Version: 1.2 Revision Date: 04/10/2019 SAFETY DATA SHEET 1. Identification Material name: TREMFIX A.F. 5 US GL Material: 350715 805 Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S. Roofing 3735 Green Road Beachwood OH 44122 US Contact person: Telephone: Emergency telephone number: EH&S Department 216-292-5000 1-800-424-9300 (US); 1-613-996-6666 (Canada) 2. Hazard(s) identification Hazard Classification Health Hazards Skin sensitizer Germ Cell Mutagenicity Carcinogenicity Toxic to reproduction Unknown toxicity - Health Acute toxicity, oral Acute toxicity, dermal Acute toxicity, inhalation, vapor Acute toxicity, inhalation, dust or mist Environmental Hazards Acute hazards to the aquatic environment Unknown toxicity - Environment Acute hazards to the aquatic environment Chronic hazards to the aquatic environment Category 1 Category 1B Category 1A Category 1B 18.96 % 18.97 % 100 % 100 % Category 1 94.5 % 100 % Label Elements 1/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Hazard Symbol: Signal Word: Danger Hazard Statement: May cause an allergic skin reaction. May cause genetic defects. May cause cancer. May damage fertility or the unborn child. Very toxic to aquatic life. Precautionary Statements Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Avoid release to the environment. Response: IF ON SKIN: Wash with plenty of water/D If skin irritation or rash occurs: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. Specific treatment (see on this label). Wash contaminated clothing before reuse. Collect spillage. Storage: Store locked up. Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Hazard(s) not otherwise classified (HNOC): None. 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%)* 2/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Coal tar pitch 65996-93-2 50 - <100% Calcium Carbonate (Limestone) 1317-65-3 5 - <10% Cellulose 9004-34-6 1 - <5% Creosote 8001-58-9 1 - <5% Phenanthrene 85-01-8 1 - <5% Fluorathene 206-44-0 1 - <5% Clay 1332-58-7 0.1 - <1% Naphthalene 91-20-3 0.1 - <1% Anthracene 120-12-7 0.001 - <1% Indeno[1,2,3-cd]pyrene 193-39-5 0.1 - <1% Benzo(a)anthracene 56-55-3 0.1 - <1% Chrysene 218-01-9 0.1 - <1% Benzo(a)pyrene 50-32-8 0.3 - <1% Acenaphthene 83-32-9 0.1 - <1% Dibenzofuran 132-64-9 0.1 - <1% Benzo(b)fluoranthene/benzo[e] acefenantrileno 205-99-2 0.1 - <1% Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 0.1 - <1% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Description of necessary first-aid measures Inhalation: Move to fresh air. Skin Contact: Get medical attention if symptoms occur. Destroy or thoroughly clean contaminated shoes. Immediately remove contaminated clothing and shoes and wash skin with soap and plenty of water. If skin irritation or an allergic skin reaction develops, get medical attention. Eye contact: Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention. Ingestion: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Personal Protection for Firstaid Responders: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Most important symptoms/effects, acute and delayed Symptoms: May cause skin and eye irritation. Hazards: No data available. Indication of immediate medical attention and special treatment needed Treatment: Symptoms may be delayed. 5. Fire-fighting measures 3/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 General Fire Hazards: No unusual fire or explosion hazards noted. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical: During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: No data available. Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: See Section 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away. Accidental release measures: In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Methods and material for containment and cleaning up: Dam and absorb spillages with sand, earth or other non-combustible material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. Avoid release to the environment. 7. Handling and storage Handling Technical measures (e.g. Local and general ventilation): Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of vapors and mist. Mechanical ventilation or local exhaust ventilation may be required. Safe handling advice: Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective equipment as required. Avoid contact with eyes, skin, and clothing. Wash hands thoroughly after handling.Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Contact avoidance measures: No data available. 4/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and immediately after handling the product. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Contaminated work clothing should not be allowed out of the workplace. Avoid contact with skin. Storage Safe storage conditions: Store locked up. Safe packaging materials: No data available. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity Type Exposure Limit Values Coal tar pitch - Aerosol. - as benzene solubles Coal tar pitch TWA 0.2 mg/m3 US. ACGIH Threshold Limit Values (2011) PEL 0.2 mg/m3 Calcium Carbonate (Limestone) - Total dust. Calcium Carbonate (Limestone) - Respirable fraction. Cellulose Cellulose - Total dust. PEL 15 mg/m3 PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA PEL 10 mg/m3 15 mg/m3 Cellulose - Respirable fraction. Clay - Respirable fraction. PEL 5 mg/m3 TWA PEL 2 mg/m3 5 mg/m3 Clay - Total dust. PEL 15 mg/m3 TWA TWA 50 millions of particles per cubic foot of air 15 millions of particles per cubic foot of air 5 mg/m3 Clay - Total dust. TWA 15 mg/m3 Naphthalene TWA PEL Clay - Respirable fraction. Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction. Crystalline Silica (Quartz)/ Silica Sand - Respirable dust. Crystalline Silica (Quartz)/ Silica Sand - Respirable dust. Crystalline Silica (Quartz)/ Silica Sand - Respirable. TWA 10 ppm 10 ppm 50 mg/m3 TWA 0.025 mg/m3 TWA 0.05 mg/m3 OSHA_AC T PEL 0.025 mg/m3 TWA 2.4 millions of particles per cubic foot 0.05 mg/m3 Source US. ACGIH Threshold Limit Values (2011) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) US. ACGIH Threshold Limit Values (2011) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016) US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016) US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016) US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016) US. ACGIH Threshold Limit Values (2011) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) US. ACGIH Threshold Limit Values (2011) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) (03 2016) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) (03 2016) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (03 2016) US. OSHA Table Z-3 (29 CFR 1910.1000) (2000) 5/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 of air 0.1 mg/m3 TWA Chemical name Type Exposure Limit Values Coal tar pitch - Aerosol. - as benzene solubles TWA 0.2 mg/m3 Coal tar pitch - Aerosol. - as benzene solubles Coal tar pitch - as benzene solubles TWA 0.2 mg/m3 TWA 0.2 mg/m3 Calcium Carbonate (Limestone) - Total dust. STEL 20 mg/m3 TWA 10 mg/m3 Calcium Carbonate (Limestone) - Respirable fraction. TWA 3 mg/m3 Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Cellulose - Respirable fraction. TWA 3 mg/m3 Cellulose - Total dust. TWA 10 mg/m3 Cellulose TWA 10 mg/m3 Cellulose - Total dust. TWA 10 mg/m3 Naphthalene STEL 15 ppm TWA 10 ppm Naphthalene TWA 10 ppm Naphthalene TWA 10 ppm 52 mg/m3 STEL 15 ppm 79 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (2000) Source Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010) Canada. Quebec OELs. (Ministry of Labor Regulation Respecting the Quality of the Work Environment) (09 2017) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. Quebec OELs. (Ministry of Labor Regulation Respecting the Quality of the Work Environment) (09 2017) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010) Canada. Quebec OELs. (Ministry of Labor Regulation Respecting the Quality of the Work Environment) (09 2017) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010) Canada. Quebec OELs. (Ministry of Labor Regulation Respecting the Quality of the Work Environment) (09 2017) Canada. Quebec OELs. (Ministry of Labor Regulation Respecting the Quality of the Work Environment) (09 2017) 6/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Benzo(a)pyrene TWA 0.005 mg/m3 Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction. TWA 0.025 mg/m3 Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction. Crystalline Silica (Quartz)/ Silica Sand - Respirable dust. TWA 0.10 mg/m3 TWA 0.1 mg/m3 Exposure guidelines Naphthalene Appropriate Engineering Controls Canada. Quebec OELs. (Ministry of Labor Regulation Respecting the Quality of the Work Environment) (09 2017) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (06 2015) Canada. Quebec OELs. (Ministry of Labor Regulation Respecting the Quality of the Work Environment) (09 2017) US. ACGIH Threshold Limit Values Can be absorbed through the skin. Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of vapors and mist. Mechanical ventilation or local exhaust ventilation may be required. Individual protection measures, such as personal protective equipment General information: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Supplementary local exhaust ventilation, closed systems, or respiratory and eye protection may be needed in special circumstances, such as poorly ventilated spaces, heating, evaporation of liquids from large surfaces, spraying of mists, mechanical generation of dusts, drying of solids, etc. Eye/face protection: Wear safety glasses with side shields (or goggles). Skin Protection Hand Protection: Use suitable protective gloves if risk of skin contact. Other: Wear suitable protective clothing. Wear chemical-resistant gloves, footwear, and protective clothing appropriate for the risk of exposure. Contact health and safety professional or manufacturer for specific information. Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and immediately after handling the product. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Contaminated work clothing should not be allowed out of the workplace. Avoid contact with skin. 9. Physical and chemical properties Appearance Physical state: Form: Color: Odor: liquid liquid Black Aromatic 7/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Odor threshold: No data available. pH: No data available. Melting point/freezing point: No data available. Initial boiling point and boiling range: 150 °C 302 °F Flash Point: > 93 °C > 199 °F Evaporation rate: Slower than Ether Flammability (solid, gas): No Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): No data available. Flammability limit - lower (%): No data available. Explosive limit - upper (%): No data available. Explosive limit - lower (%): No data available. Vapor pressure: No data available. Vapor density: Vapors are heavier than air and may travel along the floor and in the bottom of containers. Relative density: 1.26 Solubility(ies) Solubility in water: Practically Insoluble Solubility (other): No data available. Partition coefficient (n-octanol/water): No data available. Auto-ignition temperature: Decomposition temperature: Viscosity: No data available. No data available. No data available. 10. Stability and reactivity Reactivity: No data available. Chemical Stability: Material is stable under normal conditions. Possibility of hazardous reactions: No data available. Conditions to avoid: Avoid heat or contamination. Incompatible Materials: Avoid contact with oxidizing agents (e.g. nitric acid, peroxides and chromates). Hazardous Decomposition Products: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes. Skin Contact: May be harmful in contact with skin. May cause an allergic skin reaction. 8/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Eye contact: Eye contact is possible and should be avoided. Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise. Symptoms related to the physical, chemical and toxicological characteristics Inhalation: No data available. Skin Contact: No data available. Eye contact: No data available. Ingestion: No data available. Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: Dermal Product: 725.00 mg/kg ATEmix : 16,695.42 mg/kg ATEmix: 2,186.07 mg/kg Inhalation Product: Specified substance(s): Cellulose Clay LC 50 (Rabbit): 20.1 mg/l LC 50 (Rat): > 20 mg/l Repeated dose toxicity Product: No data available. Skin Corrosion/Irritation Product: No data available. Specified substance(s): Coal tar pitch in vivo (Rabbit): Not irritant Naphthalene in vivo (Rabbit): Not irritant Anthracene in vivo (Rabbit): Not irritant Serious Eye Damage/Eye Irritation Product: No data available. Specified substance(s): 9/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Coal tar pitch Rabbit, 1 hrs: Not irritating Anthracene Rabbit, 24 hrs: Not irritating Respiratory or Skin Sensitization Product: No data available. Carcinogenicity Product: No data available. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Coal tar pitch Overall evaluation: Carcinogenic to humans. Creosote Overall evaluation: Probably carcinogenic to humans. Naphthalene Overall evaluation: Possibly carcinogenic to humans. Indeno[1,2,3cd]pyrene Overall evaluation: Possibly carcinogenic to humans. Benzo(a)anthracen e Overall evaluation: Possibly carcinogenic to humans. Chrysene Overall evaluation: Possibly carcinogenic to humans. Benzo(a)pyrene Overall evaluation: Carcinogenic to humans. Benzo(b)fluoranthe ne/benzo[e]acefena ntrileno Overall evaluation: Possibly carcinogenic to humans. Crystalline Silica (Quartz)/ Silica Sand Overall evaluation: Carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens: Known To Be Human Carcinogen. Coal tar pitch Naphthalene Reasonably Anticipated to be a Human Carcinogen. Reasonably Anticipated to be a Human Carcinogen. Indeno[1,2,3cd]pyrene Benzo(a)anthracen Reasonably Anticipated to be a Human Carcinogen. e Benzo(a)pyrene Reasonably Anticipated to be a Human Carcinogen. Benzo(b)fluoranthe Reasonably Anticipated to be a Human Carcinogen. ne/benzo[e]acefena ntrileno Crystalline Silica Known To Be Human Carcinogen. (Quartz)/ Silica Sand 10/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Crystalline Silica Cancer (Quartz)/ Silica Sand Germ Cell Mutagenicity In vitro Product: No data available. In vivo Product: No data available. Reproductive toxicity Product: May damage fertility or the unborn child. Specific Target Organ Toxicity - Single Exposure Product: No data available. Specific Target Organ Toxicity - Repeated Exposure Product: No data available. Aspiration Hazard Product: Other effects: No data available. No data available. 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Product: Specified substance(s): Phenanthrene No data available. LC 50 (Rainbow trout,donaldson trout (Oncorhynchus mykiss), 96 h): 3.2 mg/l Mortality Fluorathene LC 50 (Fathead minnow (Pimephales promelas), 96 h): 0.074 - 0.113 mg/l Mortality Naphthalene LC 50 (Fathead minnow (Pimephales promelas), 96 h): 4.9 mg/l Mortality Anthracene LC 50 (Bluegill (Lepomis macrochirus), 96 h): 0.00594 - 0.00781 mg/l Mortality 11/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Acenaphthene LC 50 (Fathead minnow (Pimephales promelas), 96 h): 0.52 - 0.71 mg/l Mortality Dibenzofuran LC 50 (Sheepshead minnow (Cyprinodon variegatus), 48 h): > 3.2 mg/l Mortality LC 50 (Sheepshead minnow (Cyprinodon variegatus), 72 h): 2.6 - 4.2 mg/l Mortality LC 50 (Fathead minnow (Pimephales promelas), 96 h): 0.84 - 1.31 mg/l Mortality LC 50 (Fathead minnow (Pimephales promelas), 96 h): 1.04 - 1.25 mg/l Mortality LC 50 (Fathead minnow (Pimephales promelas), 96 h): 1.62 - 1.95 mg/l Mortality Aquatic Invertebrates Product: Specified substance(s): Phenanthrene No data available. LC 50 (Water flea (Daphnia magna), 48 h): 0.59 - 0.84 mg/l Mortality Fluorathene LC 50 (Water flea (Daphnia magna), 24 h): 1,000 - 1,600 mg/l Mortality EC 50 (Water flea (Daphnia magna), 7 d): > 0.01 - 0.012 mg/l Intoxication LC 50 (Purple-spined sea urchin (Arbacia punctulata), 48 h): > 0.127 mg/l Mortality EC 50 (Water flea (Daphnia magna), 7 d): > 0.01 - 0.015 mg/l Intoxication LC 50 (Purple-spined sea urchin (Arbacia punctulata), 96 h): > 0.033 mg/l Mortality Naphthalene LC 50 (Water flea (Daphnia magna), 48 h): 3.4 mg/l Mortality Anthracene EC 50 (Water flea (Daphnia magna), 24 h): 0.189 - 0.236 mg/l Intoxication LC 50 (Pacific oyster (Crassostrea gigas), 48 h): > 5 mg/l Mortality LC 50 (Clam (Mulinia lateralis), 96 h): > 13.3 mg/l Mortality Benzo(a)anthracene LC 50 (Water flea (Daphnia pulex), 96 h): 0.01 mg/l Mortality Chrysene LC 50 (Polychaete worm (Nereis arenaceodentata), 96 h): < 1 mg/l Mortality Benzo(a)pyrene EC 50 (Water flea (Daphnia magna), 24 h): 0.032 - 0.049 mg/l Intoxication LC 50 (Scud (Gammarus duebeni), 48 h): < 150 mg/l Mortality LC 50 (Polychaete worm (Nereis arenaceodentata), 96 h): < 1 mg/l Mortality Acenaphthene LC 50 (Water flea (Daphnia magna), 24 h): > 280 mg/l Mortality LC 50 (Snail (Aplexa hypnorum), 96 h): > 2.04 mg/l Mortality Dibenzofuran LC 50 (Water flea (Daphnia magna), 24 h): 4.4 - 13 mg/l Mortality Benzo(b)fluoranthene/be nzo[e]acefenantrileno EC 50 (Water flea (Daphnia magna), 24 h): > 1.024 mg/l Intoxication Chronic hazards to the aquatic environment: Fish Product: No data available. 12/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Specified substance(s): Coal tar pitch LC 50 (Danio rerio, 42 d): > 4 µg/l Read-across from supporting substance (structural analogue or surrogate), Key study NOAEL (Danio rerio, 42 d): 4 µg/l Read-across from supporting substance (structural analogue or surrogate), Key study Aquatic Invertebrates Product: No data available. Toxicity to Aquatic Plants Product: No data available. Persistence and Degradability Biodegradation Product: No data available. BOD/COD Ratio Product: No data available. Bioaccumulative potential Bioconcentration Factor (BCF) Product: No data available. Specified substance(s): Phenanthrene Water flea (Daphnia pulex), Bioconcentration Factor (BCF): 325 (Static) Fluorathene Water flea (Daphnia magna), Bioconcentration Factor (BCF): 1,741.8 (Static) Naphthalene Rainbow trout,donaldson trout (Oncorhynchus mykiss), Bioconcentration Factor (BCF): 13,000 (Flow through) Anthracene Green algae (Chlorella fusca vacuolata), Bioconcentration Factor (BCF): 7,800 (Static) Benzo(a)anthracene Water flea (Daphnia pulex), Bioconcentration Factor (BCF): 10,109 (Static) Chrysene Water flea (Daphnia magna), Bioconcentration Factor (BCF): 6,088.4 (Static) Benzo(a)pyrene Water flea (Daphnia pulex), Bioconcentration Factor (BCF): 2,720 (Static) Acenaphthene Bluegill (Lepomis macrochirus), Bioconcentration Factor (BCF): 387 (Flow through) Benzo(b)fluoranthene/be nzo[e]acefenantrileno Mussel (Mytilus edulis planulatus), Bioconcentration Factor (BCF): 5,200,000 (Lentic - static water system without measurable flow rate (e.g. lake)) Bioconcentration factor calculated using dry weight tissue conc Partition Coefficient n-octanol / water (log Kow) Product: No data available. 13/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Specified substance(s): Creosote Log Kow: 1.0 Phenanthrene Log Kow: 4.57 Fluorathene Log Kow: 5.16 Naphthalene Log Kow: 3.30 Anthracene Log Kow: 4.45 Benzo(a)anthracene Log Kow: 5.79 Chrysene Log Kow: 5.73 Benzo(a)pyrene Log Kow: 5.97 Acenaphthene Log Kow: 3.92 Dibenzofuran Log Kow: 4.12 Benzo(b)fluoranthene/be nzo[e]acefenantrileno Log Kow: 6.60 Mobility in soil: No data available. Other adverse effects: Very toxic to aquatic organisms. 13. Disposal considerations Disposal methods: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Contaminated Packaging: No data available. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated IMDG: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Coal Tar), 9, PG III, MARINE POLLUTANT 14/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Further Information: The above shipping description may not be accurate for all container sizes and all modes of transportation. Please refer to Bill of Lading. 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities. US. Toxic Substances Control Act (TSCA) Section 5(a)(2) Final Significant New Use Rules (SNURs) (40 CFR 721, Subpt E) None present or none present in regulated quantities. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Chemical Identity Crystalline Silica (Quartz)/ Silica Sand OSHA hazard(s) kidney effects lung effects immune system effects Cancer CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Creosote Fluorathene Phenanthrene Naphthalene Anthracene Indeno[1,2,3-cd]pyrene Benzo(a)anthracene Chrysene Benzo(a)pyrene Acenaphthene Dibenzofuran Benzo(b)fluoranthene/benzo[e]acefenantrileno Biphenyl Dibenz(a,h)anthracene Pyrene Acenaphthylene Fluorene Quinoline Reportable quantity 1 lbs. 100 lbs. 5000 lbs. 100 lbs. 5000 lbs. 100 lbs. 10 lbs. 100 lbs. 1 lbs. 100 lbs. 100 lbs. 1 lbs. 100 lbs. 1 lbs. 5000 lbs. 5000 lbs. 5000 lbs. 5000 lbs. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate (Acute) Health Hazards Delayed (Chronic) Health Hazard Skin sensitizer Germ Cell Mutagenicity Carcinogenicity Toxic to reproduction 15/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 SARA 302 Extremely Hazardous Substance Reportable quantity Chemical Identity Pyrene 5000 lbs. SARA 304 Emergency Release Notification Chemical Identity Creosote Fluorathene Phenanthrene Naphthalene Anthracene Indeno[1,2,3-cd]pyrene Benzo(a)anthracene Chrysene Benzo(a)pyrene Acenaphthene Dibenzofuran Benzo(b)fluoranthene/benzo[e]acefenantrileno Biphenyl Dibenz(a,h)anthracene Pyrene Acenaphthylene Fluorene Quinoline Threshold Planning Quantity - -- - Reportable quantity 1 lbs. 100 lbs. 5000 lbs. 100 lbs. 5000 lbs. 100 lbs. 10 lbs. 100 lbs. 1 lbs. 100 lbs. 100 lbs. 1 lbs. 100 lbs. 1 lbs. 5000 lbs. 5000 lbs. 5000 lbs. 5000 lbs. 16/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 SARA 311/312 Hazardous Chemical Chemical Identity Pyrene Coal tar pitch Calcium Carbonate (Limestone) Cellulose Creosote Phenanthrene Fluorathene Clay Naphthalene Anthracene Indeno[1,2,3-cd]pyrene Benzo(a)anthracene Chrysene Benzo(a)pyrene Acenaphthene Dibenzofuran Benzo(b)fluoranthene/benzo[e]acefenantrileno Crystalline Silica (Quartz)/ Silica Sand Threshold Planning Quantity 500lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs 10000 lbs SARA 313 (TRI Reporting) Chemical Identity Creosote Fluorathene Phenanthrene Naphthalene Indeno[1,2,3-cd]pyrene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene/benzo[e]acefenantrileno Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) None present or none present in regulated quantities. US State Regulations US. California Proposition 65 WARNING Cancer - www.P65Warnings.ca.gov 17/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 US. New Jersey Worker and Community Right-to-Know Act Chemical Identity Coal tar pitch Calcium Carbonate (Limestone) Cellulose Creosote Fluorathene Phenanthrene Naphthalene Indeno[1,2,3-cd]pyrene Benzo(a)anthracene Chrysene Benzo(a)pyrene Benzo(b)fluoranthene/benzo[e]acefenantrileno Crystalline Silica (Quartz)/ Silica Sand US. Massachusetts RTK - Substance List Chemical Identity Coal tar pitch Calcium Carbonate (Limestone) Cellulose Creosote Fluorathene Phenanthrene Indeno[1,2,3-cd]pyrene Benzo(a)anthracene Chrysene Benzo(a)pyrene Benzo(b)fluoranthene/benzo[e]acefenantrileno Crystalline Silica (Quartz)/ Silica Sand Dibenz(a,h)anthracene Pyrene US. Pennsylvania RTK - Hazardous Substances Chemical Identity Coal tar pitch Calcium Carbonate (Limestone) Cellulose Creosote Fluorathene Phenanthrene Indeno[1,2,3-cd]pyrene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene/benzo[e]acefenantrileno US. Rhode Island RTK Chemical Identity Calcium Carbonate (Limestone) Cellulose International regulations 18/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Montreal protocol Not applicable Stockholm convention Not applicable Rotterdam convention Not applicable Kyoto protocol Not applicable VOC: Regulatory VOC (less water and exempt solvent) VOC Method 310 : 299 g/l : 24.00 % 19/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 Inventory Status: Australia AICS: One or more components in this product are not listed on or exempt from the Inventory. Canada DSL Inventory List: One or more components in this product are not listed on or exempt from the Inventory. EINECS, ELINCS or NLP: One or more components in this product are not listed on or exempt from the Inventory. Japan (ENCS) List: One or more components in this product are not listed on or exempt from the Inventory. China Inv. Existing Chemical Substances: One or more components in this product are not listed on or exempt from the Inventory. Korea Existing Chemicals Inv. (KECI): One or more components in this product are not listed on or exempt from the Inventory. Canada NDSL Inventory: One or more components in this product are not listed on or exempt from the Inventory. Philippines PICCS: One or more components in this product are not listed on or exempt from the Inventory. US TSCA Inventory: One or more components in this product are not listed on or exempt from the Inventory. New Zealand Inventory of Chemicals: One or more components in this product are not listed on or exempt from the Inventory. Japan ISHL Listing: One or more components in this product are not listed on or exempt from the Inventory. Japan Pharmacopoeia Listing: One or more components in this product are not listed on or exempt from the Inventory. Mexico INSQ: One or more components in this product are not listed on or exempt from the Inventory. Ontario Inventory: One or more components in this product are not listed on or exempt from the Inventory. Taiwan Chemical Substance Inventory: One or more components in this product are not listed on or exempt from the Inventory. 20/21 800000051301 Version: 1.2 Revision Date: 04/10/2019 16.Other information, including date of preparation or last revision Revision Date: 04/10/2019 Version #: 1.2 Further Information: No data available. Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. 21/21 800000051301