THE SCIENCE OF I NTE RCO NTI ENTAL TERMINALS CONTINENTAL TANK FIRE Deer Park, TX March 18, 2019 Project #111356 1.0 Introduction On March 17, 2019 Intercontinental Terminals Company (ITC) requested that CTEH® conduct air monitoring in the surrounding community after a tank fire at the Deer Park, TX terminal. CTEH® arrived on-site on March 17, 2019 and began air monitoring operations. Activities were comprised of real-time air monitoring. This report summarizes air monitoring data collected from March 17, 2019 17:02 CDT to March 18, 2019 7:42 CDT. 2.0 Air Monitoring and Sampling Methods CTEH® developed and implemented an air sampling and analysis work plan (SAP) to document and quantify the release of fugitive emissions from the fire. All instrumentation was calibrated at least once per day or per manufacturer’s recommendations. Target analytes were measured as benzene, percent of the lower explosive limit (%LEL), Naphtha, 2.5-Micron particulate matter (PM2.5), toluene, volatile organic compounds (VOCs), and Xylene using handheld instruments such as RAE Systems MultiRAEs, TSI SidePak™ AM510 Aerosol Monitors and Gastec GV-100 pumps with chemical-specific colorimetric detection tubes. Hand-held air monitoring consisted of roaming air monitoring in the surrounding community. All handheld air monitoring was conducted in the breathing zone. 3.0 Air Monitoring Results Attachment A depicts the site location and hand-held monitoring locations for this reporting period. Table 1 summarizes the results for community hand-held air monitoring readings. Table 1: Community Hand-Held Real-Time Air Monitoring Results Instrument Gastec #121L Num Readings 6 Num Detections 0 Range¹ < 0.05 ppm UltraRAE 64 0 < 0.5 ppm Formaldehyde Gastec #91L 1 0 < 0.05 ppm Hexane Gastec #102L 2 0 < 1 ppm Gastec #4LL 3 0 < 0.1 ppm MultiRAE 53 0 < 0.1 ppm LEL MultiRAE 109 0 <1% Naphtha Gastec #106 21 0 < 0.1 mg/L Naphthalene Gastec #60 14 0 < 0.1 ppm Analyte Benzene Hydrogen Sulfide Page 1 Instrument Gastec #9L Num Readings 6 Num Detections 0 Range¹ < 0.1 ppm MultiRAE 32 0 < 0.1 ppm Oxygen MultiRAE 25 25 20.9 - 20.9 % PM2.5 AM510 44 44 0.007 - 0.043 mg/m3 Sulfur Dioxide MultiRAE 21 0 < 0.1 ppm Toluene Gastec #122L 12 0 < 0.5 ppm VOCs MultiRAE 137 1 0.1 ppm Xylene Gastec #123L 24 0 < 1 ppm Analyte Nitrogen Dioxide 1 Maximum detections preceded by the “<” symbol are considered non-detections below the limit of detection (LoD) value to the right. No detections during this reporting period exceeded the action levels as outline in the CTEH® SAP. One detection of VOCs was recorded approximately 5.5 miles WSW from the fire. 4.0 Weather Conditions Attachment B contains a wind rose depicting wind speed and direction for this reporting period. Data was acquired from the Texas Commission on Environmental Quality (TCEQ) Lynchburg Ferry meteorological station located on Tidal Road approximately 2 mi NNE of the fire. Page 2 Attachment A CTEH Monitoring Locations I Oi- Project: 111356 Incident Location . A Client: m: - City: Deerpark, TX ITC Tank Flre . . ounty. Harris - :G-a-rren ?d J. 34,. 3? Skhon Rd Cloverl ?ash; .Pasadena Spencer le' Muni Airporib . Scutl'l Houston Hobby Airport 5 Ellington H+.Fld 9? Alea Blid Project:111356 CTEH Hand?Held Real?Time Monitoring Locations 0 2.5 5 cnemc - Miles City: Deerpark, TX ITC Tank Fire Deerpark, TX County: Harris Lil, i i n-ili-u"lunl'u I 1 Int-u If; I HOME-trill} i i [Hill Hing! II, HO Hill OCCO 0 A .- og?b 0%%0 0030 0 ?0 Min. o@ 711'!- ?ill I 93 a) 06 thHliliHm?cml? d; Hrwl'ii "Lani ?mm? r1 Him-.?Iilw-i-t- Ill? 0 Legend earlan cl 7" ?Wm .. i a Fire Location ii-Z'wliw ?7 . . . . . Hand?Held Real?Time Monitoring Location COORDINATE SYSTEM: NAD 1983 UTM Zone 15N DATUM: North American 1983 I i I. i 7 LAST UPDATED: 3/18/2019 8:24:09 AM . . . . Project:111356 CTEH Hand?Held Real?Time Monitoring Locations (Benzene) 1.5 3 Client:lTC MlleS Deerparkl an Ire eerpar County:Harris :h i n-llI'L'H'nlv- In Ir- I Itl?I-?n 11,1 I?ll. WIHMII Suit?16416 . Deer Park Fire Location Jump? Tm; 8.11 Hand-711eal-Tlme Monitoring Location (BenzeneDetectlon (<0.05 ppm) COORDINATE SYSTEM: NAD 1983 UTM Zone 15N DATUM: North American 1983 LAST UPDATED: 3/18/2019 8:23:41 AM Project:111356 Client: Hand?Held Real?Time Monitoring Locations (H28) City: Deerpark, TX County: Harris ITC Tank Fire Deerparkif. Ciliai?ii'ielvieu?. 3 Jr?z? . ?y JJ-iil?it-i- Ciin if I, ?1 ii ii I i-ni i i ii! i ii ilily?i I ., i I in iiliill{Liberia Part. - 5 5'er -i Hui lwli Ii?i ,mpmxil'iuii i?illii ml i' i bi? l-t? It . i I Li. .inrl ia a [Beer {Es-South Hou 2.1.Fire Location 4'4 . . . - 3; Real-Time Monitoring Location (H28Detection ppm) COORDINATE SYSTEM: NAD 1983 UTM Zone 15N DATUM: North American 1983 LAST UPDATED: 3/18/2019 8:24:41 AM Project:111356 . . . . I CTEH Hand?Held Real?Time Monitoring Locations (A) LEL) 0 1.5 3 0mm Cit :Deer ark, TX ITC Tank Fire Deerpark, TX p. . County. Harris ~iwabliw {an} ?liilnl il, a "iHi-li I V- i'lJ-a HUI-W i. iri(CPO (3.630" . 4 i?ui Ch Fail}: 0 CR ((339 f'wuii'i vc 033 IH- ..nl CC v? or. 0 Hm?.th Saw H-?ziifini\h/Il i I ii 77 i'lluwiiuliiv i zilliuir ?'Hlil. i . irixlv-ii till-J- A i i - Fire Location 4' Real-Time Monitoring Location LEL) ,ii x-rii- I No Detection COORDINATE SYSTEM: NAD 1983 UTM Zone 15N DATUM: North American 1983 LAST UPDATED: 3/18/2019 8:27:39 AM . i Project:111356 CTEH Hand?Held Real?Time Monitoring Locations (Naphtha) 1 2 cnenmm ?:?:IMiles at ;Deer arkiTx ITC Tank Fire Deerpark, TX VC . ounty. Harris (33 Lal?mIllil'! 35J-tiimir- - - Lay/l iiHil - - 0 OC 1 i Q: 11Fire Location Real-Time Monitoring Location (Naphtha) .- a . 9 No Detection mg/L) LA.ST UPDATED: 3/18/2019 8:27:16 AM DATUM: North American 1983 COORDINATE SYSTEM: NAD 1983 UTM Zone 15N - i i Project:111356 CTEH Hand?Held Real?Time Monitoring Locations (N02) 0 1.5 3 Miles Cit :Deer ark] TX ITC Tank Fire Deerpark, TX Harris UL E: 5 l4' I .25: a" Flt?wear Jaclnto cmrulbx "Galena PartIw)? 'm pmeHuq '.mnuwm?l I I . 'f "7 ?lm-Mm! a 1.: I, mm 5c} Fun-a JL?na [We?:E-Inuth Hons-ton Flre Locatlon Real-Time Monitoring Location (N02Detection ppm) COORDINATE SYSTEM: NAD 1983 UTM Zone 15N DATUM: North American 1983 LAST UPDATED: 3/18/2019 8:25:07 AM - I i Project:111356 CTEH Hand?Held Real?Time Monitoring Locations (PIVIZB) 0 1-5 3Miles Client:lTC . Cit :Deer ark, TX ITC Tank Fire Deerpark, TX p. . County. Harris .3 1122Jamil-:- ert-?[ml1 - . Lulu] I ?xlr- H-?n 1 Mun-1m: l- I 5 I'Iwalena Park i In. . 4 . 1u'l E'Jgd?eud Ifl'w-rbnl . . . 7 F?amdena 5' [r 4?80Yogi i 'r I . ?9va kl I lv' T. n- . bouth . . .0. A a Fire Location . Concentration (mg/m3) I - ml?. 3.. r; . .1 5? 0.001?0.138 ,l a/ 5,7 - ul 4,0 0.139 0.351 . 0 II m'xr 9 f, ..1 - . COORDINATE SYSTEM: NAD 1983 UTM Zone 15N DATUM: North. American 1983 LAST UPDATED: 3/18/2019 8:25:45 AM . i Project:111356 CTEH Hand?Held Real?Time Monitoring Locations (Toluene) 1.5 3 Ciient: TC . Cit :Deer ark, TX ITC Tank Fire Deerpark, TX VC . ounty. Harris - . . .1, i- ., a "Iu.~r i' 1-111 "saute?11:1 0 Deer F'Jl'l?. H1 Si'1?11. I i 1 I '21- ~111 ;.1w 3 I I ?ItFire Location Real-Time Monitoring Location (Toluene) No Detection ppm) .11 l? DATUM: North American 1983 LAST UPDATED: 3/18/2019 8:25:55 AM COORDINATE SYSTEM: NAD 1983 UTM Zone 15N . i Project:111356 CTEH Hand?Held Real?Time Monitoring Locations (VOCs) 0 1.5 3 cum;ch . _:?:IMiles C?t k, TX ITC Tank Fire DeerparkIon nil-- "It, I 1' :iI'l I "dblw [?ll a mil"- 3' 311812019 3:11?1:41 AM 0 ii? l'lt Imbl I 'Iilil?ll LOI1 x. 636 C- (35(3) (29% ?c Hp] F'Cii?a'j'z?lkj C: i?HuuSun) ringli?c'l le'j 0. 7 Q: H'n??tm' q? i??v Ii ?'ilili-. [~71 A'l?l i a Fire Location 0 Real-Time Monitoring Location (VOCs) NO Detection 0.1 ppm) wllill.? ,1 I n. 0 Detection LAST UPDATED: 3/18/2019 8:28:25 AM DATUM: North American 1983 COORDINATE SYSTEM: NAD 1983 UTM Zone 15N . i Project:111356 CTEH Hand?Held Real?Time Monitoring Locations (Xylene) 1 2 0mm :Deer ark] ITC Tank Fire Deerpark, TX VCOM: Harris V: .l".1u ?i 'VI-ifvlm Fill}- cf 5 ?Mini H. f. "iHr-F'cmacieria E. . .- . F-Jll'. Itwtitll Hull-Jun i 71w). Farm Ht??i?ini? ley I 'til F-l nilun?i- 'leJIIlr? 7: ?it? .4 --IinliFire Location A Real-Time Monitoring Location (Xylene) 0- No Detection ppm) (- LAST UPDATED: 3/18/2019 8:28:02 AM DATUM: North American 1983 COORDINATE SYSTEM: NAD 1983 UTM Zone 15N Attachment Meteorological Conditions Oi- WIND ROSE PLOT: DISPLAY: Station #Lynchburg Ferry Wind Speed Direction (blowing from) NORTH 13.6% 10.9% 8.16% 5.44% 2.72% WEST EAST WIND SPEED (Knots) >= 11.66 5.00 - 11.66 4.00 - 5.00 3.00 - 4.00 SOUTH 2.00 - 3.00 1.00 - 2.00 Calms: 6.67% COMMENTS: DATA PERIOD: COMPANY NAME: Start Date: 3/17/2019 - 16:00 End Date: 3/18/2019 - 06:00 MODELER: WRPLOT View - Lakes Environmental Software CALM WINDS: TOTAL COUNT: 6.67% 15 hrs. AVG. WIND SPEED: DATE: 2.40 Knots 3/18/2019 PROJECT NO.: 111356