2540-FM-BWM0158 Rev. 1012010 COMMONWEALTH OF Date Prepared/Revised DEPARTMENT OF ENVIRONMENTAL PROTECTION 03/26/2018 . gr? BUREAU OF WASTE MANAGEMENT DEPARTMENT OF ENVIRONMENTAL PROTECTION Date Received FORM 50 MUNICIPAL WASTE LANDFILL LEACHATE ANALYSES This form must be futly and accurately completed. All required information must be typed or legibly printed in the spaces provided. If additional space is necessary, identify each attached sheet as Form 50, reference the item number and identify the date prepared. The ?date prepared/revised" on any attached sheets needs to match the ?date prepared/revised? on this page. General References: Section 273.255(d) and and 273.276(a) Federal Re ulations Subtitle 258 54 and Appendix to Part 258 Applicant/permittee Tervita - Rostraver Township Sanitary Landfiit Site Name Tervita - Rostraver Township Sanitary Landfill Facility ID (as issued by DEP) 100277, Facility Name: Westmoreland Waste inc. Sampling Point identification (LEACHATE) Westmoreland Municipality: Rostraver Twp. Location: County Sampling Point: Latitude: Longitude: 0 Sampling Method: Pumped I: Bailed Grab Sample Field Filtered (must be 0.45 micron)? I: Yes No 03/01/18 S. Eydlin 10:00 Sample Date (mm/dd/yy) Sample Collection Time: Sample Collector?s Name: Sample Collector?s THG GEOPWSECS Geochemical Testing Laboratory(ies) Performing Analysis: Laboratory Certification Number(s): 56430306 61803087-001 Final Lab Analysis Compietion Date: 03/12/2018 Lab Sample Number(s): Were Any Holding Times Exceeded? Yes No if Yes, please explain in comments field. Name/Affiliation of Person Who Filled Out Form GGOChemica' Testing Comments: Moderately turbid - Light brown Strong musty odor. 2540-FM-BWM0158 Rev. 1012010 COMMONWEALTH OF DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM 50 Monitoring Point No. NIH-1 QUARTERLY MUNICIPAL WASTE Sample Date 03/01/18 . . - LANDFILL LD. No. 100277 LEACHATE ANALYSES For new facilities and cells as well as existing facilities which were permitted and which received waste after April 9, 1988, discharge flow volume from leachate collection shall be measured daily Discharge flow volume from the detection zone shall be estimated weekly Form 50 is due quarterly after the flow of leach ate from the collection system has started. For facilities or cells which have received no waste since April 9, 1988, detection zone monitoring will meet permit/closure requirements. FLOW FACTOR LEACHATE DISCHARGE DETECTION ZONE DISCHARGE Volume (average gpd) 141,000 Area Drained (acres) 44.6 Ratio (gallons/acre/day) 3,161.4 Once leachate flow begins from a leachate collection system, leachate discharge wiil be analyzed quarterly for all analytes listed betow. In the leachate detection zone, any fluid found in any detection zone monitoring point must be sampled during the initial four quarters for the leachate indicator parameters (designated by below) to establish a- baseline ?uid composition. Thereafter, any fluid detected in each monitoring point in the leachate detection zone must be sampled annually for the leachate indicator parameters. Quarterly sampling of the ?uid in any detection zone monitoring point for leachate indicator parameters is required only when the quarterly ?ow at that monitoring point exceeds 10 gallons per acre per day (weekly average for the quarter) for the celi(s) served by that monitoring point. If the indicator analytes con?rm leachate contamination in the detection zone, the fluid will be analyzed initially within 30 days and thereafter annuaiiy for all analytes listed below. When MCL's (where established) of any detection zone - analytes on this form are exceeded, annual groundwater monitoring must include the Subtitle detection zone add-on . list analytes found on Form 19. . a a? . - Please indicate detection limit if analyte is not detected. . 2 DETECTION ANALYSIS ANALYTE LEACHATE ZONE METHOD (mg/l unless otherwise indicated) DISCHARGET NUMBER Alkalinity, Total [3 1820 1067-0t Ammonia-Nitrogen 332 EPA 350.1 Bicarbonate (as - 1810 SM 4500-002 0 Calcium, Total 2001? EPA 200.7 I: Chemical Oxygen Demand 960 HACH 8000 Chloride (Cl) . 1800 EPA 300.0 Magnesium, Total 114 EPA 200.7 pH, Field, (Standard Units) . pH, Laboratory, (Standard Units) 754 SM 4500+;+ i3 10.* Potassium, Total 205 EPA 200.7 113? Specific Conductance, Field (micromhos/cm) I 12.* Specific Conductance, Laboratory (micromhos/cm) 9370 EPA 120.1 13.* Sodium, Total 1090 EPA 200.7 I . 14.* Sulfate, Total 50 EPA 300.0 -. 153* Total Organic Carbon (TOC) 247 SM 5310 i 16. Fluoride 5.8 EPA 3000 17. Iron, Total 13.1 EPA 200.7- 18. Manganese, Total 3.26 A EPA 200.7. 19. Nitrate-Nitrogen 0.08 EPA 353.2 i+ga 254D-FM-BWM0158 Rev. 10l2010 Monitoring Point No. NIH-1 (LEACHAT E) . FORM 50 Sample Date 03/01/18 ID. No. 100277 DETECTION ANALYSIS LEACHATE ZONE METHOD ANALYTE DISCHARGET DISCHARGET NUMBER 20. Phenolics, Total (mg/l) 0.071 EPA 420.4 21. Totai Dissolved Solids (mg/l) 3810 SM 2540 22. Tritium (pCi/L)# EPA 906.0 23. Turbidity (mg/I) 130 EPA 180.1 24. Antimony, Total (pg/l) 20 EPA 200.7 25. Arsenic, Total (pg/I) 50 EPA 200.7 26. Barium, Total (pg/l) 1740 EPA 200.7 27. Beryllium, Total (pg/l) 4 EPA 200.7 28. Cadmium, Total (pg/l) 5 EPA 200.7 29. Chromium, Total (pg/l) 40 EPA 200.7 30. Cobalt, Total (pg/l) 30 EPA 200.7 31. Copper, Total (pg/l) 10 EPA 200.7 32. Lead, Total (pg/t) 20 EPA 200.7 33. Mercury, Total (pg/l) 0.20 SM 3112 34. Nickel, Total (pg/i) 80 EPA 200.7 . 35. Selenium, Total (pg/l) 20 EPA 200.7 36. Silver, Total (pg/l) 10,, EPA 200.7 37. Thallium, Total (pg/l) 2"0 EPA 200.7 38. Vanadium, Total (pg/t) 10 EPA 200.7 39. Zinc, Total (pg/I) 110 EPA 200.7 40. Acetone (pg/l) 227 EPA 8260 41. Acryionitrile (pg/l) 5.0 EPA 8260 42. Benzene (pg/I) 5.0 EPA 8260 43. Bromochioromethane (pg/l) 5.0 . EPA 8260 44. Bromodichloromethane (pg/l) 5.0 EPA 8260 45. Bromoform (Tribromomethane) (pg/l) 5.0 EPA 8260 46. Carbon Disulfide (pg/l) 5.0 EPA 8260 47. Carbon Tetrachloride (pg/I) 5.0 . EPA 8260 48. Chlorobenzene (pg/l) 5.0 EPA 8260 49. Chloroethane (Ethyl Chloride) (pg/i) 5.0 EPA 8260 50. Chloroform (Trichloromethane) (pg/E) 5.0 EPA 8260 51. 3?Chloro?1?propene (pg/l) 5.0 EPA 8260 53. (pg/l) (DBCP) 5.0 EPA 8260 54. 1,2-Dibromoethane (pg/l) (Ethylene dibromide; EDB) 5.0 EPA 8260 55. 1,2?Dichlorobenzene (pg/l) (o-Dtohlorobenzene) 5.0 EPA 8260 . 56. 1,3?Diohiorobenzene (pg/i) (m-Dichiorobenzene) 5.0 EPA 8260 PEe?ase indicate detection limit if analyte is not detected. -3- 2540-FM-BWM0158 Monitoring Point FORM 50 Sample Date 03/03/18 ID. No. 100277 DETECTION ANALYSIS ANALYTE LEACHATE ZONE METHOD (pg/i) DISCHARGET NUMBER 57. 1,4-Dichclorobenzene (p-Dichiorobenzene) 5.0 EPA 8260 58. 5.0 EPA 8260 59. Dichlorodifluoromethane 5.0 EPA 8260 60. 1,1?Dichloroethane (Ethylidene chloride) 5.0 EPA 8260 61. 1,2-Dichloroethane (Ethylene dichloride) 5.0 EPA 8260 62. 1,1-Dichloroethene (Vinylidene chloride) 5.0 EPA 8260 63. . 5.0 EPA 8260 64. trans-1,2-Dichloroethene 5.0 EPA 8260 65. 1,2?Dichloropropane (Propylene dichloride) 5.0 EPA 8260 66. 5.0 EPA 8260 67. 5.0 EPA 8260 68. Ethyl Benzene 5.0 EPA 8260 69. Methyl butyl ketone (2-Hexanone) 5.0 EPA 8260 70. Methyl bromide (Bromomethane) 5.0 EPA 8260 71. Methyl chloride (Chloromethane) 5.0 EPA 8260 72. Methylene bromide (Dibromomethane) 5.0 EPA 8260 . 73. Methylene chloride (Dichloromethane) 32.7 EPA 8260 74. Methyl ethyl ketone 2-Butanone) 93:03 EPA 8260 75. Methyl iodide (lodomethane) 5.0 EPA 8260 76. 4~Methyl~2npentanone (Methyl isobutyl ketone) 9.3 EPA 8260 77. Styrene 5.0 EPA 8260 78. 12,1,2,2-Tetrachioroethane 5.0 EPA 8260 79. 1,1,1,2-Tetrachloroethane 5.0 EPA 8260 80. Tetrachloroethene (Perchloroethylene) . EPA 8260 81. Toluene 5.0 EPA 8260 82. 1,1,1?Trichloroethane 5.0 EPA 8260 83. 1,1,2-Trichloroethane 5.0 EPA 8260 84. Trichloroethene 5.0 EPA 8260 1' Please indicate detection limit if analyte is not detected. 5 if Rev. 1012010 . FORM 50 ANALYTE (pg/l unless otherwise indicated) Trichlorofluoromethane 1) 1,2,3-Trichl0ropropane Vinyl acetate VinyE chioride Xyienes LEACHATE DISCHARGET 5.0 5.0 5.0 2.0 6.5 Monitoring Point Sample Date 03/01/18 100277 DETECTION ANALYSIS ZONE METHOD DISCHARGET NUMBER EPA 8260 EPA 8260 EPA 8260 EPA 8260 EPA 8260 PADEP 273.284 analyte exclusively 2 Subtitie D. Appendix analyte exclusively All other analytes are common to both lists. Analyzed in the 4th calendar quarter only 7 . 1? Please indicate detection limit if analyte is not detected. 335-: 2540-FM-BWM0158 Rev. 10/2010 Monitoring Point No. NIH-1 (LEACHATEI . FORM 50 Sample Date 03/01/18 ID. No. 100277 Qualitatively Identified Organic Compounds List at least ten volatile organic compounds not otherwise identified in this section. Their identification should be based upon those compounds showing the greatest apparent concentration from the peaks of a mass spectrum of each sample. These ten compounds shall be identi?ed but the concentration of each is not required. Constituent CAS Number TIC: 1,4-Dioxane TIC: 1?Propanol TIC: 2~Methyl-1-propanol TIC: 2-Propanol TIC: Acetonitrile TIC: 1,7,7-trimeth TIC: Cyciohexanone TIC: Diethyl Ether . TIC: n-Butanol a TIC: Tetrahydrofuran I Rev 1012010 COMMONWEALTH OF Date PreparediRevised OF ENVIRONMENTAL PROTECTION pen ma BUREAU OF WASTE MANAGEMENT 07?l89l'201 8 . a DE we: MEN: tent pltDEtCR ox Date Received FORM 50 MUNICIPAL WASTE LANDFILL LEACHATE ANALYSES 7 ?i?tiis form must be fully and accurately compieted All required information must be typed or legiely printed in the seaces provided If additional space is necessary, identify each attached sheet as Fe rm 50, reference the item . number and identify the date prepared. The ?date preparedlrevised? on any attached sheets needs to match the ?date prepared/revised? on this page General Reierences: Section 2?3 255(d} and and 273 2T8(a) Federat Regui ations pendi to Part 258. 'A'ppiicantfperrnittee Tervita - Rosttever Township Sanitary Land?ll Site Name ?tervita - Rostraver Township Sanitary "3 I . Name' Westmmeiand Waste Inc Facility iD (as issued by DEF) 200277 Sampling Point Identi?cation MM 1 (LEACHATE) location. County Westmoreiaod Municipality: Rostraver Twp. sampling Point: Latitude: . Longitude: i 0 i Sampling Method: Pumped [j sailed erab example Field Filtered (must be 0.45 micron)? Yes No eitsiie 1029 Sample Date Sampte Collection Time D. Pius/S. Edylin Sample Collector?s Name: . The Hetchinsosn Group semple Coilector?s Affiliation Geochemical Testing 56-06306 Laboratory?es) Pedorming Analysis: I Laboratory Certi?cation Numbeds): Gisossti-ooz Final Lab Analysis Completion Date: 9812612018 Lain Sampie Numbeds): Wete Any Hoiding Times Exceeded? Yes No it Yes, please explain in comments field. NemetAt?ltetton of Person Who Filled Out Form Geochemical Testing Comments: Turbid, black, suspended solids, strong musty odor, petroleum sheen. Rev. 1012010 COMMONWEALTH OF DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF MANAGEMENT FORM 50 Monitoring Point No. lam lL QUARTERLY MUNICIPAL WASTE Sample Date 6i13118 ID. No. 10027? LEACHATE ANALYSES For new facilities and cells as well as existing facilities which were permitted and which received waste after April 9, l988, discharge flow volume from teachete collection shall be measured daily Discharge flow volume from the detection zone shall be estimated weekly Form 50 is due quarterly after the flow of leach ate from the collection system has started. For facilities or cells which have received no waste since April 9, 1988, detection zone monitoring will meet permitfclosure requirements. FLOW FACTOR LEACHATE DISCHARGE DETECTION ZONE DISCHARGE Volume (average goo) Area Drained (acres) Ratio (gallons/acrefday) Once leacnate flow begins from a leacnate collection system, leachate discharge will be analyzed quarterly for all analytes listed below. In tine ieachate detection zone, any fluid found in any detection zone monitoring point must be sampled during the initial four quarters for the leachate indicator parameters (designated by below) to establish a baseline fluid composition. Thereafter, any fluid detected in each monitoring point in the leachate detection zone must be sampled annually for the leacnate indicator parameters. Quarterly sampling of the fluid in any detection zone monitoring point for leaohate indicator parameters is required only when the quarterly flow at that monitoring point exceeds 10 gallons per acre per day (weekly average for the quarter) for the cell(s) served by that monitoring point. if tile indicator anatytes confirm leachate contamination in the detection zone, the fluid will be analyzed initially within 30 days and thereafter annually for all analytes listed below. When (where established) of any detection zone analytes on this form are exceeded, annual groundwater monitoring must include the Subtitle detection zone add?on list analyies found on Form 19. oarecnon ANALYSIS ANALYTE LEACHATE zone METHOD (mgll unless otherwise indicated) NUMBER Alkalinity, Total 2460 0 106??1? - Ammonia-Nitrogen 631 I EPA 3501 Bicarbonate (as Cocoa) 2440 SM 45004302 Calcium, Total 25? EPA 200.7 Chemical Oxygen Demand 2600 .. HACH 8000 Chloride (C l) 3400 EPA 300.0 Magnesium, Total 143 EPA 200.7 83? pH, Field, (Standard Units) pH, Laboratory, (Standard Units) 10* Potassium, Total 362 EPA 200.7 11.* Specific Conductance, Field (micromhosicrn) 12* Specific Conductance, Laboratory (micromhosfcm) 15600 EPA 120.1 13.* Sodium, Total 1910 EPA 200.7 14.* Sulfate, Total 76 EPA 300.0 15.* Total Organic Carbon (TOC) 633 SM 5310 16. 7 Fluoride i8.4 EPA 300.0 Iron, Total 18. Manganese. Total 319 EPA 200.7 19. Nitrate-Nitrogen 1' Please indicate detection limit if analyte is not detected. - 2 - 7.92 SM 45:30am '3 22.7 EPA 200.7 . 0.06 EPA 353.2 2540+" 58 Rev. 1012610 . - - Manito?ng 0 DETECTION LEACHATE ZONE METHOD .- . ANALYTE DESC NUMBER 20. Phenolics, Total (mga?l) 1.02 EPA 420.4 21'. Total Dissolved Solids (mgiE) 7000 . SM 2540 22. .- Tritium (pCilL)# . EPA 906.0 23,- Turbidity (mail) 0 230 EPA 180.1 24: Antimony, Total (ugll) 20 EPA 2007 25. Arsenic, Total (poll) 80 EPA 200.? 26.. Barium, Total (pgll) 7660 EPA 200.7 27.. 3 Beryllium, Total (pg/l) cl 4 EPA 200.? 2.6, Cadmium, Total (pgli) 5 - EPA 200.? 29.. Chromium, Total (090) 70 EPA 200.? 30. --'Cobalt, Total (poll) 0 20 EPA 2007 . 31.. - Copper, TotaE ((190) 10 EPA 200.? 32.. Lead, Total (pgll) 40 EPA 200.?" - Mercury, Total 020 SM 3112 8 '64. Nickel, Total {pg/l) cl 90 EPA 2007 I 3 35. Selenium, Total (ugll) <20 EPA 200.? 236.; Silver, Totai (poll) 10 EPA 200.7 Thaliium, Tolal (pgll) 20 EPA 2200.? Vanadium, Tolial (pg/l) 20 EPA 200.7 39.. - Ziao, Total (mil) 1370 EPA 200.? 4o. Acetone (pgil) <5 682 . EPA 8260 41.. Aorylonitrile (pg/E) cl 5.0 EPA 8260 42.. . Benzene (pg/l) 50. EPA 8260 43., .. Bromochloromethane (5190) 5.0 EPA 8260 44. Bromod?ohloromethane (pgfi) 5.0 EPA 8260 Bromoforra (Trihromomethane) ((190) 5.0 EPA 8260 46- Carbon D?sul?de (pglf) 5.0 EPA 8260 47?. Carbon Tetraohloride {pg/E) 50 EPA 8260 46. Chlorobenzene 5.0 EPA 8260 49. Chloroethane (Eihyl Chloride) (ugll) 5,0 EPA 8260 3 50, Chloroform (Trichloromethane) 5.0 EPA 8260 51. 3-Chloro-?l-propene (pg/l) 50 EPA 8260 52' I 53. l,2~Dibromo~3~chloropropane (ugll) (DBCP) 50 EPA 8260 54.. - 1,2?Dibromoethane (pg/l) (Ethylene dibromide; EDB) 50 EPA 3260 55. I 2-Dichlorobenzene (pgll) (o?Dichlorobenzene) 50 EPA 8260 . 56. ?l 3- Dichlorobenzene (pg/l) (m-Dichlorobenzene) 5.0 EPA 8260 Please indicate detection limit if aneiyte is not demoted Rev.10]2010 . FORM 50 Sample Date 51?13118 ID. No. 1002177 DETECTION ANALYSIS ANALYTE LEACHATE ZONE METHOD (ugil) DESCHARGET NUMBER 57. 1,4-Dichcl0robenzene (p?Dichiorobenzene) 5.0 EPA 8260 58. 5.0 EPA 8260 59. Dichierodifluoromethane 5.0 EPA 8260 60. 1.1-Diehieroethaize (Ethyiiciene chloride) 5.0 EPA 8260 61- 1,2-Dichieroetharze (Ethylene dichloride) 5.0 EPA 8260 62. (Vinylidene chi-wide) 5.0 EPA 8260 63. sis-1.2-Dichloroethene 5.0 EPA 8260 64. trans-1,2-Dichi0reethene 5.0 EPA 8260 65. 1,2-Dichloropropaee (Propylene dismantle) 5.0 EPA 8280 66. 5.0 EPA 8260 67. 50 EPA 8260 68. Ethyl Benzene 9.0 EPA 8260 60. Nietbyi butyi keiene {2?Hexanone) 8.2 EPA 8260 70. Methyl bromide (Bromomethane) 5.0 EPA 8250 71. Methyl chloride (Chloromethane) 5.0 EPA 8260 72. Methylene bromide (Dibromomethane) 5.0 EPA 8260 73. Methylene chloride (D?ohioromethene) 5.0 EPA 8260 74. Methyl ethyl ketone 2-Butanone) ?$981 EPA 8260 75. Methyl iodide (lodomethane) 5.0 EPA 8260 76. 4~Methyi-2-pentanone (Methyl isobutyi ketone) 36.5 EPA 8260 W. Styrene 5.0 EPA 8260 78. 1,1 50 EPA 8260 7'9. 5.0 EPA 8260 80. Tetrachloroethene (Perchloroethylene) $5.0 EPA 8260 81. Te?uene 2?.91- EPA 8260 82. 1,1,1-Trichioroethene 5.0 EPA 8260 as. 5.0 EPA 8260 84. Tfichiomethene 5.0 EPA 8260 Moniton?ng Point No. mm Please indicate detection iimit if analy?te is net detected. 2540-FM-BWM0153 Rev. 1012010 . FORM 50 ANALYTE (ugii unless otherwise indicated) Trichlorofluoromethane (CF01 1) 1,2,3-Trichi0r0propane View acetate Vinyl chioride Xylenes LEACHATE 5.0 5.0 5.0 2.0 30.1 Monitoring Point E. Sample Date 6/13118 ID. No. 10027? ANALYSIS ZONE METHOD DISCHARGET RUMBER EPA 8260 EPA 8260 EPA 8260 EPA 8266 EPA 8260 PADEP 273.284 analyte exclusively Subtitle D. Appendix I analyte exclusiveiy Ail other analytes are common to both lists" 1' Please indicate detection limit if analyte is not detected. Analyzed in the calendar quarter oniy 2540-FM-BWM0153 Rev. 1012010 FORM 50 Quaiitativety Identified Organic Compounds Monitoring Point No. (LEAGHATE) Sample Date 6l13!18 ED. No. 30027? List at least ten voiatile organic compounds not otherwise identified in this section ??heir identification should be based upon those compounds showing the greatest apparent concentration from the peaks of a mass spectrum of each sample These ten compounds shalt be icentified but the concentration of each is not reqm Cred Constituent mime TIC: TIC: 1,4?Dioxane TIC: ?I??ropanol TIC: 2?Methyi??l~propanoi TIC: 2-Propanol TIC: Acetonitrile TIC: Diethy! Ether TIC: Naphthalene TIC: n?Butanol TIC: Tetrahydrofuran Rev. 10:2010 COMMONWEALTH OF Date PgeparedIRevised - . DEPARTMENT OF ENVERONMENTAL PROTECTION 0827/2018 BUREAU OF WASTE MANAGEMENT i_ . . a ML Date Received FORM 50 WASTE LANDFILL LEACHATE ANALYSES This form meet be tuliy and accurately compteted. required information must be typed or iegibiy printed in the spaces provided. if additional space is necessary, identify each attached sheet as i-"o rm 50, reference the item number a not identify the date prepared. The ?date prepared/revised? on any attached sheets needs to match the ?date preparedfrevised? on this page General References: Section and and Federal Regulations Subtitle i} 256 54 and Appendix to Part 258 sis. Dee Appiicant/perrnittee Tervita Rostrever Township Sanitary Land?il Site Name Tervita - Rostrayer Township Sanitary Land?li Facility 10 (as issued by 1002?? Facility Name: Westmoreland Waste Inc. iVlH~1 (LEACHATE) Sampling Point identi?cation Location: County WBSWOMEW Municipality; Sampling Point: Latitude: ?t . Longitude: it Sampling Method: [3 Pumped Bailed Grab Sample Field Filtered (must be 0.45 micron)? Yes No 819/ 18 10:00 Sample Date Sampie Collection Time: Sample Coilector?s Name: 0' Eydlin Sample Coiiector?s Affiliation: The Hutchinson Group Geochemical Testing 56?00306 LaboratOiyUes) Performing Analysis: LaboratOi?y Codi?cation Numbeds): Gi808662~001 Final Lab Analysis Compietion Date: 08" 212018 Lab Sampie Numbeds): Wez'e Any Hoiding Times Exceeded? Yes No If Yes, please explain in comments fieid. NamelAffiliation of Person Who Filled Out Form GeOChemiC?i Testing Comments: Highly turbid, dark brown, strong musty odor. 2540-FM-BWM9153 Rev. 1012910 COMMONWEALTH OF DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM 50 QUARTERLY MUNICIPAL WASTE LANDFILL LEACHATE ANALYSES Sample Date 8/9i18 No, 300277 Monitoring Point No. MM . For new tacitities and oeils as weil as existing facilities which were permitted and which received waste after Aprli 9, 1988, discharge ?ow volume from teachate collection shalt be measured daily Discharge flow volume from the detection zone snail be estimated weekly Form 50 is due quarterly after the flow of leach ate from the collection system has started. For facilities or cells which have received no waste since April 9, 1988, detection was monitoring will meet permitlclosure requirements. FLOW FACTOR LEACHATE DISCHARGE DETECTION ZONE DISCHARGE Volume (average gpd) 401138 Area Drained (acres) 40-5 991.1 Ratio (gallonslacrelday) Once ieacttate flow begins from a leachate coltection system, ieachate discharge will be analyzed quarterly for all anaiytes listed below. lo the ieachate detection zone, any ?uid found in any detection zone monitoring point must be sampled during the ir-iitial tour quarters for the leachate indicator parameters (designated by below) to establish a baseline fluid composition. Thereafter, any fluid'detected in each monitoring point in the ieachate detection zone must be sampled annuatty for the leachate indicator parameters. Quarterly sampling of the fluid in any detection zone monitoring point for leachate indicator parameters is required onty when the quarterty flow at that monitoring point exceeds to gallons per acre per day (weekly average for the quarter) for the cell(s) served by that monitoring point. if the indicator analytes confirm leachate contamination in the detection zone, the fluid will be anatyzed initiaily within 30 . days and thereafter annuatly for alt anatytes listed below. When (where established) of any detection zone anaiytes on this form are exceeded, annual groundwater monitoring must include the Subtitle detection zone add~ort . . - - list found on Form 19. a, DETECTION ANALYSIS ANALYTE LEACHATE ZONE METHOD (mgr! unless otherwise indicated] NUMBER Atkalinity, Total 2780 10611 21* Ammonia?Nitrogen 814 EPA 350.1 33" Bicarbonate (as 08003) 2140 SM 4500-(302 [3 4f Catciom, Total 2197 EPA 200.7 53? Chemical Oxygen Demand 9 2200 HACH 8000 Chloride (Ci) 3540 EPA 3000 1* Magnesium, Total . 15?! EPA 200.".Jr 33' pH; Field, (Standard Units) NA SM 4500 - - . pH, Laboratory, (Standard Units) 3,15 SM 4500-344. - 3' 10* Potassium, Total . 438 EPA 200.7 11.* Specific Conductance, Fietd (micromhosfcm) NA EPA 120.1 12* Specific Conductance, Laboratory (micromhos/cm) 17000 EPA 120.1 18.* Sodium, Total in 2130 EPA 200.7 .- 14.* Sulfate. Totat 50 EPA 300.0 15* Total Organic Carbon (TOG) 529 SM 5310 16. Fluoride 9.3 EPA 300.0 :3 iron, Total 132 EPA 20012.". 18. Manganese. Totat 2.73 EPA 200.7". -. 19. Nitrate-Nitrogen 0.13 EPA 353.21?- Please indicate detection limit if analyte is not detected. -2- Rev. 10f201 ?56. Monitoring Point No. FORM 50 Sample Bate 8.19/18 ID. No. 1002?? DETECTION LEAGHATE ZONE METHOE ANALYTE NUMBER 20. Phenolics, Total (mgfl) 0.032 EPA 4204 21. Total Dissolved Solids (mgA) 8230 SM 2540 22. Tritium EPA 906.0 23, Turbidity (mgl'i) 165 EPA 180.1 24. Antimony, Total 20 EPA 2200,? 25. Arsenic, Total {pgil} 100 EPA 200.17 26. Barium, Total (pgil) EPA 200.? .27. Bewli?um. ?Fetal c: 4 EPA 290.7 28. Cadmium, Total (ygfi) 5 EPA 200.7 29. .. Chromium, Total (pgll) 90 EPA 200.? 30. Cobalt, Total (mil) (1 30 EPA 200.7 31. Copper, Total (pg/i) 10 EPA 200.? 32. Lead, Total (ygfl) 20 EPA 200.? 33. Mercury, Total 020 SM 3112 8 34. Nickel. ?fetal (ugfl) 120 EPA 200.7 .- 35. Selenium. Total (p911) 20 EPA 200.? 36. Silver, Total (Mgr?) 1905 . EPA 200.7 Thallium, Toial (091E) cl 20 EPA 200.?? 38. Vanadium. Total (ugll) 20 EPA 200.7 39. Zinc, Total (pgl?l) 130 EPA 200.? 40. Acetoae (pgll) 84? EPA 8260 41. Acyylonitrile {pgfl} 5.0 EPA 8260 42. Benzene (ugli) 50 EPA 8260 43. Bromochloromethane (ugfl) 5.0 EPA 8260 44. Bromodichloromethane {pgll} 5.0 EPA 8260 45. Bromoform (Tr?bromomethane) 5.0 EPA 8260 46. Carbon Disulflde (09.0) 5.0 EPA 8260 47. Carbon Tetrachloride (pgll) 5.0 EPA 8260 48. Chlorobenzene (098) 5.0 EPA 8260 49. Chloroethane (Ethyl Chloride) (pgfl) 5.0 EPA 8260 50. Chloroform (pg/l) 5.0 EPA 8260 51. 3?Chloro?1vpropene (pg/l) 5.0 EPA 8260 .3) 53. (pgll) (DBCP) cl 5.0 EPA 8260 54. 1 ,2?Dibromoethane (pgll) (Ethylene dibromide; EDS) 5.0 EPA 8260 55. 1,2-chhlorobenzerle (pgfl) (o?Dichlombenzene) 5.0 EPA 8260 1.3-Dichlor0benzene (pg/l) (m~Dichlorohenzene) 50 EPA 8260 1* Please indicate detection limit if analyte is not detected. -3- 2540-FM-BWM0158 Rev. 1012010 Monitoring Point No. W4 R- 50 Sampie Date 819MB ANALYSIS ANALYTE LEACHATE ZGNE METHOD NUMBER 57. 1.4-Dichclorobenzene (p-Qichlorobenzene) 5.0 EPA 8280 58. frees-1,4-Dichloro-2-b0tene 5.0 EPA 8280 59. Dichierodifluoromethane 5.0 EPA 8280 60. 1,1?Diehlomethane {Ethyiidene chloride) 5.0 EPA 8260 63. 3,2?Dichieroethane (Ethyiene dichloride) 5.0 EPA 8280 62. ?Ll-Dichioroethene (Vinylidene chloride) 5.0 EPA 8280 63. 7 5.0 EPA 8280 64. trans-1,2-Dichioroethene 5.0 EPA 8280 65. 1,2-Dichloropmpane (Propylene dichloride) 5.0 EPA 8250 68. 5.0 EPA 8280 67. trans-1,S-Dichlompropene 5.0 EPA 8280 . 68. Elm: Benzene 50 EPA 8260 68. Methyl may: {2~Hexanone) ?z 5.0 EPA 8260 7o. Meihyl bromide (Bromemethane) 5.0 EPA 8260 Methyl chios?ide (Chloromethane) 5.0 EPA 8260 Methyiene bromide (Dibromomethane) 5.0 EPA 8280 73. Methylene chloride (Dichloromei'hane) 25.0 EPA 8260 74. Methyl etbyi ketone 2-Bu?ienene) "?1620 EPA 8260 . 75. Methyl iodide (ledomethane) c! 50 EPA 8260 78. 4-MethyE?2-pentenoee (Methyl isobutyi ketene) NA EPA 8280 7'7. Styrene 5.0 EPA 8280 78. 3.1 ,2,2-Tetrachlemethane 5.0 EPA 8260 2?0. 1,1,1,2?Tetrachlomethane 5.0 EPA 8280 80. Tetrachieroeihene (Perchloroethyiene) EPA 8260 Toiuene 5.0 EPA 8260 82. 3,1,1?Trichloroethene (Methyichloroferm) 5.0 EPA 8260 83. 3,1,2-Trichieroethene 5.0 EPA 8260 84. Trichioroethene 5.0 EPA 8280 Please indicate detection limit if analyte is not detected. . Monitoring Point No. MM {Ll-imam FORM 50 Sample Date 819/18 1.0. No. ANALYSIS ANALYTE . . . LEACHATE ZONE METHOD (pgll unless otherwme Indicated) QESCHARGET DISCHARGET NUMBER Trichlorofluommethane (CFC-11) 5,0 EPA 8260 c: 5.0 EPA 8260 Viayt acetate 5.0 EPA 8260 Vinyl chloride - 2.0 EPA 8260 Xylenes 5,0 EPA 8260 PADEP 273.284 analyte exclusive?y Analyzed in the calendat quarter only at Subtitle D. Appendix I analyte exclusively . All other analytes are common ta both lists. 1" Please indicate detection limit if anaiyte is fact detected, -5- Rev.1t?h?2010 Monitoring Point No. (LEACHATE) 50 Sample Date FORM 100277 Quailtetively identified Organic Compounds List at feast ten volatile organic compounds not otherwise identified in this section. Their identification should be based upon those compounds showing the greatest apparent coecentration from the peaks of a mass spectrum of each sample. These tee compounds shall be identi?ed but the ooecentration of each is not required Constituent CAS Number TIC: 1,4-Dioxene TIC: 4?Methyi-2?Pentanone TIC: Acetonitrile TIC: TIC: Cyciohexanol, Diethyl Ether TIC: {Jodecane TIC: Naphthalene, TIC: n?Butano] TIC: Tetrahycirofuran 2540-FM-BWM0158 Rev. 1012010 COMMONWEALTH OF Date Prepared/Revised . DEPARTMENT OF ENVIRONMENTAL PROTECTION 01/11/2019 r: ma BUREAU OF WASTE MANAGEMENT DEPARTMENT OF ENVIRONMENTAL PROTECTION Date Received MUNICIPAL WASTE LANDFILL LEACHATE ANALYSES This form must be fuliy and accurateiy completed. All required information must be typed or legibly printed in the spaces provided. if additional space is necessary, identify each attached sheet as Form 50, reference the item number and identify the date prepared. The ?date prepared/revised? on any attached sheets needs to match the ?date prepared/revised" on this page. General References: Section 273.255(d) and and 273.276(a) Federal Re ulations, Subtitle D: 258.54 and Appendix to Part 258. Applicant/permittee Westmoreland Waste LLC Site Name Westmoreland Waste LLC Facility ID (as issued by DEP) 100277 Facility Name: Westmoreland Waste LLC Sampling Point Identification (LEACHATE) Westmoreland Municipality: Rostraver Twp. Location: County )1 Sampling Point: Latitude: Longitude: 0 Sampling Method: Pumped CI Baiied Grab Sample Field Filtered (must be 0.45 micron)? Yes No 12/13/18 11:10 Sample Date Sampie Collection Time: Sample COllector's Name: David Custer Sample Coilector?s Affiliation: Geochemical Testing Geochemical Testing 56-00306 Laboratory(ies) Performing Analysis: Laboratory Certification Number(s): (31812865003 Final Lab Analysis Compietion Date: 01/09/2019 Lab Sample Number(s): Were Any Holding Times Exceeded? Yes No it Yes, please explain in comments field. Name/Affiliation of Person Who Filled Out Form GSOChemica' TeSting Comments: Turbid Strong Odor - Amber. 2540-FM-BWM0158 Rev. 1012010 COMMONWEALTH OF DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM 50 Monitoring Point No. . QUARTERLY MUNICIPAL WASTE Sample Date 12/13/18 LANDFILL LE). No_ 100277 LEACHATE ANALYSES For new facilities and cells as well as existing facilities which were permitted and which received waste after April 9, 1988. discharge flow volume from leachate collection shall be measured daily Discharge flow volume from the detection zone shall be estimated weekly Form 50 is due quarterly after the flow of leach ate from the collection system has started. For facilities or cells which have received no waste since April 9, 1988, detection zone monitoring will meet permit/closure requirements. FLOW FACTOR LEACHATE DISCHARGE DETECTION ZONE DISCHARGE Volume (average gpd) 101471.33 Area Dralned (acres) 44.6 Ratio (gallons/acre/day) 2275.1 Once leachate flow begins from a leachate collection system, leachate discharge will be analyzed quarterly for all analytes listed below. in the leachate detection zone, any fluid found in any detection zone monitoring point must be sampled during the initial four quarters for the leachate indicator parameters (designated by below) to establish a baseline fluid composition. Thereafter, any fluid detected in each monitoring point in the leachate detection zone must be sampled annually for the leachate indicator parameters. Quarterly sampling of the fluid in any detection zone monitoring point for leachate indicator parameters is required only when the quarterly flow at that monitoring point exceeds 10 gallons per acre per day (weekly average for the quarter) for the cell(s) served by that monitoring point. If the indicator analytes con?rm leachate contamination in the detection zone, the fluid will be analyzed initially within 30 days and thereafter annually for all analytes listed below. When (where established) of any detection zone analytes on this form are exceeded, annual groundwater monitoring must include the Subtitle detection zone add-on list analytes found on Form 19. 4 a DETECTION ANALYSIS ANALYTE LEACHATE ZONE METHOD (mg/l unless otherwise indicated) DISCHARGET NUMBER Aikalinity, Total 1830 1067-1? Ammonia-Nitrogen 298 EPA 3501 Bicarbonate (as 1820 SM 4500-002 Calcium, Total 120;, EPA 200.7 Chemical Oxygen Demand 1000 HACH 8000 8* Chloride (Ci) 1770 EPA 300.0 Magnesium, Total 87.1 EPA 200.7 pH, Field, (Standard Units) 7.70 SM 4500 pH, Laboratory, (Standard Units) 0 7.53 SM 10.* Potassium, Total 202 EPA 200.7 11.* Specific Conductance, Fieid (micromhos/cm) 7170 EPA 120.1 123* Specific Conductance, Laboratory (micromhos/cm) 8790 EPA 120.1 13.* Sodium, Total 922 EPA 200.7 14.* Sulfate, Total 72 EPA 300.0 15.* Total Organic Carbon (TOC) 136 SM 5310 16. Fluoride 1.0 EPA 300.0 17. Iron, Total 4.79 EPA 200.7 18. Manganese, Total 0 0.58 EPA 200.7 19. Nitrate-Nitrogen 0.36 EPA 353.2 1' Please indicate detection limit if analyte is not detected. 2 Rev. 1012010 Monitoring Point No. MH-1 (LEACHAT FORM 50 Sample Date 12/13/18 l.D. No. 100277 DETECTION ANALYSES LEACHATE ZONE METHOD ANALYTE DISCHARGET NUMBER 20. Phenolics, Total (mg/l) 0.057 EPA 420.4 21. Total Dissolved Solids (mg/I) 3650 SM 2540 22. Tritium (pCi/L)# 23400+?2260 EPA 906.0 23. Turbidity (mg/l) 55.0 EPA 180.1 24. Antimony, Total (pg/l) 100 EPA 200.7 25. Arsenic, Total (pg/l) 30 EPA 200.7 26. Barium, Total (pg/l) 1800 EPA 200.7 27. Beryllium, Total (pg/I) 4 EPA 200.7 28. Cadmium, Total (pg/I) 5 EPA 200.7 29. Chromium, Total 30 EPA 200.7 30. Cobalt, Total (pg/l) 10 EPA 200.7 31. Copper, Total (pg/l) 10 EPA 200.7 32. Lead, Total (pg/I) 20 EPA 200.7 33. Mercury, Total (pg/I) 020 SM 3112 34. Nickel, Total (pg/l) 50 EPA 200.7 35. Selenium, Total (pg/I) 20 EPA 200.7 36. Silver, Total (pg/l) 10 EPA 200.7 37. Thallium, Total (pg/I) 20 EPA 200.7 38. Vanadium, Total (pg/l) 10 EPA 200.7 39. Zinc, Total (ug/I) 80 EPA 200.7 40. Acetone (pg/l) 100 EPA 8260 41. Acrylonitrile (pg/I) 5.0 EPA 8260 42. Benzene (pg/l) 5.0 EPA 8260 43. Bromochloromethane (pg/l) 5.0? EPA 8260 44. Bromodichloromethane (pg/i) 5.0 EPA 8260 45. Bromoform (Tribromomethane) (pg/l) 5.0 EPA 8260 46. Carbon Disulfide (pg/I) 5.0 EPA 8260 47. Carbon Tetrachloride (pg/I) 5.0 EPA 8260 48. Chlorobenzene (pg/l) 5.0 EPA 8260 49. Chloroethane (Ethyl Chloride) (pg/l) 5.0 EPA 8260 50. Chloroform (Trichloromethane) (pg/l) 5.0 EPA 8260 51. 3-Chloro?1-propene 5.0 EPA 8260 - 53. (pg/l) (DBCP) 5.0 . . - EPA 8250-57 . 54. 1,2?Dibromoethane (pg/l) (Ethylene dibromide; EDB) 5.0 - .. EPASZBO 3 55. 1,2?Dichlorobenzene (pg/l) (o-Dichlorobenzene,3-Dichlorobenzene (pg/l) (m-Dichlorobenzene) 3 5.0-- EPA3250- 1' Please indicate detection limit if analyte is not detected. -. -- - Rev. 10/2010 FORM 50 Monitoring Point No. Mil-1m Sample Date 12/131118 .. LD. No. 100277 DETECTION ANALYTE LEACHATE ZONE METHOD (pg/l) NUMBER 57. 1,4-Dichcior0benzene (p?Dichlorobenzene) 5.0 EPA 8260. 58. 5.0 EPA 8260, 59. Dichlorodifluoromethane 5.0 EPA 8260 - 60. 1,1~Dichloroethane (Ethylidene chloride) 5.0 EPA 8260 61. 1,2~Dichloroethane (Ethylene dichioride) 5.0 EPA 62. 1,1-Dichloroethene (Vinylidene chloride) 5.0 EPA 8260 63. 5.0 EPA 8260. 64. trans-1,2-Dichloroethene 5.0 EPA 8260 65. 1 ,2-Dichloropropane (Propylene dichloride) 5.0 EPA 8260 66. 5.0 EPA 8260 67. trans-1,3-Dichloropropene 5.0 EPA 8260 68. Ethyl Benzene 11.4 EPA 8260 69. Methyl butyl ketone (2-Hexanone) 5.0 EPA 8260 70. Methyl bromide (Bromomethane) 5.0 EPA 8260 71. Methyl chloride (Chloromethane) 5.0 EPA 8260 72. Methylene bromide (Dibromomethane) 5.0 EPA 8260 73. Methylene chloride (Dichloromethane) 5.0 EPA 8260 74. Methyl ethyl ketone 2~Butanone) 80.4 EPA 8260 75. Methyl iodide (lodomethane) 5.0 EPA 8260 76. 4-Methyl-2-pentanone (Methyl isobutyl ketone) 6.5 EPA 8260 77. Styrene 5.0 EPA 8260 78. 1,1,2,2-Tetrachloroethane 5.0 EPA 8260 79. 5.0 EPA 8260 80. Tetrachloroethene (Perchloroethyiene) 55.0, EPA 8260 81. Toluene 18.5" EPA 8260 82. 1,1,1-Trichloroethane (Methyichloroform) 5.0 EPA 8260 83. 1,1,2-Trichioroethane 5.0 EPA 8260 84. Trichloroethene 5.0 EPA 8260 Please indicate detection limit if analyte is not detected. zsao-FMQmemsa Rev. 1012010 FORM 50 ANALYTE (pg/l unless othenivise indicated) Trichlorofiuoromethane (CFC-11) 1,2,3?Trichloropropane Vinyt acetate Vinyl chloride Xylenes LEACHATE DISCHARGET 5.0 5.0 5.0 2.0 36.1 Monitoring Point No. NIH-1 Sample Date 12/13/18 ID. No. 100277 DETECTION ZONE DISCHARGET ANALYSIS METHOD NUMBER EPA 8260 EPA 8260 EPA 8260 EPA 8260 EPA 8260 PADEP 273.284 analyte exclusively Subtitle D. Appendix I analyte exclusively All other analytes are common to both lists. 1? Please indicate detection limit if analyte is not detected. Analyzed in the 4f? palendariquaifter only: 2540-FM-BWM0158 Rev. 1 201 Monitoring Point No. marinade/lie FORM 50 Sample DateW' ID, No. 100277 . -- Qualitatively Identified Organic Compounds List at least ten volatile organic compounds not otherwise identi?ed in this section. Their identification should be . 3 . .. based upon those compounds showing the greatest apparent concentration from the peaks of a mass spectrum of I each sample. These ten compounds shail be identified but the concentration of each is not required. Constituent CAS Number TIC: TIC: TIC: 1,4-Dioxane TIC: TIC: Acetonitrile TIC: Diethyl Ether TIC: Naphthalene TIC: n?Butanol . TIC: Tetrahydrofuran