\LOGINIANCHOR\PATRICK\31690H31_AN3. DOC 9 Modified Final Concentration 1.73U pg/L 11.6U pg/L 3.09U pg/L 4.76U pg/L 4.05U pg/L 2.45U pg/L 4.48U pg/L 3.45U pg/L 3.32U pg/L 3.51U pg/L 2.57U pg/L 2.29U pg/L AorP A VALIDATION COMPLETENESS WORKSHEET LDC #: 31690H31 SDG#: A6504 Stage 28 Laboratory: SGS Analytical Perspective -5<;"::> N &<-\'h. ~ e v\ et>.METHOD: HRGC/HRMS Polychlorinated Biphenyl Congeners (EPA Method 1668A) Date: 5-;).-1<-} Page:..Lof-L Reviewer:--St::1......2nd Reviewer:~ The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I I llalidatioD lama I. Technical holding times II. GC/MS Instrument performance check III. Initial calibration IV. ContinuinQ calibrationfie'lt""" V. Blanks VI. Matrix spike/Matrix spike duplicates VII. Laboratory control samples VIII. Regional quality assurance and quality control IX. Internal standards x. Target compound identifications XI. Compound quantitation/RULGQ,lbG8s XII. System performance XIII. Overall assessment of data XIV. Field duplicates XV. Note: A A ~ SW = = = I Cam meets 3 JI?>/JLf Sampling dates: ~ :;;>-0 ~ ~o/s:o c-> . N A IOF~ N A N ~'f'J N A N SyJ EB-:::1S',q Field blanks A Acceptable N Not provided/applicable SW See worksheet A I = = = NO No compounds detected R Rinsate FB Field blank 0= Duplicate TB EB =Trip blank =Equipment blank Validated Samples' .~/ 1 PB020-1SWMID-140313-N (TOTAL) 11 21 31 2 PB031.1-1SWMID-140313-N (TOTAL) 12 22 32 3 PB047.3-1SWMID-140313-N (TOTAL) 13 23 33 4 PB056 C-1SWMID-140313-N (TOTAL) 14 24 34 5 PB056 C-1SWMID-140313-N (DISSOLVED) 15 25 35 6 EF006.1-1SWMID-140313-N (TOTAL) 16 26 36 7 PB119 B-1SWMID-140313-N (TOTAL) 17 27 37 8 EB1-01 (TOTAL) 18 28 38 9 EB1-01 (DISSOLVED) 19 29 39 30 40 10 20 31690H31W.wpd MB'_I \<6 q).. VALIDATION FINDINGS WORKSHEET Blanks LDC #: 31690H31 Page:Lof 2nd Reviewer:~ METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) Please see N NIA Y N I Y N A qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". Were all samples associated with a method blank? Was a method blank performed for each matrix and whenever a sample extraction was performed? Was the method blank contaminated? Blank extraction date:_---!::.03!:::!/....!.1:::!-'8/'-!1.::!:4__ Blank analysis date: Conc. units· naIL I~[ Associated samples:,_.!....A!!!II__Q=ua::::.!I'-!U~_ 03/26/14 B~nkiD Sample Identification MB1, 11892 5x PCB-118 2.52 12.6 PCB-11 8.96 44.8 PCB-31 2.28* PCB-28/20 PCB-52 8 9 2.66 1.73* 13 11.6 11.4 3.3 3.09 2.49* 12.5 4.85 4.76 4.39* 22.0 4.45* 4.05* 2 10.0 2.85 2.45 PCB-44/47/65 3.07* 15.4 PCB-61 170/74/76 2.85 14.3 PCB-95 3.83* 19.2 16 4.66 3.45* PCB-113/90/101 4.13 20.7 19.3 4.16 3.32 PCB-110 2.77* 13.9 4.57 3.51 PCB-147/149 2.56* 12.8 4.57* 2.57 PCB-153/168 2.84 14.2 2.32* 2.29 2.82 14.1 4.18* l:! .... '" A PCB-69/49 PCB-163/138/129 1 30.7 2 23.5 3 18.8* 4 30.9 5 24.3 6 23.1 7 15 9.2 4.48 .~ I oral UI-v-OS 0 ~. Imar Z;nt I d'ral I etra-CBs V:\Validation-Blanks\31690H31.wpd '12.3' 01.0 .:I- Reviewer:~ i i '" VALIDATION FINDINGS WORKSHEET Compound Quantitation and Reported CRQLs Page: _1_of_1_ Reviewer:~ 2nd Reviewer: c-t... METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) Please see qualifications below for all questions answered "N", Not applicable questions are identified as "N/A", ~ ~ # I I Were the correct internal standard (IS), quantitation ions and relative response factors (RRF) used to quantitate the compound? Compound quantitation and CRQLs were adjusted to reflect all sample dilutions and dry weight factors (if necessary), Date Compound I I Finding Associated Samples Qualifications EMPC results All Jdets/A I I I Comments: __________________________________________________________________ P:lAnchor_PO\1668-COMQUA. wpd LDC #: 31'\tAQ~2) J. COv VALIDATION FINDINGS WORKSHEET Field Blanks Page:--Lof Reviewer: 2nd reviewer: C!2- METHOD: HRGC/HRMS Polychlorinated Biphenyl Congeners EPA Method 1668A ~ Were field blanks identified in this SDG? Were target compounds detected in the field blanks? ~ Sample: _ _--=E=B=----(...,,8:.L.)_ _ __ I Field Blank I Trip Blank I Rinsate (circle one) Com~ound I Concentration Units ! ~g/L I PCB-118 2.66 PCB-8 3.13 PCB-11 13 PCB-17 8.35 PCB-31 3.3 PCB-28/20 4.85 PCB-21 133 4.52* PCB-51 81.8 PCB-52 4.45* PCB-69/49 2.85 PCB-44/47/65 29.3 PCB-68 37.1 PCB-95 4.66 PCB-113/90/101 4.16 PCB-110 4.57 PCB-147/149 4.57* PCB-153/168 2.32* PCB-163/138/129 4.18* PCB-187 1.86* PCB-180/193 2.84 T~I OJ-CBs-. ~ -. -46+- T-otel +fi 6Bs- ~ Total Tetre eBs- -155 'l=gtal eiiR~e.s~ T~11:I8*a lotal GSs epta-I,.,!:SS" * EMPC FLDBLK16.wpd HI ~ ...,1.:U.!-- ~ - I LDC #?;4 LAD K~' Page: ~ of.2:.. Reviewer: ~ 2nd reviewer: C(1../' VALIDATION FINDINGS WORKSHEET Field Blanks METHOD: HRGC/HRMS Polychlorinated Biphenyl Congeners EPA Method 1668A Were field blanks identified in this SDG? Were target compounds detected in the field blanks? N N/A Y N N/A Sample: _ _....:E:.;B=--.>..:(9:..t.)_ _ _ _ Field Blank I Trip Blank I Rinsate (circle one) I Com~ound I Concentration Units ! ~g/L I PCB-118 1.73* PCB-11 11.6 PCB-17 5.99 PCB-25 2.98 PCB-31 3.09 PCB-28/20 4.76 PCB-21/33 4.35* PCB-22 1.95* PCB-51 52.5 PCB-52 4.05* PCB-69/49 2.45 PCB-44/47/65 22.2 PCB-68 33.1 PCB-61/70/74/76 4.48 PCB-66 2.47 PCB-95 3.45* PCB-113/90/101 3.32 PCB-110 3.51 PCB-147/149 2.57 PCB-153/168 2.29 T..Qtal Di-C~ ~ ~ ~ T-etal 'feUa-C8s" ~ 'Fe~el ~ Pel Ita-CBS -foral Ri!!xa-CBs *EMPC FLDBLK16_2.wpd 4.86 I LDC Report# 31690131 Laboratory Data Consultants, Inc. Data Validation Report Project/Site Name: Patrick Bayou Superfund Site Collection Date: March 14, 2014 LDC Report Date: May 8,2014 Matrix: Water Parameters: Polychlorinated Biphenyls as Congeners Validation Level: Stage 2B Laboratory: SGS North America, Inc. Sample Delivery Group (SDG): A6506 Sample Identification PB070_B-2SWMID-140314-N (TOTAL) PB070_B-1 SWMID-140314-N (TOTAL) PB079-1SWMID-140314-N (TOTAL) PB081_A-1SWMID-140314-N (TOTAL) PB081_A-1SWMID-140314-N (DISSOLVED) PB089-1SWMID-140314-N (TOTAL) PB085-1 SWMID-140314-N (TOTAL) P B097A-1 SWM ID -140314-N (TOTAL) V:ILOGINIANCHORIPATRICKI31690131_AN3.DOC 1 Introduction This data review covers 8 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA Method 1668A for Polychlorinated Biphenyls as Congeners. This review follows USEPA Contract Laboratory Program (CLP) National Functional Guidelines for Chlorinated Dibenzo-p-Dioxins (CDDs) and Chlorinated Dibenzofurans (CDFs) Data Review (September 2011). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of the presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, therefore qualification was not required. V:\LOGIN\ANCHOR\PATRICK\31690131_AN3,DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. HRGC/HRMS Instrument Performance Check Instrument performance was checked at the required daily frequency. Retention time windows were established for all congeners. The chromatographic resolution between the congeners PCB-23 and PCB-34 and congeners PCB-182 and PCB187 was resolved with a valley of less than or equal to 40%. III. Initial Calibration A five point initial calibration was performed as required by the method. Percent relative standard deviations (%RSO) were less than or equal to 20.0% for all compounds. The ion abundance ratios for all PCBs were within method criteria. The minimum SIN ratio was greater than or equal to 10 for each unlabeled compound and labeled compound. IV. Routine Calibration (Continuing) Routine calibration was performed at the required frequencies. All of the routine calibration percent differences (%0) between the initial calibration RRF and the routine calibration RRF were less than or equal to 30.0% for unlabeled compounds and less than or equal to 50.0% for labeled compounds. The ion abundance ratios for all PCBs were within method criteria. V. Blanks Method blanks were reviewed for each matrix as applicable. No polychlorinated biphenyls as congeners contaminants were found in the method blanks with the following exceptions: V:ILOGINIANCHORIPATRICKI31690131_AN3.DOC 3 Method Blank ID MB1_11899 Extraction Date 3/19/14 Compound PCB-105 PCB-118 PCB-8 PCB-11 PCB-30/18 PCB-31 PCB-28/20 PCB-21/33 PCB-52 PCB-69/49 PCB-44/47/65 PCB-61 170/74/76 PCB-66 PCB-95 PCB-84 PCB-113/90/101 PCB-99 PCB-108/119/86/97/125/87 PCB-116/85 PCB-110 PCB-136 PCB-147/149 PCB-132 PCB-153/168 PCB-163/138/129 PCB-180/193 Concentration 1.06 pg/L 2.29 pg/L 1.64 pg/L 7.71 pg/L 2.66 pg/L 2.29 pg/L 2.34 pg/L 1.53 pg/L 3.95 pg/L 1.78 pg/L 2.6 pg/L 2.76 pg/L 1.4 pg/L 3.4 pg/L 0.983 pg/L 3.6 pg/L 1.71 pg/L 2.7 pg/L 0.686 pg/L 3.95 pg/L 0.87 pg/L 3.22 pg/L 1.79 pg/L 2.53 pg/L 3.12 pg/L 1.57 pg/L Associated Samples All samples in SDGA6506 Sample concentrations were compared to concentrations detected in the method blanks. The sample concentrations were either not detected or were significantly greater (>5X blank contaminants) than the concentrations found in the associated method blanks with the following exceptions: Sample Compound Reported Concentration Modified Final Concentration PB070_B-2SWMID-140314-N (TOTAL) PCB-11 36.3 pg/L 36.3U pg/L PB070_B-1SWMID-140314-N (TOTAL) PCB-11 35 pg/L 35U pg/L PB079-1SWMID-140314-N (TOTAL) PCB-11 28.1 pg/L 28.1U pg/L PB081_A-1SWMID-140314-N (TOTAL) PCB-11 29 pg/L 29U pg/L PB081_A-1SWMID-140314-N (DISSOLVED) PCB-11 34.5 pg/L 34.5U pg/L PB089-1SWMID-140314-N (TOTAL) PCB-11 37.4 pg/L 37.4U pg/L PB085-1SWMID-140314-N (TOTAL) PCB-11 30.7 pg/L 30.7U pg/L PB097A-1 SWM ID-140314-N (TOTAL) PCB-11 PCB-136 24.1 pg/L 4.17 pg/L 24.1 U pg/L 4.17U pg/L V:ILOGINIANCHORIPATRICKI31690131_AN3.DOC 4 VI. Matrix Spike/Matrix Spike Duplicates The laboratory has indicated that there were no matrix spike (MS) and matrix spike duplicate (MSD) analyses specified for the samples in this SDG, and therefore matrix spike and matrix spike duplicate analyses were not performed for this SDG. VII. Ongoing Precision & Recovery Samples (OPR) Ongoing precision and recovery (OPR) control samples were reviewed for each matrix as applicable. The percent recoveries (%R) were within the QC limits. VIII. Regional Quality Assurance and Quality Control Not applicable. IX. Internal Standards All internal standard recoveries (%R) were within QC limits. X. Target Compound Identifications Raw data were not reviewed for this SDG. XI. Compound Quantitation All compound quantitations were within validation criteria with the following exceptions: Sample All samples in SDGA6506 Compound Flag A or P All compounds reported by the laroratory as estimated maximum possible concentration (EM PC) J (all detects) A Raw data were not reviewed for this SDG. XII. System Performance Raw data were not reviewed for this SDG. XIII. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. Due to compound quantitation problems, data were qualified as estimated in eight samples. V:ILOGINIANCHORIPATRICKI31690131_AN3.DOC 5 Due to method blank contamination problems, data were qualified as nondetected in eight samples. The quality control criteria reviewed, other than those discussed above, were met and are considered acceptable. Sample results that were found to be estimated (J) are usable for limited purposes only. Based upon the Stage 2B data validation all other results are considered valid and usable for all purposes. Data flags are summarized at the end of this report if data has been qualified. XIV. Field Duplicates No field duplicates were identified in this SDG. XV. Field Blanks No field blanks were identified in this SDG. V:ILOGINIANCHORIPATRICKI31690131_AN3.DOC 6 Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Data Qualification Summary - SDG ASSOS I SDG I A6506 I Sample PB070_B-2SWMID-140314-N (TOTAL) PB070_B-1SWMID-140314-N (TOTAL) PB079-1SWMID-140314-N (TOTAL) PB081_A-1SWMID-140314-N (TOTAL) PB081_A-1SWMID-140314-N (DISSOLVED) PB089-1SWMID-140314-N (TOTAL) PB085-1SWMID-140314-N (TOTAL) PB097A-1SWMID-140314-N (TOTAL) Compound All compounds reported by the laboratory as estimated maximum possible concentration (EMPC) I Flag I A orP I Reason J (all detects) A Compound quantitation Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Laboratory Blank Data Qualification Summary - SDG ASSOS SDG Compound Sample Modified Final Concentration AorP A6506 PB070_B-2SWMID-140314-N (TOTAL) PCB-11 36.3U pg/L A A6506 PB070_B-1SWMID-140314-N (TOTAL) PCB-11 35U pg/L A A6506 PB079-1SWMID-140314-N (TOTAL) PCB-11 28.1U pg/L A A6506 PB081_A-1SWMID-140314-N (TOTAL) PCB-11 29U pg/L A A6506 PB081_A-1SWMID-140314-N (DISSOLVED) PCB-11 34.5U pg/L A A6506 PB089-1SWMID-140314-N (TOTAL) PCB-11 37.4U pg/L A A6506 PB085-1 SWMID-140314-N (TOTAL) PCB-11 30.7U pg/L A A6506 PB097A-1SWMID-140314-N (TOTAL) PCB-11 PCB-136 24.1U pg/L 4.17U pg/L A V:\LOGI NIANCHOR\PATRICK\31690131_AN3. DOC 7 I VALIDATION COMPLETENESS WORKSHEET LDC #: 31690131 Stage 28 SDG#: A6506 Laboratory: SGS Af'lel ttieel Persl3eotive I Date:~L{ Page:.Lofj_ Reviewer: ~I 2nd Reviewer: CJ?-?' METHOD: HRGC/HRMS Polychlorinated Biphenyl Congeners (EPA Method 1668A) The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I I llalidatioD Atea I I. Technical holding times A II. GC/MS Instrument performance check A 111. Initial calibration IV. Continuing calibration/I&.£-- V. Blanks VI. Matrix spike/Matrix spike duplicates VII. Laboratory control samples ~ VIII. Regional quality assurance and quality control N A A rJ slit J,Ll ~dO ~ ~D/Si2 L---$. nf>l?- ~ Internal standards X. Target compound identifications XI. Compound quantitation/RUl:gel'l:ees- XII. System performance XIII. Overall assessment of data A XIV. Field duplicates tJ xv. Field blanks A =Acceptable N = Not provided/applicable SW = See worksheet Sampling dates: '5W IX. Note: I Commeois N 6'l'1 N rJ ND = No compounds detected R Rinsate FB Field blank = = D = Duplicate TB Trip blank EB Equipment blank = = Validated samPlesWoJ..t.e... 1 PB070 B-2SWMID-140314-N (TOTAL) 11 21 31 2 PB070 B-1SWMID-140314-N (TOTAL) 12 22 32 3 PB079-1SWMID-140314-N (TOTAL) 13 23 33 4 PB081 A-1SWMID-140314-N (TOTAL) 14 24 34 5 PB081 A-1SWMID-140314-N (DISSOLVED) 15 25 35 6 PB089-1SWMID-140314-N (TOTAL) 16 26 36 7 PB085-1SWMID-140314-N (TOTAL) 17 27 37 8 PB097A-1SWMID-140314-N (TOTAL) 18 28 38 9 19 29 39 10 20 30 40 31690131W.wpd tv'-~ 1- It <6'11 VALIDATION FINDINGS WORKSHEET Blanks LDC #: 31690131 Page: 2nd Reviewer: METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) Base see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". Y N NIA Were all samples associated with a method blank? ~ Was a method blank performed for each matrix and whenever a sample extraction was performed? ~ Was the method blank contaminated? Blank extraction date: Conc. units' DalL Blank analysis date: 03/19/14 Associated samPles:_:..:A!.!..II_-",[).:....>..;tY&:....==-l>..L.;l 03/27/14 Sample Identification Blank 10 1_ _ [ MB1 11899 5x PCB-105 1.06 5.3 PCB-118 2.29 11.5 PCB-8 1.64 8.2 PCB-11 7.71 38.6 PCB-30/18 2.66 13.3 PCB-31 2.29 11.5 PCB-28/20 2.34* 11.7 PCB-21 133 1.53 7.7 PCB-52 3.95 19.8 PCB-69/49 1.78 8.9 PCB-44/47/65 2.6 13.0 2.76* 13.8 PCB-66 1.4 7.0 PCB-95 3.4 17.0 PCB-84 0.983* 4.9 PCB-113/90/101 3,6 18,0 PCB-99 1.71 8.6 PCB-61 170/74/76 V:IValidation-BlanksI31690131.wpd J of d Reviewe~---,--,::::-_ I ~ 3 ~ 5 & f ?>(,. "6 35 ~~ I d-.q 31-/.5' ~7.4 30,l-- ~ ~'-f. I or ~ Page:~of2 VALIDATION FINDINGS WORKSHEET Blanks LDC #: 31690131 Reviewer:Vfl. ... 2nd Reviewer: 01..... METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) __l Blank 10 Sample Identification MB1 11899 5x 2.7* 13.5 PCB-116/85 0.686 3.4 PCB-11 0 3.95 19.8 PCB-136 0.87 4.4 PCB-147/149 3.22 16.1 PCB-132 1.79 9.0 PCB-153/168 2.53 12.7 PCB-163/138/129 3.12 15.6 PCB-180/193 1.57 7.9 PCB-108/119/86/97/125/87 T. ~ "C, n Total Tri-CBs a'la IT. "D. 1? I ..... '" "'" -'"'" l;* I I. ... ~, 'u,"" ~ n 'v.v 0.0":;- IT. IT. I .oJ ~ 'VL.." ,,-, d v .oJ 7. *EMPC All contaminants within five times the method blank concentration were qualified as not detected. V:lValidation-Blanks\31690131. wpd 3_ '-I 5 f..p -:}- ~ 4./'f VALIDATION FINDINGS WORKSHEET Compound Quantitation and Reported CRQLs Page: _1_of_1_ Reviewer:~ 2nd Reviewer: OZ::: METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) Please see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". ~ ~ # I I Were the correct internal standard (IS), quantitation ions and relative response factors (RRF) used to quantitate the compound? Compound quantitation and CRQLs were adjusted to reflect all sample dilutions and dry weight factors (if necessary). Date Compound I I Finding Associated Samples Qualifications EMPC results All Jdets/A I I I Comments: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ___ P:\Anchor_POI 1668-COMQUA. wpd LDC Report# 31690J31 Laboratory Data Consultants, Inc. Data Validation Report Project/Site Name: Patrick Bayou Superfund Site Collection Date: March 15, 2014 LDC Report Date: May 8,2014 Matrix: Water Parameters: Polychlorinated Biphenyls as Congeners Validation Level: Stage 2B Laboratory: SGS North America, Inc. Sample Delivery Group (SDG): A6517 Sample Identification PB081 A-2SWMIO-140315-N V:ILOGINIANCHORIPATRICKI31690J31_AN3.DOC 1 Introduction This data review covers one water sample listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA Method 1668A for Polychlorinated Biphenyls as Congeners. This review follows USEPA Contract Laboratory Program (CLP) National Functional Guidelines for Chlorinated Dibenzo-p-Dioxins (CDDs) and Chlorinated Dibenzofurans (CDFs) Data Review (September 2011). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of the presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, therefore qualification was not required. V:ILOGINIANCHORIPATRICKI31690J31_AN3.DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. HRGC/HRMS Instrument Performance Check Instrument performance was checked at the required daily frequency. Retention time windows were established for all congeners. The chromatographic resolution between the congeners PCB-23 and PCB-34 and congeners PCB-182 and PCB187 was resolved with a valley of less than or equal to 40%. III. Initial Calibration A five point initial calibration was performed as required by the method. Percent relative standard deviations (%RSO) were less than or equal to 20.0% for all compounds. The ion abundance ratios for all PCBs were within method criteria. The minimum SIN ratio was greater than or equal to 10 for each unlabeled compound and labeled compound. IV. Routine Calibration (Continuing) Routine calibration was performed at the required frequencies. All of the routine calibration percent differences (%0) between the initial calibration RRF and the routine calibration RRF were less than or equal to 30.0% for unlabeled compounds and less than or equal to 50.0% for labeled compounds. The ion abundance ratios for all PCBs were within method criteria. V. Blanks Method blanks were reviewed for each matrix as applicable. No polychlorinated biphenyls as congeners contaminants were found in the method blanks with the following exceptions: V:ILOGINIANCHORIPATRICKI31690J31_AN3.DOC 3 Extraction Date Method Blank ID 3/20/14 MB1_11903 Compound Concentration PCB-118 PCB-1 PCB-3 PCB-11 PCB-31 PCB-28/20 PCB-21/33 PCB-52 PCB-69/49 PCB-44/47/65 PCB-61/70/74/76 PCB-95 PCB-113/90/101 PCB-99 PCB-1 08/119/86/97/125/87 PCB-110 PCB-151/135 PCB-147/149 PCB-132 PCB-153/168 PCB-163/138/129 2.91 pg/L 1.08 pg/L 1.69 pg/L 8.82 pg/L 1.96 pg/L 2.82 pg/L 2.06 pg/L 5.34 pg/L 2 pg/L 3.67 pg/L 3.84 pg/L 4.27 pg/L 4.17 pg/L 1.67 pg/L 2.67 pg/L 5.2 pg/L 2 pg/L 3.55 pg/L 2.01 pg/L 2.85 pg/L 2.96 pg/L Associated Samples All samples in SDGA6517 Sample concentrations were compared to concentrations detected in the method blanks. The sample concentrations were either not detected or were significantly greater (>5X blank contaminants) than the concentrations found in the associated method blanks with the following exceptions: Sample PB081_A-2SWM ID-140315-N Compound PCB-3 PCB-11 Reported Concentration Modified Final Concentration 3.18 pg/L 20.4 pg/L 3.18U pg/L 20.4U pg/L VI. Matrix Spike/Matrix Spike Duplicates The laboratory has indicated that there were no matrix spike (MS) and matrix spike duplicate (MSD) analyses specified for the samples in this SDG, and therefore matrix spike and matrix spike duplicate analyses were not performed for this SDG. VII. Ongoing Precision & Recovery Samples (OPR) Ongoing precision and recovery (OPR) control samples were reviewed for each matrix as applicable. The percent recoveries (%R) were within the QC limits. VIII. Regional Quality Assurance and Quality Control Not applicable. V:\LOGINIANCHOR\PATRICK\31690J31_AN3.DOC 4 IX. Internal Standards All internal standard recoveries (%R) were within QC limits with the following exceptions: Internal Standards Sample MB1_11903 13C PCB-104 Compound %R (Limits) PCB-96 PCB-104 158 (25-150) Flag A orP J (all detects) UJ (all non-detects) P X. Target Compound Identifications Raw data were not reviewed for this SDG. XI. Compound Quantitation All compound quantitations were within validation criteria with the following exceptions: Sample All samples in SDGA6517 Compound Flag A orP All compounds reported by the laroratory as estimated maximum possible concentration (EM PC) J (all detects) A Raw data were not reviewed for this SDG. XII. System Performance Raw data were not reviewed for this SDG. XIII. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. Due to method blank contamination problems, data were qualified as nondetected in one samples. Due to compound quantitation problems, data were qualified as estimated in one sample. The quality control criteria reviewed, other than those discussed above, were met and are considered acceptable. Sample results that were found to be estimated (J) are usable for limited purposes only. Based upon the Stage 2B data validation all other results are considered valid and usable for all purposes. Data flags are summarized at the end of this report if data has been qualified. V:ILOGINIANCHORIPATRICK131690J31_AN3. DOC 5 XIV. Field Duplicates No field duplicates were identified in this SDG. XV. Field Blanks No field blanks were identified in this SDG. V:ILOGINIANCHORIPATRICKI31690J31_AN3. DOC 6 Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Data Qualification Summary - SDG A6517 SOG A6517 Sample PB081_A-2SWMIO-140315-N Flag A or P J (all detects) A Compound All compounds reported by the laboratory as estimated maximum possible concentration (EM PC) Reason Compound quantitation Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Laboratory Blank Data Qualification Summary - SDG A6517 SOG A6517 Compound Sample PB081_A-2SWMIO-140315-N V:ILOGINIANCHORIPATRICKI31690J31_AN3.DOC PCB-3 PCB-11 7 Modified Final Concentration 3.18U pg/L 20.4U pg/L A orP A VALIDATION COMPLETENESS WORKSHEET LDC #: 31690J31 SDG #: A6517 Stage 28 Laboratory: SGS Allalytical Pel !I?eeti'v'e ::r--Iy Date:5Page:_fof_J_ Reviewer: '--1L 2nd Reviewer: 0'\.--- METHOD: HRGC/HRMS Polychlorinated Biphenyl Congeners (EPA Method 1668A) The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I ~alidatiQD I Atea A I. Technical holding times II. GC/MS Instrument performance check III. Initial calibration IV. Continuing calibration/IGIV- V. Blanks VI. Matrix spike/Matrix spike duplicates VII. Laboratory control samples VIII. Regional quality assurance and quality control Internal standards X. Target compound identifications XI. Compound quantitation/RUL:eQ7te6s- XII. System performance XIII. Overall assessment of data XIV. Field duplicates XV. Field blanks A =Acceptable N Not provided/applicable SW = See worksheet = V ard I ate d S amp es: 1 A A A- 5W IX. Note: I N A I CClllmeDts 3/,t::; /,...t Sampling dates: f)-O ~30l~ r..,.~S . IOPR N SvJ N S-.N N A N N = = ND No compounds detected R Rinsate FB = Field blank = = = D Duplicate TB Trip blank EB Equipment blank WCA..~ PB081 A-2SWMID-140315-N 11 21 31 2 12 22 32 3 13 23 33 4 14 24 34 5 15 25 35 6 16 26 36 7 17 27 37 8 18 28 38 9 19 29 39 10 20 30 40 31690J31W.wpd t-A~ \ -llqO~ Page:~of2 VALIDATION FINDINGS WORKSHEET Blanks LDC #: 31690J31 Reviewer:C-:fk..... 2nd Reviewer: c::z... METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) e ease see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". N NIA Were all samples associated with a method blank? Y N @A Was a method blank performed for each matrix and whenever a sample extraction was performed? N NIA Was the method blank contaminated? \V Blank extraction date:_~03~/=2~0/~1~4__ Blank analysis date: Conc. units· naIL ~I MB1.11903 5x PCB-118 2.91 14.6 PCB-1 1.08 5.4 PCB-3 1.69 8.5 3.18 PCB-11 8.82 44.1 20.4 PCB-31 1.96* 9.8 PCB-28/20 2.82* 14.1 PCB-21/33 2.06 10.3 PCB-52 5.34 26.7 2* 10.0 PCB-44/47/65 3.67 18.4 PCB-61/70/74/76 3.84 19.2 PCB-95 4.27 21.4 PCB-113/90/101 4.17* 20.9 PCB-99 1.67* 8.4 PCB-108/119/86/97/125/87 2.67* 13.4 5.2 26.0 2 10.0 PCB-110 PCB-151/135 V:lValidation-Blanks\31690J31 .wpd Associated samples: All Sample Identification .'ankiD PCB-69/49 03/28/14 1 Qual U VALIDATION FINDINGS WORKSHEET Blanks LDC #: 31690J31 Page: ;). of2 Reviewer:~ 2nd Reviewer: METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) I~l Blank 10 Sample Identification MB1 11903 5x PCB-147/149 3.55 17.8 PCB-132 2.01* 10.1 PCB-153/168 2.85* 14.3 PCB-163/138/129 2.96 ... 1 14.8 ~ ~. .~ I~'Q'-= ,",no ITnt". TriJ'R" 1= ., 77 ~~ - O.OL 0.0'+ .....,-.. . ,)~ ITotal .... 14. IT"'-r- .. ",a-lJI:!S 20.9" ,"'"'""" ITnt"l 13.4* 07':"tT !'-- *EMPC All contaminants within five times the method blank concentration were qualified as not detected. V:\Validation-Blanks\31690J31. wpd 07 - LDC #: 3llAOS '?l VALIDATION FINDINGS WORKSHEET Internal Standards page:_(_of-.L Reviewer: ~ 2nd Reviewer: D7 - METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) Please see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". Y N) NIA Are all internal standard recoveries within the QC criteria? Y N "IW/A Was the SIN ratio all internal standard peaks> 10? Date " # I I Lab ID/Reference Internal Standard MB1 11903 13C PCB-104 I P:IAECOMIINTST_1668.wpd I % Recovery (Limit: Qualifications ) J/UJ/P (PCB-96, PCB-104+T 158 ( 25-150 ) I I • I D, .~ I VALIDATION FINDINGS WORKSHEET Compound Quantitation and Reported CRQLs Page: _1_of_1_ Reviewer: ~ . / 2nd Reviewer: ~ METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) Please see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". ~ ~ # Date Were the correct internal standard (IS). quantitation ions and relative response factors (RRF) used to quantitate the compound? Compound quantitation and CRQLs were adjusted to reflect all sample dilutions and dry weight factors (if necessary). Compound Finding EMPC results Associated Samples Qualifications All Jdets/A Comments: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ P:lAnchor_PO\ 1668-COMQUA. wpd LDC Report# 31690K31 Laboratory Data Consultants, Inc. Data Validation Report Project/Site Name: Patrick Bayou Superfund Site Collection Date: March 18, 2014 LDC Report Date: May 8,2014 Matrix: Water Parameters: Polychlorinated Biphenyls as Congeners Validation Level: Stage 2B Laboratory: SGS North America, Inc. Sample Delivery Group (SDG): A6521 Sample Identification PB083-1 SWMIO-140318-N PB083-1 SWMIO-140318-0 PB087-1 SWMIO-140318-N PB091-1 SWMIO-140318-N PB093-1 SWMIO-140318-N PB095-1 SWMIO-140318-N V:ILOGINIANCHORIPATRICKI31690K31_AN3.DOC 1 Introduction This data review covers 6 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA Method 1668A for Polychlorinated Biphenyls as Congeners. This review follows USEPA Contract Laboratory Program (CLP) National Functional Guidelines for Chlorinated Dibenzo-p-Dioxins (CDDs) and Chlorinated Dibenzofurans (CDFs) Data Review (September 2011). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of the presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, therefore qualification was not required. V:lLOGI NIANCHORIPATRICKI31690K31_AN3. DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. HRGC/HRMS Instrument Performance Check Instrument performance was checked at the required daily frequency. Retention time windows were established for all congeners. The chromatographic resolution between the congeners PCB-23 and PCB-34 and congeners PCB-182 and PCB..; 187 was resolved with a valley of less than or equal to 40%. III. Initial Calibration A five point initial calibration was performed as required by the method. Percent relative standard deviations (%RSO) were less than or equal to 20.0% for all compounds. The ion abundance ratios for all PCBs were within method criteria. The minimum SIN ratio was greater than or equal to 10 for each unlabeled compound and labeled compound. IV. Routine Calibration (Continuing) Routine calibration was performed at the required frequencies. All of the routine calibration percent differences (%0) between the initial calibration RRF and the routine calibration RRF were less than or equal to 30.0% for unlabeled compounds and less than or equal to 50.0% for labeled compounds. The ion abundance ratios for all PCBs were within method criteria. V. Blanks Method blanks were reviewed for each matrix as applicable. No polychlorinated biphenyls as congeners contaminants were found in the method blanks with the following exceptions: V:ILOGINIANCHORIPATRICKI31690K31_AN3,DOC 3 Method Blank 10 MB1_11903 Extraction Date 3/20/14 Compound PCB-118 PCB-1 PCB-3 PCB-11 PCB-31 PCB-28/20 PCB-21 133 PCB-52 PCB-69/49 PCB-44/47/65 PCB-61 170/74/76 PCB-95 PCB-113/90/101 PCB-99 PCB-108/119/86/97/125/87 PCB-110 PCB-151/135 PCB-147/149 PCB-132 PCB-153/168 PCB-163/138/129 Concentration 2.91 pg/L 1.08 pg/L 1.69 pg/L 8.82 pg/L 1.96 pg/L 2.82 pg/L 2.06 pg/L 5.34 pg/L 2 pg/L 3.67 pg/L 3.84 pg/L 4.27 pg/L 4.17 pg/L 1.67 pg/L 2.67 pg/L 5.2 pg/L 2 pg/L 3.55 pg/L 2.01 pg/L 2.85 pg/L 2.96 pg/L Associated Samples All samples in SOG A6521 Sample concentrations were compared to concentrations detected in the method blanks. The sample concentrations were either not detected or were significantly greater (>5X blank contaminants) than the concentrations found in the associated method blanks with the following exceptions: Sample Compound Reported Concentration Modified Final Concentration PB083-1 SWMI0-140318-N PCB-3 PCB-11 5.7 pg/L 22.7 pg/L 5.7U pg/L 22.7U pg/L PB083-1 SWM I0-140318-0 PCB-3 PCB-11 4.96 pg/L 21.2pg/L 4.96U pg/L 21.2U pg/L PB087-1 SWMI0-140318-N PCB-3 PCB-11 6.04 pg/L 26.3 pg/L 6.04U pg/L 26.3U pg/L PB091-1 SWMI0-140318-N PCB-3 PCB-11 5.96 pg/L 30.6 pg/L 5.96U pg/L 30.6U pg/L PB093-1 SWM I0-140318-N PCB-3 PCB-11 5.06 pg/L 27.6 pg/L 5.06U pg/L 27.6U pg/L PB095-1 SWM I0-140318-N PCB-3 PCB-11 5.66 pg/L 26.2 pg/L 5.66U pg/L 26.2U pg/L V:ILOGINIANCHORIPATRICKI31690K31_AN3.DOC 4 LABORATORY DATA CONSULTANTS, INC. 2701 Loker Ave. West, Suite 220, Carlsbad, CA 92010 Bus: 760-827-1100 Fax: 760-827-1099 Anchor QEA, LLC 720 Olive Way, Suite 900 Seattle, WA 98101 ATTN: Ms. Cindy Fields SUBJECT: May 21,2014 Revised Patrick Bayou, Data Validation Dear Ms. Fields, Enclosed is the revised validation report for the fraction listed below. Please replace the previously submitted report with the enclosed revised report. LDC Project #31690: SDG# Fraction A6528 Polychlorinated Biphenyls as Congeners • Revised to correct the field duplicate IDs Please feel free to contact us if you have any questions. Sincerely, () L eG>VLChristina Rink Project Manager/Chemist L:\Anchor\Patrick\31690_RV1.wpd UL-SF LDC Report# 31690L31_RV1 Laboratory Data Consultants, Inc. Data Validation Report ProjectlSite Name: Patrick Bayou Superfund Site Collection Date: March 19,2014 LDC Report Date: May 21,2014 Matrix: Water Parameters: Polychlorinated Biphenyls as Congeners Validation Level: Stage 2B Laboratory: SGS North America, Inc. Sample Delivery Group (SDG): A6528 Sample Identification PB099-1 SWMID-140319-N (TOTAL) PB099-1SWMID-140319-MD (TOTAL) PB1 01.1-1SWMID-140319-N (TOTAL) PB1 01.1-1 SWMID-140319-N (DISSOLVED) V:ILOGINIANCHORIPATRICKI31690L31_AN3_RV1. DOC 1 Introduction This data review covers 4 water samples listed on the cover sheet including dilutions and reanalysis as applicable. The analyses were per EPA Method 1668A for Polychlorinated Biphenyls as Congeners. This review follows USEPA Contract Laboratory Program (CLP) National Functional Guidelines for Chlorinated Dibenzo-p-Dioxins (COOs) and Chlorinated Dibenzofurans (CDFs) Data Review (September 2011). A qualification summary table is provided at the end of this report if data has been qualified. Flags are classified as P (protocol) or A (advisory) to indicate whether the flag is due to a laboratory deviation from a specified protocol or is of technical advisory nature. Raw data were not reviewed for this SDG. The review was based on QC data. The following are definitions of the data qualifiers: U Indicates the compound or analyte was analyzed for but not detected at or above the stated limit. J Indicates an estimated value. R Quality control indicates the data is not usable. NJ Presumptive evidence of the presence of the compound at an estimated quantity. UJ Indicates the compound or analyte was analyzed for but not detected. The sample detection limit is an estimated value. A Indicates the finding is based upon technical validation criteria. P Indicates the finding is related to a protocol/contractual deviation. None Indicates the data was not significantly impacted by the finding, therefore qualification was not required. V:\LOGINIANCHOR\PATRICK\31690L31_AN3_RV1. DOC 2 I. Technical Holding Times All technical holding time requirements were met. The chain-of-custodies were reviewed for documentation of cooler temperatures. All cooler temperatures met validation criteria. II. HRGC/HRMS Instrument Performance Check Instrument performance was checked at the required daily frequency. Retention time windows were established for all congeners. The chromatographic resolution between the congeners PCB-23 and PCB-34 and congeners PCB-182 and PCB187 was resolved with a valley of less than or equal to 40%. III. Initial Calibration A five point initial calibration was performed as required by the method. Percent relative standard deviations (%RSO) were less than or equal to 20.0% for all compounds. The ion abundance ratios for all PCBs were within method criteria. The minimum SIN ratio was greater than or equal to 10 for each unlabeled compound and labeled compound. IV. Routine Calibration (Continuing) Routine calibration was performed at the required frequencies. All of the routine calibration percent differences (%0) between the initial calibration RRF and the routine calibration RRF were less than or equal to 30.0% for unlabeled compounds and less than or equal to 50.0% for labeled compounds. The ion abundance ratios for all PCBs were within method criteria. V. Blanks Method blanks were reviewed for each matrix as applicable. No polychlorinated biphenyls as congeners contaminants were found in the method blanks with the following exceptions: V:\LOGINIANCHOR\PATRICK\31690L31_AN3_RV1. DOC 3 Method Blank ID MB1_11906 Extraction Date 3/21/14 Compound PCB-105 PCB-118 PCB-11 PCB-31 PCB-28/20 PCB-52 PCB-69/49 PCB-44/47/65 PCB-61170174176 PCB-66 PCB-95 PCB-113/90/101 PCB-99 PCB-108/119/86/97/125/87 PCB-110 PCB-136 PCB-151/135 PCB-147/149 PCB-132 PCB-146 PCB-153/168 PCB-163/138/129 PCB-209 Concentration 1.59 pg/L 2.96 pg/L 10.2 pg/L 2.06 pg/L 2.88 pg/L 5.29 pg/L 2.11 pg/L 3.59 pg/L 4.02 pg/L 1.89 pg/L 4.79 pg/L 4.4 pg/L 1.95 pg/L 4.19 pg/L 5.96 pg/L 0.662 pg/L 1.64 pg/L 3.63 pg/L 1.52 pg/L 1.1 pg/L 3.47 pg/L 3.99 pg/L 1.01 pg/L Associated Samples All samples in SOG A6528 Sample concentrations were compared to concentrations detected in the method blanks. The sample concentrations were either not detected or were significantly greater (>5X blank contaminants) than the concentrations found in the associated method blanks with the following exceptions: Sample Compound Reported Concentration Modified Final Concentration PB099-1SWMIO-140319-N (TOTAL) PCB-11 PCB-146 PCB-209 23 pg/L 4.71 pg/L 2.41 pg/L 23U pg/L 4.71U pg/L 2.41 U pg/L PB099-1SWMIO-140319-MO (TOTAL) PCB-11 PCB-146 PCB-209 23.5 pg/L 4.76 pg/L 2.95 pg/L 23.5U pg/L 4.76U pg/L 2.95U pg/L PB101.1-1SWMIO-140319-N (TOTAL) PCB-11 PCB-146 PCB-209 26.9 pg/L 5.37 pg/L 3.08 pg/L 26.9U pg/L 5.37U pg/L 3.08U pg/L V:\LOGINIANCHOR\PATRICK\31690L31_AN3_RV1. DOC 4 Sample Compound PB101.1-1SWMID-140319-N (DISSOLVED) Reported Concentration Modified Final Concentration 4.55 pg/L 10.2 pg/L 22 pg/L 19.5 pg/L 17.2 pg/L 8.58 pg/L 14.5 pg/L 21.5 pg/L 1.45 pg/L 3.17 pg/L 6.31 pg/L 2.47 pg/L 1.12 pg/L 5.53 pg/L 7.93 pg/L 1.18 pg/L 4.55U pg/L 10.2U pg/L 22U pg/L 19.5U pg/L 17.2U pg/L 8.58U pg/L 14.5U pg/L 21.5U pg/L 1.45U pg/L 3.17U pg/L 6.31U pg/L 2.47U pg/L 1.12U pg/L 5.53U pg/L 7.93U pg/L 1.18U pg/L PCB-105 PCB-118 PCB-11 PCB-95 PCB-113/90/101 PCB-99 PCB-108/119/86/97/125/87 PCB-110 PCB-136 PCB-151/135 PCB-147/149 PCB-132 PCB-146 PCB-153/168 PCB-163/138/129 PCB-209 VI. Matrix Spike/Matrix Spike Duplicates The laboratory has indicated that there were no matrix spike (MS) and matrix spike duplicate (MSD) analyses specified for the samples in this SDG, and therefore matrix spike and matrix spike duplicate analyses were not performed for this SDG. VII. Ongoing Precision & Recovery Samples (OPR) Ongoing precision and recovery (OPR) control samples were reviewed for each matrix as applicable. The percent recoveries (O/OR) were within the QC limits. VIII. Regional Quality Assurance and Quality Control Not applicable. IX. Internal Standards All internal standard recoveries (O/OR) were within QC limits. X. Target Compound Identifications Raw data were not reviewed for this SDG. XI. Compound Quantitation All compound quantitations were within validation criteria with the following exceptions: I Sample All samples in SDG A6528 I ComEound All compounds reported by the laboratory as estimated maximum possible concentration (EM PC) V:\LOGINIANCHOR\PATRICK\31690L31-AN3_RV1.DOC 5 I Flag J (all detects) I AorP A I Raw data were not reviewed for this SDG. XII. System Performance Raw data were not reviewed for this SDG. XIII. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. Due to method blank contamination problems, data were qualified as nondetected in four samples. Due to compound quantitation problems, data were qualified as estimated in four samples. The quality control criteria reviewed, other than those discussed above, were met and are considered acceptable. Sample results that were found to be estimated (J) are usable for limited purposes only. Based upon the Stage 2B data validation all other results are considered valid and usable for all purposes. Data flags are summarized at the end of this report if data has been qualified. XIV. Field Duplicates Samples PB099-1SWMID-140319-N (TOTAL) and PB099-1SWMID-140319-MD (TOTAL) were identified as method duplicates. No polychlorinated biphenyls as congeners were detected in any of the samples with the following exceptions: Concentration (pg/L) PB099-1SWMID-140319-MD (TOTAL) PB099-1SWMID-140319-N (TOTAL) RPD PCB-001 13.1 16.7 24 PCB-002 2.26 3.71 49 PCB-003 5.06 8.82 54 PCB-004 85.4 92.3 8 PCB-006 44.7 53 17 PCB-007 1.96 3.84U 200 PCB-008 32.8 39 17 PCB-009 2.69 4.4U 200 PCB-010 2.84 5.41U 200 PCB-011 23.5 23 2 Compound V:ILOGINIANCHORIPATRICKI31690L31_AN3_RV1. DOC 6 Concentration (pg/L) PB099-1SWMID-140319-MD (TOTAL) PB099-1SWMID-140319-N (TOTAL) RPD PCB-012/013 15.4 17.4 12 PCB-015 21.7 23.5 8 PCB-016 68.3 70.6 3 PCB-017 95.3 87.9 8 PCB-018/030 203 201 1 PCB-019 45 46.1 2 PCB-0201028 182 181 1 PCB-021/033 33.3 33.7 1 PCB-022 49.8 48.7 2 PCB-025 62.3 62.1 0 PCB-026/029 51.7 53.4 3 PCB-027 15.8 13 19 PCB-031 161 162 1 PCB-032 94.6 90.7 4 PCB-037 25.1 23.7 6 PCB-0401071 114 102 11 PCB-041 12.4 10.1 20 PCB-042 67.7 59.7 13 PCB-043 11.5 2.91U 200 PCB-044/047/065 264 229 14 PCB-045 36.6 33.4 9 PCB-046 21.2 18.4 14 PCB-048 34.9 30.2 14 PCB-049/069 156 139 12 PCB-0501053 57.7 52.4 10 PCB-051 53.6 41.1 26 PCB-052 295 256 14 PCB-054 1.67 1.93U 200 Compound V:\LOGINIANCHOR\PATRICK\31690L31_AN3_RV1.DOC 7 Concentration (pg/L) PB099-1SWMID-140319-MD (TOTAL) PB099-1SWMID-140319-N (TOTAL) RPD PCB-o.56 73.6 69.4 6 PCB-o.57 1.26 2.37U 20.0. PCB-o.59/o.62/o.75 18.4 16.6 10. PCB-o.6o. 27.8 27.9 0. PCB-o.63 7.63 6.86 11 PCB-o.64 90..2 81.6 10. PCB-o.66 147 131 12 PCB-o.67 4.53 3.45 27 PCB-o.68 31.6 26.6 17 PCB-o.72 1.67 2.27U 20.0. PCB-o.77 14 12.9 8 PCB-o.82 17.4 15 15 PCB-o.83 5.83 4.19 33 PCB-o.84 36.7 31.5 15 PCB-o.85/116 21.8 17.3 23 PCB-o.9o./101/113 76.4 69.9 9 PCB-o.91 19 17.3 9 PCB-o.92 15.4 15.6 1 PCB-o.93/1o.o. 1.59 1.76U 20.0. PCB-o.95 71.2 66.4 7 PCB-o.96 2.85 2.57 10. PCB-o.99 49.3 45.9 7 PCB-1o.2 6.81 4.44 42 PCB-1o.5 32 29 10. PCB-1o.9 6.0.4 1.2U 20.0. PCB-11o. 10.2 92.3 10. PCB-114 2 1.29U 20.0. PCB-117 o..581U 2.46 20.0. Compound V:\LOGINIANCHOR\PATRICK\31690L31_AN3_RV1. DOC 8 Concentration (pg/L) PB099-1SWMID-140319-MD (TOTAL) PB099-1SWMID-140319-N (TOTAL) RPD PCB-118 65.1 63.5 2 PCB-123 1.94 1.27U 200 PCB-128/166 4.86 5.47 12 PCB-129/138/163 36.2 36.2 0 PCB-130 2.57 1.94U 200 PCB-132 12.4 10.8 14 PCB-134 2.49 2.22U 200 PCB-135/151 10.2 10.1 1 PCB-136 4.72 4.98 5 PCB-137 2.74 1.53U 200 PCB-139/140 0.938 1.57U 200 PCB-141 5.66 5.15 9 PCB-146 4.76 4.71 1 PCB-147/149 24.3 22.5 8 PCB-153/168 25.7 23.5 9 PCB-156/157 3.37 3.87 14 PCB-158 3.85 3.77 2 PCB-164 2.13 1.26U 200 PCB-167 1.5 1.28U 200 PCB-170 4.01 3.79 6 PCB-171/173 2.12 1.69U 200 PCB-172 1.12 1.64U 200 PCB-174 5.25 3.84 31 PCB-177 3.63 1.72U 200 PCB-178 1.14 1.87U 200 PCB-179 2.8 2.54 10 PCB-180/193 11.6 10.2 13 PCB-183 3.36 2.72 21 Compound V:\LOGINIANCHOR\PATRICK\31690L31_AN3_RV1.DOC 9 Concentration (pg/L) PB099-1SWMID-140319-MD (TOTAL) PB099-1SWMID-140319-N (TOTAL) RPD PCB-184 0.981 1.37U 200 PCB-187 7.73 6.57 16 PCB-190 1.42 1.09U 200 PCB-194 2.69 1.85U 200 PCB-195 1.51 2.06U 200 PCB-196 1.59 2.23U 200 PCB-198/199 4.23 2.35U 200 PCB-202 1.51 1.6U 200 PCB-203 2.41 2.18U 200 PCB-209 2.95 2.41 20 PCB-061 10701074/076 229 203 12 PCB-086/087/097/108/119/125 64.6 62.3 4 Compound xv. Field Blanks No field blanks were identified in this SDG. V:\LOGINIANCHOR\PATRICK\31690L31_AN3_RV1.DOC 10 Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Data Qualification Summary - SDG A6528 SDG A6528 Sample PB099-1SWMID-140319-N (TOTAL) PB099-1SWMID-140319-MD (TOTAL) PB101.1-1SWMID-140319-N (TOTAL) PB101.1-1SWMID-140319-N (DISSOLVED) Compound All compounds reported by the laboratory as estimated maximum possible concentration (EMPC) FlaR AorP J (all detects) A Reason Compound quantitation Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Laboratory Blank Data Qualification Summary - SDG A6528 SDG Sample Compound Modified Final Concentration AorP A6528 PB099-1SWMID-140319-N (TOTAL) PCB-11 PCB-146 PCB-209 23U pg/L 4.71U pg/L 2.41U pg/L A A6528 PB099-1SWMID-140319-MD (TOTAL) PCB-11 PCB-146 PCB-209 23.5U pg/L 4.76U pg/L 2.95U pg/L A A6528 PB101.1-1SWMID-140319-N (TOTAL) PCB-11 PCB-146 PCB-209 26.9U pg/L 5.37U pg/L 3.08U pg/L A A6528 PB101.1-1SWMID-140319-N (DISSOLVED) PCB-105 PCB-118 PCB-11 PCB-95 PCB-113/90/101 PCB-99 PCB-108/119/86/97/125/87 PCB-110 PCB-136 PCB-151/135 PCB-147/149 PCB-132 PCB-146 PCB-153/168 PCB-163/138/129 PCB-209 4.55U pg/L 10.2U pg/L 22U pg/L 19.5U pg/L 17.2U pg/L 8.58U pg/L 14.5U pg/L 21.5U pg/L 1.45U pg/L 3.17U pg/L 6.31U pg/L 2.47U pg/L 1.12U pg/L 5.53U pg/L 7.93U pg/L 1.18U pg/L A V:ILOGINIANCHORIPATRICKI31690L31_AN3_RV1.DOC 11 LDC #: 31690L31 VALIDATION COMPLETENESS WORKSHEET SDG#: A6528 Stage 2B Laboratory: SGS-AnalvtioaJ P8rspective-- Date: 5-7-ILj Page:Lof-L Reviewer: 2nd Reviewer: ~ ----rJ.n METHOD: HRGC/HRMS Polychlorinated Biphenyl Congeners (EPA Method 1668A) The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I ~lidatiaD I Atea I I. Technical holding times & II. GC/MS Instrument perfonnance check A III. Initial calibration IV. Continuing V. Blanks VI. Matrix spike/Matrix spike duplicates VII. Laboratory_control VIII. R~onal A a calibration/~ 3/lct SampJir1fl dates: llu ~ ;;}O ~30/S;O ~W AI A sam~es quali!y assurance and quality control Internal standards A x. Target compound identifications N XI. Compound Quantitation/RUl:eOltOC~ XII. System perfonnance XIII. Overall assessment of data XIV. Field duplicates XV. Field blanks = A Acceptable N = Not provided/applicable SW = See worksheet L-S· 01?-"R N IX. Note: I Comments ~'N N A S\\I ~'-I-\'# AI ND = No compounds detected R = Rinsate FB = Field blank D = Duplicate TB = Trip blank EB Equipment blank = Validated Samples' ·"NG-..k (l 1 PB099-1SWMID-140319-N (TOTAL) 11 21 31 2 PB099-1SWMID-140319-MD (TOTAL) 12 22 32 3 PB101.1-1SWMID-140319-N (TOTAL) 13 23 33 4 PB101.1-1SWMID-140319-N (DISSOLVED) 14 24 34 5 15 25 35 6 16 26 36 7 17 27 37 8 18 28 38 19 29 39 30 40 9 10 \ 20 31690L31W.wpd M"B\-JnO\o Page:...Lof ~ VALIDATION FINDINGS WORKSHEET Blanks LDC #: 31690L31 Reviewer: :D-r\.. 2nd Reviewer: Qt METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) ase see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". N NIA Were all samples associated with a method blank? ~ Was a method blank performed for each matrix and whenever a sample extraction was performed? ~ Was the method blank contaminated? Blank extraction date: _ _. ----- ..... Blank analysis date: 03/21/14 Associated samples: 04/03/14 All .- ~ f . .- . '~" . " II Blank 10 MB1_11906 II 5x Samele Identification I I ~ .3 L/ PCB-105 1.59 8.0 L/.,e;z:; PCB-118 2.96* 14.8 /0· d. PCB-11 10.2 51.0 PCB-31 2.06 10.3 PCB-28120 2.88 14.4 PCB-52 5.29 26.5 PCB·69149 2.11 10.6 PCB-44147165 3.59* 18.0 PCB-61170174176 4.02 20.1 PCB-66 1.89 9.5 PCB-95 4.79 24.0 Iq~5 PCB·1131901101 4.4" 22.0 1-:+· d. PCB-99 1.95* 9.8 «)·5<6 PCB-10811191861971125187 4.19 21.0 PCB-110 5.96* 29.8 JLJ..5 ;)}. S- PCB-136 0.662 3.3 PCB-1511135 1.64* 8.2 ~3 dto.q ~~ /.t./C;* - V:\Validation·Blanks\31690L31 ,wpd ~~.5 ~ ~-- . S·/-:C Qual U VALIDATION FINDINGS WORKSHEET Blanks LDC #: 31690L31 Page: dof ~ Reviewer:~ 2nd Reviewer: 21.... METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) I Compound ; 1" l" ~IIIUIIII MB1_11906 I 5x I Sample Identification \ d 3 t-) PCB-147/149 3.63* 18.2 to.3\ PCB-132 1.52* 7.6 ~.41* PCB-146 1.1 5.5 PCB-153/168 3.47 17.4 PCB-163/138/129 3.99 20.0 PCB-209 1.01 5.1 IV«.. LlI-v"''' TO.Q, ~-.~ ... I Qlal I elra-vDS TntalP.. n"'_~R., Tn~~' ~ I Blank 10 II ... lU.:,!: OT.V 4.94 :t:.'f;T _1J::~* -U d' ;.J."} I 4·-=[(P J.'-II.JI. dw<1< " · .U .,,, n, • .,n n IV ov.v _- All contaminants within five times the method blank concentration were qualified as not detected. V:\Validation-Blanks\31690L31. wpd &~~ I. I:J ~.D~ 1):'53 1-83 ,. \9- I LDC #: 31 lA ot....:?> I VALIDATION FINDINGS WORKSHEET Compound Quantitation and Reported CRQLs Page: _1_of_1_ Reviewer:~ 2nd Reviewer: Q2 METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) Please see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". YNQ ~ Were the correct internal standard (IS). quantitation ions and relative response factors (RRF) used to quantitate the compound? Compound quantitation and CRQLs were adjusted to reflect all sample dilutions and dry weight factors (if necessary). ------ # Date ----- Compound Finding EMPC results I I I I I - - Associated Samples Qualifications All Jdets/A I I I Commenffi: ______________________________________________________________________________________________________________ P:\Anchor_Po\1668-COMQUA.wpd VALIDATION FINDINGS WORKSHEET Field Duplicates LDC#:31690L31 PCB Congeners (EPA Method 1668A) Analyte Concentration (pg/L) y--z.- RPD ?,\ 16.7 24 2.26 3.71 49 5.06 8.82 54 iPCB-004 85.4 92.3 8 PCB-OOG 44.7 53 17 PCB-007 1.96 3.84U 200 PCB-008 32.8 39 17 PCB-OOI 13.1 PCB-002 PCB-003 PCB-{)09 2.69 4.4U 200 PCB-OIO 2.84 5.41U 200 PCB-Oll 23.5 23 2 PCB-012j013 15.4 17.4 12 PCB-015 21.7 23.5 8 ;PCB-OIG 68.3 70.6 3 PCB-017 95.3 87.9 8 PCB-018j030 203 201 1 PCB-019 45 46.1 2 PCB-{)20j028 182 181 1 PCB-021j033 33.3 33.7 1 PCB-022 49.8 48.7 2 PCB-025 62.3 62.1 0 PCB-026j029 51.7 53.4 3 PCB-{)27 15.8 13 19 PCB-{)31 161 162 1 PCB-{)32 94.6 90.7 4 PCB-{)37 25.1 23.7 6 PCB-040/071 114 102 11 PCB-041 12.4 10.1 20 PCB-042 67.7 59.7 13 PCB-043 11.5 2.91U 200 PCB-044j047/065 264 229 14 PCB-045 36.6 33.4 9 PCB-046 21.2 18.4 14 PCB-048 34.9 30.2 14 PCB-049/069 156 139 12 PCB-050/053 57.7 52.4 10 PCB-051 53.6 41.1 26 PCB-052 295 256 14 PCB-054 1.67 1.93U 200 PCB-056 73.6 69.4 6 PCB-{)57 1.26 2.37U 200 PCB-{)59j062j075 18.4 16.6 10 PageLof3 Reviewe~ 2nd Reviewer:~. LDC#:31690L31 VALIDATION FINDINGS WORKSHEET Field Duplicates PCB Congeners (EPA Method 1668A) Concentration (pg/L) Analyte RPD 1 2 PCB-060 27.8 27.9 PCB-063 7.63 6.86 11 PCB-064 90.2 81.6 10 PCB-066 147 131 12 PCB-067 4.53 3.45 27 PCB-068 31.6 26.6 17 200 0 PCB-072 1.67 2.27U PCB-077 14 12.9 8 PCB-082 17.4 15 15 PCB-083 5.83 4.19 33 PCB-084 36.7 31.5 15 PCB-085/U6 21.8 17.3 23 PCB-090/101/113 76.4 69.9 9 PCB-091 19 17.3 9 PCB-092 15.4 15.6 1 PCB-093/100 1.59 1.76U 200 PCB-095 71.2 66.4 7 PCB-096 2.85 2.57 10 PCB-099 49.3 45.9 7 PCB-102 6.81 4.44 42 PCB-lOS 32 29 10 PCB-I09 6.04 1.2U 200 PCB-ll0 102 92.3 10 PCB-114 2 1.29U 200 PCB-117 0.581U 2.46 200 PCB-118 65.1 63.5 2 PCB-123 1.94 1.27U 200 PCB-128/166 4.86 5.47 12 PCB-129/138/163 36.2 36.2 0 PCB-130 2.57 1.94U 200 PCB-132 12.4 10.8 14 PCB-134 2.49 2.22U 200 PCB-135/151 10.2 10.1 1 PCB-136 4.72 4.98 5 PCB-137 2.74 1.53U 200 PCB-139/140 0.938 1.57U 200 PCB-141 5.66 5.15 9 PCB-146 4.76 4.71 1 PCB-147/149 24.3 22.5 8 PCB-153/168 25.7 23.5 9 PCB-156/157 3.37 3.87 14 Page~of S Reviewe""F.?h--2nd Reviewer:~ LDC#:31690L31 VALIDATION FINDINGS WORKSHEET Field Duplicates PCB Congeners (EPA Method 1668A) Concentration (pg/L) Analyte RPD 1 2 PCB-15S 3.85 3.77 2 PCB-164 2.13 1.26U 200 PCB-167 1.5 1.2SU 200 PCB-170 4.01 3.79 6 PCB-171/173 2.12 1.69U 200 PCB-172 1.12 l.64U 200 PCB-174 5.25 3.84 31 PCB-l77 3.63 l.72U 200 200 PCB-178 1.14 1.87U PCB-179 2.8 2.54 10 PCB-180/193 11.6 10.2 13 PCB-183 3.36 2.72 21 PCB-1S4 0.981 1.37U 200 PCB-iS7 7.73 6.57 16 PCB-190 1.42 1.09U 200 PCB-194 2.69 1.85U 200 PCB-195 1.51 2.06U 200 PCB-196 1.59 2.23U 200 PCB-198/199 4.23 2.35U 200 PCB-202 1.51 1.6U 200 PCB-203 2.41 2.18U 200 PCB-209 2.95 2.41 20 PCB-061/070/074/076 229 203 12 PCB-086/087/097/108/119/125 64.6 62.3 4 Page:30f3 Review~ 2nd Reviewer:~ VI. Matrix Spike/Matrix Spike Duplicates The laboratory has indicated that there were no matrix spike (MS) and matrix spike duplicate (MSD) analyses specified for the samples in this SDG, and therefore matrix spike and matrix spike duplicate analyses were not performed for this SDG. VII. Ongoing Precision & Recovery Samples (OPR) Ongoing precision and recovery (OPR) control samples were reviewed for each matrix as applicable. The percent recoveries (%R) were within the QC limits. VIII. Regional Quality Assurance and Quality Control Not applicable. IX. Internal Standards All internal standard recoveries (%R) were within QC limits with the following exceptions: Internal Standards Sample MB1_11903 13C PCB-104 %R (Limits) Compound 158 (25-150) PCB-96 PCB-104 Flag A orP J (all detects) UJ (all non-detects) P X. Target Compound Identifications Raw data were not reviewed for this SDG. XI. Compound Quantitation All compound quantitations were within validation criteria with the following exceptions: I Sample All samples in SDGA6521 I Compound All compounds reported by the lal:oratory as estimated maximum possible concentration (EM PC) Raw data were not reviewed for this SDG. XII. System Performance Raw data were not reviewed for this SDG. V:\LOGIN\ANCHOR\PATRICK\31690K31_AN3.DOC 5 I Flag J (all detects) I A orP A I XIII. Overall Assessment of Data The analysis was conducted within all specifications of the method. No results were rejected in this SDG. Due to method blank contamination problems, data were qualified as nondetected in six samples. Due to compound quantitation problems, data were qualified as estimated in six samples. The quality control criteria reviewed, other than those discussed above, were met and are considered acceptable. Sample results that were found to be estimated (J) are usable for limited purposes only. Based upon the Stage 2B data validation all other results are considered valid and usable for all purposes. Data flags are summarized at the end of this report if data has been qualified. XIV. Field Duplicates Samples PB083-1SWMID-140318-N and PB083-1SWMID-140318-D were identified as field duplicates. No polychlorinated biphenyls as congeners were detected in any of the samples with the following exceptions: Concentration (pg.t.) Compound PB083-1SWMID-140318-N PB083-1SWMID-140318-D RPD PCB-001 23 21.4 7 PCB-002 2.1 1.49 34 PCB-003 5.7 4.96 14 PCB-004 151 145 4 PCB-005 2.02 1.83 10 PCB-006 47 45.8 3 PCB-007 3.57 3.16 12 PCB-008 101 101 0 PCB-009 7.02 6.87 2 PCB-010 4.44 4.61 4 PCB-011 22.7 21.2 7 PCB-012/013 15.2 13.8 10 PCB-015 51.5 52.4 2 PCB-016 172 181 5 V:\LOGI N\ANCHOR\PATRICK\31690K31_AN3. DOC 6 Concentration (pg.t...) PB083-1SWMID-140318-N PB083-1SWMID-140318-D RPD PCB-017 180 184 2 PCB-018/030 510 522 2 PCB-019 79.7 79.7 0 PCB-019-C13 94.3 104 10 PCB-020/028 461 482 4 PCB-021/033 130 137 5 PCB-022 131 135 3 PCB-024 3.43 2.8 20 PCB-025 62.9 63.6 1 PCB-026/029 90.3 91.5 1 PCB-027 31.1 31.5 1 PCB-031 463 483 4 PCB-032 170 170 0 PCB-034 2.42 2.48 2 PCB-035 7.39 7.21 2 PCB-037 73.5 77.6 5 PCB-038 0.957U 0.797 200 PCB-039 3.81 4.53 17 PCB-040/071 312 330 6 PCB-041 52.3 51.6 1 PCB-042 178 184 3 PCB-043 28.3 28.2 0 PCB-044/047/065 702 737 5 PCB-045 129 144 11 PCB-046 57.3 62.5 9 PCB-048 125 131 5 PCB-049/069 408 425 4 PCB-050/053 154 159 3 Compound V:\LOGINIANCHOR\PATRICK\31690K31_AN3.DOC 7 Concentration (pg.t.) PB083-1SWMID-140318-N PB083-1SWMID-140318-D RPD PCB-051 70.9 62 13 PCB-052 829 875 5 PCB-054 2.83 3.2 12 PCB-055 4.43 5.47 21 PCB-056 225 237 5 PCB-057 2.47 2.38 4 PCB-058 0.923 1.12 19 PCB-059/062/075 49.3 52.3 6 PCB-060 96.8 105 8 PCB-063 16.3 17.2 5 PCB-064 264 277 5 PCB-066 453 482 6 PCB-067 10.6 11.3 6 PCB-068 25.6 27.1 6 PCB-072 3.15 3.23 3 PCB-073 1.59 1.71 7 PCB-077 35.4 37.7 6 PCB-079 8.5 3.07 94 PCB-081 1.82 1.68 8 PCB-082 52.4 54.2 3 PCB-083 15.1 18.8 22 PCB-084 103 110 7 PCB-085/116 68.5 73.9 8 PCB-089 10.6 10.5 1 PCB-090/101/113 230 241 5 PCB-091 52.7 55.9 6 PCB-092 45.1 46.8 4 PCB-093/100 5.16 5.05 2 Compound V:ILOGINIANCHORIPATRICKI31690K31_AN3.DOC 8 Concentration (pg.t.) PB083-1SWMID-140318-N PB083-1SWMID-140318-D RPD PCB-094 3.32 3.65 9 PCB-095 217 227 5 PCB-096 7.27 7.49 3 PCB-098 0.974 1.45 39 PCB-099 146 149 2 PCB-102 15.2 15.6 3 PCB-103 2.67 2.85 7 PCB-105 99.3 108 8 PCB-106 1.18 0.823 36 PCB-107/124 8.58 9 5 PCB-109 15.7 16.1 3 PCB-110 292 305 4 PCB-112 1.07 0.984 8 PCB-114 6.19 6.49 5 PCB-115 7.61 9.47 22 PCB-117 8.96 8.19 9 PCB-118 182 191 5 PCB-120 0.681 0.555 20 PCB-122 4.58 4.31 6 PCB-123 5.04 5.63 11 PCB-126 1.23 1.08 13 PCB-128/166 16.5 17.1 4 PCB-129/138/163 105 104 1 PCB-130 7.57 7.57 0 PCB-131 1.84 2.1 13 PCB-132 37.2 36.5 2 PCB-133 1.43 1.32 8 PCB-134 6.39 5.51 15 Compound V:ILOGINIANCHORIPATRICKI31690K31_AN3.DOC 9 Concentration (pgA..) P8083-1 SWMID-140318-N P8083-1 SWMID-140318-D RPD 28.2 28.4 1 PC8-136 14 13.1 7 PC8-137 5.51 5.75 4 PC8-139/140 2.37 2.24 6 PC8-141 16.9 17 1 PC8-143 0.717 0.367 65 PC8-144 4.2 4.67 11 PC8-146 13.8 13.9 1 71 70.2 1 PC8-150 0.259U 0.275 200 PC8-152 0.263U 0.228 200 69.2 68.6 1 PCB-154 1.1 1.03 7 PCB-155 0.329 0.273 19 PCB-156/157 11.4 11.5 1 PCB-158 10.1 10.4 3 PCB-159 0.749 0.677 10 PCB-162 0.411 U 0.473 200 PCB-164 7.06 6.63 6 PCB-167 3.4 3.5 3 PCB-170 14.7 14.5 1 PCB-171/173 4.68 4.32 8 PCB-172 2.63 2.48 6 PCB-174 15.9 14 13 PCB-175 0.667 0.662 1 PCB-176 1.95 1.91 2 PCB-177 7.61 8.43 10 PCB-178 3.24 3.27 1 Compound PC8-135/151 PC8-147/149 PCB-153/168 V:ILOGINIANCHORIPATRICKI31690K31_AN3.DOC 10 Concentration (pg.t.) PB083-1 SWMID-140318-N PB083-1 SWMID-140318-D RPD PCB-179 7.12 6.7 6 PCB-180/193 31.5 28.6 10 PCB-183 7.79 7.14 9 PCB-184 0.31U 0.498 200 PCB-185 1.48 1.59 7 PCB-187 18.3 17.5 4 PCB-189 0.645 0.73 12 PCB-190 2.78 2.73 2 PCB-191 0.677 0.726 7 PCB-194 6.46 6.09 6 PCB-195 2.5 2.23 11 PCB-196 3.55 2.65 29 PCB-197 0.581 0.501 15 9.2 7.B2 16 PCB-200 0.B53 1.08 23 PCB-201 1.16 1.09 6 PCB-202 2.06 1.B3 12 PCB-203 4.61 4.23 9 PCB-206 4.21 4.7 11 PCB-207 1.47 2.22 41 PCB-20B 2.19 2.33 6 PCB-209 42.6 45.2 6 PCB-061 10701074/076 726 774 6 PCB-086/0B7/097/108/119/125 207 218 5 Compound PCB-198/199 xv. Field Blanks No field blanks were identified in this SDG. V:ILOGINIANCHORIPATRICKI31690K31_AN3.DOC 11 Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Data Qualification Summary - SDG A6521 SOG A6521 Sample PB083-1SWMIO-140318-N PB083-1 SWMIO-140318-0 PB087-1 SWMIO-140318-N PB091-1 SWMIO-140318-N PB093-1 SWM I0-140318-N PB095-1 SWMIO-140318-N Compound Flag A orP All compounds reported by the laboratory as estimated maximum possible concentration (EMPC) J (all detects) A Reason Compound quantitation Patrick Bayou Superfund Site Polychlorinated Biphenyls as Congeners - Laboratory Blank Data Qualification Summary - SDG A6521 SOG Sample Compound Modified Final Concentration A orP A6521 PB083-1 SWM I0-140318-N PCB-3 PCB-11 5.7U pg/L 22.7U pg/L A A6521 PB083-1 SWMIO-140318-0 PCB-3 PCB-11 4.96U pg/L 21.2U pg/L A A6521 PB087-1SWMIO-140318-N PCB-3 PCB-11 6.04U pg/L 26.3U pg/L A A6521 PB091-1 SWMIO-140318-N PCB-3 PCB-11 5.96U pg/L 30.6U pg/L A A6521 PB093-1 SWMIO-140318-N PC B-3 PCB-11 5.06U pg/L 27.6U pg/L A A6521 PB095-1 SWM I0-140318-N PCB-3 PCB-11 5.66U pg/L 26.2U pg/L A V:ILOGINIANCHORIPATRICKI31690K31_AN3.DOC 12 LDC #: 31690K31 VALIDATION SDG#: A6521 Laboratory: SGS AflBlytisal perspectiye.. COMPLETENESS WORKSHEET Stage 2B Date: If- 1--1'1 Page:-1-0f-/Reviewer: '-:fbc....2nd Reviewer: OZ- METHOD: HRGC/HRMS Polychlorinated Biphenyl Congeners (EPA Method 1668A) The samples listed below were reviewed for each of the following validation areas. Validation findings are noted in attached validation findings worksheets. I I I llalidatioD A[ea I A I. Technical holdinq times II. GC/MS Instrument performance check ;j III. Initial calibration A IV. Continuinq calibration/IQ.L- V. Blanks VI. Matrix spike/Matrix spike duplicates VII. Laboratory control samples VIII. Regional quality assurance and quality control 1+ ~"" "A X. Target compound identifications XI. Compound quantitation/RUI.,QQ,ll::9Ss XII. System performance N XIII. Overall assessment of data A XIV. Field duplicates XV. Field blanks = = = Validated Samples: ~d-iJ ~3()IS0 c..S· OPR sv.J Internal standards A Acceptable N Not provided/applicable SW See worksheet 3hc'-::f-!-.!...!!.!./A..!.. Was the method blank contaminated? Blank extraction date:_---"'-o3""' ..:::2~0/c...!1c...!4 __ Blank analysis date: Cone. units· PQ/L 1 . . . . . .[ MB1. 11~~nkID 5x 2.91 14.6 PCB-1 1.08 5.4 PCB-3 1.69 8.5 PCB-11 8.82 44.1 PCB-31 1.96* 9.8 PCB-28/20 2.82* 14.1 PCB-21 133 2.06 10.3 PCB-52 5.34 26.7 2* 10.0 PCB-44/47/65 3.67 18.4 PCB-61 170/74176 3.84 19.2 PCB-95 4.27 21.4 PCB-113/90/101 4,17* 20.9 PCB·99 1.67* 8.4 PCB-108/119/86/97/125/87 2.67* 13,4 5.2 26.0 2 10.0 PCB-110 PCB-151/135 V:lValidation-Blanks\31690K31 ,wpd I ;;Z 5.1d-~ .1- All Associated samples: Sample PCB-118 PCB-69/49 03128/14 ;) ." . ..,,' "...&:, Qual U .... 3 L/ L-L0 \p ~-otf 5.Qtp '3)~tXo 5.{Ptt ;)J. ). .;1-tp. ~ 30-lo cf"f,(P ~,)- S- (p Page~ of~ VALIDATION FINDINGS WORKSHEET Blanks LDC #: 31690K31 Reviewer: ':11"",,; 2nd Reviewer: ~ METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) ~f BlanllO Sample Identification MB1. 11903 5x PCB-147/149 3.55 17.8 PCB-132 2.01" 10.1 PCB-153/168 2.85" 14.3 PCB-163/138/129 2.96 14.8 ,- ~ ~ ~- IUlar IT.• _I " I n: I trnrr 1"'- -\"05 1"'_,_1 T_ ••_ 1"'0_ I~ £.. A A? AA 1 6.84" ~2 14.tr "?n ,- ,- - lU~ ITcitaT 13.il' ,)7 .IT n:rn:n ."" "EMPC All contaminants within five times the method blank concentration were qualified as not detected. V:IValidation-BlanksI31690K31.wpd 3 '-I c::: (0 page:~of+­ VALIDATION FINDINGS WORKSHEET Internal Standards Reviewer:~ 2nd Reviewer: 07 - METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) PI e~~ see qua IT bi I' I entlTIed as "N/A" I Icaf Ions e ow f or aIquestions answered "N' '. Not app rIca bl e questions are 'd Y NIA Are all internal standard recoveries within the QC criteria? Y N filA Was the SIN ratio all internal standard peaks> 10? ~ # I I Date Lab ID/Reference Internal Standard MB1 11903 13C PCB-104 I P:\AECOMIINTST_1668.wpd I % Recovery (Limit: Qualifications ) J/UJ/P (PCB-96, PCB-1 04 I =Fet81 Pellt8 6Bsj 158 (25-150) I I ~ I LDC #: 3) 'I10}L31 VALIDATION FINDINGS WORKSHEET Compound Quantitation and Reported CRQLs Page: _1_of_1_ Reviewer: 2nd Reviewer: '::fh= O? METHOD: HRGC/HRMS PCB Congeners (EPA Method 1668A) Please see qualifications below for all questions answered "N". Not applicable questions are identified as "N/A". ~ ~ # I Were the correct internal standard (IS), quantitation ions and relative response factors (RRF) used to quantitate the compound? Compound quantitation and CRQLs were adjusted to reflect all sample dilutions and dry weight factors (if necessary). Date I Compound I I Finding Associated Samples Qualifications EMPC results All Jdets/A I I I Comments: __________________________________________________________________________________________________________ P:lAnchor_P0\1668-COMQUAwpd LDC#:31690K31 VALIDATION FINDINGS WORKSHEET Field Duplicates PCB Congeners (EPA Method 1668A) Concentration (pg/L) Analyle RPD 1 2 PCB-OOl 23 21.4 7 PCB-002 2.1 1.49 34 PCB-003 5.7 4.96 14 PCB-004 151 145 4 PCB-005 2.02 1.83 10 PCB-006 47 45.8 3 PCB-007 3.57 3.16 12 PCB-008 101 101 0 PCB-009 7.02 6.87 2 IpCB-01O 4.44 4.61 4 PCB-Oll 22.7 21.2 7 PCB-012/013 15.2 13.8 10 PCB-015 51.5 52.4 2 IpCB-016 172 181 5 IpCB-017 180 184 2 IpCB-018/030 510 522 2 IpCB-019 79.7 79.7 0 IpCB-019-C13 94.3 104 10 PCB-020/028 461 482 4 PCB-021/033 130 137 5 PCB-022 131 135 3 IpcB-024 3.43 2.8 20 IpCB-025 62.9 63.6 1 IpCB-026/029 90.3 91.5 1 IpCB-027 31.1 31.5 1 IpCB-031 463 483 4 PCB-032 170 170 0 PCB-034 2.42 2.48 2 PCB-035 7.39 7.21 2 PCB-037 73.5 77.6 5 PCB-038 0.957U 0.797 200 PCB-039 3.81 4.53 17 PCB-040/071 312 330 6 PCB-041 52.3 51.6 1 PCB-042 178 184 3 PCB-043 28.3 28.2 0 PCB-044/047/065 702 737 5 PCB-045 129 144 11 PCB-046 57.3 62.5 9 PCB-048 125 131 5 PCB-049/069 408 425 4 PageLofY Reviewe~ 2nd Reviewer: Ct'I.---- LDC#:31690K31 VALIDATION FINDINGS WORKSHEET Field Duplicates PCB Congeners (EPA Method 1668A) ~,,~ Concentration (pg/L) I RPD 1 2 PCB-050/053 154 159 3 PCB-051 70.9 62 13 PCB-052 829 875 5 PCB-054 2.83 3.2 12 PCB-055 4.43 5.47 21 225 237 5 PCB-057 2.47 2.38 4 PCB-058 0.923 1.12 19 PCB-059/062/075 49.3 52.3 6 PCB-060 96.8 105 8 PCB-063 16.3 17.2 5 PCB-056 PCB-064 264 277 5 PCB-066 453 482 6 PCB-067 10.6 11.3 6 PCB-068 25.6 27.1 6 PCB-072 3.15 3.23 3 PCB-073 1.59 1.71 7 PCB-On 35.4 37.7 6 PCB-079 8.5 3.07 94 PCB-081 1.82 1.68 8 PCB-082 52.4 54.2 3 PCB-083 15.1 18.8 22 PCB-084 103 110 7 PCB-085/116 68.5 73.9 8 PCB-089 10.6 10.5 1 PCB-090/101/113 230 241 5 PCB-091 52.7 55.9 6 PCB-092 45.1 46.8 4 PCB-093/100 5.16 5.05 2 PCB-094 3.32 3.65 9 PCB-095 217 227 5 PCB-096 7.27 7.49 3 PCB-098 0.974 1.45 39 PCB-099 146 149 2 PCB-l02 15.2 15.6 3 PCB-103 2.67 2.85 7 PCB-lOS 99.3 108 8 PCB-106 1.18 0.823 36 PCB-107/124 8.58 9 5 PCB-109 15.7 16.1 3 PCB-110 292 305 4 page:2?f~ Reviewe~ 2nd Reviewer:~ LDC#:31690K31 VALIDATION FINDINGS WORKSHEET Field Duplicates PCB Congeners (EPA Method 1668A) Concentration (pg/L) Analyte RPD 1 2 PCB-112 1.07 0.984 8 PCB-114 6.19 6.49 5 PCB-115 7.61 9.47 22 PCB-117 8.96 8.19 9 PCB-118 182 191 5 PCB-120 0.681 0.555 20 PCB-122 4.58 4.31 6 PCB-123 5.04 5.63 11 PCB-126 1.23 1.08 13 PCB-128/166 16.5 17.1 4 PCB-129/138/163 105 104 1 PCB-130 7.57 7.57 0 PCB-131 1.84 2.1 13 PCB-132 37.2 36.5 2 PCB-133 1.43 1.32 8 PCB-134 6.39 5.51 15 PCB-135/151 28.2 28.4 1 PCB-136 14 13.1 7 PCB-137 5.51 5.75 4 PCB-139/140 2.37 2.24 6 PCB-141 16.9 17 1 PCB-143 0.717 0.367 65 PCB-144 4.2 4.67 11 PCB-146 13.8 13.9 1 71 70.2 1 PCB-150 0.259U 0.275 200 PCB-152 0.263U 0.228 200 PCB-147/149 PCB-153/168 69.2 68.6 1 PCB-154 1.1 1.03 7 PCB-155 0.329 0.273 19 11.4 11.5 1 PCB-156/157 PCB-158 10.1 10.4 3 PCB-159 0.749 0.677 10 PCB-162 O.411U 0.473 200 PCB-l64 7.06 6.63 6 PCB-167 3.4 3.5 3 PCB-170 14.7 14.5 1 PCB-171/173 4.68 4.32 8 PCB-l72 2.63 2.48 6 PCB-174 15.9 14 13 PCB-175 0.667 0.662 1 page:~ Reviewe " 2nd Reviewer: C/I-- LDC#:31690K31 page:LfOf~ VALIDATION FINDINGS WORKSHEET Field Duplicates Review&:W' 2nd Reviewer: CIt-- PCB Congeners (EPA Method 1668A) 'Analyte I I Concentration (pg/L) 1 I 2 I I RPD I PCB-176 1.95 1.91 2 PCB-l77 7.61 8.43 10 PCB-178 3.24 3.27 1 IpCB-179 7.12 6.7 6 PCB-180/193 31.5 28.6 10 PCB-183 7.79 7.14 9 PCB-184 0.31U 0.498 200 IpCB-185 1.48 1.59 7 IpCB-187 18.3 17.5 4 IpCB-189 0.645 0.73 12 PCB-190 2.78 2.73 2 PCB-191 0.677 0.726 7 PCB-194 6.46 6.09 6 PCB-195 2.5 2.23 11 PCB-196 3.55 2.65 29 IpCB-197 0.581 0.501 15 9.2 7.82 16 PCB-200 0.853 1.08 23 PCB-201 1.16 1.09 6 PCB-198/199 PCB-202 2.06 1.83 12 PCB-203 4.61 4.23 9 PCB-206 4.21 4.7 11 PCB-207 1.47 2.22 41 IpCB-208 2.19 2.33 6 PCB-209 42.6 45.2 6 PCB-061/070/074/076 726 774 6 IpCB-086/087/097/108/119/125 207 218 5 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Conventional Parameters (mg/L) Total suspended solids Dissolved organic carbon Total organic carbon PCB Congeners (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 mg/L mg/L mg/L SM2540D SW9060 SW9060 11 J -6.44 ---- 14 J -5.52 11 J 9.8 J 6.75 17 J 9.4 J 5.47 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.00145 U 0.00132 U 0.00147 U 0.00869 J 0.00153 U 0.00153 U 0.00141 U 0.0051 J 0.00161 U 0.00189 U 0.0231 U 0.00147 U 0.00128 U 0.00674 J 0.017 0.0183 0.0532 0.00817 J 0.0677 0.0112 J 0.0139 0.00142 U 0.00185 U 0.00608 J 0.00945 J 0.00475 J 0.0467 0.0193 0.00144 U 0.00151 U 0.00137 U 0.00334 U 0.00249 U 0.00276 U 0.0048 U 0.00327 U 0.00326 U 0.003 U 0.00313 J 0.00345 U 0.00308 U 0.013 U 0.00315 U 0.00272 U 0.00324 U 0.00505 U 0.00835 J 0.00322 U 0.00432 U 0.00485 U 0.00452 J 0.00265 U 0.00251 U 0.00289 U 0.00246 U 0.00247 U 0.00276 U 0.0033 U 0.00258 U 0.00255 U 0.00268 U 0.00242 U 0.00604 J 0.00207 U 0.00204 U 0.0986 J 0.00425 UJ 0.00423 UJ 0.00396 UJ 0.0205 J 0.0044 UJ 0.00473 UJ 0.0233 UJ 0.00445 UJ 0.00366 UJ 0.0472 J 0.0542 0.0559 0.11 0.0475 0.0962 0.0176 J 0.0271 0.00295 U 0.00333 U 0.0125 0.0159 J 0.0121 0.0767 0.0486 0.00294 U 0.00333 U 0.00282 U 0.035 0.00348 J 0.00963 J 0.245 J 0.00375 UJ 0.0377 J 0.00441 J 0.163 J 0.0109 J 0.00949 J 0.0298 UJ 0.0145 J 0.00324 UJ 0.108 J 0.429 0.417 1.18 0.134 1.07 0.376 0.281 0.00377 U 0.00604 J 0.0678 0.17 0.0653 1.12 0.353 0.00542 J 0.00425 U 0.0036 U 0.0566 0.0066 U 0.0167 J 0.368 J 0.014 UJ 0.0524 J 0.0131 UJ 0.244 J 0.0145 UJ 0.0106 UJ 0.0459 J 0.0228 J 0.0121 UJ 0.175 J 0.753 0.741 2.08 0.219 1.66 0.595 0.436 0.00972 U 0.0206 0.0968 0.248 0.123 1.7 0.642 0.00967 U 0.0273 0.00929 U 1 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.00164 U 0.00146 U 0.00132 U 0.0518 0.00549 J 0.0263 0.00097 U 0.14 0.0139 0.00586 J 0.0141 0.0824 0.0182 J 0.0217 0.182 0.000732 U 0.00122 U 0.0425 0.00116 U 0.00115 U 0.0111 J 0.0278 0.148 0.00103 U 0.0583 0.118 0.00108 U 0.0234 0.0011 U 0.00063 U 0.0114 0.00126 U 0.00106 U 0.00101 U 0.00125 U 0.0126 0.00291 U 0.00258 U 0.00234 U 0.0017 U 0.00206 U 0.00189 U 0.00202 U 0.0293 J 0.00187 U 0.0021 U 0.00173 U 0.00285 U 0.0017 U 0.0818 0.00445 U 0.00138 U 0.0017 U 0.00169 U 0.00162 U 0.0016 U 0.00124 U 0.00168 U 0.00161 U 0.00144 U 0.00117 U 0.00167 U 0.00151 U 0.0371 0.00154 U 0.00131 U 0.0016 U 0.00176 U 0.00149 U 0.00142 U 0.00175 U 0.00194 U 2 of 67 0.0158 0.00313 U 0.00283 U 0.0385 0.00406 U 0.0235 0.00414 U 0.104 0.0127 0.00624 J 0.0127 0.06 0.0195 J 0.0217 0.113 0.00315 J 0.00269 U 0.0241 0.00258 U 0.00253 U 0.00696 J 0.0049 J 0.0871 0.00231 U 0.0315 0.051 0.00244 U 0.0207 0.00252 U 0.00241 U 0.00338 J 0.0028 U 0.00229 U 0.00228 U 0.00277 U 0.00941 J 0.173 0.00399 U 0.00361 U 0.743 0.0829 0.427 0.0557 1.74 0.303 0.113 0.312 1.08 0.3 0.0962 2.16 0.0056 J 0.0108 J 0.582 0.00463 J 0.00395 U 0.124 0.242 2.21 0.0393 0.681 1.3 0.0272 0.00364 U 0.00394 U 0.00276 U 0.102 0.00437 U 0.00358 U 0.00357 U 0.00433 U 0.124 0.308 0.0103 U 0.0093 U 1.18 0.16 0.674 0.0865 2.66 0.418 0.164 0.486 1.69 0.426 0.14 3.31 0.0106 J 0.00992 U 1 0.00953 U 0.00932 U 0.181 0.428 4 0.0705 1.09 2.34 0.0485 0.0323 0.0239 J 0.00792 U 0.196 0.0103 U 0.00845 U 0.00841 U 0.0102 U 0.224 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.00669 J 0.0265 0.027 0.0674 0.00112 U 0.00186 J 0.0892 0.0167 0.0181 0.00108 U 0.00118 U 0.066 0.00058 U 0.00111 U 0.0525 0.00427 J 0.000991 U 0.000472 U 0.0439 0.000872 U 0.00337 J 0.00732 J 0.115 0.000785 U 0.000816 U 0.0022 J 0.000842 U 0.000868 U 0.0769 0.000773 U 0.000775 U 0.000927 U 0.000779 U 0.00107 U 0.000871 U 0.0151 J 0.00204 U 0.00187 U 0.00139 U 0.00138 U 0.00159 U 0.00172 U 0.00416 U 0.00157 U 0.00159 U 0.00154 U 0.00168 U 0.00466 U 0.00106 U 0.00157 U 0.00137 U 0.00153 U 0.00141 U 0.000864 U 0.00122 U 0.00124 U 0.00122 U 0.0011 U 0.00457 U 0.00112 U 0.00116 U 0.00104 U 0.0012 U 0.00124 U 0.00266 U 0.0011 U 0.0011 U 0.00123 U 0.00111 U 0.00173 U 0.00127 U 0.0014 U 3 of 67 0.0049 U 0.0208 0.0105 J 0.0389 J 0.00395 U 0.00424 U 0.0627 0.013 0.0141 0.00385 U 0.0041 U 0.0555 0.00309 U 0.00402 U 0.0326 0.00347 U 0.00355 U 0.00272 U 0.0159 0.00313 U 0.00303 U 0.00403 J 0.0719 0.00278 U 0.00292 U 0.00274 U 0.00282 U 0.0031 U 0.0427 0.00279 U 0.00279 U 0.00313 U 0.00298 U 0.00232 U 0.00298 U 0.00946 J 0.036 0.263 0.183 0.565 0.00492 U 0.0207 0.715 0.16 0.118 0.0161 J 0.0051 U 0.643 0.0164 0.005 U 0.433 0.0431 0.00884 J 0.00253 U 0.308 0.0039 U 0.0253 0.0471 0.94 0.00345 U 0.00363 U 0.0167 0.0035 U 0.00386 U 0.6 0.00347 U 0.00347 U 0.00952 J 0.0142 0.00252 U 0.00392 U 0.056 0.0632 0.499 0.303 1.05 0.012 U 0.0316 J 1.37 0.307 0.228 0.0117 U 0.0125 U 1.15 0.0411 0.0122 U 0.824 0.0795 0.0108 U 0.00798 U 0.591 0.00955 U 0.04 0.0894 1.69 0.00845 U 0.00889 U 0.0263 0.0389 0.0411 1.17 0.00849 U 0.00849 U 0.0143 J 0.0246 0.00696 U 0.01 U 0.121 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0905 0.00679 J 0.000744 U 0.024 0.000677 U 0.00542 J 0.0195 J 0.00676 J 0.00435 J 0.000632 U 0.0122 0.000761 U 0.000642 U 0.00227 J 0.000472 U 0.0121 0.0489 0.000625 U 0.000438 U 0.000451 U 0.0596 0.000559 U 0.000389 U 0.0108 J 0.00868 J 0.000805 U 0.000554 U 0.000494 U 0.000809 U 0.0061 J 0.000532 U 0.00358 J 0.000971 U 0.018 0.00548 J 0.00346 J 0.00418 U 0.00155 U 0.00149 U 0.00145 U 0.00136 U 0.00173 U 0.00133 U 0.000956 U 0.00123 U 0.00127 U 0.0014 U 0.00153 U 0.00129 U 0.00128 U 0.000944 U 0.00122 U 0.00457 U 0.00125 U 0.000875 U 0.000901 U 0.00232 U 0.00112 U 0.000777 U 0.00163 U 0.000946 U 0.00115 U 0.00111 U 0.000991 U 0.00116 U 0.00103 U 0.00107 U 0.00106 U 0.00134 U 0.00163 U 0.00161 U 0.00154 U 4 of 67 0.0515 0.00349 J 0.00301 U 0.014 J 0.00283 U 0.0031 U 0.0185 J 0.0104 0.00276 U 0.00259 U 0.00849 J 0.00299 U 0.00288 U 0.00263 U 0.00239 U 0.00822 J 0.0457 0.00263 U 0.00229 U 0.00229 U 0.0424 0.00236 U 0.00212 U 0.00572 J 0.00303 J 0.00304 U 0.00223 U 0.00209 U 0.00303 U 0.00317 J 0.00225 U 0.00295 U 0.00357 U 0.0074 J 0.00432 U 0.00433 U 0.398 0.0307 0.00677 J 0.125 0.00663 J 0.0222 J 0.113 0.0558 0.0168 J 0.00907 J 0.0569 0.00463 U 0.00444 U 0.0143 J 0.00315 U 0.0602 0.292 0.00406 U 0.00302 U 0.00302 U 0.298 0.00698 J 0.00279 U 0.0378 0.0392 0.00263 U 0.00344 U 0.00322 U 0.00262 U 0.0279 0.00348 U 0.0111 J 0.0031 U 0.0647 0.0188 J 0.0108 J 0.739 0.0538 0.0103 U 0.229 0.00967 U 0.0309 J 0.221 0.114 0.0196 J 0.00885 U 0.102 0.0102 U 0.00982 U 0.0301 0.00769 U 0.105 0.594 0.00896 U 0.00738 U 0.00736 U 0.558 0.00807 U 0.00682 U 0.0786 J 0.0647 0.008 U 0.00761 U 0.00712 U 0.00797 U 0.0492 0.00769 U 0.028 0.0101 U 0.137 0.0511 0.0239 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0138 0.000897 U 0.00132 J 0.00834 J 0.00397 J 0.00555 J 0.033 0.000908 U 0.00082 U 0.00874 J 0.000659 U 0.000933 U 0.000636 U 0.0183 0.000541 U 0.00103 U 0.00293 J 0.000726 U 0.000763 U 0.00722 J 0.00186 U 0.00399 J 0.000767 U 0.00864 J 0.00077 U 0.000748 U 0.00255 J 0.00418 J 0.000805 U 0.00131 U 0.00369 U 0.00252 J 0.00415 J 0.0414 0.00147 U 0.00147 U 0.00151 U 0.00139 U 0.00103 U 0.00159 U 0.00158 U 0.00109 U 0.00284 J 0.00141 U 0.00127 U 0.00124 U 0.00114 U 0.00145 U 0.0011 U 0.00186 J 0.000936 U 0.0015 U 0.00118 U 0.00113 U 0.00119 U 0.00231 U 0.00251 U 0.00177 U 0.00124 U 0.00187 U 0.00124 U 0.00121 U 0.00128 U 0.00173 U 0.0013 U 0.00177 U 0.0052 U 0.00303 U 0.00307 U 0.00169 U 0.00334 U 0.00334 U 5 of 67 0.0106 J 0.00385 U 0.00188 U 0.00495 J 0.00274 U 0.00426 J 0.0208 0.00385 U 0.00357 U 0.00427 J 0.00211 U 0.00372 U 0.00202 U 0.0138 0.00191 U 0.00249 U 0.00308 U 0.00328 U 0.00336 U 0.00525 U 0.00538 U 0.00372 U 0.00242 U 0.00505 J 0.00274 U 0.00253 U 0.00274 U 0.00363 U 0.00271 U 0.00449 U 0.00684 U 0.00421 U 0.00437 U 0.0441 0.008095 J 0.00604 J 0.0635 0.00459 U 0.00895 J 0.0378 0.0201 0.0341 0.138 0.00458 U 0.00425 U 0.0405 0.00214 U 0.00442 U 0.00205 U 0.0845 0.00194 U 0.00286 U 0.0134 0.00391 U 0.004 U 0.032 0.0141 0.0229 0.0023 U 0.048 0.00261 U 0.00906 J 0.0196 J 0.0302 0.00258 U 0.00509 U 0.0621 0.0395 0.0468 1.68 0.04811 J 0.04811 J 0.132 0.0123 U 0.0124 0.0916 0.024 J 0.0653 0.279 0.0123 U 0.0114 U 0.0761 J 0.00766 U 0.0118 U 0.00732 U 0.173 0.00693 U 0.00782 U 0.0246 J 0.0105 U 0.0107 U 0.0716 0.0229 J 0.0249 J 0.00843 U 0.0616 J 0.00955 U 0.0139 J 0.0397 0.0378 0.00945 U 0.0155 U 0.144 0.061 0.0841 3.66 0.0766 J 0.0733 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) PCB Congeners, Dissolved (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.03744 J 0.02053 J 0.281755 J 0.27575 J 1.009076 J 1.00225 J 0.6454655 J 0.63751 J 0.3419275 J 0.33665 J 0.1268465 J 0.12289 J 0.02971 J 0.02658 J 0.008515 J 0.00667 J 0.0414 0.0414 2.5242555 J 2.47023 J 0.024615 J 0.00313 J 0.04014 J 0.01287 J 0.173975 J 0.1482 J 0.00466 U 0.00466 U 0.00457 U 0.00457 U 0.017958 J 0.0047 J 0.00251 U 0.00251 U 0.0052 U 0.0052 U 0.00169 U 0.00169 U 0.33117 J 0.1689 J 0.19279 J 0.1663 J 0.600765 J 0.5901 J 0.66254 J 0.64463 J 0.42974 J 0.39204 J 0.252095 J 0.22408 J 0.089335 J 0.06608 J 0.022855 J 0.00505 J 0.00684 U 0.00684 U 0.0441 0.0441 2.310025 J 2.13842 J 0.611395 J 0.593 J 5.85717 J 5.84756 J 12.7564 J 12.74133 J 5.330595 J 5.30596 J 1.70615 J 1.68435 J 0.55252 J 0.53515 J 0.18215 J 0.17586 J 0.1484 0.1484 1.68 1.68 28.87289 J 28.75972 J 0.94025 J 0.9081 J 9.67384 9.6497 20.852325 J 20.8153 J 9.960005 J 9.896 J 3.209705 J 3.1379 J 1.139365 J 1.09 J 0.293865 J 0.2724 J 0.2891 0.2891 3.66 3.66 50.095055 J 49.7918 J ---------------- 0.00167 U 0.00138 U 0.00161 U 0.00307 U 0.00196 U 0.00199 U 0.00187 U 0.00191 U 0.0022 U 0.00198 U 0.0116 U 0.00199 U 0.00168 U 0.00207 U 0.00362 U ---------------- 0.0328 0.00291 U 0.00662 J 0.241 J 0.00389 UJ 0.028 J 0.00362 UJ 0.144 J 0.00691 J 0.00813 J 0.03 UJ 0.00406 UJ 0.00335 UJ 0.0836 J 0.327 0.0332 0.00279 U 0.00276 U 0.265 J 0.00464 UJ 0.0342 J 0.00432 UJ 0.152 J 0.00972 J 0.00972 J 0.0348 J 0.00752 J 0.004 UJ 0.0904 J 0.398 6 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- 0.00599 J 0.00242 U 0.00328 U 0.00476 U 0.00435 J 0.00195 J 0.00144 U 0.00218 U 0.00298 J 0.00141 U 0.00208 U 0.00309 U 0.00195 U 0.00146 U 0.00165 U 0.00145 U 0.0018 U 0.00155 U 0.00139 U 0.00133 U 0.00166 U 0.00149 U 0.0016 U 0.0222 J 0.00155 U 0.00163 U 0.00135 U 0.00245 U 0.00131 U 0.0525 0.00405 U 0.00084 U 0.00126 U 0.00128 U 0.0012 U 0.00115 U 7 of 67 ------------------------------------- 0.309 0.919 0.117 0.719 0.254 0.19 0.00435 U 0.00538 J 0.0444 0.118 0.0503 0.773 0.256 0.00433 U 0.00995 J 0.00416 U 0.0937 0.00461 U 0.00417 U 0.381 0.071 0.219 0.031 J 0.94 0.181 0.068 0.173 0.569 0.194 0.0589 1.22 0.00417 U 0.00447 U 0.231 0.0043 U 0.0042 U 0.362 1.11 0.139 0.738 0.26 0.203 0.00423 U 0.00752 J 0.0444 0.121 0.0647 0.803 0.312 0.00421 U 0.00966 J 0.00405 U 0.0987 0.00448 U 0.00405 U 0.379 0.081 0.223 0.0326 0.944 0.194 0.0681 0.171 0.567 0.195 0.0508 1.23 0.00453 J 0.00324 U 0.266 0.00311 U 0.00304 U August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- 0.000989 U 0.00127 U 0.00448 U 0.00107 U 0.000936 U 0.00247 J 0.00113 U 0.0331 0.00113 U 0.00103 U 0.00137 U 0.00134 U 0.00112 U 0.00107 U 0.00137 U 0.0014 U 0.00135 U 0.00132 U 0.0011 U 0.000997 U 0.00121 U 0.00126 U 0.00332 U 0.00103 U 0.00116 U 0.00111 U 0.00118 U 0.00345 U 0.000861 U 0.0013 U 0.00107 U 0.000942 U 0.000997 U 0.000709 U 0.000915 U 0.000925 U 8 of 67 ------------------------------------- 0.0678 0.0962 0.948 0.0139 0.351 0.522 0.00926 J 0.00387 U 0.00418 U 0.00375 U 0.03 0.00465 U 0.00381 U 0.00379 U 0.0046 U 0.0459 0.0176 0.102 0.0544 0.184 0.00542 U 0.00581 U 0.236 0.053 0.038 0.00528 U 0.00563 U 0.252 0.00761 J 0.00551 U 0.129 0.0162 0.00486 U 0.00383 U 0.0774 0.0043 U 0.0698 0.104 1.01 0.015 0.354 0.559 0.00935 J 0.0139 0.00303 U 0.00264 U 0.0351 0.00337 U 0.00276 U 0.00275 U 0.00333 U 0.035 0.0149 0.101 0.0472 0.177 0.00416 U 0.00446 U 0.234 0.0486 0.0389 0.00405 U 0.00432 U 0.246 0.011 0.00423 U 0.128 0.00999 J 0.00373 U 0.0032 U 0.0781 0.0033 U August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- 0.000915 U 0.000809 U 0.00351 U 0.000818 U 0.00082 U 0.00082 U 0.000837 U 0.000936 U 0.00173 U 0.000808 U 0.000782 U 0.000955 U 0.000844 U 0.00105 U 0.000893 U 0.00107 U 0.000947 U 0.00115 U 0.00109 U 0.00107 U 0.000995 U 0.00131 U 0.000946 U 0.00075 U 0.000925 U 0.000913 U 0.00104 U 0.00111 U 0.000915 U 0.000931 U 0.000722 U 0.000906 U 0.00257 U 0.000914 U 0.000689 U 0.00069 U 9 of 67 ------------------------------------- 0.00754 J 0.0148 0.283 0.00381 U 0.004 U 0.00395 U 0.00386 U 0.00425 U 0.145 0.00382 U 0.00382 U 0.0045 U 0.00409 U 0.00332 U 0.00425 U 0.00822 J 0.0832 0.00473 U 0.00451 U 0.0288 0.00425 U 0.00465 U 0.0273 J 0.0135 J 0.00415 U 0.00389 U 0.0156 0.00449 U 0.00431 U 0.00395 U 0.00326 U 0.0157 0.07 0.00394 U 0.00313 U 0.00312 U 0.00708 J 0.0125 0.292 0.00292 U 0.00307 U 0.003 U 0.00296 U 0.005 J 0.157 0.00293 U 0.00293 U 0.00342 U 0.00417 J 0.00262 U 0.00339 U 0.0132 J 0.0906 0.0112 0.00309 U 0.0318 0.00291 U 0.00319 U 0.0259 J 0.0192 0.00284 U 0.00266 U 0.0171 0.00308 U 0.00296 U 0.00271 U 0.00242 U 0.0175 0.0742 0.0027 U 0.00232 U 0.00232 U August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- 0.00229 U 0.0008 U 0.000588 U 0.00132 U 0.000701 U 0.000879 U 0.000815 U 0.000726 U 0.000887 U 0.000773 U 0.000788 U 0.000815 U 0.00102 U 0.00143 U 0.00145 U 0.0014 U 0.0014 U 0.00126 U 0.000937 U 0.00142 U 0.00143 U 0.000992 U 0.00111 U 0.00126 U 0.00115 U 0.0011 U 0.00103 U 0.00133 U 0.00102 U 0.00117 U 0.000837 U 0.00108 U 0.00103 U 0.00103 U 0.00107 U 0.00198 U 10 of 67 ------------------------------------- 0.0644 0.00355 U 0.00289 U 0.00659 J 0.00932 J 0.00366 U 0.00334 U 0.00313 U 0.00364 U 0.00304 U 0.00338 U 0.00355 U 0.00487 U 0.0113 0.00547 U 0.00549 U 0.00975 J 0.00488 U 0.00297 U 0.0055 U 0.00433 U 0.00706 J 0.0243 0.00488 U 0.00452 U 0.00446 U 0.00334 U 0.00471 U 0.00319 U 0.0159 0.00302 U 0.00359 U 0.00434 U 0.00416 U 0.00426 U 0.00759 U 0.0706 0.00243 U 0.00215 U 0.0076 J 0.0112 0.00262 U 0.00229 U 0.00215 U 0.00261 U 0.00208 U 0.00232 U 0.00254 U 0.00316 U 0.0118 0.00476 U 0.00477 U 0.0121 0.00424 U 0.00211 U 0.00794 J 0.00307 U 0.0106 0.0242 0.00424 U 0.00392 U 0.00513 J 0.00236 U 0.00409 U 0.00226 U 0.0165 0.00214 U 0.00328 U 0.00346 U 0.00361 U 0.0037 U 0.00746 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID EF006.1_201403 Field QC HSC14.1_201403 PB006.2_201403 PB006.2_201403 Sample ID EF006.1-1SWMID-140313-N EB1-01_20140313 HSC14.1-1SWMID-140311-N PB006.2-1SWMID-140311-D PB006.2-1SWMID-140311-N Sample Date 03/13/2014 03/13/2014 03/11/2014 03/11/2014 03/11/2014 Sample Type N RB N FD N X 3201916.50194 -3201174.50723 3202147.78626 3202147.78626 Y 13831060.0595 -13837021.2519 13836299.7878 13836299.7878 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- 0.00203 U 0.00167 U 0.0011 U 0.00178 U 0.00119 U 0.00113 U 0.00118 U 0.0016 U 0.0012 U 0.00157 U 0.00394 U 0.00248 U 0.00253 U 0.00131 U 0.00167 U 0.00167 U 0.0116 U 0.0116 U 0.033035 J 0.01527 J 0.1314975 J 0.11027 J 0.00351 U 0.00351 U 0.00257 U 0.00257 U 0.00145 U 0.00145 U 0.00203 U 0.00203 U 0.00394 U 0.00394 U 0.00131 U 0.00131 U 0.2484295 J 0.12554 J 11 of 67 ------------------------------------- 0.00777 U 0.00546 U 0.00355 U 0.00937 J 0.00402 U 0.00372 U 0.00403 U 0.00533 U 0.00398 U 0.0065 U 0.00865 U 0.00562 U 0.00757 J 0.189 0.040875 J 0.03942 J 0.5341 J 0.51164 J 4.19654 J 4.18573 J 6.397955 J 6.37506 J 1.705605 J 1.66345 J 0.386345 J 0.34263 J 0.104865 J 0.06831 J 0.035345 J 0.00937 J 0.014705 J 0.00757 J 0.189 0.189 13.605335 J 13.39218 J 0.00505 U 0.00428 U 0.00278 U 0.00787 J 0.00315 U 0.00291 U 0.00316 U 0.00418 U 0.00312 U 0.00422 U 0.0072 U 0.00472 U 0.0071 J 0.196 0.035975 0.0332 0.60984 J 0.60336 J 4.68149 J 4.67098 J 6.589815 J 6.57618 J 1.676785 J 1.64744 J 0.418875 J 0.3901 J 0.114275 J 0.08827 J 0.031755 J 0.01533 J 0.01306 J 0.0071 J 0.196 0.196 14.36787 J 14.22796 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Conventional Parameters (mg/L) Total suspended solids Dissolved organic carbon Total organic carbon PCB Congeners (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 mg/L mg/L mg/L SM2540D SW9060 SW9060 20 J -7.12 16 J -6.79 18 J -5.69 34 12.9 9.34 19 J -9.44 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0343 0.00296 J 0.0102 J 0.191 0.00118 U 0.0369 0.00437 J 0.16 0.011 0.00835 J 0.0307 U 0.0104 J 0.000983 U 0.102 0.368 0.381 1.06 0.109 1.06 0.382 0.295 0.00166 U 0.00134 U 0.0707 0.172 0.0577 1.11 0.317 0.00575 J 0.019 0.0016 U 0.0251 0.00129 U 0.00672 J 0.169 0.00155 U 0.029 0.00384 J 0.13 0.00797 J 0.00709 J 0.0235 U 0.0106 J 0.00129 U 0.0946 0.324 0.316 0.918 0.103 0.879 0.296 0.245 0.00163 U 0.00119 U 0.0598 0.14 0.051 0.903 0.274 0.00447 J 0.0129 0.00157 U 0.0178 0.00383 J 0.00808 J 0.1 0.00162 U 0.0123 J 0.00149 U 0.0586 0.00431 J 0.00533 J 0.0188 U 0.00753 J 0.00135 U 0.0589 0.131 0.14 0.37 0.0573 0.397 0.109 0.103 0.00163 U 0.0015 U 0.0274 0.063 0.0245 0.39 0.123 0.00222 J 0.00735 J 0.00157 U 0.0337 0.00136 U 0.00773 J 0.218 0.00171 U 0.0543 0.00588 J 0.233 0.0145 0.00821 J 0.0309 U 0.0224 0.00142 U 0.16 0.623 0.625 1.79 0.155 2.13 0.702 0.594 0.00137 U 0.0114 0.133 0.327 0.0987 2.17 0.559 0.00885 J 0.039 0.00132 U 0.0618 0.00274 J 0.00823 J 0.531 0.00626 J 0.0887 0.00876 J 0.362 0.024 0.0216 0.035 U 0.0331 0.00107 U 0.279 1.43 1.31 3.93 0.391 2.74 0.778 0.732 0.00147 U 0.0264 0.165 0.425 0.226 2.78 1.19 0.00961 J 0.04 0.00142 U 12 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.205 0.00171 U 0.00155 U 0.849 0.132 0.486 0.0651 1.95 0.323 0.126 0.367 1.2 0.333 0.103 2.35 0.00602 J 0.0138 0.703 0.00611 J 0.00157 U 0.143 0.302 2.65 0.05 0.773 1.54 0.034 0.0288 0.014 0.00321 J 0.123 0.00172 U 0.014 0.00138 U 0.00171 U 0.167 0.162 0.00167 U 0.00151 U 0.658 0.113 0.367 0.0542 1.47 0.261 0.0983 0.295 0.887 0.266 0.0853 1.79 0.00571 J 0.00179 U 0.519 0.00499 J 0.00302 J 0.107 0.24 1.94 0.0389 0.589 1.12 0.0259 0.0322 0.0095 J 0.00215 J 0.0834 0.00185 U 0.00884 J 0.00149 U 0.00364 J 0.125 13 of 67 0.0715 0.00168 U 0.00411 J 0.33 0.0441 0.184 0.027 0.77 0.117 0.0519 0.139 0.456 0.141 0.0478 0.912 0.00389 J 0.0051 J 0.252 0.00226 J 0.00173 U 0.0516 0.106 0.953 0.0185 0.289 0.541 0.0119 0.0132 0.00488 J 0.00266 J 0.0437 0.0019 U 0.00402 J 0.00153 U 0.00188 U 0.064 0.447 0.00685 J 0.026 1.84 0.353 1.05 0.17 4.1 0.661 0.251 0.846 2.5 0.69 0.167 4.87 0.00982 J 0.00214 U 1.71 0.0137 0.00467 J 0.298 0.809 6.23 0.125 1.69 3.61 0.0812 0.0305 0.0226 0.000761 U 0.298 0.00222 U 0.0318 0.00178 U 0.0154 0.417 0.482 0.00627 J 0.027 2.06 0.41 1.17 0.182 4.59 0.907 0.364 0.936 2.61 0.874 0.198 5.34 0.0166 0.0349 1.61 0.0128 0.00746 J 0.329 0.687 5.5 0.107 1.78 3.32 0.0712 0.028 0.0186 0.0102 J 0.241 0.0014 U 0.0203 0.00114 U 0.0101 J 0.385 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0543 0.33 0.24 0.716 0.00172 U 0.0297 0.88 0.205 0.157 0.0173 J 0.01 J 0.77 0.0202 0.0017 U 0.524 0.0616 0.0115 0.000455 U 0.37 0.00134 U 0.0313 0.0595 1.09 0.00121 U 0.00125 U 0.0211 0.00129 U 0.00133 U 0.702 0.00119 U 0.00119 U 0.0154 0.0188 0.00508 J 0.00137 U 0.0782 0.0442 0.244 0.167 0.523 0.00159 U 0.0238 0.642 0.148 0.114 0.0121 J 0.00832 J 0.57 0.0157 0.00158 U 0.367 0.0469 0.00716 J 0.000591 U 0.268 0.00124 U 0.023 0.0433 0.792 0.00112 U 0.00116 U 0.0155 0.0012 U 0.0138 0.5 0.0011 U 0.0011 U 0.0114 0.0123 0.00104 U 0.0013 U 0.0527 14 of 67 0.0197 0.139 0.0982 0.28 0.00179 U 0.0124 0.352 0.0843 0.0667 0.00173 U 0.00562 J 0.324 0.00967 J 0.00177 U 0.2 0.0236 0.00447 J 0.000593 U 0.134 0.0014 U 0.0127 J 0.0228 0.419 0.00126 U 0.00131 U 0.00732 J 0.00135 U 0.00139 U 0.256 0.00124 U 0.00124 U 0.00491 J 0.00724 J 0.00103 U 0.0014 U 0.0306 0.146 0.731 0.566 1.7 0.00222 U 0.0733 1.95 0.467 0.357 0.0387 0.0241 1.6 0.0488 0.0022 U 1.16 0.138 0.0197 0.000408 U 0.977 0.00174 U 0.0812 0.135 2.43 0.00156 U 0.00163 U 0.056 0.00168 U 0.0685 1.66 0.00154 U 0.00154 U 0.0401 0.0488 0.0107 0.00173 U 0.159 0.112 0.761 0.456 1.46 0.00179 U 0.0781 1.61 0.397 0.31 0.0374 0.0225 1.56 0.0532 0.00738 J 1.04 0.11 0.0163 0.000385 U 0.714 0.00212 J 0.0606 0.108 1.94 0.00117 U 0.00528 J 0.041 0.0502 0.0516 1.27 0.00314 J 0.00116 U 0.0319 0.0342 0.00734 J 0.00128 U 0.103 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.492 0.0351 0.00786 J 0.159 0.00816 J 0.0313 0.141 0.0639 0.0225 0.01 J 0.0754 0.000833 U 0.000703 U 0.0207 0.000496 U 0.0722 0.368 0.0012 J 0.000459 U 0.000473 U 0.351 0.00848 J 0.000408 U 0.0511 0.047 0.00427 J 0.000607 U 0.00054 U 0.00215 J 0.0339 0.000582 U 0.0165 0.00102 U 0.0795 0.0286 0.0151 0.335 0.0244 0.00515 J 0.111 0.00521 J 0.0214 0.0968 0.0429 0.0125 0.00605 J 0.0544 0.000937 U 0.00079 U 0.0133 0.000531 U 0.0467 0.247 0.000769 U 0.000492 U 0.000507 U 0.234 0.00467 J 0.000437 U 0.0351 0.0311 0.00291 J 0.000682 U 0.000607 U 0.000968 U 0.0241 0.000654 U 0.0109 0.00108 U 0.054 0.02 J 0.01 J 15 of 67 0.191 0.0117 J 0.00321 J 0.0634 0.00338 J 0.01 J 0.0575 0.0254 0.00678 J 0.0041 J 0.0297 0.000963 U 0.000812 U 0.00803 J 0.000592 U 0.0288 0.146 0.00079 U 0.000549 U 0.000565 U 0.14 0.00318 J 0.000488 U 0.0189 J 0.0168 0.000926 U 0.000701 U 0.000624 U 0.00093 U 0.0129 0.000673 U 0.00635 J 0.00103 U 0.0301 0.012 J 0.00634 J 0.926 0.0687 0.0164 0.306 0.0125 0.0561 0.24 0.107 0.0442 J 0.0189 J 0.154 0.000757 U 0.000638 U 0.0399 0.000492 U 0.115 0.608 0.000621 U 0.000456 U 0.00047 U 0.593 0.0108 0.000405 U 0.108 0.0936 0.00672 J 0.000551 U 0.000491 U 0.00354 J 0.0607 0.000529 U 0.031 0.00111 U 0.133 0.0485 0.0255 0.589 0.0421 0.0118 0.217 0.00794 J 0.0414 0.161 0.0753 0.0336 0.0142 J 0.0934 0.000502 U 0.00356 J 0.0259 0.000514 J 0.0713 0.395 0.000868 J 0.000654 J 0.00102 J 0.357 0.00626 J 0.000254 U 0.0677 0.0589 0.00328 J 0.000357 U 0.000328 U 0.00214 J 0.0377 0.000355 U 0.0197 0.000615 U 0.069 0.0246 0.0122 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0806 0.0045 J 0.0115 0.0523 0.0209 0.0384 0.157 0.00117 U 0.00106 U 0.0463 0.000661 U 0.00957 J 0.000638 U 0.105 0.000543 U 0.00361 J 0.0139 0.00426 J 0.000986 U 0.0367 0.015 0.0197 0.00682 J 0.0441 0.00477 J 0.00849 J 0.0167 0.0236 0.000855 U 0.00303 J 0.0605 0.0491 0.0534 1.37 0.04746 J 0.04746 J 0.0539 0.00336 J 0.0065 J 0.0375 0.0129 0.0262 0.109 0.00102 U 0.000921 U 0.0321 0.000554 U 0.00526 J 0.000534 U 0.0731 0.000455 U 0.00205 J 0.0116 0.00174 J 0.000857 U 0.0245 0.0102 0.013 0.000697 U 0.0289 0.0007 U 0.0048 J 0.00914 J 0.0146 J 0.000732 U 0.00132 U 0.0249 0.0192 0.0205 0.58 0.032465 J 0.03182 J 16 of 67 0.031 0.00147 U 0.00453 J 0.0228 0.00813 J 0.0165 0.0677 0.00149 U 0.00134 U 0.0199 0.000713 U 0.00292 J 0.000688 U 0.0451 0.000585 U 0.00175 J 0.00633 J 0.00127 J 0.00125 U 0.014 J 0.00621 J 0.00784 J 0.000874 U 0.0198 J 0.000877 U 0.00284 J 0.00458 J 0.00863 J 0.000917 U 0.00135 U 0.0123 0.00792 J 0.00841 J 0.223 0.02971 J 0.02971 J 0.129 0.00636 J 0.0173 0.0829 0.0295 0.0586 0.263 0.00185 J 0.00112 U 0.0754 0.000597 U 0.0128 0.000576 U 0.161 0.00049 U 0.00503 J 0.0257 0.00636 J 0.00104 U 0.0549 0.0222 0.0302 0.00431 J 0.0689 0.00764 J 0.0096 J 0.0167 0.0356 0.000825 U 0.00301 J 0.0383 0.0211 0.0259 0.545 0.04211 J 0.04143 J 0.0716 0.00306 J 0.00888 J 0.0435 0.0151 0.0323 0.135 0.0011 J 0.000573 U 0.0382 0.000426 U 0.008 J 0.000409 U 0.0841 0.000345 U 0.00296 J 0.0129 0.00255 J 0.000541 U 0.0266 0.0108 0.0149 0.00169 J 0.0347 0.00414 J 0.00505 J 0.00868 J 0.0187 0.000475 U 0.00139 J 0.0175 0.00813 J 0.00981 J 0.249 0.07277 J 0.07277 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) PCB Congeners, Dissolved (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.5404515 J 0.52402 J 5.61608 J 5.61215 J 14.69123 J 14.68804 J 6.5138025 J 6.50678 J 2.1039805 J 2.10092 J 0.673569 J 0.67104 J 0.1793375 J 0.17891 J 0.163 0.163 1.37 1.37 31.898911 J 31.86232 J 0.46527 J 0.4521 J 4.691955 J 4.68817 J 11.080615 J 11.07805 J 4.7439905 J 4.73748 J 1.421517 J 1.41729 J 0.4613805 J 0.45921 J 0.1068645 J 0.10514 J 0.0646 0.0646 0.58 0.58 23.6486575 J 23.61386 J 0.2586 J 0.24697 J 2.02357 J 2.02038 J 5.52603 J 5.52251 J 2.5563815 J 2.54763 J 0.8225515 J 0.81773 J 0.280138 J 0.27637 J 0.065909 J 0.0639 J 0.02863 J 0.02863 J 0.223 0.223 11.81452 J 11.77683 J 0.733305 J 0.71629 J 10.447145 J 10.4458 J 32.4811405 J 32.47769 J 14.952024 14.9439 3.78232 J 3.77906 J 1.0837115 J 1.0818 J 0.2534725 J 0.25306 J 0.0853 0.0853 0.545 0.545 64.4055285 J 64.36933 J 1.372455 J 1.35442 J 16.689725 J 16.68828 J 33.44643 J 33.44516 J 12.7381525 J 12.73526 J 2.4424415 J 2.441236 J 0.566197 J 0.56505 J 0.1268875 J 0.12665 J 0.03544 J 0.03544 J 0.249 0.249 67.7394985 J 67.713266 J ---------------- ---------------- ---------------- 0.0264 0.00121 U 0.00496 J 0.17 0.00199 U 0.0337 0.00183 U 0.136 0.0021 U 0.00743 J 0.0243 U 0.0116 J 0.00166 U 0.08 0.34 ---------------- 17 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 18 of 67 ------------------------------------- 0.321 0.995 0.0967 0.818 0.277 0.239 0.00161 U 0.00573 J 0.0533 0.136 0.0555 0.894 0.275 0.00365 J 0.0123 0.00155 U 0.137 0.00165 U 0.00149 U 0.51 0.0932 0.285 0.047 1.17 0.227 0.0833 0.242 0.697 0.238 0.0584 1.49 0.00383 J 0.00163 U 0.35 0.00332 J 0.00153 U ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 19 of 67 ------------------------------------- 0.0843 0.168 1.33 0.0271 0.461 0.729 0.0185 0.0167 0.00459 J 0.000899 U 0.0466 0.00169 U 0.00142 U 0.00136 U 0.00167 U 0.0562 0.0202 J 0.125 0.0756 0.247 0.00149 U 0.013 0.295 0.0707 0.0551 0.00566 J 0.00158 U 0.292 0.00895 J 0.00148 U 0.164 0.0238 0.00133 U 0.000576 U 0.11 0.00117 U ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 20 of 67 ------------------------------------- 0.00947 J 0.0167 0.357 0.00105 U 0.00109 U 0.0067 J 0.00113 U 0.00651 J 0.199 0.00103 U 0.00104 U 0.00532 J 0.00535 J 0.000899 U 0.00123 U 0.0135 J 0.0874 0.00686 J 0.000881 U 0.0302 0.000801 U 0.00583 J 0.0265 0.0113 J 0.00429 J 0.000748 U 0.0146 0.000901 U 0.00076 U 0.00396 J 0.000538 U 0.0119 0.0634 0.00074 U 0.000499 U 0.000513 U ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 21 of 67 ------------------------------------- 0.0597 0.000662 U 0.000443 U 0.00976 J 0.00956 J 0.000672 U 0.000656 U 0.000584 U 0.000675 U 0.00638 J 0.00063 U 0.00306 J 0.000701 U 0.0114 0.00492 J 0.00119 U 0.0104 J 0.00108 U 0.00166 J 0.0076 J 0.0029 J 0.00581 J 0.0223 0.00109 U 0.000985 U 0.0065 J 0.000673 U 0.00112 U 0.00065 U 0.013 J 0.000553 U 0.000874 U 0.00206 J 0.000872 U 0.000917 U 0.00371 J ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB020_201403 PB031.1_201403 PB047.3_201403 PB056_C_201403 PB070_B_201403 Sample ID PB020-1SWMID-140313-N PB031.1-1SWMID-140313-N PB047.3-1SWMID-140313-N PB056_C-1SWMID-140313-N PB070_B-1SWMID-140314-N Sample Date 03/13/2014 03/13/2014 03/13/2014 03/13/2014 03/14/2014 Sample Type N N N N N X 3201304.60061 3201398.81385 3201688.0477 3201506.28651 3201105.66718 Y 13835636.4127 13834597.3501 13832857.2637 13832189.4532 13830874.0613 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 22 of 67 ------------------------------------- 0.00152 U 0.00278 J 0.000859 U 0.0061 J 0.000862 U 0.000838 U 0.00174 J 0.00289 J 0.000901 U 0.00108 U 0.006 J 0.00301 J 0.00293 J 0.065 0.031965 J 0.03136 J 0.45467 J 0.43873 J 4.66233 J 4.65918 J 8.3889395 J 8.38384 J 2.1758075 J 2.16826 J 0.373902 J 0.3682 J 0.093552 J 0.08855 J 0.02025 J 0.01722 J 0.01194 J 0.01194 J 0.065 0.065 16.278356 J 16.23228 J ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Conventional Parameters (mg/L) Total suspended solids Dissolved organic carbon Total organic carbon PCB Congeners (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 mg/L mg/L mg/L SM2540D SW9060 SW9060 18 J -9.99 18 J -13.7 8J 26.3 16.2 11 J -13.8 25 U -10.2 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0701 0.00182 U 0.00895 J 0.521 0.00767 J 0.0982 0.0109 0.399 0.0293 0.0221 0.0363 U 0.0328 0.00246 U 0.268 1.18 1.1 3.41 0.356 3.01 0.893 0.832 0.00294 U 0.0226 0.183 0.471 0.191 3.11 1.02 0.00981 J 0.0405 0.00284 U 0.0498 0.00336 J 0.0081 J 0.3 0.00305 J 0.0691 0.00581 J 0.177 0.012 0.0116 0.0281 U 0.0231 0.00105 U 0.116 0.585 0.564 1.66 0.192 1.18 0.32 0.318 0.00114 U 0.0091 J 0.105 0.198 0.102 1.16 0.543 0.00508 J 0.0168 0.0011 U 0.0387 0.00314 J 0.00517 J 0.245 0.00244 J 0.0637 0.00372 J 0.107 0.0084 J 0.0095 J 0.029 U 0.0218 0.00117 U 0.086 0.47 0.482 1.34 0.187 0.839 0.181 0.202 0.000973 U 0.00741 J 0.0949 0.15 0.0915 0.782 0.508 0.00373 J 0.0125 0.000942 U 0.0262 0.00172 J 0.00318 U 0.155 0.00216 J 0.0551 0.00319 J 0.101 0.00772 J 0.0054 J 0.0204 U 0.0158 J 0.000319 U 0.0538 0.233 0.236 0.686 0.104 0.63 0.152 0.165 0.00104 U 0.00439 J 0.0879 0.122 0.0424 0.625 0.227 0.00332 J 0.00823 J 0.000997 U 0.0214 0.00149 J 0.00496 U 0.145 0.00183 J 0.0458 0.00316 J 0.101 0.00687 J 0.00461 J 0.0212 U 0.0138 J 0.000356 U 0.0524 0.181 0.184 0.522 0.0797 0.482 0.137 0.135 0.000664 U 0.0028 J 0.0636 0.0915 0.0315 0.483 0.17 0.00248 J 0.00721 J 0.000637 U 23 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.534 0.00703 J 0.0291 2.15 0.444 1.23 0.188 4.87 0.979 0.373 1 2.85 0.945 0.198 5.85 0.0154 0.0341 1.76 0.0147 0.00723 J 0.362 0.79 6.05 0.12 1.94 3.67 0.0795 0.0277 0.0208 0.0102 J 0.268 0.00352 U 0.0268 0.00286 U 0.0132 0.426 0.203 0.00295 J 0.0099 J 0.874 0.144 0.49 0.072 1.93 0.37 0.143 0.367 1.11 0.351 0.0823 2.26 0.0081 J 0.0126 0.697 0.00556 J 0.00314 J 0.14 0.299 2.35 0.0474 0.752 1.42 0.0292 0.0256 0.00843 J 0.00414 J 0.101 0.00104 U 0.000834 U 0.000841 U 0.00433 J 0.17 24 of 67 0.13 0.00102 U 0.00813 J 0.742 0.115 0.409 0.0604 1.6 0.315 0.123 0.301 0.933 0.306 0.082 1.88 0.00725 J 0.00828 J 0.539 0.00415 J 0.00173 J 0.113 0.205 1.8 0.0357 0.594 1.12 0.0234 0.0318 0.00631 J 0.00348 J 0.0801 0.00116 U 0.0054 J 0.000944 U 0.00281 J 0.142 0.0872 0.00108 U 0.00514 J 0.438 0.0576 0.245 0.0381 0.982 0.197 0.0788 0.172 0.581 0.214 0.0645 1.18 0.00365 J 0.00649 J 0.298 0.00287 J 0.000649 U 0.0719 0.13 1.02 0.0228 0.368 0.629 0.0139 0.0307 0.00439 J 0.00228 J 0.0462 0.000721 U 0.00453 J 0.0006 U 0.00196 J 0.0717 0.0776 0.000797 J 0.00453 J 0.33 0.0516 0.184 0.0282 0.737 0.144 0.0625 0.131 0.425 0.159 0.062 0.875 0.0032 J 0.00547 J 0.237 0.00238 J 0.00112 J 0.0523 0.105 0.774 0.0172 0.277 0.482 0.0113 0.0271 0.00323 J 0.00171 J 0.0377 0.000762 U 0.00307 J 0.000635 U 0.00168 J 0.0542 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.129 0.781 0.492 1.6 0.0158 0.0833 1.75 0.41 0.331 0.0393 0.0256 1.67 0.0533 0.00461 J 1.14 0.114 0.0166 0.000986 U 0.804 0.00341 J 0.0719 0.118 2.16 0.00269 U 0.00857 J 0.0485 0.0753 0.066 1.41 0.00265 U 0.00266 U 0.0354 0.0431 0.00833 J 0.00281 U 0.12 0.053 0.311 0.203 0.63 0.00108 U 0.0313 0.695 0.169 0.134 0.0132 J 0.00994 J 0.655 0.0238 0.00209 J 0.447 0.0473 0.00678 J 0.000379 U 0.32 0.00141 J 0.0264 0.0462 0.86 0.000713 U 0.00201 J 0.0181 0.0301 0.0262 0.571 0.000702 U 0.000704 U 0.0142 0.0167 0.0031 J 0.000744 U 0.0489 25 of 67 0.0414 0.267 0.163 0.506 0.00105 U 0.0274 0.559 0.143 0.11 0.0111 J 0.00882 J 0.533 0.02 0.00114 U 0.361 0.0415 0.00535 J 0.000405 U 0.25 0.00103 J 0.0216 0.0364 0.702 0.000689 U 0.00163 J 0.0134 0.0165 0.0203 0.445 0.000678 U 0.000681 U 0.011 0.0137 0.00212 J 0.000774 U 0.0357 0.0212 0.14 0.104 0.283 0.00451 J 0.0141 0.322 0.0718 0.062 0.00739 J 0.0045 J 0.294 0.01 0.00058 U 0.21 0.022 0.00322 J 0.000163 U 0.143 0.00111 J 0.0118 J 0.0218 0.396 0.000354 U 0.000366 U 0.00876 0.0106 0.00884 0.258 0.000517 J 0.000357 U 0.00612 J 0.00708 J 0.00149 J 0.000393 U 0.0227 0.0188 0.11 0.0739 0.218 0.000733 U 0.0105 0.241 0.0559 0.0468 0.00505 J 0.00365 J 0.227 0.00749 J 0.00145 J 0.149 0.0156 0.00285 J 0.000208 U 0.108 0.000823 J 0.009 J 0.0161 0.305 0.000472 U 0.000984 J 0.00649 J 0.00947 0.00819 J 0.191 0.000555 J 0.000476 U 0.00431 J 0.00563 J 0.00108 J 0.000489 U 0.0171 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.682 0.0481 0.0117 0.243 0.00904 J 0.0434 0.177 0.0841 0.0393 0.0157 J 0.111 0.00177 U 0.00491 J 0.028 0.001 U 0.0805 0.44 0.00146 U 0.00094 U 0.000953 U 0.416 0.00778 J 0.000836 U 0.0813 0.0662 0.00439 J 0.00126 U 0.00115 U 0.00251 J 0.042 0.00125 U 0.0225 0.0018 U 0.085 0.0281 0.0146 0.29 0.0211 0.00463 J 0.101 0.00374 J 0.0193 0.0742 0.0367 0.0145 0.0064 J 0.0457 0.000513 U 0.00147 J 0.0128 0.000327 U 0.0347 0.188 0.000422 U 0.000557 J 0.000801 J 0.179 0.00293 J 0.000433 J 0.0309 0.0289 0.0021 J 0.000364 U 0.000335 U 0.0013 J 0.02 0.000363 U 0.00903 J 0.000533 U 0.0342 0.0109 J 0.00601 J 26 of 67 0.219 0.016 0.00418 J 0.0801 0.00254 J 0.0162 0.0581 0.0288 0.013 0.00534 J 0.0356 0.000578 U 0.00113 J 0.00907 J 0.000333 U 0.0272 0.144 0.000476 U 0.000423 J 0.000546 J 0.133 0.00218 J 0.00044 J 0.0237 0.0225 0.000963 J 0.000411 U 0.000378 U 0.000722 J 0.0139 0.000409 U 0.00715 J 0.000545 U 0.0245 0.00858 J 0.00487 J 0.138 0.0102 0.00246 J 0.046 0.00166 J 0.00784 J 0.0355 0.0174 0.00757 J 0.00284 J 0.0223 0.000262 U 0.000667 J 0.00574 J 0.00015 U 0.0178 0.0909 0.000217 U 0.000236 J 0.000364 J 0.0875 0.00119 J 0.000294 J 0.0158 J 0.0141 0.000933 J 0.000179 U 0.000169 U 0.000525 J 0.00881 0.000184 U 0.00497 J 0.00028 U 0.0195 0.0064 J 0.00343 J 0.104 0.00757 J 0.0021 J 0.0365 0.00132 J 0.00551 J 0.0284 0.0131 0.00575 J 0.00224 J 0.017 0.000289 U 0.000367 J 0.00467 J 0.000184 U 0.0139 0.0702 0.000239 U 0.000275 J 0.000228 J 0.0686 0.00103 J 0.000273 J 0.0115 J 0.0104 0.000677 J 0.000197 U 0.000186 U 0.000473 J 0.00663 J 0.000203 U 0.0035 J 0.000259 U 0.0145 0.00432 J 0.00248 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0848 0.00398 J 0.0102 J 0.0501 0.0169 0.0368 0.16 0.00172 U 0.00154 U 0.0447 0.00109 U 0.00833 J 0.00105 U 0.099 0.00088 U 0.00381 J 0.0158 0.00363 J 0.00145 U 0.033 0.014 0.017 0.00205 J 0.0446 0.00415 J 0.00592 J 0.0112 0.0235 0.00159 U 0.00237 U 0.024 0.0131 0.0126 J 0.332 0.07996 J 0.07905 J 0.0365 0.00194 J 0.0049 J 0.0211 0.00784 J 0.0163 0.0683 0.000629 U 0.000565 U 0.0199 0.000403 U 0.00312 J 0.000387 U 0.0415 0.000325 U 0.00156 J 0.00669 J 0.00144 J 0.000533 U 0.0132 0.00536 J 0.00837 J 0.000781 J 0.0186 J 0.0022 J 0.00227 J 0.00471 J 0.0106 0.000452 U 0.000564 U 0.00942 J 0.00431 J 0.00479 J 0.121 0.06126 J 0.06126 J 27 of 67 0.025 0.00123 J 0.00329 J 0.0144 0.00586 J 0.0114 0.0474 0.000632 U 0.000568 U 0.0131 0.000455 U 0.00252 J 0.000436 U 0.0303 0.000367 U 0.00122 J 0.00448 J 0.00118 J 0.000536 U 0.00906 J 0.00357 J 0.00597 J 0.000495 J 0.0134 J 0.00171 J 0.00189 J 0.00314 J 0.00704 J 0.000488 U 0.000589 U 0.0063 J 0.00151 J 0.00244 J 0.054 0.04701 J 0.04701 J 0.0189 0.00072 J 0.00241 J 0.0117 0.00363 J 0.00789 J 0.0385 0.000459 J 0.000361 U 0.00977 0.000395 J 0.00207 J 0.000225 U 0.021 0.00019 U 0.000937 J 0.00364 J 0.000781 J 0.00033 U 0.00927 0.00389 J 0.00449 J 0.000458 J 0.0109 J 0.00108 J 0.00153 J 0.00197 J 0.00532 J 0.000252 U 0.000363 U 0.00528 J 0.00264 J 0.00306 J 0.0522 0.02951 J 0.02792 J 0.014 0.000662 J 0.00191 J 0.00843 J 0.00327 J 0.0067 J 0.0286 0.000318 U 0.000289 U 0.00714 J 0.000498 J 0.00159 J 0.000186 U 0.0175 0.000157 U 0.00073 J 0.00273 J 0.000726 J 0.000264 U 0.00609 J 0.00223 J 0.00265 J 0.000501 J 0.00782 J 0.00108 J 0.00109 J 0.00183 J 0.00423 J 0.000262 U 0.000346 U 0.0047 J 0.00222 J 0.00233 J 0.0452 0.02537 J 0.02289 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) PCB Congeners, Dissolved (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 1.40835 J 1.38897 J 16.40193 J 16.39904 J 36.28982 J 36.28663 J 13.939918 J 13.93402 J 2.7866395 J 2.78043 J 0.669615 J 0.66575 J 0.1574 J 0.15542 J 0.0497 J 0.0497 J 0.332 0.332 72.1153325 J 72.07101 J 0.732235 J 0.71766 J 7.17495 J 7.17383 J 14.1021575 J 14.1008 J 5.538991 J 5.53683 J 1.1805195 J 1.179091 J 0.283621 J 0.2822 J 0.066599 J 0.066091 J 0.01852 J 0.01852 J 0.121 0.121 29.279853 J 29.257282 J 0.562645 J 0.54756 J 5.4906375 J 5.48917 J 11.448862 J 11.44781 J 4.4769585 J 4.47425 J 0.903049 J 0.901484 J 0.200827 J 0.19933 J 0.0468135 J 0.046275 J 0.01025 J 0.01025 J 0.054 0.054 23.2410525 J 23.217139 J 0.4095295 J 0.39917 J 3.4201385 J 3.41858 J 6.905655 J 6.90467 J 2.5216435 J 2.520537 J 0.5650195 J 0.564299 J 0.152685 J 0.152132 J 0.0392155 J 0.038908 J 0.01098 J 0.01098 J 0.0522 0.0522 14.1065765 J 14.089396 J 0.385248 J 0.37447 J 2.6563675 J 2.655717 J 5.2324585 J 5.23176 J 1.909011 J 1.907822 J 0.4340915 J 0.433313 J 0.116393 J 0.115786 J 0.027825 J 0.027521 J 0.00925 J 0.00925 J 0.0452 0.0452 10.8412145 J 10.823729 J ---------------- ---------------- 0.0388 0.00202 U 0.00552 J 0.213 0.00276 U 0.0623 0.00397 J 0.093 0.0083 J 0.00888 J 0.0345 U 0.0184 J 0.00232 U 0.0529 0.249 ---------------- ---------------- 28 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 29 of 67 0.24 0.689 0.116 0.364 0.0893 0.0998 0.00176 U 0.00504 J 0.0616 0.0748 0.0468 0.356 0.24 0.00176 U 0.0036 J 0.0017 U 0.0472 0.00185 U 0.00165 U 0.212 0.0322 0.114 0.0187 0.487 0.109 0.0457 0.0849 0.276 0.115 0.0479 0.599 0.00322 J 0.00219 J 0.12 0.00124 U 0.00121 U ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 30 of 67 0.0348 0.0501 0.408 0.00838 J 0.167 0.245 0.00569 J 0.0316 0.00118 U 0.00124 J 0.0159 0.00137 U 0.0011 U 0.00111 U 0.00136 U 0.0227 0.00818 J 0.0534 0.0268 0.0903 0.00176 U 0.00516 J 0.106 0.0266 0.0216 0.0016 U 0.00176 U 0.118 0.00421 J 0.00192 U 0.0646 0.00794 J 0.00148 U 0.000743 U 0.0401 0.0013 U ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 31 of 67 0.00385 J 0.0046 J 0.127 0.00116 U 0.00119 U 0.00222 J 0.00388 J 0.00337 J 0.0733 0.00114 U 0.00115 U 0.00135 U 0.00205 J 0.0012 U 0.00125 U 0.00565 J 0.0339 0.00296 J 0.000961 U 0.0123 0.000865 U 0.00238 J 0.0106 J 0.00552 J 0.0022 J 0.000813 U 0.00633 J 0.000975 U 0.000818 U 0.00189 J 0.000587 U 0.00528 J 0.0214 J 0.000804 U 0.000549 U 0.000557 U ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 32 of 67 0.0238 0.000724 U 0.000489 U 0.00311 J 0.0038 J 0.000759 U 0.000693 U 0.000637 U 0.000765 U 0.00216 J 0.00069 U 0.00111 J 0.000884 U 0.00385 J 0.00153 U 0.00149 U 0.00459 J 0.00134 U 0.000855 U 0.00236 J 0.00128 U 0.00203 J 0.00797 J 0.00135 U 0.00122 U 0.00254 J 0.00095 U 0.0014 U 0.000912 U 0.0048 J 0.000768 U 0.00097 U 0.00117 U 0.00107 U 0.00115 U 0.00147 U ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB070_B_201403 PB079_201403 PB081_A_201403 PB081_A_201403 PB083_201403 Sample ID PB070_B-2SWMID-140314-N PB079-1SWMID-140314-N PB081_A-1SWMID-140314-N PB081_A-2SWMID-140315-N PB083-1SWMID-140318-D Sample Date 03/14/2014 03/14/2014 03/14/2014 03/15/2014 03/18/2014 Sample Type N N N N FD X 3201105.66718 3200739.58911 3200753.74845 3200753.74845 3200739.89221 Y 13830874.0613 13830192.2364 13829960.4001 13829960.4001 13829765.6659 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 33 of 67 0.00158 U 0.00122 U 0.000826 U 0.0029 J 0.00087 U 0.000823 U 0.000887 U 0.00121 U 0.000885 U 0.00118 U 0.00429 U 0.00214 U 0.00216 U 0.0119 0.04533 J 0.04432 J 0.48054 J 0.46075 J 2.6865 J 2.68214 J 3.238805 J 3.23452 J 0.8253615 J 0.81586 J 0.150675 J 0.14439 J 0.0368675 J 0.02814 J 0.0083755 J 0.0029 J 0.00429 U 0.00429 U 0.0119 0.0119 7.4886495 J 7.42492 J ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Conventional Parameters (mg/L) Total suspended solids Dissolved organic carbon Total organic carbon PCB Congeners (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 mg/L mg/L mg/L SM2540D SW9060 SW9060 5J -10.3 8J -15.4 5J -11.1 12 J -14.9 12 J -11.6 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.023 0.0021 J 0.0057 U 0.151 0.00202 J 0.047 0.00357 J 0.101 0.00702 J 0.00444 J 0.0227 U 0.0152 J 0.000421 U 0.0515 0.172 0.18 0.51 0.0797 0.461 0.13 0.131 0.000923 U 0.00343 J 0.0629 0.0903 0.0311 0.463 0.17 0.00242 J 0.00739 J 0.000885 U 0.0233 J 0.00148 U 0.00534 J 0.145 0.00326 U 0.057 0.00307 U 0.0571 0.00508 J 0.00488 J 0.0307 U 0.0189 J 0.00275 U 0.0345 0.138 0.176 0.418 0.0912 0.283 0.0529 0.0736 0.00176 U 0.00355 J 0.0718 0.0683 0.034 0.253 0.186 0.00213 J 0.00397 J 0.00171 U 0.0189 0.00203 J 0.00604 U 0.149 0.000852 U 0.0473 0.000801 U 0.0656 0.00433 J 0.00354 J 0.0263 U 0.017 J 0.000716 U 0.0359 0.126 0.15 0.368 0.0812 0.267 0.0608 0.0758 0.00107 U 0.00256 J 0.0652 0.064 0.0264 0.242 0.157 0.00209 J 0.00447 J 0.00103 U 0.0176 0.00144 U 0.00425 J 0.125 0.00239 U 0.0603 0.00263 J 0.0468 0.00453 J 0.0048 J 0.0374 U 0.022 0.00202 U 0.0356 0.118 0.18 0.389 0.0824 0.366 0.0567 0.0885 0.00171 U 0.00293 J 0.11 0.0979 0.0321 0.315 0.195 0.00337 J 0.00689 J 0.00165 U 0.0152 0.00269 J 0.00596 U 0.147 0.00082 U 0.0706 0.00259 J 0.0683 0.00377 J 0.00357 J 0.0306 U 0.0251 0.000689 U 0.0384 0.119 0.181 0.383 0.0911 0.349 0.0644 0.0926 0.00102 U 0.00213 J 0.106 0.0892 0.0308 0.302 0.192 0.00318 J 0.00708 J 0.000975 U 34 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0735 0.000957 U 0.00381 J 0.312 0.0523 0.178 0.0283 0.702 0.129 0.0573 0.125 0.408 0.154 0.0709 0.829 0.00283 J 0.00443 J 0.225 0.00247 J 0.000923 J 0.0493 0.0968 0.726 0.0163 0.264 0.453 0.0106 0.0256 0.00315 J 0.00159 J 0.0354 0.000805 U 0.0085 0.00067 U 0.00182 J 0.0524 0.0365 0.00185 U 0.00166 U 0.179 0.022 0.105 0.014 0.418 0.0651 0.035 0.0587 0.253 0.087 0.0545 0.473 0.00232 J 0.00297 J 0.122 0.00124 J 0.00112 U 0.0297 J 0.051 0.394 0.0103 J 0.151 0.253 0.00526 J 0.0267 0.00186 J 0.00135 J 0.0191 0.00127 U 0.00146 J 0.00103 U 0.00126 U 0.0312 35 of 67 0.0388 0.00112 U 0.00219 J 0.177 0.018 0.1 0.0144 0.389 0.0672 0.033 0.0557 0.228 0.0886 0.0564 0.451 0.00288 J 0.00283 J 0.119 0.0014 J 0.000898 U 0.0274 J 0.0494 0.35 0.00959 J 0.137 0.231 0.00556 J 0.0239 0.00181 J 0.00113 J 0.0208 0.000998 U 0.00185 J 0.000831 U 0.00102 U 0.0285 0.0476 0.0018 U 0.00269 J 0.251 0.0273 0.147 0.0206 0.574 0.0771 0.0421 0.0745 0.372 0.113 0.0592 0.666 0.00306 J 0.00532 J 0.182 0.00322 J 0.00128 J 0.04 0.0771 0.6 0.0182 0.21 0.403 0.0104 0.0295 0.00452 J 0.00162 J 0.0337 0.0013 U 0.00273 J 0.00105 U 0.00179 J 0.0509 0.0484 0.00105 U 0.00299 J 0.24 0.0186 0.138 0.0195 0.511 0.0771 0.0419 0.069 0.326 0.113 0.0631 0.574 0.00341 J 0.00412 J 0.169 0.0022 J 0.00124 J 0.0356 0.0634 0.49 0.0157 0.187 0.337 0.00875 J 0.0227 0.0035 J 0.00135 J 0.0322 0.000784 U 0.00342 J 0.000653 U 0.00134 J 0.0395 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0151 0.103 0.0685 0.207 0.000759 U 0.0106 0.23 0.0527 0.0451 0.00516 J 0.00332 J 0.217 0.00727 J 0.000974 J 0.146 0.0152 0.00267 J 0.000282 U 0.0993 0.00118 J 0.00858 J 0.0157 0.292 0.000489 U 0.00107 J 0.00619 J 0.00761 J 0.00896 0.182 0.000681 J 0.000493 U 0.00458 J 0.00504 J 0.00123 J 0.000507 U 0.0165 J 0.0116 0.0643 0.0414 0.122 0.00109 U 0.00557 J 0.149 0.0341 0.0313 0.00286 J 0.00182 J 0.135 0.00431 J 0.00119 U 0.0941 0.00942 J 0.00143 J 0.000564 U 0.0601 0.000804 U 0.00589 J 0.0102 J 0.186 0.000719 U 0.00074 U 0.00367 J 0.00241 J 0.00364 J 0.116 0.000708 U 0.000711 U 0.00298 J 0.00338 J 0.00114 U 0.000767 U 0.0118 J 36 of 67 0.0119 0.0596 0.0444 0.117 0.00103 U 0.00543 J 0.136 0.0298 0.0274 0.00289 J 0.0017 J 0.128 0.00422 J 0.00109 U 0.0788 0.00836 J 0.00141 J 0.000344 U 0.0556 0.00115 J 0.00479 J 0.00923 J 0.179 0.000664 U 0.000986 J 0.00348 J 0.000693 U 0.000681 U 0.105 0.000655 U 0.00067 U 0.00267 J 0.00282 J 0.000752 U 0.000693 U 0.0118 J 0.0208 0.106 0.0642 0.209 0.00142 U 0.00909 J 0.257 0.0604 0.0528 0.00539 J 0.00328 J 0.22 0.00599 J 0.00155 U 0.163 0.0159 0.0032 J 0.000495 U 0.107 0.00105 U 0.00976 J 0.0175 0.316 0.000935 U 0.000962 U 0.00596 J 0.00563 J 0.0103 J 0.206 0.000921 U 0.000924 U 0.00394 J 0.00543 J 0.00142 U 0.00095 U 0.0211 0.0164 0.0829 0.0532 0.158 0.000834 U 0.0083 J 0.177 0.0441 0.0372 0.00464 J 0.00315 J 0.157 0.0059 J 0.000905 J 0.116 0.012 0.00209 J 0.000302 U 0.0769 0.00149 J 0.00634 J 0.0139 0.235 0.000537 U 0.00068 J 0.00442 J 0.00352 J 0.00702 J 0.148 0.000529 U 0.000541 U 0.00331 J 0.00335 J 0.000864 U 0.000583 U 0.0127 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.105 0.00757 J 0.00184 J 0.0372 0.00143 J 0.00639 J 0.0282 0.014 0.00551 J 0.00237 J 0.0169 0.000431 U 0.000717 J 0.0042 J 0.000273 U 0.0138 0.071 0.000356 U 0.000259 U 0.000263 U 0.0692 0.0011 J 0.000329 J 0.0114 J 0.0101 0.000749 J 0.000294 U 0.000277 U 0.000411 U 0.00706 J 0.000302 U 0.0034 J 0.000434 U 0.0147 0.00468 J 0.00263 J 0.0776 0.00515 J 0.00133 J 0.0264 0.000702 U 0.00573 J 0.021 0.01 J 0.0035 J 0.0019 J 0.0119 0.000792 U 0.000664 U 0.0031 J 0.000506 U 0.0099 J 0.0513 0.000652 U 0.000474 U 0.00048 U 0.0504 0.000588 U 0.000421 U 0.00742 J 0.00784 J 0.000593 U 0.000563 U 0.000517 U 0.000598 U 0.00448 J 0.00056 U 0.00249 J 0.000643 U 0.012 0.00385 J 0.0019 J 37 of 67 0.0712 0.00505 J 0.00133 J 0.0263 0.00131 J 0.00394 J 0.019 J 0.00951 J 0.00372 J 0.00166 J 0.0116 0.000511 U 0.000475 U 0.00287 J 0.000342 U 0.00956 J 0.0485 0.000423 U 0.000324 U 0.000329 U 0.045 0.000709 J 0.000321 J 0.00798 J 0.00725 J 0.000502 J 0.000349 U 0.000329 U 0.000328 U 0.00504 J 0.000359 U 0.00242 J 0.000342 U 0.00847 J 0.00305 J 0.00143 J 0.136 0.00889 J 0.00203 J 0.0447 0.00151 J 0.00902 J 0.0358 0.0173 0.00664 J 0.00283 J 0.0193 0.000651 U 0.000546 U 0.00512 J 0.000426 U 0.018 0.0882 0.000536 U 0.000399 U 0.000405 U 0.0865 0.00148 J 0.000733 J 0.0143 J 0.0128 0.000633 U 0.000463 U 0.000425 U 0.000638 U 0.0092 J 0.000461 U 0.00375 J 0.00068 U 0.0172 0.0061 J 0.00266 J 0.0828 0.00586 J 0.00149 J 0.0276 0.00128 J 0.00519 J 0.022 0.0102 J 0.00405 J 0.002 J 0.0128 0.00039 U 0.000362 U 0.00322 J 0.000245 U 0.0113 0.0537 0.000322 U 0.000232 U 0.000235 U 0.054 0.000288 U 0.000698 J 0.00899 J 0.00802 J 0.000674 J 0.000266 U 0.000251 U 0.0004 U 0.00575 J 0.000273 U 0.00278 J 0.000446 U 0.0104 0.00316 J 0.00204 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0159 0.000667 J 0.00195 J 0.00761 J 0.00324 J 0.00712 J 0.0315 0.000578 U 0.000526 U 0.00779 J 0.00031 U 0.00148 J 0.000305 U 0.0183 0.000258 U 0.000645 J 0.00278 J 0.000677 J 0.000481 U 0.00646 J 0.0025 J 0.00355 J 0.000581 J 0.0092 J 0.000853 J 0.00116 J 0.00206 J 0.00461 J 0.000349 U 0.00049 U 0.00421 J 0.00147 J 0.00219 J 0.0426 0.028 J 0.0251 J 0.0108 0.000906 U 0.00164 J 0.00568 J 0.00248 J 0.00521 J 0.0219 0.000915 U 0.000822 U 0.00597 J 0.000638 U 0.000948 U 0.000613 U 0.0134 0.000516 U 0.000723 U 0.00209 J 0.000725 U 0.000776 U 0.00406 J 0.00174 J 0.00249 J 0.000715 U 0.00653 J 0.000753 U 0.000712 U 0.00168 J 0.00315 J 0.000766 U 0.000828 U 0.00243 U 0.00152 U 0.00153 U 0.012 0.02938 J 0.02864 J 38 of 67 0.00803 J 0.000468 U 0.00104 J 0.00505 J 0.00166 J 0.0043 J 0.0187 J 0.000469 U 0.000426 U 0.00433 J 0.000533 J 0.00141 J 0.000364 U 0.0115 0.000307 U 0.000628 J 0.00144 J 0.000503 J 0.00039 U 0.00387 J 0.00108 J 0.00198 J 0.000408 U 0.00485 J 0.000649 J 0.000836 J 0.00128 J 0.00274 J 0.000418 U 0.000563 U 0.00203 U 0.00122 U 0.00127 U 0.0115 0.02395 J 0.02093 J 0.0195 0.000867 U 0.00228 J 0.0107 0.00391 J 0.00893 J 0.0363 0.000876 U 0.000787 U 0.0106 0.00225 J 0.00193 J 0.000553 U 0.0235 0.000466 U 0.000723 U 0.00308 J 0.000694 U 0.000742 U 0.00668 J 0.00218 J 0.00334 J 0.000648 U 0.00996 J 0.00107 J 0.00147 J 0.00289 J 0.00514 J 0.000694 U 0.00093 U 0.00255 U 0.00149 U 0.00151 U 0.0115 0.02257 J 0.02185 J 0.0112 0.000576 J 0.00131 J 0.00616 J 0.0024 J 0.00536 J 0.0218 0.000535 U 0.000487 U 0.0069 J 0.00114 J 0.000912 J 0.000309 U 0.0145 0.00026 U 0.000617 J 0.00199 J 0.000415 U 0.000445 U 0.00428 J 0.00182 J 0.00262 J 0.000405 J 0.00725 J 0.000601 J 0.000796 J 0.00164 J 0.00283 J 0.000407 U 0.000425 U 0.00305 J 0.000872 U 0.00104 J 0.00581 J 0.02087 J 0.01789 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) PCB Congeners, Dissolved (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.3943105 J 0.38275 J 2.5729325 J 2.57155 J 4.9742505 J 4.973513 J 1.81738 J 1.816115 J 0.437615 J 0.435965 J 0.122898 J 0.121669 J 0.0313935 J 0.030974 J 0.00787 J 0.00787 J 0.0426 0.0426 10.4292 J 10.408106 J 0.34235 J 0.32246 J 1.89544 J 1.89195 J 2.8399 J 2.83756 J 1.1378965 J 1.13368 J 0.3176165 J 0.31324 J 0.090711 J 0.08692 J 0.021537 J 0.01965 J 0.00243 U 0.00243 U 0.012 0.012 6.689571 J 6.6461 J 0.3370045 J 0.32267 J 1.73512 J 1.73351 J 2.6657235 J 2.66385 J 1.053772 J 1.050136 J 0.2986275 J 0.296572 J 0.073286 J 0.072074 J 0.0179795 J 0.017285 J 0.00203 U 0.00203 U 0.0115 0.0115 6.219223 J 6.188527 J 0.322565 J 0.30166 J 2.09666 J 2.09408 J 4.052415 J 4.05124 J 1.9397835 J 1.93447 J 0.5483345 J 0.545203 J 0.151794 J 0.14894 J 0.033866 J 0.03273 J 0.00255 U 0.00255 U 0.0115 0.0115 9.182263 J 9.141673 J 0.3753845 J 0.35933 J 2.0654025 J 2.06388 J 3.5738485 J 3.57313 J 1.42431 J 1.422215 J 0.338957 J 0.337102 J 0.0916905 J 0.090465 J 0.022658 J 0.022242 J 0.004526 J 0.00409 J 0.00581 J 0.00581 J 7.923457 J 7.896154 J ---------------- ---------------- ---------------- ---------------- ---------------- 39 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 40 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 41 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 42 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 43 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB083_201403 PB085_201403 PB087_201403 PB089_201403 PB091_201403 Sample ID PB083-1SWMID-140318-N PB085-1SWMID-140314-N PB087-1SWMID-140318-N PB089-1SWMID-140314-N PB091-1SWMID-140318-N Sample Date 03/18/2014 03/14/2014 03/18/2014 03/14/2014 03/18/2014 Sample Type N N N N N X 3200739.89221 3200716.68822 3200888.51485 3200952.5211 3200940.11827 Y 13829765.6659 13829591.4279 13829475.1089 13829302.1963 13829124.5159 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 44 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Conventional Parameters (mg/L) Total suspended solids Dissolved organic carbon Total organic carbon PCB Congeners (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 mg/L mg/L mg/L SM2540D SW9060 SW9060 6J -11.4 14 J -10.7 19 J -10.3 9J -12.1 6J -11.9 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0138 0.00251 J 0.00506 U 0.116 0.000926 J 0.0632 0.00228 J 0.0521 0.00357 J 0.00322 J 0.0276 U 0.0206 0.000473 U 0.0308 0.0796 0.129 0.277 0.0713 0.262 0.0436 0.0686 0.000867 U 0.0016 J 0.0914 0.0776 0.0222 0.24 0.137 0.00277 J 0.00469 J 0.000832 U 0.013 0.00258 J 0.00566 U 0.111 0.000309 U 0.0555 0.00206 J 0.0517 0.00348 J 0.00305 J 0.0262 U 0.0208 0.00026 U 0.0313 0.0866 0.139 0.296 0.0771 0.31 0.049 0.0802 0.000833 U 0.00198 J 0.104 0.0844 0.0243 0.267 0.158 0.00306 J 0.00594 J 0.0008 U 0.012 0.00176 J 0.00304 J 0.0645 0.00124 U 0.0319 0.00152 J 0.0237 0.00234 J 0.00183 U 0.0241 U 0.0108 J 0.00104 U 0.0153 J 0.0497 0.0761 0.157 0.0359 0.117 0.0168 J 0.0301 0.000828 U 0.00195 J 0.0429 0.0346 0.0133 0.0997 0.0745 0.00104 J 0.00304 J 0.000801 U 0.0167 0.00371 J 0.00882 0.0923 0.00409 U 0.053 0.00384 U 0.039 0.0044 U 0.00541 U 0.023 U 0.0174 0.00346 U 0.0235 0.0706 0.0879 0.201 0.0461 0.181 0.0337 0.0487 0.00393 U 0.00351 U 0.0621 0.0534 0.013 J 0.162 0.0907 0.00398 U 0.00424 U 0.00367 U 0.0131 0.00226 J 0.00506 J 0.0854 0.0015 U 0.0447 0.00196 J 0.0328 0.00269 J 0.00284 J 0.0235 U 0.0154 J 0.00126 U 0.0217 0.0683 0.0953 0.203 0.045 0.182 0.0333 0.0498 0.00162 U 0.00191 U 0.0623 0.0517 0.0158 0.161 0.0946 0.00164 U 0.00174 U 0.00151 U 45 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0341 0.0009 U 0.000809 U 0.163 0.0162 0.0978 0.0147 0.378 0.0555 0.0308 0.0455 0.245 0.086 0.0555 0.429 0.00247 J 0.00321 J 0.113 0.00211 J 0.000891 J 0.0268 0.0416 0.331 0.0114 0.132 0.218 0.00663 J 0.0241 0.00256 J 0.000842 J 0.0211 0.000793 U 0.00167 J 0.00066 U 0.0013 J 0.0255 0.0411 0.000865 U 0.00107 J 0.214 0.0206 0.127 0.0179 0.473 0.0641 0.0355 0.058 0.303 0.103 0.0608 0.53 0.00282 J 0.0038 J 0.149 0.0025 J 0.00161 J 0.0328 0.0606 0.287 0.0146 0.169 0.3 0.00859 0.0232 0.00346 J 0.00135 J 0.0288 0.000711 U 0.00271 J 0.000592 U 0.00152 J 0.0376 46 of 67 0.0158 0.00087 U 0.000778 U 0.0688 0.00824 J 0.0412 0.00572 J 0.168 0.024 0.0126 0.0201 0.104 0.0333 0.0242 0.186 0.00137 J 0.00133 J 0.0452 0.000652 U 0.000637 U 0.0117 J 0.0175 0.142 0.00502 J 0.0564 0.0883 0.00234 J 0.0167 0.00105 J 0.000711 J 0.0081 J 0.000723 U 0.000891 J 0.000587 U 0.000718 U 0.0125 0.0237 0.00408 U 0.00367 U 0.102 0.0101 0.0597 0.00291 U 0.229 0.0334 0.0184 0.0302 0.139 0.0524 0.0411 0.256 0.00193 U 0.00245 U 0.0694 0.00237 U 0.00233 U 0.0166 J 0.0279 0.203 0.00686 J 0.0816 0.131 0.00345 J 0.0266 0.00227 U 0.00171 U 0.0129 0.00252 U 0.00202 U 0.00209 U 0.00253 U 0.015 0.0251 0.00168 U 0.00151 U 0.114 0.0124 0.0677 0.0115 0.264 0.0366 0.0212 0.0349 0.156 0.0577 0.0536 0.295 0.00167 J 0.00121 U 0.0736 0.00126 J 0.00115 U 0.0184 J 0.0278 0.229 0.00763 J 0.0902 0.147 0.00453 J 0.0316 0.00167 J 0.000835 U 0.014 0.00124 U 0.000998 U 0.00103 U 0.00125 U 0.0174 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0114 0.0558 0.036 0.106 0.000713 U 0.0052 J 0.122 0.0293 0.0261 0.00324 J 0.00207 J 0.106 0.00365 J 0.000752 0.0783 0.00795 J 0.0015 J 0.000208 U 0.0497 0.00156 J 0.00444 J 0.00898 0.158 0.000459 U 0.000604 J 0.00283 J 0.00431 J 0.00317 J 0.097 0.000453 U 0.000463 U 0.00188 J 0.00299 J 0.000751 U 0.000475 U 0.00943 J 0.0148 0.0754 0.0501 0.143 0.000771 U 0.00714 J 0.167 0.0402 0.0355 0.00361 J 0.00277 J 0.145 0.00536 J 0.00128 J 0.108 0.0111 0.00213 J 0.00017 U 0.0719 0.00142 J 0.00606 J 0.0126 0.219 0.000497 U 0.000943 J 0.00412 J 0.00442 J 0.00591 J 0.136 0.00049 J 0.000501 U 0.00307 J 0.00391 J 0.000921 J 0.000537 U 0.0117 J 47 of 67 0.00489 J 0.0259 0.0139 J 0.0503 J 0.000836 U 0.00205 J 0.0598 0.0141 0.0125 0.00151 J 0.000833 U 0.0565 0.00156 J 0.000911 U 0.0371 0.00359 J 0.000699 U 0.000363 U 0.0234 0.000615 U 0.00247 J 0.00445 J 0.0739 0.00055 U 0.000566 U 0.0015 J 0.00225 J 0.00348 J 0.0459 0.000541 U 0.000543 U 0.000968 J 0.00116 J 0.000633 U 0.000602 U 0.00502 J 0.00419 J 0.0315 0.0173 0.0623 0.0019 U 0.00199 U 0.0699 0.0173 0.0156 0.00176 U 0.00191 U 0.0664 0.00257 J 0.00173 U 0.0459 0.00444 J 0.0016 U 0.00116 U 0.029 0.00138 U 0.00138 U 0.0012 U 0.0923 0.00125 U 0.00131 U 0.00129 U 0.0013 U 0.00246 J 0.0635 0.00124 U 0.00125 U 0.00154 U 0.00127 U 0.00164 U 0.00148 U 0.00547 J 0.00583 J 0.0367 0.0218 0.0646 0.000776 U 0.000813 U 0.0764 0.019 0.0154 0.00159 J 0.000781 U 0.0712 0.00285 J 0.000709 U 0.0493 0.00681 J 0.000655 U 0.000564 U 0.032 0.000565 U 0.000564 U 0.00604 J 0.102 0.000512 U 0.000534 U 0.002 J 0.000531 U 0.000581 U 0.0651 0.000508 U 0.000512 U 0.000618 U 0.00194 J 0.000872 U 0.000543 U 0.00486 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0559 0.0042 J 0.00087 J 0.0171 0.00095 J 0.0028 J 0.015 J 0.00655 J 0.0034 J 0.0011 J 0.00812 J 0.000332 U 0.000444 J 0.00222 J 0.000213 U 0.00746 J 0.0366 0.000274 U 0.000201 U 0.000205 U 0.037 0.00061 J 0.000615 J 0.00603 J 0.00531 J 0.000351 J 0.000227 U 0.000214 U 0.000283 J 0.00316 J 0.000233 U 0.00177 J 0.000254 U 0.00703 J 0.00242 J 0.00143 J 0.0724 0.00576 J 0.00129 J 0.0247 0.00106 J 0.00378 J 0.0191 0.00964 0.00409 J 0.00159 J 0.0109 0.000257 U 0.000483 J 0.00277 J 0.000159 U 0.00947 0.0475 0.000213 U 0.00015 U 0.00025 J 0.0486 0.001 J 0.000818 J 0.00807 J 0.00696 J 0.000458 J 0.000176 U 0.000166 U 0.000264 U 0.00412 J 0.000181 U 0.00273 J 0.000281 U 0.00954 0.00295 J 0.00183 J 48 of 67 0.0323 0.00192 J 0.000706 J 0.0109 0.000634 J 0.00234 J 0.00919 J 0.00417 U 0.00141 J 0.000835 J 0.00467 J 0.000471 U 0.000395 U 0.00121 J 0.0003 U 0.00465 J 0.0206 J 0.000388 U 0.000281 U 0.000284 U 0.021 0.00035 U 0.00064 J 0.00358 J 0.00304 J 0.000375 U 0.000335 U 0.000308 U 0.000378 U 0.00179 J 0.000333 U 0.00116 J 0.000435 U 0.00363 J 0.00122 J 0.000637 U 0.0362 0.00194 U 0.00187 U 0.0108 0.0017 U 0.00222 U 0.0101 J 0.00498 J 0.00153 U 0.00157 U 0.00515 J 0.0019 U 0.00161 U 0.0016 U 0.00125 U 0.00471 U 0.0225 0.00159 U 0.00117 U 0.00121 U 0.0235 0.0014 U 0.00104 U 0.00387 J 0.00377 J 0.00139 U 0.00135 U 0.00124 U 0.00137 U 0.00126 U 0.00132 U 0.00128 U 0.00132 U 0.00379 J 0.00169 U 0.00164 U 0.0362 0.00257 J 0.000728 U 0.0124 0.000665 U 0.00249 J 0.0102 J 0.00472 J 0.00274 J 0.000938 J 0.00566 J 0.000742 U 0.000628 U 0.000626 U 0.000485 U 0.00476 U 0.0243 0.000619 U 0.000454 U 0.000469 U 0.0257 0.000547 U 0.000401 U 0.00337 J 0.00385 J 0.000519 U 0.000525 U 0.000482 U 0.000513 U 0.00213 J 0.000516 U 0.0015 J 0.000524 U 0.00401 J 0.00212 J 0.00112 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.00803 J 0.000425 U 0.000977 J 0.00452 J 0.00174 J 0.00396 J 0.016 J 0.000426 U 0.000388 U 0.00427 J 0.000889 J 0.000909 J 0.00024 U 0.00988 0.000203 U 0.000261 U 0.00132 J 0.00033 U 0.000354 U 0.00325 J 0.0013 J 0.0015 J 0.00024 U 0.00458 J 0.000592 J 0.000799 J 0.00147 J 0.0025 J 0.000246 U 0.000357 U 0.00204 J 0.000632 U 0.000997 J 0.00456 J 0.01884 J 0.01631 J 0.0106 0.000408 J 0.00155 J 0.00574 J 0.00286 J 0.00466 J 0.021 0.000369 U 0.000336 U 0.00549 J 0.00158 J 0.000957 J 0.000196 U 0.0134 0.000166 U 0.000362 J 0.00175 J 0.000437 J 0.000307 U 0.00438 J 0.00175 J 0.00243 J 0.000444 J 0.00682 J 0.000559 J 0.0011 J 0.00192 J 0.00369 J 0.000219 U 0.000334 U 0.00224 J 0.000689 U 0.00105 J 0.00517 J 0.01841 J 0.01558 J 49 of 67 0.00448 J 0.000572 U 0.000581 J 0.00203 J 0.00112 J 0.00225 J 0.00874 J 0.000578 U 0.00052 U 0.00249 J 0.000846 J 0.000599 U 0.000398 U 0.00553 J 0.000335 U 0.000489 U 0.000829 J 0.000458 U 0.00049 U 0.00193 J 0.00073 U 0.00111 J 0.000433 U 0.00338 J 0.000456 U 0.000432 U 0.000712 J 0.00164 J 0.000464 U 0.000548 U 0.00166 U 0.000953 U 0.000961 U 0.00281 J 0.0168 J 0.0168 J 0.00384 J 0.00149 U 0.00124 U 0.00172 U 0.00187 U 0.00254 J 0.0102 J 0.00149 U 0.00133 U 0.00272 J 0.00137 U 0.00154 U 0.00133 U 0.00657 J 0.00111 U 0.00136 U 0.00109 U 0.00115 U 0.00124 U 0.00185 U 0.00206 U 0.00223 U 0.0015 U 0.00235 U 0.00158 U 0.00151 U 0.0016 U 0.00218 U 0.0016 U 0.00142 U 0.00505 U 0.00326 U 0.00332 U 0.00241 U 0.02923 J 0.02923 J 0.00525 J 0.000928 U 0.000544 U 0.00363 J 0.00114 J 0.0028 J 0.0116 J 0.000928 U 0.000834 U 0.00336 J 0.000981 J 0.000965 U 0.000586 U 0.00773 J 0.000487 U 0.0006 U 0.00142 J 0.000722 U 0.000772 U 0.00269 J 0.00151 J 0.00159 J 0.000714 U 0.00423 J 0.000753 U 0.000717 U 0.00151 J 0.00241 J 0.000762 U 0.000748 U 0.00259 U 0.00157 U 0.0016 U 0.00295 U 0.02042 J 0.02042 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) PCB Congeners, Dissolved (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.3067325 J 0.292696 J 1.544164 J 1.54246 J 2.5584095 J 2.557683 J 0.957987 J 0.956226 J 0.2283495 J 0.227273 J 0.0646885 J 0.063375 J 0.0164125 J 0.015991 J 0.003353 J 0.003037 J 0.00456 J 0.00456 J 5.7034965 J 5.679611 J 0.2922745 J 0.27889 J 1.729999 J 1.72875 J 3.1009115 J 3.10026 J 1.321992 J 1.320754 J 0.3001625 J 0.299239 J 0.085801 J 0.085114 J 0.0233695 J 0.023093 J 0.0036345 J 0.00329 J 0.00517 J 0.00517 J 6.8817245 J 6.86014 J 0.164165 J 0.15006 J 0.7710685 J 0.76943 J 1.0964305 J 1.094772 J 0.459524 J 0.455678 J 0.1319965 J 0.127595 J 0.036284 J 0.033746 J 0.0103035 J 0.008772 J 0.00166 U 0.00166 U 0.00281 J 0.00281 J 2.691169 J 2.659663 J 0.2473 0.2252 1.08744 J 1.0739 J 1.563175 J 1.55061 J 0.55445 J 0.53966 J 0.14576 J 0.12634 J 0.04099 J 0.02966 J 0.00235 U 0.00235 U 0.00505 U 0.00505 U 0.00241 U 0.00241 U 3.685305 J 3.5746 J 0.22062 J 0.20749 J 1.093005 1.0872 1.7768165 J 1.77296 J 0.603279 J 0.59796 J 0.1507295 J 0.143628 J 0.048844 J 0.045161 J 0.015787 J 0.01394 J 0.00259 U 0.00259 U 0.00295 U 0.00295 U 3.933856 J 3.888759 J ---------------- ---------------- ---------------- ---------------- ---------------- 50 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 51 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 52 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 53 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 54 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater 2014SurfaceWater Location ID PB093_A_201403 PB095_201403 PB097_A_201403 PB099_201403 PB099_201403_MD Sample ID PB093_A-1SWMID-140318-N PB095-1SWMID-140318-N PB097_A-1SWMID-140314-N PB099-1SWMID-140319-N PB099-1SWMID-140319-MD Sample Date 03/18/2014 03/18/2014 03/14/2014 03/19/2014 03/19/2014 Sample Type N N N N FD X 3200967.69985 3201056.9615 3201111.78081 3201139.93874 3201138.73978 Y 13828915.1377 13828738.307 13828556.6898 13828443.8494 13828426.2285 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A ------------------------------------- ------------------------------------- 55 of 67 ------------------------------------- ------------------------------------- ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Conventional Parameters (mg/L) Total suspended solids Dissolved organic carbon Total organic carbon PCB Congeners (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 mg/L mg/L mg/L SM2540D SW9060 SW9060 7J 10.9 10.9 7J -8.12 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 0.0151 0.00373 J 0.00712 J 0.0744 0.00156 U 0.0298 0.00145 U 0.0251 0.00165 U 0.00194 U 0.0269 U 0.00863 J 0.0013 U 0.0194 0.0598 0.0788 0.163 0.0367 0.15 0.0256 0.0388 0.00162 U 0.00223 U 0.0468 0.0393 0.014 0.122 0.0797 0.00164 U 0.00174 U 0.00152 U 0.0017 U 0.00149 U 0.00165 U 0.00704 J 0.00154 U 0.00154 U 0.00142 U 0.00147 U 0.00162 U 0.00157 U 0.015 U 0.00148 U 0.00128 U 0.0083 J 0.00694 J 0.0113 0.0135 J 0.00254 U 0.0149 J 0.00324 J 0.00333 J 0.00152 U 0.0017 U 0.00458 J 0.00275 J 0.00162 U 0.0122 0.00463 J 0.00154 U 0.00162 U 0.00146 U 56 of 67 August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 57 of 67 0.0234 0.00168 U 0.00151 U 0.106 0.0144 0.0626 0.00959 J 0.243 0.0398 0.0181 0.033 0.142 0.0462 0.0346 0.255 0.000983 J 0.00152 U 0.072 0.00149 U 0.00142 U 0.0174 J 0.0294 0.215 0.00716 J 0.083 0.134 0.00437 J 0.024 0.00141 U 0.000971 U 0.0134 0.00157 U 0.0032 J 0.00128 U 0.00156 U 0.0188 0.00791 J 0.00155 U 0.00141 U 0.00771 J 0.00107 U 0.00373 J 0.00105 U 0.0336 0.000975 U 0.00109 U 0.00309 J 0.0092 U 0.00213 J 0.0263 0.0235 0.000678 U 0.0014 U 0.00452 J 0.00134 U 0.00132 U 0.000645 U 0.00297 J 0.0234 J 0.00119 U 0.0061 J 0.00886 J 0.00125 U 0.0301 0.00127 U 0.000681 U 0.00349 J 0.00145 U 0.00123 U 0.00117 U 0.00144 U 0.00142 U August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 58 of 67 0.0087 J 0.0378 0.0223 0.0753 0.0014 U 0.00509 J 0.0844 0.0215 0.0152 J 0.00135 U 0.00147 U 0.078 0.00302 J 0.00134 U 0.0468 0.00672 J 0.00123 U 0.000505 U 0.0326 0.0014 J 0.00278 J 0.00572 J 0.104 0.000946 U 0.00101 U 0.00202 J 0.00102 U 0.00275 J 0.0633 0.000949 U 0.000961 U 0.00115 U 0.0016 J 0.00117 U 0.00105 U 0.00644 J 0.00149 U 0.00543 J 0.00264 J 0.0128 J 0.00117 U 0.00126 U 0.0193 U 0.00295 J 0.00334 J 0.00113 U 0.00123 U 0.016 U 0.000742 U 0.00115 U 0.00809 J 0.00112 U 0.00103 U 0.000604 U 0.00426 J 0.00091 U 0.000897 U 0.000807 U 0.0204 0.00082 U 0.000852 U 0.000788 U 0.000879 U 0.000906 U 0.0132 0.000807 U 0.000809 U 0.000939 U 0.000814 U 0.0016 U 0.00089 U 0.00284 J August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 59 of 67 0.0383 0.00334 J 0.000899 U 0.013 0.000813 U 0.00101 U 0.0115 J 0.00452 J 0.00209 J 0.000746 U 0.00639 J 0.000897 U 0.000783 U 0.000758 U 0.000556 U 0.00537 U 0.0286 0.000769 U 0.000523 U 0.000536 U 0.027 0.000678 U 0.000457 U 0.00393 J 0.00331 J 0.000755 U 0.000594 U 0.000552 U 0.000754 U 0.00243 J 0.000622 U 0.00129 J 0.000735 U 0.00547 J 0.00117 U 0.00113 U 0.0169 J 0.00102 U 0.000981 U 0.00517 J 0.000892 U 0.00114 U 0.00743 J 0.00261 J 0.000806 U 0.000834 U 0.00327 J 0.001 U 0.000846 U 0.000839 U 0.0006 U 0.00302 J 0.0147 J 0.000824 U 0.000556 U 0.000573 U 0.0163 J 0.000737 U 0.0014 J 0.00169 J 0.00171 J 0.000592 U 0.000731 U 0.000651 U 0.000594 U 0.000675 U 0.000701 U 0.000547 U 0.000711 U 0.00374 J 0.000967 U 0.000924 U August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 60 of 67 0.00557 J 0.00103 U 0.000903 J 0.00434 J 0.0015 J 0.00415 J 0.0131 J 0.00102 U 0.000946 U 0.00328 J 0.00221 J 0.00109 U 0.000672 U 0.0112 0.000574 U 0.000822 U 0.000824 U 0.000796 U 0.000853 U 0.00333 J 0.00138 U 0.00248 J 0.000698 U 0.00561 J 0.000791 U 0.000727 U 0.00176 J 0.00299 J 0.000765 U 0.00094 U 0.00267 U 0.0017 U 0.00171 U 0.00308 U 0.02595 J 0.02595 J 0.00359 J 0.000836 U 0.000639 U 0.00215 J 0.000977 U 0.00293 J 0.00983 J 0.000846 U 0.000764 U 0.00269 J 0.00299 J 0.000869 U 0.000682 U 0.00665 J 0.000581 U 0.000781 U 0.00071 U 0.000677 U 0.000711 U 0.00198 J 0.00152 U 0.00104 U 0.00073 U 0.00421 J 0.000733 U 0.000712 U 0.00125 J 0.0022 J 0.000766 U 0.00108 U 0.00337 U 0.00196 U 0.00199 U 0.00249 J 0.0017 U 0.0017 U August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) PCB Congeners, Dissolved (ng/L) PCB-001 PCB-002 PCB-003 PCB-004 PCB-005 PCB-006 PCB-007 PCB-008 PCB-009 PCB-010 PCB-011 PCB-012/013 PCB-014 PCB-015 PCB-016 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 61 of 67 0.17473 J 0.15733 J 0.88387 0.8779 1.6138135 J 1.608203 J 0.6475755 J 0.6398 J 0.1615435 J 0.15214 J 0.0571865 J 0.051723 J 0.0188205 J 0.01617 J 0.00267 U 0.00267 U 0.00308 U 0.00308 U 3.5880695 J 3.529216 J 0.0288 J 0.01534 J 0.09276 J 0.08528 J 0.1937245 J 0.1795 J 0.103292 J 0.07311 J 0.085465 J 0.07704 J 0.040052 J 0.03457 J 0.0129305 J 0.00964 J 0.00337 U 0.00337 U 0.00249 J 0.00249 J 0.565594 J 0.47697 J 0.0113 0.00249 J 0.00669 J 0.0528 0.000504 U 0.0211 0.00137 J 0.0199 0.00205 J 0.00197 J 0.022 U 0.00784 J 0.000422 U 0.0122 0.0384 ---------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-017 PCB-018/030 PCB-019 PCB-020/028 PCB-021/033 PCB-022 PCB-023 PCB-024 PCB-025 PCB-026/029 PCB-027 PCB-031 PCB-032 PCB-034 PCB-035 PCB-036 PCB-037 PCB-038 PCB-039 PCB-040/071 PCB-041 PCB-042 PCB-043 PCB-044/047/065 PCB-045 PCB-046 PCB-048 PCB-049/069 PCB-050/053 PCB-051 PCB-052 PCB-054 PCB-055 PCB-056 PCB-057 PCB-058 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 62 of 67 0.0434 0.095 0.024 0.0664 0.0133 J 0.0191 0.000687 U 0.00116 J 0.0242 0.019 0.00851 J 0.0569 0.0427 0.000696 U 0.000738 U 0.000644 U 0.00952 0.000713 U 0.000641 U 0.0357 0.00458 J 0.0198 0.00316 J 0.0827 0.0175 0.00787 J 0.0107 0.0438 0.02 0.0254 0.0906 0.000544 J 0.00047 U 0.0174 0.000461 U 0.000441 U ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-059/062/075 PCB-060 PCB-061/070/074/076 PCB-063 PCB-064 PCB-066 PCB-067 PCB-068 PCB-072 PCB-073 PCB-077 PCB-078 PCB-079 PCB-080 PCB-081 PCB-082 PCB-083 PCB-084 PCB-085/116 PCB-086/087/097/108/119/125 PCB-088 PCB-089 PCB-090/101/113 PCB-091 PCB-092 PCB-093/100 PCB-094 PCB-095 PCB-096 PCB-098 PCB-099 PCB-102 PCB-103 PCB-104 PCB-105 PCB-106 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 63 of 67 0.00589 J 0.00686 J 0.0508 0.0016 J 0.0272 0.0295 0.00116 J 0.0243 0.000438 U 0.000378 U 0.00265 J 0.000487 U 0.000396 U 0.000398 U 0.000483 U 0.00311 J 0.00147 J 0.00936 0.00433 J 0.0145 U 0.000373 U 0.000863 J 0.0172 U 0.00428 J 0.00371 J 0.000359 U 0.00039 U 0.0195 U 0.0007 J 0.000356 U 0.00858 U 0.00166 J 0.000328 U 0.0002 U 0.00455 U 0.000264 U ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-107/124 PCB-109 PCB-110 PCB-111 PCB-112 PCB-114 PCB-115 PCB-117 PCB-118 PCB-120 PCB-121 PCB-122 PCB-123 PCB-126 PCB-127 PCB-128/166 PCB-129/138/163 PCB-130 PCB-131 PCB-132 PCB-133 PCB-134 PCB-135/151 PCB-136 PCB-137 PCB-139/140 PCB-141 PCB-142 PCB-143 PCB-144 PCB-145 PCB-146 PCB-147/149 PCB-148 PCB-150 PCB-152 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 64 of 67 0.000545 J 0.000256 U 0.0215 U 0.000252 U 0.00011 J 0.000442 J 0.000272 U 0.000278 U 0.0102 U 0.000253 U 0.000256 U 0.000298 U 0.00025 U 0.000367 U 0.000268 U 0.00103 J 0.00793 U 0.000376 U 0.000375 U 0.00247 U 0.00034 U 0.000421 U 0.00317 U 0.00145 U 0.00049 J 0.000312 U 0.00142 J 0.000375 U 0.000327 U 0.000317 U 0.00023 U 0.00112 U 0.00631 U 0.000321 U 0.000216 U 0.000221 U ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-153/168 PCB-154 PCB-155 PCB-156/157 PCB-158 PCB-159 PCB-160 PCB-161 PCB-162 PCB-164 PCB-165 PCB-167 PCB-169 PCB-170 PCB-171/173 PCB-172 PCB-174 PCB-175 PCB-176 PCB-177 PCB-178 PCB-179 PCB-180/193 PCB-181 PCB-182 PCB-183 PCB-184 PCB-185 PCB-186 PCB-187 PCB-188 PCB-189 PCB-190 PCB-191 PCB-192 PCB-194 Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 65 of 67 0.00553 U 0.000283 U 0.000189 U 0.000706 J 0.000768 J 0.000237 U 0.000248 U 0.00023 U 0.000236 U 0.000537 J 0.00026 U 0.000216 U 0.000238 U 0.00177 J 0.000462 U 0.000447 U 0.00142 J 0.000408 U 0.000234 U 0.000895 J 0.000351 U 0.000748 J 0.00327 J 0.000403 U 0.000375 U 0.000913 J 0.000255 U 0.000433 U 0.000248 U 0.00183 J 0.000212 U 0.00031 U 0.000349 U 0.000316 U 0.000338 U 0.000857 J ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results FINAL VALIDATED DATA PCB-195 PCB-196 PCB-197 PCB-198/199 PCB-200 PCB-201 PCB-202 PCB-203 PCB-204 PCB-205 PCB-206 PCB-207 PCB-208 PCB-209 Total Monochlorobiphenyl homologs (U = 1/2) Total Monochlorobiphenyl homologs (U = 0) Total Dichlorobiphenyl homologs (U = 1/2) Total Dichlorobiphenyl homologs (U = 0) Total Trichlorobiphenyl homologs (U = 1/2) Total Trichlorobiphenyl homologs (U = 0) Total Tetrachlorobiphenyl homologs (U = 1/2) Total Tetrachlorobiphenyl homologs (U = 0) Total Pentachlorobiphenyl homologs (U = 1/2) Total Pentachlorobiphenyl homologs (U = 0) Total Hexachlorobiphenyl homologs (U = 1/2) Total Hexachlorobiphenyl homologs (U = 0) Total Heptachlorobiphenyl homologs (U = 1/2) Total Heptachlorobiphenyl homologs (U = 0) Total Octachlorobiphenyl homologs (U = 1/2) Total Octachlorobiphenyl homologs (U = 0) Total Nonachlorobiphenyl homologs (U = 1/2) Total Nonachlorobiphenyl homologs (U = 0) Total Decachlorobiphenyl homologs (U = 1/2) Total Decachlorobiphenyl homologs (U = 0) Total PCB Congener (U = 1/2) Total PCB Congener (U = 0) Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site Task 2014SurfaceWater 2014SurfaceWater Location ID PB-101.1_201403 PB-119_B_201403 Sample ID PB101.1-1SWMID-140319-N PB119_B-1SWMID-140313-N Sample Date 03/19/2014 03/13/2014 Sample Type N N X 3201247.13475 3201529.19757 Y 13828263.2413 13826349.5712 ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A E1668A 66 of 67 0.000477 U 0.000337 U 0.000225 U 0.0011 J 0.000256 U 0.000235 U 0.000249 U 0.000328 U 0.000247 U 0.000324 U 0.000872 U 0.000558 U 0.000564 U 0.00118 U 0.02048 J 0.02048 J 0.130693 J 0.11923 J 0.4636495 J 0.46159 J 0.53169 J 0.529714 J 0.081105 J 0.03058 J 0.021925 J 0.004951 J 0.0134165 J 0.010846 J 0.003296 J 0.001957 J 0.000872 U 0.000872 U 0.00118 U 0.00118 U 1.267842 J 1.179348 J ------------------------------------August 2014 040284-01.08 Appendix E Detailed Analytical Results Notes: Bold = Detected result J = Estimated value U = Compound analyzed, but not detected above detection limit UJ = Compound analyzed, but not detected above estimated detection limit FD = field duplicate or method duplicate J = Estimated value mg/L = milligrams per liter N = normal field sample ng/L = nanograms per liter PCB = polychlorinated biphenyls TEQ = toxic equivalency U = Compound analyzed, but not detected above estimated detection limit UJ = Compound analyzed, but not detected above estimated detection limit Horizontal coordinate datum is NAD 1983 StatePlane Texas South Central FIPS 4204 (US Survey Feet). All undetect PCB results are reported at the estimated detection limit. Other results were reported at the reporting limit. USEPA Stage 2B data validation was completed by Laboratory Data Consultants (LDC). Totals are calculated as the sum of all detected results (U=0). If all results are not detected, the highest estimated detection limit value is reported as the sum. Totals are calculated as the sum of all detected results and half of the estimated detection limit of undetected results (U=1/2). If all results are not detected, the highest estimated detection limit value is reported as the sum. Total PCB congeners is the sum of all PCB congeners listed in this table. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 67 of 67 August 2014 040284-01.08 Appendix F Discharge Calculations Station ID: PB081_A Time Started: 16:00 Stream Width: 39 ft Section 1 2 3 4 5 6 7 8 9 Date: 3/14/2014 Time Ended: 16:30 Section Width: 4.0 ft a Discharge Section Midpoint (ft) Section Depth (ft) Observation Depth (ft) Velocity (ft/s) Area (ft2) (ft3/s) 2 9 10 14 18 22 26 30 34 3.2 2.9 3.2 3.0 3.6 4.1 4.3 4.6 3.8 1.9 1.7 1.9 1.8 2.2 2.5 2.6 2.8 2.3 0.00 0.00 0.05 0.43 0.27 0.25 0.00 0.03 0.00 12.80 11.60 12.80 12.00 14.40 16.40 17.20 18.40 15.20 Total Discharge 0.00 0.00 0.64 5.16 3.89 4.10 0.00 0.55 0.00 14.34 Notes: ft - feet ft/s - feet per second ft2 - square feet ft3/s - cubic feet per second a - It is possible that discharge data collected during this sampling program may have been influenced by wedges of water pushed upstream in the waterway from large ships passing the outlet of Patrick Bayou. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 1 of 7 August 2014 040284-01.08 Appendix F Discharge Calculations Station ID: PB087 Time Started: 15:40 Stream Width: 32 ft Section 1 2 3 4 5 6 7 8 9 10 Date: 3/14/2014 Time Ended: 15:55 Section Width: 3.2 ft Discharge Section Midpoint (ft) Section Depth (ft) Observation Depth (ft) Velocity (ft/s) Area (ft ) (ft /s) 4.8 8.0 11.2 14.4 17.6 20.8 24.0 27.2 30.4 31.6 2.9 4.1 4.9 4.5 6.5 7.0 7.0 6.3 3.5 1.9 1.5 1.5 2.0 2.0 2.0 2.0 2.0 2.0 2.0 1.5 0.40 0.13 0.25 0.26 0.35 0.25 0.35 0.45 0.69 0.00 9.28 13.12 15.68 14.40 20.80 22.40 22.40 20.16 11.20 6.08 Total Discharge 3.71 1.71 3.92 3.74 7.28 5.60 7.84 9.07 7.73 0.00 50.60 2 3 Notes: ft - feet ft/s - feet per second ft2 - square feet ft3/s - cubic feet per second a - It is possible that discharge data collected during this sampling program may have been influenced by wedges of water pushed upstream in the waterway from large ships passing the outlet of Patrick Bayou. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 2 of 7 August 2014 040284-01.08 Appendix F Discharge Calculations Station ID: PB087 Time Started: 16:15 Stream Width: 32.5 ft Section 1 2 3 4 5 6 7 8 9 10 Date: 3/18/2014 Time Ended: 16:50 Section Width: 3.25 ft Discharge Section Midpoint (ft) Section Depth (ft) Observation Depth (ft) Velocity (ft/s) Area (ft ) (ft /s) 1.63 4.88 8.13 11.36 14.63 17.88 21.13 24.38 27.63 30.86 2.3 3.4 4.4 5.5 6.3 7.1 7.1 7.5 6.8 4.8 1.4 2.0 2.6 3.3 3.8 4.3 4.3 4.5 4.1 2.9 0.09 0.09 0.04 0.00 0.03 0.02 0.06 0.11 0.01 0.054 7.48 11.05 14.30 17.88 20.48 23.08 23.08 24.38 22.10 15.60 Total Discharge 0.67 0.99 0.57 0.00 0.61 0.46 1.38 2.68 0.22 0.84 8.44 2 3 Notes: ft - feet ft/s - feet per second ft2 - square feet ft3/s - cubic feet per second a - It is possible that discharge data collected during this sampling program may have been influenced by wedges of water pushed upstream in the waterway from large ships passing the outlet of Patrick Bayou. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 3 of 7 August 2014 040284-01.08 Appendix F Discharge Calculations Station ID: PB095 Time Started: 18:00 Stream Width: 25 ft Section 1 2 3 4 5 6 7 8 9 10 Date: 3/18/2014 Time Ended: 18:20 Section Width: 2.5 ft Discharge Section Midpoint (ft) Section Depth (ft) Observation Depth (ft) Velocity (ft/s) Area (ft ) (ft3/s) 1.3 3.8 6.3 8.8 11.3 13.8 16.3 18.8 21.3 23.4 2.2 2.5 2.9 3.3 4.0 3.7 3.4 3.5 3.8 1.1 1.3 1.5 1.8 2.0 2.4 2.2 2.0 2.1 2.3 0.7 0.07 0.45 0.00 0.00 0.25 0.28 0.13 0.00 0.08 0.00 5.50 6.25 7.25 8.25 10.00 9.25 8.50 8.75 9.50 2.75 Total Discharge 0.39 2.81 0.00 0.00 2.50 2.59 1.11 0.00 0.76 0.00 10.15 2 Notes: ft - feet ft/s - feet per second ft2 - square feet ft3/s - cubic feet per second a - It is possible that discharge data collected during this sampling program may have been influenced by wedges of water pushed upstream in the waterway from large ships passing the outlet of Patrick Bayou. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 4 of 7 August 2014 040284-01.08 Appendix F Discharge Calculations Station ID: PB097_A Time Started: 17:56 Stream Width: 24 ft Section 1 2 3 4 5 6 7 8 9 10 Date: 3/15/2014 Time Ended: 18:07 Section Width: 2.4 ft Discharge Section Midpoint (ft) Section Depth (ft) Observation Depth (ft) Velocity (ft/s) Area (ft ) (ft3/s) 1.2 3.6 6.0 8.4 10.8 13.2 15.6 18.0 20.4 22.8 2.4 3.0 3.4 3.9 4.1 3.9 3.0 3.0 4.0 3.5 1.6 1.6 1.6 1.6 2.0 2.0 2.0 2.0 2.0 2.0 0.05 0.00 0.00 0.02 0.19 0.48 0.32 0.22 0.13 0.25 5.76 7.20 8.16 9.36 9.84 9.36 7.20 7.20 9.60 8.40 Total Discharge 0.29 0.00 0.00 0.19 1.87 4.49 2.30 1.58 1.25 2.10 14.07 2 Notes: ft - feet ft/s - feet per second ft2 - square feet ft3/s - cubic feet per second a - It is possible that discharge data collected during this sampling program may have been influenced by wedges of water pushed upstream in the waterway from large ships passing the outlet of Patrick Bayou. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 5 of 7 August 2014 040284-01.08 Appendix F Discharge Calculations Station ID: PB097_A Time Started: 16:00 Stream Width: 25 ft Section 1 2 3 4 5 6 7 8 9 10 Date: 3/19/2014 Time Ended: 16:19 Section Width: 2.5 ft Discharge Section Midpoint (ft) Section Depth (ft) Observation Depth (ft) Velocity (ft/s) Area (ft ) (ft /s) 2.25 4.75 7.25 9.75 12.25 14.75 17.25 19.75 22.25 24.75 1.7 2.4 2.8 3.2 3.7 3.0 3.1 2.9 3.4 NA 1.0 1.4 1.7 1.9 2.2 1.8 1.9 1.8 2.0 NA 0.06 0.24 0.00 0.38 0.23 0.06 0.19 0.22 0.10 NA 4.25 6.00 7.00 8.00 9.25 7.50 7.75 7.25 8.50 NA Total Discharge 0.26 1.44 0.00 3.04 2.13 0.45 1.47 1.60 0.85 NA 11.23 2 3 Notes: ft - feet ft/s - feet per second ft2 - square feet ft3/s - cubic feet per second a - It is possible that discharge data collected during this sampling program may have been influenced by wedges of water pushed upstream in the waterway from large ships passing the outlet of Patrick Bayou. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 6 of 7 August 2014 040284-01.08 Appendix F Discharge Calculations Station ID: PB099 Time Started: 18:18 Stream Width: 23 ft Section 1 2 3 4 5 6 7 8 9 10 Date: 3/19/2014 Time Ended: 18:34 Section Width: 2.3 ft Discharge Section Midpoint (ft) Section Depth (ft) Observation Depth (ft) Velocity (ft/s) Area (ft ) (ft /s) 24.7 22.2 19.9 17.6 15.3 13.0 10.7 8.4 6.1 3.8 0.8 1.4 1.7 1.5 1.3 1.2 1.2 1.3 1.2 0.1 0.5 0.9 1.0 0.9 0.8 0.8 0.8 0.8 0.8 NA 0.06 0.47 0.13 0.26 0.29 0.00 0.00 0.01 0.00 NA 1.84 3.22 3.91 3.45 2.99 2.76 2.76 2.99 2.76 NA Total Discharge 0.11 1.51 0.51 0.90 0.87 0.00 0.00 0.03 0.00 NA 3.93 2 3 Notes: ft - feet ft/s - feet per second ft2 - square feet ft3/s - cubic feet per second a - It is possible that discharge data collected during this sampling program may have been influenced by wedges of water pushed upstream in the waterway from large ships passing the outlet of Patrick Bayou. Supplemental Surface Water Sampling Data Report Patrick Bayou Superfund Site 7 of 7 August 2014 040284-01.08 APPENDIX E EMPIRICAL EVALUATION OF NATURAL RECOVERY BASED ON SURFACE WATER DATA PATRICK BAYOU SUPERFUND SITE Prepared for Patrick Bayou Joint Defense Group U.S. Environmental Protection Agency Prepared by Anchor QEA, LLC 614 Magnolia Avenue Ocean Springs, Mississippi 39564 March 2017 TABLE OF CONTENTS 1 INTRODUCTION ................................................................................................................ 1 2 APPROACH ......................................................................................................................... 1 3 RESULTS .............................................................................................................................. 2 4 REFERENCES ...................................................................................................................... 4 List of Tables Table E-1 Summary of Average Surface Water PCB Concentrations and Results from Analytical First Order Decay Modeling ............................................................... 3 List of Figures Figure E-1 Spatial Profile of Water Column PCB Data Collected in 2009, 2011, and 2014 Figure E-2 Estimated Rate of Decline in Surface Water Concentrations in Samples from PB 70-82 Figure E-3 Estimated Rate of Decline in Surface Water Concentrations in Samples from PB 56-76 Figure E-4 Estimated Rate of Decline in Surface Water Concentrations in Samples from PB 56-73 Figure E-5 Estimated Rate of Decline in Surface Water Concentrations in Samples from PB 06 Empirical Evaluation of Natural Recovery Based on Surface Water Data Patrick Bayou Superfund Site E-i March 2017 040284-01.08 LIST OF ACRONYMS AND ABBREVIATIONS FS Feasibility Study ng/L nanograms per liter PCB polychlorinated biphenyl RAO remedial action objective Site Patrick Bayou Site Empirical Evaluation of Natural Recovery Based on Surface Water Data Patrick Bayou Superfund Site E-ii March 2017 040284-01.08 1 INTRODUCTION This appendix describes an analysis conducted to estimate the rate of natural recovery in Patrick Bayou based on water column polychlorinated biphenyl (PCB) data. As part of the Patrick Bayou site (Site) Remedial Investigation, surface water samples were collected during two sampling events (November 2009 and August 2011 [22 samples in 2009 and four samples in 2011]; Anchor QEA 2013). In 2014, additional surface water data were collected to: 1) develop a better understanding of the nature and extent of PCBs in surface water in a specific portion of the Site; and 2) provide additional information for development and calibration of the fate and transport model being developed for the Site (Appendix A of the Feasibility Study [FS]). Evaluation of these datasets indicated that the 2014 water column PCB results were systematically lower than those collected in 2009 and 2011 (Appendix D of the FS). Numerous factors were evaluated to attempt to explain the observed differences between the 2009, 2011, and 2014 datasets, including differences in sampling locations, tidal conditions, flows, and antecedent precipitation (Appendix A). Based on this evaluation, it was determined that there were no significant differences in any of these factors that could explain the change in water column PCB concentration over this 5-year period. As such, it was concluded that the observed reduction in water column concentrations between 2009 and 2014 was a result of natural attenuation processes that reduced flux of PCBs to the water column. Analytical modeling was therefore performed to estimate the rates of natural recovery exhibited by the water column data, as presented in the remainder of this appendix. 2 APPROACH Figure E-1 shows a spatial profile of water column PCB data collected at the Site in 2009, 2011, and 2014. This figure illustrates that the magnitude of the observed decline between 2009, 2011, and 2014 varies spatially throughout the Site. Therefore, data were grouped into four locations for this evaluation to provide a range of recovery rate estimates based on the following criteria: • Locations with samples collected during 2009 and 2014 (and 2011 where possible) in close proximity to one another were selected. • Locations upstream of approximately PB-082 were excluded because they are located upstream of the predominant source area within the concrete-lined channel (this Empirical Evaluation of Natural Recovery Based on Surface Water Data Patrick Bayou Superfund Site E-1 March 2017 040284-01.08 Appendix E source area is apparent based on the observed sharp increase in water column PCB concentrations at this location in the 2009, 2011, and 2014 datasets, as discussed in Appendix A). • The three locations sampled in 2014 between Stations PB-020 and PB-050 (shown as open symbols on Figure E-1) were excluded because they are considered potentially less representative of water column PCB transport at the Site (see Section 3.3 of Appendix A for additional discussion). The data selected at each of the four locations are shown as time-series plots on Figures E-2 through E-5. Mechanisms controlling natural recovery of contaminated sediment (e.g., processes such as deposition and degradation) often follow a first order decline (Chapra 1997; Magar et al. 2009). Thus, the rate of natural recovery at these four locations was estimated by fitting an exponential rate of decline (i.e., first order decay) through PCB concentrations measured over time using least squares regression to estimate a half-life (see bottom panel of Figures E-2 through E-5). The resulting regression lines were extended out over a 20-year period to estimate the time at which the water column PCB concentrations would be predicted to meet the surface water remedial action objective (RAO) of 8.2 nanograms per liter (ng/L) total PCBs. 3 RESULTS Table 1 provides a summary of average PCB concentrations measured in samples collected from each of the four location groups for each year of sampling as well as the calculated half-life and number of years estimated from the first order decay fit for the PCB concentrations to fall below the PCB surface water RAO. Empirical Evaluation of Natural Recovery Based on Surface Water Data Patrick Bayou Superfund Site E-2 March 2017 040284-01.08 Appendix E Table E-1 Summary of Average Surface Water PCB Concentrations and Results from Analytical First Order Decay Modeling Stations PB 06 PB 56-73 PB 56-76 PB 70-82 2009 Average PCB (ng/L) 121 283 153 87 2011 Average PCB (ng/L) NS 100 100 112 2014 Average PCB (ng/L) 50 68 68 45 Estimated Half-life (years) 4.0 2.9 6.1 4.4 Estimated Number of Years (from 2014) to Meet RAO of 8.2 ng/L 10 9 19 10 Notes: ng/L – nanograms per liter NS – not sampled PCB – polychlorinated biphenyl RAO – remedial action objective The results of this analysis indicate that water column PCB concentrations decreased at halflives of approximately 3 to 6 years between 2009, 2011, and 2014, depending on location sampled. If those observed rates of decline continue into the future, it is estimated from the first order fits that water column PCB concentrations would decrease below the PCB surface water RAO within 9 to 19 years, depending on location. However, it is important to recognize that there is uncertainty in this analysis, given that the regressions from which the rates of decline were estimated were based on data from 2 to 3 points over time (given this paucity of data, quantification of uncertainty intervals on the rates of decline could not be calculated). Therefore, additional surface water sampling would need to be conducted as part of a Monitored Natural Recovery alternative at the Site to evaluate whether the observed declines continue into the future. Empirical Evaluation of Natural Recovery Based on Surface Water Data Patrick Bayou Superfund Site E-3 March 2017 040284-01.08 4 REFERENCES Anchor QEA, 2013. Patrick Bayou Remedial Investigation Report. Patrick Bayou Superfund Site, Deer Park, Texas. Prepared for U.S. Environmental Protection Agency and the Patrick Bayou Joint Defense Group. September 2013. Chapra, S.C., 1997. Surface Water Quality Modeling. New York: McGraw-Hill. Magar, V.S., D.B. Chadwick, T.S. Bridges, P.C. Fuchsman, J.M. Conder, T.J.Dekker, J.A. Steevens, K.E. Gustavson, and M.A. Mills, 2009. Technical Guide: Monitored Natural Recovery at Contaminated Sediment Sites. ESTCP Project ER-0622. May 2009. Empirical Evaluation of Natural Recovery Based on Surface Water Data Patrick Bayou Superfund Site E-4 March 2017 040284-01.08 HGES Water Column Total PCB (ng/L) Houston Ship Channel East Fork End Concrete-lined Channel 100.0 Start Concrete-lined Channel 1000.0 Surface Water RAO (8.2 ng/L) 10.0 1.0 2009 Data 2011 Data 2014 Data Upstream Data 0.1 100 80 60 40 Station ID 20 0 -20 Figure E-1 Spatial Profile of Water Column PCB Data Collected in 2009, 2011, and 2014 Patrick Bayou Feasibility Study Report - Appendix E Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas Open circles represent samples having potential incomplete lateral mixing. DR - \\helios\aq\D_Drive\Projects\Patrick_Bayou_Joint_Defense_Group\Patrick_Bayou(040284-01)\MODEL\analysis\MNR_Analytical_Model\PB_WC_data_spatial_depth_avg_longterm_2014_TFigureE1_rev01.pro Wed Aug 31 10:53:31 2016 PB 70-82 PB 70-82 Data 160 1st Order Decay Fit to Data 140 Surface Water RAO (8.2 ng/L) Total PCB (ng/L) 120 100 80 60 40 20 0 0 5 10 15 20 Years Figure E-2 Estimated Rate of Decline in Surface Water Concentrations in Samples from PB 70-82 Patrick Bayou Feasibility Study Report – Appendix E Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas PB 56-76 PB 56-76 Data 500 1st Order Decay Fit to Data 450 Surface Water RAO (8.2 ng/L) Total PCB (ng/L) 400 350 300 250 200 150 100 50 0 0 5 10 15 20 Years Figure E-3 Estimated Rate of Decline in Surface Water Concentrations in Samples from PB 56-76 Patrick Bayou Feasibility Study Report – Appendix E Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas PB 56-73 RM 56-73 Data 500 1st Order Decay Fit to Data 450 Surface Water RAO (8.2 ng/L) Total PCB (ng/L) 400 350 300 250 200 150 100 50 0 0 5 10 15 20 Years Figure E-4 Estimated Rate of Decline in Surface Water Concentrations in Samples from PB 56-73 Patrick Bayou Feasibility Study Report – Appendix E Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas PB 6 PB 6 Data 200 1st Order Decay Fit to Data 180 Surface Water RAO (8.2 ng/L) Total PCB (ng/L) 160 140 120 100 80 60 40 20 0 0 5 10 15 20 Years Figure E-5 Estimated Rate of Decline in Surface Water Concentrations in Samples from PB 06 Patrick Bayou Feasibility Study Report – Appendix E Patrick Bayou Superfund Site Remedial Investigation, Deer Park, Texas APPENDIX F ALTERNATIVES ANALYSIS FOR INSTITUTIONAL CONTROLS PATRICK BAYOU SUPERFUND SITE Prepared for Patrick Bayou Joint Defense Group U.S. Environmental Protection Agency Prepared by Anchor QEA, LLC 614 Magnolia Avenue Ocean Springs, Mississippi 39564 March 2017 TABLE OF CONTENTS 1 2 INSTITUTIONAL CONTROLS ............................................................................................ 1 1.1 Overall Protection of Human Health and the Environment.........................................2 1.2 Compliance with Applicable or Relevant and Appropriate Requirement ...................3 1.3 Long-Term Effectiveness .................................................................................................3 1.4 Reduction in Toxicity, Mobility or Volume ...................................................................4 1.5 Short-Term Effectiveness ................................................................................................4 1.6 Implementability ..............................................................................................................4 1.7 Cost....................................................................................................................................4 1.8 State and Community Acceptance ..................................................................................5 REFERENCES ...................................................................................................................... 6 Table Table F-1 Institutional Controls Relevant to the Patrick Bayou Superfund Site Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site F-i March 2017 040284-01.08 LIST OF ACRONYMS AND ABBREVIATIONS ARAR Applicable or Relevant and Appropriate Requirement CERCLA Comprehensive Environmental Response, Compensation, and Liability Act COC chemical of concern FS Feasibility Study HSC Houston Ship Channel JDG Patrick Bayou Superfund Site Joint Defense Group NOAA National Oceanic and Atmospheric Administration POHA Port of Houston Authority ROD Record of Decision TDSHS Texas Department of State Health Services TPWD Texas Parks and Wildlife Department TMV toxicity, mobility or volume TSA U.S. Transportation Security Administration TWIC Transportation Worker Identification Credential USCG U.S. Coast Guard USEPA U.S. Environmental Protection Agency Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site F-ii March 2017 040284-01.08 1 INSTITUTIONAL CONTROLS Institutional controls are administrative and legal controls that are used to limit human exposure to chemicals or to protect the integrity of a remedy. The National Contingency Plan (i.e., the regulations that guide Superfund response actions [codified at 40 CFR Part 300]), contains a preference for the use of engineered remedial actions that treat, remove, or contain chemically impacted materials to the extent that such actions are cost effective. Institutional controls are typically used in conjunction with engineered controls where risks to human health have been identified. While there are no identified direct risks to human health from Patrick Bayou, institutional controls could be used as protective measures against potential indirect human health exposures. The three major types of institutional controls considered are government controls, proprietary controls, and informational devices. Government controls may include the following: • Zoning changes, such as restricting land use to prevent residential development • Local permits, such as those that require specific actions be taken before an activity is authorized • Police power ordinances, such as enforceable bans on fishing and swimming • Property condemnation Proprietary controls may include the following: • Waterway use restrictions and maintenance agreements • Access and property use restrictions, such as easements and covenants Informational devices may include the following: • Monitoring and notification of waterway users • Seafood consumption advisories, public outreach, and education • Enforcement tools • Site registry Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site F-1 March 2017 040284-01.08 Institutional Controls The Site has a variety of institutional controls already in place because of its industrial setting, including access and property use restrictions, and Homeland Security requirements that prevent unauthorized access to the site. Beyond the Site, additional measures have been taken by others, including monitoring and notification of waterway uses in the Houston Ship Channel (HSC), seafood consumption advisories in the HSC and Galveston Bay, and associated public outreach and education. Institutional controls are potentially applicable to all areas of the Site. In addition to the existing institutional controls, an additional control could be applied in the form of deed restrictions preventing dredging within Patrick Bayou. As described in the Feasibility Study (FS), the concentration of chemicals of concern (COCs) increases with depth. By restricting dredging within Patrick Bayou, the potential for exposing these currently buried COCs is significantly reduced, preventing future potential exposure of these COCs to the environment. Table F-1 presents a list of institutional controls relevant to the Patrick Bayou Superfund Site, describing the type of control, its objective, when it would be implemented, and the duration of implementation and who holds primary responsibility for instituting and maintaining the institutional control. The following is an assessment of institutional controls relative to the nine Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) evaluation criteria. The assessment covers institutional controls in general as a category; however, where specific institutional controls listed in Table F-1 have different considerations than the general category, highlights of those differences are described in the assessment. 1.1 Overall Protection of Human Health and the Environment The institutional controls in place already (Table F-1) provide for overall protection of human health by severely restricting access to the Site by the public and limiting activities within Patrick Bayou to properly credentialed and approved personnel. Enhanced Texas811 notifications and annual notifications to any entities with easements or property ownership adjacent to the Site are institutional controls that would provide additional protection of Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site F-2 March 2017 040284-01.08 Institutional Controls human health by minimizing potential for unauthorized site activities or activities without proper engineering controls in place. Similarly, a deed restriction preventing future dredging of the Site would provide for protection of human health by minimizing the potential that buried sediment would be disturbed. By restricting disturbance, related water column and downstream sediment impacts would be prevented. To the extent that such potential impacts could result in human exposure, deed restrictions on dredging would provide for enhanced overall protection of both human health and the environment. In addition, existing engineering controls (e.g., fencing) effectively prevent human exposure to the Site. Institutional controls rank high for overall protection of human health and the environment. 1.2 Compliance with Applicable or Relevant and Appropriate Requirements Institutional controls do not require construction or other changes to baseline conditions that would trigger any action-, chemical-, or location-specific Applicable or Relevant and Appropriate Requirements (ARARs), which are identified in Section 3 of the FS. Because no construction activity is included in this alternative, there are no substantive permit conditions that would need to be met. Institutional controls rank high for compliance with ARARs. 1.3 Long-term Effectiveness Institutional controls have been widely used to effectively protect human health from certain exposure pathways. Institutional controls are compatible and often used in conjunction with remedial technologies that treat or isolate chemically impacted sediments in places or in circumstances where potential exposure to chemicals is expected to persist (USEPA 1997). Generally, the institutional controls already in place and applicable to the Site are effective in reducing potential human exposure to Site chemicals of potential concern. The addition of deed restrictions on future dredging as well as enhanced reporting and notification to property, right-of-way, and easement holders would provide for additional protection and enhance the long-term effectiveness of institutional controls. Therefore, as a category, institutional controls rank high for long-term effectiveness. Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site F-3 March 2017 040284-01.08 Institutional Controls 1.4 Reduction in Toxicity, Mobility, or Volume Institutional controls do not reduce the toxicity, mobility, or volume (TMV) of chemicals. However, the toxicity of surface sediments will naturally decline over time due to deposition of relatively clean sediments within Patrick Bayou. Institutional controls rank low for the reduction in TMV. 1.5 Short-term Effectiveness Implementation of institutional controls does not entail active construction. Thus, shortterm risks, such as impacts to water quality, air emissions, noise, and worker health and safety, are non-existent for institutional controls. These controls require coordination to implement; however, this coordination can be accomplished relatively quickly and thus institutional controls would be very effective in the short term. Institutional controls rank high for short-term effectiveness. 1.6 Implementability Institutional controls are technically implementable. The administration of institutional controls would need to be further coordinated with stakeholder groups, such as Harris County, the Port of Houston Authority (POHA), and regulatory agencies, where appropriate. When using institutional controls alone, implementability is often considered to have a moderate rank at many CERCLA sites, as there may be administrative hurdles to overcome to enact certain use restrictions. For example, a deed restriction on dredging in Patrick Bayou would preclude any future efforts to increase the flood capacity of this segment of the drainage system. However, given the industrial setting of Patrick Bayou and the fact that there is a long history of successfully implementing a variety of institutional controls at the Site, institutional controls rank moderate to high for implementability. 1.7 Cost The cost of implementing institutional controls is low compared to the cost of implementing engineering controls. Costs are primarily related to administrative and legal activities, community education and engagement, construction and maintenance of fencing and warning signs, and potential long-term maintenance of the institutional controls. Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site F-4 March 2017 040284-01.08 Institutional Controls Assuming a one-time administrative and legal cost of $100,000 to implement institutional controls and annual maintenance of $15,000, the cost of institutional controls is approximately $250,000 to $300,000 over 30 years on a Net Present Value basis, assuming a discount rate of 7 percent. 1.8 State and Community Acceptance State and community acceptance are considered by USEPA in preparing the Record of Decision based on consultation with the State environmental agency and a review of public comments received in response to the FS and the proposed plan. As such, State and community acceptance are not considered directly in this evaluation of institutional controls and will be evaluated by USEPA separately after public comments are received on the proposed plan. Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site F-5 March 2017 040284-01.08 2 REFERENCES USEPA (U.S. Environmental Protection Agency), 1997. Rules of Thumb for Superfund Remedy Selection. U.S. Environmental Protection Agency. Office of Emergency and Remedial Response, Washington, DC. EPA 540-R-97-013. Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site F-6 March 2017 040284-01.08 Table F-1 Institutional Controls Relevant to the Patrick Bayou Superfund Site Institutional Control Type Objective Transportation Worker Identification Credential (TWIC) Government Controls Local Land Use Zoning Government Controls HSC Notifications Government Controls Deed Restriction Preventing Dredging Proprietary Controls Enhanced Texas811 notifications and annual notifications to easement holders Proprietary Controls Prevent unauthorized Site work or work without appropriate engineering controls in place by non-JDG entities JDG Member Property Restrictions Proprietary Controls Site security procedures require specific safety training and escort to access properties including Patrick Bayou. Seafood Consumption Advisories Informational Devices Restricts access to the site due to Homeland Security issues. TWIC credentials required to access properties. Property bounding the Site is zoned as Industrial, preventing residential development and limiting access. The downstream 200 yards of Patrick Bayou is within a Security Zone established in 33 CFR §165.814. Unauthorized access is prohibited without permission from the Captain of the Port Houston-Galveston. Prevent dredging in Patrick Bayou that could expose deeply buried, higher-concentration sediments. Notify the public recommending limits on seafood consumption to limit potential exposure to dioxins, pesticides and PCBs. Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site 1 When Implemented and for How Long? Currently implemented; maintained for the foreseeable future Currently implemented; maintained for the foreseeable future Currently implemented (NOAA Chart 11325); maintained for the foreseeable future Implemented following the ROD; maintained for the foreseeable future Implemented prior to or following the ROD; maintained for the foreseeable future Currently implemented; maintained for the foreseeable future Currently implemented (TDSHS ADV-49); maintained for the foreseeable future Responsibility Existing Control? TSA/JDG Yes City of Deer Park Yes USCG/POHA Yes JDG No JDG No JDG Yes TDSHS Yes March 2017 040284-01.08 Institutional Control Type Public Outreach and Education Informational Devices Objective News releases and linkages to other web sites (e.g., TPWD) advising public about seafood consumption advisories. When Implemented and for How Long? Currently implemented; maintained for the foreseeable future Responsibility Existing Control? TDSHS Yes Notes: JDG – Patrick Bayou Superfund Site Joint Defense Group NOAA – National Oceanic and Atmospheric Administration PCB – polychlorinated biphenyl POHA – Port of Houston Authority ROD – Record of Decision TDSHS – Texas Department of State Health Services TPWD – Texas Parks and Wildlife Department TSA – U.S. Transportation Security Administration USCG – U.S. Coast Guard Alternatives Analysis for Institutional Controls Patrick Bayou Superfund Site 2 March 2017 040284-01.08 ATTACHMENT 1 MEETING NOTES AND RESPONSE TO COMMENTS ON DRAFT INTERIM FINAL FEASIBILITY STUDY REPORT Patrick Bayou Superfund Site EPA/JDG Meeting Notes Date: July 20, 2016 Participants: Patrick Bayou Joint Defense Group Bob Piniewski, PNL David Keith, AnchorQEA David Haury, AnchorQEA David Anderson, Glenn Springs Holdings Tony Saturni, Lubrizol Dan Kirk, Shell EPA Phil Allen Jon Rauscher Carlos Sanchez John Meyer Agenda 1. Meeting Objectives 2. Review Feasibility Study Alternatives 3. Discussion of JDG Proposal for Implementation of appropriate PCB and PEL-Q remediation strategy outlined in Alternative 3 while Addressing All Relevant and Applicable Regulations (ARARs) for mercury (Hg) and dioxin/furans (D/F) during a Pre-Design Investigation (PDI) 4. Next Steps July 20, 2016 Page 1 of 2 No. Topic #1 Meeting Objectives 1. Discuss proposed response to June 20, 2016 EPA letter 2. Develop Amenable Process for Project Advancement 3. JDG desire to continue the cooperative working arrangement with EPA and TCEQ to move the project forward #2 Review Feasibility Study 1. Reviewed Alternatives from the draft Feasibility Study (FS) 2. Reviewed details of Alternative #3 3. Discussed feasibility of MNR, Reactive Caps, ACBM and In Situ Treatment with Activated Carbon Discussion of Path Forward 1. The JDG and EPA discussed various administrative mechanisms to allow the implementation of appropriate PCB and PEL-Q remediation strategy outlined in Alternative 3.The JDG proposed that it would address the ARARs for Hg and D/F during the Pre-Design Investigation (PDI) for Alternative #3. 2. The EPA and JDG discussed the mechanism for bioavailability of Hg and how the limited (if any) bioavailability at the Site would potentially limit the concerns about Hg. 3. EPA discussed the potential for a Record of Decision (ROD), either Interim (to allow implementation of Alt #3) or Final with provision for ROD Amendment (to address D/F and Hg), as the administrative mechanism. 4. EPA further discussed the potential for an Administrative Order on Consent (AOC) to complete the PreDesign Investigation concurrent with ROD (Interim or Final) and Proposed Plan development Next Steps 1. EPA will: o Determine the most appropriate administrative mechanism(s) to allow the implementation of Alternative #3 while concurrently addressing the ARARs for Hg and D/F o Confirm that the July 20, 2016 meeting meets the 30-day response requirement contained the June 20, 2016 EPA letter to the JDG 2. JDG will: o Prepare and distribute meeting notes from July 20, 2016 o Prepare and submit a revised final FS by November 1, 2016 to include:  Listing of new ARARs for Hg and D/F State Water Quality Standards  Existing data set for D/F and Hg to evaluate current known distribution/concentrations  Discussion of sampling and evaluation methods to address Hg and D/F  Case studies supporting use of In Situ Treatment with Activated Carbon #3 #4 July 20, 2016 Major Points from Discussion Page 2 of 2 Patrick Bayou – Interim Final FS Comments Comments: 1. Section 4.1.3 Delineation of Natural Recovery Areas: The projection time to achieve the sediment remedial action objective (RAO) of 10 years is proposed to determine which areas are proposed for monitored natural recovery (MNR). The time frame would be less than 2 Five Year Review cycles and would appear to be a reasonable proposal. 2. Section 6.1.1 Overall Protection of Human Health and the Environment: I agree with the conclusion that Alternative 3 would achieve overall protection in the shortest time period. 3. Section 6.3 Summary of Comparative Evaluations: I agree with Alternative 3 having the highest ranking of all the alternatives. Alterative 1 (no action) doesn’t achieve the sediment RAO and Alternative 2 (MNR) will take an extended period of time to meet the sediment RAO. Alternatives 3 (capping & treatment and 4 (capping) will meet the sediment RAO in a reasonable time frame. Alternative 3 allows for more flexibility if additional actions are necessary to achieve the sediment RAO. 614 Magnolia Avenue Ocean Springs, Mississippi 39564 228.818.9626 March 2017 Response to Comments Project Name: Patrick Bayou Federal Superfund Site Commenter: Satya Dwivedula, P.E., Texas Commission on Environmental Quality Deliverable: October 2016 Draft Interim Final Feasibility Study Report Date Comments Received: January 25, 2017 No. Comments Responses 1 Section l mentions a meeting between the Potentially Responsible Parties (PRPs) and the United States Environmental Protection Agency (EPA) on July 20, 2016. The TCEQ requests this Section be revised to include the referenced agreements between the EPA and the PRPs during this meeting. The meeting summary will be provided as an attachment to the Feasibility Study Report (FS Report). 2 The fourth paragraph on page 21 under Section 2.6.2.3.1 states that mercury was not identified as a chemical of concern (COC) in baseline human and ecological risk assessments. Please note that mercury concentrations in fish and shellfish tissue were not evaluated under the human health risk assessment. The FS Report will be footnoted to indicate that the approved Baseline Human Health Risk Assessment Work Plan (Anchor QEA 2011) included a spatial analysis of Texas Department of State Health Services fish advisory tissue data. This U.S. Environmental Protection Agency (USEPA) approved analysis concluded that Patrick Bayou is not an incrementally significant source of mercury to fish in the Houston Ship Channel (HSC), and therefore, mercury is not a human health contaminant of potential concern with respect to the fish consumption pathway. Response to Comments Page 2 No. 3 Comments Responses Sections 2.6.2.4.1 and 3.4 discussed background concentrations of total PCBs and polychlorinated dibenzodioxin (PCDD)/polychlorinated dibenzofuran (PCDF) toxic equivalents (TEQs). These background concentrations were determined using the data collected between 2002 and 2009 for the Houston Ship Channel total daily maximum load (TMDL) studies. The 95% upper prediction limit (UPL) values calculated for total PCBs and PCDD/PCDF TEQ are significantly less stringent than their Texas Surface Water Quality Standards (TSWQS). The proposed background concentration for total polychlorinated biphenyls (PCBs) in surface water was calculated consistent with USEPA’s guidance and the request received from Texas Commission on Environmental Quality (TCEQ) in a letter dated January 12, 2016, that was sent in response to the Submittal of Response to EPA and TCEQ July 2015 Comments on Feasibility Study (September 22, 2015). The background concentration for polychlorinated dibenzodioxin (PCDD)/polychlorinated dibenzofuran (PCDF) toxic equivalents (TEQs) was also calculated using this same approach. Considering that the TMDL data is more than eight years old, the TCEQ suggests resampling and recalculation of representative background concentrations as part of the efforts planned for the design phase. The TCEQ also suggests that the high end statistical outliers not be included in UPL determination. 4 Section 3.1 specified that establishment of Remedial Action Objectives (RAOs) for mercury and PCDD/PCDF TEQ in surface water will be considered using the adaptive management framework during the design phase. As a component of the adaptive management framework, the TCEQ requests determination of sediment targets for PCBs, mercury, and PCDD/PCDF TEQ that will be protective of the determined surface water RAOs. 5 Section 3.1, page 34, stated that “The surface water RAO was developed in part to address ARARs and To Be Considered (TBC) requirements as directed by USEPA.” The TCEQ requests an elaboration of this statement for clarification. Please note that the sustainable fishery criteria is an ARAR for the site, and the TSWQS are not TBC requirements. Given the robust sampling performed as part of the TMDL program and widespread use of the data set by TCEQ and industry, resampling and recalculation of the background values for PCBs and PCDDs/PCDFs are not warranted. The TMDL dataset is representative of conditions within the HSC, and the proposed background numbers are appropriate for establishing remedial action objectives (RAOs). Sediment-based preliminary remediation goals protective of surface water are not necessary based on the site conceptual model. Partitioning of mercury, PCBs, and PCDD/PCDFs into porewater and discharge into surface water are considered the primary drivers for surface water conditions. Thus, porewater is the primary source media with respect to surface water RAOs. In addition, remedial technologies using activated carbon will sequester PCBs and PCDD/PCDFs, reducing porewater concentrations, but will not reduce overall bulk sediment concentrations. Assessment of porewater conditions is included in the pre-design phase and is expected to be included in the remedy performance and monitored natural recovery plans. This sentence will be edited to read, “The surface water RAO was developed to address ARARs as directed by USEPA.” Response to Comments Page 3 No. Comments Responses 6 In Section 3.1 on page 34, it appears that the statement on the reduction of total PCB concentrations in surface water was meant to be a part of the bulleted list. The TCEQ suggests revision of the language as necessary. The suggested edit will be made. 7 Section 4.2.1, page 54, provides information on existing institutional controls (ICs) for the site and the surrounding areas and lists additional ICs for consideration. Please specify the entities that are responsible for enforcing existing ICs and drafting, recording, and enforcing proposed future ICs. Additionally, Section 1.5 on page F-5 mentioned that state acceptance was not considered directly in the evaluation of ICs. In Appendix F, please state how and by whom ICs will be enforced. If enforcement of an IC involves the TCEQ, then the IC must comply with TCEQ rules. The members of the Patrick Bayou Joint Defense Group each have security measures in place for their facilities, including facility access restrictions and other security measures to comply with Homeland Security requirements. These measures are the responsibility of each facility. Typically, additional ICs, if required, are drafted, recorded, and enforced after a remedy has been implemented. Should additional ICs be required, they will be prepared and enforced in accordance with pertinent USEPA guidelines such as Institutional Controls: A Guide to Planning, Implementing, Maintaining, and Enforcing Institutional Controls at Contaminated Sites (USEPA 2012). 8 If remedial action objectives (RAOs) for mercury and PCDD/PCDF TEQs in the water column are necessary based on additional data collected during the design phase, the long term surface water and sediment monitoring discussed in Section 4.2.2 (Monitored Natural Recovery) may need to be modified to include these constituents. Agreed, with the exception of bulk sediment sampling to assess achievement of water quality standards for the reasons stated in the response to Comment 4. 9 Section 4.2.5 indicates that dredging may not be more effective than capping in areas with hard bottom or debris due to a higher potential for releases during dredging. However, in areas with soft sediment, dredging may be more appropriate. The TCEQ requests revision of the language to acknowledge this. As summarized in the FS Report, targeted sediment removal may be appropriate in certain situations, such as to accommodate capping materials, and to maintain hydraulic capacity; however, based on the evaluations in the Remedial Alternatives Technology Screening Report (Anchor QEA 2013), dredging is not considered a viable technology in Patrick Bayou on a large-scale basis. In addition to more general dredge residuals considerations, the subsurface profile of Site-specific COC concentrations increases with sediment depth, particularly in areas of soft sediment. Thus, the effectiveness of removal decreases with increasing depth, because the relative concentration of the post-dredge sediment surface and the relative concentration of dredge residuals increase with depth. As a result, removal alternatives are considered to present greater risk compared to containment alternatives, particularly in areas dominated by soft sediment. Response to Comments Page 4 No. Comments Responses 10 Section 4.2.5.1 states that the use of rigid controls as best management practices during any removal actions could cause upstream flooding. It is not clear if the flooding risk could be mitigated by dredging one side of the channel at a time, without completely restricting the flow. The TCEQ requests clarification. The engineering team evaluated the option of splitting the channel but determined that it was not viable due to the high flows that periodically drain through the bayou during storm events. 11 The second row in Table 3-2 on page 5 cites 30 Texas Administrative Code (TAC) Chapter 335, Subchapter P for information on potential ICs. Please note that the cited rule has its own procedures and does not require institutional controls. The rules concerning ICs are provided in 30 TAC§ 350.111. Please revise Table 3-2 to reflect this. Table 3-2 will be revised. 12 The fourth row in Table 3-2 on page 5 states that “The higher of the human health (fish) standard for PCBs (0.064 nanograms per liter [ng/L]) or background (8.2 ng/L) is to be considered as a remedial goal.” (Emphasis added.) Please note that the “fish only” criterion for human health protection in the TSWQS is 0.64 ng/L and not 0.064 ng/L (see 30 TAC § 307.6(d)(l)). The text will be corrected to indicate the “fish only” criterion for human health protection in the TSWQS is 0.64 ng/L (not 0.064 ng/L). Please revise Table 3-2 to state that the TSWQS of 0.64 ng/L is an ARAR for PCBs, and this value would remain as the RAO until a representative background concentration is recalculated in consultation with the TCEQ. In any case, please revise the comment to make clear that while TSWQS may be ARARs, they may not be included within any “to be considered” (TBC) category. The text will be revised to indicate that the TSWQS for PCBs is applicable and that USEPA has directed that RAOs be set to the TSWQS, or background, if higher. 13 Please revise Figure 4-2 to include the adaptive management process for mercury and PCDD/PCDF in addition to PCBs. The requested edit to Figure 4-2 will be made. 14 In Appendix C, the net present value for the remedial costs was calculated using a discount rate of 7%, with no assumed inflation in accordance with EPA guidance. This methodology may not provide realistic costs, considering that it would be difficult to achieve a 7% return on investment in today’s financial markets. We believe that a 4% discount rate along with 2% inflation would provide a more realistic cost estimate. The net effect of using EPA’s methodology of a 7% discount rate may understate the actual costs, especially for longer term remediation alternatives. Noted. Response to Comments Page 5 No. 15 Comments Responses Section 1 on Page F-2 states that an IC could be applied in the form of deed restrictions preventing dredging within Patrick Bayou. Please note that dredging may be necessary for remediation of portions of the Bayou. For example, excavation may be necessary between Station Nos. 40 and 50 in the wider portion of the bayou. Sediment in this area is soft and prone for erosion. An activated carbon cap may not hold the deeper sediment in this area, and it could get washed downstream along with the sediment during storm events. Also, to offset any loss of channel flood capacity from capping, Section 4.2.5 on page 62 recognized removal (dredging) as a possibility for the preferred remedial alternative. Please revise the language or provide an explanation. The ICs described in the FS Report would not apply to remedial actions but rather to other non-Comprehensive Environmental Response, Compensation, and Liability Act actions only.