#=CL# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LIMS USE: FR - ERIN SAVAGE LIMS OBJECT ID: 92374970 March 07, 2018 Ms. Erin Savage Appalachian Voices 171 Grand Blvd. Boone, NC 28607 RE: Project: Sampling 2/27 Pace Project No.: 92374970 Dear Ms. Savage: Enclosed are the analytical results for sample(s) received by the laboratory on February 28, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lorri Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures cc: Mr. Willie Dodson, Appalachian Voices Mr. Matt Hepler, Appalachian Voices REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 17 #=CP# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 CERTIFICATIONS Project: Sampling 2/27 Pace Project No.: 92374970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Wyoming Certification: FL NELAC Reciprocity West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 17 #=SA# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Sampling 2/27 Pace Project No.: 92374970 Lab ID Sample ID 92374970001 Number 6 well 92374970002 Number 6 Punch Out 92374970003 92374970004 Number 20 Punch Out RM Spring Method Analysts EPA 200.7 SER Analytes Reported Laboratory 27 PASI-A EPA 200.8 KPP 1 PASI-O EPA 200.7 SER 27 PASI-A EPA 200.8 KPP 1 PASI-O EPA 200.7 SER 27 PASI-A EPA 200.8 KPP 1 PASI-O EPA 200.7 SER 27 PASI-A EPA 200.8 KPP 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 17 #=AR# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Sampling 2/27 Pace Project No.: 92374970 Sample: Number 6 well Parameters 200.7 MET ICP Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Silicon Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc 200.8 MET ICPMS Selenium Lab ID: 92374970001 Results Units Collected: 02/27/18 11:27 Report Limit Received: 02/28/18 09:55 DF Prepared Matrix: Water Analyzed CAS No. Qual Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 711 6.9 79.2 589 3.4 ND ND 35200 10.7 ND 56.5 373000 16.9 6250 1300 14.0 19.8 ND 25400 ND 9830 462 ND ND 6.7 9.0 258 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 100 5.0 10.0 5.0 1.0 50.0 1.0 100 5.0 5.0 5.0 500 5.0 100 5.0 5.0 5.0 5000 100 5.0 5000 5.0 10.0 5.0 5.0 5.0 10.0 1 1 1 1 1 1 1 1 1 1 1 10 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 15:57 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 03/05/18 16:03 7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-98-7 7440-02-0 7440-09-7 7440-21-3 7440-22-4 7440-23-5 7440-24-6 7440-28-0 7440-31-5 7440-32-6 7440-62-2 7440-66-6 Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 ND ug/L 1.0 1 03/03/18 04:04 03/04/18 22:16 7782-49-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 17 #=AR# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Sampling 2/27 Pace Project No.: 92374970 Sample: Number 6 Punch Out Parameters 200.7 MET ICP Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Silicon Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc 200.8 MET ICPMS Selenium Lab ID: 92374970002 Results Units Collected: 02/27/18 12:15 Report Limit Received: 02/28/18 09:55 DF Prepared Matrix: Water Analyzed CAS No. Qual Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 ND ND ND 98.7 ND ND ND 28700 ND ND ND 454 ND 9240 201 ND ND ND 5020 ND 86700 759 ND ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 100 5.0 10.0 5.0 1.0 50.0 1.0 100 5.0 5.0 5.0 50.0 5.0 100 5.0 5.0 5.0 5000 100 5.0 5000 5.0 10.0 5.0 5.0 5.0 10.0 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 03/05/18 16:07 7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-98-7 7440-02-0 7440-09-7 7440-21-3 7440-22-4 7440-23-5 7440-24-6 7440-28-0 7440-31-5 7440-32-6 7440-62-2 7440-66-6 Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 ND ug/L 1.0 1 03/03/18 04:04 03/04/18 22:18 7782-49-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 17 #=AR# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Sampling 2/27 Pace Project No.: 92374970 Sample: Number 20 Punch Out Parameters 200.7 MET ICP Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Silicon Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc 200.8 MET ICPMS Selenium Lab ID: 92374970003 Results Units Collected: 02/27/18 12:33 Report Limit Received: 02/28/18 09:55 DF Prepared Matrix: Water Analyzed CAS No. Qual Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 1130 ND ND 1410 ND ND ND 168000 ND 103 ND 231000 ND 44800 120000 ND ND ND 7700 ND ND 616 ND ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 100 50.0 100 50.0 10.0 50.0 10.0 1000 50.0 50.0 50.0 500 50.0 1000 500 50.0 50.0 5000 1000 50.0 5000 50.0 100 50.0 50.0 50.0 100 1 10 10 10 10 1 10 10 10 10 10 10 10 10 100 10 10 1 10 10 1 10 10 10 10 10 10 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/05/18 13:49 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 13:49 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:19 03/05/18 16:00 03/05/18 16:00 03/05/18 13:49 03/05/18 16:00 03/05/18 16:00 03/05/18 13:49 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 03/05/18 16:00 7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-98-7 7440-02-0 7440-09-7 7440-21-3 7440-22-4 7440-23-5 7440-24-6 7440-28-0 7440-31-5 7440-32-6 7440-62-2 7440-66-6 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 ND ug/L 1.0 1 03/03/18 01:14 03/05/18 00:29 7782-49-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 17 #=AR# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Sampling 2/27 Pace Project No.: 92374970 Sample: RM Spring Parameters 200.7 MET ICP Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Silicon Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc 200.8 MET ICPMS Selenium Lab ID: 92374970004 Results Units Collected: 02/27/18 12:59 Report Limit Received: 02/28/18 09:55 DF Prepared Matrix: Water Analyzed CAS No. Qual Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 ND ND ND 57.1 ND ND ND 24600 ND ND ND ND ND 8170 ND ND ND ND 5600 ND 10800 120 ND ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 100 5.0 10.0 5.0 1.0 50.0 1.0 100 5.0 5.0 5.0 50.0 5.0 100 5.0 5.0 5.0 5000 100 5.0 5000 5.0 10.0 5.0 5.0 5.0 10.0 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/01/18 23:55 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 03/05/18 16:10 7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-98-7 7440-02-0 7440-09-7 7440-21-3 7440-22-4 7440-23-5 7440-24-6 7440-28-0 7440-31-5 7440-32-6 7440-62-2 7440-66-6 Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 ND ug/L 1.0 1 03/03/18 01:14 03/05/18 00:31 7782-49-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 17 #=QC# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Sampling 2/27 Pace Project No.: 92374970 QC Batch: 400358 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: METHOD BLANK: 92374970001, 92374970002, 92374970003, 92374970004 2220370 Associated Lab Samples: Parameter Matrix: Water 92374970001, 92374970002, 92374970003, 92374970004 Blank Reporting Units Result Limit Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Silicon Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L LABORATORY CONTROL SAMPLE: Parameter Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 100 5.0 10.0 5.0 1.0 50.0 1.0 100 5.0 5.0 5.0 50.0 5.0 100 5.0 5.0 5.0 5000 100 5.0 5000 5.0 10.0 5.0 5.0 5.0 10.0 Analyzed Qualifiers 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 03/05/18 12:51 2220371 Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Spike Conc. 5000 500 500 500 500 500 500 5000 500 LCS Result 4930 489 482 505 502 491 490 4860 488 LCS % Rec % Rec Limits 99 98 96 101 100 98 98 97 98 Qualifiers 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 17 #=QC# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Sampling 2/27 Pace Project No.: 92374970 LABORATORY CONTROL SAMPLE: 2220371 Parameter Spike Conc. Units Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Silicon Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Parameter Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Silicon Silver Sodium Strontium 500 500 5000 500 5000 500 500 500 5000 2500 250 5000 500 500 500 500 500 500 213 28.5 <10.0 31.3 <1.0 146 <1.0 16200 <5.0 <5.0 33.8 1250 <5.0 1740 38.5 13.5 18.9 <5000 2890 <5.0 17000 80.6 LCS % Rec 479 512 4820 471 4660 470 497 483 4910J 2410 244 4900J 501 478 480 478 482 459 2220372 92375090001 Units Result ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L LCS Result % Rec Limits 96 102 96 94 93 94 99 97 98 96 97 98 100 96 96 96 96 92 Qualifiers 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 85-115 2220373 MS Spike Conc. 5000 500 500 500 500 500 500 5000 500 500 500 5000 500 5000 500 500 500 5000 2500 250 5000 500 MSD Spike Conc. 5000 500 500 500 500 500 500 5000 500 500 500 5000 500 5000 500 500 500 5000 2500 250 5000 500 MS Result 5570 540 502 552 522 681 510 21400 504 487 560 6230 482 6670 521 526 512 9820 5770 255 22200 599 MSD Result MS % Rec 5640 540 499 558 528 692 513 22000 512 489 565 6310 484 6740 524 530 516 10000 5900 256 22700 608 107 102 100 104 104 107 102 105 101 97 105 100 96 99 97 102 99 104 115 102 105 104 MSD % Rec 109 102 100 105 106 109 103 116 102 98 106 101 96 100 97 103 99 108 120 102 114 106 % Rec Limits RPD 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 Qual 1 0 1 1 1 2 1 2 2 0 1 1 1 1 1 1 1 2 2 1 2 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 17 #=QC# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Sampling 2/27 Pace Project No.: 92374970 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Parameter Thallium Tin Titanium Vanadium Zinc 92375090001 Units Result ug/L ug/L ug/L ug/L ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Parameter 2220372 <10.0 <5.0 <5.0 12.6 120 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Cobalt Copper ug/L ug/L Iron Lead ug/L ug/L Magnesium Manganese Molybdenum Nickel ug/L ug/L ug/L ug/L Potassium Silicon Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 500 500 500 500 500 MSD Spike Conc. 500 500 500 500 500 2220374 92375009002 Units Result Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium 2220373 MS Spike Conc. 119 ND 13.7 212 ND 77.2 ND 1750 0.013 mg/L ND 0.063 mg/L 1630 0.0085 mg/L 426 81.3 39.6 0.068 mg/L 83000 11000 ND 54200 13.0 ND ND ND ND 0.40 mg/L MS Result 488 494 502 514 594 MSD Result MS % Rec 492 495 504 517 620 98 99 100 100 95 MSD % Rec 98 99 100 101 100 % Rec Limits RPD 70-130 70-130 70-130 70-130 70-130 Qual 1 0 0 1 4 2220375 MS Spike Conc. MSD Spike Conc. MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD 5000 500 500 500 500 500 500 5000 500 5000 500 500 500 500 500 500 5000 500 5130 512 510 716 509 601 508 6760 506 5260 516 518 725 521 611 515 6920 522 100 102 99 101 102 105 102 100 99 103 102 101 103 104 107 103 103 102 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 3 1 1 1 2 2 1 2 3 500 500 500 500 488 573 497 580 97 102 99 103 70-130 70-130 2 1 5000 500 5000 500 6560 483 6660 495 99 95 101 97 70-130 70-130 1 2 5000 500 500 500 5000 500 500 500 5300 564 545 552 5430 575 554 565 98 97 101 97 100 99 103 99 70-130 70-130 70-130 70-130 2 2 2 2 5000 2500 250 5000 500 500 500 500 500 500 5000 2500 250 5000 500 500 500 500 500 500 88800 13600 250 60600 508 469 495 497 502 883 89000 13600 255 60700 520 481 507 509 515 899 117 103 100 128 99 94 99 98 100 97 120 105 102 129 101 96 101 101 103 100 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 0 0 2 0 2 3 2 2 3 2 Qual Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 17 #=QC# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Sampling 2/27 Pace Project No.: 92374970 QC Batch: 430254 Analysis Method: EPA 200.8 QC Batch Method: EPA 200.8 Analysis Description: 200.8 MET Associated Lab Samples: METHOD BLANK: 92374970003, 92374970004 2339915 Associated Lab Samples: Matrix: Water 92374970003, 92374970004 Parameter Blank Result Units Selenium ug/L LABORATORY CONTROL SAMPLE: ND Spike Conc. Units Selenium ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Selenium 1.0 Analyzed Qualifiers 03/04/18 23:24 2339916 Parameter Parameter Reporting Limit 50 0.61J LCS % Rec 50.4 2339917 35377344001 Units Result ug/L LCS Result % Rec Limits 101 Qualifiers 85-115 2339918 MS Spike Conc. 50 MSD Spike Conc. 50 MS Result 43.6 MSD Result MS % Rec 45.9 86 MSD % Rec 91 % Rec Limits RPD 70-130 Qual 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 17 #=QC# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Sampling 2/27 Pace Project No.: 92374970 QC Batch: 430260 Analysis Method: EPA 200.8 QC Batch Method: EPA 200.8 Analysis Description: 200.8 MET Associated Lab Samples: METHOD BLANK: 92374970001, 92374970002 2339970 Associated Lab Samples: Matrix: Water 92374970001, 92374970002 Parameter Blank Result Units Selenium ug/L LABORATORY CONTROL SAMPLE: ND Spike Conc. Units Selenium ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Selenium 1.0 Analyzed Qualifiers 03/04/18 22:11 2339971 Parameter Parameter Reporting Limit 50 0.50U LCS % Rec 51.1 2339972 35377122002 Units Result ug/L LCS Result % Rec Limits 102 Qualifiers 85-115 2339973 MS Spike Conc. 50 MSD Spike Conc. 50 MS Result 47.4 MSD Result MS % Rec 47.2 94 MSD % Rec 94 % Rec Limits RPD 70-130 Qual 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 17 #=QL# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: Sampling 2/27 Pace Project No.: 92374970 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 17 #=CR# Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Sampling 2/27 Pace Project No.: 92374970 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92374970001 92374970002 92374970003 92374970004 Number 6 well Number 6 Punch Out Number 20 Punch Out RM Spring EPA 200.7 EPA 200.7 EPA 200.7 EPA 200.7 400358 400358 400358 400358 EPA 200.7 EPA 200.7 EPA 200.7 EPA 200.7 400431 400431 400431 400431 92374970001 92374970002 Number 6 well Number 6 Punch Out EPA 200.8 EPA 200.8 430260 430260 EPA 200.8 EPA 200.8 430268 430268 92374970003 92374970004 Number 20 Punch Out RM Spring EPA 200.8 EPA 200.8 430254 430254 EPA 200.8 EPA 200.8 430262 430262 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/07/2018 07:50 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 17 Document Revised: February 7, 2018 Page 1 of 2 issuing Authority: Pace Carolinas Quality Office Document Name: . Sample Condition Upon Receipt(SCUR) Document No.: Laboratory receiving samples: Asheville EdenEl UponReceipt A pp . Huntersville RaleighB MechanicsvilleB P. BCTient Greenwood Courier: BFed Ex ?ups Buses Commercial BPace 92374970 i I Custody Seal Present? BYes Seals Intact? BYes BNO 23/ L8. Date/initials Person Examining Contents: Packing Material: BBubble Wrap BBubble Bags %e Other Biological Tissue Fyze?? . BYes BNO Thermometer. . . 0 I mm: TDD mm. ?ew? Jam Cooler Temp {if/a Correction Factor: Add/Subtract Cooler Temp Corrected Temp should be above freezing to BSamples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soil A, water sample] Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps}? BYes BNO Did samples originate from a foreign source (internationally, including Hawaii and Puerto Rico)? BYes BN0 Comments/Discrepancy: Chain of Custody Present? [Ire/[live 1. Samples Arrived within Hold Time? [:16 BN0 2. Short Hold Time Analysis (<72 BYes KIM: BNIA 3. Rush Turn Around Time Requested? BYes Bag 4- Sufficient Volume? [24 BN0 BNXA 5. Correct Containers Used? BN0 BNIA 6. -Pace Containers Used? es . BN0 BNIA Containers Intact? Bag BN0 7. Dissolved analysis: Samples Field Filtered? 26M 8. Sample Labels Match ? ncludes Date/Time/ID/Analysis Matrix: El?s BNO BNIA 9. gw' 10. Headspace in VOA Vials BYes BN0 Trip Blank Present? BYes BN0 11. Trip Blank Custody Seals Present? BYes BN0 NIA COM DISCRE PAN CY Field Data Required? BYes CLIENT Lot ID of split containers: Person contacted: Date/Time: Project Manager SCURF Review: Project Manager SRF Review: Date: Date: alas/ill? alas/lg l? Page150f17 aceAna/yn'cal Document Name: Document Revised: February 2018 Sample Condition Upon Page 1 of 2 Document No.: Issuing Authority: Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is [lied and within the acceptance: Idnge pl use: vaiiun samples. Exceptions: VOA, Coliforrn, TOC, Oil and Grease, (water) DOC, ?Bottom half of box is to list number of bottle Project PM: LJP Due Date: 03/14/18 CLIENT: 93-FIPP VOICE unsemmaesv savu c:,1 Etc?55553:19283Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time presarvation Amount of Preservative Lot ll adjusted added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le. Out of hold, incorrect preservative, out of temp, incorrect containers. Page160f17 6 CHAIN-OF-CUSTODY I Analytical Request Document . The Chain?Of?Custody is a LEGAL DOCUMENT. All relevant ?elds must be completed accurately. PaceAna/ynca 7of17 . Page: at Section A Section Section Required Client Information: Required Project Information: Report To: Invoice Information: Attention: Company: gin-Vt our;- Name: 4.3.) Address: 1 I .. ,1 SID [vii-If?! NW 14" Email TO: .I I 5 ?ierREGULATORY AGENCY I NPDES GROUND WATER DRINKING WATER 6:17 ?q - La. Purchase Order No.: Ouole UST RCRA Wl/ Requested Analysis Filtered (YIN) OTHER Fax: Project Name: Projocl Phone: . . . . St 179L7?l Ie ocalon Requested Due Project Number: Profile II: 5 TA TE: Section Matrix Codes 5 E: . 2 RequiredCIient Inlorrnation MATRIX CODE 2 COLLECTED Preservatives Drinking Water ow 5 ?at? COMPOSITE COMPOSITE as a er 3? :n START ENDIGRAB Lu 2 Product SoilISotid SL 3 5' SAMPLE .9. Sample 103 MUST BE UNI DUE Tissue T8 0 0-3 5 Other DATE TIME DATE 03 4* _p D: Pace Project Lab I. TIME A A It? 7Ii' J74, I3 1.19" I 4.) coon-ummnuh: _t ADDITIONAL CC MMENTS RELINQUISHED BY I AFFILIATION Le? A. DATE Airs-"i9 TIME ACCEPTED I AFFILIATION DATE SAMPLE CONDITIONS 99.54 .1 SS SAMPLER NAME AND SIGNATURE 0 Ln PRINT Name of SAMPLER: (YIN) (YIN) Temp in Ice (YIN) Custody Sealed Cooler SIGNATURE of SAMPLER: r' I (Z, Note: By signii this form you are accepling Paco's. NET 30 day payment terms and agreeing to late charges OI per month Iorany invoices not paid within 30 days. 15-May-2007 Received on Samples Intact DATE Signed